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FIRESTONE SYNTHETIC RUBBER fc LATEX CO. MATERIAL SAFETY DATA SHEET To: MONSANTO Date*. 03/03/92 Attention: VARARIE PATRICK FAX 413-730-2997 ***************************t**4*************t*****j,********444A4AA44*** S**e*c*ti*o*n**I**-**P**ro*d**u*c*t *I*dx*e*n*t*i*ty**********************4*****4*********44**** Product, Chemical name: Poly(butadiene-co-styrene) CAS No.: 90C3-55-8 Manufacturer: Firestone Synthetic Rubber & Latex Co. A Division of 3ridgestone/Firestone Inc, Address: 381 W. wilbeth Rd. Akron, OH 44301 Phone: For Information - (216) 379-6018 Emergency - (800) 424-9300 *********************** ********************************* *******4**4**** S**e*c*t*io*n**I*I**-**H**a*z*a*rd*o*u*s**I*n*g**r*e*d*i*e*n*t*s*/*I*d*e*n**ti*ty*4****x******4********4444*** Hazardous Components None Pet. 0SHA PEL ACGIH TLV Comments: As defined by 29CFR1910.1200 ****************************x**4**4*4*4*44*4***4*44*44**444**4*4444444 Section III - Health Hazard Cata ***************************************** a**************************** Routes of entry: Inhalation ( ) skin ( ) Ingestion ( ) Acute health hazards: None Chronic health hazards: None Carcinogenicity: NTP ( ) IARC ( ) OSHA ( ) NA Sicns and symptoms of exposure: NA Medical conditions generally aggravated by exposure: NA Emergency and first aid procedures: NA Comments: None NA **************** *******************************************4 *******4444 S**e*c**ti*o*n***IV***-***C*o**n*t*r*o*l**M**e*a*s*u*r*e*s**********44*44444444444*4444444444444 Respiratory protection; None required. Recommended ventilation: local exhaust ( ) mechanical/general ( ) special ( ) other/comments: NA Protective gloves: NA Eye protection: NA other protective clothing or equipment: NA Work/hygienic practices: at the end of each work period and before eating, wash, with soap and water, areas of the body ccming in contact with this product. Page 1 DO 085432 CONFTDFNTIAL. FIRESTONE SYNTHETIC RUBBER & LATEX CO. MATERIAL SAFETY DATA SHEET STEREON 730A ****************************************************************44*** Section V - Physical and Chemical Properties *********************************************************************** Appearance and odor: Amber, rubbery solid; little, if any, odor. Specific Gravity: >0.93 Solubility in water: Nil Melting Point: NA Evaporation rate: NA Boiling Point: NA Vapor density: NA *********************************************************************** Section VI - Fire and Explosion Data *********************************************************************** Flash point: NA Method: NA Flammable limits: LEL: NA UEL: NA Extinguishing method: Water or foam Special fire fighting methods: Use self-contained breathing apparatus. Unusual fire and explosion hazards: None Combustion byproducts: Oxides of carbon. *********************************************************************** S**e*c*t*io*n**V**I*I **- *R**e*a**c*ti*v*it*y**D**a*ta******************************************* Material is: unstable ( ) stable (x) Conditions to avoid: NA Incompatibility (materials to avoid): NA Hazardous decomposition: NA Hazardous polymerization: may occur ( ) Conditions to avoid: NA may not occur (x) *********************************************************************** Section VIII - Precautions for Safe Handling and Use ************** ********************************************************* Steps to be taken in case of release or spill: A release or spill of this material would not constitute a safety hazard. Waste disposal method: In accordance with local regulations for disposal of ncnhazardcus waste. Precautions to be taken in handling and storage: Store at temperatures <150o F. Other precautions: NA Page 2 DO 085433 CONFTDENTIAl FIRESTONE SYNTHETIC RUBBER & LATEX CO. MATERIAL SAFETY DATA SHEET STEREON 730A *********************************************************************** S**e*c*t*io*n**I*X**-**O**t*h*e*r*R**e*g*u*l*a*t*o*ry***In*f*o*r*m**a*t*io*n******************************* SARA: This