Document 99JOQZ8xaz6kXDQjnaZbobgZ6
DO A 041689 CONF tofntiai
Product Environmental Data
vironmental Laboratory ^.ivironmentat Engineering and Pollution Control
900 Bush Avenue
PO Box 33331
St. Paul. 612/778
5M1N0455133
COMMERCIAL CHEMICALS DIVISION
LIGHT WATER* BRAND ALCOHOL TYPE CONCENTRATE AQUEOUS FILM FORMING FOAM FC-600
DESCRIPTION! Water-miscible fire extinguishing agents.
APPEARANCE! Light brown liquid.
COMPOSITION!
Percent by Weight
Water Butyl Carbitol* Synthetic Detergents Fluoroalkyl Surfactants Hydrophilic Polymer
80 15 <5 <5 <5
USAGE:
Foams are normally made from solutions containing 3% or 6% FC-600 in water. These foams cover and thus extinguish
hydrocarbon liquid or polar solvent based fires. For more detailed usage information, see your technical servic representative.
BIODEGRADATION:
Chemical Oxygen Demand (COD) 5-Day Biochemical Oxygen Demand (BOD5)* 20-Day Biochemical Oxygen Demand (BOD20) 28-Day Biochemical Oxygen Demand (BOD28)
0.35 g/g 0.025 g/g
0.21 g/g 0.27 g/g
20-day BOD of 3% aqueous solution: 20-day BOD of 6% aqueous solution:
6,300 mg/1 12,600 mg/1
BOD20 to COD ratio:
0.6
* The reported BOD values were determined using a nitrification inhibitor. The inhibitor prevents errors in BOD measurements due to oxidation of NH3, a component of BOD dilution wat r.
Date: 4/18/83 (Supersedes 6/13/80)
Page 1 of 3
rse data are intended for the use of a person qualified to evaluate environmental data.
All statements, technical information and recommendations contained herein are of a general nature and are based on laboratory tests or
literature information we believe to be reliable, but the accuracy, completeness or applicability to particular circumstances is not guar
anteed. 3M makes no representation that the customer's use and disposal of the product will comply with ail applicable environmental
laws, regulations and rules.
Form 1470S-C PWO
DO A 041690
CONFIDFNT T Al
3M General Offices 3M Center SL Paul. Minnesota 55144-1000 612/733 1110
Duns No.i 00-617-5062 MATERIAL SAFETY DATA SHEET
06-12 7409
MSDSi FC-600 LIGHT HATER Brand ATC/AFFF SEPTEMBER 6, 1988
PAGEi 2 of 3
XI .teontlnuofil
SPECIAL FZRE FIGHTING PROCEDURES! Nona Known
UNUSUAL FIRE AND EXPLOSION HAZARDS* Toxic by-products# including small amounts of HF# may ba formed. Saa Section 4.
STABILITY! Stable INCOMPATIBILITY - MATERIALS TO AVOIDi
NA HAZARDOUS POLYMERIZATION! Hill Not Occur HAZARDOUS DECOMPOSITION PRODUCTS *
Thermal decomposition may produce toxic materials including HF. Decomposition of usage concentrations does not present a hazard.
C*I7
SPILL RESPONSE* Observe precautions from other sections. Cover with absorbent material. Collect spilled material. Clean up residue with water.
RECOMMENDED DISPOSAL* Bleed spent solutions and small product quantities# <5 gal.# to a wastewater treatment system. Reduce discharge rate if foaming occurs. Mix with flammable material and incinerate in an industrial or commercial facility. Combustion products will include HF. Disposal alternative! Dispose of completely absorbed waste product in a facility permitted to accept chemical wastes. Since regulations vary# consult applicable regulations or authorities before disposal. U.S. EPA Hazardous Haste No.i None
ENVIRONMENTAL DATA* 96-Hr. LC50# Bluegill SunfishCLepomia macrochirus)*1500 mg/1; 96-Hr. LC50# Fathead Minnow(Pimephalas promelas)*1700 mg/1; 48-Hr. EC50# Daphnia magna*280Q mg/1; COD*0.35 g/g; BOD20*0.21 g/g.
SARA HAZARD CLASS* FIRE HAZARD* No PRESSURE* No REACTIVITY* No ACUTE* Yes CHRONIC> Yes
i. wmm m*tup
' --_11 --
EYE CONTACT* Immediately flush with plenty of water. Continue for 10 minutes. Call a physician.
SKIN CONTACT! Hash affected area with soap and water.
INHALATION* Remove to fresh air.
Abbreviations! M/D - Not Determined N/A - Not Applicable
A 04 1f,9] CONF T DFNT T Ai
3M General Offices 3M Center SI Paul. Minnesota 55144*1000 612/733 1110
Duns No.i 00-617-3082 MATERIAL SAFETY DATA SHEET
06-12 7410
MSDS* FC-600 LIGHT HATER Brand ATC/AFFF SEPTEMBER , 198*
PAOEi 3 of 3
_ 6. SUGGESTED FlRSf~AIO
/continued)
__ ' ~ ~
IF SHALLOWED* Give two glasses of water.
OTHER FIRST AID* NONE
Call a physician or Poison Control Center.
Use only in wall ventilated areas with sufficient air movement to maintain airborne levels at recognized health and safety levels. Av id prolonged breathing of vapors. Avoid aye and skin contact. Store above 30 degrees F. SPECIAL PROTECTION*
EYE PROTECTION* Safety Glasses or Goggles SKIN PROTECTION* Rubber Gloves VENTILATION* General ventilation adequate. RESPIRATORY PROTECTION* Above component exposure limits* usa organic vapor cartridge respirator.
V
EYE CONTACT * Can causa moderate irritation of the eye on direct contact with the concentrate. Diluted FC-600 (6 parts FC-600 in 94 parts water) is miniiaally irritating to the eyas. * SKIN CONTACT* Causes moderate irritation of skin on direct contact with FC-600 concentrate. Causes ainimal irritation of skin on direct contact with FC-600 diluted (6 parts FC-600 and 94 parts water).
*
INHALATION* Mist or vapors aay"eausa irritation af respiratory system.
Very high concentration of vapors may causa vomiting* nausea*
diarrhas* abdominal pain* pulmonary edema and stupor. Symptoms of
overexposure may include unconsciousness! repeated overexposure nay
include nystagmus* recurrent unconsciousness* hemolysis and bone
marrow depression.
