Document 99bZGao142JVrqMMjOZ4jKka3

CRi NUMBER D-1223V ! p & D REPORT ' f - DOW C H E M IC A L U.S.A. \ ^ RESTRICTED^ for usa wilhin The Dow Cnamical Company oniy. 0pAHTMCNf *- a .CRT RPORrCQOc" oOaCrt/i7ss3u-.9z5 October 27. 1Q7R jUA. NW. >AOrik.fcMMC ORGANI IC CHEMICALS RESEARCH Ttrus DSO^flO'onnn A STUDY OF THE FORMATION AMD REMOVAL OF IMPURITIES T>T rrtr=! 57 PROCESS FOR 2.4-D *- - --- - *--- pages IN FULL REPORT AU T H U * lU K. L. Krumel S R . F. Arnold____________________________________ A U T H O n A* J i C M * ( U f t , w*t i- 0SCSIPTIVE SUMMARY WITH CONCLUSIONS: ^fT & -- ^ ___________ T h is [ Y ] INTERIM j x ] NEW n REVIEWreport ____ and mainly: s-_____n -ctNAL_____________ (Include in rhis space references ta dara boaicl, and to arliar ralarsa reports, parents and publiesrions.} Shortly after the startup of the 2,4-bD,,process-- ia-- 13-43 .Building, a new and unexpected class of nonac.iaic "'impurities were isoieTteA in which two of the major components '.'were 'tetrachloroxanthone .arid .octachlorospirobixanthene. These impur itie's"weTsT c a u s i n g - p r o b l e m ^ in the subsequent formulation of 2,4-D as amine salts. Q A project was started to learn the source of these impurities a n c s ^ methods for controlling them. It was found that the impurities o ^ - are formed mainly in the 2,4-D reaction star by several different70^ routes * * i'O--? A number of techniques were evaluated for removing the impurities were totally successful. None of the treatments pjd D IS T R IB U T IO N : r 1L i R 0 A 0 M 1N J S T J? A T 1 0 N CENTRAL R6P0PT ih O SX I j S lj g . -- - C O P IE S <$^00^-0 A -- 0 ! s fri b u t t o n lis t is e o n itn u a on atta ch ed pa^a* mw'-i CCR TABLE OF CONTENTS INTRODUCTION RESULTS AND DISCUSSION (a) The Mechanism of TCX F o r m a t i o n ---- -- 3 (a) The Distribution of TCX in the Process T ( c ) Reduction of TCX by Chemical Means --j (d) Reduction of TCX by Physical Means --GENERAL CONCLUSIONS SAFETY & ECOLOGY -- ;--E X P E R I M E N T A L ----------------- ACKNOWLEDGEMENTS -- REFERENCES r r'OC/73--;3 5' ' ' ~\ P cs 10 25 30 38 50 5-0 51 55 57 cK) O'hR _ 7 - O C / 7 3 - 35 ' M \ INTRODUCTION neMOZMOC! A process for preparing high purity 2,4-D was started in Mav 1977 a t 943 Building. The high purity no1 ten acid is transferred bv oice- l i n e from 94S Euilding to 489 Building where it is formulated into esters and water soluble amine salts. Starting in lata October 1977, precipitates were observed regularly in diluted amines formulations t h a t were found to be made up of a number of impurities associated with''the process but that were never detected during laboratory or pilot plant development work. In addition, these impurities were not fou n d in the old 439 Building 2,4-D process. R. McLachlan^* analyzed the precipitates and found 1,3,5,8-tetrachloroxanthcne (I: TCX) , 1 , 1 '3,3'6,S '8 ,3'-octachloro-9,9'-spirobixanthene (II: OCSX) and marginally soluble salts of 2,4-D. i A screening program in the plant showed TCX at levels of 200-500 ppm in the crude reaction mass, the recycle solution, and in the final product. Levels of 1000-2000 ppm were found in the solvent and as much as 102 in the ? M l tars. McLachlan analyzed a sample of summarized in Table 1. still tars and his results are 9,0^0^ OCR OC/73-3'5 : `-f Table 1: An Analysis cf One Tar Samcle S tructure Approxrmat: Comment i a\ o *> - D C ? " :" 2 , 4-D T C X (I) O C S X (II) ichlcrophenyldichlorcvinyl ether Dichlorcpher.vlttrichlorovinyl ether P T^23i 25% 0.5% 0 .01% 1 .5% 1 .1% 1 .2% ) ' f 0 .8% _ J . Main Component__ __ . From a heat exchanger leak (Dowtherm J) raw material Product Rxn product * a t least eleven other minor components structurally similar to the above. See Ref. 1 for details. V fj OCR -4- OC/73-9 5 A. project was started to study the formation cf TCX and 0CSX in some detail to learn more about their formation and fate in the process because it as net obvious how tney are made. Several months after ^ O T" "'s startinc this studv, another sicnificant imuuritv was found in the ^ * Ct produce and, to a 1-eSser-extant, in the tars. It was icaneiziec as (III: "3-3") 2 ,2 ',4,4 ',5 ',7,7 ',9-octachlorospiro-(bencofuro (3,2-b) benncpyran-Il,9'-xanthere). CO olOolC) Q> OCR. Ineartant Sica Reactions C l C H 2C a 2Na -r NaGK O C / /3-1.33 HOCH-CO-Na NaCi Glvcclic Acid W U M M l' /V\VJ>wl o Ul 1 T h e reaction is p e r f o m e d in two stages by first reacting 2.2 males of DC? with 1.2 moles of caustic (added as 50% NaOE) to form a solution of NaDC? in DC?. High purity 2,4-dichlorophenol (2,4-DC?) made by the chlorination of phenol with sulfuryl chloride in the presence of JeCl^/Diphenyl sulfide catalyst is used with chlcroacetic acid (MCAA) made by the oxidation o f vinylidine chloride to make 2,4-D as shown above. The typical ra w materials analyses for each is shewn in Table 2. Table 2: Tvcical Raw Material Analyses- for the 2,4-D Process v DC? MCAA 2, 4 -DC? 2 , 6-DC? Other Chloropheno Is 9 3.5% o-0.3% ^0.5% MCAA Dichloroacatic acid Chloromaleic acid h 2o 99.0% a.0.05% <1 .0% `Gz --o-- OC/73-S 5 N \ Cr O rc Ct O A rapid initial screening of the tonicity of purified TCX and tars gave the following results. Tar (contains 3-55 TCX -r OCSXJ Oral LD-a,,Q (sincle dose) >5g/Kg Skin/Eve slight transient initiation, chloracne response after 10 applications of neat tars. v Purified TCX >4g/Kg not irritating. Chloracne response after 10 applications of 15 solution in C H C l ^ . _K "1 " b 0 P\ IA l/l -81/30 1 DO 0CR - 8 - O C / 7 8 - 83 \ These results are encenraging from a plant hygiene standpoint, but more data is necessary regarding lcng tern effects. When the im purities were firsc discovered in the plant, the soil! was used very. occasionally'' The still was originally added to the process as a-way of purging contaminants out of the stream to maintain high quality recycle solvent. At this point, tar impurities made up 60-7^5 of the precipitates formed in diluted amines formulations. Of O' "T" ro cz CO About February 1978, the capacity of the still'was increased and the average levels of TCX levels dropped to 'voO ppm in the crude reaction mass and product and to 200-500 ppm in the recy cled From the period op March-Mav 1973, the ability to produce quality 2,4-Di continued to improve and the amount -of tar im purities found in the dilution test precipitates dropped . The'balance were sparingly soluble metal salts of 2,4-D and seme new impurities called Complex 1 and Complex 2, too of which are shown below (IV & V) . IV V I.. July 1973, the still capacity was increased and errorrs trained at uncerstanding the parameters affecoing formulation quality by S. Siegel (OCF.) , S. Schell (Production 439), ana J. King (Fcemulation - 9001 Slug) and their co-worhers have greatly improved D OCR _a_ C C / i 3-- 33 the consistency with \ upon parricien coeff to be discussed, lata .on of TCX cer.erated a com.outer of recycle the steady state level of TCX in the product would ha M.Q ppm and in_the recycled perc_ the TCX level, would be--- - ^40 cca. T h e purpose of this report is to present data on the formation and fate of the impurities in the 2,4-D process. In addition, the resu of experiments aimed at reducing or eliminating the impurities by chemical and physical methods will be presented. -- RESULTS AND DISCUSSION 4* _ 1I This study was divided into the following sections and the results of ' each are discussed separately. (A) The mechanism of TCX formation. (3) The distribution of TCX in the process. (C) Reduction of TCX by chemical means. (D) Reduction of TCX by physical means. Although there are many impurities formed in this process, it was decided to focus the research on TCX for several reasons: (1) The rate and mode of formation of TCX was the most predicable of the major multicyclic impurities; (2) it was a major impurity; (3) a .pure sample was readily obtained (by D. Humbert, Anal. L a b ) ; (4) the analysis is not complicated; and; (5) structurally, it is the simplest of the multicvclic imourities. GCS -10- O C / 7 3 - 35 '(A) The Mechanise of TCX F o o ^ t i o n A brief search of the literature including Chemical Abstracts shewed C7 O thee the xanthone ring system is formed from a numb er of reactions, A common synthetic reaction is" shown below'in'which the -X is included ro cn --0 to shew the orientation of reaction. Xanthone is formed along with other products from the pyrolysis of o-chlorobenzoic acid, salicylic acid, aspirin, o-phenoxybensoic acid, ancL salts of the carboxylic acids. Most of these cyclisations take" place in the presence of cidic catalysts such as ^2^5' - ^ ^ 3 ' Acetic anhydride, or sulfuric acid. Xanthone is prepared in reasonable yield by the pyrolysis of phenol salicylate with or without a catalyst. T h e ease of- formation of ring systems that acre structurally similar to xanthones is most clearly shown by the formation of fluorescein an d fluorescein dyes. Fluorescein"^ is made by reaction of phthalic anhvdride and resorcinol as shown on the following page. j i I v . r21 VLISZ M\Oa Phenalpnthalein 8 is also mads by this process using phenol instead o f resorcinol. v . Of* CR .V --1 1- OC/7S-35 Do\y 2G774G These background data give some important clues as to reaction mechanisms as will be w'nown later in the resort. % rvo i/i- CCR -13- OC/73-35r 1 ) In order to understand tine pathway of TCX formation, a series of > ampoule tests were performed to determine which chemicals and/or i combinations give rise to TCX. T**able 3 summarises the results of \ study. A series of ampoules ( 25 ml capacity) were charged with 3-5 gms of mixtures in molar ratios as shown inTable 3 and were heated in an oil bath fo 72 hours at 1S0C. The sources of the chemicals were as follows: 2,4-D: High Purity Rhone-Progil Acid DC? : Doubly distilled 948 Bldg ma erial Perc : NaOH ' : Giyaxal _: Glvoxylic acid : Reagan' ma Tetrachloroethane : (50:50 1,1,2,2- & 1,1,1, ials V OCR -Id- CC/73-3 5 V Table 3: The Formation of TCIC from Synthetic Mixtures Heated at 150 far 72 hrs. (o OCR OC/73-35 i Save: :sl ccr.pcur.ds other than those found in the process were tested. The :etrach!aroethane mixture is a known contaminant in tne 941 Blcg. chio: rcacacylchlcride that is used to make MC.--A. 2,5-Dichlcrcsaiicyiic a a c -c is a proposed intermediate `from the reactions suggested below: o 0 Mi* ci2c=cci2 A /0, :i-- -- Cl Metal OH(Na) OH 0 k OH u T h e decomposition of perc to yield phosgene is known but the second reaction is only speculated. Th e glyonylic acid is postulated to come from bis 2,4-D as shown below: which is a well known acetal hydrolysis. The glyoxal was included to show the general nature of the reaction whose mechanism is suggested later in this reoort. krXA DW 2U7750 gcr IS O C / 7 3 - 3 5 Several tentative conclusions can be mads from the data in Table 3. (a) TCX can be made by several routes siJaCH and/cr _NaDCB is neces4s* ary for the forma tic n of TCX. o b i s - 2 ,4-D appears to be a key intermediate. cBerc is a source of TCX. (b) Significant amounts of TCX are probably made only in the "'reactor crude storage tank in the plant since strong base is required. Run 14 (Table 3) simulates the Na 2,4-D storage tank (V-301: 943 Bldg) and Run 1 (Table 3) simulates the product storage tank (V-5G2: 943 Bldg) in which no TCX was observed. m order to study the formation of TCX as a function of reaction araneters, a series of 2,4-D reactions were performed in the lab oratory. These reactions were run to evaluate the effect on the amount and r a t a of TCX formation. The data are summarized in Table 4. In these experiments, 1.1 mol of DC? was treated w t h O . S mol of caustic and the mixture was heated to 130C. The majority of the w a t e r that was formed was boiled off. To this mixture, 0.5 mol of N a O H and 0.5 mol of MCAA were con-added during 1 hr at 1308 and the crude product was heated an-additional 1 hr. Water was continuously distilled out during the con add step. A t this point the desired number of ampoules were charged with 5-10 gms of crude reaction mixture and were heated in oil baths at 130, 1458 , and/or ISO8 for 24, 43, and 72 hours. C)7k I CCR -17 CC/78-3 5' Table 4 : Tbc P in c h e --V r .T n .^ i 1" *- 1 ( TJm 1 r ! 1 !. ! ***** /-- c t r r ' t f - - ci *S* Vt :u t s . i . - f i ' - i l i; t u w* VJ*=* 1i 3.4 j I !e4 1 -- At sic Affaccine the Formation of TCIC S e t i - ly d r c u s pro coco fa r P r o p e r in e 2 ,4 -D A< t. -- H. * I,, u. / ./ # C * r . ve * : i * -.. w T * --a t . -i c*m I 1U L. L- i1 r ii. -- N i A3. 14 n j1 /M I- >0 -- //*" re ; . ! r -t X uf /3 Ji t " or um l* u . ^ 110 J3 J /1 7 fm f il-- Ti *1 ` - 1/ 1 ce C o / V tri Ao* 1 y 1 1! cet' - & * s \ 'W .iri'iie * * . i i . T /itai 1 1 P 1 1 Z C t / / o ,* C 3 Z j U ^ > r fta i* . 1 ! s l-- j i ` m t - r i n ^4 ^ * / r r e M - r i , i . y_ r S 4 * "L a / lfa Jj4 *+ 4 i y p j i w -l ai T V ii 1/ s * y 1. C 7*J ! V A I A !1 i? j f w t iliU o l . aV A t ay a ""i C i/ S -A t h j i 1 -- r t X J. 1 y ' a - Z Z 1 -- J J I. r fijs . 1 !! i a / -a 1 1 */ 1i 7.y i//N 1 1 ii 1 ; aJ . A/S Au. / ja l /* Oj //a /ya rx rt 09 s -r 1 Z22! -- /r*T /4 vs />3 ya 1 J . T ry 7// /-- -- /i IC IH 3 t* t* . //* Aa A tu -- A u im A n i* -- / j ! -- -- JU 3 r- i. -- ./ s o l . V a . /a i V. a . 11 i i "r -- A 3 ! / a n o* 1 -- 4 -U 1*7 4? r- / tr a. A * i -- - :Jt < i \ - A3 M /SO 4* 1 - a/ fe A VI Si rr ti sz t m jt f . O c ^ A V m t ( a S a w 9 / -- O u / t Z C i3 A / / / n ftv ;U k U A S < S '- r -A it t S . I t a t i fi * r t * i- -/ e t j-r r " - / K C -- y > r . t o i o /s* i j. ~m J. -t fn t . yy/ a iJ ir M /sa V a * S c a r t a i . i iS e .7 Z C . O i t j r r t c j tu r s a m ia '. S c J i i i . ! r . t t t i , - ^ y O o v iT -s .-v rr* /o j : l A* / ./ i -- r j5 to a tZ S \ /oi 1 uo\ /m Vo nr A3 #4 * / <* J7t / / ,i / l i "* ~ / r r i r z / o + ** 4 27J S i ." \ A -e . - es* fe S/ jV - ! t f1 ^n 'OCR 13 O C / 73-35 T h e data in Tarla 4 show a nuotar of intarastinc coints. Ih IT.US ite eoi?ha si zac that in viaw of th fact that thesa data a. a basad or. carzs-rer-ziiilicn chaizistry, tha pracisicn must be su. jazz to s cita e The data ara racrcducibis to about 20"-. oO - ? co ' Ci - Cl co <9,0 CCR - 1Q- OC/7a-35 mere facile route to TCX from pre whese ef: higher temperatures by a primary routa (com:: an d P.ur.s 3 S 4} . :t is masked at the re Table 4, Pairs 1 & 2 (C) Effect cf .-.tmosphere in the Reactor trocar blanketing appears to lower the TCX level to ^2/3 that obser/ad in air. It is not certain that this rasult is significant and sir.ca the magnitude of the.drop was low, further work was not warranted. Since C Q 2 is known to be p r e s e n t ^ in the vapor space throughout the 2 , 4 -D process, a run was made to determine its effect on TCX formation. Carbon dionida comes into the process from the caustic and from pare deccmccsiticn. The.reaction was run as described earlier with 20 mol% of NaHCO^ added before the boil down step and then blanketing the reaction mass with C O 2 curing the post reaction heating step. Since this is a high temperature, nearly anhydrous process, the fallowing reaction was thought possible which could eventually lead to TCX (See Table 3, Runs 15 and 15). ONa ONa Comparing Runs 1 and 10 (Table 4) show that NaECO^ and/or C 0 2 co '* not measurablv affect the formation of TCX. On^ OCR 20- OC/73-35 (D) Chancir.c NaDC?/NaHC.---. Ratio Comparing Runs 1 and 7 (Table 4) show that levering the NaDC?/NaMC ratios significartly reduces the-CCX levels as was also rem the data in Table 3. The effect was studied furth r and is discussed later in this reoert. oC7 re cc (Z) ..Source of DC? A run was made using the old lower purity DC? from the 349 Bldg process an d assure that 94S 3ldg, high purity, DC? was not a source of TCX. R u n 6 shews that TCX formation is not associated with the source of DC?. (?) Effect of Ferric Ion Runs 11-14, Table 4, show that F e `^ clearly increases the rata of TCX formation which suggest that aDcylation step(s) are involved! D. Humbert a n d colleagues"^ performed a material balance of Fe in the fallowing scheme. NaOEDC? MCAA- Reactor Recycl; Phenat; Product 9\b A s cl cc/ / 0-- o Z T h e y fcur.d that test of the iron is entering the prccsss in the caustic ar.c that the reactcr normally contains 20 com of F e " ^ . A recurrinc problem for the past several mc'nths was how to explain the fact that V A plant observed TCX form.atacn rates were 5 times greater than j-1a, Lab " *^bs von results exclaim at 1east pare of this discrepancy and suggest that efforts aimed ah removing iren from the process are .desirable. _ __ ______ 3ased upon the data presented up to this point, the mechanism shewn, in Figure 1 for TCX formation is suggested. This mechanism is consistent w i t h the observations of the effect of caustic, the fact that TCX can b e made from NaDC? and glyoxal or glvoxylic acid and the levels of bis-2,4-D. If this mechanism is correct, it is easy to see how perc e n n influence TCX formation when one considers the possible hydrolysis products using either NaOH'or NaDC?r Some of these possibilities are shewn in Figure 2 and many a r e `known precursors to TCX. I n addition to TCX, OCSX and "8-5" are known to be formed in measurable quantities during the reaction to 2,4-D. It was initially assumed that T C X is the probable precursor to OCSX and "8-3". However, a series o f ampoule experiments in which TCX was mixed with various, ratios, of..... DCF, 2,4-D, NaOH, and perc showed none farmed in detectable amounts. In addition, a reaction was run in the presence of 500 ppm of added T C X and gave normal levels of the impurities when the 500 ppm of added T C X is subtracted out. It is apparent that OCSX, "3-5", and TCX are probably made by independent routes and proposed mechanisms are shewn in. Figures 3 and 4. v Figure 1: Proposed Mechanism of TCK Formation o o -c* rc c: <E CT cs OCR -23 OC/73-32 , li.i'u 1'.'-'- Fi~urs 2 Seme of the Possible Products of the Hydrolysis o: chloroeuhvlens with NaGH or iiaOCP nO-k-**-\ i ^/0H '---2 ~\ Z XCl n 20 C H C 1 2 -C DC.--A OH... -N-a-O-C-Pc._2^ -C Cl 2 'CKx ~ Cl OH N C=c(/ Cly OH known inouritv CEC1--C 2 \H r~ r* 1 zsf c -"2 ' 7 --2 3 .HO X C=C/ Cl]y/ N i l Cl 2 NaDC? Cl CCI ''OOCI. 1 - Tauton -p* HC-C02Na *2 -H-2-C\HC12-C-H, H 2.221. S < a " HOX ^ C 1 h 20 . OOCI 3 NaOC?^ (C i2io) 2C=C Cl 4 OH or ^ 4 ;;aoc? 00 Il II HC-CH HC-CO 4-,51a 0 Cl Il I H-C-CH 'ooci. Id 2- 3: Propasad Mechanism far the Fcrnatico of OCSX By a Routa Thar is Indscer.dsnt of TCIC O ? N 3 Ct Cl CO NaOH v 2 ring closures as shown in the TCM mechanisa OCS oa-o,^ hii AiAi OCR OC/73-3; . Figura Proposed Mechanise far ths Formation cf "8-5" By a Routa that is Independent of TCX t OCR -1C- OC/73-35 The fcrmauicn cf OCSX uses an intermediate in the TCX mechanism as its s e a m i n g material The apparent fact that TCX is not a n r*"3i","niscL^3 suggests is necessary for alkyllaattion. The. mechanism far "3-5" formation involves a major component' in the Complex I and II mixture as a ^n s h a m i n g materia l . Recent analytical results" have., shown- -- - ^>100-200 ppm of this mixture in the process. A proposed mechanism far..the formation of Complex Acid I is shewn in Figure 5. It m u s t be emphasised that the mechanisms shown in Figures 3,4, and 5 ara speculations and are only one of a number of possibilities. M u c h more work is necessary to prove their accuracy. OCR oO Fi re oc/7; 5 : Procosed. Mechanism cr tha Formation of the Major Inpurity in Complex I mixture (Compound IV) Bis H20 ---- > 2 DC? :0 0 2 2f - C O COMF1 ACID I OCR _ 7Q _ OC/7a-35 V-50 Final Product Storage Tank: Testa m at 120-1759 on it " wet and dry 2,4-D shewed than there is an initial slew build up ci about 20 ppm of TCX during the first 43 hrs at >150 that stabilizes out. This suggests a snail around of an unstable unknown species that decomposes in-acidic media. Molten 2,4-D can be treated for at least 100 hrs under the above, conditions without affecting product performance. oC7 re. cz Since TCM is farmed in the reactor and was found throughout 943 Bldg process, a laboratory study of the distribution was requested. In this experiment a reaction was carried out and the crude reaction mass was spiked with TCIC. The purification process was then-'simu lated and the fate of the TCX was determined. Figure 6 summarizes the results of the extraction study performed at 90/atm. S iO iS o ' OC?. -TQ_ C C / 7 3 - 35 These data shew an excellent TCX recover*/ an which/ using claan zero, all the dezectable TCX is removed from th Na 2,4-D solution. Tha ) f2.cn that tha olant observes sens TC1C in. ha produce suggests that seta e n o r s m e c pare as carraac c,vernead so immunities _ .'carried with it end in tha product. The excraction of tha ce-c/DCP ' r:- mixture with caustic_ to recover tha NaDC? also extracts about 51____ 13 o f the TCX which is recycled to the raactor. This schema was followed in a second experiment that was performed at 1253/ 35 psig which more closely follows the plant conditions. Under these con ditions the aqueous solutions can be mors concentrated in Na 2,4-D, NaCi, and DC? which could affect the distribution of TCX. * A high pressure, mechanically stirred glass raactor was constructed and was charged with partially neutralized material from V-301 (tha DC? neutralizer). The molten material was extracted six times with perc at 125C and the molten 2,4-D was isolated. The TCX an d "3-5" levels were monitored throughout and the analytical results fo r tha products are summarized in Table 5 for the two r u n s . The data shew that TCX is effectively removed at the mare drastic condi tions. Table 5: The Analysis of the Product from the High Temperature Extraction of Crude Na 2,4-D with Clean Perchloroethvlene TCX (ppm) Run init final 1 292 2 173 13 2 "3-5 " (ppm) init final 54 N.D. 52 25 Ms ils (com) Na Fa Ca Na 34 5 40 13 91 3 50 15 I t is interesting to note that "3-5" is not efficiently removed with perc extraction. Henca most of what is made goes out with the redact. OCSX was not detected in these samples. OCR. -30- OC/73-35 Oc c; Assuming a rata of TCX formation of 0.5-1.0 f/hr it the plant i. (based upon analyses or plant sarnies) K. E. First' has taken distribution coefficient data and has modeled the orocess in terms of TCX content in various streams as a function of '% of perc distilled in the perc still. To date, there is not enough in-plant data to'verify this model. (C) Reduction of TCX by Chemical Means ,.o approaches for chemical reduction of TCX were studied. These were methods for reducing it from process streams. The following approaches were studied and each will be discussed in detail. 1. Changing NaDC?/NahCAA ratio. 2. Post reaction neutralization. 3. Effect of DCAA. 4. Bleaching Na 2,4-D solutions. (1) Chanoine NaDCP/NaMCAA ratio Excess caustic or NaDC? was shown earlier to have a significant qualitative effect on the increased production of TCX. The 2,4-D reaction as developed by H. Brust^2 used a ratio of NaDCP/NaMCAA = 1.2. As described earlier in the discussion, at this ratio the product contains theoretically ^6.3 mole % excess alkalinity as NaDC? ' ' shown on the following page. / OCR \ S tc M a t '1 0.5 mcl DC? 0.6 mol NaDC? 0.5 ml NaMCAA OC/73-3 0.5 mol DC? 0.1 ml NaDC? 0.5 mol Na 2,4-D 0.5 mol NaCl (below 1.2 lead to lower yields based on MCAA and, (b) low H 20 in solution gives higher 2,4-D yields. The effect of changing the N&DC?/NaMCAA was restudied in order to determine if the lower yield f m c m MCAA could be justified by reduced TCX formation due to less excess caustic. Tiie runs were carried out by using a constant amount of NaMCAA and varying the amounts of NaDC? which was done by adding differing amounts of caustic in the initial boil down step. Tables 6 and 7 and Figure 7 summarizes the results of this study. These data show t h a t lowering the ratio from 1.2 to 1.1 results in a 'two fold reduction of TCX along with a 1% loss in MCAA, yield. This is reason a b l e and was tested in the plant. After three weeks of operation, t h e y did not note a measurable reduction for reasons that are not understood at this time. Ariy further reduction is not practical sizica the yield rapidly approaches that of the old plant thereby losing much of the advantage of the 943 Bldg process. It is inte resting to note that at ratios below 1.0 there is still a measurable amount of NaDC? which explains why formation of TCX is still observed A l l of the data to data indicate that formation of TCX cannot be limited to much less than 60 ppm (in the standard 72 hr/160C ampoule -j - OC/ 7 0-0 b TABLE 6 EFFECT OF NaDCP/NaMCAA RATIO ON TCX FORMATION & YIELD ON 'NCAA I RUN REF DCP l OC 417-5-143 0.50 Moles NaDCP 0.60 NaMCAA 0.50 Mol Ratio NaDCP NaMCAA 1.2 ppm IIOG 951 MCAA YIELD 96.44 CRUDE ANALYSIS Na 2,4-D 45.4 DCP NaDCP 31.2 0.9 2 OC 417-5-144 0.55 0.55 0.50 1.1 1514 94.2 45.5 30.0 6.0 3 OC 417-5-146 0.60 0.50 0.50 1.0 3000 06.0 41.3 40.3 2.2 4 OC 640-1-1 0.61 0.49 0.50 0.90 3606 06.2 43.0 41.7 2.5 Mar: 10 . 77. 7. I I *I M oq rn./.nc OCR -33- L ' L L M H \O d OC/7Q-5 t a i h .e 7 Mnncp_ THE RATE OF TCX FORHATIOM AS A FUNCTION OF T IM E , TEMPERATURE , iMCAA RATIO nun REF i 417-5-143 2 417-5-144 3 417-5-146 4 640-1 TEMP 130 145 160 130 14 5 160 130 145 160 130 145 160 18 HRS 37 29 18 0 27 42 <10 15 29 17 23 36 TCX/OCSX 42 11RS 66 HRS 34 86 ` ,42 19 39 74 19 70 110/107 66 33 64 93 <10 . 20 47 / 28 31 61 15 41 55 22 34 65 114 HRS 53 218 i 24 0 * 114 llrs 52 93 14 2 90 llrs 30 59 67 90 llrs 18 52 77 OCR .. . "34_ OC/73-5 5 Oc?. T O C / 7 3 - 33 . (2) Post Raction Neutralization. ) iJ . G. Aar stir. suggested that if the reactor crude were immediately t treated with enough acid to neutralise the NaDC? after the cost 3 reaction before transfer to the reactor storage tank (V-202) , TCX ~ foroation might_be greatly reduced. This concept was tested using " 32!; EC1, and dry and wet 2,4-D as the neutralising acid. The first experiment used enough dry 2,4-D to completely neutralise the residu 31 N a D C ? . The neutralised crude showed 1.4% NaBC? and a rate of TCX formation as shown below that is consistent with the data shewn in Tables 6 & 7. oora TCX Tsrriw ISO0 24 hr 24 43 hr 51 72 hr 62 T h e use of wet, molten 2,4-D ( 25% r^O or 32% aqueous ECl has some serious physical handling problems. A s was discussed in an earlier r e p o r t ^ , water added -to 2,4-D raises the freesing point of the mass creating a mate, ial similar to- ccusage-cheese in consistency. In addition, the added salts (either Na 2,4-D o r NaCl) also raised the freesing point of the reactor batch from a ranee of 115-120C to !iS-1250C. In summary, whereas post reaction neutralisation reduces TCX by a factor of four, it offers several disadvantages: (a) it would add at least 30 min - 1 hr to the reacsion cycle inu a olant already reactor limited near caoacity operation. (b) Addition of acid could causa corrosion problems in the Incoloy 300 decanter . (c) The possibility of praci sates farming i n `the reactor would u a .* -- cassive ssresses on the agita r. Their fermasion could not be a\ 'OCR G~ - ? CC//g ~o; DOW in the laccrttcry even by very slowing adding the acuecus acid. (c) Control cf the acid addi tier, would be dif;----wa m----]tw , iJnw the plant would have to run a slightly smaller batch size in order for the acid. Further work on this concent i.s net warranted at this tine. rc ct (3} DCAA Content of MCAA T h e effect of DCAA was discussed earlier. (4) Sleachinc Na 2,4-D Solutions T h e major chemical difference' between 943 3!dg and 43 9 Bldg technicues fo r processing crude 2,4-D is that 439 31dg uses'a bleach step in ; ich residual DC? is oxidized out of the Na 2,4-D solution with 8-- 125 NaOCl at pH 1Q.5/100C. Several experiments were performed to determine if bleach would effect the impurity levels and/or improve the ability of the plant to consistently produce 2,4-D that passes the formulation dilution test. The results of these experiments ar e shewn in Table 8. T h e results of the first experiment appeared very encouraging since the dilution test solids, the TCX and the "8-3'' were all significantly reduced. The second series of runs showed a consistent improvement in dilution test solids when near or out of spec, but not much effect .4 on the impurities. A capital estimate perzormed by K. E. First showed the cost of implementing a bleach step in 2,4-D to be $3G0wM which immediately eliminated any further interest in this project in viaw of the marginal benefits. It is assumed, posthumously, that the main effect of the bleach was to reduce residual DC? which is a 'known contributor to ooor dilution test results. OC OC/73 3 Tbia 8: The Tra a n cf Na 2,4-D Soluticr.s viti 3leacn Na 2,4-D Solution Scorce cH Mol Ratio NaGCl Na 2,4-D mi sci ^s .. DM-.-4 F-40 V-501 (4-7-73) ' 943 Bice. starnine material 10.5 0.1 0.13 0.02 Imperizies (?==; t c :c CCSX -a-5- 53 N.D. 127 25 N.D. N.D. V-501 (6-5-- 78) 943 Bice - starting matarial 10.5 0.1 10.5 0.2 10.5 0.05 10.5 0.1 5 0.1 0.01 TU TR -- -- ------ TR TR TR -- -- ------ 80 - 35 85 104 94 72 N.D. It n rt ti n 31 10 25 23 15 47 o re c: -- -i v OCR -33- OC/ /a-2 5 (D) Removal cf TCM by Physical Means To date, a s .age has been reached in 943 Bldg, where the 2,4-D "3"= "tl CZ*' 33 wC ccr^s -- 2tiar' *v wirci"',^a in-spec nacerial and has camensorasea an abaunty to run at near ca parity of 100-120 M=/day With the cere still.'running at v!5 GFM, tfie 2,4-D product contain -v.20 com of TCM and ^20 pen of "3-3". A numbered attempts have been nace to see if the levels of TCM can be reduced bv ohvsical means that include: O O rc ci to 1. Carbon treatment of'the recycling perc and the molten 2,4-D. 2 . Removing perc from the reaction step. 3_. Improved washing of the molten 2,4-D. 4. Recrystallioahion of Na 2,4-D and recrystaliioaticn of 2,4-D acid. 'he details of each alternative are discussed below. In all cases, these experiments were short term, range finding efforts and^ not comprehensive. Further work is justified only if the levels of im purities presently found in the product prove unacceptable in the future from a toxicity, environmental, or performance standpoint. (1) Removal of TCM with Activated Carbon The removal of TCM with activated carbon from perohloroethylene from V-402 ("clean" perc storage tank) was evaluated by a standard isotherm method. A 100 ml portion of perc was treated with ground Pittsburg SGL carbcn at 70C/72 hrs. The data, summarised in Table 9, were evaluated by a known technique that is summarised below, va plat was made of X/M vs. C on log-log paper as shewn in Figure 5. By e:-:trapoling C to incoming TCM concentration,- the corresponding X / M value gives the amount of impurity absorbed per unit weight of carbon when that carbcn is in equilibrium with the incoming cancan- .ration and recresents the ultimata capacity of the carbon. The J-r\ OCR C C / 7 3 - 35 . ' theoretical volume of liquid to be completely freed by TCX/gram. of carter. is calculated from the fcllcving ecuacicr.: . C3 JO-JCo CO V theoretical v o l u m to be treated. = capacity/gn at incoming concentration V = volume of licuia used in test Co = incoming concentration . F or this experiment: VC0 = X 100 = 155 mi/g of Carbon or 19.9 gal of perc/= C or 255 % perc/# C Carbon loading at 241 ppm of TCX in feed = 155 ml/g C x 1.6 g ml x .00024 = ' 6 4 mg/gc v cc?. -4 0 - O C / 7 3 - 35 w O Table 9: The Absorption Isotherm for TCX Renoval fro ethylene with Pittsbrp SGL Activated Carbo n CiTw" rc cz <1 oc?. fa r> O 0 o OCP. -42- OC/73- 3 This is a low loading level and at the present ra tes of TCX pro duo tien 15-20 # of carbon per hour would be required to remove the impurity. The data shewn in Table 9 ir.di that carbon cces net.remove "3-3"' fret pert. The shece of the iso there; curve indicates that tore that one species is being ab sorbed*onto' the,carbon. 'No effort was. made to determine the identity of that compound although it was probably perc. o A. run was made to remove impurities from wet molten 2,4-D. Since molten 2,-D is so difficult to handle at atmospheric pressure, pressurized system was built using a capillary feeder for controlling the continuous flew of molten 2,4-D at 1QQ/2S psig onto a vertical 2' x 0.5" column that was maintained liquid full. The flow rate was 10 ml/min down the column far a mass flux of M..0 gpm/ft. 2 The results are summarized in Table 10. _ Table 10: The Treatment of Molten 2,4-D with Activated Carbon m Temo (C) csic Approx Approx. feed Prod, cut ml/hr (ml) Product Analysis (ppm) TCX ocsx 1 ico U1l 3 F-40* sal ids... (ml) 112 110 2 110 no no no 23 2 33 33 33 33 300 100 600 375 600 .375 600 375 600 ' 375 42 N.D. 32 .005 ---- -- 14 N.D. 29 .04 ! 23 N.D. 33 .005 32 N.D. 42 v 30 N.D. 36 1 tuia tien contains 23 Versene & 03 PG 4000 -e data are fairly c ude in that the column was shot than is desirable og^amum column work coLumn was a little (2* vs fas ter the reco:amended 5-5 18 > and than the mere desir able in o the flow through c-*om/%t"7 recommenc.es 12 OCR GC/73-35 now r*'**TV The data shew that TCX load!: ,c is rather low. Breakthrough CCCUCCSC after 900 ml molten D (^9 35g pure 2,4-3) was treated. From the analyses, the 59.3 ca of Pit: .3burr SGL 3 x 30 granular caret * * charred to the colts absorbs d 231 mg of TCX for a loadinc of ^0.5 mg/g cf carhcn which is quite low. Again, "3-5" was not absorbed by the carbon. Based aper. these preliminary experiments, carbon absorption of these impurities is not an attractive puriracatton tecnnacue. (2) Remove Perchloroethylene From the Reactor Since cere is known to give rise to TCX, several methods were examined to eliminate its recycle to the reactor. A t present, since pert is soluble to 1.25 in the recycle NaOCP. solution, there are about 350= returning to the reactor in each batch. Since a continuous percphenate phase separation is performed in V-401 just before recycle to the reactor, a brief study was undertaken to evaluate the phase separation to determine the time required for complete layer separation and the solubility of perc in NaDCB solution. A solution of 625 NaDCP and 25 NaOH in water was slurried with an excess of perc and vigorously stirred for 30 min at 7 5 a . The stirring was stopped and the phenata layer was analyzed for 5 perc as a function o f time. The results are summarized in Table 11. These data shew that the solubility of pert in NaDCP is 1.300.15 at 75C and that layer separation is complete within 15 minutes. The residence time in V-401 Is ^40 minutes so that with proper operation, no layer separation problems should result. The question was also asked if the p e r c W a s entrained in the NaDCP solution as an emulsion or was it in solution? A sample was centrifuged at 60 (minimum temperature) far 30 min at 'v-iOOO rpm and 1.25 perc was found in the phenata. It is concluded that the present equipment gives optimum layer separation and the 1.25 of oerc is soluble. DOW > 8 7 7 7 8 CCR 4 C C / 7 3 - 33 Table 11 The Solubility and Separation Rate ai Perchlarcethylene and 62* NaDCP in Water at 7 5 3C TXZ--- * 5 min 15 " 30 " 1 hr 2" `4 " 6" 24 " ' e m xn Phenate Lave: 1.9 1.3 1.4 1.5 1.4 1.4 1.2 1.3 *Time zero is when the vigorous s ,nc of the two 1avers V OCR OC/73-3: 2 U7 7 7 J Several attempts were mads to strip perc from the reaction mass and : plant tried to strip perc frtm the m l boil down step. Whereas no the. distilled. organic layer to the organic layer was discarded. m s 350= of DC? to th^ r, in this experiment' even after 4000# of DC? was distilled off, there was still detectable perc in the distillate- As a result, this approach was judged impractical. Two attempts were made to distill the 1.35 of oerc from the 605 NaDC?-25 NaOE solution. The first involved a batch distillation from a standard solution from V-403. A to tal of 65.9 gms were distilled out and 73.35 of i tI I I I ! the perc was removed. The reaction was then carried out as usual and samples were heated for 24, 48, and 72 hrs and-the results are summarised below. These data suggest that distillation of 755 of the perc does not reduce TCX formation (See Table 4, Runs 4s 5);. ppm TCX Temo 160 24 hrs 21 48 hr 75 . 72 hr 145 The second approach taken for stripping out perc was using a falling film stil T.# The resulis of two experiments are shown in Table 12. The resul shew that, as before, 70-305 of the perc is easily zrsmcvsc p. i*iii but that last 205 is likely to be quite ficult. No mere wcric is planned in this area until it can be better proven that removing oerc orrers anv real acvantace an reaucang rates or TCX formation. v (3) Improved Washing of 2.4-0 Acid Several experiments were run to see if improved washing would affect impurity levels in the 2,4-D product. A sample of 2,4-D product was taker, from V-502 (943 Bldg) and. was treated in the following ways: (a) A 250 cm sample of molten acid was washed 3 times with-2QQof water Per wash at 100C. M n l A1 t IO CO 1 OCR -4 5TA3LZ 12 OC/73 p^eiinirarv Data for Faliinc Film Distiilauicn of Perc From NaDC? Solution Still: 1 " x 12" Tube oSj O '"a. -cti T s n p (col'm) " (feed) F e e d R a t a (ave.) Run 120 75s -..... . - - - --- R u n 2 ATM. 75 10 ml/ m i n 10 ml/min rc : ^, < CO o Overhead Temp Feed analysis .% P e r c % DCP 8 5 '-- r 90 1.0 51.5 90-- > 953 1.1 50.1 W t . C h a r g e d (Feed) 725 gns 733 gns Product: Wt % Peru % DC? 652 gns 0.3% 53.9% 645 gns 0.2% 61.6% % Perc 46.7 gns 1.5% 75.0 gns 3.3% <2-0 OCR --47-- OC/73 (b) Another sample was reacidified to pH 0.5 with cone HC1 and o rewashed 2 titles with water at 100C. -i. (c ) A synthetic V-501 mixrure was made up using Rhone Frcoil 2.4- D ta determine if any impurities are made in the washime co step. The synthetic mixture was acidified and washed and the 2.4- D'was recovered for analysis. This experiment was repeated in the presence of 2750 ppm of added TCX. iT h e results of these experiments are shown in Table 13. Based upon ' these experiments, it is shown that the impurities are not made or reduced by improved washing. If anything, they are slichtlv increased; in the product due to the greater solubility of 2,4-D in the'hot watero r brine. (d) Recrystallisation of Na 2,4-D and 2,4-D Acid A n attempt was made to determine if the impurities could be removed by recrystallisation of Na 2,4-D from water and 2,4-D acid from organic solvents. Na 2,4-D was recrystalliced by taking 500 gms of material from V-501 and adding enough water (350 ml) to form a-hom o geneous solution at 10 0C. The solution was cooled and the precipi tated Na 2,4-D was filtered and washed with 55 brine. The Na 2,4-D was redissclved in hot water and the 2,4-D was isolated and analysed. The results are shown in Table 14. In two separate experiments, 2,4-D from V-502 was recrystalliced from perchloroethylene and ethylbenzene. A weight ratio of 3 parts solvent to 1 part 2,4-D was heated to boiling, the water contained in the molten 2,4-D was boiled out as an acetrope (the organic distillate was returned) and the solution was cooled. The 2,4-D was recovered by filtration and the solvent removed by heating in a vacuum oven at \,a0C. The results are summarised in Table 14. CCR -43- OC/73 1 The Effect, cf Improved Washing cf Ma it 2,4-D en Levais ci Xmcii^ri. ss C O ro ce -vl CG No te Rhone Procil 2,4-D shews no detectable TCM, OCSX & "S tf ^0^50 OCR jo $ T -49- CC/73 14 : The Effset of Recrvstallir aticn of Na 2,4-D and 2,4-D Acid on Imcuritv Levels Recrystallire Na 2,4-D Before* Recrystailire 2,4-D From Pert _ Recrystailire 2,4-D From Ethyibenrera After Before After Before After Impurity Level (ppm) TCX OCSX "3-5" F-4 0** Dilution 53 -- 127 0.13 81 53 54 0 .3-r Comment Product Eichly c lorad 52 N.D. 45 1 N.D. N.D. 52 N.D. 46 N.D. N.D. N.D. - kk k 91% Reco very of 2,4-D - 87% Recoverv of 2,4-D 'The impurities analysis was performed on a sample of 2,4-D acid isolated from Na 2,4-D without any extra treatment. *20: 1 dilution in 1000 ppm hard water, formulation contained 2* Versene and no P-4QQQ. **The recrystallited product behaved like the hich purity Rhone Procil 2,4-D which is difficult to formulate as was mentioned earlier in this report. GENZPAi CONCLUSIONS X and other non-acidic impurities are formed chieflv in the reaction s ep of the 2,4-D bv several routes. A numcsr or attempts to chemically and physically remcve these soecies nave met with limited success. SAFETY & ECOLOGY i 2 , 4-Oichlorophenoi, 50% NaOH, and chloroacetic acid are highly tcuic and corrosive raw rnau'ieis. When Kaiiaii.iu, the protective clothing included lab coat, rubber gloves and gaggles, and when passible, a i l operations were performed in a fume hood. A number of operations were carried out at elevated pressure which required the use of a __ice shield and secondary shielding in the hood. All waste samples a n d solutions were sent to the burner for disoosal. % I oc: OC/73-35 TT r 1 The Pracaration er.c Worlds of 2,4-D 3 -The following is a general ascription of the procedure used to 4 prepare and isolate 2,4-D whan simulating 943 Bldg. A 1 liter n round bottom flash equipped with a bottom drain, two rancirg funnels, a mechanical stirrer, a thermometer, and a distillation head was charged with 179g (1.1 moles) of 2,4-DCP and 43 g (0.6 moles ) of 50% NaCH. The flask was heated with a heating mantel attached to n a n I"R Thermowatch controller. The reactor contents were heated while stirring and a DC?-watar aretrope was distilled out. The distillation was continued until enough water was removed so that a temperature of 13 0C could be achieved. Normally 9-10 ml of E 20 and 2-3 ml of DC? were removed. T h e DC? was returned to the pot. Then 47.3g (0.5 moles) of melted M C A A and 40.Og (0.5 moles) of 50% caustic were con-added from the two dropping funnels during 5 0-50 minutes at 130C. The 'rates of addition w e r e carefully controlled so that neither added reactant was signi ficantly in excess of the other. Water and DC? continuously distilled o u t during the con-add and the DC? was returned to the reactor. After -c the addition was complete, the reaction was heated an additional 60 minutes. About 43-47 gms of H 20 was recovered in the con-add step. A t the end of the pest reaction samples of the viscous crude reaction melt were taken into amooules,*if desired. Th e work up procedure for isolating the 2,4-D is as follows: (The amounts used assumes no samples were taken after reaction). The reaction mass was diluted with about 500 ml o f water, heated to boiling to ensure complete dissolution and the pH was adjusted to 5.2 0 .2 with about 12 ml of cone HCl. The solution was then extracted with six 150 ml portions of pert at a temperature of >90C to remove the DC?. Occasionally 50-100 ml of additional H20 was. necessary :a_ keerL-.i L on the solids dissolved. Nr-i j -- -~1 0 ^ . 1 . . ^ : - . , OCR CC/73-23 to bailing and any traces of perc were distilled c i f . The cH of the solution was then lowered. to 0.5-0.7 with about 55 mi of cone EC! added rapidly and the me iter 2,4-D laver was seoarated and drained A* * " into a beaker. The restitirg brine was discarded. The 2,4-D was reslurried in 250 mi. or hot distilled B^O in.the pot and washed in this manner two times . The final pa of the aqueous layer was 2-7-2.9. The 2,4-D was recovered and dried o v e m i c h t at ambient tamo era fares. oC7 c CO CD The analyses of product and intermediate streams wer personnel in the 948 Bldg quality control laboratory for TCR, OCSX, and "8-5" were performed as described Derfarmed bv The analyses ,. 8 The Carbon Clean up of Molten 2,4-D v A glass pressure apparatus was assembled in which molten 2,4-D was pumped onto a carbon column (downflow). The apparatus is shown schematically in Figure 10. The flow of 2,4-D was controlled by c trolling the pressure drop across a capillary tube. To handle <^09^5^ Ftgura A Schematic Drawing of the apparatus used far Extracting DCP from Na 2,4-D with Perchioroechylene. (' CO ow 207780 w -J CCS 3- CC/la-3 5 r mcltan 2,4-D reliably and effectively, required at least 10 psic/ /vlQ0-l0S3C to avoid flashing and freezing problems. The 2,4-D and a slight excess cf* water were placed in the feed tanh and heated to 110C. When, the entire contents were melted the valve on the bottom of the column was closed, the column was filledwith molten acid to 1" above the top of the carbon, and the system stood for 60 min. The pressure drop across the capillary was adjusted to 7 psi (^IQ ml/min flaw) and the valve on the bottom of the column was adjusted so as to maintain the liquid level above the carbon bed. The results are shown in Table 10. C . Q L L 3 Z /'Nu v l n -''OCR >t '-56- OC/To-3 5 A CI\^0W~LE3GZMZNT S T h e anthers wish to thank D. Eurrert, R. M a d e G. Jewett, ?. Schlcenann, and their celleacues analytical support- The assistance of K. Firs madelinc efsorts- are also acknowledged. or their and his Droces oC7 rc -a V OCR z t-- GC/73-S 5 '-'nXK! niH-IMM O H REFERENCES 1. R. McLachian, D. E"" -ert, G. Falles, AL 7300101, tc b 2." p . Keller, et . a l . , EET K-272- (13) 9 f 1973 3. D. Humbert: et. al., unpublished results. 4. Unpublished results to date. 5. -Beilstain I, 17, 354. 6. Organic Synthesis Coll, Vol 1, 'Pg. 552. 7. Beilstein 19 (3) 222, Merck Inden 9, 4040. a. (1963)< Pg. 634. Allan and Bacon, Boston 9. (a) S. MacLean, AL-75-20Q21. (b) V. Stevens, 'Ccnnunicaticn, Inoroanic Chem. TSSD. . Humbert, unpublished results. K. L. Krunel, LR 73-74, 8-15-73. * H HH lo H. F. Brust, OC 0730013-2, 2-25-73. 13. Y. R. Dhingra OCR Lab Book OC 327-5 , p. 22-57, 1972. 14. D. L. Fern, PE 73-10, 4-15-73. F. G. Aerstin, private discussion. 16. K. L. Krunel, OC 73-17 LR, 39-73. 17. S. Si egei, Results tc be published. 13. Absor ption Handbook: Issued by Act ivated Carbon Div., Calgon C o r p ., Pittsburg, ?A. H Ul LABORATORI NOTEBOOK REFEREMCES : R. F. Arnold OC 417, Pg. 109-150, OC 640 Pg. 1-73. K. L. Krunel OC 559, Pg. 95-131. D-12330 a , 4 - OEKZtd&i a* ! pFT /! loon E.R. Zumwalt, Jr. Admiral, U.S. Navy (Ret.) 1500 Wilson Boulevard Arlington, Virginia 22209 Dear Admiral Zumwalt: The Agency has recently received a full and unexpurgated copy of the Krumel Report, the Dow study which documents the formation of xanthones during a 2,4-D manufacturing process and the company's efforts to prevent the formation of those contaminants. In a June 8 letter, you provided this Office with an expurgated version of that report and asked the Agency to consider its implications for the regulation of 2,4-D compounds. At that time, I had informed you of the Agency's plans to locate and evaluate the full report. The full report contains information that DowElanco (the successor of Dow Chemical Company) claims is Confidential Business Information because it relates information on manufacturing technology. The Agency is following a formally established procedure to verify that claim. The claim by DowElanco prevents the public release by EPA of the/ full report pending a determination of the validity of the claim. DowElanco has also provided a copy of the report from which all the material claimed to be confidential has been deleted. This expurgated report has been placed on the Public Docket, and I am enclosing a copy for your use. The new expurgated version differs somewhat from the version you transmitted in your letter of June 8; there are fewer deletions. The Office of Pesticide Programs is researching toxicologic data on the compounds reported in the Dow document. I will keep you advised of the outcome of that review, and of the Agency's judgement on DowElanco's claim of confidentiality. Sincerely yours, n//^ 1 A Douglas D. Campt, Director Office of Pesticide Programs Enclosure H7508C:SRB:J.Bloom:WF3-1N4:308-8019:11/14/90 O R & D REPORT D-12233 / Z .4 -t> C O N H U . ... , D O W C H E MBUSIICNEASS LINFOUR.MSAT.IAON. LABORATORY REPORT CODE OC/78-85________ R E S T R I C T E D : for u se within The Dow C h e m ic a l C o m p a n y only. OATE is su ed DEPARTMENT October 27. 1q78 LA B . NO. P R O B L E M NO. ORGANIC CHEMICALS RESEARCH oeobooooin A STUDY OF THE FORMATION AND REMOVAL OF IMPURITIES IN THE SFMT - ^ 5 H 00 HYDROUS PROCESS FOR 2,4-D CO ( UJ O c2a A U T H O R IS) G) 3 N Z ' K. L. Krumel & R. F. Arnold A U T H O R (SI S I G N A T U R E (SI C U PAG IN FI REPC REVIEWER'S S IG NA TURE D ESC R IP T IV E SUMMARY WITH C O N C L U S IO N S : This report is: ixlI N T E R I M 1 1F IN A L and mainly: X NEW REVIE ( I n c l u d e in this s p a c e r e f e r e n c e s to da ta b o o k s , and to e o rl ie r relc reports, patents and publications.) Shortly after the startup of the new 2,4-D process in 948 Building, a new and unexpected class of nonacidic impurities were isolated in which two of the major components were tetrachloroxanthone and octachlorospirobixanthene. These impurities were causing problems in the subsequent formulation of 2,4-D as amine salts. A project was started to learn the source of these impurities and methods for controlling them. It was found that the impurities are formed mainly in the 2,4-D reaction step by several different routes and that the rate of formation is increased by increased caustic ratios, perchloroethylene, heat and iron. A number of techniques were evaluated for removing the impurities including carbon treatment, recrystallization, bleaching, varying reaction conditions, and improved washing. None of the treatments were totally successful. In the plant, the impurities tend to concentrate in the recirculati: perchloroethylene system. It has been found that by increasing the capacity of the perchloroethylene distillation column from 0.7 to 15 gpm, the steady state concentration of impurities is reduced to where they do not adversely affect general product quality or the ability of the plant to operate at optimum rates. P jd ioqn 0C "ReleASAblt p O nuAt^ D tfy ^(A O C -O . ,CiSl ; le t^ ___ OCR -1 - OC/78-85 TABLE OF CONTENTS INTRODUCTION ----------------------------------------------- Page' 2 RESULTS AND D I S C U S S I O N ----------------------------(a) . The Mechanism of TCX F o r m a t i o n ----------------------(b) The Distribution of TCX in the P r o c e s s -------------(c) Reduction of TCX by Chemical M e a n s -----------------(d) Reduction of TCX by Physical M e a n s ------------------ 9 10 26 30 38 GENERAL C O N C L U S I O N S ---------------------------------------- 50 SAFETY & E C O L O G Y ----------------------------- 50 EXPERIMENTAL ----------------------------------------------- 51 ACKNOWLEDGEMENTS ------------------------------------------- 56 R E F E R E N C E S ------------------------------ 57 X9 m o a OCR -2 - OC/78-85 INTRODUCTION A new process for preparing high purity 2,4-D was started in May 1977 at 948 Building. The high purity molten acid is transferred by pipe line from 948 Building to 489 Building where it is formulated into esters and water soluble amine salts. Starting in late October 1977, precipitates were observed regularly in diluted amines formulations that were found to be made up of a number of impurities associated with the process but that were never detected during laboratory or pilot plant development work. In addition, these impurities were not found in the old 489 Building aqueous 2,4-D process. R. McLachlan^ analyzed the precipitates and found 1,3,6,8-tetrachloroxanthone (I: T C X ) , 1,1'3,3'6,6'8,8 *-octachloro-9,9'-spirobixanthene (II: OCSX), and marginally soluble salts of 2,4-D. (II) A screening program in the plant showed TCX at levels of 200-500 ppm in the crude reaction mass, the recycle sodium dichlorophenate (NaDCP) solution, and in the final product. Levels of 1000-2000 ppm were found in the perchloroethylene (Perc) solvent and as much as 10% in the perc still tars. McLachlan^ analyzed a sample of perc still tars and his results are summarized in Table 1. _ <3 0 2 Cr>^ OCR -3- OC/78-85 Table 1: An Analysis of One Pere Tar Sample Structure Approximate Percentage Comment Perc Diethyl benzene DCP 2,4-D TCX (I) OCSX (II) Dichlorophenyldichlorovinyl ether Dichlorophenyltrichlorovinyl ether 60% 25% 0.5% 0.01% 1.5% 1.1% 1.2% 0.8% Main Component From a heat exchanger leak (Dowtherm J) raw material Product Rxn product of NaDCP & pere & its impurities Plus: at least eleven other minor components structurally similar to the above. See Ref. 1 for details. OCR -4- OC/78-85 A project was started to study the formation of TCX and OCSX in some detail to learn more about their formation and fate in the process because it is not obvious how they are made. Several months after starting this study, another significant impurity was found in the product and, to a lesser extent, in the perc tars. It was identified as (III: "8-5") 2,2',4,4',5',7,7',9-octachlorospiro-(benzofuro(3,2-b)benzopyran-11,9'-xanthene). A description of the 2,4-D process in 948 Building is as follows: Main Reactions Na 2,4-D OCR -5- Important Side Reactions ClCH2C02Na + NaOH ----- > H0CH2C 0 2Na + NaCl Glycolic Acid O C / 7 8 - 85 ONa "Bis 2,4-D" The reaction is performed in two stages by first reacting 2.2 moles of DCP with 1.2 moles of caustic (added as 50% NaOH) to form a solution of NaDCP in DCP. High purity 2,4-dichlorophenol (2,4-DCP) made by the chlorination of phenol with sulfuryl chloride in the presence of FeClg/Diphenyl sulfide catalyst is used with chloroacetic acid (MCAA) made by the oxidation of vinylidine chloride to make 2,4-D as shown above. The typical raw materials analyses for each is shown in Table 2. Table 2: Typical Raw Material Analyses for the 2,4-D Process DCP MCAA 2,4-DCP 2,6-DCP Other Chlorophenols O Uc1V 98.5% -vO.8% MCAA Dichloroacetic acid Chloromaleic acid h 2 99.0% 0.3% 'v-O.05% <1.0% OCR -6 - OC/78-85 The solution is then boiled down to remove most of the water. Then, 1.0 moles of NaOH (added as 50% NaOH) and 1.0 moles of MCAA are added to the solution at 130 and the water formed is continuously boiled off. The crude product, whose approximate analysis is shown below, is transferred to a storage tank that feeds the continuous purification equipment. Approximate 2,4-D Crude Product Analysis Na 2,4-D Na DCP DCP NaCl h 20 45% 10% 30% 12% 3% The 2,4-D is purified by partial acidification to selectively neutra lize the DCP, extraction with Perc to remove the DCP, and then final acidification to liberate molten 2,4-D which is decanted from the brine and washed with water. A schematic flow sheet of the process is shown below. A rapid initial screening of the toxicity of purified TCX and perc tars gave the following results. Pere Tar (contains 3-5% TCX + OCSX) oral L D 50 (single dose) >5g/Kg Skin/Eye slight transient initiation. Chloracne response after 10 applications of neat tars. Purified TCX >4g/Kg not irritating. Chlor acne response after 10 applications of 1% solution in CHCl^. J O VJ Vj N I 0 \A SB -8 /DO -- OCR -8- O C / 7 8 - 85 These results are encouraging from a plant hygiene standpoint, but more data is necessary regarding long term effects. When the im purities were first discovered in the plant, the perchloroethylene still was used very occasionally and at a rate of <1 gpm vs a total perc flow of 40 gpm. The still was originally added to the process as a way of purging contaminants out of the stream to maintain high quality recycle solvent. At this point, perc tar impurities made up 0-75% of the precipitates formed in diluted amines formulations. About February 1978, the capacity of the perc still was increased to 3 gpm and the average levels of TCX levels dropped to ^50 ppm in the crude reaction mass and product and to 200-500 ppm in the recy cled perc. From the period of March-May 1978, the ability to produce quality 2,4-D continued to improve and the amount of perc tar im purities found in the dilution test precipitates dropped to 10% of 3 the total . The balance were sparingly soluble metal salts of 2,4-D and some new impurities called Complex 1 and Complex 2, two of which are shown below (IV & V ) . c o 2H IV V In July 1978, the perc still capacity was increased to 15 gpm and efforts gained at understanding the parameters affecting formulation quality by S. Siegel (OCR), S. Schell (Production 489), and J. King (Formulation - 9001 Bldg) and their co-workers have greatly improved OCR -9- OC/78-85 the consistency with which 94 8 Bldg. 2,4-D can be formulated. Based upon partition coefficients and data on the rate of formation of TCX to be discussed later in this report, K. E. First4 (Process Engineering) generated a computer program which predicted that by distilling 15 gpm of recycle perc, the steady state level of TCX in the product would be M.0 ppm and in the recycled perc the TCX level would be M O ppm. The purpose of this report is to present data on the formation and fate of the impurities in the 2,4-D process. In addition, the results of experiments aimed at reducing or eliminating the impurities by chemical and physical methods will be presented. RESULTS AND DISCUSSION This study was divided into the following sections and the results of each are discussed separately. (A) The mechanism of TCX formation. (B) The distribution of TCX in the process. (C) Reduction of TCX by chemical means. (D) Reduction of TCX by physical means. Although there are many impurities formed in this process, it was decided to focus the research on TCX for several reasons: (1) The rate and mode of formation of TCX was the most predicable of the major multicyclic impurities; (2) it was a major impurity; (3) a pure sample was readily obtained (by D. Humbert, Anal. L a b ) ; (4) the analysis is not complicated; and; (5) structurally, it is the simplest of the multicyclic impurities. CloTirrn OCR -10- O C / 7 8 - 85 (A) The Mechanism of TCX Formation A brief search of the literature including Chemical Abstracts showed that the xanthone ring system is formed from a number of reactions."* A common synthetic reaction is shown below in which the -X is included 1. MeOH/MeONa + Cu to show the orientation of reaction. Xanthone is formed along with other products from the pyrolysis of o-chlorobenzoic acid, salicylic acid, aspirin, o-phenoxybenzoic acid, and salts of the carboxylic acids. Most of these cyclizations take place in the presence of acidic catalysts such as P25' Acetic anhydride, or sulfuric acid. Xanthone is prepared in reasonable yield** by the pyrolysis of phenol salicylate with or without a catalyst. The ease of formation of ring systems that are structurally similar to xanthones is most clearly shown by the formation of fluorescein and fluorescein dyes. Fluorescein is made by reaction of phthalic anhydride and resorcinol as shown on the following page. < 3 0 a .'-fi OCR O -11- OC/78-85 g Phenolphthalein is also made by this process using phenol instead of resorcinol. ' OCR -12- OC/78-85 color less red These background data give some important clues as to reaction mechanisms as will be whown later in the report. Q.OA 7 ? OCR -13- OC/78-85 In order to understand the pathway of TCX formation, a series of ampoule tests were performed to determine which chemicals and/or combinations give rise to TCX. Table 3 summarizes the results of this study. A series of ampoules ( 25 ml capacity) were charged with 3-6 gms of mixtures in molar ratios as shown inTable 3 and were heated in an oil bath fo 72 hours at 160C. The sources of the chemicals were as follows: 2,4-D: High Purity Rhone-Progil Acid DCP : Doubly distilled 948 Bldg material Perc NaOH Glyoxal Glyoxylic acid Reagent materials Tetrachloroethane (50:50 1,1,2,2- & 1,1,1,2-isomers) ^ /"-s nul OCR -14- OC/78-85 Run # 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 2,4-D 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 Molar Ratio Bis DCP NaOH Pere 2,4-D Other 1.0 1.0 2.0 1.0 1.0 1.0 1.2 1.16 1.4 1.16 1.2 1.16 0.06 1.0 0.26 0.25 1.2 1.16 1.15 1.0 4.7 1.5 1.0 1.0 1.0 0.16 1.0 1.0 0.26 1.0 0.26 TCE mixture*: 0.11 NaCl:1.5, H 20: 26.0 3,5-dichlorosalicylic acid: 0.16 If If Glyoxal: 0.26 Glyoxylic Acid: 0.55 rpm TCX N.D N.D N.D N.D N.D N.D 8 28 24 24 21 12 189 -ND 10 N.D 10 21 *TCE Mixture: 50:50 Mixture of 1,1,1,2- & 1,1,2,2-Tetrachloroethane Table 3: The Formation of TCX from Synthetic Mixtures Heated at 160 for 72 hrs. -0^73 OCR -15- OC/78-85 Several compounds other than those found in the process were tested. The tetrachloroethane mixture is a known contaminant in tne 941' Bldg, chloroacetylchloride that is used to make MCAA. 2,5-Dichlorosalicylic acid is a proposed intermediate from the reactions suggested below: c i 2c=cci2 Metal 0 Cl. J k . Cl OH(Na) Cl q The decomposition of perc to yield phosgene is known but the second reaction is only speculated. The glyoxylic acid is postulated to come from bis 2,4-D as shown below: which is a well known acetal hydrolysis. The glyoxal was included to show the general nature of the reaction whose mechanism is suggested later in this report. r > ^ -'i n f OCR -16- OC/78-85 Several tentative conclusions can be made from the data in Table 3. (a) TCX can be made by several routes NaOH and/or NaDCP is necessary for the formation of TCX. bis-2,4-D appears to be a key intermediate. CPerc is a source of TCX. (b) Significant amounts of TCX are probably made only in the . reactor crude storage tank in the plant since strong base is required. Run 14 (Table 3) simulates the Na 2,4-D storage tank (V-501: 948 Bldg) and Run 1 (Table 3) simulates the product storage tank (V-602: 948 Bldg) in which no TCX was observed. In order to study the formation of TCX as a function of reaction parameters, a series of 2,4-D reactions were performed in the lab oratory. These reactions were run to evaluate the effect of different raw materials, perc, a i r / ^ / and iron on the amount and rate of TCX formation. The data are summarized in Table 4. In these experiments, 1.1 mol of DCP was treated wth 0.6 mol of caustic and the mixture was heated to 130C. The majority of the water that was formed was boiled off. To this mixture, 0.5 mol of NaOH and 0.5 mol of MCAA were con-added during 1 hr at 130 and the crude product was heated an additional 1 hr. Water was continuously distilled out during the con add step. At this point the desired number of ampoules were charged with 5-10 gms of crude reaction mixture and were heated in oil baths at 130, 145, and/or 160 for 24, 48, and 72 hours. OCR -17- OC/78-8 5 Tabic 4: The Parameters Affecting the Formation of TCX in the Semi-Hydrous Process for Preparing 2,4-D T>C?* H ^cc? MCM *CM 2*ro y r<xj ! t V a - iijs - t it IS ci 1i 9/8 V a c -fir-s -n * Xb<J 9/3 O.1* (.2. aoM/ a /a . DoW /.* hcat >.c r t s T a !* *tK X rtec. C *rzir . *-. .* TC X 41 T | 2*<c l i ' 5 CO 3+^ *Ua 130 e il. T. JJ J A A * . W f 4.2. A l 8 I/O iv US' J- je o /s a A A3 31 A tt* /-/9* -- //s ' TA. J2. r j /3 7 /6 u z c A ll. nr.a /, /.3a f iD r e . A 7 / a ya 20 S I io 4 /a o r S S AAA W > coM M furi y ac.'iil-S-isS x)^J fio tU J il 9/8 3<m , A3. AnC _ /aa __ f i 100 Va A3- A3 fin M -- yo S3 44 y ecV/;-V2a a j - I f u s o l r 3-2. /.a . - *u) c c .ti? -s -n ', 377 3uc. A le s a li 0-2- A3. y_ CCW S-USt ' e st*T I A O V LOs-Ui l *r*r l7s e o fif'-S '-iii W lL X . C*+ /3*. \y C c Cm4o~lt x w H'4M V is ile v.$. /. 3L. y c. l4o -a.% ? f lJ W lk c 0.4 /-a >y OC. v j o - u l XiOiJ " /Aae o 4 1.3. fili- x/% f ili. fili. ' -- fin e . ` -- fin e . - 130 -- A4S Juo _,. -- - rA60 AbO 1 ' r *-- /&A3 r^ D - /bo - a4 4 41 49 T& /c.7 /X, 32 r/' % 9/ SI 481 4/ S3 V. //^ 7>/ tfO 2d t<OC.SS -- 3 > it e c .r cm -oAUWa t i O/J; c v ic a . AH1* x iT * ~ A U c e . We* /j * n * A t - in s ' sb / it 3 ~Jfei4 i l i r i h e i i A *-f CQ /O - /bo aT 7 / X 19 4 - 4- t f n c . n o /A n WeATiWe. - 8 / 1 1 1 4 4 4 A- AJi t i AIl HAUlt b C tA iiS fiA .e s * ii r 4 0 * 0 % //(Lf/CO. t hi?X ! r e * 3}*sJbm~?3-r * c r r z c ^ A * . _ 5C /Jo: /io b /$> J o n r 2 / / />02- \y . \c c .ifa -i(. 1 iV33<j6 ^-- ; ec.ifio-U l |2 o J 4*6 su 1^ e c Wb-7J f r f o- i 1 1 1! 0 .4 /-A. o-4 A 3 0.4 A 3 f i . e A. l i t s o o /30 /o f/t> 9 -73 4 i Al7 S s 's " 4C6 A t e. - Zoo /JO /be A , aC. - z r /b o 9 / / 37 3 /> fn C A 30 aAa s y . - x r / ^ i 213 3 b r `9t J' to -A ' S ' bf *-i/ j o y 1 ^ a rt <2 OCR -18- OC/78-85 The data in Table 4 show a number of interesting points. It must be emphasized that in view of the fact that these data are based on parts-per-million chemistry, the precision must be subject to some error. The data are reproducible to about 20%. (A) Effect of Dichloroacetic Acid in MCAA Runs 1,4,8, and 9 show that DCAA affects TCX formation presumably through the formation and decomposition of bis-2,4-D. Run 9 was especially interesting because not only was TCX made but bis 2,4-D was observed as shown below: ppm TCX % Bis Hrs at 160 24 48 12 41 0.4 0.3 72 56 0.2 These data indicate there is another route to bis-2,4-D besides reaction of NaDCP with dichloroacetic acid since the monochloroacetic acid used in this experiment showed no detectable DCAA (< 100 ppm) by liquid chromatography. (B) Effect of Perchloroethylene Whereas Perc showed a significant increase in TCX levels in the am poule experiments, its effect in the reactions is uncertain. In most of the runs, the reactions contaminated with perc showed more TCX at 130C and similar amounts at 160C. K. E. First,- Process Engineering, 4 ran a computer analysis of the data which gave the best fit when calculated as two consecutive first order reactions with an Ea = ^30 Kcal/mol. In the presence of perc the Ea dropped to 'V15 Kcal/mol. These data suggest that there is another OCR -19- OC/78-85 more facile route to TCX from perc whose effect is masked at the higher temperatures by a primary route (compare Table 4, Runs 1 & 2 and Runs 3 & 4). (C) Effect of Atmosphere in the Reactor Nitrogen blanketing appears to lower the TCX level to ^2/3 that ob served in air. It is not certain that this result is significant and since the magnitude of the drop was low, further work was not warranted. Since CO2 is known to be present^" in the vapor space throughout the 2,4-D process, a run was made to determine its effect on TCX formation. Carbon dioxide comes into the process from the caustic and from perc decomposition. The reaction was run as described earlier with 20 mol% of NaHCC^ added before the boil down step and then blanketing the reaction mass with CC>2 during the post reaction heating step. Since this is a high temperature, nearly anhydrous process, the following reaction was thought possible which could eventually lead to TCX (See Table 3, Runs 15 and 16). ONa + CO 2 NaOH ONa Cl Comparing Runs 1 and 10 (Table 4) show that NaHCO^ and/or CO 2 do not measurably affect the formation of TCX. ^ -><zr\ OCR -20- OC/78-85 (D) Changing NaDCP/NaMCAA Ratio Comparing Runs 1 and 7 (Table 4) show that lowering the NaDCP/NaMCAA ratios significantly reduces the TCX levels as was also predicted from the data in Table 3. The effect was studied further and is discussed later in this report. (E) Source of DCP A run was made using the old lower purity DCP from the 349 Bldg process and assure that 948 Bldg, high purity, DCP was not a source of TCX. Run 6 shows that TCX formation is not associated with the source of DCP. (F) Effect of Ferric Ion J-*3 Runs 11-14, Table 4, show that Fe clearly increases the rate of TCX formation which suggest that alkylation step(s) are involved. D. Humbert and colleagues performed a material balance of Fe in the following scheme. -- $>-- > \r Product P O O L S '/ OCR -21- O C / 7 8 - 85 They found that most of the iron is entering the process in the caustic and that the reactor normally contains 20 ppm of Fe +3 . A recurring problem for the past several months was how to explain the fact that the plant observed TCX formation rates that were 5 times greater than the lab. The iron results explain at least part of this discrepancy and suggest that efforts aimed at removing iron from the process are desirable. Based upon the data presented up to this point, the mechanism shown in Figure 1 for TCX formation is suggested. This mechanism is consistent with the observations of the effect of caustic, the fact that TCX can be made from NaDCP and glyoxal or glyoxylic acid and the levels of bis-2,4-D. If this mechanism is correct, it is easy to see how perc can influence TCX formation when one considers the possible hydrolysis products using either NaOH or NaDCP. Some of these possibilities are shown in Figure 2 and many are known precursors to TCX. In addition to TCX, OCSX and "8-5" are known to be formed in measurable quantities during the reaction to 2,4-D. It was initially assumed that TCX is the probable precursor to OCSX and "8-5". However, a series of ampoule experiments in which TCX was mixed with various ratios of DCP, 2,4-D, NaOH, and perc showed none formed in detectable amounts. In addition, a reaction was run in the presence of 500 ppm of added TCX and gave normal levels of the impurities when the 500 ppm of added TCX is subtracted out. It is apparent that OCSX, "8-5", and TCX are probably made by independent routes and proposed mechanisms are shown in Figures 3 and 4. n OCR -22- Figure 1: Proposed Mechanism of TCX Formation OC/78-85 <RC><3 5? ^ OCR -23- OC/78-85 Figure 2: Some of the Possible Products of the Hydrolysis of Perchloroethylene with NaOH or NaDCP 9 5 > 0 .4h 20 CHCl DCAA Cl OH NaDC^> c i ^ - o i - c ^ 1 'Cl Cl OH 2 OH \ zc=c( x7 cr oh or c d 2= c c i 2 HO .HO Cl^ ''Cl Cl d>OCl 2 .. NaD?P> \ C=C/ /\ Cl OOCl- known impurity CHC1--C ~ 2 \H 1. Tautom > 2. H 20 O 4 - C02Na h 20 o CHCl2-C-H 2 ^ V < 0H H0x Cl >h 20 o II H C - C O 2Na OOC1. 3 NaDCP> (Cl2<j)0)2c=c Cl 4 OH or 4 NaDCP ?? HC-CH O Cl \ H-ICI-CIH ^\ OOCl. O /r\^ 'A OCR -24- OC/78-85 Figure 3: Proposed Mechanism for the Formation of OCSX By a Route That is Independent of TCX (Proposed TCX Intermediate) V Cl Cl DCP Cl NaOH 2 ring closures as shown in the TCX mechanism Cl Cl Cl Cl OCR -25- OC/78-85 Figure 4: Proposed Mechanism for the Formation of "8-5" By a Route that is Independent of TCX Cl Cl OCR -26- OC/78-85 The formation of OCSX uses an intermediate in the TCX mechanism as its starting material. The apparent fact that TCX is not an intermediate suggests that the more activated dihydroxy ketone is necessary for alkylation. The mechanism for "8-5" formation involves a major component in the Complex I and II mixture as a starting material. Recent analytical results^"0 have shown 'V/100-200 ppm of this mixture in the process. A proposed mechanism for the formation of Complex Acid I is shown in Figure 5. It must be emphasized that the mechanisms shown in Figures 3,4, and 5 are speculations and are only one of a.number of possibilities. Much more work is necessary to prove their accuracy. (B) The Distribution of TCX in the Process . As mentioned earlier, TCX appears to be formed only in the reactor section of the process. Each of the process hold tanks were tested using either synthetic mixtures and/or actual plant material under normal operating conditions and the results are shown below: V-201 and V-202: Reactor & crude reactor hold tank. Tables 3&4 summarize these results. V-403: Phenate Recycle Storage Tank. 60% NaDCP was heated for up to 7 days in presence and absence of air in presence and absence of steel at 90c and showed no detectable TCX. V - 501: Na 2,4-D Storage Tank Mixtures of Na 2,4-D, NaCl & H 20 were, heated at 145-160 for 3 days in presence and absence of traces of perc and DCP: no detectable TCX was formed. OCR -27- OC/78-85 Figure 5: Proposed Mechanism for the Formation of the Major Impurity in Complex I mixture (Compound IV) 0 Bis + H20 ----> 2 DCP + H-lt-CO. COMPLEX ACID I ^ ^ <2,^1 OCR -28- OC/78-85 V-602: Final Product Storage Tank: Tests run at 120-175 on wet and dry 2 , 4 - D ^ showed that there is an initial slow build up of about 20 ppm of TCX during the first 48 hrs at >160 that stabilizes out. This suggests a small amount of an unstable unknown species that decomposes in acidic media. Molten 2,4-D can be treated for at least 100 hrs under the above conditions without affecting product performance. Since TCX is formed in the reactor and was found throughout 948 Bldg process, a laboratory study of the distribution was requested. In this experiment a reaction was carried out and the crude reaction mass was spiked with TCX. The purification process was then simu lated and the fate of the TCX was determined. Figure 6 summarizes the results of the extraction study performed at 90/atm. Figure 6: The Distribution of TCX in a Laboratory Simulation of the 948 Bldg 2,4-D Process REACTION (TCX not detected) MASS Pere 30% NaOH <----- 0.248g TCX added (1000 ppm) \' \/ ..DC:p EXTRilCTION Na 2,4-D Solution (TCX not detected) \' N/ PE:r c SOLIJTION (0.240g TCX Recovered) 0.016g TCX Recovered) NaDCP SOLUTION Pere SOLUTION (0.214g TC Recovered OCR -29- O C / 7 8 - 85 These data show an excellent TCX recovery in which, using clean perc, all the detectable TCX is removed from the Na 2,4-D solution. The fact that the plant observes some TCX in the product suggests that some entrained perc is carried overhead so that the impurities carried with it end in the product. The extraction of the perc/DCP mixture with caustic to recover the NaDCP also extracts about 5% of the TCX which is recycled to the reactor. This scheme was followed in a second experiment that was performed at 125/ 35 psig which more closely follows the plant conditions. Under these con ditions the aqueous solutions can be more concentrated in Na 2,4-D, NaCl, and DCP which could affect the distribution of TCX. A high pressure, mechanically stirred glass reactor was constructed and was charged with partially neutralized material from V-301 (the DCP neutralizer). The molten material was extracted six times with perc at 125C and the molten 2,4-D was isolated. The TCX and "8-5" levels were monitored throughout and the analytical results for the products are summarized in Table 5 for the two runs. The data show that TCX is effectively removed at the more drastic condi tions . Table 5: The Analysis of the Product from the High Temperature Extraction of Crude Na 2,4-D with Clean Perchloroethylene TCX (ppm) Run init final 1 292 2 178 13 2 "8-5 " (ppm) init final 54 N.D. 52 25 Metals (ppm) Na Fe Ca Mg 84 5 40 13 91 3 50 16 It is interesting to note that "8-5" is not efficiently removed with perc extraction. Hence most of what is made goes out with the product. OCSX was not detected in these samples. OCR -30- OC/78-85 In summary, TCX is formed in the reactor and most of, it remains in the recirculating perchloroethylene system. A certain amount of TCX spills into the product and the magnitude is directly related to the level in the perc. TCX is easily separated by distillation in the perc still so by increasing the rate of distillation one would achieve a lower steady state concentration of TCX in the perc. Assuming a rate of TCX formation of 0.5-1.0 #/hr in the plant 4 (based upon analyses of plant samples) K. E. First has taken distribution coefficient data and has modeled the process in terms of TCX content in various streams as a function of % of perc distilled in the perc still. To date, there is not enough in-plant data to verify this model. (C) Reduction of TCX by Chemical Means Two approaches for chemical reduction of TCX were studied. These were methods for inhibiting its formation during the reaction step and methods for reducing it from process streams. The following approaches were studied and each will be discussed in detail. 1. Changing NaDCP/NaMCAA ratio. 2. Post reaction neutralization. 