Document 91pNLGEnLgyd1XabnV827DRm7

DOW CHEMICAL U.S.A. TEXAS OPERATIONS FREEPORT, TEXAS 77541 January 30, 1990 W. M. Huff EDC/NPA A-7001 Building xc: C. K. Browdy, B-101 0. E. Cragar, B-101 R. A. Jones, OC-1120 J. H. Lippman, OC-1120 W. J. Turney, A-7001 OCCUPATIONAL HEALTH PROTOCOL FOR ETHYLENE DICHLORIDE/NORTH PROCESS* AREA (EDC/NPA), A-7001; IHS FILE A70-3581-89 The protocol which outlines the two-year Occupational Health Program for EDC/NPA is enclosed. The program provides a basic strategy for industrial hygiene monitoring, health hazards training and medical surveillance. Matthew J." Sorrells Industrial Hygiene Services B-101 Building R&S153870 AN OPERATING UNIT OF THE DOW CHEMICAL COMPANY =Quality=_ Performance Means More At Dow OCCUPATIONAL HEALTH PROTOCOL DOW CHEMICAL COMPANY TEXAS OPERATIONS PROTOCOL STATUS ' _JL PRELIMINARY FILE NUMBER: A70-3581-89 DATE: 01/10/90 LOCATION: A-7001 PLANNED STARTING DATE: 01/30/90 REVIEW DATE: DECEMBER, 1990 PLANNED COMPLETION DATE: DECEMBER, 1991 j/_ FINAL SIGNATURES: Prepared By:. M. J.^SorrlHJs, Industrial Hygiene Reviewed By : C. k. Browdy, Occupational Health U) f------ T. W. Parsons, Industrial Hygiene Date: /? 9oDate: U-zj - Date:: fo Accepted By: --------------------------- --------- Date: W. fl.'Huff^C/NPA OCCUPATIONAL HEALTH PROTOCOL ETHYLENE DICHLORIDE/NORTH PROCESS AREA TABLE OF CONTENTS PAGE INTRODUCTION........................................................................................................... 1 REVIEW OF PAST MONITORING DATA.................................................................. 1-4 EVALUATION CRITERIA......................................................................................... 5-6 APPENDIX SUMMARY.................................................................................................. 7 APPENDIX A: IndustrialHygiene Surveillance Program..................... 8-10 APPENDIX B: Industrial Hygiene Education Program......................... 11 APPENDIX C: Medical Surveillance Program............................................ 12 APPENDIX D: Occupational Health Goals and Plans........................... 13 APPENDIX E: List of Chemical and Physical Agents......................... 14 APPENDIX F: Personnel Roster...................................................................... 15 APPENDIX G: Job Descriptions..................................................................... 16 APPENDIX H: Process Descriptions......................................................... 17 - 18 \ IHS FILE B54-3579-89 PAGE #1 INTRODUCTION The purpose of this protocol is to establish a two-year Occupational Health Program for EDC/NPA, A-7001. The program provides a basic strategy for industrial hygiene monitoring, health hazards training and medical surveillance for employees assigned to the units. A review of the personnel roster and chemical and physical agent inventories will be conducted annually. Revisions to the protocol will be made as necessary and the complete protocol document will be reissued on a two-year basis following the consolidated audit. The results of industrial hygiene monitoring will be reported to employees as soon as possible after completion. A formal report will. be issued when all monitoring is completed. Medical surveillance will be, reported to each participating employee. Using individual medical information and pertinent industrial hygiene data, a group analysis of the entire plant population will also be conducted and reported to supervision. If any special health concerns are identified, the physician, in cooperation with supervision and industrial hygiene will jointly review the data and communicate findings to affected plant personnel. REVIEW OF PAST MONITORING DATA Personal monitoring of chemical exposures has been evaluated at