Document 936z2wyNmMomnGV8b7LEZLqOe

Emergency Number (800)457-2022 or (415)233-3737 Chevron Material Safety Data Sheet GULFTENE 10 CC41000400 Page l of 6 This Material Safety Data Sheet contains environmental, health and toxicology information for your employees. Please make sure this information is given to them. It also contains information to help you meet community right-to-know/emergency response reporting requirements under SARA Title ill and many other lavs. if you resell this product, this MSDS must be given to the buyer or the information incorporated in your MSDS. Discard any previous edition of this MSDS. ,This revision updates Sections 1 5, 7, 9, 10 and the Product Information Number. 1. PRODUCT IDENTIFICATION GULFTENE 10 DANGER 1 - HARMFUL OR FATAL IF SHALLOWED - CAN ENTER LUNGS AND CAUSE DAMAGE - COMBUSTIBLE SYNONYM: GULF Decene-1 (CIO) PRODUCT NUMBER(S) : CC41000400 CC41000600 PRODUCT INFORMATION: (713)754-4260 CC41006500 CC41006700 SAL 000009720 Revision Number: 5 Revision Date: 08/28/90 . MSDS Number: PE0018 NDA - No Data Available NA - Not Applicable Prepared According to the OSHA Hazard Communication Standard (29 CFR 1910.1200) by the Chevron Environmental Health Center, inc., F.O. Box 4054, Richmond, CA 94804. X-OQS051 IOG-e 6S360 GULFTKNX 10 Page 2 of 6 2. FIRST AID - EMERGENCY NUMBER (800)457-2022 OR (4X5)233-3737 EYE CONTACT: > No first aid procedures are required. However, as a precaution flush eyes with fresh water for 15 minutes. Remove contact lenses if worn. SKIN CONTACT: No first aid procedures are required. As a precaution, wash skin thoroughly with soap and water. Remove and wash contaminated clothing. inhalation: If respiratory discomfort or irritation occurs, move the person to fresh air. See a doctor if discomfort or irritation continues. INGESTION: If swallowed, give water or milk to drink and telephone for medical advice. DO NOT make person vomit unless directed to do so by medical personnel. If medical advice cannot be obtained, then take the person and product container to the nearest medical emergency treatment center or hospital. Note to Physician: Ingestion of this product or subsequent vomiting can result in aspiration of light hydrocarbon liquid which can cause pneumonitis. 3. IMMEDIATE HEALTH EFFECTS - (ALSO SEE SECTIONS XI 4 12) EYE CONTACT: This substance is not expected to cause prolonged or significant eye irritation. SKIN IRRITATION: Prolonged or frequently repeated contact may cause the skin to become cracked or dry from the defatting action of this material. DERMAL TOXICITY: If absorbed through the skin, this substance is considered practically non-toxic to internal organs. RESPIRATORY/INHALATI ON: If inhaled, this substance is considered practically non-toxic to internal organs. This substance may be irritating if inhaled. Signs and symptoms of respiratory tract irritation may include, but may not be limited to, one or more of the following: nasal discharge, sore throat, coughing, bronchitis, pulmonary edema and difficulty in breathing. INGESTION: If swallowed, this substance is considered practically non-toxic to internal organs. Because of the low viscosity of this substance, it can directly enter the lungs if it is swallowed (this is called aspiration). This can occur during the act of swallowing or when vomiting the substance. Once in the lungs, the substance is very difficult to remove and can cause severe injury to the lungs and death. 4. PROTECTIVE EQUIPMENT SAL 000009721 Revision Number: 5 Revision Date: 08/24/90 KSDS Number: PE0018 NDA - No Data Available NA - Not Applicable X-0QSG21 (01-89) GULfTXNX 10 j Page' 3 of 6 KYE PROTECTION: No special eye protection is usually necessary. G S 3 60 SKIN PROTECTION: No special skin protection is usually necessary. Avoid prolonged or frequently repeated skin contact vith this material. Skin contact can be minimized by wearing protective clothing. RESPIRATORY PROTECTION: No special respiratory protection is normally required. However, if operating conditions create high airborne concentrations, the use of an approved respirator is recommended. VENTILATION: No special ventilation is usually necessary. However, if operating conditions create high airborne concentrations of this material, special ventilation may be needed. 