Document 93d936m5KK49JxJOwzvgJZJre
^Sl4ubthjecJtuctdoonicfPiidroe*Kt TIALv: e Order
No.
al Distric SI-1145
Court
PPG Industries, Inc. Chemical Division - U. S. Lake Charles, Louisiana
CONFIDENTIAL: Subject to Protective Order Of 14th Judicial District Court
LR-2135
May 29, 1981
BAILEY, T A HANSON, D B
The Reliability Study of the Lake Charles Plant "B-ll" Tri-Ethane Unit - MC Section CONFIDENTIAL
Distribution G. C. Strickler/R. E. Eakin (Abstract only) T. R. E. Baker/J. H. Morgan 2. R. P. Lyneh/T. G. Taylor 3. J. E. Fike 4. R. E. Sanders 5. L. W. Carter
6. D. K. Pearson 7. Authors ___ 8. C. R. West - G. O.
Technical Files (Title Page Only)
Key Wards MC Toxic Release Reliability Study Chlorine Vcporizer TOXIDISP Proof-Testing HO DCE Chlorine Fire Explosion Reactor
SL 011752
TABLE OF CONTENTS
Abstract
Introduction
CONFIDENTIAL: Subject to Protective Order
Of 14th Judicial District Court
Discussion
No. 91-1145
Results
Recommendations
Table I - Toxic Gas Hazard Classification
Ttile II - Hazard Summary For MC Reactor
Table III - Hazard Summary For DCE Recycle Still
Table IV - Hazard Summary For HQ System
V - MC Reactor & L.P. HCI System Hazard Summary
VI - Instruments To Be Proof Tested
Appendix
Fault Trees
Fault Tree Hazard Calculations
Release Probability Calculations
Fire & Explosion Probability Calculations
TOXIDISP Computer Printouts
Page 1 * 2 3 4 5 6 7
.8 10 11 12 13 32 135 156 158
LR-2135 5/29/81
SL 011753
LR-2135 May 29, 1981
ABSTRACT
A detailed Reliability Study (Level III) was made on the MC Section of the Tri-Ethane II Unit Including the HQ System. Fault trees were drawn and quantified for the potentially hazardous systems to determine the hazard frequencies and what effect proof-testing would have on reducing these frequencies. The hazards, which include the release of CI2/ DCE, and HQ, were entered into IQ's computer program NEW TOX1DISP to determine the sev rity of each release along with the possibility of explosion. While all releases were found to be potentially dangerous in regard to toxicity none of the releases posed a problem of explosion. However proof-testing reduced the frequency on any such occurrence to an acceptable level. Therefore with the proposed proof-testing schedule the MC Section and the HQ System of the Tri-Ethane II Unit are considered safe from a relidsility standpoint.
CONFIDENTIAL:
of l4?hC?
Protective Order
r -Mth Judicial District Court
No>s 91-1145
SL 011754
INTRODUCTION
COFlE^^ve Order 5ub^Ct to P^C D, istrict court
No- 91 ll^*5
LR-2135/2
SL 011755
Ad tailed Reliability Study (level III) was made on the MC Section of the Tri-Ethane II Unit including the HCI System cs part of the continuing effort to study all of the units in Plant "B-l" and "B-ll". This report will complete the Tri-Ethane II Unit with OHC-II to be studied next.
DISCUSSION
The P & I drawing and operations manual for the MC Section were studied to develop a working knowledge of the operation of this section of Tri-Ethane II. Cause-consequence sheets were developed for every piece of equipment in the MC Section including the HCI System. These sheets were reviewed with an operations representative for their accuracy. These sheets and their review indicated the areas of potential hazard. These areas included (T) Chlorine Vaporizer, (2) MC Reactor, (3) DCE Recycle Still, (4) MC Product Still, (5) HCI System, and (6) Stabilizer and Storage Area. Fault trees were developed for these areas and a detailed analysis was performed. The remainder of the system was considered to be studied sufficiently by the cause-consequence sheets. System integrity was assumed in drawing the fault trees. This means no pipe leaks, pump leaks, sanple point leaks or failures due to corrosion were included in fault tree derivation.
The fault trees were quantified using data from ICI's iqanual of failure rates by D. W. Heckle along with information gathered from previous studies, operations experience and other published sources. Some of the failure rate data obtained was modified to fit the conditions applicable to the MC Section and HCI System.