product does not contain any chemicals reportable under SARA Title III, Section 313. WHMIS: This product does net meet any of the criteria of a controlled product, as defined by WHMIS. DOT: Not regulated as a hazardous material. *********************************************************************** S**e*c*t*io*n**X***- **L*a*b*e*l*in*g**************************************************** No special labeling required. If special labeling is requested, please call number below. *********************************************************************** S**e*c*t*io*n**X**I **- **C*o*m*m*e*n*ts*************************************************** None Prepared by: Robert X. Richmond Phene: (216) 379-7150 Date: 7/31/90 Reviewed ( )/ Revised (x) Date: 9/23/91 The information contained in this material safety data sheet is based on data and recommendations considered accurate, in some cases, the information has been obtained from other organizations and companies. However, no warranty or representation is expressed or implied that the information is accurate, complete, or representative. Bridgestone/ Firestone assumes no responsibility for injury to buyer, the buyer's employees, or any third persons, if reasonable safety procedures are not followed. Additionally, Bridgestone/Firestone assumes no responsibility for injury to buyer, the buyer's employees, or any third persons, if such injury Is the result of abnormal use of the material, even if reasonable safety procedures are followed. DO 085434 CONFIDENTIAL firestone SYNTHETIC RUBBER & LATEX COMPANY aui** tJaiEBiaL-SfiEEIX-fiAIA-SUEEI PRODUCT IDENTIFICATION CAS No. 9003-55-8 CHEMICAL FAMILY: Poly(butadiene-co-styrene) SECIIQN_I Emergency Telephone Number: (800) 424-9300 Telephone Number For Information: (216) 379-6018 Date Prepared: January 14, 1987 SEGIIQU-lI_=_tiezaBBQU5-XUGBEBIEUISZI&EUim_SECIlQtf Hazardous Components 0SHA ACGIH IChemicai-aDd.CQtDUQn-tiamesl Eci*____ EEI______ILY_____ Qltiei None SECIIDN_III.z-EHTSIC6LZCHEbIC6L_C0aB6CIEBISIICS Boiling Point: NA(Not Applicable) Sp. Gravity<H20=1): 0.93 Vapor Pressure(mm Hg): NA Melting Point: NA Vapor Density(Air=1): NA Evaporation Rate: NA Solubility in Uater: Nil (Butyl acetate = 1) Appearance and Odor: Rubbery, white solid; sLight odor. SECIIQfcLIY_z_EIBE_AND_EXELQSIQN_HazaBD_Daia_ Flash Point(Method):.NA Flammable Limits - LEL: NA UEL: NA Extinguishing Media: Uater or foam. Special Fire Fighting Procedures: Use self-contained breathing app Unusual Fire and Explosion Hazards: None Combustion Byproducts: Oxides of carbon FIRESTONE SYNTHETIC RUBBER & LATEX COMPANY # P.O, BOX 26611 AKRON, OHIO 44319-0006 TELEX NO 986467 A DIVISION OF THE FIRESTONE TIRE 4 RUBBER COMPANY 17 DO 08*5435 C0NFIDFNTTA! firestone SYNTHETIC RUBBER & LATEX COMPANY SECiiQH-y_=-REacmm_Daifi Material Is Unstablet > Stable(X) Conditions to Avoid: NA IncoMpatibiLitytMaterials to Avoid): NA Hazardous Decomposition: NA Hazardous Polymerization May Occur( ) Will Not Occur(X) Conditions to Avoid: NA SECIlQti.yi-r-tiEALIti-UfiZfiBB.QAIA Route(s) of Entry: Inhalation( ) Skin< ) Ingestion( ) NA Health HazardstAcute and Chronic): None Carcinogenicity: NTP( ) IARC Monographs< ) OSHA Regulatedt ) i Signs and Symptoms of Exposure: NA Medical Conditions Generally Aggravated by Exposure: NA Emergency and First Aid Procedures: NA <S-721) FIRESTONE 5YNTHETIC RUBBER & LATEX COMPANY PO BOX 2W11 AKRON, OHIO 4431X006 TELEX NO. W6467 049*01217A DIVISION OF THE FIRESTONE TIRE & RUBBER COMPANY DO 085436 DONFTDFNTT Al firestone SYNTHETIC RUBBER & LATEX COMPANY SEQIIQU_II_=_eBECflUIIQt!lS-EQR_SfiEE_UfiMm.ING_fiNB_USE SteE5_lQ_Be,,Iak.en_xn_Case_tlalei:Ifll_l5_BeLeased_ar_S&ilLedA reie or spill of this material would not constitute a safety hazard. WasB_DiSEQsai_tjeihQd: In accordance with local regulations, for disposal of nonhazardous waste. P.iecauiQns_io_Be_Tftkfin_iD-tiaiidLin2_aDd.SiQLaae: Store at temperai Less than 150 deg. F Dlher^Erecaulions: NA SECI1QM_1I1_=_CQNIBQL_MEASUBES Respiratory Protection(Specify Type): None required. Ventilation - Local Exhaust( ) Meehanical(GeneraL)( ) Sp cial( ) Other/Comments: NA Protective Gloves: None required. Eye Protection: None required. Other Protective Clothing or Equipment: None reauired. Work/Hygienic Practices: At the end of each work period and before ing, wash, with soap apd water, areas of the body coming in contact with this product. ********************W***WW*W***WM*MW*****W**M*NttKtttt** ********* The information contained herein is based on data considered accuru which has been obtained from other companies and organizations. Hoy no warranty or representation is expressed or implied that the infc mation is accurate, complete, or representative. Firestone assumes responsibility for injury to buyer, the buyer`s employees, r any 1 persons, if reasonable safety procedures are not followed. Additioi Firestone assumes no responsibility for injury to buyer, the buyer' employees, or any third persons caused by abnormal use of the matei even if reasonable safety procedures are followed. <S FIRESTONE SYNTHETIC RUBBER & LATEX COMPANY P.O. BOX 26611 AKRON, OHIO A43H-OOOB TELEX NO. 96M4T A DIVISION OF THE FIRESTONE TIRE i RUBBER COMPANY DO 085437 CONFIDENTIAL MAR-06-'92 FRI 10:55 ID:DCW CHEMICAL POLY A TEL NO:FAX 504 389 0765 0800 P06 PAGE 1 material safety data sheet CIBA-GEIOY CORPORATION ADDITIVES DIVISION SEVEN SKYLINE DRIVE HAWTHORNE, NEW YORK 10532 C91R1 367-6700 EMERGENCY PHONE HUMBERi (BOO) B88-S372 SECTION I-IDENTITY INFORMATION IDENTITY (TRADENAME) IRGANOX 1076 FAMIIY/CHEMICAL NAME* UTYl-4-HYDROXYHYDROCINNAMATE PRwuw r b ANTIOXIDANT. IMPORTANT PLEASE NOTE* REVISION 08 - SECTION IX REVISED. XXKXXXKXXXKKXXXXXXXXXXXXXXXXKK X THIS MATERIAL WILL NOT BE SOLD FOR USE IN PRODUCTS X X FOR WHICH PROLONGED CONTACT WITH MUCOUS MEMBRANES OR X X ABRADED SKIN, OR IMPLANTATION WITHIN THE HUMAN BODY, IS X x SPECIFICALLY INTENDED. BECAUSE OF THEHIDE RANGE OF X X SUCH POTENTIAL USES, CIBA-GEIGY CORPORATION IS NOY'ABLE X X TO RECOMMEND THIS MATERIAL AS SAFE ANDEFFECTIVE FOR X X SUCH USES AND ASSUMES NO LIABILITY FOR ANY SUCH USES. X XXXXXXXXXXXKXXXXXKXXXKXXXXXXKX HAZARD STATEMENT XXXXKXXXKKXKXKXXKXXXXKXXXXXMXX X THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN X X PREPARED IN COMPLIANCE WITH THE FEDERAL OSKA HAZARD X X COMMUNICATION STANDARD 29 CFR 1910.1200. X X THIS PRODUCT IS NOT CONSIDERED TO BE A HAZARDOUS X X CHEMICAL UNDER THAT STANDARD. X MKXXXXKXXXXXXKXXXXKXKXXXXXXKXX SECTION II-HAZARDOUS INGREDIENTS NONE KNOWN. ZROANOX 1076 DO 085438 CONFIDENT TAl MAR-06-'92 FRI 10:54 IDiDOLJ CHEMICAL POLY A TEL NO:FAX 504 389 0765 tt800 P05 PAGE 2 SECTION III-PHYSICAL DATA APPEARANCE: WHITE TO OFF-HHITE, CRYSTALLINE POWDER. ODOR: ODORLESS. BOILXNO POINT: NOT DETERMINED. MELTING POINT: 50-55C DECOMPOSITION TEMPERATURE: >220C. EVAPORATION RATE: NOT APPLICABLE. PERCENT VOLATILE: <1 VAPOR DENSITY: NOT APPLICABLE. VAPOR PRESSURE: AT 20C# CA. 2 X 10t-9) CMM HO) SOLUBILITY IN MATER: AT 23C, INSOLUBLE PH i NOT APPLICABLE. SPECIFIC ORAVITY: CA. 1.02 (H20 1) ______________ ________ SECTION IV-FIRE AND EXPLOSION HAZARD DATA FLASH POINT: 523F (MARCUSSON) FLAMMABLE LIMITS IN AIR-LOWER: NOT DETERMINED. FLAMMABLE LIMITS IN AIR-UPPER: NOT DETERMINED. NFPA CODE: NONE. EXTINGUISHING MEDIA: CARBON DIOXIDE: FOAM, DRY CHEMICAL, MATER SPRAY. FIRE FIGHTING PROCEDURES-SPECIAL: USE SELF-CONTAINED BREATHING APPARATUS. UNUSUAL FIRE AND EXPLOSION HAZARDS: THE PRODUCT CAN FORM AN EXPLOSIVE DUST/AIR MIXTURE. AVOID DUST FORMATION AND CONTROL IGNITION SOURCES: EMPLOY OROUNDXNO, VENTING AND EXPLOSION RELIEF PROVISIONS IN ACCORD WITH ACCEPTED ENGINEERING PRACTICES IN PROCESS OPERATIONS CAP ABLE OF GENERATING DUST AND/OR STATIC ELECTRICITY. SECTION V-REACTIVITY DATA STABILITY: STABLE. IRGANOX 1076 DO 085439 CONFIDENTIAL MAR-06-'92 FRI 10:54 ID:DOW CHEMICAL POLY A TEL NO:FAX 504 389 8765 #800 P04 PAGE 3 INCOMPATIBILITY. STRONG OXIDIZING AOENTS. HAZARDOUS DECOMPOSITION PRODUCTS. THERMAL DECOMPOSITION AND BURNING MAY PRODUCE CARBON MONOXIDE AND CARBON DIOXIDE. HAZARDOUS POLYMERIZATION HILL NOT OCCUR. SECTION VI-HEALTH HAZARD