.
m
f
INGESTION* Undiluted FC-600 men acute oral LD50 (rat) greater than 10 grams par kilogram of body weight. This classifies Jhis product as being practically non-toxic/orally. *
i
%
Abbreviations* N/D - Not~Determined N/A - Not Applicable
OO A 04169P CONFIdfnttai
The information on this Data Sheet represents our currant data and East opinion as to th proper use in handling of this product under normal conditions. Any usa f the product which is not in conformance with this Data Sheet or which involves using the product in combination with any other product or any oth r process is the responsibility of the user.
Froauct Environmental Data
'ironmental Laboratory
Environmental Engineering and Pollution Control
900 Bush Avenue
3M LIGHT WATER BRAND AQUEOUS
PO Box 33331
FILM FORMING FOAM (AFFF)
St. Paul. 612/778
MN 551334736
333g)ispoSAL
RECOMMENDATIONS
AND
HAZARD
EVALUATION
CONCLUSIONS:
Light Water Brand AFFF and ATC wastes are treatable in a wastewater treatment system if disposed of according to 3M recommendations. These products have low toxicity to the microorganisms in wastewater treatment systems even at concentrations much higher than those recommended by 3M. Foaming problems may develop, however, particularly when recommended discharge concentrations are exceeded.
Fluorochemical thermal decomposition products do not present a health hazard during fire fighting nor do they affect the treatability of aqueous fire fighting wastes. The major reasons for this are that during usage, the concentration of fluorochemicals in Light Water AFFF solutions is low and little fluorochemical is burned.
DISPOSAL RECOMMENDATIONS FOR AFFF (AQUEOUS FILM FORMING FOAM) AND ATC (ALCOHOL TYPE CONCENTRATE) WASTES:
3M recommends handling wastes resulting from the use of Light Water *FFF products by pretreatment in an oil/water separator. The oil fraction should be incinerated in a facility designed to accept such wastes. The aqueous fraction should be metered to a wastewater treatment system at a rate sufficiently low so that the concentrations reaching the aeration basin of the wastewater treatment system will not cause excessive foaming. Appropriate discharge rates will be determined by individual circumstances and should follow applicable regulations.
When pretreatment by oil/water separation is not possible, 3M recommends metering wastes to a wastewater treatment system. Since regulations vary, consult applicable regulations or authorities before disposal. In addition, treatment plant operators should be contact d before discharge to determine the capacity of the treatment system and sewage flow rates into the system so that discharge rates can be estimated.
For most AFFF or ATC products used at 6%, 3M recommends adjusting the discharge rate so that the product concentration in the aeration basin of the wastewater treatment system will be less than 100 mg per liter of sewage. For most products used at 3%, 3M recommends a maximum
^re.
9/11/92Pace 1 of 8 *
*e data are intended for the use of a person qualified to evaluate environmental data.
. .statements, technical information and recommendations contained herein are of general nature and are based on laboratory
tests or literature information we believe to be reliable, but the accuracy, completeness or aoDlicability to particular circumstances
is not guaranteed, 3M makes no representation that the customer's use and disposal of the product will comply with all applicable
environmental laws, regulations and rules
- 3..-
pO ^ 041693
OONFTDFNTT At
Product Environmental Data
Environmental Laboratory 3M Environmental Engineering and Pollution Control
900 Bush Avenue
3M LIGHT WATER BRAND AQUEOUS
PO Box 33331
FILM FORMING FOAM (AFFF)
^55l33'333i)ISPOSAL RECOMMENDATIONS AND HAZARD EVALUATION
612/778 4736
(CON'T)
product concentration of 50 mg/L in the aeration basin. Products used at 3% require greater dilution than products used at 6% because the 3% concentrates have higher surfactant concentrations than the 6% concentrates. Product Environmental Data Sheets for products with higher surfactant concentrations may recommend somewhat greater dilution.
In some situations, metered discharge of wastes to a wastewater tr atment system is impractical because the small size of the treatment system limits the discharge rate to such an extent that too much time would be required for disposal. 3M recommends two disposal alternatives in these situations: (1) transporting collected waste materials by tank trucks for metered discharge into a larger waste treatment facility, or (2) discharging the waste at a somewhat higher rate with appropriate concentrations of antifoaming agent added to the waste stream to control foaming.
Experiments conducted in the 3M Environmental Laboratory have determined that several antifoaming products are effective at controlling excessive foaming in activated sluge/AFFF mixtures. The effectiveness of antifoaming agents, however, will be determined by the specific conditions in the aeration basin in individual wastewater treatment systems.
While this is not an endorsement, the following nine products were found to be the most effective of thirty-one antifoam products tested using activated sludge/AFFF mixtures in laboratory tests:
GE Silicones 1-800-332-3390
Antifoam Emulsion AF72 Antifoam Emulsion AF93 Antifoam Emulsion AF9020
Henkel 1-800-922-0605
Defoamer WB-209 FoammasterTM DS
Union Carbide 1-800-523-5862
SAG 2001 Organosilicone Emulsion
'ate: 9/11/92
Page 2 of 8
These data are intended for the use of a person qualified to evaluate environmental data. All statements, technical information and recommendations contained herein are of general nature and are based on laboratory tests or literature information we believe to be reliable but me accuracy comoieteness or aopiicabiiity to Darticuiar circumstances s "c bua'3',`eeb 2`-` maxes nc 'ecesentation tnat 'e customs' s use ana disposal e` me sroduct will cpmpiv .vth an applicable
DO A 041694 OONFTDFNTTAl
Product Environmental Data
3M
(.iivironmental Laboratory 3M Environmental Engineering and Pollution Control
900 Bush Avenue
PO St.
PBaouxl,3M33N3155133-3331II
3M LIGHT WATER BRAND AQUEOUS FILM FORMING FOAM (AFFF)
612/778 4736
CDISPOSAL RECOMMENDATIONS AND HAZARD EVALUATION
Wacker Silicones 1-800-248-0063
Antifoam Agent SE-36 Antifoam Agent SWS-214 Antifoam Emulsion SRE
Of these nine products, the most cost-effective were Henkel WB-209, GE Silicones AF9020, Henkel FoammasterTM DS, and Wacker Silicones SRE. The cost analysis used in that study was based on antifoam prices obtained in July, 1992. Price and transport charges may vary which could cause other products to be more cost-effective in some locations.