The hazards or top events developed in the fault trees for the MC Section and HCI System are the release of CI2, DCE, or HCI. This can result from either an SRV or RD release r a vessel failure. The frequency of occurrence (occasions/year) and the severity of these hazards was calculated with the exception of chlorine release from the vaporizer which is being studied by Process Engineering in confunction with a consulting firm. The quantified hazards included releases from the MC Reactor, DCE Recycle Still and the HC System. Releases from the MC Product Still and the Stabilizer and Storage Tanks were not quantified because either the occurrence was so seldom as with the stabilizer tank rupture or the material released was not sufficiently hazardous as in the case of a release from the MC Product Still. It should be noted that the stabilizers are potential hazards as ail of them are flammable and Dioxolane will form explosive peroxides on contact with air. It is the proper proof-testing of the breather valves on top of each stabilizer storage tank and the dependability of the N2 system that enables this study to define this area as essentially non-hazardous.
Th quantities of material (CI2, HQ or DCE) reiecsed from the MC Reactor, DCE Recycle Still and the HCI System were calculated and entered into ICI's computer progran, NEW TOXIDI5P to determin the severity ond cat gory classification (0, I, II, III) of each rel ase (See Tabl I). Th occasions per year of each release and their subsequ nt categories for both situations, with and without proof-testing, are presented in Tables II, III, and IV. The summation of these hazards is presented in Table V.
CONFIDENTIAL: Subject to Protective Orde
Of 14th Judicial District Court No. 91-1145
LR-2135/3
Any release of DCE was also entered into ICPs computer progran NEW TOXIDISP to determine if these releases could cause a vapor cloud explosion. None of the DCE releases fit this criteria.
The Loss Prevention Jobs list was reviewed and pending jobs in the MC Section of the Tri-Ethane II Unit were studied. No fault trees were drawn but some calculations were mad . The jobs studied were: LPJ-363 Can N2 System be Contaminated at Stabilizer Pumps?, LPJ-366 Are Motor Shutdown Alarms Needed on Stabilizer Pumps?, and LPJ-368 Are Level Alarms Needed on Sterilizer Tanks?
The pump curves were studied for the stdsilizer pumps to evaluate LPJ-363. Neither the NRE pump or the other two pumps for the rest of the stabilizers Is able to produce enough pressure to overcome the N2 header pressure. Therefore it would take a low N2 pressure along with a valving error to contaminate the N2 system with sterilizers.
LPJ-366 was discussed with operations and the major problem seems to be that the Smith metering valves do not close all the way thus the pump does not trip and excess stabilizers are pumped into the MC. A relidrility problem would be posed if the Smith valve closed completely but did not trip the pump thus deadheading the pump. This could cause the pump to overheat and possibly cause a leak of flammable liquids. Motor alarms alone would not solve this problem since there would also need to be some indication of valve position. The Smith valves in service seem to be adequate to prevent this type of hazardous occurrence.
Level alarms on the stabilizer tanks mentioned in LPJ-368 would require excessive prooftesting to maintain them in a more reliable state than the present system of the operators monitoring tank levels.
RESULTS
The release and hazard frequencies of the MC Reactor are presented in Table il. This shows that yearly proof-testing reduces the hazards due to an SRV or rupture disc release by a factor of 10 and due to a vessel failure by a factor of 400 bringing the total hazard reduction factor gained by proof-testing once a year to about 20. Proof-testing every 6 months further reduces the hazard from an SRV release by a factor of 40 and from a rupture disc release by a factor of 20. The reduction factor of the hazard associated with vessel failure is over 2,000 bringing the total hazard reduction factor due to proof-testing every 6 months to about 60.
Table III summarizes the release and hazard frequencies of the DCE Recycle Still. Yearly proof-testing reduce these frequencies by almost a third for hazards associated with rupture disc releases and vessel failures. Increasing the proof-test frequency to every 6 months gives only a slightly greater reduction than that gained with yearly proof-testing.
SL 01)756
CONFIDENTIAL: Subject to Protective Order q 14th Judicial District Court
No. 91-1145
LR-2135/4
The HC! System's releases and hazard frequencies are shown in Table IV. Yearly prooftesting does very little to Improve the reliability of the system with the frequencies being nearly equal to those achieved with no proof-testing. These frequencies are reduced by about a factor of 10 for ail hazards associated with the HCI System when the system is proof-tested every 6 months.
