Document 8Vxbr957O9azQdp1aa2Q4Mdgy

From tha dtak oi PAULA CLINE, THE ARCHIVES OFFICE First Printing 1942 see "Monsanto Magazine" June, 1942 - last page 0683738 TOWOLDMON0041822 WATER_PCB-00026291 0683739 TOWOLDMON0041823 WATER_PCB-00026292 0683740 TOWOLDMON0041824 WATER_PCB-00026293 MONSANTO CHEMICALS 0683741 TOWOLDMON0041825 WATER_PCB-00026294 T vkRoY ollli > 2nd National 111111 ii11 Telephone: II Eml< rk oi`M 1 (>S V NOLI.I S. CVI If . till W et < )K nipir HImI. Telephone: Michigan hOlK liiKMINOII \\l. \i.\. \| ar\ lli.il.linT.-i.-pi..... . :.uh;: MoNTKE VL. C \ \ VI) V ATH SI. Paul Street tt Te|ephon<`: M \rket 12 Ui 10 >STO V \l \ss. IN <T<-It Station r. l. pl,|.\ I t- 1 .Vim \l AV 'HiRK. V 1 . AH <o, ke|,-||,.r Pla/a Telephone: ( If.le 7.l,|7'l CHARLOTTE. N. <: johnstott Building Telephone: J-H.U CHICAGO. ILL. Tribune Tower Telephone: Vt llltehall 6?o<) DETROIT, MICH. 127 Fi*her Building Telephone: TRinit 2-'>72rt LONDON, ENGLAND \ ietoria Station House ST. 1.1 M IS. Ml i. 1 700 South Second >freel Teleplu ne: ( . I'.Mt Till llJ i \ S VN FRANCISCO. (. \| If ion Hu>h Street Telephone; DOuglas II JO TORONTO, CAN AI) V 18A Front Street Fat Telephone: WAverh MIA MELBOURNE. AL STH \l Somerville Road Bravhrook ^ . 19 MANCHESTER. ENGLAND King'* Hoit*c King'* Street ^ est If orks. WNISTON, ALABAMA CARONDELET, MISSOURI CAMDEN, NEW JERSEY DAYTON. OHIO EVERETT, MASS. KARNACK. TEXAS MONSANTO, ILLINOIS MONSANTO, TENNESSEE MTRO, WEST VIRGIN \ NORFOLK. \ IKGIM V TEXAS CITY. TEX VS TRENTON. MICHIC VN SPRINGFIELD. MASS. ST. LoUIS, MISSOURI MONTREAL. CANADA Rl'ABON, N. WALES SUNDERLAND, F.N'CLVND MET.BOURNE. AUSTR M l \ 0683742 TOWOLDMON0041826 WATER_PCB-00026295  Divisions and Associated Companies________________ MERRIMAC DIVISION. Everett Station, Boston, Mass. ORGANIC CHEMICALS DIVISION, 1700 S. Second St., St. Louis. Mo. PHOSPHATE DIVISION, 1700 S. Second St., St. Louis, Mo. PLASTICS DIVISION, Springfield, Mass. TEXAS DIVISION. Kamack. Texas. RUBBER SERVICE DEPARTMENT, 2nd National Building, Akron, Ohio. CENTRAL RESEARCH DEPARTMENT, Dayton, Ohio. NEW ENGLAND ALCOHOL COMPANY, Everett Station. Boston, Mass. SHAWINTGAN RESINS CORPORATION, Springfield, Mass. MONSANTO (CANADA), LTD., 378 St. Paul St. West, Montreal, Quebec. MONSANTO CHEMICALS LTD., Victoria Station House, Victoria St., London, S. W. 1, England. MONSANTO (AUSTRALIA) PTY. LTD., Somerville Road, Bravbrook W. 19, Melbourne, N. S. W., Australia. ________ Cable Address________ "Monsanto" St. Louis Codes: ABC. 6th and 7th Acme, Bentley's and Bentley's Second 2 6TH EDITION Page 3 0663743 TOWOLDMON0041827 WATER_PCB-00026296 CONTENTS How To Ise This Hook.................. A Word About Containers................. Monsanto--The Organization. . Industries Served by Monsanto.......................................................... II Monsanto Products .................................... ........................................ IT Monsanto Literature............................................................................ 145 General Data..............................................................................................149 Testing Liquids With the Hydrometer.......................................... 149 Dilution and Concentration of Liquids........................................151 Sulfuric Acid Tables.......................................................................... 152 Hydrochloric Acid Table#............................................................... 154 Nitric Acid Tables............................................................................ 156 Acetic Acid Tables .......................................................................... 158 Aqua Ammonia Tables................................................................... 159 Anhydrous Ammonia Tables.........................................................161 Aluminum Chloride Tables .........................................................162 Aluminum Sulfate Tables ............................................................. 163 Sodium Bisulfite Tables..................................................................165 MerclorTables..................................................................................... 166 Weights Per Gallon.......................................................................... 167 Conversion Tables for Volume and Weight..................... 168 Page 4 MONSANTO CHEMICALS 0663744 TOWOLDMON0041828 WATER_PCB-00026297 HOW TO USE THIS BOOK This is an entirely nevv book, designed to bring together in the most convenient and useful form possible, sufficient information on all Monsanto products to serve as a buying guide and to enable users of chemicals to determine whether a material unfamiliar to them is of sufficient interest to merit further consideration. Those desiring more detailed information on specific products are referred to the Mon santo literature listed on page 14d or to their nearest Monsanto dis trict office. Locations of these offices are given on page 2. All products are listed alphabetically in the main section of the hook according to their common chemical names or Monsanto trade names. Where a product has more than one common name, or both a trade name and a chemical name, it has been attempted to list all of these along with proper cross references, thus making the book self indexing and eliminating the trouble of referring to an index first and then to a given page number. To assist users of chemicals in acquainting themselves with the Monsanto products applicable in their particular industry, a classi fication of products according to industries is given on page 11. This classification should not be considered final or complete. New uses for Monsanto chemicals and plat-tics are opening up dailv, some in fields entirely unsuspected a snort time before. Likewise, no product should be considered as limited to the uses mentioned in this book. The general data section beginning on page 149 contains a variety of physical and chemical information which will be useful in connec tion with certain products described in the alphabetical section. rence to this data is made under products to which any If as you use this book suggestions come to mind as to how it might be made more helpful we would appreciate your passing them along to us. In this way we will be able to make our next edition even more useful to you and the many other users of Monsanto products. A WORD ABOUT CONTAINERS Because of the rapid changes taking place in the availability of con tainers at the time this book was compiled, no attempt was made to include container data of any kind. Users of Monsanto products mav rest assured, however, that at all times their orders will be shipped in the highest quality and most satisfactory containers available. For current container information write your nearest Monsanto district office. CAUTION: The products described in this book are primarily for manufacturing use. They should not be used on the human body, either internafiv or externally, until their safety for the use intended is clearly established, and then not unlesB under competent direction. J6TH EDITION Page 5 0683745 TOWOLDMON0041829 WATER_PCB-00026298 0663746 TOWOLDMON0041830 WATER_PCB-00026299 MONSANTO -- The Organization Monsanto Chemical Company, founded in 1901 by John Francis Queenv and given his wife s maiden name, today is one of the major American producers of chemicals and plastics. Stemming from broadlv diversified chemical raw materials such as coal tar. petroleum, phos phorus. cellulose, salt and sulfur. Monsanto products number in the liundreds and find use in virtually every branch of manufacturing industrv. The company's five divisions and Canadian affiliate operate four teen plants in North America, and subsidiary companies operate three overseas. Four government plants are in operation or under construction. ORGANIC CHEMICALS DIVISION The Organic Chemicals Division is the lineal descendent of the original Monsanto works. To considerable extent, the division's products, too, derive from the research program begun in the first days. The original Monsanto product, saccharin, is now one of manv made and sold by the division. Others fall in a wide varietv of classi fications including pharmaceuticals, drug intermediates, dve inter mediates. petroleum additives, flavorings, plasticizers, resins, insect icides and neavy chemicals. The division's largest plant is on the site of the original works at St. Louis. Here are manufactured the fine chemicals, many derived from coal tar, that established Monsanto's earlv reputation, as well as numerous other classes of products. Across the Mississippi River from St. Louis, in Monsanto, Illinois, the Organic Chemicals Division operates a large plant producing heavy chemicals and organic inter mediates. At Norfolk, Virginia, the division operates a plant manufacturing intermediates. Rubber Service Department Monsanto's Rubber Service Department, part of the Organic Chem icals Division, specializes in supplying the needs of one industrv. It provides the rubber industry with many chemicals sucb as accelera tors, antioxidants, mold lubricants, pigments, colors, preservatives, softeners and plasticizers. A modern laboratory is maintained for solving compounding problems. The facilities of this laboratory and the help of its trained and experienced staff is available without cost to users of Rubber Service materials. The Rubber Service headquarters are at Akron, Ohio, in the 26TH SDITtON Page 7 06837*7 TOWOLDMON0041831 WATER_PCB-00026300 heart of the rubber manufacturing district. The plant is at .Vitro, West Virginia. MERRIMAC DIVISION Monsanto'9 Merrimac Division, headquartered at Everett Station. Boston, manufactures a diversified line of heavv and industrial chem icals. Included among its products are acids, lacquers, alcohol, sol vents, intermediates, tanning chemicals, commercial gases and lampblack. The division operates thne plants, the largest being at Everett Station, Boston. Adjoining this are the facilities of the New England Alcohol Company, a partly owned subsidiary of Monsanto. At Camden, Vew Jersey, Mongsnto lampblack is manufactured. Some of the products of the Merrimac Division duplicate those made at other plants of the company and thus provide an eastern source of supply for Monsanto customers. PHOSPHATE DIVISION The phosphates and other compounds of phosphorus are, as a class, increasing in importance. They are finding use in such varied fields as medicinals, water treatment, dentifrices, soaps, metal treatment, and foods. Operations of Monsanto's Phosphate Division are based on the production of elemental phosphorus at Monsanto, Tennessee. At this location, phosphate earth ts dug from large open pit mines and charged into huge electric furnaces where the phosphorus is freed in elemental form. From elemental phosphorus comes phosphoric acid, the parent of the large family of phosphates which are made in the division's other plants at Anniston, Alabama, Carondelet, Missouri, and Trenton, Michigan. At Anniston, in addition to phosphates, those products of the division not derived from phosphorus, such as diphenyl, Aroclors, Santowax, calcium carbide and aluminous abrasives are made. Head quarters for the division are at St. Louis. PLASTICS DIVISION Monsanto's Plastics Division has attained a leading position in the new and growing plastics industry. The development of new plastics and their application is a continuing and accelerating process, a fact Page H MONSANTO CHEMICALS 0683746 TOWOLDMON0041832 WATER_PCB-00026301 MoniantOt Tennessee, phosphorus furnace plant at night which guides the policies of the division from research through pro duction to sales and advertising, Monsanto's plastics operations are consolidated at Springfield, Massachusetts. As a result of a construction program begun in 1938 there have been several major additions at Springfield, including a plant for the production of Kesinox phenol-formaldehyde resins and molding materials, and the plant of the Shawinigan Resins Corpora tion, a Monsanto affiliate manufacturing vinyl resins. TEXAS DIVISION In 1941 Monsanto was requested by the Rubber Reserve Company, a government agency, to design, construct and operate a plant to manufacture an important raw material for synthetic rubber. The same year, at the request of the Ordnance Department of the United States Army, the company contracted to operate a major plant for the manufacture of munitions. The Texas Division was created to operate these two plants. The division makes no products for general sale. CENTRAL RESEARCH DEPARTMENT Research at Monsanto is both a divisional and a centralized function. Each division maintains its own research laboratories--Organic 26TH EDITION Page 9 06837*19 TOWOLDMON0041833 WATER_PCB-00026302 Chemicals Division at St. Louis and Nitro, Phosphate Division at Anniston and Carnndelet, Plastics Division at Springfield, and Merrimac Division at Everett, in each, the reascarch function is kept separate from other laboratory operations, such as analytical control and testing. The work of the divisional research laboratories is supplemented and augmented by the Central Research Department at Davton, Ohio. It is here that much of the fundamental research of the com pany is carried out. The Central Research laboratories are equipped with the latest type of research aids, including such equipment as the electron microscope and X-ray, The department carries on special investigations in cooperation with the operating divisions am) also carries out studies of an exploratory nature that mav not he related to the company's present products. TECHNICAL SERVICE Each of the Monsanto divisions maintains a technical service staff comprised of qualified personnel who are experienced in the chemical problems and requirements of a wide variety of industries. Industrial users of chemicals are invited to make use of these men. Their func tion is to provide sound technical counsel on problems relating to the use of chemicals. Plant of the Shawinigan Resins Corporation, a Monsanto affiliate 0683750 TOWOLDMON0041834 WATER_PCB-00026303 SOME INDUSTRIES SERVED BY MONSANTO AND PRODUCTS SUPPUIED AGRICILTI RAL Uirarives ( ..ilrinrti Phosphate, I)i I '.ilrinni Sulfate I' I'rrir ( lilorulc < ! ln>p hornn >)Ufl \rid Nitre Cake N ii ric Acid I'hosilage Phosphoric Acid Plastics Sodium Sulfate Sulfur Sulfuric Add W etting Agents (Santomerse) APPLIANCES Ibrasives Cresol Ferric Chloride lacquers Lampblack Maleic Anhydride Muriatic Acid Nitric Acid Phosphoric Arid Phthalic Anhydride Plastics Solvents Sulfuric Acid AUTOMOTIVE Abrasives Acetic Acid Alcohol Aluminum Sulfate Amyl Acetate Aroclors (Chlorinated Diphenyl) Battery Acid Benzene Butyl Acetate Butyl Alcohol Caustic Soda Chlorine Cresol Diacetone Alcohol Dibutyl Phthalate Diethyl Phthalate Ethyl Acetate Ferric Chloride Perrophosphorua Lacquers Muriatic Acid Nitric Acid Phenol Plicxph >rir Acid I'lilhali Anhydride Plastics Rubber Accelerators Bone Ash Muriatic; Acid Phosphoric \< id Salt Take Sodium Pyrophosphate, Tetra Sulfuric Acid AAVttinp Agent Rubber Anii'Oddant* Santirizer ') (Sumomerse) Sodium Acetate Sodium Phosphates CHEMICAL Sodium Sulfate Sulfur Sulfuric Acid Tarmirq Chemicals Thinner* Tricresy l Phosphate PROCESS Acetic Acid para*Acetvl>Viiiino-Benzenesulfonechloride Alcohol Aluminum Sulfate AVIATION Ammonia, Aqua Abrasives Amyl Acetate Alcohol ortho-Anisidine Vntvl Acetate Butyl Acetate Butyl Acetate Calcium Pyrophosphate Ethyl Acetate Caustic Soda Finishes Chlorine Lacquer* meta-Cresol Phosphoric Acid ortho-Cresol Plastics para'Cresol Primers Cresylic Arid Solvents Diacetone Alcohol Sulfuric Acid Dinitrochlornbenzenr Surfaces* Ethyl Acetate Thinnen Mersol (Solvent) Methvl Salicvlate CARPET and RUGS Mixed Acid Acetic Acid Monoehlorobenzene Aluminum Sulfate Glauber'* Salt Monsanto Salt Muriatic Acid Lacquen Nitric Acid Latex Accelerators ortho'Xitroaniline Nitre Cake para-Nitroanilinr Sodium Bisulfite, ortho-Nitroanisole Anhydrous Nitrocellulose Solution Sodium phosphate, Tri ortho-Nitroohlorobenzene Sodium Pyrophosphate, part-Nitrochlorobenzenr Tetra para-Phenetidin Sodium Sulfate, Anhydrous Phenol Phosphoric Acid Sulfuric Acid Phosphorus Oxychloride Wetting Agent Phosphorus Trichloride (Santomerse) Phthalic Anhydride CERAMICS Abrasives Piperidine Pyridine Salicylic Acid 26TH BPITION Page 11 0663751 TOWOLDMON0041835 WATER_PCB-00026304 Salt Tale Sodium Minninaie Sodium Bisulfite Sodium Pyrophosphate, Tetra Sodium Sulfite SuKenlS Sulfuric Arid Sqlfurvl Chloride liiourea I'rirrrsy I Phosphate I'.ira I iiliif'Tif^iiifonjiiiiilc I'.ira- I uliii'n'nlfi>n ,I,lor.de Calcium Pyrophosphate Oy.alhd ' Methyl Salicylate Plastics " Phosphoric Acid Saccharin Sodium Benzoate DYESTUFF -MAM FACTURE Acelic \, d Mumintiiu Sulfate ortho, Vmnodinlienvl Aniline 0,1 ' Sodium Hi'tillite Sodium Sulfate Sulfury I Chloride Thiourea para-Tolitencsulfonamidr para-Toltteresulfon- chloride para-Ttiluenesiilfonic Acid Wetting anil Spreading Agent* (Nreskap. Vresket. \reklene. WrllilHf Agent* ortho- \tii tdine electrical COSMETICS AND ijen/,trichloride \roelor9 PERFUMES Vl.nl,nl IJ.