The antifoam concentration required to limit foaming in laboratory tests on FC-203CF solutions of various concentrations are tabulated below. The products are listed in the table in order of most to least cost-effective. The antifoam concentrations given in the table are intended to serve as estimates since the actual antifoam concentration required to suppress foaming will be determined by the specific conditions in the aeration basin. Where no data are given in the table, the antifoam agent is not recommended for suppressing foam at or
above that AFFF concentration.
The antifoam concentrations in the table were obtained in laboratory tests using 3M FC-203CF, but they are the approximate antifoam concentrations required for other 3M AFFF and ATC products used at 3%. For 3M AFFF products used at 6% in water, the antifoam concentrations should be approximately correct for twice the AFFF concentrations given at the top of each column. This is, the antifoam concentrations would be approximately correct for 6% AFFF concentrates at 200, 600, 1000, 1200,*1400, 1600, 1800, and 2200 mg/L in the aeration basin.
The AFFF and antifoam concentrations given in the preceding paragraph and in the table below are for foam control only. Other factors must be considered in selecting rates of discharge to a sewer. 3M recommends a case-by-case determination of the maximum concentrations of AFFF and antifoam to be discharged to a treatment system and subsequently to an aquatic environment. The maximum concentration will
depend on a variety of factors, including the conditions in the individual wastewater treatment system and in the receiving watercourse, as well as the dilution factor of the treated wastewater in the receiving watercourse. These factors should be evaluated in
/ate: 9/11/92
________
Page 3 of 8
These data are intended for the use of a person qualified to evaluate environmental data. All statements, technical information and recommendations contained herein are of general nature and are based on laboratory tests or ine'at'jrs information we oeiieve to be reliable, but the accuracy, completeness or applicability to particular circumstances is "C; ouarantee 3M maes np representation that the custome's use anc disposal of the product will comply with all applicable
Product Environmental Data
vironmental Laboratory 3M Environmental Engineering and Pollution Control
900 Bush Avenue PO Box 33331 St. Paul. MN 55133-3331
3M LIGHT WATER BRAND AQUEOUS' FILM FORMING FOAM (AFFF)
612/778 4736
DISPOSAL RECOMMENDATIONS AND HAZARD EVALUATION
(CON'T)
each situation to ensure that neither the AFFF nor the antifoam will cause harm. Product Environmental Data Sheets on the particular 3M AFFF product(s) will help in this evaluation.
FC-203CF Concentration (mg/L)* 10 0 300 500 600 700 800 900 1100
Henkel WB-209
GE Silicones AF9020
Henkel FoammasterTM DS
Wacker Silicones SRE
20 100 190 20 100 190 270 430 500 740 1950 20 110 200 300 430 500 690 1600 20 100 190 270 400 490 -- --
Wacksr Silicones SWS-214
GE Silcones AF93
GE Silicones AF72
Wacker Silicones SE-36
40 170 430 ----- -----
20 100 190 270 430 480 530 1600
20 100 190 270 430 480 600 1800
30 140 310 470 580 --
--
Union Carbide SAG 2001
50 220 600 -- -- -- -- --
* See text for precautions and for extrapolating these data to other 3M AFFF products.
9/11/92
-ate:
Page 4 of 8
i hese data are intended for the use of a person qualified to evaluate environmental data.
All statements, technical information and recommendations contained herein are of general nature and are based on laboratory tests or literature information we believe to be reliable, but the accuracy, completeness or applicability to particular circumstances is not guaranteed. 3M makes no representation that the customer's use and disposal of the product will comply with all applicable anvironr^en!3l laws regulations ana rules
- - DO A 041696
CONFTDFNTTAI
Product Environmental Data
3M
Environmental Laboratory 3M Environmental Engineering and Pollution Control
900 Bush Avenue PO Box 33331
3M LIGHT WATER BRAND AQUEOUS
St. Paul. MN 55133-3331
FILM FORMING FOAM (AFFF)
612/778 4736
DISPOSAL RECOMMENDATIONS AND HAZARD EVALUATION
(CON'T)
In situations where antifoam agents are used to control excessive foaming by 3M products used at 6% in water, 3M recommends adjusting the discharge rate so that the product concentration in the aeration basin of the wastewater treatment system will be less than 1,000 mg/L of sewage, when antifoam agents are used to control foaming by 3M products used at 3%, 3M recommends a maximum AFFF concentration of 500 mg/L in the aeration basin. These maximum concentrations are based on laboratory studies that have shown that 3M AFFF products at or below these concentrations are unlikely to cause toxicity in wastewater treatment systems. The AFFF and antifoam concentrations in the table that are greater than these maximum recommended concentrations are provided to assist customers in dealing with emergency foaming situations or where elevated concentrations are appropriate becaus of individual circumstances. In all cases, applicable local regulations and the antifoam Material Safety Data Sheet (MSDS) should be consulted
before use.
At 3M's own wastewater treatment facilities, foaming caused by Light Water AFFF discharges has been controlled by spraying a dilution of Wacker Silicones Antifoam Emulsion SWS-214 over the aeration basin. This dilution is prepared by mixing one part of SWS-214 in twenty parts of water. The antifoam dilution is sprayed over the aeration basin surface until the desired level of foam control is obtained. This procedure could be used as an alternative to adding the antifoam directly to the AFFF containing waste stream.
REASONS FOR 3M DISPOSAL RECOMMENDATIONS:
The primary reason for recommending discharge to a sewer is that 3M AFFF wastes are treatable in a biological wastewater treatment syst m. Light Water AFFF usage wastes are approximately 99% water and therefore have very low concentrations of organic compounds. The dilute nature of the waste makes alternative disposal methods, such as incineration, carbon adsorption, ultrafiltration, or reverse osmosis, both difficult and costly. Moreover, the major components of 3M AFFF usage wastes are a biodegradable solvent. Butyl CarbitolTM {<1%), and a mixture of biodegradable and partially biodegradable surfactants (<0,3%).
'ate: 9/11/92
Page 5 of 8
These data are intended tor the use of a person qualified to evaluate environmental data. All statements, technical information and recommendations contained herein are of general nature and are based on laboratory tests or literature information we believe to be reliaDie. but the accuracy, comoieteness or applicability to particular circumstances s not guaranteed 3M makes no representation that me customer s use anc discosai cf the product will comply with all applicable
d . . DO A 041 6.9?
CONFTDFNTTA1.
