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AR R26 - 07/0 BIODEGRADATION (BOD/COD) EST SUBSTANCE Identity: A mixture containing perfluorooctanesulfonate, which may also be referred to as PFOS, FC-95, or as a component of FC-203. (1Octanesulfonic acid) (CAS # 2795-39-3). Remarks: The 3M production lot numbers were not noted. The test sample is FC-203. Current information indicates it is a mixture of 1.34% PFOS, 35% diethylene glycol butyl ether, 37.85% water, 20% ethylene glycol, 2.66 % Sultone foamer, 3% sodium octyl sulfate, 0.1% sodium lauryl sulfate, and 0.05% tolyltriazole. The following is an abbreviated summary ofmultiple biodegradation studies on FC-203. These studies apply to a mixture with incompletely characterized concentrationsof impurities. Data does not accurately reflect the degradation potential of the fluorochemical component of the test sample. METHOD: Method: Various methods, most not noted. Type: BOD and Dichromate Reflux COD GLP: No Year completed: 1973 - 1980 Contact time: 20 days Inoculum: Seed from various sources. RESULTS Chemical Oxygen Demand (COD) range: 420,00--0 1,070,000 mg/kg Biochemical Oxygen Demand (BOD) range: 5-Day: 206,250 -- 560,000 mg/kg - 10-Day: 450,000 - 646,875 mg/kg 12-Day: 15-Day: 660,000 -- 830,000 mg/kg 426,312 -- 604,687 mg/kg 18-Day: 20-Day: 660,000 mg/kg 426,562 - 1,100,000 mg/kg Remarks: Testing was conducted on the mixture as described in the Test Substance Remarks field. The values reported apply to that mixture and not ~ the fluorochemical proportion alone. conclusions 000000000 000429 tNhoatrtelhieabmlaejocrointcyloufsitohnespcraondubcet cdeormipvoendefnrtosmatrheesreeasdtiuldyibesi.odeTghreadianbdliec.ation is PSauublm,itMtienrn:esot3aM, C5o5m1p3a3ny, Environmental Laboratory, P.O. Box 33331, St. DATA QUALITY Rmeeltiahboidliftoyl:loKwleid.misTchherainnkoicnuglu=m3i.s nSottudpyrolpaecrklsydcehsacrraicptteiroinzeadn.dTrheecotredsstoifngthe was conducted on a mixture with chemicals having varying degrees of sbiaomdpeglreadpaubriiltiytwy,aslenaodtinpgrotpoeproltyencthiaarlacmtiesriintzeerdparentdattihoen sotfutdhyelraecskusltasn.alTythiecal confirmationofthe amount of fluorochemical proportion in the solution. REFERENCES _ TSth.ePasutlu,diMeNs,weLraebcRoenqduuecsttednubmybtehres31M94C0omapnadn5y3,6E0nSviirno1n9m7e3n.tal Laboratory, OTHER Last changed: 6/28/00 000430 ASRa0ESTook -- s2om Wren PRODUCT ECOLOGICAL ASSESSMENT mgt| Tron][Ea] Ret, .ENVIR, ASES,raINnG.i4. TEE REQUEST BVEON FOR LABORATORY WORK LAB REQUESTNO. 