-nz.iir Arid Benzyl Chloride Calcium Phosphate, Di Calcium Phosphate, Tri Caustic Soda Cotimarin meia-Cresol l)irih> i Phthalate Manicure Lacquer Manicure Lacquer Remover Methyl Salicylate Phosphoric Acid Phlhalic Anhydride IJenzov I < hloride Be,ml Chloride 'triho-Chliroaniline tneta-Chlnroaniline para*Chlotoaniline para-Chloio-meta-Creso] ortho-Chhirophenol Cable Dope Larqtiers Lampblack Nitric Acid Phosphoric Acid Plastics Sulfuric Arid para-Chloiophenol chlnrrmilfonir Acid orlho-Chloro-para- Toltiene Sodium Sulfon ate (Monsanto Salt) ortho.Cresol ENGRAVING Acetic Acid Nitric Acid Perchloride of Iron Plastics Sulfuric Arid Cyolohexylamine Dichloroa rtiline V etling Agent (Santomerse) Potassium Pyrophosphate, ortho-Dirfrorobenzene __ Tetra ' Dichlorophenol FLORISTS AND Salicylic Acid Dinitroanil.ne FRUITGROWERS V uepak Dini trochlorobenzene Ammonia, Anhydrous Gening Agent Glauber's Salt ortho-Dirhlorobenzene H Acid para-Dichlorobenzene DAIRY PRODUCTS Mixed Acid Muriatic Acid Ammonia. Anhydrous Monochlorobenzene Sodium Phosphate, Tri Ammonium Phosphate, Monsanto Salt Vttepak Mono Nitre Cake Wetting Agent Couniarin ortho-Nitroaniiine (Santomerse) Kthavan para-Nitroeniline Merclor (Sodium Hvpo- _ chlorite) ' Santamine Sodium Acid Pyro phosphate Sodium Phosphate, Di Sodium Phosphate, Trl Sodium Pyrophosphate, ortho-Nilrosnisole FOOD ortho- Nitrochlorobenzenr Ammonium Benzoate meta-N'itro hlorobrnzenr Benzoic Acid L . S. P. ara-Nitrochlorobenzene Calcium Phosphates R itrodlchlotobenzene ortho-Nitrophenol para-Nitropnenol Oil of V itriol Calcium Pyrophosphate Calcium Sulfate Coumarin Monsanto Dry Ice Sulfuric Acid \ anillin ortho-Phenttidin para-Pheneiidin Phenol Etnavan Ferric Phosphate Methyl Saliry!,e DENTAL PRODUCTS Alcohol Benzoic Acid Calcjum Phosphate, Di Calcium Phosphate, Tri Phosphoric Acid Phosphorus Oxychloride Phosphorus Trichloride Phthalic Anhvdride Sodium Acei ate Sodium Aci<" Pyro phosphate Muriatic Acid Phosphoric Acid Phosphoric Acid Paste Saccharin Monsanto Sodium Acid pyro phosphate Sndinm Benzoate I'.S.P. Page 12 Mi TO CHEyflCyl.S 0683752 TOWOLDMON0041836 WATER_PCB-00026305 Sodium Bisulfate Sodium Phosphate, Di Sodium Phosphate, Mono Sodium Phosphate, Tri Vanillin Monsanto GLASS AND VIT REOUS WARE Abrasives Pone Ash Chlorine Muriatic Acid Plastics Salt Cake Wetting Agent (Santomerse) INSECTICIDES Cresol Dibutyl Pbtbalate ortho Dichlorobenzene nara-Dichlorobeazene Methyl Salicylate Sulfur Trichlorobeozene Wetting Agent (Santomerse) LAUNDRY Chloramine T Chlorine Merclor (Sodium Hypochlorite) Sodium Bisulfate Sodium Bisulfite Sodium phosphate, Tri Sodium Pyrophosphate, Tetra Wetting Agent (Santomerae) Sodium Sulfide Sulfuric Acid Wetting and Spreading Agents, (Areekap, Aresket, Aresklene, Santomerse) LUMBER LEATHER AND TANNING Lacquers Permasan Santobrite Aluminum Sulfate Santophen 20 Ammonia, Aqua Belt Cement METALS Caustic ^oda Abrasives para-Chl.oro-meta-Cresol Ammonia, Aqua para*Chl>ro.meta-Xylenol Bone Ash ortho-Dichlorobcnzene C. P. Acids Dopes Caustic Soda Glauber's Salt Cresylic Acid Lacquert Ferrisul (Ferric Sulfate) Lampblack Ferrophosphorus Merclor (Sodium liibitito Hypochlorite) Inhibited Acids Mertanol (Syntan) Miied Acid Muriatic Acid Muriatic Acid Permanol Nitric Acid Phenol Phosphoric Acid Salicylic Acid Sodium Phosphate, Di Santotap (Basic Chrome Sodium Phosphate, Tri Sulfau) Sodium Pyrophosphate, Sodium ftisulfate Tetra Sodium Bisulfite, Sulfuric Acid Anhydrous Wetting Agent Sodium phosphate, Di (Santomerse) Sodium Suifhydrate Zinc Chloride Solutions New baking laboratory at Carondelet for research and testing of phosphates for food products. 0683753 TOWOLDMON0041837 WATER_PCB-00026306 Inspecting safety valves on the electrolytic chlorine cells at Monsanto, Illinois. MINING Abrasive* Hone Ash C. P. Acids Flotation Agents (Xanthates) Nitre Cake Sodium Sulfide Sodium Sulfiie - OIL REFINING Caustic Soda Chlorine Cresols Muriatic Acid Phenol Phosphoric Acid Santolubes Santopoid Santopour Sulfuric Acid PACKAGING Cast Phenolic Resin Cellulose Acetate Cellulose Nitrate Lacquers Polystyrene Santiefzer-8 Vuepak PAINT, VARNISH AND LACQUER Amyl Acetate Antioxidants Benzoic Acid Butyl Acetate Cotton Solutions Diacetoue Alcohol Dibutyl Phthalate Diethyl Pbthalate Dimethyl Phthalate Ethyl Acetate Lampblack Maleic Anhydride Mertee (Chlorinated Rubber Base Paiot) Monochlorobenzene Paint Anti-SI inning Materials Phenol Phthalic Anhydride Resins Santicizers (Phthalyl Glycollates and other Plasticizers) Santoiites (Resins) Sautomask (Deodorant) Solvent Alcohol (Mersol) Thinnera Tricresyl Phosphate Tripheny] Phosphate PAPER Alcohol Aluminum Sulfate, Com mercial and Iron Free Ammonia, Anhydrous Ammonia, Aqua Benzoic Acid Bone Ash C. P. Acids Chlorine Coumarin Dibutyl Phthalate Ferric Sulfate Ferrisul Lacquers Muriatic Acid Page 14 MONSANTO CHEMICALS 068375A TOWOLDMON0041838 WATER_PCB-00026307 Sail Cake Santicizers (Specialty Sulfuric Acid Sanlicizers plasticizers) Getting Agent Santobrite Santolites (Synthetic (Santomerse) Santolites resins) Sanlosite Thiourea TEXTILES Sodium Aluminuie Trioresyl Phosphate Acetic Acid Sodium Risulfate Triphenyl Phosphate Alcohol Sodium Bisulfite. Vuepak Aluminum Chloride Sodium Hypochlorite Sodium Phosphate, Tri Sodium Sulfide S(limn Sulfur Sulfuric Acid Tricrej I Phosphate Wetiinc Agents PHARMA CEUTICAL Aoetanilid l. S. P. Aoetopheneiidin L. S. P. Acetyl Salicylic Acid (Aspirin) Benzoic Acid U. S. P. Caffeine U. S. P. Calcium Phosphate, Di Chloral Hydrate U. S. P. Chloramine-T U. S. P. Dichloramine-T N. F. Glycerophosphates Magnesium Phosphates. Methvl Salicvlate U.S.P. Phenol V. S. P. Phenolphlhalein U. S. P. Phosphoric Acid Potassium Ammonium Phosphate Potassium Phosphate, Mono Saccharin U. S. P. Salicylates Salol Sodium Benzoate U. S. P. Sulfanilamide U. S. P. PLASTICS AND SYNTHETIC RESINS Ammonia, Aqua Benzoic Acid, Technical POWER AND POWER PLANTS Vluniiniun Sulfate Chlorine Ammonium Phosphate, Mono Ammonia \myl Acetate Butyl Acetate nrtho-Dichlorobenzene Calcium Phosphate, Tri Ferrisul Calcium Sulfate Saniobrile Saniophen Caustic Soda Chlorine Santosite Sodium ^luminate Sodium Phosphates Cresol Dibnlyl Phthalate Ethyl Acetate Sodium Sulfate Ferric Sulfate PRINTING INKS Glauber's Salt Mtiminutrt Chloride Lacquers Aluminum Sulfate Merclor Antioxidants Mixed Acid Anti-Skinning Agents Nitrate of Iron Aroclors Nitre Cake Coumarin Oil of Vitriol Lampblack Plasticizers Methyl Salicylate Potassium Pyrophos Nitrate of Iron phate. Tetra Phenol Santobrite Santocel Santophen 20 Samomask Sodium Acetate Sodium Aluminate Sodium Acid Pyro RUBBER Accelerators Antioxidants Caustic S|)da Cycline Oil Ptperidint Santobrite Sodium Sulfite Softeners Sulfur Sulfuric Acid phosphate Sodium Bisulfite Sodium Phosphate. Di Sodium Phosphate, Tri Sodium Pvrophosphate, Tetra Sodium Sulfate Sodium Sulfite Sopet Sulfuric Acid Tricresyl Phosphate Wetting Agent SOAPS AND (Santomerse) Cast Phenolic Resin Cellulose Acetate DETERGENTS Antioxidants WATER Cellulose Nitrate C. P. Acicis TREATMENT Cresols Calcium Sulfate Aluminum Sulfate Dibutyl Phthalate Caustic Soda Ammonia, Aqua Diethyl Phthalate Chlorosullonic Acid Chlorine Dimethyl Phthalate Coumarin Ferrisul (Ferric Sulfate) Maleic Anhydride Cresol Santobrite Monsanto Plastics Phenol Santosite (Reducing Phenol Soda Ash Agent) Phthalic Anhydride Sodium Phosphate, Di Sodium Aluminate Polystyrene Sodium Phosphate, Tri Sodium Hypochlorite Polyvinyl Acetala Sodium Pyrophosphate. Sodium Phosphate, Di Resinox (Phenol* Tetra Sodium Phosphate, Tri Formaldehyde) Sopanox Sodium Sulfate JrtTH EDITION Page IS 0683755 TOWOLDMON0041839 WATER_PCB-00026308 0683756 TOWOLDMON0041840 WATER_PCB-00026309 ACCELERATORS MONSANTO PRODUCTS ABRASIVES (See Aluminum Oxide Abrasive Crain). ACCELERATORS, Kl'BBEK....................................................... miji\ iilii.il accelerators below for specification* ami properties. H.H. ( iliissifioo t ion ! Rubber Accelerators NUlUV Available Literature! "Monsanto Oheniicals for (he Lubber Industry," 12 pages. "Latex Compounding." 36 page,. "Rubber Compounding for the Wire Industry," ifi pages. "Sanlocure-- Vn Accelerator for Rubber \ ulcanizaiinn," 32 pages. **A-10"____________ Specifications] Comiensatinii product of aniline and formaldehyde. It is neither met by le ne dianilirle nor formaldehyde aniline, but probably a mixture in which the latter product predominates. White or yellowish tinted powder; 95 per cent through 200 mesh anti 99 per cent through 100 mesh; loss on healing less than 5.0 per cent when heated for two hour* at 105'C.: m.p.. begins to soften at 120:C.; `I*, g. 1.17: tinnombineil reagents, no excess of free aniline and not more than truces of formaldehyde. Specifications: Formaldehyde derivative of a condensation product of aniline anti acetaldehyde, of complex chemical composition. Brown resinous powder; m.p. between 755C. and 85C.; sp. g 1.17. _________________________ Specifications: Reaction product of butyraldehyde and butylidene aniline. The chemical structure of such products is necessarily complex. Red yellow to orange brown oily liquid, slightly turbid when cold; sp. g. 0.98; flash point soluble in benzene, chloroform, acetone and solvent naphtha. . Specifications: Light tan powder; constant composition blend of Santocure and Kl Sixty. .'(STH BniTIO.V Page 17 0663757 TOWOLDMON0041841 WATER_PCB-00026310 "A-T7" Specifications! Condensation product of acetaldehyde and aniline by a special Monsanto process. Such procliu- s, known as aldehyde derivatives of SchifTs bases, are of complex chemical composition. Free flowing reddish brown liquid: -p. jt. I.'U: flash point 55*G.; solnlde in bentene, chloroform and acetone; partly -oliiMe in alcohol and gasoline. *|>ccificationt Aldehyde derivative of a SchifTs base made with the use of built butyruldehvde and acetaldehyde. Dark reddish brown oily liquid; sp. g. I.llf; flash point 855C.; soluble in benzene, chloroform, acetone and solvent miphiha. `BLTASAN" (Zinc Salt of Dibutyl Dithiocarbamic Acid)____ Specification*: Cream colored powder: sp.g., 1.21: melting point, 1065C.; cur> at temperatures below lOO^C. ifi General Information! 0.5% to 1% otl rubber weight used io latex, cements, for dipped goods, adhesives, coatings, etc. 0 DPG (Diphenylguanidine) Specifications! White powder, not darker than the approved color standard: no residue on UK) mesh screen; m. |*. not less than 1 ; sp. g. 1.19; strength, 99.0% min. of DPG by acidimetric titration; soluble in alcohol, benzene, chloro form and ether; very slightly soluble in water. *EL SIXTY" (Dibenzothiatyldimethylthiol urea) Specifications: A light cream colored powder; 99.5% min. through 200 mesh, no coarse particles: m.p. 220flC. min.; sp. g. 1.29; very slightly soluble in acetone, alcohol and chloroform; slightly soluble in hot pyridine or orthodichlorbenzene. "ETHASAN" (Zinc Salt of Diethyl Dithiocarbamic Acid)___ Specifications: White powder; sp.g , 1.5; melting point, 173C. General Information: 0.5% to 1% on rubber weight used in latex. Page 18 honSanto chemicals 0683758 TOWOLDMON0041842 WATER_PCB-00026311 "Gl ANTAL" Specifications: Ester formed by reading two molecules of diphenylguanidine and one molecule of phtbaJie arid: contains one-balf mole of water of cryHaUizalion. White powder ranging from blue white to faint gray: 99.5% min. through 200 mesh, no coarse particles: m. p 178C. min.; ap. g. 1.20: soluble in alcohol: insoluble in benzene and gasoline. "METHASAN" (Zinc Salt of Dimethyl Dithiocarbamic Acid) Specifications) White powder; sj .g., 2.00; melting point, 249C.; cures at temperatures below 100C. General Information: 0.5 to 1% >n rubber weight used in later and cements. PIP-PIP (Piperidine-pentamethylene Dithiocarbamate)_____ /) Specifications: Fluffy, cream colored powder; 98.0% min. through 200 mesh S and 99.5 per cent through 100 mesh: m.p. over 160C. at time of shipment. P Decomposes slowly in the presence of water and during storage with a corre sponding drop in melting point. 5p. g. 1.13; soluble in alcohol and solvents con* taining water. 6S -J u "R*2" CRYSTALS u Specifications: Reaction product of carbon bisulfide with methylene dipiperi* dine. Light brown coarse crystalling solid; sp. g. Ml; m. p. between 50C. and 60C. "SANTOCURE"---------------- ---------------------------------------------------------Specifications: Condensation product of mercaptobenzothiazole with cyclo* hexylamine. Light tan or buff colored powder; 99.5% min. through 200 mesh; m.p. 90C. min.; sp. g. 1.27. Available Literature: S2*page booklet, "Santocure--An Accelerator for Rubber Vulcanization." "TACKOL" Specifications: Standardized, uniform blend of resins and oils. Viscous brown liquid. Odor it distinctive coumarone-libe; sp. g. 1.05; flash point lt0C. torn EDITION 0683759 TOWOLDMON0041843 WATER_PCB-00026312 ACCHI FKATOKS General Information: l sed a* a softener nr tack producer in rubber. Available Literature! 42-page booklet: ".Monsanto Chemicals for the Rubber THIOC..AKB ANILIDE Specifications: While powder, not darker (ban the approved color -tjndurd; o min. llirmich I<>U mesh, no co; rse particle*: m. p. not tees than I IB;G.; s|>. g. 1.12: insoluble in water and many other -oKeni>: soluble in a Icoliol. 'THIL'RAD,, (Teiramethyl Thiuram Disulfide) ______________ Specifications! Sp.g., 1.29; melting point, 116 t WC.: color, white; odor, none; soluble in carbon bisulfide, benzene and chloroform; insoluble in water, dilute caustic and gasoline. "IREKA" Specifications! Constant composition blend of diphenylguanidine and 2, tdinilrophenyl lliiobenzolhiazole. I'niform light yellow powder; 99.5% min. through 200 mesh, no coarse particles: m. p. between 117C. and 127C.; sp. g. 1,25; soluble in alcohol and chloroform. "I REKA BLEND B"_________ Specifications! A blend similar to "Ireka" with a portion of the "DPG" re placed by "Gnantal." Yellow to brownish powder; 99.5% min. through 200 mesh, no coarse particles; tn.p. 130C. min.; sp. g. 1.33. "UREKA C" (Benzothiazylthiohenzoate) Specifications! An acyl-thiasole powder in which the acidic hydrogen atom of Diercaptobenzothiazole has been replaced by a benzoyl group. A pale ivory or yellowish powder: 100 per cent through 30 mesh: tn.p. not less than 1159C.; __ sp. g. 1.43; soluble in chloroform and benzene; slightly soluble in alcohol. ACETAMLID, U.S.P. NHCOCH* 0 Page 20 Mol. Wt. 135.16 Standard Forma: Crystals, powder{Continued) MONSANTO CHEMICALS 0683760 TOWOLDMON0041844 WATER_PCB-00026313 Specification*! White crystals or powder; ash 0.05% max.; conforms to L'.S.P. tests for carbonizable impurities ami heavy metals: solubility in ethyl alcohol 95%, complete: m p. 11 I.DeC. min.: no crystals retained on 11 mesh; 3.0% max. ponder retained on 80 mesh. II.II. Classification: Vcetanilid. Generul Information! I'liarmai eutical product. ACETIC ACID CHjCOOH Grades: 6% CjHiOj: sp.g. 1.06?; freezing point --8.0F. 70% sp.g. 1.074; freezing point -H>.6F. 80% C}H,Oj! sp.g. 1.076; freezing point -j- 17.fF. 81% CjIl^Oj! sp.g. 1.075; freezing point +27.3F. Clacial: 09% sp g. 1.0576; freezing point +58.3F. H.H. Classification i Aretic Arid. Ceneral Information! Used in dyeing where a weak acid is required in the dye bath; in the manufacture of acetate solvents; manufacture of cellulose acetate; and in the formation of oi her acetates, such as aluminum, lead, sodium, and ammonium acetate. Also used in manufacture of fish glue; as an antichlor: coagulation of rubber latex; destruction of fungi; disinfectant in gelatine: pickling foodstuffs; giving added detergency and firmness to soap: stabilizing olive oil; protecting seedlings from injury due to root rot and damping off; hardening and developing solutions for photographic films. (See table in general data section) ACETONE C. P. ___________ ______________________________ Typical Analysis: Water white liquid; non-volatile matter, not more than 0.001 gram when 100 cc. are evaporated and heated to constant weight at 10(JC. to 110C.; water solubility, miscible with distilled water in all proportions; drvness, no turbidity when one volume is mixed with 19 volumes of 60B6. gasoline st 20C.; ap. g., 0.791 to 0.793 at 20Gv 20C.; ccidily, less than 0.002%, calculated as COj.; purity, 99-100% dimethyl ketone: potassium permanganate test, color of added potassium permanganate retained at least two hours when 1 cc. of a 0,1% solution is added to 100 cc. of Acetone; chlorides, none; iron, none; odor, mild--non-residual; flash point, -- 18C. (--0.4F.); * i, per U.S. gal., 6.59 lbs. at 68F. R.ll. Classificationi Acetone. General Information: Acetone m faster drying than ethyl acetate and a more active solvent. It is an important constituent of quick-drying water proof ce ments; an active solvent for cellulose acetate; a good dye solvent; resin solvent used extensively in paint removtrs and cleaners and for various extraction, processes. 