3. Effect of DCAA. 4. Bleaching Na 2,4-D solutions. (1) Changing NaDCP/NaMCAA ratio Excess caustic or NaDCP was shown earlier to have a significant qualitative effect on the increased production of TCX. The 2,4-D reaction as developed by H. Brust 12 used a ratio of NaDCP/NaMCAA = 1.2. As described earlier in the discussion, at this ratio the i product contains theoretically ^6.3 mole % excess alkalinity as NaDCP as shown on the following page. OCR -31- OC/78-85 Stq M a t 11 0.5 mol DCP 0.6 mol NaDCP ---- > 0.5 ml NaMCAA Product 0.5 mol DCP 0.1 ml NaDCP 0.5 mol Na 2,4-D 0.5 mol NaCl D h m g r a 13 and Fear 14 evaluated the effect of this ratio on the yield and kinetics of this reaction and concluded: (a) lower ratios (below 1.2 lead to lower yields based on MCAA and, (b) low H 20 in solution gives higher 2,4-D yields. The effect of changing the NaDCP/NaMCAA was restudied in order to determine if the lower yield from MCAA could be justified by reduced TCX formation due to less excess caustic. The runs were carried out by using a constant amount of NaMCAA and varying the amounts of NaDCP which was done by adding differing amounts of caustic in the initial boil down step. Tables 6 and 7 and Figure 7 summarizes the results of this study. These data show that lowering the ratio from 1.2 to 1.1 results in a two fold reduction of TCX along with a 1% loss in MCAA yield. This is reason able and was tested in the plant. After three weeks of operation, they did not note a measurable reduction for reasons that are not understood at this time. Any further reduction is not practical since the yieldrapidly approaches that of the old plant thereby losing much of the advantage of the 948 Bldg process. It is inte resting to note that at ratios below 1.0 there is still a measurable amount of NaDCP which explains why formation of TCX is still observed. All of the data to date indicate that formation of TCX cannot be limited to much less than 60 ppm (in the standard 72 hr/160C ampoule test) . 0^ OCR -32- OC/78-85 TABLE 6 EFFECT OF NaDCP/NaMCAA RATIO ON TCX FORMATION & YIELD ON MCAA RUN REF DCP 1 OC 417-5-143 0.50 2 OC 417-5-144 0.55 3 OC 417-5-146 0.60 4 OC 640-1-1 0.61 Moles NaDCP 0.60 NaMCAA 0.50 0.55 0.50 0.50 0.50 0.49 0.50 Mol Ratio NaDCP NaMCAA 1.2 Ppm HOG 951 1.1 1514 1.0 3808 0.98 3606 MCAA YIELD 96.4% 94.2 86.8 86.2 CRUDE ANALYSIS Na 2,4-D 45.4 DCP NaDCP 31.2 8.9 45.5 38.0 6.0 41.3 40.3 2.2 43.0 41.7 2.5 NaCl 10.0 7.4 7.4 7.9 0 & OCR -33- OC/78-85 TABLE 7 NaDCP THE RATE OF TCX FORMATION AS A FUNCTION OF TIME, TEMPERATURE & NaMCAA RATIO RUN REF TEMP 1 417-5-143 130 145 160 2 417-5-144 130 145 160 18 HRS 37 29 18 0 27 42 TCX/OCSX 42 HRS 66 HRS 34 86 42 19 39 74 19 70 118/107 66 33 64 93 3 417-5-146 130 <10 <10 15 145 15 20 41 160 29 47 55 4 640-1 130 17 145 23 160 36 28 22 31 34 61 65 114 HRS 53 218 240 114 Hrs 52 93 142 90 Hrs 30 59 67 90 Hrs 18 52 77 2 ; so ^ OCR -34- OC/7 8-8 5 OCR -35- O C / 7 8 - 85 (2) Post Reaction Neutralization . 15 F. G. Aerstxn suggested that if the reactor crude were immediately treated with enough acid to neutralize the NaDCP after the post reaction before transfer to the reactor storage tank (V-202), TCX formation might be greatly reduced. This concept was tested using 32% H C 1 , and dry and wet 2,4-D as the neutralizing acid. The first experiment used enough dry 2,4-D to completely neutralize the residual NaDCP. The neutralized crude showed 1.4% NaDCP and a rate of TCX formation as shown below that is consistent with the data shown in Tables 6 & 7. ppm TCX Temp 160 24 hr 24 48 hr 51 72 hr 62 The use of wet, molten 2,4-D ( 25% 1^0 or 32% aqueous HCl has some serious physical handling problems. As was discussed in an earlier r e p o r t ^ , water added to 2,4-D raises the freezing point of the mass creating a material similar to cottage cheese in consistency. In addition, the added salts (either Na 2,4-D or NaCl) also raised the freezing point of the reactor batch from a range of 115-120C to 118-125C. In summary, whereas post reaction neutralization reduces TCX by a factor of four, it offers several disadvantages: (a) it would add at least 30 min - 1 hr to the reaction cycle in a plant already reactor limited near capacity operation. (b) Addition of acid could cause corrosion problems in the Incoloy 800 decanter . (c) The possibility of precipitates forming in the reactor would put ex cessive stresses on the agitator. Their formation could not be avoided ''i ^ n frt  OCR -36- OC/78-85 in the laboratory even by very slowing adding the aqueous acid. (d) Control of the acid addition would be difficult and, in addition, the plant would have to run a slightly smaller batch size in order to provide room for the acid. Further work on this concept is not warranted at this time. (3) DCAA Content of MCAA The effect of DCAA was discussed earlier. (4) Bleaching Na 2,4-D Solutions The major chemical difference between 948 Bldg and 489 Bldg techniques for processing crude 2,4-D is that 489 Bldg uses a bleach step in which residual DCP is oxidized out of the Na 2,4-D solution with 8-12% NaOCl at pH 10.5/100C. Several experiments were performed to determine if bleach would effect the impurity levels and/or improve the ability of the plant to consistently produce 2,4-D that passes the formulation dilution test. The results of these experiments are shown in Table 8. The results of the first experiment appeared very encouraging since the dilution test solids, the TCX and the "8-5" were all significantly reduced. The second series of runs showed a consistent improvement in dilution test solids when near or out of spec, but not much effect 4 on the impurities. A capital estimate performed by K. E. First showed the cost of implementing a bleach step in 2,4-D to be $500 M which immediately eliminated any further interest in this project in view of the marginal benefits. It is assumed, posthumously, that the main effect of the bleach was to reduce residual DCP which is a known contributor to poor dilution test results. A n J <3 rr OCR -37- O C / 7 8 - 85 Table 8: The Treatment of Na 2,4-D Solutions with Bleach Na 2,4-D Solution Source PH Mol Ratio NaOCl Na 2,4-D V-501 (4-7-78) 948 Bldg. starting material 10.5 0 .1 ml solids DMA-4 F-40 0.18 0.02 Impurities (ppm TCX OCSX "8 58 N.D. 25 N.D. 12 N. V-501 (6-5-78) 948 Bldg starting material 10.5 0 .1 10.5 0.2 10.5 0.05 10.5 0 .1 5 0 .1 0.01 TR TR -- -- ------ TR TR TR -- -- ---- -- 80 85 85 104 94 72 N.D. II II II II It 3 1 2 2 1 * OCR -38- OC/78-85 (D) Removal of TCX by Physical Means To date, a stage has been reached in 948 Bldg, where the 2,4-D plant can be run to consistently produce in-spec material and has demonstrated an ability to run at near capacity of 100-120 M#/day. With the perc still running at ^15 GPM, the 2,4-D product contains ^20 ppm of TCX and ^20 ppm of "8-5". A numberof attempts have been made to see if the levels of TCX can be reduced by physical means that include: 1. Carbon treatment of the recycling perc and the molten 2,4-D. 2. Removing perc from the reaction step. 3. Improved washing of the molten 2,4-D. 4. Recrystallization of Na 2,4-D and recrystallization of 2,4-D acid. The details of each alternative are discussed below. In all cases, these experiments were short term, range finding efforts and not comprehensive. Further work is justified only if the levels of im purities presently found in the product prove unacceptable in the future from a toxicity, environmental, or performance standpoint. (1) Removal of TCX with Activated Carbon The removal of TCX with activated car'-on from perchloroethylene from V-402 (''clean" perc storage tank) was evaluated by a standard isotherm method. A 100 ml portion of perc was treated with ground Pittsburg SGL carbon at 70C/72 hrs. The data, summarized in Table 9, were evaluated by a known technique that is summarized below. A plot was made of X/M vs. C on'log-log paper as shown in Figure 5. By extrapoling C to incoming TCX concentration, the corresponding X/M value gives the amount of impurity absorbed per unit weight of carbon when that carbon is in equilibrium with the incoming concen tration and represents the ultimate capacity of the carbon. The OCR -39- O C / 7 8 - 85 theoretical volume of liquid to be completely freed by TCX/gram of carbon is calculated from the following equation: VCo - 'Co Co V Co = theoretical volumn to be treated j j / = capacity/gm at incoming concentration <2o V = volume of liquid used in test Co = incoming concentration For this experiment: VCo = X 100 = 166 ml/g of Carbon or 19.9 gal of perc/# C or 265 # perc/# C Carbon loading at 241 ppm of TCX in feed = 1 6 6 ml/g C x 1.6 g ml x .00024- 64 mg/gc OCR -40- OC/78-85 Table 9: The Absorption Isotherm for TCX Removal from Perchloroethylene with Pittsburg SGL Activated Carbon Sample STG. Mat' 1 1 2 3 4 5 Impurity (ppm) TCX OCSX "8-9" (M) (C) Res id WTC/lOOml ppm Perc TCX (X) ppm TCX Removed (X/M) ppm TCX removed gm Carbon 241 159 108 57 40 29 N.D. 1 II II If tl 19 17 17 0 0.25 0.50 1.00 1.50 2.00 241 159 108 57 40 29 0 82 133 184 201 212 328 266 184 134 106 -3/0 3 / n t 2|x OCR -41- OC/78-85 -Q ^ OCR -42- OC/78-85 This is a low loading level and at the present rates of TCX pro duction in the plant, about 15-20 # of carbon per hour would be required to remove the impurity. The data shown in Table 9 indicate that carbon does not remove "8-5" from perc. The shape of the isotherm curve indicates that more than one species is being ab sorbed onto the carbon. No effort was made to determine the identity of that compound although it was probably perc. A run was made to remove impurities from wet molten 2,4-D. Since molten 2,-D is so difficult to handle at atmospheric pressure, pressurized system was built using a capillary feeder for controlling the continuous flow of molten 2,4-D at 100/25 psig onto a vertical 2' x 0.5" column that was maintained iiquid full. The flow rate 2 was 10 ml/min down the column for a mass flux of ^1.0 gpm/ft. The results are summarized in Table 10. Table 10: The Treatment of Molten 2,4-D with Activated Carbon Sample # Temp (C) Pressure psig Approx feed Tau6 ml/hr Approx. Prod. cut volume (ml) Product Analysis (ppm) TCX OCSX "8-5" F-40* solic (ml) Feed 1 2 3 4 5 112 110 2 110 110 110 110 33 2 33 33 33 33 300 100 600 375 600 375 600 376 600 375 42 N.D. 32 ---- -- 14 N.D. 29 28 N.D. 38 32 N.D. 42 30 N.D. 36 .005 .04 .005 Formulation contains 2% Versene & 0% PG 4000 x'hese data are fairly crude in that the column was shorter than is desirable 18 for optimum column work (2' vs the recommended 5-6' ) and the flow through 2 the column was a little faster than the more desirable 0.5 gpm/ft recommended OCR -43- OC/78-85 The data show that TCX loading is rather low. Breakthrough occurred after 900 ml molten D ( ^ S S g pure 2,4-D) was treated. From the analyses, the 59.8 gra of Pittsburg SGL 8 x 30 granular carbon charged to the column absorbed 281 mg of TCX for a loading of ^0.5 mg/g of carbon which is quite low. Again, "8-5" was not absorbed by the carbon. Based upon these preliminary experiments, carbon absorption of these impurities is not an attractive puri fication technique. (2) Remove Perchloroethylene From the Reactor Since perc is known to give rise to TCX, several methods were examined to eliminate its recycle to the reactor. At present, since perc is soluble to 1.2% in the recycle NaDCP solution, there are about 350# returning to the reactor in each batch. Since a continuous percphenate phase separation is performed in V-401 just before recycle to the reactor, a brief study was undertaken to evaluate the phase separation to determine the time required for complete layer separation and the solubility of perc in NaDCP solution. A solution of 62% NaDCP and 2% NaOH in water was slurried with an excess of perc and vigorously stirred for 30 min at 75. The stirring was stopped and the phenate layer was analyzed for % perc as a function of time. The results are summarized in Table 11. These data show that the solubility jof perc in NaDCP is 1.30.1% at 75C and that layer separation is complete within 15 minutes. The residence time in V-401 is 'MO minutes so that with proper operation, no layer separation problems should result. The question was also asked if the perc was entrained in the NaDCP solution as an emulsion or was it in solution? A sample was centrifuged at 60 (minimum temperature) for 30 min at y M 0 0 0 rpm and 1.2% perc was found in the phenate. It is concluded that the present equipment gives optimum layer separation and the 1.2% of perc is soluble. ''N t n " h OCR -44- OC/78-85 Table 11: The Solubility and Separation Rate of Perchloroethylene and 62% NaDCP in Water at 75C TIME* 5 min 15 " 30 " 1 hr 2" 4" 6* 24 " % Perc in Phenate Layer 1.9 1.3 1.4 1.5 1.4 1.4 1.2 1.3 Time zero is when the vigorous stirring of the two layers is stopped. OCR -45- OC/78-85 Several attempts were made to strip perc from the reaction mass and from the NaDCP solution. The plant tried to strip perc from the reaction mass during the normal boil down step. Whereas normal operation involves returning the distilled organic layer to the reactor, in this experiment the recovered organic layer was discarded. Whereas normal boil down returns 350# of DCP to the reactor, in this experiment even after 4000# of DCP was distilled off, there was still detectable perc in the distillate. As a result, this approach was judged impractical. Two attempts were made to distill the 1.3% of perc from the 60% NaDCP-2% NaOH solution. The first involved a batch distillation from a standard solution from V-403. A total of 65.9 gms were distilled out and 73.8% of the perc was removed. The reaction was then carried out as usual and samples were heated for 24, 48, and 72 hrs and the results are summarized below. These data suggest that distillation of 75% of the perc does not reduce TCX formation (See Table 4, Runs 4&5). ppm TCX Temp 160 24 hrs 21 48 hr 72 hrs 75 ` 145 The second approach taken for stripping out perc was using a falling film still. The results of two experiments are shown in Table 12. The results show that, as before, 70-80% of the perc is easily removed but that the last 20% is likely to be quite difficult. No more work is planned in this area until it can be better proven that removing perc offers any real advantage in reducing rates of TCX formation. (3) Improved Washing of 2,4-D Acid ) Several experiments were run to see if improved washing would, affect impurity levels in the 2,4-D product. A sample of 2,4-D product was taken from V-602 (948 Bldg) and was treated in the following ways: (a) A 250 gm sample of molten acid was washed 3 times with 200 ml of water per wash at 1'00C. ^ n'h hlo OCR -46TABLE 12 OC/ 7 8 - 85 Preliminary Data for Falling Film Distillation of Perc From NaDCP Solution Still: 1" x 12" Tube Pressure Temp (col'm) " (feed) Feed Rate (ave.) Overhead Temp Feed analysis % Perc % DCP Wt. Charged (Feed) Product: Wt % Perc % DCP Overhead: Wt % Perc Run 1 120 75 10 ml/min 85-- > 90 1.0 51.5 725 gins 652 gms 0.3% 53.9% 46.7 gms 1.5% o in Run 2 ATM. 10 ml/min 90-- > 95 1.1 50.1 738 gms 645 gms 0.2% 61.6% 75.0 gms 3.3% OCR -47- OC/78-8,5 (b) Another sample was reacidified to pH 0.5 with cone HCl and rewashed 2 times with water at 100C. (c) A synthetic V-501 mixture was made up using Rhone Progil 2.4- D to determine if any impurities are made in the washing step. The synthetic mixture was acidified and washed and the 2.4- D was recovered for analysis. This experiment was repeated in the presence of 2750 ppm of added TCX. The results of these experiments are shown in Table 13. Based upon these experiments, it is shown that the impurities are not made or reduced by improved washing. If anything, they are slightly increased in the product due to the greater solubility of 2,4-D in the hot water or bri n e . (d) Recrystallization of Na 2,4-D and 2,4-D Acid An attempt was made to determine if the impurities could be removed by recrystallization of Na 2,4-D from water and 2,4-D acid from organic solvents. Na 2,4-D was recrystallized by taking 500 gms of material from V-501 and adding enough water (350 ml) to form a homo geneous solution at 100C. The solution was cooled and the precipi tated Na 2,4-D was filtered and washed with 5% brine. The Na 2,4-D was redissolved in hot water and the 2,4-D was isolated and analyzed. The results are shown in Table 14 . In two separate experiments, 2,4-D from V-602 was recrystallized from perchloroethylene and ethylbenzene. A weight ratio of 3 parts solvent to 1 part 2,4-D was heated to boiling, the water contained in the molten 2,4-D was boiled out as an azetrope (the organic distillate was returned) and the solution was cooled. The 2,4-D was recovered by filtration and the solvent removed by heating in a vacuum oven at <\,60C. The results are summarized in Table 14. OCR -48- OC/78-8 5 Table 13: The Effect of Improved Washing of Molten 2,4-D on Levels of Impurities Material V-602 Starting Mat'l Wash three times Reacidify, wash two times Synthetic V-501'Na 2,4-D: NaCl DCP 21.5% 7.0% . 0.2% After Acidif. & Wash Repeat the synthetic V-501 spiked with 2750 ppm TCX Impurities TCX OCSX "8-5" 56 N.D. 73 N.D. 96 34 58 60 68 N.D. N.D. N.D. After Acidif & wash 3150 N.D. 10 Note: Rhone Progil 2,4-D shows no detectable TCX, OCSX & "8-5" r^L/~\ r~~. OCR -49- OC/78-85 Table 14: The Effect of Recrystallization of Na 2,4-D and 2,4-D Acid on Impurity Levels Treatment Recrystallize Na 2,4-D Before* Recrystallize 2,4-D From Pere Recrystallize 2,4-D From Ethylbenzene After Before After Before After Impurity Level (ppm) TCX ocsx "8-5" F-40** Dilution Test 58 -- 127 0.18 81 53 52 N.D. 54 0.3+ 46 *** 1 N.D. 52 N.D. N.D. 46 *** N.D. N.D. N.D. Commen Product Highly lored 91% Ree very of 2,4-D 87% Re very Oj_ 2,4-D *The impurities analysis was performed on a sample of 2,4-D acid isolated from Na 2,4-D without any extra treatment. **20:1 dilution in 1000 ppm hard water, formulation contained 2% Versene and no P-4000. ***The recrystallized product behaved like the high purity Rhone Progil 2,4-D which is difficult to formulate as was mentioned earlier in this report. r\ ^ O. I f! O C R -50- OC/78-85 Based upon these results, recrystallization of Na 2,4-D is not a good option since the TCX tends to concentrate in the product and the product was highly colored. It was also observed that the iron level in the product increased from 22 ppm to 91 ppm which could explain the off-color. Recrystallization from an organic solvent clearly improves the product quality although it would be difficult and expensive to implement in the plant. No further work is planned in this area unless it is determined that extremely low levels of impurities are necessary from a toxicity or an environmental standpoint. GENERAL CONCLUSIONS TCX and other non-acidic impurities are formed chiefly in the reaction step of the 2,4-D by several routes. Additional caustic, perchloroethylene, elevated temperatures and iron all promote their formation. A number of attempts to chemically and physically remove these species have met with limited success. It was found that the impurities are concentrated the recirculating perchloroethylene system and that by increasing the capacity of the clean up distillation column from 0.75 to 15 gpm, the levels of impurities in the process do not cause serious operating or quality problems. SAFETY & ECOLOGY 2,4-Dichlorophenol, 50% NaOH, and chloroacetic acid are highly toxic and corrosive raw materials. When handling, the protective clothing included lab; coat, rubber gloves and goggles, and when possible, all operations were performed in a fume hood. A number of operations were carried out at elevated pressure which required the use of a face shield and secondary shielding in the hood. All waste samples and solutions were sent to the burner for disposal. 'Z.// OCR -51- OC/78-85 EXPERIMENTAL The Preparation and Workup of 2,4-D The following is a general description of the procdure used to prepare and isolate 2,4-D when simulating 948 Bldg. A 1 liter round bottom flask equipped with a bottom drain, two dropping funnels, a mechanical stirrer, a thermometer, and a distillation head was charged with 179g (1.1 moles) of 2,4-DCP and 48 g (0.6 moles ) of 50% NaOH. The flask was heated with a heating mantel attached to 2 an I R Thermowatch controller. The reactor contents were heated while stirring and a DCP-water azetrope was distilled out. The distillation was continued until enough water was removed so that a temperature of 130C could be achieved. Normally 9-10 ml of HjO and 2-3 ml of DCP were removed. The DCP was returned to the pot. Then 47.3g (0.5 moles) of melted MCAA and 40.0g (0.5 moles) of 50% caustic were con-added from the two dropping funnels during 50-60 minutes at 130C. The rates of addition were carefully controlled so that neither added reactant was signi ficantly in excess of the other. Water and DCP continuously distilled out during the con-add and the DCP was returned to the reactor. After the addition was complete, the reaction was heated an additional 60 minutes. About 43-47 gras of ^ 0 was recovered in the con-add step. At the end of the post reaction samples of the viscous crude reaction melt were taken into ampoules, if desired. The work up procedure for isolating the 2,4-D is as follows: (The amounts used assumes no samples were taken after reaction). The reaction mass was diluted with about 500 ml of water, heated to boiling to ensure complete dissolution and the pH was adjusted to 5.20.2 with about 12 ml of cne HCl. The solution was then extracted with six 150 ml portions of perc at a temperature of >90C to remove the DCP. Occasionally 50-100 ml of additional H^O was necessary to keep all of the solids dissolved. The extracted Na 2,4-D solution was heated OCR -52- OC/78-8 5 to boiling and any traces of perc were distilled off. The pH of the solution was then lowered to 0.5-0.7 with about 55 ml of cone HCl added rapidly and the molten 2,4-D layer was separated and drained into a beaker. The resulting brine was discarded. The 2,4-D was reslurried in 250 ml of hot distilled ^ 0 in the pot and washed in this manner two times. The final pH of the aqueous layer was 2.7-2.9. The 2,4-D was recovered and dried overnight at ambient temperatures. The analyses of product and intermediate streams were performed by personnel in the 948 Bldg quality control laboratory. The analyses O for TCX, OCSX, and "8-5" were performed as described earlier . The Extraction of DCP and Impurities from Na 2,4-D Solution Under Pressure A glass apparatus was designed and fabricated from heavy wall glass pipe as shown schematically in Figure 9 . The main pot was equipped with a mechanical stirrer and was loaded with 700g of material from V-301 (948 Bld g ) . The reactor was sealed and heated to 125C. The perchloroethylene was added in 649 gm increments from the pressurized shot tank. The perc layer was drained into the bottom receiver where it was cooled bfefore draining into a bottle. All analyses on the perc and Na 2,4-D layers were performed in the 948 Bldg Q. C. Laboratory. The Carbon Clean up of Molten 2,4-D A glass pressure apparatus was assembled in which molten 2,4-D was pumped onto a carbon column (downflow) . The apparatus is shown schematically in Figure 10. The flow of 2,4-D was controlled by controlling the pressure drop across a capillary tube. To handle Q /-\'Z ic* OCR -53- OC/78-85 C PRV 50# Figure 9: A Schematic Drawing of the apparatus used for Extracting DCP from Na 2,4-D with Perchloroethylene. I v_ rS \lA OCR -54- OC/78- Figure 10: A Schematic Drawing of the apparatus used to treat Molten 2,4-D with activated carbon OCR -55- OC/78-85 molten 2,4-D reliably and effectively, required at least 10 psig/ 'V/100-105C to avoid flashing and freezing problems. The 2,4-D and a slight excess of water were placed in the feed tank and heated to 110C. When the entire contents were melted the valve on the bottom of the column was closed, the column was filled with molten acid to 1" above the top of the carbon, and the system stood for 60 min. The pressure drop across the capillary was adjusted to 7 psi ('vlO ml/min flow) and the valve on the bottom of the column was adjusted so as to maintain the liquid level above the carbon bed. The results are shown in Table 10. n m ?") I( OCR -56- OC/78-85 ACKNOWLEDGEMENT S The authors wish to thank D. Humbert, R. MacLachlan, T. Evans, G. Jewett, P. Schloemann, and their colleagues for their analytical support. The assistance of K. First and his process modeling efforts are also acknowledged. OCR -57- OC/78-85 ` REFERENCES 1. R. McLachlan, D. Humbert, G. Kallos, AL 7800101, to be issued. 2. P. Keller, et. al., HET K-2372-(18) February 9, 1978. 3. D. Humbert et. al., unpublished results. 4. Unpublished results to date. 5. Beilstein I, 17, 354. 6. Organic Synthesis Coll, Vol 1, Pg. 552. 7. Beilstein 19 (3) 222, Merck Index 9, 4040. 8. Morrison & Boyd Organic Chemistry, Allan and Bacon, Boston (1963) Pg. 684. 9. (a) S. MacLean, AL-75-20021. (b) V. Stevens, Communication, Inorganic Chem. TS&D. 10. D. Humbert, unpublished results. 11. K. L. Krmel, LR 78-74, 8-15-78. 12. H. F. Brust, OC 0730013-2, 2-26-73. 13. Y. R. Dhingra OCR Lab Book OC 327-5, p. 22-67, 1972. 14. D. L. Fern, PE 73-10, 4-16-73. 15. F. G. Aerstin, private discussion. 16. K. L. Krmel, OC 78-17 LR, 39-78. 17. S. Siegel, Results to be published. 18. Absorption Handbook: Issued by Activated Carbon Div., Calgon Corp., Pittsburg, PA. LABORATORY NOTEBOOK REFERENCES: R. F. A r n o l d 'OC 417, Pg. 109-150, OC 640 Pg. 1-73. K. L. Krmel OC 559, P g . 95-131. ^ ci UNITED STATES ENVIRONMENTAL PROTECTION AGENCY l 23 CERTIFIED MAIL - RETURN RECEIPT REQUESTED Mr. Garry Hamlin, Manager Corporate Public Affairs DowElanco P.0. Box 681428 9002 Purdue Road Indianapolis, IN 46268-1189 Subject: Krumel Report Dear Mr. Hamlin: The EPA Office of Pesticide Programs anticipates receiving requests under the Freedom of Information Act for copies of the documents listed on Enclosure 1, and in accordance with 40 CFR 2.204(a)(3), we are asking you to examine them for confidential information. If you do not claim these records to be confidential, we will release them under FOIA to requesters who submit a signed Affirmation of Non-multinational Status. A blank affirmation and an explanation of its requirements are enclosed (Enclosure 2). HOW TO RESPOND TO THIS LETTER Please answer the questions on Enclosure 3 if you believe any of the records or portions of the records identified on Enclosure 1 contain confidential information. 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You are therefore asked to carefully prepare your reply to questions 1 and 2 on Enclosure 3. WHERE TO SEND COMMENTS Your reply can be mailed to me at the following address: Susan Lawrence, Acting Chief Public Information Branch Field Operations Division (H7506C) Office of Pesticide Programs Environmental Protection Agency Washington, D.C. 20460 Or your reply can be delivered to the following address: Crystal Mall #2, Room 246 1921 Jefferson Davis Highway Arlington, Virginia 22202 DEADLINE FOR RESPONSE Your reply must be postmarked or hand-delivered within 15 business days of your receipt of this letter. REQUESTS FOR EXTENSION OF DEADLINE You may request an extension of the 15-day deadline by writing to me at the address given above or by calling me at (703) 5574454. Your request for an extension must be made within the 15day period. FAILURE TO RESPOND TO THIS LETTER Failure to respond by the established deadline will constitute a waiver of your claim of confidentiality. If we do not receive any reply from you within the specified time period, we will verify that no response has been sent and then declare the records not to be entitled to confidential treatment. RELEASE OF NON-CONFIDENTIAL RECORDS TO REQUESTERS Records named on Enclosure 1 which are not claimed as confidential will be released under FOIA to requesters who submit a signed Affirmation of Non-multinational Status. This office maintains a public file of letters and signed affirmations from FOIA requesters who are provided with FIFRA health and safety data determined not to be confidential. The file is organized by company name and then subdivided by pesticide name. You can review the file of letters and affirmations in Room 242, Crystal Mall #2. Or you can request copies of the letters and affirmations by writing to me at the address given above. In your request, please specify the company and pesticide of interest. This file will be your only notification of any release of the records or portions of the records named on Enclosure 1 determined not to be confidential. You will not receive written notification before the records are released to FOIA requesters who submit a signed Affirmation of Non-multinational Status. CONTACT PERSON FOR QUESTIONS ABOUT THIS LETTER If you have any questions or need additional information about this letter, please contact me at (703) 557-4454. Cordially, Enclosures Susan M. Lawrence, Acting Chief Public Information Branch Field Operations Division Office of Pesticide Programs 503^1 UNITED STATES ENVIRONM ENTAL PROTECTION AGENCY W A S H IN G T O N , D.C. 20460 Date OFFICE OF PESTICIDES AND TOXIC SUBSTANCES COMPANY DATA REVIEW REQUESTED UNDER 40 CFR 2,204(a)(3) The following records, which were submitted by your organization to the EPA Office of Pesticide Programs, may be requested under the Freedom of Information Act. You are asked to review these records and substantiate any claims of confidentiality by answering the questions on Enclosure 3. Company name DowElanco___________ Pesticide 2,4-D________ Volume number: "A Study of the Formation and Removal of Impurities... for 2,4-D." (Krumel Report) Microfiche copies of the records are enclosed X Paper copies of the records are enclosed. _ Sample pages which identify the records are enclosed. _ No copies are enclosed. The reference numbers will direct you to the records in your files. Enclosure 1 (Letter C) PRIN- Docket Number- ^O D -1 3 9 ^ 2 , 4 - 0 TRANSMITTAL DOCUMENT (O4 2 5 5 1 0 - 1. Name and address of submitter: Hunt-Wesson, Inc. (La Choy Food Products Division) 1645 W. Valencia Drive Fullerton, CA 92633-3899 4 2. Regulatory action in support of which this package is submitted: Reregistration of Para chlorophenoxy acetic acid Company No.: 008906-1 Chemical No.: 019401 Case No.: 2115 3. Transmittal Date: October 30, 1992 4. List of Submitted Data: C\Z. Volume 1: K?c?l Volume 2: 1exr^Volume 3: ^Volume 4: u . Volume 5 : Volume 6: no-551 Volume 78:: no.55'<?0S Possible Maximum Dioxin/Furan Contamination in Bean Sprouts Summary of Levels of Substituted[/Dioxins and Benzofurans in Samples of 2,4-D ; Determination of Dioxins and Benzofurans in 2,4-D, 2,4-DCP, MCPA, 2,4-DP, CMPP and 2,4-DPB by GC/MS July 25, 1990 letter to EPA summarizing Hunt- Wesson's request to waive dioxin/furan data and documents supporting low volume/minor use. Includes EPA's response of March 31, 1991. August 11, 1992 letter from Hunt-Wesson to R.J. Otten reporting result of analysis of 4- CPA. .. Report from Wright State University. ... 4-CPA Magnitude of Residue Study. Hunt-Wesson Report. *.... 4 <. . < <,:-t COMPANY OFFICIAL: COMPANY NAME: COMPANY CONTACT: Richard J . Otten Phone: 919-846-7860 4 << << R03 2.3 1 26/93 REFERENCE FILES SYSTEM PAGE 1 ACTIVE INGREDIENTS FOR CASE 0073 2,4-D PC CODE CHEMICAL NAME 30001 30002 30004 30005 30010 30011 30013 30014 30016 30017 30019 30020 30021 30023 30024 ?'^25 3^ ^/28 30029 30030 30033 30034 30035 30039 30052 30053 30055 30056 30062 30063 30064 30065 30066 30072 2,4-Dichlorophenoxyacetic acid Lithium 2,4-dichlorophenoxyacetate Sodium 2 ,4-dich1orophenoxyacetate Ammonium 2,4-dichlorophenoxyacetate Alkanol* amine 2 ,4-dichlorophenoxyacetate * (salts of the ethanol and ispropanol series) Alkyl* amine 2,4-dichlorophenoxyacetate *(100% C12) Alkyl* amine 2,4-dichlorophenoxyacetate *(100% C14) Alkyl* amine 2,4-dichlorophenoxyacetate * (as in fatty acids of tall oil) Diethanolamine (2,4-dichlorophenoxy)acetate Diethylamine 2,4-dichlorophenoxyacetate Dimethylamine 2,4-dichlorophenoxyacetate N ,N-Dimethyloleylamine 2,4-dichlorophenoxyacetate Ethanolamine 2,4-dichlorophenoxyacetate Heptylamine 2,4-dichlorophenoxyacetate Isopropanolamine 2 ,4-dichlorophenoxyacetate Isopropylamine 2,4-dichlorophenoxyacetate Morpholine 2 ,4-dichlorophenoxyacetate N-01eyl-l,3-propylenediamine 2,4-dichlorophenoxyacetate Octylamine 2,4-dichlorophenoxyacetate Triethanolamine 2,4-dichlorophenoxyacetate Triethylamine 2,4-dichlorophenoxyacetate Tri isopropanolamine 2 ,4-dichlorophenoxyacetate N,N-Dimethyl oleyl-linoleyl amine 2 ,4-dichlorophenoxyacetate Butoxyethoxypropyl 2 ,4-dichlorophenoxyacetate Butoxyethyl 2,4-dichlorophenoxyacetate 3-Butoxypropyl 2 ,4-dichlorophenoxyacetate Butyl 2,4-dichlorophenoxyacetate Isobutyl 2 ,4-dichlorophenoxyacetate Acetic acid, (2,4-dichlorophenoxy)-, 2-ethylhexyl ester Isooctyl(2-ethyl-4-methylpentyl) 2,4-dichlorophenoxyacetate Isooctyl(2-octyl) 2,4-dichlorophenoxyacetate Isopropyl 2,4-dichlorophenoxyacetate Propylene glycol butyl ether 2,4-dichlorophenoxyacetate 11/26/93 REFERENCE FILES SYSTEM ACTIVE INGREDIENTS FOR CASE 0196 2,4-DB PC CODE CHEMICAL NAME 30801 30804 30819 30853 30856 30863 4- (2,4-Dichlorophenoxy)butyric acid Sodium 4-(2,4-dichlorophenoxy)butyrate Dimethylamine 4-(2,4-dichlorophenoxy)butyrate Butoxyethano1 4- (2,4-dichlorophenoxy)butyrate Butyl 4- (2,4-dichlorophenoxy)butyrate Isooctyl 4-(2,4-dichlorophenoxy)butyrate PAGE 1 11/26/93 REFERENCE FILES SYSTEM ACTIVE INGREDIENTS FOR CASE 0294 2,4-DP PC CODE CHEMICAL NAME 31401 31419 31453 31463 2-(2,4-Dichlorophenoxy)propionic acid Dimethylamine 2-(2,4-dichlorophenoxy)propionate Butoxyethyl 2- (2,4-dichlorophenoxy)propionate Isooctyl 2-(2,4-dichlorophenoxy)propionate PAGE 1 oLd 3 `l3? REPORT ID : PDR20B01 RUH DATE: 11/26/93 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT -AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 SEARCH TERMS: CHEMICALS : 0 30 0 0 1 OR 0 30 0 0 2 OR 0 3 0 0 0 4 OR 0 30 0 0 5 OR OR 0 30 0 1 1 OR 0 30 0 1 3 OR 0 3 0 0 1 4 OR 0 30 0 1 6 OR OR 0 30 0 1 9 OR 0 30 0 2 0 OR 0 3 0 0 2 0 OR 0 30 0 2 1 OR OR 0 30 0 2 4 OR 0 30 0 2 5 OR 0 3 0 0 2 8 OR 0 30 0 2 9 OR AND SUBJECT: PRODUCT CHEMISTRY AND SUBMITTER: ALL AND SUBMISSION DATE: ALL AND LAB-ID: ALL AND DOCUMENT TYPES: ALL SELECTED STUDIES REGARDLESS OF DOCUMENT TYPE AND ENTRY DATE: ALL 0 30 0 1 0 0 30 0 1 7 0 300 2 3 0 30 0 30 DUMBER OF STUDIES: 759 MRID SEQUENCE BIBLIOGRAPHY ------ NUMBER AUTHOR SEQUENCE BIBLIOGRAPHY ---- NUMBER SUBMITTER SEQUENCE BIBLIOGRAPHY - NUMBER GUIDELINE SEQUENCE BIBLIOGRAPHY SUMMARY FORMAT ---------------- NUMBER EXPANDED FORMAT --------------- NUMBER OF COPIES: OF COPIES: OF COPIES: OF COPIES: OF COPIES: PAPER SIZE: 8 1/2 BY 11 INCH PAPER 1 0 0 0 0 REPORT ID: PDR2 0B0 1 RUN DATE: 11/26/93 PAGE: 1 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SE2UENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 00004039 Starr, R.I.; Cunningham, D.J. (1966?) Translocation and Degradation of 4-Aminopyridine in Corn Plants. (Unpublished study received Jan 3, 1973 under 1F1013; prepared by U.S. Fish and Wildlife Service, Denver Wildlife Research Center, submitted by Phillips Petroleum Co., Bartlesville, Okla.; C D L :0917 5 7 - T ) 00004126 Starr, B. (19??) Thin-Layer Chromatography-- Avitrol. (Unpublished study received Apr 15, 1969 under 224-EX-3; prepared by U.S. Fish and Wildlife Service, Denver Research Center, submitted by Phillips Petroleum Co., Bartlesville, Okla.; C D L :122745-J) 00004457 Dow Chemical Company (1967) Introduction and General Consideration Regarding the Performance Section of Compilation. Summary of studies 003622-B through 003622-Y, 003622-AA through 003622-AB. (Unpublished study received Nov 6, 1967 under 464-398; CDL: 003622-A) 00004480 Watson, A.J.; Reimer, C.A. (1965) Response of Selkirk Spring Wheat to Foliage Sprays of Tordon and Combinations of Tordon and 2,4-D or MCPA-- 1963. (Unpublished study received Nov 6, 1967 under 464-398; submitted by Dow Chemical U.S.A., Midland, Mich.; CDL: 003622-AA) 00004725 Stanley, C.W. (1966) Derivatization of pesticide-related acids and phenols for gas chromatographic determination. Journal of Agri cultural and Food Chemistry 14( 3): 32 1-323. (A l s o 0I n 0unpublished submission received Sep 12, 1968 under 8F0676; submitted by Dow Chemical U.S.A., Midland, Mich.; C D L :092980-A2) 00004729 Storrs, E.E.; Burchfield, H.P. (1962) Internal standards in the analysis of Chlorine-containing herbicides by gas chromatography. Contributions from the Boyce Thompson Institute 21 (7): 423-437. (AlsoInunpublished submission received Sep 12, 1968 under 8F0676; submitted by Dow Chemical U.S.A., Midland, Mich.; CDL: 092980-AV) 00004731 Bruynje, J.H. (1973) Principles of MCPP and 2.4 D Production at Akzo's. (Unpublished study received Feb 20, 1973 under 6305-10; prepared by Akzo $Zout Chemie n v I , submitted by Robeco Chemicals, Inc., New York, N.Y.; C D L :022388- B) Q 0 39/T REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 2 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SESUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 00004777 Kenaga, E.E. C1972) The Comparative Toxicity to Birds of Dow Herbi cides Containing Chlorophenoxyalkanoic Acids and Derivatives. (Unpublished study received Apr 16, 1974 under 802-517; prepared by Dow Chemical Co., submitted by Lilly Charles H. Co., Miller R d . Div., Portland, Oreg. ; C D L :128581-A 1 00004784 Chipman Chemical Company, Incorporated. (19671 Summary of Available Acute Toxicity Data on a Bromoxynil octanoate/MCPA Isoocty Ester Formulation as Compared with Bromoxynil and MCPA: SR/3/67. (Un published study received Mar 10, 1967 under 359-601; submitted by Rho ne-Polenc, Inc., Monmouth Junction, N.J.; C D L :023320-D) 00004816 Klingman, G.C. (1966) Laboratory Determination of Precipitates Formed from Various 2,4-D Formulations with Solutions of Ammoni um nitrate and Mixtures of Ammonium nitrate and Urea (Uran 30%). (Unpublished study including letter dated May 5, 1966 from B.A. Sprayberry for files, received Mar 13, 1967 under 677-245; prepared in cooperation with North Carolina State U n i v ., submit ted by Diamond Shamrock Agricultural Chemicals, Cleveland, Ohio; CDL:133084-E) 00005568 Velsicol Chemical Corporation (1973) Banvel + Lasso + Sprayable Fluid Fertiliser. (Unpublished study received Mar 15, 1973 under 876-25; C D L :005053-A ) 00013389 Guardigli, A. (1971) Analysis of Weed-Broom Formulation by Ultra violet Spectrophotometry and Thin Layer Chromatography. Rhodia Analytical Method No. 114 dated Nov 1, 1971. (Unpublished study received Dec 14, 1971 under 359-627; prepared by Rhodia, Inc., submitted by Rhon e- Po ul en c, Inc., Monmouth Junction, N.J.; CDL: 003176-D) 00019897 Garbrecht, T.P., Sr. (1978) Determination of Dicamba, 2,4-D, MCPA, or MCPP in Formulations by High Pressure Liquid Chromatography (H P L C ). Method no. CF 78-2 dated Feb 16, 1978. (Unpublished study received Nov 6 , 1979 under 538-160; submitted by O.M. Scott Sons Co., Marysville, Ohio; C D L :241 34 9 - F ) 00021791 Stauffer Chemical Company (19??) R-1910 + 2,4-D 3-1E. (Unpublished study received Mar 30, 1966 under unknown admin, no., CDL: 123645-A) Qs.(3 REPORT IDs PD R2 0B0 1 RUN DATE: PAGE: 1 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 11/26/93 3 00021792 Stauffer Chemical Company (19??) ^Composition of R-1910; Shipments of R - 1 9 1 0 ! . (Unpublished study received Mar 30, 1966 under unknown admin, no.; C D L :12364 5 - C ) 00022448 O.M. Scott Sons Company (1966) Summary of Results Report for Five Dry Granular Fertiliser and Vermiculite Formulations Containing Dicamba as a Replacement for M C P P . (Unpublished study received Jun 15, 1966 under 538-28; C D L :023114-A ) 00022516 Stagen, R. (1972) B12D-- W.S. B12T-- W.S.: Report 407386, No. 1. (Unpublished study received May 10, 1972 under 876-176; submit ted by Velsicol Chemical Corp., Chicago, 111.; C D L :005085-1) 00022545 Ferguson, F. (1978) Accelerated Shelf Life Study: New Fertilizer plus Dicot Weed Control: Formulation F-8481. (Unpublished study received Nov 1, 1978 under 538-33; submitted by O.M. Scott Sons Co., Marysville, Ohio; C D L :235612-A) 000226 14 Velsicol Chemical Corporation (1969) Stability of Stull Invert Formulations Containing Banvel and Various Other Herbicides at 0-onF and 122- o h f . (Unpublished study received Jul 9, 1969 under 2738-56; submitted by Stull Chemical Co., San Antonio, Tex.; C D L :006092-A) 00022721 Stagen, R.S. (1973) 1 Lb. B a n v e l - (R )n--3 L b S . 2,4D-Dimethylamine Salt/Gal. W.S.: Report 407386, No. 3. (Unpublished study re ceived Nov 2, 1973 under 876-203; submitted by Velsicol Chemi cal Corp., Chicago, 111.; C D L :00 9058-D) 00025386 Ross, R.D.; Morrison, J.; Rounbehler, D.P.; et a l . (1977)Ni-Nitroso compound impurities in herbicide formulations. Journal of Agricultural and Food Chemistry 25(6) :1416-- 1418. (AlsoInunpublished submission received Feb 27, 1978 under 876-25; submit ted by Velsicol Chemical Corp., Chicago, 111.; C D L :23 33 52- A) 00026306 Zaratzian, V.L. (1966) $R-1910* Toxicity to Rats and Rabbits!. (U.S. Agricultural Research Service, Pesticides Regulation D i v ., unpublished report.) 00026341 Boots Pure Drug Company, Limited (1957) Iso-Cornox: (Formulation of C M P P ). (Unpublished study received Jan 2, 1980 under 2217-485; submitted by PBI-Gordon Corp., Kansas City, K a n s .; C D L :241579 - W ) / REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 4 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 00026721 Diamond Shamrock Corporation (19??) Formula: Dacthal-* (R )h W-75 Her bicide (75% Wettable Powder): A Selective Preemergence Herbicide for Control of Annual Grasses and Certain Broadleaved Weeds. (Unpublished study received Dec 10, 1968 under 9F0780; CDL: 092028-A) 00028174 S.C. Johnson and Sons, Incorporated (19??) Johnson Yard Master Foam Lawn Weed Killer: Analytical Stability Data. Includes undated method. (Unpublished study received Oct 30, 1972 under 4822124; CDL:007519-A) 00028314 O.M. Scott Sons Company (1967) The Stability of 2,4-D-Dicamba Combinations on Vermiculite and Fertilizer Carriers. (Unpub lished study received Jan 10, 1967 under 538-9; C D L :004053-A ) 0028317 Rhodia, Incorporated (1969) Analysis of a Granular Formulation Con taining 2,4-D, Banvel D, MCPP, and Chlordane: AR No. 45. (Un published study received May 22, 1969 under 359-621; submitted by Rhone-Poulenc Chemical Co., Monmouth Junction, N.J.; CDL: 003173-A) 00028325 Stebbins, P.; Drew, D. (1979) Formal Report of Analysis for NNitroso Compounds: Report No. 5450-711. (Unpublished study re ceived Aug 29, 1979 under 2217-624; prepared by Thermo Electron Co r p . , submitted by PBI-Gordon C o r p . , Kansas City, K a n s .; CDL: 240871-A) 00028326 Forrette, J.E.; Trujillo, W.A; Smith, M.; et a l . (1977) Analysis of the Dimethylnitrosamine Content of Technical Dicamba, Prin cipal Banvel Formulations and Dimethylamine Used in the Formu lation of Banvel Products: Report No. 4. Unpublished study; 43p. 00028327 Rozek, A.; Grins, G.; Smith, M. (1978) Analysis of Various Pesti cide Formulations for Nitrosamine Content: Report No. 2. (Un published study received Feb 8 , 1979 under 35911-16; prepared by Velsicol Chemical Corp., submitted by Rivhard Conn., Inc., South Field, Mich.; C D L :23 8583-B) 0 33 REPORT ID: PD R2 0B0 1 RUN DATE: PAGE: ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM CPDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 11/26/93 5 00028328 Born, G.L. (1979) Long Term Shelf Life Storage. (Unpublished study including letter dated Jan 24, 1979 from G.L. Born to U.S. En vironmental Protection Agency, Office of Pesticide Programs, Registration Div., received Jan 24, 1979 under 538-33; submitted by O.M. Scott Sons Co., Marysville, Ohio; C D L :236858-A) 00028333 F.J. Week Company (1978) $Study of Herbicides for N-Nitroso Com pounds!. (Unpublished study received Mar 14, 1979 under 5571654; submitted by Swift Agricultural Chemical, Chicago, 111.; C D L :237844--A) 00028396 Mom a r , Incorporated (19??) Quality Control Test for Chlorine Con tent. Undated method. (Unpublished study received on unknown date under 1553-83; CD L :101698-A) 0028460 Bishop, J.R. (1979) Production of 2,4-D Acid. (Unpublished study received Mar 10, 1980 under 264-231; submitted by Union Carbide Agricultural Products Co., Ambler, Pa.; CDL -*24 198 4 - C ) 00030428 Schwamb, L. (1980) Formal Report of Analysis for N-Nitroso Com pounds: Report No. 5450-892. (Unpublished study received Mar 18, 1980 under 9198-47; prepared by Thermo Electron C o r p ., sub mitted by Anderson Lawn Fertilizer, Div. of Free Flow Fertilizer Co., Maumee, Ohio; C D L :242167-A) 00032125 Dow Chemical Company (1977) Determination of N-Nitrosodimethylamine in DMA- 6 Herbicide. Method ML-AM-77-56 dated Dec 27, 1977. (Unpublished study received Mar 18, 1980 under 802-146; submit ted by C h a s . H. Lilly Co., Miller Road Div., Portland, Oreg.; C D L :242334-A) 00032217 Kaldon, H. (19??) 4L Compatibilities. (Unpublished study received Oct 22, 1969 under 100-497; submitted by Ciba-Geigy Corp., Greensboro, N.C.; C D L :00 05 23 -D ) 00032366 O.M. Scott Sons (1964) Quantitative Analysis of Proposed Combina tion Product Formulations. (Unpublished study received Sep 16, 1964 under 538-29; C D L :05013 6 - B ) <3.0331 REPORT ID: PDR20 B0 1 RUN DATE: PAGE: ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 11/26/93 6 00033124 American Chemical Paint Company (1955) Weedazol: H-60. (Unpub lished study received Jun 9, 1955 under 264-68; submitted by Union Carbide Agricultural Products Co., Ambler, Pa.; CDL: 0 0 1845-A) 00033316 Geigy Chemical Corporation (19??) Simazine Herbicides for Selective and Non-Selective Uses. Ardsley, N.Y.: Geigy. (Simazine tech nical bulletin no. 62-1; alsoInunpublished submission received Feb 8 , 1963 under 7401-192; submitted by Voluntary Purchasing Group, Inc., Bonham, Tex.; C D L :009207-A) 00034185 Davis, D.L.; Hondo, W .T .; Sumida, A.M.; et a l . (1965) Efficacy of Paraquat on Lawn Weeds I: Project No. 170-W64-1. (Unpublished study including project nos. S64-13 and 118-S64-13, received Aug 11, 1966 under 239-1994; submitted by Chevron Chemical Co., Richmond, Calif.; C D L :001437-A) 00035914 Woolson, E.A.; Thomas, R.F.; Ensor, P.D.J. (1972) ^Without title I. Journal of Agricultural and Food Chemistry 20(2):351-354. (Also iInunpublished submission received Sep 24, 1970 under 1E1046; submitted by U.S. Dept, of the Army, Office of the Chief of En gineers, Washington, D.C.; C D L :096474-D) 00035936 Bandurski, R.S. (1947) Spectrophotometric method for determination of 2,4-Dichlorophenoxyacetic acid. Botanical Gazette ? (?/Ma r):446-449. (AlsoInunpublished submission received Jul 11, 1971 under 1E1046; submitted by U.S. Dept, of the Army, Washington, D.C.; C D L :093359-A) 00035940 Carlile, B.L. (1968) Degradation and Depletion of Herbicides in Drainage Waters and Accumulation of Residues in Crops Irrigated with Treated Water: Annual Report-- 2,4-D and Silvex. (Battelle Memorial Institute, unpublished study; C D L :093359-E) 00036042 Tennessee Valley Authority (19??) Name, Chemical Identity, and Composition. (Unpublished study; C D L :095539-A) 00037488 Thermo Electron Corporation (1979) Recovery Data for Nitrosamines. (Unpublished study including letter dated Jan 14, 1980 from W.A. Davis to Willa Y. Garner, received Jan 15, 1980 under 264-236; submitted by Union Carbide Agricultural Products Co., Ambler, Pa.; C D L :242777-A) ao33^ REPORT ID: PDR20B01 RUH DATE: 11/26/93 PAGE: 7 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 00039731 National Agricultural Chemicals A ss oc ia ti on 's Industry Task Force on Phenoxy Herbicide Tolerances (19??) Ingredient Data Sheet: $Amine 4 D I . (Unpublished study received Dec 8 , 1967 under 8F0670; C D L :09515 2 - D ) 00039733 Dow Chemical U.S.A. (1972) 2,4-D Sodium salt Weed Killer. (Unpub lished study received on unknown date under 8F0670; submitted by National Agricultural Chemicals Association's Industry Task Force on Phenoxy Herbicide Tolerances, Washington, D.C.; CDL: 095152-H) 00039738 Dow Chemical U.S.A. (1972) Dow DMA-4 Weedkiller: M-3538. (Unpub lished study received on unknown date under 8F0670; submitted by National Agricultural Chemicals Association's Industry Task Force on Phenoxy Herbicide Tolerances, Washington, D.C.; CDL: 095152-M) 00039739 Dow Chemical U.S.A. (1972) Dow DMA- 6 Weed Killer: m - 3637. (Unpub lished study received on unknown date under 8F0670; submitted by National Agricultural Chemicals Association's Industry Task Force on Phenoxy Herbicide Tolerances, Washington, D.C.; CDL: 095152-N) 00039748 Dow Chemical U.S.A. (1972) Formula 40: m - 3604. (Unpublished study received on unknown date under 8F0670; submitted by National Ag ricultural Chemicals Association, Industry Task Force on Phenoxy Herbicide Tolerances, Washington, D.C.; C D L :095152 - W ) 00039753 Rhodia, Incorporated (1971) Chipman 2,4-D Amine No. 4. (Unpub lished study received on unknown date under 8F0670; submitted by National Agricultural Chemicals Association, Industry Task Force on Phenoxy Herbicide Tolerances, Washington, D.C.; CDL: 095152-AB) 00039754 Rhodia, Incorporated (1971) Chipman 2,4-D Amine No. 6 . (Unpub lished study received on unknown date under 8F0670; submitted by' National Agricultural Chemicals Association, Industry Task Force on Phenoxy Herbicide Tolerances, Washington, D.C.; CDL: 095152-A C ) <5l33i? REPORT ID: PDR20B01 RUN DATE: PAGE: ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SESUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 11/26/93 8 00040425 Eshel, Y.; Warren, G.F. (1967) A simplified method for determining phytotoxicity, leaching, and adsorption of herbicides in soils. Weeds 15C2):115-- 118. (AlsoInunpublished submission received Feb 24, 1977 under 748-161; submitted by PPG Industries, Inc., Barberton, Ohio; CDL *096035-B ) 00043758 U.S. Department of the Army, Office of the Chief of Engineers (1961) Nomenclature, Physical and Chemical Properties, Use, and Behavior of 2,4-D. (Unpublished study; CDL s099544-C) 00043765 U.S. Department of the Army, Office of the Chief of Engineers (19??) Summary for All Sections of Petition. Summary of study 099544-J. (Unpublished study; C D L :09 9544-K) 00043828 Gangstad, E.O.; Fish, F.; Stanley, R . A . ; et al. (1976) Butoxyethanol ester of 2,4-D for Control of Eurasian Water Milfoil. Final rept. Vicksburg, Miss.: u.S. Army Engineer, Waterways Experiment Station. (Aquatic Plant Control Program, technical report 12, published study; C D L :0995 42-A) 00044670 Al t h a u s , R.E.; Howe, G.L. (1965) The Name, Chemical Identity, Physical Composition of the Pesticide Chemical: $Roundupl. (Un published study received Sep 30, 1965 under 524-157; submitted by Monsanto Co., Washington, D.C.; C D L s 10 0 7 54 -A ) 00044817 Song, L. (1977) Formal Report of Analysis: $ N D M A I . (Unpublished study received May 10, 1978 under 8414-15; prepared by Thermo Electron Research Center, submitted by Hoyt's Insecticide Co., Atlanta, Ga.; C D L :242938-A ) 00045408 Dow Chemical Company (1969) The Name, Chemical Identity, and Compo sition of the Pesticide Chemical: $ T o r d o n | . (Unpublished study received Aug 4, 1969 under 0F0863; C D L :093160 - F ) 00046137 Nachemco, Incorporated (19??) Comparison of Dimethylamine salt of 2 , 4-Dichlorophenoxyacetic acid with Di methylammonium-2,4-Dichlorophenoxyacetate. (Unpublished study received on unknown date under 10629-2; C D L :013013-A) 00046138 Nachemco, Incorporated (19??) Gator Weed Spray. (Unpublished study received on unknown date under 10629-2 ; C D L *013013 - B ) a o 33-f REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 9 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 00046140 Penniian Broune, Incorporated (1971) Report of Analysis: Aceta mide: Report No. 711196. (Compilation; unpublished study in cluding report no. 711196-A, received on unknown date under 10629-2; submitted by Nachem, Inc., Fort Lauderdale, Fla.; C D L : 013013-F) 00046185 U.S. Office of Science and Technology, Panel on Herbicides (1970) Report on 2,4-D. (Unpublished study; C D L :119429-A) 00048102 Clearwater Chemical Corporation (19??) Dimethyl 2-4-D Acetate. (Unpublished study received Nov 22, 1971 under 16133-1; CDL: 015056-M) 00048909 Stull Chemical Company (1969) Stability of Stull Invert Formula tions Containing Banvel and Various Other Herbicides at 0-on F and 120- oh F. (Unpublished study received Jul 9, 1969 under 2738-55; C D L :225649- A ) 00048910 Stull Chemical Company (1969) Stability of Stull Invert Formula tions Containing Banvel and Various Other Herbicides at O-on F and 1 2 2 -on F. (Unpublished study received Jul 8 , 1969 under 2738-54; C D L :225 648 -A ) 00048911 Stull Chemical Company (1969) Stability of Stull Invert Formula tions Containing Banvel and Various Other Herbicides at 0 -on F and 1 2 2 -'on F. (Unpublished study received Jul 9 , 1969 under 2738-55; C D L :225 647 -A ) 00048912 Stull Chemical Company (1969) Stability of Stull Invert Formula tions Containing Banvel and Various Other Herbicides at 0 - o h f and 1 2 2 -on F. (Unpublished study received Jul 9, 1969 under 2738-52; C D L :225 646 -A ) 00051196 Kross, R.D. (1971) Letter sent to L.H. Nash dated Aug 13, 1971: C,H,N,0,C1 percent composition, and stability of aqueous solu tion. (Unpublished study received on unknown date under 10629-2; prepared by Kross-Reference Laboratories, submitted by Nachemco, Inc., Fort Lauderdale, Fla.; C D L :013013- E ) 0 3 b>9 REPORT ID: PDR20 B0 1 RUN DATE: 11/26/93 PAGE: 10 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 00051197 Erwin, R. (1972) Letter sent to L.H. Nash dated Nov 30, 1972 ilnfra-red curves of Dimethylamine salt of 2-4-D and Dimethylammonium 2-4-dichlorophenoxyacetateI: Y-037326. (Unpublished study received on unknown date under 10629-2; prepared by Erwin Chemi cal Laboratory, submitted by Nachemco, Inc., Fort Lauderdale, F l a .; C D L :013013- G ) 00051198 Erwin, R. (1972) Letter sent to L.H. Nash dated Nov 30, 1972 $Light transmission graph of Dimethylamine salt of 2-4-D and Dimethylammonium 2-4-D acetate I: Y-037326. (Unpublished study received on unknown date under 10629-2; prepared by Erwin Chemical Labo ratory, submitted by Nachemco, Inc., Fort Lauderdale, Fla.; CDL: 013013-H) 00051202 Sherwin-Williams Company of Canada, Limited (1964) ^Toxicity Study of C M P P , MCPA and 2,4-D-- Rats, Mice!. (Compilation; unpub lished study received Feb 10, 1964 under 461-EX-13; submitted by Stubbins Hollander Co., East Orange, N.J.; C D L :127413 - A ) 00051206 Nash, L.H. (1971) Letter sent to Environmental Protection Agency, Pesticide Regulation Division dated Nov 18, 1971 ^Efficacy, safety, stability and chemistry of Di methylammonium-2,4-dichloroph en oxyacetateI. (Unpublished study received Nov 22, 1971 under 16133-1; prepared by Nachemco, Inc., submitted by Clear water Chemical C o r p ., Mt. Myers, Fla.; C D L =015 0 5 6 - A ) 00052294 U.S. Department of the Army, Office of the Chief of Engineers (19??) Data Sheet Giving the Chemical and Physical Properties of the Chemical: $3 MCAP-24I. (Unpublished study; C D L :096474 - H ) 00052298 U.S. Department of the Army, Office of the Chief of Engineers (19??) Mechanism of Release: *2,4-DI. (Unpublished study; CDL: 096474-L) 00052607 U.S. Environmental Protection Agency (19??) 2,4-D acetate Evalua tion Summary Report. Summary of studies 128404-B through 128404-D. (Chemical Biological Investigations Branch, Tech nical Services Div., unpublished study; C D L :128405-A) 00052612 Thomas, R.F. (1972) Report of Tests on Two 2,4-D Products. (Un published study received Apr 5, 1973 under 10629-1; submitted by Nachemco, Inc., Fort Lauderdale, Fla.; C D L :12 8 4 04 -A ) 2 - 0 3 3 (b REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 11 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SE2UENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 00053697 Upton, E.T. (19721 Letter sent to Drew M. Baker, Jr. dated Jun 5, 1972 ^Identity of the inert ingredients used in the formulations for 2,4-D, Silvex and MC P A I . (Unpublished study received on un known date under 9F0761; prepared by Thompson-Hayward Chemical C o . , submitted by National Agricultural Chemicals Association, Industry Task Force on Phenoxy Herbicide Tolerances, Washington, D.C.; C D L :096516- G ) 00053746 Akzo Zout Chemie Nederland, B.V. (1973) Determination of Total Acid in Phenoxy acetic acid or Phenoxy propionic acid and Their Salts by Direct Potentiometrie Titration. Method 248.1 dated Feb 12, 1973. (Unpublished study received Aug 15, 1977 under 38117-2; C D L :2 31 352 -B) 00053748 Akzo Zout Chemie Nederland, B.V. (1973) Spectrophotometric Deter mination of Chlorophenol in Phenoxy acetic acid or Phenoxy pro pionic acid and Their Salts with 4-Amino antipyrine. Method no. 259.3 dated Feb 12, 1973. (Unpublished study received Aug 15, 1977 under 38117-2; C D L :23135 2 - D ) 00055668 O.M. Scott Sons Company (1980) Method of Manufacture: Dry Applied Super Broadleaved Weed Control and Fertilizer F-8791: New Im proved Super Turf Builder Plus 2. (Unpublished study received Nov 6 , 1980 under 538-167; C D L :243671- A ) 00055669 O.M. Scott Sons Company (1980) New Improved Super Turf Builder Plus 2: Long Term Shelf Life Storage. (Unpublished study re ceived Nov 6 , 1980 under 538-167; C D L :243671- B ) 00056373 Hercules, Incorporated (19??) H e r c u l e s - (R )n Rosin Amines--Amine D, Amine 750, Amine D acetate and Amine 750 acetate. Wilmington, Del.: Hercules. (Bulletin PC-132A; also0Inunpublished submis sion received Jun 14, 1976 under 900-110; submitted by Chemical Service, Franklin Park, 111.; C D L :22 60 2 0 - B ) 00058889 Dow Chemical Company (1971) Analytical Method: Determination of 2,3,7,8 -Tetrachlorodibenzo-p-dioxin in 2,4,5-Trichlorophenoxyacetic acid and Related Materials. Method ML-AM-71-48 dated Sep 24, 1971. (Unpublished study received Oct 7, 1974 under 359670; submitted by Rhone-Poulenc Chemical Co., Monmouth Junction, N.J.; CDL:230487-B) o337 REPORT ID: PDR20B01 / RUN DATE: 11/26/93 PAGE: 12 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM CPDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 00059656 Dow Chemical U.S.A. (19??) Basic Manufacturing Process for Lontrel 205 Herbicide. (Unpublished study received Nov 12, 1980 under 464-563; CDL:099729-G) 00059657 Dow Chemical U.S.A. (19??) Lontrel 205 Herbicide (M-3785). (Unpub lished study received Nov 12, 1980 under 464-563; C D L :099729- H ) 00059658 Boswell, G.L.; Jensen, D.J. (1979) Analysis of Dowco 290 and Vari ous Amine salts of 2,4-D in Formulation M-3785. Method # 79.5 dated Jul 6 , 1979. (Unpublished study received Nov 12, 1980 un der 464-563; submitted by Dow Chemical U.S.A., Midland, Mich.; CDL:099729-1) 00059659 Dow Chemical U.S.A. (19??) Physical and Chemical Properties of Lon trel 205 Herbicide. (Unpublished study received Nov 12, 1980 under 464-563; CDL:099729-J ) 00059660 Krause, R.E. (1976) Dowco 290 Alkanolamine salt Herbicide Formula tions: Dowco 290/2,4-D; M-3785 and Dowco 290/MCP; M-3786: Two Year Stability Data. (Unpublished study received Nov 12, 1980 under 464-563; submitted by Dow Chemical U.S.A., Midland, Mich.; CDL=099729-K) 00059698 Boswell, G.L.; Jensen, D.J. (1979) Analytical Procedure: Analysis of Dowco 290 and Various Amine.salts of 2,4-D in Formulation M-3785. Method # 79.5 dated Jul 6 , 1979. (Unpublished study received Nov 12, 1980 under 464-563; submitted by Dow Chemical U.S.A., Midland, Mich.; C DL:099730-C) 00059947 Pollock, R.J. (1980) Letter sent to Richard Mountfort dated Aug 1, 1980 $How levels of Nitrosamine are calculated I. (Unpublished study received Aug 6 , 1980 under 802-30; prepared by Analytical Development C o r p ., submitted by C h a s . H. Lilly Co., Miller Road Div., Portland, O r e g .; C D L :24 30 45 -A ) 00059948 Dow Chemical Company (1977) Determination of N-Nitrosodimethylamine in DMA- 6 Herbicide. Method ML-AM-77-56 dated Dec 27, 1977. (Unpublished study recieved Aug 6 , 1980 under 802-30; submitted by Chas. H. Lilly Co., Miller Road Div., Portland, Oreg.; CDL: 243045-B) 2,0 3 3 $ REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 13 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 29 D PART 1 MRID CITATION 00059949 Pollock, R.J. ( 1980) Letter seht to Willa Y. Garner dated Mar 26, 1980 $Raw data for Nitrosamine levels found in C h a s . H. Lilly C o . 's products I. (Unpublished study received Aug 6 , 1980 under 802-30; prepared by Analytical Development Corp., submitted by Chas. H. Lilly Co., Miller Road D i v ., Portland, O r e g .; CDL: 243045-C) 00060052 Green Dot Chemical Company (19??) Storage Stability Tests. (Un published study received Nov 25, 1969 under 10685-1; CDL: 226776-B) 00060871 Don Chemical U.S.A. (19??) The Name, Identity, and Composition of the Pesticidal Chemical: 4*2,4-- Dl . (Unpublished study received Jan 2, 1958 under PP0162; C D L :09 2439-B) 0061317 Guth Chemical Company (1961) Memorandum: iLithiuml. (Unpublished study received Feb 24, 1961 under unknown admin, no.; CDL: 101836-A) 00061642 Dow Chemical Company (19??) Lontrel 205 Herbicide (M-3785). (Un published study received Nov 12, 1980 under 464-563; CDL= 099730-B) 00063496 Monsanto Company (19??) The Name, Chemical Identity, Physical Com position of the Pesticide Chemical and Physical Properties: $Limit|. (Unpublished study received Aug 15, 1963 under 524148; CDL:100169-A) 00063508 Boving, P.A. (1978) Letter sent to Frank Phipps dated Apr 19, 1978 iTests of Sulv formulation using 80015 nozzles to apply 3/4 pint per acre of 2,4-D). (U.S. Department of Agriculture, Science and Education Administration, Federal Research-- Western Region, Yakima Agricultural Research Laboratory; unpublished study, in cluding Thompson-Hay ward Chemical Co. no. 4711; CDL *244533-K ) 00063509 Boving, P.A.; Winterfeld, R.G. (1977) Flow Tests and Droplet Sizing for Selected Materials from Thompson-Hayward Chemical Company. (U.S. Agricultural Research Service, Western Region, Yakima Ag ricultural Research Laboratory; unpublished study, including Thompson-Hayward Chemical Co. no. 4440; C D L ;24 4533-G) 5*033? REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 14 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 00063510 Colorado. Department of Agriculture C1977) Report on Flou Tests of Thompson-Hayward Sulv 2,4-D Preparations. (Unpublished study, including Thompson-Hayuard Chemical Co. no. 4392 ; C D L :244533-M) 00063816 Chevron Chemical Company (19??) Product Chemistry Data for Weed-BGon Intermediate. (Unpublished study received Nov 12, 1980 under 239-2485; C D L :243695 - A ) 00064510 Oxford Chemicals (1971) Analysis of 222 for 2,4-Dichlorophenoxyacetic Acid. (Unpublished study received Mar 23, 1971 under unknown admin, no.; C D L :22 83 3 4 - A ) 00066153 Velsicol Chemical Corporation (1971?) Summary. Summary of studies 229171--B, 229171-C and 229171-E. (Unpublished study received Aug 4, 1976 under 876-222; C D L :229171- A ) .,0067481 Vertac Chemical Corporation (1981) Product Chemistry for Vertac A6 D Technical. (Unpublished study received Jan 7, 1981 under 39511-84; CDL:244051-A) 00067482 Vertac Chemical Corporation (19??) 2,4-Dichlorophenoxyacetic Acid (2,4-D), Determination of. Undated method VJ-DA-1. (Unpub lished study received Jan 7, 1981 under 3951 1-84; C D L :244051- B ) 00067483 Fisher, J.R. (1980) 2,4-Dichlorophenoxyacetic Acid (2,4-D), Deter mination of the Isomeric Composition of. Undated method VJ-DA5. (Unpublished study received Jan 7, 1981 under 39511-84; sub mitted by Vertac Chemical Corp., Memphis, T e n n . ; C D L :244051- C ) 00067484 Vertac Chemical Corporation (19??) Sodium Chloride Content of the Phenoxy Acids. Undated method VJ-MS-4. (Unpublished study re ceived Jan 7, 1981 under 39511-84; C D L :244051-D) 00067500 Vertac Chemical Corporation (19??) Chlorophenoxyalkanoic Acids-Loss on Drying. Undated method VJ-MS-2. (Unpublished study re ceived Jan 7, 1981 under 39511-84; C D L :244051- E ) 00067501 Vertac Chemical Corporation (19??) Determination of Dichlorophenol in 2,4-D Acid. Undated method VJ-DA-4. (Unpublished study re ceived Jan 7, 1981 under 39511-84; C D L :244051-F) REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 15 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 00068008 Buser, H.R. (1976) Determination of 2,3,7,8-TCDD in TPH Samples; GC-MS Analysis of Fraction 2 of TPH Samples; prepared by Swiss Federal Research Station for Fruit Growing, Viticulture and Horticulture, Switzerland. Unpublished study; 10 p. 00071447 Chevron Chemical Company (1980) tNitrosamine Analyses: 2,4-D Amine and Other Products I. (Reports by various sources; unpublished study received Mar 3, 1981 under 239-2342 ; C D L :244486- A ) 00072445 Anderson Lawn Fertilizer (1979) Chromatogram Revisions. (Compila tion; unpublished study received Aug 28, 1980 under 9198-46; C D L :243173-A) 00072452 Anderson Lawn Fertilizer (1980) Chromatogram Revisions. (Compila tion; unpublished study received Aug 28, 1980 under 9198-46; CDL:243173-B) 00072597 Louie, H. (1981) ^Chemical Data Regarding Weed-B-Gon Interme diate (S X - 1290 )1 : Notebook No. 7107-07. (Unpublished study received May 12, 1981 under 239-2485; submitted by Chevron Chemical Co., Richmond, Calif.; C D L :245071- A ) 00073761 Norris, E.; Policastro, P. (1979) Formal Report of Analysis for N-Nitroso Compounds: Report No. 5450-677. (Unpublished study received Jul 24, 1979 under 7764-48; prepared by Thermo Electron C o r p ., submitted by Heritage House Products C o r p . , Warrensville Heights, Ohio; C D L :2 388 86 -A ) 00075710 Day, E.W.; Powers, F.L.; Koenig, D.K. (1978) Determination of Volatile Nitrosamines in Granular Formulations of Dinitroaniline Herbicides. Undated method 5801695. (Unpublished study re ceived Mar 20, 1978 under 961-209; prepared by Eli Lilly and Co., submitted by Lebanon Chemical Corp., Lebanon, Pa.; CDL: 242875-A) 000757 13 Marchio, J.L.; Spurlock, O.L. (1981) Letter sent to L.J. Helfant dated May 7, 1981: Nitrosamines in Super D Weedone, FWC. (Un published study received Jun 8 , 1981 under 264-190; submitted by Union Carbide Agricultural Products Co., Inc., Ambler, Pa.; CDL: 245480-A) <3.03*-f ( REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 16 K ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SE2UENCE BIBLIOGRAPHY 24 D PART 1 1RID CITATION 00075788 Dow Chemical Company (1963?) List of Formulations: $Tordonl. published study received Nov 21, 1967 under 8F0660; CDL: 091155-V) (Un 00077280 U.S. Department of Labor, Occupational Safety and Health Adminis tration (1972) Material Safety Data Sheet. (Unpublished study; CDL:244533-1) 0078452 Marchio, J.L.; Spurlock, O.L. (1981) Letter sent to Stan Harrison dated Jan 20 , 1981 ^Analyses for ni tr os amine I. (Unpublished study, including letter dated Sep 18, 1980 from J. Kruzynski to S.L. Harrison, received Jun 24, 1981 under 264-47; submitted by Union Carbide Agricultural Products Co., Inc., Ambler, Pa.; CDL: 245309-A) 0078878 Ralston Purina Company (1981) Four Power Plus: r t Lab No. 866441. Includes undated method entitled: Analysis of non-polar nitrosamines. (Unpublished study received Jul 16, 1981 under 3470484; submitted by Platte Chemical Co., Fremont, N e b r .; CDL: 245565-A) 00079473 Rothman, L.D.; Wisniewiski, D.F.; Kracht, W.R. (1978) Analysis of DMA-(TM)-4 Herbicide, DMA- 6 Unsequestered Herbicide, DMA- 6 Se questered Herbicide and MCP-amine Herbicide for N-nitrosodimethylamine: ML-AL 78-00370. Includes method dated Jun 19, 1978. (Unpublished study received Aug 24, 1978 under 464-467; submitted by Dow Chemical U.S.A., Midland, Mich.; C D L :245000- A ) 00079603 O.M. Scott Sons Company (19??) Method of Manufacture-- Dry Applied Super Turf Builder Plus 2, F-9299 (Imrpoved $sicl Super Turf Builder Plus 2). (Unpublished study received Nov 6 , 1980 under 538-168; C D L :2 4367 6 - A ) 00083114 Cholakis, J.M. (1979) Primary Eye Irritation Studies in Rabbits Using PBI/Gordon Corporation Test Materials EH590, EH591, EH597, adn EH598: MRI Project No. 4823-B(1). Final rept. (Unpublished study received Jul 15, 1981 under 2217-624; prepared by Midwest Research Institute, submitted by PBI-Gordon C o r p ., Kansas City, Kans.; C D L :245537- A ) 3o3^ REPORT ID: PDR20B01 RUN DATE : 11/26/93 PAGE: 17 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SESUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 000831 5 Unwin, S.E.; Cho lak is, J.M. (1980) Primary Eye Irritation Study in Rabbits Using PBI/Gordon Corporation Test Material EH552: MRI Project No. 4823-BC3). Final rept. (Unpublished study received Jul 15, 1981 under 2217-624; prepared by Midwest Research Institute, submitted by PBI-Gordon C o r p . , Kansas City, K a n s .; CDL :245537--B) 000831 6 Cholakis, J.M. (1980) Letter sent to J.S. Skaptason dated Jan 17, 1980= Eye irritation screen on nine (9) test compounds (EH604EH612): MRI Project No. 4823-B(2). (Unpublished study received Jul 15, 1981 under 2217-624; prepared by Midwest Research Institute, submitted by PBI-Gordon Corp., Kansas City, Kans.; C D L :245537 --C) 00083 1 7 Cholakis, J.M. (1979) Primary Eye Irritation Studies in Rabbits Using PBI/Gordon Corporation Test Materials EH588, EH589, EH592, EH594, EH595, and EH596: MRI Project No. 4823-B(1). Final rept. (Unpublished study received Jul 15, 1981 under 2217-624; pre pared by Midwest Research Institute, submitted by PBI-Gordon Corp., Kansas City, Kans.; C D L :245537 -D ) 000831 9 PBI/Gordon Corporation (1981) Confidential Statement of Formula: Gordon's Brush Killer 823. (Unpublished study received Ju1 15, 1981 under 2217-624; C D L :24 5537-F) 000831 0 Mehta, C.S.; Cannelongo, B.F.; Sabol, R.J.; et al. (1979) Rabbit Eye Irritation: e h 599 (Code 875): Project No. 1340-79. (Un published study received Jul 15, 1981 under 2217-624; prepared by Stillmeadow, Inc., submitted by PBI-Gordon Corp., Kansas City, Kans.; C D L :245537- H ) 000831 1 Cholakis, J.M. (1980) Primary Eye Irritation Studies in Rabbits Uwing PBI/Gordon Corporation Test Materials EH595 and EH601: MRI Project No. 4823-B(2). Final rept. (Unpublished study re ceived Jul 15, 1981 under 2217-624; prepared by Midwest Research Institute, submitted by PBI-Gordon Corp., Kansas City, Kans.; CDL:245537-1) 0.03^3 REPORT I D ' PDR20B01 RUH DATE: 11/26/93 PAGE: 18 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SE2UENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 00083123 Mehta, C.S.; Sabol, E.J.; Soliz, D.P. et. a l . (19811 Rabbit Eye Irritation: EH 683 Amine 2,4-D Acid 3.323% Dicamba 4.89% EX 003: Project No. 2131-81. (Unpublished study received Jul 15, 1981 under 2217-624; prepared by Stillmeadow, Inc., submitted by PBI-Gordon C o r p ., Kansas City, K a n s .; C D L :245537- K 1 00083124 PBI/Gordon Corporation (1981) Confidential Statement of Formula: BL 8,000 Lawn Weed Killer. (Unpublished study received Jul 15, 1981 under 22 17-624; C D L :245537-S) 00083125 PBI/Gordon Corporation (1981) Confidential Statement of Formula: T r i m e c - ' ( R ) H 448 Turf Herbicide Mfg . Cone. (Unpublished study received Jul 15, 1981 under 2217-624; C D L :2 45537-T) 00083127 PBI/Gordon Corporation (1981) Confidential Statement of Formula: G o r d o n 's Professional Turf P r o d u c t s ' T r i m e c - ( R ) n Herbicide. (Unpublished study received Jul 15, 1981 under 2217-624; CDL: 245537-V) 00083128 PBI/Gordon Corporation (1979) Confidential Statement of Formula: G o r d o n 's Professional Turf Products' Amine 2,4-D Turf Herbicide. (Unpublished study received Jul 15, 1981 under 2217-624; CDL: 245537-W) 00084413 O.M. Scott Sons Company (19??) Method of Manufacture: $Super Plus 2 Weed Control I. (Unpublished study received Nov 23, 1981 under 538-175; C D L :246 28 2 - A ) 00084414 O.M. Scott Sons Company (19??) Methods of Manufacture: Dry Ap plied Fertilizer Plus Dicot Weed Control I. (Unpublished study received Nov 23, 1981 under 538-175; C D L :246282 - B ) 00084415 O.M. Scott Sons Company (19??) Accelerated Shelf Life Study: $Super Plus 2 Weed Control I. (Unpublished study received Nov 23, 1981 under 538-175; C D L :246282-C) 00084416 O.M. Scott Sons Company (19??) Accelerated Shelf Life Study: $Dry Applied Fertilizer plus Dicot Weed Control!. (Unpublished study received Nov 23, 1981 under 538-175; C D L :24628 2 - D ) 9 3 cf ci REPORT ID: PDR20B01 RUH DATE : 11/26/93 PAGE: 19 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SESUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 00085933 O.M. Scott Sons Company (19??) Accelerated Shelf Life S t u d y - D r y Applied Super Turf Builder Plus 2 (Improved Super Turf Builder Plus 2). (Unpublished study received Nov 6 , 1980 under 538-168, C D L :243676-B) 00087666 Helton, D.O. (1979) Letter sent to John Wise dated Feb 8 , 1979: MRI letter report: Dimethylnitrosamine analysis in herbicide for mulations: MRI Project No. 4534-C. (Unpublished study received Mar 6 , 1979 under 1990-332; prepared by Midwest Research In stitute, submitted by Farmland Industries, Inc., Kansas City, Mo.; C D L :23778 2- A ) 00087667 Helton, D.O. (1978) Letter sent to John Wise dated Oct 26, 1978: Letter report: Dimethylnitrosamine analysis in herbicide for mulations: MRI Project No. 4534-C. Unpublished study; 8 p. U0088573 Unwin, S.E.; Cholakis, J.M. (1980) Primary Eye Irritation Study in Rabbits Using PBI/Gordon Corporation Test Material EH595: MRI Project No. 4823-B(3). Final rept. (Unpublished study received Jul 15, 1981 under 2217-624; prepared by Midwest Research Institute, submitted by PBI-Gordon C o r p ., Kansas City, K a n s .; C D L :245 53 7- G) 00089021 Cantor, L. (1981) Formal Report of Analysis for N-Nitroso Com pounds: Report No. 5450-3144. (Unpublished study received Jan 4, 1982 under 2217-647; prepared by Thermo Electron Corp., submitted by PBI-Gordon Corp., Kansas City, Kans.; C D L :246522 -A ) 00091037 Alferness, P. (1981) The Determination of Diethanolnitrosamine in Ortho Weed-b-gon Jet Weeder, Ortho Poison Ivy Control, and Ortho Diquat Water Weed Killer. Final rept. (Unpublished study re ceived Jan 5, 1982 under 239-1663; prepared by SRI Interna tional, submitted by Chevron Chemical Co., Richmond, Calif.; CDL:246548-A) 00091038 Alferness, P. (1981) The Determination of Diethanolinitrosamine in Ortho Weed-b-gon M. Final rept. (Unpublished study received Jan 5, 1982 under 239-2342; prepared by SRI International, sub mitted by Chevron Chemical Co., Richmond, Calif.; C D L :24 6549-A) Ro 3^-3 REPORT ID: PDR20B01 RUN DATE : 11/26/93 PAGE: 20 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 00093696 , Cantor, L. (1981) Formal Report of Analysis for N-Nitroso Com pounds: Report No. 5450-3267. (Unpublished study received Jan 8 , 1982 under 2217-655; prepared by Thermo Electron C o r p . , submitted by PBI-Gordon Corp., Kansas City, K a n s .; C D L :24 65 78- A) 00094059 O.M. Scott E Sons Company (1979) Long Term Shelf Life Storage. (Unpublished study received Jan 28, 1982 under 538-176; CDL: 246696-A) 00094624 Powers, F.L. (1981) Nitrosamine Assay Report: $Leb 10-6- 4/ 2,4 - D I . Includes procedure 5801695 dated Jan 4, 1978. (Unpublished study received Sep 17, 1981 under 961-214; prepared by Eli Lilly and Co., submitted by Lebanon Chemical Corp., Lebanon, Pa.; CDL:245975-A) 0094625 Powers, F.L. (1981) Nitrosamine Assay Report: ^Lebanon Dandelion Killer I. Includes procedure 5801695 dated Jan 4, 1978. (Un published study received Sep 17, 1981 under 961-214; prepared by Eli Lilly and Co., submitted by Lebanon Chemical Corp., Lebanon, Pa.; C D L :24 59 75 -B ) 00094626 Powers, F.L. (1981) Nitrosamine Assay Report: tGreen Goldl. In cludes procedure 5801695 dated Jan 4, 1978. (Unpublished study received Sep 17, 1981 under 961-214; prepared by Eli Lilly and Co., submitted by Lebanon Chemical Corp., Lebanon, Pa.; CDL: 245975-C) 00094629 Powers, F.L. (1981) Nitrosamine Assay Report: ^Homestead Weed E Feed!. Includes procedure 5801695 dated Jan 4, 1978. (Unpub lished study received Sep 17, 1981 under 961-214; prepared by Eli Lilly and Co., submitted by Lebanon Chemical Corp., Lebanon, Pa.; CDL:245975-F) 00094630 Powers, F.L. (1981) Nitrosamine Assay Report-' $Leb 10 - 6 -4/ 2,4 - D !. Includes procedure 5801695 dated Jan 4, 1978. (Unpublished study received Sep 17, 1981 under 961-214; prepared by Eli Lilly and Co., submitted by Lebanon Chemical Corp., Lebanon, Pa.; C D L :245 976 -A) SLO 3 REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 21 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 00094631 Powers, F.L. (1981) Nitrosamine Assay Report: $Green Goldl. In cludes procedure 5801695 dated Jan 4, 1978. (Unpublished study received Sep 17, 1981 under 961-214; prepared by Eli Lilly and Co., submitted by Lebanon Chemical C o r p ., Lebanon, Pa.; CDL: 245976-0 00094634 Powers, F.L. (1981) Nitrosamine Assay Report: ^Homestead Weed F e e d l . Includes procedure 5801695 dated Jan 4, 1978. (Unpub lished study received Sep 17, 1981 under 961-214; prepared by Eli Lilly and Co., submitted by Lebanon Chemical Corp., Lebanon, Pa.; CDL:245976-F) 00094635 Harwell, C.; Jones, C. (1981) Formal Report of Analysis for N-Nitroso Compounds: tMCPP + 2,4-D Amine I. Includes method no. F12-5-81 dated May 1981. (Unpublished study, including published data, received Aug 24, 1981 under 677-437; submitted by Diamond Shamrock Agricultural Chemicals, Cleveland, Ohio; C D L :245779 - A ) 00094655 Thompson-Hayward Chemical Company (1978) <tFlow Rates and Droplet Sizing Tests on Sulv Formulations I. (Compilation; unpublished study received Apr 21, 1981 under C081/3; submitted by state of Colorado for Thompson-Hayward Chemical Co., Kansas City, K a n s .; C D L :2 4 6 7 17-H) 00094657 Phipps, F.E.; Emenegger, D.B. (1981) A Study on the Drift of Two Different 2,4-D Amine Formulations from Aerial Application. (Unpublished study, including letters dated Apr 19, 1978 from P .A . Boving to Frank Phipps and Sep 25, 1981 from M. Mont gomery to Frank Phipps, received Jan 27, 1982 under 46946-246; submitted by Agriculture Nutrition Co., Crop Protection Div., Kansas City, Kans.; C D L :2467 15 - A ; 2467 14) 00094696 Cantor, L. (1982) Formal Report of Analysis for N-Nitroso Com pounds: Report No. 5450-3283. (Unpublished study received Feb 1, 1982 under 10107-30; prepared by Thermo Electron Corp., sub mitted by Corn Belt Chemical Co., McCook, N e b r .; C D L :246743-A ) 00094823 Thermo Electron Corporation (1981) ^Analysis of Gordon's 2,4-D1 Dicamba Amine Turf Herbicide I. (Unpublished study, including letter dated Dec 11, 1981 from U.A. Wessling to Richard Mountfort, received Dec 29, 1981 under 2217-647; submitted by PBIGordon Corp., Kansas City, Kans.; C D L :246521- A ) 9,02 REPORT ID: PDR20BO1 RUN DATE: 11/26/93 PAGE: 22 * ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (FDMS MRID SEUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 00096319 Cantor, L. (19821 Formal Report of Analysis for N-Nitroso Com pounds: Report No. 5450-3360. (Unpublished study received Feb 19, 1982 under 2217-657; prepared by Thermo Electron C o r p ., submitted by PBI-Gordon Corp., Kansas City, K a n s .; C D L :24 6839-A) 00096627 Cantor, L. (19821 Formal Report of Analysis for N-Nitroso Com pounds: Report No. 5450-3379. (Unpublished study received Mar 15, 1982 under 2217-656; prepared by Thermo Electron Corp., submitted by PBI-Gordon Corp., Kansas City, Kans.; C D L :247003 - A 1 00097949 O.M. Scott Sons Company ( 19 ??1 Method of Manufacture: Pets TB + 2 S. (Unpublished study received Mar 18, 1982 under 538179; C D L :247085-A1 00097950 O.M. Scott Sons Company ( 19 ?? 