Product Environmental Data
..Ltvironmental Laboratory 3M Environmental Engineering and Pollution Control
900 Bush Avenue PO Box 33331
3M LIGHT WATER BRAND AQUEOUS
St. Paul. MN 55133-3331
FILM FORMING FOAM (AFFF)
612/778 4736
DISPOSAL RECOMMENDATIONS AND HAZARD EVALUATION
(CON'T)
Chemicals are generally considered biodegradable when the ratio of their 20-day Biochemical Oxygen Demand (BOD20) to their Chemical Oxygen Demand (COD) is greater than 0.6. The BOD20/COD for Butyl Carbitol was found to be 0.85. There are several biodegradable surfactants in these products and their BOD2o/COD ratios were found to lie between 0.74 and 0.94. There are also surfactants in these products with BOD20/COD ratios less than 0.6. This includes the fluorochemical surfactants and some of the hydrocarbon surfactants. The hydrocarbon surfactants that do not meet this BOD20/COD criteria will likely fully biodegrade given more time. Some fluorochemical surfactants may have both hydrocarbon and fluorochemical portions. The fluorochemical portions of thes surfactants are not known to biodegrade, but the hydrocarbon portions are likely to be biodegraded to some degree in most wastewater treatment systems and, like the fully hydrocarbon surfactants, eventually completely biodegrade. Possible fates of the nondegradable materials in wastewater treatment systems include sorption onto the microbial solids or passage out of the system with the treated wastewater. In any event, their concentration will be very low. Nonbiodegradable fluorochemical materials are used in AFFF products because they are required to make the products work. All effective AFFF products on the market today (and all fluoroprotein products as well) contain fluorochemical surfactants. Finally, laboratory tests on both the individual product components and the product concentrates have determined the low toxicity of these materials to activated sludge bacteria, so discharge to ordinary wastewater treatment systems is
reasonable.
Laboratory studies have shown that foaming, not toxicity, is usually the cause of problems from improper disposal of AFFF wastes to wastewater treatment systems. In laboratory studies, wastewat r containing FC-600 Light Water AFFF at 1,000 mg/L was treated successfully without toxicity. In that lab study, the foam was physically broken down and returned to the treatment system along with activated sludge solids that came out because of foaming. With these modifications to the normal treatment process, the quality of the treated effluent from the laboratory scale system was not adversely affected. Treatment at this concentration is not recommended, however, because of excessive foaming.
sate:
9/11/92
Page 6 of 8
These data are intended for the use of a person qualified to evaluate environmental data.
All statements, technical information and recommendations contained herein are of general nature and are based on laboratory tests or literature information we believe to be reliable, but the accuracy, completeness or applicability to particular circumstances is not guarantee::. 3M maxes no representation that me customer's use and disposal of the product will comely with ail applicable envirorno-vai 'aws recuiations anc ruies .- _ DO A 041A9A
CONFTDFNTTAI
Product Environmental Data
3M
i j.ronmental Laboratory
3M Environmental Engineering and Pollution Control
900 Bush Avenue PO Box 33331
3M LIGHT WATER BRAND AQUEOUS
St. Paul. MN 55133-3331
FILM FORMING FOAM (AFFF)
612/778 4736
DISPOSAL RECOMMENDATIONS AND HAZARD EVALUATION
(CON'T)
Light Water AFFF wastes resulting from testing the operability of a fire fighting system, such as that installed in a hanger facility, normally don't contain much fuel or oil. On the other hand, wastes from fire fighting training facilities where hydrocarbon fires are extinguished may contain suspended oil. If oil is present, it should be separated from the waste before discharging the waste to a s wer as described above. If oil is emulsified in the waste, it may be difficult to separate but many oils can biodegrade. Furthermore, emulsified oils are more likely to biodegrade in a wastewater treatment system than are nonemulsified oils.
3M recommends metered discharge of Light Water AFFF wastes to flowing sewers because discharge to an intermittently flowing sewer could cause waste to collect and to be flushed to aeration basins at higher than recommended concentrations. Uncontrolled sewer discharge rates also could result in foam baching out of sewer drains.
THERMAL 'DECOMPOSITION FROM LIGHT WATER AFFF USAGE:
Thermal decomposition products resulting from Light Water AFFF usage present an insignificant hazard. Considerable confusion was caused by a precautionary statement formerly used on Light Water AFFF Material Safety Data Sheets (MSDSs). That statement was frequently misinterpreted as meaning that thermal decomposition products from usage concentration levels could cause a health hazard. The precaution one simply stated: "Thermal decomposition may produce toxic materials, including HF." This statement has now been modified to include: "Decomposition of usage concentrations does not present a hazard."
The former MSDS precaution for Light Water AFFF products is still used on the MSDSs for other 3M products containing fluorochemicals. The statement is used because it is well known that most fluorochemical materials, including such commonly used items as polytetrafluoroethylene (PTFE) coated frying pans, utensils, etc., can liberate toxic fumes including HF or perfluorobutylenes under combustion or pyrolysis conditions. However, this will occur only if very high temperature conditions exist {>3000.
9/11/92 -ate:
Page 7 of 8
. nese data are intended tor the use of a person qualified to evaluate environmental data.
All statements, technical information and recommendations contained herein are of general nature and are based on laboratory tests or literature information we believe to be reliable, but the accuracy, completeness or applicability to particular circumstances
is not guaranteed, 3M makes no representation that the customer's use and disposal of the product will comply with all applicable environmental laws, regulations and rules
- - - -
A 04.1699
oonftdfnttai
Product Environmental Data
(,, hnvironmental Laboratory
3M Envir nmental Engineering and Pollution Control
900 Bush Avenue
3M LIGHT WATER BRAND AQUEOUS
PO Box 33331
FILM FORMING FOAM (AFFF)
5t Paul. MN 55l33-3335iSpoSAL RECOMMENDATIONS AND HAZARD EVALUATION
612/778 4736
(CON'T)
Furthermore, formation of hazardous concentrations of thermal by-products is more likely in fluorocarbon containing products with high fluorine content (65 or 70%) , but the fluorochemical content of 3M AFFF products is very low. For example, FC-206CF Light Water AFFF concentrate contains only about 1.1% fluorine, and when diluted to the usage concentration, it contains only about 0.06% fluorine. Thus, from a combustion or pyrolysis product hazard perspective, PTFE, which is widely known as a nontoxic, inert material, would be far more hazardous.