5. FIRE PROTECTION FLASH POINT: (TCC) 120F (490 AUTOIGNITION: 410F (2100 FLAMMABILITY: 1-5% EXTINGUISHING MEDIA: C02, dry chemical, foam, and water fog. NFPA RATINGS: Health 0; Flammability 2; Reactivity 0; Special NDA; HMIS RATINGS: Health 0; Flammability 2; Reactivity 0; Other NDA; (Least-0, Slight-1, Moderate-2, High-3, Extreme-4). These values are obtained using the guidelines or published evaluations prepared by the National Fire Protection Association or, if applicable, the National Paint and Coating Association, and do not necessarily reflect the hazard evaluation of the Chevron Environmental Health Center. Read the entire document and label before using this product. FIRE FIGHTING PROCEDURES: Liquid evaporates and forms vapor (fumes) which can catch fire and burn with explosive violence. Invisible vapor spreads easily and can be set on fire by many sources such as pilot lights, welding equipment, and electrical motors and switches. Fire hazard is greater as liquid temperature rises above 85 F. For fires involving this material, do not enter any enclosed or confined fire space without proper protective equipment. This may include self-contained breathing apparatus to protect against the hazardous effects of normal products of combustion or oxygen deficiency. Read the entire document. COMBUSTION PRODUCTS: Normal combustion forms carbon dioxide and water vapor; incomplete combustion can produce carbon monoxide. 6. STORAGE, HANDLING, AND REACTIVITY SAL 000009722 HAZARDOUS DECOMPOSITION PRODUCTS: NDA STABILITY: This material is considered chemically and thermally stable. Revision Number: 5 Revision Date: 08/28/90 MSDS Number: PEOO10 NDA - No Data Available NA - Not Applicable X--D0SG21 (01-89) GULPTKNK ID 6S360 Page 4 of 6 HAZARDOUS POLYMERIZATION: Polymerization will not occur. INCOMPATIBILITY: May react with strong acids or strong oxidizing agents, such as chlorates, nitrates, peroxides, etc. SPECIAL PRECAUTIONS: READ AND OBSERVE ALL PRECAUTIONS ON PRODUCT LABEL- DO NOT USE OR STORE near flame, sparks or hot surfaces. USE ONLY IN WELL VENTILATED AREA. Keep container closed. DO NOT veld, heat or drill container. Replace cap or bung. Emptied container still contains hazardous or explosive vapor or liquid. CAUTION! Do not use pressure to empty drum or explosion may result. 7. PHYSICAL PROPERTIES SOLUBILITY: Soluble in hydrocarbon solvents; APPEARANCE: Clear, colorless liquid. BOILING POINT: 162C (324F) MELTING POINT: -66C {-86.8F) EVAPORATION: NDA SPECIFIC GRAVITY: 0.75 6 15.6/15.6C VAPOR PRESSURE: 1.6 mm Hg 75F PERCENT VOLATILE (VOLUME %): NDA VAPOR DENSITY (AIR=1): 4.B4 VISCOSITY: NDA POUR POINT: NA FREEZING POINT: -66C (-86.8F) insoluble in water. 8. ENVIRONMENTAL CONCERNS, SPILL RESPONSE AND DISPOSAL CHEMTREC EMERGENCY PHONE NUMBER: (800) 424-9300 (24 hour). SPILL/LEAR PRECAUTIONS: Eliminate all open flame in vicinity of spill or released vapor. Stop the source of the leak or release. Clean up releases as soon as possible, observing precautions in Protective Equipment. Contain liquid to prevent further contamination of soil, surface water or groundwater. Clean up small spills using appropriate techniques such as sorbent materials or pumping. Where feasible and appropriate, remove contaminated soil. Follow prescribed procedures for reporting and responding to larger releases. DISPOSAL METHODS: Place contaminated materials in disposable containers and dispose of in a manner consistent with applicable regulations. Contact local environmental or health authorities for approved disposal of this material. SAL 000009723 Revision Number: 5 Revision Date: 08/28/90 MSDS Number: PE0018 NDA - No Data Available KA - Not Applicable X-00SD?1 (01-89) CULFTKME 10 Page 5 of 0 6SS609. EXPOSURE STANDARDS, REGULATORY LIMITS AND COMPOSITION COMPOSITION COMMENT: All the components of this material are on the Toxic Substances Control Act Chemical Substances Inventory. The percent compositions are given to allow for the various ranges of the components present in the whole product and may not equal 100%. PERCENT/CAS# COMPONENT/REGULATORY LIMITS 100.0 % GULFTENE 10 CONTAINING < 96.0 % CAS872059 DECENE-N-l IMPURITIES WHICH INCLUDE < 1.0% CAS124185 DECANE-N 2.0 % 2-ETHYL-1-OCTENE CAS51655642 t 1.0 % 2-BUTYL-1-HEXENE CAS6795795 TLV - Threshold Limit Value STEL - Short-term Exposure Limit RQ - Reportable Quantity CC - Chevron Chemical Company TWA - Time Weighted Average TPQ - Threshold Planning Quantity CPS - CUSA Product Code CAS - Chemical Abstract Service Number 10. REGULATORY INFORMATION DOT SHIPPING NAME: PETROLEUM NAPHTHA DOT HAZARD CLASS: COMBUSTIBLE LIQUID DOT IDENTIFICATION NUMBER: UN1255 SARA 311 CATEGORIES: 1. Immediate (Acute) Health Effects; YES 2. Delayed (Chronic) Health Effects; NO 3. Fire Hazard; YES 4. Sudden Release of Pressure Hazard; NO 5. Reactivity Hazard; NO WHEN A COMPONENT OF THIS MATERIAL IS SHOWN IN THIS SECTION, THE REGULATORY LIST ON WHICH IT APPEARS IS INDICATED. SAL 