Table V which combines ail of the hazard frequencies encountered in the MC Section and HC1 System shows that without proof-testing a Category III release will occur about every 7 years. Yearly proof-testing will reduce this frequency to about once every 12 years while proof-testing every 6 months further reduces this frequency to once every 100 years.
RECOMMENDATIONS
The existing instruments are sufficient to make the MC Section and HCI System of the TriEthane II Unit very reliable. However this equipment must be regularly tested and main tained. This study recommends that the instruments listed in Table VI be proof-tested at th interval specified in the table.
The Loss Prevention Jobs
LPJ-363 Can N2 System be Contaminated at Stabilizer Pumps? LPJ-366 Are Motor Shutdown Alarms Needed on Stabilizer Pumps? LPJ-368 Are Level Alarms needes on stabilizer Tanks?
were listed in the original reliability overview as jobs worthy of further study but unresolved. The hazards associated with the three [obs listed above are of such a nature that any effort to reduce them through the previously mentioned measures would not be cost effective. This study se s no problem in deleting these [obs from the Loss Prevention Job list.
Approved
Date
Date
SL 0U757
TABLE I TOXIC GAS HAZARD CLASSIFICATIONS
LR-2135/5
Toxic gas emission hazard calculations were made using the I.C.I. prepared computer program TOXIDISP to determine the probability for obtaining various hazard categories at the plant boundary based on multiple conditions such as release rates, location, weather conditions, etc.
Hazard Gass 0 I II
III
Definition
No nuisance to the public at the plant boundary.
May be smelled and thereby cause a nuisance to the public at the plant boundary - unlikely to cause alarm.
May cause some degree of distress to people, or damage to vegetation at the plant boundary which would cause a nuisance and which could lead to claims for compensation.
Could be dangerous or distressing to personal safety, or could be possible risk of life at the plant boundary.
CONFIDENTIAL: Subject to Protective Order
Of 14th Judicial District Court
No. 9i-ll45
SL 011758
TABLE II HAZARD SUMMARY FOR MC REACTOR
Hazard
Total Occ/Year
la. SRV Release as is
.0357
b. SRV Release - 1 year Proof-Test
.00323
c. SRV Ret ase - 6 month Proof-Test .0009
2a. RD Releases - as is b. RD Rel ases - 1 year Proof-Test c. RD Releases - 6 month Proof-Test
.0019 .00017 .0001
3a. Vessel Failure - as is
b. Vessel Failure 1 year Proof-Test
c. Vessel Failure 6 month Pioof-Test
!
a
Total - as is
b. Total - 1 year Proof-Test
c. Total - 6 month Proof-Test
.0292 6.758 x t0"5
11.1719 x 10~5
.0668 ,0034 .0010
______ Toxic Gas Releases Occasions/Year 0 1 II III
1.07 x 10"5
.0006
.0192
.0159
9.69 x 10"7
5.33 x I0"5
1.74 x 10~3
1.434 x 10'3
2.7 x !0"7
1.49 x 10"5
4.85 x 10"5
3.85 x 10"5
9.5 x 10"7 8.5 x 10"7 5.8 x 10"8
0 0
0
1.165 x 10'5 1.819 x 10"6 3.2 x I0"7
8.6 x 10`5 9.67 x 10"6 4.5 x 10"6
1.08 x 10"3 9.67 x 10"5 5.69 x 10"5
8.76 x 10"6 2.027 x 10"8