There are other reasons that make the production of hazardous concentrations of thermal degradation products during fire fighting with Light Water AFFF very unlikely. Most importantly, little of the fluorochemical would burn or thermally decompose. The reasons for this are that the product rapidly covers and extinguishes the fire, and the high percentage of water absorbs considerable heat, thereby cooling and limiting the decomposition of the dissolved fluorochemical.
The 3M Industrial Hygiene Department conducted a test to confirm the lack of hazard from fluorochemical combustion when Light Water AFFF is used in fire fighting. The test was designed to simulate a "worst case" situation by maximizing the chance of fluorochemical combustion. The test burned a 2-3 inch layer of FC-203CE Light Water AFFF foam in a 10 square foot pan of gasoline inside a 20 by 20 foot wide and 15 foot high open topped concrete building. To cause the fluorochemical in the Light Water AFFF product to burn, the test operator had to stir vigorously the foam and gasoline, an atypical procedure. Stirring broke the foam barrier and allowed combustion that would normally have been extinguished by the foam. Even under this worst case situation, two HF measurements taken above and near this fire were only 0.23 and 0.16 parts per million (ppm). While not directly applicable to this situation, these measurements were below the Threshold Limit Value for HF of 3 ppm, a concentration judge not to present a health hazard for nearly all
persons.
Thus, fluorochemical decomposition products from Light Water AFFF present an insignificant risk when compared to the many other hazardous decomposition products resulting from a fire. Light Water AFFF products certainly play a much more significant role in reducing the toxicity hazards of fire situations by rapidly cooling and extinguishing a fire and by covering and preventing the volatilization of other potentially toxic materials.
ate: 9/11/92 Page 8 of 8
These data are intended for the use of a person qualified to evaluate environmental data.
Ail statements, technical information and recommendations contained herein are of general nature and are based on laboratory
tests or literature information we believe to be reliable, but the accuracy, completeness or applicability to particular circumstances
is not guaranteed 3M makes no representation that the custome- s use and disposal of tne product will comply with all applicable
o-ra' aws. regulations and rules --
,,,, Do A 041700
oonfjdfnttai
c.
/
4
i
Con e Material Safaty Data Sh at
Page i
COXCOOll
DEHYDRATED CPBC ASK Revised 6-SEP-1993
Printed 32-SSP-1993
CHEMICAL PRODUCT/COMPANY IDENTIFICATION Tradenamas and Synonym*
Unhydratad Circulating Fluidi2*d Bad Combustor Aah Unhydratad Bottom Aah Unhydratad Fly Aah CALSORB
Company Identification
KAMUFACT0RER/DI8TRXBUT0R NISCO/DBMC P.0. BOX 2150
Xanner, LA 70063 504-468-3247 (Mark Hite)
PHONE NUMBERS
Product Information Transport Emergency Madieal Emergency
i 1-713-293-5550 t CHEMTREC 1-800-424-9300 t 1-800-441-3637
COMPOSITION/INFORMATION ON INGREDIENTS Components
Material Calcium Oxide
Cftg Nuafrfg 1305-78-8
1 30-46
Anhydrite - Calcium Sulfate
7778-18-9
38-61
Silicon Dioxide (Crystalline Silica) Magnesium Oxide
Components (Remarks)
14808-60-7 1309-48-4
<4.5 0.4-;
Remaining components are not known to be hazardous as defined by OSKA's Hazard Communication Standard, 29 CFR 1910.1200.
T- r-
^ A o<j j 7^.,
C0NFr^NTT^
COXCOOll
Ceaoe Material Safety Data Sh at
Page .;
HAZARDS IDHNTXPICATXOlf
Potential Health Effects
Primary Routes of Exposure/Entry: skin, inhalation.
Signs and Symptoms of Exposure/Medical Conditions Aggravated by Exposure to:
Crystalline silica: Eye contact may initially include irritation with discomfort, tearing, or blurring of vision.
The predominant effect of overexposure to airborne crystalline silica in humans is silicosis. Silicosis is a chronic disease characterized by pulmonary fibrosis and the formation of silica-containing scar tissue in the lungs with symptoms of coughing, dyspnea, wheezing, and nonspecific respiratory ailments. Individuals with
preexisting diseases of the lungs may have increased susceptibility to the toxicity of exceesive exposures t crystalline silica. Very high concentrations of short exposures to crystalline silica may be lethal.
Several recent epidemiology studies have shown, that in addition to silicosis, there is limited evidence of an excess of lung cancer in occupations involving Chronic excessive exposures to crystalline silica, such as stone cutters and granite industry workers. Occupational
exposure at the recommended AEL of 0.1 mg/m3 for crystalline silica should protect workers from silicosis and lung tumors.
Carcinogenicity information
The following components are listed by XARC, NTP, OSHA or ACGZH as carcinogens. A "P" indicates a proposed carcinogen.
Material Silicon Dioxide (Crystalline Silica)
IARC NTP Q8HA ACOIH XX
FIRST AID MEASURES
first Aid
INHALATION
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, givs oxygan. Call a physician.
SKIN CONTACT
00 A 04170? CONF TDFNTTAl
r^r in fcw
XtpJ 1 Wl WIMI'W W
cokcooii
Con e Material Safety Data Shaat
Page 2
(FIRST AID MEASURES - Continued)
In easa of contact, immediately flush akin with planty f water for at least 15 minutes, while removing contaminated clothing and ahoas. Call a physician. Wash contaminated clothing before reusa.
EYE CONTACT
In case of contact, immediately flush ayes with planty of water for at least 15 minutes. Call a physician.
INGESTION
Ingestion is not considered a potential route of exposure.
FIRE FIGHTING MEASURES Flammable Properties
Not a fire hazard under normal conditions. Extinguishing Media
Use media appropriate for surrounding material. Firs righting Instructions
Wear self-contained breathing apparatus.
ACCIDENTAL RELEASE MEASURES
safeguards (Personnel)
NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with clean-up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up.
spill clean Up
Recover undamaged and minimally contaminated material for reuse and reclamation. Shovel or sweep up.
Accidental Release Measures
Avoid generating dusting conditions.
Please note Hazardous Reactivity Section: Reacts exothermically to release heat when water is added.