000009724 Revision Number: S Revision Date: 0B/28/90 MSDS Number: PE0018 NDA - No Data Available NA - Not Applicable X-DOS071 (O' --89) 6 3 60GOLFTENI 10 S Pag* 6 of 6 DECAKE 10,11, REGULATORY LISTS SEARCHED: 01-SARA 313 04-CA Prop. 65 07-IARC Group 2A 10-PA RTK 13-MN RTK 16-ACGIH calculated tlv 19-Chevron TLV 22-TSCA SECT 5 SNT/R 25-TSCA SECT BA CAIR 28-canadian WHMIS 02-MASS RTK C5-MI 406 08-IARC Group 2B 11NJ RTK 14-ACGIH TLV 17-OSHA TWA 20EPA Carcinogen 23-TSCA SECT 6 RULE 26-TSCA SECT 8D REPORT 29-OSHA CEILING 03-NTP Carcinogen 06-IARC Group 1 09-SARA 302/304 12-CERCLA 302.4 15-ACGIH STEL 18-OSHA STEL 21-TSCA SECT 4 24-TSCA SECT 12 EXPORT 27-TSCA SECT 8E 11. PRODUCT TOXICOLOGY DATA EYE IRRITATION: The Draize Eye Irritation Score (range, 0-110) in rabbits is 0.7. SKIN IRRITATION: The Draize Skin Primary Irritation Score (range 0-8) for a 24-hour exposure (rabbits) is 0.9. DERMAL TOXICITY: The dermal LD50 in rabbits is greater than lOg/kg. RESPIRATORY/INHALATION: The 1-hour inhalation LC50 in rats is > 320 ppm (0.03%). INGESTION: The oral LD50 in rats is greater than lOg/kg. 12. ADDITIONAL HEALTH DATA ADDITIONAL HEALTH DATA COMMENT: All available data is expressed elsewhere ir. this document. ********************************************************************** The above information is based on the data of which we are aware and is believed to be correct as of the date hereof. Since the information contained herein may be applied under conditions beyond our control and with which we may be unfamiliar and since data made available subsequent to the date hereof may suggest modification of the information, we do not assume any responsibility for the results of its use. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the material for his particular purpose. Revision Number: 5 Revision Date: 08/28/90 MSDS Number: PE0018 NBA - No Data Available NA - Not Applicable SAL 000009725 X-D0SQ21 101-89) DATE* 07/E5/90 index* ii893*ftoi8 ACCT. l*9*-0* CT NOi T383* SSTOLUCNESS >TOLUENES* SSTOLUENES* MATERIAL SAFETY DATA SHEET PAGE, X PO NMi N/A QC3^7 FX8HEA SCIENTIFIC CHEMICAL DIVISION 1 REAGENT LANE FAIR LAWN NJ -0 7 + 10 (013 796-7100 EMERGENCY CONTACT*! GASTON L. PXLLORXt CE013 796-7100 AFTER BUSINESS HOURS, HOLIDAYS. <013 796-7SE3 CHEMTREC ASSISTANCE. (8003 **-9300 THE INFORMATION BELOW IB BELIEVED TO 8E ACCURATE AND REPRESENTS THE BEST INFORMATION CURRENTLY AVAILABLE TO US. HOWEVER. WE MAKE NO WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY. EXPRESS OR IMPLIED. WITH RESPECT TO SUCH INFORMATION. AND WE ASSUME NO LIABILITY RESULTING FROM ITS USE. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION FOR THEIR PARTICULAR PURPOSES. SUBSTANCE IDENTIFICATION SUBSTANCEt SITOLUENESS CAS-NUMBER 10S-8S-3 TRADE NAMES/SYNONYMS. BENZENE. METHYL-, METHYLBENZCNE, TOLUOL, METHYLBENZOL, METHACXDE, 6TCC *909305, RCRA U20, UN 19*, TS90, T289, T3301 T32*, T32*-S, T32*-SK, T3E3, TE32-S, PHENYLMETHANE, T313, C7H8, ACCZ3S90 CHEMICAL FAMILY. HYDROCARBON. AROMATIC MOLECULAR FORMULA. C6-HS-C-H3 IOLECULAR WEIGHT! 92.1* sERCLA RATINGS CSCALE 0-33. HEALTHsS FIRE:3 REACTIVITY:0 PERSISTENCE:1 IFPA RATINGS CSCALE 0-*3t HEALTH:S FIRE:3 RERCTXVITVrO COMPONENTS AND CONTAMZNANTS OMPONENTi TOLUENE CASS 10ft-88-3 PERCENT* 100.0 THER CONTAMINANTS. NONE XPOSURE LIMITS. OLUENE. 100 PPM C 375 MG/M33 OSHA TWA, 150 PPM C5S0 MG/M33 OSHA STEL 100 PPM (375 MS/M33 ACCXH TWA, 150 PPM (5S0 MG/M33 ACGXH STEL ICO PPM NIOSH RECOMMENDED 3WA, 00 PPM NXOSM RECOMMENDED 10 MINUTE CEILING 1000 POUNDS CERCLA SECTION 103 REPORTABLE QUANTITY SUBJECT TO SARA SECTION 313 ANNUAL TOXIC CHEMICAL RELEASE REPORTING PHYSICAL DATA DESCRIPTION. CLEAR. COLORLESS LIQUID WITH AN AROMATIC ODOR. BOILING POINT, 31 F (111 03 MELTING POINT* -139 F (-9S C3 SPECIFIC GRAVITY. 0. 8669 VOLATILITY* 1007 VAPOR PRESSURE* ZZ MMHG a 0 C EVAPORATION RATE, (BUTYL ACETATE:13 . * SOLUBILITY IN WATER. 0. CSX 20 C ODOR THRE8HOLD. 10-15 PPM VAPOR DENSITY. 3.1*^ SOLVENT SOLUBILITY. SOLUBLE IN ALCOHOL. ETHER. BENZENE. LIGROIN, ACETONE. CHLOROFORM. GLACIAL ACETIC ACZ0. CARBON DISULFIDE. FIRE AND EXPLOSION DATA FIRE AND EXPLOSION HAZARD* DANGEROUS FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL A CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. VAPOR-AIR MIXTURES ARE EXPLOSXVC. DUE TO LOW ELECTROCONDUCTIVITY OF THE SUBSTANCE. FLOW OR AGITATION MAY GENERATE ELECTROBTATIC CHARGES RESULTING IN SPARK8 WITH POSSIBLE IGNITION, FLASH POINT* *0 F C* C3 CCC3 UPPER EXPLOSIVE LIMIT* 7.1* LOWER EXPLOSIVE LIMIT, 1. EX AUIOIGNXTXON TEMP.