Document 936Zwk1jqVGg7gBrNzXKv1Nq7
AR 126-0065
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Centre Analytical Laboratories, Inc.
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Ph0on8e:Ro(8s14e)a2c31h-D80v3e2 Fax: (814) 231S-1t2o5e3 lor (l814o)P2gA31T-e61858,001
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Analytical Report
EHn-3
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Fluorochemical Characterization of Drinking Water Samples
Columbus, GA (W236)
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Centre Analytical Laboratory Report No. 023-007F
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Testing Laboratory
Centre Analytical Laboratory, Inc.
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St3a0te48CoRlelesgeea,rcPhAD1r6i8ve01
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Kent R. Lindstrom
Bldg, 2-3E-09
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P.O. Box 33331 St. Paul, MN 55133-3331
Phone: (651) 778-5352
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emme re r
Requester
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3M EnvironmenKtriaslJT.eHcahnnsoelno,gyPh&.DS.afety Services
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Bldg, 2-35-09
P.O. Box 33331
St. Paul, MN 55133-3331
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cerns 0600314
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1 Introduction
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AcRonelaesycilsecdaafrLoabmroorCpaootrlotrueimdebsuf,osrI,ct.GheA(.CaneTanlhtyers)iCsferonofmtartssheeurdi3eyMsnoEufnmvdbireriornnkaimsnesgnitwgaanltaeLdrabfsooartamihpolrpeyr,sojreTechtcoaisva0em2d3p.ib0ye0sC7w.eentrree
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`Spec fuorochemical characterizationbyliquid chromatograph/y tandem mass spectrometry
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(LCMS/MS)was requestedforall samples. Atotalof16sampleswerereceivedforanalysis.
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ThesamplesworeproparedandanalyzedbyLCIMSIMSforthefolowing stof uorochemicas:
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+ Teblo 1: TargetAnalysis
[FPertuoroocaneSuforate
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[PerfuorooctaneSufonviamide
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(Pefu~ o~ coctan[c poa an te|
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iPraactigceense(rGaLtPesd).n TshpeoanralyotfictailsmesthyodwussedgweasnrvaleidastedcbyrCenotroU.STEPhAe.vaGliodadtioLnapbroolroeys
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atnimde.resusareonfewithCente.Dataposedhere i the highestquality dataavaiableat ns
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2 Sample Receipt
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Thesamples wero submitedin individual las containersandwere notpreserved. Shisen cInodlievcidtuoanl dsaatmepslweecroentnaoitnesurpspwlieerde, Crehcaelinve-do.f-cSuasmtpdlyeisnfworemraetiroencesivperdeosnen0t2e/d15n/0A0t.iTahchemesnatmpA.le
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3 Holding Times
nm
Tshtaebainlyaofltyhe!anmaeltyhteosdoufsiendtewraesstvfoarlildoangteerdpaegraiiondsshaasmnaoxtibmeuemnhdeotenrmginteid.eof 14days. The
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4 Methods -Analytical and Preparatory
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44111 SLaompMlSeIPoMpSaration for LCMSIMS Analysis
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LSrGeasMmipdSulaeMlsScwhealnroareilnyaes.ilsS.yoAdvfoeraptthyea-dmsiweiltiheexr2t0oa0rcituooLnonof(f2S5sPa0Em)pmlpwe1ew.sassoutdsrieaudnmstfeiropesrdeupla0araee.GsyothuotSoPsnEamtcpalrretesimdogovere,
"dTihseccaarrdteiddagnodwtahserSsPtEelcuotelduwminwha5smtLheonf4o0l%dmewtihtahno1l0i0n%watmeethsaonlcult.on.AT5hmeiepoaritoensoossf
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c`omnectehnatnroaltwioansofcohlelecstaemdpfloersapnarliyosiorsabnaylyLsCi/s.MS/MS. This treatment resuited in an eight-fold
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412 Sample Analysis by LCMSIMS
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mkinlodwnteompreorcathuermesi;cmaosleacreuloebssearrveedioaninzdedq,uafrnatgamteendteadg,aiannstdsdaentedcatredd.s lons characteristic of
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a(nSAaRlHMey)wz.ietStahemPpaslcekeamswrpdeerHePexe1ax1ct0r0tascH.tPeALdnCosanyyss2t1se2wm4ca0o0suappelnredfdaon0ra.nl8oydMziecudsrbionymgasMsesSlUeIlctStiebmdaerMteSwaIeceMtnoS2nwa5mso0nul0osraeinntdgo
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2127/00. The HPLC and MSIMS methods usedfo
found in atiachment D.