DATA PRIMARY ROUTES OF EXPOSURE. DERMAL* INGESTION, AND INHALATION. THRESHOLD LIMIT VALUE. NONE ESTABLISHED. ORAL LDSOi (RATS) >10,000 MQ/KG INTRAPERITONEAL LD50. (RATS) >1000 MO/KG DERMAL LD50. (RABBITS) >2000 MQ/KQ SKIN IRRITATION. (RABBITS) MINIMAL (DRA1ZE SCORE 0.95/8) PHOTOTOXICITY. NEGATIVE. EYE IRRITATION. (RABBITS) MINIMAL (DRAIZE SCORE 4/110) SENSITIZATION. (GUINEA PIGS) CONSIDERED TO POSSESS NO SKIN SENSITIZING POTENTIAL. RIPT (HUMANS) IN A SEPARATE STUDIES, A TOTAL OF 3 OF 183 SUBJECTS EXHIBITED REACTIONS INDICATIVE OF SENSITIZATION) CONCENTRATIONS RANGED FROM 25X IN PETROLATUM (25 SUBJECTS), IN DIMETHYL PHTHALATE (58 SUBJECTS), TO NEAT MATERIAL (100 SUBJECTS). INHALATION LC50 (RATS) >1.8 MG/l AIR FOR A 4-HOUR DUST EXPOSURE WITH APPROX. 90X OF PARTICLES <7 MICRONS DIAMETER. TERATOGENICITY. (RATS) NO TERATOGENIC EFFECT SEEK. (MICE) NO TERATOGENIC EFFECT SEEN. MUTAGENICITY. AMES TEST. NEGATIVE DOMINANT LETHAL TEST (MOUSE). NO EVIDENCE OF A DOMINANT LETHAL EFFECT. SIGNS AND SYMPTOMS OF EXPOSURE-ACUTE. CAUTION!! MAY CAUSE IRRITATION TO SKIN, ESPECIALLY AFTER PROLONGED OR REPEATED EXPOSURE, AND ESPECIALLY IN BODY AREAS OF HEAVY PERSPIRATION, BASED UPON USE EXPERIENCE. SIGNS AND SYMPTOMS OF EXPOSURE-CHRONIC. NO IDENTIFIED HEALTH EFFECTS. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE. SKIN CONDITIONS. EMERGENCY AND FIRST AID PROCEDURES-EYES 0.5X IRGANOX 1078 DO 085440 CONFTDFNTIAL MftR-06_,92 FRI 10s53 ID:DOW CHEMICAL POLY A TEL NO:FAX 504 389 8765 8800 P03 PAGE 4 PLUSH EYES WITH WATER FOR AT LEAST 13 MINUTES. GET MEDICAL ATTENTION. EMERGENCY AND FIRST AID FROCEDURES-SKIN WASH WITH MILD SOAP AND HATER. EMERGENCY AND FIRST AID PROCEDURES-INQESTION. IF CONSCIOUS^ GIVE LARGE QUANTITIES OF WATER. GET MEDICAL ATTENTION. EMERGENCY AND FIRST AID PROCEDURES-INHALATION REMOVE TO FRESH AIR. EMERGENCY AND FIRST AID PROCEDURES-OTHERi REMOVE AND HASH CONTAMINATED CLOTHING PRIOR TO REUSE. _______________________ SECTION VJI-SPILl OR LEAK PROCEDURES _ SPILL PROCEDURES* PREWET MATERIAL WITH WATER TO AVOID DUST FORMATION. SHEEP OR VACUUM AND PLACE IN CLOSADLE CONTAINER FOR DISPOSAL. WEAR PROTECTIVE EQUIPMENT SPECIFIED BELOW. FLUSH RESIDUE WITH HATER. WASTE DISPOSAL METHODS* INCINERATE IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTER BURNER AND SCRUBBER. FOLLOW ALL FEDERAL. STATE AND LOCAL REGULATIONS. EFFLUENT DATA-BOD* (STURM TEST) PARTIALLY BIODEGRADABLE. SEHAOE BACTERIAL TOXICITY* INHIBITORY CONCENTRATION ON RESPIRATION OF AEROBIC HASTE WATER BACTERIA* IC20 IC50, ICBO >100 PPM FISH TOXICITY* BLUEOILL LC 50 (96 HOURS)* >100 PPM RAINBOH TROUT LC 50 (96 HOURS)* >100 PPM INVERTEBRATE TOXICITY. DAPHNIA MAONA EC50 (24 HOURS)* >100 PPM SECTION VIII-SPECIAL PROTECTION INFORMATION ___________________________ VENTILATION* USE LOCAL EXHAUST. GOOD VENTILATION IS REQUIRED TO PRFVENT DUST BUILDUP WHICH MAY RESULT IN WORKER IRRITATION. PROTECTIVE OLOVESt NEAR RUBBER OR PLASTIC GLOVES. EYE PROTECTION* WEAR SAFETY GLASSES OR GOGGLES. RESPIRATORY PROTECTION* USE NIOSH APPROVED DUST MASK. OTHER PROTECTIVE EQUIPMENT* WEAR COVERALLS. SECTION IX-SPECIAL PRECAUTIONS HMIS CODE* HEALTH * 2 HANDLING PRECAUTIONS* FIRE > 1 REACTIVITY i 0 IRGANOX 107' DO 085441 CONFIDENTIAL MAR-06-'92 FRI 10:53 ID:DOUJ CHEMICAL POLY A TEL NO:FAX 504 389 8765 0800 P02 PAGE 9 AVOID CONTACT WITH EYES AND PROLONGED OR REPEATED SKIN CONTACT. AVOID CONTINUOUS OR REPETITIVE BREATHING OF DUST. GOOD INDUSTRIAL ENGINEERING CONTROLS MUST BE EMPLOYED TO PREVENT EXCESS DUSTING IN THE WORK AREAS. DO NOT HANDLE ZN SUCH A MANNER AS TO CAUSE EXCESSIVE DUSTING. USE ONLY HITH ADEQUATE VENTILATION. FOR INDUSTRIAL USE ONLY. SHIPPING AND STORING PRECAUTIONS: KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE AND DURING TRANSPORT. PERSONAL HYGIENEr HASH THOROUGHLY AFTER HANDLING. SECTION X- REGULATORY INFORMATION DOT PROPER SHIPPING NAME: NOT REGULATED AS A HAZARDOUS MATERIAL BY THE U.S. DEPT. OF TRANSPORTATION (DOT) 49 CFR 172.10) HAZARDOUS MATERIALS TABLE. DOT CLASS: NONE. DOT NUMBER: NONE. RCRA STATUS: NOT A HAZARDOUS WASTE UNDER RCRA (40 CFR 261). CERCLA STATUS: NOT LISTED. SARA/TITLE III - TOXIC CHEMICALS LIST: THIS PRODUCT DOES NOT CONTAIN A TOXIC CHEMICAL FOR ROUTINE ANNUAL 'TOXIC CHEMICAL RELEASE REPORTING* UNDER SEC. 313 (40 CFR 372). TSCA INVENTORY STATUS: CHEMICAL COMPONENTS LISTED ON TSCA INVENTORY. CALIFORNIA PROPOSITION 65. THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS CURRENTLY ON THE CALIFORNIA LIST OF KNOWN CARCINOGENS AND REPRODUCTIVE TOXINS. MASSACHUSETTS RIGHT-TO-KNOW ACT: CONTAINS NO COMPONENTS ON THE MASSACHUSETTS LIST AT A THRESHOLD LEVEL. NEW JERSEY RIGHT-TO-KNOW LABELING INFORMATION: THIS PRODUCT CONTAINS THE FOLLOWING : CHEMICAL NAME : OCTADECYL 3,5-DI-TERT-BUTYL-4-HYDR0XYHYDR0CI NNAMATE CAS NUMBER : 2082-79-3 XKK PENNSYLVANIA RIGHT-TO-KNOW ACT: THE FOLLOWING IS REQUIRED COMPOSITION INFORMATION. CHEMICAL NAME : BENZENEPROPANOIC ACID, 3,5~BIS(1,1-DIMETHYLE THYL)-4-HYDROXY-, OCTADECYL ESTER CA5 NUMBER : 2082-79-3 COMMON NAME . OCTADECYL 3,5-DI-TERT-BUTYL-4-HYDR0XYHYDR0CI IRGANOX 1076 DO 08544? CONFTDFNTTAl MAR-06-'92 FRI 10:52 ID:DOW CHEMICAL POLY A TEL NO:FAX 504 389 8765 8800 P01 PAGE 6 COMMENTS NNAMATE; IRGANOX 1076 i NOT ON PENNSYLVANIA HAZARDOUS SUBSTANCE LIST. MKX ISSUE DATE: 04/05/90 REVISION' 09C FOR FURTHER INFORMATION* PLEASE CONTACT. BRUCE SCMWEMMER THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA BELIEVED TO BE CORRECT. HOWEVER. NO GUARANTEE OR WARRANTY OF ANY KINO EXPRESSED OR IMPLIED IS MADE WITH RESPECT TO THE INFORMATION CONTAINED HEREIN. IRGANOX 1076 D0 08SA43 confidential PRODUCT SAFETY DATA SHEET TRADE NAME ESSO SA.F. 2. Rue dee Martinet* 92S88 RUEIL MALMAISON CEOEX Presentation and rules of drafting complying to the atandard NF T 01-100 SPECIFIC RISKS 1 IDENTIFICATION 1.1 Commercial name; 1.2 Supplier 1.3 Types ef use (for other information, saa the technical ahaet) 1.4 Other data: 1 } 2 CHEMICAL CONSTITUTION 1 OF THE PRODUCT i 1 *' | to hazard : Other data: PLASTOL 135 ESSO $A.F. Tele* : 770827 F Extender for elastomers and plastics None Tel.: 35.74.70A3 Solvent extracted and hydrogenated paraffinic mineral oil Nono None 3 PHYSICAL PROPERTIES 3.1 Physical state: 3J2 Chsrsctsrlstlc temperature: 3.3 Solubility: 3.4 pH ; 3J5 Vapour presaure ; 3.6 Density : 3.7 Other data: Liquid, colourless, odourless Initial boiling point : 330'C Insoluble In water N.A. at 20'C : -i 0.1 mbnr (10 Pa) 852 kg/m3 at ISX Viscosity at dO'C : 25 mm2/s . ........ .`.r 1 im MR Ifni fill* k* J i uimuk Any i tntivkii*v 4.1 Precautions during storage and Handling : 4.2 Materials for packaging or bottling ; 4J Hazardous reactions with ; 4.4 Hazardous decomposition products ; 4.5 Individual protective measures : 4.6 Special protective measures;. 4.7 Measures altar spillage or leakage : 4.8 Other recommendations; o not store with flammable products . Keep containers closed when not in use . Take extreme care to avoid contamination by other products and material. Only use hydrocarhon resistant materials Strong oxidants (liquid chlorine, concentrated oxygen). Product does not decompose at ambient temperature. Wear safety glassos. None Recover by pumping pnd/or with absorbent! and frClHCrst* mafortaf nfiffar r.nnlro/frtd condition! ensuring conformity with iocai dispuvui leyuieiiuu*. Do not use dispersants In case of risk of contamination of the environment 00 o85444 CONFrDpNTTAi U3/U7 U2 10:03 tX33 35 74 71 00 Nme of product : PLASTOL 135 K55U LIUJU UI003 J> - mi slAumurr!!tAii ft*im* cMv.n. taA*emM 5.1 Flesh point: 5.2 Sell-Ignition temperature: 5.3 Special lira end explosion nezards : 6.4 Extinguishing media: 5.5 Special fire protective mesauras: 5.5 Other recommendation* ; > 200*C (open cup) > 250*C Ci JiwCc C.vtcr. rr.cr.rtitc zr.i :"?*'* ~""r r Incomplete combustion. Foam - carbon dioxido - dry chemical powder. Use supplied - air respiratory protection for lire lighting personnel exposed to fumes or smoke Avoid heat sources, open flames and other sources of Ignition. 