6.83 x 10'4 1.581 x 10-6
3.516 x 10"9 2.742 x 10-7
6.95 x 10"4 6.102 x 10'5 1.94 x 10"5
2.096 x 10~2 1.838 x 10"3 5.422 x 10"4
7.3 x 10`A4 -5
6.45 x 10 3
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ST %5 6.598 x 10 Jr & 2 *
UT nCA* fHF- s K H. ** 1.144 x 10 3 o
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4.513 x 10
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(0 '
1.564 x 10~3
4.499 x 10-4
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SL 01)759
Hazard la. RD Releases as is b. RD Releases
1 year Proof-Test c. RD Releases
6 m nth Proof-Test
2a. Vessel Failure as is b. Vessel Failure
1 year Proof-Test c. Vessel Failure
6 month Proof-Test
3a. Total as is b. Total 1 year Proof-Test c. Total 6 month Proof-Test
SL 011760
TABLE III HAZARD SUMMARY FOR DCE RECYCLE STILL
Total Occ/Year
.15838
.10989
______________________ Toxic Gas Releases Occasions/Year 0 1 II
.0568
.0435
.0415
.0523
.0321
.0233
III .0166 .0022
.10609
.0515
.0311
.0221
.0014
5.0 x 10-8 1.5 x 10" U 2.75 x 10-8 8.25 x 10"12
1.114 x 10"8 6.13 x 10`9
2.066 x 10"8 1.14 x 10"8
1.818 x 10`8 1.0018 x 10"8
2.655 x 10"8 7.965 x 10-12
5.918 x 10"9
1.0968 x 10"8
9.656 x 10"9
.15838 . 10989
.10609
.0568 .0523
.0515
.0435 .0321
.0311
.0415 .0233
.0221
.0166 .0022
.0014
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LR-2135/7
SL 011761
Hazard
la. HCI Compressor Damage - as Is
b. HCI Compressor Damage 1 year Proof-Test
c. HCI Compressor Damage 1 year Proof-Test except for compressor shutdown (6 month)
d. HCI Compressor Damage 6 month Proof-Test
TABLE IV HAZARD SUMMARY FOR HCI SYSTEM
Total Occ/Year
.0454
.0446
0
.0045 .0044
Toxic Gas Releases Occasions/Year
1 II
.0097
.0094
.0095
.0093
.0032
.0003
.0007
.0007
.0031
.0003
.0007
.0006
2a. L.P. Accumulator SRV Release as is
b. L.P. Accumulator SRV Release 1 y ar Proof-Test
c. L.P. Accumulator SRV Release 6 month Proof-Test
.1079 .1018
.0111
.0019 .0019 .00024
.0173 .0165 .0018
.0266 ,0247 .0027
III
.0218
.0215 .0015
.0015 .0621
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c. L.P. Accumulator Vessel Failure - .0006 6 month Proof-T st
1.195 x 10"3 .00125
1.32 x 10"4
9.212 x 10"4 1.674 x 10-3
.00092
.00171
1.03 x 10-4
1.889 x 10"4
1.66 x 10'3 .00152
1.7 x 10"4
ip--a rio
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b. Total - 1 year Proof-Test c. Total - 6 month Proof-Test
TABLE IVJCont'd.) HAZARD SUMMARY FOR HCI SYSTEM
Total Occ/Year
.1590
.1520
.0146
0 .0076 .00755 .0007
Toxic Gas Releases Occasions/Year 1 II
.0280
.0377
.02692
.03571
.0026
.0032
III .0656 .08072 .0081
LR-213 5 / 9
SL 011762
LR-2135/10
TABLE V TRI-ETHANE II UNIT MC REACTOR AND L.P. HC1 SYSTEM HAZARD SUMMARY
Condition
Present Equipment and Procedures
Toxic Gas Re looses Occasions/Year
o i n nr
.0644 (15.53)*
.0722 03.85)*
.1002 (9.98)
.1473 (6.79)*
6 month Proof-Testing of .0522
Existing Equipment
(19.16)*
.0337 (29.66)*
.0258 (38.70)*
.0099 (100.5)*
1 Year Proof-Testing of .05985
Existing Equipment
(16.71)*
.05908 (16.93)*
. 06085 (16.43)*
. 08448 (11.84)*
*Years Per Occasion.