26TH aniTio Page 21 0683761 TOWOLDMON0041845 WATER_PCB-00026314 0 ACETOPHENETIDIN, U.S.P NUCOCH, Mol. Wt. 17Q.11 Standard Forms: Crystals: powder. SpccifiratirmsiWhite crystals or crystalline powder; Solubility in ethyl alcohol 05% (1:15), complete: m.p. 135.0C. min.: a*h .05% max. No crystals retained on 11 mesh screen: 5% powder retained on 100 mesh. It.K. Clasafication: Chemicals NOILN. General Information: Pharmaceutical product. para-ACETYL-AMI.\0-BEN2ENESULFONECHLORIDE_____ NHCOCH, Mol. Wt. 233.59 Standard Form: Crystals. Characteristics: Light tao to browr.ish powder or fine crystals; assay, 97.5% min. R.R. Classification: Chemicals NOI8N. General Information: Used as an intermediate in the manufacture of sulfa drugs. ACETYL SALICYLIC ACID, U.S.P. (Also known as Aspirin) COOH 0OCOCH, Mol. Wt. 180.06 Standard Forma: Crystals, 20 mesh Crystals, 40 mesh Powder, 80 meeh Specifications: White crystals or powder: assay 99.5% min.; solubility in ethyl alcohol 95% (1:5), complete; solubility in 10% N&jCOj(1:20), complete; ash, 0.05% max.; conforms to U.S.P. teat for heavy metals, carbonisable impurities, rrsinous products, chloride, sulfate, and free salicylic acid. (Continued) Page 22 NTO CHEMICAL* so,a 0683762 TOWOLDMON0041846 WATER_PCB-00026315 Ml.SlI: Rci^ii:ird on-- 20 inc-.li screen :io mesh screen to mesh screen IS mesh screen 50 mesh screen 60 mesh screen 80 mesh screen Thru-- 100 mesh screen 140 mesh screen JO-mesh t0-mesh 80-mesh Trace max. 5.0%, min. 10.0% min. 43.0%, min. 60.0% max. 70.0% min. 85.0% max. Trace max. 10.0% min. 20.0% mat. 20.0% max. 15.0% min. 60.0% max. none 2.0% r 10.0% max. 25.0% max. R.R. Classification! Acetyl Salicylic Acid. General Information! Pharmaceutical product. ACETYL SALICYLIC ACID, Starch Granulations Standard Format 10%, 12-50 mesh, white 16%, 12-50 mesh, white 20%, 12-50 mesh, white 10%, 12-50 meah, pink 10%, 20 meah, pink 10%, 12-50 meah, green 10%, 20 mesh, green Specifications! (Made with Acetyl Salicylic Acid l\S.P.) White, pink or green granules. Aaaav: starch granulation 10%, 90.0% min. 91.0% max.; search granulation 16%, 84.0% min. 85.0% max.; starch granulation 20%, 80.0% min. 81.0% max, Free salicylic acid conforms to U.S.P. test on Acetyl Salicylic Void. MESH: Retained on-- 12 mesh screen 14 mesh screen 16 mesh screen 2(J mesh screen Thru-- 40 mesh screen TH EDITION 12-50 mesh Trace, max. 5.0% min. 15.0% max. 20.0% min. 35.0% max. 60.0% min. "5.0% max. i0.0% max. (Continued) 20-mesh Trace, max. 0683763 TOWOLDMON0041847 WATER_PCB-00026316 K,U, Classification: Acetyl Sa Iicy lie Acid. Ccneral Information: Pharmaceutical product. AC.II) CALCIL M PHOSPHATE (See Calcium Phosphate. Mono). WRCRAFT FINISHES _ Commercial Finishes; \ircraft finishes include protective and decorative coatings for every part of the aircraft structure, such as fabric dopes (clear and colors) for Mings, control snr. faces and fusilage; primers, snrfacers and lacquers for aluminum and dural sheet; llutne-proof dopes fur interiors, tbinners cleaning solvents. Properties of the com mercial finishes in application conform to the best modern plant practice, and properties in service meet the severe requirements of resistance to stress, sea water corrosion, weather, gas and oil, .Monsanto finishes have for years been accepted as standard by manufacturers and airlines. CODE NO. TYPE OF PRODUCT For Fabric--Dopes I,..'Idtll L-1031 L-2194 L-760 L-3193 L-3195 I,-2391 Clear Nitrate Dope (high solids) Clear Nitrate Dope (medium solids) Clear Nitrate Dope (comm, grade) Fully Pigmented Dopes--all colors: non-bleeding reds: mas. resist ance to fading and chalking. Interior Fire-Resistant Clese Dope Interior Fire-Resistant Pigmented Dopes--all colors. Finish Reclaimer (Rejuvent tor) for Nitrate Dope For Metal--Primers, Sur/acers, and Lacquers R-4017 Yellow 728 Zinc Chromate--Fat Drying. R-4063 Cray 578 Synthetic Primer Surfaces--Slowi Drying. R-3552 Cray 423 Lacquer and Dope Snrfacer. L-2939 Clear Aluminum Vehicle. R-3785 Fully Pigmented Lacquers--all colors (except light shades); non. bleeding reds; max. resistance to fading. I,. (518 1.-1087 L-2680 L-3196 L-)034 Page 24 Tbinners (Reducers)--All Types Standard lacquer and dope thinner. Retarder (anti-blush) Brush wash for general cleaning. For fire-resistant (acetate). Vax-free remover (dope and lacquer). (Continued) monjvnto chemicals 068376V TOWOLDMON0041848 WATER_PCB-00026317 I . S. Irm.v uii'.l Nmy Specification Finishes-. `in.... tlage linish<*! fore.... ibai aircraft a ere added n the Monsanto line ejrl> in tlie Defense Program. These finishes are in addition to the original l\ $. Army and l, S. Navy specification materials of which Monsanto has long been an approved supplier. Finishes under the new combined Ar_ / and Navy specifica tions (\N-TT) are imw available. W - l T-p.n' W-IT-I -'.I W-TT.Do. I I Ills M.IK.U Mi tat Surfaces /inr (Jironiuie Primer. Llo*s Lai 'picr Color*. (dear Aluminum llrmw.e Vehicle. Army (.amoiithige Colored Lacquers. Navy CaiiHnillflge Colored Lacquers. Fabric Surfaces AV-TT-D-SU \\.TT-1)."6 \VTT-Do54 I 1106 M-198 Clear Dojw. Semi-Pigmented Colored Dopes. Fully*Pigmented Colored Dopes. Army CamoulUge Colored Dopes. Navy Cauiouflcge Colored Dopes. Thinners AN.TT-T-256 For use with above lacquers. AN.TT-T-258 Blush Retarder for above lacquers. ILK. Classification! Lacquer. ALCOHOL (See Ethyl Alcohol). ALKYL PHOSPHORIC ACIDS Properties! Amyl Phosphoric Acid (from Pentaso))i fluorescent reddish amber liquid; sp.g., 1.33 at 25C.; alky I acid content, approx. 99%.* n-Butyl Phosphoric Acidi fluorescent reddish amber liquid; sp.g., 1.21 at 25C.: alkyl acid content, approx. 99%.* Ethyl Phosphoric Acidi pale straw colored liquid; sp.^., 1,33 at 25C., alkyl acid content, appiox. 97%.* Methyl Phosphoric Acidi pale straw colored liquid; sp.g., 1.139 at 25C.; alkyl acid content, approx. 97%.* n-Propyl Phosphoric Acidi reddish amber liquid; sp.g., 1.30 at 25C.; alkyl acid content, approx. 97%.* * Balance of assay is ortho-phosphoric acid and unconverted alcohol. R.K. Classificationt Phosphoric Acid. (Continued) 2<v rH edition Page 25 0683765 TOWOLDMON0041849 WATER_PCB-00026318 Central Information: The Alky! Phosphoric Acids are mobile liquids which ran be neutralized with alkalis and amines with resultant water-soluble salts. The methyl, ethvl and propyl phosphoric acids are water-soluble, but the butyl and amyl acids are not. The salts of all are water-soluble. The methyl and ethyl phosphoric acids ami their salts a^e very hygroscopic (amine, sodium and pousdiim salts) hhcreu* the propyl, hi lyl anil amyl acids are not hygroscopic .1 imI their salts only .lii'hllv so. Alkyl Phosphoric Acids are used in textile and paper processing compounds; .1- ruialy -is in urea resin formation: as polymerizing agents for resins and oils. ALUM (See Aluminum Sulfate). ALUMINUM CHLORIDE AliCl. Mol. Wt, 266.7 Standard Format Liquid, 32a B+, 5(>% ALCl* +12 H.O approx.; crystals,* 97% A1..C1,+12H:0 approx. Typical Analysis: Neutral salt, low in iron content. Solutions have an acid re* action but contain no free acid. Typical analysis as follows: Crvstal Liquid ALCU 12 H-O 97.2% 50.3% AfO, 20.5 10.6 Cl 42.7 22.1 Fe .003*.005 .005 M.ll. Classifications: Aluminum Chlor-de Dry or Aluminum Chloride Liquid. Ceneral Information t Used in carbonizing fine wool such as piece goods, raw slock or shoddy, resulting in an exceptionally white, lofty wool. Also in car bonizing colored goods where it has veiy little stripping action. Used in soap manufacture for treatment of glycerin lyes where chloride of alumina is more desirable than sulphate. (SeetoWe in general data section) Crystals: Resale product. ALUMINUM OXIDE ABRASIVE GRAIN (Also known as fused aluminum oxide: artificial corundum.) Specificationai Fused aluminum oxide containing 95-99% A!}0$; hardness 9.6, Moh's scale. R.H. Claasificationa: Abrasive flour or grain. Ceneral Information! Coarse to flour grades are available for grinding wheels, polishing, refractory purposes, and for arti-slip or tread use. Page 26 MONSANTO CHEMICALS 0683766 TOWOLDMON0041850 WATER_PCB-00026319 ALLMI>UM SULFATE, COMMERCIAL Al,(SO,)j. 14.5 H,0 Standard Form! Fine to lump. Typical Analysis! AIjOj, 17.2%; FeO, 0.35%; FejOj, 0.01%. K.K. Classification! Aluminum Sulfate. General Information; Used in paper sizing and water treatment. Monsanto also provides a slab form (6'*6'*18') for stock solutions; this form contains 15.5 16.0% AIjOj. (See table in general data section) ALUMINUM SULFATE, IKON FREE AI,(S04),. 14.5 HjO Standard Form! Fine to lump. Typical Analysis) AIjOj, 17.2%; FejOj, 0.01%. R.R. Classification! Aluminum Sulfate. General Information! Used in sizing fine papers; manufacture of satin white and dry colors; tanning white leathers; dyeing operations. ortho-AMlNODIPHENYL, TECHNICAL (Also known at 2-aminobipbenyl.) NH* Standard Form t Fused solid. ' Specifications! Purplish crystalline mass; crystallizing point 47.0C. min.; assay 94.5% min. Distillation range: first drop, 29S.0eC. min.; 95% (1-96 ml). 8.0C. max.; dry point, 310.0C. max. R.R. Classification! Dye Intermediate. General Informations Used as su intermediate in dyestuff synthesis; in the production of resins; in the production of varnishes; in the synthesis of rubber products; as a solvent. CAUTION: Thit product it toxic. Amid breathing its vapors and avoid contact with the thin, 26TH COITION Page 27 0683767 TOWOLDMON0041851 WATER_PCB-00026320 paro-AMINODIPHENYL, TECHNICAL (Alto known at 4-atninnbipbenyl.) ^ y- y NH, Mol. Wt. 169.10 Standard Forms Fused solid. Specifications! Yellowish brown crystalline mass; crystallizing point 50.5C. min. Distillation range; Firat drop, 325.0'C. min.; 95% {1 -96 mJ), 8.08C. max.; dry point, 3i08C. max. R.K. Classifications Dye Intermediate. General Informations Used as an intermediate in dyestuff synthesis; in the production of resins; in the production of varnishes; as a solvent. CAUTION: Thi$ product it toxic. Avoid breathing its vapors and avoid contact with the tkin. 2-AMINOTHIAZOLE_____________________________________ 11C-------s tip p \ MT| * Mol. Wt. 100.14 Standard Forms Crystals Characteristics s Light brown crystals. R.R. Classifications Chemicals NOIBN. General Informations Used as an intermediate in organic synthesis. AMMONIA, ANHYDROUS Properties! At normsl temperatures and pressures Ammonia Anhydrous is a colorless gas, 0.597 times as heavy as air. It is readily condensed by the ap. plication of pressure below 268'F, to a colorless Liquid weighing 5.33 lbs. per gal., and having a boiling point of--28eF. R.R. Glassifications Anhydrous Ammonia. General Informations Ammonia Anhydrous is used in refrigeration; as a eon. densing agent in the formation of pbeoolfonnaldehyde resins; in water treatment in connection with chlorine; partial neutralization of phosphate fertiliser; in vulcanisation of rubber; nitriding of steel; as a neutralising agent after carbon, izing; neutralising excess carbon dioxide in water supplies; neutralising and deodorising rubber goods which have been cured with sulfur chloride; neutral* izing petroleum stocks before crackling; as a relatively inexpensive source of hydrogen or nitrogen; and as a solveut. (See table in general data tedion) Available Literature! Leaflet: "Monsanto Ammonia for Refrigeration." Page 28 MONSANTO CH1MICALS 0633768 TOWOLDMOIM0041852 WATER_PCB-00026321 AMMONIA, AQUA NHtOH Mol. Wt. 3S.0S Standard Forma: Commercial Aqua Ammonia 16s, 1R6, 20s, 26s B6. Properties: Pungent, water white liquid; wt. per gal. 7.48 lbs. (26s). K.K. Classificationi Ammonia Aqua. General Information! Uses--1. Partial neutralization of phosphate fertilizers. 2. General household cleaning purposes. 3. As a condensing agent in the forma, tion of phenol-formaldehyde resin*. 4. As an antichlor. 5. After carbonizing, as a neutralizing agent. 6. Neutralization of excess carbon dioxide in water supplies. 7. Neutralizing and deodorising rubber goods which have been cured with sulphur chloride. 8. Neutralizing goods which have been dyed with aniline black. 9. Pre serving rubber latex. 10. Neutralizing oil before cracking. 11. Silk degumming. 12. Manufacture of cuprammoniqm silk. 13. As a solvent. 14. As a debarring agent for bides. 15. For reeling silk. 16. At a penetrant in wetting back crusted tanned leather. 17. As a penetrant for driving in fat liquor in leather making. (See table in general data tection) AMMONIUM BENZOATE Mot. Wt 139.15 Standard Formi Powder. Specificationsi Fine white crystalline powder; assay 98.0% min.; solution in water (1:10) clear. H.R. Classificationt Chemicals NOIBN. General Inforznatlom Used as a preservative. AMMONIUM ETHYL PHOSPHATE (Mixture of mono- and diethyl ammonium pboepbstes). Standard Form: 75% solution is water. Properties: Wster-wbiie to yellow-tinged liquid of ammoniscal odor; ap. g. 1.23 at 25SC.; wt. per gal. 10.37 lbs.; pH 75% sol.; 7.0 7.2; viscosity at 25C., 60 centipoises. Chemical constitution: 67% mono ethyl ammonium phosphate; (Continued) 26TB SDITION Page 29 0683769 TOWOLDMON0041853 WATER_PCB-00026322 53% di ethyl ammonium phosphate. In thin film is liquid at relative humidities above 40%; not stable to heat; when subjected to elevated temperatures for any length of time as a solution or while on any article, will liberate ammonia with a reduction in pH; at temperatures below IS'C. crystals will form in ibe solution and will dissolve with a rise in temperature or on dilution. 11,It, Classificationt Ammonium Phosphate. General Informations Used as flams proofing agent for paper, textiles, wood ;iml other combustible materials. AMMONIUM HYDROXIDE C. P. NHtOH Mot. Wt. 35.06 specifications* Colorless liquid, free from suspended matter; strength (NHj) 28.0% min.; non-volatile matter 0.005% max.; carbon dioxide (CO}) 0.i,'*2% max.; total sulphur (as SO*) 0.0003% oiax.; chloride (Cl) 0.00005% max.: pyri dine, to pass A.C.S. test; substances reducing (K.WnO*), to pass A.C.S. teat; iron 0.0001% max.; heavy metals (as had) 0.0005%. R.R. Classificationt Chemicals, Ammonia. General Information! Laboratory reagent. AMMONIUM PHOSPHATE, Dl (Also knowo as diammonium hydrogen phosphate, secondary ammonium phoe- phate, and ammonium phosphate di-basic.) (NH,)jHPOi Mol. Wt. 132.068 Gradest Food (meets al) U. $. Pure Food Law requirements); special grades supplied on request. Properties! White crystalline material, stable in air and very soluble in water: pH value of 1% solution, 7.75. At temperatures above 70C. aqueous solutions lose ammonia readily. Dissociation Pressure: According to Britxke and Dumajew (Gmelin'a Handbuch der anorganiscbe Cbemie, Ammoniak, p.423) and Warren (JACS 49,1904,1927)i Temp, C. 98 111 125 135 147 p NH, in mm. Hg. 3.2 10.7 26.0 55.2 123.4 R.R. Classification* Phosphate of Ammonia. General Information! Used as a fire retardant in fire-proofing and as a yeast food by yeast producers and breweries. Page 30 NSANTO CHEMICALS 0663770 TOWOLDMON0041854 WATEFLPCB-00026323 PM ttMUfvr I of O'Qmminivn tivmmmon um Pxcite*iH c A H-43S L\ \ 'v. s' 1-1 rs ' AMMONIUM PHOSPHATE, MONO (Also known at ammonium acid phosphate, primary ammonium phosphate, ammonium dihydrogen phosphate, ammonium phosphate mono-basic, am monium biphosphate). NH4HjPO* Mol. Wt. 115.04 Cradesi Food grade meets all U.S. Pure Food Law requirements. Special grade* will be supplied on request. Properties! A white crystalline material, stable in air and soluble in hot and coid water; pH of 1% solution, 4 7. R.R. Classificationi Phosphate of Ammonia. General Information) Used as a retardant in fireproofing and paper special ties, for special medicinal purposes, in the production of woven belting, and as a yeast food. AMMONIUM SALICYLATE N.F. (See Salicylates). AMYL ACETATE________________________________________________ Typical Analysis) Water white liquid; odor, no residual; sp. g. 0.865 0.870 at I5.5C.; shipping wt, per gal., 7.?0 lbs.; acidity, less than 0.01% as free acetic acid; dryness, mixes with petroleum benzine in all proportions without turbidity. Boiling range: below 110C., none above 130'C,, less than 50%; above 150C., none. Ester content, 85-90%. (Continued) KTI EDITION Page 31 0683771 TOWOLDMON0041855 WATER_PCB-00026324 R.R. Classification; Amyl Acetate General Information! Used as a nitrocellulose solvent. It is less active than ethyl or butyl acetate and more resistant to moisture. Blends of all three with appropriate diluents such as alcohols (ethyl, butyl, and amyl) yield thinners and solvent mixtures of excellent cutting power, moisture resistance, good flow ar.d leveling, and compatability with various resins and oila. Used in the artificial leather industry and in formulating