EDC/NPA since 1973. The most recent data was collected in 1988 and 1989. Routine personal exposures to ethylene dichloride; 1,1,1,2 tetrachloroethane; 1,1,2,2-tetrachloroethane; 1,1,2-trichioroethane; vinyl chloride and vinylidene chloride were the stresses of major concern; however, several other chlorinated organics were evaluated as well. All average 8-hr TWA exposures were less than the exposure guidelines with the exception of ethylene dichloride. A summary of the 1988-89 monitoring results are given in Tables I and II. In 1988, the Control C Operator 8-hr TWA exposure of 3.6 ppm to ethylene dichloride exceeded the OSHA proposed Permissible Exposure Limit (PEL) of 1.0 ppm. The Control C Operator short-term exposure of 25 ppm to ethylene dichloride exceeded the OSHA proposed Short-Term Exposure Limit (STEL) of 2.0 ppm. Installation of a closed-loop sampling system was recommended to reduce employee exposure potential. Respiratory protection was made mandatory during the interim. In 1989, the Control C Operator 8-hr TWA and short-term exposures to ethylene dichloride exceeded the OSHA PEL and STEL of 1.0 ppm and 2.0 ppm, respectively with average exposures of 1.3 ppm and 5 ppm, respectively. The closed-loop sampling systems had not been installed yet to control the exposures. Respiratory protection was worn. CONFIDENTIAL R&S153873 IHS FILE A70-3581-89 CONFIDENTIAL npage TABLE I SUMMARY OF 8-HR TWA AVERAGE EXPOSURES TO CHEMICALS EDC/NPA, 1988-1989 JOS COOE / CLASSIFICATION ALPHA-DI CONTROL A OPER. 16026770 ND(<0.02) (6)* CONTROL C OPER. 16026790 0.03 (6) EC 0.03 (6) 0.81 (6) OSHA PEL 100 150 EDC 0.18 (6) 2.3 (11) 1 8-HR TWA CONCENTRATIONS (Paul MECL2 1112 TETRAS 1122 TETRAS ... 0.01 (6) ALPHA-TRI 0.03 (5) 0.01 (5) 0.01 (11) 0.01 (5) 50 ... 0.1 10 VINYL 0.03 (6) 0.03 (6) VINYLIDENE 0.05 (6) 0.11 (6) 11 LEGEND: EC = ETHYL CHLORIDE y EDO x ETHYLENE DICHLORIDE HECL2 = METHYLENE CHLORIDE 1112 TETRAS = 1,1,1,2-TETRACHLOROETHANE 1122 TETRAS = 1,1,2,2-TETRACHLOROETHANE ALPHA-TRI = 1,1,2-TRICHLOROETHANE VINYL = VINYL CHLORIDE VINYLIDENE = VIHYUDENE CHLORIDE * Number in parentheses denotes the total number of samples. IHS FILE A70-3581-89 CONFIDENTIAL R&S153875 PAGE #3 TABLE II SUMMARY OF AVERAGE SHORT-TERM EXPOSURES TO CHEMICALS DURING SAMPLE CATCHING EDC/NPA, 1988-1989 JOB CODE / CLASSIFICATION ALPHA-0I CONTROL C OPER. 16026790 KD(<0.19) <6> EC 0.22 (6) EXCURSION IKG 250 -- EDC 18 < 13) 2 SHORT- TERM CONCENTRATIONS fDcm) MECL2 1112 TETRAS 1122 TETRAS ALPHA-TRI ND(cO.IQ) (5) N0(<0.10) (5) 0.07 (11) 0.10 (5) 100 ... 3 30 VINYL 0.37 (6) VINYLIDENE ND(<0.19) (6) 5 20 LEGEND: EC = ETHU CHLORIDE EDC = ETHYLENE DICHLORIDE MECL2 = METHYLENE CHLORIDE 1112 TETRAS = 1,1,1,2-TETRACHLORQETHANE 1122 TETRAS = 1,1,2,2-TETRACKLOROETHANE ALPHA-TRI = 1,1,2-TRICHLOROETHANE VINYL = VINYL CHLORIDE VINYLIDENE = VINYLIDENE CHLORIDE * Number in parentheses denotes the total number of samples. IHS FILE A70-3581-89 PAGE #4 REVIEW OF PAST MONITORING DATA (CONT'D) Comprehensive noise surveys were carried out in 1982 and 1988. All 8-hour TWA noise exposures were well below 50% of the OSHA allowable (See Table III below). However, 1988 area data identified many areas and/or equipment that exceeded the IHG of 90 dBA as a Ceiling. As a result, the production"area of A-7001 has been designated as a hearing protection area until engineering controls can reduce the noise levels below 90 dBA. Sound muffling devices are currently being investigated to reduce bleed valve noise. TABLE III SUMMARY OF AVERAGE EXPOSURES TO NOISE EDC/NPA, 1988 OB CODE/ CLASSIFICATION NUMBER OF SAMPLES Prodn Maint Foremn 4 Instrument Techn 5 Control Operator C 5 % OF OSHA ALLOWABLE RANGE AVERAGE 9.1-33.8 18.6 9.8-28.5 15.2 9.2-29.8 17.2 OSHA PEL ACTION LEVEL 100.0 50.0 EQUIVALENT dBA LEVEL 77.9 76.4 77.3 90.0 85.0 