* S96 P (*80 C) SAL 000009726 I I* G s 397 DATE, INDEX* 07/2S/9D 11693*8012* ACCTi 1692*2-0* CAT NO* T32Jt PAGE* s PO MBRi M/A . _AMMABXLXTV CLASSCOSHAl* IS FIREFIGHTING MEDXAt DRV CHEMICAL CARBON DIOXIDE- HALON. WATER SPRAY OR STANDARD FOAM (1987 EMERGENCY RESPONSE GUIDEBOOK. DOT P 5800.10. FOR LARGER FIRES, USE WATER SPRAY. FOG OR STANDARD FOAM (19*7 EMERGENCY RESPONSE GUIDEBOOK. DOT P 5*00.93. FIREFIGHTING* MOVE CONTAINER FROM FIRE AREA IF POSSIBLE. COOL FZRE-EXPOSED CONTAINERS WITH WATER FROM SIDE UNTIL WELL AFTER FIRE IS OUT. STAY AWAY FROM STORAGE TANK ENDS. FOR MASSIVE FIRE IN STORAGE AREA. USE UNMANNED HOSE HOLDER OR MONITOR NOZZLES, ELSE WITHDRAW FROM AREA AND LET FIRE BURN. WITHDRAW IMMEDIATELY IN CA8E OF RISING SOUND FROM VENTING SAFETY DEVICE OR ANY DISCOLORATION OF STORAGE TANK DUE TO FIRE (I97 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.*, GUIOC PAGE 73. EXTINGUISH ONLY IF FLOW CAM BE 6TOPPED| USE WATER IN FLOODING QUANTITIES AS FOG. SOLID STREAMS MAY SPREAD FIRE. COOL CONTAINERS WITH FLOODING AMOUNTS OF WATER, APPLY FROM RS FAR A DISTANCE AS POSSIBLE. AVOID BREATHZNG TOXZC VAPORS, KEEP UPWIND. WATER MAY BE INEFFECTIVE (MFPA 3S5M. FIRE HAZARD PROPERTIES OF FLAMMABLE LIQUIDS, GASES, AND VOLATILE SOLIDS. 19**3 TRANSPORTATION DATA DEPARTMENT OF TRANSPORTATION HAZARD CLASSIFICATION *9 CFR 172.101i FLAMMABLE LIQUID DEPARTMENT OF TRANSPORTATION LABELING REQUIREMENTS *9 CFR 172.101 AND SUBPART Ei FLAMMABLE LXQUXO DEPARTMENT OF TRANSPORTATION PACKAGING REQUIREMENTS! *9 CFR 173.119 EXCEPTIONS* *9 CFR 177. 11* TOXICITY DLUENEi .RR1TATION DATA* 300 PPM EYE-HUMAN* 870 UG EYE-RABBIT MILD, 2 MG/2* HOURS EYE-RABBIT SEVERE, 100 MG/ 30 SECONDS RINSED EYE-RABBIT MILD, *35 MG SKIN-RABBIT MILD, 500 MG SKIN-RABBIT MODERATE, 20 MG/2* HOURS SKIN-RABBIT MODERATE. TOXICITY DATAi 200 PPM INHALATION-HUMAN TCLO, 100 PPM XNMALATION-MAN TCLO, *000 PPM/* HOURS INHALATION-RAT LCLO, 5320 PPM/* HOURS XNHALATION-MOUSE LC5D> 1600 PPM INHALATION-GUINEA PIG LCLO, 1212* MG/KG SKIN-RABBIT LD50* 50 MC/KD ORAL-HUMAN LDLO, 5000 MG/KG ORAL-RAT LDSO, 2250 MG/KG SUBCUTANEOUS-MOUSE LDSO; 1960 MG/KG INTRAVENOUS-RAT LD50, 1332 MG/KG XNTRAPERITONEAL-RAT LD50, 1126 MG/KG ZNTRAPERITONEAL-MOUSE LOSOj 6900 MG/KG UNREPORTED-RAT LDSO, 2000 MC/KG UNREPORTED-MOUSE LDSO, REPRODUCTIVE EFFECTS DATA (ATECS3, MUTAGENIC DATA (RTEC83. CARCINOGEN STATUSi NONE. LOCAL EFFECTS: IRRITANT- SKIN, EYE, INHALATION. ACUTE TOXICITY LEVEL* MODERATELY TOXIC BY INHALATION. INGESTION, 8LIGHTLY TOXZC BY DERMAL ABSORPTION. TARGET EFFECTS* CENTRAL NERVOU8 SYSTEM DEPRESSANT, NEUROTOXZN. POISONING MAY AL80 AFFECT THE HEART. LIVER, KIDNEYS. AND BLOOD. AT INCREASED RISK FROM EXPOSURE* ASTHMATICS ANO PERSONS WITH OTHER RESPIRATORY DIFFICULTIES OR CARDIOVASCULAR DISEASE, SMOKERS, ANO CHRONIC ALCOHOL DRINKERS. ADDITIONAL DATA* STIMULANTS SUCH AS EPINEPHRINE MAY INDUCE VENTRICULAR FIBRILLATION. TOLUENE INHIBITS MITOCHONDRIAL OXXDATXVE PHOSPHORYLATION. ALCOHOL MAY ENHANCE THE TOXIC EFFECTS. HEALTH EFFECTS ANO FIRST AZD INHALATION* TOLUENE, IRRITANT/NARCOTZC/NEUROTOXXN. 2000 PPM IMMEDIATELY DANGEROUS TO LIFE OR HEALTH. ACUTE EXPOSURE- THE LEVEL REQUIRED*TO PRODUCE NARCOSX8 CAN EXIST WITHOUT ASSOCIATED RESPIRATORY TRACT IRRITATION. ODOR DETECTION IS INSUFFICIENT FOR WARNING DUE TO OLFACTORY FATIGUE. 200-600 PPM FOR UP TO * HOURS CAUSED MILD UPPER RESPIRATORY TRACT IRRITATION, FATIGUE, WEAKNESS, CONFUSION, HEADACHE, NAUSEA, IMPAIRED COORDINATION AND REACTION TIME, PARE8THESZAS OF THE 8KZN, EUPHORIA. DIZZINESS, AND DILATED PUPILS. 200 PPM CAUSES RAPID IRRITATION, MA8AL MUCOUS 8ECRETXON, METALLIC TASTE. DROWSINESS. ANO IMPAIRED BALANCE. AFTEREFFECTS INCLUDING NERVOUSNESS, MUSCULAR FATIGUE, AND INSOMNIA LASTED FOR SEVERAL DAYS. A WORKER FOUND UNCONSCIOUS AFTER EXPOSURE TO HIGH VAPOR CONCENTRATIONS FOR 18 HOURS DEVELOPED HEPATIC AND RENAL DAMAGE WITH MYOGLOBINURIA, RECOVERY WAS COMPLETE WITHIN 6 MONTHS. HEMATOLOGIC EFFECTS OCCUR RARELY WITH EXPOSURE TO HIGH CONCENTRATIONS. RECOVERY USUALLY FOLLOWS REMOVAL FROM EXPOSURE. EXTREME INHALATION MAY CAUSE DEATH BY PARALYSIS OF THE RESPIRATORY CENTER. SAL 000009727 I 1* DATE* 07/25/90 ZNDEXi 11893TB0122 ACCT* 15921-2-0V CAT NOi T323* PAGE* * AO NSAi N/A 6 S 3 97 CHRONIC EXPOSURE- REPEATED OR PROLONGED EXPOSURE MAY CAUSE MUCOUS MEMBRANE IRRITATION, VOMITING, INSOMNIA, NOSEBLEEDS, CHEST PAIN. EUPHORIA. HEADACHE. VERTIGO, NAUSEA. ANORCXZA, BAD TASTE. MOMENTARY LOS8 OF MEMORY, PALPITATIONS, EXTREME WEAKNESS, LOSS OF COORDINATION AND IMPAIRMENT OF REACTION TIME. TINNITUS, ALCOHOL INTOLERANCE. P ETECHXAE AND ABNORMAL BLEEDING SYSTEMIC OCULAR DZSTURBRNCES, SUCH AS ''REDDENING* OF THE VISION HAVE OCCURRED. BONE MARROW HYPOPLRSIA ANO LEUKOPENIA HAVE BEEN REPORTED OCCASIONALLY. BUT MAY BE DUE TO