lacquer finishes for wood, metals, textiles, unii paper. WML PHOSPHORIC ACID (See Alkyl Phosphoric Acids). ANILINE OIL___________________________________________ ( Men known as atuinobenzeae). NH* Mol. Wt. 93.15 Specifications! Slightly yellowish liquid; purity, 99.5% min.; distillation range, 95% within 0.5C.; distillation limits, 182.0 to 185.0C. (dry point); crystallizing point, --6.2`C. min.; moisture, 0.10% max.; solution in HCI, complete; nitro benzene. none. R.lt. Classification* Aniline. "Poison*' label required. General Information! A basic intermediate in the dyestuff industry. It also finds application in the production of rubber accelerators, as a constituent of resins and in the manufacture of explosives. CAUTION: This product it toxic. Avoid breathing itt vapors. Avoid contact with the skin. ortho-AMSIDINE_________ (Also known as ortho-metboxyantline, ortfio-amtnoaniaolc, and l-amino-2-tne- ihoxybenzene.) OCHs Mot. Wt. 123.15 Standard Form! Liquid Specifications! Reddish brown to amber liquid; crystallising point 5.3C. min. Distillation range: first drop 223.0C. min.; 95%, 1.2*0. max.; dry point, 22fi.0C. max. Solution in UC1, clear. R.R. Classificationi Dye Intermediate. General Information i Used as a component of azo dyes and in the manufacture {Continued) Page32 Monsanto cbsmicxls 06B3772 TOWOLDMON0041856 WATER_PCB-00026325 of dyestuff intermediates. CAUTION: This product is toxic. Avoid breathing Us (upon and avoid contact uith the skin. para-ANISIDINE (Also known as para-metboxyamlioe. para-aminoanieole. and l-amino-4-methoiy benzene.) OCH, Mol. Wt. 123.15 Ml. Standard Form: Fused solid Specifications: Fused, crystalline mass; crystallizing point 57.2C. min. Distilla tion range: first drop 240.0C. mi.; 95% 2.0C. max.; dry point 243.0'C. max. Solution in HCI clear, darkens on ageing. K.R. Classification: Dye Intermediate. General Information: L'sed as a component of various azo dyestuffs and as an intermediate in chemical synthesis. CAUTION: This product is toxic. Avoid breathing its vapors. Avoid contact with the skin. ANTI-OXIDANTS, OIL (See Santolube). I-- ANTIOXIDANTS, RUBBER See individual antioxidants below for specifications. R.R. Classificationt Chemicals NOIBN. Available Literature: "Monsanto Chemicals for the Rubber Industry," 42 pages. "Latex Compounding," 36 pages. "Rubber Compounding for the Wire Industry," 48 page*. "FLECTOL H" Specifications: Condensation product of acetone and aniline. Light colored powder; 99.5% min. through 200 mesh, no coarse particlee; m. p. 120C. min.; sp. g, 1.08; antioxidant value equal to that of the accepted standard in vulcan ized rubber, both in oxygen bomb and standard flexing teats; solubility approx. 10% in bsntsns, alcohol and gasoline; insoluble in water. "FLECTOL WHITE"_____ Specifications t Light colored powder, not darker than the approved color (Continued) 26TH edition Page 33 A N T IO X ID A N T S 0683773 TOWOLDMON0041857 WATER_PCB-00026326 s j.x v a ix o u .x v standard; 99.5% min. through 200 Utah, no coartro panicles; m. p. 145C. n>in.> sp. g. 1.25: antioxidant value equ I io that of the accepted standard in ultra violet light tests; soluble in alcohoi. very slightly soluble in water and benzene, insoluble in gasoline. "OXYN'ONE** (2, 4-Diamino Diphenylamine) Specifications: Brown crystalline powder; 99.5 per cent through 100 mesh and 95 per cent thronch 200 mesh, nocoari>e particles; m. p. not less than tp. g. 1.23; soluble in alcohoi, chloroform and benzol; very slightly soluble in cold water and gasoline. "SANTOFLEX B" Specifications: Reaction product of acetone and para-aminodipbenyl. Waxy, dark gray, lumpy solid; crystallizing point about 80C.; sp. g. 1.045. "SANTOFLEX BX" Specifications: Constant composition blend of Santoftex B and diphenyl-para* pheoyleoe diamine. Waxy, dark gray, lumpy solid; sp. g. 1.11. "SANTOVAR A" Specifications: Alkylated polybydroxy phenol. Nearly white crystalline powder, o darker than the accepted standard; m. p. not less than 165'C,; sp. g. 1.049; completely soluble in twice its weight of acetone. General Information: Used as a varnish anti-skinning agent; as an antioxidant in oils, paints, and rubber. ANTISEPTICS AND GERMICIDES Chloramine-T U.S.P. (See under C). pora-Cbloro-meto-Cresol (See under C). para-Chlnro-meta-Xylenol (See under C). Dichloramine-1 N.F. (See under D). Phenol U.S.P. (See under P). "Santamine" (See under S). "Santopben" (See under 5). ARESKAP (MooobutylPhenylphenol Sodium Mononulfoaate) Standard Forms: Liquid and dry powder. (Continued) Page 34 lONsa'iTO CHBMICALS 068377* TOWOLDMON0041858 WATEFLPCB-00026327 K.R. Classification! Washing Compound VMBN General Information: Wetting, penetrating and spreading agent; used as spreading agent in insecticidal compositions, in embalming fluids and in metal pickling. AKESKKT (Monobutyl Diphenyl Sodium Monosulfonate)___ Standard Forms: Liquid ami dry powder. It.It. Classification: Washing Compound NOIBN. General Information t Wetting, penetrating and spreading ageot. AKESKLENE (Dibutyl Phenylphenol Sodium Disulfonate)__ Standard Forms: Crystals and glauboids. Typical Analysis: 43% NajSO^ available. Dry AreBklene-400: Tan hygroscopic powder, slightly aromatic; sulfates, trace; chlorides, trace; m, p. about 160C.; pH, appro*. 7.5 for 1% solution of dry material at 25C.; soluble (10 parts to 90 parts solvent) in alcohol, acetone, dibutyl tartrate, ethylene glycol, ethyl acetate and butyl cellosolve. Aresklene-375: Light brown paste, slightly aromatic; sulfates, trace; chlorides, (Continued) A laboratory In the new rubber chemicals research building at Nitro, W, Va, 06837?S TOWOLDMON0041859 WATER_PCB-00026328 trace: ni, p., decomposes al about 175 C ; not soluble in solvents which are immiscible with water. R.R. Classification; M ashing Compound, NOIBN. (General Information: Writing, penetrating and spreading agent used in kicrhoiling, scouring and dying textiles, in industrial cleaners, in deodorant preparations, in insecticidal formulations, in metal cleaning and as a stabilizer .md wetting agent in latex used to treat tord or other fabrics. Specifications: The Aroclors are chlorinated hydrocarbons which varv from water-white mobile liquids and pale yellow viscous oils to light amber resins and opaque crystalline solids. I\'on-fiammability: The viscous Aroclor oils and resins do not support combustion when heated alone even at their boiling points-- temperatures above 360C. Most of the Aroclors flux readily with resinous and pitch-like materials to give a product hating a decreased fire hazard. Electrical properties: The Aroclors have excellent electrical characteristics, high dielectric strength and resistivity, low power factor. Certain of the liquid Aroclors have a high dielectric constant as compared with that of mineral oils. Solubility: The Aroclor oils and resins are easily soluble in most of the couuiiim organic solvents and drying oils. The hard crystalline materials are in general less soluble than the oils of resins, All Aroclors are insoluble in water. Adhesit'eness: The more viscous Aroclor and Aroclor resins have excellent adhesive properties. Thermoplasticitv: The Aroclors are thermoplastic, and apparently undergo no further condensation or hardening upon repeated melting and cooling. Aon-drvmg properties: The Aroclors are non-drving, and when they are exposed to the air no noticeable oxidation or hardening takes place. Vaporisation loss: The clear resins have rather low vaporization losses. At 65.8`C. (150F.) these losses are less than 0.04 g. per square inch of surface per month. Odor and taste: The Aroclor viscous oils and resins are almost without odor and taste at ordinary temper atures. Refractive indices.' The refractive indices of these materials are above 1,6125. Stability: The Aroclors in general are stable on long heating at 150C. and are not affected by boiling with sodium hydroxide solution. The light oils ran be distilled at atmospheric pressure without appreciable decomposition and the viscous oils and resins distill readily under vacuum. Corrosiveness: The Aroclors have practically no corrosive anion when applied to metallic surfaces. General Information: Uses: Lacquer, paint and varnish: Aroclors impart resistance to moisture, gas, acids, alkalies, and ultra violet light and improve electrical insulating properties and durability. They function as both plasticizers and resins in nitrocellulose and ethyl cellulose lacquers. Sealing Waxes: Where a moisture proof, non-flammable wax or one with good electrical insulating properties is desired. Adhesives: Aroclors in adhesive application have the desirable qualities of being non-crystalline, insoluble in water, thermoplastic, light in color, practically odorless, non-drying, and soluble in most organic sol vents. They provide excellent adhesion even to lacquered or varnished surfaces. Impregnation: Aroclors are used in impregnation of materials and articles to give them resistance to moisture, flame, alkalies and acids, and to improve electrical insulating properties. Corresponding to each clear Aroclor there is also a black Aroclor of similar properties. Flameproofing: Aroclors are used in combination with many other materials to reduce the flammability of those materials. Rubber and rubber substitutes: The liquid Aroclors have a solvent (Continued) Page 36 Monsanto chemicals 0683776 TOWOLDMON0041860 WATER_PCB-00026329  action on rubber and act as pUstreizer. The solid Aroclors impart flame resist ance. Plastics: The Aroclors are compatible with nitrocellulose, ethyl cellulose and vinyl resins. In ground powder form is an excellent organic pigment. Available Literature: 20-page Utokler "The Aroclors -- I'hvsical Pro|>orties and Suggested Applications." ASPIRIN (See Acetyl Salicylic Acid). BATTERY ACID (Electrolyte) Typical Analysis: Practically colorless liquid; HjSO,, 93.2% min.; iron, 0.005% max.; nitrogen compounds (as HNOj), 0.001% max; sp. g. 1.210-1.835. (Acids of lower strengths should be calculated in proportion to above specification on HjSOj content.) R.R. Classification! Sulfuric Acid. General Information: Electrolyte is sulfuric acid, especially adapted to the needs of the storage battery trade Various strengths can be furnished to meet the needs of the individual purchaser. BELT CEMENT _. General Informationi Nitrocellulose base cements for cementing ply belting and laps. Characterized by strength, flexibility, rapid drying properties, and resistance to water. Specially adapied to power belting. More flexible typee are offered for wool combing aprons and paper machine dryer felts. R.R. Classification! Lacquers. BENZENE SULFONAMIDE, TECHNICAL 0 o-- 0 Mol. Wt. 157.18 Characteristics: A brownish crystalline solid, crystallizing si 150" 152C. R.K. Classification: Lacquer Solvents, NOIBN. General Informations This product is the tecbincal form of Santiciser 129. It may be used in orgsnic syntheses, production of dyestuffs or as a plasticizer in resinous compositions where colt* is not a factor; is analogous to Monsanto's para-ToluenesuLfonamide and can probably be used as a substitute in most applications. 26TH IDtTIOM Page 37 06S377? TOWOLDMON0041861 WATER_PCB-00026330 T BENZENE SULFONIC ACID, TECHNICAL Mol. Wt. 153.17 SO,H Characteristics! Greenish black viscous liquid or crystalline mass: crystallizing point. 25.8``C. (appro*.): HjSO,. 24.0.25.0%; benzene sulfonic acid. 70 6.71.0%; sp.g. 25/I5.5,C., 1.45 (appro*.). K.R. Ossification! Chemicals. NOIBN. General Information! Used as an intermediate in organic synthesis and as a catalyst in certain condensation reactions. BENZOATE OF SODA (See Sodium Benzoate). BENZOIC ACID Mol.Wt. 122.12 Grade*! U.S.P. and Technical. Specification* of U.S.P. Grades White crystalline needles or fine powder; assay 99.5 min. (dry basis); m.p. 122.5'C. min.; solution in alcohol (1:2.5) and in 10% sodium carbonate (1:6), clear and colorless: meets U.S.P. test for carboaisable impurities; 5% max. powder retained on 100 mesh screen. Specifications of Technical Grades White to yellowish white granules or powder; assay, 99.25% min.; odor, characteristic; solution in 10% NfljCOj (1:6), slightly turbid or opalescent and practically colorless; approx. 10-20% retained on 20 mesh; approx. 100% retained on 100 mesh. R.R. Classification! Of U.S.P. Grade--Food Preserving Compound; of Tech* nical Grade--Chemicals, NOIBN. General Information! U.S.P. Grade used in medicinal preparations and as a preservative in foodstuffs. Technical Grade used in the manufacture of ben* zoates and benzoyl compounds; aa an intermediate in the manufacture of dyes; as a mordant in calico {Minting; as a modifying agent in alkyd resins; as a color stabiliser in baking varnishes; a* a dispersing agent in the grinding of pigments. P.,.38 MONSANTO CHEMICALS 0663770 TOWOLDMON0041862 WATER_PCB-00026331 BENZOTRICHLORIDE _ CCIi 0 Mol. Wt. 195.45 Standard Form: Liquid. Specifications: Colorless ro light green or yellow liquid; crystallizing point 6.<>C. min. Distillation range; fWt drop, 218.0C. min.; 95% (1.96 ml). 2.DC. mu*.; dry point, 223.0C. uiax. K.K. Classification; Chemicals NOIBN. General Information; Used as an intermediate in dyestuff synthesis. C 41T10.\- Irritating to the skin, t npors are highly irritating to the eyes. Avoid breathing vapors. Avoid contact with the skin. BENZYL CHLORIDE CHiCl Mol. Wt. 126.59 Specifications: For anhydrous liquid and material recovered from 10% solution below: Colorless to light green to brown liquid; sp. g. at 15.5/15.5'C.. I. 104 1.10B. Distillation range: first drop, 177.5*0. min.; 95% (1*96), 3.0C. max.; dry point, 185.0C. max. Liquid with 10% NajCOj: NajCO, in water solution, 9.0 11.0%. Note: 23 lbs. of 10% NajCOj solution are addtd to 450 lbs. of benzyl chloride contained in 55 gal. black iron drums. The wet material is a milky white emulsion, from which water may separate into a definite layer at either the bottom or top de> pending on the temperature and the concentration of NajCOj. The concentration of VajCOj slowly decreases on standing. II. 11. Classification: Chemicals M31BN. General Information: Used in the production of the following: Dyestuffs; perfume bases such as benzyl alcohol, acetates, benzoate and phenyl ethyl ah cohol; plasticizers; resins; wetting agents; rubber accelerators: gasoline gum inhibitors; benzyl cellulose; various pharmaceuticals. CAUTION: This product is irritating to the skin. Vapors are highly irritating to the eyes. Avoid contact with the skin. Avoid breathing vapors. BISL'LFATE OF SODA (See Nitre Cake) BISULFITE OF SODA (Set Sodium Bisulfite). 26TH EDITION Page 39 0689779 TOWOLDMON0041863 WATER_PCB-00026332 BLEACH (See Merclor). BONE ASH. Cenerallnforntationt Mold wash grade for coaling molds used incastingcop|>er wire bars, ingots and slabs. A siifxrior un>ld coaling for certain steel casting operations. This product is also used in producing opal and other translucent glasses. lt.lt. riu^ifioution, Hone Ash. BONE BLACK Crudest Twelve grades are available which vary in fineness, top tone, undertone, liming strength, and color in oil. Specifications! In general, bone blacks when compared with lampblack or carbon black have greater hardness and lower oil absorption. They mix easily wiih water, shellacs and lacquer, and are relatis able to sunlight. Specific#, lions for the various standard grades are as foil Grade No. % of Moisture % PjOj +5 4.10 33.50 150 4.10 33.50 250 4.94 33.05 350 4.07 30.1S 439 4.78 32.05 439 Spec. 4.78 31.73 450 & 450-CT. 4.86 34.50 650 4.28 34.00 841 4.02 32.95 850 3.82 34.60 32.30 Lbs. oil pec 100 lbs. pigment. **No. 450, 99.90; No. 450-CT.. * % Caru>>.i 9.20 9.20 9.75 13.84 14.57 15.12 9.30 8.75 8.90 8.37 9.70 Oil Absorption* 46.2 46.2 43.9 43.9 50.2 50.5 42.7 43.9 46.2 43.9 46.3 % thru 325 Screen 99.89 99.90 99.40 99.85 99.95 99.90 ** 99.73 99.90 99.90 99.95 R.K. Classification! Animal Charcoal, Other Than Spent. General Information! Chief use is as a pigment in leather finishes, artificial leather, paints, iacquera, japans, inks and wail paper. Bone black has good jetnesa and is easy to wet, whereas lampblack wers only with difficulty and has much less jetness. BRONZING LIQUIDS General Information! Clear lacquei base mediums for aluminum and bronze powders. Several types offered for metal, wood, fabric, and paper. Applied by spray or machine coating. Many are inhibited to retard gelling. II.R. Classifications Bronzing Liquids. Page 40 MONSANTO CHEMICALS 0683780 TOWOLDMON0041864 WATER_PCB-00026333  'HLTASAN" (See Accelerators, Hubber). BUTYL ACETATE Typical Analysis! Water * hite liquid; sp. g. 0.872 0.877 at 2O'205C.: 7.3 lbs. I'T gal.: csier con tern, 88-90%. Boiling range: below 1 l.VC., none; below 122C.. n..l over 10%; below 12SC., a: least 90%; below 130C., l<m%. Drvne mixes w ilh 14 vol*. 