1 Accelerated Shelf Life Study: Pets TB+2 (Si F-9974. (Unpublished study received Mar 18, 1982 under 538-179; C D L :24 70 85 -B 1 00097951 O.M. Scott Sons Company (19791 Long Term Shelf Life Storage: $New Improved Turf Builder Plus 2, F-79881. (Unpublished study received Mar 18, 1982 under 538-179; C D L :24708 5- C1 00097970 Drinkwine, A.D. (19821 Letter sent to Don Fox dated Mar 11, 1982: Letter report, MRI project no. 4712-A37, nitrosamine analysis. (Unpublished study received Mar 25, 1982 under 36480-53; pre pared by Midwest Research Institute, submitted by Mid-America Chemical Co., Inc., Leavenworth, Kans.; C D L :247104 - A 1 00098483 Allen, A. (19811 Formal Report of Analysis for N-Nitroso Compounds: Report No. 5450-2586. (Unpublished study, including letter dated May 1, 1981 from U.A. Wessling to Richard Mountfort, re ceived May 8 , 1981 under 2217-647; prepared by Thermo Electron Corp., submitted by PBI-Gordon Corp., Kansas City, Kans.; CDL: 245 049-A 1 00100096 Rozek, A.; Grins, G.; Smith, M.; et a l . (19781 Analysis of Various Pesticide Formulations for Nitrosamine Content: Report 480060, No. 2. (Unpublished study received Aug 29, 1978 under 876-234; submitted by Velsicol Chemical Corp., Chicago, IL; C D L :235035-B 1 REPORT ID: PD R2 0B0 1 RUN DATE: 11/26/93 PAGE: 23 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (P D M S ) MRID SE2UENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 00100976 Forrette, J.; Trujillo, W.; Smith, M.; et a l . (1977) Analysis of the Dimethylnitrosamine Content of Technical Dicamba, Principal Banvel Formulations and Dimethylamine Used in the Formulation of Banvel Products: Report 480060, No. 4. (Unpublished study received Aug 29, 1978 under 876-234; submitted by Velsicol Chemical Co r p . , Chicago, IL; C D L :235035-A) 00100977 Rozek, A. (1978) Dimethylnitrosamine Storage Stability Study for Banvel DMA Formulations. (Unpublished study received Aug 29, 1978 under 876-234; submitted by Velsicol Chemical Corp., Chicago, IL; C D L :23503 5 - C ) 00101519 Warden, S.W. (1981) Weed-b-gon RTU (CC 11545). (Unpublished study received Apr 16, 1982 under 239-2499; submitted by Chevron Chem ical Co., Richmond, Calif.; C D L :247287-A) U O 101520 Chevron Chemical Company (19??) Product Chemistry Data for Weed-bgon Weed Killer. (Unpublished study received Apr 16, 1982 under 239-2499; C D L :247 28 8- A) 00101521 Chevron Chemical Company (1982) Weed-b-gon Weed Killer: Product Chemistry Data. (Unpublished study received Apr 16, 1982 under 239-2499; C D L :247 289-A) 00101525 Eckerl, J.A. (1982) Determination of N-Nitrosodimethylamine in a Sample for Testing Broadleaf Spot Weed Killer Aerosol: PGU-0182. Unpublished study; 10 p. 00101613 Eckert, J. (1932) Determination of N-Nitrosodimethylamine in a Sam ple for Testing Broadleaf Spot Weed Killer Aerosol: PGU-01-82: 1.21% DMA Salt of 2,4-D; 31% DMA Salt of Dicamba. Unpublished study; 10 p . 00101712 Dow Chemical Co. (1971) Determination of 2,3,7,8 -Tetrachlorodibenzo-P-dioxin in 2,4,5-Trichlorophenoxyacetic Acid and Related Materials: ML-AM-71-48. (Unpublished study received Apr 18, 1972 under 464-431; C D L :003666-C) 00102539 Renner, V., inventor; O.M. Scott and Sons Co., assignee (1963) Fertiliser compositions and process. U.S. patent 3,076,700. Feb 5. 9 p. Cl. 71-29. (Published study; C D L :008534-A ) > REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 24 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 00102545 Parker Laboratory, Inc. (1971) Certificate of Analysis: ^Chicago Activated Sludge!: Analysis No. 4611. (Unpublished study re ceived Oct 28, 1971 under 7404-8; submitted by Nulife Fertil isers, D i v . of Hygrade Food, Takoma, WA; C D L :009138-A ) 00102546 Nulife Fertilisers (19??) Chicago Activated Sludge or Chi-organic or Sterilised Organic Matter. (Unpublished study received Oct 28, 1971 under 7404-8; C D L :009138-B ) 00102565 Wirth, M.; Wasco, J. (19??) Formula 40 Herbicide: Evaluation of Boric Acid-- Versene Acid Chelant Combination as Sequestrant. (Unpublished study received Sep 3, 1970 under 464-1; submitted by Dow Chemical U.S.A., Midland, MI; CDLs003389-A ) 00102596 Wirth, M.; Wasco, J. (19??) DMA-4: Evaluation of Formulation M-3538. (Unpublished study received on unknown date under 196; submitted by Dow Chemical U.S.A., Midland, MI; CDL: 022966-A) 464- 00102604 General Aniline 8 Film Corp. (19??) Igepon. New York, NY: G A F C . (Technical bulletin 7543-093; also In unpublished submission received Apr 24, 1970 under 1990-102; submitted by Farmland I n d ., Inc., Kansas City, MO; C D L :02 52 22 -A ) 00102615 U.S. Dept, of the Army (19??) Data Sheet Giving the Chemical and Physical Properties of the Chemical: tAlkanolamine Salts of 2, 4-Dl. (Unpublished study; C D L :091051- C ) 00102617 U.S. Dept, of the Army (19??) Laboratory Test I: $Availability of Encapsulated Alkanolamine Salts of 2,4-Dl. (Unpublished study; C D L :091051-E) 00102707 Florida Fruit Vegetable Assoc. (19??) Name, Chemical Identity and Composition of the Pesticide Chemical: $2,4-Dl. (Unpublished study received Sep 26, 1960 under PP0272; C D L :092551- A ) 00102823 Dow Chemical Co. (1963) $2,4-Dow Weed Killer Formula: Chemical Study!. (Unpublished study received Apr 10, 1963 under unknown admin, no.; C D L :122181- A ) &{C>3S REPORT ID: PDR20B01 RUH DATE: 11/26/93 PAGE : 25 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 00102832 Anon. (1957) 2,4-D and 2,4,5-T Compounds. (Unpublished study re ceived Aug 1, 1957 under unknown admin, no.; submitted by ?; C D L :124813-A) 00102880 Inter-Chem, Ltd. (1977) ^Chemical Study of 2,4-Dichlorophenoxyacetic Acid I. (Compilation; unpublished study received Apr 25, 1977 under 40512-EX-1; C D L :233162 - A ) 00102882 Inter-Chem, Ltd. (1976) ^Residue Studies of 2,4-Dichlorophenoxyacetic Acid, Its Amine Salts and Esters on a Variety of Crops I. (Compilation; unpublished study received Apr 25, 1977 under 4051 2- E X - 1; C D L :233162-C) 00102890 Powers, F.; Koenig, D. (1978) Nitrosamine Assay Report: ^Dandelion and Chickweed Killerl. (Unpublished study received Oct 30, 1978 under 961-282; prepared by Eli Lilly and Co., submitted by , Lebanon Chemical C o r p . , Lebanon, PA; C D L :235902-A) 00102891 Powers, F.; Koenig, D. (1978) Nitrosamine Assay Report. (Unpub lished study received Oct 30, 1978 under 961-219; prepared by Eli Lilly and Co., submitted by Lebanon Chemical Corp., Lebanon, PA; C D L :235903-A) 00102892 Powers, F.; Koenig, D. (1978) Nitrosamine Assay Report. (Unpub lished study received Oct 30, 1978 under 961-327; prepared by Eli Lilly and Co., submitted by Lebanon Chemical Corp., Lebanon, PA; C D L :235905-A) 00102893 Fan, T. (1978) Formal Report of Analysis for N-Nitroso Compounds. (Unpublished study received May 23, 1978 under 034704-5; pre pared by Thermo Electron Corp., submitted by Platte Chemical Co., Fremont, NE; C D L :23 65 4 6 - A ) 00102894 Kulkarni, S. (1978) Report on the Analysis of N-Nitrosoamine Contaminant: iVertac Weed-Rhap A-6 D Herbicidel. (Unpublished study received Jul 14, 1978 under 35911-67; prepared by Vertac, Inc., submitted by Rivhard Conn., Inc., Southfield, MI; C D L :236547-A ) 00102895 Kulkarni, S. (1977?) Report on the Analysis of N-Nitrosoamine Contaminant: tVertac Weed Rhap A-5D Herbicidel. Unpublished study received Jul 14, 1978 under 35911-66; prepared by Vertac, Inc., submitted by Rivhard Conn., Inc., Southfield, MI; C D L :236549-A ) <3,03 5 [ REPORT ID: PDR20B01 RUH DATE: 11/26/93 PAGE: 26 ENVIRONMENTAL PROTECTION AGENC PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM CPDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 001028 96 Kulkarni, S. (1978) Report on the Analysis of N-Nitrosoamine Con taminant: iVertac Brush Rhap A-2D-2T Herbicide I. (Unpublished study received Jul 11, 1978 under 35911-16; prepared by Vertac, Inc., submitted by Rivhard Conn., Inc., Southfield, MI; CDL: 2 36550-A) 001029 00 Stebbins, P. (1978) Formal Report of Analysis for N-Nitroso Com pounds. (Unpublished study received Jan 4, 1979 under 34704-5; prepared by Thermo Electron C o r p . , submitted by Platte Chemical Co., Fremont, NE; C D L :236768-A ) 001029 01 Raltech Scientific Services, Inc. (1978) Report of Analyses. $228148 Riverdale Turf W e e d e s t r o y - D I : Lab No. 710806. (Unpublished study received Jan 12, 1979 under 228-148; submitted by Riverdale Chemical Co., Chicago Heights, IL; C D L :237378-A ) V/01029 02 O.M. Scott Sons Co. (1979) Long Term Shelf Life Storage: $New Improved Turf Builder Plus 2, F-7988I. (Unpublished study re ceived Apr 18, 1979 under 538-28; C D L :238174 - A ) 001029 03 Raltech Scientific Services, Inc. (1978) Report of Analyses: $Riverdale Turf Weedestroy-D: Batch BC-02I. (Unpublished study re ceived Apr 17, 1979 under 228-148; submitted by Riverdale Chem ical Co., Chicago Heights, IL; C D L :238201- A ) 00 1029 07 Vernetti, J.; Meyer, D. (1979) HPLC Method and Analysis Results for Five Representative Samples of Technical 2,4-D Products. (Unpublished study received Aug 16, 1979 under 359-177; sub mitted by Rhone-Po ul en c, Inc., Manmouth Junction, N J ; CDL: 240915-A) 00 1046 73 Cantor, L. (1982) Formal Report of Analysis for N-Nitroso Com pounds: Report No. 5450-3341. (Unpublished study received Feb 2, 1982 under 2217-662; prepared by Thermo Electron Corp., submitted by PBI-Gordon Corp., Kansas City, K a n s .; C D L :246710 - A ) 001051 94 Gaudin, D. (1982) Summary of R e s u l t s : $Assay for N-nitrosodimethylamine in 2 , 4 - D l . (Unpublished study received Jun 15, 1982 under 677-446; submitted by Diamond Shamrock Agricultural Chem icals, Cleveland, OH; C D L :247714 -A ) 5kC>3iSc5s. REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE : 27 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 00106021 Cantor, L. (1981) Formal Report of Analysis for N-nitroso Com pounds: Report No. 5450-2980. (Unpublished study received Jul 7, 1982 under 2217-681; prepared by Thermo Electron Cor p., sub mitted by PBI-Gordon Corp., Kansas City, MO; C D L :247822-A) 00107814 Hercules Powder Co., Inc. (1959) Amine D or Amine 750 Acetate in Water, Brine, Etc.: a 43.5-6. Rev. (Unpublished study received Oct 20, 1961 under unknown admin, no.; C D L :120046 - A ) 00108873 Rivhard Conn., Inc. (1978) Report on the Analysis of N-nitrosoamine Contaminant. (Compilation; unpublished study received Jul 14, 1978 under 35911-64; C D L :236548-A) 00109249 Hazleton Raltech, Inc. (1982) Report: Riverdale 3 Plus 3 Amine: E D 08: RT Lab No. 932758. (Unpublished study received Jul 19, 1982 under 228-160; submitted by Riverdale Chemical Co., Chicago Heights, IL; C D L :247881- A ) 00109282 Logsdon, 0. (1982) Letter sent to L. Maillet dated Jul 8, 1982 Data on dimethyl nitrosamine I. (Unpublished study received Jul 27, 1982 under 40831-124; prepared by Rocky Mountain Ana lytical Laboratory, submitted by Falls Chemicals, Inc., Great Falls, MT; C D L :247908 - A ) 00110436 Gaudin, D. (1982) Report of Analysis for N-Nitrosodimethylamine in MCPP/2,4-D Amine (2 + 2). (Unpublished study received Aug 17, 1982 under 677-451; submitted by Diamond Shamrock Agricultural Chemicals, Cleveland, OH; C D L :248120- A ) 00112870 Cormier, J. (1982) Formal Report of Analysis for N-nitroso Com pounds: Report No. 5450-3832. (Unpublished study received Aug 30, 1982 under 2217-603; prepared by Thermo Electron Corp., submitted by PBI-Gordon Corp., Kansas City, MO; C D L :248222-A) 00 116264 Lee, J. (1978) $Evik 80W: Chemical Study I: Project No. 102039. (Unpublished study received Jun 22, 1978 under 100-473; sub mitted by Ciba-Geigy Corp., Greensboro, NC; C D L :234173 - A ) 00118420 Cantor, L. (1982) Formal Report of Analysis for N-Nitroso Com pounds: Report No. 5450-3979. (Unpublished study received Nov 23, 1982 under 2217-671; prepared by Thermo Electron Corp., sub mitted by PBI-Gordon Corp., Kansas City, MO; C D L :248890 -A) 9\03^3 REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 28 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 00118421 Hazleton Raltech, Inc. C1982) Fertiliser 10-6-4 (with Broadleaf Weed Killer): r t Lab No. 701516. (Unpublished study received Nov 22, 1982 under 8123-100; submitted by Frank Miller Sons, Inc., Chicago, IL; C D L :248891- A ) 00123280 Dow Chemical U .S .A . (1978) Chemical Study: Picloraml. (Compila tion; unpublished study received Dec 9, 1982 under 464-502; CDL: 248983-A) 00125386 Cantor, L. (1983) Formal Report of Analysis for N-Nitroso Com pounds: $Weed and Feed|: Report No. 5450-4327. (Unpublished study received Feb 16, 1983 under 2217-697; prepared by Thermo Electron C o r p . , submitted by PBI-Gordon C o r p . , Kansas City, MO; C D L :249528-A) 0126081 Cantor, L. (1982) Formal Report of Analysis for N-Nitroso Com pounds : Report No. 5450-4246. (Unpublished study received Feb 7, 1983 under 2217-543; prepared by Thermo Electron Corp., submitted by PBI-Gordon Corp., Kansas City, MO; C D L :249479- A ) 00126136 Cantor, L. (1982) Formal Report of Analysis for N-nitroso Com pounds: Report No. 5450-4221. (Unpublished study received Dec 17, 1982 under 802-547; prepared by Thermo Electron Corp., submitted by C h a s . H. Lilly Co., Portland, OR; C D L :24914 0 - A ) 00126211 Hawley, T. (1983) Nitrosamine Analysis of Ded-weed Sulv. (Unpub lished study received Feb 22, 1983 under 400-390; prepared by Hazleton Raltech, Inc., submitted by Uniroyal Chemical, Bethany, CT; C D L :249624-A) 00126683 Cantor, L. (1982) Formal Report of Analysis for N-Nitroso Com pounds: Report No. 5450-3979. (Unpublished study received Apr 1, 1983 under 2217-703; prepared by Thermo Electron Corp., submitted by PBI-Gordon Corp., Kansas City, MO; C D L :249863 - F ) 00126758 Hazleton Raltech, Inc. (1983) Riverdale Weedestroy AM-40 Salt, Herbicide Dimethylamine Salt of 2,4-D 47.3%: 1: No. 747117. (Unpublished study received Mar 24, 1983 228-145; submitted by Riverdale Chemical Co., Chicago IL; C D L :249900-A) Amine RT Lab under Heights, 0 .0 3 5 *+ REPORT ID-' PDR20 B0 1 RUN DATE: 11/26/93 PAGE: 29 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM CPDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION O O 127784 PBI-Gordon Corp. (1983) Product Chemistry: iMecoprop, Trimec| . (Compilation; unpublished study received Apr 1, 1983 under 2217-EX-3 ; C D L :07 1501-A ) 00129608 Hazleton Raltech, Inc. (1983) Report: Ded Weed Sulv 2,4-D: RT Lab No. 780676. (Unpublished study received Jul 27, under 400-390; submitted by Uniroyal Chemical, Bethany, C D L :250 848 -A) 1816: 1983 CT; 00129634 O.M. Scott Sons Co. (1983) Product Chemistry to Support Proturf Fertilizer Plus Dicot Weed Control III. (Compilation; unpub lished study received Jul 28, 1983 under 538-186; C D L :250866 - A ) 00130239 Powers, F. (1981) Nitrosamine Assay Report: ^Lebanon Dandelion Killer I. (Unpublished study received Sep 17, 1981 under 961-214; prepared by Eli Lilly and Co., submitted by Lebanon Chemical Corp., Lebanon, PA; C D L :245976- A ) 00130255 Hazleton Raltech, Inc. (1982) Report: $Dimethylamine Salt of 24 D : 38.6% 24D Isomer I: RT Lab No. 937477. (Unpublished study received Apr 2, 1982 under 34704-120; submitted by Platte Chemical Co., Fremont, NE; C D L :247137- A ) O O 130701 Chevron Chemical Co. (1983) Weed-B-Gon Jet Weeder Formula II: Human Safety Data. (Compilation; unpublished study received Aug 15, 1983 under 239-2510; C D L :251025-A ) 00131028 Forster Consultants, Inc. (1983) Report of Analysis for N-Nitrosodimethylamine in . . . inert ingredient. Unpublished study. 00132505 O.M. Scott Sons Co. (1979) $Study--Chemistry: Turf Builder Plus 2, F-7988I. (Compilation; unpublished study received Feb 15, 1983 under 538-28; C D L :249518 - D ) 00133169 Guardigli, A. (1971) Analysis of Weed-Broom Formulation by Ultravi olet Spectrophotometry and Thin Layer Chromatography. (Unpub lished study received Dec 14, 1971 under 359-627; prepared by Rhodia, Inc., submitted by Rhone-Poulenc, Inc., Monmouth Junc tion, NJ; C D L :023338-B) <^0353^ REPORT ID: PDR20B01 RUH DATE: 11/26/93 PAGE: 30 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 00135687 National Agricultural Chemicals Assoc. (1973) The Name, Chemical Identity and Composition of the Pesticide Chemical: tDou 2,4-D Acid and Esters I. (Compilation; unpublished study received Sep 7, 1973 under 8F0670; C D L :092969-A) 00138866 Dow Chemical U.S.A. (1983) Product Chemistry: $2,4-Dichlorophenoxy Acetic Acidi. 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(1978) Analysis of M-3785 Herbicide for Possible Pres ence of N-nitrosodiisopropanolamine and N-nitrosodiethanolamine. (Unpublished study received Dec 21, 1978 under 464-EX-55; sub mitted by Dow Chemical U . S . A . , Midland, MI; C D L :236656 - K ) 00141319 Zilis, K. (1984) Letter sent to R. Mountfort dated July 3, 1984: [analysis of Dimethylnitrosoamine by Chromatograms]. Prepared by Rocky Mountain Analytical Laboratory. 10 p. 00145022 Craine, E. (1984) A Stability Study with Lesco Tri-Power: Project WIL-23011. Unpublished study prepared by Wil Research Laborato ries, I n c . 16 p . 00145023 Craine, E. (1984) A Method for Analysis of Active Ingredients in Lesco Tri-Power: Project: WIL-23011. Unpublished study prepared by Wil Research Laboratories, Inc. 16 p. c3.033fc REPORT ID: PDR20B01 RUH DATE: 11/26/93 PAGE: 31 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SE2UENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 00145425 Union Carbide Agricultural Products Company, Inc. C1985) [Product Chemistry-Weedone DPC Amine]. Unpublished compilation. 23 p. 00146263 Kowite, W. (1985) Letter sent to W. Davis dated Jun 4, 1985. Weedone DPC Amine Method of Manufacture. Prepared by Union Carbide Agricultural Products Co., Inc. 8 p. 00146504 Thermo Electron Corp. (1985) Formal Report of Analysis for NNitroso Compounds: Report No. 5450-5934. 23 p. 00146715 Union Carbide Agricultural Products Company, Inc. (19??) Product Chemistry [Super D Weedone Brand-- Manufacturing Concentrate]. Unpublished compilation. 27 p. 00146718 Union Carbide Agricultural Products Company, Inc. (19??) 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Analytical Services Laboratory. 24 p . 40053700 PBI/Gordon Corp. (1986) Trimec 871 pilation of 1 s tudy . Product Chemistry Data Corn- 40053701 Cahoy, R. (1987 ) Trimec 871 - Product Chemistry prepared by PBI/Gordon Corp. 6 p. Unpublished study 40095900 Riverdale Chemical Co. (1987) Application for Pesticide Registra tion on Riverdale Triamine Premium Liquid Weed and Feed. Trans mittal of 1 study. 40095901 Sawyer, R. (1987) Product Chemistry [Data]: Riverdale Triamine Premium Liquid Weed and Feed. Unpublished study prepared by Riverdale Chemical Co. 19 p. 40109000 PBI/Gordon Corp. (1987) Submission of Product Chemistry Data to Support the Registration of Trimec Southern Liquid Weed Feed 25-0-0. Transmittal of 2 studies. c k 0 3 (o I REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 36 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SE2UENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 40109001 Cahoy, R. (1987) Trimec Southern Liquid Weed Feed 25-0-0--Product Chemistry. Unpublished study prepared by PBI/Gordon Corp. 7 p. 40109002 Goff, U. (1987) Trimec Southern Liquid Weed Feed 25-0-0: Formal Report of Analysis for N-Nitroso Compounds: Laboratory Project ID: 5450-2599. Unpublished study prepared by Thermedics, Inc. 16 p. 40124700 PBI/Gordon Corp. (1987) Submission of Chemistry Data to Support the Registration of Trimec 902. Transmittal of 1 study. 40124701 Cahoy, R. (1987) Trimec 902 - Product Chemistry. Unpublished study prepared by PBI/Gordon Corp. Formulation Laboratory. 7 p. 40129500 Riverdale Chemical Co. (1987) Submission of Product Chemistry Data in Support of Application for Registration of Riverdale Triamine 3-way Lawn Weed Killer. Transmittal of 1 study. 40129501 Sawyer, R. (1987) Product Chemistry: Triamine 3-way Lawn Weed Killer. Unpublished compilation prepared by Riverdale Chemical C o . 19 p . 40131600 MFA Oil Co. (1987) Supplemental Submission of Product Chemistry Data in Support of Application for Registration of MFA Oil Co. Amine Weed Killer. Transmittal of 1 study. 40131601 Currie, G. (1987) MFA Oil Co. Amine Weed Killer: Supplemental Submission: storage Stability. Unpublished study prepared by Imperial, Inc. 6 p. 40 134600 Imperial Inc. (1 87 ) submissi on of Chemistry Data To Support the Application f r Ne w Produc t Registration: Land O'Lakes, Inc. Amine 4 2,4-D We ed K i l l e r . Transmittal of 1 study. 40134601 40134800 Cu r r i e , G . (1987 Lan d 0 'Lake s, Inc.: Amine 4 2,4-D Weed Killer: Product Chemi tr y Unpubl ished compilation prepared by Imperial Inc. 6 P / Imperial Inc. (1987) Submission of Chemistry Data To Support the Application for New Product Registration of Land O'Lakes, Inc. Low Volatile 4 2,4-D Weed Killer. Transmittal of 1 study. P i03(o ^L REPORT ID: PDR20B01 RUN DATE : 11/26/93 PAGE: 37 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 40 134301 Currie, G. (198 7) Land O 'Lakes, Inc.: Lou Volatile 4 2,4-D Weed Killer: Product Chemistry. Unpublished compilation prepared by Imperial Inc. 6 p. 40 134900 Land O'Lakes, Inc. (1987) Submission of Product Chemistry Data To Support the Registration of Land O 'Lakes Inc. Lou Volatile 6 2,4-D Weed Killer. Transmittal of 1 study. 40134901 Currie, G. (1987) Land O'Lakes, Inc. Lou Volatile 6 2,4-D Weed Kil ler: [Storage Stability Data]. Unpublished study prepared by Imperial Inc. 6 p. 40167700 Nationuide Chemical Products, Inc. (1987) Submission of Product Chemistry Data in Support of Registration of Liquid Weed & Feed for Sensitive Grasses. Transmittal of 1 study. -,0 167701 Nationuide Chemical Products, Inc. (1987) Liquid Weed & Feed for Sensitive Grasses: Product Chemistry Data. Unpublished com pilation. 14 p. 40167800 Nationuide Chemical Products, Inc. (1987) Submission of Product Chemistry Data in Support of Application for Registration of Liquid Weed Feed. Transmittal of 1 study. 40167801 Nationuide Chemical Products, Inc. (1987) Liquid Weed Feed: Product Chemistry Data. Unpublished compilation. 14 p. 40180300 Riverdale Chemical Co. (1987) Submission of Data To Support the Application for Riverdale Triamine II Premium Liquid Weed and Feed Registration: Product Chemistry Study. Transmittal of 1 study. 40180301 Sauyer, R. (1987) Product Chemistry [Data for]: Riverdale Triamine II Premium Liquid Weed and Feed. Unpublished study prepared by Riverdale Chemical Co. 19 p, 40183100 PBI/Gordon C o r p . (1987) Submission of Chemistry and Toxicity Data of Trimec M 905: Application for Registration. Transmittal of 2 studies . 40183101 Cahoy, R. (1987) Trimec M 905--Product Chemistry. Unpublished com pilation prepared by PBI/Gordon Corp. 7 p. 0 3 (o3> REPORT I D PDR20B01 RUN DATE : 11/26/93 PAGES 38 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SESUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 40201300 Riverdale Chemical Co. (1987) Submission of Data To Support the Application for Registration of Riverdale Triamine Premium 6 6 6 6 Liquid Weed and Feeds Product Chemistry Study. Transmittal of 1 study. 40201301 Sawyer, R. (1987) Product Chemistry: Riverdale Triamine Premium 6 6 6 6 Liquid Weed and Feed. Unpublished compilation prepared by Riverdale Chemical Co. 19 p. 40218800 Riverdale Chemical Co. (1987) Submission of Product Chemistry Data To Support the Application for Pesticide Registration of River dale Triamine II Premium 75 Liquid Weed and Feed. Transmittal of 1 st u d y . 40218801 Sawyer, R. (1987) Product Chemistry: Riverdale Triamine II Premium 75 Liquid Weed and Feed. Unpublished study prepared by River dale Chemical Co. 19 p. 40221200 Riverdale Chemical Co. (1987) Submission of Data To Support the Application for Pesticide Registration of Riverdale Sweet Six teen Weed and Feed with Triamine II. Transmittal of 7 studies. 40221201 Sawyer, R. (1987) Product Chemistry: Riverdale Sweet Sixteen Weed and Feed with Triamine II. Unpublished compilation prepared by Riverdale Chemical Co. 19 p. 40237900 Nationwide Chemical Products, Inc. (1987) Submission of Chemistry Data for Liquid Weed Feed for Sensitive Grasses 20-0-0. Transmittal of 1 study. 40237901 Valentine, D. (1987) Liquid Weed Feed for Sensitive Grasses 20-00: Product Chemistry Data. Unpublished study prepared by N a tionwide Chemical Products, Inc. 14 p. 40241300 Riverdale Chemical Co. (1987) Submission of Product Chemistry Data in Support of Application for Registration of Riverdale Tri amine Granular Weed Killer. Transmittal of 1 study. 40241301 Sawyer, R. (1987) Product Chemistry: Riverdale Triamine Granular Weed Killer. Unpublished compilation prepared by Riverdale Chemical Co. 19 p. REPORT ID: PDR20B01 RUN DATE PAGE : ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 11/26/93 39 40257200 Knox Fertilizer Chemical Co. (1987) Submission of Product Chemis try Data To Support the Registration of Shaw's Premium Weed Feed w/25-3-3 Lawn Food. Transmittal of 2 studies. 40257201 McLane, H. (1987) Product Specific Data: S h a w 's Premium Weed Feed W/25-3-3 Lawn Food: Laboratory Project ID: P C/ 83 78 -W F .P C 1 . Unpublished study prepared by Knox Fertilizer Chemical Co. in cooperation with Hazelton Laboratories, Inc. 6 p. 40257202 McLane, H. (1987) Nitrosamine Study: Shaw's Premium Weed Feed W/25-3-3 Lawn Food: Laboratory Project ID: 02xx 000385-00. Un published study prepared by Hazelton Laboratories, Inc. 7 p. 40273600 Dow Chemical U.S.A. (1987) Submission of Product Chemistry Data for Curtail Herbicide. 38 p. -+027360 1 Baker, R. ( 1987 ) Product Chemistry: Curtail Herbicide. Unpublished study prepared by Dow Chemical U.S.A. , Agricultural Chemistry Laboratories Research and Development. 38 p. 40286700 Nationwide Chemical Products, Inc. (1987) Submission of Chemistry Data of Liquid Weed Feed 25-0-0. Transmittal of 1 study. 40286701 Valentine D. (1987) Liquid Weed Feed 25-0-0: [Product Chemistry ]. Unpublished study plepared by Nationwide Chemical Prod u c t s , I n c . 14 p . 40305300 PBI/Gordon Corp. (1987) Submission of Product Chemistry and Toxi cology Data in Support of Application for Registration of DM 899 Liquid Weed Feed. Transmittal of 8 studies. 40305301 Cahoy, R. (1987) DM 899 Liquid Weed Feed-- Product Chemistry. Unpublished compilation prepared by PBI/Gordon Corp. 7 p. 40305302 Goff, U. (1937) DM 899 Liquid Weed Feed: Formal Report of Analy sis for N-nitro Compounds: Lab Project ID: 5450-2626. Unpub lished study prepared by Thermedics Inc. 20 p. 40305700 PBI/Gordon Corp. (1987) Submission of Product Chemistry Toxicity Data To Support the Registration of DMDP 897. Transmittal of 8 studies. oiC>3 REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE : 40 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SE2UENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 40305701 Cahoy, R. C1987) DMDP 897--Product Chemistry [Data]. Unpublished study prepared by PBI/Gordon Corp. 7 p. 40305702 Goff, U. (1987) DMDP 897: Formal Report of Analysis for N-Nitroso Compounds: Laboratory Project ID: 5450-2712. Unpublished study prepared by Thermedics Inc. 16 p. 40306700 PBI/Gordon Corp. (1987) Submission of Data To Support the Applica tion for New Registration of DM 896. Transmittal of 8 studies. 40306701 Cahoy, R. (1987) DM 896-- Product Chemistry [Data]. Unpublished compilation prepared by PBI/Gordon Corp., Formulation Laborato ry. 4 p. 40307000 PBI/Gordon Corp. (1987) Submission of Chemistry Data for New Regis tration of Trimec M908. Transmittal of 2 studies. 40307001 Cahoy, R. (1987) Trimec M 908 Liquid Weed Feed-- Product Chemis try. Unpublished compilation prepared by PBI/Gordon Corp. 7 p. 40307002 Steven, J. (1987) Trimec M 908 Liquid Weed Feed: Formal Report of Analysis for N-Nitroso Compounds: Laboratory Project ID: 54502815. Unpublished study prepared by Thermedics Inc. 18 p. 40307300 PBI/Gordon Corp. (1987) Submission of Toxicology Data to Support the Registration of DMDP 898 Liquid Weed Feed. Transmittal of 8 studies. 40307301 Cahoy, R. (1987) DMDP 898 Liquid Weed Feed - Product Chemistry. Unpublished study prepared by PBI/Gordon Corp. 7 p. 40309400 Imperial Inc. (1987) Submission of Product Chemistry Data in,Sup port of Application for Registration of Cenex/Land O'Lakes 4 L G . Transmittal of 1 study. 40309401 Currie, G. (1987) Cenex/Land O'Lakes 4LG: (2,4-D Amine)-- Product Chemistry and Storage Stability. Unpublished compilation pre pared by Imperial Inc. 26 p. 40339800 PBI/Gordon Corp. (1987) Submission of Data To Support the Applica tion of Trimec 914: Product Chemistry Data. Transmittal of 2 studies. 0-03 Q>Cq REPORT ID: PDR20B01 RUN DATE PAGE : ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 MRID ' CITATION 1 1/26/93 41 40339801 Cahoy, R. (1987) Trimec 914--Product Chemistry. Unpublished compi lation prepared by PBI/Gordon Corp., Formulation Laboratory. 7 P 40339302 Stevens, J. (1987) Trimec 914: Formal Report of Analysis for N-Nitroso Compounds: Laboratory Project ID: 5450-3165. Unpublished compilation prepared by Thermedics Inc., Analytical Service Lab oratory. 14 p. 40346500 Dow Chemical Co. (1978) Submission of Efficacy, Toxicity and Environmental Fate Data To Support the New Registration of Garion 3A Herbicide. Transmittal of 19 studies. 40424000 Chevron Chemical Co. (1987) Submission of Data To Support the Regi stration of Weed-B-Gon Ready-Spray Lawn Weed Killer: Product Chemistry Data. Transmittal of 1 study. 40424001 Thornberry, N.; Namnath, J. (1987) Product Identity and Composition Analysis and Certification of Product Ingredients, Physical and Chemical Characteristics: Laboratory Project ID: 8727050. Un published compilation prepared by Chevron Chemical Co. 32 p. 40475400 Platte Chemical Co. (1987) Submission of Chemistry Data in Support of Clean Crop Alkanolamine 4 Herbicide. Transmittal of 1 study. 40475401 Allen, W.; Mahlburg, W. (1987) Product Chemistry Data: Clean Crop Alkanolamine 4 Herbicide: study No. 87-29A. Unpublished compil ation prepared by Transbas, Inc. Laboratory in cooperation with Platte Chemical Co. 7 p. 40475500 Platte Chemical Co. (1987) Submission of Chemistry Data in Support of Clean Crop Low Voi 6 Ester Weed Killer. Transmittal of 1 study. 40475501 Allen, W.; Mahlburg, W. (1987) Product Chemistry Data: Clean Crop Low Vol 6 Ester Weed Killer: Study No. 87-21A. Unpublished compilation prepared by Transbas, Inc. Laboratory in cooperation with Platte Chemical C o . 19 p . 40475800 Platte Chemical Co (1987) Submission of Chemistry Data in Support of Clean Crop 2 4-D Amine TC. Transmittal of 1 study. REPORT I D : PDR20B01 RUN DATE : 11/26/93 PAGE: 42 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SQUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 40475801 Allen, M.j Mahlburg, W. (1987) Product Chemistry Data: clean Crop 2,4-D Amine TC: Study No. 87-15A. Unpublished study prepared by Transbas, Inc. Laboratory in cooperation with Platte Chemical Co. 21 p. 40475900 Platte Chemical Co. (1987) Submission of Chemistry Data to Support the Registration for Clean Crop Mec Amine-D. Transmittal of 1 study. 40475901 Allen, L.; Mahlburg, W. (1987) Clean Crop Mec-Amine D: Product Chemistry Data: Study No. 87-17A. Unpublished study prepared by Transbas, Inc. Laboratory. 10 p. 40476000 Platte Chemical Co. (1987) Submission of Data To Support the Regis tration of Clean Crop Mec Amine Plus: Product Chemistry Data. Transmittal of 1 study. 40476001 Allen, W.; Mahlburg, W. (1987) Product Chemistry Data: clean Crop Mec-Amine Plus: study No. 87-19A. Unpublished compilation pre pared by Transbas, Inc. Laboratory. 12 p. 40476100 Platte Chemical Co. (1987) Submission of Chemistry Data in Response to Data Call-in for Dioxin/Furan. Transmittal of 1 study. 40476101 Allen, L.; Mahlburg, W. (1987) Clean Crop Four Plus Herbicide: Pro duct Chemistry Data: Study No. 87-18A. Unpublished study pre pared by Transbas, Inc. Laboratory. 10 p. 40546600 The Chas H. Lilly Co. (1988) Submission of Product Chemistry Data to Support the Registration of Lilly/Miller Ready-to-use Spurge Oxalis Killer. Transmittal of 1 study. 40546601 Klettke, M. (1988) Lilly/Miiler Ready-to-use Spurge Oxalis Killer Product Chemistry Data. Unpublished study prepared by The Chas H. Lilly Co. 35 p. 40589100 PBI/GORDON C o r p . (1988) Submission of Data To Support the Applica tion for Registration of EH 922; Product Chemistry Data. Trans mittal of 1 study. 40589101 Cahoy, R. (1988) Trimec 922-- Product Chemistry. Unpublished compi lation prepared by PBI/GORDON Corp Formulation Laboratory. 7 p. 3.C>3(2?8^ REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE : *13 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 40595700 Environmental Protection Agency (1988) Submission of Documents Received from the RD PM for Addition to the 2,4-D Registration Standard. Transmittal of 4 studies. 40595703 Aly, 0.; Faust, S. (1964) Determination of Phenoxyacetic Acids with J and Phenyl J Acids. Analytical Chemistry 36 (1 1): 2200-220 1. 40596500 PBI/Gordon Corp. (1988) Submission of Chemistry Data in Support of Trimec M 9,36. Transmittal of 1 study. 40596501 Cahoy, R. (1988) Trimec M936--Product Chemistry. Unpublished com pilation prepared by PBI/Gordon Corp. 4 p. 40651500 PBI/Gordon Corp. (1988) Submission of Chemistry Data to Support the Registration for Trimec 973 Weed Feed. Transmittal of 1 study. 40651501 Cahoy, R. (1988) Trimec 973 Weed Feed - Product Chemistry. Un published study prepared by PBI/Gordon Corp. 7 p. 40651600 PBI/Gordon Corp. (1988) Submission of Chemistry Data to Support the Registration for DM 969 Liquid Weed Feed. Transmittal of 1 study. 40651601 Cahoy, R. (1988) DM 969 Liquid Weed Feed - Product Chemistry. Unpublished study prepared by PBI/Gordon Corp. 7 p. 40651700 PBI/Gordon Corp. (1988) Submission of Data To Support the Applica tion for Registration of Trimec 970 Weed and Feed: Product Chem istry Data. Transmittal of 1 study. 40651701 Cahoy, R. (1988) Trimec 970--Product Chemistry. Unpublished study prepared by PBI/Gordon Corp. 7 p. 40748300 Chas H. Lilly Co. (1988) Submission of Data To Support the Regi stration of Lilly/Miller Ready-to-Use Spurge Oxalis Killer: Product Chemistry Data: Accelerated Storage Stability. Trans mittal of 1 study. 40748301 Klettke, M. (1988) Lilly/Miller Ready-to-Use Spurge Oxalis Killer: Product Chemistry Data. Unpublished study prepared by Columbia Laboratories, Inc. 21 p. 2.03^9 REPORT ID: PDR20B01 RUH DATE: 11/26/93 PAGE : 44 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS1 MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 40772200 Riverdale Chemical Co. (19881 Submission of Product Chemistry Data in Support of Registration of Riverdale Weedestroy Amine 6 D. Transmittal of 1 study. 40772201 Sawyer, R. (19861 Product Chemistry: Riverdale Weedestroy Amine 6 D: Laboratory project ID Amine 6 D. Unpublished study prepared by Riverdale Chemical Co. 17 p. 40808300 Platte Chemical Co. 919881 Submission of Product Chemistry Data to Support the Data Call-in Notice for Polyhalogenated Dibenzo-pdioxins/Dibenzofurans in 2,4-Dichlorophenoxyacetic acid. Transmittal of 1 study. 40808301 Allen, W.; Mahlburg, W. C1988) Clean Crop 2,4-D Acid: Product Chemistry Data: study No. 88-9A. Unpublished study prepared by Transbas, Inc. Laboratory. 64 p. 40935700 Hoechst Celanese Corp. C19881 Submission of Toxicity Data in Sup port of Application for Registration of Tiller Herbicide and Petition for Tolerence for Fenoxaprop-ethy1 for Use on Wheat. Transmittal of 8 s t u d i e s . 40935701 Albrecht, Dr.; Rexer, K. (1988?1 Physical and Chemical Characteris tics of Tiller Herbicide (Hoe 033171+ 2,4-D + M C P A M 2 4 EC 50 A 3001. Unpublished study prepared by Hoechst AG. 16 p. 41035600 The C h a s . H. Lilly Co. (19891 Submission of Chemistry Data in Support of Conditional Registration of Trimec. Transmittal of 1 study. 41035601 Klettke, M. (19891 Storage Stability/Corrosion Characteristics Data $of Lilly/Miller Feed Weed I. Unpublished study prepared by Columbia Labs. 32 p. 41035700 The Chas. H. Lilly Co. (19891 Submission of Chemistry Data in Support of Conditional' Registration of lilly/Miller Super Rich Feed Weed with Trimec Herbicide. Transmittal of 1 study. 41035701 Klettke, M. (19891 Storage Stability/Corrosion Characteristics Data of Lilly/Miller Super Rich Feed Weed with Trimec Herbicide. Unpublished study prepared by Columbia Laboratories. 32 p. <o3 70 REPORT ID: PDR20B01 RUH DATE: 11/26/93 PAGE: 45 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 41049700 41049701 41053200 41053201 f 1055800 41055801 41055802 41055803 41055804 41055805 41055809 41055810 C h a s . H. Lilly Co. (1989) Submission of Data To Support Registra tion of Lilly/Miller Envy 2,4-D: Product Chemistry Data. Trans mittal of 1 study. Klettke, M. (1989) Product Chemistry Data: Pesticide Assesment (...): Lilly/Miller Envy 2.4 - D . Unpublished study prepared by Chas. H. Lilly Co. 42 p. E. B. Stone Son, Inc. (1989) Submission of Chemistry Data in Sup port of GreenAll Pro-Formula Weed Control and Lawn Fertilizer 25-5-3. Transmittal of 1 study. E. B. Stone Son, Inc. (1989) Product Chemistry Data: GreenAll Pro-Formula Weed Control and Lawn Fertilizer 25-5-3. Unpublish ed compilation. 56 p. Dow Chemical Co. (1989) Submission of Data To Support Registration of 2,4-D Acid: Product Chemistry Data. Transmittal of 20 stu dies . Dow Chemical Co. (1989) 2,4-D Acid: Product Identity and Composi tion. Unpublished study. 40 p. Dow Chemical Co. (1989) 2,4-D Acid: Analysis and Certification of Product Ingredients. Unpublished study. 32 p. Dow Chemical Co. (1989) 2,4-D Acid: Physical and Chemical Charac teristics. Unpublished study. 6 p. Dow Chemical Co. (1989) 2,4-D Acid, Flake: Product Identity and Composition. Unpublished study. 14 p. Dow Chemical Co. (1989) 2,4-D Acid, Flake: Analysis and Certifica tion of Product Ingredients. Unpublished study. 12 p. Dow Chemical Co. (1989) 2,4,-D DM A- 6 Unsequestered Weedkiller: Pro duct Identity and Composition. Unpublished study. 23 p. Dow Chemical Co. (1989) 2,4-D-6 Unsequestered Weedkiller: Analysis and Certification of Product In gr ed i e n t s . Unpublished s t u d y . 2 2 p. <^03 77 REPORT ID-' PDR20B0 1 RUH DATE: 11/26/93 PAGE : 46 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 0558 1 1 Dow Chemical C o . (1989) 2,4-D DMA- 6 Unseqestered Weedkiller: Physical and Chemical Characteristics. Unpublished study. 6 p . 0558 1 2 Dow Chemical Co. (1989) 2,4-D Butoxylethyl Ester: Product Identity and Composition. Unpublished study. 27 p. 0558 13 Dow Chemical C o . ( 1989 ) 2,4-D Butoxyethyl Ester: Analysis and Certification of Product Ingredients. Unpublished study. 34 p. 055814 Dow Chemical C o . (1989) 2,4-D Butoxyethyl Ester: Physical and Chemical Characte ristics . Unpublished study. 6 p. 0558 15 Dow Chemical C o . (1989) 2,4-D Isopropylamine Salt: Product Identity and Composition. Unpublished study. 22 p. 1055816 Dow Chemical Co. (1989) 2,4-D Isopropylamine Salt: Analysis and Certification of Product Ingredients. Unpublished study. 26 p. 41055817 Dow Chemical Co. ( 1989 ) 2,4-D Isopropylamine Salt: Physical and Chemical Characteristics. Unpublished study. 6 p. 41065500 Master N u r s e r y 's Association (1989) Resubmission of Data To Support Registration of 49'er Weed Control and Lawn Fertiliser 25-5-3= Product Chemistry Data. Transmittal of 1 study. 41065501 Strong, L. (1989) Product Chemistry Data: 49'er Weed Control and Lawn Fertiliser 25-5-3. Unpublished study prepared by Master Nurserymen's Association. 56 p. 41067000 Rhone-Poulenc Ag Co. (1989) Submission of Product Chemistry Data to Support the Registration Standard of 2,4-D. Transmittal of 1 study. 41067001 May Baker Ltd. (1988) Product Chemistry Data Requirements under EPA Pesticide Assessment Guidelines dated Oct 1982 (2,4-Dichloro p he no xy )acetic Acid 2,4-D Technical Acid. Unpublished study. 138 p. 41123600 Riverdale Chemical Co. (1989) Submission of Data To Support Reregistration of 2,4-D Products Product Chemistry Data. Transmittal of 1 study. 3l o 3 7z ~. REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 47 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM CPDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 41123601 Sawyer, R. (19891 Riverdale Sodium Salt of 2,4-D: Product Chemi stry: Project ID: Sodium Salt of 2,4-D. Unpublished study pre pared by Riverdale Chemical Co. 18 p. 41133600 Platte Chemical Co. (1989) Submission of Product Chemistry Data in Support of Clean Crop Weed Feed 2,4-D Granular Registration Standard. Transmittal of 1 study. 41 13360 1 Mahlburg, W.; Thompson, J. (1989) Product Chemistry Information Clean Crop Weed Feed 2,4-D Granular: study No. 89-13A. Unpublished study prepared by Platte Chemical Co. 90 P 41136900 Platte Chemical Co. (1989) Submission of Product Chemistry Data in Support of Clean Crop Weed Feed 2,4-D Granular Registration Standard. Transmittal of 1 study. -1 13690 1 Stevens, J. (1989) Supplement to Product Chemistry Data Clean Crop Weed Feed 2,4-D Granular: Lab ID No. 5450-4976B: Study No. 8913B. Unpublished study prepared by Thermedics, Inc. 43 p. 41140200 A.H. Marks and Co., Ltd. (1989) Submission of Data To Support Regi stration of Products Containing 2,4-dichlorophenoxyacetic Acid (2,4-D): Product Chemistry Data. Transmittal of 1 study. 41140201 41179100 Hardwick, F. (1989) Product Chemistry for Marks 2,4D Technical Acid. Unpublished study prepared by A.H. Marks C o . , Ltd. P 24 The C h a s . H. Lilly Co. (1989) Submission of Product Chemistry Data in Support of Lilly/Miller Super Rich Feed Weed with Trimec Herbicide Conditional Registration. Transmittal of 1 study. 41179101 Klettke, M. (1989) Storage Stability/Corrosion Characteristics Data: Lilly/Miller Super Rich Feed Weed with Trimec Herbicide. Unpublished study prepared by Columbia Laboratories. 25 p. 41179200 The C h a s . H. Lilly Co. (1989) Submission of Product Chemistry Data in Support of Lilly/Miller Feed Weed Conditional Registration. Transmittal of 1 study. A 0 3 13 REPORT ID: PDR20B01 RUH DATE: 11/26/93 PAGE: 48 EKVIROHMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 41179201 Klettke, M. (19891 Storage Stability/Corrosion Characteristics Data: Lilly/Miller Feed 8 Weed. Unpublished study prepared by Columbia Laboratories. 25 p. 41203300 Rhone-Poulenc Ag Co. (1989) Submission o Product Chemistry Data in Response to 2, 4-D Dioxin Data Call-in. Transmittal of 1 study. 41203301 Silvestre, D. (1989) 2,4-D Determination of Polychlorinated Dibenzo-p-dioxins and Dibenzofurans by GC/MS: Laboratory ID: 89-10. Unpublished study prepared by Rhone-Poulenc Industrialisation. 133 p. 41219700 PBI/Gordon C o r p . (1989) Submission of Chemistry Data in Support of Dibenzo-p-Dioxins/Dibenzo-furans. Transmittal of 1 study. '1219701 Ambruster, J. (1989) Certification of Limits for Dibenzo-p-Dioxins/ Diben zof ur ans . Unpublished study prepared by PBI/Gordon Corp. 179 p. 41223800 PBI/Gordon Corp. (1989) Submission of Product Chemistry Data in Support of Registration for 2,4-Dichlorophenoxyacetic Acid, EPA Reg. No. 2217-455. Transmittal of 1 study. 41223801 Armbruster, J. (1989) EPA Reg. No. 2217-455 - Product Chemistry $of 2.4- Dichlorophenoxyacetic Acidl. Unpublished study prepared by Agro-Gor Corp. 30 p. 41224200 Agrolinz, Inc. (1989) Submission of Product Chemistry Data in Sup port of Registration Standard of 2,4-D Isopropyl Ester. Trans mittal of 1 study. 41224201 Fisher, J. (1989) Product Chemistry Data Requirements for Isopropyl 2.4- D Ester Technical: P r o j . ID P-890824. Unpublished study prepared by Agrolinz, Inc. 61 p. 41243100 The C h a s . H. Lilly Co. (1989) Submission of Chemistry Data in Sup port of Lilly/Miller Ready-to-Use Lawn Weed Killer Conditional Registration. Transmittal of 1 study. 3.037^ REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 49 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 412431 01 Klettke, M. (1989) Product Chemistry Data - Storage Stability and Corrosion Characteristics: Lilly/Miller Ready-to-Use Lawn Weed Killer. Unpublished study prepared by Columbia Laboratory. 16 p. 413 08 900 Industry Task Force II on 2,4-D (1989) Submission of Product Chemi stry Data in Support of the 2,4-D Reregistration Standard. Transmittal of 1 study. 413089 01 Reim, R. (1989) Dissociation of 2,4-Dichlorophenoxyacetic Acid (2,4-D) and 2,4-D Dimethylamine Salt in Water: Lab Project Number: ML AL 89 041014. Unpublished study prepared by Dow Chemical U.S.A. 25 p. 413185 00 A. H. Marks and Co., Ltd. (1990) Submission of Product Chemistry Data in Response to the 2,4-D Data Call-In. Transmittal of 3 studies. 413185 01 Langvoigt, ?. (1989) Analysis of DD/DF in 2,4-D Acid for A. H. Marks. Unpublished study prepared by Chemserv Analytik, Aus t r i a . 11 p . 413185 02 Langvoigt, ?. (1989) Analysis of DD/DP in 2,4-DP Acid for A. H. Marks. Unpublished study prepared by Chemserv Analytik. 11 p. 413185 03 Langvoigt, ?. (1989) Analysis of DD/Df in 2,4-DB Acid for A. H. Marks. Unpublished study prepared by Chemserv Analytik. 11 p. 413296 00 Riverdale Chemical Co. (1989) Submission of data in support of registration of Weedestroy Dri-D Amine; Product chemistry. Transmittal of 2 studies. 413296 01 Sawyer, R. (1989) Product Chemistry: Riverdale Weedestroy Dri-D Amine: Lab Project Number: Dri-D Amine. Unpublished study prepared by Riverdale Chemical Co. 21 p. 413296 02 Stevens, J. (1989) Nitrosamine Analysis: Tri-anahydramine; EX-01 (Dri-D Amine): Lab Project Number 5450-5598. Unpublished study prepared by Thermedics Inc. 16 p. REPORT ID: PDR20B01 RUH DATE: 11/26/93 PAGE: 50 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM CPDMS) MRID SESUENCE BIBLIOGRAPHY 29 D PART 1 MRID CITATION 41 332000 Industry Task Force on 2,4-D (19 90 ) Submission of Product Chemistry Data in Support of the 2,4-D Data Call-In. Transmittal of 9 studies . 41332001 Hopkins, D. C1987) 2,4-Dichlorophenoxyacetic Acid Dimethylamine Salt: Determination of the Water Solubility: Lab Project Number: ES/DR/0008/3556/3. Unpublished study prepared by The Don Chemical Co. 14 p. 41332002 Hopkins, D. (1987) 2,4-Dichlorophenoxyacetic Acid: Determination of the Water Solubility: Lab Project Number: ES/DR/0002/2297/8. Unpublished study prepared by The Dow Chemical Co. 14 p. 41332003 Chakrabarti, A.; Gennrich, S. (1987) Vapor Pressure of 2,4-Dichlorophenoxyacetic Acid: Lab Project Number: M L/ AL /8 7/4 00 47. Unpublished study prepared by The Dow Chemical Co. 9 p. 41332004 Bailey, R.; Hopkins, D. (1987) 2,4-Dichlorophenoxyacetic Acid: Determination of Octanol/Water Partition Coefficient: Lab Project Number: ES/DR/0002/2297/9. Unpublished study prepared by The Dow Chemical Co. 12 p. 41332005 Nicholson, L. (1989) Determination of the Octanol/Water Partition Coefficient for n-Propylbensene Using Generator Column Technology: Lab Project Number: AL/88/080547. Unpublished study prepared by Dow Chemical Co. 3 P 41332006 Nicholson, L. (1989) Determination of the Octanol/Water Partition Coefficient for Naphthalene Using Generator Column Technology: Lab Project Number: AL /8 8 / 0 8 0 5 4 6. Unpublished study prepared by The Dow Chemical Co. 29 p. 41332007 Chakrabarti, A.; Gennrich, S. (1987) Vapor Pressure of 2,4-D-Ethoxyhexyl Ester: Lab Project Number: ML/AL/87/40048. Unpublished study prepared by The Dow Chemical Co. 9 p. 41332008 Helmer, D. (1987) Determination of the Water Solubility of 2,4-Dichlorophenoxy Acetic Acid, 2-ethylhexyl Ester: Lab Project Number: ML/AL/87/70817. Unpublished study prepared by the Dow Chemical Co. 13 p. 903 7G REPORT ID: PDR20B01 RUH DATE: 11/26/93 PAGE: 51 ENVIRONMENTAL *PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 41332009 Helmer, D. (1987) Determination of the Octanol/Water Partition Coefficient for 2,4- Dichlorophenoxy Acetic Acid, 2-Ethylhexyl Ester: Lab Project Number: ML /A L/ 8 7 / 7 0 8 19. Unpublished study prepared by Dow Chemical Co. 14 p. 41349000 Riverdale Chemical Co. (1990) Submission of Analytical Chemistry Data in Response to the Data Call-in Notice for Polyhalogenated Dibenzo-p-Dioxins/Dibensofurans in 2,4-D Acid and Its Salts and Esters. Transmittal of 2 studies. 41349001 Fiene, J.; Mahlburg, W. (1990) Determination of Halogenated Dibenzo -p-Dioxins and Dibenzofurans in 2,4-D Acid: Lab Project Number: 90-1. Unpublished study prepared by Chemserv Industries Service Ges.m.b.H. 323 p. 1375700 C h a s . H . Lilly C o . (1990) Submission of Supplemental Chemistry Data in Support of Lilly/Miller Ready-to Use Lawn Weed Killer, Transmittal of s t u d y . 41375701 Klettke, M. (1990) Product Chemistry Data - Storage Stability: Lilly/Miller Ready-To-Use Lawn Weed Killer. Unpublished study prepared by Columbia Laboratories, Inc. 4 p. 41376700 Agrolinz, Inc. (1990) Submission of Product Chemistry Data to Support the Special Review on Polyhalogenated Dibenzo-p-dioxins/ Dibenzofurans in 2,4-D and Its Salts and Esters. Transmittal of 1 study. 41376701 Fisher, J. (1989) Manufacturing Process for the Production of Esters of 2,4-Dichlorophenoxyacetic Acid: Lab Project ID: P89030L. Unpublished study prepared by Agrolinz, Inc. 15 p. 41431100 DowElanco (1990) Submission of Vapor Pressure Data in Support of 2,4-D Registration Standard. Transmittal of 1 study. 41431101 Chakrabarti, A. (1990) Vapor Pressure of the Isopropyl Amine Salt of 2,4-Dichlorophenoxy Acetic Acid Measured by the Knudsen-Effusion/Weight Loss Method: Lab Project Number: ML-AL 89-020235. Unpublished study prepared by Dow Chemical U.S.A. 11 p. D377 REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 52 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 41447100 Rhone-Poulenc Ag Co. (1990) Submission of Product Chemistry Data to Support the 2, 4-D DMA Dioxin/Dibenzofuran Data Call-in Notice. Transmittal of 1 study. 41447101 Scarborough, D. (1990) Weedar Brand 64 Broadleaf Herbicide Product Identity and Composition: Lab Project Number: AC-90-005. Unpub lished study prepared by Rhone-Poulenc Ag Co. 84 p. 41472700 Riverdale Chemical Co. (1990) Submission of Product Chemistry Data to Support the Registration of Riverdale Triplet Selective Herbicide. Transmittal of 2 studies. 41472701 Sawyer, R. (1986) Riverdale Triplet Selective Herbicide. Unpub lished study prepared by Riverdale Chemical Co. 20 p. '1472702 Stevens, J. (1990) Nitrosamine Analysis: Triplet: Lab Project No.: 5450-6221. Unpublished study prepared by Thermedics, Inc. 17 p. 41478700 Riverdale Chemical Co. (1990) Submission of Product Chemistry and Toxicological Data to Support the Registration of Riverdale Dri-Tri Amine. Transmittal of 8 studies. 41478701 Sawyer, R. (1990) Product Chemistry: Riverdale Weedestroy (R) DriTri Amine. Unpublished study prepared by Riverdale Chemical Co. 2 0 p. 41478708 Stevens, J. (1990) Nitrosamine Analysis: Riverdale Dri-Tri Amine: Lab Project Number: 5450-6195. Unpublished study prepared by Thermedics, Inc. 17 p, 41496700 DowElanco (1990) Submission of Data in Response to Data Call-in for Dio xin / Fu ra n : Product Chemistry Study. Transmittal of 1 study. 41496701 DowElanco (1990) 2,4-D Acid: Product Identity and Composition: ''Amendment". Unpublished study prepared by The Dow Chemical Co. 51 p. 41525700 Fermenta ASC C o r p . (1990) Submission of Product Chemistry and Toxicological Data to Support the Registration Standard for 2,4-D. Transmittal of 2 studies. 9o>3 7# REPORT ID PDR20B01 RUH DATE: 11/26/93 PAGE: 53 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 41525701 Sweetapple, G. (1990) Dacamine 4D Determination of Corrosion Characteristics: Fermenta ASC Proj . No. 14581; Doc. No. 1081-89-0244-AS-00 1 . Unpublished study prepared by Ricerca, Inc., Dept of Analytical Services. 38 p. 41527500 Rhone- Poulenc Ag Company (1990) Submission of product chemistry data in response to a dioxin/dibensofuran data call-in. Transmittal of 1 study. 41527501 Scarborough, D. (1990) DPD-Amine Herbicide: Product Identity and Composition: Lab Project Number: 40781. Unpublished study pre pared by Rhone-Poulenc A g . Co. 64 p. 41539300 Lesco, Inc. (1990) Submission of Chemistry and Toxicity Data in Support of Registration of Three-way 53% DG Herbicide. Trans mittal of 7 s t u d i e s . 41539301 McLane, H. (1990) Lesco Three-way 53 percent DG Selective Herbicide : Product Chemistry: Lab Project Number: a LESCO 10-DGPC1.P M 3 . Unpublished study prepared by Lesco, Inc. 9 p. 41559800 Lesco, Inc. (1990) Submission of nitrosamine record of analysis for Lescopar herbicide. Transmittal of 1 s t u d y . 41559801 McClane, H. (1990) Lesco Lescopar Herbicide: Lab Project Number: WO 60388AS. Unpublished study prepared by Hazleton Labs America, Inc 4 p . 41572000 DowElanco (1990) Submission of Product Chemistry Data in Support of Formula 40 Herbicide Amended Registration for Revised Formula tion. Transmittal of 1 study. 41572001 Schriber, C. (1990) Product Chemistry for Formula 40 Herbicide: Lab Project Number: XRM-5226. Unpublished study prepared by DowE l a n c o . 28 p. 41599400 Rhone-Poulenc Ag Co. (1990) Submission of Additional Product Chemistry Data in Support of 2,4-D Dioxin Data Call-in. Transmittal of 1 study. 37^ REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 54 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SE2UENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 41599401 Buddie, G. (1990) 2,4-D Technical Acid Product Chemistry: Supple mental Information: Lab Project Number: ACD/GCB/MS/8364. Unpub lished study prepared by Rhone-Poulenc Ag Co. 10 p. 41637500 PBI/GORDON Corp. (1990) Submission of Chemistry Data in Support of Lavelle 348 in Response o^f EPA Letter Dated July 11, 1990. Tra nsmittal of 1 study. 41637501 Armbruster, J. (1990) Revised Partial Product Chemistry. Unpub lished study prepared by PBI/GORDON Corp. 18 p. 41668700 NCH Corp. (1990) Submission of Product Chemistry Data to Support the Registration of the RF89482. Transmittal of 1 Study. 41668701 Wright, S. (1990) Product Chemistry: RF89482: Lab Project Number: 89/482. Unpublished study prepared by Mohawk Laboratories. 101 p. 41681900 AGRO/GOR Corp. (1990) Submission of Product Chemistry Data to Support the Registration of 2,4,-Dichlorophenoxyacetic acid. Transmittal of 1 Study. 41681901 Armbruster, J. (1990) Revised Partial Product Chemistry. Unpub lished study prepared by AGRO/GOR Corp. 20 p. 41694900 Monsanto Agricultural Company (1990) Submission of Toxicology and Product Chemistry Data in Support of Registration of Mon-18729, Expedite Broadleaf Herbicide 3-way Amine. Transmittal of 7 studies. 41694901 41706300 Gibson, K. (1990) Product Chemistry Data to support the Registra tion of Mon-18729: Lab Project Number: 0436-90-15: MSL-10539: Unpublished study prepared by Monsanto Agriculture Company. 78 P PBI/Gordon Corp. (1990) Submission of Supplementary Product Chem istry Data to Fulfill MCPP Dioxin/Furan DCI Data Gaps. Trans mittal of 93 studies. 41706302 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-488. Unpublished study prepared by PBI/Gordon C o r p . 12 p . >3$D REPORT ID: PDR20B01 RUH DATE: 11/26/93 PAGE: 55 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 41706303 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-489. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706304 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-483. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706305 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-507. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706306 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-508. Unpublished study prepared by PBI/Gordon C o r p . 12 p . ,1706307 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-516. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706308 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-517. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706309 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-529. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706310 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-530. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706311 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-531. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706312 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-532. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 0 B2f REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 56 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 41706313 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-533. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706314 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-536. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706315 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-537. Unpublished study prepared by PBI/Gordon Corp. 12 p. 41706316 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-539. Unpublished study prepared by PBI/Gordon C o r p . 12 p . -,1706317 v Armbruster, J. (1990 ) Updated Product Identity and Composition: EPA Reg. No. 2217-540. Unpublished study prepared by PBI/Gordon Corp. 12 p. 41706318 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-543. Unpublished study prepared by PBI/Gordon Corp. 12 p. 41706319 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-559. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706320 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-560. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706321 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-561. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706322 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-563. Unpublished study prepared by PBI/Gordon C o r p . 12 p . REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 57 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 41706323 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-566. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706324 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-567 . Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706325 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-568. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706326 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. NO. 2217-570. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706327 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-571. Unpublished study prepared by PBI/Gordon Corp. 12 p. 41706328 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-579. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706329 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-580. Unpublished study prepared by PBI/Gordon Corp. 12 p. 41706330 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-581. Unpublished study prepared by PBI/Gordon Corp. 12 p. 41706331 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-585. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706332 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-593. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 30323 REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 58 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 41706333 Armbruster , J . (1990) Updated Product Identity and Composition: EPA Reg. No . 2217-594. Unpubl ished study prepared by PBI/Gordon Corp . 1 2 p. 41706334 Armbruster , J . (1990) Updated Product Identity and Composition: EPA Reg. No . 2217-597. Unpubl ished study prepared by PBI/Gordon Cor p . 1 2 p. 41706335 Armbrus ter , J . (1990) Updated Product Identity and Composition: EPA Re g . No . 2217-602. Unpubl ished study prepared by PBI/Gordon Corp . 1 2 p. 41706336 Armbrus ter , J . (1990) Updated Product Identity and Composition: EPA Reg . No . 2217-603. Unpubl ished study prepared by PBI/Gordon Cor p . 1 2 p. *+1706337 Armbruster , J . ( 1990 ) Updated Product Identity and Composition: EPA R e g . No . 2217-615. Unpubl ished study prepared by PBI/Gordon Corp . 1 2 p. 41706338 Armbruster , J . (1990) Updated Product Identity and Composition: EPA R e g . No . 2217-618. Unpubl ished study prepared by PBI/Gordon Corp . 1 2 p. 41706339 Armbruster , J . (1990) Updated Product Identity and Composition: EPA R e g . No . 2217-621. Unpubl ished study prepared by PBI/Gordon Corp . 1 2 p. 41706340 Armbruster , J. (1990) Updated Product Identity and Composition: EPA Reg. No . 2217-623. Unpubl ished study prepared by PBI/Gordon Cor p . 1 2 p. 41706341 Armbruster , J . (1990) Updated Product Identity and Composition: EPA R e g . No . 2217-624. Unpubl ished study prepared by PBI/Gordon Corp . 1 2 p. 41706342 Armbruster , J . (1990) Updated Product Identity and Composition: EPA R e g . No . 2217-625. Unpubl ished study prepared by PBI/Gordon C o r p . 12 p . REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 59 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 K MRID CITATION 41706343 Armbruster, J. (19901 Updated Product Identity and Composition: EPA Reg. No. 2217-639. Unpublished study prepared by PBI/Gordon Corp. 12 p. 41706344 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-640. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706345 Armbruster, J . (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-643. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706346 Armbruster, J . (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-644. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 1706347 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-655. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706348 Armbruster, J . (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-656. Unpublished study prepared by PBI/Gordon Corp. 12 p. 41706349 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-657. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706350 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-658. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706351 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-659. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706352 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-660. Unpublished study prepared by PBI/Gordon C o r p . 12 p . IO REPORT ID: PDR20B01 RUH DATE: 11/26/93 PAGE: 60 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 41706353 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-661. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706354 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-662. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706355 Armbruster, J . (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-663. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706356 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-674. Unpublished study prepared by PBI/Gordon C o r p . 12 p . *1706357 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-681. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706358 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-694. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706359 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-695. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706360 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-698. Unpublished study prepared by PBI/Gordon Corp. 12 p. 41706361 Armbruster, J . (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-709. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706362 Armbruster, J. (1990) Updated Product Identity and Composition: EPA Reg. No. 2217-710. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 0.03 REPORT IDs PD R2 0B0 1 RUN DATE: 11/26/93 PAGE: 61 X ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SE2UENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 41706363 Armbruster, J. (1990 ) Updated Product Identity and Composition: EPA Reg. No. 2217-716. Unpublished study prepared by PBI/Gordon C o r p . 12 p . 41706364 Cahoy, R. (1990) EH 896--Product Chemistry: Supplement. Unpublish ed study prepared by PBI/Gordon Corp. 7 p. 41706365 Cahoy, R. (1990) EH 870--Product Chemistry: Supplement. Unpublish ed study prepared by PBI/Gordon Corp. 7 p. 41706366 Cahoy, R. (1990) EH 871--Product Chemistry: Supplement. Unpublish ed study prepared by PBI/Gordon Corp. 7 p. 41706367 Cahoy, R. (1990) Trimec Northern Liquid Weed Feed 25-0-0= Product Chemistry: Supplement. Unpublished study prepared by PBI/Gordon Corp. 7 p . 41706368 Cahoy, R. (1990) Trimec Northern Liquid Weed Feed 25-0-0: Product Chemistry: Supplement. Unpublished study prepared by PBI/Gordon Corp. 7 p. 41706369 Cahoy, R. (1990) Trimec 901: Product Chemistry: Supplement. Unpub lished study prepared by PBI/Gordon Corp. 7 p. 41706370 Cahoy, R. (1990) Trimec 902: Product Chemistry: Supplement. Unpub lished study prepared by PBI/Gordon Corp. 7 p. 41706371 Cahoy, R. (1990) M 885--Product Chemistry: Supplement. Unpublished study prepared by PBI/Gordon Corp. 7 p. 41706372 Cahoy, R. (1990) Trimec M 8 8 6 --Product Chemistry: Supplement. Un published study prepared by PBI/Gordon Corp. 7 p. 41706373 Cahoy, R. (1990) Trimec M887-- Product Chemistry: Supplement. Un published study prepared by PBI/Gordon Corp. 7 p. 41706374 Cahoy, R. (1990) Trimec M 9 0 3--Product Chemistry: Supplement. Un published study prepared by PBI/Gordon Corp. 7 p. 41706375 Cahoy, R. (1990) Trimec M904-- Product Chemistry: Supplement. Un published study prepared by PBI/Gordon Corp. 7 p. 9-03^7 REPORT IDs PDR20B01 RUN DATE: 11/26/93 PAGE? 62 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SESUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 41706376 Cahoy, R. (1990) Trimec M905--Product Chemistry: Supplement. Un published study prepared by PBI/Gordon Corp. 7 p. 41706377 Cahoy, R. (1990) MM890 Liquid Weed Feed 20-0-0: Product Chemist ry: Supplement. Unpublished study prepared by PBI/Gordon Corp. 7 p. 41706378 Cahoy, R. (1990) Trimec M 907 Liquid Weed Feed: Product Chemist ry: Supplement. Unpublished study prepared by PBI/Gordon Corp. 7 P. 41706379 Cahoy, R. (1990) Trimec M 908 Liquid Weed Feed: Product Chemist ry: Supplement. Unpublished study prepared by PBI/Gordon Corp. 7 p. 1706380 Cahoy, R. (1990) Trimec M 909 Liquid Weed Feed: Product Chemist ry: Supplement. Unpublished study prepared by PBI/Gordon Corp. 7 P. 41706381 Cahoy, R. (1990) DM 896--Product Chemistry: Supplement. Unpublish ed study prepared by PBI/Gordon Corp. 7 p. 41706382 Cahoy, R. (1990) DMDP 897--Product Chemistry: Supplement lished study prepared by PBI/Gordon Corp. 7 p. Unpub- 41706383 Cahoy, R. (1990) DMDP 898 Liquid Weed Feed-- Product Chemistry: Supplement. Unpublished study prepared by PBI/Gordon Corp. 7 P 41706384 Cahoy, R. (1990) DM 899 Liquid Weed Feed-- Product Chemistry: Supplement. Unpublished study prepared by PBI/Gordon Corp. P 7 41706385 Cahoy, R. (1990) Trimec M891 Weed Feed-- Product Chemistry: Supplement. Unpublished study prepared by PBI/Gordon Corp. P 7 41706386 Cahoy, R. (1990) Trimec M892 Weed Feed-- Product Chemistry: Supplement. Unpublished study prepared by PBI/Gordon Corp. P 7 2,033$ REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 63 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 41706387 Cahoy, R. (1990) Trimec M893 Weed Feed-- Product Chemistry: Supplement. Unpublished study prepared by PBI/Gordon Corp. P 7 41706388 Cahoy, R. (1990) Trimec 914 Weed Feed-- Product Chemistry: Supple ment. Unpublished study prepared by PBI/Gordon Corp. 7 p. 41706389 Cahoy, R. (1990) Trimec 932-- Product Chemistry: Supplement. Unpub lished study prepared by PBI/Gordon Corp. 7 p. 41706390 Cahoy, R. (1990) Trimec M936--Product Chemistry: Supplement. Un published study prepared by PBI/Gordon Corp. 7 p. 41706391 Cahoy, R. (1990) DM 969 Liquid Weed F e e d - P r o d u c t Chemistry: Supplement. Unpublished study prepared by PBI/Gordon Corp. P 7 41706392 Cahoy, R. (1990) Trimec 970--Product Chemistry: Supplement. Unpub lished study prepared by PBI/Gordon Corp. 7 p. 41706393 Cahoy, R. (1990) Trimec 973 Weed Feed-- Product Chemistry: Supple ment. Unpublished study prepared by PBI/Gordon Corp. 7 p. 41724200 Nufarm USA, Inc. (1990) Submission of product Chemistry Data in Response to the Data Call-in Notice for 2,4-D. Transmittal of 3 studies. 41724201 Landvoight, W. ; Mahlburg, W. (1990) Quality Assurance Project Plan for Determination of Halogenated Dibenzo-p-Dioxins and Dibenzof u r a n s ... in 2,4-D...: Lab Project Number: 90-3. Unpublished study prepared by Chemserve Industries Service Ges.m.b.H. 43 p. 41724202 Landvoight, W.; Mahlburg, W. (1990) Determination of Halogenated Dibenzo-p-Dioxins and Dibenzofurans in 2,4-D Acid by Method of Analysis 50288= Lab Project Number: 90-4. Unpublished study prepared by Chemserve Industries Service Ges.m.b.H. 561 p. 41734800 Lesco, Inc. (1990) Submission of product chemistry data to reflect changes in the end product (Lesco 53 Three-Way DG) due to a change of supplier of formulating m a t e r i a l s . Transmittal of 1 study. 9,0 381 REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 64 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SESUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 41734801 McLane, H. (1990) Lesco Three-Way 53% DG Selective Broadleaf Herbi cide: Product Chemistry: Lab Project Number: 10-AOPC1. P M 3 . Un published study prepared by Lesco, Inc. 9 p. 41735700 Rhone-Poulenc Ag Co. (1990) Submission of Additional Product Chemistry Data In Support of Technical 2,4-D Acid. Transmittal of 1 Study. 41735701 Silvestre, D. (1990) Determination of Polychorinated Dibenzo-pDioxins and Dibensofurans In 2,4-D: Complementary Analytical Raw Data Relative to Study 89-10= Lab Project Number: 343-484. Unp ublished study prepared by Rhone-Poulenc Industrialisation. 100 P 41745300 PBI/Gordon C o r p . (1991) Submission of Chemistry data in support of 2,4-Dichlorophenoxyacetic Acid in response to agency's letter dated July 11, 1990. Transmittal of 2 studies. 41745301 Etchepa reb ord a, I.; Sancrica, J. (1990) Storage Stability of Tech nical 2,4 Dichlorophenoxyacetic Acid. Unpublished study pre pared by Atanor S.A./ Laboratorios de Estudios An a l i t i co s . 8 p. 41745302 Castaneda, J. (1990) 2,4 Dichlorophenoxyacetic Acid Ex plodability: Unpublished study prepared by Instituto de Desarrollo Tecnologico/para la Industria fiuimica (INTEC). 8 p. 41755700 DowElanco (1991) Submission of Product Chemistry Data to Support the Reregistration of 2,4-D Dimethylamine Salt Solution. Transmittal of 1 Copy. 41755701 Schriber, C. (1990) Chemical Stability of 2,4-D Dimethyl Salt Solution: Lab Project Number-* GH-C 24428. Unpublished study prepared by DowElanco. 17 p. 41760100 Rhone-Poulenc Ag Company (1991) Submission of product chemistry data to support the registration of Weedar 64 Broadleaf Herbi cide (2,4 D). Transmittal of 1 study. 41760101 Crownover, R. (1990) Product Chemistry: Weedar 64 Broadleaf Herbi cide: Analysis and Certification of Ingredients : Lab Project Number: AC-90-019. Unpublished study prepared by Rhone-Poulenc Ag Company. 63 p. a o 390 REPORT ID: PD R2 0B0 1 RUN DATE: 11/26/93 PAGE: 65 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 41787900 S.C. Johnson Sons, Inc. (1991) Submission of Product Chemistry Data to Support the Application for Amended Registration of Johnson Yard Master Foam Lawn Weed Killer. Transmittal of 1 Study. 41787901 Duda, D. (1990) Lawn Weed Killer: EPA No. 4822-124: Lab Project Number: 59 6 6 D 114 - 2 C 1. Unpublished study prepared by S.C. Johnson Son Inc. 47 p. 41789900 Rhone-Poulec AG Co. (1991) Submission of Supplemental Chemistry data in support of 2,4-D Dioxin Data Call-in. Transmittal of 2 studies. 41789901 Rajoharison, G. (1991) Responses to EPA Queries on 2,4-D Product Chemistry: Lab Project Number: GR/B C/ 91-18 9 / P T C 2 11. Unpublished study prepared by Rhone-Poulenc C h i m i e . 