DO A 041700 CONFTDFNTTAl
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Conoc Material Safety Data Sh t
Pag*
HANDLING AND STORAGE
mmveeeeee^wwMMMfe*-' ***
Handling (Personnel)
Avoid breathing duet. Avoid contact with eyas, skin, or clothing. Wash thoroughly after handling. Wash clothing after uae.
Storage
Store in accordance with National Fir* Protection Association recommendatir :s.
EXPOSURE CONTROL /PERSONAL PROTECTION
Engineering Cent ?ls
Ventilation: of dust.
aep area well ventilated and avoid inhalation
Personal Protect, e Equipment
Respiratory Pr section: A NIOSH/MSHA approved air purifying respirator wit a dust/mist cartridge or canister nay be
permissible un ir certain circumstances where airborne concentrations ura expected to exceed exposure limits. Protection pro* ded bv air-purifying respirators is limited. Use < positive pressure air-supplied respirator if there is any pc antial for an uncontrolled release, exposure levels are not .:novn, or any other circumstances where air-purifying respirators may not provide adequate protection.
Protective Gloves: Wear impervious gloves.
Eye Protection: Use close fitting goggles.
Other Protective Equipment: Sufficient protective olothing
to minimize skin exposure. Launder contaminated clothing before reuse.
Other Precautions: Wash thoroughly with soap and water to avoid any prolonged skin contact.
# Exposure Guidelines
C)0 A 041 704 OONFTDFNTJA!
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Cea go Material Safety Data Sheet
Fag*
Applicable Exposure Limits
Calcium Oxide
PEL (OSHA) TLV (ACGIH) AEL * (Du Pont)
: 9 mg/a3, 8 Hr. TWA : 2 mg/m3, 8 Hr. TWA
: Kona Established
Anhydrite Calcium Sulfate
PEL (OSHA)
: 15 ag/m3, total dust, 8 Hr. TWA
5 mg/m3, respirable dust, 8 Hr. twa
TLV (ACGIH)
: io mg/m3 of Total Duet - containing no
asbestos and <1% free silica - 8 Hr twa
AEL * (Du Pont)
: Kona Established
Silicon Dioxide PEL (OSHA) TLV (ACGIH)
AEL * (Du Pont)
(Crystalline Silica) : Total dust, (30 mg/m3 / % si02 + 2) Respirabla dust, (10 mg/m3 / % Si02 + as 8 Hr TWA's
: 0.1 mg/m3, respirabla dust, 8 Hr. TWA Or sea: Christobalita [14464-46-1], Silica, Fused [60676-86-0], Tridymite [15468-32-2], Tripoli [1317-95-9]
: o.l mg/m3, 8 Hr. TWA, respirable dust
2
Magnesium Oxide PEL (OSHA) TLV (ACGIH) AEL * (Du Pont)
: 15 mg/mi, total dust, 8 Hr. TWA : 10 mg/m3, 8 Hr. TWA , : Kona Established
* AEL is Du Pont'a Acceptable Exposure Limit. Where governmentally imposed occupational exposure limits which are lower than the AEL are in effect, such limits shall take precedence.
PHYSICAL AMD CHEMICAL PROPERTIES
Physical Data
Solubility in Water Odor Fora Color Bulk Density (Loose)
J Insoluble
a Kona
e
Dust
: Ashen grey to white
e
Approximately
52
lb/cu
ft
STABILITY AMD REACTIVITY Chemical Stability
stable. Reacts exothermically to release heat when water is added.
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COECQOli
Cob oo Material Safety Data Sheet
(STABILITY AND REACTIVITY - Continu d)
incompatibility with other Materials
Kona reasonably foreseeable.
Polymerization
Polymerization will not occur.
Pag* c
TOXICOLOGICAL INFORMATION
Animal Data
Crystalline silica: In animal studies, lung tumors were observed in rats exposed for up to two years by inhalation to 12.4 or 51.6 mg/m3 quartz. Pulmonary fibrosis, emphysema, and lung tumors were also observed in rats exposed to quartz by intratracheal instillation.
DISPOSAL CONSIDERATIONS
Waste Disposal
Treatment, storage, transportation, and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations* Do not flush to surface water or sanitary saw r system.
TRANSPORTATION INFORMATION
Shipping Information
DOT Proper Shipping Name
: Not regulated.
ICAO/IMO
Proper Shipping Name
: Not restricted.
REGULATORY INFORMATION
U.S. Federal Regulations
OSHA HAZARD DETERMINATION This material is hazardous as defined by OSHA's Hazard Communication Standard, 29 CFR 1910*1200.
CERCLA/SUPERFUND This material is n t known to contain any ingr dl nt(s) subject to the Act.
DO A 041706 CONFTDFNTTAl.
COXCOOll
con e Material Safety Data She t
(Continued)
Telephone
Houston, TX 77252 : 713/293-5550
# Indicates updated section.
End of MSDS
Page
00 A 0417q7
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Con e Material Safety Data Sheet
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(REGULATORY INFORMATION - Continued)
SARA, TITLE III, 302/304 Thie material ie not known to contain extremely hazardous substances.
TITLE III HAZARD CLASSIFICATIONS SECTIONS 311, 312
Acute Chronic Fire Reactivity Pressure
: Yes : Yes ; No i No : No
SARA, TITLE III, 313 This material is not known to contain any chemical(s) at a leval of 1.0% or greater (0.1% for carcinogens) on the list of Toxic Chemicals and subject to release reporting requirements.
TSCA Material and/or components are listed in the TSCA Inventory of Chemical Substances (40 CFR 710).
RCRA This material, when discarded or disposed of, is not specifically listed as a hazardous waste in Federal regulations. It could become a hazardous waste if it is mixed with, or comes in contact with, a listed hazardous waste. If it is a hazardous waste, regulations at 40 CFR 262-266 and 268 may apply.
CLEAN WATER ACT This material is not known to contain any ingredient(s) subject to
the Act.
OTHER INFORMATION
RTFA, VPCA-EKXB
npca-hmis Rating Health Flammability Reactivity
:1 :0 :0
Personal Protection rating to be supplied by user depending on use conditions.
The data in this Material Safety Data Sheet relates only to the specific material designated herein and does not relate to use in, combination with any ther material r in any process.
Reap nsibility f r MSDS : MSDS Administrat rs
Address
: Con c Inc.
PO Box 2197
DO A 041708 CONFIDFNTIAl
chemists helping chemists in research & industry
aldrlch chemical co.