CONFIDENTIAL ISDo CO Ol CO 00 IHS FILE A70-3581-89 PAGE #5 EVALUATION CRITERIA Industrial hygiene monitoring is performed to determine potential exposure levels both as a daily time-weighted average (TWA) and peak or short-term exposure. The results of monitoring are compared with the recommended exposure guidelines given in Tables IV-A and IV-B. These values are basedvon toxicology data and industrial experience. Threshold Limit Values (TLVs) are established by the American Conference of Governmental Industrial Hygienists (ACGIH), Industrial Hygiene Guides (IHGs) are established by Dow, and Permissible Exposure Limits (PELs) are established by the Occupational Safety and Health Administration (OSHA). They represent airborne concentrations of substances to which nearly all employees may be repeatedly exposed throughout a working lifetime without adverse effect. OSHA recently adopted most of the guidelines set by the ACGIH. Employers are required to be in compliance with the new limits by September 1, 1989, using any combination of engineering controls, work practices and personal protective equipment. Whenever feasible, engineering controls must be in place by December 31, 1992. A Short-Term Exposure Limit (STEL) is defined as a 15-minute timeweighted average exposure which should not be exceeded at any time during a work day even if the 8-hour time-weighted average is below the TLV. The Skin (S) notation refers to the potential contribution to the overall exposure by absorption through the skin including mucous membranes and eyes, either by airborne or more particularly, by direct skin contact with the substance. Repeated or prolonged contact with most organic liquids will result in drying of the skin which enhances a chemical's skin absorption properties. Skin contact should be avoided A Ceiling (C) is defined as a concentration that should not be exceeded at any time during a work day even if the 8-hour timeweighted average is below the TLV. A Dow Biological Limit Guide (BLG) represents the amount of contaminant in a worker's exhaled air, urine, blood or other appropriate biological specimen that may not be exceeded. The contaminant can be the contaminant itself, a metabolite or a biochemical change brought on by the introduction of the contaminant into the body. CONFIDENTIAL 3S3 CD CJI CO 00 IHS FILE A70-3581-89 PAGE #6 TABLE IV-A CHEMICAL AGENT EXPOSURE GUIDELINES CHEMICAL AGENT 8-HOUR TWA -(PPM) STEL (PPM) SOURCE Ethyl Chloride Ethylene Dichloride Hexachlorobenzene 1.1.2-Trichioroethane 1.1.1.2-Tetrachloroethane 1.1.2.2-Tetrachloroethane Vinyl Chloride Vinylidene Chloride 1000 1 150 ppb blood 300 ng/cm2 10 S 0.1 S 1 1 2 5 OSHA OSHA* DOW DOW ** OSHA DOW OSHA OSHA * Must be in compliance with the OSHA PEL and STEL by 09/01/89. ** Surface cleanliness guide for wipe tests TABLE IV-B PHYSICAL AGENT EXPOSURE GUIDELINES PHYSICAL AGENTS Noise GUIDELINES 90 dBA C 85 dBA (8-Hr TWA) 90 dBA (8-Hr TWA) SOURCE DOW IHG OSHA Action Level OSHA PEL The Dow Industrial Hygiene Guide is a 90 dBA Ceiling. It requires that employees wear hearing protection when exposed to continuous, intermittent or impact/impulse noise exceeding 90 dBA. Whenever exposures exceed the OSHA PEL, feasible engineering and administrative controls are required to reduce exposures. The OSHA Action Level of 85 dBA as an 8-hr TWA requires a Hearing Conservation Program. Annual audiometric testing, education and training, and other requirements are included in the program. In addition, Texas Operations Safety Standard 0-46 requires the use of hearing protection by all employees whenever the noise dose exceeds 85 dBA as an 8-hr TWA. Further details on the program are located in the "Texas Operations Hearing Conservation Program Guidelines" (1/88) CONFIDENTIAL r &SI 53878 IHS FILE A70-3581-89 