9 p. 41789902 Buddie, G.j Patel, P. (1991) 2,4-dichlorophenoxyacetic acid (2,4D): Analysis and Certification of Product Ingredients, Provision of Supplementary Analytical Method Validation: Lab Project Num ber: p-91-016. Unpublished study prepared by Rhone-Poulenc Agriculture Ltd. 20 p. 41790600 PBI/Gordon Corp. (1991) Submission of Chemistry data in support of Dioxin/Furan data gaps cited in agency's letter dated Nov. 27, 1990. Transmittal of 2 studies. 41790601 Armbruster, J. (1991) Product Chemistry: 61 63 Series. Unpub lished study prepared by PBI/Gordon Corp. 8 p. 41790602 Armbruster, J. (1989) Certification of Limits for Dibenzo-p-Dioxins/Dibenzofurans. Unpublished study prepared by PBI/Gordon Corp. 489 p. 41796200 Agor-Gor Corp. (1991) Submission of Product Chemistry Data to Support the Supplemental Application for Registration of Dioxin Furan. Transmittal of 2 Studies. 41796201 Armbruster, J. (1989) EPA Reg No. 61469-001-Product Chemistry. Unpublished study prepared by Agro-Gor Corp. 8 p. 2 . 0 3 e?/ REPORT ID: PDR20B01 RUH DATE : 11/26/93 PAGE: 66 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEBUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 41796202 Armbruster, J. (1989) EPA REG No. 6149-001-Certification of Limits for Dibenso-p-Dioxins/Dibenzofurans. Unpublished study prepar ed by Agro-Gor Corp. 489 p. 41799500 A H Marks Company Limited (1991) Submission of Product Chemistry Data to Support the Application for Registration of 2,4-D Data Call-In. Transmittal of 3 Studies. 41799501 Landvoigt, ?. (1990) Summary of Analysis of 2,4-D: Detailing the Levels of Substituted Dioxins and Benzfurans Found in the Samp les. Unpublished study prepared by Chemserve Industrie Service Ges.m.b.H. 19 p. 41799502 Landvoigt, ?. (1990) Determination of Dioxins and Benzofurans in 2,4-D, 2,4-DCP, M C P A , 2,4-DP, CMPP and 2,4-DPB by G C / M S : Lab Project Number: 40288. Unpublished study prepared by Chemserv Industrie Service Ges.m.b.H. 15 p. 41799503 Landvoigt, ?. (1990) Product Chemistry: Calibration File Using TM1 to T M 10: Lab Project Number: 0689. Unpublished study prepared by Chemserv Industrie Service Ges.m.b.H. 30 p. 41800800 A H Marks Company Limited (1991) Submission of Product Chemistry Data to Support the Data Call-In of 2,4-DB. Transmittal of 2 Studies . 41800801 Landvoigt, ?. (1990) Summary of Analysis of 2,4-DB Detailing the Levels of Substituted Dioxins and Benzfurans Found in the Samples. Unpublished study prepared by Chemserv Industrie Services Ges.m.b.H. 19 p. 41800802 41801100 Landvoigt, ?. (1990) Determination of Dioxins and Benzofurans in 2,4-D, 2,4-DCP, M C P A , 2,4-DP, CMPP and 2,4-DPB by GC/MS: Lab Project Number: 40288. Unpublished study prepared by Chemserv Industrie Service G e s . m.b.H. 15 p. / A H Marks Company Limited (1991) Submission of Product Chemistry Data to Support the Dioxins/Furans Data Call-In. Transmittal of 3 Studies. REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 67 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 41801101 Landvoigt, W. (1990) Summary of Analysis of 2,4-DP: Detailing the Levels of Substituted Dioxins and Benzfurans Found in the Sampl es. Unpublished study prepared by Chemserve Industrie Service Ges.m.b.H. 19 p. 41801102 Landvoigt, W. (1990) Determination of Dioxins and Benzofurans in 2,4-D, 2,4-DCP, MCPA, 2,4-DP, CMPP and 2,4-DPB by GC/MS-- Lab Project Number: 40288. Unpublished study prepared by Chemserve Industrie Service Ges.m.b.H. 15 p. 4180 1103 Landvoigt, W. (1990) Calibration File Using TM1 to TM10: Lab Proje ct Number: 0689. Unpublished study prepared by Chemserve Industrie Service G e s . m.b.H. 35 p. 41814500 McLane, H.R., Inc. (1991) Submission of product chemistry data to support the registration of Lesco Lescopar Herbicide. Transmit tal of 1 study. 41814501 Mclane, H. (1990) Lesco Lescopar Herbicide: ^Nitrosamine Record Analysis I: Lab Project Number: EPA LESCO 10 -A IP C1.P M 3 . Unpub lished study prepared by Hazleton Labs America. 12 p. 41842000 Howard Fertilizer Co. (1991) Submission of Chemistry data in sup port of Turf Pride Lawn Food with Trimec in response to Agency's Letter dated Mar 23 1991. Transmittal of 1 study. 41842001 McLane, H. (1991) Product Specific Data: Turf Pride Lawn Food with Trimec: Lab Project Number: E P A /P C/ 35 512 - E N . PC 1. Unpublished study prepared by Howard Fertilizer C o . 5 p. 41876500 A H Marks 8 Company Ltd. (1991) Submission of Data to Support the Registration of Dioxin/Furan Data Call-In for 2,4-DP: Product Chemistry Data. Transmittal of 1 Study. 41876501 Landvoigt, W. (1990) Calibration File Using TM1 to TM10: Analysis 8 Certification: Lab Project Number: MARKS 0689. Unpublished Study prepared by Chemserv Industrie Service Ges.m.b.H. 35 p. 41880600 Rhone-Poulenc Ag Co. (1991) Submission of Data in Response to Data Call-in for 2,4-D Dioxin: Product Chemistry Study. Trans mittal of 1 study. REPORT IDs PDR20B01 RUN DATEs 11/26/93 PAGE: 68 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 41880601 Cicotti, M. (1991) Determination of the Solubility of 2,4-D in Organic Solvents in accordance with EPA 63-8 and BBA Guidelines: Lab Project Numbers BE/P/1/91/0 1/BG. Unpublished study prepared by Battelle Europe. 15 p. 41890700 Van Diest Supply Co. (1991) Submission of Data To Support Cornbelt Salvan Application for Registrations Product Chemistry Study. Transmittal of 1 study. 41890701 Hanson, W. (1991) Salvan-- Product Chemistry $ D a t a l . Unpublished study prepared by Van Diest Supply Co., Formulation Control L a b s . 38 p . 41920500 PBI Gordon/Corp. (1991) Submission of product chemistry data to support the registration standard for 2,4-D Diethanolamine Salt. Transmittal of 2 s t u d i e s . 41920501 Hambrick, A. (1990) 2,4-Dichlorophenoxyacetic Acid, Diethanolamine Salt--Analytical Characterisation: Lab Project Number: 4102-900303-AS-001. Unpublished study prepared by Ricerca, Inc. 33 p. 41920502 Hambrick, A. (1990) 2,4-Dichlorophenoxyacetic Acid, Sodium Salt: Analytical Characterisations Lab Project Number: 4102-90-0302AS-001. Unpublished study prepared by Ricerca, Inc. 72 p. 41924300 Celex Corporation (1991) Submission of product chemistry data in support of registration of Super K-Gro Weed and Feed, Formula II Transmittal of 1 study. 4192430 1 Celex Corporation (1991) Product Chemistry: Super K-Gro Liquid Weed and Feed Formula II. Unpublished study prepared by Celex Corp oration . 15 p . 41926200 PBI/Gordon (1991) Submission of product chemistry data to fulfill subject data gaps for 2,4 dichlorophenoxyacetic acid 97%. Transmittal of 3 studies. 41926201 Etchep are bor da, I.; Sancricca, J. (1991) Preliminary Analysis of 2,4 Dichlorophenoxyacetic acid 97%. Unpublished study prepared by Atanor S. A. 17 p. 2-0394 REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE : 69 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM CPDMS) MRID SESUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 41926202 Etchepareborda, I. (1991) pH of 2,4-Dichlorophenoxyacetic acid 97%. Unpublished study prepared by Atanor S. A. 5 p. 41926203 Etchepareborda, I.; Sancricca, J. (1991) Storage Stability (1 year in commercial packaging) of 2,4 Dichlorophenoxyacetic acid 97%. Unpublished study prepared by Atanor S. A. 7 p. 41932200 DouElanco (1991) Submission of Data to Support the Application for New End Use Product Registration for XRM-5202: Product Chemistry Data. Trasnmittal of 1 Study. 41932201 Hamburg, F. (1990) Product Chemistry for XRM-5202 Herbicide: Lab Project Number: M-005202. Unpublished study prepared by Dou Elanco . 35 p . 1932500 DowElanco (1991) Submission of product chemistry and toxicity studies to support the application for registration of Justice Herbicide (2,4-D). Transmittal of 9 studies. 4193250 1 Cobb, J. (1991) Series 61: Product Identity and Composition of XRM5238 (Justice) Herbicide: Lab Project Number: GH-C 2558. Unpub lished study prepared by DouElanco, Formulations and Environmen tal Chem. Lab. 23 p. 41932502 Murphy, G. (1991) Series 62: Analy sis and Certification of Product Ingredients of XRM 5238 (Justic e Herbicide) an End Use Wettable Powder Formulation of 2,4-Dichl orophenoxyacetic Acid: Lab Pro ject Number: FOR91074. Unpubli shed study prepared by DowElanco, Formulations and Environmental C h e m . L a b s . 15 p. 41932503 Murphy, G. (1991) Series 63: Physical and Chemical Characteristics of XRM-5238 (Justice Herbicide), an End Use Wettable Powder For mulation of 2 , 4-Dichlorophenoxyacetic Acid: Lab Project Number: GH-C 2557. Unpublished study prepared by DowElanco, Formula tions and Environmental Chem. Lab. 10 p. 41932504 Murphy, G. (1991) Determination of Color, Physical State, Odor, pH, Density, Oxidizing and Reducing Action and Explodability of XRM5238 (Justice Herbicide): Lab Project Number: FOR91073. Unpub lished study prepared by DouElanco, Formulations and Environ mental Chem. Lab. 15 p. REPORT ID: PDR20 B0 1 RUN DATE: 11/26/93 PAGE: 70 J ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SE2UENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 41961300 DouElanco C1991) Submission of supplemental product chemistry data in support of reregistration of 2,4-D. Transmittal of 1 study. 41961301 DouElanco (1991) 2,4-D Butoxyethyl Ester: Response to 2,4-D Task 4: Registrants Response to Product Chemistry Data Requirements DEB N o .5454-5455, 5440-5544 Dated September 22, 1989. Unpublished study 1 1 p . 1 41964400 DouElanco (1991) Submission of Data to Support the Reregistrtion of 2,4-D: Product Chemistry. Transmittal of 1 Study. 41964401 DouElanco (1991) Response to 2,4-D Task 4: Registrant's Response to Product Chemistry Data Requirements DEB No. 5454-5455, 5440-5544 Dated Sep. 22, 1989 (Tinsuorth Letter Dated January 23, 1990) 2,4-Dimethylamine Salt. Unpublished study prepared by DouElanco . 17 p. 41972500 PBI/Gordon C o r p . (1991) Submission of Data To Support the Reregis tration of Diethanolamine Salt of 2,4-D: Product Chemistry Study. Transmittal of 1 study. 41972501 Gallacher, A. (1991) Dissociation of 2,4-Dichlorophenoxyacetic Acid (2,4-D) and 2,4-D Diethanolamine Salt in Water: Lab Project Num ber: 4102-90-0304-AS: 4102-90-0304-AS-001. Unpublished study prepared by Ricerca, Inc. 231 p. 41973500 DouElanco (1991) Submission of product chemistry data in support of reregistration of 2,4-D. Transmittal of 2 studies. 4197350 1 DouElanco (1991) 2,4-D Acid and 2,4-D Acid Flake: Response to 2,4-D Task 4: Registrant's Response of Product Chemistry Data Require ments Deb. No. 5454-5455, 5489, 5440-5544 Dated September 22, 1989. Unpublished study. 57 p. 41973502 Schriber, C. (1991) Chemical Stability of 2,4-Dichlorophenoxyacetic Acid: Lab Project Number: 90089. Unpublished study prepared by DouElanco. 17 p. 41978000 DouElanco (1991) Submission of product chemistry data in support of reregistration of 2,4-D isopropylamine salt. Transmittal of 2 studies. Zlo3^(b REPORT ID: PD R2 0B0 1 RUN DATE: 11/26/93 PAGE: 71 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SE2UENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 41 97800 1 > DowElanco (1991) 2,4-D Isopropylamine Salt: Response to 2,4-D Task 4: Registrant's Response to Product Chemistry Data Requirements DEB Nos. 5454-5455, 5489, 5440-5544 Dated September 22, 1989. Unpublished study prepared by DowElanco. 16 p. 41978002 Schriber, C. (1991) Chemical Stability of 2,4-D Isopropylamine Salt Solution: Lab Project Number: 90088. Unpublished study prepared by DowElanco 17 p. 42021000 DowElanco (1991) Submission of product chemistry data in support of reregistration of 2,4-D. Transmittal of 2 studies. 42021001 MacDaniel, R.; Weiler, D. (1987) Vapor Pressure Determination of 2,4-Dichlorophenoxyacetic Acid: Dimethylamine Salt: Lab Project Number: 41023. Unpublished study prepared by Rhone-Poulenc Inc. 9 p. 42021002 Hopkins, D. (1987) 2,4-Dichlorophenoxyacetic Acid Dimethylamine Salt: Determination of the Water Solubility: Lab Project Number: ES-DR-0008-3556-3 . Unpublished study prepared by The Dow Chemi cal Company. 15 p. 42023600 PBI Gordon C o r p . (1991) Submission of product chemistry data in support of fulfilling the subject data gaps cited in an EPA letter dated May 15, 1991 for 2,4-D acid. Transmittal of 1 study. 42023601 Desai, L. (1991) Technical 2,4-D Acid: Physical and Chemical Char acteristics: Lab Project Number: 91-GR-0004. Unpublished study prepared by Toxicon Corp. 120 p. 42102900 A>H. Marks Co. (1991) Submission of product chemistry data to comply with an Agency data call-in for dioxin/furan data. Transmittal of 1 study. 42102901 Landvoight, ? (1990) Analysis of DD/DF in 2,4-D Acid...: Lab Pro ject Number: K N R . 2954367. Unpublished study prepared by Chemserv Industrie Service Ges.m.b.H. 57 p. 42105500 Riverdale Chemical Co. (1991) Submission of Data To Support Registration of Riverdale Dissolve: Product Chemistry. Trans mittal of 1 study. ^03^7 REPORT ID: PDR20 B0 1 RUN DATE: 11/26/93 PAGE: 72 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 42105501 Sawyer, R. (1990) Product. Chemistry: Riverdale Dissolve: Lab Pro ject Number: DRI/TRI/TRIAMINE/W/S. Unpublished study prepared by Riverdale Chemical Co. 8 p. 42149600 Riverdale Chemical Co. (1992) Submission of product chemistry and toxicity data to support the registration of Triamine Premium Granular Weed Killer. Transmittal of 7 studies. 42149601 Sawyer, R. (1990) Product Chemistry: ^Riverdale Triamine Premium Granular Weed Killer I. Unpublished study prepared by Riverdale Chemical Co. 19 p. 42149607 Bresnahan, J. (1991) Nitrosamine Analysis: tTriamine Premium Weed and Feed|: Lab Project Number: 5450-6985. Unpublished study prepared by Thermedics, Inc. 30 p. 42190200 2,4-DP Task Force (1992) Submission of product chemistry data in support of a reregistration standard for 2,4-DP-P acid and dimethylamine salt. Transmittal of 10 studies. 42190201 Muller, F. (1991) Comminution of Herbicide: Lab Project Number: 191.0308.3. Unpublished study prepared by BASF Akteingesellschaft 24 p . to 190202 Ziegler, ?. (1990) Determination of Dichlorprop: Lab Project Number: CF-A 414. Unpublished study prepared by BASF Ak tei ngesellschaft. 19 p. 42 190203 Liesner, M. (1990) 2,4-DP-P BASF Task Force Sample: Determin ation of Active Ingredient: Lab Project Number: PCP01126. Unpublished study prepared by BASF Ak te in gesellschaft. 10 p. 42190204 Liesner, M. (1991) 2,4-DP-P BASF Task Force Sample: Determin ation of Active Ingredient: Lab Project Number: PCP01419. Unpublished study prepared by BASF Akteinge se ll sc ha ft . 10 p. 42190205 Petersen, M. (1991) 2,4-DP-P Composite Task Force Sample: Determination of Active Ingredient and Methods Information: Lab Project Number: PCP01517. Unpublished study prepared by BASF Aktei nge sel lsc ha ft. 14 p. 3 .0 3 9 6* REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 73 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 42190206 Euler, K. (1991) 2,4-DP-P BASF Task Force Sample: Determination of Impurities: Lab Project Number: 0/91/12. Unpublished study prepared by BASF Ak teingesellschaft. 28 p. 42190207 Euler, K. (1991) 2,4-DP-P A .H . Marks Task Force Sample: Determination of Impurities: Lab Project Number: 0/91/6555-57. Unpublished study prepared by BASF Akteingesellschaft. 13 p. 42190208 Euler, K. (1991) 2,4-DP-P Composite Task Force Sample: Deter mination of Impurities: Lab Project Number: 0/91/16306-308. Unpublished study prepared by BASF Akteingesellschaft. 13 p. 42190209 Landvoigt, W. (1990) 2,4-DP-P Summary of Dioxin/Dibenzofuran Analysis: Lab Project Number: 2057516: 2057517. Unpublished study prepared by Chemserv Industrie Service Ges.m.b.H. 8 p. -21 90210 Landvoigt, W. ( 1990 ) A.H. Marks Analytical Methods Information: Lab Project Number: 40288: 2060150: 2060151. Unpublished study prepared by Chemserv Industrie Service Ges.m.b.H. 98 p. 42212100 Riverdale Chemical Co. (1992) Submission of product chemistry and toxicity data in support of registration of Riverdale Sweet Six teen Weed and Feed with Dissolve. Transmittal of 6 study. 42212101 Sawyer, R. (1991) Riverdale Sweet Sixteen Weed and Feed with Dissolve: Product Chemistry: Lab Project Number: SWEET SIXTEEN WEED A. Unpublished study prepared by Riverdale Chemical Co. 14 p. 42227500 Riverdale Chemical Co. (1992) Submission of Data To Support Reregistration of 2,4-D Riverdale Sodium Salt: Product Chemistry Study. Transmittal of 1 study. 42227501 Sawyer, R. (1990) Product Chemistry: Riverdale Sodium Salt of 2,4-D. Unpublished study prepared by Riverdale Chemical Co. 8 p. 42240200 Riverdale Chemical Co. (1992) Submission of Data To Support Application for Registration of Riverdale Sweet Sixteen Weed and Feed with Dissolve: Product Chemistry Study. Transmittal of 1 study. &JD3V REPORT ID: PDR20B01 RUH DATE: 11/26/93 PAGE : 74 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 42240201 Bresnahan, J. (1992) Nitrosomine An al y s i s : Riverdale Sweet Sixteen Weed & Feed with Dissolve: Lab Project Number: 5450-7922. Unpublished study prepared by ThermedeTec Inc. P 21 42258800 Riverdale Chemical Co. (1992) Submission of Data To Support Application for Riverdale Dissolve Weed and Feed Registration: Product Chemistry Study. Transmital of 1 study. 42258801 Sawyer, R. (1992) Product Chemistry: Riverdale Dissolve Weed and Feed. Unpublished study prepared by Riverdale Chemical C o . 15 p. 42264700 Riverdale Chemical Co. (1992) Submission of product chemistry and toxicity data in support of registration of Riverdale Dri D + DP Amine. Transmittal of 7 studies. 42264701 Sawyer, R. (1992) Product Chemistry: Riverdale Dri D + DP Amine: Lab Project Number: DRI D + DP AMINE. Unpublished study prepared by Riverdale Chemical Co. 18 p. 42264707 Stevens, J. (1990 ) Nitrosamine Analysis-* Riverdale Dri-D + DP Amine * Lab Project Number: 5450-6298. Unpublished study prepared by Thermedics, Inc. 18 p. 42285800 Riverdale Chemical Co. (1992) Submission of chemistry and toxicity data to support the registration of Riverdale Triplet Water Soluble. Transmittal of 7 studies. 42285801 Sawyer, R. (1992) Riverdale Triplet Water Soluble: Product Chemistry: Lab Project Number: TRIPLET W S . Unpublished study prepared by Riverdale Chemical Co. 23 p. 42285807 Bresnahan, J. (1991) Triplet W. S.: Nitrosamine Analysis: Lab Project ,Number: 5450-7371. Unpublished study prepared by C .S .E ., I n c . 22 p . 42454500 Riverdale Chemical Co. (1992) Submission of product chemistry data in support of the registration of Riverdale Sweet Sixteen Weed and Feed with CL/DAP . Transmittal of 1 study. gjo'O REPORT ID: PDR20B01 RUH DATE: 11/26/93 PAGE: 75 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 1 /MRID CITATION 42454501 Sawyer, R. (1991) Riverdale Sweet Sixteen Weed and Feed with CL/DAP. Unpublished study prepared by Riverdale Chemical Co. 8 P. 42518000 Chevron Chemical Co. (1992) Submission of product chemistry and toxicity data in support of the registration of Kleenup Grass Weed Killer. Transmittal of 7 studies. 42518001 Wong, D. (1992) Kleenup Grass and Weed Killer Formula II Product Chemistry: Lab Project Number: 92003. Unpublished study prepared by Chevron Chemical Co. 42 p. 42537500 Riverdale Chemical Co. (1992) Submission of product chemistry data in support of the registration of Riverdale Sodium Salt of 2,4-D. Transmittal of 1 study. ,2537501 Sawyer, R. (1992) Product C h e m i s t r y - A d d e n d u m : Riverdale Sodium Salt of 2,4-D. Unpublished study prepared by Riverdale Chemical Co. 14 p. 42545000 Riverdale Chemical Company (1992) Submission of product chemistry data in support of the registration of Riverdale Sweet Sixteen Weed and Feed with Dissolve. Transmittal of 1 study. 42545001 Sawyer, R. (1992) Product Chemistry: Riverdale Sweet Sixteen Weed and Feed with Dissolve. Unpublished study prepared by Riverdale Chemical Co. 8 p. 42676800 Chevron Chemical (1993) Submission of product chemistry data in support of the Ortho Triamine Jet Weeder registration. Transmittal of 1 study. 42676801 Wong, D. (1992) Ortho Triamine Jet Weeder Product Chemistry: Lab Project Number: 92007. Unpublished study prepared by Chevron Chemical Co. 41 p. 42724800 Riverdale Chemical Company (1993) Submission of Product Chemistry and Toxicity Data is Support of Registration for Riverdale Triplet MC DRI. Transmittal of 7 Studies. ao^for REPORT ID: PDR20B01 RUH DATE PAGE: ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 29 D PART 1 MRID CITATION 11/26/93 76 42724801 Sawyer, R. (1992) Product Chemistry: Riverdale Triplet MC DRI: Lab Project Number: TRIPLET MC DRI. Unpublished study prepared by Riverdale Chemical Company. 15 p. 42732300 DowElanco (1993) Submission of product chemistry data in support of the registration of 2,4-D/MCPP Weed Stick. Transmittal of 2 studies. 42732301 Burns, K. (1992) Product Identity and Composition of Weedstick TurfIon .V 1.0: Series 61: Lab Project Number: GH-C 2720. Unpublished study prepared by DowElanco. 27 p. 42732302 Murphy, J. (1992) Analysis and Certification of Product Ingredients of the End Use Product Turflon V1.0 Weedmaster Weedstick, a Formulation Containing 2,4-D and Triclopyr: Series 62: Lab Project Number: GH-C 2844: GHC 2674. Unpublished study prepared by DowElanco. 42 p. 42764800 DowElanco (1993) Submission of product chemistry data to support the registration of Turflon II Weed Stick (Weedstick Turflon V1.0). Transmittal of 2 studies. 42764801 Burns, K. (1993) Series 61: Product Identity and Composition of Weedstick Turflon V1.0: Lab Project Number: GH-C 2720. Unpublished study prepared by DowElanco. 27 p. 42764802 Murphy, G. (1992) Series 62: Analysis and Certification of Product Ingredients of the End Use Product Turflon V1.0 Weedmaster Weedstick, a Formulation Containing 2,4-D and Triclopyr: Lab Project Number: GH-C 2844. Unpublished study prepared by DowElanco. 42 p. 42769800 Riverdale Chemical Co. (1992) Submission of product chemistry and toxicity data to support the registration of Riverdale Triplet MC SAF. Transmittal of 7 studies. 42769801 Sawyer, R. (1992) Riverdale Triplet MC SAF: Product Chemistry. Unpublished study prepared by Riverdale Chemical Co. 15 p. 42795400 DowElanco (1993) Submission of product chemistry data in support of registration standard for 2,4-D Acid Flake. Transmittal of 1 study. cWS- REPORT ID: PDR20 B01 RUN DATE: 11/26/93 PAGE: 77 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (FDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 42795401 Murphy, J. (1993) Determination of Stability of 2,4-Dichlorophenoxyacetic Acid (2,4-D) Technical Grade of Active Ingredient (TGAI): Lab Project Number: FOR93058. Unpublished study prepared by Formulation Science and Technology Lab. 9 p. 42796200 DouElanco (1993) Submission of product chemistry data in support of the registration standard for 2,4-D 2HE and 2,4-D BEE. Transmittal of 1 study. 42796201 Murphy, G. (1993) Response to Letter Written by Lois A. Rossi (10/5/92) Subject: Product Chemistry Review for Dow Technicals: 62719-24, 62719-25, 62719-26, 62719-33 for 2,4-D Acid, IOE and BEE: Lab Project Number: GM052893C. Unpublished study prepared by DowElanco. 9 p. -+2798100 DowElanco (1993) Submission of supplemental product chemistry data to support the registration of DowElanco's 2,4-D DMA salts. Transmittal of 1 study. x 42798101 Murphy, G. (1993) Response to the Letter Written by Lois A. Rossi (10/05/02): Subject: Product Chemistry Review for DowElanco 2,4-D DMA FI: Lab Project Number: GM052793A. Unpublished study prepared by DowElanco. 7 p. 42798300 DowElanco (1993) Submission of supplemental product chemistry data to support the registration of 2,4-D IPA FI. Transmittal of 1 s t u d y . 4279830 1 Murphy, G. (1993) Response to Letter Written by Lois A. Rossi (1/08/93): Subject: Product Chemistry Review for DowElanco 2,4-D IPA FI: Lab Project Number: GM052793B. Unpublished study prepared by DowElanco. 7 p. 42803700 PBI/Gordon Corp. (1993) Submission of product chemistry and toxicity data in support of registration for Trimec 1 144 405? S P . Transmittal of 8 studies. 42803701 Cahoy, R. (1993) Product Identity and Composition of Trimec 1144 405? SP. Unpublished study prepared by PBI/Gordon Corp. 16 p. QjO ^ 0 3 REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 78 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 42803702 Irving, J. (1992) Trimec 1144 40% SP: Chemical and Physical Properties: Lab Project Number: p b g - 04. Unpublished study prepared by Dartec Inc. 49 p. 42804300 Riverdale Chemical Co. (1993) Submission of product chemistry data in support of the registration for Riverdale Dissolve 4000 Weed and Feed. Transmittal of 1 study. 42804301 , Sawyer, R. (1993) Product Chemistry: Riverdale Dissolve 4000 Weed and Feed: i ab Project Number: DISSOLVE 4000 WEED AND FEED. Unpublished study prepared by Riverdale Chemical Co. 8 p. 42829900 DowElanco (1993) Submission of product chemistry data in support of registration for 2,4-D DMA FI. Transmittal of 1 study. '2829901 Murphy, G. (1993) Determination of Melting Point of 2,4-Dichlorophenoxyacetic Acid Dimethylamine Salt (2,4-D DMA) Technical Grade of Active Ingredient (TGAI): Lab Project Number: FOR93053. Unpublished study prepared by Formulation Science and Technology Lab. DowElanco. 9 p. 42830700 DowElanco (1993) Submission of product chemistry and toxicity data in support of registration for 2,4-D/MCPP Weed Stick (Weedstick WMD2 V1.0). Transmittal of 6 studies. 42830701 Hamburg, F. (1992) Physical and Chemical Characteristics of Weedstick, WMD 2 V I .0: a Formulation of 2,4-Dichlorophenoxyacetic Acid and 2-(4-Chloro-2-Methylphenoxy) Propionic Acid: Lab Project Number? FOR 91039.02. Unpublished study prepared by Formulation Environmental Chemistry Labs, DowElanco. 10 p. 42830800 DowElanco (1993) Submission of product chemistry and toxicity data in support of registration for Turfion II Weed Stick (Weedstick Turfion VI.0). Transmittal of 6 studies. 42830801 Hamburg, F. (1992) Physical and Chemical Characteristics of Weedstick, Turflon V I. 0 an End Use Formulation of Turflon Amine: Lab Project Number: FOR 91039. Unpublished study prepared by Formulation Environmental Chemistry L a b s . DowElanco. 10 p. II oLL REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 79 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM CPDMS) MRID SE2UENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 42831000 DouElanco (1993) Submission of product chemistry data in support of registration for 2,4-D IPA. Transmittal of 1 study. ^42831 00 1 Murphy, G. ( 1993) Determination of Melting Point of 2,4-Dichlorophenoxyacetic Acid Isopropylamine Salt (2,4-D IPA) Technical Grade of Active Ingredient (TGAI): Lab Project Number: FOR93054. Unpublished study prepared by Formulation Science and Technology Lab. DowElanco. 9 p. 42857200 PBI/Gordon C o r p . (1993) Submission of product chemistry data in support of registration standard for Diethanolamine Salt of 2,4-D. Transmittal of 9 studies. 42857201 Malone, S. (1992) Characterization of Technical Diethanolamine Salt of (2,4-Dichlorophenoxy) Acetic Acid: Lab Project Number: 4102-92-0055-AS: 4102-92-0055-AS-O01. Unpublished study prepared by Ricerca, Inc. 47 p. 42857202 Malone, S. (1992) Characterization of Purified Diethanolamine Salt of (2,4-Dichlorophenoxy) Acetic Acid: Lab Project Number: 4 102-92-0056-AS: 4 102-92-0056-AS-00 1 . Unpublished study prepared by Ricerca, Inc. 73 p. 42857203 Wojcieck, B. (1992) Color, Physical State, Odor of the Diethanolamine Salt of (2,4-Dichlorophenoxy) Acetic Acid: Project Number: 4 102-92-0 08 2- AS : 41 02-92-0082-AS-00 1 . Unpublished study prepared by Ricerca, Inc. 24 p. Lab 42857204 Wojcieck, B. (1992) Bulk Density of the Diethanolamine Salt of (2,4-Dichlorophenoxy) Acetic Acid: Lab Project Number: 4102-92-0083-AS: 4102-92-0083-AS-001. Unpublished study prepared by Ricerca, Inc. 22 p. 42857205 Douglass, M. (1993) Technical Diethanolamine Salt of (2,4-Dichlorophenoxy) Acetic Acid-- Solubility: Lab Project Number: 4102-92-0057-A S : 4102-92-0057-AS-001. Unpublished study prepared by Ricerca, Inc. 92 p. 42857206 Douglass, M. (1993) Purified Diethanolamine Salt of (2,4-Dichlorophenoxy) Acetic Acid--Vapor Pressure: Lab Project Number: 4102-92-0058-AS: 4102-92-0058-AS-00 1. Unpublished study prepared by Ricerca, Inc. 6 8 p. "dJOHoS REPORT ID: PDR20B01 RUH DATE: 11/26/93 PAGE: 80 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM CPDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 42857207 Douglass, M. C1993) Purified Diethanolamine Salt of C2,4-Dichlorophenoxy1 Acetic Acid--Octanol/Water Partition Coefficient: Lab Project Number: 4102-92-0059-A S : 4 102-92-0059-AS-001. Unpublished study prepared by Ricerca, I n c . 55 p . 42857208 Furlong, K. (1992) pH of the Diethanolamine Salt of (2,4-Dichlorophenoxy) Acetic Acid: Lab Project Number: 4102-92-0088-AS: 4102-92-0088-AS-001. Unpublished study prepared by Ricerca, Inc. 27 p. 42857209 Malone, S. (1993) Technical Diethanolamine Salt of (2,4-Dichlorophenoxy) Acetic Acid--Stability: Lab Project Number: 4102- 92- 08 5- AS : 4102-92-0085-AS-001. Unpublished study prepared by Ricerca, Inc. 51 p. 42870600 The Scotts Company (1993) Submission of product chemistry and toxicity data in support of registration for Fertiliser With Weed Control. Transmittal of 8 studies. 42870601 Davidson, A. (1993) Product Specific Chemistry Requirements for Fertilizer with Weed Control: Lab Project Number: SS-013: S-4298. Unpublished study prepared by The 0. M. Scott & Sons Co. 5 p. 42870602 Daugherty, G. (1993) Product Specific Chemistry Requirements for Fertilizer with Weed Control. Unpublished study prepared by The 0. M. Scott & Sons Co. 6 p. 42895000 DowElanco (1993) Submission of Toxicity Data for NAF-73 in Support of Experimental Use Permit on Field Corn. Transmittal of 9 Studies. 42895001 Baker, R. (1993) Product Identity and Composition of NAF-73, A Water Dispersible Granule Formulation of 2,4-D, Clopyralid, and Flumetsulam: Lab Project Number: GH-C 3049. Unpublished study prepared by Formulation Science 8 Technology Lab. 75 p. LO L+ tc REPORT ID: PDR20B01 RUH DATE*. 11/26/93 PAGE : 81 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SE2UENCE BIBLIOGRAPHY 24 D PART 1 MRID CITATION 42895002 Hamilton, T. (1993) Analysis and Certification of Product Ingredients of the End Use Product NAF-73, a Water Dispersible Granule Formulation of 2,4-D, Clopyralid, and Flumetsulam: Lab Project Number: GH-C 3052. Unpublished study prepared by Formulation Science Technology Lab. 31 p. 42895003 Hamilton, T. (1993) Determination of Physical and Chemical Properties of NAF-73, a Water Dispersible Granule Formulation of 2,4-D, Clopyralid, and Flumetsulam: Lab Project Number: FOR93092. Unpublished study prepared by Formulation Science Technology Lab. 12 p. 42927000 Whitmire Research Labs., Inc. (1993) Submission of Toxicity Data for Whitmire TC 73 Weed Killer in Support of Registration. Transmittal of 7 S t u dies. 42927001 Sarli, M. (1993) Whitmire TC 73 Weed Killer Herbicide: Product Chemistry: Lab Project Number: WRL-92-0059: 92-0061: 92-0070. Unpublished study prepared by Whitmire Research Lab., Inc. 1 2 p. 42973900 PBI/Gordon C o r p . (1993) Submission of Product Chemistry and Acute Toxicology Data in Support of Registration of EH 1148 Herbicide. Transmittal of 7 Studies. 42973901 Cahoy, R. (1993) Product Identity and Composition of EH 1148 Herbicide. Unpublished study prepared by PBI/Gordon Corp. 9 P. 42992700 PBI/GORDON Corp. (1993) Submission of Product Chemistry Data for EH 1148 Weed and Feed in Support of Registration. Transmittal of 1 Study. 42992701 Irving , J . (1993) EH 1148 Weed and Feed: Chemical and Phy sical Pro per ties: Lab Project Number: PBG-07. Unpublished study pre par ed by DARTEC Inc. 38 p. REPORT ID: PDR20B01 RUN DATE' 11/26/93 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS1 MRID SEBUENCE BIBLIOGRAPHY 24 D PART 2 SEARCH TERMS: CHEMICALS : 030033 OR 030034 OR 030035 OR 030039 OR 030052 OR 030053 OR 030055 OR 030056 OR 030062 OR 030063 OR 030064 OR 030065 OR 030066 OR 030072 AND SUBJECT: PRODUCT CHEMISTRY AND SUBMITTER: ALL AND SUBMISSION DATE: ALL AND LAB-ID : ALL AND DOCUMENT TYPES: ALL SELECTED STUDIES REGARDLESS OF DOCUMENT TYPE AND ENTRY DATE: ALL MBER OF STUDIES: 259 MRID SEBUENCE BI BLI OG R AP HY ----- --NUMBER OF COPIES: AUTHOR SEBUENCE BIBLIOGRAPHY ---- NUMBER OF COPIES: SUBMITTER SEBUENCE BIBLIOGRAPHY - NUMBER OF COPIES: GUIDELINE SEBUENCE BIBLIOGRAPHY SUMMARY FORMAT ---------------- NUMBER OF COPIES: EXPANDED FORMAT --------------- NUMBER OF COPIES: PAPER SIZE: 8 1/2 BY 11 INCH PAPER 1 0 0 0 0 LO t+O g REPORT ID: PDR20B01 RUN DATE: PAGE: ENVIRONMENTAL PROTECTION AGENCY .PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 2 MRID CITATION 11/26/93 1 00004777 Kenaga, E.E. (1972) The Comparative Toxicity to Birds of Dow Herbi cides Containing Chlorophenoxyalkanoic Acids and Derivatives. (Unpublished study received Apr 16, 1974 under 802-517; prepared by Dow Chemical Co., submitted by Lilly Charles H. Co., Miller Rd . Div., Portland, Oreg. ; C D L :128581- A ) 00013373 Nalco Chemical Company (1977) Gas Chromatographic Analysis of Her bicide Formulations Containing the Isooctyl Ester of 2,4 Dichlorophenoxy acetic acid (2, 4 D). Method dated Mar 18, 1977. (Unpublished study received Nov 9, 1977 under 1706-104; CDL: 232180-B) 00013377 Nalco Chemical Company (19??) Analysis of Active Components: Nalkil 2728 (BX-939) Emulsifiable Concentrate. (Unpublished study re ceived Nov 9, 1977 under 1706-105; C D L :23217 7 - C ) 00013380 Nalco Chemical Company (19??) Analysis of Active Components: Nalkil 2726 (BX-933) Emulsifiable Concentrate. (Unpublished study re ceived Nov 9, 1977 under 1706-107; C D L :23218 3 - C ) 00022377 Friedrich, W.E.; Smith, W.J.; Below, J.F. (1964) The Analyses of Knoxweed 52, Knoxweed 105 and Knoxweed 42: Report No. RR-64-51. Three methods dated Aug 13, 1964. (Unpublished study received Oct 20, 1964 under 476-1794; submitted by Stauffer Chemical Co., Richmond, Calif.; C D L :101402-A) 00022391 Stauffer Chemical Company (19??) Composition of Formulation: $Ept a m l . (Unpublished study received Dec 4, 1963 under unknown admin, no.; C D L :119596-A) 00022392 Smith, W.J.; Below, J.F. (1963) The Determination of Eptam and 2, 4-D Isooctyl ester in the 2,4-E Formulations: Report No. 63572. Method dated Oct 15, 1963. (Unpublished study received Dec 4, 1963 under unknown admin, no.; submitted by Stauffer Chemical Co., Richmond, Calif.; C D L :119596 - B ) 00023109 Oregon State University (1961) Annual Report-- 1961. (Unpublished study received Aug 30, 1965 under 6F0466; prepared by Agri cultural Experiment Station, Dept, of Agricultural Chemistry, submitted by Velsicol Chemical Corp. Chicago, 111.; CDL: 090517-AM) 3-0^0^ REPORT ID : PDR20B01 RUN DATE: 11/26/93 PAGE: 2 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 2 MRID CITATION 00028194 Stagen, R.; Omilinsky, B.; Lyons, R.J.; et al. (1971) Laboratory Report: Report No. 7. (Unpublished study received Oct 7, 1971 under 876-156; submitted by Velsicol Chemical C o r p ., Chicago, 111.; C D L :005 075 -A) 00028313 Velsicol Chemical Corporation (19??) Stability Data: Banvel-(R)a 310, Oil Soluble Industrial Herbicide. (Unpublished study re ceived Sep 15, 1972 under 876-180; C D L :220115 - A ) 00028315 Stagen, R. (1971) B12D; B12T; and B14D Oil Soluble Formulations: Report No. 8 . (Unpublished study^received Jan 25, 1972 under. 876-168; submitted by Velsicol Chemical Corp., Chicago, 111.; C D L : 133116-A) \ 00032217 Kaldon, H. (19??) 4L Compatibilities. (Unpublished study received Oct 22, 1969 under 100-497; submitted by Ciba-Geigy Corp., Greensboro, N.C.; C D L :00052 3 - D ) 00036042 Tennessee Valley Authority (19??) Name, Chemical Identity, and Composition. (Unpublished study; C D L :095539-A) 00036152 Dow Chemical Company (19??) Tordon-(R)o 202 Mixture. (Unpublished study received Jul 3, 1975 under 6F1653; C D L :094499 - E ) 00036153 Dow Chemical Company (1966) Tordon 202 Mixture. Method no. 87124 dated May 24, ,1966. (Unpublished study received Jul 3, 1975 under 6F1.653; ^DL :0 9449 9-F ) 00039732 National Agricultural Chemicals As so ci a t i o n 's Industry Task Force on Phenoxy Herbicide Tolerances (19??) Ingredient Data Sheet: $2,4-D 20% Terra Gl. (Unpublished study received Dec 8 , 1967 under 8F0670; CDL:095152-E) 00039734 Dow Chemical U.S.A. (1972) Brushkiller LV 2-2: m - 3509. (Unpub lished study received on unknown date under 8F0670; submitted National Agricultural Chemicals As so ci at io n's Industry Task Force on Phenoxy Herbicide Tolerances, Washington, D.C.; CDL: 095152-1) by ^ 0 4(0 REPORT ID= PDR20B01 RUN DATE: PAGE: ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 2 MRID CITATION 11/26/93 3 00039735 Dow Chemical U.S.A. (1972) Brush Killer X: M-3507. (Unpublished study received on unknown date under 8F0670; submitted by n a tional Agricultural Chemicals Association's Industry Task Force on Phenoxy Herbicide Tolerances, Washington, D.C.; C D L :095152 -J ) 00039736 Dow Chemical U.S.A. (1972) Butyl 265: M-3512. (Unpublished study received on unknown date under 8F0670; submitted by National Ag ricultural Chemicals Association's Industry Task Force on Phe noxy Herbicide Tolerances, Washington, D .C .; C D L :095152 - K ) 00039737 Dow Chemical U.S.A. (1972) Dow Butyl 400: m - 3527. (Unpublished study received on unknown date under 8F0670; submitted by N a tional Agricultural Chemicals Association's Industry Task Force on Phenoxy Herbicide Tolerances, Washington, D.C.; C D L :095152- L) ''0039740 Dow Chemical U.S.A. ( 1972 ) Esteron-'(R)B Brush Killer: M-3507. (Un published study received on unknown date under 8F0670; submit ted by National Agricultural Chemicals Association's Industry Task Force on Phenoxy Herbicide Tolerances, Washington, D.C.; CDL:095152-0) 00039741 Dow Chemical U.S.A. (1972) Esteron Four Low Volatile Weed Killer: M-3503. (Unpublished study received unknown date under 8F0670; submitted by National Agricultural Chemicals Associa tion's Industry Task Force on Phenoxy Herbicide Tolerances, Washington, D.C.; C D L :09515 2 - P ) 00039742 Dow Chemical U.S.A. (1972) Esteron 6 E= M-3564. (Unpublished study received on unknown date under 8F0670; submitted by National Ag ricultural Chemicals Association's Industry Task Force on Phe noxy Herbicide Tolerances, Washington, D.C.; C D L :095152-) 00039743 Dow Chemical U.S.A. ( 1972) Esteron-" (R )n 44 Weed Killer: m - 3704. (Unpublished study received on unknown date under 8F0670; sub mitted by National Agricultural Chemicals Association's Industry Task Force on Phenoxy Herbicide Tolerances, Washington, D.C.; C D L :095152 --R) 00039744 Dow Chemical U.S.A. (1972) Est e r o n - (R )o 76BE: M - 3 5 5 5 . (Unpublished study received on unknown date under 8F0670; submitted by N a tional Agricultural Chemicals Association's Industry Task Force on Phenoxy Herbicide Tolerances, Washington, D.C.j C D L 095152 -S ) I oLO Lf ( ( REPORT ID: PD R 20B 01 RUN DATE: 11/26/93 PAGE: 4 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 2 MRID CITATION 00039745 Dow Chemical U.S.A. (1972) Esteron 76E: M-3558. (Unpublished study received on unknown date under 8F0670; submitted by National Ag ricultural Chemicals Association, Industry Task Force on Phenoxy Herbicide Tolerances, Washington, D.C.; C D L :09515 2 - T ) 00039746 Dow Chemical U.S.A. (1972) Esteron-(R) 99: M-3502. (Unpublished study received on unknown date under 8F0670; submitted by N a tional Agricultural Chemicals Association, Industry Task Force on Phenoxy Herbicide Tolerances, Washington, D.C.; C D L :095152 -U ) 00039747 Dow Chemical U.S.A. ( 1972 ) Es ter on-- (R )n 99 Concentrate: M-3503. (Unpublished study received on unknown date under 8F0670; sub mitted by National Agricultural Chemicals Association, Industry Task Force on Phenoxy Herbicide Tolerances, Washington, D.C.; CDL:095152-V) 00039749 Dow Chemical U.S.A. (1972) Tippon-(R)o 2-2: M-2213. (Unpublished study received on unknown date under 8F0670; submitted by N a tional Agricultural Chemicals Association, Industry Task Force on Phenoxy Herbicide Tolerances, Washington, D.C.; C D L :095152 - X ) 00039750 Dow Chemical U.S.A. (1972) Verton-(R) 2D: m - 3591. (Unpublished study received on unknown date under 8F0670; submitted by N a tional Agricultural Chemicals Association, Industry Task Force on Phenoxy Herbicide Tolerances, Washington, D.C.; C D L :095152 -Y ) 00039751 Dow Chemical U.S.A. (1972) Weed Killer LV 4= M-3514. (Unpublished study received on unknown date under 8F0670; submitted by N a tional Agricultural Chemicals Association, Industry Task Force on Phenoxy Herbicide Tolerances, Washington, D.C.; C D L :09515 2 - Z ) 00039752 Thompson-Hayward Chemical Company (19??) Confidential Disclosure of Ded-weed Products. (Unpublished study received Dec 8 , 1967 u n der 8F0670; submitted by National Agricultural Chemicals Associ ation, Industry Task Force on Phenoxy Herbicide Tolerances, Washington, D.C.; C D L :09515 2 - A A ) 00039755 Rhodia, Incorporated (1971) Chipman 2,4-D Butyl ester 334E. (Un published study received on unknown date under 8F0670; submitted by National Agricultural Chemicals Association, Industry Task Force on Phenoxy Herbicide Tolerances, Washington, D.C.; CDL: 095152-AD) 3-0 REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 5 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM CPDMS) MRID SE2UENCE BIBLIOGRAPHY 24 D PART 2 MRID CITATION 00039756 Rhodia, Incorporated (1971) Chipman 2 , 4-D Lou Volatile Ester 4L. (Unpublished study received on unknown date under 8F0670; sub mitted by National Agricultural Chemicals Association, Industry Task Force on Phenoxy Herbicide Tolerances, Washington, D.C.; CDL:095152-AE) 00039757 Rhodia, Incorporated (1971) Chipman 2,4-D Butyl ester 6 E. (Unpub lished study received on unknown date under 8F0670; submitted by National Agricultural Chemicals Association, Industry Task Force on Phenoxy Herbicide Tolerances, Washington, D.C.; C D L : 095152-AF) 00041485 Dow Chemical Company (1963) Formulations Used in Fish and Wildlife Toxicity Studies: Summary Statement. (Unpublished study re ceived Nov 6 , 1967 under 0F0863; C D L :094524 - S ) 00043764 Anchem Products, Incorporated (1969) Chemistry: H q u a - K l e e n 201. (Unpublished study received Dec 17, 1971 under 2E1221; submit ted by U.S. Dept, of the Army, .Office of the Chief of Engineers, Washington, D.C.; C D L :099544-J ) 00043765 U.S. Department of the Army, Office of the Chief of Engineers (19??) Summary for All Sections of Petition. Summary of study 099544-J. (Unpublished study; C DL : 099544-K) 00043828 Gangstad, E.O.; Fish, F.; Stanley, R.A.; et al . (1976 ) Butoxyethanol ester of 2 , 4-D for Control of Eurasian Water Milfoil. Final rept. Vicksburg, Miss.: u . S . Army Engineer, Waterways Experiment Station. (Aquatic Plant Control Program, technical report 12, published study; C D L : 099542 - A ) 00045066 Uniroyal Chemical (1970) 2 , 4-D Isooctyl Ester Technical-- AnAgri cultural Herbicide for Formulating Use Only: Technical Bulletin AG 121. (Unpublished study received Oct 28, 1976 under 400-134; CDL: 226397-A) 00045078 Uniroyal Chemical (1970) 2,4-D Butylester Technical-- an Agricul tural Herbicide for Formulating Use Only: Technical Bulletin AG 120. (Unpublished study received Oct 28, 1976 under 400-134; CDL : 226395-A) `Z p ' + O REPORT ID: PDR20B01 RUN DATE: PAGE: ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) 24 D PART 2 MRID SEUENCE BIBLIOGRAPHY ! MRID CITATION 11/26/93 6 00045080 Uniroyal Chemical (1976) Summary of Method of Preparation and Analysis of 2,4-D Isooctyl ester. Includes methods dated Oct 6 , 1976. (Unpublished study received Oct 28, 1976 under 400-134} CDL:226394-B) 00045408 Dow Chemical Company (1969) The Name, Chemical Identity, and Compo sition of the Pesticide Chemical: Tordonl. (Unpublished study received Aug 4, 1969 under 0F0863; C D L :093 160 - F ) 00046185 U.S. Office of Science and Technology, Panel on Herbicides (1970) Report on 2,4-D. (Unpublished study} C D L :119429-A) 00052566 National Agricultural Chemicals Association's Industry Task Force on Phenoxy Herbicide Tolerances (1970) Ingredient Data Sheet: Butyl 4 D | . (Unpublished study received on unknown date under 8F0670} CDL:095152-B) 00052567 National Agricultural Chemicals Association's Industry Task Force on Phenoxy Herbicide Tolerances (1970) Ingredient Data Sheet: Lo-Vol 4 D I . (Unpublished study received on unknown date under 8F0670} CDL:095152-C) 00052568 National Agricultural Chemicals Association's Industry Task Force on Phenoxy Herbicide Tolerances (1970) Ingredient Data Sheet: Butyl 6 D I. (Unpublished study received on unknown date under 8 F 0 6 7 0 } C D L :095152-F) 00052569 National Agricultural Chemicals Association's Industry Task Force on Phenoxy Herbicide Tolerances (1970) Ingredient Data Sheet: Lo-Vol 6 Dl . (Unpublished study received on unknown date under 8F0 67 0 } CDL:095152-G) 00052617 Dow Chemical U.S.A. (1967) Chemical Composition of Raw Materials of M-3766I. (Unpublished study received Jun 28, 1973 under unknown admin, no.} C D L :123467 - A ) 2.04(4 REPORT ID? PD R 20B 01 RUN DATE: 11/26/93 PAGE : 7 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 2 MRID CITATION 00053697 Upton, E.T. (1972) Letter sent to Drew M. Baker, Jr. dated Jun 5, 1972 ^Identity of the inert ingredients used in the formulations for 2,4-D, Silvex and M C P A I . (Unpublished study received on un known date under 9F0761; prepared by Thompson-Hayward Chemical Co., submitted by National Agricultural Chemicals Association, Industry Task Force on Phenoxy Herbicide Tolerances, Washington, D.C. ; CDL:096516-G) 00053793 Uniroyal Chemical (19??) 2,4-D Butyl ester technical: An agricul tural herbicide for formulating use only. ?: Uniroyal. (Tech nical bulletin AG 120; summary of studies 226392-C through 226392-G; alsoInunpublished submission received Oct 28, 1976 under 400-133; CDL:226392-A) 000565*18 00063509 Parsey, E.S.; Van Horn, R.L. (1970) Butyl 400: Evaluation of Formu lation M - 3 5 2 7 . (Unpublished study received Nov 9, 1972 under 464-184; submitted by Dow Chemical U.S.A., Midland, Mich.; CDL: 230490-B) * Boving, P.A.; Winterfeld, R.G. (1977) Flow Tests and Droplet Sizing for Selected Materials from Thompson-Hayward Chemical Company. (U.S. Agricultural Research Service, Western Region, Yakima Ag ricultural Research Laboratory; unpublished study, including Thompson-Hayward Chemical Co. no. 4440; C D L :24 4 5 33 -G ) 00063510 Colorado. Department of Agriculture (1977) Report on Flow Tests of Thompson-Hayward Sulv 2,4-D Preparations. (Unpublished study, including Thompson-Hayward Chemical Co. no. 4392 ; CDL s244533-M) 00065214 Dow Chemical U.S.A. (19??) Stability of M-3516. (Unpublished study received Mar 26, 1970; Mar 25, 1970 under 464-382; C D L :230493 -B ) 00068565 Anon. (19??) 2,4-D Butyl Ester Technical, an Agricultural Herbicide for Formulating Use Only. N.P. (Technical bulletin AG 120; alsoInunpublished submission received Oct 28, 1976 under 400133; submitted by Uniroyal Chemical, Bethany, Conn.; CDL: 226390-A) 00068566 Uniroyal Chemical (1976) Summary of Method of Preparation and Analysis of 2,4-D Butyl Ester. (Unpublished study received Oct 28, 1976 under 400-133; C D L :226390 -B ) REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 8 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SE2UENCE BIBLIOGRAPHY 24 D PART 2 MRID CITATION 00068567 Hager, F.M. (1976) Letter sent to Gracie Stone dated Feb 21, 1976: 2,4-D and 2,4,5-T ester processes. (Unpublished study received Oct 28, 1976 under 400-133; prepared by Uniroyal Ltd., Canada, submitted by Uniroyal Chemical, Bethany, Conn.; C D L :226390-C) 00068568 Thompson, H. (1976) Clover Bar Plant-Raw Material Specifications. (Unpublished study received Oct 28, 1976 under 400-133; prepared by Uniroyal Ltd., Canada, submitted by Uniroyal Chemical, Bethany, Conn.; C D L :226390- D ) 00068569 Shipley, W.G. (1976) New Normal Butyl Alcohol. (Unpublished study received Oct 28, 1976 under 400-133; submitted by Uniroyal Chemical, Bethany, Conn.; C D L :226390- E ) 00068570 Thompson, H. (1976) Clover Bar Plant--Raw Material Specifications. (Unpublished study received Oct 28, 1976 under 400-133; prepared by Uniroyal Ltd., Canada, submitted by Uniroyal Chemical, Bethany, Conn.; C D L :22 63 90 -F ) 00068571 Hager, F.M. (1976) Method for Gas Chromotographic $sicl Determina tion of DCP (2,4-Dichlorophenol). Method dated Oct 6 , 1976. (Unpublished study received Oct 28, 1976 under 400-133; sub mitted by Uniroyal Chemical, Bethany, Conn.; C D L :226390- G) 00068572 Hager, F.M. (1976) Method for Gas Chromatographic Determination of MCA (Monochloroacetic Acid). Method dated Oct 6 , 1976. (Unpub lished study received Oct 28, 1976 under 400-133; submitted by Uniroyal Chemical, Bethany, Conn.; C D L :226390 - H ) 00068573 Hager* F.M. (19??) Method for Gas Chromatographic Determination of Butyl Ester of 2 , 4-Dichlorophenoxy Acetic Acid. (Unpublished study received Oct 28, 1976 under 400-133; submitted by Uniroyal Chemical, Bethany, Conn.; C D L :226390- I ) 00070900 Chevron Chemical Company (1978) Registration Program R-127: Tank Mix Stability: File No. 774.10. (Unpublished study received Mar 24, 1981 under 239-2186; C D L :244723-A) 00070901 Bohnert, W.P. (1978) Physical Compatability Assessment of Paraquat + Atrazine + Igran + 2,4-D Tank Mix. (Unpublished study re ceived Mar 24, 1981 under 239-2186; submitted by Chevron Chemi cal Co., Richmond, Calif.; C D L :244723 - B ) .0 (b REPORT ID: PDR20B01 RUN DATE: PAGE: ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 2 MRID CITATION 11/26/93 9 00082612 Allen, A. (1981) Formal Report of Analysis for N-Nitroso Compounds: Report No. 5450-2586. (Unpublished study received May 15, 1981 under 2217-648; prepared by Thermo Electron C o r p . , submitted by PBI-Gordon Corp., Kansas City, K a n s .; C D L :245094 - A ) 00083116 Cholakis, J.M. (1980) Letter sent to J.S. Skaptason dated Jan 17, 1980: Eye irritation screen on nine (9) test compounds (EH604EH612): MRI Project No. 4823-B(2). (Unpublished study received Jul 15, 1981 under 2217-624; prepared by Midwest Research Institute, submitted by PBI-Gordon Corp., Kansas City, Kans.; C D L :245537-C) 00088574 PBI/Gordon Corporation (1981) Confidential Statement of Formula: Gordon's Brush Killer 801. (Unpublished study received Jul 15, 1981 under 2217-624; C D L :2455 37 -M ) 00088575 PBI/Gordon Corporation (1981) Confidential Statement of Formula: Gordon's Brush Killer 800. (Unpublished study received Jul 15, 1981 under 2217-624; C D L :245537-2) 00094655 Thompson-Hayward Chemical Company (1978) tFlow Rates and Droplet Sizing Tests on Sulv Formulations!. (Compilation; unpublished study received Apr 21, 1981 under C081/3; submitted by state of Colorado for Thompson-Hayward Chemical Co., Kansas City, Kans.; C D L :246717-H) 00102547 Langer, J. (1973) Spot Weed Killer. (Unpublished study received Apr 3, 1973 under 498-90; submitted by Chase Products Co., Broadview, IL; C D L :020028 - A ) 00102548 Chase Products Co. (19??) Spot Weed Killer. (Unpublished study received Apr 3, 1973 under 498-90; CDL 5 02 00 28 -B ) 00102566 Parsey, E.; Van Horn, R. (1970) Esteron 44: Evaluation of Formu lation M-3499. (Unpublished study received Jul 30, 1970 under 464-26; submitted by Dow Chemical U.S.A., Midland, MI; CDL: 003395-A) 00102568 Parsey, E.; Van Horn, R. (1970) Brush Killer LV2-2: Evaluation of Formulation M-3509. (Unpublished study received Sep 17, 1970 under 464-352; submitted by Dow Chemical U.S.A., Midland, MI; CDL:003553-A) ao*f{ 7 REPORT ID: PDR20B01 RUH DATE: 11/26/93 PAGE : 10 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM CPDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 2 MRID CITATION 00102591 Van Horn, R. (1973) Tordon 101 Mixture Reformulated as M-3943: Versene Acid Substituted for Diglycolic Acid. (Unpublished study received Jul 18, 1974 under 464-306; submitted by Dou Chemical U.S.A.; Midland, MI; CDL '02 28 25 -A ) 00102592 Parsey, E . ; Van Horn, R. (1970) Esteron 6 E: Evaluation of Formula tion M-3564. (Unpublished study received Sep 25, 1970 under 464-347; submitted by Dou Chemical U.S.A., Midland, MI; CDL: 0228 46-A ) 00102593 Parsey, E.; Van Horn, R. (1970) Weed Killer LV-4: Evaluation of Formulation M-3514. (Unpublished study received on unknown date under 464-349; submitted by Dou Chemical U.S.A., Midland, MI; CDL:022853-A) ^0102594 Parsey, E.; Van Horn, R. (1970) Esteron 76E: Evaluation of Formu lation M-3558. (Unpublished study received Oct 13, 1970 under 464-150; submitted by Dou Chemical U.S.A., Midland, MI; CDL: 022937-A) 00102595 Parsey, E., Van Horn, R. (1970) Esteron 99: Evaluation of Formu lation M-3502. (Unpublished study received Oct 13, 1970 under 464-150; submitted by Dou Chemical U.S.A., Midland, MI; CDL: 022937-B) 00102597 Parsey, E.; Van Horn, R. (1970) Butyl 265: Evaluation of Formula tion M-3512. (Unpublished study received Sep 3, 1970 under 464-183; submitted by Dou Chemical U.S.A., Midland, MI; CDL: 022967-A) 00102598 Dou Chemical Co. (1959) Esteron 99 Concentrate: Method No. 22821. (Unpublished study received Oct 20, 1964 under 464-201; CDL: 022970- A) 00102599 Parsey, E.; Van Horn, R. (1970) Reformulation of Esteron 99 Con centrate. (Unpublished study received Feb 26, 1974 under 464201; submitted by Dou Chemical U.S.A., Midland, MI; CDL: 022971- A) REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 11 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM CPDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 2 MRID CITATION 00102600 Pa r s e y , E.; Van Horn, R. (1970) Esteron Brush Killer: Evaluation of Formulation M - 3 5 0 7 . (Unpublished study received Jul 17, 1970 under 464-204; submitted by Dow Chemical U.S.A., Midland, MI; C D L :022972-A) 00102603 Twin City Testing and Engineering Laboratory, Inc. (1972) Report of Petroleum Inspection: Laboratory No. 2-17783. (Unpublished study received Nov 20, 1972 under 1180-17; submitted by Midland Cooperatives, Inc., Minneapolis, MN; CDL *02 46 9 3 - A ) 00102620 U.S. Dept, of the Army (1969 ) ^Chemistry Data on Aqua Kleen 20 I. (Compilation; unpublished study received Jul 18, 1972 under 2E 12 21; C D L :091051-1) 00102727 U.S. Dept, of the Army, Office of the Chief of Engineers (19??) Name, Chemical Identity, and Composition: Butoxyethanol Ester of 2,4-Dichlorophenoxyacetic Acid (Granular). (Unpublished study; C D L :096649- B) 00102827 Hammond, H. (19??) Report on Herbicides: $2,4-D; 2,4,5-T and MCP Type Herbicides I. (Unpublished study received on unknown date undere unknown admin, no.; prepared by North Dakota, State Labo ratories Dept., submitted by ?; C D L :122427-A ) 00102897 Rivhard Conn., Inc. (1978) Transamine 0A-3D Herbicide. (Unpub lished study received Nov 28, 1978 under 35911-59; C D L :236627-A) 00102898 Kulkarni, S. (1978) Dinitro Weed-Killer. (Unpublished study re ceived Nov 28, 1978 under 35911-59; prepared by Vertac, Inc., submitted by Rivhard Conn., Inc., Southfield, MI; C D L :23 6627-B) 00102899 Kadakia, H. (1978) Formal Report of Analysis for N-Nitroso Com pounds. (Unpublished study received Nov 28, 1978 under 3591159; prepared by Thermo Electron C o r p ., submitted by Rivhard Conn., Inc., Southfield, MI; C D L :23662 7 - C ) 00102904 Union Carbide Agricultural Products Co., Inc. (1979) Assay Proce dure for Weedone Super BK-32. (Unpublished study received Apr 24, 1979 under 264-307; C D L :238208-A) 9s o REPORT ID: PDR20B01 RUN DATE: PAGE: ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM CPDMS) MRID SESUENCE BIBLIOGRAPHY 24 D PART 2 MRID CITATION 11/26/93 12 00102907 Vernetti, J.; Meyer, D. (1979) HPLC Method and Analysis Results for Five Representative Samples of Technical 2,4-D Products. (Unpublished study received Aug 16, 1979 under 359-177; sub mitted by Rho ne-Poulenc, Inc., Manmouth Junction, NJ ; CDL: 240915-A) 00107931 Union Carbide Agricultural Products Co., Inc. (1979) Assay Pro cedure for Weedone 20 Weed and Feed. (Unpublished study re ceived Apr 24, 1979 under 264-309 ; C D L :238210 - A ) 00108695 Dow Chemical Co. (1967 ) Tordon 144 Brush Killer: ^Chemical Study 1. (Unpublished study received Apr 11, 1967 under 464-EX-26; CDL: 123519-C) 001 11565 Wisniewski, D.; Rothman, L. (1978) Analysis for Possible Presence of N-Nitrosodiisopropanolamine in Tordon 101 Mixture Weed and Brush Killer, Tordon 101R Forestry Herbicide, Tordon 212 Mixture Herbicide, and Tordon 225E Herbicide and N-Nitrosodiethylamine in Tordon 225 Mixture Herbicide: ML-AL 78-00053. (Unpublished study received Aug 24, 1978 under 464-306; submitted by Dow Chemical U.S.A., Midland, MI; C D L :235093 - A ) 00115495 Parsey, E.; Van Horn, R. (1970) Brush Killer LV2-2: Evaluation of Formulation M-3509. (Unpublished study received Nov 16, 1970 under 464-352; submitted by Dow Chemical U.S.A., Midland, MI; C D L :022855-A) 00117989 Dow Chemical U.S.A. (1982) tTordon: Product Chemistryl. (Compila tion; unpublished study received Nov 12, 1982 under 464-502; C D L :24879 1-A) 00119032 Helfant, L.; Oestreicher, S. (1982) Temperature Stability of AXF1182: Weedone CB Woody Plant Herbicide: Project No. 858F60, File No. 30763. (Unpublished study received Nov 26, 1982 under 264393; submitted by Union Carbide Agricultural Products Co., Inc., Research Triangle Park, NC; C D L :248956-B) 00124806 Dow Chemical U.S.A. (1982) ^Chemical Study: Esteron BK Weed and Brush Killerl. (Compilation; unpublished study received Jan 5, 1983 under 464-589; C D L :24 9242-A) ! REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 13 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 2 MRID CITATION 00125254 Dow Chemical U.S.A. (1983) A Data Sheet Giving the Chemical and Physical Properties of the Chemical: A Complete Statement of the Names and Percentages by Weight of Each Active and Inert Ingredient in the Formulation To Be Shipped. (Compilation; un published study received Jan 14, 1983 under 464-EX-79; CDL : 249266-A) 00140230 Parsey, E.; Van Horn, R. (1970) Butyl 400: Evaluation of Formula tion M-3527. (Unpublished study received Jul 17, 1970 under 464-184; submitted by Dow Chemical U . S . A . , Midland, MI; CDL: 003457-A) 00140233 Parsey, E.; Van Horn, R. (1970) Esteron 99 Concentrate: Evaluation of Formulation M-3503. (Unpublished study received Jul 2, 1970 under 464-201; submitted by Dow Chemical U.S.A, Midland, MI; CDL:003465-A) 00140704 Parsey, E. (1969) Letter sent to R. Morgan dated Oct 28, 1969: Chemical stability of M-3516. (Unpublished study received Nov 12, 1969 under 464-382; submitted by Dow Chemical U.S.A., M id land, MI; C D L :003595-B) 00145783 Gilmore, Inc. (19??) [Product Chemistry of 2,4-D Solventless Butyl Ester 41. Unpublished compilation. 22 p. 00150048 BASF Wyandotte Corporation (1985) [Product Chemistry of BAS 528 00 H . I Unpublished compilation. 20 p. 00158583 Riverdale Chemical Co. (1986) [Chemical Composition of Riverdale ID + 1DP Low Vol ]. Unpublished compilation. 11 p. 00158585 Riverdale Chemical Co. (1986) [Analytical Methods for Physical and Chemical Properties of Riverdale 1D+ 1DP Low Vol]. Unpublished compilation. 39 p. 00162558 Imperial Inc. (1986) 2,4-D 560 Butyl Ester Weed Killer: Product Chemistry. Unpublished study. 25 p. 00162559 Imperial Inc. ( 1986 ) 2,4-D 560 Lo Vol Ester Weed Killer-* Product Chemistry. Unpublished study. 23 p. REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 14 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 2 MRID CITATION 00162560 Imperial Inc. C1986) 2,4-D 380 Butyl Ester Weed Killer: Product Chemistry. Unpublished study. 25 p. 00162577 Imperial Inc. (1986) Product Chemistry [Data for]: 2,4-D 380 Lo Vol Ester Weed Killer. Unpublished study. 23 p. 00162594 Imperial Inc. (1986) Product Chemistry [Data]: Lo-V 2,4-D Weed Kil ler. Unpublished study. 23 p. 00162595 Imperial Inc. (1986) Product Chemistry [Data]: Lou Volatile 4 2, 4-D Weed Killer. Unpublished compilation. 23 p. 00162596 Imperial Inc. (1986) Product Chemistry [Data]: Butyl Ester 2,4-D. Unpublished compilation. 25 p. '0162598 Imperial Inc. (1986) Product Chemistry [Data]: Lou Volatile 6 2, 4-D Weed Killer. Unpublished compilation. 23 p. 00162599 Imperial Inc. ( 1986 ) Product Chemistry [Data ]: Butyl Ester 6 2, 4-D Weed Killer. Unpublished compilation. 25 p. 00162600 Imperial Inc. (1986) Product Chemistry [Data]: Butyl Ester 6 2, 4-D Weed Killer. Unpublished compilation. 25 p. 00 1652 14 Parsey, E.; Van Horn, R. (1970) Esteron 76BE: Evaluation of Formu lation M-3555. Unpublished study prepared by Dou Chemical Co. 9 p. 05003909 Faust, S.D.; Hunter, N.E. (1965) Chemical methods for the detection of aquatic herbicides. Journal of the American Water Works Association 57(8 ): 1028-1037. 05009244 Keener, J.A.; Pless, C.D. (1974) Effects of direct application of selected pesticides on honey bee c o l o n i e s . Tennessee Farm and Home Science Progress Report (89):5-8. 40131700 Imperial Inc. (1987) Submission of Product Chemistry Data in Sup port of Application for Registration of MFA Oil Company Butyl Ester 2,4-D. Transmittal of 1 study. XOH'XX REPORT ID: PDR20B01 RUH DATE: PAGE: ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM CPDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 2 MRID CITATION 1/26/93 5 40131701 Currie, G. (1987) MFA Oil Company Butyl Ester 2,4-D: Supplemental Submission: Storage Stability. Unpublished study prepared by Imperial Inc. 6 p. 40132000 Imperial Inc. (1987) Submission of Data To Support Application for New Product Registration: imperial Inc. 2,4-D 380 Butyl Ester Weed Killer. Transmittal of 1 study. 40132001 Currie, G. (1987) Imperial Inc. 2,4-D 380 Butyl Ester Weed Killer: Product Chemistry: [Tests Nos. 003-86-A; 003-86-B]. Unpub lished compilation prepared by Imperial Inc. 6 p. 40132100 Imperial Inc. (1987) Submission of Data To Support Application for New Product Registration: Imperial Inc. 2,4-D 560 Butyl Ester Weed Killer. Transmittal of 1 study. 40132101 Currie, G. (1987) Imperial Inc. 2,4-D 560 Butyl Ester Weed Killer: Product Chemistry: [Tests Nos. 004-86-A; 004-86-B]. Unpub lished compilation prepared by Imperial Inc. 6 p. 40132200 Imperial Inc. (1987) Submission of Data To Support Application for New Registration: imperial Inc. 2,4-D 380 Lo Vol Ester Weed Killer. Transmittal of 1 study. 40132201 Currie, G. (1987) Imperial Inc. 2,4-D 380 Lo Vol Ester Weed Killer: Product Chemistry: [Tests Nos. 005-86-A; 005-86-Bl. Unpub lished compilation prepared by Imperial Inc. 6 p. 40132300 Imperial Inc. (1987) Submission of Data To Support Application for New Product Registration: Imperial Inc. 2,4-D 560 Lo Vol Ester Weed Killer. Transmittal of 1 study. 40132301 Currie, G. (1987) Imperial Inc. 2 4-D 560 Lo Vol Ester Weed Killer : Product Chemistry [Data: Tests Nos. 006-86-A; 006-86-B ]. Unpublished compilation prepared by Imperial I n c . 6 p . 40134700 Imperial I n c . (1987) Submission of Chemistry Data To Support the Application for New Product Registration of Land 0 'L a k e s , Inc . Butyl Ester 6 2,4-D Weed Killer. Transmittal of 1 study. & S > L l 3 REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 16 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM CPDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 2 MRID CITATION 40 13470 1 Currie, G. C1987) Land O'Lakes, Inc.: Butyl Ester 6 2,4-D Weed Killer: Product Chemistry. Unpublished compilation prepared by Imperial Inc. 6 p. 40 144200 Imperial Inc. (1987) Product Chemistry Data submitted To Support Butyl 4 2,4-D Weed Killer Registration. Transmittal of 1 study. 40144201 Currie, G. (1987) Land O 'Lakes, Inc.: Butyl Ester 4 2,4-D Weed Kil ler: ... storage Stability [Data]. Unpublished study prepared by Imperial Inc. 6 p. 40226700 Riverdale Chemical Co. (1987) Submission of Product Chemistry Data for Riverdale 25-3-3 Weed and Feed. Transmittal of 1 study. 40226701 Sawyer, R. (1987) Product Chemistry: Riverdale 25-3-3 Weed and Feed: Laboratory Project ID: 25-3-3 Weed and Feed. Unpublished study prepared by Riverdale Chemical Co. 18 p. 40232000 Riverdale Chemical Co. (1987) Submission of Product Chemistry Data for Inclusion in Registration File of Riverdale Fertilizer Plus 2.4- D. Transmittal of 1 study. 40232001 Sawyer, R. (1987) Product Chemistry: Riverdale Fertilizer Plus 2.4- D. Unpublished study prepared by Riverdale Chemical Co. 18 p. 40357700 Amvac Chemical Corp. (1987) Submission of Product Chemistry Studies for Technical Isopropyl Ester of 2,4-D. Transmittal of 3 studies. 40357702 Braden, G.; Feiler, W. (1987) Technical Isopropyl Ester of 2,4-D-Product Chemistry Analysis. Unpublished study prepared by Amvac Chemical Corp. 12 p. 40442100 Hoechst Celanese Corp. (1987) Submission of Data in Support of App lication for Registration of Tiller Herbicide. Transmittal of 12 studies . 40442 10 1 Albrecht, Dr.; Hommel, K.; Martinez, J.; et al. (1987) Product Identity, Composition, and Analytical Methods for Active Ingredients in Tiller Herbicide (HOE-03317 1 PH EC49 A 105) . Unpublished study prepared by Hoechst AG. 25 p. 2_0 REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 17 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 2 MRID CITATION 40442102 Albrecht, Dr. ; Rexer, K. (1987) Physical and Chemical Characteris tics of Tiller Herbicide (HOE 033171 + 2,4-D + MCPA). Unpub lished study prepared by Hoechst AG. 16 p. 40443300 Gilmore, Inc. (1987) Submission of Chemistry Data in Support of 2,4-D Isopropyl Ester. Transmittal of 1 study. 40443301 Collins, R. (1987) Product Chemistry: 2,4-D Isopropyl Ester: Labo ratory Project ID: 2,4-D ISOPROPYL ESTER. Unpublished study prepared by Gilmore, Inc. 11 p. 40475000 Platte Chemical Company (1987) Submission of Chemistry Data on Clean Crop 2,4-D Butyl Ester (EPA Reg. No. 34704-77) in Support of Dioxin/Furan Data Call-In. Transmittal of 1 study. 0475001 Allen, L.; Mahlburg, W.; Pomeroy, T. (1987) Clean Crop 2,4-D Butyl Ester ...: Product Chemistry Data: study Number 87-31A. Unpublished compilation. 57 p. 40475200 Platte Chemical Company (1987) Submission of Chemistry Data on Clean Crop Butyl 6 Ester Weed Killer (EPA Reg. No. 34704-127) in Support of Dioxin/Furan Data Call-In. Transmittal of 1 study 40475201 Allen, L.; Mahlburg, W.; Pomeroy, T. (1987) Clean Crop Butyl 6 Ester Weed Killer ...: Product Chemistry Data? Study Number 87-22A. Unpublished compilation. 16 p. 40475300 Platte Chemical Company (1987) Submission of Chemistry Data on Clean Crop Lou Vol 4 Ester Weed Killer (EPA Reg. No. 34704-124). Transmittal of 1 study. 4047530 1 Allen, L.; Mahlburg, W. (1987) Clean Crop Low Vol 4 Ester Weed Killer ...: Product Chemistry Data: Study Number 87-24A. Unpublished compilation. 19 p. 40475600 Platte Chemical Company (1987) Submission of Chemistry Data on Clean Crop 2,4-D Isooctyl Ester (EPA Reg. No. 34704-81) in Support of Dioxin/Furan Data Call-In. Transmittal of 1 study. ar>4ib REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 18 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 2 MRID CITATION 40475601 Allen, L.; Mahlburg, W.; Pomeroy, T. (1987) Clean Crop 2,4-D Isooctyl Ester ...: Product Chemistry Data: study Number 87-30A. Unpublished compilation. 53 p. 40475700 Platte Chemical Co. (1987) Submission of Chemistry Data in Support of Clean Crop Amine 4 2,4-D Weed Killer. Transmittal of 1 study. 40475701 Allen, W.; Mahlburg, W. (1987) Product Chemistry Data: Clean Crop Amine 4 2,4-D Weed Killer: Study No. 87-16A. Unpublished compi lation prepared by Transbas, Inc. Laboratory in cooperation with Platte Chemical Co. 12 p. 40530700 Monsanto Agricultural Co. (1988) Submission of Chemistry and Toxi city Data To Support the Registration of Nomix Broadleaf Herbi cide (MON-18744). Transmittal of 9 studies. 40530701 Berk, H. (1988) Volume 2- Product Chemistry to Support the Regis tration of Nomix Broadleaf Herbicide (MON-18744) (9.6% 2,4-D Iso-octyl Ester and 19.4% MCPP Iso-octyl Ester): Product Identity and Composition: Laboratory Project I.D. MSL-7518. Un published compilation prepared by Monsanto Co. 62 p. 40530702 Berk, H. (1988) Volume 3: Product Chemistry To Support the Regis tration of Nomix Broadleaf Herbicide (MON-18744) (9.6% 2,4-D Iso-octyl Ester and 19.4% MCPP Iso-octyl Ester): Analysis and Certification of Product Ingredients: Laboratory Project I.D. MSL-7519. Unpublished compilation prepared by Monsanto Co. 32 40530703 Berk, H. (1988) Volume 4: Product Chemistry To Support the Regis tration of Nomix Broadleaf Herbicide (MON-18744). (9.6% 2,4-D Iso-octyl Ester and 19.4% MCPP Iso-octyl Ester): Physical and Chemical Characteristics: Laboratory Project I.D. MSL-7520. Un published study prepared by Monsanto Co. 21 p. 40636600 Monsanto Agricultural Co. (1988) Submission of Product Chemistry Data To Support Nomix Registration . Transmittal of 1 study. 40636601 Armstrong, T. (1988) Application for Registration of Nomix Broad leaf Herbicide: Supplemental Submission: R.D. No. 868. Unpu blished study prepared by Monsanto Agricultural Co. 38 p. elO REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 19 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 2 MRID CITATION 40772100 Gilmore, Inc. (1988) Submission of Product Chemistry Data in Suppo rt of Registration of O v l a s . Transmittal of 1 study. 40772101 Fisher, R. (1988) Product Chemistry: Ovlas. Unpublished study pre pared by Gilmore, Inc. 4 p. 40791200 PBI/Gordon C o r p . (1988) Submission of Data To Support the Applica tion for Registration of Trimec 937 Herbicide: Product Chemistry and Toxicology Data. Transmittal of 7 studies. 40791201 Cahoy, R. (1988) Trimec 937-- Product Chemistry tDatal. Unpublished study prepared by PBI/Gordon Corp., Formulation Laboratory. 7 p 40911900 Dow Chemical U.S.A. (1988) Submission of Data in Response to 2,4-D/ Dibensa-p-dioxins Data Call-In: Product Chemistry Data. Trans mittal of 3 studies. 40911901 Gegel, B. (1987) 2,4-D Isooctyl (2- Et hylhaxel) Ester: Product Identity and Composition. Unpublished study prepared by Dow Chemical Co. 20 p. 40911902 Gegel, B. (1987) 2,4-D Isooctyl (2- Et hylhexyl) Ester: Product Iden tity and Composition. Unpublished study prepared by Dow Chemi cal C o . 20 p . 40911903 Gegel, B. (1987) 2,4,-D Butyl Esters: Product Identity and Composi tion. Unpublished study prepared by Dow Chemical Co. 20 p. 40998700 Rhone-Poulenc Ag Co. (1989) Submission of 2,4-D IOE Manufacturing Process Data. Transmittal o 1 study. 40998701 Snell, R. (1988) Technical 2,4-D Iso-octyl Ester Method of Manufac ture. Unpublished study prepared by Rhone-Poulenc Ag Co. 6 p. 41015000 Amvac Chemical Corp. (1989) Submission of Product Chemistry Data in Support of the Technical Isopropyl Ester of 2,4-D Registration Standard. Transmittal of 3 studies. 41015001 Braden, G.; Feiler, W. (1989) Technical Isopropyl Ester of 2,4-D: Product Chemistry Ingredients Identification. Unpublished study prepared by Amvac Chemical Corporation. 39 p. REPORT I D PDR20B01 RUN DATE! 11/26/93 PAGE: 20 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 2 MRID CITATION 41015002 Braden, G.; Feiler, W. (19891 Technical Isoproryl Ester of 2,4-D: Product Chemistry Analysis. Unpublished study prepared by Amvac Chemical Corp. 10 p. 41015003 Feiler, W.; Braden, G. (1989) Technical Isopropyl Ester of 2,4-D: Produst Chemistry: Physical and Chemical Properties. Unpublish ed study prepared by Amvac Chemical Corp. 15 p. 41049700 C h a s . H. Lilly Co. (1989) Submission of Data To Support Registra tion of Lilly/Miller Envy 2,4-D: Product Chemistry Data. Trans mittal of 1 study. 41049701 Klettke, M. (1989) Product Chemistry Data: Pesticide Assesment (...): Lilly/Miller Envy 2.4-D. Unpublished study prepared by Chas. H. Lilly Co. 42 p. 41055800 Dow Chemical Co. (1989) Submission of Data To Support Registration of 2,4-D Acid: Product Chemistry Data. Transmittal of 20 stu dies . 41055806 Dow Chemical Co. (1989) 2,4-D Isooctyl (2-Ethylhexyl) Ester: Product Identity and Composition. Unpublished study. 26 p. 41055807 Dow Chemical Co. (1989) 2,4-D Isooctyl (2-Ethylhexyl) Ester: Analy sis and Certification of Product Ingredients. Unpublished stu dy . 35 p . 41055808 Dow Chemical Co. (1989) 2,4-D Isooctyl (2-Ethylhexyl) Ester: physi cal and Chemical Characteristics. Unpublished study. 6 p. 41055818 Dow Chemical Co. (1989) 2,4-D Triisopropanolamine Salt-4: Product Identity and Composition. Unpublished study. 23 p. 41055819 Dow Chemical Co. (1989) 2,4-D Triisopropanolamine Salt-4: Analysis and Certification of Product Ingredients. Unpublished st u d y . 22 p. 41055820 Dow Chemical Co (1989) 2,4-D Triisopropanolamine Salt-4: Physical and Chemical Characteristics. Unpublished study. 6 p. 41206900 Agrolinz, Inc. (1989) Submission of Analytical Methods to Support Registration for 2 4-D Isopropyl Ester. Transmittal of 1 study. 5-0 REPORT IDs PDR20B01 RUH DATE 1 1/26/93 PAGE: 21 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 D PART 2 MRID CITATION 41206901 Fisher, J. (1989) Product Chemistry! Agrolinz Isopropyl 2,4-D Ester Technical: Analytical Methods. Unpublished study prepared by Agrolinz, Inc. 17 p. 41349000 Riverdale Chemical Co. (1990) Submission of Analytical Chemistry Data in Response to the Data Call-in Notice for Polyhalogenated Dibenzo-p-Dioxins/Dibenzofurans in 2,4-D Acid and Its Salts and Esters. Transmittal of 2 studies. 41349002 Fiene, J.; Mahlburg, W. (1989) Determination iia x v * -p-Dioxins and Dibenzofurans in 2,4-D Isooctyl Ester Technical: Lab Project Number: 90/2. Unpublished study prepared by Chem- serve Industries Service Ges.m.b.H. 325 p. 41431200 DowElanco (1990) Submission of Vapor Pressure Data in Support of 2.4- D Registration Standard. Transmittal of 1 study. 41431201 Chakrabarti, A. (1990) Vapor Pressure of the Triisopropanol Amine Salt of 2,4-Dichlorophenoxy Acetic Acid Measured by the KnudsenEffusion/Weight Loss Method: Lab Project Number: ML-AL 89-020234. Unpublished study prepared by Dou Chemical U.S A. 11 p. 41431300 DowElanco (1990) Submission of Vapor Pressure Data in Support of 2.4- D Registration Standard. Transmittal of 1 study. 41431301 Chadrabarti, A. (1989) Vapor Pressure of the Butoxyethyl Ester of (2,4-Dichlorophenoxy) Acetic Acid Measured by the Knudsen-Effusion/Weight Loss Method: Lab Project Number: ML-AL-89-020197. Unpublished study prepared by Dow Chemical U.S.A. 12 p. 41572000 DowElanco (1990) Submission of Product Chemistry Data in Support of Formula 40 Herbicide Amended Registration for Revised Formula tion. Transmittal of 1 study. 41572001 Schriber, C. (1990) Product Chemistry for Formula 40 Herbicide: Lab Project Number: XRM-5226. Unpublished study prepared by Dow Elanco . 28 p . 41647000 DowElanco (1990) Submission of Chemistry Data in Support of 2,4-D Reregistration Standard. Transmittal of 1 study. REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 22 ENVIRONMENTAL PROTECTION AGENCY .PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 2 MRID CITATION *4164700 1 Heimerl, J. (1990 ) Determination of the Octanol/Water Partition Coefficient of 2,4-D Butoxyethyl Ester (2,4-D BEE): Lab Project Number: ML-AL 90-080378. Unpublished study prepared by Dow Chemical USA. 22 p. *41 669500 DowElanco ( 1990 ) Submission of Product Chemistry Data to Support the Reregistration of the 2,4-Dichlorophenoxyacetic acid, butoxyethyl ester. Transmittal of 1 Study. *41669501 Moore, R. (1990) 2,4-Dichlorophenoxyacetic acid, butoxyethyl ester: Aqueous Solubility: Lab Project Number: 9585/F/02. Unpublished study prepared by Midwest Research Institute. 17 p. *41 695000 Rhone-Poulenc Ag Co. ( 1990 ) Submission of product chemistry and toxicity data to support the registration of Weedone LV-6 IOE Broadleaf Herbicide. Transmittal of 9 studies. *4169500 1 Scarborough, D. (1990 ) Weedone Brand LV-6 Herbicide Product Identi ty and Composition: Lab Project Number: AC-90-009. Unpublished study. 