60 Be. gaol,ne. Less than 0.01% as free arctic acid. II.It. Classification i duty! Acetate. General Informations Used as a nitrocellulose solvent. Is intermediate in uumity between ethyl aertate and amyl acetate. Blends of all three with ap pro] riate diluents such as alcohols (ethyl, butyl, and amyl) yield thinners and advent mixtures of excellent cutting power and moisture resistance, good flow and leveling, and compatability with various resins and oils. Used in the artificial leather industry and in formuiatmg lacquer finishes for wood, metals, textiles, and paper. BtTYL BENZENE SULFONAMIDE (See Santiciter 127). rt-BL'TYL PHOSPHORIC ACID (See Alkyl Phosphoric Acids). BUTYL PHTHALATE (Set Dibutyl Phthalate). BUTYL PHTHALYL BUTYL GLYCOLLATE (See Samidr B-i6) CABLE LACQUERS. General Information! Manufactured in clear, black and color# for application hv gasket, for high tension automotive cables and primary wires. Special types are available that are flameproof, resistant to hot oil, and have high beat test ratings; also noodnflsmmable type sleeving lacquer of high dielectric strength. All types build well, giving g tough, glossy, flexible finish. R.R. Classification! Lacquers. 26TH Bft'TION Page 41 0683781 TOWOLDMON0041865 WATER_PCB-00026334 CAFFEINE, U.S.P. CH, I \-C = 0 o = d: c-n' CH, . HiO iu . N --C -- N ' I CII, Mol. Wt. 212.21 Standard Formal Powder, anhydrous powder, hydrated. Specification*! White powder. Los* on drying at 80C: anhvdrous pon.lrr 0.25% max.; hydrated flake* 5.75 6.50%. M.p. 235C. min.; meet* U.S.P. test Tor rarbonizable impurities. MESH Retained on-- 20 mesh screen 35 mesh screen 45 mesh screen 100 mesh screen 200 mesh screen Hydrated Trace max. 12 0% max. 18 0% max. R.R. Clasaficatlont Chemical* NOIBN. Anhydrous None 2.5% max. General Information i Pharmaceutical product. CAFFEINE, CITRATED, U.S.P. _. CH, := o .CH, 0 .CH :-N * H,C -- COOH ,1 + HO--C-COOH 1 HjC -- COOH (Caffeine) (Citric Acid) Equal quantities by weight Standard Form i Powder. Specification*! White powder; asaay 48.0-52.0% anhydrous caffeine; lost on dry ing at80C., 0.2% max.; solubility in watet(1-4), complete; conform* to U.S.P. tests for sulfate and heavy metals; 15.0% max. retained on 100 mesh screen. R.R. Classification Chemical* NOIBN. General Informations Pharmaceutical product. Page 42 MONSANTO CHEMICALS 0663782 TOWOLDMON0041866 WATER_PCB-00026335 CALCIUM GLYCEROPHOSPHATE N.F. (See Glycerophosphates). CALCIUM NITRATE Ca(NOj)j.3 11*0 Standard Format White crystals; 75% water solution. Typical Analysis; Cd<NOj)} 3 IIjO Heavy Metals RA Water white Crystals 98.95% make up nitrate. Solution 71.21% none none none 25% 100% is probably ILK. Classification: Calcium Nitrat*. General Information: Used as a coagulant in latex dipping processes. CALCIUM PHOSPHATE, MONO_______ _______________________ (\lso known as primary calcium phosphate, calcium di-hydrogen phosphate, mono-basic calcium phosphate, calcium acid phosphate, and acid phosphate of lime). Grades: Regular for phosphated and self-rising flour and baking powder Granular for baking powder. All grades meet U S. Pure Food Law requirements. Special grades will be supplied on request. The following mixtures are carried in stock: A'eut. Strength 52 50 50 45 45 45 Constituents Regular, Starch and 15% Calcium Sulfate. Regular and Starch Granular a(id Starch Regular, Starch and 18% Calcium Sulfate. Regular, Starch and 30% Calcium Sulfate. Regular and Starch. Propertied A white stable material, soluble in water, giving an acid reaction. K.R. Classification: Calcium Phosphate. General Information: Used in baktries for leavening purposes and to prevent the formation of "rope'' in bread; as a leavening agent in biscuits and crackers and as an acid leavening agent in pancakes; as sole acid agent or mixed with sodium aluminum sulfate or sodium acid pyrophosphate in baking powders: in making self-rising, phosphated plain flour and prepared flours: to control pH of solution in malt. 76TH EDITION 0663783 TOWOLDMON0041867 WATER_PCB-00026336 CALCIUM PHOSPHATE, DI____________ ________________________ (Also known as phosphate of lime, precipitated bone, secondary phosphate of lime, dic&lciuDi ort/io-phosphate and bibasic calcium phosphate.) Anhydrous C 1 l>01 Dihydrate CaHP0i.2H}0 Mol. Wi. 136.068 Mol. Wi. 172.084 Standard Forms t Anhydrous; dihydrale. Properties: Insoluble in alcohol; solut-l in dilute citric acid solution, Solubility in COj free water in grate per liter: Anhydrous: CaO PjOj Dihydrate: CaO P,04 30C. .0414 .0866 .0954 .2066 soc. .667 .1630 .2617 .6182 68c. .0985 .2234 .3409 .3245 loo.rc. .1046 .2461 ,3109 .7591 Gradest Medicinal; food; dentifrice. R.R. Classification > Calcium Phosphate. General Information} Used as a mineral supplement in diets that are deficient in calcium and phosphorus; as polishing agent in tooth pastes and powders. Anniston, Alabama, plant of the Phosphate Division. 068378V TOWOLDMON0041868 WATER_PCB-00026337 CALCIUM PHOSPHATE, TRI________________________________ (Also known as tri-basic calcium phosphate, normal calcium phosphate, neutral calcium phosphate, tertiary calcium phosphate.). Standard Formt White powder. Grades) Dentifrice, conditioner (salt, sugar, etc.), and medicinal. All material conforms to requirements of the I .S. Pure Food Laws. Properties! White amorphous powder, odorless and tasteless: practically in soluble in water. K.R. Classification! Calcium Phosphate. General Information! Used as a mineral supplement to supply calcium and phosphorus; as a tooth paste base or polishing agent in tootb powder: as an in gredient in making milk glasses; as an antacid; aa a conditioner to prevent caking in salt, sugar, talc and other powdered material. CALCIUM PHOSPHATE, X-C Generallnformation: Extra rich in calcium. Used as a mineral supplement to supply calcium and phosphorus, especially in enriched flours; to control pH of baked products in order to reduce loss of Thiamin (Bj) in baking process; in phnsphating plain flours. CALCIUM PYROPHOSPHATE Ca2P207 Mol. Wt 254.12 Properties! A finely subdivided powder; contains 43.8% CaO and 55.5% P205. General Information! Used io food fortification as a mineral supplement. CALCIUM SALICYLATE (See Salicylates). CALCIUM SULFATE (See Crysalba). CARBOLIC ACID (See Phenol). CARBON DIOXIDE GAS________________________________________ CO* Typical Analysis! 100% CO* appiox.; sp. g. of liquefied gas, 1.057. Continued) 26TH EDITION Page 45 0683785 TOWOLDMON0041869 WATER_PCB-00026338 K.R. Classification: Liquefied Carbon Dioxide. General Information: Monsanto carbon dioxide is liberated from pure soda ash. It is purified, dried and compressed to 400 lbs. per sq. in. in a multi-stage compressor, then condensed or liquefied and placed in steel cylinders. Thus pre pared, it is entirely free from odors and tastes and is widely used in carbonating beverages. It is also used as a non-oxidising atmosphere, in rubber vulcanizing, in dry cleaning, in preserving foods, or wherever an inert oxygen-free medium is required. Liquefied Carbon Dioxide is the cheapest source of high pressure which is portable and without tire hazard. CARBON DIOXIDE, SOLID (Dry Ice)___________ Standard Formt Blocks, 10'xl0'x]0', weighing 50 to 55 lbs. K.R. Classification: Dry Ice. General Information: A product of molasses fermentation in the manufacture of alcohol. Carbon dioxide thus produced as compared with the gas from other sources permits higher yield and a purer product, requiring less processing for purification prior to liquefying and solidifying. Used for low temperature refrig eration. CAST PHENOLIC (See Plastics, Opalon). CATECHOL {See Pyrocatechol). CAUSTIC SODA (Also known as sodium hydroxide) NaOH Mol. Wt. 40.00 Standard Form: Solution 50%. Specifications: Practically clear, colorless or slight yellowish or greenish tinge; sodium hydroxide 48.5% min., 50.$% max.; sodium carbonate 0.20% max.; sodium chloride 1.25% max.; sodium chlorate 0.04% max.; iron 0.007% max.; sodium sulfate 0.04% max.; copper 0.0005% max. R.R. Classification: Caustic Sods. General Information: Used in petroleum refining, vegetable oil refining, tanning, soap making, textile manufacture (rayon), rubber reclaiming. CELLULOSE ACETATE (See Plastics. Fibeetoa). CELLULOSE NITRATE (See Plastics, Nitron). Page 46 lONSANTO CRI Wt CA IS 0683786 TOWOLDMON0041870 WATER_PCB-00026339 CEMENTS General Information: Rapid-drying waterproof cement in various soluble cellulose and resin bases: also heat sealing cements. A complete line of cements is offered for adhering wood, metal, paper and fabric to various plastic materials: also cements for packaging in collapsible metal tubes, such as household cement, model airplane cement, and library cement. K.R. Classification) Lacquer. CHLORAL HYDRATE, U.S.P CCIjCU(OH)j Standard Form) Crystals. Mol. Wt. 165.39 Specifications: Colorless, dry transparent crystals; assay 99.5% min,; solubility in water (1:1), complete: water solution neutral to litmus: comforms to U.S.P. test for carbonizable impurities and chlorides. R.R. Classification: Chemicals NOIBN. General Information) Used id pharmaceutical preparations and veterinary medicines. CHLORAMINE-B______________________________ (Also known as N.N-sodium chlorobenzene sulfonamide) . 1V2 H.O Mol. Wt. 240.63 I N^N^C1 Standard Formt Crystalline powder. Specification*: Nearly white crystal* or crystalline powder: soluble in water; active chlorine 14.45% min. General Information! Chloramine-B is a water-soluble, chlorine-bearing pow der used as a germicide, disinfectant and deodorant. CHLORAMINE-T, U.S.P oM II Na y'S--. 3H0 o Standard Formt Cryatalline powder. Mol. Wt. 281.70 Specification*i White or faintly yellow powder or granules; solubility in water (2;15), complete; free alkali (as N*OH), 0.07 0.15%; loaa on drying (3 hr*, at (Continued) 26TB edition page 47 068378? TOWOLDMON0041871 WATER_PCB-00026340 97C.), 18.9 20.0%: active chlorine 12.25 - 12.60%; assay 97.3% mm. MESH Retained on 10 mesh screen--Trace max. Retained on 35 mesh screen--1.0% min. R.R. Classification: Disinfectant other than medicinal. General Information: Chloraraine-T is a water-soluble, chlorine-bearing pow. iler used as a germicide, disinfectant and deodorant. C'HLORCOSANE (Chlorinated Paraffin, N.F.) Specifications: Light yellow oil; odorless and tasteless; sp. g. 1.00 to 1.07 at 25'C.; combined chlorine content 27% to 30%; reaction of water extract to lit mus. nrutral; chlorides (as HCI> 0.004% max.; free chlorine, none; unchlorinated paraffin, negative (N.F. test). K.R. Classification i Chemicals NOIRN. General Information: A solvent for dichloramine-T. For uses where a product with fire-resistant, insulating and aoivait properties are indicated. CHLORINATED DIPHENYL (See Arodort). CHLORINATED PARAFFIN, N.F. (See Chlorcosane). CHLORINE Specifications: Ctear, amber colored liquid; about 1 times as heavy as water; conforms with American Water Works Association specifications. R.R. Classification: Chlorine- General Information: Used for municipal water purification, sewage treatment and swimming pool sterilization, for slime control, in pulp and textile bleaching, metallurgy, bleaching and processing of flour, organic synthesis, and in the manufacture of metallic chlorides and hypochlorites. CAUTION: Chlorine is toxic and highly irritating. Avoid contact with the tkin and breathing the vapors. Available Literature: 20-page booklet "Monsanto Chlorine" paro-CHLORO-meta-CRESOL, white transparent cryatala; used a disinfectant intensifier; made by Monsanto Chemicals Limited. ortAo-CHLORO-poro-TOLUENE-SODIUM SULFONATE (See Monsanto Salt). para-CHLORO-meta-XYLENOL, white crystala; used as a disinfect(Continued) Page 46 MONSANTO CHI MICA LS 0683736 TOWOLDMON0041872 WATER_PCB-00026341 ant intensifier and as a preservative and preventive against mold and mildew; made by Monsanto Chemicals Limited. ortho-CHLOROAMLINE__________________________________ (Also known as ort/io-aminochlonbenzene and l-araino-2-rblorobenzene.) Nn, Mol. Wt. 127.58 Standard Formi Liquid Specifications; Discolors readily on exposure to air; crystallizing point --2.3'C. min. Distillation range: first drop, 208.0C. min.: 95% (1*96 ml), 1.0C. max.; dry point, 210.0'C, max; Solution in HC1, very slightly opalescent max. R.R. Classification! Dye Intermediate. General Information! Used aa an intermediate in the production of dyestuffs. CAUTION: This product is toxic Avoid breathing its vapors and avoid contact uith the skin. meta-CHLOROANILINE _________________________________ (Also known as fneta-ammocblorolpensene and 1 -arnino-3-chlorobenzene.) Mol. Wt. 127.58 Standard Formi Fused solid Specifications i Clear, light yellow liquid; crystallizing point approx. --10.0CC. Distillation range: first drop, 228.0. min.; 95% (1-96 ml), 1.0C. max.; dry point, 231. 0C. max. R.R. Classification! Dye Intermediate. General Information! Used as an intermediate in the manufacture of azo dyestuffs. CAUTION: This product U toxic. Avoid breathing Us vapors. Avoid contact with ths skin. para-CHLOROANILINE _____________________________ _ .... [Also known as Para-ajDinochlorobenzene and l*amino4<blorolenzene.) NUt Mol. Wt. 127.58 Cl 2TB COITION Standard Formt Fused solid. (Continued) Page 49 0683769 TOWOLDMON0041873 WATER_PCB-00026342 Specifications: Yellowish. white solid; crystallizing point 69.5'C. ruin. Distilla tion range: first drop, 229.05O. min.: 95% (1*96 ml), 1.5"C. max.; dry point, 233.0C. max. Solution in HCI. slight opalescence max. It.R. Classification: Dye Intermediate. General Information: l sed as an intermediate in the production of dyestuffs. CAUTION: This product is toxic. Avoid breathing its vapors and avoid contact u ith the skin. CHLOROBENZENE Cl Mol, \Fi. 112.56 Standard Forms Liquid. Specification*! Clear, almost colorless liquid. Distillation range: first drop, 131.5C. min.; 95% (1*96 ml), 0.5C. max.: dry point. 133.SC. max. R.R. Classification! Monochlorobenzene. General Information! Major use is s an intermediate in tbe preparation of the various substituted chlorobenzenes which are in turn intermediates for the preparation of dyestuffs, explosives, and various other organic chemicals. Also used as an organic solvent. ortho-CHLOROPHENOL, TECHNICAL (Also known as ortho -bydroxycblorobenzene and l-chloro-2-hydroxybenzene. OH Mol. Wt. 128.56 Standard Formi Liquid. Specifications: Clear yellow to brown liquid: monochloropbenol (from Cl con. tent), 95.0% min. Distillation range: first drop. 173.0C. min.: 95% (1*96 ml.), 2.0eC. max.; dry point, 178.0C. max. R.R. Classification! Dye Intermediate General Information! Used as an intermediate in tbe production of dyeatuffs and various other organic products. CAUTION: This product it toxic. Avoid breathing its vaport. Avoid contact with tht thin. pora-CHLOROPHENOL_ (Also known at para-bydroxychlorobeotene and 1 -chioro-4-hydroxybetizene.) {Continued) Page 50 MONSANTO CBBMICAL 0683790 TOWOLDMON0041874 WATEFLPCB-00026343 OH Mol. Wt. 128.56 Standard Forms Fused solid. Specifications) Yellow to brown crystalline mass; crystallizing point 42.5'C. min.; sp.g. at 4S.0/15.5C., 1.256>1.262. Il.ll. Classification] Dye Intermediate. f.eneral Information! Used as an intermediate in the production of dyestuffs, us a germicide and in the synthesis of pharmaceuticals. C.4 UTION: Car should / exercised in handling this product. Avoid contact with the skin. CHLOROSULFONIC ACID (Also known as sulfuric chlorohydrin.) CISOjOH Mol. Wt. 116.53 Standard Formt Liquid. Specifications) Heavy mobile liquid; assay 98.5% min. R.R. Classification) Acid. General Information! Used in chlorosulfonation reactions. CAUTION: Chlorosuifonic acid reacts violently uith water, forming hydrochloric and tulfuric acidi. CHROME SULFATE (See Saototan). CITRATED CAFFEINE* C.S.P. (See Caffeine, Citrated). CONTACT MASS (See Vanadium Catalyst). COPPERAS NITRATE OF IRON (See Nitrate of Iron C). COTTON SOLUTIONS General Informations Made from RS (regular soluble) cotton of any desired viscosity. Viscosity, aolid content, and solvent composition can be regulated to meet customer requirements. Used in manufacture of lacquers, leather dopes, fabric coatings, artificial leather finishes, etc. Composition of standard base solutions follow: {Continued) 26TB edition Page 51 0683191 TOWOLDMON0041875 WATER_PCB-00026344 Formula Number R.1202 R4683 R.28I6 R-1205 R-1204 L-4692 Standard Nitrocellulose Solutions Viscosity Wt. VC Percenl of to l gal. Nitrocel. Nitrocellulose Solvents dry Active Solvent* Seconds 64 o*. 