BENZENE CONTAMINATION. EXAMINATION OF WORKERS EXPOSED TO 100-1100 PPM REVEALED HEPATOMEGALY, MILD MACROCVT0816, MODERATE ERVTHROPENZA, AND ABSOLUTE LYMPHOCYTOSIS, BUT NO LEUKOPENIA. OTHER WORKERS EXPOSED TO TOLUENE FUMES DEVELOPED LEUKOPENIA AND ESPECIALLY NEUTROPENIA. WITHIN 6 MONTHS, THEY SHOWED DECREASED PROTHROMBIN LEVEL AND INCREASED COAGULATION TIME. PERIODONTAL EFFECTS WERE ALSO NOTED. CARDIAC 6ENSZTZZATION MAY OCCUR AMO MAY RE8ULT IN CAROIAC ARREST DUE TO VENTRICULAR FIBRILLATION. REPEATED INHALATION OF TOLUENE TO THE POINT OF EUPHORIA HAS CAUSED IRREVERSIBLE ENCEPHALOPATHY WITH CEREBELLAR ATAXIA, RHYTHMIC LIMB MOVEMENTS. UNSTEADINESS, BIZARRE BEHAVIOR, EMOTIONAL LABILITY, OPTIC ATROPHY. ANO DIFFU8E CEREBRAL ATROPHY. OTHER NEUROPSYCHIATRIC EFFECTS MAY INCLUDE DIZZINESS. SYNCOPE. PARESTHESIAS. PERIPHERAL NEUROPATHY. HALLUCINATIONS. LETHARGY. AND COMA. INTENTIONAL SNIFFING CAN PRODUCE RENAL TUSULAR DEFECTS WITH METABOLIC ACIDOSIS, ELECTROLYTE ABNORMALITIES AND POTASSIUM LOSS. SEVERE MU8CLE WEAKNESS LEADING TO LIMB PARALYSIS AND CARDIAC ARRHYTHMIAS MAY RESULT FROM THE HYPOKALEMIA; HOWEVER, SENSORY FUNCTION AND TENDON REFLEXES RRE NOT IMPAXAEO. GASTROINTESTINAL EFFECTS MAY INCLUDE ABDOMINAL- PAIN. NAUSEA, VOMITING. AND HEMATCMESZS. CHROMOSOME CHANGES WERE OBSERVED IN SOME WORKERS UP TO TWO YEARS AFTER CESSATION OF EXPQ8URE TO TOLUENE. WOMEN OCCUPATIONALLY EXPOSED TO TOLUENE ANO OTHER VARNISH SOLVENTS HAVE REPORTED MENSTRUAL DISORDERS, UNDERWEIGHT OFFSPRING WHO DID NOT NURSE WELL, ANO FETAL ASPHYXIA. DYSMENORRHEA HAS BEEN REPORTED.IN WOMEN OCCUPRTXONRLLV EXPOSED TO TOLUENE LEVELS OF 60-100 FFM. REPRODUCTIVE EFFECTS HAVE BEEN REPORTED IN ANIMALS. FIRST AID- REMOVE FROM EXPOSURE AREA TO FRESH AIR.IMMEDIATELY. IF BREATHING HAS STOPPED, PERFORM ARTIFICIAL RESPIRATION. KEEP PERSON WARM AND AT RE8T. TREAT SYMPTOMATICALLY AND SUPPORT!VELV. GET MEDICAL ATTENTION IMMEDIATELY. SKIN CONTACT t TOL UENEi IRRITANT. ACUTE EXPOSURE- CONTACT WITH THE LIQUID MAY CAUSE IRRITATION, SCALING, CRACKING AND DERMATITIS. SKIN ABSORPTION DOES OCCUR, BUT XT IS GENERALLY TOO SLOW TO PRODUCE SIGNS OF ACUTE SYSTEMIC TOXICITY. PARESTHESIAS OF THE SKIN MAY OCCUR FROM VAPOR EXPOSURE. CHRONIC EXPOSURE- REPEATED OR PROLONGED CONTACT WITH THE LXSUXD MAY CAU8E DEFATTING OF THE SKIN, RESULTING ZN A DRY, FISSURED DERMATITIS. TEN TO TWENTY APPLICATIONS TO RABBIT 8KIN PRODUCED SLIGHT TO MODERATE IRRITATION ANO SLIGHT NECROSIS, FIRST AID- REMOVE CONTAMINATED CLOTHING AND SHOE8 IMMEDIATELY. WASH AFFECTED AREA WITH SOAP OR MILD DETERGENT AND LARGE AMOUNTS OF WATER UNTIL NO EVIDENCE OF CHEMICAL REMAINS CAPPROXIMATELY- 15-20 MINUTES). GET MEDICAL ATTENTION IMMEDIATELY. EYE CONTACT. TOLUENEi IRRITANT. ACUTE EXPOSURE- CONTACT WITH THE LIQUID MAY CAUSE CORNEAL BURNS IF NOT PROMPTLY REMOVED. VAPORS MAY CAUSE NOTICEABLE IRRITATION AND LACRZMATXON 500-200 PPM, ANO EXTREMELY HIGH CONCENTRATIONS MAY CAUSE BLURRING OF VISION. CORNEAL LESIONS AND VERY FINE VACUOLES HAVE BEEN REPORTED ZN WORKERS EXPOSED TO A SOLVENT MIXTURE CONTAINING TOLUENE. THE LESIONS SUBSIDED FOLLOWING SEVERAL DAYS OF NON-EXPOSURE. SIMILAR LESIONS HAVE BEEN PRODUCEO IN CATS FOLLOWING EXPOSURE TO TOLUENE. CHRONIC EXPOSURE- REPEATED OR PROLONGED CONTACT MAY CAUSE CONJUNCTIVITIS. R FIRST AID- WA8H EYES IMMEDIATELY WITH LARGE AMOUNTS OF WATER OR NORMAL SALINE, OCCASIONALLY LIFTING UPPER AND LOWER LIDS, UNTIL NO EVIDENCE OF CHEMICAL REMAINS (APPROXIMATELY 15-20 MINUTES). GET MEDICAL ATTENTION IMMEDIATELY. ZNGESTIONi TOLUENEi NARCOTIC. ACUTE EXPOSURE- MAY CAUSE NAUSEA. VOMITING, COLIC. DIARRHEA, BURNING SENSATION IN THE EPIGASTRIUM. HEADACHE, TINNITUS, DIZZINESS, WEAKNESS, EUPHORIA. DROWSINESS ANO INCOORDINATION. ZF LARGE AMOUNTS ARE INGESTED, SYMPTOMS MAY PROGRESS TO ZNCLUDE SHALLOW, RAPID RESPIRATION, TREMORS. VENTRICULAR IRREGULARITIES WITH FIBRILLATION, CONVULSIONS, STUPOR RNO UNCONSCIOUSNESS. METABOLIC ACIDOSIS AND LIVER ANO KIDNEY DAMAGE MAY OCCUR. APPROXIMATELY 15-30 MILLILITERS IS THE HUMAN LETHAL D08E. ASPIRATION OF THE LIQUID INTO THE LUNGS MAY CAUSE COUGHING, GAGGING. ACUTE HEMORRHAGIC PNEUMONITIS AND RAPIDLY DEVELOPING PULMONARY EDEMA. CHRONZC EXPOSURE- NO EFFECTS WERE REPORTED IN RATS FCO UP TO S90 MG/KG/DAV FOR 193 DAYS. REPRODUCTIVE EFFECTS HRVE BEEN REPORTED ZN ANIMALS. FIRST AXO- EXTREME CARE MUST BE USED TO PREVENT ASPIRATION. GASTRIC LAVAGE WITH A CUFFED ENDOTRACHEAL TUBE ZN PLACE TO PREVENT FURTHER RSPXRATZON SHOULD SE DONE WITHIN 15 MINUTES. IN THE ABSENCE OF DEPRESSION OR CONVULSIONS OR ZMPRXRED GAG REFLEX, EMESIS CAN ALSO SE INDUCED USING SYRUP SAL 000009728 6S397 DATE* XMDEXi 07/25/90 112S31-G01S*' ACCTi 1C92+2-01- CAT NOi T3231- PACEi PO NBAs N/A iP XPECAC WITHOUT INCREASING THE HAZARD OP ASPIRATION (DAEISBACH, HANDBOOK OF POISONING, 12TH ED. 3. TREAT SYMPTOMATICALLY AMO SUPPORTXVELY CABTRXC LAVAGE SHOULD SE PERFORMED BY SUALXFXEO MEDICAL PERSONNEL. GET MEDICAL ATTENTION IMMEDIATELY. ANTIDOTEi NO 8PECXFIC ANTIDOTE. TREAT SYMPTOMATICALLY AND SUPPOATIVELY. REACTIVITY REACTIVITY! STABLE UNDER NORMAL TEMPERATURES AND PRESSURES. INCOMPATXBXLXTXESt TOLUENES ALLYL CHLORIDE DICHLOROETHVL ALUMINUM OR ETHYLALUMXNUM SESQUXCHLORXDE. POSSIBLE EXPLOSION. BROMINE TRXPLUORXDE (SOLID). VIOLENT REACTION. 