. o
to
SL 011763
CONFIDENTIAL: rtf to Protect j ve Ordar Of 14th JMBfcfiM
No. 91-1145 INSTRUMENTS TO BE PROOF-TESTED
LR-2135/11
CI2 Vaporizer Vaporizer (butler Temp. Alarm TR-309, 303 CI2 Surge Drum Inlet Temp. Alarm TR-311 02 Surge Drum Inlet Temp. Alarm (Shutdown) TR-3111 2 Surge Drum Bottom Temp. Alarm TRR-313 CI2 Surge Drum Bottom Temp. Alarm (Shutdown) TR-3130 CI2 Shutdown System (Low CI2 Temp.) SDS-3 CI2 Surge Drum Outlet Temp. Alarm UJR-321
AIBN Feed System AIBN Feed Pump Shutdown Alarm UJR-317 AIBN Flow Alarm FR-324 AIBN Feed Pump (Spare Used Periodically) AIBN Feed Tank Level Indicator and Alarm U-308 - 310
MC Reactor MC Reactor Overpressure Control Valve PCV-360 MC Reactor Overpressure Alarm PIC-360 MC Reactor High Pressure Alarm PR-334 MC Reactor Anti-Back Flow Valve PV-358 MC Reactor Temp. Alarms UJR-329, 331, 327, 328 MC Reactor Feed Pump Shutdown Alarm UJR-291 MC Reactor Level Alarm LRC-332 MC Reactor Backup Level Alarm UJR-333
DCE Recycle Still Condenser Fans Shutdown Alarms UJR-391, 393, 387, 389, 383, 385 DCE Recycle Still Pressure Alarm PIC-394 DCE Reflux Pump S/D Alarm UJR-397 DCE Reflux Tank Level Alarm LR-386 High Vent Flow Alarm FR-392
HC1 System L.P. HCI Vent Condensate Pump Shutdown Alarm UJR-451 L.P. HQ Accumulator Level Alarm LlC-442 HCI Compressor Shutdown (High Level L.P. HCI All) LSH-4550 H.P. HCI Accumulator Level Alarm UJR-441, 447 HCI Compr. Suction Press. Control Valve to Emergency Scrubber PV-448
MC Product Still Product Still Condenser Fan Shutdown Alarms UJR-413, 415 Product Still Pressure Alarm UJR-419
Stabilizer System Product Storage V nt Absorber Pressure Control Valve PCV-2950
Interval 6 months
II II
II II II II
6 months 11
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1 year II
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1 1
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1 year
SL 011764
LR-2135/12 CONFIDENTIAL Subject to Protective COrder Of 1144tthh Judicial Dis.-i.-Ci ;; o u i!-?APPENDIX
SL 011765
SL 011766
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CONFIDENTIAL: Subject to Protectee order
Court of 14th Judicial District
NO. 91-U45
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SL 011910
LR-2135/158
4 a;
^./OvA'.L'o. r, ::,..;
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COMPONENT
QUANTITY LB /HR
HrU+1CL^L^.
DCS TRIETHANE TCE MIXTURE
53485.00
.00
60316.00` 45654.00
7165.00 166620.00
FLOW < RM3/HR) - 26976.7
TEMP ' *C ,
M0L.U7 3F.HT
J/K5.C
121.00 121.00
121.00 121.00
121.00 121.00
36.47 70.91
98.97 133*42 133.42 67.41
786 * 80 434.30
916*10 SOI.50 773.90 337.29
XU/tt
XV/V
32.10
.00
36.20' 27.40
4.30
100.00
J7t OO . 00
- -24-. 6513.84 2.17
100.00
"H .
WHAT NEXT? CDM02
EXIT VELOCITY- (M/S) = 253.337
APPPft*.
i nn . a y enurr tin nr-Tv___________________________
1.1 2.1
3.1 4.1 5.3
6.1
1.2 2.2
3.2 4.2 5.4
6.2
1.3 2.3
0** *0^
4.3
6.3
2.4 3*4 4.4
3.5 4.5
3.6 4.6
CAT. PROB(X) CUM.PROB(X) LIMITING CGNC(PPM)
3 37 .104 37 .104
80.00
------ 6rQ-r$m---------- S3-i-6*06-------------------------S-3-r-AQ-----------------------_______------- .