33.9 Butyl Acetate Vi " 64 " 6 " 45 " 36.5 Ethyl Acetate 28.1 Butyl Acetate 15-20 '' 28 " 19.5 Butyl Acetate 15-20 " 28 " 19.5 Ethyl Acetate 250-400 " 16 " 13.0 Ethyl Acetate Weight one gallon 8.71 lbs 8.34 " 8.53 " 7.99 " 8.1 " 7.24 " * Usual added diluents: Toluol, xylol, ipbtbas (varying aromaticity), alcohols (ethyl, butyl, amyl). R.K. Classification i Lacquers. "COUMARIN MONSANTO" 'Coumarin N. F.) --o--c=o Mol. Wt. 146.14 Standard Forms: Crystals, fines crystals, large--4 mesh. Specifications! Fine or large white crystals: melt (liquid), clear and colorless; m.p. 68-8C. min.; solubility in ethyl alcohol (1:10), complete; loss on dryiag 0.03% max.; ash 0.05% max.; conforms to X.F. test for acelanilid; 5.0% max. retained on 4 mesh screen; 95.0% min. retained on 8 mesh screen. R.R. Classification i Coumarin. General Information! Coumarin is a flavor and odor principle used separately and in conjunction with vanillin. It is used in perfumes, soaps, tobacco, inks, foods and other product# where flavoring or aromatic ingredients are required. Available Literature! Folder, "Coumsxin Monsanto''. CREAMERY ACID (See Sulfuric Acid). mettl-CRESOL, colorless liquid, assay 98*100%, crystallizes at 10.5 12*C.; used in the manufacture of synthetic perfumes and nitroderivatives; made by Monsanto Chemicals Limited. ortho-CRESOL* white crystalline mass, crystallizes 30 31C.; used iu the manufacture of rlmmlrsls and as a dye intermediate: made by Monsanto Chem icals Limited. Page 52 MONSANTO CHEMICALS 0663792 TOWOLDMON0041876 WATER_PCB-00026345 para-CRESOL, loose white crystals, crystallizes 34.5C,; dye intermediate: made by Monsanto Chemicals Limited. CRESOL-CRESYLIC ACID, duty-free gTades; used as a dotation agent and gasoline antioxidant and in the manufacture of soaps, disinfectants, paint removers, textile chemicals, resins and dyestuffs; made by Monsanto Chemicals Limited. CRESYLIC ACID (See Cretol), "CRYSALBA** CaSO Mol. Wt. 136.14 Properties! Extremely fine, white powder composed of minute particles of crystalline-shaped anhydrous calcium sulfate, standardized and specially pre pared for use as s dentifrice base (paste or powder). R.R. Gassificatiom Calcium Sulfaie. Principal Useei Used as a tooth paste base or polishing agent. Suitable for preparation of oeutral, acid, basic, soap, or magnesia type dentifrice. "CURODEX" A complete line of reodorants for the rubber trade; not manufactured by us but furnished for the convenience of our customers. "CYCUINE" OIL Specifications! Blend of mineral and vegetable oils. Clear, yellow oil with pale blue-green fluorescence; sp. g. 0.89; Bash point, 185C.; viscosity, between 105 and 115 Saybolt viscosimeter at 37.5C.; soluble in benzene, gasoline, dry al cohols, ethers and acetone. R.R. Gasalficatiom Petroleum Oil, NOIBN. General Information* Used as a rubber softener. Available Literature! 42-page booklet "Monoeanto Chemicals for the Rubber Industry." 26TB EDITIOH Page 53 0683793 TOWOLDMON0041877 WATER_PCB-00026346 CYCLOHEX YLAMI.NE____ (Also known as hexahydroaniline.) NH, |1 CH litC <JH| |1 1 1 II,C CH, \/ CH. Mol, Wt. 99.17 Standard Form: Liquid. Specifications! Clear, practically colorless; sp. g. at 15.5/15.5C., 0.870-0.87-1. Distillation range: first drop, 132.0'G. min.; 95% (1-96 ml.), 4.0C. max.; dry point, 137.5C. max. R.R. Classifications Chemicals NOIBN. General Information t Used as a dyestuff intermediate; as an intermediate or ingredient for insecticidal compositions: as a component of corrosion inhibitors: in organic synthesis. CA UTION: Thts product it toxic. Avoid breathing iu vapor* and avoid contact with the skin. DETERGENTS (See Areeltap, Aresket, Aresklene, Santomerse). DIACETONE, TECHNICAL . Typical Aoalyaisi Nearly water white liquid; acidity, neutral; odor, no residual; sp. g. 0.918 at 15.5eC.; shipping wt. per gal., 7.60 lbs.; diacetone content, 85%; tailing range, theoretical b.p. 164C. (decomposes at 130* 140*C.); dryness, mixes with 5 vols. of petroleum naptha without turbidity. K.R. Gratification! Diacetone. General Informations Diacetone is one of the most active high boiling solvents for nitrocellulose. It is a good solvent for cellulose acetate and many resins, waxes and dyes. Diacetone ia miscible and has a high tolerance for nearly all lacquer diluent*. Higher percentage* of water are tolerated than with most solvents. D1AMMONIUM PHOSPHATE (See Ammonium Phosphate, Di). "D.P. SOLUTION 4519" Standard Forms 40% sol. in ethyl alcohol. (Continued) Page 54 NSANTO CBtMICALS 060379* TOWOLDMON0041878 WATER_PCB-00026347 Properties! Pale straw colored liquid; 8.2 lbs. per gal. R.K. Classification: Chemicals NOIBN. General Information] l sed as aa anti-corrosion agent in lacquers and cotton solutions, and as an agent to prevent the settling of Santocel in Sat lacquer formulations. IMBL'TYL PHTH.ALATE . 0 II -C -0-C4H, -C -- O -- C,H, II o Mol. Wt. 278.17 Specifications; Clear, oily, liquid, color (APHA) 10 max.; odor, slight; acidiIv (as phtbalic acid) 0.01% max.; ep. g. at 20/20'C,, 1.0480.001; refrac. index at 25"C., 1.490$ sh 0.001; assay (ester content) 99% min.; sulfur (copper strip test), negative. K.K. Classification: Dibutyl Phthaiate. General Information: Dibutyl Phthaiate is one of the most widely used plasticizers for nitrocellulose. It is miscible with all the common organic solvents and with oils but is soluble in water only to the extent of 0.001% at 30C. It has excellent light stability which permits its use in colorless, white or deiicaielv tinted produets. The stability of Dibutyl Phthaiate and its high solvent power for most plastic materials make ii one of the most acceptable plasticizers for general use. Available Literaturei 40 Page booklet "Plasticizers and Resina". DICALCIUM PHOSPHATE (See Calcium Phosphate, Di). DICHLORAMINE-T, N.F. - o /-------V. II H,C ^ S-NCIs Mol. Wt. 240.11 Standard Form: Crystalline powder. Specifications: Yellowish white crystalline powder; crystallizing point 80.5C. min.; assay (available chlorine) 29.35%. R.R. Classification: Chemicals NOIBN. (Continued) J6TH KDtTION Page 55 0663795 TOWOLDMON0041879 WATER_PCB-00026348 General Informations Dirhlnramine-T is a *ater soluble, active chlorine bearing product. It roust be stored away from light and in a cool place. . 2,5-DICHLOROANILINE__________ (Also known as l-aniinri*'2,5-tiichloiobenzene) Mol. Wt. 162.03 Standard Formi Fused cryetellint mass. Characteristic# t Light brown crystalline mass; crystallizing point, 48.6C. min. Distillation raoge; start, 24TC. min.: 95%, within l.SC. R.R. Classificationi Dye Intermediate. General Informations Used as an intermediate in the preparation of ago dye stuffs. CA L TION: This product is toxic- Avoid breathing its vapors. Avoid contact icith the skin. "Poison'' label requited. DICHLOROBENZENE (See Santochlor and ortbo.Dichlorobeosene) paro-DICHLOROBENZENE (See Santocblor). orfho-DICHLOROBENZENE, TECHNICAL. (Also known as 1, 2'dichlorobenzene) Cl Mol. Wt. 147.00 Standard Forms Liquid. Characteriaticas Colorless to slightly yellow liquid; crystallizing point, 7.0*0. max.; 100% (1st drop, dry point), 14.0*C. max. Sp.g. 15.5/1S.S, 1.30S . 1.313: composition, 75 85% ortho-dicblorobenzene, 15 * 25% para-dichlorobenzene. R.R. Classifications Ortho-dicblorobenzene. General Informations Used aa a dyestuff intermediate; solvent; ingredient in cleaning preparations; and as an insecticide and fungicide. Page 56 MONSANTO CHEMICALS 0683796 TOWOLDMON0041880 WATER_PCB-00026349 2, 4-DICHLOROPHENOL _____________ (Also known ai l,3-dicbloro-4-bydjoxybenxene.) OH Mol. Wt. 163.00 Cl Standard Formt Fused solid. Specifications! Yellow to brown crystalline mass: crystallizing point 42.0C. min. Distillation range: first drop, 211.5C. min.: 95% (1-96 ml.), 2.0C. on. R.R. Classificationl Dye Interim diate. General Information* Used as an intermediate in the production of dyestuffs and as a germicide. CA UT/O.V: Ce-re should be exercised in handling this material. Avoid contact with the ikin. Avoid breathing its vapors. DICYCLOHEXYLAMIIVE _ H, lh \ N-H / Mol. Wt. 181.32 Standard Formi Liquid. Characteristicst Clear, practically colorless liquid; sp.g. 15.5/15.5C., 0.916 0.920. Distilling range: first drop, i!52.0C. min. Flash point ("Tag'* open cup), above 2008F. R.R. Classification) Chemicals NDIBN. General Informationi Used as an intermediate la the manufacture of oil additivea and insecticides. CA UTtON: This product is toxic. Avoid breathing its lapors. Avoid contact with the skin. DIETHYL PHTHALATE _ o -C-O-C.H, 0-C-O-C.H, II o Mol. Wt. 222.11 Specification*! Clear, water-wbitt oily liquid; color (APHA), not darker than 10; odor, very slightly aromatic; acidity (as pbthalic acid) 0.01% max.; ip. g. at 20720*0., 1.1230.005; refrac. bdex at 20C., 1.5030 0.001, sulfur (copperatrip test), negative. (Continued) 20TB IDITION Page 57 0683797 TOWOLDMON0041881 WATER_PCB-00026350 R.R. ClauiBcationt Diethyl Pbthelete. General Information* Diethyl Phthalste is a colorless liquid plaiticieer gen erally used in mixture with dimethyl pbtha ate aa a plaaticizer for celluloae acetate. It ia miscible with all the common organic solvent* and diluents. Evap oration rate of Diethyl Pbthalate is too high for successful use as a regular nitro cellulose plasticizer and it is not a solvent for cellulose acetate. Thus its range of usefulneaa ia somewhat restricted. Mixtures of Diethyl and Dimethyl Pbthaiatea usually give better results than can be obtained by either one alone. Boiling point ia 295C.; weight per gal.. 9.35 lbs. Available Literature! 40 Page booklet "Plasticizers and Resins'*. 2, 3-DI.METHOXY BENZALDEHYDE, TECHNICAL (Also known as ortho-veratraldehyde). A OCII, 0OCH, Mol. Wt. 166.0 Characteristics) Yellowish brown fused crystalline mass; solubility in sodium bisulfite, nearly complete; crystallizing point, 4?.5C. min.; sp.g. at 60C.f 1.117; wt. per gal., 9.3 lbs. approx. R.R. Clasalflcationt Chemical* NOIBN. General Informations Used aa a perfume fixative and a* an intermediate in chemical synthesis. DIMETHYL PHTHALATE . O -C -O-- CHi 0-C--O--CH, II Mol. Wt. 194.08 Specifications* Clear, water-white oily liquid; color (APHA), not darker than 10; odor, not more than slightly aromatic; acidity (as phtbalic acid) 0.01% max.; p. g. at 15.6/1S.6*C., 1.1960.001; refrac. index at 20C,, 1.51550.001; sulfur (copper strip test), negative. R.R, Classificationt Dimethyl Pbthalate. General Information i Dimethyl Pbthalate is a solvent plasticiser for cellulose acetate. It ie miscible with all common organic solvent* and with oils (except (Continued) Page 58 Monsanto chbmicals 0663798 TOWOLDMON0041882 WATER_PCB-00026351 petroleum oils) and has a solubility in water of 0.4% at 32C. It baa excellent light stability. Dimethyl Pbthalate is much used but cannot be said to meet very rigid plasticizer requirements. Its use is restricted almost entirely to the cellulose acetate field, and there, as a general rule, it is used In combination with diethyl phlhalate or sera* other plasticizer. Dimethyl Phthalate has a boiling point of 282C., a crystallizing point of 0JC., and weighs 10 lbs. p.r gallon. Available Literature* 40 Page booklet 'Plasticizers and Resina." 2, 4-DIMTROANILINE______________________ (Also known as i-aniino.2, 4-dinitrobenzeoe.) NR, Mol. Wt. 183.12 NO, Standard Form, Powder. Specifications! Bright yellow powder: m. p. 177.3*C. min.; chloride# (total) 0.15% mas. R.R. Classification, Dye Intermediate, General Information! Used as an intermediale in the preparation of dyestuffs. CAUTION: This product is toxic. Avoid breathing its dust. Avoid contact with the shin. 2, 4-DINITROCHLOROBKNZENE, TECHNICAL (Also known as l*chloro-2,4-dinitcobenzene.) Cl Mol. Wt. 202.56 X, NO, Standard Form * Fused crystalline solid. 7 Grade#! 3 grade# of fused crystalline solids with crystallizing points of 48.0C., 46.5C., and 44.QC. Approximate Analysis* 2:4 dinitio* chlorobenzene 48.0C. 95%Approx. 46.5*C. 90% A 44.0*0. 85% " isomeric dinitrochlorobenzene# 5% Approx. 10% " 15% " R.R. Clasaificatiom Dye Intermediate. (Continued) 26TH EDITION Page 59 0684^99 TOWOLDMON0041883 WATER_PCB-00026352 I General Information t Used in the production of explosives, photographic chemical*, and dinitrophenol, and as an intermediate in the preparation of dyestuffs. CAUTION: This product ir toxic. Avoid breathing ks vapors. Avoid contact with the skin. DIPHENYL_______________________ (Also known as biphenyl; phenyl benzene). o-o Mol. Wt. 154.2 Propertiesi Technical diphenyl is a light yellow crystalline solid. Boiling point 254.9eC. freezing point 68.5C. to 68.9* C. R.R. Classification* Diphenyl. General Information! Used as a high temperature, low pressure heat transfer medium. It is also the starting point for many derivatives such as Aroclors (chlorinated diphenyl) and the sulfonic acid, nitro, amino and hydroxy com pounds. DIPHENYL PHTHALATE 0-1 -o-O -o-O Mol. Wt. 318.31 Specifications* Essentially white fused solid; melt, clear and light yellow colors free acid (as phtbalic) 0.20% max., free phenol 0.2S% max. R.R. Classification* Lacquer Solvent, General Informations Diphenyl Phtbalate has a crystallizing point of about 69C. and is readily soluble In ketone*, esters and chlorinated hydrocarbons. Its solubility in alcohols, turpentine ai>d linseed oil is rather low, approx. S.O grams per 100 c.c. of solvent at 25C. Diphenyl Phtbalate ia compatible with nitrocellulose and with the sulfonamide, phenolic, polystyrene and vinyl types of synthetic resins. In nitrocellulose lacquers it produces hard coatings that have excellent gloss retention and weather resistance. Mixtures of Diphenyl Phtbalate with either Santolite MS or Santolite MHP are excellent plasticizer* for nitro* cellulose in odorless, flexible, adhesive coalings. Diphenyl Phtbalate is completely insoluble in water and gives increased water resistance to all compositions in which it is used. It is especially recommended for vinyl resins, polystyrene, ethyl cellulose, and some of the natural resins such as Damar. Available Literature! 40 Page booklet "Plasticizers and Resins'*. Page 60 MONSANTO CHIMICALS 0683800 TOWOLDMON0041884 WATER_PCB-00026353 DIPHENYLGUANIDINE (See DPG under Accelerator*, Rubber). DIPPING LACQUERS (Set Lacquer*). DISINFECTANT INTENSIFIERS (See Saotophen. Arnkap). DISODIUM PHOSPHATE (See Sodium Phosphate, Di). DISPERSING AGENTS (See Areekap, Aresket, Aresklene. Saotomene). DRY ICE (See Carbon Dioxidf Solid). **EL SIXTY'* (See Accelerators, Rubber). ELECTROLYTE (See Battery Acid). EMULSIFYING AGENTS (See Areekap, Aresket, Aresklene, Santomene). ENAMELS (See Lacquer* and Re*ins). "ETHASAN" (See Acceleratoie, Rubber). "ETHAVAN" (Ethyl Vanillin)----------------------------------------------------- OH c=o H Standard Forms Needle*. Specification* Fine white crysulline needles; completely soluble in ethyl alco hol 95% (1:2); ash 0.05% ma*.; n .p. 76.5C. min. R.R. ClaMiflcationi Chemical* NOIBN. {Continued) 26TB boition Page 61 0683601 TOWOLDMON0041885 WATER_PCB-00026354 1 Genera] Information! Etbavan is used as a flavoring and aromatic, and has a flavor similar to that of Vanillin but not identical with it. The relative flavoring strength of Ethavan approximates three times that of Vanillin. Available Literature! Leaflet, ''Ethavan." ETHYL ACETATE___________ _________________________ Typical Analysis: Water white liquid; sp. g,, 0.895 at 15.5C.; 7.40 lbs. per gal.; ester content, 85-90%. Boiling range: 7(>C. 809C. Dryness, mixes with not less than 10 vols. of petroleum benzine without turbidity. Less than 0.02% as free acetic acid. K.it. ClassiScationi Ethyl Acetate. General Information! Used as a nitrocellulose solvent. It is a more active solvent than either butyl or amyl acetate, evaporating the fastest, and having the least resistance to moisture blush. Blends of all three with appropriate diluents eucb as alcohols (ethyl, butyl, and amyl) yield thinners and solvent mixtures of excellent cutting power and moisture resistance, good flow and leveling, and com patibility with various resins and oils. Used in the artificial leather industry and in formulating lacquers and finishes foi wood, metals, textiles, and paper. ETHYL ALCOHOL--190 Proof QHjOH (Also see Mersol, a proprietary solvent type alcohol, and Nealco Anti-Freeze.) Grades t 1. Tax Free: 190 proof pure Ethyl Alcohol (95% by volume). May be withdrawn Under Regulations and Provisions by the U. S. or any governmental agency thereof, or by tbe several states and territories, or any municipal subdivision thereof, or by the District of Columbia, or for the use of any scientific university or college of learning, any laboratory foi use exclusively in scientific research, or use in any hospital, or janitarium, or for the use of any clinic operated for charity and not for profit, including use in tbe compounding of bona fide medicines for treatment outside of such clinics of patients thereof, but not for sale. 2. Tax Paid: 190 proof pure Ethyl Alcohol (95% by volume), (a) May be pur chased by manufacturers and others for non-beverage use without Federal Permit or bond, but auch users must sign affidavit that the alcohol so purchased is for industrial use only, as defined by Federal Alcohol Administration Regula tion 2. (b) May be purchased by blenders and rectifier*, (c) Subject to Federal Government Tax. Individual state regulations apply on tbe purchase and use of pure Tex Paid Alcohol. 