P.O. Box 355, Mllwaukoo, Wisconsin 53201 USA
Telephone: (414) 273-3850 TWX: (910) 262-3052 Aldrichem Ml Telex: 26 843 Aldrich Ml
FAX: (414) 273-4979
ATTN: SAFETY DIRECTOR DOW CHEMICAL CO P 0 BOX 500 LOUISIANA DIVISION PLAQUEMINE LA 70764
DATE: 01/06/68 COST * 181706 P.O. # 926981-10
MATERIAL SAFETY DATA SHEET
PAGE:
-- IDENTIFICATION ---------------------- -------------
PRODUCT # 25254-9
NAME:
iT&irp*
CAS # 50-00-0
--------- TOXICITY HAZARDS --
RTECS ft LP8925000
FORMALDEHYDE
IRRITATION DATA
SKN-HMN 150 UG/3D-I MLD
85DKA8 --tI27e77
EYE-HMN 4 PPM/5M
IAPWAR 4*79*61
EYE-HMN l PPM/6M NSE MLO
AIHAAP 44*463* 83
SKN-RBT 500 MG/24H SEV
28ZPAK --e40e72
SKN-RBT 540 MG OPEN MLO
UCOS 4/21/67
SKN-RBT 50 MG/24H MOD
TXAPA9 21*369*72
EYE-RBT 50 UG/24H SEV
28ZPAK -*40*72
EYE-RBT 750 UG SEV
AJOPAA 29*1363*46
EYE-RBT 10 MG SEV
TXAPA9 55*501*80
TOXICITY DATA
ORL-WMN LOLOZIOS MG/KG
29ZWAE -*328*68
UNR-MAN LDL0:477 MG/KG
85DCAI 2*73*70
ORL-RAT L050:800 MG/KG
JIHTAB 23*259*41
IHL-RAT LC50:590 MG/M3
GISAAA 41(61*103*76
SCU-RAT LD50:420 MG/KG
APT0A6 6*299*50
IVN-RAT LD50:87 MG/KG
AEPPAE 221*166*54
ORL-MUS LD50:42 MG/KG
NTIS AO-Al25-539
IHL-MUS LC50:400 MG/M3/2H
85GMAT -*69*82
SCU-MUS LD50:300 MG/KG
APT0A6 6*299*50
SKN-RBT LD50:270 MG/KG
UCDS 4/21/67
ORl-GPG LD50:260 MG/KG
JIHTAB 23*259*41
IHL-MAM LC50:92 MG/M3
GTPZAB 19(81,37,75
REVIEWS* STANDARDS* AND REGULATIONS
ACGIH TLV--SUSPECTED CARCINOGEN 85INA8 5*276*86
ACGIH TLV--TWA 1 PPM 85INA8 5*276*86
MSHA STANOARDtAlR-CL 2 PPM (3 MG/M3) DTLWS# 3*19*73
OSHA STANDARD-AIRSTWA 3 PPMiCL 5 PPMJPR 10 PPM/30M/8H FEREAC 39*23540,
74
NIOSH REL TO FORMALDEHYOE--AIR:LIMIT TO LOWEST FEASIBLE LEVEL MMWR**
34(1SI*17S*85
EPA GENETOJF,.PROGRAM 1986* POSITIVE: CARCINOGENICITY-MOUSE/RAT
EPA GENETOr PROGRAM 1986* POSITIVE: 0 MELANOGASTER-RECIPROCAL
TRANSLOCATION
EPA GENETOY PROGRAM 1986* POSITIVE: N CRASSA-REVERSIONS E COLI POLA
WITHOUT S9?>
EPA GENETOX PROGRAM 1986* POSITIVE: 0 MELANOGASTER SEX-LINKED LETHAL
EPA GENETOX PROGRAM 1986* POSITIVE: S CEREVISIAE GENE CONVERSION; S
C ER EVISIAE--REVERSION
EPA GENETOX PROGRAM 1986* INCONCLUSIVE: IN VITRO UDS-HUMAN FIBROBLAST
EPA TSCA CHEMICAL INVENTORY* 1986
EPA TSCA SECTION 8(E) STATUS REPORT 8EHO-1079-0314
EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE* JUNE 1987
NIOSH CURRENT INTELLIGENCE BULLETIN 34* APRIL 1981
NIOSH ANALYTICAL METHODS: SEE FORMALDEHYDE (OXAZOLIDINE)* 2502;
(CHROMOTROPIC ACID)* 3500
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Japan
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61030 B'wattH
F-47000 SiraabOwfg
10 Kanaa-MKuraeno
Ttiaphon* 102)2428750
Taiaphona (Mi 327010 Cnivooa Ku Toxyo
Talax *J302AlcHam 8
Tala* 890078 Aldrich F Telephone (03)258-0155
PAX .02)242 82 16
PAX () 74 12 83
PAX (03) 248 0157
Ontta* Kingdom Aidrtch Cnamtcai Co Ud Tht Old 8ncfcytrd Maw Road fiiiiingrtam Dorsai SP8AJL
Ttwpnoi* i0747422ii T*s 417238 Alflrch G
PAX (07474) 3779
*ti Oarman* Aiduch CnamiaGmoMA Co kg D 79?a Si*<nha>m Taiapnona i07329i47 0
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PAX i07329) 87 39
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chemists helping chemists in research & industry
aldrlch chemical co.
9 ft0. Box 355. Milwaukee, Wisconsin 53201 USA
Telephone: (414) 273-3850
TWX: (910) 262-3052 Aldrichem Ml Telex: 26 843 Aldrich Ml FAX: (414) 273-4979
HAT E R I A L S A F E_T Y 0 AT A SHEET
PAG.