6 TOXICOLOGICAL INFORMATION 7 FIRST AID PROCEDURES JL - Inhalation : No hazard In normal industrial use. Inoesticn : No hazard in normal Industrial use. Skin contact: Not considered to be a hazard. Eve contact: Nui uuiibtuwvd to be a hazard. OccuDatfonal Excosure Umlt: 5 mo/ m3 for oil mist (TWA. 8h - workday) recommended based upon the ACOIH TLV. - Inhalation : at ambient I normal handlino temperatures (O-SS'Cl no adverse effects due to inhalation cl vapeur are expected Incestfon : No adverse effect* due to ingestion are expected. - Skin contact: No adverse effects due to skin contact are expected. Eve contact: No adverse effects due to eye contact are expected 8 ECOLOGICAL INFORMATION - Waste dtsDosat: Incinerate absorbed material under controlled conditions. * ,# -- ji****i sn.j nMAupA FF)Rrnmlh/ wifh local disposal regulations 9 SPECIAL INFORMATION Steps In case or Accidental Release LAND SPILL : Prevent liquid from entering sewers, water courses or low areas. Shutt off source taking normal safely precautions. Advise relevant authorities If material nas entered a water course or sewer or has contaminated soll-er-vegetation. Take measures to minimise the effects on the ground water, Recovor by skimmfng/pumprng (use exploslon-prpor devfee) or conteln spilled liquid with booms/sand or other suitable absorbents and remove mechanically into containers. WATER SPILL: Warn elhor shipping. Notify port or other relevant i: rrtnftnr. If CCirltle v."'h hoTM"*. Remnv* from surface by skimming or tvfth suitable absorbents. If allowed by local aulhorites and environmental agendas, sinking anchor suitable dispersants may be used if non-confined waters. Tfr/t sheet complete* the technic*! sheet or use but does not replace n. The information contained In this sheet are baaed on our knowledge of the product at the date JULY 3 1992. They are given quite sincerely. Moreover the attention of the users is drawn on the risks possibly taken when a product it used for other uses than those for which it Is intended. DO 085445 CONFIDENTIAL EfcON CHEMICALS MATERIAL SAFETY DATA SHEET EXXON CHEMICAL COMPANY POLYMERS GROUP . P.O. SOX J272. HOUSTON, TEXAS 77001 A DivKion of EXXON CORPORATION 10/20/87 N0.OW1SOOOO SECTION I PRODUCT IDENTIFICATION & EMERGENCY INFORMATION PRODUCT NAME POLYMER MODIFIED ASPHALT CHEMICAL name Polymer Modified Petroleum Asphalt CHEMICAL FAMILY Petrochemical polymers blended with asphalt PRODUCT APPEARANCE Semi-solid whsn cold, viscous fluid whsn hot; Character let 1c asphaltic odor black color EMERGENCY TELEPHONE NUMBERS; EXXON CHEMICAL COMPANY CHEMTREC 713-870-6000 800-424-9300 SECTION II HAZARDOUS INGREDIENT INFORMATION This product Is hazardous as'defined In CFR1910.1200. OSHA HAZARD ACGIH TLV ACGIH TLV For additional information sss Sactlon III. SECTION III HEALTH INFORMATION AND PROTECTION MATURE OF HAZARD EYE CONTACT: Exposure to hot material may cause thermal burns. SKIN CONTACT: Exposure to hot material may cause thermal burns. INHALATION: High vapor concentrations are irritating to the eyes and the respiratory tract, may cause headaches and dizziness, are anesthetic and may have other central nervous system effects. Highly toxic at high Hydrogen Sulfide concentrations. INGESTION: No hazard in normal Industrial use. FIRST AID EYE CONTACT: Immediately flush eyes with large amounts of water for at least IS minutes. Get prompt medical attention. SKIN CONTACT: For hot product, Immediately Immerse In or flush affected area with large amounts of cold water to dissipate heat. Cover with clean cotton sheeting or gauze and get prompt medical attention. For hot product, no attempt should be made to remove material from skin or to remove contaminated clothing, as the damaged flesh can easily be torn. INHALATION: Using proper respiratory protection, immediately remove the affected victim from exposure. Administer artificial respiration If breathing is stopped. Keep at rest. Call for prompt medical attention. INGESTION: TXll OTHER INFORMATION MATERIALS RELATES OR IN ANY TO THE SPECIFIC PROCESS. SUCH MATERIAL DESIGNATED INFORMATION It TO THE AND MAY BEST OP **8ubEBMVO--AV--LL-EI-DO--O--SFOARNOSUBCHILMIIAPT,ERAICALe