PAGE #7 APPENDIX SUMMARY The surveillance program for EDC/NPA is outlined in Appendix A. The industrial hygiene"education program is described in Appendix B. Chemical and physical agents with the greatest exposure potential will be reviewed. The medical surveillance plan for the unit is outlined in Appendix C. Appendix D outlines the goals and plans for 1990 and 1991. The plans include all aspects of the industrial hygiene program. The updated list of chemical and physical agents, personnel roster, job descriptions and process descriptions are presented in Appendices E, F, G and H. CONFIDENTIAL D CJ1 00 00 C'sOi IHS FILE A70-3581-89 PAGE #8 APPENDIX A SURVEILLANCE PROGRAM 1. RATIONALE In 1990, wipe testing will be conducted for hexachlorobenzene to determine if this compound is present in the EDC/NPA process areas and if it has been tracked into the nearby buidlings, maintenance shops, etc. Also, short-term monitoring will be conducted for ethyl chloride; ethylene dichloride; 1,1,2-trichloroethane; 1.1.1.2-tetrachloroethane; 1,1,2,2-tetrachloroethane; vinyl chloride and vinylidene chloride during line and vessel opening activities. In 1991, personal and area noise monitoring will be conducted as required by Safety Standard 0-46 which requires a noise survey every three years. The last noise survey was in 1988. The survey will also ensure the effectiveness of the noise controls. In 1991 (if the closed-loop sampling systems are installed by this date), the following chemicals will be monitored for eight-hour TWA and short-term exposures: ethyl chloride; ethylene dichloride; 1.1.2-trichloroethane; 1,1,1,2-tetrachloroethane; 1,1,2,2tetrachloroethane; vinyl chloride and vinylidene chloride. The monitoring will be done to ensure the effectiveness of the closedloop sampling systems. 2. SAMPLING STRATEGY 1990 SHORT-TERM MONITORING JOB CLASSIFICATION JOB TASKS AGENTS NUMBER OF SAMPLES Control C Oper. Line clearing Prod Maint Foreman Vessel opening Foreman Ethyl chloride Ethylene dichloride 1.1.2-Trichloroethane 1.1.1.2-Tetrachloroethane 1.1.2.2-Tetrachloroethane Vinyl chloride Vinylidene chloride * Number of samples collected depends upon job size, job frequency and number of personnel involved. CONFIDENTIAL iR&S 53880 IHS FILE A70-3581-89 PAGE #9 APPENDIX A (CONT'D) 1991 8-HOUR TWA MONITORING JOB CLASSIFICATION Prodn. Maint. Foreman Control A Operator Control C Operator Instrument Techn. JOB TASKS Routine Routine Routine Routine AGENT Noise Noise Noise Noise NUMBER OF SAMPLES 4 4 6 4 AFTER CLOSED LOOP SAMPLING SYSTEM INSTALLED 8-HOUR TWA MONITORING JOB CLASSIFICATION JOB TASKS AGENTS NO. OF SAMPLES PER JOB CLASS Control A Operator Control C Operator Instrument Techn. Routine Ethyl chloride 4-6 Ethylene dichloride 1.1.2-Trichioroethane 1.1.1.2-Tetrachloroethane 1.1.2.2-Tetrachloroethane Vinyl chloride Vinylidene chloride SHORT-TERM MONITORING JOB CLASSIFICATION JOB TASKS AGENTS NUMBER OF SAMPLES Control C Oper. Sample Catching Ethyl chloride Ethylene dichloride 1.1.2-Trichioroethane 1.1.1.2-Tetrachloroethane 1.1.2.2-Tetrachloroethane Vinyl chloride Vinylidene chloride 6 CONFIDENTIAL R&Sl 53881 IHS FILE A70-3581-89 PAGE #10 3. METHODOLOGY Eight-hour TWA samples of ethyl chloride; ethylene dichloride; 1,1,1,2-tetrachlorethane; 1,1,2,2-tetrachloroethane; 1,1,2 trichloroethane and vinyl chloride will be collected on 1 gram charcoal tubes using calibrated personal sampler pumps (approx. 