1 2.362 99.967
3.00
0
.033
100.000
.00
FLOW 26976.7 DURN 1 MC-REACTOR-RELEASE FROM RO FROPUGRION
-- --------____
SL 011911
U-2135/159
' WHAT NEXT? MIXG2
QUANTITY FOR: HCL? 71752
BCE? 50316* TRlETHAffE?^ 6X248 ----- TCET 96IS-------------------
... . ** l
; V' ` >'Sr.rC1 ` : iiS^
,-,y, v *
" - ' '
; :-------- WHAT NEXT? SQH02
.4
EXIT VELOCITY <H/g? ~ 254.5^3------APPROX* 101.3 Z SONIC VELOCTTYV
i4 4
1.1 1.2 1.3
2.1
2.2
2.3
2.4 ^4
--r |--
'* 4.1 4.2 4.3 4.4 4.5 4.8 *'. Zi *3 5.4 8.3
CAT. PROB(.%) CUM.PROBX/:) LIMITING CONC(PPM)
-3----------- M . 109----------- 44*403--------------------- 8fr.OO--------------------------------
2 53*91.0 98.319
22.00
1
1.649
99.967
5.00
-0------------- .,.033--------- 100.009------------------------- rOO-------------------------------
FLOW 36190.1
BURN 1------------------------------------------------------------------------- *---------------------------
MC REACTOR RELEASE FROM RD PRODUCRION
5*V #*At
Of
SL 011912
WARMING - EMISSION IS A BURST. CALCULATED CONCENTRATIONS
C AND PROBABILITIES ARE WRONG SEEK ADVICE FROM PROGRAM CONTACT.
91
4
*
7 ft 1
*
11
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11
131
N 14
=- t: it iff
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5.3 3.4 ____ 6.^1___ A.?
4.3 4.4 4.5 A.7__ - -:
4.6 '
CAT. PROB (JJ) CUM.PROB<X) LIMITING CONC(PFM)
. 3_______27.6A9_______ 77.AA9_____________1
__________________
2
33.734
63.403
25*74
2 . 27.384 .. ;;..?a.7S7:^ ..
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**
5.00
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FLOW 91531.3 nURN 0.1 A3 HC REACTOR RELEASE RD HCL ONLY
WHAT NEXT? NEW22
OLD VALUE FOR 22 STACK DIAM <M> WAS 0.4 WFW- VAr UF" .707?
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LR-2135/161
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SL 011914
34
4 4T ill
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COMPONENT
QUANTITY V/V
TEMP *C
MQL.UT SP. HT . J/KG.C
, HCL MIXTURE
. 100*00 ,;v.,, 121.00 * S-&.47 7B6.30
100.00
T21.G0
36.47 TSA.SO.
FLOW (RM3/HR)=21823
.. ,,;v > . - * ;w<- .**>.' * *
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WHAT NEXT? C0M02
.--
11 13
0'* 1$ 14
.
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EXIT VELOCITY (M/S) * 251.343 APPROX . 73.-4. Z- SOKIC VELOCITY .
1.1 1.2 1.3 M M 7.X 7.4
3*1 3*2 3*3 3*4 3.5 3.6
4.1 4*2 4.3 4.4 4.5 4.6
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1 139 m 133
3 173
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440 804 970
' ' TM ;. 'vT* i
3 1083
9 1726 10 1367 11. 107?
12 841
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4.57
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BURN 1*17 MC REACTOR RELEASE
^ WHAT NEXT? END
USED 302.S3 UNITS. ______ gnri m rnr Tnn
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LR-2135/765
.
COMPONENT
QUANTITY V/U
TEMP *C
HCL DCE .. TRIETKAftE TCE MIXTURE
37.30 24.70 13. 90
2.10 100.00
.121.00 1.21.00 121.00 121.00 121.00
FLOW (RM3/HR) = 21825
MQL.UT 'sp.'ht' J/KG.C
36.47 93.97 133.42
133 * 42 67.42
736.30 736.30 301 * 60
773*90 790.54
-
xu/u
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4.16 100.00
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MC REACTOR RELEASE FEDH RD r'RGDUCi
SL 011918
C LR-2T35/166
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7<Y.TnyT-rt rt v
______;______
14 21.LOCATION! METCHARL
BOUNDARY DISTANCES(M>I
14 _L 13.9
17 2 153
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SL 011920
LR-2T35/168
v/V
HCL DCS TRIETHANE MIXTURE
5.14 94.03
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FLOW (RMS/HR) = 42340.7
it.
72.20 '72.20
72.20 72.20
36.47 93.97 133.42 96.04
J / UIN . w
7S6.30 344.96 752.36 342.79
14 . n7 i*"1
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100.00
5*14
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`.........................................-
: r,i . .--------------------------------------------------------------------------------------------------------------------------------------------------------------------------------------
. LE NAME' HC5TUDT_Y
1
W r A T NEXT? CGH02
E'-`! IT VELOCITY (K/S> = 196.012
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3 173 4 193 w 6 304 7 970
9 1726 10 1367
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SRV
RELEASE
12 341 *1^J ^/ 0* 3i---
13 493 1* 6^ 4j 3*1^ vIDn ljO^On -^-X" 3" T1 H* LIt\ U* t ^1 AM.<M) i^i -t juM;Lf 1i'i.:fvXw. -* hi! (M) -Wr UH3 ,",M 1 t \ R H 3 / H R )
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SL 011923
PCD
LR-2I35/17I
4 t5 JT
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!! i
19.TITLEI LP'HCL ACCUMULATOR
' 20.TOXIC: HCL, - > 21.location: metcharl BOUNDARY DISTANCES(M) *.