20 p . *41695002 Crownover, R. ( 1990) Product Chemistry: Weedone Brand LV-6 Herbicide-- Analysis and Certification of Ingredients: Lab Project Number AC-90-10: 40830. Unpublished study. 66 p. *41 6 9 5 0 0 3 Crownover, R. ( 1900 ) Product Chemistry: Weedone Brand LV-6 Herbi cide, Physical and Chemical Properties: Lab Project Number: AC90-011: 40832. Unpublished study prepared by Rhone-Poulenc Ag Co. 36 p . *41 6 97700 Rhone-Poulenc Ag Co. ( 1990 ) Submission of Physical and Chemical Characteristics Data. In Support Of Application for New Product Registration. Transmittal of 3 Studies. *4169770 1 Scarborough, D. ( 1990 ) Weedone Brand LV-4 Herbicide: Procuct Ident ity and Composition: Lab Project No: AC-90-006. Unpublished study prepared by Rhone-Poulenc Inc. 33 p.* *41697702 Crownover, R. ( 1990 ) Weedone Brand LV-4 Herbicide: Analysis and Ce rtification of Ingredients: Lab Project No: AC-90-007. Unpub lished study prepared by Rhone-Poulenc Inc. 66 p. ^0^30 REPORT I D PDR20B0 1 RUH DATE'. 11/26/93 PAGE: 23 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 2 MRID CITATION 41697703 Crownover, R. ( 1990 ) Weedone Brand LV-4 Herbicide-' Physical and Chemical Properties: Lab Project No: AC-90-008. Unpublished study prepared by Rhone-Poulenc Inc. 36 p. 41724200 Nufarm USA, Inc. (1990) Submission of product Chemistry Data in Response to the Data Call-in Notice for 2,4-D. Transmittal of 3 studies. 41724203 Landvoight, W.; Mahlburg, W. (1990) Determination of Halogenated Dibenso-p-Dioxins and Dibenzofurans in 2,4-D Isooctyl Ester by Method of Analysis 50288: Lab Project Number: 90-5. Unpublished study prepared by Chemserve Industries Service Ges.m.b.H. 423 P- 41968300 DowElanco (1991) Submission of Data To Support 2,4-D Reregistra tion: Product Chemistry Studies. Transmittal of 3 studies. 41968302 Helmer, D. (1987) Determination of the Water Solubility of 2,4dichlorophenoxy Acetic Acid, 2-ethylhexyl Ester: Lab Project No: ML -AL-87-70817. Unpublished study prepared by Dow Chemical USA. 13 p. 41968303 Schriber, C.; Tiszai, N. (1991) Chemical Stability of 2,4-D 2-Ethyl hexyl Ester: Lab Project Number: 90086. Unpublished study pre pared by DowElanco. 17 p. 41968400 DowElanco (1991) Submission of product chemistry data in support of reregistration of 2,4-D. Transmittal of 3 studies. 41968402 Schriber, C.; Kraft, N. (1991) Solubility of 2,4-Dichlorophenoxyac etic Acid, Triisopropanloamine Salt in Water, pH Buffers and Various Organic Solvents: Lab Project Number: 90048. Unpublish ed study prepared by DowElanco. 17 p. 41968403 Schriber, C. (1991) Chemical Stability of 2,4-D Triisopropanolamine Salt Solution: Lab Project Number: 90091. Unpublished study prepared by DowElanco. 17 p. 42050600 A.H. Marks and Co., Ltd (1991) Submission of product chemistry data for 2,4-DB Acid in response to E P A 's 1987 Dioxin/Furan data call-in for 2,4-D. Transmittal of 7 studies. REPORT ID: PD R 20B 01 RUN DATE: 11/26/93 PAGE: 24 f ENVIRONMENTAL PROTECTION AGENC PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 2 MRID CITATION 42050601 Landvoigt, W. ( 1990 ) Analysis' o f .DD/DF in 2,4-DB Acid for A.H. M a rks: Lab Project Number: 2954379 S= 2954382 S: 2954381 S. Unpu blished study prepared by Chemserv Industrie Service Ges.m.b.H. 76 p. 42050602 Landvoigt, W. (1990) Analysis of DD/DF in 2,4-DB Acid for A.H. Ma rks: Lab Project Number: 2954379. Unpublished study prepared by Chemserv Industrie Service G e s . m.b.H. 58 p. 42050603 Landvoigt, W. (1990) Analysis of DD/DF in 2,4-DB Acid for A.H. M a rks: Lab Project Number: 2954380. Unpublished study prepared by Chemserv Industrie Service Ges. m.b.H. 62 p. 42050604 Landvoigt, W. (1990) Analysis of DD/DF in 2,4-DB Acid for A.H. Ma rks: Lab Project Number: 2954382. Unpublished study prepared by Chemserv Industrie Service Ges. m.b.H. 62 p. 42050605 Landvoigt, W. (1990) Analysis of DD/DF in 2,4-DB Acid for A.H. M a rks: Lab Project Number: 2954383. Unpublished study prepared by Chemserv Industrie Service Ges. m.b.H. 63 p. 42050606 Landvoigt, W. (1990) Analysis of DD/DF in 2,4-DB Acid for A.H. M a rks: Lab Project Number: 2954384. Unpublished study prepared by Chemserv Industrie Service Ges. m.b.H. 65 p. 42050607 Landvoigt, W. (1990) Analysis of DD/DF in 2,4-DB Acid for A. H. Ma rks: Lab Project Number: 2954385. Unpublished study prepared by Chemserv Industrie Service Ges. m.b.H. 65 p. 421 16700 Amvac Chemical Corp. (1991) Submission of product chemistry data to support the reregistration of 2,4-D (Isopropyl Ester). Transmittal of 2 studies. 42116701 Fieler, W . (1991) Analysis and Certification of Product Ingredients for 2,4-D Isopropyl Ester I. Unpublished study prepared by Amvac Chemical Corp. 7 p. 42116702 Feiler, W. (1991) Technical Isopropyl Ester of 2,4-D-- Product Chemistry: Physical and Chemical Properties. Unpublished study prepared by Amvac Chemical Co. 4 p. o i* REPORT ID*. PDR20B01 RUN DATE'- 11/26/93 PAGE: 25 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SESUENCE BIBLIOGRAPHY 24 D PART 2 MRID CITATION 42138500 PBI/Gordon (1991) Submission of product chemistry and toxicity data to support the registration of EH 1068 and EH 1073 Trimec E s t e r s . Transmittal of 8 studies. 42138501 Arm bruster, J. (1991) EH 1068 Trimec Ester: Product Identity, Compo sition and Certification of Limits. Unpublished study prepared PBI/Gordon Corp. 8 p. 42138502 Hart, J. (1991) EH 1068 Trimec Ester: Chemical and Physical Proper ties: Lab Project Number: PBG-01. Unpublished study prepared by DARTEC, Inc. 60 p. 42138600 PBI/Gordon Corp. (1991) Submission of product chemistry and toxicity data to support the registration of EH 1068 and EH 1073 Trimec Esters. Transmittal of 8 studies. -42 138601 Armbruster, J. (1991) EH 1073 Trimec Ester Product Identity, Compo sition and Certification of Ingredient Limits. Unpublished study prepared by PBI/Gordon Corp. 7 p. 42138602 Hart, J. (1991) EH 1073 Trimec Ester Chemical and Physical Proper ties: L ab Project Number: PBG-02. Unpublished study prepared by DARTEC, Inc. 59 p. 42188600 Amvac Chemical Corp. (1992) Submission of product chemistry data in support of reregistration of 2,4-D Isopropyl Ester Technical. Transmittal of 1 study. 42188601 Feiler, W. (1991) Technical Isopropyl Ester of 2,4-D: Product Chemistry Ingredients Identification. Unpublished study prepared by Amvac Chemical Corp. 41 p. 42328500 DowElanco (1992) Submission of Product Chemistry data in support of reregistration for 2,4-D 2-EHE. Transmittal of 1 study. 42328501 Potter, R. (1990) 2,4-D Ethylhexyl Ester: Solubility in Industrial Water: Lab Project Number: ES-DR-0019-1208-8. Unpublished study prepared by Analytical Chemistry Laboratory, Dow Chemical Co. 16 p. ^ 33 REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 26 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 2 MRID CITATION 42420700 PBI Gordon C o r p . (1992) Submission of supplmentary product chemistry data to support the registration of EH 1068 and 1073 Trimec Ester. Transmittal of 2 studies. 4242070 1 Savage, J. (1992) Supplemental Report: e h 1068 Trimec Ester: Lab Project Number: PBG-01. Unpublished study prepared by Dartec Labs, Inc. 39 p. 42420702 Savage, J. (1992) Supplemental Report: EH 1073 Trimec Ester: Lab Project Number: PBG-02. Unpublished study prepared by Dartec Labs, Inc. 39 p. 42448800 Rhone-Poulenc Ag Co. (1992) Submission of product chemistry and toxicity data in support of the registration of Weedone No-Sol 4 Broadleaf Herbicide. Transmittal of 9 studies. -+2448801 Crounover, R. (1992) Weedone LV-4 EW = Product Identity and Composition: Lab Project Number: AC-92-004: 41192. Unpublished study prepared by Rhone-Poulenc Ag C o . 61 p. 42448802 Louder, J. (1992) Weedone LV-4 EW: Product Chemistry: Series 62--Analysis and Certification of Product Ingredients: Lab Project Number: AC-91-020: 41196. Unpublished study prepared by Rhone-Poulenc Ag C o . 41 p. 42448803 Louder, J. (1992 ) Weedone LV-4 EW : Product Chemistry: Series 63-- Physical and Chemical Characteristics: Lab Project Number: AC-91-021: 41244. Unpublished study prepared by Rhone-Poulenc Ag C o . 22 p . 42468800 Platte Chemical Co. (1992) Submittal of product chemistry, irritation and toxicity data in support of Shotgun Flouable Herbicide reregistration. Tramsmittal of 10 studies. 42468801 Mahlburg, W. (1992) Product Chemistry Data for Shotgun Flouable Herbicide: identity, Composition, Analysis and Certification of Ingredients I: Lab Project Number-' 92-73A. Unpublished study prepared by Platte Chemical Co. 38 p. 9,0 ^ 3 ^ REPORT ID: PDR20B01 RUH DATE: 11/26/93 PAGE: 27 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 2 MRID CITATION 42468802 Herold, A. C1990) Shotgun Flowable Herbicide Product Chemistry Data: ^Multiple Physical and Chemical Characteristics!: Lab Project Number: PLT-31: 92-74A. Unpublished study prepared Dartec Inc. 56 p. by 42468803 Nunnally, M. (1992 Shotgun Flowable Herbicide Product Chemistry Data: ^Storage stability!: Lab Project Number: PLT-31: 92-82A . Unpublished study prepared by Dartec Inc. 29 p. 42487900 DowElanco (1992) Submission of product chemistry data to support 2,4-D BEE registration standard. Transmittal of 1 study. 42487901 Schriber, C. (1992) Chemical Stability of 2, 4-Dichlorophenoxyacetic Acid, Butoxyethyl Project Number: 90090. Unpublished study DowElanco. 16 p. Ester Solution: prepared by Lab i 42744200 Rhone-Poulenc AG Co. (1993) Submission of Product Chemistry and Toxicity Data in Support of Registration for 2,4-D 2-EHE Gel Broadleaf Herbicide. Transmittal of 6 Studies. 42744201 Siemann, L. (1993) 2,4-D 2-EHE Gel End-Use Product Chemistry: Lab Project Number: 3164. Unpublished study prepared by Midwest Research Institute. 77 p. 42796200 DowElanco (1993) Submission of product chemistry data in support of the registration standard for 2,4-D 2HE and 2,4-D BEE. Transmittal of 1 study. 42796201 Murphy, G. (1993) Response to Letter Written by Lois A. Rossi (10/5/92) Subject: Product Chemistry Review for Dow Technicals: 62719-24, 62719-25, 62719-26, 62719-33 for 2,4-D Acid, IOE and BEE: Lab Project Number: GM052893C. Unpublished study prepared by DowElanco. 9 p. 42798200 DowElanco (1993) Submission of product chemistry data to support the registration of 2,4-D TIPA. Transmittal of 1 study. 42798201 Murphy, G. (1993) Product Chemistry Review for DowElanco 2,4-D TIPA FI: Lab Project Number: GM052993A. Unpublished study prepared by DowElanco. 4 p. <5.6^ 3-5 REPORT ID: PDR20B01 RUH DATE : 11/26/93 PAGE: 28 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 D PART 2 MRID CITATION 42830900 DouElanco (1993) Submission of product chemistry data in support of registration for 2,4-D BEE. Transmittal of 1 s t u d y . 42830901 Murphy, G. (1993) Determination of Boiling Point and Solubility of 2,4-Dichlorophenoxyacetic Acid Butoxyethyl Ester (2,4-D BEE) Technical Grade Active Ingredient (T G A I ): Lab Project Number: FOR93057. Unpublished study prepared by Formulation Science and Technology Lab. DouElanco. 17 p. 42831100 DouElanco (1993) Submission of product chemistry data in support of registration for 2,4-D 2 - E H E . Transmittal of 1 study. 42831101 Murphy, G. (1993) Determination of Boiling Point and Solubility of 2,4-Dichlorophenoxyacetic Acid 2-Ethylhexyl Ester (2,4-D 2-EHE) Technical Grade of Active Ingredient (TGAI): Lab Project Number: FOR93055. Unpublished study prepared by Formulation Science and Technology Lab, DouElanco. 17 p. I (o REPORT ID: PDR20B01 RUN DATE: 11/26/93 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 DB SEARCH TERMS: CHEMICALS: 0 3 0 8 0 1 OR 0 3 0 8 0 4 OR 0 3 0 8 1 9 OR 0 3 0 8 5 3 OR 0 3 0 8 5 6 OR 0 3 0 8 6 3 AND SUBJECT: PRODUCT CHEMISTRY AND SUBMITTER: ALL AND SUBMISSION DATE: ALL AND LA B -ID : ALL AND DOCUMENT TYPES: ALL SELECTED STUDIES REGARDLESS OF DOCUMENT TYPE AND ENTRY DATE: ALL NUMBER OF S T U D IE S : 106 iir<ID SEQUENCE B I B L I O G R A P H Y ---------------- NUMBER OF C O P IE S : AUTHOR SEQUENCE BIBLIOG R APH Y -------- NUMBER OF C O P IE S : SUBMITTER SEQUENCE B IB LIO G R APH Y - NUMBER OF C O P IE S : GUIDELINE SEQUENCE BIBLIOGRAPHY SUMMARY FORMAT ----------------------------------- NUMBER OF C O P IES: EXPANDED FORMAT -------------------------------- NUMBER OF C O P IE S : PAPER S I Z E : 8 1 / 2 BY 11 INCH PAPER 1 0 0 0 0 REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 1 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM CPDMS) MRID SE2UENCE BIBLIOGRAPHY 24 DB MRID CITATION 00004725 Stanley, C.W. C1966) Derivatization of pesticide-related acids and phenols for gas chromatographic determination. Journal of Agri cultural and Food Chemistry 14C3 ) *321-32 3. CAlso 0Inunpublished submission received Sep 12, 1968 under 8F0676; submitted by Dow Chemical U.S.A., Midland, Mich.; CDL 0 9298 0-A2 ) 00004784 Chipman Chemical Company, Incorporated. (1967) Summary of Available Acute Toxicity Data on a Bromoxynil octanoate/MCPA Isoocty Ester Formulation as Compared with Bromoxynil and MCPA= SR/3/67. (Un published study received Mar 10, 1967 under 359-601; submitted by Rhone-Poulenc, Inc., Monmouth Junction, N.J.; C D L :023320- D) 000359 14 Woolson, E.A.; Thomas, R.F.; Ensor, P.D.J. ( 1972 ) ^Without title I. Journal of Agricultural and Food Chemistry 20(2):351-354. (Also i 0I n 0unpublished submission received Sep 24, 1970 under 1E1 046 ; submitted by U.S. Dept, of the Army, Office of the Chief of En gineers, Washington, D.C.; C D L :096474-D) 00050542 Gannon, R.W. (1957) Letter sent to R.O. White dated Jan 2, 1957 ^Toxicity of the gamma Bytyric acids I. (Unpublished study received Jan 2, 1957 under 264 - E X - 7 ; prepared by American Chemi cal Paint Co., submitted by Union Carbide Agricultural Products Co., Ambler, Pa.; C D L :10 2 6 8 2 - A ) 00078273 Ting, J.J.S. (1978) Letter sent to T.T. Rushing dated Dec 12, 1978: Compatibility study: L o r o x - ( R ) n and Lorox-'(R)o 4L with other herbicides and/or liquid fertilisers. (Unpublished study re ceived Mar 27, 1979 under 352-391; submitted by E.I. du Pont de Nemours Co., Wilmington, Del.; C D L :237890 - C ) 00078452 Marchio, J.L.; Spurlock, O.L. (1981) Letter sent to Stan Harrison dated Jan 20, 1981 ^Analyses for ni tr os a m i n e I . (Unpublished study, including letter dated Sep 18, 1980 from J. Kruzynski to S.L. Harrison, received Jun 24, 1981 under 264-47; submitted by Union Carbide Agricultural Products Co., Inc., Ambler, Pa.; CDL: 245309-A) 00094409 Snow, E.A.; Bouw, R.M. (1974) Letter sent to E.E. Chambers dated Jun 28, 1974: Compatibility of tank mixed enide 50W with 2,4-DB. (Unpublished study received Aug 1, 1974 under 1023-23; submitted by Upjohn Co., Kalamazoo, Mich.; C D L :005407-B) Q-Q^3 REPORT IDs PDR20B01 RUH DATE: 11/26/93 PAGE: 2 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM CPDMS) MRID SEQUENCE BIBLIOGRAPHY 24 DB MRID CITATION 00105875 Rhodia, Inc. (1978) Results of N-Nitroso Contaminant Analysis. (Unpublished study received Jun 26, 1978 under 359-677; submitted by Rho ne-Poulenc, Inc., Monmouth Junction, NJ ; C D L : 237357-A) 00115130 Uniroyal Chemical (1982 ) ^Chemical Study: RESCUE I. (Compilation; unpublished study received Sep 15, 1982 under 400-166; CDL: 248367-A) 00124089 Union Carbide Agricultural Products Co., Inc. (1982) ^Chemical Study: Amine 2,4,5-T|. (Compilation; unpublished study received Dec 21 , 1982 under 264-86 ; C D L :2491 17 - A ) 00125618 Rhodia, Inc. (1970) The Name, Chemical Identity, and Composition of the Pesticide Chemical: 2,4-DBl. (Compilation; unpublished study received Dec 16 , 1970 under 1F1089 ; C D L :093401- B ) 00151535 A.H. Marks and Co., Ltd. (1985) Marks Technical Butoxyethanol Ester of 2.4--D B : Butyoxy Et hyl-4-(2,4-dichorophenoxy)B u t y r a te . Unpub lished compilation. 14 p. 00153216 A. H. Marks Co. Ltd. (1985) Marks 2,4-DB Technical Acid: 4-(2,4-Dichlorophenoxy) Butyric Acid: Information for EPA Regis tration :[Product Chemistry Data]. Unpublished compilation. 16 p 00156716 Aceto Chemical Co., Inc. (1982) Chemistry of Technical Grade 2,4 - DB: Aceto DB - 175. Unpublished compilation. 43 p. 00158916 Union Carbide Agricultural Products Co. (19??) Manufacturing Pro cess for 2,4-DB Technical Acid. Unpublished compilation. 7 p. 00158917 Union Carbide Agricultural Products Co. (19??) Manufacturing Pro cess for 2,4-DB Butoxy Ethanol Ester. Unpublished study. 4 p. 00158918 A. H. Marks (19??) Analysis and Certification of Product Ingre dient: [2,4-DB Ester]. Unpublished study. 2 p. 00158919 A. H. Marks (19??) 2,4-DB Butoxy Ethanol Ester: Physical and Chem ical Properties. Unpublished study. 1 p. REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 3 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SE2UENCE BIBLIOGRAPHY 24 DB MRID CITATION 05003559 Collier, R.H.; Grimes, G.S. C1974) Determination of chlorophenoxy acids in formulations by gas-liquid chromatography of their trimethylsilyl derivatives. Journal of the Association of Official Analytical Chemists 57(4)=78 1-784. 05005846 Zweig, G.; Sherma, J. (1972) 2,4-Dichlorophenoxyacetic acid. Pages 630-635,0I n 0Analytical Methods for Pesticides and Plant Growth Regulators. Vol. VI: Gas Chromatographic Analysis. New York: Academic Press. 40125500 PBI/Gordon Corp. (1987) Submission of Product Chemistry Data in Support of Application for Registration of Trimec 901. Trans mittal of 2 studies. 40125501 Cahoy, R. (1987) Trimec 901--Product Chemmistry. Unpublished compilation prepared by PBI/Gordon Corp. Formulation Laboratory. 7 p. 40125502 Goff, U. (1987) Trimec 901 Liquid Weed Feed 20-0-0: Formal Report of Analysis for N-Nitroso Compounds: Laboratory Project No. 5450-2631. Unpublished study prepared by Thermedics Inc. 16 p. 40295900 Union Carbide Agricultural Products Co., Inc. (1987) Submission of Chemistry Data in Support of 2,4-DB Technical Acid. Transmittal of 3 studies. 40295901 A.H. Marks and C o . (1987) A.H. Marks 2,4-DB Technical Acid: Product Identity and Composition: (Supplemental Data for May 1985 Re port): Document No. 1. Unpublished compilation. 11 p. 40295902 A.H. Marks and Co. (1987) A.H. Marks 2,4-DB Technical Acid: Analy sis and Certification of Product Ingredients: (Supplemental Data for May 1985 Report): Document No. 2. Unpublished study. 32 p. 40295903 A.H. Marks and Co. (1987) A.H. Marks 2,4-DB Technical Acid: Physi cal and Chemical Properties: (Supplemental Data for May 1985 Re port): Document No. 3. Unpublished study. 3 p. 40709200 AH Marks Co. Ltd. (1988) Submission of Chemistry Data in Support of Marks DB Technical Acid. Transmittal of 1 study. REPORT ID : PDR20B01 RUH DATES 11/26/93 PAGE: 4 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM CPDMS) MRID SEUENCE BIBLIOGRAPHY 24 DB MRID CITATION 40755600 Gilmore, Inc. (1988) Submission of Chemistry Data to Support the Registration for Buxatone 2E. Transmittal of 1 study. 40755601 Fisher, R. ( 1988) Product Chemistry (Buxatone 2 E I . Unpublished study pre pared by Gilmore, Inc. 4 P . 40774100 H.R. McLane, Inc. (1988) Submission of Product Chemistry to Support the Regis tration for Turf Pride 0-10-10 Lawn Food with Tria m i n e . Transmittal of 1 study. 40774101 Mclane, H. (1988) Product Specific Data: Turf Prode 10-10-10 Lawn Food with Triamine. Unpublished study prepared by Howard Ferti liser C o . 4 p . 40817900 Aceto Chemical Co., Inc. (1988) Submission of Chemistry Data in Support of 4-(2,4-Dichlorophenoxy butyric acid) dimethylamine salt. Transmittal of 1 study. 40817901 Baldi, A. (1987) 2,4-DB 175 ...; 4-(2,4-Dichlorophenoxy butyric acid dimethylamine salt.: Product Chemistry. Unpublished study prepared by Laboratory of the Government Chemist. 46 p. 40977800 Cedar Chemical Corp. (1989) Submission of Chemistry Data in Support of 2,4-DB Reregistration Standard. Transmittal of 6 studies. 40977801 Bellet, E. (1989?) Product Chemistry for Butoxone 200: ^Typical Physical Properties I. Unpublished study prepared by Cedar Chem ical Corp. 6 p. 40977802 Bellet, E. (1989?) Product Chemistry for Butoxone Ester: (Typical Physical Properties I. Unpublished study prepared by Cedar Chem ical Corp. 6 p . 40977803 Bellet, E . (1989?) Product Che mistry for Butoxone SB : (Typical Phy- sical Propertie s I Unpubli shed study prepared by Ceder Chemical Corp . 6 p. 40977804 Bellet, E . (1989?) P roduct Che mistry for 2,4-DB I .0 .E. Technical(Typic al Physic al Propertie s I. Unpublished study prepared by Cedar Chemical Co r p . 6 p . . H -H I REPORT ID-' PDR20B01 RUH DATE: 11/26/93 PAGE: 5 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 DB MRID CITATION 40977805 Bellet, E. ( 1989?) Product Chemistry for 2,4-DB Acid Technical: Typical Physical Properties!. Unpublished study prepared by Cedar Chemical C o r p . 6 p. 40977806 Bellet, E. (1989?) Product Chemistry for B u t o x o n e : ^Typical Physi cal Properties!. Unpublished study prepared by Cedar Chemical Corp. 6 p . 41 148200 2.4- DB Task Force (1989) Submission of Product Chemistry Data in Support of 2,4-DB Registration Standard. Transmittal of 1 study. 41148201 Hardwick, F. (1988) Product Chemistry for Marks DB Technical Acid. Unpublished study prepared by A H Marks Co. Limited. 24 p. 1337500 Aceto Agricultural Chemicals Corp. (1989) Submission of Data in Support of Data Call-in Notice for Analytical Chemistry Data on Polyhalogenated Dibenso-p-dioxins/Dibenzofurans in 2,4-Dichlorophenoxybutyric Acid and Its Salts and Esters (2,4-DB). Trans mittal of 1 study. 41337501 Baldi, A. (1989) Determination of Dioxins and Dibenzofurans in Chlorophenoxy Alkanoic Acids: Protocol and Preliminary Analysis. Unpublished study prepared by Aceto Agricultural Chemicals Corp. 13 p. 41374900 2.4- DB Task Force (1990) Submission of Chemistry Data in Support of 2,4-DB Registration Standard List A. Transmittal of 1 study. 41374901 Pesselman, R. (1989) Octanol/Water Partition Coefficient Determina tion of 2,4-DB Acid: Final Report:, Lab Project Number: HLA 600 1397. Unpublished study prepared by Hazleton Laboratories Ameri ca, Inc. 44 p. 41381400 2.4- DB Task Force (1990) Submission of Product Chemistry Data to Support the 2,4-DB Registration Standard. Transmittal of 1 study. 41381401 Hardwick, F. (1988) Product Chemistry for Marks DB Technical Acid. Unpublished study prepared by A.H. Marks Co., Ltd. 24 p. REPORT ID: PDR20B01 RUN DATE : 11/26/93 PAGE: 6 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SESUENCE BIBLIOGRAPHY 24 DB MRID CITATION 41402200 2,4-DB Task Force (1990) Submission of Product Chemistry Data in Support of the 2,4-DB Registration Standard. Transmittal of 16 studies. 41402201 Pesselman, R. (1989) Munsell Color Determination of 2,4-DB Acid: Lab Project Number: HLA 6001-391. Unpublished study prepared by Hazleton Laboratories America, Inc. 20 p. 41402202 Pesselman, R.; Semann, T. (1989) Physical State Determination of 2.4- DB Acid: Lab Project Number? HLA 6001-402. Unpublished stu dy prepared by Hazleton Laboratories America, Inc. 19 p. 41402203 Pesselman, R. (1989) Odor Determination of 2,4-DB Acid: Lab Project Number: HLA 6001-392. Unpublished study prepared by Hazleton Laboratories America, Inc. 22 p. -,1 4 0 2 2 0 4 Pesselman, R.; August, J. (1989) Melting Point/Melting Range Deter mination of 2,4-DB Acid: Lab Project Number: HLA 6001-394. Unp ublished study prepared by Hazleton Laboratories America, Inc. 22 p . 41402205 Pesselman, R. (1989) Solubility Determination of 2,4-DB Acid: Lab Project Number: HLA 6001-396. Unpublished study prepared by Hazleton Laboratories America, Inc. 52 p. 41402206 Pesselman, R. (1989) Vapor Pressure Determination of 2,4-DB Acid: Lab Project Number: HLA 6001-406. Unpublished study prepared by Hazleton Laboratories America, Inc. 33 p. 41402207 Pesselman, R. (1989) Dissociation Constant Determination of 2,4-DB Acid: Lab Project Number: HLA 6001-408. Unpublished study prep ared by Hazleton Laboratories America, Inc. 33 p. 41402208 Pesselman, R. ; Woosencraft, J. (1989) pH Value Determination of 2.4- DB Acid: Lab Project Number: HLA 6001-410. Unpublished stu dy prepared by Hazleton Laboratories America, Inc. 23 p. 41402209 Pesselman, R. (1989) Stability Determination of 2,4-DB Acid: Lab Project Number: HLA 6001-404. Unpublished study prepared by Hazleton Laboratories America, Inc. 26 p. Ao^<-i3 REPORT ID: PDR20B01 RUN DATE : 11/26/93 PAGE: 7 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 DB MRID CITATION 41402210 Pesselman, R. (1989) Physical State Determination of 2,4-DB Dimethylamine Salt: Lab Project Number: HLA 6001-403. Unpublished st udy prepared by Hazleton Laboratories America, Inc. 20 p. 41402211 Pesselman, R. (1989) Odor Determination of 2,4-DB Dimethylamine Sa lt: Lab Project Number: HLA 6001-393. Unpublished study prepar ed by Hazleton Laboratories America, Inc. 22 p. 41402212 Pesselman, R.; August, J. (1989) Boiling Point/Boiling Range Deter mination of 2,4-DB Dimethylamine Salt: Lab Project Number: HLA 6001-395. Unpublished study prepared by Hazleton Laboratories America, Inc. 24 p. 41402213 Pesselman, R. (1989) Solubility Determinaion of 2,4-DB Dimethylami ne Salt: Lab Project Number: HLA 6001-399. Unpublished study prepared by Hazleton Laboratories America, Inc. 41 p. 41402214 Woosencraft, J.; Pesselman, R. (1989) Dissociation Constant Determ ination of 2,4-DB Dimethylamine Salt: Lab Project Number: HLA 6001-409. Unpublished study prepared by Hazleton Laboratories America, Inc. 28 p. 41402215 Pesselman, R. (1989) pH Value Determination of 2,4-DB Dimethylamine Salt: Lab Project Number: HLA 6001-401. Unpublished study prep ared by Hazleton Laboratories America, Inc. 25 p. 41402216 Pesselman, R. ; Woosencraft, J. (1989) Stability Determination of 2,4-DB Dimethylamine Salt: Lab Project Number: HLA 6001-405. Unpublished study prepared by Hazleton Laboratories America, Inc. 26 p . 41460400 2,4-DB Task Force (1990) Submission of Product Chemistry Data in Support of the 2,4-DB Registration Standard. Transmittal of 1 study. 41460401 Pesselman, R. (1989) Munsell Color Determination of 2,4-DB, Dimeth ylamine Salt: Lab Project Number: 6001-398. Unpublished study prepared by Hazleton Laboratories America, Inc. 20 p. 41479700 <3,4-DB Task Force (1990 ) Submission of Product Chemistry and Photolysis Data to Support the Reregistration of 2,4-DB. Transmittal of 2 s t u d i e s . REPORT ID: PDR20B01 RUH DATE: 11/26/93 PAGE: 8 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 DB MRID CITATION 41479701 Pesselman, R. (1989) Octanol/Water Partition Coefficient Determina tion of 2,4-DB Acid: Final Report: Lab Project I.D.: HLA 6001-397. Unpublished study prepared by Hazleton Laboratories America, Inc. 44 p. 41517000 A .H . Marks (1990) Submission of Product Chemistry Data in Support of Registration of Marks DB Technical Acid. Transmittal of 4 studies. 41517001 Pesselman, R. (1989) Vapor Pesselman Determination of 2,4-DB Acid: Lab Project Number: 6001-406. Unpublished study prepared by Hazleton Laboratories America, Inc. 33 p. 41517002 Pesselman, R. (1989) Dissociation Constant Determination of 2,4-DB Acid: Lab Project Number: 6001-408. Unpublished study prepared by Hazleton Laboratories America, Inc. 26 p. 41517003 Pesselman, R. (1989) Octanol/Water Partition Coefficient Determina tion of 2,4-DB Acid: Lab Project Number: 6001-397. Unpublished study prepared by Hazleton Laboratories America, Inc. 44 p. 41517004 Pesselman, R. ( 1989 ) Stability Determination of 2,4-DB Acid-* Lab Project Number: 6001-404. Unpublished study prepared by Hazle ton Laboratories America, Inc. 26 p. 41582900 2.4- DB Task Force (1990) Submission of product chemistry data to support the registration standard for 2,4-DB. Transmittal of 2 studies. 41582901 Pesselman, R. (1990) Determination of Boiling Point/Boiling Range of 2,4-DB Acid: Lab Project Number: HLA 6001-488. Unpublished study prepared by Hazleton Labs America, Inc. 23 p. 41582902 Pesselman, R. (1990) Density/Specific Gravity Determination of 2,4-DB Acid? Lab Project Number: 6001-489. Unpublished study prepared by Hazleton Labs America, Inc. 23 p. 41765500 2.4- D, MCPA Task Force (1991) Submission of Chemistry Data in Supp ort of 2,4-DB Acid Data Call-in. Transmittal of 1 study. REPORT ID: PDR2 0B01 RUN DATE: 11/26/93 PAGE: 9 ENVIRONMENTAL PROTECTION .AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 DB MRID CITATION 41765501 Landvoigt, W. (1990) Determination of Dioxins and Benzofurans in 2, 4-DB-Acid by G C / M S : Lab Project Number: AGRO USA0989. Unpub lished study prepared by Chemserv Industrie Service Ges.m.b.H. 394 p. 42045500 Agrolinz, Inc. (1991) Submission of product chemsitry data in response to a data call-in notice for analytical data on polyhalogenated dibenso-p-dioxins/dibenzofurans in 2,4-D acid and it's salts and esters. Transmittal of 1 study. 42045501 Landvoigt, W. (1990) Determination of Dioxins and Benzofurans in 2,4-D-Acid by GC/MS: Lab Project Number: AGRO USA0989. Unpubli shed study prepared by Chemserv Industrie Service Ges.m.b.H. 473 p. 2065300 A .H . Marks Co., Ltd. (1991) Submission of Data in Response to Dioxin/Furan Data Call-in for 2,4-DB: Product Chemistry Studies. Transmittal of 8 studies. 42065301 Langvoigt, W. (1990) Calibration File Using TM1 to TM10: Product Chemistry: Lab Project Number: MARKS/0689. Unpublished study prepared by Chemserv Industrie Service Ges.m.b.H. 34 p. 42065302 Landvoigt, W. (1990) Analysis of DD/DF in 2,4-DB Acid for A. H. Mar ks ^Product Chemistryl: Lab Project Number: KNR/2954379/.S: KNR/2 954382/S: KN R/ 295 43 81 /S . Unpublished study prepared by Chemserv Industrie Service Ges.m.b.H. 76 p. 42065303 Langvoigt, W. (1990) Analysis of DD/DF in 2,4-DB Acid for A .H . Marks ^Product Chemistryl : Lab Project Number: K N R . 2954379. Unpublished study prepared by Chemserv Industrie Service Ges.m.b.H. 58 p. '42065304 Landvoigt, W. (1990) Analysis of DD/DF in 2,4-DB Acid for A .H . Marks ^Product Chemistryl : Lab Project Number: KNR. 2954380. Unpublished study prepared by ChemServ Industrie Service Ges.m.b.H. 62 p. 42065305 Landvoigt, W. (1990) Analysis Marks ^Product Chemistryl: Unpublished study prepared Ges.m.H. 62 p. of DD/DF in Lab Project by Chemserv 2,4-DB Acid for A .H . Number: KNR. 2954382. Industrie Service <5.04 4-k REPORT ID: PDR20B01 RUN DATE: 11x26/93 PAGE: 10 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SESUENCE BIBLIOGRAPHY 24 DB MRID CITATION 42065306 Landvoigt, W. (1990) Analysis of DD/DF in 2,4-DB Acid for A.H. Marks $Product Chemistry I: Lab Project Number: KNR/2954383. Unpublished study prepared by Chemserv Industrie Service Ges.m.b.H. 63 p. 42065307 Landvoigt, W . (1990) Analysis of DD/DF in 2,4-DB Acid for A.H. Marks: Lab Project Number * K N R . 2954384. Unpublished study pre pared by Chemserv Industrie Service Ges.m.b.H. 65 p. 42065308 Landvoigt, W. (1990) Analysis of DD/DF in 2,4-DB Acid for A.H. Marks ^Product Chemistry I Lab Project Number: KNR. 2954385. Unpublished study prepared by Chemserv Industrie Service Ges.m.b.H. 65 p. 42120500 Cedar Chemical Corp. (1991) Submission of product chemistry data to support the me-too product registration for Butoxone 7450. Transmittal of 1 study. 42120501 Bernard, M. (1991) Manufacturing and Chemistry Data for Butoxone 7450. Unpublished study prepared by Cedar Chemical Corp. 8 p 42558000 A H Marks Co Ltd (1992) Submission of product chemistry data in support of registration standard for 2,4-DP. Transmittal of 1 study. 42558001 Varcoe, F. (1992) Analysis of Polychlorinated Dibenzo-p-Dioxins and Polychlorinated Dibensofurans in R (+)2-(2,4-dichlorophenoxy)propionic acid: Final Report: Lab Project Number: 21918R: Unpublished study prepared by Triangle Laboratories, Inc. 1171 p. 42569300 2,4-DB Task Force (1992) Submission of product chemistry to support registration standard of 2,4-DB. Transmittal of 4 studies. 42569301 McDaniel, R.; Weiler, D. (1987) Vapor Pressure Determination of 2,4-Dichlorophenoxybutyric Acid dimethylamine Salt: Lab Project Number: 8710006. Unpublished study prepared by Rhone-Poulenc Inc 8 p . <20447 REPORT ID-' PDR20B01 RUN DATE : 11/26/93 PAGE: 11 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID.SE2UENCE BIBLIOGRAPHY 24 DB MRID CITATION 42569302 McDaniel, R.; Weiler, D. (1987) Design and Validation of High Flow Apparatus for Vapor Pressure Determination: 2,4-Dichlorophenoxybutyric Acid dimethylamine Salt: Lab Project Number*- 8710020. Unpublished study prepared by Rhone-Poulenc Inc 20 p . 42569303 Helfant, L.; Lowder, J. (1987) Concentration of 2,4-Dichlorophenoxybutyric Acid dimethylamine Salt in Deionized Water: Lab Project Number: 87080. Unpublished study prepared by Rhone-Poulenc Inc. 9 p. 42569304 Rhone-Poulenc Inc. (1988) Mass Transfer Considerations in the Use of the Gas Saturation Method for Vapor Pressure Determination-- 2,4-Dichlorophenoxybutyric Acid dimethylamine Salt: the Attainment of Test Compound Saturation of the Carrier Gas at High Flow Rates. Unpublished study prepared by Rhone-Poulenc Inc. 22 p. 42626500 Cedar Chemical Corp. (1993) Submission of product chemistry data in support of the data call-in for 2,4-DB. Transmittal of 1 study. 42626501 Bernard, M. comp. (1989) Product Chemistry: Manufacturing and Analytical Data for 2,4-DB Isooctyl Ester. Unpublished compilation prepared by Cedar Chemical Corp. 12 p. 42626700 Cedar Chemical Corp. (1993) Submission of product chemistry data in support of the registration of 2,4-DB Amine Concentrate. Transmittal of 1 study. 42626701 Bernard, M. comp. (1992) Product Chemistry: Manufacturing and Analytical Data for 2,4-DB Amine Concentrate. Unpublished compilation prepared by Cedar Chemical Corp. 11 p. 42741500 2,4-DB Task Force (1993) Submission of Product Chemistry Data in Support of Registration Standard for 2,4-DB Dimethyl Amine Salt (DMAS). Transmittal of 1 Study. 42741501 An dr ew s, K. (1993) Dissociation of 2,4-DB Dimethyl Amine Salt (DMAS ) in Water: Lab Project Number: SC920205. Unpublished study prepared by Battelle Columbus Op e r a t i o n s . 60 p . Lh'~ir^ REPORT ID: PDR20B01 RUH DATE: 11/26/93 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (FDMS) MRID SEUENCE BIBLIOGRAPHY 24 DP SEARCH TERMS: CHEMICALS: 031401 OR 031419 OR 031453 OR 031463 AND SUBJECT: PRODUCT CHEMISTRY AND SUBMITTER: ALL AND SUBMISSION DATE: ALL AND LAB-ID: ALL AND DOCUMENT TYPES: ALL SELECTED STUDIES REGARDLESS OF DOCUMENT TYPE AND ENTRY DATE: ALL NUMBER OF STUDIES: 164 'ID SEQUENCE BIBLIOGRAPHY ---rtdTHOR SEQUENCE BIBLIOGRAPHY -- SUBMITTER SEQUENCE BIBLIOGRAPHY GUIDELINE SEQUENCE BIBLIOGRAPHY SUMMARY FORMAT -------------EXPANDED FORMAT --------- --- NUMBER OF COPIES : NUMBER OF COPIES : NUMBER OF COPIES : NUMBER OF COPIES : NUMBER OF COPIES : PAPER SIZE: 8 1/2 BY 11 INCH PAPER 1 0 0 0 0 REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 1 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 DP MRID CITATION 00029069 Bishop, J.R. (1980) Analysis of 2,4-DP I. (Unpublished study re ceived Jan 15, 1980 under 264-307; prepared in cooperation with Fallek-Lankro C o r p ., submitted by Union Carbide Agricultural Products Co., Ambler, Pa.; C D L :241869 - A ) 00029070 Jones, C. (1979) Determination of the 2,4-DP Specific Isomer Con tent in the Technical Acid and Formulations of 2,4-DP Salts and 2,4-DP Esters. Method no. F-10-11-79 dated Dec 10, 1979. (Unpublished study received Jan 15, 1980 under 264-307; p re pared by Fallek-Lankro Corp., submitted by Union Carbide A g ricultural Products Co., Ambler, Pa.; C D L :241869 - B ) 00029464 Union Carbide Agricultural Products Company, Incorporated (19??) 2.4- DP Product Specifications. (Unpublished study received Mar 10, 1980 under 264-231; C D L :241984 - A ) J0029465 Union Carbide Agricultural Products Company, Incorporated (1980) 2.4- DP Product Manufacture. (Unpublished study received Mar 10, 1980 under 264-231; C D L :2419 8 4 - B ) 00029466 Fallek-Lankro Corporation (1980) Typical Analysis: Product: 2,4-DP Butoxye thy les ter . (Unpublished study received Mar 10, 1980 under 264-231; submitted by Union Carbide Agricultural Products Co., Ambler, Pa.; C D L :2419 8 4 - D ) 00029467 Jones, C. (1979) Determination of the 2,4-DP Specific Isomer Con tent in the Technical Acid and Formulations of 2,4-DP Salts and 2.4- DP Esters. Method no. F-10-11-79 dated Dec 10, 1979. (Un published study received Mar 10, 1980 under 264-231; prepared by Fallek-Lankro Corp., submitted by Union Carbide Agricultural Products Co., Ambler, Pa.; C D L :241984 - E ) 00035914 Woolson, E.A.; Thomas, R.F.; Ensor, P.D.J. ( 1972 ) Without title I. Journal of Agricultural and Food Chemistry 20(2):351-354. (Also # Inunpublished submission received Sep 24, 1970 under 1E1046; submitted by U.S. Dept, of the Army, Office of the Chief of En gineers, Washington, D.C.; C D L :096474 -D) 00046185 U.S. Office of Science and Technology, Panel on Herbicides (1970) Report on 2,4-D. (Unpublished study; C D L :119429-A ) REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 2 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 DP MRID CITATION 00047255 Dow Chemical U.S.A. (1976) General Chemistry Items Requested. published study received Nov 22, 1976 under 464-530; CDL: 226965-A) (Un 00047256 McLachlan, R.; McLaughlin, E.L., eds . (1976) Analytical Method: Dichlorprop, Butoxyethanol ester. Method no. 21001a dated Oct 5, 1976. (Unpublished study received Nov 22, 1976 under 464-530; submitted by Dow Chemical U . S . A . , Midland, Mich.; C D L :226965-B) 00053746 Akzo Zout Chemie Nederland, B.V. (1973) Determination of Total Acid in Phenoxy acetic acid or Phenoxy propionic acid and Their Salts by Direct Potentiometrie Titration. Method 248.1 dated Feb 12, 1973. (Unpublished study received Aug 15, 1977 under 38117-2; CDL:231352-B) '0053748 Akzo Zout Chemie Nederland, B.V. (1973) Spectrophotometric Deter mination of Chlorophenol in Phenoxy acetic acid or Phenoxy pro pionic acid and Their Salts with 4-Amino a n t i p y r i n e . Method no. 259.3 dated Feb 12, 1973. (Unpublished study received Aug 15, 1977 under 38117-2; C D L :231352 - D ) 00067484 Vertac Chemical Corporation (19??) Sodium Chloride Content of the Phenoxy Acids. Undated method VJ-MS-4. (Unpublished study re ceived Jan 7, 1981 under 39511-84; C D L :244051- D ) 00067500 Vertac Chemical Corporation (19??) Chlorophenoxyalkanoic Acids-Loss on Drying. Undated method VJ-MS-2. (Unpublished study re ceived Jan 7, 1981 under 39511-84; C D L :244051- E ) 00068008 Buser, H.R. (1976) Determination of 2,3,7,8-TCDD in TPH Samples; GC-MS Analysis of Fraction 2 of TPH Samples; prepared by Swiss Federal Research Station for Fruit Growing, Viticulture and Horticulture, Switzerland. Unpublished study; 10 p. 000826 12 Allen, A. (1981) Formal Report of Analysis for N-Nitroso Compounds: Report No. 5450-2586. (Unpublished study received May 15, 1981 under 2217-648; prepared by Thermo Electron C o r p ., submitted by PBI-Gordon Corp., Kansas City, K a n s .; C D L :245094 - A ) 00088574 PBI/Gordon Corporation (1981) Confidential Statement of Formula: G o r d o n 's Brush Killer 801. (Unpublished study received Jul 15, 1981 under 2217-624; C D L :24553 7- M) ZUd H I REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 3 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 DP MRID CITATION 00088575 PBI/Gordon Corporation (1981) Confidential Statement of Formula: Gordon's Brush Killer 800. (Unpublished study received Jul 15, 1981 under 2217-624; C D L :245537-2) 00102904 Union Carbide Agricultural Products Co., Inc. (1979) Assay Proce dure for Weedone Super BK-32. (Unpublished study received Apr 24, 1979 under 264-307; C D L :23 8208-A) 00104673 Cantor, L. (1982) Formal Report of Analysis for N-Nitroso Com pounds: Report No. 5450-3341. (Unpublished study received Feb 2, 1982 under 22 17-662 ; prepared by Thermo Electron C o r p ., submitted by PBI-Gordon Corp., Kansas City, K a n s .; C D L :246710 - A ) 00107931 Union Carbide Agricultural Products Co., Inc. (1979) Assay Pro cedure for Weedone 20 Weed and Feed. (Unpublished study r e ceived Apr 24, 1979 under 264-309; C D L :238210 - A ) 00109215 A.H. Marks Co., Ltd. (19??) (Chemistry of 2,4-DP/Butoxy Ethanol Ester!. (Compilation; unpublished study received May 26, 1982; Mar 19, 1982 under 15440-6; C D L :247621- A ) 00110435 PBI-Gordon Corp. (19??) Information in Respect of 2,4-DP Technical Acid Ester. (Unpublished study received Aug 17, 1982 under 2217-652; CDL:248119-A) 00116497 A.H. Marks Co. Ltd. (19??) (Chemistry Data on 2,4-DP Butoxy Ethanol Ester I. (Compilation; unpublished study received May 26, 1982 under 15440-6; C D L :247621- A ) 00119032 Helfant, L.; Oestreicher, S. (1982) Temperature Stability of AXF1182: Weedone CB Woody Plant Herbicide: Project No. 858F60, File No. 30763. (Unpublished study received Nov 26, 1982 under 264393; submitted by Union Carbide Agricultural Products Co., Inc., Research Triangle Park, NC; C D L :24 89 56 -B ) 00123280 Dow Chemical U.S.A. (1978) (Chemical Study: Picloraml. (Compila tion; unpublished study received Dec 9, 1982 under 464-502; CDL: 248983-A) REPORT ID : PDR20B01 RUN DATE: 11/26/93 PAGE: 4 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 DP MRID CITATION 00132990 Chemie Lins AG ( 1983) $Study--Chemistry : 2,4-Dichlorophenoxypro pionic Acidl. (Compilation; unpublished study received Dec 12, 1983 under 2217-652; submitted by PBI-Gordon Corp., Kansas City, MO; CDL:251948-A) 00145102 Kowite, W.; Helfant, L. (1984) Product Chemistry for Weedone CB Woody Plant Herbicide: Laboratory Project No. 856F10. Unpublis hed study prepared by Union Carbide Agriculture Products Co., Inc 8 p . 00146263 Kowite, W. (1985) Letter sent to W. Davis dated Jun 4, 1985. Weedone DPC Amine Method of Manufacture. Prepared by Union Carbide Agricultural Products Co., Inc. 8 p. 00152164 Kemisk Vaerk Koge A/S (1985) [Product Chemistry Data for KVK Herbatox - DP ((+-)-2-2,4-dichlorophenoxy)propionic acid)]. Unpub lished compilation. 47 p. 00153852 Riverdale Chemical Company (1985) [Product Chemistry Data with Reports of Analysis of Riverdale Triamine Weed and Feed 25-3-3]. Unpublished study. 43 p. 00153855 Hazleton Laboratories America, Inc. (1985) Report of Analysis: Dimethylamine salt of 2,4-D, 2,4-DP, MCPA, Weed Feed 25-3-3. Unpublished study. 6 p. 00153856 Riverdale Chemical Company (1985) [Product Chemistry Data with Reports of Analyses of Riverdale 3-Way Weed and Feed ]. Unpub lished study. 45 p. 00158451 Riverdale Chemical Co. (1986) [Product Chemistry of Riverdale 1D + 1DP Low Vol ]. Unpublished compilation. 56 p. 00158500 Dow Chemical U.S.A. (1976) General Chemistry Items Reguested [for Dichlorprop ]. Unpublished compilation. 8 p. 00158501 A.H. Marks Co,Ltd. (19??) [Product Chemistry for 2-(2,4-Dichlorophenoxy) propionic Acid]. Unpublished compilation. 8 p. 00158583 Riverdale Chemical Co. (1986) [Chemical Composition of Riverdale 1D + 1DP Low Vol]. Unpublished compilation. 11 p. REPORT ID? PDR20B01 RUN DATE: 11/26/93 PAGE: 5 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 DP MRID CITATION 00158774 Riverdale Chemical Co. (1986) (Product Chemistry Data for Riverdale Weedestroy Tri-Ester]. Unpublished compilation. 66 p. 00165544 A H Marks (19??) [Product Chemistry Data for 2,4-DP Technical Acid]. Unpublished compilation. 8 p. 05004844 Cessna, A.J.; Grover, R. (1978) Spectrophotometric determination of dissociation constants of selected acidic herbicides. Journal of Agricultural and Food Chemistry 26(1):289-292. 40008500 Riverdale Chemical Co. (1986) Package is submitted for pesticide registration: Data on chemistry and toxicology. Compilation of 8 studies. 40008501 Sawyer, R. (1986) Product Chemistry: Riverdale Triamine II Liquid Weed and Feed: Triple A Liquid Weed and Feed. Unpublished com pilation prepared by Riverdale Chemical Co. 19 p. 40008508 Sawyer, R. (1986) Nitrosamine Analysis: Riverdale Triamine II Liquid Weed and Feed. Unpublished study prepared by Haselton Laboratories America. 7 p. 40046300 Riverdale Chemical Co. (1986) Application for Pesticide Registra tion: Riverdale Weedestroy Tri-Ester II: Product Chemistry and Acute Toxicity Studies. Compilation of 7 studies. 40046301 Sawyer, R. (1986) Product Chemistry: Riverdale Weedestroy TriEster II. Unpublished study prepared by Riverdale Chemical C o . 19 p . 40059200 Riverdale Chemical Co. (1987) Product Chemistry and Toxicological Data for Riverdale Weedestroy Triamine. Compilation of 7 stu dies . 40059201 Sawyer, R. (1986) Product Chemistry: Riverdale Weedestroy Triamine II. Unpublished study prepared by Riverdale Chemical Co. 19 p. 40077100 Riverdale Chemical Co. (1987) Product Chemistry of Weedestroy Triamine II. Compilation of 1 study. REPORT ID: PDR20B01 RUH DATE : 11/26/93 PAGE: 6 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM CPDMS) MRID SE2UENCE BIBLIOGRAPHY 24 DP MRID CITATION 4007710 1 Stevens, J. (1987) Nitrosamine Analysis: Weedestroy Triamine II: Project No.: 5450-2556. Unpublished study prepared by Thermedics Inc. 13 p. 40095900 Riverdale Chemical Co. (1987) Application for Pesticide Registra tion on Riverdale Triamine Premium Liquid Weed and Feed. Trans mittal of 1 study. 40095901 Sawyer, R. (1987) Product Chemistry [Data]: Riverdale Triamine Premium Liquid Weed and Feed. Unpublished study prepared by Riverdale Chemical Co. 19 p. 40129500 Riverdale Chemical Co. (1987) Submission of Product Chemistry Data in Support of Application for Registration of Riverdale Triamine 3-way Lawn Weed Killer. Transmittal of 1 study. 40129501 Sawyer, R. (1987) Product Chemistry: Triamine 3-way Lawn Weed Killer. Unpublished compilation prepared by Riverdale Chemical Co. 19 p. 40180300 Riverdale Chemical Co. (1987) Submission of Data To Support the Application for Riverdale Triamine II Premium Liquid Weed and Feed Registration: Product Chemistry Study. Transmittal of 1 study. 40180301 Sawyer, R. (1987) Product Chemistry [Data for]: Riverdale Triamine II Premium Liquid Weed and Feed. Unpublished study prepared by Riverdale Chemical Co. 19 p. 40201300 Riverdale Chemical Co. (1987) Submission of Data To Support the Application for Registration of Riverdale Triamine Premium 6666 Liquid Weed and Feed: Product Chemistry Study. Transmittal of 1 study. 40201301 Sawyer, R. (1987) Product Chemistry: Riverdale Triamine Premium 6666 Liquid Weed and Feed. Unpublished compilation prepared by Riverdale Chemical Co. 19 p. 40214800 Riverdale Chemical Co. (1987) Submission of Product Chemistry and Toxicity Data in Support of Application for Registration of Riverside Triamine II Lawn Weed Killer. Transmittal of 1 study. REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 7 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 DP MRID CITATION 402 1480 1 Sawyer, R. (1987) Product Chemistry: Riverdale Triamine II Lawn Weed Killer. Unpublished compilation prepared by Riverdale Chemical Co. 19 p. 40218800 Riverdale Chemical Co. (1987) Submission of Product Chemistry Data To Support the Application for Pesticide Registration of River dale Triamine II Premium 75 Liquid Weed and Feed. Transmittal of 1 study. 40218801 Sawyer, R. (1987) Product Chemistry: Riverdale Triamine II Premium 75 Liquid Weed and Feed. Unpublished study prepared by River dale Chemical Co. 19 p. 40221200 Riverdale Chemical Co. (1987) Submission of Data To Support the Ap pl i ca ti o n'for Pesticide Registration of Riverdale Sweet Six teen Weed and Feed with Triamine II. Transmittal of 7 studies. 40221201 Sawyer, R. (1987) Product Chemistry: Riverdale Sweet Sixteen Weed and Feed with Triamine II. Unpublished compilation prepared by Riverdale Chemical Co. 19 p. 40228600 Riverdale Chemical Co. (1987) Submission of Chemistry Data in Sup port of Riverdale 2D + 2DP Amine. Transmittal of 2 studies. 40228601 Sawyer, R. (1986) Product Chemistry: Riverdale 2 D + 2 DP Amine. Unpublished study prepared by Riverdale Chemical Co. 19 p. 40228602 Feit, M. (1986) Nitrosamine Analysis: Riverdale 2 D + 2 DP Amine: Laboratory Project No. 61104023. Unpublished study prepared by Hazleton Laboratories America. 8 p. 40236400 Riverdale Chemical Co. (1987) Submission of Product Chemistry Data To Support the Registration of Riverdale Triamine II Premium Liquid Weed and Feed. Transmittal of 1 study. 40241300 Riverdale Chemical Co. (1987) Submission of Product Chemistry Data in Support of Application for Registration of Riverdale Tri amine Granular Weed Killer. Transmittal of 1 study. 40241301 Sawyer, R. (1987) Product Chemistry: Riverdale Triamine Granular Weed Killer. Unpublished compilation prepared by Riverdale Chemical Co. 19 p. O REPORT ID: PDR20B0 1 RUH DATE: 11/26/93 PAGE: 8 r ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM CPDMS) MRID SEUENCE BIBLIOGRAPHY 24 DP MRID CITATION 40250800 Riverdale Chemical Co. (1987) Submission of Product Chemistry Data To Support the Application for the Registration of Riverdale Triamine II Weed and Feed. Transmittal of 1 study. 40250801 Sawyer, R. (1987) Product Chemistry: Riverdale Triamine II Weed and Feed. Unpublished compilation prepared by Riverdale Chemical Co. 18 p. 40305700 PBI/Gordon Corp. (1987) Submission of Product Chemistry Toxicity Data To Support the Registration of DMDP 897. Transmittal of 8 studies. 40305701 Cahoy, R. (1987) DMDP 897--Product Chemistry [Data]. Unpublished study prepared by PBI/Gordon Corp. 7 p. '0305702 Goff, U. (1987) DMDP 897: Formal Report of Analysis for N-Nitroso Compounds: Laboratory Project ID: 5450-2712. Unpublished study prepared by Thermedics Inc. 16 p. 40307300 PBI/Gordon Corp. (1987) Submission of Toxicology Data to Support the Registration of DMDP 898 Liquid Weed Feed. Transmittal of 8 studies. 40307301 Cahoy, R. (1987) DMDP 898 Liquid Weed Feed - Product Chemistry. Unpublished study prepared by PBI/Gordon Corp. 7 p. 40394600 Riverdale Chemical Co. (1987) Submission of Product Chemistry Data To Support the Application for Registration of Riverdale 3-Way Weed and Feed with Triamine II. Transmittal of 1 study. 40394601 Sa w y e r , R. (1987 Product Chemistry: Riverdale 3-Way Weed and Feed with Triamine II. Unpublished compilation prepared by Riverdale Chemical C o . 18 p . 40481 100 Riverdale Chemical Company (1988) Submission of Chemistry Data on Riverdale Triamine II Granular Weed Killer in Support of Registration Application. Transmittal of 1 study. 40481101 Sawyer, R. (1987) Product Chemistry: Riverdale Triamine II Granular Weed Killer: Laboratory Project ID Triamine II Granular Weed Killer. Unpublished study prepared by Riverdale Chemical C o m p a n y . 18 p. aoq-s'v REPORT ID: 24 DP MRID PDR20B01 RUN DATE: PAGE: ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY CITATION 11/26/93 9 40655900 H.R. McLane, Inc. (1988) Submission of Product Chemistry Data to Support the Registration for New Products Containing Triamine. Transmittal of 1 study. 40655901 McLane, H. (1988) Product Specific Data: Turfic VII Weed & Feed with Triamine: Laboratory Project ID EPA/HRM/47056-Q.P C 1 . Unpublished study prepared by H.R. McLane, Inc. 4 p. 40656000 H.R. McLane, Inc. (1988) Submission of Product Chemistry Data to Support the Registration of Turfic VI Weed Feed with Triamine. Transmittal of 1 study. 40656001 McLane, H. (1988) Product Specific Data, Turfic VI Weed Feed with Triamine: Laboratory Project ID EPA/HRM/47056/ P/PC1. Unpub lished study prepared by H.R. McLane, Inc. 4 p. -tO6 5 6 100 H.R. McLane, Inc. (1988) Submission of Product Chemistry Data to Support the Registration of Turfic V Weed Feed with Triamine. Transmittal of 1 study. 40656101 McLane, H. (1988) Product Specific Data: Turfic V Weed Feed with Triamine: Laboratory Project ID EPA/ HR M/ 47 05 6- 0.P C 1 . Unpub lished study prepared by H.R. McLane, Inc. 4 p. 40656200 H.R. McLane, Inc. (1988) Submission of Product Chemistry Data to Support the Registration of Turfic IV Weed Feed with Triamine, Transmittal of 1 study. 40656201 McLane, H. (1988) Product Specific Data-' Turfic IV Weed Feed with Triamine: Laboratory Project ID EPA/HRM/47056 - N .PC 1. Unpub lished study prepared by H.R. McLane, Inc. 4 p. 40656300 H.R. McLane, Inc. (1988) Submission of Chemistry Data to Support the New Registration for Turfic III Weed Feed with Triamine. Transmittal of 1 study. 40656301 McLane, H. (1988) Product Specific Data: Turfic III Weed Feed with Triamine. Unpublished study prepared by H. R. McLane, Inc. 4 P. REPORT ID: PDR20B01 RUN DATE : 11/26/93 PAGE: 10 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SESUENCE BIBLIOGRAPHY 24 DP 1RID CITATION 40656400 H.R. McLane, Inc. (1988) Submission of Chemistry Data to Support the New Registration for Turfic II Weed Feed with Triamine. Transmittal of 1 study. 40656401 McLane, H. (1988) Product Specific Data: Turfic II Weed Feed with Triamine. Unpublished study prepared by H. R. McLane, Inc. 4 P 40755500 Gilmore, Inc. (1988) Submission of Product Chemistry to Support the Registration for Visko-Rhap LV 2D-1DP. Transmittal of 1 study. 40755501 Fisher, R. (1988) Product Chemistry $Visko-Rhap LV 2D-1DPI. Un published study prepared by Gilmore, Inc. 4 p. 0791200 I PBI/Gordon Corp. (1988) Submission of Data To Support the Applica tion for Registration of Trimec 937 Herbicide: Product Chemistry and Toxicology Data. Transmittal of 7 studies. 40791201 Cahoy, R. (1988) Trimec 937-- Product Chemistry $Datal. Unpublished study prepared by PBI/Gordon Corp., Formulation Laboratory. 7 p 40955600 BASF Corp. (1988) Submission of Data To Support the Application for Registration of Dic hl or pr op -p : Toxicology Data. Transmittal of 9 studies. 40955601 Dattilo, D. (1988) Product Chemistry Data for Dic hl or pr op -p : Docu ment No. BASF: 88/5108. Unpublished study prepared by BASF A g . 46 p. 40956600 BASF Corp. (1988) Submission of Chemistry and Toxicity Data in Sup port of Dichlorprop. Transmittal of 7 studies. 40956601 Dattilo, D. (1988) Product Chemistry Data for Dichlorprop: Regi stration Document No. BASF: 8 8 5072. Unpublished compilation prepared by BASF Aktiengesellschaft. 88 p. 41058000 C h a s . H. Lilly Co. (1989) Submission of Data To Support Registra tion of Lilly/Miller Ultragreen Weed Feed with Trimec Herbi cide: Product Chemistry Data. Transmittal of 1 study. ^ 0 4-5^ REPORT ID: PDR20B0 1 RUH DATE: 11/26/93 PAGE: 11 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SE2UENCE BIBLIOGRAPHY 24 DP MRID CITATION 41058001 Klettke, M. (1989) Lilly/Miller Ultragreen Weed Feed with Trimec Herbicide: Product Chemistry Data. Unpublished study prepared by C h a s . H. Lilly Co. 37 p. 41065500 Master Nursery's Association (1989) Resubmission of Data To Support Registration of 49'er Weed Control and Lawn Fertiliser 25-5-3: Product Chemistry Data. Transmittal of 1 study. 41065501 Strong, L. (1989) Product Chemistry Data: 49'er Weed Control and Lawn Fertiliser 25-5-3. Unpublished study prepared by Master Nurserymen's Association. 56 p. 41079900 Rhone-Poulenc Ag Co. (1989) Submission of Data To Support Registra tion of 2,4-DP Technical: Product Chemistry Data. Transmittal of 1 s t u d y . 41079901 Buddle, G. (1988) Product Chemistry Data Requirements Under EPA Pesticide Assessment Guidelines Dated October 1982 2-(2,4-Dichlorophenoxy)propionic Acid 2,4-DP Technical Acid. Unpublished study prepared by May Baker Ltd. 149 p. 41082300 BASF Corp. (1989) Submission of Product Chemistry Data to Support the Registration of 2,4-DP-P Acid Tech. Transmittal of 1 study. 4108230 1 Ohnsorge (1989) Analysis of Dichloroprop-P for Polychlorinated Dibenzo Dioxins (PCDD's) and Polychlorinated Dibensofurans (PCDF's): Registration Document No. BASF 89/5039. Unpublished study prepared by BASF Aktiengesellschaft. 35 p. 41082302 Dattilo, D. (1989) Product Chemistry Data for Dichlorp r o p - P : Regis tration Document No. 89/5040. Unpublished study prepared by BASF Aktiengesellschaft. 10 p. 41088100 Rhone-Poulenc Ag Co. (1989) Submission of Manufacturing Process Data in Support of Technical 2,4-DP and Technical MCPA Registra tion Standard. Transmittal of 1 study. 41088101 Beale, R. (1989) Method of Manufacture for 2,4-DP IOE Technical and Process Flow Diagram for 2,4-DP and MCPA Acid Technical. Unpub lished Study Prepared by Rhone-Poulenc Ltd. 7 p. REPORT ID : PDR20B01 RUN DATE: 11/26/93 PAGE-' 12 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 DP MRID CITATION 41140100 A .H . Marks and Co., Ltd. (1989) Submission of Data To Support Registration of Product Containing 2-(2,4-dichlorophenoxy) pro pionic Acid (2,4-DP): Product Chemistry Data. Transmittal of 1 study. 41140101 Hardwick, F. (1989) Product Chemistry for Marks 2,4DP Technical Acid. Unpublished study prepared by A. H. Marks & Co., Ltd. 26 p. 41318300 2,4-DP 1988 Task Force (1989) Submission of Chemistry Data in Support of 2,4-DP Registration Standard. Transmittal of 1 study. 41318301 Buddle, G.; Fitsmaurice, M.; Patel, P.; et a l . (1989) Herbicides: Phenoxyalkanoic Acids: 2,4-DP: Analytical Examination of 5 Batches of 2,4-DP Technical, intended as components of the TPH Committee Composite Sample: Lab Project Number: ACD/GCB/SSK/ 5502. Unpublished study prepared by Rhone-Poulenc A g . 51 p. 41478700 Riverdale Chemical Co. (1990) Submission of Product Chemistry and Toxicological Data to Support the Registration of Riverdale Dri-Tri Amine. Transmittal of 8 studies. 41478701 Sawyer, R. (1990) Product Chemistry: Riverdale Weedestroy (R) DriTri Amine. Unpublished study prepared by Riverdale Chemical Co. 2 0 p. 41478708 Stevens, J. (1990) Nitrosamine Analysis: Riverdale Dri-Tri Amine: Lab Project Number: 5450-6195. Unpublished study prepared by Thermedics, Inc. 17 p. 41527500 Rhone- Poulenc Ag Company (1990) Submission of product chemistry data in response to a dioxin/dibenzofuran data call-in. Transmittal of 1 study. 41527501 Scarborough, D. (1990) DPD-Amine Herbicide: Product Identity and Composition: Lab Project Number: 40781. Unpublished study pre pared by Rhone-Poulenc A g . Co. 64 p. 41560600 Howard Johnson's Enterprises, Inc. (1990) Submission of product chemistry data to support the registration of "...Weed and Feed" containing MCPA. Transmittal of 1 study. ' X O '4 M REPORT ID: PDR20B01 RUN DATE: 11/26/93 PAGE: 13 r ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY 24 d p MRID CITATION 41560601 Sawyer, R. C1990) Product Chemistry: Howard Johnson's Enterprises, Inc. All Seasons Sprayable Weed and Feed: Lab Project Number: 32802-45. Unpublished study prepared by Riverdale Chemical Co. 16 p. 41855700 Rhone-Poulenc A g ., Ltd. (19911 Submission of product chemistry data to support the registration standard for 2,4-D. Transmittal of 1 study. 41855701 Buddie, G.; Mills, E. (1991) 2,4-Dichlorophenoxyacetic Acid (2,4-D) Physical and Chemical Characteristics: Density and Stability (Supplement to MRID 41599401): Lab Project Number: p-91-016. Unpublished study prepared by Rhone-Poulenc A g ., Ltd. 27 p. 41960900 A.H. Marks and Co. (1991) Submission of product chemistry data in response to EPA's June 1987 dioxin/furan data call-in for 2,4DP. Transmittal of 8 studies. 41960901 Landvoigt, W. (1990) Analysis of DD/DF in 2,4-DP Acid for A. H. Ma rks: Lab Project Number: KNR. 2954372 S: K N R . 2954375 S: KNR 295374 S. Unpublished study prepared by Chemserv Industrie Serv ice Ges.m.b.H. 82 p. 41960902 Landvoigt, W. (1990) Analysis of DD/DF in 2,4-DP Acid for A. H. Ma rks: Lab Project Number: KNR. 2954372. Unpublished study prepa red by Chemserv Industrie Service Ges.m.b.H. 58 p. 41960903 Landvoigt, W. (1990) Analysis of DD/DF in 2,4-DP Acid for A. H. Ma rks: Lab Project Number: KNR. 2954373. Unpublished study prepa red by Chemserv Industrie Service Ges.m.b.H. 60 p. 41960904 Landvoigt, W. (1990) Analysis of DD/DF in 2,4-DP Acid for A. H. Ma rks: Lab Project Number: KNR. 29554374. Unpublished study prep ared by Chemserv Industrie Service Ges.m.b.H. 55 p. 41960905 Landvoigt, W. ( 1990 ) Analysis of DD/DF in 2,4-DP Acid or. A. H. Ma rks: Lab Project Number: KNR. 2954375. Unpublished study prepa red by Chemserv Industrie Service Ges.m.b.H. 56 p. 41960906 Landvoigt, W. (1990) Analysis of DD/DF in 2,4-DP Acid for A. H. Ma rks: Lab Project Number: KNR. 2954376. Unpublished study prepa red by Chemserv Industrie Service Ges.m.b.H. 53 p. '2J *4 REPORT ID: 24 DP PIRID PDR20B0 1 RUN DATE: PAGE : ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEQUENCE BIBLIOGRAPHY CITATION 11/26/93 14 41960907 Landvoigt, W. C 19901 Analysis of DD/DF in 2,4-DP Acid fo r A. H. Marks: Lab Project Number: KNR. 2954377. Unpublished s tudy prepared by Chemserv Industrie Service Ges.m.b.H. 52 p. 41960908 Landvoigt, W. (1990) Analysis of DD/DF in 2,4-DP Acid fo r A . H . Marks: Lab Project Number: KNR. 2954378. Unpublished s tudy prepared by Chemserv Industrie Service Ges.m.b.H. 56 p. 42105500 Riverdale Chemical Co. (1991) Submission of Data To Supp ort Registration of Riverdale Dissolve: Product Chemistry Transmittal of 1 study. 42105501 Sawyer, R. (1990) Product Chemistry: Riverdale Dissolve: Lab Project Number: DRI/TRI/TRIAMINE/W/S. Unpublished study prepared by Riverdale Chemical Co. 8 p. 42138500 PBI/Gordon (1991) Submission of product chemistry and toxicity data to support the registration of EH 1068 and EH 1073 Trimec E s t e r s . Transmittal of 8 studies. 42138501 Armbruster, J. (1991) EH 1068 Trimec Ester: Product Identity, Compo sition and Certification of Limits. Unpublished study prepared PBI/Gordon Corp. 8 p. 42138502 Hart, J. (1991) EH 1068 Trimec Ester: Chemical and Physical Proper ties: Lab Project Number: PBG-01. Unpublished study prepared by DARTEC, Inc. 60 p. 42138600 PBI/Gordon Corp. (1991) Submission of product chemistry and toxicity data to support the registration of EH 1068 and EH 1073 Trimec Esters. Transmittal of 8 studies. 42138601 Armbruster, J. (1991) EH 1073 Trimec Ester Product Identity, Compo sition and Certification of Ingredient Limits. Unpublished study prepared by PBI/Gordon Corp. 7 p. 42138602 Hart, J. (1991) EH 1073 Trimec Ester Chemical and Physical Properties: Lab Project Number: PBG-02. Unpublished study prepared by DARTEC, Inc. 59 p. Q j O t-/ C r-3 REPORT ID: PDR20B01 RUH DATE: 11/26/93 PAGE: 15 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (FDMS) MRID SE2UENCE BIBLIOGRAPHY 24 DP MRID CITATION 42149600 Riverdale Chemical Co. ( 19 9 2 ) Submission of product chemistry and toxicity data to support the registration of Triamine Premium Granular Weed Killer. Transmittal of 7 studies. 42149601 Sauyer, R. C1990) Product Chemistry: ^Riverdale Triamine Premium Granular Weed Killer I. Unpublished study prepared by Riverdale Chemical Co. 19 p. 42149607 Bresnahan, J. (1991) Nitrosamine Analysis: iTriaraine Premium Weed and Feed!: Lab Project Number: 5450-6985. Unpublished study prepared by Thermedics, Inc. 30 p. 42212100 Riverdale Chemical Co. (1992) Submission of product chemistry and toxicity data in support of registration of Riverdale Sweet Six teen Weed and Feed with Dissolve. Transmittal of 6 study. 422 12 10 1 Sawyer, R. (1991) Riverdale Sweet Sixteen Weed and Feed with Dissolve: Product Chemistry: Lab Project Number: SWEET SIXTEEN WEED A. Unpublished study prepared by Riverdale Chemical Co. 14 p. 42240200 Riverdale Chemical Co. (1992) Submission of Data To Support Application for Registration of Riverdale Sweet Sixteen Weed and Feed with Dissolve: Product Chemistry Study. Transmittal of 1 s t u d y . 42240201 Bresnahan, J. (1992) Nitrosomine Analysis: Riverdale Sweet Sixteen Weed Feed with Dissolve: Lab Project Number: 5450-7922. Unpublished study prepared by ThermedeTec Inc. P 21 42258800 Riverdale Chemical Co. (1992) Submission of Data To Support Application for Riverdale Dissolve Weed and Feed Registration: Product Chemistry Study. Transmital of 1 study. 42258801 Sawyer, R. (1992) Product Chemistry: Riverdale Dissolve Weed and Feed. Unpublished study prepared by Riverdale Chemical C o . 15 p . 42264700 Riverdale Chemical Co. (1992) Submission of product chemistry and toxicity data in support of registration of Riverdale Dri D 4- DP Amine. Transmittal of 7 studies. REPORT D: PDR20B0 1 RUH DATE: 11/26/93 PAGE: 16 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SEUENCE BIBLIOGRAPHY 24 DP MRID CITATION 42264701 Sawyer, R. (1992) Product Chemistry: Riverdale Dri D + DP Amine: Lab Project Number: DRI D + DP AMINE. Unpublished study prepared by Riverdale Chemical Co. 18 p. 42264707 Stevens, J. (1990) Nitrosamine Analysis: Riverdale Dri-D + DP Amine: Lab Project Number: 5450-6298. Unpublished study prepared by Thermedics, Inc. 18 p. 42420700 PBI Gordon C o r p . (1992) Submission of supplmentary product chemistry data to support the registration of EH 1068 and 1073 Trimec Ester. Transmittal of 2 studies. 42420701 Savage, J. (1992) Supplemental Report: EH 1068 Trimec Ester: Lab Project Number: PBG-01. Unpublished study prepared by Dartec Labs, Inc. 39 p. +2420702 Savage, J. (1992) Supplemental Report: EH 1073 Trimec Ester: Lab Project Number: PBG-02. Unpublished study prepared by Dartec Labs, Inc. 39 p. 42454500 Riverdale Chemical Co. (1992) Submission of product chemistry data in support of the registration of Riverdale Sweet Sixteen Weed and Feed with CL/DAP. Transmittal of 1 study. 4245450 1 Sawyer, R. (1991) Riverdale Sweet Sixteen Weed and Feed with CL/DAP. Unpublished study prepared by Riverdale Chemical Co. 8 p. 42545000 Riverdale Chemical Company (1992) Submission of product chemistry data in support of the registration of Riverdale Sweet Sixteen Weed and Feed with Dissolve. Transmittal of 1 study. 42545001 Sawyer, R. (1992) Product Chemistry: Riverdale Sweet Sixteen Weed and Feed with Dissolve. Unpublished study prepared by Riverdale Chemical Co. 8 p. 42676800 Chevron Chemical (1993) Submission of product chemistry data in support of the Ortho Triamine Jet Weeder registration. Transmittal of 1 study. REPORT ID : PDR20B01 RUH DATE: 11 /26/93 PAGE: 17 ENVIRONMENTAL PROTECTION AGENCY PROGRAM MANAGEMENT AND SUPPORT DIVISION PESTICIDE DOCUMENT MANAGEMENT SYSTEM (PDMS) MRID SE2UENCE BIBLIOGRAPHY 24 DP MRID CITATION 42676801 Wong, D. (1992) Ortho Triamine Jet Weeder Product Chemistry: Lab Project Number: 92007. Unpublished study prepared by Chevron Chemical Co. 41 p. 42804300 Rivendale Chemical Co. (1993) Submission of product chemistry data in support of the registration for Rivendale Dissolve 4000 Weed and Feed. Transmittal of 1 study. 42804301 Sawyer, R. (1993) Product Chemistry: Rivendale Dissolve 4000 Weed and Feed: Lab Project Number: DISSOLVE 4000 WEED AND FEED . Unpublished study prepared by Rivendale Chemical Co. 8 p. c?UD ^ ( 0 ( 0 PAGE 86 93 95 98 102 113 116 118 119 122 129 EPA TSCA 8 (D) AND 4< A) DOCKET INDEX REFERENCES OF INTEREST SUBJECT MARCH 4, 1986 public meeting on dioxins/furans; attendees included American Petroleum Institute. Transcript of proceedings. Subject: Proposed testing and reporting requirements. April 20, 1988, Protocol Review Panel Teleconference; documents list A. Dupuy, R. Harless & D. Firestone, minutes of meeting May 4, 1988, Midwest Research Inst itute. July 27, 1988, August 17, 1988 meetings of Protocol Review Panel meetings; attendees include Dow, FDA, Mobil, Ethyl. March 1, 1989 Protocol Review Panel meeting; attendees include GE Plastics Company; Dow, FDA, Ethyl, NIOSH. Subject: Exposure issues and protocol reviews. September 8 , 1989; Protocol Review Panel teleconference; attendees: EPA, Midwest Research Institute; Lockheed; FDA; subject includes analytical problems with Chiorani1. Dow: Direct testimony of David T. Buzzelli in 2,4,5-T proceedings; Exhibit 810 in re: The Dow Chemical Co. et al; Docket Nos. 415 et al, September 30, 1980. February 11, 1985 Formation of the Diox ins;Furan Work Group. List of Workgroup members March 1985; April 12, 1985 meeting notice and agenda Work group: Appendix A -- Chemicals contaminated, potentially contaminated, and/or precursors to contamination with chlorinated and brominated dibenzodioxins (DBDs) and dibenzofurans (DBFs) April 12, 1985 January 13, 1986 letter from NIEHS to D. Barnes re: the revised draft of the CDD and CDF position document. January 15, 1987, letter from EDF, Ellen Silbergeld & R. 1 ao'Jio'l r V Percival to J. Moore, EPA, re: settlement among Vulcan Materials, EPA, & Idacon, Inc., with respect to dioxin contamination of PCP. 130 June 26, 1987 letter from General Electric Company to EPA, re: request for clarification of final rule. 131 Monsanto (July 21, 1987); Kirkland & Ellis (July 29, 1987); American Paper Institute/NFPA (August 3, 1987) requests for clarification of final rule. 132 August 20, 1987 Rhone-Poulenc, Inc., test results on imported 2 ,4-dichlorophenol. 134 September 2, 1987, Dow Intent to conduct testing on 2,4dichlorophenol. 135 September 2, 1987, Dow "Request for waiver from testing all compounds except 2 ,4--Dichlorophenol". 140 January 29, 1988, General Electric Company Summary of ongoing or proposed testing. 150 September 2, 1988, Dow Final protocol submission. 153 May 4, 1990, Triangle Labs., Inc. F0IA request with enclosure containing the EPA audit chronology. 163 April 3, 1986 Monsanto analysis of brominated diphenyl oxides for brominated dibenzofurans. 165 76 October 5, 1987 Dow Chemical submission of 41 studies (published & unpublished) 166 Dow cohort mortality study of chemical workers 167 Kociba June 10, 1986, Analysis of the animal toxicity studies of 2,3,7,8-TCDD used in derivation of lifetime exposure control limit recommendations for humans. 175 undated Analysis on 2,4-Dichlorophenol to determine HDD/HDF presence 176 Dow studies in progress, revised, October 5, 1987 181 December 23, 1987, General Electric Company, Pyrolytic formation of polybrominated dibenzodioxins and polybrominated dibenzofurans; Monsanto December 22, 1987, Dibenzofuran in diphenyl oxide and the relationshiop to brominated dibenzofurans 2 9-0^% 183 184 185 187 88 198 200 210 224 247 257 259 292 304 in brominated diphenyl oxide. October 5, 1987, Rohm & Haas, Analysis of Dow and Rhodia 2,4-dichlorophenol (sanitized); Analysis of [ ] and 2,4-- DCP for 1,3,6,8 --TCDD and 2,3,7,8-TCDD and of 2,4-DCP for 2,4,6-TCP and 2,4,5-TCP (sanitized); Rsults of analyses for 2 ,7-dichlorodibenzo-p-dioxin (sanitized) Rhone--Poulenc, 2,4--Dichlorophenol test results September 30, 1987 Standard Chlorine of Delaware, Inc. submiss ion September 1987 EPA Guidelines for the determination of halogenated dibenzo--p-dioxins and dibenzofurans in commercial products. July 1, 1988 Dow submissions on sampling protocols September 12, 1988 internal EPA action memorandum on Dow protocol on 2 ,4-dichlorophenol. December 14, 1988 EPA Charter of the dioxin/furan protocol review panel June 7, 1989 Dow, Final report of the determination of halogenated dibenzo-p-dioxins and dibenzofurans in 2,4dichlorophenol. February 10, 1989 Dow protocol for determination of halogenated dibenzo-p-dioxins and dibenzofurans in 2,4dichlorophenol. February 4, 1985 Dow Analysis of 2,4-Dichlorophenol for the presence of 2,3,7,8-TCDD. February 6 , 1989 EPA Draft panel recommendations for revision 1 of the Dow protocol submitted for 2,4dichlorophenol under the EPA TSCA Section 4 Dioxin/Furan rule. Midwest Research Institute. September 1, 1989, Internal EPA memo on the analytical data for 2 ,4-dichlorophenol submitted by the Dow Chemical Company, with encli sure, letter August 23, 1989 from A. Dupuy on the review of data for 2,4dichlorophenol submitted by Dow. Refers to same Dow analysis as p. 247 March 19, 1990 "Civil trial on allegations against Dow Chemical Company, Riverdale Chemical Co., Amvac Chemical 3 4 Corp. , Vertac Chemical Corp.> and Rhone-Poulenc, Inc. " 327 July 16, 1991 Chemical Manufacturers Association letter to EPA on the analytical testing for dioxins in blood samples of certain workers. 362 June 10, 1991, Pfister Chemical, Incl, request exclusion from testing 3,4,5-tribromosalicylanilide <TBS) 404 EPA health and environmental effects profiles for chlorinated and brominated dioxins and furans <#s 31, 32, 33) 1985 EPA Drinking Water Criteria Document for 2,3,7,8 -TCDD, March 1985. 404 EPA 1985, List of chemicals contaminated or prcursors to contamination with incidentially generated polychlorinated and polybrominated dibenzodioxins and dibenzofurnas. 411 Polybrominated dibenzofurans and dibenzodioxins from the pyrolysis of neat brominated diphenylethers, biphenyls, and plastic mixtures of these compounds. (#31) 412 November 4, 1986 letter from Dioxin Toxic Equivalency Methodology Subcommittee to Lee M. Thomas. 416 Fingerhut on STS 1984 417 Kimbrough 1974, The toxicity of polychlorinated plycyclic compounds and related chemicals. [Most of the unreferenced pages refer to brominated fire retardants and Chloranil; a few to brominated salicylanilides. 1 4 9,o^7o TABLE OF CONTENTS POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCKET #83002 Decisionmaking Federal Register Notices. Aia - Authentic Federal Register Documents. a 2 - Federal Register Notices Related to the Rule. Bla Support Documents for Docket #83002. B lb " Support Documents for Docket #83002B. Support Documents for Docket #83002C. Support References for Docket #83002. b 3 - Support References for Docket #83002B. b 4 - Support References for Docket #83002C. Cl - Public Comments for Docket #83002. c 2 - Public Comments for Docket #83002B. Dla Meetings for Docket #83002. Dlb ~ Meetings for Docket #83002B. D lc Meetings for Docket #83002C. D ld - Meetings Following Docket #83002C. D2 a - Legal Proceedings for Docket #83002. D2b ~ Legal Proceedings for Docket #83002B. d 2 c ~ Legal Proceedings for Docket #83002C. B 3a Hearings for Docket #83002. D 3b _ Hearings for Docket #83002B. d 3c Hearings for Docket #83002C. D3d " Hearings Following Docket #83002C. E la Written Communications for Docket #83002. Elb " Written Communications for Docket #83002B. Eic - Written Communications for Docket #83002C. Eld ~ Written Communications Following Docket #83002C. E2a ~ TelephoneCommunications for Docket #83002. E2b ~ TelephoneCommunications for Docket #83002B. e 2 c ~ TelephoneCommunications for Docket #83002C. E2 - TelephoneCommunications Following Docket #83002C. E3a - Petitions for Docket #83002. 3^ - Petitions for Docket #83002B. FJ - Documents Received Following Decision of December 19, 1985; Docket #83002. G;l - Documents Received Following Decision of October 23, 1986; Docket #83002B. H 3 g- Documents Received Following Decision of June 5, 1987; Docket #83002C, for 1987 Only. Hj j - Dbcuments Received Following Decision of June 5, 1987; Docket #83002C, for 1988 Only. H1>2- Documents Received Following Decision of June 5, 1987; Docket #83002C, for 1989 Only. H3 3- Documents Received Following Decision of June 5, 1987; . ' , Docket #830020, for 1990 Only. . . v .............................................. <pila - Exclusion/Waiver Request and Rponse From Testing '2 Requirements for Supelco, Inc.; DockeiS#83002D^a^<,''^ , ~ ' - Exclusion/Waiver Requests and Responses From Testing Requirements for Aldrich Chemical Co., Ameribrom, Inc. Atochem, Inc., Pfister Chemical, Inc.,.Sigma Chemical Corp., Great Lakes Chemical Corp. and Ethyl Corp.; DocketS#83002E^j5W ^ ^ / ^ c/Z?