CATALOG # 5254-9
NAHE:"FORMALDEHYDE* 37 WT* X SOLUTION IN WATER* A.C.S. REAGENT
NIOSH ANALYTICAL METHODS: SEE FORMALDEHYDE (GIRARD T)* 3501 NTP FOURTH ANNUAL REPORT ON CARCINOGENS* 1984 MEETS CRITERIA FOR PROPOSED OSHA MEDICAL RECORDS RULE FEREAC 47*30420*
82
ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL ENTRY IN RTECS FOR COMPLETE INFORMATI
HEALTH HAZARD DATA ACUTE EFFECTS
MAY BE FATAL IF INHALED* SWALLOWED* OR ABSORBED THROUGH SKIN. CAUSES SEVERE EYE IRRITATION. MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT. MAY CAUSE ALLERGIC RESPIRATORY AND SKIN REACTIONS* EXPOSURE CAN CAUSE: COUGHING* CHEST PAINS* DIFFICULTY IN BREATHING. PULMONARY EDEMA. EFFECTS MAY BE DELAYED. GASTROINTESTINAL DISTURBANCES CHRONIC EFFECTS CARCINOGEN. FIRST AID IN CASE OF CONTACT* IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING ANO SHOES. ASSURE ADEQUATE FLUSHING OF THE EYES BY SEPARATING THE EYELIDS WITH FINGERS* IF INHALED* REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT* GIVE OXYGEN. CALL A PHYSICIAN. DISCARD CONTAMINATED CLOTHING AND SHOES. ADDITIONAL INFORMATION WARNING: CONTAINS METHANOL. MAY BE FATAL OR CAUSE BLINDNESS IF SWALLOWED. CANNOT BE MADE NONPOISONOUS*
PHYSICAL DATA SPECIFIC GRAVITY: 1*083
------------------------ FIRE AND EXPLOSION HAZARO OATA-------------- -----------LOWER EXPLOSION LEVEL: 7.0* UPPER EXPLOSION LEVEL: 73.0* FLASH POINT: 133 F EXTINGUISHING MEOIA WATER MAY BE EFFECTIVE FOR COOLING* BUT MAY NOT EFFECT EXTINGUISHMENT. CARBON DIOXIDE* DRY CHEMICAL POWDER* ALCOHOL OR POLYMER FOAM. SPECIAL FIRE FIGHTING PROCEDURES WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH.SKIN AND EYES* COMBUSTIBLE LIQUID* USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS* UNUSUAL FIRE AND EXPLOSION HAZAROS EMITS TOXIC FUMES UNDER FIRE CONDITIONS*
Betyum Aiaonchn Chew*iii* N vV IS A BO L#mpermonil*tn 140 0 ( 8 1030 B'utitu Telephone (Q2i 242(/5Q
Telex (2302 Aich*m B FAX (02)242 B7 IB
Alpnch Chi'"'# S i r I
2? Foil* 0*1 T*eu*
F (7000 St'ispourQ
T*i*prion* t(0)327OlO T*I*1 090076 Aldr.cn F FAX (Ml 75 12 82
Telephone 1i0033)1225588-0-015i(9( FAX 103)2(8-0157
Te*lex 417238 Alprch Q0 FAX (07476) 377#
820
Fax (07329)87 39
DO A 041710 CONFTDFNTTAI
m . m chemists helping chemists in research & industry
tfflJ aldrich chemical co. P.O. Box 3SS, Milwaukee, Wisconsin 53201 USA
Telephone: (414) 273-3850 TWX: (910) 262-3052 Aldrichem Ml Telex: 26 843 Aldrich Ml
FAX: (414) 273-4979
' j/I
MATERIAL SAFETY OATA SHEET
PAGE:
CATALOG * 25254-9
NAME: FORMALOEHYOEe 37 WT. X SOLUTION IN WATER A .C S REAGENT
-- REACTIVITY OATA ---------- ------------------------
INCOMPATIBILITIES STRONG ACIDS STRONG BASES
REACTS VIOLENTLY WITH: STRONG OXIDIZING AGENTS
HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS TOXIC FUMES OF: CARBON MONOXIDE* CARBON DIOXIDE
SPILL OR LEAK PROCEDURES --
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED EVACUATE AREA. WEAR SELF-CONTAINED BREATHING APPARATUS* RUBBER BOOTS AND HEAVY RUBBER GLOVES. ABSORB ON SAND OR VERMICULITE AND PLACE IN CLOSED CONTAINERS FOR DISPOSAL.
VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE. WASTE DISPOSAL METHOD
DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.
OBSERVE ALL FEDERAL* STATE t LOCAL LAWS.
------ PRECAUTIONS TO BE TAKEN IN HANDLING ANO STORAGE ---
WEAR APPROPRIATE NIOSH/MSHA-APPROVED RESPIRATOR* CHEMICAL-RESISTANT GLOVES* SAFETY GOGGLES* OTHER PROTECTIVE CLOTHING. USE ONLY IN A CHEMICAL FUME HOOD. SAFETY SHOWER AND EYE BATH. DO NOT BREATHE VAPCR. 00 NOT GET IN EYES* ON SKIN* ON CLOTHING. AVOID PROLONGED OR REPEATEO EXPOSURE. WASH THOROUGHLY AFTER HANDLING. POISON. CARCINOGEN. IRRITANT. SENSITIZER. LACHRYMATOR. KEEP TIGHTLY CLOSEO. KEEP AWAY FROM HEAT AND OPEN FLAME.
ADDITIONAL PRECAUTIONS AND COMMENTS
ADDITIONAL INFORMATION INCOMPATIBLE WITH: ANILINE* PHENOL* ISOCYANATES* ANHYDRIDES.
THE ABOVE fNTORNATION tS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO BE ALL '`INCLUSIVE AND SHALL BE USEO ONLY AS A GUIDE. ALORICH SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM HANDLING OR FROM CONTACT WITH THE ABOVE PRODUCT. SEE REVERSE SIDE OF INVOICE OR PACKING SLIP FOR ADDITIONAL TERMS AND CONDITIONS OF SALE.
Belgium Aldrich Cham* N v *S A 8d lamdarmomiaanlag b e Bi030 Brunei!
Telephone 1021 2428750 Tela* 302AiehtmB
Fax (02)242 *2 16
France
Japan
Aidncn.Chimt* Sari AlUnch Japan
27 FoataaatTreite F-67000 Straabourg
Kyodo Bldg Shineanaa 10 Kanda-Mikuracho
Telephone lB8> 327010 Chiyoot Ku Tokyo Tfla 8*0076 Alflntn F Telephone l03l2S8-0lS5
FAX (88) 73 12 83
Fax (03) 2S8-01S7
Untied Kingdom Aldrich Chemical Co ltd Th# Old Brickyard NawRoed Gillingham Doraat SP*ajl
T**apnon4 (Q?476l 2211 T*lfii 417238 Aidrcn G
fax (07476) 377*
df*fl Germany Aldncn Cn*mi GmoH A Co KG
0 7924 $tinhaim T*tf0hon* i07329i87-0
T*t** 714838 Ai0r Q FAX (0?329i87M
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