50 cc/minute) to draw known volumes of air through the tubes. The charcoal is desorbed with carbon disulfide and analyzed on a FID gas chromatograph. The front and back sections of the charcoal tubes will be analyzed to detect any breakthrough. Short-term samples of these chemicals will be collected by the same method. However, the personal sampler pumps will be calibrated to an approximate flow rate of 200 cc/minute The samples will be analyzed according to Dow Method HEH-IHM-83-25A Wipe testing of surfaces for hexachlorobenzene will be performed using 35 mm Whatman #1 filters. A disposable polyethylene glove will be worn and discarded for each sample. Flat surfaces such as table tops and floors will be wiped using a template with an exposed area of 100 square centimeters. Other surfaces such as door handles, phones and process control knobs, where the template cannot be used, will be completely wiped. After wiping, the filter is folded and placed in a 3 dram vial. Analysis will be performed by extracting with 10 ml of n-hexane and determining the total micrograms present using electron gas chromatography. Proper procedures for a wipe testing program are outlined in Industrial Hygiene Reference Procedure IHP-403. Personnel monitoring for noise will be conducted using Quest Model M-7B noise dosimeters which will be calibrated before and after each use with a Quest Model CA-32 sound calibrator. The area noise survey will be conducted using a Quest Model 215 sound level meter which will be calibrated before and after each use with a Quest Model CA-32 sound calibrator. 4. QUALITY CONTROL Routine quality control procedures shall be an integral part of the sampling and analysis procedures and functions. These shall include: a. Routinely introduced sampling of blanks and spikes (known content) along with the other samples for analyses. b. Routine checking, calibrating, and maintaining in good working order all equipment and instruments. Air sampling pumps will be calibrated both before and after use. c. Routine checking of procedures and results. CONFIDENTIAL R&S153882 IHS FILE A70-3581-89 PAGE #11 APPENDIX B INDUSTRIAL HYGIENE EDUCATION PROGRAM The Industrial Hygiene'Education Program is designed to inform workers of the chemical and physical agents in the workplace which may have an adverse effect on the health of the employee. It is believed that an understanding of the hazards of the chemical and physical agents will reinforce their safe handling by the workers. The annual health hazards training will focus on the following key physical agents: 1990: 1991: Ethylene dichloride Hexachlorobenzene 1.1.1.2- Tetrachloroethane 1.1.2.2- Tetrachloroethane Vinyl chloride Vinylidene chloride Ferrozine 1,1-Dichloroethane Ethyl chloride Ethylene dichloride Hexachloroethane Noise Perch!oroethylene The education program will include presentations by department supervision and/or Industrial Hygiene Services reviewing the taxi cities of the key physical agents in the block and include discussions about specific job procedures for tasks with a potential for employee exposure and the control methods in use. Industrial Hygiene will assist EDC/NPA in developing a written personal protective equipment program during 1990. The respiratory protection program will also be reviewed and revised as necessary. The Industrial Hygiene Manual contains information about the effects of overexposures to each chemical in the plant. It must be kept in an area that is readily accessible to all plant personnel. All personnel should be reminded of the location of the manual. Participation in the Industrial Hygiene Education Program should be documented. The training documentation form is in the Training Guideline section of the plant Industrial Hygiene Manual. It is important to briefly describe the program's content and to obtain the signature of employees in attendance. When the annual training is complete, forward the original form(s) to Industrial Hygiene Services, B-101, for inclusion in the plant's compliance file (75-year retention). CONFIDENTIAL R&S153883 IHS FILE A70-3581-89 PAGE #12 APPENDIX C MEDICAL SURVEILLANCE PLAN All employees in the