DATS TXf UCtOilM'SP. i_LC*sIwOSirnH0OvN*Vl(1ITV|Ss1pnl|ATi ViMeOvTOnPisMSrACaTStInSiMnFtYiAnTMiiIvOtHwMSi,KtVt AAftSftATNOi trTwWOnf|t wSOUUaAITnSAAaMBsTIiLtuCITYiIsSAMbMfPAwDCeI OAM*S PTilfOvTtNuITftpSS*AC0C* USRUACCHYi, IMRSf0tL*MIAAf'> Utt. n 00 MOT ACCIPT LIABILITY SOM AMY LOSS Ol DAMAGI THAT MAY OCCUt FROM THt USl OP THIS IMPONMATIw, AGAINST PATtMT IMPPIMOMMT, DO 085446 CONFIDENT! Al.j .w(l OFFER warranty EfcON CHEMICALS 10/20/87 MATERIAL SAFETY DATA SHEET POLYMER MODIFIED ASPHALT PAGE: 2 ,5 NO. Owl 50000 WORKPLACE EXPOSURE LIMITS THE ACGIH RECOMMENDS THE FOLLOWING OCCUPATIONAL EXPOSURE LIMIT: a TWA of 5 mg/m3 for Asphalt (petroleum) fumes. A TWA of 10 ppm (14 mg/m3), and a STEL of 15 ppm (21 mg/m3) for Hydrogen Sulfide. PRECAUTIONS SPECIAL PRECAUTIONS Contact with this product at warm or ambient temperatures may cause eye irritation but will not damage eye tissue. First Aid Is to flush eyes with large amounts of water until irritation subsides. If irritation persists, get medical attention. Prolonged or repeated contact with this product at warm or ambient temperatures may cause skin irritation and dermatitis. First Aid is to flush with large amounts of water; use soap If available. Under certain clreumstances sulfur compounds in hot product may form hydrogen sulfide (H2S) gas. Cooling product may continue to emit traces of H2S temporarily from entrapped or dissolved gases. H2S is a colorless, toxic and extremely flammable gas with an odor at low concentrations characteristlc of rotten eggs and a sweetish odor at high concentratIons. Odor cannot be relied upon as a means of detection because the sense of smell rapidly becomes Insensitive to H2S, and the H2S odor may be masked by the general odor of hot product. Because H2S may accumulate in tanks and bulk transport compartments, personnel should stand upwind, keep their faces at least two feet from compartment openings and avoid breathing vapors when opening hatches and dome covers. (In a large number of tests, permissible concentrations In the breathing zone were not exceeded by following this procedure.) Prolonged breathing of 50 to 100 ppm of H2S may produce eye and respiratory tract irritation, headache, nervousness and nausea, and only a few breaths of high concentrations (e.g. 700 to 1000 ppm) may lead to unconsciousness and could be fatal. PERSONAL PROTECTION For open systems where contact is likely, wear chemical resistant gloves, a chemical suit, rubber boots, and chemical safety goggles plus a face shield. Where contact may occur, wear long sleeves, chemical resistant gloves, chemical goggles, and a face shield. Where contact may occur with hot materials, wear thermal resistant gloves, arm protection and a face shield. Where concentratIons in air may exceed the limits given In this Section and engineering, work practice or other means of exposure reduction are not adequate, NIOSH/MSMA approved respirators may be necessary to prevent overexposure by inhalation. VENTILATION Local exhaust ventilation of process equipment may be needed to control particulate exposures to below the recommended exposure limit. See personal protection recommendations. SECTION IV FIRE ft EXPLOSION HAZARD FLASHPOINT: Greater than 350 DEG F METHOD; COG FLAMMABLE LIMITS: Not available I AUTOIGNITION TEMPERATURE: Greater than 500 DEG F EJgON CHEMICALS 10/20/87 MATERIAL SAFETY DATA SHEET POLYMER MODIFIED ASPHALT mm 3 NO.OV150000 GENERAL HAZARD Solid material, may burn at or above the flaahpolnt, and airborne dust may explode if ignited . If thermally decomposed, flammable/toxic gases may be released. Toxic gases will form upon combustion. Static Discharge, material can accumulate static charges which can cause an incendiary electrical discharge . FIRE FIGHTING Use water spray to cool fire exposed surfaces and to protect personnel. Isolate "fuel* supply from fire . Respiratory and eye protection required for fire fighting personnel. Do not use water on fire, due to potential evolution of toxic fumes or dangerous reactions. Avoid spraying