* 6 Hlc - Exclusion/Waiver Request^and Respons^From Testing Requirements for Rohm and Haas Co.; Dockets#830021. Hfd _ Modification anci Amendment Requests and Responses , from O^tobor 19 to Q^tnbn^l99^;^Docket # U pJ , ipt of Test Data; Docket #44544, December 21, 2 ^ 1(_S -IX-CLt,& -, Hs Receipt of Test Data; Docket #44546, February l, 1990. H 4 - Receipt of Test Data; Docket #44552, May 30, 1990. Note: Files Hj_ 0 , H1>lf 2 -*h * Hjl 3 ^ r e Listed ___Alphabetically. ',/ .4, 3 L O Lt,7 3 3 Chemicals for the Dioxin/Furan Docket CAS NO. 25327-89-3 37853-61-5 37853-59-1 1940-42-7 1163-19-5 99-28-5 615-58-7 2577-72-2 576-24-9 120-83-2 583-76-6 87-65-0 95-77-2 120-36-5 320-72-9 32536-52-0 32534-81-9 608-71-9 3772-94-9 79-94-7 21850-44-2 4162-45-2 55205-38-4 488-47-1 79-95-8 87-10-5 118-75-2 118-79-6 95-95-4 933-75-5 CHEMICAL NAME Alkylamine tetrachlorophenate Allyl ether of tetrabromobisphenol-A Bismethyl ether of tetrabromobisphenol-A 1.2- Bis(tribromophenoxy)ethane 4-Bromo-2,5-dichlorophenol Decabromodiphenyloxide 2,6-Dibromo-4-nitrophenol 2.4- Dibromophenol 3.5- Dibromosalicylanilide 2.3- Dichlorophenol 2.4- Dichlorophenol 2.5- Dichlorophenol 2.6 - Dichlorophenol 3.4- Dichlorophenol 2 [2 ,4-(Dichlorophenoxy)Jpropionic acid 3.5- Dichlorosalicylic acid Octabromodiphenyloxide Pentabromodiphenyloxide Pentabromophenol Pentachlorophenyl laurate Tetrabromobisphenol A Tetrabromobisphenol-A-bis-2,3-dibromopropyl ether Tetrabromobisphenol-A-bisethoxylate Tetrabromobisphenol-A diacrylate Tetrabromobisphenol B Tetrabromocatechol Tetrachlorobisphenol A 3.4.5- Tribromosalicylanilide 2.3.5.6- Tetrachloro-2,5-cyclohexadiene-l,4dione 2.4.6 - Tribromophenol 2.4.5- Trichlorophenol 2.3.6 - Trichlorophenol LISTING OF CONFIDENTIAL BUSINESS INFORMATION (CBI) DOCUMENTS o (1) 6 3 -8 8 0 0 0 0 I93 EPA (S. Hassur) Review of Testing Exclusion Request from Ameribrom, Inc. 02/05/86 (2) 63-8600141 Monsanto Company Analysis of Brominated Diphenyl Oxides for Brominated Dibenzofurans 04/03/86 (3) 63-880000097 Great Lakes Chemical Corporation Response to EPA Questions 12/17/86 (4) 40-870000052 Ameribrom, Inc. Response to EPA's Request for Additional Information 02/03/87 (5) 63-878000149 Ethyl Corporation Request for Exclusion from Testing 09/01/87 (6) 63-878000146 Great Lakes Chemical Corporation Request for Exclusion from Testing 09/03/87 (7) 63-878000147 Aldrich Chemical Company Request for Exclusion and Waiver from Testing 09/03/87 (8) 63-870000104 Ameribrom, Inc. Request for Exclusion from Testing 09/23/87 (9) 63-870000109 Pfister Chemical Company -- 09/23/87 (10) 63-870000119 Aldrich Chemical Exclusion/Waiver Company Support Information ( I D 63-870000117 Sigma Chemical Company Request for Exclusion/Waiver From Testing -1- 09/28/87 09/28/87 Oo^T5 *) (1 2 ) 63-880000063 Midwest Research Ethyl Corporation 09/29/87 Institute (13) 63-886000001 EPA (K. Wong) Great Lakes 10/21/87 Chemical Corp. and Ethyl Corp. (14) 63-886000002 EPA (S. Hassur) Great Lakes 10/21/87 Chemical Corp. and Ethyl Corp. (15) EPA (S. Hassur) Recommended Disposition of Testing Exclusion Request (Ameribrom and Great Lakes) 11/12/87 (16) EPA (S.' Hassur) Recommended Disposition of Testing Exclusion Request (Pfister) 02/02/88 (17) 63-890000005 (18) 63-90000000^9 Hoechst Celanese Corp. 8(a) Production 07/25/90 Volume, Use, Import, Exposure, Environmental Release and Disposal Information (19) 63-900000011 Chugai Boyeki (America) Corp. 8(a) Production 08/08/90 Volume, Use, Import, Exposure, Envi ronmental Release and Disposal Information -2- TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DECISIONMAKING FEDERAL REGISTER NOTICES A-l-FILE Fiche # 40-8593005 40-8693006 50 FR 51794, USEPA Polyhalogenated Dibenzo-pDioxins/Dibenzofurans; Testing and Reporting Requirements. Action: Proposed Rule. December 19, 1985 51 FR 37612, USEPA Testing and Reporting Requirements for Polyhalogenated Dibenzo-pDioxins/Dibenzofurans; Addition of Chlorinated and Brominated Benzenes to List o f Precursor Chemicals. Action: Amendment to Proposed Rule. October 23, 1986 [8300^] / I I \ j ( [83002BI (1) 513651 (2) 513652 40-8793161 52 FR 21412, USEPA Polyhalogenated Dibenzo-pDioxins/Dibenzofurans; Testing and Reporting Requirements. Action: Final Rule. June 5, 1987 J [83002C]-- 7 I (3) 513653 Ai- 1 7 TSCA SECTION 8(d) AND 4(a) ' HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS AUTHENTIC FEDERAL REGISTER DOCUMENTS A la-FILE Fiche # 40-8693007 U.S. Environmental Protection Agency (1) 513654 Polvhalogenated Dibenzo-p-Dioxins/ Dibenzofurans: Testing and Reporting Requirements: Open Meeting. Action: . Notice of Open Meeting. OPTS-83002A; 40 CFR Part 766. April 3, 1986 40-8793203 U.S. Environmental Protection Agency Polvhalogenated Dibenzo-p-Dioxins/ Dibenzofurans: Testing and Reporting Requirements Action: Final Rule. OPTS-83002C. ` June 1987 (2) 513655 40-8793185 U.S. Environmental Protection Agency Receipt of Request for Exclusion From/ Waiver of Testing of Ethvl Corporation and Great Lakes Chemical Corporation. Action: Notice of Receipt of Requests for Exclusion/Waiver of Testing Requirements. OPTS-83002E. September 27, 1987 (3) 513656 40-879-3221 U.S. Environmental Protection Agency Receipt of Request for Exclusion From/ Waiver of Testing of Certain Chemical Companies. Action: Notice of Receipt of Requests for Exclusion/Waiver of Testing Requirements. OPTS-83002G. October 23, 1987 (4) 513657 A la-1 ? TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS AUTHENTIC FEDERAL REGISTER DOCUMENTS A la-FILE Fiche # 40-8893238 U.S. Environmental Protection Agency (5)* 513658 Notice of Decision on Exclusion/Waiver Applications of Seven Companies. _. Action; Notice of Decision on A CXcSL-Qs'i^yywaiver Requests. OPTS \_ February 2, 1988 40-8893239 U.S. Environmental Protection Agency Receipt of Request for Waiver of j of Rohm and Haas Co. Action: 'ftJdtioe'ffT Receipt of Request for Waiver Q jy f y "T^stlri^ Requirements. OPTS-83002I. 0 April 21, 1988 (6) 513659 40-9093424 U.S. Environmental Protection Agency TSCA Chemical Testing; Receipt of Test Data. Action: Notice. OPTS-44546. January 25, 1990 (7) 524800 40-9093463 U.S. Environmental Protection Agency TSCA Chemical Testing: Receipt of Test Data. Action: Notice. OPTS-44552. May 17, 1990 (8) K- 5. Sil/, A la-2 2 0 4-77 ? TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET # AUTHENTIC FEDERAL REGISTER DOCUMENTS A Ia-FILE Fiche # (0 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS FEDERAL REGISTER NOTICES RELATED TO THE RULE a 2-f i l e Fiche # 40-8393008 48 FR 48434, USEPA (1) 513660 2,4,5-T and Silvex Products; Intent to Cancel Registra'^^ca^ of Pesticide Products ., Containing 2>4,5-T and ; -inv&jrK Revocati on of Notices >&, Intent to Hold a Hearing^ Determine Whether Certain ss^of 2,4,5-T or Silvex ** Sfifruld Be Cancelled. Action: Notice of Intent to Cancel Registrations; Revocation of Notices of Intent to Hold a Hearing. October 18, 1983 40-8493009 49 FR 5831, USEPA Water Quality Criteria; Availability of Document. Action: Notice of Final Ambient Water Quality Criteria Document. February 15, 1984 [OW-FRL-25 22-2] 513661 a 2- i c?ID l II TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-E-DIOXINS/DIBENZOFURANS FEDERAL REGISTER NOTICES RELATED TO THE RULE a 2-f i l e Fiche # 40-8493010 49 FR 28666, USEPA (3) .513662 Creosote, Pentachlorophenol, and Inorganic Arsenicals Intent to Cancel R e g i s t r a ^ ^ etrrons-bf pesticide Products Containing Creosote, .Pentachlorophenol (Including ^its Salts) and the Inorganic Arsenicals; Determination Concluding the Rebuttable Presumption Against Registration of the W<; Preservative Uses of Poot-rc>de Products; Document-. Action: Notice of Intent to Cancel, Notice of Determina'^^j Notice of Availability q & Position Document. ^ July 13, 1984 [O P P - 3 0 0 0 0 / 2 8 F ; PH-FRL 2630-4] 40-8593011 50 FR 1978, USEPA Hazardous Waste Management System; Dioxin-Containing Wastes. Action: Final Rule. January 14, 1985 [SWN-FRL 2701-3] '^4) i 513663 A 2-2 ^> - TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-E-DIOXINS/DIBENZOFUKANS FEDERAL REGISTER NOTICES RELATED TO THE RULE a 2-f i l e Fiche # 40-8693012 51 FR 2736, USEPA (5) 513664 Polyhalogenated Dibenzo-pDioxins/Dibenzofurans; 'T Z v 'fc * , 'Ses'Ctog and Reporting/ Requirements, Correction. January 21, 1986 [83002>=* 40-8693013 51 FR 12344, USEPA ( 6 ) 513665 ( Toxic Substances j^PolyhalogeS>nated Dibenzo-p-](i40xi\naA/ / -j '^/Dibenzofurans ; Testing afffd c J a Reporting Requirements; Opp-en- Meeting. Action: Notice of Open Meeting. April 10, 1986 [83002A] 40-8793205 52 FR 30430, USEPA (7) 513666 Receipt of Request for Waiver of Testing of Supelco, Inc. Action: Notice of Receipt of Request for Waiver of Testing Requi rements. August 14, 1987 [83002D] A 2-3 13 TSCA SECTION 8(d) AND 4(a) ' HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-E-DIOXINS/DIBENZOFUFANS FEDERAL REGISTER NOTICES RELATED TO THE RULE a 2-f i l e F iche # 40-8793230 52 FR 37009, USEPA (8) 513667 Receipt of Request for ion From/Waiver of -Testing-- of Ethyl Corp. and G-de-feti Lakes Chemical Corp.\ Action: Notice of Receipt of Requests for Exclusion/Waiver of Testing Requirements. October 2, 1987 [83002E] 40-8793235 52 FR 39703, USEPA ' Decision on Waiver Application- of Supelco, Inc. Action: Decision on Waiver Request. October 23, 1987 [83002F] (9) 513668 40-8793222 . 52 FR 43250, USEPA Receipt of Request for Exclusion From/Waiver of Testing of Certain Chemical Companies. Action: Notice of Receipt of Requests for Exclusion/Waiver of Testing Requirements. November 10, 1987 [83002G] (10) 513669 A 2-4 (4 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFUEANS FEDERAL REGISTER NOTICES RELATED TO THE RULE a 2-f i l e Fiche # 40-8893231 53 FR 3938, USEPA __ (11* 513670 Tpxic and Hazardous 'Suketanrre'S' Control; Decision kft Exclusion/Waiver AppTiTratTi5n^'of Seven CDmpaiHres-H-Aid^ie-h Chemical/ Co. et al. __-- ----' ] Action: Notice of Decision on Exclusion/Waiver Requests. February 10, 1988 [83002H ]=| 40-8893232 53 FR 15282, USEPA Receipt of Request for Waiver of Testing of Rohm and Haas Co. Action: Notice of Receipt of Request for Waiver of Testing Requirements. April 28, 1988 [830021)2 1 2 ) 513671 40-9390420 54 FR 52449, USEPA TSCA Chemical Testing; Receipt of Test Data. Action: Notice. December 21, 1989 (13) . 514801 [44544]-^ A 2-5 lb TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #8 3002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFUIANS FEDERAL REGISTER NOTICES RELATED TO THE RULE a 2-f i l e Fiche # 40-9390419 55 FR 3482, USEPA (14) 524802 TSCA Chemical Testing; Receipt of Test Data. Action: Notice. February 1, 1990 [44546] s> A2-6 9,0 (<P TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET # 4L. Fiche S t t 'S 9,0^3 7 \7 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT DOCUMENTS FOR DOCKET #83002 B la-FILE Fiche # 40-8593014 U.S. Environmental Protection Agency (1) 513672 Health Assessment Document for PolW /<fK^rinated Dibenzo-p-Dioxins. (Final) September 1985 40-8593015 U.S. Environmental Protection Agency Economic Analysis for Requirement Under TSCA Section 8(d) for Submission of Unpublished Health and Safety Studies for Chemicals Potentially Contaminated with Polvhalogenated Dibenzo-p-Dioxins and Polvhalogenated Dibenzofurans. October 1985 (2) 513673 40-8593016 U.S. Environmental Protection Agency Economic Analysis of Proposed Call-In Under TSCA Section 8(c) of Allegations of Significant Adverse Reactions for Chemicals Potentially Contaminated with Polvhalogenated Dibenzo-p-Dioxins and Polvhalogenated Dibenzofurans. October 1985 (3) _ 513674 40-8593017 U.S. Environmental Protection Agency Economic Analysis of Proposed Section 8(a) Reporting Rule for Chemicals Pft%3fotiallv Contaminated wi PoTvh^l-ogenate^ Dibenzo-p-Diox PoTv^alopenarDe^ Dibenzofurans. October 1985 (4 ; 513675 B la 1 S-O'iSS ft TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-B-DIOXINS/DIBENZOFURANS SUPPORT DOCUMENTS FOR DOCKET #83002 B la-FILE Fiche # 40-8593018 U.S. Environmental Protection Agency (5) 513676 Economic Analysis of Proposed Section 4 Testing Rule for Chemicals Potentially Contaminated with Polvhaloaenated Dibenzo^p-Dioxins and Polvhaloqenated Dibenzofurans. October 1985 Bla 2 TSCA- SECTION 8(d) AND 4(a) / HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT DOCUMENTS FOR DOCKET #83002C B lc-FILE Fiche # 40-8593014 U.S. Environmental Protection Agency (1 ) 513672 Health Assessment Document for_ P o k d v f o - PkPyBfTF&rinated Dibenzo-p-Dioxins / ( J p p (Ti'ifoT') September 1985 [Crossreferenced to Bla(l)] 40-8693157 U.S. Environmental Protection Agency Economic Analysis of Final Section 8(a) Reporting Rule for Chemicals --- PoHTeh'tLariir Contaminated With ^ - Polvhalogenated^ Pibenzo~::p:-Dioxins and/ft , ^^lyhalogenatedTPibenzofurans. Decemher J986 ( 2) 513678 40-8693158 U.S. Environmental Protection Agency Economic Analysis for Requirement Under TSCA Section 8(d) for Submission of Unpublished Health and Safety Studies for Chemicals Potentially Contaminated with Polv-halogenated Dibenzo-p-Dioxins and Polvhalogenated Dibenzofurans. December 1986 (3) 513679 40-8693159 U.S. Environmental Protection Agency (4) 513680 Economic Analysis of Final Call-In Iteglef TSCA Section 8(c) of Allegations lerfrOKfrqnificant Adverse Reactions f o v - C & L gfi^nrTDeiTE Potentially Contaminated With Po^yha-i-CT^f&nated Dibenzo-p-Dioxins and <p, Poi^-^irSdgmated Dibenzofurans. December 1986 B lc- 1 2,0 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT DOCUMENTS FOR DOCKET #83002C B lc-FILE Fiche # 40-8793160 U.S. Environmental Protection Agency (5)v 513681 Economic Analysis of Final Section 4 T-esting Rule for Chemicals Potentially Contaminated With Polvhalogenated Dibenzo-p-Dioxins and Polvhalogenated Dibenzofurans. (Third Draft) January 1987 40-8793204 U.S. Environmental Protection Agency Economic Analysis of Final Section 4 Testing Rule for Chemicals Potentially Contaminated with Polvhalogenated Dibenzo-p-Dioxins and Polvhalogenated Dibenzofurans. (Final) (Sanitized) Mathtech, Inc. January 1987 (6) 513677 B lc -2 al TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002 b 2-f i l e Fiche # 40-8593019 M Agent Orange Work Group^ (Cabinet on Human Resources) ^ e\T\ Report given to the Domestic Council of the President's Cabinet. October 1985 (1) 513682 40-7993020 Albro, P.W. , Luster, M.I., Chae, K. , Chaudhary, S.K., Clark, G . , Lawson, L.D., Corbett, J.T. and McKinney, J.D. (U.S. Department of Health and Human Services, National Institute of Environmental Health Safety, Research Triangle Park, NC) A Radioimmunoassay for Chlorinated Dibenzo-p-Dioxins. Toxicology and Applied Pharmacology; 50:137-146. 1979 (2) 513683 40-8493021 Bandiera, S., Sawyer, T . , Romkes, M . , Zmudzka, B. , Safe, L. , Mason, G. , Keys, B. and Safe, S. (Texas A&M University, College of Veterinary Medicine) Polychlorinated Dibenzofurans (PCDFs): Effects of Structure on Binding to the 2.3.7.8-TCDD Cytosolic Receptor Pr-Qt^Hfry AHH Induction and Toxicity -TO 32:131-144. 1984 (3) 513685 J> 40-8493002 Beilin, J.S. and Barnes, D.G. Health Hazard Assessment for Chlor ('hatn^cfy Dioxins and Dibenzofurans Other T/ (Than 2.3.7.8-TCDD. Presented at a Sympos-iufiT in Cincinnati, Ohio. ** October 25, 1984 [Document Not Provided to Docket] (3a) b 2-i cHL{ 9=2-- TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002 b 2-f i l e Fiche # 40-7993022 Bradlaw, J.A. and Casterline, J.L. (U.S. (4) 513687 Department of Health, Education and Welfare, Food and Drug Administration) Induction of Enzyme Activity in Cell Culture: A Rapid Screen for Detection of Planner Polychlorinated Organic Com- pounds. J. Assoc. Off. Anal. Chem,; 62(4):904-916. 1979 - .- 40-8593023 Canada Agriculture, Food Production and Inspection Branch Letter from Y.Y. Wigfield to S. Rudzinski, EPA July 15, 1985 Enclosure: (1) Answers to Ouestions/Issue on the Dioxin/Furan List and Methodology. (5) 513688 40-8593024 Canada Agriculture, Food Production W*Inspection Branch Letter from Y.Y. Wigfield to S. Rudzinski, EPA, correcting an error in the July 15, 1985 comment letter. July 29, 1985 (6) 513689 40-8593025 Canada Environmental Protection Cover letter from M.J. Boddington to D. Barnes, EPA August 28, 1985 Enclosure: (1) Interim Risk Assessment ^ 5 ^PCDDs/PCRFg Review Comments. (7) 513690 B 2-2 00^93 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002 b 2-f i l e Fiche # 40-8593026 Center for the Biology of Natural Systems Cover letter from B. Commoner to D. Barnes, EPA August 30, 1985 (8) 513691 513694 . Enclosure: (1) Comments on Chlorinated Dioxins Workshops Position Document (April 1985 - Updated: "Interim Risk Assessment Procedures for Mixtures of Chlorinated Dibenzodioxins and Dibenzofurans (CDDS and CPFs)." August 30, 1985 40-8593027 Chemical Manufacturers Association Cover letter from G. Cox to S. Rudzinski, EPA July 19, 1985 Enclosures : (1) Attachment 1: Response of the Chemical Manufacturers Association Dibenzofurans/Dibenzodioxins Program Panel to EPA's Questions Concerning Its Proposed Candidate List and Analytical Methodology. (2) Attachment II : Principles ^Environmental Analysis. The Amerir&an Chemical Society. 1983 (3) Attachment III: Soil Screening Survey at Four Midwestern Sites Quality Control Summary. EPA. May 1985 (9) 513692 B 2-3 2,0'`-f TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002 b 2-f i l e Fiche # 40-8293028 Coggan, D. and Acheson, E.D. (University of Southhampton, England) (10) 513693 Occupational Health: Do Phenoxv Hrtereides Cause Cancer in Man? Larie'fcv 1(8280) :1057-1059. May 8, 1982 40-8493029 Czuczwa, J.M. and Hites, R.A. (Indiana University) Environmental Fate of CombustionGenerated Polychlorinated Dioxins and Furans . Environ. Sci . Techno 1. ; W J jt) ' 187 6-|t 444-450. June 1984 (11) 513695 40-8593030 Dow Chemical USA (12) Letter from W. Crummett to 3* , 5r-ihia^zTnSl?:i,_EPA, commenting on thej/ di'st of chemicaTsJproposed tor testing. July T5T'~1985-" Enclosures (1) Table 1: Parts per Trillion Concentration in Unspiked Human Adipose Tissue. (2 ) Table II: Unacceptable Data P o j^ c P j ^PcriivCj? Taken in Human Adipose Uy SirUtJ7\ 513696 40-8593031 Dow Chemical USA Letter from R.J. Kociba to D. Barnes, EPA, commenting on the "Interim Risk Assessment Procedures for Mixtures of Chlorinated Dibenzodioxins and <D5-b^n>^furans." August 27, 1985 - (13) 513697 B 2-4 Q-1 TSCA SECTION 8(d) AND 4(a) ' HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002 b 2-f i l e Fiche # 40-8493033 Environmental Defense Fund (14) 513700 Letter from E. Silbergeld to D. Barnes aiid J. Beilin, EPA, reviewing the draft report "Health Hazard Assessment for CDDs and CDFs Other Than 2,3,7,8-TCDD." September 20, 1984 40-8593035 Environmental Defense Fund Letter from E. Silbergeld to S. Rudzinski, EPA, commenting on the list of chemicals and the methods for analyzing chemicals. July 26, 1985 \ Enclosures: (1) Letter from D. Sundin, NIOSH, to L . Loy, EDF July 17, 1985 (a) List of trade name products containing one or more BTbbijLZOfurans/Dibenzodioxins National Occupational Hazard Survey. (2) Sachstande Dioxine (Report on Dioxins). (German) May 1985 [See B4 (12) for Translation] (15) 513701 40-8593036 Environmental Defense Fund Letter commenting on the latest ^CLmrer^ia- Risk Assessment Procedures for MisfEtrbe-s of CDDs and CDFs" (dated July 2 ^4-j-- 198-54- from E. Silbergeld to D. ^ Barnes, EPA.------ " --- ---- ^ October 17, 1985 (16 513702 B 2-5 TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002 b 2-f i l e Fiche # 40-8393038 Fingerhut, M.A. , Halperin, W.E., Honchar, P.A., Smith, A.B., Groth, D.H. (U.S. _ Department of Health and Human National Institute for Q QGCupati-erCTi Safety and Health) and ?-RussoLT , W .O^ (North Ridge General^ Hospital and Can^er^Foundation, Forrtt,y "auderdaie, .Florida)- (17J 513704 u j 10 > Review of Exposure and Pathology Data for Seven Cases Reported as Soft Tissue Sarcoma Among Persons Occupationally Exposed to Dioxin-Contaminated^jX/^._r=:-- - j j H/feife&cides. From "Public Health Risks 'tw. ef-- fette1 Dioxins," proceedings of a /. eympesa-uitT held October 19-20, 1983, in N ' j . ) N .Y7~ pages 187-203. ' October 1983 40-8393039 Fingerhut, M.A., Marlow, D .A ., Honchar, . (17a) P.A. and Halperin, W.E. (U.S. Depart^r^i / ioefft of Health and Human Services, ' a h * * * * ^ National Institute for Occupational * -* * * Sa_fety-- and Health) The NIOSH Occupational Dioxin Registry. From "Public Health Risks of the Dioxins," proceedings from the -symposi-um held October 19-20, 1983^ in ^ j,`^ ^ 3 N.Y. City-4, pages 36 2-36 6 . October 1983 513705 40-8493040 Gierthy, J.F., Crane, D. and Frenkel, G.D. (N.Y. State Department of Health, Wadsworth Center for Laboratories and Research) Application of an In Vitro Keratinization Assay to Extracts of Soot From a Fire in a Polychlorinated BiphenvlContaining Transformer. Fundamental and Applied Toxicology; 4:1036-1041. 1984 (18) 513706 B 2-6 Z L O `4<=i7 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002 b 2-f i l e Fiche # 40-8393041 Hajdu, S.I. (Memorial Sloan-Kettering Cancer Center) (19) 513708 Classification and Pathological Diagno sis of Soft Tissue Sarcomas. From "Public Health Risks of the Dioxins," proceedings from the symposium held October 19-20, 1983 in N.Y. City; pages 173-186. October 1983 40-8593042 Helder, T.H. and Seinen, W. (State University of Utrecht, The Netherlands) Standardization and Application of an E .L .S .-Bioassav for PCDDs and PCDFs. Chemosphere; 14(2):183-193. 1985 (20) 513710 40-8193043 Honchar, P.A. and Halperin, W.E. (U.S. Department of Health and Human -SeTvrces--^ National Institute for Occupatuene-i Safety and Health) 2.4.5-T. Trichlorophenol. and Soft Tissue Sarcoma. The Lancet; 1(8214): 268-269. January 31, 1981 (21) -. 513712 40-8193044 Hutzinger, 0., Olie, K., Lustenhouwer, J.W.A. (University of Amsterdam, The Netherlands) Okey, A.B. (Hospital for Sick Children, Ontario, Canada), Bardiera, S. and Safe, S. (University of Guelph, Canada) Polychlorinated Dibenzo-p-Dioxins and Dibenzofurans: A Bioanalvtical Approach. Chemosphere; 10:19-25. 1981 (22) 513713 B 2-7 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002 b 2-f i l e Fiche # 40-8593045 Indiana University, School of Public and Environmental Affairs (R.A. Hites) (22a) 513711 Letter from R. Hites to S. Rudzinski, EPA, in response to EPA's letter of June 20, 1985 requesting a review of the preliminary list of chemicals to be tested and the rationale and analytical standards involved. July 1, 1985 40-8593037 JRC, ISPRA, Italy (S. Facchetti) Response to EPA's request to review the preliminary list of chemicals to be tested for Dioxin/Furan contamination from S. Facchetti to S. Rudinski, EPA. (Telegram) July 24, 1985 (23) 513703 40-7493047 Kimbrough, R.D. (U.S. Department of Health and Human Services, Center for Disease Control) The Toxicitv of Polvchlorinated. .PplVyclic Compounds and Related (Shemioa-bs... CRC Critical Reviews in Tcrkirberloqyv pages 445-498. January 1974 (24) 513714 ' 40-8093048 Knutson, J.C. and Poland, A. (University of Wisconsin) (25 ) Keratinization of Mouse Teratoma Cell Line XB Produced bv 2 . 3 . 7 . 8 - _ r f Tet>ra-chl(>ffrdibenzo-p-dioxin: An In_ /Vi^tro^ModeTvtfc Toxicitv. Cell; 22:27- ' November 1980 513716 B 2-8 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002 b 2-f i l e Fiche # 40-8293051 McKinney, J., Albro, P . , Luster, M. Corbett, B . , Schroeder, J. and Lawson, L. (U.S. Department of Health and Human Services, National institute of Environmental Health Sciences, Research Triangle Park, NC) (26) 513718 Development and Reliability of a Radio immunoassay for 2,3.7.8-Tetrachlorodibenzo-p-dioxin. From "Chlorinated Dioxins and Related Compounds; Impact on the Environment," proceedings held in Rome, Italy, October 22-24, 1980. 1982 40-8593053 Monsanto Company Cover letter from F. Hileman to S. Rudzinski, EPA, in response to EPA's request for comments on the preliminary risk of chemicals to be tested and the methodology and analytical standards used. July 18, 1985 Enclosure: (1) Specific Comments on the Documents Sent for Review. (27) 513720 40-8593054 Natural Resources Defense Council, Inc. (28) Letter from R. Michaels to S, ^ . ^I^dzinskTr^P A , responding to EPA's H r^ 'cequ^stvt M r'comments on the preliminary J fr X x *3 -ttst-ef chemicals chosen to be tested a ^ ~ c t C fc -etnd-the methodology and analytical * ,,standards used. July 11, 1985 513721 B 2-9 3 SLQSf&O TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002 b 2-f i l e Fiche # 40-8593055 New York State Office of Public Health (J.F. Gierthy) (28a) 513707 Letter from J. Gierthy, to D. Barnes, EPA, reviewing the document "Interim Risk Assessment Procedures for Mixtures of Chlorinated Dibenzodioxins and Dibenzofurans." August 28, 1985 .- 40-8593056 New York State Department of Health (J.K. Hawley) Comment letter on the revised Position. . Document of the CDWG concerning the . fi-sk assessment procedures from J.K. Hawley to EPA. August 30, 1985 (28b) 513709 B 2-10 31 ZLOSG l TSCA SECTION 8(d) AND 4(a) ' HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002 b 2-f i l e Fiche # 40-8593057 Ontario Environment (29) 513723 Letter from B. Birmingham to D. Barnes reviewing the "Interim Risk Assessment Procedures . . September 3, 1985 Enclosures : (1) Report on Combustion Testing Pbbgram at the SWARU Plant. pHaifi?Ttt>n*Wentworth for the Ontario of the Environment Air Res.otDrt5&9 Branch. Envirocon Ltd. January 1984 . . (2) Determination of Chlorinated Dibenzo-p-Dioxins. Chlorinated Dibenzofurans. Chlorinated Biphenyls. Chlorobenzenes and Chlorophenols in Air Emissions and Other Process Streams at SWARU in Hamilton. V. Ozvacic, G. Wong, Tosine, R.E. Clement, JY^O^bOTin^ and S. Thorndyke. 1984 (3) Emissions of Chlorinated Organics From Two Municipal Incinerators in Ontario. Presented at the 77th Annual Air Pollution Control ' AfiSQCU Meeting, June 24-29, 1984 -k in-- San-F ranc isco . June 1984 (4) Interim Risk Assessment Procedures for Mixtures of Chlorinated Dibenzodioxins and Dibenzofurans (CDDs and CPFs). Chlorinated Dioxins Workgroup Position -- <Sdcfl5Lment. (Updated) April 1985 [Enclosures (1) Prov-i-ded to Doc and (3) Not b 2- ii TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002 b 2-f i l e Fiche # 40-8293058 Poland, A. and Knutson, J.C. (McArdle Laboratory for Cancer Research, University of Wisconsin) (30^ 513725 2.3.7.8-Tetrachlorodibenzo-p-Dioxin and Related Haloaenated Aromatic Hydrocar bons: Examination of the Mechanism of Toxicity. Ann. Rev. Pharmacol. Toxicol.; 22:517-554. 1982 40-8493059 Safe, S., Sawyer, T., Bandiera, S., Safe, L . , Zmudzka, B . , Mason, G . , (College of Veterinary Medicine, Texas A&M University), Romkes, M . , Denomme, M.A. (University of Guelph, Ontario) and Fujita, T. (Kyoto University Japan) Binding to the 2.3.7.8-TCDD Receptor and AHH/EROD Induction: In Vitro OSAR. "Banbury Report 18: Biological Mechan isms of Dioxin Action"; 33:135-149. 1984 (31) 513728 40-8393289 Safety, Health and Environmental Affairs Survey for Health Effects of Potential Exposure to 2.3.7.8-Tetrachlorodibeng^ -- jSPjrp-Dioxin (TCDD). (Sanitized) October 14, 1983 (3la) 513729 40-8393060 Sawyer, T . , Bandiera, S. and Safe, S. (Texas A&M, College of Veterinary Medicine), Hutzinger, 0. and Olie, K. (University of Amsterdam, The Netherlands) Bioanalvsis of Polychlorinated Dibehzofuran and Dibenzo-p-Dioxin Mixtures in Flv Ash. Chemosphere ; 12 (4/5 ):529->"^5" ' 1983 (31b) 513730 B 2-12 33 .0^03 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002 b 2-f i l e Fiche # 40-8293061 Sawyer, T. (University of Guelph, Ontario) and Safe, S. (Texas A&M, College of Veterinary Medicine) (32) 513731 PCB Isomers and Congeners: Induction < ? t C & i Arvl Hydrocarbon Hvdroxvlase and Etrffrdyfrresorufin o-Deethvlase Enzyme in Rat Hepatoma Cells. -To x t p p T L etters; 13:87-94. 1982 40-8593062 Sawyer, T.W. and Safe, S. (College of Veterinary Medicine, Texas A&M . University) In Vitro AHH Induction bv Polychlori nated Biphenyl and Dibenzofuran Mix tures: Additive Effects. Chemosphere; 14(1):79-84. 1985 (33) 513732 40-8593065 Texas A&M University, College of Veterinary Medicine Letter from S. Safe to S. Rudzinski, EPA, responding to EPA's request for comments on the preliminary list of , / chemicals to be tested and the '7 / ^ c ^ o o / fijet-hciaoiogy and analytical standards u&e-d-. July 12, 1985 (33a) 513726 40-8593066 Texas A&M University, College of Veterinary Medicine Comment letter on the Chlorinated Dioxin'"Interim Risk Assessment y 1Pi'ocredthrB'3 . . . " from S. Safe to D.G Barnes, EPA. v-- ---- -----August 5,1985 (33b) 513727 b 2- i 3 34 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002 b 2-f i l e F iche # 40-8593067 U.S. Air Force, School of Aerospace Medicine (Brooks Air Force Base, Texas) (34) 513735 Project Ranch Hand II: An Epidemio'lgTcjTinvestiaatin of Healthj\ f iff..e...t...r..t...s..-.....i...r....r...r...7...C......r...<...^....o...r...c...e...'...-...p...e...r...s...o...n...n...e...l.. J(following Exposure tolHeroicioes:^ MMoorrttaalliity Update - 1 9 8 5 . November 29, 1985 40-8593068 U.S. Department of Health and Human Services, National Institute of Environmental Health Sciences (34a) 513684 Letter from P. Albro to S. Rudzinski, EPA in response to EPA's request for comments on the preliminary list of chemicals to be tested and the methodo logy and analytical standards used. July 15, 1985 40-8593069 U.S. Department of Health and Human Services, National Institute for Occupational Safety and Health > j Letter commenting on the Dioxin (fWoYvftgroup's position document * At "Th-ft, t Risk Assessment Proc dtrres^-- : T71 from L. Birnbaum to D. -Barnes, EPA_ August 12, 1985 (34b) 513686 / f 40-8593070 U.S. Department of Health and Human Services, Center for Disease Control Letter from R. Kimbrough to D. Barnes, EPA, reviewing the document "Interim Risk Assessment Procedures. . ." August 15, 1985 (34c) 513715 B2-14 3* TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002 b 2-f i l e Fiche # 40-0093071 U.S. Environmental Protection Agency (35) 513736 Dioxin Emissions From Stacks of Poorly and Well Operated MWCs. (Chart) Undated 40-0093072 U.S. Environmental Protection Agency Dioxin Data From Sweden. (Chart) Undated (36) 513737 40-8093046 U.S. Environmental Protection Agency, Industrial Environmental Research Lab. (Cincinnati, Ohio) Dioxins. PEDCO Environmental, Inc., Contract No. 68-03-2577; Wright State Univ., Contract No. 68-03-2659; and Walk, Haydel and Assoc., Inc., Contract NO. 68-03-2579. November 1980 (37) 513724 40-8393073 U.S. Environmental Protection Agency, Office of Water Regulations and Standards, Office of Solid Waste and Emergency Response and the Dioxin Task Force Dioxin Strategy. November 28, 1983 (38) 513738 40-8493074 U.S. Environmental Protection Agency, Office of Water Regulations and Standards Ambient Water Quality Criteria for 2.3.7.8-Tetrachlorodibenzo-p-Dioxin. February 1984 (39) 513739 B2-15 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002 b 2-f i l e Fiche # 40-8493075 U.S. Environmental Protection Agency, Office of Solid Waste and Emergency Response (40) 513740 Health and Environmental Effects- _- , * /Bro^T>B -for Tetra-. Penta- and ffg&atfhLotefS&ibenzo-p-Dioxins. (Final -&rafti-- EPA-* Environmental Criteria and -Assessment Office, Cincinnati, Ohio. August 1984 L 40-8493063 U.S. Environmental Protection Agency Cover letter from K.E. McCaleb,^ Stanford Research Institute international-- ttr-B*. Tobin, EPA December 21, 1984 Enclosure : (1) Hexachlorobenzene: Chemistry of Formation and Identified Sources (Draft) SRI Contract No. 68-023976; Tech. Directive #2. December 21, 1984 '40a) _ u \ 513733 40-8593076 U.S. Environmental Protection Agency Interim Risk Assessment Procedures for Mixtures of Chlorinated Dibenzodioxins and Dibenzofurans. Position Document of the Chlorinated Dioxin Work Group (CDWG). 1985 [See Enclosure (4) to B2 (29)] (41) 513723 B 2-16 TSCA SECTION 8(d) AND 4(a) , HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002 b 2-f i l e Fiche # 40-8593077 U.S. Environmental Protection Agency, Office of Drinking Water (42) 513741 Drinking Water Criteria Document for 2.3.7.8-Tetrachlorodibenzo-p-Dioxin. (Final Draft) EPA's Environmental Criteria and Assessment Office, Cincinnati, Ohio. March 1985 40-8593078 U.S. Environmental Protection Agency Memorandum to M. Cook. Dioxin M a n a gement)Task Force, from D. Barnes ___________ Dioxins Workgroup, jrecjarding the health) hazard assessment^! Cfor mixtures of CDDs\and CDFs. April 22, 1985 (43) 513742 40-8593079 U.S. Environmental Protection Agency Internal EPA memorandum from A. Mittelman to D. Barnes commenting on the Interim Risk Assessment Procedures document. May 10, 1985 (43a) 513722 40-8593080 U.S. Environmental Protection Agency Summary of Comments (and Responses) at TEF Work Group. May 14, 1985 (44) 513743 B 2-17 31 % TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002 b 2-f i l e Fiche # 40-8593081 U.S. Environmental Protection Agency (4^) 513744 Internal EPA memorandum from J. Stara, Environmental Criteria and Assessment Office (Cincinnati, Ohio), to H. SpirtrzreT and D. Barnes, Dioxins Work (SLr-oup-. reviewing th Chlorinated ^iox-irrs--We^k. Groups ' proposal on the 4 . ^assessmen^) ot CfTlorinatea Dioxins a ~ -r l -,and~DH7gn~ztifurana ^ M a y 17, 1985 , > r 40-8593082 U.S. Environmental Protection Agency Press Advisory: Production of Dacthal Containing Dioxin Traces. June 10, 1985 (46) 513745 40-8593083 U.S. Environmental Protection Agency Letter from S. Rudzinski to E. Silbergeld (and other addressees listed on attached list) requesting a review of documents attached. June 20, 1985 Enclosures : (1) List of addresses. (2) Ouestions/Issues on the Dioxin/ Furan List and Methodology (EPA). (3) Guidance for a Sequential Approach to the Sampling of Dibenzodioxins and Dibenzofurans. (Draft) (4) Guidance for Sampling Brominated and Chlorinated Dibenzofurans and Dibenzodioxins. (Draft) (47) 513746 B 2-18 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002 b 2-f i l e Fiche # 40-8593083 (continued) (5) Quality Assurance Plan for 14eafstfhement of Brominated and Dibenzofurans and Dibenzodioxins.v (Draft) ( 6 ) Development of the List of /Cifrgicals to be Proposed for jgVjfiv ^ (7) Summary of Current Commercial Status and Use. 40-8593084 U.S. Environmental Protection Agency Letter from S. Lee to P.W. Albro, USDHHS , NIEHS (RTP, NC) and addresses listed on attachment, requesting a review of the preliminary list of chemicals to be tested, the rationale for selection of chemicals and the analytical guidelines for testing. June 20, 1985 Enclosures: (1) Ouestions/Issues on the Dioxin/ Furan List and Methodology. (EPA) (2) List of addresses. (3) LisfT of chemicals to be tested. (4) Rationale for selection of chemicals. (5) Analytical guidelines for testing. [See B2 (47) for Enclosures (3)^ (4) and. (5)] U (48) 513747 B2 - 1 9 4o <2.03 [o TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002 b 2-f i l e Fiche # 40-8593052 U.S. Environmental Protection Agency (48a) 513719 Guidelines for the Determination of Polvhalogenated Dibenzo-p-Dioxins and Dibenzofurans in Commercial Products. (Draft Final Report)'Midwest Research Institute; Contract No. 68-02-3938. June 27, 1985 40-8593050 U.S. Environmental Protection Agency Survey of Dioxin Testing Laboratories. (Draft) Mathtech, Inc.; Contract No. 68-01-6630.' July 3, 1985 (48b) 513717 40-8593085 U.S. Environmental Protection Agency Internal EPA memorandum from R. Harless to S. Rudzinski reviewing the five documents enclosed. July 11, 1985 Enclosures : (1) Development of the List of, _ ftdirr}cals to be Proposed for (49) 513748 (2) Summary of Current Commercial Status and Use. (3) Guidance for Sequential Approach to the Sampling of Dibenzodioxins and Dibenzofurans. (4) Guidelines for the Determination in Commercial Products. Midwest Research Institute. June 3, 1985 B 2-20 lS~il TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002 b 2-f i l e Fiche # 40-8593085 (continued) (5) Ouestions/Issues on the Dioxin/ Furan List and Methodology. [See.B2 (47) for all Enclosures] 40-8593086 U.S. Environmental Protection Agency, Environmental Chemistry Laboratory, MS (49a) EPA letter from A. Dupuy to S . y t ^Rudzinskf) reviewing the list of ruhgmrcaTg^to bg/tested for Dioxin/Furan (L&-r f ^ tpr es ne dLramination and the method to be ^ July 24, 1985 513698 40-8593187 U.S. Environmental Protection Agency Letter from J. Beilin and D. Barnes to E. Silbergeld, Environmental Defense Fund, in response to EDF's reaction to EPA's assessment of hazards for -- ChToT^nated Dioxins and Dibenzofurans. July 24, 1985 (50) 513749 40-8593087 U.S. Environmental Protection Agency, Office of Solid Waste and Emergency Response .Lt. /^ ^ OHealth and Environmental Effects f rPrbfTYe^ for Brominated Dibenzo-p- ~ giox~iyris^ Draft) EPA's s m TironmontalCriteria and Assessment Of-f-Lce.^ Cincinnati , Ohio. August 1985 (51) 513750 B 2-21 JOS'/A TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002 b 2-f i l e Fiche # 40-8593064 U.S. Environmental Protection Agency (51a) 513734 Dioxin/Furan Screening: Production and Process Identification of Subject ___ /gfegMcals. (Revised Draft) Stanford Institute International; S 68-02-3976, Tech. ractrivo. N o . /Jo t-ja / o > ^August 1985 40-8593032 U.S. Environmental Protection Agency Market Study of Selected Chemical Products Possibly Contaminated with Dioxins and Dibenzofurans. Dynamac Corp.; Contract No. 68-02-3952. August 19, 1985 (51b) 513699 40-8593088 U.S. Environmental Protection Agency, Chlorinated Dioxin Workgroup Interim Risk Assessment Procedures for Mixtures of Chlorinated Dibenzodioxins and Dibenzofurans. Revised Position Document. October 1985 [Document Not Provided to Docket] (51c) B 2-22 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002 b 2-f i l e Fiche # 40-8593089 U.S. Environmental Protection Agency (52) 513751 Internal memorandum from I. Baumel to J. Beilin reviewing the CDWG's Position Document on the "Interim Risk -A ssessment- Procedures for Mixtures of 0h4jOiJjaatd^ Dibenzodioxins anWd<l ^Dibenzofurans." ---------V October 24, 1985 Enclosures: (1) Comments. (2) Genetically Mediated Induction of Arvl Hydrocarbon Hvdroxvlase Activity in Human Lvmphoblastoid Cells bv Polychlorinated Dibenzofuran Isomers and 2.3.7.8-Tetrachlorodibenzo-p-Dioxin. J . Nagayama, C. Kiyohara, Y. Masuda, M. Kuratsune. Arch. Toxicol.; 56: 230-235. 1985 40-8593092 U.S. Environmental Protection Agency List of Chemicals Contaminated or Precursors to Contamination with Incidentally Generated Polychlorinated and Polvbrominated Dibenzodioxins and Dibenzofurans. Versar, Inc.; Contract No. 68-02-3968. October 30, 1985 (53) 513754 40-8593090 U.S. Environmental Protection Agency Internal memorandum from R. Morgan to D. Barnes regarding OWPE comments on the CDWG Position Document: "Interim Risk Assessment Procedures for Mixtures of Chlorinated Dibenzodioxins and Dibenzofurans (CDDs and CDFs)." October 31, 1985 B 2-23 (54) 513752 5 1 *-/ TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002 b 2-f i l e Fiche # 40-8593049 U.S. Environmental Protection Agency (55J 513755 Cost Analysis for the Determination of Polvhalogenated Dioxins and Dibenzofurans in Commercial Products. Martin Marietta Data Systems, Mathtech Div. Contractor; Versar Inc. subcontractor. November 25, 1985 40-8593091 Versar, Inc. Internal Versar memorandum on the In Vitro testing of Dioxins from B. Gregg and D. Dixon to B. Boethling. May 21, 1985 (56) 513753 B 2-24 TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002B B3 -FILE Fiche # 40-8693093 Chemical Industry Institute of Toxicology (1) 513756 Letter from R. Neal to V. Kim reviewing the revised procedures for estimating risk exposures. January 24, 1986 Enclosure: ( 1 ) Data from C. Boreiko's (CUT) ^ Strwsty with TCDD, 2,7-DCDD, < L , 2Y3 7 >TF>^)HCDD and 1 ,2 ,3,6 ,7,8 -//(> PP. Heee-r ( 2 ) 2.3.7.8 -Tetrachlorodibenzo-p-./w1<-/,~/ B-iroxlrr (TCDD Promotes the ^^ Transf ormatIdnj ot l U T / 2 f/ L s ' -/ (^^]^xt7 ~fQvJj~Abernathy, W.fT ^ 1 ./ ctfreeiiTee , jTc ^ Huband , and C.J. 3^^e'-Te^>,. Carcinogenesis; / f ^ 6(4) :651-653.-------- ----- 1985 40-8693094 Environmental Defense Fund (2) 513757 Cover letter from E. Silbergeld to S. Rudzinski, EPA June 12, 1986 Enclosures : (1 ) Automated Apparatus for the ^ I s m l a J L - * ^tTightion and Enrichment of ;2.-?7/^^ _ -- fTWTVff^iTetrachlorodibenzo-p-Dioxin Human Adipose Tissue. C.R. . Lpefra* Jr., D.G. Patterson, Jr.c x * J f > /r f _^_an<d--3v?k Liddle (U.S. Department .t r H - S e-Lr-HHS-, Center for Disease CtJ C tr J c ^ -- Gontrol4-.~ Analytical Chemistry; ^ ^ ( u ) ; --? J 3 5'mT>T3V716. April 1986 B 3-l ^ 0 ^ 1 c, TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002B B 3 -FILE Fiche # 40-8693094 (continued) (2) High-Resolution Gas Chromatographic/High-Resolution Mass Soectrometric Analysis of Human Adipose Tissue for 2.3.7.8Tetrachlorodibenzo-p-Dioxin. D.G! Patterson, J.S. Holler, C.R. Lapeza, Jr., L.R. Alexander, D.F. Groce, R.C. O 'Connor, S.J. Smith, J.A. Liddle and L.L. Needham (USDHHS, Center for Disease Control). Analytical Chemistry; 58(4): 705-713. April 1986 40-8693095 Great Lakes Chemical Corporation Cover letter from C. O 'Connor of McKenna, Conner and Cuneo to S . Rudzinski, EPA June 9, 1986 Enclosure: (1) Comments on Recent Publications Relating to the Determination of Halogenated Dibenzodioxins and Dibenzofurans in Commercial Products. Great Lakes Chemical Corporation. June 2, 1986 (3) 513758 Ij-f] S-o5" I*7 TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002B B 3 -FILE Fiche # 40-8693097 U.S. Environmental Protection Agency (4) 513761 Internal EPA memorandum from P. Tong to S. Lee and K. McCormack responding to a Manufacturer's comments on the health effects of Tetrabromobisphenol A. August 21, 1986 40-8593096 U.S. State Department of Health Letter from J. Hawley to D. Barnes, EPA, commenting on the October 1985 version of the CDWG Position Document. December 27, 1985 Enclosure: (1) Reasoning for wording change from "root mean square" to "geometric mean" on page 8 , Section 4 of the "CDWG Position Document on Risk Assessment Procedures for Mixtures of CDDs and CDFs." (5) 513759 40-8693098 Wisconsin, University of, McArdle Laboratory for Cancer Research Letter from A. Poland to D. Barnes, commenting on the revised interim r^i-sk assessment procedures for Chlorinated Dibenzo-p-Dioxins. January 6 , 198 6' (6 ) -/ 513760 B 3-3 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002C B 4-FILE Fiche # 40-7993020 40-8393162 Albro, P.W., Luster, M.I., Chae, K., Chaudhary, S.K., Clark, G., Lawson, L.D. , Corbett, J.T. and McKinney, J.D. (U.S. Department of Health and Human Services, National Institute of Environmental Health Sciences, Research Triangle Park, NC) A Radioimmunoassay for Chlorinated Dibenzo-p-Dioxins. Toxicology and Applied Pharmacology; 50:137-146. 1979 [Crossreferenced to r2 <']2 )] t*rC> Bandiera, S. (University of Guelph, Ontario Canada), Sawyer, T.W. (Texas A&M-University), Campbell, M.A. -(Univ ersity of Guelph, Ontario, - ) ^Fuj ita,--T-r (Kyoto Uni vers it y , (Japan) and Safe~, Si) (Texas A&M ' University) Competitive Binding to the Cytosolic 2.3.7.8-Tetrachlorodibenzo-p-Dioxin Receptor. Effects of Structure on the Affinities of Substituted Halogenated Biphenvls-A Osar Analysis. Biochemical Pharmacology; 32 (24 ): 3.803-3.813 .. 1983 (1) (2) r ic i^ tu / /} 513683 513762 40-8493021 Bandiera, S., Sawyer, T . , Romkes, M . , Zmudzka, B . , Safe, L., Mason, G., Keys, B. and Safe, S. (Texas A&M University, College of Veterinary Medicine) Polychlorinated Dibenzofurans (PCDFs): Effects of Structure on Binding to the 2.3.7.8-TCDD Cytosolic Receptor > AHH Induction and Toxicity. ^ TOScecrt'ogyv 32:131-144. ' 1984 [Crossreferenced to B2 (3)] B 4-l (3) 513685 uJ GLo S l TSCA SECTION 8 (d) AND 4(a) / HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002C B 4-FILE Fiche # 40-8493002 Beilin, J.S. and Barnes, D.G. Health Hazard Assessment for 7 (4) October 25, 1984 [Crossreferenced to B2 (3a) - Document Not Provided to Docket] 40-7993022 Bradlaw, J.A. and Casterline, J.L. (U.S. (5) 513687 Department of Health, Education, and Welfare, Food and Drug Administration) v Induction of Enzyme Activity in Cell Culture: A Rapid Screen for Detection of Planar Polychlorinated Organic Com pounds . J. Assoc. Off. Anal. Chem.; 62(4):904-916. 1979 [Crossreferenced to B2 (4)] B 4-2 TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFUlANS SUPPORT REFERENCES FOR DOCKET #83002C b 4-f i l e F iche # 40-8693184 Cambridge Isotope Laboratories V (5a) 513763 Cover letter from J. Bradley to M. Dreyfus, EPA July 8 , 1986 Enclosures: ^ (1) Summary of `^ T O /86 Phone Conver sation Between Mark Drevfus. USEPA. and Dr. Joel Bradley. CIL. (2) Quality Standards From Cambridge Isotope Labs, and Radian Corn. (3) Proposed Rule Stock Status of Standards. (4) Form letter from Dr. J. Bradley, CIL, to "Participating Labs" regarding the proposed inter laboratory testing program. 40-8593025 Canada Environmental Protection Letter from M. Boddington to D. Barnes, EPA August 28, 1985 Enclosure: (1) Tnterim_Risk Assessment leview Comments, K -- 1Crossreferenced to B2 (7)] (6 ) 513690 B 4-3 5( TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002C b 4-f i l e Fiche # 40-8493163 Cull, M.R., Dobbs, A.J. (Princes Risborough Lab., Buckinghamshire United Kingdom), Goudot, M. (Rhone-Poulenc, Le Pont de Claix, France) and Schultz, N. (Dynamit Nobel AG, Federal Republic of Germany) Polvchlorodibenzo-p-Dioxins and Diben^y/) -- y'aftfurans in Technical Pentachlorophenol -- /^Results of a Collaborative Analytical Exercise. Chemosphere; 13(10):1157- r=p ^ 1984 (7) 513764 .- 40-8493164 Czuczwa, J.M. and Hites, R.A. (Indiana University) Environmental Fate of CombustionGenerated Polychlorinated Dioxins and Furans. Envir. Sci. Techno 1; 444-450. 1984 (8 ) 513765 40-8593165 Czuczwa, J.M., McVeety, B.D. and Hites, R.A. (Indiana University) Polychlorinated Dibenzodioxins and^ Dibenzofurans in Sediments froi Lake. Isle Royale. (L eflinSpQerf> 14(6/7) :6 23-6 26. 1985 , (9) 513766 40-8593001 Dow Chemical USA Review and Trends in the Analysis for PCDD/PCDF. Dow Chemical USA. 1985 [See C4 (3) Enclosure- (2a)] (10) 513786 B 4-4 5^ TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-E-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002C b 4-f i l e Fiche # 40-8493034 Environmental Defense Fund Cover Letter from R. Percival to W.D. Ruckelshaus, EPA October 22, 1984 Enclosure: (1) Petition of the Environmental Defense Fund and the National \ n A A ' -- : lW iTCftlife Federation for RuTfetnakim^S-X^ Prevent and to <-U7educe"'Etiva^N^nirranted> Contamination ^rv--Duox-i>nis^~knd~BiidSizofurans. E . gi-djagr^g^dryHl Percival (EPF) , M.^ (tfan Putten and^jLTT! Silbert ife Federation) . October 22, 1984 [Crossreferenced to E3a (l)] (11) 513902 w . K' 40-8493167 Germany (Federal Republic of), Federal Health Office Report on Dioxins (Sachstand Dioxine) - Update to November 198 4. (German " v^atoslation) 1984 (12) 513768 B 4-5 83 TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002C B 4-FILE Fiche # 40-8493040 Gierthy, J.F., Crane, D. and Frenkel, G.D. (N.Y. State Department of Health, Wadsworth Center for Laboratories and Research) Application of an In Vitro Keratinization Assay to Extracts of Soot From a Fire in a Polychlorinated BiphenvlContaining Transformer. Fundamental and Applied Toxicology; 4:1036-1041. 1984 [Crossreferenced to B2 (18)] (13) 513706 40-8593042 Helder, Th. and Seinen, W. (State University of Utrecht, The Netherlands) Standardization and Application of an E .L .S .-Bioassay for PCDDs and PCDFs. Chemosphere; 14(2):183-193. 1985 [Crossreferenced to B 2 (20)] (14) 513710 40-8693168 Hoar, S.K., Blair, A. National Cancer Institute Holmes, F.F., Boysen, C.D. (University of Kansas Medical Center), Robel, R.J. (Kansas State University), Hoover, R. and Fraumeni, J.F. (National Cancer Institute) Agricultural Herbicide Use and Risk of Lvmphoma and Soft-Tissue Sarcoma. S '4 M ft 256 (9) :1141-1147. September 5, 1986 (15) 513769 B4 -6 TSCA SECTION 8 (d) AND 4(a) / HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002C B 4-FILE Fiche # 40-8193044 Hutzinger, 0., Olie, K . , Lustenhouwer, J.W.A. (University of Amsterdam, The Netherlands) Okey, A.B. (Hospital for Sick Children, Ontario, Canada), Bardiera, S. and Safe, S. (University of Guelph, Canada) Polychlorinated Dibenzo-p-Dioxins_and Dibenzofurans : A Bioanalvtical Chemosphere ; 10:19-25. 1981 . [Crossreferenced to B2 (22)] (16) 513713 40-8093048 Knutson, J.C. and Poland, A. (University of Wisconsin) Keratinization of Mouse Teratoma Cell Line XB Produced bv 2.3.7.8 -Tetrachlorodibenzo-D-Dioxin: An In Vitro Model of Toxicity. Cell; 22:27-36. November 1980 [Crossreferenced to B2 (25)] (17) 513716 40-8593169 Mason, G . , Sawyer, T . , Keys, B . , Bandiera, S., Romkes, M . , PiskorskaPliszczynska, J . , Zmudzka, B. and Safe, S. (Texas A&M University) Polychlorinated Dibenzofurans (PCDFs): Correlation Between In Vivo and In Vitro Structure-Activity Relationships. Toxicology; 37:1-12. 1985 (18) 513770 B 4-7 5F TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002C B 4-FILE Fiche # 40-8293051 McKinney, J., Albro, P., Luster, M. Corbett, B . , Schroeder, J. and Lawson, L.' (U.S. Department of Health and Human Services, National Institute of Environmental Health Sciences, Research Triangle Park, NC) Development arid Reliability of a Radio immunoassay for 2.3.7.8 -Tetrachlorodibenzo-p-Dioxin. From "Chlorinated Dioxins and Related Compounds; Impact on the Environment". Proceedings held in Rome, Italy, October 22-24, 1980. 1982 [Crossreferenced to B2 (26)] (19) 513718 40-8293004 McKinney, J. and McConnell, E. Structural Specificity and the Dioxin Receptor. From "Chlorinated Dioxins and Related Compounds: Impact on the Environment"; pages 367-381. 1982 (20) 513771 40-7993170 Moore, J.A., McConnell, E.E. (National Institute of Environmental Health Safety, Research Triangle Park, NC), Dalgard, D.W. (Hazleton Res. Labs, of America, Inc.) and Harris, M.W. (National Institute of Environmental Health Sciences, Research Triangle Park, NC) Comparative Toxicity of Three Halogenated Dibenzofurans in Guinea Pias. Mice, and Rhesus Monkeys. Annals New York Academy of Sciences; 320:151-163. 1979 (21) 513772 B4 - 8 TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002C b 4-f i l e Fiche # 40-8693171 Patterson, D.G., Jr., Hoffman, R.E. Needham, L.L. (Centers for Disease Control), Roberts, D.W., Bagby, J.R. (Missouri Department of Health), J.L. , Falk, H. , Sampson, E. J. jntL-Heuk^ V.N. (Centers for Disease Confer^)- 2.3 . 7 .8 -Tetrachlorodibenzo-p-Dioxin Levels in Adipose Tissue of Exposed and Control Persons in Missouri. JAMA; 256(19):2683-2686. November 21, 1986 ( 22) 513773 40-8693098 Wisconsin, University of, McArdle Laboratory for Cancer Research Letter from A. Poland to D. Barnes, EPA, commenting on the revised interim risk assessment of Dibenzo-p-Dioxins and Dibenzofurans. January 6 , 1986 [Crossreferenced to B 3 (6 )] (23) 513760 40-8293058 Poland, A. and Knutson, J.C. (McArdle Lab. for Cancer Research, University of Wisconsin) 2.3.7.8 -Tetrachlorodibenzo-p-Dioxin and Related Haloaenated Aromatic Hydro carbons: Examination of the Mechanism of Toxicity. Ann. Rev. Pharmacol. Toxicol.; 22:517-554. . 1982 [Crossreferenced to B2 (30)] (24) 513725 B 4-9 51 TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002C b 4-f i l e Fiche # 40-8493059 Safe, S., Sawyer, T . , Bandiera, S., Safe, L . , Zmudzka, B . , Mason, G . , (College of Veterinary Medicine, Texas A&M University), Romkes, M . , Denomme, M. A. (University of Guelph, Ontario) and Fujita, T. (Kyoto University, Japan) Binding to the 2.3.7.8-TCDD Receptor and AHH/EROD Induction: In Vitro OSAR. "Banbury Report 18: Biological - (ijedfiknisms of Dioxin Action"; 33:135-/^^ ' V 1984 [Crossreferenced to B2 (31)] (25) 513728 ,- 40-7393172 Schwetz, B .A ., Norris, J.M., Sparschu, G.L., Rowe, V.K., Gehring, P.J., Emerson, J.L. and Gerbig, C.G. (The Dow Chemical Company) Toxicology of Chlorinated Dibenz.o-pDioxins. Environmental Health t Pensp^vtives ; 5:87-89. September 1973 (26) 513774 40-8693173 Thoma, H . , Rist, S., Hauschulz, G. and Hutzinger, 0. (University of Bayreuth, Federal Republic of Germany) Polvbrominated Dibenzodioxins and F^grarrS from the Pyrolysis of Some Flame (Rtetatfdants. Chemosphere; 15(5): 649 1986 (27) 513775 . B 4-10 b^ TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002C B4 -FILE Fiche # 40-8793003 Thoma, H. et al. Polvbrominated Dibenzofurans (PBDF) and Dibenzodioxins (PBDD) from the BvrblVjBir^ of Neat Brominated /I v ' (grphenvlethets^ ;BiPhenvis and Plastic^ fktrnr~dg Of~~Th^se \ C o m p o u n d s * emosphere. (In Press) --- ^ 1987 , [Document Not Provided to Docket] (28) 40-8093046 U.S. Environmental Protection Agency Dioxins. PEDCO Environmental, Inc., Contract No. 68-03-2577; Wright State Univ., Contract No. 68-03-2659; and Haydel and Associates Inc., Contract NO. 68-03-2579. November 1980 [Crossreferenced to B 2 (37)] (29) 513724 40-8293166 U.S. Environmental Protection Agency Pre-Regulatorv Analysis of Flame (Rey^rdants. Dynamac Corp. ContracztXjJfrrx>No. 68-01-6239. ^--------v May 7, 1982 (29a) 513767 40-8393073 U.S. Environmental Protection Agency, Office of Water Regulations Standards, Office of Solid Waste and Emergency Response and the Dioxin Task Force Dioxin Strategy. November 28, 1983 [Crossreferenced to B2 (38)] (30) 513738 B4 - 1 1 TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002C B 4-FILE Fiche # 40-8493074 U.S. Environmental Protection Agency, Office of Water Regulations and Standards Ambient Water Quality Criteria for 2.3.7.8 -Tetrachlorodibenzo-Dioxin. February 1984 [Crossreferenced to B 2 (39)] (31) 513739 40-8493063 U.S. Environmental Protection Agency Cover letter from K.E. McCaleb, Stanford- Research Institute to P.^i December 21, 1984 Enclosure: (1) Hexachlorobenzene: Chemistry of Formation and Identified Sources (Draft) Stanford Research Insti tute; Contract No. 68-02-3976, Tech. Directive #2. December 21, 1984 [Crossreferenced to B2 (40a)] (31a) 513733 B 4-I2 &0S30 TSCA SECTION 8 (d) AND 4(a) / HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002C B4 -FILE Fiche # 40-8593052 U.S. Environmental Protection Agency Guidelines for the Determination of Polvhalogenated Dibenzo-p-Dioxins and Dibenzofurans in Commercial Products. (Draft Final Report) Midwest Research Institute; Contract No. 68-02-3938. June 27, 1985 [Crossreferenced to B2 (48a)] (3lb) 513719 40-8593187 U.S. Environmental Protection Agency Letter from J. Beilin and D. Barnes to v E. Silbergeld, Environmental Defense Fund, in response to EDF's reaction to EPA's assessment of hazard for Chlori nated Dioxins and Dibenzofurans. July 24, 1985 [Crossreferenced to B2(50)] (31c) 513749 40-8593092 U.S. Environmental Protection Agency (31d) List of Chemicals Contaminated or Pre cursors to Contamination With Inciden tally Generated Polychlorinated and Polvbrominated Dibenzodioxins and -- /frThr^H'zofurans. Versar , Inc. ; Contract / / 0 68-02-3968. October 30, 1985 > [Crossreferenced to B2 (53)] 513754 B 4-13 sostsi 6/ TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002C B4 -FILE Fiche # 40-8693174 U.S. Environmental Protection Agency, Science Advisory Board Report of the Science Advisory Board's Dioxin Toxic Equivalency Methodology Subcommittee Following its Evaluation of EPA's Toxic Equivalency Factor Methodology for CDDs and CPFs. 1986 (32) 513776 `' 40-8693193 U.S. Environmental Protection Agency Internal memorandum from J. Smith to M. Dreyfus on the analytical standards for Polybrominated Dibenzofurans and Polybrominated Dibenzodioxins. August 4, 1986 (32a) . 513777 40-8693176 U.S. Environmental Protection Agency (32b) Letter from L. Thomas to N. Nelson, Science Advisory Board December 19, 1986 Enclosure: (1) Response to SAB Comments on the "Interim Procedures for Estimating Risks Associated With Exposures to Mixtures of Chlorinated Dibenzo-jo- n5^Dioxins and Dibenzofurans f o n ,^>r / r t ^ p y C D F s l ." --------------- 513778 40-8793194 U.S. Environmental Protection Agency Interim Procedures for Estimating Risks Associated With Exposures to Mixtures Chlorinated Dibenzo-p-Dioxins and Izofurans (CDDs and CPFs). March 1987 (33) 513779 b 4 -i4 65- TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002C b 4-f i l e Fiche # 40-8793190 U.S. Environmental Protection Agency Internal EPA memorandum from D. Keehner to the Dioxin/Furan rulemaking record on the exposure assessment to support target limits of quantitation. May 6,1987 (34) 513780 40-8793191 Versar, Inc. Internal Versar memorandum from C. Carpenter to B. Boethling on the docu mentation for the November 4, 1986 memo concerning the organic chemical dermal exposure estimates to DBDs/DBFs. April 10, 1987 (35) 513781 40-8793189 Versar, Inc. Internal Versar memorandum from D, Dixon >to L . Bryan on the dermal ^ (Exposure toTThadvertently produced ^ CDioxins inrCTiemical plants. April 29, 1987 Enclosures: (1) Internal Versar memorandum from D. Dixort to B. Boethling on the revised estimates of worker dermal exposure to DBDs/DBFs during organic chemical synthesis. November 4, 1986 (36) 513782 sure to DBDs/DBFs During Organic Chemical Synthesis^ refill Use Estimated bv Method / B 4 -I5 L3 TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS SUPPORT REFERENCES FOR DOCKET #83002C B 4 -FILE Fiche # 40-8793189 (continued) (b) Table 2. Worker Dermal Expo sure to DBDs/DBFs During Organic Chemical Synthesis and Use Estimated by Method 2. (c ) Table 26. Worker Dermal fyya> /j^xT^fisure to DBDs/DBFs Durlrrg Organic Chemical Synthesis and Use. - 40-8793192 Versar, Inc. Internal Versar memorandum from D. Dixoft to L. Bryon April 30, 1987 Enclosure: (1) Resumes for C. Carpenter, D. E. Rissmann a: Hergenrader. ------- (37) 513783 B4 -I6 TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS PUBLIC COMMENTS FOR DOCKET #83002 Ci-FILE Fiche # 40-8693099 Ameribrom, Inc. Comments of Ameribrom. Inc, on EPA's Proposed Testing and Reporting Rules for Polvhaloaenated Dibenzodioxins and Dibenzofurans. A. Tillman. February 18, 1986 . (1) 513784 J . 40-8693100 Cambridge Isotope Laboratories Comment letter from J. Bradley to EPA. February 14, 1986 (2) 513785 40-8693101 Chemical Manufacturers Association Comment letter from G. Cox to M. Halper, EPA February 18, 1986 Enclosures : (1) Letter from R. Fensterheim, CMA, to J. Moore submitting the comments and requesting a meeting with EPA. February 18, 1986 (a) Comments on EPA's Proposed Testing and Reporting Rules for Polvhalogenated Dibenzo dioxins and Dibenzofurans. 1. Appendix A - Letter from G. Cox, CMA, to S. Rudzinsky, EPA, comment ing on the preliminary list of chemicals. July 19, 1985 (3) 513786 C i-l C5~ TSCA SECTION-8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-E-DIOXINS/DIBENZOFURANS PUBLIC COMMENTS FOR DOCKET #83002 Cj-FILE Fiche # 40-8693101 (continued) a. Attachment I : Response of the Chemical Manufac- . _ turers Association Dibenzofurans/Dibenzodioxins Program Panel to EPA's (\Y u U Omettions Concerning""5 Proposed Cand/j^ifi i^a^e^List and Analv^p Methodology. b. Attachment II: Principles of Envi ronmental Analysis. American Chemical Society. c . Attachment III: EPA's Soil Screening Survey at Four Mid western Sites Quali ty Control Summary. USEPA Region V, Central Regional Laboratory. May 1985 2a. Appendix B: Review and Trends in the Analysis for PCDD/PCDF. Dow Chemical U S A - W.B. Crummett, L.L. Lamparski and T.J.g Nestrick. 1985 9 C x-2 <Sk&S3 Qs TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING / TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS PUBLIC COMMENTS FOR DOCKET #83002 C 2.-FILE Fiche # 40-8693101 (continued) 2b. Polychlorinated Dibenzodioxins and Dibenzo^^ig^ b /<tffrayrs in SedimentsT from r: JLake . Is1 r lL I /(^RoV^TgT>t7r% .M*T^Crue z'va -McV^et y ^ a n d J Hites 0 TIndianannlvefsity).-4 ^ Chemosphere; 14(6/7): 623-626. 1985 a* 4 2c. Environmental Fate of Combustion-Generated Polychlorinated Dioxins and Furans. J.M. Czuczwa and R. Hites (Indiana University). Environ. Sci. Tech.; 18(6):444450. 1984 2d. An Evaluation of Reports of Dioxin Exposure and Soft Tissue Sarcoma.^,, f Pathology in U. S. {* * & * & ^. r f/S ( p o ^hginircal Workers. M.A. Fingerhut, W.E. Halperin, P .A. HonChar, A.B. Smith, D.H. Groth, (USDHHS, NIOSH) and W.O. Russell (North Ridge General Hospital and Cancer Foundation). Banbury Report; 18:461-470. 1984 Ci-3 7 ^0537 TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS PUBLIC COMMENTS FOR DOCKET #83002 Cj^-FILE Fiche # 40-8693101 (continued) 2e. Chlorocarbons in Adipose Tissue from a Missouri Population. M. Graham, F. Hileman, R.G. Orth, J.M. Wendling and J.D. Wilson'(St. Louis Univ. School of Medicine and Monsanto Co.). Chemosphere (in press). 1986 V 2 f , Health Implications of 2.3.7.8 -Tetrachloroffi^yt frirbgtyzodioxin (TCDD) Cfifcnlnation of Soi 1. R . a T en ter fo r ^ 2 jealth^ rsease ) and . Dept._of J Tojcrtro-i^and Environ. HeaTtILf^U'W47-9 3. 1984 la {))\ ; 2 g. Scientific Criteria Docu ment for Standard "-- Development. No.4-84 Polychlorinated Dibenzop-Dioxins (PCDDS) and Polychlorinated Dibenzofurans (PCDFs). Ontario Ministry of the Environ ment. Pages l-l to l56, 3-130 to 3-147. September 1985 Ci-4 6^ O 53 3 TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS PUBLIC COMMENTS FOR DOCKET #83002 Cj^FILE Fiche # 40-8693101 (continued) 2h. A Critical Examination of Assessments of the Health Risks Associated with 2.3.7.8-TCDD in Soil. D.J. Paustenbach and F.J. Murray (Syntex (USA) Inc.). Chemosphere (din Press). . 1986 2i. Update on Soft Tissue Sarcoma and Phenoxvher- bicides in New Zealand. A.H. Smith (Univ. of Calif.) and N.E. Pearce (Univ. of North &aT>cftpna) . From "Dioxin, 85"; the Fifth Interna- ( tional Symposium on ( Chlorinated Dioxins and I Related Compounds, September 21, 1985 in / Mitwitz, FRG. Chemo- 1 sphere (in Press). 1986 < C jl-- 5 6? S L O S 3 c? TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS PUBLIC COMMENTS FOR DOCKET #83002 C1~FILE Fiche # 40-8693109 -- 2,4-D Task Force Cover letter from J.D. Conner of McKenna, Conner and Cuneo to Document Control Officer, EPA February 14, 1986 Enclosures: (1) Comments on Proposed Testing and Reporting Rules Under the Toxic Substances Control Act for Polvhalogenated Dibenzodioxins and Dibenzofurans. February 14, 1986 (2) Letter from J. Conner, Jr., McKenna, Conner and Cuneo, to E. Johnson, EPA, concerning unregistered 2,4-D Acid being imported and sold into the United States. June 16 , 198 3 (a) Weedone 138. Label for herbicide containing 2,4-D Acid. Union Carbide Corp. 1982 (3) Letter from E. Johnson, EPA, to J. Conner, Jr., McKenna, Conner and Cuneo, responding to his letter of June 16, 1983. August 31, 1983 (3a) 513795 C 1-6 no TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS PUBLIC COMMENTS FOR DOCKET #83002 Ci-FILE Fiche # 8693102 (The) Dow Chemical Company Cover letter from P. Brown to Document Control Officer, EPA February 17, 1986 Enclosures: (1) Comments of the Dow Chemical Company on EPA*s Proposed Testing and Reporting Rules for Polvhalogenated Dibenzodioxins and Dibenzofurans. February 17, 1986 (2) Cost Analysis for the Determination of Polvhalogenated Dioxins and Dibenzofurans in Commercial Products. Martin Marietta Data Systems; Versar, Inc. 1985 (3) Summaries of Completed Toxicology Studies bv the Industry Task Force on 2.4-D Research Data. (4a) Pharmacokinetics of 2.4-Dichlorophenoxv Acetic Acid (2.4-D) in Fischer 344 Rats. F .A . Smith, K.J. Nolan, E .A . Herman and W.E. Braun (The Dow Chemical Co.) (Abstract) Abstracts of Papers No. 180 Society of Toxicology, Inc.; 19th Annual Meeting, Wash., D.C., March 9-13, 1980. March 1980 (4) 513787 C l -7 TSCA SECTION- 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS PUBLIC COMMENTS FOR DOCKET #83002 C 1-FILE Fiche # 40-8693102 (continued) (4b) 2.4-D ((2.4-Dichlorophenoxv) Acetic Acid): Results of a 13-Week Feeding Study in CDF Fischer 344 Rats. S. J_ Gorzinski, R.J. Kociba, C.E. Wade, D.c. Morden, P.G. Keyes and B.A. Schwetz (Dow Chemical USA). (Abstract) The Toxicologist; 1(1):216. March 1981 (4c-l) Neurotoxicologic Assessment of Rats Dermallv Exposed to 2.4-D Amine. J. L. Mattsson, R.R. Albee and K. A. Johnson (Dow Chemical USA). (Abstract) The Toxicologist; 4(1). March 1984 (4c-2) A Teratology Study in Fischer 344 Rats With 2. 4-Dichlorophenoxvacetic Acid. D.E. Rodwell, R.D. Wilson, M.D. Nemec and E.J. Tasker (WIL Res. Labs., Inc.). (Abstract) The Toxicologist; 4(1). March 1984 (4c-3) A Teratology Study in Fischer 344 Rats with 2.4-Dichlorophenol. D.E. Rodwell, R.D. Wilson, M.D. Nemec and M.D. Merciera (WIL Res. Labs., Inc.). (Abstract) The Toxicolgist; 4(1) . March 1984 SKc>^> TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING f TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS PUBLIC COMMENTS FOR DOCKET #83002 C^FILE Fiche # 40-8693102 (continued) (4c-4) Oral Administration of the '^da^lrhexvl (Isooctvl) Ester of 2.4-PS7 <07^(9 Fischer 344 Rats! S .W. >ctL } cFnantygY B.E. Kropscott, y \ /Td o w Chemical USATT^TSbstract) "The Toxicologist 7~b( 1) -- -- -- -- ' March 1985 (5) \ (6 ) NTP Technical Report on the Toxi cology and Carcinogenesis Studies of Decabromodiphenvl Oxide in F344/N Rats and B6C3Fj Mice (Feed Studies). (Draft) USDHHS, NTP. August 1985 Analysis for Brominated Dibenzodioxin and Dibenzofuran Impurities in Two Decabromodiphenvl Oxide Samples. USDHHS, NIEHS. June 20, 1985 (7) Results of a 2-Year Dietary Feeding Study with Decabromodiphenvl Oxide (DBDPO) in Rats. R.L. Kociba, L.O. Frauson, C.G. Humiston, J.M. Norris, C.E. Wade, R.W. Lisowe, J.F. Quast, G.C. Jersey and G.L. Jewett (Dow Chemical USA). J. ' Combustion Toxicology; 2:267-285. November 1975 C x-9 13 alQJa H 3 > TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS PUBLIC COMMENTS FOR DOCKET #83002 Cj-FILE Fiche # 40-8693102 (continued) (8 ) Toxicological and Environmental Factors Involved in the Selection of Decabromodiphenvl Oxide as a Fire Retardant Chemical. J.M. Norris, J.W. Ehrmantraut, C.L. Gibbons, .J. Kociba, B.A. Schwetz, J.Q. Rose, C.G. Humiston, G.L. Jewett, W.B. Crummett, P.J. Gehring, J.B. Tirsell and J.S. Brosier (Dow Chemical Co.). Applied Polymer Symposia No. 2 % : 0jftl95-219. 1973 (9) Toxicology of Qctabromobiphenvl and Decabromodiphenvl Oxide. J.M. Norris, R.J. Kociba, B.A. Schwetz, J.Q. Rose, C.G. Humiston, G.L. Jewett, P.J. Gehring and J.B. Mailhes (Dow Chemical USA), ~~ t fefi^ronmentai Health Perspectives; /// '5^153-161. June 1975 (10) Letter from R. Griesemer and N. Nelson, EPA's Science Advisory Board, to L.M. Thomas, EPA April 26, 1985 (a) Technical Report of the .dSff^ronmental Health Committee < s - EPA's Science Advisory Regarding a Draft Health Sment Document for Polv-^dj^* ch^.o#?nated Dibenzo-p-Dioxins. C 1-10 n TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS PUBLIC COMMENTS FOR DOCKET #83002 Ci-FILE Fiche # 40-8693103 Eastman Kodak Company Comment letter from R. Brothers to Document Control Officer, EPA. February 12, 1986 (5) 513788 40-8693104 Environmental Defense Fund Comment letter from E. Silbergeld to E. Klein, EPA, requesting an opportunity for oral comment. February 3, 1986 (6 ) 513789 40-8693105 Environmental Defense Fund (7) 513790 Cover letter from E. Silbergeld to Document Control Officer, EPA February 18, 1986 Enclosures: (1) Comments of the Environmental Defense Fund on EPA's Proposed Testing and Reporting Requirements for Polvhalogenated Dibenzo-pDioxins/Dibenzofurans. February 18, 1986 (a) Appendix A - Label for Lvsol Disinfectant. (b) Appendix B - Memorandum of Points and Authorities in Support of Plaintiff's Motion for Partial Summary Judgment. R. Percival, EDF and M. Van Putten, NWF. Civil Action No. 85-0973; EDF and NWF vs. L.M. Thomas, EPA. December 16, 1985 C^ll TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS PUBLIC COMMENTS FOR DOCKET #83002 Ci-FILE Fiche # 40-8693105 (continued) (c) Appendix C - Memorandum of Points and Authorities in Opposition to Defendants* Motion to Dismiss and to Defendants' and DefendantIntervenor's Motions for Partial Summary Judgment and in Reply to Defendants' and Defendant-Intervenor's Opposi tion to Plaintiffs' Motion for Partial Summary Judgment. Civil Action No. 85-973; EDF and NWF vs. L. Thomas, EPA. February 11, 1986 (d) Appendix D - Supplemental Declaration of Ellen K. Silbercreld. Civil Action No. 85-973; of EDF and NWF vs. L. Thomas, EPA. February 10, 1986 1 . '' ' " i ifySD reporting rule. 40-8693106 Ethyl Corporation Comment letter from G.L. Ter Haar to Document Control Officer, EPA. February 18, 1986 ( 8 ) 513791 StoSY 6 TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS PUBLIC COMMENTS FOR DOCKET #83002 Ci-FILE Fiche # 40-8693108 Great Lakes Chemical Corporation Comment letter from C. O 'Connor of McKenna, Conner, and Cuneo to Document Control Officer, EPA. February 3,1986 (9) 513792 40-8693110 Great Lakes Chemical Corporation Cover letter from C. O 'Connor of McKenna, Conner and Cuneo to Document Control Officer, EPA February 19, 1986 Enclosures: (1) Comments on Proposed Testing and Reporting Rules Under the Toxic Substances Control Act for Polvhalogenated Dibenzodioxins and Dibenzofurans. (Sanitized) Great Lakes Chemical Corp. February 19, 1986 (2) Technical Comments on Proposed Testing and Reporting Rules Under the Toxic Substances Control Act for Polvhalogenated Dibenzodioxins and Dibenzofurans. Great Lakes Chemical Corp. (Sanitized) February 18, 1986 (3) Appendix A : Curriculum} Vitae for three Great Lakes Chenu^Corp. employees. (4a) Appendix B: Review and Trends in the Analysis for PCDD/PCDF. W.B. Crummett, L.L. Lamparski and T.J. Nestrick (Dow Chemical USA). (10) 513793 C x-13 TSCA SECTION-8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS PUBLIC COMMENTS FOR DOCKET #83002 Ci-FILE Fiche # 40-8693110 (continued) (4b) Letter from D. Rodwell, WIL Res. Labs., Inc., to D. McFadden, Great Lakes Chemical Corp. (Sanitized) . June 7, 1985 (4c) Acute and Chronic Toxicity Testing of 1.3.6.8 -Tetra-chlorodibenzo-pDioxin (1.3.6 r8 -TCDD). (Japanese Translation) K. Kawamura, R. Sato and M. Kashima. Oyo Yakuri ; 70 3-711. 1983 (5a) Summaries of Toxicity Data for Pentabromodiphenvl Oxide. (J'S'Shtlftized) Great Lakes Chemical November 1984 (5b) Summaries of Toxicity Data for Octabromodiphenvl Oxide. Great Lakes Chemical Corp. (5c) Summaries of Toxicity Data for Decabromodiphenvl Oxide. Great Lakes Chemical Corp. May 5, 1977 (5d) Summaries of Toxicity Data for Tetrabromobisphenol A . Great Lakes Chemical Corp. December 1979 (5e) Summaries of Toxicity Data for Tetrabromobisphenol A Bis(2-Hvdroxvethvl Ether). Great Lakes Chemical Corp. March 21, 1979' C-l-14 Sl q TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS PUBLIC COMMENTS FOR DOCKET #83002 Ci-FILE Fiche # 40-8693110 (continued) (5f ) Summaries of Toxicity Data for Bis(Allvl Ether) of Tetrabromobisphenol A . Great Lakes Chemical Corp. May 19, 1981 (5g) Summaries of Toxicity Data for Bis(2.3--Dibromopropvl Ether) of TBBPA. (5h) Summaries of Toxicity Data for 2.4.6-Trihromopheno1. Great Lakes Chemical Corp. March 31, 1982 (5i) Summaries of Toxicity Data for 1.2Bis(Tribromophenoxv) Ethane. Great Lakes Chemical Corp. November 1981 40-8593107 Imperial, Inc. Comment letter from G. Currie to i ^*^ment Control Officer, EPA. ^ " December 31, 1985 (11) 513794 40-8693111 Platte Chemical Company Comment letter from D. Burchett to Document Control Officer, EPA. January 17, 1986 (12) 513796 40-8693112 Vulcan Materials Company Comment letter from T.A. Robinson to Document Control Officer, EPA. February 18, 1986 (13) 513797 77 < X 0 5 ' c-<=f TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-E-DIOXINS/DIBENZOFURANS PUBLIC COMMENTS FOR DOCKET #83002 Ci-FILE Fiche # 40-8693113 W o r k e r s ' Institute for Safety and Health Comment letter from M. Gillen to ;nent Control Officer, EPA. February 26, 1986 (14)^ 513798 C-l-16 5 50 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS PUBLIC COMMENTS FOR DOCKET #83002B c 2-f i l e Fiche # 40-8693179 Eastman Kodak Company (1) 513799 Comment letter from R. Brothers to Document Control Officer, EPA. November 21, 1986 40-8693180 Environmental Defense Fund Cover letter from R. Percival to Docu ment Control Officer, EPA November 21, 1986 Enclosure: (1) Comments of the Environmental Defense Fund on EPA's Proposed Addition of Certain Chlorinated and Brominated Benzenes to List of Precursor Chemicals in Proposed Testing and Reporting Rule for Polvhalogenated Dibenzo-p-Dioxins/ Dibenzofurans. November 21, 1986 (2) 513800 40-8693181 Great Lakes Chemical Corporation Comments on the Proposed Addition of 18 Chlorinated and Brominated Benzenes to the List of Precursor Chemicals. (Sanitized) November-24, 1986 (3) 513801 C 2- ! TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-B-DIOXINS/DIBENZOFURANS PUBLIC COMMENTS FOR DOCKET #83002B c 2-f i l e Fiche # 40-8693182 Uniroyal Chemical Company, Inc. (4) 513802 Comment letter from R .A . Cardona to Document Control Officer, EPA November 21, 1986 Enclosures: (1) Letter from R. A. Cardona, tx f / t (UniT'oi^aTv to J.W. Akerman, EPA, pegardi-ftg> PCWB Data-Call-in Notice7^ f-JdayrS-* 1985. Q May 5, 1986 J ( 2 ) Letter from J.D.L. Salcedo, - g f o ^ h & c a l Org. of Mexico, to R. j topaYjdOTsra^, Uniroyal, authorizing t y r o - r e y d Unrirf^S^dTDtb rely on data from Ch.emT^^l^Ttrgrvc5i Mexico. April 28, 1986 (3) Letter from EPA to R. Cardona, Uniroyal, giving the status of submitted studies. March 31, 1986 (a) Letter from G. Werdig, EPA, to Chemical Group, Uniroyal Inc., providing the EPA accession number for data submitted. September 23, 1985 C 2-2 TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS MEETINGS FOR DOCKET #83002 D la-FILE Fiche # 40-8593116 EDF/NWF Meeting Attendees: Environmental Protection Agency Environmental Defense Fund National Wildlife Federation Date: January 31, 1985 Subject: EPA's response to Section 21 petition. Enclosure: (1) Meeting summary. February 8 , 1985 (1) 513803 40-8593117 EPA Dioxin/Furan Work Group Meeting Date: June 11, 1985 Subject: Review of the MRI Report. Documents: (1) Meeting summary. (2) 513804 Dia" 1 &3 TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS MEETINGS FOR DOCKET #83002 D la-FILE Fiche # 40-8593118 EPA Dioxin/Furan Work Group Meeting Date: July 22, 1985 Subject:. Levels of quantification and action levels. Documents : (1 ) Meeting summary. (2 ) List of attendees. (3) Options for Dioxin Work Group. (4) Schedule! for Dioxin/Furan Rule Development. (3) 513805 40-8593120 EPA Dioxin/Furan Work Group Date: August 5, 1985 Subject: Direction of the proposed rule. Documents: (1) Meeting summary. August 13, 1985 (4) 513806 D la- 2 TSCA SECTION 8 (d) AND 4(a) ./ HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES r DOCKET #83002 - POLYHALOGENATED DIBENZO-E-DIOXINS/DIBENZOFURANS MEETINGS FOR DOCKET #83002 D la-FILE Fiche # 40-8593119 Chemical Manufacturers Association Meeting Attendees: Chemical Manufacturers Association Environmental Protection Agency Date: August 12, 1985 Subject: Technical aspects of the rule. Documents: (1) Meeting summary. , August 14, 1985 (2) List of attendees. (5) 513807 D la-3 ^b BOSS'S' TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS MEETINGS FOR DOCKET #83002B D lb-FILE Fiche # 40-8693114 Public Meeting on Dibenzo-p-Dioxins/ Dibenzofurans (if 513808 Attendees : Environmental Protection Agency McKenna, Conner and Cuneo Kirkland and Ellis Pesticide and Toxic Chemical News Chemical Manufacturers Association Ethyl Corporation National Wildlife Federation American Petroleum Institute Monsanto Company The Dow Chemical Company Environmental Defense Fund Ameribrom, Inc. Great Lakes Chemical Corporation Bureau of National Affairs Date: March 4, 1986 Subject: Proposed testing and reporting requirements. Documents : (1) List of attendees. (2) Transcript of Proceedings. Dlb" 1 % SIOS^ TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS MEETINGS FOR DOCKET #83002B D lb-FILE Fiche # 40-8693121 Great Lakes Chemical Corporation Meeting (2) 513809 Attendees : Environmental Protection Agency McKenna, Connor and Cuneo Great Lakes Chemical Corporation Date: March 4, 1986 Subject: CBI and comments to the proposed rule from the Great Lakes Chemical Corp. Documents : (1) Transcript of private meeting. (Sanitized) 40-8693115 Public Meeting on Dioxins and Furans Attendees : Environmental Protection Agency NCAMP Standard Chlorine of Delaware, Inc. The Dow Chemical Company Harvard School of Public Health Pesticide and Toxic Chemical News Kirkland and Ellis Bureau of National Affairs Great Lakes Chemical Corporation Piper and Marbury Vulcan Chemicals Company Ethyl Corporation Environmental Defense Fund Chemical Manufacturers Association (3) 513810 Dlb 2 87 AD57T7 TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS MEETINGS FOR DOCKET #83002B D lb-FILE Fiche # 40-8693115 (continued) Date: April 22, 1986 Subject: Proposed testing and reporting requirements. Documents: (1) Attendees list. (2) Transcript of Proceedings. 