Ethylene Dichloride Department (EDC/NPA) are offered a Periodic Core Examination every two years. Participation in the periodic examination program is voluntary. The examination consists of a health history questionnaire, blood and urine tests, physical measurements (height, weight, and blood pressure), and breathing, hearing, and vision tests. Chest x-rays, electrocardio grams, hemoccult (blood in the stool), and glaucoma tests are offered on an age-related schedule. The Dow Medical Surveillance Requirement (MSR) program is also voluntary and is supplemental to the Periodic Core Examination Program. MSR examinations are targeted to detect health effects attributable to specific agents or work requirements. However, except for limited instances where actual tissue levels of a substance are determined (biological monitoring), most tests are non-specific Indicators of organ function or injury. A MSR does not exist for all chemicals or physical agents. Where an MSR does exist only those job classifications with a Priority Rating of 1 or 2 must be included in the program. There are a few Medical Surveillance Requirements based on plant/department assignment or previous exposure potential. MSR tests and frequencies are different for each material. All OSHAregulated chemicals or physical agents have Dow Medical Surveillance Requirements which conform to the OSHA Standard. Individuals whose potential exposures meet or exceed the Action Level are included in the MSR program and must be offered examinations as specified in the Standard. On occasion other employees whose potential exposures are less than the Action Level may be placed on the Dow MSR. These two groups will be clearly differentiated. Review of the current Chemical and Physical Agent Inventory reveals that no chemicals with a Dow MSR have a Priority Rating of 1 or 2. Ethylene dichloride does have a Priority Rating of 2 for the Control C Operators. However, under the Dow MSR system there is no additional testing required. Review of the 1988 Noise Survey shows that the eight-hour time-weighted average exposures to noise are all below 85 decibels on the A-scale and therefore there are no job classifications that must be included in the Hearing Conservation Program. All employees in the Ethylene Dichloride Department will continue to be offered the Periodic Core Examination. CONFIDENTIAL J3 to OwCOl CD IHS FILE A70-3581-89 PAGE #13 APPENDIX D OCCUPATIONAL HEALTH GOALS AND PLANS Industrial Hygiene Surveillance Program: 1. Complete sampling program 2. Communicate results to employees Industrial Hygiene Education Program: 1. Update CPAIs 2. Review MSDSs compared to CPAIs 3. Conduct annual health hazards training 4. Conduct new chemicals training Respiratory Protection Program: 1. Review written respirator program 2. Conduct training for mouthbit 3. Conduct training for half-face 4. Conduct training for full-face 5. Conduct training of SCBAs/Airlines 6. Conduct inspections of mouthbit 7. Conduct inspections of half-face 8. Conduct inspections of full-face 9. Conduct inspections of airlines 10. Conduct inspections SCBAs Hearing Conservation Program: 1. Conduct noise survey 2. Employee training on how to use hearing protection and noise Personal Protective Equipment Program: 1. Develop protective equipment program 2. Review protective equipment program 3. Conduct employee training on proper PPE use Asbestos: 1. Conduct inspection for asbestos-containing materials DUE DATES 1990 1991 08/90 10/90 08/91 10/91 11/90 11/91 11/90 11/91 12/90 12/91 as needed 03/90 03/91 06/91 06/90 06/91 06/90 06/91 06/90 06/91 10/90 10/91 10/90 10/91 10/90 10/91 10/90 10/91 - monthly - -- 08/91 -- 09/91 05/90 -- 11/90 11/90 *o. 05/91 10/91 __ CONFIDENTIAL n V) ccon CD CD IHS FILE A70-3581-89 APPENDIX E PAGE #14 -JAN-90 CHEM