water directly into storage containers due to danger of bollover. DECOMPOSITION PRODUCTS UNDER FIRE CONDITIONS Incomplete combustion: fumes, CO, H2S, sulfur oxides, and aldehydes SECTION V SPILL CONTROL PROCEDURE LAND SPILL Eliminate sources of ignition. Prevent additional discharge of material. If possible to do so without hazard. For small spills Implement cleanup procedures; for large spills Implement cleanup procedures and, If In public area, keep public away and advise authorities. Also, if this product is an EPA hazardous substance (See Section X, Page 4) notify the U.S. EPA If appropriate. Recover spilled material and place in suitable containers for recycle or dispose 1. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. WATER SPILL Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. SECTION VI NOTES HOT ASPHALT FLASH WARNING Studies have shown that relatively low flash point substances, such as hydrogen sulfide and low-boiling hydrocarbons, may accumulate In the vapor space of hot asphalt tanks and bulk transport compartments. Such vapors may exhibit flammability characteristics of a significantly lower flash point product than would be indicated by the open cup flash test. As a precauti n, keep Ignition sources away from vents and openings. Including preventl n of accumulation of pyrophoric iron sulfide. Asphalt Institute Publication IS-180 and American Petroleum Institute Publication 852-20230 contain further information and guidance on the safe storage and handling of hot asphalt. E*ON MATERIAL SAFETY DATA SHEET PAGE3A CHEMICALS 10/20/87 POLYMER MODIFIED ASPHALT SECTION VII REGULATORY INFORMATION NQ.OwlSOOOO TSCA: This product Is listed on the TSCA Inventory. CERCLA: Under the Comprehensive Response. Compensation, and Liability Act, (CERCLA), c rtain releases to air, land, or water may be reportable to the National Response C nter at 800-424-8802. Circumstances surrounding the release and cleanup determln reportablIty. This product is not subject to CERCLA reporting requirements. SARA TITLE III: Under the provisions of Title III, Sections 311/312 of the Superfund Amendments and Reauthorizatlon Act, this product Is classified into the following hazard categories: Immediate health. Delayed Health. DO 085449 oonfidenttai EfrON CHEMICALS MATERIAL SAFETY DATA SHEET 10/20/87 POLYMER MODIFIED ASPHALT PAGE 4 NO. owl 50000 SECTION VIII SP -Pr66'-T^05 P 60 R,F- T,WP ' f TYPICAL PHYSICAL & CHEMICAL PROPERTIES N/APQA PRESSUWS^mmHg < '/ ^ 0.1 tit gB Lin than SOLUBILITY IN WATER, WT. % at ' F Insoluble VISCOSITY OF LIQUID, eST at 'F 6,000 at 375 Maximum SP. GRAVITY OF VAPOR, at 1 ATM AIR-1 Not Available EVAPORATION RATE. n-BU ACETATE-1 Less than 0.01 FREEZING MELTING POINT/RANGE, "F Not Available BOILING POINT/RANOE, 'F 800 Initial Bolling Point SECTION IX STABILITY? Stable CONDITIONS TO AVOID INSTABILITY Strong oxidants such as 1Iquld chlorine, concentrated oxygen, sodium hypochlorite or calcium hypochlorite Rl^ACTIVITY DATA HAZARDOUS POLYMERIZATION OCCUR? Will not occur CONDITIONS TO AVOID HAZARDOUS POLYMERIZATION Not applicable MATERIALS AND CONDITIONS TO AVOID INCOMPATIBILITY Hot product in contact with water can cause foaming or sudden evolution of steam which could cause pressure build-up and possible rupture a tank or vessel, H2S from product can react with Iron to form pyrophoric products. HAZARDOUS DECOMPOSITION PRODUCTS H2S and low-boiling hydrocarbons SECTION X U.S. DOT CLASSIFICATION ORM-C above Flash Point TRANSPORT AND STORAGE UN NUMBER ELECTROSTATIC ACCUMULATION HAZARD ____Yftft __use proper arounrllnn nrncartufa STORAGE TEMPERATURE, ' F Not available STORAGE/TRANSPORT PRESSURE, mmHg Not available SECTION XI LOADING/UNLOADING temperature, 'F Not available VISCOSITY AT LOADING/UNLOAOING TEMPERATURE.cST Not available OT HER INFORMATION REFERENCE NUMBER HDHA-D-11011 DATE PREPARED JUNE 16,1888 FOR ADDITIONAL PRODUCT INFORMATION CONTACT YOUR TECHNICAL SALES REPRESENTATIVE FOR ADDITIONAL HEALTH/SAFETY INFORMATION CALL 71I-S76-SSSS SUPERCEDES ISSUE DATE OCTOBER 20.1887