40-8693122 EPA Dioxin/Furan Work Group Meeting Date: April 23, 1986 Subject: Summary of the public meeting and discussion of issues. Documents : (1) Meeting summary. (2) List of attendees. (4) 513811 40-8693123 EPA Dioxin/Furan Work Group Meeting Date: May 7, 1986 Subject: Testing recommendations. Documents: (1) Meeting summary. May 15, 1986 (5) 513812 D lb -3 TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS MEETINGS FOR DOCKET #83002B D lb-FILE Fiche # 40-8693124 EPA Dioxin/Furan Work Group Meeting (6 ) 513813 Date: May 21, 1986 Subject: Testing recommendations. Documents: (1) Meeting summary. June 10, 1986 (2) Attendance sign-in sheet. D ib-4 TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO--DIOXINS/DIBENZOFURANS MEETINGS FOR DOCKET #83002C D lc-FILE Fiche # 40-8693201 Dioxin Update Conference (1) 513814 Attendees: (Not listed) Date: July 1-2, 1986 Subject: Scientific issues associated with Dioxins. Documents: (1) Introduction to the Report. (2) Conclusions of the Dioxin Update Committee. (3) Review of the Epidemiologic Data Regarding Dioxin and Cancer. A. Blair; National Cancer Institute. (4) Immunotoxicitv of the Chlorinated Dibenzodioxins and Dibenzofurans. J. Dean and R. Kimbrough, C U T and CDC. (5) Bioavailabilitv of Dioxins from Complex Mixture. M . Gallo. June 19, 1986 (6 ) Mechanism of Action. /? * Poland. (7) Risk Assessment.^ D. Hoel. -------- Die- 1 'ck.oS'l&G TSCA SECTION 8 (d) AND 4(a) r HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS MEETINGS FOR DOCKET #83002C D lc-FILE Fiche # 40-8693201 (continued) (8 ) Teratology and Reproduction Studies with TCDD. . Kimbrough. (9) "Dioxin Update" Participants. 40-8793202 EPA Workgroup Closure Meeting Date: February 18, 1987 Subject: Test rule and data submission requirements. Documents: (1) Meeting summary. February 20, 1987 (2) Attendees list. (2) 513815 Die 2 (q / TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS MEETINGS FOLLOWING DOCKET #83002C D ld-FILE Fiche # 40-8793220 EPA Dioxin/Furan Workgroup Meeting (1)* 513816 Date: July 2, 1987 Subject: System for handling exclusion and waiver 'applications. Documents: (1) Meeting summary. 40-8893233 Dioxin Panel Meeting Attendees: Midwest Research Institute Environmental Protection Agency Date: February 29, 1988 Subject: Protocol review. Documents : (1) Meeting summary from Midwest Research Institute. March 15, 1988 (2) List of attendees. (3) Dioxin/Furan Rule Company Compliance Status. (4) Protocol Review Process. (5) Charter of the Dioxin/Furan Protocol Review Panel. (2) 513817 D l d -1 9s~ TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS MEETINGS FOLLOWING DOCKET #83002C D ld-FILE Fiche # 40-8893293 Protocol Review Panel Teleconference (3) 524803 Attendees : Midwest Research Institute Environmental Protection Agency Date: April 20, 1988 Subject: Protocol review. Documents : (1) Cover letter from D. Steele, Midwest Research Institute, w.to R. Mitchum, EPA (Also identical letters to Bontoyan, A. Dupuy, R. Harless and D. Firestone, EPA) . May 4, 1988 (a) Minutes of meeting from Midwest Research Institute. May 4, 1988 (b) Participants at meeting. D ld -2 LoS(s 3 TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS MEETINGS FOLLOWING DOCKET #83002C Di^-FILE Fiche # 40-8893294 Protocol Review Panel Teleconference (4) 524804 Attendees: Environmental Protection Agency U.S. Food and Drug Administration Midwest Research Institute Date: May 18, 1988 Subject: Protocol review. Documents: (1) Cover letter from D. Steele, Midwest Research Institute to W. Bontoyan, EPA. May 24, 1988 (a) Minutes of the meeting from Midwest Research Institute. May 24, 1988 40-8893295 Protocol Review Panel Teleconference Attendees: Environmental Protection Agency U.S. Food and Drug Administration Midwest Research Institute Date: June 15, 1988 Subject: Protocol review. Documents: (]) Minutes of the teleconference from Midwest Research Institute. June 16, 1988 (5) 524805 Dld~3 `-f- TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS MEETINGS FOLLOWING DOCKET #83002C D ld-FILE Fiche # 40-8893300 Protocol Review Panel Meeting (6 ) 24806 Attendees: Environmental Protection Agency Lockheed Environmental Services Midwest Research Institute Great Lakes Chemical Corporation Dead Sea Bromine Company Hoechst-Celanese Corporation - U.S. Food and Drug Administration Ethyl Corporation Triangle Laboratories, Inc. Latham and Watkins The Dow Chemical Company Borg-Warner Corporation GE Plastics Corporation Mobil Chemical Company Date: July 27, 1988 Subject: Review of protocols. Documents: (1) Minutes of July TSCA Section 4 Dioxin/Furan Protocol Review Panel Meeting. Midwest Research Institute. August 17, 1988 (2) List of attendees. D id -4 95 TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS MEETINGS FOLLOWING DOCKET #83002C D ld-FILE Fiche # 40-8893301 Protocol Review Panel Teleconference (7) 524807 Attendees: Environmental Protection Agency Midwest Research Institute Date: August 16, 1988 Subject: Review of protocols. Documents: (1) Minutes of August EPA TSCA Section 4 Dioxin/Furan Proto col Review Panel Telecon ference. Midwest Research Institute. August 18, 1988 40-8893317 Protocol Review Panel Meeting Attendees: Environmental Protection Agency U.S. Food and Drug Adminstration Midwest Research Institute Date: September 20, 1988 Subject: Review of protocols. Documents: (l ) Minutes of September EPA TSCA Section 4 Dioxin/Furan Protocol Review Panel Meeting. (8 ) 524808 D ld -5 3 u o S ( o Co TSCA SECTION 8 (d) AND 4(a) ' HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS MEETINGS FOLLOWING DOCKET #83002C D ld-FILE Fiche # 40-8893328 Protocol Review Panel Teleconference (9) 524809 Attendees: Environmental Protection Agency Midwest Research Institute Date:' December 14, 1988 Subject: Status of the protocol reviews. Documents : (1) Minutes of the December EPA TSCA Section 4 Dioxin/Furan Protocol Review Panel Tele conference . 40-8893329 Protocol Review Panel Teleconference (10) 524810 Attendees : Environmental Protection Agency Midwest Research Institute Date: January 25, 1989 Subject: Review of Revision l of the Dow Chemical Analytical Protocol. Documents : (1) Minutes of the January EPA TSCA Section 4 Dioxin/Furan Protocol Review Panel Teleconference. D ld-6 77 ax'5t. 7 TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS MEETINGS FOLLOWING DOCKET #83002C D ld-FILE Fiche # 40-8993361 Pi ox in/Furan Protocol Review Panel Meeting (lij 524811 Attendees: Environmental Protection Agency Great Lakes Chemical Corporation GE Plastics Company Lockheed Environmental Services The Dow Chemical Company Hoechst-Celanese Corporation U.S. Food and Drug Administration Ethyl Corporation Triangle Laboratories, Inc. National Institute for Occupational Safety and Health, USDHHS Borg-Warner Corporation Midwest Research Institute Latham and Watkins Ameribrom, Inc. Date: March 1, 1989 Subject: Exposure issues and protocol reviews.. Documents : (1) Minutes of March TSCA Section 4 Dioxin/Furan Protocol Review Panel Meeting. (2) .List of attendees. Did"? (o^ TSCA SECTION 8 (<3) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS MEETINGS FOLLOWING DOCKET #83002C D ld-FILE Fiche # 40-8993362 Protocol Review Panel Teleconference (12) 524812 Attendees: Environmental Protection Agency Midwest Research Institute Date: March 23, 1989 Subject: Panel recommendations and comments on the protocols. Documents: (1) Letters from D. Steele of Midwest Research Institute to W. Sovocool, W. Bontoyan, R. Harless and A. Dupuy of EPA and D. Firestone of FDA. March 28, 1989 (a) Minutes of March 23 EPA TSCA Section 4 Dioxin/ Furan Protocol Review Panel Teleconference. Status, O f TSCA Section 4 Dioxin/Furan Protocols. March 2, 1989 D id"8 99 (9 *7 TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-E-DIOXINS/DIBENZOFURANS MEETINGS FOLLOWING DOCKET #83002C Dld-FILE Fiche # 40-8993363 Panel Review Teleconference (13) 524813 Attendees: Environmental Protection Agency Midwest Research Institute Date: May 17, 1989 Subject: Protocol reviews. Documents: (1) Minutes of Mav EPA TSCA Section 4 Dioxin/Furan Protocol Review Panel Teleconference. 40-8993364 Protocol Review Panel Teleconference Attendees: U.S. Food and Drug Administration Environmental Protection Agency Midwest Research Institute Date: June 14, 1989 Subject: Protocol review. Documents: (1) Minutes of June EPA TSCA Section 4 Dioxin/Furan Protocol Review Panel Teleconference. (14) 524814 D ld"9 2 x > $ '7 0 loo TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS MEETINGS FOLLOWING DOCKET #83002C D ld-FILE Fiche # 40-8993396 Protocol Review Panel Meeting (15) 524898 Attendees : Environmental Protection Agency U.S. Food and Drug Administration Midwest Research Institute Date : August 23-24, 1989 Subject: Triangle Labs, audit <2 ^Pfication of the from A&D and Chugai.-^ ^ . fo^STfntQiranil ; Protocols ^na-irrg cr received ; Review w * er^S}ampi>in^ and analytical /TBfi) to 0 2 0 for the HroftiTcEt^ Compounds. Documents : (1) Minutes of EPA TSCA Section 4 Dioxin/Furan Protocol Review Panel Teleconference. [See H^ #2 (30a) for Summary) D i d - 10 SL05 7( li TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS MEETINGS FOLLOWING DOCKET #83002C D ld-FILE Fiche # 40-8993397 Protocol Review Panel Teleconference (16) 524898 Attendees : Environmental Protection AgencyMidwest Research Institute Lockheed Engineering and Sciences Company U.S. Food and Drug Administration Date: September 8 , 1989 Subject: Storage conditions for Brominated Compounds ; Analytical problems with Chloranil; Approval of Protocols 002 to 005. Documents : (l) Minutes of EPA TSCA Section 4 Dioxin/Furan Protocol Review Panel Teleconference. [See H^ _2 (30a) for Document] Did-H I0JL TSCA SECTION 8 (d) AND 4(a) ' HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS MEETINGS FOLLOWING DOCKET #83002C D ld-FILE Fiche # 40-8993398 Protocol Review Panel Teleconference (17) 524898 Attendees : Environmental Protection Agency Midwest Research Institute Lockheed Engineering and Sciences Company U.S. Food and Drug Administration Date: September 29, 1989 Subject: Chloranil analysis; Review of protocol 006 to 0 2 0 . Documents: (1) Minutes of EPA TSCA Section 4 Dioxin/Furan Protocol Review Panel Teleconference. [See H^ _2 (30a) for Document] D ld~ 1 2 lo3 c3 A 5 "7 3 TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS MEETINGS FOLLOWING DOCKET #83002C D ld-FILE Fiche # 40-8993399 Protocol Review Panel Teleconference (1?) 524898 Attendees: Environmental Protection Agency Midwest Research Institute Lockheed Engineering and Sciences Company U.S. Food and Drug Administration Date: October 25, 1989 Subject: Chloranil analysis; BFRIR protocols; and Pfester protocol No. 021. Documents: (1) Minutes of EPA TSCA Section 4 Dioxin/Furan Protocol Review Panel Teleconference. [See Hjl^2 (30a) for Document] D ld~13 L0b lof TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS MEETINGS FOLLOWING DOCKET #83002C D ld-FILE Fiche # 40-9093400 Protocol Review Panel Teleconference (19) 524815 Attendees : Environmental Protection Agency Lockheed Engineering and Sciences Company U.S. Food and Drug Administration Midwest Research Institute Date: January 10, 1990 Subject: BFRIP testing extension request; Data from Hoechst Celanese; Data from Chugai. Documents : (1) Minutes of January EPA TSCA Section 4 Dioxin/Furan Jtd r f t w - RratkOcol Review Panel 'T-eiec'ortfrgrence. 40-9093450 Protocol Review Panel Teleconference Attendees : Environmental Protection Agency Midwest Research Institute U.S. Food and Drug Administration Lockheed Engineering and Sciences Company Date: February 21, 1990 Subject: Update on protocol review. Documents: (1) Minutes of February EPA TSCA Section 4 Dioxin/Furan ~ PfrdfeCcol Review Panel T T -T^L-eTgpflfearence. (20) ~~ 524816 of SLtp 7 5 TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS MEETINGS FOLLOWING DOCKET #83002C D ld-FILE Fiche # 40-9093460 Review Panel Meeting (21) 524817 Attendees : Environmental Protection Agency Lockheed Engineering and Sciences Company U.S. Food and Drug Administration Midwest Research institute Date: March 14, 1990 Subject: Protocol reviews. Documents: (1) TSCA Section 4 Dioxin/Furan Protocol Review Panel Meeting. . (2) Exhibit I : EPA memo from D. McDaniel (Miss.) to A. Dupuy, Jr. Description of samples methods used in the of Tetrabromc^ bisphenol A.-----March 12, 1990 (3) Exhibit II: EPA memo from R. Harless (RTP, NC) to T. .Murray'on the analysis for jb J tT L t* /) Dioxins and DUho^gerfu r arrs in j fl / ^'CTreettrrabromobispohenol A. March 13, 1990 Did-15 ti SiO>7(o TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS MEETINGS FOLLOWING DOCKET #83002C D ld-FILE Fiche # 40-9093461 Review Panel Meeting (22) 524818 Attendees: Environmental Protection Agency Lockheed Engineering and Sciences Company U.S. Food and Drug Administration Midwest Research Institute Great Lakes Chemical Corporation Arnold and Porter Ethyl Corporation Triangle Laboratories Chemical Manufacturers Association Ameribrom, Inc. Brominated Flame Retardant Industry Panel Date: March 14, 1990 Subject: Analytical methods development. Documents: (1) TSCA Section 4 Protocol Review Panel/BFRIP Meeting. (la) TSCA Section 4 Protocol Review Panel/BFRIP Meeting. (Revised) (2) Exhibit I : Letter from D. Steel'e, Midwest Research Institute to C. Mazac of Great Lakes Chemical Corp. on the Panel questions of BFRIP protocols. March 8 , 1990 A D id -16 o jp 7 7 TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS MEETINGS FOLLOWING DOCKET #83002C D ld-FILE Fiche # 40-9093461 (continued) (3) Exhibit I I : EPA memo from D . McDaniel (Miss.) to A. Dupuy on the description of samples and methods, used in the " ChS^sis of T e t r a b r o m o A ^]ai<?pherrer3>-A-- N. March 12, 1990 (4) Exhibit III; EPA memo from R. Harless (RTP, NC) to T. Murray on the analysis Dibenzo-p-Dioxins and CiBen^jfurans in <- (^etrabromobi sphenoidA . March 13, 1990 (5) Exhibit IV: Telefax from C. Mazac of Great Lakes ChemicalL Corporation to Chemsyn y 4 ^ A jL ^ < J i -Soterrce Labs, requesting the synthesrs-of additional ferominatbd standards. November 6 , 1989 / (6 ) Exhibit V : Letter from J. Kreuzberger of Chemsyn 6 cionce- Labs. to C . Mazac of Gireaf Lakes Chemical Corp. in .response .to their request of November 6 , 1989. December 13, 1989 J- (7) Exhibit VI: Internal Great Lakes Chemical Corp. memo v + r y ' f-rem-A.S. Klemene to D.W. Abbot#--err the structural^) ^etrmdnatjioij of ----~ Hdptabrom'Odibenzofuran/^ March 9, 1990 (8 ) Exhibit VII: Single Labora tory Method Evaluation for . TBBPA. March 7, 1990 D ld -17 TSCA SECTION 8 (d) AND 4(a) f HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS MEETINGS FOLLOWING DOCKET #83002C D ld-FILE Fiche # 40-9093461 (continued) (9) Exhibit VIII; Single Labora tory Method Evaluation for PH-73. March 7, 1990 40-9093462 Attendees : Environmental Protection Agency Midwest Research Institute U.S. Food and Drug Administration Date: May 9, 1990 Subject: Compliance complaints and protocol reviews. Documents : (1) TSCA Section 4 Dioxin/Furan Protocol Review Panel Teleconference. May 9, 1990 (23) 524819 TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS MEETINGS FOLLOWING DOCKET #83002C D ld-FILE Fiche # 40-9093486 Review Panel Teleconference (24') Attendees: Environmental Protection Agency Midwest Research Institute U.S. Food and Drug Administration Date: June 27, 1990 Subject: Enforcement-actions, protocol status and (chlornil analysis. ^ Documents: (1) of June EPA TSCA Section 4 Dioxin/Furan Protocol Review Panel Teleconference. 40-9093487 BFRIP Teleconference Attendees : Environmental Protection Agency Triangle Laboratories, Inc. Midwest Research Institute r Great Lakes Chemical Corporation =:^2p^^<FlBrominated Flame Retardant Industry Panel) Date: July 12, 1990 Subject: Clarification of points raised as a result of analytical protocols prepared by Triangle Labs and submitted by BFRIP. Documents: (1) Minutes of Teleconference. M / 990 D ld-19 (25 ) SLOt>&0 l to TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS MEETINGS FOLLOWING DOCKET #83002C D ld-FILE Fiche # 40-9093488 Review Panel Meeting (26) Attendees: Environmental Protection Agency Lockheed Engineering and Sciences Company U.S. Food and Drug Administration Midwest Research Institute Date: August 14, 1990 Subject: Chloranil testing. Documents: (1) Minutes of August EPA Section 4 Dioxin/Furan Protocol Review Panel Meeting. rff > (2) Revised Minutes of August EPA TSCA Section 4 Dioxin/Furan Protocol Review Panel Meetina. id TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS MEETINGS FOLLOWING DOCKET #83002C D ld-FILE Fiche # 40-9093489 Review Panel Teleconference (21) 5 Z $ ^ O Attendees: Environmental Protection Agency Lockheed Engineering and Sciences Company U.S. Food and Drug Administration Midwest Research Institute Date: August 23, 1990 Subject: Review of the Panel's responses to the second revision of the analytical protocols. Documents : 40-9093507 (1) Minutes of August 23rd. 1990 EPA TSCA Section 4 Dioxins/ Furan Protocol Review Panel Teleconference. j /9f Review Panel Teleconference (28) Attendees: Environmental Protection Agency Lockheed Engineering and Sciences Company U.S. Food and Drug Administration Midwest Research Institute Date: October 4, 1990 Subject: Status on the protocol reviews. Documents : (1) Minutes of the October EPA TSCA Section 4 Dioxin/Furan Protocol Review Panel Teleconference. $ 11^0 Did-21 If3- TSCA SECTION 8(d) AND 4(a) ' HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS LEGAL PROCEEDINGS FOR DOCKET #83002 D 2a-FILE Fiche # 40-8093125 The Dow Chemical Company et al. (1) 513818 Direct testimony of David T. Buzzelli rgarding 2,4,5-T and Silvex before the Environmental Protection Agency of the United States of America. Exhibit 810 in regards to The Dow Chemical Co. et al.; Docket Nos. 415 et al. September 30, 1980 ` D 2a-1 1(3 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS LEGAL PROCEEDINGS FOR DOCKET #83002C d 2c -f i l e Fiche # 40-8093125 The Dow Chemical Company et al. Direct testimony of David T. Buzzelli regarding 2,4,5-T and Silvex before the Environmental Protection Agency of the United States of America. Exhibit 810 in regard to The Dow Chemical Co. et al.; Docket Nos. 415 et al. September 30, 1980 [Crossreferenced to D2a(l)] (1) 513818 d 2c -! TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKETS #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS HEARING FOLLOWING DOCKET #83002C D 3d-FILE Fiche # 40-9093454 EPA vs. Chuaai Boveki (America^ Corporation (1) 524820 Attendees : Chugai Boyeki (America) Corporation Sandoz Chemicals Corporation Hochst-Celanese Corporation Triangle Laboratories, Inc. Date: Subject: June 1, 1990 [ Submission of study conducted in violation of Section 4 of TSCA. Documents : (1) Complaint and Notice of Opportunity for Hearing Under Section 16(a) of the Toxic Substances Control Act. Docket No. TSCA 90-H-ll. Dad' 1 rQ- cnfBJ? US TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-JD-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOR DOCKET #83002 Ela-FILE Fiche # 40-8593126 From: Environmental Protection Agency D. Keehner (1) 513819 To: Environmental Protection Agency M. Callahan' Date: February 11, 1985 Subject: Formation of the Dioxins/Furan Work Group. 40-8593127 From: Environmental Protection Agency D . Keehner To: Environmental Protection Agency A. Carpien Date: February 11, 1985 Subject: Formation of the Dioxins/Furan Work Group. (2) 513820 40-8593128 From: Environmental Protection Agency D. Keehner To: Environmental Protection Agency J. Carra Date: February 11,1985 Subject: Formation of the Dioxins/Furan Work Group. (3) 513821 Ela-l QjO > ^(o Wo TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOR DOCKET #83002 E la-FILE Fiche # 40-8593129 From: Environmental Protection Agency D. Keehner To: Environmental Protection Agency F . Kover Date: February 11, 1985 Subject: Formation of the Dioxins/^ Furan Work Group. (4) '5138 22 40-8593130 From: Environmental Protection Agency D . Keehner To: Environmental Protection Agency G. Timm Date: February 11, 1985 Subject: Formation of the Dioxins/ Furarr Work Group. (5) 513823 40-8593131 From: Environmental Protection Agency A. Ralph To: Environmental Protection Agency R. Boethling Date: February 11, 1985 Subject: Formation of the Dioxins/^^^,^ Jurats Work Group. (6) 513824 Ela-2 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOR DOCKET #83002 Ela-FILE Fiche # 40-8593132 From: Environmental Protection Agency M. Halper To: Environmental Protection Agency I. Baumel and M. Shapiro Date: February 14, 1985 Subject: Formation of the Dioxins/^a^*^. Puran Work Group. (7) 513825 40-8593133 From: Environmental Protection Agency A. Ralph To : Environmental Protection Agency Dioxin/Furan Work Group Date : March 1985 Subject : Meeting announcement. Enclosures (1) List of Workgroup members. (2) Draft Development Plan for the Rule. [See Ela(10) for Enclosures] (8) 513826 40-8593134 From: Environmental Protection Agency A. Ralph To : Environmental Protection Agency Dioxin/Furan Work Group Date : April 12, 1985 Subject: Meeting notice and agenda. (9) 513827 Ela ^ 9s> 5 8 IIS' , TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOR DOCKET #83002 Ela-FILE Fiche # 40-8593135 From: Environmental Protection Agency A. Ralph (10) To: Environmental Protection Agency Dioxin/Furan Work Group Date:. April 26, 1985 Subject : Meeting announcement and agenda. Enclosures: (1) Briefing paper. (2) Schedule. V (3) Environmental Protection Agency Start Action Request. (4) Development Plan for a Section 4/8 Dioxin/Furan Rulemaking. (Draft) (5) Appendix A - Chemicals Conta- minated. Potentiallv Contami- nated. and/or Precursors to Contamination with Chlort^u^u^/. , A ia f c h G i and Brominated D ib e n z o d ic & ic * * * * . ^ d i (DBDs ) and DibenzoZ>_^****^' (DBFs). jr April 19, 1985 (6) Appendix B - Isomers and availability of analytical standards (table). 513828 Ela"4 tn TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOR DOCKET #83002 Ela-FILE Fiche # 40-8593136 From: Environmental Protection Agency S. Lee/K. McCormack To : Environmental Protection Agency Dioxin/Furan Work Group Date: Subject: June 20, 1985 t Meeting announcement and agenda. Enclosures: (l) List of addressees asked to review the methodology, list of chemicals and rationale for selection of chemicals. (2) Minutes of June 11, 1985 meeting. [See Dla(2) for Enclosure a (2) ] -_________________ -- ^ (11) 513829 LO 1 i-H w (U) TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOR DOCKET #83002 Ela-FILE Fiche # 40-8593137 From: Environmental Protection Agency S. Lee and K. McCormack To : Environmental Protection Agency Dioxin/Furan Work Group Date : July 31, 1985 Subject: Meeting announcement and agenda. Enclosures: (1) Summary of comments from the workgroup on the rule. (2) Minutes of July 22, 1985 meeting. [See Dfa(3) for Enclosure ( 2) ]. (12) 513830 40-8593138 From: Environmental Protection Agency K. McCormack and S. Lee To : Environmental Protection Agency Dioxin/Furan Work Group Date: August 13,1985 Subject : *'Meeting announcement and agenda. Enclosure: (1) Minutes of August 5, 1985 meeting. [See D l a (4) for Enclosure] (13) 513831 Ela 6 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOR DOCKET #83002B Elb-FILE Fiche # 40-8693139 From: National Institute of Environmental Health Sciences J. Goldstein To: Environmental Protection Agency D. Barnes Date: January 13, 1986 Subject: The revised draft of the CDD and CDF position document. (1) 513832 - 40-8693140 From: Environmental Protection Agency S. Rudzinski To: McKenna, Conner and Cuneo C. O 'Connor III Date: February 26, 1986 Subject: Response to request for a private meeting with the Great Lakes Chemical Corp. (2) 513833 40-8693141 - -- From: McKenna, Conner and Cuneo C. O 'Conner III To: Environmental Protection Agency S. Rudzinski Date: February 28, 1986 Subject: Confirmation of the upcoming private meeting. (3) 513834 Elb- 1 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOR DOCKET #83002B Elb-FILE Fiche # 40-8693143 From: Environmental Protection Agency S. Lee and K. McCormack To: Environmental Protection Agency Dioxin/Furan Workgroup Date: March 11, 1986 Subject : Comments to the proposed rule. Enclosure: (1) List of file headings for Dioxins/Furan comments. (2) Comments received. [See C;l File for Enclosure / j \ (2) ]-- -------------- ---- ' (4) ^513835 40-8693144 From: Chemical Manufacturers Association (5) R. Fensterheim To: Environmental Protection Agency S . Lee Date: April 3, 1986 Subject: Agenda for the April 22, 1986 meeting. Enclosures : (1) Letter from R. Fernsterheim, CMA, to M. Halper, EPA, commenting on the proposed rule. February 18, 1986 513836 Elb-2 133 0-05 CL 3 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #8 3002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOR DOCKET #83002B E lb-FILE Fiche # 40-8693144 (continued) (a) Letter from CMA to Dr. Moore, EPA, requesting a meeting. February 18, 1986 (b) Comments on EPA's pro posed rule. [See C^(3) for Enclosures (a) and (b)] 40-8693145 From: Cambridge Isotope Laboratories J.C. Bradley To: Environmental Protection Agency S. Rudzinski Date: April 7, 1986 Subject: List of materials in catalog. (6) 513837 40-8693142 From: McKenna, Conner and Cuneo A. Kerester To : Environmental Protection Agency S. Rudzinski Date : April 16, 1986 Subject : Cover letter for enclosure. Enclosure: (l) Transcript of private meeting. [See D lt)(l) for Enclosure] (6a ) 513838 Elb -3 .0^4- IdA TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING ' TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOR DOCKET #83002B Elb-FILE Fiche # 40-8693146 From: Environmental Protection Agency S. Lee and K. McCormack To: Environmental Protection Agency Dioxin/Furan Workgroup Date:. May 5, 1986 Subject: Removal of chemicals from the list. Enclosure: (1) Minutes from the April 23, 1986 meeting. \ [See Dlb(4) for Enclosure] (7) 513839 40-8693147 From: Environmental Protection Agency S. Lee and K. McCormack To: Environmental Protection Agency Dioxin/Furan Work Group Date: May 15, 1986 Subject: Work Group meeting announce ment and agenda. Enclosure: (1) Minutes from the May 7, 1986 meeting. [See Dlb(5) for Enclosure] (8) 513840 E lb~4 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOR DOCKET #83002B Elb-FILE Fiche # 40-8693148 From: Environmental Protection Agency S. Lee and K. McCormack To: Environmental Protection Agency Dioxin/Furan Workgroup Date: June 10, 1986 Subject: Meeting announcement and agenda. Enclosures: (1) Minutes from the May 21, 1986 meeting. (2) Decision paper used to brief R. Tinsworth (EPA). June 1986 [See Dib (6)for Enclosure (1) ; Enclosure (2) Not Provided to Docket] (9) 513841 From: Environmental Protection Agency M. Dreyfus To : Cambridge Isotope Laboratories J. Bradley Date : June 19, 1986 Subject : Information submitted on the economic analysis. Enclosure: (1) Summary of June 18, 1986, phone call. [See E 2 b (3) for Enclosure] (10) 513842 E lb-5 9>S^t< ISA TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOR DOCKET #83002B E lb-FILE Fiche # 40-8693150 From: Environmental Protection Agency K. McCormack and S. Lee To: Environmental Protection Agency .Dioxin/Furan Workgroup Date : July 14, 1986 Subject : Meeting announcement and agenda. (11) 513843 E ib -6 30^77 9-1 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOR DOCKET #83002C Elc-FILE Fiche # 40-8693196 From: Mathtech, Inc. J. Orrell To: Environmental Protection Agency M. Dreyfus" Date: September 26, 1986 Subject: Production, producers and importers of the Chloranil market. (1) 513844 40-8693175 From: Environmental Protection Agency (Science Advisory Board) R. Griesemer and N. Nelson To: Environmental Protection Agency L . Thomas Date: November 4, 1986 Subject: Science Advisory Board's review of "Interim Procedures for Estimating Risk jciated With Exposures to/t fixtures of"^Chlorinated //-m^en'20-p-l3ioxins'rand Dibenzufurans (CCDs and-^ CDFs)". (2) 513845 40-8693178 From: McKenna, Conner and Cuneo A. Kerester (for C. O 'Connor) To: Environmental Protection Agency Document Control Officer Date: November /, 1986 Subject: Participation in a public meeting. (3) 513846 Elc" 1 ToS'H' ITS TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOR DOCKET #83002C Elc-FILE Fiche # 40-8693197 40-8693188 From: Environmental Protection Agency K. Wong To: Environmental Protection Agency M. Dreyfus Date: December 8, 1986 Subject: Input on cost estimate for Dioxin/Dibenzofuran section 8(a) form. From: Environmental Defense Fund E. Silbergeld and R. Percival To: Environmental Protection Agency J. Moore Date: January 15, 1987 Subject: Settlement among Vulcan Materials, EPA, and Idacon, Inc., with respect to Dioxin contamination of PCP. (4) (5) '513847 513848 40-8793195 From: Environmental Protection Agency J. Moore To: Environmental Defense Fund E. Silbergeld Date: March 24, 1987 Subject: Response to EDF's letter of January 15, 1987. (6) 513849 Elc 2 /2f TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOLLOWING DOCKET #83002C Eld-FILE Fiche # 40-8793206 From: General Electric Company S.F. Austin To: Environmental Protection Agency Document Control Officer Date: June 26 , 1987 Subject: Request for clarification of Final Rule. (1) 513850 40-8793207 From: Kirkland and Ellis T. Hardy To: Environmental Protection Agency D. Keehner Date: June 30, 1987 Subject: Request for clarification of the Final Rule. (2) 513851 40-8793208 From: Supelco, Inc. L. Witting To: Environmental Protection Agency E. Klein Date: July 9, 1987 Subject: Request for a waiver from testing. (3) 513852 E ld~l 13a SLOfkOO TSCA SECTION 8(d) AND 4(a) / HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOLLOWING DOCKET #83002C E ld-FILE Fiche # 40-8793337 From: Monsanto Chemical Company R. Olszewski . To : Great Lakes Chemical Corporation D. McAllister Date : July 21, 1987 Subject: Confidentiality status of the April 3, 1986 submission from Monsanto (Fi(2)). (3a) 524821. 40-8793209 From: Kirkland and Ellis T. Hardy To : Environmental Protection Agency D. Keehner Date : July 29, 1987 Subject: Request for additional f&l'eftri/'f^'cation of final rule issues-. (4) - 513853 40-8793210 From: American Paper Institute and the National Forest Products Association J. Festa To : Environmental Protection Agency Document Control Office Date: August 3, 1987 Subject : Request for clarification of Final Rule. (5) 513854 E ld - 2 abl 131 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOLLOWING DOCKET #83002C Eld-FILE Fiche # 40-8793211 From: Ciba-Geigy Corporation A. DiBattista To: Environmental Protection Agency Document Control Officer Date: Subject: August 14, 1987 * Clarification of the Final Rule. (6) 513855 40-8793223 From: Rhone-Poulenc, Inc. N.I. Rouse To: Environmental Protection Agency Document Control Office Date: August 20, 1987 Subject : Application for exemption from testing 2,4-Dichlorophenol. Enclosure : (1) Test results on imported 2,4Dichlorophenol. (7) 513856 Eld" 3 1325.0C> os^- TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DlOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOLLOWING DOCKET #83002C Eld-FILE Fiche # -8793212 From: Ethyl Corporation T. Pullin (8) To: Environmental Protection Agency Document Control Officer Date: September 1, 1987 Subject: Cover letter for enclosures. Enclosures: (1) Letter of intent to conduct tests on Pentabromodiphenyloxide and Octobromodiphenyloxide from T. Pullin, Ethyl Corp. to Document Control Officer, EPA. September 1, 1987 (2) Application letter from T. Pullin, Ethyl Corp. to Document Control Officer, EPA for an exclusion to conduct testing on TetrabromaAtV&ftjt? " A andJ & s g f & n o l ^ U .f CDecabromodiphenyl-' Sanitized) L September 1, 1987 (a) Attachment I: Poly> --, frffiminated Dibenzo (PBrDD) and EtHsen^fl>raii^ (PBrDF) in <F3T3St& Retardant a (^Prpartions^ Chemo^r^^r^ y ic{9 - / 1 2111- 7 H y , 1986 (b) Attachment II (Deleted) (c) Attachment III. (Deleted) E ld -4 513857 LD(o03 133 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOLLOWING DOCKET #830020 Eld-FILE Fiche # 40-8793240 From: BASF Corporation D. Briese To: Environmental Protection Agency Document Control Office Date: September l, 1987 Subject: Exemption request for 1,2Bis(tribromophenoxy)ethane. (9) 513858 40-8793213 From: Ameribrom, Inc. A. Tillman To: Environmental Protection Agency Document Control Officer Date: September 2, 1987 Subject: Request for a waiver. Enclosure: (1) Letter request for a waiver from testing for Brominated Chemicals from M. Eldan, Ameribrom, Inc. to Document Control Officer, EPA. September 4, 1987 (10) 513859 40-8793214 From: The Dow Chemical Company J. Gray To: Environmental Protection Agency Document Control Officer Date: September 2, 1987 Subject: Intent to conduct testing on 2,4-Dichlorophenol. (ID 513860 Eld 5 134- TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOLLOWING DOCKET #83002C Eld-FILE Fiche # 40-8793215 From: The Dow Chemical Company J. Gray To: Environmental Protection Agency Document Control Officer Date: September 2, 1987 Subject: Letter of intent to conduct testing on 2,4-Dichloro^k phenol.----------------5 (12) '513861 40-8793216 From: The Dow Chemical Company W. Hancock To: Environmental Protection Agency Document Control Officer Date: September 2, 1987 Subject: Request for waiver from testing all compounds except 2,4-Dichlorophenol. (13) 513862 40-8793217 From: Atochem, Inc. M. Hanley To: Environmental Protection Agency Document Control Officer Date: September 3, 1987 Subject: Request for an exemption from testing Pentabromodiphenyl Oxide. (14) 513863 Eid ^ [35 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOLLOWING DOCKET #83002C E-^-FILE Fiche # 40-8793218 From: McKenna, Conner and Cuneo C. O 'Connor, III To: Environmental Protection Agency Document Control Officer Date: September 3, 1987 Subject: Cover letter for enclosure. Enclosure: (1) Request of Great Lakes Chemical Corporation for Exclusion and Waiver of Certain Chemicals From the Testina dllU. LJ.11U -- Requirements of the Polvhalo- qenated Dibenzo-p- Dioxin/Dibenzofuran Test ---- Rule. 40 CFR Parts 707 and 766 (52 FR 21412. June 5. 1987). (Sanitized) September 3, 1987 (15) 513864 40-8793219 From: Smithkline Chemicals Company B. Sherry To : Environmental Protection Agency Document Control Officer Date : September 3, 1987- Subject : Cover letter for enclosure. Enclosure: (1) Submitter Information - EPA form 7910-51 for the chemical Bromobenzene. (15a) 513865 Eia- 7 oLQ (oO I3t TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING / TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOLLOWING DOCKET #83002C E ld-FILE Fiche t 40-8793224 .From: Crescent Chemical Company, Inc. S. Bobrow (16) To: Environmental Protection Agency L. Mack Date: September 21, 1987 Subject: Waiver request for i m p o r t a ^ ^ a without special testing . procedures. ($-7 C ? 40-8793225 From: Pfister Chemical, Inc. R.D. Huth ' To: Environmental Protection Agency Document Control Officer Date: September 23, 1987 Subject: Application for testing waiver. Enclosures: (1) Letter from R. Huth, Pfister Chemical to E. Mack, EPA requesting testing waiver far 3,4 ',5-Tribromosalicylani^v-^^ and 3,5-Dibromo^-<i^r^^<<y September 3, 1987 (2) Followup to Pfister Chemical letter dated September 3, 1987. September 9, 1987 (17) 513866 513867 E ld-8 (37 Rob 07 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOLLOWING DOCKET #83002C Eld-FILE Fiche # 40-8793226 From: Rohm and Haas Company R.L. Keener (18) To : Environmental Protection Agency E.S. Klein Date : September 23, 1987 Subject : Request for a waiver from testing requirements. Enclosure : (1) Internal Pfister Chemical s v r U r r i* ) leiS- from J.E. Plamondan to_/?-.' Keener on research i bOtTgbgeTK searching. September 17, 1987 513868 40-8793333 From: Diaz Chemical Corporation M . Bonn To : Environmental Protection Agency Document Control Officer Date: September 29, 1987 Subject: Application of HDD/HDF rule u' 'e the production of D i ~~ >h>rk59i0benzene. Enclosure : (1) Chemical reaction involving Bromobenzene during the processing at Diaz Chemical Corp. (18a) 524822 E ld "9 \3$ SlO(oO% TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOLLOWING DOCKET #83002C E ld-FILE Fiche # 40-8793227 From: Great Lakes Chemical Corporation D.L. McFadden To: Environmental Protection Agency Document Processing Center Date: October l, 1987 Subject': Response to the request for any information on TlegationSVS adverse^ effects------------ -- ^ (19) 513869 40-8793228 From: Stauffer Chemical Company J.T. Elfstrum To: Environmental Protection Agency Document Control Office Date: October 13, 1987 Subject: Letter of intent to test. (20) 513870 40-8793241 From: Stauffer Chemical Company J. Elfstrum To: Environmental Protection Agency Document Control Office Date: November 13, 1987 Subject: Test data availability. (21 ) 513871 40-8893242 From: Pfister Chemical, Inc. R. Huth To: Environmental Protection Agency Document control Office Date: January 29, 1988 Subject: Letter of intent to test. E ld -1 0 (22) 513872 139 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOLLOWING DOCKET #83002C Eld-FILE Fiche # 40-8893243 From: General Electric Company S. Austin To: Environmental Protection Agency Document Control Office Date: January 29, 1988 Subject: Summary of ongoing or proposed testing. (23) 513873 40-8893244 From: Great Lakes Chemical Corporation D. McFadden To: Environmental Protection Agency Document Control Office Date: March 10, 1988 Subject: Intent to test. (24) 513874 40-8893245 From: Horsehead Industries, Inc. R. Marshall To: Environmental Protection Agency L. Marcus Date: March 17, 1988 Subject: Production of chemicals falling under the rule. (25) 513875 40-8893246 From: Davos Chemical Corporation A. DelPrete To: Environmental Protection Agency Document Control Office Date: March 22, 1988 Subject: Importation of Chloranil. (26) 513876 Eid-H ZLQ&IO TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOLLOWING DOCKET #83002C Eld-FILE Fiche # 40-8893247 From: Sandoz Crop Protection Corporation (27) J. Licata To : Environmental Protection Agency Document Control Office Date : March 28, 1988 Subject : Subject to TSCA rule. Enclosure: (1) Information on Banve S 1 (nTIrrampa^ r Pesticide)" [Enclosures are CBI] '513877 40-8893248 From: Great Lakes Chemical Corporation D. McAllister To : Environmental Protection Agency Document Control Officer Date : March 28, 1988 Subject : Formation of Brominated Dibenzofurans. (28) 513878 Eld" 1 2 IH i c?X> (b I i TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOLLOWING DOCKET #83002C Eld-FILE Fiche # 40-8893249 From: Ameribrom, Inc. A. Tillman To: Environmental Protection Agency L. Marcus Date: March 30, 1988 Subject: Intent to test. Enclosure: (l) Letter from M. Halper, EPA to A. Tillman, Ameribrom, Inc. denying request for waiver or exclusion from testing. March 8, 1988 (29) 513879 40-8893250 From: Midwest Research Institute D. Steele To: Environmental Protection Agency R. Mitchum (Las Vegas, Nevada) Date: March 30, 1988 Subject: Cover letter for enclosure. Enclosure: (1) Copy of the February 29, 1988 meeting summary. - [See Dld(2) for Enclosure] (30) 513880 Eid-13 /4P- 9-0&(<?- TSCA SECTION 8(d) AND 4(a) / HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOLLOWING DOCKET #83002C Eld-FILE Fiche # 40-8893251 From: Midwest Research Institute D. Steele To : Environmental Protection Agency W. Bontoyan (Beltsville, MD) Date: March 30, 1988 Subject: Cover letter for enclosure. Enclosure: (1) Copy of the February 29, 1988 meeting summary. [See Dld(2) for Enclosure] (31) 513881 40-8893252 From: Midwest Research Institute D. Steele To: Environmental Protection Agency R. Harless (RTP, NC) Date: March 30, 1988 Subject: Cover letter for enclosure. Enclosure: (1) Copy of the February 29, 1988 meeting summary. [See Dld(2) for Enclosure] (32) 513882 E^-14 143 oLO (a 13 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOLLOWING DOCKET #83002C Eld-FILE Fiche # 40-8893253 From: Midwest Research Institute D. Steele To: Environmental Protection Agency A. Dupuy (NSTL, MS) Date: March 30, 1988 Subject: Cover letter for enclosure. Enclosure: (1) Copy of the February 29, 1988 meeting summary. [See Dld(2) for Enclosure] (33) 513883 40-889.3254 From: Midwest Research Institute D. Steele To: Food and Drug Administration D. Firestone Date: March 30', 1988 Subject: Cover letter for enclosure. Enclosure: (1) Copy of the February 29, 1988 meeting summary. [See Dld(2) for Enclosure] (34) __ 513884 E ld~15 o L Q ( l^4 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOLLOWING DOCKET #83002C Eld-FILE Fiche # 40-8893255 From: Sartomer Company J. Cortese To: Environmental Protection Agency L. Marcus Date: March 31, 1988 Subject: Manufacture of Tetrabromobisphenol A Diacrylate. (35) 513885 40-8893256 40-8893257 From: Pacific Anchor Chemical Corporation D. Johnson To: Environmental Protection Agency L. Marcus Date: March 31, 1988 Subject: Manufacture of Dioxin chemicals. From: Aceto Manufacturing Company R. Weaving, Jr. To: Environmental Protection Agency Document Control Officer Date: March 31, 1988 Subject:~ Manufacture of any Dioxin product. (36) (37) 513886 513887 Efd-16 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOLLOWING DOCKET #83002C E ld-FILE Fiche # 40-8893258 From: Biddle Sawyer Corporation H. Zeller To : Environmental Protection Agency L. Marcus ,, Date: April 7, 1988 Subject : Cover letter for enclosure. Enclosures : (1) Letter from R.E. Chavkin, Biddle Sawyer to Document Control Officer, EPA on the production of Dioxin/Furans. March 17, 1988 (2) Copy of return receipt. (38) 513888 40-8893259 - From: Sartomer Company J. Cortese To : Environmental Protection Agency L. Marcus Date : April 8, 1988 Subject : Manufacture of chemicals falling under the test rule. (39) 513889 40-8893284 From: Chugai International Corporation R. Tanaka To : Environmental Protection Agency L. Marcus Date : April 12, 1988 Subject : Intent to test. (40) 513890 E ld-17 c?\0(q l( TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOLLOWING DOCKET #83002C Eld-FILE Fiche # 40-8893260 From: Inchema, Inc. H. Wessel To: Environmental Protection Agency Document Control Officer Date: April 18, 1988 Subject: Manufacture of subject A chemicals.---- -------- / (41) i 513891 40-8893261 From: Ruhrkohle Tracking Corporation D . Fuhrmann To: Environmental Protection Agency L. Marcus Date: April 19, 1986 Subject: Manufacture of subject chemiik^fc' (42) 513892 40-8893290 From: Atochem, Inc. O. Shusko (M. Hanley's Secretary) To: Environmental Protection Agency L. Marcus Date: May 6,1988 Subject: Cover' letter for enclosure. Enclosure: (l) Letter from M. Hanley to L. Mack, EPA concerning their product "Rilsan BESNO P40 WS" . September 24, 1987 (43) 524823 Eid-18 3_0 6 lV tW TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-e -DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOLLOWING DOCKET #83002C Eld-FILE Fiche # 40-8893291 From: Hoechst Celanese Corporation R. Jourdenais To: Environmental Protection Agency Document Control Officer Date: June 14, 1988 Subject: Intent to test 2,3,5,6-Tetrachloro-2,5-cyclohexadiene1,4-dione. (44) 524824 40-8893292 From: Great Lakes Chemical Corporation C . Mazac To: Environmental Protection Agency L. Marcus Date: July 6, 1988 Subject: Topics and questions for the upcoming protocol review meeting (Letter and Telefax). (45) 524825 40-8893303 From: A and D International, Inc. C. Gupta To: Environmental Protection Agency L. Marcus Date: July 22, 1988 Subject: Exemption request from tontrinq Chloranil. ^ (46) 524826 E ld-19 iH 5-0 G ( TSCA SECTION 8(d) AND 4(a) / HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOLLOWING DOCKET #83002C Eld-FILE Fiche # 40-8893304 From: A and D International, Inc. C . Gupta To: Environmental Protection Agency L. Marcus Date:. July 22, 1988 Subject: Intent to test Chloranil. (47) 524827 40-8893307 From: Sandoz Chemicals Corporation B . Drum To: * Date: Environmental Protection Agency L. Marcus August 17, 1988 Subject: Intent to test 2,3,5,6-Tetrachloro-2,5-cyclohexadiene1,4-dione. (48) 524828 40-8893316 From: Ethyl Corporation P. Sistrunk To: Environmental Protection Agency Document Control Officer Date: September 26, 1988 Subject: Notification of the start of the 2,3,7,8-Tetrabromodibenzofuran test. (49) 524829 Eid- 2 0 /`H 3_0(s? ^ TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOLLOWING DOCKET #83002C Eld-FILE Fiche # 40-8893330 From: A and D International, Inc. C . Gupta To: Environmental Protection Agency C. Elkins Date: November 29, 1988 r Subject: Revision of protocol. (50) 524830 40-8893331 From: The Dow Chemical Company J. Gray To: Environmental Protection Agency Document Control Office Date: December 2, 1988 Subject: Final protocol submission. (51) 524831 40-8993332 From: Midwest Research Institute D. Steele To: Food and Drug Administration, USDHHS D. Firestone Date: January 19, 1989 Subject: Planning for Teleconference. (52) 524832 40-8993359 From: Ethyl Corporation L.L. Wen To: Environmental Protection Agency Document Control Office Date: May 22, 1989 Subject: Production of Pentabromodiphenyl Oxide. (53) 524833 E id-21 15b TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOLLOWING DOCKET #83002C Eld-FILE Fiche # 40-8993365 From: Ethyl Corporation R.L. Smith To: Environmental Protection Agency Document Control Office Date: July 5, 1989 Subject: Waiver request. Enclosure: (1) Letter from L. Wen of Ethyl Corp. to Document Control Office, EPA requesting a waiver on the required testing. May 22, 1989 (54) 524834 40-8993360 From: White Chemical Corporation S.L. Shopsis To: Environmental Protection Agency L. Marcus Date: July 12, 1989 Subject: Manufacture of Decabromodiphenyl Oxide. (55) 524835 40-9093395 From: FMC Corporation R. Roseberry To: Environmental Protection Agency Document Control Officer Date: January 2, 1990 Subject: Request for waiver from testing 2,4-Dibromophenol. (56) 524836 E ld-22 157 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOLLOWING DOCKET #83002C Eld-FILE Fiche # 40-9093445 From: Akzo Chemicals, Inc. E. Bisinger, Jr. To: Environmental Protection Agency Document Control Office Date: March 16, 1990 Subject : Letter of intent to test. (57) 524837 40-9093446 From: Akzo Chemicals, Inc. L. Rausch To : Environmental Protection Agency L. Marcus Date : March 27, 1990 Subject : Cover letter for enclosure. Enclosure (1) Letter of intent to test from E. Bisinger, Jr. of Akzo Chemicals, Inc. to Document Control Office, EPA. March 16, 1990 (58) 524838 Eld-23 I5L TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOLLOWING DOCKET #83002C E ld-FILE Fiche # 40-9093447 From: Triangle Labs., Inc. R. Hass To: Environmental Protection Agency C. Elkins Date : May 4, 1990 Subject : Freedom of Information^^ request.^--- " -- Enclosure: (1) Triangle Laboratories memo from R. Varcoe to R. Hass containing the EPA audit chronology. May 4, 1990 (59) ? 52483j 40-9093448 From: Environmental Protection Agency J. Merenda To : Environmental Protection Agency M. Wood Date : May 9, 1990 Subject: Enforcement action tfecommehHetiragainst Pfister^i Chemical, Inc. --------- (60) 524840 40-9093449 From: Environmental Protection Agency C. Elkins To : Great Lakes Chemical Corporation C. Mazac Date : May 10, 1990 Subject : Acceptance of their sampling protocol. (61) 524841 Eid-24 /53 Q_> fa i TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOLLOWING DOCKET #83002C E ld-FILE Fiche # 40-9093453 From: Environmental Protection Agency J. Remmers To : Great Lakes Chemical Corporation C. Mazac Date : June 11, 1990 Subject : Transmittal of three reports. [Reports Not Provided to Docket] (62 40-9093482 From: Chemical Manufacturers Association (63) H . Shaw To : Environmental Protection Agency L. Marcus Date: June 13, 1990 Subject: Changes in the Brominated Flame Retardant Industry Run-el'Organization. 40-9093483 From: Environmental Protection Agency J. Remmers To : Sandoz Chemicals Corporation B. Drum Date : July 9, 1990 Oy Subject : EPA analysis of Chlornil sample. (64) E ld ^5 /5V' TSCA SECTION 8(d) AND 4(a) / HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS WRITTEN COMMUNICATIONS FOLLOWING DOCKET #83002C Eld-FILE Fiche # 40-9093484 From: Chemical Manufacturers Association (65) H . Shaw To : Environmental Protection Agency J. Remmers Date: July 9, 1990 Subject : Amendment of protocol. 40-90934-85 From: Chemical Manufacturers Association (6 6 ) H . Shaw To : Environmental Protection Agency J. Remmers Date: July 19, 1990 Subject: Conference call of July 25, 1990. Enclosure: (1) Tentative Agenda far /irl-dctolference Call Eid-26 TSCA SECTION 8(d) AND 4 (a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-E-DIOXINS/DIBENZOFURANS TELEPHONE COMMUNICATIONS FOR DOCKET #83002 E 2 a"FILE Fiche # 40-8593151 From: University of Wisconsin, McArdle Lab. for Cancer Research A. Poland (Ik 513893 To: Environmental Protection Agency K. McCormack Date: July 31, 1985 t Subject: Comments on the Position Docuument. (Notes of conversation) 40-8593152 From: Environmental Protection Agency S. Lee To: National Institute of Environmental Health Sciences D. Cantor (NTP) Date: July 31, 1985 Subject: NTP work with Furans. (2) 513894 40-8593153 From: Center for the Biology of Natural Systems B. Commoner To: Environmental Protection Agency K. McCormack Date: August 30, 1985 Subject: Delay in comment submission. (3) 513895 E2a_1 <5.0 ^-(s> TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS TELEPHONE COMMUNICATIONS FOR DOCKET #83002B Ezb-FiLE Fiche # 40-8693154 From: Environmental Protection Agency S. Lee To: Environmental Defense Fund E. Silbergeld Date: June 3, 1986 Subject: EDF's concerns on Dioxins/ Furans in Chlorinated Benzenes. (1) 513896 ...... 40-8693177 From: Environmental Protection Agency P. Tong and R. Gnaedinger To: Environmental Protection Agency S. Billet (Las Vegas, Nevada) Date: June 3, 1986 Subject: Chemical screening methods for the detection of PHDDs and PHDFs. (2) 513897 40-8693155 From: Environmental Protection Agency M. Dreyfus To: Cambridge Isotope Laboratories J. Bradley Date: June 18, 1986 Subject: Current availability of standards. (3) 513898 E 2 b-i 157 aocs.7 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS TELEPHONE COMMUNICATIONS FOR DOCKET #83002C Ezc-FiLE Fiche # 40-8693177 From: Environmental Protection Agency P. Tong and R. Gnaedinger To : Environmental Protection Agency S. Billet Date : June 3, 1986 Subject : Chemical screening methods for the detection of PHDDs and PHDFs. [Crossreferenced to E2t>(2)1 (1) 513897 40-8793198 From: Environmental Protection Agency D. Keehner To : Worker's Institute for Occupational Safety and ,<r>He a T t h Vs- M. Gillen Date : April 15, 1987 Subject : Reasonable estimate of worker dermal exposure. (2) 513899 40-8793199 From: Chemical Manufacturers Association (3) C. Stack To : Environmental Protection Agency D. Keehner Date : April 24, 1987 Subject : Status of test rule. 513900 E2C-! ls i 3l o (o 3 & TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS TELEPHONE COMMUNICATIONS FOR DOCKET #83002C e 2c -f i l e Fiche # 40-8793200 From: Environmental Protection Agency D. Keehner To: The Dow Chemical Company K. Burgess Date: May 4, 1987 Subject: CMA's comments on the dermal exposure of chemical workers. (4) J 513901 E2 c 2 if? TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS PETITIONS FOR DOCKET #83002 E 3a-FILE F iche # 40-8493034 Environmental Defense Fund (1) 513902 Cover letter from R. Percival to W.D. Ruckelshaus, EPA October 22, 1984 Enclosure: (1) Petition of the Environmental ~ i f ) 4 Defense Fund and the National .Wi-LS'life Federation for ^ ^^^mgileirSer^to Prevent `and to ^edutae-^Envi-ro^mental Contamination bYv_ Dioxins and Dibenzofurans. E. ( / Silbergeld, R. Percival (EDF) M. Van Putten, and L.K. Silbert (National Wildlife Federation). October 22, 1984 \ -- E 3a-1 /oo SLOG 3 0 TSCA SECTION 8(d) AND 4(a) ' HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-E-DIOXINS/DIBENZOFURANS PETITIONS FOR DOCKET #83002B E 3b-FILE Fiche # 40-8693156 Section 21 Petition: Environmental Defense Fund and National Wildlife Federation vs. EPA Plaintiffs' Opposition to Defendants* Motion to Dismiss and to Defendants' and Defendant - Intervenor's Motions for Partial Summary Judgment. Civil Action No. 85-973; U.S. District Court for the District of Columbia. EDF and NWF vs. Lei M. Thomas, USEPA et al. February 11, 1986 (1) Order. Plaintiffs' Response to Statements of Material Facts as to Which There is No Genuine Issue bv Defendants ,and Intervenor CMA. Plaintiff's Replv to Defendants' Response to Plaintiff's Statement of Material Facts as to Which There is No Genuine Issue. Memorandum of Points and Authorities in Opposition to Defendants' Motion to Dismiss and to Defendants' and Defendant -Intervenor's Motions for Partial Summary Judament and in Replv to Defendants' and Defendant - Intervenor's Opposition to Plaintiffs' Motion for Partial Summary Judament. February 11 , 1986 (1) 513903 Esb"1 Ib I TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS PETITIONS FOR DOCKET #83002B E 3b-FILE Fiche # 40-8693156 (continued) (5) Supplemental Declaration of Ellen K. Silbergeld. February 10, 1986 (a) Chemicals Ignored in Federal Register Testing Notice Pre viously Acknowledged bv EPA as Possibly Contaminated with Dioxin. (Exhibit A) E 3b - 2 /i>2 - TSCA SECTION 8(d) and 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF DECEMBER 19, 1985 (DOCKET #83002) F-l- F I L E Fiche # 40-8693183 Chemical Manufacturers Association (1) 513904 Cover letter from C. Stack to S. Rudzinski, EPA September 12, 1986 . Enclosure: (1) Letter from Visband Der Chemischen Industrie (Germany) to R. Roland, CMA (Press Release). September 3, 1986 (a ) Kunststoffe mit Flammschutz auf dem Prfstand. (German) August 29, 1986 40-8693338 Monsanto Chemical Company Letter from C. Farley to Document Control Officer, EPA April 3, 1986 Enclosure : (1) Analysis of Brominated Diphenyl Oxides for Brominated Dibenzofurans. (2) 524842 F -1 1 (>3 aofc33 TSCA SECTION 8(d) and 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF OCTOBER 23, 1986 (DOCKET #83002B) Gi-FILE Fiche # 40-8693283 Great Lakes Chemical Corporation Response to EPA Ouestions Received from Steven Hassnr. Ph.D. (Sanitized) December 17, 1986 (1) 513905 - --1 i i-1 Oof 5.0 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1987 ONLY H 1 .0 "FILE 40-8793277 Atochem, Inc. Fiche # j (1) 513909 Letter from M. Hanley to Document Con trol Officer, EPA concerning informa tion requested on "RiIson Besno P40 - W5". September 24, 1987 40-8793278 Dead Sea Bromine Company Ltd. Teratology Study in the Rat (FR-1208). Life Science Research, Israel Ltd. February 10, 1987 (2) 513908 40-8793334 (The) Dow Chemical Company (3) Letter from R.L. Hagerman to Document Control Office, EPA October 5, 1987 Enclosures: (1) PCDDs and PCDFs in Environmental Samples: Air. Particulates. Sedi ments and SoiT C . Rappe and Kjeller, Univ. of Umea, Sweden. Presented at the U.S. Vinyl Insti- ^-- - '\ tute Meeting. Document No. f r c t l d O j > ^ 0 'Btr0"24-enl. 8(d) Submission: 86-880000047. '-- ---- - ' January 26, 1987 (2) Search for Industrial Sources of PCDD/PCDF. III. Short-Chain Chlorinated Hydrocarbons. A. Heindl and 0. Huntzinger, Univ. of Bayreuth, FRG. Document No. D002402. 8(d) Submission: 86-880000048. Undated 524843 Hi.cr1 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1987 ONLY H i .q - F I L E Fiche # 40-8793334 (continued) (3) Letter from R. Cook, The Dow Chemical Co. to T. Cresswell, P. Gehring, C. Goodman, R. Kagel and B. Weaver August 7, 1986 (a) A Cohort Mortality Study of Chemical Workers with Poten tial Exposure to the Higher Chlorinated Dioxins. M.G. Ott, R .A. Olson, R. Cook and G. Bond. Document No. D002403. 8(d) Submission: 86-880000049. July 8, 1986 (4) Dioxin and Resource Recovery Symposium ASCE - New York Hilton 2/10/87 The Dioxin Situation in West Germany. K. Ballschmiter. Document No. D002404. 8(d) Submi ssion:86-880000050. Undated (5) Summary of Experiments with PVC Combustion Products. L.C. Dickson and F.W. Karasek, Univ. of Waterloo, Ontario. Document No. D002405. 8(d) Submission: 86-880000051. Undated (6) Toxicity of Particulate Emissions From a Municipal Incinerator: Critique of the Concept of TCDDEauivalents. M. Suter-Hofman and Ch. Schlatter, Univ. of Switzer land and Federal Institute of Technology, Switzerland. Document No. D002406. 8(d) Submission: 86-880000052. Undated H1.0"2 TSCA SECTION 8 (d) AND 4(a) / HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1987 ONLY H i .q - f i l e Fiche 40-8793334 (continued) (7) Dioxins and Incineration - Visit to Professor C. Rappe. UMEA. January 16. 1987. M. Ronnmark and H.M. Clayton. Document No. "V O c ` 8 (d) Submission:^ 86-880000053.-- ------------ Undated (8 ) Analysis of the Animal Toxicity Studies of 2 .3.7.8 -Tetrachloro- dibenzo--o-Dioxin (TCDD) Used in Derivation Of Lifetime ExDosure Control Limit Recommendations for Humans. R.J. Kociba, The Dow q Chemical Co. Document No. rQ V t ) > {{ o D00240S> 8 (d) Submission:*^ 8 6-88000005 4. -----------J June 10, 1986 (9) The Toxicological Significance of 2.3.7.8 -Tetrachlorodibenzo-pDioxin and Related Compounds in Human Adipose Tissue. J.L. Byard. Document No. D002409. 8 (d) Submission:86-880000055. Undated 10) The Formation of Folliculitis in the Rabbit Ear Following a Single , Subcutaneous Injection of C ~ ~ -B-yrompf^cal Tetrachlorodibenzo-<d^L:A Benzene^ The Dow Chemical--Ge- Document No. > 3 // B0B3G&L.. ^TK'&fomission^:J/<\ ----------------------------------------------- >* March 5, 1965 ^ f ($ ) yJ nt H i . 0-3 3,0(02)7 I/ TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1987 ONLY H]_.q -FILE Fiche 40-8793334 (continued) (11) The Effects of Repeated Applica tions of Symmetrical Tetrachlordibenzodioxin on Guinea Pig Ears. The Dow Chemical Co. Document No. D002380. 8(d) Submission: 86-88000040. Undated (12) The Effects of Repeated Applica tions of Symmetrical Tetrachlordibenzodioxin on the Rat Ear. The Dow Chemical Co. Document No. D002382. 8(d) Submission: 86-880000041. Undated (13) Chloracne Study Conducted on 1.2.3.4,7.8-Hexachlorodibenzo-pDioxin. The Dow Chemical Co. Document No. D002385. 8(d) Submission:86-880000042. March 22, 1971 (14) The Ineffectiveness of Washing as a Preventive Measure in the ^Fp-ry^tion of Folliculitis in the -- Rabbit Ear Following Repeated Applications of Symmetrical Tetrachlorodibenzodioxin. The Dow Chemical Co. Document No. D002386. 8(d) Submission:86-880000043. March 5 , 1965 (15) Bioconcentration Kinetics of T y ^ - f 2 f3 .7.8--Tetrachlorodibenzo--p-- -- r Dioxin in Rainbow Trout (A Revised Draft of Dow Report November 15. j 1978 ). D.R. Branson, J.T. Tukahashi, W.M. Parker and G.E. Blass. Document No. D002394. ( 8(d) Submission:86-880000044. 1983 H l.O -" ao(<>3 M TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1987 ONLY Hi . o - F IL E Fiche 40-8793334 (continued) (16) Analysis of Gall Bladders of Trout Exposed to 14C-TCDD in the Static Biocbncentration Experiment. Dow _ Chemical USA. Document No. 1 iD00-2398-- 8(d) Submission: 86-880000045. September 29 1978 (17) Notes by G. Stabenow on the German translation of study enclosed. Document No. D002400. 8(d) Submission:86-880000041. November 24, 1986 (a) Mass Burning - Unprepared Refuse Martin Stocker J r i g { j [ / " fWgy^fwall Boiler-Power-----Generator and Steam Supply to District Heating Systems.-- (b) Analyses of the Blood Serum < of Employees of a Refuse. /L L a T ~ and-Power Plant in ---- --- Regard to Cadmium. Lead and Mercury. (German Translation) Translation) International -- Journal for Power Plant Tech nology. October 1984 (c ) The New Bielefeld - Herford Refuse Incinerator Plant - An Unexpected Case of Corrosion. (German Translation) Inter national. Journal for Power Plant Technology. September 1989 (d) Mass Burning Unprepared Refuse Duesseldorf Stoker Waterwall Boiler Power Generation and In-plant Steam Use. 3-00>3S TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1987 ONLY H1 . ( T FILE Fiche # 40-8793334 (continued) (e ) Chance of Emissions of NOx and CO After Optimization of the Refuse Incineration Instilla tion Wuppertal-Remseheid. (German Translation) Mull and Abfall. January 1985 (f ) Technical Installation Measures for the Emission. Reduction of Chlorinated Hydrocarbons at Municipal Refuse Incineration Plants. (German Translation) Mull and Abfall. February 1985 (g ) Emissions of Polychlorinated Dibenzodioxins and P o l y , -/j <iS h .'C b tTflnated Dibenzofurans from Waste Incinerators.---- -- (German Translation) Hull and "-- Abfall; page 313-327. November 1984 (h) List of Task Group for Dioxin control - German Federal Government. (i) Establishment of a Project Group "Dioxin in Refuse Incineration Installations". (German Translation) (j) Street European NOx Code Brings SCR Into the Limelight. Pollution Control; pages 53 and 56. August 1966 H 1.0-6 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1987 ONLY Hl.O-FILE Fiche # 40-8793334 (continued) (18) Results of Chick Edema Bioassav Test Using Young Chickens Treated Orally for 21 Davs with Hexachlorodibenzo-p-Dioxin. J.L. Emerson and C.G. Gerbig. Document No. D002365. 8(d) Submission: 86-880000024. August 4, 1971 (19) Summary of Eve Irritation Study Conducted on Hexachlorodibenzo-pDioxin. Dow Chemical USA. Document No. D002366. 8(d) Submission:86-880000025. October 25, 1971 (20) Summary of Chloracne Study ^rtducted on 1.2.3.7.8.9-Hex ^chT^r-<5j3lbenzo-p-Dioxin. Dow Chemical USA. Document No. D002367. 8(d) Submission: 86-880000026. July 8, 1971 .(21) Summary of Chloracne Study Q ~ j ^Cbflducted on Hexachlorodibenzo-pDioxin. Dow Chemical USA, Document No. D002368. 8(d) Submission: " 880000027. July 14, 1971 (22) Summary of Acute Oral and Chloracne Studies on Hexachlorodibenzo-pDioxin. Dow Chemical USA. Document No. D002369. 8(d) Submission:86-880000028. April 10, 1971 H 1.0-7 P-OfcMi TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1987 ONLY Hl.o -FILE Fiche 40-8793334 (continued) (23 ) Summary of Chloracne Study conducted on Hexachlorodibenzo-pDioxin. The Dow Chemical Co. Document No. DO02370. 8(d) Submission:86-880000029. December ll, 1970 (24) Summary of Chloracne Studies Con ducted on Hexachlorodibenzo-pDioxin Studies. The Dow Chemical Co. Document No. D002371. 8(d) Submission:86-880000030. November 3, 1970 (25) Summary of Chloracne Studies Con ducted on Hexachlorodibenzo-pDioxin Studies. The Dow Chemical Co. Document No. D002372. 8(d) Submission:86-880000031. September 10, 1970 (26) Results of Chick Edema Bioassay Test Using Young Chickens Treated Orally for 21 Davs with 2.3.7.8Tetrachlorodibenzo-p-Dioxin. The Dow Chemical Co. Document No. D002373. 8(d) Submission: 86-880000032. August 6, 1971 (27 ) Urinary Excretion of Radioactivity Following Oral Admininstration of 14C-Labeled 2.3.7.8-Tetrachlorodibenzo-p-Dioxin (TCDD) to Female Guinea Pigs. Dow Chemical USA. Document No. D002374. 8(d) Submission:86-880000033. July 9, 1979 H 1.0-8 TSCA SECTION 8(d) AND 4(a) / HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1987 ONLY H i .q -f i l e Fiche # 40-8793334 (continued) (28) 2.3.7.8-Tetrachlorodibenzo-pDioxin: Tissue Distribution and Excretion Following a Single Oral Dose in Female Guinea Pigs. Dow Chemical USA. Document No. D002375. 8(d) Submission: 86-880000034. August 22,1978 (29) Summary of Eve Irritation Study Conducted on 2,3.7.8-Tetrachlorodibenzo-p-Dioxin. Dow Chemical USA. Document No. D002376. 8(d) * Submission:86-880000035. October 25, 1971 (30) Summary of Chloracne Study Con ducted on 2.3.7.8-Tetrachlorodibenzo-p-Dioxin. Dow Chemical USA. Document No. D002377. 8(d) Submi ssion:86-880000036. April 20, 1971 (31) The Effects of Various Doses of 2.3.7.8-Tetrachlorodibenzo-pDioxin Administered with 2.4.5Trichlorophenoxv Acetic Acid on Rat Fetal Development. G.L. Sparschu, F.L. Dunn, R.W. Lisowe and V.K. Rowe. Document No. D002378. 8(d) Submission: 86-880000037. (32) The Ineffectiveness of Washing as a Preventive Measure in the Formation of Folliculitis in the Rabbit Ear Following Repeated. a Applications of 2 . 3 . 7 . ~ . T^tr^ati^lt^rydibenzo-p-Dioxin in (v**L Gor-rsJ&vts Dow Chemical USA. Document No. D002379. 8(d) Submission:86-880000038. ' March 26, 1965 H 1.0-9 173 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1987 ONLY Hi . o - FILE Fiche # 40-8793334 (continued) (33) Acute Oral Toxicity of 2.3.7.8Tetrabromodibenzo-p-Dioxin in the Rat. Brominated Flame Retardant Industry Panel; Inhausen Research Institute, Inc. Document No. D002364. 8(d) Submission: 86-880000023. Undated (34) Rabbit Ear Bioassav for C o m e g o g e ^ -- M e itv. Multiple-Dose-Level tive Study with 2.3.7.8-' - Tetrr%frfqfttftdibenzofuran. r * ' u Retardant *-- -7^7---- ____ Industry Panel; Inhausen Research " Institute, Inc. Document No. D002363. 8(d) Submission:"""" 86-880000022. Undated (35) Acute Oral Toxicity of 2.3.7.8Tetrabromodibenzofuran in the Rat, Brominated Flame Retardant rntts&ETy Panel; Inhausen Research-*--Institute, Inc. Document No.-D002362. 8(d) Submission: ' "" 86-880000021. Undated (36) Rabbit Ear Bioassav for Comedoge/U^ a c itv. Multiple-Dose-Level Definitive Study with 2.3.7.8Tetrabromodibenzo-p-Dioxin. Brominated Flame Retardant Industry Panel; Inhausen Research Institute, Inc. Document No^--- D002361. 8(d) S u b m i ssion: -- " 86-880000020. Undated H i . c r 10 SlfcC TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1987 ONLY H i .0 -F!LE Fiche # 40-8793334 (continued) (37) Toxicology of Chlorinated Dibenzop-Dioxins. B.A. Schwetz, J.M. Norris, G.L. Sparschu, V.K. Rowe and P.J. Gehring. Document No. D002358. 8(d) Submission: 86-880000019. Undated (38) Mortality Among Employees Engaged in the Manufacture of Higher Chlorinated Phenols and Derivative Products. Dow Chemical USA. Document No. D002356. 8(d) Submission:86-880000018. 1982 (39) Evaluation of Mortality Patterns Among Chemical Workers with Chloracne. G.G. Bond, R. Cook, F. E. Brenner, D.J. Ducommun and E .A . McLaren. Document No. D002354. 8(d) Submission: 86-880000017. September 1986 (40) Update of the Mortality Experience of Workers Exposed to Chlorinated Dioxins. R. Cook, G. Bond, R. Olson and M.G. Ott. Document No. D002353. 8(d) Submission: 86-880000016. September 1986 (41) A Soft Tissue Sarcoma Case Control Study in a Large Multi-Chemical Manufacturing Facility. W. Sobel, G. Bond, B. Skowronski, P. I^wyi and R . C o o k . D ocum ent * 3-0(45 \1S TSCA SECTION 8(d) AND 4(a) ' HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1987 ONLY Hi .q-f i l e Fiche # 40-8793335 (The) Dow Chemical Company (4) 524844 Letter from R.L. Hagerman to Document Control Office, EPA October 6, 1987 Enclosures: (1) Original letter from R.L. Hagerman, The Dow Chemical Company to Document Control Office, EPA submitting 8(d) studies. October 5, 1987 (2) List of Studies Known to Us But ___ > Copies of Which We Do Not Possess in Our Files. 40-8793336 (The) Dow Chemical Company - 'Jtfketter from R.L. Hagerman to Document 4 'Control Office, EPA p c t o ber 7, 1987 Enclosures: (1) Studies in Progress. (Revised) (2) Original cover letter from R.L. Hagerman, The Dow Chemical Co., to Document Control Office, EPA transmitting 8(d) studies. October 5, 1987 (5) 524845 il*' H i.o- 12 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET # 8 3 0 0 2 0 - FOR 1987 ONLY H l.0 -F ILE 40-8793280 Eastman Kodak Company V (6) Fiche # 513910 Letter to Document Control Officer, EPA from R.D. Gerwe September 28, 1987 Enclosure: (1) Report forms in compliance with TSCA Section 8(a) for 1,2Dichlorobenzene, Chlorobenzene, imported products and (CBI) products. (Sanitized) 40-8793279 E.I. Dupont de Nemours and Company, Inc. (7) 513907 Letter from R.R. Houston to Document Control Officer, EPA (Sanitized) September 22, 1987 Enclosure : (1) EPA Form 7710r51, Part II containing process and reaction condition information. (Sanitized) 40-8793281 Ethyl Corporation Letter from Terry H. Pullin to Document Control Officer, EPA September 1, 1987 Enclosures: (1) Letter of intent from T. Pullin, Ethyl Corp. to Document Control Officer, EPA to conduct tests on Pentabromodiphenyl Oxide and Octabromodiphenyl Oxide. September 1, 1987 (8) 513906 H l . O " 13 111 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-J3-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1987 ONLY f H-i-FILE ( `V J V Fiche # 40-8793281 (continued) (2) Application for an exclusion to conduct tests on Tetrabromobisphenol A and Decabromodiphenyl Oxide from T. Pullin, Ethyl Corp. to Document Control Officer, EPA. (Sanitized) September 1, 1987 (a ) Polybrominated Dibenzodioxins (PBrDD) and Dibenzofurans (PBrDF) in Some Flame Retar dant Preparations --- -Chemosphere; 15(9-12):2111-n 2113.----- --------------- ^ 1986 (b ) CBI. (c) CBI. 40-8793282 Ethyl Corporation Cover letter from T.G. Pullin to Document Control Officer, EPA September 29, 1987 Enclosures: (1) Analysis of Brominated Diphenyl Oxides for Brominated Dibenzofurans. (2) Rabbit Ear Bioassay for Comedoqenicity, Dose-Range-Findinq Study for Soot and Char Generated from the Combustion of High Impact Poly styrene . Inhausen Research Institute Inc.; Study #119.001. August 1987 (9) 513913 Hi-14 XOio'M 111) TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1987 ONLY H i >0-f i l e Fiche 40-8793282 (continued) (3) Rabbit Ear Bioassav for Comedogenicitv. Dose-Ranae-Finding Study for Soot and Char Generated from the Combustion of High Impact Polystyrene Flame Retarded with Decabromodiphenvl Oxide and Antimony Trioxide. Inhausen Research Institute, Inc.; Study #119.002. August 1987 (4) Rabbit Ear Bioassav for Comedogenicitv. Multiple-Dose-Level Definitive Study with 2.3.7.8Tetrabromodibenzo-p-Dioxin. Inhausen Research Institute, Inc.; Study #119.003. August 1987 (5) Rabbit Ear Bioassav for Comedogenicitv. Multiple-Dose-Level Definitive Study with 2.3.7.8Tetrabromodibenzofuran. Inhausen Research Institute, Inc.; Study #119.004. August 1987 (6) Rabbit Ear Bioassav for Comedogenicitv Multiple-Dose-Level Definitive Study for Soot and Char Generated from the Combustion of High Impact Polystyrene. Inhausen Research Institute, Inc.; Study #119.005. August 1987 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1987 ONLY H i .q - f i l e Fiche # 40-8793282 (continued) (7) Rabbit Ear Bioassav for Comedogenicitv. Multiple-Dose-Level Definitive Study for Soot and Char Generated from the Combustion of High Impact Polystyrene Flame Retarded with Decabromodiphenvloxide and Antimony Trioxide. Inhausen Research Institute, Inc.; Study #119.006. August 1987 (8) Acute Oral Toxicity of 2.3.7.8Tetrabromodibenzo-p-Dioxin in the Rat. Inhausen Research Institute, Inc.; Study #119.007. August 1987 (9) Acute Oral Toxicity of 2.3.7.8Tetrabromodibenzo-p-Dioxin in the Rat. Inhausen Research Institute, Inc.; Study #119.008. August 1987 (10) Acute Oral Toxicity in the Rat of Soot and Char Generated from the Combustion of High Impact Poly styrene (HIPs). Inhausen Research Institute, Inc.; Study #119.009. August 1987 (11) Acute Oral Toxicity in the Rat of Soot and Char Generated from the Combustion of High Impact Poly styrene Flame Retarded with Decabromodiphenvl Oxide and Antimony Trioxide (HIPs FR). Inhausen Research Institute, Inc.; Study #119.010. August 1987 H i . o - 16 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1987 ONLY H1>0-FILE Fiche # 40-8793236 General Electric Company (10) 513918 Letter from S. Austin to Document Control Officer, EPA December 23, 1987 Enclosure: (1) Pvrolvtic Formation of Polvbrominated Dibenzodioxins and Polvbrominated Dibenzofurans. (Table III) 40-8793237 Monsanto Company Letter from J. Downes to Document Control Officer, EPA December 22, 1987 Enclosure: (1) Dibenzofuran in Diphenyl Oxide and the Relationship to Brominated Dibenzofurans in Brominated Diphenyl Oxide. F. Hileman, J. Wehler, J. Wendling, R. Orth, C. Ritchie and D. McKenzie. Preprint to be published in Chemosphere. From the Proceedings of the 7th International Symposium on. Chlorinated Dioxins and Related Compounds,- October 4-9, 1987. 1988 (11) 513917 J>G?51 l?l TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1987 ONLY H i >0-f i l e Fiche # 40-8793286 Rohm and Haas Company (12) 513911 Cover letter from G.J. Powell to Document Control Officer, EPA September 28, 1987 Enclosure: (1) Dioxin/Furan Report Form (in compliance with TSCA Section 8(a)) for Chlorobenzenes. (Sanitized) 40-8793287 Rohm and Haas Company Cover letter from R.L. Keener to Document Control Officer, EPA September 29, 1987 Enclosure: (1) Dioxin/Furan Report Form for Chlorobenzene (TSCA Section 8(a) submission). (Sanitized) (13) 513912 Hi.cr1 1^ TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1987 ONLY Hi ,0-FILE .Fiche # 40-8793288 Rohm and Haas Company (14) 513915 Letter from R.L. Keener to Document Control Officer, EPA (Sanitized) October 5, 1987 Enclosures: (1) Analysis of Dov and Rhodia 2.4Dichlorophenol. (Sanitized) October 17, 1977 (2) , Analysis of i 1 and 2.4-DCP for 1.3.6.8-TCDD and 2.3.7.8-TCDD and of 2.4-DCP for 2.4.6-TCP and 2.4.5-TCP. (Sanitized) May 18, 1987 (3) Results of Analyses for 2,7-Dichlorodibenzo-p-Dioxin. (Sanitized) October 2, 1970 40-8793285 Rhone-Poulenc, Inc. Letter from N.I. Rouse to Document Control Officer, EPA October 5, 1987 Enclosures: (1) 2.4 Dichlorophenol Test Results. (2) Plan for the Determination of Polychlorinated Dibenzo-p-dioxins (PCDDs) and Polychlorinated Dibenzofurans (PCDFs). (15) 513916 H i . o - 19 (?3 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1987 ONLY Hx 0-FILE 40-8793234 Standard Chlorine of Delaware, Inc. V (16) Fiche # 513914 Letter from R. Touhey to Document Control Officer, EPA September 30, 1987 - Enclosure: r (1) Process Block Flow Diagram. Corrected copy of one submitted in the September 28, 1987 submission (CBI). H1.0-20 f / f }!>-<& TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET vSPPeRT RE FERENCES FOR DOCKFT // S^FlLE 's/*O 5 - F/?/?- _Fi C he ^0 /J TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1988 ONLY H 2 !