3. Specially Denatured Alcohol: May be withdrawn for use in a great number of specialised arts and industries. Tbe character of the denaturant or denaturants employed is auch that Specially Denatured Alcohol may be sold, posseseed and used only pursuant to permit and bond approved by Internal Revenue Depart ment, Alcohol Tax Diviaion. All application forme covering tbe withdrawal of (Continued) Page 62 MONSANTO Cl iMtCAxa 0663802 TOWOLDMON0041886 WATER_PCB-00026355 Molasses storage tanka of the New England Alcohol Company. Specially Denatured Alcohol may be obtained from the office of the District Supervisor, Internal Revenue Department, Alcohol Tax Division of the district in which the purchaser's plant is located. 4. Completely Denatured Alcohol: 188 proof. May be withdrawn without permit or tax, hut buyer must comply with certain Federal and State regulations govern* ing records and storage. K.R. Classifications Alcohol NOII*N or Denatured Alcohol. General Information! Nealco ethyl alcohol is manufactured by the fermenta tion of molasses. It is offered in its pure state and in all formulas of Specially Denatured and Completely Denatured Alcohol as authorized by Federal Law under the provisions of Title III of the National Prohibition Act. It is of high uniform quality complying with the exacting specifications of the National Formulary VI and U.S.P. XI. Available Literature! 68-page booklet "Nealco Industrial Alcohol." ETHYL BENZENE SULFONAMIDE (See Santidser 128). ETHYL PHOSPHATE (See Triethyl Phosphate). 2f>TH KniTIOIN Page 63 0683803 TOWOLDMON0041887 WATER_PCB-00026356 ETHYL PHOSPHORIC ACID (Sec Alkyl Phosphoric Acids). ETHYL PHTHALYL ETHYL GLYCOLLATE (Sec Santicizer E-15). ETHYL TRIETHANOLAMINE PHOSPHATE___________ ... Properties! Medium siraw colored liquid of slightly alcoholic odor: sp. g. 1.19 a! 25 C.; wt. per gal. 9.9 lbs.; liquid at all ranges of relative humidity but very i-soous when anhydrous; pH 7.0 7.4: strength, 60% solution in water. R.R. Classification*i Chemicals NOIBN. (.eneral Information) Used as a plasticiztr for water soluble materials and as a humectant. ETHYL VANILLIN (See Ethavan). FERRIC CHLORIDE SOLUTION (Iron Perchloride)______ FeClj Standard Formt Liquid. Grades! 37Be.; 40B6.; 42t>Bd. Typical Analysis! Ferric Chloride 42B<.: total FejOj, 20.3%; FeO, 1.0%; combined FejOj, 19.2%; FeClj, 39.0%. R.R. Classification: Iron Chloride Liquid. General Information t Used as an acid oxidizing agent in etching, photoengrav ing, and in the manufacture of textile printing rolls and brass signs. It is used in water and sewage treatment for its iron content. FERRIC GLYCEROPHOSPHATE (See Glycerophosphates). FERRIC NITRATE, LIQUID (Trut Nitrate of Iron) Fe(NOj)j Gradest 47Bf., 16.0% Fe*0 R.R. Classification! Iron Nitrate. General Information! A source of ferric hydroxide for mineral tan and buff colors on cotton; brown papers; logwood blacks on silk; shoe stains and inks. FERRIC PHOSPHATE--_____________________ Sodium Ferric Pyrophosphate NasFe|(Pj0r)j.XHj0 (Continued) Page 64 MON SANTO CHEMICALS 06B380A TOWOLDMON0041888 WATER_PCB-00026357 Ferric Orthophosphate Ferric Pyrophosphate Ferric Acid Pyrophosphate General Information! Used in food and pharmaceutical fortification as a mineral supplement. FERRIC SULFATE (See Fetrisul). FERRIC SULFATE, LIQUID (Copperas Nitrate of Iron) ____ Fej(SO)* Gradest 40B., 13.6% FejOj 47eB4., 15.7% Fe*Oj Containers) Carboys; barrels. General Informations A strong solution of ferric sulfste, containing no nitric acid. Used as a source of ferric hydroxide for mineral tan and buff color* on cotton, brown papers, logwood blacks on silk, shoe stains and inks. "FERRISULM(Anhydrou Ferric Sulfate) Fej(SO*)| Standard Forms Pellets 4-40 mesh. Typical AnalyaUs 90% min. FetfSO*)*. R.R. Clas*ification: Dry Ferric Sulfate. General Informations An effective coagulant for the treatment of water upplies, sewage, and industrial wate. In solution, it is a mild oxidising agent and can be used for pickling certain alloy* auch aa the stainleas steels, braaa and other copper alloys. It ia also used in various organic reactions. Available Literatures Booklets, "Ferrisul lor Treatment of Water, Sewage and Industrial Wastes'* and "FerruuJ for Metal Treating," FERROPHOSPHORUS (Iron Phosphide) Standard Format Chill cast lumps, egg sixe; powder. Contains 23 26% phos phorus. R.R. Classifications Ferropboophorus. General Informations An alloy of iron and phosphorus. Used in iron end steel castings to increase fluidity; in sheet steel to prevent nicking of sheet* in final rolling; in wire to give stiffness and better surface for drawing. Available Literatures Phospborus-lrou Alloys Bulletin No. 1. A report of (Continued) 26TB aoiTioN Page 65 0683805 TOWOLDMON0041889 WATER_PCB-00026358 L'eneral exploratory research upon the influence of phosphorus in low carbon, low alloy steels, 36 pages. Bulletin No. 2. A report of experimental research investigation upon corrosion jnd mechanical influences of alloying elements in low alloy steels. 62 pages plus harts. Bulletin No. 3. Abstracts of t'.S. patent* relating to phosphorus as an alloying lenient in steel and list of iron and steel patents. 54 pages. Hiillelin No. 4. Re|>orts of experimental research investigation upon influence <>f phosphorus in steels in elevated temperature service and in Cr.Mo steels, 2d pages. "FIBESTOS" (See Plastics). FLECTOL" H and WHITE (See under Antioxidants). F LOTATION AGENTS (See Xanthates). FUNGICIDES (See Santobrite and Santophen 20). GERMICIDES (See Antiseptics nd Germicides). GLAUBER'S SALT (Sodium Sulfate) ________________________ NajSO*4` 10 HiO Standard Formal Crystals and Glauboida. Typical Analyst at 43% NajSO* available. R.R. Classification! Glauber's Salt. General Information! Used principally aa a leveler in dyeing wool and silk; for the precipitation of barium sulfate or blanc fixe; neutralizing of sulfonated oils; treating softened boiler feed Mater to prevent caustic embrittlement; salting skins. GLYCEROPHOSPHATES Specifications! See individual glycerophosphates below. General Information! The Glycerophosphate* are a group ofproducts contain* (Continued) Page66 Monsanto chbmicals 0663806 TOWOLDMON0041890 WATER_PCB-00026359 ing the glycerophosphate radical and may be used advantageously to carry such important elements as calcium, iron, magnesium, manganese, potassium, and sodium in the formulation of pharmaceutical preparations. In the case of the less soluble salts, such as calcium, iron, magnesium, and manganese, the solubility of these products may be materially increased if they are formulated with Glycerophosphoric Acid or certain accepted food acids, such as lactic, citric and tartaric. GLYCEROPHOSPHATE, CALCIUM, N.F. CaCiHj(OH)jPO, Mol. Wt. 210.15 Standard Formi Powder. 80 t-iesh. Specifications! Fine white powder; assay (dry basis) 98.0% min.; sp. g. 0.42 0.50; loss on drying at 130C., 12.0% mu.; solubility in water (1:50),complete; chloride (as CaCl.) 0.1% mas.; sulfate (as CaSO,)O.SO% max.; iree phosphate (as PjOs) 0.02% max.: conforms to N.F. test for heavy metals; 3.0% max. re tained on 80 mesh screen: 5.0%. max. on 100 mesh screen. R.R. Classifications Chemical* NOIBN. GLYCEROPHOSPHATE, FERRIC, N.F. Fei|CjH4(OH)sPO,]j Mol. Wt. 621.90 Standard Formt Powder. Specifications! Buff or yellowish green powder: assay (dry basis), 17.0% Fe min.; moisture, 10.0% max.; chloride (as FeCIi), 0.10% max.; sulfate (as Fe:(SO)), 0.10% max.; free phosphate (as PiOj), 0.20% max.; 2.0% max. re tained on 60 mesh screen, 10.0% max. on 150 mesh screen, 30.0% max. on 250 mesh screen. R.R. Classification! Chemical! NOIBN. GLYCEROPHOSPHATE, MAGNESIUM MgCHi(OH)iPO, Mol. Wt. 194.39 Standard Forms Powder, 80-mesh. Specifications! White powder; assay, 97.0% min.; moisture, 12,5% max.; calcium (as CaO), negative; chlotide (sa MgClj), 0.10% max.; sulfate (as MgSO), 0.10% max.; free phosphate (as PiOi), 0.20% max.; conforms to N.F. test for heavy metals; 2.0% max, retau-ed on 60 mesh screen, 4.0% max. on 80 mesh screen, 10.0% max. on 100 mesh screen. R.R. Classification! Chemicals NOIBN. 26TB coition Page 67 068380? TOWOLDMON0041891 WATER_PCB-00026360 GLYCEROPHOSPHATE, MANGANESE, N.F. MoCjHjCOHJjPO, Mol. Wt. 225.00 Standard Formt Powder, 80-meh. Specifications! Pinkish white powder: assay (dry basis), 98.0% min.; solubility in 25% citric acid solution (1:5), complete: moisture, 10.0% max.; chloride (as MnCL), 0.15% mas.: sulfate (as MnSO,), 0.03% max.; free phosphate (as P.0,), 0.20% max.; conforms to N.F. test for heavy metals; 2.0% max. retained on 60 mesh screen, 4.0% max on 80 mesh screen, 10.0% max. on 150 tnesb screen. K.R. Classification! Chemicals NOIBN. GLYCEROPHOSPHATE, POTASSIUM (Solution) K1C,H(OH),PO< Standard Formt Solution 75%. Specifications! Clear, colorless or slightly yellowish solution; assay, 61.6 63.2% anhydrous salt; carbonate (as FjCOi), 0.50 % max.; chloride (as KCI), 0.10% max.; sulfate (as K:SO), 0.10% max.; free phosphate (as P3O4), 0.20% max.; conforms to N.F. teat for heavy metals. R.R. Classification! Chemicals NOIBN. GLYCEROPHOSPHATE, SODIUM, N.F. Na,C1H,(OH),PO,. 5HHtO Mol. Wt. 315.15 Standard Formsi Crystals, 10-80 mefcb; powder. Specifications! White crystals; assay, 68.0 72.0% anhydrous salt (equivalent to 96.35 104.9% hydrated salt); solubility in water (1:10), complete; chloride (ss NaCI), 0.05% max.; free phosphate (at PiOi)0.02% max.; conforms to N.F. test for heavy metals and sulfate (aa NsjSOi); no crystal* retained on 10 mesh screen, 40.0% min. crystal* on 80 mesh screen. R.R. Classification! Chemicals NOIBN. GLYCEROPHOSPHATE, SODIUM (Solution) NatCHt(OH)tP04 Standard Forms Solution 75%. Specification! 1 Clear, colorless or slightly yellow eolation; assay 50.0 52.0% (Continued) Page 68 Monsanto chemicals 0683806 TOWOLDMON0041892 WATER_PCB-00026361 anhydrous salt; carbonate (a* NaCOj) 0.5% max.; chloride (as NaCI) 0.10% max.; sulfate (as NaSO.) 0.10% max.; free phosphate (as PjO) 0.15% max.; conforms to N.F. test for heavy metals. R.R. Classification] Chemicals NOIBN. GLYCEROPHOSPHORIC ACID (Solution) I!CiHi(OH)>PO< Mol. Wt. 172 Standard Formt Solution 35%. Specifications] Clear, colorleea liquid, APHA 20 max.; asaay 35.0 36.0%; chloride (as CaCI]), 0.10% max.; sulfate (as CaSO<), 0.20% max.; calcium (aa CaO), 0.25% max.; free phosphate (aa PjOj), 0.35% max.; conforms to N.F. test for heavy metals. R.R. Classification] Chemicals NOIBN. ``GUANTAL" (See Accelerators, Rubber). H ACID (Monoscxiiuni-l-Aniino-8-Naphthol-3,6-Disulfonate) OH NHt NsSOi' SO.H Mol. Wt. 341.29 Typical Analysis! White powdet; 86-38% monosodium sslt; trace of NaCI sad NajSOi; solubility in water, complete. R.R. Classification t Dye Intermediate NOIBN. General Information! Used as aa intermediate in the manufacture of dyestuffs. "HIBITITEn_________________________________________________ Standard Format Hibitite; Hibitite A, a commercial blend having half the strength of regular Hibitite. Properties! Derivative of an organic base; reddish brown powder; aolnble in concentrated sulfuric and muriatic acids. R.R. Classificationt Iron or Steel Cleaning NOIBN. (Continued) 26TB BDtTION Page 69 0683609 TOWOLDMON0041893 WATER_PCB-00026362 General Information] Hibitite is widely employed in acids used for pickling and cleaning ferrous metals. It protects the metal by inhibiting the attack of tbe acid and by reducing the possibility of embrittlement caused by hvdrogen pene tration. Hibitite A is similar in action to Hibitite with the exception that it is more readily dispersed (ban Hibitite in making up the acid solutions. Sulfuric acid containing Hibitite is used for pickling tin plate, wire, alloy steels, sheets for galvanizing; for cleaning steel drums and sand filters: for pre. paring articles for vitreous enameling; for removing metal coatings. Muriatic acid containing Hibitite is used for cleaning boilers, economizers, heat exchangers, pipe lines, condensers, tanka, tubes, coils, screens, pans, drums and similar equipment. For steel pickling acid containing Hibitite, see Inhibited Acid. Available Literature: 4-page mimeographed leaflet, "Hibitite and Its L'ses," HYDROCHLORIC ACID, C. P. _ HCI Mol. Wt. 36.46 Specificationst Colorless liquid free from suspended matter; strength 37.0 to 38.5%; non-volatile matter 0.0005% max.; sulphate 0.0002% max.; free chlorine 0.0002% max.; sulphite 0.003% max.; arsenic 0.00001% max.; iron 0.0001% max.; heavy metals (as lead) O.OOOS% max. K.R. Classification! Muriatic Acid General Informationi Laboratory reagent. HYDROCHLORIC ACID (See Muriatic Acid). 2-HYDROXY-3-METHOXY BENZALDEHYDE, TECHNICAL (Also known as crtAo-vanillin.) Mol. Wt. 152.1 Characteristic#t Yellowish crystalline solid; crystallising point, 40.0C. min.; density, 1.20 at 60C.; wt. per gai., 10.0 lbs. R.R. Classification! Chemicals NOIBN. General Information t Used as so antioxidant and as an intermediate In chem ical synthesis. Psge70 MONSANTO CHEMICALS 0683810 TOWOLDMON0041894 WATER_PCB-00026363 INHIBITED ACIDS Grades: These acid* are solutioi* of Hibitite in Monsanto'* commercial grades of 604B6. sulfuric acid. 66B#. sulfuric acid. 18B4. muriatic acid and 20*B. muriatic acid. General Information.' Addition of Hibitite to sulfuric and muriatic acid* results in a decreased rate of attack of the acid on metal hilt does not retard the action of the acid on surface scab on (he metal. Inhibited sulfuric acid is used for pickling tin plate stock, pickling sheets for galvanizing, preparing articles fov vitreous enamel, pickling Hire, pickling high curbon steel, removing metal coatings, cleaning steel drums and cleaning sand tillers. Inhibited oiuriatic acid is uied for pickling alloy wire and cleaning boiler tubes, condensers, pipes, heater oils and drums. INHIBITORS (See Hibitite). INKS, LACQUER BASE General Information! Lacquer inks are rapid drying, waterproof, greaseproof, adherent, flexible, and resistant to abrasion. Colon are light, fast and opaque, glossy or dull. Adapted for printing or coating cellophane, glassine, foil and other wrapper stock. Application is by intaglio photo engraved roll printing only, print roll being cleared by doctor blade. R.R. Classificationi Lacquers. INSECTICIDES ortho-Dichlorobenzene (See under D). "Santochlor" (See under S). IRON CHLORIDE (See Fenic Chloride). IRON GLYCEROPHOSPHATE (See Glycerophosphate, Ferric). IRON NITRATE (See Feme Nitrate). IRON PHOSPHATE (See Fwric Phoepbate). IRON PHOSPHIDE (See FetTopboapborua). IRON GLYCEROPHOSPHATE N.F. (See Glycerophosphates). IRON SULFATE (See Ferric Sulfate and Ferrisul). 26TB EDITION Pate 71 06B3GU TOWOLDMON0041895 WATER_PCB-00026364 I-ACQUERS--------------------------------------------------------------------- For information on special lacquers and related products offered by Monsanto see the following listings elsewhere in this catalog: Acetone: Aircraft Finishes: Amyl Acetate: Belt Cement: Bronzing Liquids: Butyl Acetate: Butyl Alcohol: Cable Lacquers: Cements: Cotton Solutions: Diacetone; Ethyl Acetate: Inks. Lacquer Base: Leather Dopes: Manicure Lacquers: Mersol (Solvent Alcohol): Mertec; Textile Larquere; Textile Printing Lacquers: Thinoers. General Information i The Lacquer and Solvent Department of Monsanto has been engaged for twenty years in th< development and manufacture of a wide variety of nitrocellulose base coalings for industrial use. At the present time Monsanto finishes for textiles, leather, paper, rubber, wood and metal are being used in practically all classes of industry. Specific information available on re quest. K.R. Classifications Lacquers. LACQUER COTTON (See Cotton Solutions). LACQUER EMULSIFYING AGENTS (See Areeidene and Santomerse). LAMPBLACK Grades: Ten grades are available which vary in free carbon, density, and oil absorption, Specifications! Grad* Ordinary Black Lampblack Bear Germantown Commercial Black Lampblack No. 10 Lampblack B5 Lampblack B*16 Lampblack BTA Lampblack S-I00 Lampblack No. 8 Lampblack AA Free Carbon 8{..0% 9?.20% 8f*.05% 90.11% 9?.20% 98.38% 98.23% 91.70% 91.03% 9<-.34% R.R. Classification) Lampblack NOIBN. Apparent Density Lb. per Cu. Ft. 25A 7.76 25.4 12.11 7.76 6.75 6.30 5.72 5.15 4.77 Beniol Extract % -- 1.65 -- .20 1.65 .7 .6 .6 .65 .85 General Information! Used as pigment in paints, varnishes, enamels, inks, leather finishes, stencils, crayons, polishes; in pressed forms as electrical conduc tors and electrodes. Available Literature! Booklet, "Monsanto Lampblack." LATEX PENETRANTS (See Aresklene and Santomerse). LATEX STABILIZERS (5ee Aresklene and Santomerse). Page 72 MONSANTO CBBMICALS 0663812 TOWOLDMON0041896 WATER_PCB-00026365 LEATHER DOPES_________________________________________ General Information! Nitrocellulose solutions specially formulated for the incorporation of plasticizer and pigment for use in finishing split, patent, and artificial leathers. R.K. Classification! Lacquers. LITHIUM SALICYLATE N.F. (See Salicylate*). "LUSTRON" (See Plastics). MAGNESIUM AMMONIUM PHOSPHATE____ _ (Also known as magnesium ammonium ortho phosphate.) MgNHP0.6H,0. Mol. Wt. 245.44 Standard Formi White powder. Properties! Insoluble in water and soluble in acids. Decomposes on heating. Grade: Technical. R.R. Classification! Chemicals NOIBN. Principal l'see: As an ingredient In fire retarding paints for theatre scenery and curtains. General Information! A hexahydrale and a monohydrate form exist. At ordinary temperatures disassocia;ion of the hexabydrate to the monohydrate takes place without appreciable loss of ammonia. Above 60aC. the monobydrate loses NH3 forming MgHPO4.Hj0. MAGNESIUM GLYCEROPHOSPHATE (See Glycerophosphates). MAGNESIUM PHOSPHATE, MONO ------- ------------ ;------------------ (Also known as magnesium phosphate, monobasic; acid magnesium phosphate; magnesium tetrahydrogen phosphate; magnesium biphosphate.) MgH(PO|)i Mol. Wt. 218.31 Standard Form! White crystals. Grade: Technical. 