1, 3-DXCMLORO-5, 5-DIMETHYL-2,V-iMIDAZOLIDIDIONEs EXPLOSIVE REACTION OXNXTROGEN TETRAFLUORZDEi FORMS EXPLOSIVE MIXTURE. NZTRXC ACXDi VIGOROUS REACTION. NITRIC ACID SULFURIC ACID. VIOLENT DECOMPOSITION POSSIBLE NITROGEN TETROXlDEs EXPLOSIVE REACTION. OXZDZZERS C STRONG 31 FIRE AMD EXPLOSION HAZARD. PLASTICS, RUBBER, AND COATINGS. MAY BE ATTACKED. SILVER PERCHLORATEi FORMS SHOCK* SENSITIVE MIXTURE. SULFUR DZCHLORIDEi VIOLENT REACTION, GREATLY ACCELERATED IN THE PRESENCE IRON OR FERRIC CHLORIDE. SULFURIC ACIDt EXOTHERMIC REACTION. tc-tdauTTBOMFTMANEs FORMS EXPLOSIVE MIXTURE. OF DATEi XMDEXi 07/ES/90 11S931-50123 ACCTi. 15921-2-0* CAT NOi T3B3 + MOBILIZE SPILL WITH UNIVERSAL GELLING AGENT. PAGE. PO NBRi N/A G s 397 REDUCE VAPOR AND FIRE HAZARD WITH APPROPRIATE FOAM. AXA SPILL. KNOCK DOWN VAPORS WITH WATER SPRAY. KEEP UPWIND. WATER SPILL. LIMIT- SPILL MOTION AND DISPERSION WITH NATURAL BARRXER8 OR OIL SPILL CONTROL BOOMS. APPLY DETERGENTS. SOAPS. ALCOHOLS OR ANOTHER SURFACE ACTIVE AGENT. APPLV UNIVERSAL GELLING AGENT TO IMMOBILIZE TRAPPED BPXLL AND INCREASE EFFICIENCY OF AEMOVAL. IF DISSOLVED. AT A CONCENTRATION OF 10 PPM OR GREATER, APPLY ACTIVATED CARBON AT TEN TIMES THE AMOUNT THAT HAS BEEN SPILLED. U8E SUCTION HOSES TO REMOVE TRAPPED BPXLL MATERIAL. USE MECHANICAL DREDGES OR LIFTS TO EXTRACT IMMOBILIZED MASSES OF POLLUTION AND PRECIPITATES. OCCUPATIONAL SPILLt SHUT OFF IGNITION SOURCES. STOP LEAK IF YOU CAN OO XT WITHOUT RISK. USE WATER SPRAY TO REDUCE VAPORS. FOR SMALL SPILLS. TAKE UP WITH SAND OR OTHER ABSORBENT MATERIAL AND PLACE INTO CONTAINERS FOR LATER DISPOSAL. FOR LARGER SPILLS. DIKE FAR AHEAD OF SPILL FOR LATER DISPOSAL. MO SMOKING. FLAMES OR FLARES IN HAZARD AREA. KEEP UNNECESSARY PEOPLE AWAY, ISOLATE HAZARO AREA ANO RESTRICT ENTRY. REPORTABLE QUANTITY (RQ3. 100G POUNDS THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT CSARA) 8ECTION 301- REQUIRES THAT A RELEASE EQUAL TO OR GREATER THAN THE REPORTA8LE QUANTITY FOR THIS SUBSTANCE BE IMMEDIATELY REPORTED TO THE LOCAL EMERGENCY PLRNNXNG COMMITTEE AMD THE STATE EMERGENCY RESPONSE COMMISSION C+0 CFR 3S5. 1-0). IF THE RELEASE OF THIS SUBSTANCE IS REPOATABLE UNDER CERCLA SECTION 103. THE NATIONAL RESPONSE CENTER MUST BE NOTIFIED IMMEDIATELY AT CBOO) +21--8S02 OR (202) YES-2675 IN THE METROPOLITAN WASHINGTON, D. C. AREA (1-0 CFR 302.6). PROTECTIVE EQUIPMENT SENTZLATZON. ROVZOE LOCAL EXHAUST OR GENERAL DILUTION VENTILATION TO MEET PUBLISHED EXPOSURE LIMITS. VENTZLATZON EQUIPMENT MUST BE EXPLOSION-PROOF. RESPIRATOR. THE FOLLOWING RESPIRATORS RND MAXIMUM USE CONCENTRATIONS ARE RECOMMENDATIONS BY THE U.S. DEPARTMENT OF HEALTH AND HUMAN SERVICES. NZOSH POCKET GUIDE TO CHEMICAL HAZARDS; NIOSH CRITERIA DOCUMENTS OR BY THE U.S. DEPARTMENT OF LABOR. 29 CFR 1910 SUBPART Z. THE SPECIFIC RESPIRATOR SELECTED MUST BE BASED ON CONTAMZNATZON LEVELS FOUND IN THE WORK PLACE. MUST NOT EXCEED THE WORKING LIMITS OF THE RESPIRATOR AND BE JOINTLY APPROVED BY THE NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH AND THE MINE SAFETY AND HEALTH ADMINISTRATION CNI08H-MSHA). TOLUENEi lAfin iUV CHEMICAL CARTRIDGE RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE( S3. GS 397 DATE* INDEX* 0T/E5/90 11B93*B01*' AeeTt 169*-0+ CAT NOi T33V PRGEi 9 PO NAAi N/A iF IPECAC WITHOUT INCREASING THE HAZARD OF ASPIRATION CDREXSBACH, HANDBOOK UF POISONING, 1RTW ED. >. TREAT SYMPTOMATICALLY AND SUPPORTIVELY. GASTRIC LAVAGE SHOULD BE PERFORMED BY SUALZFIED MEDICAL PERSONNEL. GET MEDICAL ATTENTION IMMEDIATELY. ANTIDOTE* NO SPECIFIC ANTIDOTE. TREAT SYMPTOMATICALLY AND SUPPORTIVELY. REACTIVITY REACTIVITY* STABLE UNDER NORMAL TEMPERATURES AND PRESSURES. INCOMPATIBILITIES! TOLUENE* ALLVL CHLORIDE DICHLOROETHYL ALUMINUM OR ETHYLALUMINUM SESAUXCHL ORIDEi POSSIBLE EXPLOSION. BROMINE TRZFLUOAZDE (SOLID)i VIOLENT REACTION. 