-AO
.1 139
2
" ..3
-153
,."
178 - "--T
.
.
...
: ..................;*
'
SRV
RELEA3E-HP
'
ACC
LEVEL
LOU
5 440 6 304
7 970 3 1083 ? 1726
10 1367 11 1079 12 341
13 763 14 632 13 493
16 431
X/ j ,"n 1C
4. ~T -ti
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24
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32 SHALL TABLE WTHF; 0
33 3 Li F. r A C E F!' N E 3 3 ( M ) 0*1
34 ISur'LETH wGNC(F'PM) 0
94 EFFLUX ANGLE (DEG) 97 0\ *
"tl AnBISWT THr
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t
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BURN 10 LP HCL ACCUMULATOR SRV RELEASE-HP ACC LEVEL LOU
UHAT NEXT?
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END
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SL 011925
c 19. title: lp hcl accumulator vessel failure 20. toxic: hcl
21.location; metcharl
BOUNDARY DISTANCES (M) *.
LR-2135/173
"7--------- TTTT 8 1083 9 172&
TSST 1079
341 uf
To 43T 17 143
IS 133
2l s rauk diah (h) *^a oTim* *w-*iI\. n* i \/ Un ./
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SHALL TABLE WTHR. y_
1 o5 3u" r hlm r\ tttaaui) 0.1
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m, >
ro
AnoIeNi i cfip (so AMBIENT PRESS(BAR)
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SL 011926
V
f
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7
f
11 9"IT
ii *~f'u*
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t* If Czmzc
i?.title: lp hcl accumulator H0ATGNIST? HCL
21location: metcharl
BOUNDARY DISTANCES<M)I
1. 139
, 2 133
3 178
4 193
3 440
6 S04
"
7
a
970 ^ .*',
\ '** ,
1083 .
.
'-'J\ - - r> >1 **- - -i--.
. ,,,. 1
* ,9 172a
10 136/
11 1079
12 841
13 765
14 632
15 493
X w X
17 143
IS 133 22 STACK DIAM (M; 23 STACK HT <M>
0*053 6.1
24 BUILDING HT (M)
0
*i 2 GAS R A 7 E ( S M 3 / H R ) 12u n + 14
VESSEL FAILURE DUE TO HP
,, -
Subject tv I oE 14t"
ACC LOW LEVEL LR-2135/174
-. 1
t i ve or Apr ^ p^gtriCL ("JU
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j 1 SHALL TABLE UIHIi
32 wc
S^:unrA,rLi~ Li*-iu^wTill ABr\iLiE;*i<tAawXt/h\ r/i".\ .;
0 0Ti
^ : j*+ isurunn CL!ixC\rr;*u A
j 94 ErrLuX ANGLE (DEG) ?0a
16 AL ArtBlcHi 7EHF i'-KC) 15
96 AMBIENT PRESS(BAR)
SX
f
14
V
4i
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^=59 MIXTURE OF 2 TOXICS: SI i * ^
V
ii\
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X *O
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SL 011927
*I 6 t 7 0 II !7 ,3I
*~ul
,s____
14 if *R 7i
(
!!
13
L
CAT. 3 2
i 0
PRQBCC) 43 * 073 20.311 21.315 9.301
CUM.PRQB(2)
48 * 073 o3* 334 90.199 100.000
LIMITING CONC (PPM)
60.30 18.24
5.07 00
FLOW 1234*14, " - `
'
BURN 10 .. ...
/S-^v:.;.
LP HCL"Accumulator vessel failure Bufc to HP ACC LOW LEVEL
LR-2135/175 :
WHfi i NtXlY ,LWU'
~
uatu iaa.i/ UNiib
end of cmf run
READY
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02233.74 CRU
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SL 011928