analysis and nstument parameters can be
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5 Analysis
B
51 foCAraltpiohbiecnrtoamctaipolonburnadosnocfanveerweass.aTnhaelyczaelbdaratitohnepbooignitnsriwnegrapnrdeepnadreodfahe0a,nal25y,t5ic,als1e0q0,u2en5c0e,
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c5op0rl0e,olatanidofonrc1eo0ae0cf0hincgpioLnint(tp.(t))UasTnihdnegconrsefesiacprioenrnsetegoroeffsdtseiheoenrcmuwiahnnait1liaxonwn(e7i)gownheiynregr,suhsteetrhSmoeipcnooe,ndy.cloenAricacateioprntawiaaonsnd
curveisacceptaifbrl>e0.985 (> 0.970).
B
Calibration standardsarepreparedusingthesame SPE procuseed fdorsuamrplees.
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caFlbroratoonntchuhceeacrkagaenswatilathynnhsdiiansr+oid-ss2ew0quaeu%reenotfctaen.aayCozocamadpnilpivearasinlocdeeiciasl eavbeirayneedeffttofoe.ssatmapndlaerdfeacntoaness)
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Fortheresusroporied ere albraton reawere met.
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52 Blanks eExtraxcionfbbllaarnnkkssawsehrocuedprnteotpahroaevdeananndy taargent anawaielhsevpyerreyzseexntaerttaocrtdiaonbbaatvcthheeofcosnceemntpraltieoTsnh.oef thelowevel calibration standard. For these samples, heextraction bawernecokmplset.
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lIenvsetlrcuamlebnrtatbiloannksstanndtahred,foarnmdofafctleer aknnomwenthhaingohlvseovlevlesnatmwpelrese."alAsgoaainn,altyhzaedblaafnekrs esvheoryudhingoht-
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`hsaavmeplaensyprteasregnetteadnhaelyrteetshepriesenntsatobrlraanbkousvremetcheoemplnloiwartnotv.el calbraton standard. For the
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53 `SSuurrrrogoagteatspeiskesarenota comofptheoLCInMSIMeSannalytticalmethod.
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54 MaMtartirxixspSkpeiskweesrepreparedforeverysampleal aconcentration of 100nglLusingall
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compooufnnerdests. Mat spikerecoveriesaregiveninAtiachmentC.
Ficelodsmpipkeos owufeirnnetaedrlessst.pFrieepladrsepdikoen rseecvoevrearliessaamrpolaelssaofgiavecnoinnceAnttiaatcohnmaonftC1.00Tnhge fiuasdinsgpakle rinedsicuastinfgorthstamthpilsseaMmCp-l5e2w0aHspgoasvseibrleycsopviekrieedsatf1o00al0lpcaotmpnostuenaddsofof10a0pppprtodmately 1000 %,
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55 ADlupslaimpclaetseswere analyzed in cuplicate, Results aro given slong with the sample results in
Atechment .
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56 Laboratory Control Samples
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Mi`licwatoerwmwaesrpebspeoitkweuedewnin7h0a-ldl1c30so%mpoinuenadcohfLiCnSe.restat25and250ngIL.Al recovefroieasl
" ema ee ha Tut 57 Sample Related Comments Fieldblanksamples consistedofemptycontainers. Fortymiltofetrypes|waterfitored `manneras the oer samples.
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6 Data Summary
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PleaseseeAttachment Bfor adetailed ising oftheanalyticalresus.
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7 Data/Sample Retention
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8 Attachments
81 AttachmenAt: Chain-of-Custody
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62 Atschments: Ress.
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8043 mens: LononsSess a AtachmenCt:MatrixSpike Recoveries(FieldandLaboratorySpikes)
I 9 Signatures
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