360S ie Ruii2p ooUCT <5 (F-5919RE3QULEoSTTE-R]) [ iasomatonyyx J aRmeeq:uir2e710 7-K2h4u-n80 Phone No. _3077 AnDaolyesRte:ceived SwmgAlerar7e-29-70 PCroodjeectNo,No. Prob. e OHnoeusCSoponrnBpAinegng:_W22--A=2.42SLR=0AF~0D SDB aemcpilpetoDna,t--e: NewRSeadrpslirBkaISrDcaee F_i_DatTC0eD NeSeudeld: aJO+CE1 FAESAEPT. | vp. sn GaB. tewPpA. easEny coums ire Wax naw Sample DHaoenantsofCombustion CllG (8TU/Lb.) - ie ------------ WATER POLLUTION . oneatrr be rr 3% Solutionrr r rr rr r r rr rr r I 11 EER SO c~opr-gmyeJagd Lh abae IX|X TifI2G0E,00000| LT020,% #6050.5Urirare XlEr EBcE eeg| a| bol1y11 A Toe (elo) IN| zs xlosis|[Sead Zlces i6WC, onmmmDumanmeir - g/m [[[ x [1.04]m | rebele Z| |[srheer irFeOnCb Hohics beth GPP Detwirope Aci r7eT 2mry cfW.EOr NOTES TocVALUE BASE 1 ES 1%ToFSeionae,fGlec]den Confk RAGE | 1oeonmensdtb; of OF Aiud (S) SELALITE, To [PherohaAeis Fosks BIOASSAY Soecty Or sndMn eth r Bo r ESULTS --\ mipp [Ag i 1% JA mmm || plpall5] oiry 8$0000,5Urirare To73c Bory omer r Booi a 00 S538 000 |r _| Boplir 2[- 82gobo|] [79% 09 [I | BaD[ZoT /= 1,JT 00,po0_____N[paf1scs [ C 7ase At e warpAa idatak l) | r rr rr r hl TTcesrocramalol|e| SBertccuomsution Seraivionprosiar EE 1BE5OHCIOPYP-AYVAAHVA ARABLE1 r r-- rrr rrr r Tr T oupa rr ----r ---- 71 me-- ts EnvironmentalLaboratory OW a SPEFc-203 (eT) (F-5919,e01-1 | eisousnponer| joo res a Fla F [= 8 me] r T [97|Lerlo.so[995[790 | sus | 0.8)[ysioee| 9/4 [Je{eur |2.0 [3.95 45S|440 |4.06 [60go00l Seop00 ih cr rer Cr rrr Crrrr rr rT 1 Cr rr rr1 CT rr rT] UO: S-- BEST COPYAVA cae gated Envirur val Laboratory Mm wheat 5360S i 200Mato FBO- Coesee es 5g f= FC-20 PE [otttenreser | _s9:q, 1200 (oases LOT-1 (Dilutionfactor = 1 1undiutad) Fue Em Tm]om | Ee [ves lee ee CeTT 20T[e3395[[2s.p8o0[]6 5.5 75[|2s:e67qlLaaseliosecde)] 334300 Tos re Tae fggs -- 1 = [= SUR HE pepe Re --TTC Tea ARE rr rr hE Now: 1. 2. GSoanmopl.e= Cionoenltortrionfofsmamlp eomlhutoeed@mgDlien aBdOdOebd1o0t8s0.DBort. 3 ) i") T COPY AVAILABLE oe I fiA d \ . - 0000044333, id7 vo E8n0vDirWoonrmeknSthaeleLtab-oSraamtpolreys. : 3M Sheed 5360S p[ o aces] 00tated 20 Bo ~ cowwenes ose [hwestl : Be Fle = =m] 5s [rrr a Fc-20 -s419, [w| esoiien|__ 0.250 rose | 200 toT- Sampledead ie 20m wiOtlwahte tionfor 1 undid) [isot a a PHoeEnR]2r.o0 1[58.9032[[4L.o5e0 [[47..4750||3.:6187|Lpoiweesraedd) 1 iaeja8 lage Etre gee -- 1 - --1 | Sa bi pep-- --r1r 1 rer e SEAR GER FS rrr rr Sak Now: 1. 2 Gone. Sunpl Conmnaton of rile(mi San = mh ogofsameor oABOD bot. utdsampleaided12 80DBore. P= 0.500ddbitich muttslD alin 1 6.50 / "2i-8p. : || Fi ; rp BODY di a 0 ; it B OPY-AVAILAB 2 em Sooner vae EnvironmentalLaborstory 80DWorkSheet - Blanks, Controls, andStandards y oral MM rt oof [5300 (7% od wasloch ITET=[ww NonssadedDiktion WorseBank IN) |ow| (72s |e.90 le2 II I SoodedDition - eterBlank fopaonal) 5 DV 717 ga95 s_l8[3 es [pgs 190.9 I = l0 o35| = [8.90 [50 , 1930 Sand Controls ~AVC 1] 0.30 IE I I I 7% 1 20 er | an CFT a0 ----Tr-- Glucose -GivaieAcdStandard M |sec lo9s 1 165 A |290 gp 1330 1 | 2.9 1070 | 705 | rr 1 1 1] < AVE (207 20090 [ree[ome Tome |oe| 5 |om [et [ST=rTeo]9c laxt [odo [210 mw) PotasiumHydrogenPhatStandard options) Tinfo enirddLki - Towvo. I [| --SRSTCOPYAVAIL1 ABIE SFemE ESSS EY 5 E8m0irDoWnomrektntlhLaab-Boransntketsr,y CConte rol,wdSunderds: Shequted C3608 00 MaNe.d Zr dnt ashe [ro|om Bo waplr eaift l | tua Monod Obes WetBank NN BO- or00 st 4-0 II a = _ 7% | 89s |ges | o30 | e690 | w370 [| ea06 | | C726 | 6.90 | 810 | o.20 | `SeadedDiluion -WeerBonk optional) SNE TE Te we rm00. /3 |x95[| z84s [~ese | C7[2.90 |x95 | ods | avwa Corde SA IM Cu-go TE =3 o2 == oH" ST [EE[hE se[=] re oa ee [gn x | go |@de |2.a5 | | 2.9 |<eos | -- r1 r [r-- Rh Ts s75 "e = 7S 3 |gids| 6.50 [2. | 4 a75| 9 [Co3a[ l 5 1 |[ g.90e ]54..a 9805 |[e4l s.s0e5 ||3s5o8s |aiLaise t1210 Potwsiam Hydro PhthalesStandard optional rr r T 1"1 I |OESTCOPYAVAILARLE | | 000436 EL MM EnvrironmentelLaberetery BCDWorkSheet - Blanks, Ss E te-- ereesm-- eieeee-- sseits------im rs m bhaib 5 RCOS hned BO- 6 (Cr gtr vis hl Fnge|_t aowworam| TE = [| ow ansendod Dlbon Wo Bank NY [BZ 189s |geo | o.35 | R-y Kg) = T=e [we |a | Cree TT690 TT8c | o3s | 03 SeatedDiedon -WoterBlankfaptanil) 5 PNT 3 7/3 |gas [92.8 | Jao | wa ES ea a SondControls ~RC 78 | 20 -- |mec | 360 [== | go |@90 | cos | s.00< 1 ~~ | --rT Glucose -GlutamicAcidStandard Sp Toon. ol 2a. [omen[omeTe[me| [reer [Rr]Sm [773 1 3 [gas|a.ss|440|3.64 |3647] [31 5Tao zss| gac|ss9[336 | 340 Coo [7 [8551095| goo | 2.25 |31 | PotassiumHydrogenPhthalate Standard(optional) Too : a. ee [er| [ee | 1117 1 1 r1r |[1 [_[ T |BESTCOPYAVAI|L= ABL|E } 000437 5 en Metin ' bry Mone 8ES TT1 : Bab- Fem 60 TGren 7) | Loma sosceo Tum absliSoabcellausnerl] |oLouve RE smo mp rile iT Th 00 a0: ER Toma I | aoe: ~ ee wen | RAE aE oow Qo AKE e [oelo aai Enn ooe oaeus ATM oi U[Arn ree ellyi1t A or | -| sro Co | AILAB i] Co : : i . 000435 ro=nu roszerwe 4 ce LAB seauksr 800K -- 428W cc Fes204t Fle: Cocpots Fec203 i Water and Wastewster REQUEST FOR LABORATORY WORK Lib Reauesct. JANS TO: ENVIRONMENTAL ENGINEERING LABORATORY -- BUILDING 536N Requestor Lab Personnel nPomre BNoo.C1j1o-e0m2c)8prtob,Nneyoan2o._nCeo0(de #22/05 OSoumspilpotoDnat:e:2DFaitgegNesced: IEE HoldSampleFor Days Est. Time: He. 4 OAnwaelyRstegg2.0Sapgier = 1x1 F NS0 DatYe ComEpletNed:I 12, v | Hope: Seon (Fe203) meas]BSE,[0 | Total Hardness, mgl ssCaCO C7alcAilukmalHianridtnye,smso,l mg8/lCaSsCCOa3CO3 N-- +4 [T T TTT " 7 He reas LLTTTLT 1 TM" Alkalinity, mg/l as CaCO3 oHuste mgsS02 eeeTT 17 A IT Nitrate, mg/l as NOs IES EN iEN I Chioride, mg/l as CI Silica, mgh as 5102 rrrrr rrr Tuoride, mg/l as TOorttahloPPhhoossphpahtaet,e,mmgtg/l 5as7P_ rT TTT I rT -- --11 THoetxalCChhrroommiiuumm,,mmgy/lsasCCrr H EEt EYI ES ToetraolcCyyaanndiede,,mgm/aT/aisaCs CVN. H rH rr TMraonng,amnge/s1ea,s Fmole5M 25-DAY |I [S37 03 [YesI|756--peTaT1767871 35]| Surfactant, mg/l