-FILE Fiche # 40-8893310 A and D International, Inc. (1) 524846 Letter to L. Marcus, EPA September 16, 1988 Enclosure: (1) Analytical Procedures for the Determination of Polychlorinated Dibenzodioxins and Dibenzofurans by High-Resolution Gas Chromato graphy /High-Resolution Mass Spec trometry (HRGC/HRMS). Triangle Laboratories, Inc. August 1988 40-8893308 Brominated Flame Retardants Industry Panel Letter from P.H. Sistrunk, Ethyl Corp. to Document Processing Center, EPA September 6, 1988 Enclosure: (1) Acute Oral Toxicity of 2.3.7.8Tetrabromodibenzofuran (TBDF) in the Rat. (Draft) Inhausen Research Institute, Inc.; Study No. 119.022. (2) 524847 H l.l- 1 iSCo TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1988 ONLY H-l x-f i l e Fiche # 40-8893299 Chugai International Corporation (3) -524848 Cover letter from R. Tanaka to P. Halper, EPA July 21, 1988 Enclosure: (1) Letter from N. Takahashi of Nippon Kayaku Co. Ltd. July 18, 1988 (a) Analytical Determination of Dioxin in Tetrachloro-pBenzoauinone (Chloranil). Japan Food Research Labs. 40-8893296 (The) Dow Chemical Company Cover letter from J. Gray to Document Control Office, EPA July 1, 1988 Enclosures : (1) Sampling Protocol for the Determi nation of Halogenated Dibenzo-pDioxins and Dibenzofurans in 2.4Dichlorophenol. Dow Chemical USA. June 29, 1988 (2) Quality Assurance Project Plan for Determination of Halogenated Dibenzo-p-Dioxins and Dibenzofurans. Environmental Protection Agency; Chemserv. (4) 524849 H i . 1-2 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET # 8 3 0 0 2 0 - FOR 1988 ONLY H x j-FILE Fiche # 40-8893319 (The) Dow Chemical Company (4a) 524850 Letter from J. Gray to Document Control Office, EPA December 1 6 , 1988 Enclosure: (1) Sampling Protocol for the Deter mination of Halogenated Dibenzop-Dioxins and Dibenzofurans in 2.4-Dichlorophenol. Dow Chemical USA. (2) Protocol and Quality Assurance Plan for the Determination of Halogenated Dibenzo-p-Dioxins and Dibenzofurans in 2.4-Dichloro phenol . Dow Chemical USA. 40-8893339 Great Lakes Chemical Corporation Letter from D.L. McFadden to Document Processing Center, EPA November 28, 1988 Enclosures : (1) Listing of.test studies. (2) Studies on 1.2-Bis-(Tribromophenoxv)Ethane for Velsicol Chemical Corp.: (a) Rate of Hydrolysis Studies. September 22, 1988 (b) Pharmacokinetic Study of FM680 in Rats. August 11, 1978 (c ) Photolysis of Firemaster 680 January 23, 1979 (4b) 524851 H i . 1-3 3.0 (of TSCA SECTION 8(d) AND 4(a) ./ HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1988 ONLY H x>2-FILE .Fiche # 40-8893339 (continued) (d) Water Solubility of Several Flame Retardants a n d ^ ^ w JTIQftytrial Chemicals. April 12, 1978 (3) Studies on 1 ,2-Bis(Tribroommoo: s^frenoxv-1)-Ethane for Michig; Chemical Corp.-~----- --- (a) 28-Dav Rat Feeding Study. WARF Institute, Inc.; Report No. 2071960. (b) Acute Oral LD50: Acute Dermal LD50: Skin Irritation and Eve Irritation Studies. Warf Institute, Inc.; Report No. 2081295. September 11, 1972 (c) Acute Oral Toxicity Study in /. the Albino Rat. Interna ^tj-errasi. Research and A Development Corp. November 27, 1974 (d) Acute Dermal LD50 on GMTrmaster 680. (Corrected] Wari Institute, Inc.; Report 3022861 . June 14, 1973 (e ) Acute Inhalation Toxicitvin the Albino Rati nterna^^' <'CTU!Ta4r-Research and A Development^Corp57^Toeport No. 134-013 .-- -- _________ ___________ November 27, 1974 (f) Acute Oral Toxicity Study in Beagle Dogs. International Research and Development Corp.; Report No. 134-012. November 27, 1984 H i . 1-4 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1988 ONLY Hx 2.-FILE Fiche # 40-8893339 (continued) (g) Acute Toxicity (TL50) Study. f\ in the BIuegilL. Intern fl'dn'dT Research and Develop'****~f "iireirt- Corp. ; Report No. 134-fl/(i > I December 13. 1974 (h) Acute Heated Vapor Inhalation Toxicity Study in Rats. Industrial Bio-Test Labs., Inc.; Report No. 8562-09787. December 6,1976 (i) Modified Draize Multiple Insult Test in Male Humans. International Research and Development Corp.; Report No. 134-017. January 30, 1975 (j) Twenty-Eight Dav Dermal Toxicity Study in Rabbits. International Research and Development Corp.; Study No. 134-015. February 11, 1975 (k) Twentv-One Dav Inhalation Toxicity Study in Rats. International Research and Development Corp.; Study No. 134-016. February 11, 1975 (1) Acute Inhalation Toxicity in the Albino Rat After Pvrolvsis. International Research and Development Corp.; Study No. 134-039 and No. 134-038. March 12, 1975 Hi.l-= \% TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1988 ONLY H x 2 -FILE Fiche # 40-8893339 (continued) (m) Fourteen-Dav Range Finding Study in Rats. International Research and Development Corp.; Study No. 134-053. April 10, 1975 (n) Twenty-Eight Dav Toxicity Study in Rats. International Research and Development Corp.; Study No. 134-018. May 19, 1975 (o) Biodegradation Study with flyflY^Tagged MC-680. LndustT-rat' Bio -Test Labs , No 632-07189 June 11, 1976 (p) Primary Skin Irritation Test with Mother Liquor 680 Process. Code No. 7-29-.76-B / Tn Albino Rabbits. FTTdustTrar Bio-Test # J7a5oraori'eK~;-- indTTjStudy 8530-09618 No. > October 25, 1976 (q) Shin Sensitization Test With Mother Liquor 680 Process in Albino Guinea Pigs. Indus trial Bio-Test Laboratories, Inc.; Study No. 8530-09618. December 8, 1976 (r) 90-Dav Subacute Oral Tbxicitv Study with Firemaster^ 680 in Albino Rats. Industrial Bior Test Laboratories, Inc. ; S jJ & H ^tuGy^No. 8532-08925 and f y * Addendum.----January 6, 1977 and March 10, 1977 H i . 1-6 |Sf| TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1988 ONLY h 2 x-FILE Fiche # 40-8893339 (continued) (s ) Mutagenicity Evaluation of 859-74-5. Litton Bionetics, Inc.; Project No. 2547. May 25 , 1976 (t) Pilot Teratology Study in Rats. International Research and Development Corp.; Study No. 163-544. March 2, 1978 (u) Teratology Study in Rats. International Research and Development Corp.; Study No. 163-547. February 13, 1979 (v) Tissue Residue^ Accumulai:ion/ /bBoir^tories , Inc. ; Study No. f 5"3^- " (8>3^V08950. January 9, 1979 (4) Studies on Pentabromodiphenvl (U Qy-Lrto- for Great Lakes Chemical r. ion : (a) Mutagenicity Evaluation of Pentabromodiphenvl Ether. Litton Bionetics, Inc.; Project No. 2547. May 25, 1976 (b) The Acute Oral Toxicity of Pentabromodiphenvl Ethpr to Rats. The British Industrial Biological Research Assoc. 132- TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1988 ONLY H x q-FILE Fiche # 40-8893339 (continued) (c ) Acute Toxicity Studies , ftdtA and Rabbits. fj internaLiTjiial Research and O^ve^opHterTt* Corp. ; Study N o . 4 \ * 274-025 October 31, 1975 (d) Twenty-eight Dav Toxicity Study in Rats. International Research and Development Corp.; Study No. 274-023. January 24, 1976 (e ) The Bioaccumulation of Compound S-512 by Carp. Chemicals Inspection and Testing Institute, Japan. (f) 30-Dav Dietary Study. WIL Research Laboratories, Inc.; Project No. 12042. Three volumes. December 4, 1985 (g) 90-Dav Dietary Study. Three y Volumes. Wil Research Laboratories, Inc.; Project No. 12011. October 8, 1984 (5) Studies on Qctabromodiphenvl Oxide for Great Lakes Chemical Corp.: (a) The Bioaccumulation of Compound S-511 bv Carp. Chemicals Inspection and Testing Institute, Japan. 1982 Hl . l - 8 a (. 6 3 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1988 ONLY Hx j-FILE Fiche # 40-8893339 (continued) (b) Acute Toxicity Studies in fca/b-g^and Rabbits. Interna"=fci*v^iy trioflgT Research and Develop^^^^* -men-te Corp. ; Study No. 274- 0 ^ ( i ' I VOctober 31, 1975 (c ) Subacute Inhalation Toxicity Study in Rats. International Research and Development Corp.; Study No. 274-035. July 27, 1978 (d ) Mutagenicity Evaluation of Compound 345-79A. Litton Bionetics, Inc. 1976 (e ) In Vitro Sister Chromatid Exchange in Chinese Hamster Ovarv Cells with Octabromodiphenvl Ether. Hazleton Laboratories America, Inc. November 18, 1982 (f ) Unscheduled DNA Synthesis _j-- Assay Compound DE799. Har&iefeQn Laborator ies /\0 America,"Inc.---- , March 9, 1983 (g ) Twentv-eight Dav Toxicity Study in Rats. International Research and Development Corporation; Study No. 3274023. January 24, 1976 (h) Thirteen Week Feeding Study Ua jy Rats. (Revised) I n t e r / r U L * - ^tional Research and - &eveSk7pment Corp.; Study No.lk 27 4-029.--- ------- -- ----- ---- 1 April 18, 1978 H l.l-9 Co4 TSCA SECTION 8(d) AND 4(a) / HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET # 8 3 0 0 2 0 - FOR 1988 ONLY E 1 -l-FILE Fiche # 40-8893339 (continued) (i) A Range-Finding Teratology Study in Rats with DE-79. WIL Research Labs., Inc.; Study No. 12051. August 25, 1986 ... 40-8893297 Hoechst Celanese Corporation Cover letter from R. Jourdenais to Document Control Officer, EPA July 8, 1988 x Enclosures: (1) Quality Assurance Plan for Poly chlorinated Chemical Sample Analysis. Triangle Labs., Inc. July 3, 1988 (2) Analytical Procedures for the Determination of Polychlorinated Dibenzodioxins and Dibenzofurans by High-Resolution Gas Chromato- graphv/High-Resolution Mass ) -t 'gfo&fltrometrv (HRGC/HRMS). "T -Ji'rNLafP?i& Labs. Inc. July 1988 J (5) 524852 40-8893313 Hoechst Celanese Corporation (6) Letter from D. Woodhull to L. Moos, EPA October 24, 1988 Enclosure : (1) Report of Air Sampling for the Presence of Polvbrominated -- pngetOfipdioxins and Dibenzofuranj/ the Production of P a f\ ^dlyBtrtfvtrf^Terephthalate Resin'u a w V~ fr4th~-dTb'ab:DOofodiphenvl Oxide. (j 524853 __ ~~ Hi.i-10 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1988 ONLY Hi i-FILE Fiche # 40-8893186 Hoechst-Celanese Corporation (7) 524854 Letter from D. Woodhull to L. Moos EPA with corrections to the October 24 I 9 U 3r9-8fT report "Air Sampling for the Presence-- Poiybrominated Dibenzc dioxifts-- and l#&ftzofurans During the & / p ^ P roduction of Poi^jbutvlene Terephtha&tc Late 1 1 ! rffibromodiphenyl Oxide" November 8, 1988 - M & O u' ^ M n 40-8893298 Midwest Research Institute Letter from D. Steele to T. Murray, EPA July 13, 1988 Enclosure: (1) Review of "The Dow Chemical Co. Sampling and Analytical Protocols for 2 ,4-Dichlorophenol". (8) 524855 40-8893341 Midwest Research Institute Letter from D. Steele to T. Murray, EPA on the review of the report by BFRIP on the Hoechst Celanese Corp., Bishop, Texas plant air monitoring study. November 18, 1988 (9) 524856 H i . 1-11 [% TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1988 ONLY H-l -l-FILE Fiche # 40-8893302 Sandoz Chemicals Corporation (10) 524857 Letter from B. Drum to L. Marcus, EPA August 17, 1988 Enclosures: (1) Determination of Polvhalogenated Dibenzo-p-Dioxins and Dibenzofurans in 2.3.5.6-Tetrachloro2.5-cvclohexadiene-l.4-dione: Sample Selection and Sampling Plan. August 17, 1988 40-8893305 Sandoz Chemicals Corporation Letter from B. Drum to L. Marcus, EPA August 17, 1988 Enclosure : (1) Dioxins/Furans Report form #791051 Part II for: 2.6-Dibromo-4riitroaniline. Chlorobenzene and 2 .6-Dichloro-4-nitroaniline. (11) 524858 h i .i-12 I <N TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1988 ONLY H x -l-FILE Fiche # 40-8893306 Sandoz Chemicals Corporation (12) 524859 Letter from B. Drum to L. Marcus, EPA August 17, 1988 Enclosures: (1) Existing test data from a study testing for presence of HDDs/HDFs in 2,3,5,6-Tetrachloro-2,5cyclohexadiene-1,4-dione. (2) Test method for determination of 2,3,7,8-Tetrachlorodibenzo-pdioxin in environmental samples. Federal Register; 49(209):136- 141 . October 26, 1984 40-8893309 U.S. Environmental Protection Agency Internal EPA Action Memorandum from M. Halper to C. Elkins on the recommenda tion concerning The Dow Chemical Co. protocol on 2,4-Dichlorophenol. September 12, 1988 Enclosure: (1) Letter from C. Elkins, EPA, to J. Gray, The Dow Chemical Co., on the review and recommendation of their test protocol on 2,4Dichlorophenol. September 14, 1988 (13) 524860 H l . l " 13 Q-> (o(p TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1988 ONLY Hx x--FILE Fiche # 40-8893311 U.S. Environmental Protection Agency (14) 624861 Letter from C. Elkins to R. Jourdenais, Hoechst Celanese Corp. on their Chloranil testing protocol for the presence of Dioxins and Furans. October 14, 1988 [Enclosure Not Provided to Docket] 40-8893312 U.S. Environmental Protection Agency Letter from C. Elkins to R. Tanaka, Chugai International Corp. on their protocol for testing Chloranil for the presence of Dioxins and Furans. October 14, 1988 Enclosures: (1) Polvhalogenated Dibenzo-o-Dioxins/ Dibenzofurans Testing and Report/>^t^ Requirements Final Rule. DoekeiT #83002C. Federal Register; <5^)21412. June 5,1987 (2) Guidelines for the Determination of Halogenated Dibenzo-p-Dioxins and Dibenzofurans in Commercial Products. _ ------------ ----- ---------------------------------- f o r / ? , h ~ e 1V be (15) 524862 ii T, 1 ,- TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY.DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1988 ONLY H x i-FILE Fiche # 40-8893314 U.S. Environmental Protection Agency (16) 524863 Letter from C. Elkins to B. Drum, Sandoz Chemicals Corporation on the protocol for measuring Dioxins and Furans in Chloranil. November 7, 1988 40-8893315 U.S. Environmental Protection Agency Letter from C. Elkins to A.P. G u p t a , ^ P f and D International, Inc. on their protocol for measuring Dioxins and Furans in Chloranil. November 7, 1988 (17) 524864 40-8893318 U.S. Environmental Protection Agency Charter of the Dioxin/Furan Protocol Review Panel. December 14, 1988 (18) 524865 7 1 3 , 0 (otO 3 -0 0 TSCA SECTION 8(d) AND 4(a) / HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY Hi.2 -FILE Fiche # -8993340 A and D International, Inc. (1) 524866 Letter from C.K. Gupta to T. Murray/C. Elkins, EPA February 3, 1989 Enclosures: (1) Letter from C. Elkins, EPA to A.P. Gupta of A and D International on the Chloranil protocol. November 7, 1988 [See H ^ .i(17) for Enclosure (1)] v (2) Sampling Plan for Testing HDD's and HDF's in Chloranil Imported by A and D International. Inc. (3) Letter from Y. Tondeur of Triangle Labs., Inc. to A.P. Gupta of A and D International, Inc. December 5, 1988 (a) Analytical Procedures for the Determination of Polychlori nated Dibenzodioxins and Dibenzofurans bv High-Resolu tion Gas Chromatography/HighResolution Mass Spectrometry (HRGC/HRMS). Triangle Labs., Inc. December 1988 1 .2 - 1 ' O Q > rt[ CUDl TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY H i .2~FILE Fiche # 40-8993368 A and D International, Inc. Telefax from C.K. Gupta to L. Marcus, EPA August 8, 1989 Enclosures: (1) Letter from C. Gupta of A and D International, Inc. to C. Elkins, EPA on their Analytical Protocol. August 1, 1989 (a ) Sample Selection and Sampling Plan. (b) Agreement for sharing test cost with Sandoz. (2) 524867 40-8993369 Akzo Chemicals, Inc. (3) Letter from E. Bisinger, Jr. to Document-control Office, EPA August 16, 1989 Enclosure: ( 1 ) Analytical Protocol for the >^^r1i>ination of Polvbrominated gTbgfiZdw-p-Dioxins and Dibenzo^i/g^g-^ J ) -^ dh^rayatzT}? High-Resolution Gasv " ----- - * Chromatography/High-Resolution Mass Spectrometry in Pentabromodiphenvloxide. Brominated Flame ~~ Retardant Industry Panel; Triangle Laboratories, Inc. July 4, 1989 524868 H1.2 -2 aob'fx 5L07- TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY Hi.2 -FILE Fiche # 40-8993353 Ameribrom, Inc. Letter from M. Eldan to Office of Compliance Monitoring, EPA July 3, 1989 Enclosures: (1) Letter from M. Eldan, Ameribrom to Document Control Office, EPA July 3, 1989 (a) Sampling Protocol for the Determination of Polvbrominated Dibenzo- p-Dioxins and Dibenzofurans in Decabromodiphenvloxide. Bromine Compounds Ltd. (Israel) July 1989 (b) Analytical Protocol for the Determination of Polvbrominated Dibenzo-p-Dioxins and Dibenzofurans by High-Resolu tion Gas Chromatography/HighResolution Mass Spectrometry in Decabromodiphenvloxide. Triangle Labs., Inc. July 4, 1989 (4) 524869 h 1.2-3 3,0? TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY H 1 .2 -FILE Fiche # 40-8993358 Ameribrom, Inc. (5) Letter from A.S. Tillman to J. Johnson, EPA, Office of Compliance Monitoring July 13, 1989 Enclosures: (1) Letter from M. Eldan, Ameribrom, Inc. to Office of Compliance Monitoring, EPA July 3, 1989 (a) Letter from M. Eldan, Ameribrom, Inc. to Document Control Office, EPA July 3, 1989 Sampling Protocol for Determination of (PpTfrblvfominated Dibenzo- r. ^ -- and Dibenzen^Wav^g-^'1 g o f n r - m r e < An P e n t a f t ^ 1/ (^SrombaiphenvioxideT Broomchemie-Terneuzen. July 1989 (2) Letter from M. Eldan of Ameribrom, Inc. to Office of Compliance Monitoring, EPA July 3, 1989 > (a) Letter from M. Eldan of Ameribrom, Inc. to Document Control Office, EPA July 3, 1989 524870 H 1 . 2 -4 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY H x 2 -FILE Fiche # 40-8993358 (continued) 1. Sampling Protocol for. Determination of r -a - . gfTWB^minated Dibenza-f^ r^PfpjtyxTrTs and DibenzoX^**^ ^ y> f~^rctgg~~isn .TetrabromoM^yyAi^P**// Bromine^ Compounds Ltd. (Israel July 1989 (3) Letter from M. Eldan, Ameribrom, Inc. to Office of Compliance Monitoring, EPA July 3, 1989 (a) Letter from M. Eldan, Ameribrom, Inc. to Document Control Office, EPA July 3, 1989 Sampling Protocol for.t k Determination of Pcrivbkgiminated Dibenzo- ro-iDi-e?fink and Dibenzo xfUr^n^iTi Octabromodi pheiiyJroxide.. Broomi 6hemie-erneuzen .July 1989 *r r f 40-8993343 Brominated Flame Retardant Industry Panel Letter from D. McAllister to T. Murray, EPA responding to EPA letter of November 18, 1988 reviewing the Bishop, Texas "Air Sampling Report". February 22, 1989 (6) 524871 1 . 2-5 2of TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY Hi.2-FILE Fiche # 40-8993370 Brominated Flame Retardant Industry Panel Letter from D. McAllister to Document Processing Center, EPA on the progress of the "90-Day Oral Subchronic Study on 2,3,7,8-Tetrabromodibenzodioxin. July 6, 1989 (7) 524872 - - 40-8993322 Chugai Boyeki (America) Corporation (8) Letter from R. Tanaka to C. Elkins, EPA January 13, 1989 Enclosures: (1) Sampling Procedures for Chloranil. Tokuyama Soda Co. Ltd. (2) Analytical Procedures for the Determination of Polvchlorin Dibenzo-p-Dioxins and Dibenz |pita)Q bv High-Resolution Ga r , . GhIt&rtTfttfo&&&>hv/High-Resoluti on `A n i* ? S / g it& b M a ^ Jreefctrqbmetrv (HRGC/HRMS TriranifTe Laboratories, Inc. December 1988 524873 H 1 . 2 -6 2o($> TSCA SECTION 8(d) AND 4(a) f HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY H x 2 "f i l e Fiche # 40-8993350 Chugai Boyeki (America) Corporation Letter from R. Tanaka to C. Elkins, EPA June 22, 1989 Enclosures: (1) Sampling Plan. Tokuyama Soda Co., Ltd. June 1,1989 (2) Analytical Procedures for the Determination of Polychlorinated Dibenzodioxins and Dibenzofurans bv High-Resolution Gas Chromato- j graphv/. iHigh-Resolution Mass Sj Qj u X ?0 " S*foo^Wetrv (HRGC/HRMS). ^ Triaiig~l Laboratories, Inc. May 1989 (9) 524874 h 1.2"7 2o1 ^GbTI TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY Hi.2-FILE Fiche # 40-8993371 Chugai Boyeki (America) Corporation Letter from M. Tanaka to L. Marcus, EPA August 1, 1989 Enclosure: (1) Letter from R. Tanaka of Chugai Bayeki Corp. to C. Elkins, EPA July 24, 1989 (a) Analytical Procedures for the Determination of Polychlori nated Dibenzodioxins and Dibenzofurans bv High-Resolu tion Gas Chromatography/HighResolution Mass Spectrometry (HRGC/HRMS). Triangle Laboratories, Inc. July 1989 (b) Sampling Plan. Tokuyama Soda Co. Ltd.. July 14, 1989 [Enclosure (b) Not Provided to Docket] (10) 524875 40-8993425 Chugai Boyeki (America) Corporation Letter from R. Tanaka to C. Elkins, EPA listing the sample numbers selected for analytical testing. September 22, 1989 (10a) 524876 H 1 .2 - 8 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY H 1 .2 ~FILE Fiche # 40-8993388 Chugai Boyeki (America) Corporation Letter from M. Tanaka to L. Marcus on the delay of the Chlbranil samples. November 9, 1989 Enclosure: (1) Letter from D. Williford of Triangle Labs, to M. Tanaka of Chugai Boyeki Corp. on the reasons for the delay of the Chloranil samples. November 6, 1989 (10b) 524877 40-8993342 (The) Dow Chemical Company Letter from J. Gray to Document Control Office, EPA February 1?, 1989 Enclosure: O/ ( 1 ) Protocol and Quality Assurance P=Lan for the Determination of. /SaXpEfenated Dibenzo-p-Dioxinss and . /-LXftla&flzofurans in 2.4-Dichlor phtirftrlL Dow Chemical USA. February 10, 1989 (11) 524879 1.2-9 ao? TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY H x 2_filE Fiche # 40-8993349 (The) Dow Chemical Company Letter from J. Gray to Document Control Office, EPA June 7, 1989 Enclosure: (1) Final Report of the Determination of Halogenated Dibenzo-p-Dioxins and Dibenzofurans in 2.4-Dichlorophenol. Dow Chemical USA. June 6, 1989 (12) 524880 40-8993389 E.I. Dupont de Nemours and Company, Inc. Letter from K.D. Dastur to H. Podall, EPA on their use of o-Dichlorobenzene. October 17, 1989 (12a) 524881 40-8993347 Ethyl Corporation Letter from P.H. Sistrunk to Document Control Officer, EPA March 22, 1989 Enclosure: (1 ) 28-Dav Range Finding Study < & > 3, 7,^ ^2ljrJi.Vt78^Tetrabromodibenzofuran ( /J \ T B D F t h e Rat. Inhausen Research Zifel^tute, Inc.; Stud^ No. 119-048, (13) 524882 t>- ~ .H 1 2 - 1 0 3.3 m TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY H x 2~fiLE Fiche # 40-8993355 Ethyl Corporation Letter from R.L. Smith to Document Control Office, E.PA July 5, 1989 Enclosures: (1) Sampling Protocol for the Deter mination of Brominated Dibenzo-pDioxins and Dibenzofurans in Decabromodiphenvloxide. July 1989 (2) Analytical Protocol for the Deter mination of Polvbrominated Dibenzop-Dioxins and Dibenzc^fefurans by High-Resolution Gas Chromatography/ High-Resolution Mass Spectrometry in Decabromodiphenvlfapxide. Triangle Labs. , IncX J July 4, 1989 (14) 524883 h1.2 -H PJS>68( 5UJ TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY H]_.2_FILE Fiche # 40-8993356 Ethyl Corporation (15) Letter from R.L. Smith to Document Control Office, EPA July 5, 1989 Enclosures : (1) Sampling Protocol for the Peterifei^gib^ ,,.^ftion of Brominated Dibenzo-p-# ^ T n s and Dibenzofurans in Oct~ iphenvloxide. July 1989 (2) Analytical Protocol for the_ ___ Belffirtmination of Polvbrominated ^jipqn^M-p-Dioxins and Dibenzofev***-^ ftrrafTk High-Resolution Gas ^ (CLThFomaLography/^High-Resolution Mass 4 .{bpec^ometr^V^m"Octabromo^iphenvl * ^Px?^v TTrriiaannggle Laabbss... rnc. July 4 1989 f ' 524906 .H 1 2 - 1 2 a oGdcL di\^ TSCA SECTION 8(d) AND 4(a) ' HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY Hi.2 -FILE Fiche # 40-8993354 Ethyl Corporation Letter from R.L. Smith to Document Control Office, EPA July 5, 1989 Enclosures: (1) Analytical Protocol for the Dtetn^Vmination of Polvbrominated ^ Bth-ginken-p-Dioxins and Dibenzcy fyirarrs^BV High-Resolution Gas*^ ^ h fn r r ia fo q r a p I T y ^ i q h - R e s o lU t l 'g n /ft GMass SpectrometrvTin Tetrahromobisphenol A .^^TTangle L Inc. __________________--- ---- x July 4, 1989 (2) Sampling Protocol for the Deter mination of Brominated Dibenzo-p Dioxins and Dibenzofurans in ^f&ir^abromobisphenol A . June 26, 1989 (16) 524907 40-8993372 -Great Lakes Chemical Corporation Letter from C. Mazac to J. Glatz, EPA with the agenda for the upcoming March 1, 1989 meeting. February 21, 1989 (17) 524884 * 1 .I - 1* 13 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY Hi.2-FILE Fiche # V 40-8993352 Great Lakes Chemical Corporation Letter from C.J. Mazac to L. Marcus, EPA July 5, 1989 y Enclosures: (1) Letter from C.J. Mazac, Great Lakes Chemical Corp. to L. Marcus, EPA July 1, 1989 (a) Sampling Protocol for the Determination of Haloaenated Dibenzo-p-Dioxins and J i l t -- 'J>iJBeiizt)furans in LetralnpomobTsphefog^. A . June 26, 1989 (b) Analytical Protocol for the ^ ^/P^t^mination of PolvbromiJ nated Dibenzo-p-Dioxins and Dibenzofurans bv High-Resolu tion Gas Chromatoaraphv/HighResolution Mass Spectrometry in Tetrabromobisphenol A . Triangle Labs., Inc. July 4, 1989 (2) Letter from C.J. Mazac, Great ( T f '* 'L(1ker5k_/Chemical Corp. to L. Marcus, V. July 1 , 1989 (a) Sampling Protocol for the Determination of Halogenated Dibenzo-p-Dioxins and Diben zofurans in Tetrabromobisphenol-A-Bisethoxvlate (BA50 ). June 26, 1989 (18) 524885 H j .2-14 9.0^ aw TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY Hi.2 -FILE Fiche 40-8993352 (continued) (b) Analytical Protocol for the Determination of Polvbrominated Dibenzo-p-Dioxins and Dibenzofurans bv High-Resolu tion Gas Chromatography/HighResolution Mass Spectrometry in Tetrabromobisphenol-ABisethoxvlate. Triangle Labs., Inc. July 4, 1989 (3) Letter from C.J. Mazac, Great LSSss Chemical Corp. to L. Marcus f \ July 1, 1989 (a) Sampling Protocol for the Determination of Halogenated Dibenzo-p-Dioxins and Diben zofurans in Allvl Ether of Tetrabromobisphenol A (BE51) . June 26, 1989 (b) Analytical Protocol for the Determination of Polvbro' r t t o ~ /nfifriated Dibenzo-p-Dioxins and Dibenzofurans bv High-ReSo- - lution Gas Chromatography/ High-Resolution Mass Spectro metry in TetrabromobisphenolA-Bis(Allvl Ether). Triangle Labs., Inc. July 4, 1989 (4) Letter from C.J. Mazac, Great ' Chemical Corp. to L. Marcus, f / / V July 1, 1989 H l . 2" 1* QjbCs'S*? TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY Hi.2-FILE F iche # 40-8993352 (continued) (a) Sampling Protocol for the Determination of Haloaenated Dibenzo-p-Dioxins and Dibe SDbfurans in 2.4.6-Tribromo XSfrefftfl* (PH-73). June 26, 1989 (b) Analytical Protocol for the Determination of Polvbro- minated Dibenzo-p-Dioxins and Dibenzofurans bv Hiqh-Reso-fti c- Tktion Gas Chromatoqraphv/^/x^^ irqifkResolution Mass 4 * (SD^trornetry?Tn 2.4~7b->rt TrTDromopheno 1 .^~Tr iahq 1e^> Labs., Inc.''------- ----- / July 4, 1989 (5) Letter from C.J. Mazac , Great XJaie Chemical Corp. to L. Marcus, v KPA- July 1, 1989 (a) Sampling Protocol for the Determination of Halogenated Dibenzo-p-Dioxins and Diben zofurans in 1.2-Bis(Tribromophenoxv)Ethane (FF-680). June 26, 1989 (b) Analytical Protocol for the Determination of Polvbrominated Dibenzo-p-Dioxins and Dibenzofurans bv High-Resolu tion Gas Chromatography/HighResolution Mass Spectrometry in 1.2-Bis(Tribromophenoxv) Ethane. Triangle Labs., Inc. July 4, 1989 H 1.2-16 <510 ai(o TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY H i .2-FILE Fiche # 40-8993352 (continued) (6) Letter from C.J. Mazac, Great Lakes .Chemical Corp.. to L. Marcus, EPA July 1, 1989 (a) Sampling Protocol for the Determination of Haloaenated Dibenzo-p-Dioxins and Dibeiy&3 ~ r#dfurans in Pentabromo ^51"BhenVl Oxide (DE-71).' f June 26, 1989 (b) Analytical Protocol for the Determination of Polvbrominated Dibenzo-p-Dioxins and Dibenzofurans bv High-Resolu tion Gas Chromatography/ HighResolution Mass Spectro&metrv in Pentabromodiphenvl Oxide. Triangle Labs., Inc. July 4, 1989 (7) Letter from C.J. Mazac, Great Lakes Chemical Corp. to L. Marcus, EPA July 1, 1989 (a ) Sampling Protocol for the Determination of Halogenated Dibenzo-p-Dioxins and Diberffi^ ~~ fffifurans in O c t a b r o m o d i -- uaii&tr^TVoxide. Vv June 26, 1989 1.2~ 17 3 -\1 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY Hi.2-FILE Fiche # 40-8993352 (continued) (b) Analytical Protocol for the Determination of Polvbrominated Dibenzo-p-Dioxins and Dibenzofurans bv High-Resolu tion Gas Chromatography/ HighResolution Mass Spectrofametrv in 0ctabromodiphenvl4io>ljde^ Triangle Labs. , Inc.\J July 4, 1989 (8) Letter from C.J. Mazac, Great Lakes Chemical Corp. to L. Marcus, EPA July 1, 1989 (a) Sampling Protocol for the Determination of Halogenated Dibenzo-p-Dioxins and CbQfurans in Decabromo /dlpbd&v2:oxide (DE-8 3) June 26, 1989 (b) Analytical Protocol for the Determination of Polvbrominated Dibenzo-p-Dioxins and Dibenzofurans bv High-Resolu tion Gas Chromatography/ HighResolution Mass SpectroAyietrv in Decabromodiphenvl^x^rde. Triangle Labs. , I n c ^ July 4, 1989 .h 1 2 ~ 1 8 2 ,0 6 ^ TSCA SECTION 8(d) AND 4(a) / HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY H 1 .2 -FILE .Fiche # 40-8993320 Hoechst-Celanese Corporation Letter from R. Jourdenais to Document Control Officer, EPA January 5, 1989 Enclosures: (1) TCDD's in Chloranil (Tetrachlorop-Benzochinone) Sample Collection Handling and Preservation. (Revised Protocol) Hoechst Aktiengesellschaft. December 19, 1988 (2) Analytical Procedures for the M'i5d^irmination of Polychlorinated u viTi-ii^nifzodioxins and Dibenzofuransx*y j / 0 i j f y High-Resolution Gas Chromato tfiherBEfvffHigh-Resolution Mass~^t 7 f r ? vhrms: (Revised Protocol) Tangle, Laboratories, Inc.' December 1988 (19) 524886 h 1.2-19 CLObtf^ TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY Hj..2"FILE Fiche # V 40-8993348 Hoechst Celanese Corporation (20) 524887 Letter from R .A. Jourdenais to Document Control Officer, EPA May 25, 1989 Enclosures: (1) TCDD's in Chloranil Sample Collec tion. Handling and Preservation. Hoechst AG. May 12, 1989 (2) Analytical Procedures for the Determination of Polychlorinated Dibenzodioxins and Dibenzofurans High-Resolution Gas Chromotqq xu^Pfn^High-Resolution Mass / Spectrometry^ (HRGC/HRMS). c'-Tiri'ShgT^ Laboratories , Inc/ ' May 1989 (3) Brominated Flame Retardant,. ^^nddsynft Panel (BFRIP) HoechstOe^rafoese^ftLi) Samples from Bishop. 4 Texas Test.^ fRevised) Triangle Labs., Inc.'-- ----------June 24, 1988 40-8993357 Hoechst-Celanese Corporation Letter from R .A . Jourdenais to Document Control Officer, EPA July 11, 1989 Enclosure: (1) Revised pages 3 , 5 , 6 and 10 of Uy tbe-'analytical portion of the pfbb^ccuL dated May 25, 1989. ' (21) 524888 .H 1 2 - 2 0 2. 9-0 aoG/?o TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY H x 2~f i l e Fiche # 40-8993323 Midwest Research Institute Letter from D. Steele to D. Firestone, FDA January 19, 1989 Enclosure: (1) Summary report checklist for i Revision #1 of the Hoechst-V^/WtiX. Corp. analytical protocol Chloranil. (22) 524889 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY Hj..2_FILE Fiche # 40-8993324 Midwest Research Institute Letter from D. Steele to W. Sovocool, EPA (Las Vegas, Nevada) and duplicate letters sent to R. Harless, EPA (EMSL, NC), D. Firestone, FDA, A. Dupuy, EPA (ECL, Miss.) and W. Bontoyan, EPA (Beltsville, Md.) January 25, 1989 Enclosures: (1) Summary Report Checklist for the Testing Protocol for HDD's and HDF *s in Commercial Products Containing Chloranil Produced by Hoechst-Celanese Coro. January 23, 1989 (2) Charter of the Dioxin/Furan Protocol Review Panel. (Revised) January 19, 1989 (3) Status of TSCA Section 4 D/F Protocols. (23) 524890 40-8993325 Midwest Research Institute Letter from D. Steele to D. Firestone, FDA and duplicates sent to R. Harless, EPA (EMSL, N.C.), W. Bontoyan, EPA (Beltsville, MD. ) W. Sovocool, EPA (Las Vegas, Nevada) and A. Dupuy, EPA (ECL, Miss. ) February 3, 1989 Enclosures: (1) Minutes of January EPA TSCA **SecMrThh 4 Dioxin/Furan Protocol ^RevTdvf Panel Teleconference. (24) 524891 H I .2- 2 2 30--X ^ 0 6 "? 3- TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY H]_.2_FILE Fiche # 40-8993325 (continued) / (2) Status of TSCA Secti Protocols. February l, 1989 U) (3) Summary Report Checklist of the Testing Protocol for HDD's and HDF's in Commercial Products Containing Chloranil Produced bv Chugai. International Coro. February 3, 1989 [See Dld(9) for Enclosure (l)] 40-8993366 Midwest Research Institute Letter from D. Steele to D. Firestone, FDA and duplicates sent to R. Harless, EPA (EMSL, NC.), W. Bontoyan, EPA (Beltsville, Md.), A. Dupuy, EPA (ECL, Miss.) and W. Sovocool, EPA (Las Vegas, N. V. ) February 24, 1989 Enclosures: (1) Status of TSCA Section 4 D/F Protocols. February 24, 1989 (2) Testing Protocol for HDD *s and HDF's in Commercial Products Containing Chloranil from A and D International. Protocol No. 005 ; Revision 1. (3) Testing Protocol for HDD's and HDF's in Commercial Products Containing Chloranil from Sandoz Chemicals Coro. Protocol No. 004; Revision 1. (25) 524892 H i . 2-23 2^3 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY H 1 .2 -FILE Fiche # 40-8993366 (continued) (4) Protocol and Quality Assurance for the Determination of Fpyffifonated Dibenzo-p-Dioxins and \y jL W W k O /S'ilS^Tfeqfurans in 2.4-Dichloroil[Ut^ > ^ L q X l T paefted. Dow Chemical USA. (T February 10, 1989 [See H ^ ^ ( H ) for Enclosure (4)] (5) BFRIP questions for discussion at the March 1 panel meeting. [Enclosure (5) Not Provided to Docket] 40-8993367 Midwest Research Institute Letter from D. Steele to D. Firestone of FDA and duplicates sent to R. Harless, W. Bontoyan, W. Sovocool and A. Dupuy of EPA March 3, 1989 Enclosure: (1) Data Package on Hoechst-Celanese Air Samples from Bishop. Texas Test. Brominated Flame Retardant Industry Panel. (26) 524893 H 1 .2 -24 a?-*/ ao<?y TSCA SECTION 8 (d) AND 4(a) ' HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY H 1.2"FILE Fiche # 40-8993345 Midwest Research Institute (27) 524894 Letters from D. Steele to A. Dupuy, EPA (NSTL, Miss), D. Firestone, FDA, R. Harless, EPA (RTP, N.C.), W. Bontoyan, EPA (Beltsville, Md) and W. Sovocool, EPA (Las Vegas, N.V.) March 20, 1989 Enclosures: (1) TSCA Section 4 Dioxin/Furan Proto col Review Panel Draft Recommenda- . tions for Revision 1 of the /dpctis%>Celanese Protocol (002) P , 3, ^ o y ^ l d 3 V ^ T e t r a c h l o r o - 2 .S-Cyclo/^ , ^ ^ ^ hexduenti^<"4Kdione (Chloranil). > March 20, 1989 _ & / if- / (2 ) TSCA Section 4 Dioxin/Furan Proto-7 col Review Panel Draft Recommenda ,^Eo)rs for Revision l of the ftryJJtfyuj p phicriry lYTte^fimational Coro. Protocol (003) for 2.3.5.6 -Tetra- chloro-2,5-Cvclohexadiene-l.4dione (Chloranil). March 20, 1989 (3) TSCA Section 4 Dioxin/Furan Proto col Review Panel Draft Recommenda for Revision 1 of the Sandoz GT>fo4-cals Coro. Protocol (004) for 2.3.5.6-Tetrachloro-2.5-Cvclohexadiene-1.4-dione (Chloranil) March 20, 1989 1 . 2 - 2 5 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY Hi.2 -FILE Fiche # 40-8993345 (continued) (4) TSCA Section 4 Dioxin/Furan Proto--- col Review Panel Draft RecommendaS^ ^ `Otjfrra for Revision l of the A and---D International. Inc. Protocol------ (005) for 2.3.5.6-Tetrachloro2 .5-Cvclohexadiene-1.4-dione. (Chloranil). March 20, 1989 (5) Example Sampling Plan. 40-8993346 Midwest Research Institute Letters from D. Steel to R. Harless, W. Bontoyan, W. Sovocool, A. Dupuy of EPA and D. Firestone of FDA March 9, 1989 Enclosures: (1) Status of TSCA Section 4 D/F Protocols. ( 2 ) Letter from D. Steel, Midwest Research Institute to D S ! MeA11iste?"c53L responding to 4 Vthe presentation to ^the"~pane 1 March 9, 1989 (3) Minutes of the March TSCA Section Dioxin/Furan Protocol Review f t Meeting. (28) 524895 h 1 .2 ~ 2& TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANi. DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY Hi.2 -FILE F iche # 40-8993373 Midwest Research Institute Letter from D. SteelQ to D. McDaniel* EPA, J. Donnelly of Lockheed Engineering and Sciences Co.. _ (fiarless, EPA (RTP.Cn c ). D. Firestone j CQJSFDA) , ~w7~~^orrt^an2,5^PA (Beltsville /m 3 D , A" Dupuy,~EPA NSTL , M S ) and W. $ <3>dvacboT, e p a (NEKL,YLas Vegas, Nevada) August 1, 1989 7 Enclosure: (1) Review of protocols for Decabromodiphenyloxide from Ameribrom, Inc. (006), Ethyl Corp. (007) and Great Lakes Chemical Corp. (013); for Octabromodi-phenyloxide from Ethyl Corp. (008), Ameribrom, Inc. (Oil) and Great Lakes Chemical Corp. (014); for Pentabromodiphenyloxide from Ameribrom, Inc. (012), Great Lakes Chemical Corp. (015); for 1 ,2-Bis(Tribromophenoxy)Ethane from Great Lakes Chemical Corp. (017); and for Allyl Ether of Tetrabromobisphenol-A from Great Lakes Chemical Corp. (019). July 1989 (29) 524896 Hi. 2-27 2-K SkQbHI TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY Hi ^ - F I L E Fiche # 40-8993374 ._ Midwest Research Institute Letter from D. Steele to W. Bontoyan, EPA, (Beltsville, Md,), to J. Donnelly of Lockheed Engineering and Sciences Co., to R. Harless, EPA (RTP, NC), to D. Firestone (USFDA), to W. Bontoyan, EPA (Beltsville, Md. ), to A. Dupuy and D. McDaniel, EPA (NSTL, MS) and W. Sovocool, EPA (NERL, Las Vegas, Nevada) August 15, 1989 Enclosures: (1) Analytical and Sampling Protocols. Chugai Boyeki (America) Inc. July 1989 [See H1>2(10) for Enclosure (1)] (2) Analytical and Sampling Protocols. A and D International, Inc. December 1988 [See Hjl,2 (1 ) for Enclosure (2)] (3) Summary Report Checklist for HDDs and HDFs in Commercial Products Containing Tetrabromobisphenol A from Ethvl Coro. (009). (4) Summary Report Checklist for HDDs and HDFs in Commercial Products Containing Tetrabromobisohenol A from Ameribrom. Inc. (010). (5) Summary Report Checklist for HDDs and HDFs in Commercial Products Containing Tetrabromobisphenol A from Great Lakes Chemical Corp. (016) . (30) 524897 h 1.2-28 ao c o ^ TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY H i .2 ~FILE Fiche # 40-8993374 (continued) (6) Summary Report Checklist for HDDs .and HDFs in Commercial Products Containing Tetrabromobisphenol ABisethoxvlate from Great Lakes Chemical Coro. (020). (7) Summary Report Checklist for HDDs and HDFs in Commercial Products Containing 2.4.6-Tribromophenol from Great Lakes Chemical Coro. (018) . (8) Status of TSCA Section 4 D/F Protocols. August 14, 1989 .H 1 2 - 2 9 xx< ] TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY Hj_.2-FILE Fiche # 40-8993390 Midwest Research Institute Cover letter from D. Steele to W. Sovocool, EPA (Las Vegas, Nevada), R. Harless, EPA (Research Triangle Park, N C ) , D. Firestone, USFDA and A. Dupuy, EPA (NSTL, Miss.) November 8, 1989 Enclosures: (1 ) Bromodioxins and Bromofurans in Stock. Cambridge Isotope Laboratories. July 21, 1989 ( 2 ) Production Schedule for lib -6 ^ r< 4 > -- BngTwfodioxins and Bromofurans. C^mlrHrdge Isotope Laboratories. July 21, 1989 y (3) Minutes of EPA TSCA Section 4 Dioxin/Furan Protocol Review Panel Meeting. August 23-24, 1989 (4) Minutes of EPA TSCA Section 4 Dioxin/Furan Protocol Review Panel Teleconference. September 8, 1989 (5) Minutes of EPA TSCA Section 4 Dioxin/Furan Protocol Review Panel Teleconference. September 29, 1989 (6) Minutes of EPA TSCA Section 4 Dioxin/Furan Protocol Review Panel Teleconference. October 25, 1989 (30a) 524898 . ._ .H 1 2 - 3 0 9,0^00 230 TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET # DOCUMENTS RECEIVED FOLLOWING DECISION OF f^FILE 3 7fO<P Fiche 4 3.31 0,0701 TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET * DOCUMENTS RECEIVED FOLLOWING DECISION OF 'REFILE 3 Fiche i t (? ' a3a <2 - 0 * 7 0 2 - TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES ,, DOCKET * AND MIXTURES DOCUMENTS RECEIVED -FOLLOWING DECISION OF , -SyFILE 73 Fiche f a ofo3 32 3 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1990 ONLY Hi.3 -FILE 40-9093406 Chugai Boyeki (America) Corporation V (21) Fiche # 524938 Letter from R. Tanaka to L. Marcus, EPA January 9, 1990 Enclosure: (1) Letter from R. Varcoe of Triangle Labs, to S. Ushiyama of Chugai Boyeki Corp. on the reason for the blank "Certificate of Analysis" sample enclosed in their December 26, 1989 letter. November 17, 1989 40-9093474 Chugai Boyeki (America) C o r p ^ - 7 (22) Letter from D. Severn of Jellinek, Schwartz, Connolly and Freshman, Inc. to J. Canterbury, EPA on protocol modifications. August 6, 1990 Enclosures: ( 1 ) Certificate of Analysis for f^amples of PCDD/PCDF. March 11, 1990 .H 1 3 - 1 5 23V- TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1990 ONLY H i ,3 -FILE Fiche # 40-9093410 Ethyl Corporation (23) 524939 Letter from L. Wen to L. Marcus, EPA January 16, 1990 Enclosures: (1) Analytical Protocol for the Deter mination of Polybrominated Dibenzo p-Dioxins and Dibenzoitfurans bv High-Resolution Gas OMromatogr ^phyfMedium High-Resolution Mas (fflgfoctrometrv in Tetrabromobis /Phenol^A^ Triangle Laboratories V.ry'1 1 1 0 . January 12, 1990 (2) Analytical Protocol for the Deter mination of Polybrominated Dibenzop-Dioxins and Dibenzofurans bv * , High-Resolution Gas Chromatograjg-^fr/-. ^Medium High-Resolution Mas; trometrv in Qctabromodiphenv^ Triangle Laboratories, In January 12, 1990 (3) Analytical Protocol for the Deter mination of Polybrominated Dibenzop-Dioxins and Dibenzo-furans bv High-Resolution Gas Chromatogra rgiTvffiMedium-High-Resolution Mas ;trometrv in Decabromodiphenv :rde~> Triangle Laboratories, Inc. January 12, 1990 H1.3-16 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1990 ONLY H 1.3~FILE Fiche # 40-9093411 Ethyl Corporation (24) 524940 Letter from L. Wen to L. Marcus, EPA January 16, 1990 Enclosures: (1) Letter from L. Wen, Ethyl Corp. to L. Marcus, EPA January 11, 1990 (a) Sampling Protocol for the Determination of Brominated Dibenzo-p-Dioxins and Dibenzofurans in Decabromodiphenvl-oxide. Triangle Laboratories, Inc. January 4, 1990 (b ) Sampling Protocol for the Determination of Brominated Dibenzo-p-Dioxins and Dibenzofurans in Tetrabromobisphenol-A. Triangle Labora tories, Inc. January 4, 1990 (c ) Sampling Protocol for the Determination of Brominated - . Dibenzo-p-Dioxins and Dibenzofurans in Octabromodiphenvloxide. Triangle Laboratories, Inc. January 4, 1990 Hl.S"1? ZLOlOb TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-E-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1990 ONLY H 1 .3 -FILE 40-9093412 Ethyl Corporation (25) Fiche # j 524941 Ltter from L. Wen to L. Marcus, EPA enclosing a copy of complete protocol (incomplete copy sent January 16, 1990) . January 18, 1990 Enclosure: (1) Analytical Protocol for the Determi nation of Polvbrominated Dibenzo-pDioxins and Dibenzo-furans bv HighResolution Gas Chromatography/ ___ Medium High-Resolution Mass gfrdfttrometrv in Octabromodiphenvl/4iJ2/ ' <fxfode>. Triangle Laboratories, Inc! January 12, 1990 40-9093407 Great Lakes Chemical Corporation Cover letter from C. Mazac to L. EPA January 16, 1990 Enclosures: (1) Letter from C. Mazac to L. Marcus, EPA January 16, 1990 (a) Analytical Protocol for the Determination of Polvbro minated Dibenzo-p-Dioxins and Dibenzofurans bv High-Resolu tion Gas Chromatography/ Medium Hiah-Resolution Massey Spectrometry in 1.2-Bi |C rffilbromophenoxv)Ethan 6 , m Triangle Laboratories, Inc. cp January 12, 1990 (26) 524942 H .3-18 ao7<57 237 <{o ' f t fJS S J TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET # DOCUMENTS RECEIVED FOLLOWING DECISION OF l-f i l e Y V ( )) ' u/ ^^ ^//// x 2 / 2; t Yo M j , o ^ f A s t a P*~<Y' V 'W ' X o ' l o '3 3L3H Mo - V f X J TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES ' DOCKET # AND MIXTURES DOCUMENTS RECEIVED FOLLOWING ^-FILE DECISION OF VJ Fiche t r 5*"/ A L r*/ a. o7oj %3<1 TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET # DOCUMENTS RECEIVED FOLLOWING DECISION OF Fiche f Zollo Mo TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET # DOCUMENTS RECEIVED FOLLOWING DECISION OF --^-FILE - ?/ f i > > / / Fiche # " r y (h ty tx -'s ^ ^ h /ff/s&$Y * ' ' /& / 3 ,0 m,! Ml t fc tt up ^ TSCA SECTION 4 CHEMICAL SUBSTANCES AND MIXTURES f DOCKET i DOCUMENTS RECEIVED FOLLOWING DECISION OF / " %-FILE //y fa - 9 / p J^ fi Fiche * 0t7l2- fafaiX- TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES f DOCKET * DOCUMENTS RECEIVED FOLLOWING DECISION OF Fiche 4 /J- / f e ^ l V V- wr -- - '9ft f'<f/ 3.0713 M3 TSCA SECTION 4 testing of CHEMICAL SUBSTANCES AND MIXTURES DOCKET # d o c u m e n t s RECEIVED FOLLOWING DECISION OF ^ t FILE Fiche jn f j p p j 3Lr^>7it4 ifd - f(i 935 TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET t / DOCUMENTS RECEIVED FOLLOWING DECISION OF ^frTFlLE V X " ,-1 J7 ^ U--} & Z . fp' ??/ rff/ 3j7 7 (5 fcttiv ~ TSCA SECTION 4 ESTING OF CHEMICAL SUBSTANCES AND MIXTURFC >L 7< u ^ >% /?<?/ l/o -9 /fJ s c i - TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET # DOCUMENTS RECEIVED FOLLOWING DECISION OF ,-FILE U A/ M / (^ > // liche^ * ^7//^ V}/??/ s A 'S' r/yf^jT M .13. ao7/7 3of1 TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET # DOCUMENTS RECEIVED FOLLOWING DECISION OF Ra-m-E CL0 7 1 8 __ TSCA SECTION 4 testing of chemical substances and mixtures DOCKET < DOCUMENTS RECEIVED FOLLOWING DECISION OF ^-FILE Ml A071 9 orTESTING CHEMICAL " " s t a n c e s a n o MIXTURES documents * e c e i v J o Cf o L n i n g ^.-niE deci OECI SION OF XVO-?/?JSS-3 <L X Fiche * 4- y Vy (d szx X9o ^ 0 7ZI_C> TESTING 0F AND TM s d o c u m e n t s k s c e IV| ^ K3n g d e c i s i o n o f P Y /f 3 ^ 3 ^ (GG***-<-* ( ' /$J / f f / rl J ^ y a sj / f f / 71X-, TSCA SECTION 8(d) AND 4(a) ' HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY H 1 .2 -FILE Fiche # 40-8993391 Midwest Research Institute Letter from D. Steele to W. Bontoyan, EPA (Beltsville, Md.), D. Firestone, USFDA, R. Harless, EPA (RTP, NC), W. Sovocol, EPA (Las Vegas, Nevada), A. Dupuy, EPA (NSTL, Miss.) and J. Donnelly, Lockheed Engineering and Sciences Co. December 12, 1989 Enclosure: (1) ' Letter from C. Elkins, EPA to A. Gusmano, Pfister Chemical, Inc. containing the review of their.--- , protocol for the analytical"2^/^^ of 3,4',5-Tribromo-^ ^ salicylanilide.;-- ' r November 27, 1989 (30b) 524899 40-8993392 Midwest Research Institute Letter from D. Steele to W. sovocool, EPA (Las Vegas, Nevada), R. Harless, EPA (RTP, NC), D. Firestone, USFDA, A. Dupuy, EPA (NSTL, Miss.), W. Bontoyan, EPA (Beltsville, Md.) and J. Donnelly of Lockheed Engineering and Sciences (b * ^ December 18, 1989 Enclosure: (1) Initial Review of Hoechst-Celanese (002) Data for Chloronil. December 18, 1989 (30c) 524900 .H 1 2 - 3 1 75^ TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY Hi.2-FILE Fiche # 40-8993375 Pfister Chemical, Inc. Letter from A. Gusmano to L. Marcus, EPA on the manufacture of 3,4',5Tribromosalicylanilide. August 8, 1989 (31) 524901 .- 40-8993376 Pfister Chemical, Inc. Letter from A. Gusmano to Document Control Office, EPA September 15, 1989 Enclosure : (1) Analytical Protocol for the_ /^Determination of Polvbrominated ^DT^err^gyp-pioxins and Dibenzo^t High-Resolution (^hTomatographvTkj^qh^Resolution^j? /- M~a^5~~Si?ectrometrv^yin~~3~. 4 7b-- TrlDrornosadL-cviralli 1ide .*-- T rlang 1e Laboratories, Inc. August 28, 1989 (32) 524902 40-8993327 Sandoz Chemicals Corporation Letter from B. Drum to L. Marcus, EPA February 8, 1989 Enclosure: (1) Protocol for the Determination of Polvhalogenated Dibenzo-p-dioxins and Dibenzofurans in 2.3,5.6Tetrachloro-2.5-cvclohexadiene1.4-dione. February 7, 1989 (33) 524903 1.2-32 25S TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY H l .2 -F ILE Fiche # 40-8993351 Sandoz Chemicals Corporation Letter from B.W. Druqa to L. Marcus, EPA June 30, 1989 Enclosures: (l) Agreement for Sharing Testing Cost (A&D International. Inc.) ( 2 ) Sample Selection and Sampling Plan for the Determination of Polvhalogenated Dibenzo-p-Dioxins and Dibenzofurans in 2.3 .5.6-Tetrachloro-2.5-Cvclohexadiene-l.4dione. Triangle Labs., Inc. June 30, 1989 (34) 524904 40-8993451 Sandoz Chemicals Corporation Letter from B. Drum to L. Marcus, EPA revising their notice of intent to test (letter of August 17, 1988). June 30, 1989 Enclosure: (1) Analytical Testing Protocol for t h r f l trhe- Determination of Polvhalo Dibenzo-p-Dioxins and' -- J^irberrzuVura'hs in 2 .3 .5 ,6-Tetra^.. . cdV6?ye). '4lLr-tafigTQ'Labs., Inc. May 1989 (34a) 524905V H i . 2-33 V'Jt TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY H l .2 -FILE Fiche # 40-8993377 Sandoz Chemicals Corporation Letter from B. Drum to L. Marcus, EPA July 27, 1989 Enclosure: (1) Agreement for Sharing Testing Cost (Between Sandoz Chemicals Coro, and A and D International. Inc.). (35) 524908 40-8993378 Sandoz Chemicals Corporation Letter from B. Drum to L. Marcus, EPA July 27, 1989 Enclosure: (1) Four corrected pages and one missing page to the protocol submitted on 2,3,5,6-Tetrachloro2,5-Cyclohexadiene-l,4-dione submitted June 30, 1989. [See Hlt)(34a) for Protocol] (36) 524909 40-8993393 Standard Chlorine of.Delaware, Inc. (36a) 524910 Letter from R. Touhey to H. Podall, EPA in response to his letter of-^Octobe 1989 regarding contents of Pai JOiiJlilrrFi>benzene used to produce ijp, <--i r ,2,4 Tri-clLLonpbenzene. November 7, 1989 -TrMfry - H i.2-34 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY H 1 .2 -FILE 40-8993344 U.S. Department of Health and Human Services, National Institute for Occupational Safety and Health (37) Fiche # j 524911 Letter from R.W. Hartle from the GontoP for Disease Control (CDC) to L. EPA containing a status report on NIOSH's involvement with the Brominated Flame Retardant Industry Panel 's of PBDD 's and PBDF 's . ' February 22, 1989 Enclosures : (1) Report of Air Sampling for the Presence of Polvbrominated Diben/^D -- fgftdioxins and Dibenzofurans During the Production of Polvbutvlene Terephthalate Resin with Decabro^t> irfodiphenvl Oxide. H o e s c h s t - -/ j Ceianes Corp. , Brominated Flame RetrarFdant Industry Panel. J. (2) USDHHS memorandum from A. f-n K j iims-fcrnd^ to R. Hartle containing a--rev-Lew--frf~~the "analytical ft. (^section" of the^BFRlP report. - 7 \ ^ (a) Summary of PBDD/PBDF AiThL9.t*?cal Results from ,, JrtTi-krVdltj ftEiK^ratories . Inc. MTable) 40-8993321 U.S. Environmental Protection Agency EPA memo from T. Murray to "The Record" on the Sampling Protocol from A&D International, Inc. January 11, 1989 (38) 524912 H i.2-35 V'ck.Q 3^-Cd TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY H 1.2"FILE Fiche # 40-8993326 U.S. Environmental Protection Agency EPA memo from T. Murray to "The Record" on the review of The.Dow Chemical Co. Sampling and Analytic Protocol. February 6, 1989 Enclosure: (1) Draft Panel Recommendations for Revision 1 of the Dow Protocol Submitted for 2.4-Dichlorophenol Under the EPA TSCA Section 4 Dioxin/Furan Rule. Midwest Research Institute. (39) 524913 . .. 40-8993379 U.S. Environmental Protection Agency Letter from C. Elkins to R. Jourdenais of Hoechst-Celanese Corp. reviewing their revised test protocol sent January 5, 1989 on Chloranil. April 17, 1989 (40) 524914 40-8993.380 U.S. Environmental Protection Agency Letter from C. Elkins to B. Drum of Sandoz Chemicals Corp. reviewing their revised test protocol for Chloranil sent February 8, 1989. April 17, 1989 (41) 524915 40-8993381 U.S. Environmental Protection Agency Letter from C. Elkins to C.K. Gupta of A and D International, Inc. reviewing their revised test protocol for dhTt^knil sent February 3, 1989. April 17, 1989 (42) 524916 H j .2-36 3S1 3 ,0 7 3 . 7 TSCA SECTION 8(d) AND 4(a) < HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1989 ONLY Hj..2_FILE Fiche # 40-8993382 U.S. Environmental Protection Agency Letter from C. Elkins to R. Tanaka of Chugai Boyeki (America) Corp. reviewing their revised test protocol for Chloranil sent January 13, 1989. April 17, 1989 (43) 524917 . 40-8993383 U.S. Environmental Protection Agency Letter from C. Elkins to B. Drum of Sandoz Chemicals Corp. accepting their revised test protocol for Chloranil v sent July 27, 1989. August 21, 1989 (44) 524918 40-8993384 U.S. Environmental Protection Agency Letter from C. Elkins to R. Tanaka of Chugai Boyeki (America) Corp. accepting their revised test protocol for ~ CirXcn^nil sent June 22, 1989. August 21, 1989 (45) 524919 40-8993385 U.S. Environmental Protection Agency Letter from C. Elkins to R. Jourdenais of H'oechst-Celanese Corp. accept; their revised test protocol for CMreisanil sent May 25, 1989. August 21, 1989 (46) 524920 40-8993386 U.S. Environmental Protection Agency Letter from C. Elkins to C.K. Gupta of A and D International, Inc. accepting their revised test protocol for "" 'CTrtrrranil sent August 1, 1989. August 21,1989 (47) 524921 H j . 2-37 073- 3t TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET # 8 3 0 0 2 0 - FOR 1989 ONLY h 1 .2 "FILE Fiche # 40-8993387 U,S. Environmental Protection Agency Internal EPA memo from J. Merenda to C. Auer on the analytical data for 2,4Dichlorophenol submitted by The Dow Chemical Co. . September 1, 1989 Enclosure: (1) Letter from A. Dupuy, Jr., EPA (Environmental Chemistry Section, Stennis Space Center, Miss.) to E. Bryan, EPA (Hdqtrs.) on the review of data for 2,4-Dichlorophenol submitted by The Dow Chemical Co. August 23, 1989 (48) 524922 .H 1 2 - 3 8 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1990 ONLY Hi.3 -FILE Fiche # 40-9093465 A and D International, Inc. in Letter from C. Gupta to J. Canterbury and J. Breen. C P # .July 6 , 1990. \ Enclosures: (1) EPA Form 7710-51 on Chloranil (Positive Dioxin Report from Product Analysis). April 11, 1990 du (2) Log Out for Chlorynil from PhenolFlow Diagram. (3) Comments on Flow Diagram. (4) Material Safety Data Sheet for Chlor^ni1. (5) Product Label for Chloranil. 40-9093402 Ameribrom, Inc. Letter from M. Eldan to Document Control Office, EPA January 12, 1990 Enclosure: (1) Sampling Protocol for the Deter mination of Polvbrominated_ /Pil5fenrgc5tp-D ioxins/D ibenzofurans in /p ern jfrabrom odiphen vlo xid e. BJiQQmcbemi-e B.V. January 1990 (2) 524924 H 1.3-l Pv0 7 3 0 7 L t> 0 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1990 ONLY H 1.3"FILE Fiche # 40-9093403 Ameribrom, Inc. (3) 524925 Letter from M. Eldan to Document eecEEeiT Office, EPA January 12, 1990 Enclosure: (1) Sampling Protocol for the Determinaton of Polvbrominated Dibenzop-Dioxins and Dibenzofurans in Tetrabromobisphenol-A. Bromine Compounds, Ltd. January 1990 40-9093404 Ameribrom, Inc. Letter from M. Eldan to Document Control Office, EPA January 12, 1990 Enclosure: (1) Sampling Protocol for the Deter mination of Polvbrominated_yi^tg-K P ~~ DibettgcPfrp-Dioxins and Dibenzo/, ^ ^ it^ang^n/ Octabromodiphenvloxide. Broomchemie B.V. January 1990 (4) 524926 h1 .3 -2 ao 7 3 i 2 .W TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1990 ONLY Hi.3 -FILE Fiche # 40-9093405 Ameribrom, Inc. (5) '524927 Letter from M. Eldan to Document control* Office, EPA January 12, 1990 Enclosure: (1) Sampling Protocol for the Deter mination of Polvbrominated Dibenzop-Dioxins and Dibenzofurans in Decabromodiphenvloxide. Bromine Compounds, Ltd. January 1990 40-9093408 Ameribrom, Inc. ,Letter from A. Tillman to L. Marcus z W ( 6) January 16, 1990 Enclosures: ( 1 ) Analytical Protocol for the Deter mination of Polvbrominated Dibenzop-Dioxins and Dibenzofurans bv High-Resolution Gas dhromatography/ Medium High-Resolution Mass Spec trometry in Pentabromodiphenvloxide. Triangle Laboratories, Inc. January 12', 1990 ( 2 ) Analytical Protocol for the determination of Polvbrominated Di-t>pri^p^p-Dioxins and Dibenzo/^.^ jfnr^rrsHigh-Resolution GasMt ^ -- 524928 Laboratories, Inc. January 12, 1990 h 1.3-3 2<o?PJD73^- TSCA SECTION 8 (d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO--DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1990 ONLY H-l 3 -FILE Fiche # 40-9093408 (continued) (3) Analytical Protocol for the Deter mination of Polvbrominated Dibenzop-Dioxins and DibenzoJtfurans bv High-Resolution Gas cMromatograi [Medium High-Resolution Mass/ Etrometrv in Decabromodiphenv igCt Triangle Laboratories, InJanuary 12, 1990 (4) Analytical Protocol for the tBtte1rmination of Polvbrominated ~~ " ygjj'gjavp-Dioxins and Dibenzo^M-^gt-ii.. High-^Resolution G a s ^ rromatogratThVTTyiedium High?Rusolutl~on MJs SPd'cfcrometrv in TetraDromobrgphenelr^A.'^riangl Laboratories, Inc January 12, 1990 2U3 TSCA SECTION 8(d) AND 4(a) f HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1990 ONLY H l.3 -FILE Fiche # 40-9093414 Chemical Manufacturers Association (7) 524929 Letter from H. Shah to L. Marcus, EPA containing status report on progress of analytical methods development. February 1, 1990 Enclosures: (1) v Progress Report GLC No. 1 from Y. Tondeur, Triangle Laboratories, Inc. to C. Mazac of Great Lakes Chemical Corp. reporting on activities for PH-73 (Tribromophenol). January 26, 1990 (2) Progress Report GLC No. 2 from Y. Tondeur, Triangle Laboratories, Inc. to C. Mazac of Great Lakes Chemical Corp. reporting on BFRIP protocols. January 26, 1990 40-9093417 Chemical Manufacturers Association Letter from H. Shah to L. Marcus, EPA February 23, 1990 Enclosures: (1) Progress Report No. 4 on BFRIP protocols from R. Varcoe, Triangle Labs, Inc. to C. Mazac of Great Lakes Chemical Corp. February 23, 1990 (a ) Addendum to Progress Report No. 4 . (2) Progress Report GLC No. 3 on PH73 from R. Varcoe of Triangle Labs, Inc. to C. Mazac of Great Lakes Chemical Corp. February 23, 1990 h 1.3- 5 (8) 524930 aoT TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1990 ONLY 1 .3 -FILE 40-9093430 Chemical Manufacturers Association V (9) Fiche # 524931 Letter from H. Shah to L. Marcus, EPA April 6, 1990 Enclosures : (1) Report o h the Results on Compara tive Sbtidv EPA-TLI TBBPA Procedures./Triangle Labs., Inc. April 4, 1990 (2) Progress Report on Darco/AX-21 (350-100 AX-21 Procedure). April 4, 1990 40-9093431 Chemical Manufacturers Association Letter from H. Shah to L. Marcus, EPA April 20, 1990 Enclosures: 1) Progress Report No. 6 from Y. Tondeur of Triangle Labs, to Q Mazac of Great Lakes Chemical Corp, on the preparation of samples- fo* "single lab^7 evaluation" .'--- -----April 18, 1990 (a) Letter from H. Cavalier of Cambridge Isotope Labs, to Y. Tondeur of Triangle Labs# j confirming problems with-- impurities in ED-1460. March 20, 1990 (10) 524932 H 1 .3~ 6 djo6 9-073^ TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1990 ONLY Hl.3-FILE Fiche # 40-9093432 Chemical Manufacturers Association (11) 524933 Letter from H. Shah to L. Marcus, EPA May 10, 1990 . Enclosure: . (1) Letter from Y. Tondeur of Triangle Labs, to C. Mazac of Great Lakes Chemical Corp. containing the status on the solid-phase separation procedure. May 8, 1990 40-9093433 Chemical Manufacturers Association Letter from H. Shah to L. Marcus, EPA May 17, 1990 Enclosures: (1) Analytical Protocol for the Deter mination of Polvbrominated Dibenzop-Dioxins and Dibenzo^furans bv High-Resolution Gas chromatography/ Medium High-Resolution Mass Spec trometry in 2.4.6-Tribromophenol. Triangle Labs., Inc.; Brominated Flame Retardant Industry Panel. May 15 , 1990 (2) Analytical Protocol for the Deter mination of Polvbrominated Dibenzop-Dioxins and Dibenzo-furans bv High-Resolution Gas Chromatography/ Medium High-Resolution Mass Spec trometry in Decabromodiphenvl Oxide. Triangle Labs., Inc.; Brominated Flame Retardant Industry Panel. May 15, 1990 (12) 524934 h 1.3~7 < 5 0 <7"30> XU TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1990 ONLY Hi.3 -FILE Fiche # 40-9093433 (continued) (3) Analytical Protocol for the Deter mination of Polvbrominated Dibenzop-Dioxins and Dibenzo-furans bv High-Resolution Gas Chromatography/ Medium High-Resolution Mass Spec trometry in 1.2-Bis(Tribromophenoxv)Ethane. Triangle Labs., Inc.; Brominated Flame Retardant Industry Panel. May 15 , 1990 (4) Analytical Protocol for the Deter mination of Polvbrominated Dibenzop-Dioxins and Dibenzo-furans bv High-Resolution Gas Chromatography/ Medium High-Resolution Mass Spec trometry in Tetrabromobisphenol A . Triangle Labs., Inc.; Brominated Flame Retardant Industry Panel. May 15, 1990 40-9093457 .- Chemical Manufacturers Association Letter from H. Shah to L. Marcus, EPA May 31, 1990 Enclosure: (1) Progress report on the Analytical, Methods Development for Polyhalogenated Dibenzo-p-Dioxins/Dibenzofurans in Octabromodiphenyloxide and Allyl Ether of TetrabrorrKV&LO""- 05TSphenol-A. Triangle Labs., Inc. May 30, 1990 (12a) 524935 h 1.3-8 ^073 7 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1990 ONLY H i .3_F!LE Fiche # 40-9093458 Chemical Manufacturers Association (12b) 524936 Letter from H. Shah to L. Marcus, EPA June 6, 1990 Enclosure: (1) Corrected page 55 (Table 5) for all four protocols submitted May 17, 1990. 40-9093459 Chemical Manufacturers Association (12c) Letter from H. Shah to L. Marcus, EPA June 14, 1990 Enclosures : (1) Analytical Protocol for the Deter mination of Polvbrominated Diben^i-- ^grs^p-Dioxins and Dibenzofurans by > High-Resolution Gas ChromatoaraA^W / ^OHy/^Medium High-Resolution Mass^ ipetttrometrv in TetrabromobiST?/^-,^^. -- ^ merRs>3^A-Bis(Allyl Ether). Bj?ominated Flame Retardantc^r^Ji^ I'ndustrry Panel. June 15, 1990 ( 2 ) Analytical Protocol for the Deter mination of Polvbrominated Diben*pfr -- C-gffHp-Dioxins and Dibenzofurans bff , High-Resolution Gas Chromatogra^i ^ / _ $5hy^Medium High-Resolution Mass^~ trometrv in Octabromodiphenv] Brominated Flame Retardant lndugt-ey Panel. June 15, 1990 524937 H i . 3-9 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1990 ONLY H l.3 -FILE Fiche # 40-9093466 Chemical Manufacturers Association (13) Letter from H. Shah to J. Remmer^j submitting an amendment to the * /AJ*dT/#tical Protocol for Decabromodi^Bffi^^ v p&enyi Oxide Submitted by the B r o m i c it c # nal.ei'E-glame Retardant Industry Panels>* Q, CiBFRIP)^requesting a deviation f r o m - ^ teirt jitrie-'sample size in the Analytical v J i t f W w Protocol for Pentabromodilfrphenyl Oxide & * < * $ - ' a~nQ~ieques L- for a meeting^.) ? June 26. 1990 V 7i y Enclosures : (1) Progress Report on Decabromodiphenvloxide /a/nalvtical ^protocol . on BA-50 and^fethoddevelopment for PeBDPCjf, ^riangle Labs. , Inc. June 24, 19-90 (2) Note on the Single-Laboratory Evaluation of^ P^BDPO. Triangle Labs ., Inc . / 40-9093467 Chemical Manufacturers Association Letter from G. Cox to C. Elkins requesting the analysis of blood samples^ taken from employees working near the processing of Polybutylene Terephthalate (Containing D'ecabromodiphenyl Ether as a Flame Retardant) 15S" ^-performed at the Midwest Research Institute. July 16, 1990 (14) .H 1 3 - 1 0 P.0 7 3 ^ TSCA SECTION 8(d) AND 4(a) , HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1990 ONLY H 1.3-FILE Fiche # 40-9093468 Chemical Manufacturers Association (15) S $ 3 3 / Letter from H. Shah to L. Marcus, EPA July 17, 1990 Enclosures : (1) Analytical Protocol for the Botslhnination of Polvbrominated /Lrfrg&fferqvfrp-Dioxins and Dibenzoft/yy^. ( / ^ Hiah-Resolution Gag^ * <^hromatocrrapIiv7Mediiim High- - (Resolution Mass Spectrometry in Pehtabromodiplienvidxide.'-^rrianale Labs., Inc.; Brominated Flame ---- Retardant Industry Panel. July 15, 1990 -- ( 2 ) Analytical Protocol for the wM u ,w ZfelSgYmination of Polvbrominated PrLbeyi-g^MD-Dioxins and Dibenzo^v**^' f-ufante^l5V High-Resolution Gas X^romatoaTabhV^Mediiim High- A ^Resolution bias's Specttrometrv in T eLrabi uiuubTsphenoT^A-Bisethoxvlate. Triangle Labs., Inc. Brominated Flame Retardant Industry Panel. July 15, 1990 _ Hi.3-11 3-0 7 Yo rio TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANF DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET # 8 3 0 0 2 0 - FOR 1990 ONLY Hi.3 -FILE F iche # 40-9093469 Chemical Manufacturers Association (16) Letter from H. Shah to L. Marcus, EPA July 17, 1990 Enclosure: (1) DBDPQ Analytical Protoco ^--'femt^n&ment. Triangle Labs. , Inc. ; ^Z*?*^**" ^Bl'dtinated Flame Retardant ' Hfianu?dus>--fLWry v--, -- 1 - J for Sample "Macro-SG-Micro-> 7\II (b) Table 2 - Analytical Results for Sample "Macro-SG-Micro-^ B" .- 40-9093470 Chemical Manufacturers Association Letter from H. Shah to J. Remmers, P & responding to EPA's questions on the Analytical Protocol submitted by the Brominated Flame Retardant Industry Panel. July 19, 1990 (17) h 1.3-12 7M TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1990 ONLY H1.3 -FILE Fiche # 40-9093471 Chemical Manufacturers Association (is) Letter from H. Shah to J. Remmers, EPA. containing the interpretation of 'TSia^s- from Y. Tondeur of Triangle 0>j ' T^jsVr^r'Sf'hV'> on "limits of quantification" ( . * - 0 0 ) ) . - precision/matrix spike studies clJ L j recovery/consideration of the ). '^arTTdvty of data from samples presenting j& u T ' recovery. August 10, 1990 Enclosure: (1) Flow Charts on Low Recovery Sample Data. 40-9093472 Chemical Manufacturers Association Letter from H. Shah to J. Remmers, ePfh August 21, 1990 Enclosure: tr j / (1) Letter from B. Biles of Arnold and Porter -addressing modifications to test protocols and timetables for analytical testing. August 21, 1990 do: > 3 H } . 3-13 9-07^5- 7^ TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1990 ONLY H l . 3 -FILE Fiche # 40-9093473 Chemical Manufacturers Association Letter from H. Shah to L. Marcus, EPA August 24, 1990 (20) S ' Z } } $ S - Enclosure: (1) Progress Report: Evaluation of a Microcarbon Column (DBDPO Sample Fractionation Procedure). Triangle Labs., Inc. August 23, 1990 (a) Table 1. - Analytical Results for Sample "Macro-SG-Micro-/? " '* (b) Table 2. - Analytical Results for Sample "Macro-SG-Micro- a B_^i---------------- (c ) Comparison of the Analytical Results for DBDPO Analyzed bv the Two-and Three-Step -- /"~P-rocf&dures. (d) Comparison of Selected Ion Current Profiles for DBDPO After Undergoing "Two-Step" and "Three-BebC Chromatographic Cleantsi ):Recovery Standard and--Qff^SICP. Hi.3 -1 4 2-73 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET # 8 3 0 0 2 0 - FOR 1990 ONLY Hi 3-FILE Fiche 40-9093407 (continued) (2) Letter from C. Mazac to L. Marcus, EPA January 16, 1990 (a) Analytical Protocol for the Determination of Polvbrominated Dibenzo-p-Dioxins and Dibenzofurans bv High-Resolu tion Gas Chromatography/ Medium High-Resolution Mass Spectrometry in Tetrabromobisphenol-A-Bisethoxvlate. Triangle Laboratories, Inc. January 12, 1990 (3) Letter from C. Mazac to L. Marcus, EPA January 16, 1990 (a) Analytical Protocol for the Determination of Polvbrominated Dibenzo-p-Dioxins and Dibenzofurans bv High-Resolu tion Gas Chromatography/ Medium High-Resolution Mass Spectrometry in Allvl Ether of Tetrabromobisphenol-A. Triangle Laboratories,. Inc. January 12, 1990 (4) Letter from C. Mazac to L. Marcus, EPA January 16, 1990 (a) Analytical Protocol for the Determination of Polvbrominated Dibenzo-p-Dioxins and Dibenzofurans bv High-Resolu tion Gas Chromatography/ Medium High-Resolution Mass Spectrometry in 2.4.6Tribromophenol. Jrianglo- Laboratories, m e . January 12, 1990 H 1 . 3 - 19 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-E-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1990 ONLY Hi.3 -FILE Fiche # 40-9093407 (continued) ' (5) Letter from C. Mazac to L. Marcus, EPA January 16, 1990 (a) Analytical Protocol for the Determination of Polvbrominated Dibenzo-p-Dioxins and Dibenzofurans bv High-Resolu tion Gas Chromatography/ Medium High-Resolution Mass Spectrometry in Decabromodiphenvloxide. Triangle Laboratories, Inc. January 12, 1990 (6) Letter from C. Mazac to L. Marcus, EPA January 16, 1990 (a) Analytical Protocol for the Determination of Polvbrominated Dibenzo-p-Dioxins and Dibenzofurans bv High-Resolu tion Gas Chromatography/ Medium High-Resolution Mass Spectrometry in OctabromodiPhenyloxide. Triangle Laboratories, Inc. January 12, 1990 (7) Letter from C. Mazac to L. Marcus, EPA January 16, 1990 1.3-20 07^ TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET # 8 3 0 0 2 0 - FOR 1990 ONLY Hi.3-FILE Fiche # 40-9093407 (continued) (a) Analytical Protocol for the Determination of Polvbrominated Dibenzo-p-Dioxins and Dibenzofurans bv High-Resolu tion Gas Chromatography/ Medium High-Resolution Mass Spectrometry in Tetrabromobisphenol-A. Triangle Laboratories, Inc. January 12, 1990 (8) Letter from C. Mazac to L. Marcus, EPA January 16, 1990 (a) Analytical Protocol for the Determination of Polvbrominated Dibenzo-p-Dioxins and Dibenzofurans bv High-Resolu tion Gas Chromatography/ Medium High-Resolution Mass Spectrometry in Pentabromodiphenvloxide. Triangle Laboratories, Inc. January 12, 1990 40-9093409 Great Lakes Chemical Corporation Cover letter from C. Mazac to L. EPA January 16, 1990 Enclosures: (1) Letter from C. Mazac to L. Marcus, EPA January 16, 1990 (27) 524943 .h 1 3 " 21 9% TSCA SECTION 8(d) AND 4(a) , HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1990 ONLY H 1 .3 -FILE Fiche # 40-9093409 (continued) (a) Sampling Protocol for the Determination of Halogenated Dibenzo-p-Dioxins and Diben^ 0 4^furans in 1 .2-Bis(Tri|/^^^P -- _ ^bj^flfrPhenoxv)Ethane". T-riang 1e.Laboratories, Inc. January 8, 1990 (2) Letter from C. Mazac to L. Marcus, EPA January 16, 1990 (a) Sampling Protocol for the Determination of Halogenated Dibenzo-p-Dioxins and Dibeiyt/^ / zyfurans in T e t r a b r o m o b i s # ~ rt^ent)2ft-A-Bisethoxvlate. Triangle Laboratories, Inc. January 8, 1990 (3) Letter from C. Mazac to L. Marcus, EPA January 16, 1990 (a) Sampling Protocol for the Determination of Halogenated Dibenzo-p-Dioxins and DibeiW)ffifurans in Allvl Ether of v Tetrabromobisphenol-A. Triangle Laboratories, Inc. January 8, 1990 (4) Letter from C. Mazac to L. Marcus, EPA January 16, 1990 (a) Analytical Protocol for the Determination of Halogenated Dibenzo-p-Dioxins and Dibenffi ftqfurans in 2,4.6-Tribromo^yf -- iphenol! .Triangle Laboraij^L, Inc. J January 8, 1990 .H i 3 - 2 2 211 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1990 ONLY H 1 .3-FIl e Fiche # 40-9093409 (continued) (5) Letter from C. Mazac to L. Marcus, EPA January 16 , 1990,, (a) Sampling Protocol for the Determination of Haloaenated Dibenzo-p-Dioxins and Dibeivt/;/Tfipfurans in Decabromodip^^ t ^Pfeffiyftoxide. Triangle V Laboratories, Inc. January 8, 1990 (6) Letter from C. Mazac to L. Marcus, EPA January 16, 1990 (a) Sampling Protocol for the Determination of Halogenated Dibenzo-p-Dioxins and Diber frtfrfurans in Octabromodi /pfo^WTCoxide. Triangle V Inc. January 8, 1990 (7) Letter from C. Mazac to L. Marcus, EPA January 16, 1990 (a) Sampling Protocol for the-. Determination of Halogenated Dibenzo-p-Dioxins and Dibe: ^ifurans in Tetrabromobis^ phenoyVA. T r i a n g l e Labora feomresv Inc. January 8, 1990 H 1.3-23 5.07^ TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1990 ONLY H 1 .3 -FILE Fiche # 40-9093409 (continued) (8) Letter from C. Mazac to L. Marcus, EPA January 16, 1990 (a) Sampling Protocol for the Determination of Haloaenated Dibenzo-p-Dioxins and Diben* rgrefurans in Pentabromodi^^ /fahefly?.oxide. Triangle t L abor^ttHfrres, Inc. January 8, 1990 40-9093413 Great Lakes Chemical Corporation Fax letter from C. Mazac to J. Johnson, EPA concerning the adequacy of the sampling protocols. January 25, 1990 (28) 524944 40-9093415 Great Lakes Chemical Corporation Letter, from C. Mazac to T. Murray, EPA requesting an early evaluation of the analytical protocol for Tetrabromobisphenol-A. February 6, 1990 (29) 524945 40-9093416 Great Lakes Chemical Corporation Letter from C. Mazac to L. Marcus, EPA February 8, 1990 Enclosures: (1) Progress Report No. 3 from R. Varcoe, Triangle Laboratories, Inc. to C. Mazac of Great Lakes Chemical Corp. on the BFRIP protocols. February 9, 1990 Hi.3-24 (30) 524946 507^/9 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1990 ONLY H l .3 -FILE Fiche # 40-9093416 (continued) (2) Progress Report GLC No. 2 from R. Varcoe, Triangle Laboratories , ' to C. Mazac of Great Lakes hfm4<inl Corp. on protocol for PH-7^ <?TS-'+i<i7!Gr=`Tribromophenol). February 9, 1990 -A Q (t /J 40-9093434 Great Lakes Chemical Corporation Letter from C. Mazac to L. Marcus, EPA enclosing the second revision of the sampling protocol. April 16, 1990 Enclosure: (1) Letter from C. Mazac of Great Lakes Chemical Corp. to L. Marcus ''c m Cj April 16, 1990 (a) Sampling Protocol for the Determination of Halogenated Dibenzo-p-Dioxins and Dibenzofurans in Allvl Ether of Tetrabromobisphenol A (BE-51). Triangle Labs., Inc. April 1990 (31) 524947 40-9093435 Pfister Chemical Letter from R. Huth to L. Marcus, EPA May 4, 1990 Enclosure: (1) Sampling Protocol for the Determi nation of Halogenated Dibenzo-pDioxins and Dibenzo Furans in 3.4'.5-Tribromosalicvlanilide. (32) 524948 .H 1 3 - 2 5 TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1990 ONLY H 1 .3-FILE Fiche # 40-9093475 Pftster Chemical, Inc. osi m $ y i > Letter from R. Huth to L. Marcus, EPA September 10, 1990 Enclosure: (1) Sampling Protocol for the nation of Halogenated Dlbeyay^My^Dioxins and ,5 Tribromos^licvlrfniifcffife. SeptemberJ 5 , 1 9 ^ * .J IM (a) Curriculum Vitae for PfisterChemical and Triangle Laps # personnel. 40-9093492 Pfister Chemical, Inc. (33a) Letter from R.c. Brady to Document Control Office, EPA October /8 , /l990 E,,ncl,osvure/: (1) Analytical Protocol for t h e -- - ^ B^tSrmination of Polvbrominated <Di&ei^^ap-Dioxins and Dibenzo^A/g'*^ J lA i -fUrana n J t t High-Resolution Oas /finro'm^tograT^iv^ediiim High- s k . /^esoilifTrrn-^Mas^ apec)t:rometrv in 4 3.4 r.5-T'rIbrOmoS Ehiiide. Triangle Laborat'oU r ie s ,IInc October 5, 1990 Cu 1 .H i 3 - 2 6 2075/ TSCA SECTION 8(d) AND 4(a) HEALTH AND SAFETY DATA REPORTING TESTING OF CHEMICAL SUBSTANCES AND MIXTURES P #83002 - POLYHALOGENATED DIBENZO-p-DIOXINS/DIBENZOFURANS DOCUMENTS RECEIVED FOLLOWING DECISION OF JUNE 5, 1987 (DOCKET #830020 - FOR 1990 ONLY i.3 -FILE Ficht .1 Ethyl Corporation (24) 52494\ Letter from L. Wen to L. Marcus, EPA January 16, 1990 Enclosures: (1) Letter from L. Wen, Ethyl Corp. to L. Marcus, EPA January 11, 1990 (a) Sampling Protocol for the Determination of Brominated Dibenzo-p-Dioxins and Dibenzofurans in Decabromodiphenvl-oxide. Triangle Laboratories, Inc. January 4, 1990 (b) Sampling Protocol for the Determination of Brominated Dibenzo-p-Dioxins and Dibenzofurans in Tetrabromobisphenol-A. Triangle Labora tories, Inc. January 4, 1990 (c) Sampling Protocol for the Determination of Brominated Dibenzo-p-Dioxins and Dibenzofurans in Octabromodiphenvloxide. Triangle Laboratories, Inc. January 4, 1990 H 1 3~ 17 <f ' f i TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES ^ DOCKET # -FILE / f~ \ f\ fi i f * f\ ft J TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES ' DOCKET # DOCUMENTS RECEIVED FOLLOWING DECISION OF ^-FILE {3 J ^ Fiche # r (j / <5, fy ) l/V\ L (t 9.075 4 TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET # DOCUMENTS RECEIVED FOLLOWING DECISION OF Fiche # f x / / /( P tM ^ * / Q ^O'TSS TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET DOCUMENTS RECEIVED FOLLOWING D ECISIO N OF -^sj-FILE A Fiche # -- } , ^ / P> ' ' ' /??/ X 0 7S& TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES , DOCKET # DOCUMENTS RECEIVED FOLLOWING DECISION OF N&a-FILE fo1 - p / ? 3 y ( ? 0 m <30757 TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES , DOCKET # DOCUMENTS RECEIVED FOLLOWING DECISION OF Fiche # 2 - 0 7 ^ TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET # DOCUMENTS RECEIVED FOLLOWING DECISION OF VFILE t}0 - 5 i ? 3 <7 t r f Fiche 4 r ft/, ^ //// ft / \ c&rQ' t **/ Vs ^ TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET I / DOCUMENTS RECEIVED FOLLOWING DECISION OF ^-FILE V ,q &<L, LP' TSCA SECTION 4 esting of chemical substances and mixtures DOCKET | documents received following decision of N^-riLE ^ 'i Fiche 1 2-7/ j i/o -?/fJ s c \ * 1 I i TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET DOCUMENTS RECEIVED FOLLOWING DECISION OF *fc^FlLE u /' H J L (Ly*uy / /f/A .fiche < 7 2 J> 7 y f /A ' : ft - t f c t t u p ^ ,, TSCA SECTION 4 testing of chemical substances and mixtures DOCKET # DOCUMENTS RECEIVED FOLLOWING DECISION OF Rj^FILE V) r c- TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES , DOCKET # DOCUMENTS RECEIVED FOLLOWING DECISION OF ^-FILE H b (f Fiche <3. 9 ^ '""i x\ /*!r~y > / TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET 4 DOCUMENTS RECEIVED FOLLOWING DECISION OF S^-FILE h / , if 1) ... o, 0-?/f3f*3 tJ> x' j ^ ftf t /Sj, / f f t / (]J ^&~yajLy 2*r~^ ^ /'K t - f / , TESTING of CHEMTTSrC^ CHEMICAL SSEUCB7S*TOANNC4Pc ddcumews s e " ' v JJ ^ -F I L E sg d; c " s D ECISIO N OF a/ r* o V . s //,/ff/ (A"J kZvt 377-- ' ~ 9 /9 * TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET # DOCUMENTS RECEIVED FOLLOWING DECISION OF n V " " /-f (i P - vC h > Fiche f/-f tf, /'ff/ r% /ra / 73$ TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET # DOCUMENTS RECEIVED FOLLOWING DECISION OF FILE 9/ /7 ., )l Ac > Fiche W tT n ^ -r^ SL11 2 0 '7Z.Q TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET # DOCUMENTS RECEIVED FOLLOWING DECISION OF 1 ^-FILE , Fiche # >< ) 3 3 s p &?- /*, / ? ? / 3oo o r\ n >7r. f/ 9 TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES DOCKET DOCUMENTS RECEIVED FOLLOWING DECISION OF ^-FILE v <?i / t 7 / f t ------ V w ->*/ f f / 3oi TSCA SECTION 4 TESTING OF CHEMICAL SUBSTANCES AND MIXTURES / DOCKET # DOCUMENTS RECEIVED 'FOLLOWING DECISION OF ^-FILE f / ?J 5 5 ^ ^Jb c ' / W fV. 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