DR# INDUSTRIAL HYGIENE CHEMICAL USAGE BY PLANT PLANT NAME - EDC NPA (58800) CHEMICAL NAME USE CODE USE NAME MISCELLANEOUS LABORATORY CHEMICALS BY-PRODUCTS BY-PRODUCTS MISCELLANEOUS BY-PRODUCTS BY-PRODUCTS PRODUCTS MISCELLANEOUS BY-PRODUCTS RAW MATERIALS BY-PRODUCTS BY-PRODUCTS BY-PRODUCTS BY-PRODUCTS BY-PRODUCTS LABORATORY CHEMICALS BY-PRODUCTS MISCELLANEOUS BY-PRODUCTS BY-PRODUCTS RAW MATERIALS LABORATORY CHEMICALS BY-PRODUCTS BY-PRODUCTS BY-PRODUCTS LABORATORY CHEMICALS MISCELLANEOUS LABORATORY CHEMICALS LABORATORY CHEMICALS LABORATORY CHEMICALS LABORATORY-CHEMICALS MISCELLANEOUS MISCELLANEOUS LABORATORY CHEMICALS BY-PRODUCTS BY-PRODUCTS MISCELLANEOUS WATER TREATMENT CHEMICALS HEAT TRANSFER AGENTS MISCELLANEOUS MISCELLANEOUS MISCELLANEOUS MISCELLANEOUS ~~ LABORATORY CHEMICALS -> LABORATORY CHEMICALS RAW MATERIALS LABORATORY CHEMICALS LABORATORY CHEMICALS PHYSICAL AGENTS -...... PHYSICAL AGENTS LABORATORY CHEMICALS LABORATORY CHEMICALS CONFIDENTIAL R&s 153886 IHS FILE A70-3581-89 APPENDIX F PAGE #15 NAME NAME EDC NPA PLANT (58800) PERSONNEL ROSTER AS OF 12-18-89 MASTER JOB CODE/SUF JOB CLASSIFICATION -- ASSIGNMENT 01600000 FOREMAN 01632700 PRODN MAINT FOREMAN 16026770 CONTROL OPERATOR A 16026770 CONTROL OPERATOR A 16026770 CONTROL OPERATOR A 16026770 CONTROL OPERATOR A 16026770 CONTROL OPERATOR A 16026790 CONTROL OPERATOR C 16026790 CONTROL OPERATOR C 16026790 CONTROL OPERATOR C 16026790 CONTROL OPERATOR C 16209680 CLERK TYPIST ADDITIONS TO PLANT ROSTER o >n H MASTER ORIGINAL JOB CLASSIFICATION -- JOB CODE/SUF DEPART. ASSIGNMENT 01200000 57335 SUPERVISOR 18700004 59000 SR ELECTRICIAN 12704054 59000 SR INST TECHNICIAN CONFIDENTIAL * NO POTENTIAL FOR EXPOSURE DURING NORMAL OPERATING CONDITIONS. NO CPAI REQUIRED > PLANT PERSONNEL NO LONGER WORKS IN THIS DEPARTMENT IHS FILE A70-3581-89 PAGE #16 APPENDIX G JOB DESCRIPTIONS PLANT SUPERINTENDENT " The job is primarily administrative with the individual spending 80% to 90% of the time in offices or control rooms. Remaining time is spent in production areas as an observer or supervisor. Non-routine situations require close inspection of damaged or leaking equipment and operation of process equipment. MAINTENANCE/PRODUCTION FOREMAN AND FOREMAN Approximately 40% of work time is performed from office. Maintenance job supervision in production areas and dealing with open process systems requires 40% of work time. Remaining 20% involves direct supervision of outside operations including spill cleanup, clearing of process equipment and operation of process equipment. CONTROL A OPERATOR Control room operation involves 95% of work time. Remaining 5% involves handling small process samples and performing chromatographic analysis inside the laboratory area. CONTROL C OPERATOR Outside operation work involves 85% of available time. Work includes sampling, draining equipment, piping line-up, starting/stopping process pumps and plant clean-up. Remaining time is spent in laboratory area performing analysis on process samples. Lab area includes approved fume hoods. SENIOR ELECTRICIAN Responsible for all electrical work in the A-7000 block. Fifty percent of the time is spent in the plant. The remaining time is spent in office and work shop areas. This employee currently reports to Chlorinated Ethanes Products (CEP) Maintenance management. SENIOR INSTRUMENT TECHNICIAN Repairs and troubleshoots process analytical equipment and other instruments. Approximately 60% - 70% of the time is spent in the plant process areas and the remaining time is spent in the instrument shop. This employee currently reports to CEP Maintenance management. CONFIDENTIAL R&s153888 IHS FILE A70-3581-89 APPENDIX H PROCESS DESCRIPTION PAGE #17 R&si53889 , CONFIDENTIAL REDACTED Hit A/d-iisl-sy REDACTED ' 1' CONFIDENTIAL ' PAGE #1* R&S153890 ^PC/NPA A-70M