as LAS Phenol, mg/l "DAY [Teo a7] | v26,38 [//9,600 [7795750| 0-DAY | 1096,@5| [565900 | /53)33]17/9665] | BOD, mg/t 1 [300 cod) $20"16 686., 000[2 "T'5/5 56250 | | COD, moi (ShoriCong Diltel TotalSuspended Solids, [c+ 998 cool #20,ool"#324 Clr Ho ond | rrr rr TVuorbliadtitiyl,e SumsgpendSeidcaSolids, mg/l HF 1 Total Solids,mg TCootnadlucVtoilvaittiyl,e mSohloidrs, mg/l rrr 17 H I --H I Be ESTebH bvaom H lI Total Bacteria, No./100 ml Toul Coliform, No/100 ml [=eo orY AVAILAB|LE| J cfeeeeee le emerm1 Fecal Coliform, No./100mi FAemcmalonSitraepNtiovcoogoeuns,,mNgo.//a1s00 ml rrr TTI H--H--HT --F T --I H KOjedmidah! NGreime,mtg rogen, mg/as lN [1I TrrT 11 Doe rr (Comments TTT T7717 ~ AB,ED CE i fs TTT 000439 mami . 5-DhY af TR RX I 'o == ENVIRONMENTAL ENGINEERING LAB Dvialtutei:o_nW3a/t7er/s:7232 BOD WORKSHEET seed: __20mf 5. sake: 2 26,264 7 BDRBS maeig HV 2 [Tor FRU |83 |geeboran| AY Vn | samp[Lg[Ji xmas] T eep e esa 73% [ylFed3eZ|&27 [w | =| tr Us of wie [96| ==sma0l C5 DT e 1r oT 8T % xteol' T2es --7 ----6 frJaeneko|1Fa2 z 19g7 oTeSetaso25n0 l | -Late T 33""owlae d [eSee[aol 2 peSTCOVARLARIE. 7 [1 3 T rT r ] r 1 r1 1 1 =: gry 1] _. ee Bar Cv. me re I mvs 0-DAY ENVIRONMENTAL ENGINEERING LAB BOD WORK SHEET Banke: 26.0, 8 23.7 6.x R22 bee947/ 2= 3 sec __200. nme 2g /42 LY AZ 1.2 1Baowv [55[77 |/25ezm) Ye o3 Ixy[97 ljoglee| 7A 132 1 amo IJ]Zo |estos | 1 cays T4d [J0 |zdx0ln 7 | Ze] Weao[YR[J [<vsgovol] 0 33 tw1 ee | IO [8 |vsoem] r rr 1 11 3 lg RaJ Gehl]9 | 13 liosomn| 5 [ feseece [31 8 | 9. Romeo] 4B [.@ T Geo |Zo ['=/2 |/<35 0d 59 V1 e C75127 1733549) 1 =1 TT 7 | Skdgu$w 5e |7c7i|e/9l 7s] 000 25 | 2b1 "gam |22[59 og dsoW bk [| =a TCT9 [cedsi [Tree rr rr Tr rr rT [ | rr er Ta rr TT] = r | r - rrr pees 1 TT im rom sosrrma 7S Dy oy vmavann, poncana we aril3242 BOD WORK SHEET Seed: S0mf mone:] 3.3 Lhd 2 6.9,067 wave. b7, J IL Teeod |oF[73 [Zao] / ps ---- eden Lod 1 42 lorioo All AE BT 1 50600 [3 | S2 [oofam| TT Swe od bo [06875] 733 rr | SIChzepI|r =5.9 |2T |tonmd| 37 1 137 1 BT33 50[79 300] 7G <kbooo[vs[J.0 [<a BY Sate Se Then 7s Lf IRR SK; fame || 519. 17.568 000] [= Zweo |gam[507 10 750on --/39 v1 e IE 701c.; [837%00| r=r Tr //9 Z [ | FA T TE eleh | |5 3&28J [[7333a [[77J0r o5d0o0so0]| | 22 71 Hoco| T)olb. to |'e/tisn| ----t----F--T1-- I beerrer. rrr r rr r T rr rr mr rr r T - rT rr r T rr 1 [ovo , ips sane: Ee er 4s Jo xDy PRA ERRL) Be TR . \b BOD WORK SHEET Seed: 2. 7 45, FC) 23.2 Ld sweCo..l 12 A Ve | Iwo |3-135 [season| 3% | ZIX3%h [57 FF 7 enmeo] F / sa al wsTPR L6TI s oTtbmar] s] 3 S tr l ome T,o7 [77e L[Zeostdom)] AT SE | Fox[2.9 3 V<soAom| <9 v1 e1 1= 70y159 r 10230] [9 | ITPlex |Hx |7.3 | Pum bKLoshT | 1 3Z2u 3b%CB0ieegeonlT [ ||3 ZdNC 105.E 97 S TJooouruiedT sososso]ol\ ----r--t--+--F rT > -- r ------Fr --T1-- _ r r rr r r > | r 1 r | [T r oc T o