1, Z-DXCHLORO-5, 5*DIMETHYL-Y-IMIDAZOLIDIDIONEi EXPLOSIVE REACTION. DXNXTROGEN TETRAFLUORIDEi FORMS EXPLOSIVE MIXTURE. NITRIC ACXDi VIGOROUS REACTION. NITRIC ACID * 8ULFURIC ACXDi VIOLENT DECOMPOSITION POSSIBLE. NITROGEN TETROXIDEi EXPLOSIVE REACTION. OXIDIZERS CSTRONG)* FIRE AND EXPLOSION HAZARD.PLASTICS. RUBBER, AND COATINGS* MAY BE ATTACKED. SILVER PERCHLORATE* FORMS SHOCK-SENSITIVE MIXTURE. SULFUR DICHLORIDE* VIOLENT REACTION, GREATLY ACCELERATED IN THE PRESENCE IRON OR FERRIC CHLORIDE. SULFURIC ACID* EXOTHERMIC REACTION. TETRANITROMETHANE* FORMS EXPLOSIVE MIXTURE. URANZUM HEXAFLUORIDE* VIOLENT REACTION. OF DECOMPOSITION! THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE TOXIC OXIDES OF CARBON. POLYMERIZATION* HAZARDOUS POLYMERIZATION HAS NOT BEEN REPORTED TO OCCUR UNDER NORMAL TEMPERATURES AND PRESSURES. STORAGE AND DISPOSAL jSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS WHEN STORING OR DISPOSING OF THIS SUBSTANCE, FOR ASSISTANCE. CONTACT THE DISTRICT DIRECTOR OF THE ENVIRONMENTAL PROTECTION AGENCY. SSSTORAGESS STORE IN ACCORDANCE WITH 9 CFR 1910.106. PROTECT AGAINST PHYSICAL DAMAGE. OUTSIDE OR DETACHED 8TORAGE IS PREFERABLE. INSXOE STORAGE SHOULD BE IN A STANDARD FLAMMABLE LI6UXDS STORAGE ROOM OR CABINET. SEPARATE FROM OXIDIZING MATERZAL8 (NFPA *9. HAZARDOUS CHEMICALS DATA, 1975). BONDING AND GROUNDING* SUBSTANCE8 WITH LOW ELECTROCONOUCTIVJTY, WHICH MAY BE IGNITED BY ELECTROSTATIC SPARKS, SHOULD BE STORED IN CONTAINERS WHICH MEET THE BONDING AND GROUNDING GUIDELINES 8PECZFZEO IN NFPA 77-19*3, RECOMMENDEO PRACTICE ON STATIC ELECTRICITY. STORE AWAY FROM INCOMPATIBLE SUBSTANCES. SBDISPOSALS* DISPOSAL MUST BE IN ACCORDANCE WITH STANDARDS APPLICABLE TO ~ GENERATORS OF HAZARDOUS WASTE. VOCFR 6. EPA HAZARDOUS WASTE NUMBER UZBO. CONDITIONS TO AVOID AVOID CONTACT WITH HEAT, SPARKS. FLAMES. OR OTHER SOURCE8 OF IGNITION. VAPORS MAY BE EXPLOSIVE. AVOID OVERHEATING OF CONTAINERS) CONTAINERS MAY VIOLENTLY RUPTURE IN HEAT OF FIRE, AVOID CONTAMINATION OF MATER SOURCES. SPILL ANO LEAK PROCEDURES SOIL SPILL* DIG HOLDING AREA SUCH AS LAGOON, POND OR PIT FOR CONTAINMENT. DIKE FLOW OF 8PILLED MATERIAL USING SOIL OR SANDBAGS OR FOAMED BARRIER8 SUCH 8 POLYURETHANE OR CONCRETE. USE CEMENT POWDER OR FLY ASH TO ABSORB LXSUID MASS. SAL 000009729 MATERIAL SAFETY OATA SHEET ENHANCE AEROSOL rage : 01 (O06342-0158P EOO16293"5077 )JDATE OF ISSUE 1 01/26/90 SUPERSEDES 01/26/90 I SECTION I - GENERAL INFORMATION CHEMICAL NAME A SYNONYMS N,'A chemical Family AOUECUS ALCCHOL CLEANER TRADE NAME & SYNONYMS ENHANCE AEROSOL FORMULA X <--MIXTURE MANUFACTURERS NAME: NATIONAL CWEMSEARCH DIV. OF NCH CORF. ADDRESS (NUMBER, STREET. CITY. STATE & Zip codei BOX 152170 IRVING. TEXAS 75015 PREPARED BY: KELLY SEALS/T.S.CHEMIST ! PRODUCT CODE NUMBER i EMERGENCY TELEPHONE NUMBER 5077 214-438-1301 SECTION II- HAZARDOUS INGREDIENTS THE HAZARDS PRESENTED BELOW ARE THOSE OF THE INDIVIDUAL COMPONENTS AS THE PRODUCT MIXTURE HAS NOT BEEN TESTEO AS A WHOLE. CHEMICAL NAME (INGREDIENTS) ISOROPANOl ISOBUTANE ] HAZARD FLAM FLAM | TL V 400PPM N/E { PEL 400PPM N/E ! CAS* 67-63-0 75-28-5 SECTION I IA NON-HAZARDOUS INGREDIENTS NON-HAZARDouS rNGRECIENT NAMES AND CAS NUMBERS ARE PROTECTED UNDER NJ TRADE 5ECRET REGISTRY A 409363-S160P ENHANCE AEROSOL SECTION III - PHYSICAL DATA PAGE : 02 BOILING *T.(FAHRENHEIT) VAPOR PRESSURE (MM HG). VAPOR DENSITY (AIR1) PH * 100* PERCENT. VOLATILE BY VOLUME <%) S0LU8ILITY IN WATER VISCOSITY ! 190 !2o 12.0 !o {>90 l J 1 SPEC GRAVITY (H20-1) tt COLOR FOAMY WHITE 1* ODOR ALCOHOLIC 1 CLARITY CLEAR 1 f J EVAPORATION RATE <BU AC - 1 ) JO.1 ! ; COMPLETE ! NON- VISCOUS :.960 - .050 SECTION IV - FIRE ANO EXPLOSION HAZARD FLASH POINT (METHOD USED) 87 F T.C.C. EXTINGUISHING MEDIA ALCOHOL' X<--FOAM <-- FOAM j FLAMMABLE LIMITS i X<-C02 DRY X<--CHEMICAL SPECIAL FIRE FIGHTING PROCEDURES USE WATER SPRAY TO COOL FIRE EXPOSED SURFACES. , LEL !n/a WATER < - -SPRAY 1 . wel [n/a <--OTHER UNUSUAL FIRE 6 EXPLOSION HAZARDS MIXTURE WITH PROPELLANT IS NON-FLAMM.ABLE . LEVEL 1 AEROSOL (NFPA 30E) NF PA HAZARD RATING (0*I NS IGNIFI CANT ; 1SLIGHT;2-M00ERATE.3HIGH:4-EXTREME) : 1 <--HEALTH 3 <--FLAMKABILITV 0 ^--REACTIVITY ^--SPECIAL SECTION V - HEALTH HAZARD DATA THRESHOLD LIMIT VALUE : NOT ESTABLISHED FOR MIXTURE. SEE SECTION 11. SAL 000009732 ri 'r S 5 81 (CONTINUED) ENHANCE AEROSOL SECTION V HEALTH HA2ARO DATA PAGE : 03 EFFECTS OF OVEREXPOSURE - ACUTE (SHORT TERM EXPOSURE) ACUTE'EXPOSURE TO LOW CONCENTRATIONS OF THIS MIXTURE MAT RESULT IN MILD IRRITATION TO EYE OR SKIN TISSUE. - CHRONIC - (LONG TERM EXPOSURE) PROLONGED CONTACT CAN CAUSE APPRECIABLE IRRITATION TO EVES- LEADING TO CORNEAL OPACITY IN REPEATED SEVERE EXPOSURES. INGESTIONS OR INHALATION OF LARGE 0UANTJT1ES OF THE VAPOR MAY CAUSE FLUSHING. HEADACHE, D1221 NESS . MENTAL DEPRESSION, NAUSEA. VOMITING. NARCOSIS. ANESTHESIA, COMA, lOOML CAN BE FATAL. PRIMARY ROUTE OF ENTRY <-- INHALATION INGESTION <-- ABSORPTION EMERGENCY & FIRST AID PROCEDURES INHALATION REMOVE DERSON FROM AREA TO FRESH AIR IRRITATION PERSISTS. SEEK MEDICAL ATTENTION IF ANT EYE CONTACT OBJECT IS TC SEEK MEDICAL ATTENTION IMMEDIATELY. IMMEDIATELY FLUSH WITH PLENTY CF WATER FOR AT LEAST 15 MINUTES HOLDING EYELIOS APART TO ENSURE FLUSHING OF THE ENTIRE EYE SURFACE. SEEK MECICAL ATTENTION IMMEDIATELY. SKIN CONTACT. IF OVEREXPOSEO: WASH WITH PLENTY OF WATER. INGESTION : IF SWALLOWED. DO NOT INDUCE VOMITING. GIVE LARGE OUANTITIE5 OF WATER. AVAILABLE. GIVE SEVERAL GLASSES OF CITRUS JUICE. NEVER GIVE ANYTHING BY MOUTH tO AN UNCONSCIOUS PERSON. SEEK MEDICAL ATTENTION IMMEDIATELY N/A NOTES TO PHYSICIAN SECTION VI - TOXICITY INFORMATION PRODUCT CONTAINS CHEMICAL LISTED AS CARCINOGEN OR POTENTIAL CARCINOGEN BY: I ARC <--YES NTP <--YES OSHA <--YE$ ACGIH <--YES OTHER <--YES X<--NC X< --NC X <-"NO XC--NO X<-*NO ISOPROPANOL EYE-HMN: 20PM 2. CRL-HMN TOLO: 15.7 lOMG/KG:CNS ORL-MAK LDLC: B60OMG/KG 2. IHL-HMN TCLO: AOOPPM 2. 2. SECTION VII - REACTIVITY DATA STABILITY j X<* ST ABLE <-UNST ABL \ CDNDIDTIONS TO AVOID KEEP AWAY FROM HEAT AND OPEN FLAME. (CONTINUED) ENHANCE AEROSOL SECTION VII - REACTIVITY DATA INCOMPATIBILITY (MATERIALS TO AVOIO) H2 PD. NITROFORM. OLEUM. C0CL2 HA2AR00US DECOMPOSITION PRODUCTS CARBON MONOXIDE POSSIBLE. HAZARDOUS ! WILL NOT j X <--OCCUR polymerization! !n/a MAY <--OCCUR ! CONDITIONS TO AVOID [ PAGE : 04 SECTION VIII - SPILL OR LEAK PROCEDURES STEPS TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED AEROSOL CONTAINER SO SPILL UNLIKELY. IN THE EVENT OF A SPILL, PICK UP WITH ABSORBANT ANO OISPDSE OF IN AN APPROVEO MANNER. WASTE DISPOSAL METHOD OISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS CONCERNING HEALTH POLLUTION. 00 NOT ikjNCTURi OR INCINERATE CONTAINER. DISPOSE OF IN A SANITARY LANDFILL. NEUTRALIZING AGENT WATER. SECTION IX - SPECIAL PROTECTION INFORMATION RE0U1REC VENTILATION AREAS OF USE WITH ADEOUATE VENTILATION SHOULD BE SUFFICIENT IN USE AS A GLASS CLEANER. RESPIRATORY PROTECTION IF EXPOSURE MAY OR DDES EXCEEO OCCUPATIONAL EXPOSURE LIMITS (SEC. IV) USE A MCSH-APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. USE EITHER A FULL-FACE. ATMOSPHERE-SUPPLYING RESPIRATOR OR AIR-PURIFYING RESPIRATOR FOR ORGANIC VAPORS. IDLH 20.000 PPM/GMOVFB PROTECTIVE GLOVES WEAR IMPERVIOUS GLOVES ANO OTHER PROTECTIVE CLOTHING AS REQUIRED TO PREVENT SKIN CONTACT. EYE PROTECTION CHEMICAL GOGGLES DEPENDING UPON SEVERITY OF CONTACT. (CONTINUEO) OTHER PROTECTION N/A CINi SECTION IX - SPECIAL PROTECTION INFORMAT IOPAGE : 05 <r S 5 8 1 SECTION r. - STORAGE AND HANDLING INFORMATION JSTORAGE TEMPERATURE 120 F <--MAX 32 F.<--MIN J INDOOR X j HEATED ! PRECAUTIONS TC 6E TAKEN IN HANDLING & STORING STORE AT MODERATE TEMSERATURS OTHER PRECAUTIONS KEEP OUT C* REACH OF CHILDREN READ ENTIRE LABEL BEFORE USING PRODUCT ]JREFfiIGERATED|JxOUTDOOR SECTION XI * REGULATORS INFORMATION CHEMICAL NAME C.A.S NUMBER UPPER K LIMIT JSOPRCPANOL 63-67-12 UE THOSE INGREDIENTS LISTED ABOVE ARE SUBJECT TO THE REPORTING REQUIREMENTS OF 313 OF TITLE III OF THE SUPERFUNO AMENDMENTS ANO REAUTHDRJZAT 1DN ACT OF 1S66 AND 40 CFR ART 372. IF UE (USE EXEMPTION) APPEARS UNDER UPPER % LIMIT, END USERS ARE EXEMPT FROM NOTIFICATION BECAUSE THE PRODUCT IS USED AND LABELED FOR ROUTINE JANITORIAL WORK. OR THE PRODUCT IS USED ANO LABELED FOR FACILITY GROUNDS MAINTENANCE (SUCH AS FERTILIZERS ANO HERBICIDES). OR THE PRODUCT IS USED AND LABELED FOR MAINTAINING MOTOR VEHICLES- SECTION XU - TRANSPORTATION (FOR FUTURE USE) APPLICABLE REGULATIONS <--49 CFR <--IMCC SHIPPING NAME HAZARD CLASS LABELS < -- TARIFF 6 0 <-- 1 ATfc <--MlLlTARY AIR (AFR 71-4) ! ID NUMBER 1 REPORT OTY | LIMITED TY (CONTINUED) ENHANCE AEROSOL SECTION XII - TRANSPORTATION * (FOR FUTURE USE) UNIT CONTAINER DOT SPS CONTAINER | NET EXPLOSIVE WT. AEROSOL PROPELLANT(S) SECTION XIII - REFERENCES 1. THRESHOLD LIMIT VALUE FOR CHEMICAL SUBSTANCES IN THE WORK ENVIRONMENT. 2ND EDITION, ACGIH. 198*. 2. OANSEROUS PROPERTIES OF INDUSTRIAL MATERIALS. 6TH EDITION. N. IRVING SAX. PAGE : 06 THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED ACCURATE IN LIGHT OF CURRENT FORMULATION. HOWEVER. NO WARRANTY IS EXPRESSEO OR IMPLIED REGARDING THE ACCURACY OF THIS DATA OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. NATIONAL CHEMSEARCH DIV. OF NCH CORF. ASSUMES NO RESPONSIBILITY FOR PERSONAL INJURY OR PROPERTY DAMAGE CAUSED BY THE USE . STORAGE OR DISPOSAL OF THE PROOUCT IN A MANNER NOT RECOMMENDED ON THE PRODUCT LABEL. USERS ASSUME ALL RISKS ASSOCIATED WITH SUCH UNRECOMMENDED USE. STORAGE. OR DISPOSAL OF THE PRODUCT. SAL 000009734