26TB EDITION (Continued) P*ge 73 0683813 J TOWOLDMON0041897 WATER_PCB-00026366 Rotary kiln at Camden, New Jersey, plant. R.R. Classification! Chemical* NOIBN. Principal Usest Used in pharmaceutical preparations. MAGNESIUM PHOSPHATE, TRI______________ (Also known as neutral magnesium phosphate.) Mgj<POi>t Mol. Wt. 262fid Standard Form t White crystalline powder. Grade i Technical. R.R. Classification! Chemicals NOIBN, General Information! Used In pharmaceutical products as an antacid. Pge 74 MONSANTO CHEMICALS 068381A TOWOLDMON0041898 WATER_PCB-00026367 MAGNESIUM SALICYLATES (See Salicylates). MALEIC ANHYDRIDE Viol. Wt. 98.06 Standard Form: Fused solid. Specifications) White crystalline mass; crystallizing point 52.0C. min.; water solution (l grams in 10 ml.), cl. ar and colorless; glyceromaleate re.in, clear with slight amber color; iron 0.0005% nj. K.R. Classification Chemicals NOIBN. General Information! Used alone or id combination with other acids ia the manufacture of alkyd type resins. MANGANESE GLYCEROPHOSPHATE (See Glycerophosphates). MANICURE LACQUERS (See Lacquers). MANICURE LACQUERS and REMOVERS________________ General Informations Manicure lacquers are offered in two typestrans parent and creme. The dyes used in the transparent type are selected for stability to light, soapy water and ag^ng. The bottle appearance of the creme type lacquers is unusually good. There ia no objectionable separation due to settling, and the lacquer applies without streaking. The bottle color matches the applied lacquer very closely. Colors and shades are provided according to the suggestions and specifications of the customer, and the opportunity to assist in development of new shades is welcomed. For those who prefer to select from standard shades, the following are offered in Manicure Lacquer R-4Q40 Creme and Transparent: Reddish Creme Shades Natural Robio Red Rose Tulip Sunrose Burgundy Old Rose Carnet Broxmish Creme Shades Thistle Suntan Rust Chestnut Bluish Creme Shadet Windsor Grape Heather {Continued) Transparent Natural Rose Garnet 26TB BDtTION Page 75 0683815 TOWOLDMON0041899 WATER_PCB-00026368 Manicure Lacquer Remover R*2522 is an active solvent and has an agreeable odor. Containers! Cane, 5 gal.; drome, 55 gal. Available Literature! Color chip folder, ''Monsanto Manicure Lacquers." "MERCLOR" (Sodium Hypochlorite) NaOCl Standard Formi Liquid. Typical Analysis! 22B6.; 12% available chlorine by volume K.R. Classificationt Sodium Hypotblcrite Solution. General Informations Merclor is veed as an oxidizing agent for bleaching cf vegetable fibers and as a chlorinating agent for water, organio compounds and wool. (See table in general data section^ "MERSOL"________________ _________________________________ Typical Analysis! Water white liquid: sp. g. 0.80 0.82 at 15.6*C.; odor, mild, non-residual; distillation range, 74" 80 C.; acidity, less than 0.005% as acetic acid. Compositions Alcohol, Special Denatured No. 1 Methyl isobutyl ketone Ethyl acetate, denatured withmethyl isobutyl ketone Gasoline 100 gals. 1 gaL 1 gat. I gal. R.R. Classification! Denatured Alcohol Solvent Containing Not Less Than 90% Denatured Alcohol. General Informations Mersol, a proprietary solvent alcohol, is formulated to have the advantages of Special Denatured Alcohol No. 1 without the necessity and burden of purchasing and operating under a government permit. It bae the mild odor of alcohol and no residual Mersol may be used for most industrial purposes where SDA No. 1 is indicated, as a solvent for shellac and soft manila gums, in lacquer thinners, cleaners, removers, polishes, dressings, inks, adhesives, celluloid, softeners, brighteners, and s a fuel and dye and stain solvent. Available Literatures 68 page booklet "Nedco Industrial Alcohol." "MERTANOL" Grade#! Mertanol SSt Mertaaol L; Merunol 7L; Mertaool D; Mertanol 7D. (Gtniinued) Page 76 Monsanto chemicals 0663816 TOWOLDMON0041900 WATER_PCB-00026369 Typical Analyses: \fertanol SS Merlanol L .Mertanoi 7L Tannin Acidity equivalent to Sp. Gr. Inorganic Salta 12% 19-20% 19-20% .64 .66 normal 1.22 1.26 normal neutral 2.66 * 2.74% HjSOa approx. 4.74% HjSO* pH 6- 8 U76-M78 1.205 - 1.212 1.214 - 1.225 8.2% Na,S04 11.4% (NH)|50 18.8% (NH^O, Xfertsuh/l D Mertanul 7D Tannin Acidity equivalent to Sp. Gr. Inorganic Salta 19 - 20% 1.22 1.26 normal approx. 4.74% Ht504 1.22 1.23 U.4% (MlifcSOa 19 - 20% neutral pH 6 - 8 1.23 - 1.24 18.8%(NH4),S04 Inorganic salt crystallizes out at temperatures below 40` F. K.K. Classification! Liquid Tanning Extract XOIBN. Central Information* Mertanol is a synthetic tanning agent consisting of a naptbslene sulfonic acid condensation product in liquid form. Tbe free aulfuric acid acidity baa been completely neutralised and the sulfonic acidity neutralized to a definite acidity. L'aed in tbe manufacture of leather for bleaching of chrome tanned leather, bleaching base Mock for making pastel leathers, for pre-tanning pickled stock before regular tan in order to mail-tain a lighter colored leather throughout tbe tannage, in vegetable tanning as an td to penetration of the extracts and solubil ization of non-tans, in dyeing to give even dyeing and increased penetration of (he dye, and as a mordant to hasten dyeing of chrome tanned and untanned leathers. "MERTEC** (Corrosion-Resistant Paint) Mertec is a corrosion-resistant paint designed for use as a protective finish under severe acid and alkaline conditions. It is formulated on a chemically inert base and gives remarkable protection against acid fumes and cauitie alkali attack. Merteo ia primarily for use on metal, but tbe inert base makes it a practical finish for concrete. It may also be used on wood surfaces. It gives a tough, glossy, oil and water resistant finis)*. Fire resistance is excellent; tbe paint does not support flame travel. Heat resistance in continuous service is good up to about 200F. Mertec is supplied in gray, rust, black, white and clear. Coverage is about 300 sq. ft. per gal. Pigmented Merteo R-3311 Cray $59 has the most desirable general properties. It is flexible and adberea well to almost any reasonably clean surface. It should cover satisfactorily in one coat, particularly the gray color which ia recom mended for general mill use on exposed metal. Clear Mertec R-3300 is inferior tv tbe pigmented type in weather resistance. 11 is also slightly less effective as a protective coating, and is recommended only where a pigmented finish is impractical. In using Clear Mertec R-3300 as a vehicle for aluminum, use about 1% pounds Aluminum Powder per gal. A (Continued) 26TR EDITION Page 77 0633817 I TOWOLDMON0041901 WATER_PCB-00026370 ready mixed product, Aluminum Met tec R-3457, can be supplied. For outside exposure a prime coat of R*3137 Gray 326 is recommended. Clear Mertec Topcoat R3311 is a special type for application over ordinary painted surfaces to give resistance to corrosion. Clear Mertec Topcoat also im parts greater resistance to corrosion when used over the Pigmented Mertec, and is especially recommended for use over Clear Mertec R-3300. Pigmented Mertec R-3799 is a special type for concrete floors. No priming roais or special preparation of the surface is necessary other thaD cleaning off loose grit ami dirt and any accumulation of oil and grease. The surface should preferably be dry but damp surfaces can be successfully finished. From the standpoint of durability under traffic the concrete surface should be smooth. K.R. Classification: Lacquers. Available Literature! Leaflet, ''Maintenance Paints.*' META-CHLOROANILINE (Sea meta-Chloroaniime under C). META-CRESOL (See tnetB-Cresol under C.) META-NITROCHLOROBEN2ENE (See meta-Nitrocblorobenzene under N). "METHASAN" (See Accelerators, Rubber). METHYL PHOSPHORIC ACID (See Alkyl Phosphoric Adda). METHYL PHTHALYL ETHYI., GLYCOLATE(SeeSamid*er M-17). METHYL SALICYLATE U.S.P. (See Salicylate*). MIXED ACID (See Nitrating Acid). MOLDING COMPOUNDS (Se* Plaatlcs). MOLD PASTE______________ ________________________________ Specifications! Several materials blended to give a satisfactory combination of the properties necessary for use on molds for vulcanizing rubber. Light brown colored paste; p. gr., 1.S4. {Continued) Pf78 MONSANTO CHZMICALS 0683816 TOWOLDMON0041902 WATER_PCB-00026371 T R.R. Classification: Chemicals NOIB,\. Available Literatures 42-page booklet "Monsanto Chemicals for the Robber Industry". MONOAMMONILM PHOSPHATE^ Ammonium Phosphate, Mono). MONOCALCILM PHOSPHATE (See Calcium Phosphate, Mono). MONOCHLOROBENZENE (See Chlorobenzene). MONOMAGNESIUM PHOSPHATE (See Magnesium Phosphate,Mono). MONSANTO PLASTICS (S< Plastic*). ``MONSANTO SALT'* (ortfio-Chloro-para-Toluene Sodium Sulfonate) _--. --.. (Also known as 3-chloro-4-methyI benzene sodiumsulfonate). CH, Characteristics! Light gray to light tan powder; assay (from Cl content), 97.0 100.5%; NaCI, 0.5% max.; moisture (H,0), 1.0% max. R.R. Classification! Dye Intermediate. General Information! Used in dyestuff synthesis. MURIATIC ACID (Hydrochloric)_______________ HCI Grades! 18 B<; 20 B4; 22" Bfi. Typical Analysis! 18 B&, 27.9% HCI.; 20 B., 31.5% HCI.; 22 B4., 35.2% HCI. R.R. Classifications Muriatic Acid General Information! Used extensively in the starch, glucose, steel, galvanii ing, paper, leather and glass industries. (See tobie in general data tectum) 26tb BoiTiON Page '9 0683819 TOWOLDMON0041903 WATER_PCB-00026372  NEALCO" ANTI-FREEZE. General Information: A completely denatured ethyl alcohol type aoti-freeze fluid for automobile, airplane and other gasoline engine cooling system*. Will not corrode the radiator, form rust, sludge or sediment: will not cause leaks nor attack Imse connections. K.R. Classification t Anti-freeze Alcohol. NITRATE OF IRON, COPPERAS (See Ferric Sulfste). NITRATE OF IRON, TRUly (See Ferric Nitrate). NI ATING ACID (Mix. Acid) 1 Analysis! Nitric Acid (HNOj) Sulphuric Acid (HjSO,) Oxides of Nitrogen (NjOj) 80.15 80.0% 15.0% 0 25% R.R. Classification! Nitrating Acid. 85-12 85.0% 12.0% 0.25% 18 60.0% 38.0% 0.25% 4543 45.0% 53.0% 0.25% Ceneral Information! Mixed acid is used for nitrating in the chemical industry, particularly in tbe manufacture of explosives and dyestufTs, Special mixtures can be furnished to meet individual requirements. (See table in general data section) NITRE CAKE (Sodium Bisulfate) Standard Format Bulk; ground; globular. Typical Analysisi 35% HjSOj available. R.R. Glassificationi Nitric Cake. General Informations Used to replace either sulfuric acid or combination of sulfuric acid and Glauber's salt. One hundred lbs. of Nitre Cake is approximately equivalent to 35 lbs. of 06* sulfuric acid and 141 I be. of Glauber's salt. Used principally in viscose rayon spinning baths; dyeing woolen goods; re fining nickel ores; msnufacture of sulfate pulp; in tanneries for pickling, deliming and making one batb tan solutions; as an acid scour for household use; is agri culture for disinfecting soil; as a bowl cleaner in sanitary trade. Page 80 MONSANTO CBBHICALS 0663620 TOWOLDMON0041904 WATER_PCB-00026373 NITRIC ACID. HNOj Standard Format 36 B6.. 38 Bf.. 40 Be.. and 12 B6. Typical Analysis! %HNOj: 36B.. 52.3:38B6.. 56.5; 61.4: 429B6., 67.2. Sp. g. will not vary more than 0.,5* terms of B6. HjSO* 0.1% max.; HCI 0.1% max. For higher strengths refer t* Merrimac Division Sales Office. It.K. Classification! Nitric Acid. General Information! Used in the manufacture of insecticides, dyestuffs, drugs, pharmaceuticals, explosive^, photo engravings, nitrates and other nitro products. (See table in general data section) NITRIC ACID C. P. UNO* Mol. Wt. 63.01 Typical Analysis! Colorless Iquid, free from suspended matter; strengtbfHNOs), 70.0 to 71.5%; non-volatile matter, 0.0005% mas.; sulphate (SO<) 0.0002% max.; chloride (Cl), 0.00007% Qtax.: arsenic (As), 0.000003% max.; heavy metals (as lead), 0.0005% max.; heavy metals (as iron), 0.0001% max. R.R. Classification! Nitric Acid. General Information! Laboratory reagent. l-NITRO-2, 5-DICHLOROBENZENE (Also known aa 2, 5-dichloronitrobenzene.) Mol. Wt. 192.01 Cl Standard Forms Fused solid. Specification*! Light yellow to light brown crystalline solid; crystallising point, 52.5C. min. R.R. Classification: Dye Intenmdiate. General Information! Used aa st> intermediate in the preparation of dyestuffs. CAUTION: This product u toxic. Avoid breathing its vaport and avoid contact with the shin. 2ATH IDITtOlt Page 81 0683821 TOWOLDMON0041905 WATER_PCB-00026374 orf/to-NITROANILINE (Also known as ortho* aminonilrobenzene and l-aminn.2<nitrobenzcne.) NHi Mol. Wt. 138.12 Standard Forms: Powder; powder with 0.5% triralciun* phosphate. Specifications: Yellow to nrangt powder; m. p. 70.0C.. min. Assay, powder. ')H.?ti% min.; powder with tricaMum phosphate, 98.50% min. Ash: powder, 0.25% max.; powder with tricalcium phosphate, 0.75% max. K.K. Classification: [)te IiilertiK'diate. General Information: ortho-Ntiroaniline powder has a tendency to "set up" in lumps on standing. It is recommended that it be milled to proper fineness just before using. The addition of 0.5% tricalcium phosphate reduces the caking tendency, ortho.Nitroaniline ia used as an intermediate in the preparation of dyestuffa. CA L'TION: This product is toxic. Avoid breathing its dust and avoid contort with the skin. para-MTROANILINE NH* Mol. Wt. 138.12 NOi Standard'Formi Powder. Characteristics: Bright yellow crystallise powder; soluble in HCI; m. p. 148SC. min.; assay 99% min. R.H, Classification: Dye Intermediate. "Poison" label required. General Information: Intermediate in dyestuff syntheses. CAUTION: This product u toxic, /fvotd contact with tJtin. Avoid inhaling vapors. ortho- NITROANISOLE___ __ (Also known as ortho>aminoanUo]e, onho-nitrophenylmethylether and l-me* thoxy'2>nitrobeneeoe. OCHi 1 NOi Mol. Wt. 153.14 Page 82 Standard Forms Liquid (Continued) MONSANTO CBIMICALS 0683822 TOWOLDMON0041906 WATER_PCB-00026375 Specifications! Light reddish or light amber liquid; crystallizing point, 9.6C. min., dry basis. Distillation range: first drop 270.0C. min.; 95% 2.08C. max.; dry point 273.0eC. max. Nitropbepol 0.05% max. R.R. Classifications Dye Intermediate. General Information t onfco-NitroanisoIe is used in the production of such dye intermediates as onfio-anisidine apd dianisidiae. It is also used in various or ganic syntheses. CAUTION: This product it toxic. Avoid breathing iu vapors and avoid contact with the shin. NITROCELLULOSE SOLUTIONS (See Cotton Solutions). meta-NITROCHLOROBENZENE ____________________ (Also known as msSo-chloronitrcbenzene and I chloro-3-nitrobenzene.) NO, Mol. Vt. 157.50 Standard Form i Fused solid Specifications, Greenish yellow crystalline mass; clear when melted; crystalliz ing point 43,9'C. min. R.R. Qaaaification Dye Intermediate. General Informatloni Used for icover*ion into various dyestuff intermediates, cbloroanilinea and chlorobenzidines. CAUTION: This product is toxic. Avoid breathing Us vapors. Avoid oontad with the skin. orf/io-NITROCHLOROBENZENE_____________________ (Also known as crtAo-chlorooitrobeiucne and l-chioro-2-nitrobenxene.) Cl r^No, MoL Wt. 157.50 Standard Form, Fused solid Specifications! Greenish yellow crystalline mase; crystallising point 31.7C. (on sample aa received). R.R. Classifications Dye Intermediate. General Information! Used in tbe preparation of dyestuff intermediates. C4 C770.V? 77iu material is toxic Avoid breathing Us vapors. Avoid contact uitA the skin. 26TU XDITIOn Page 83 0683823 TOWOLDMON0041907 WATER_PCB-00026376 para-MTROCHLOROBENZENE___________ __________ (Alu known as /wa-chlornnitmbfnzene and l-ohloro-4'oitrobenzeDe.) 0 Mol. Wt. I57.S6 Standard Form: Fused solid Specification*! Light greenish yellow solid; crystallizing point 82.5C. min. K.R. Classification: Dye Intermediate. General Information: para-Nitrobtnzene is used in the preparation of dyestuff intermediates. CA L TIO.V: This pioduct is toxic. Avoid breathing its vapors and avoid contact with the skin. ort/io-NITRODIPHENYL, TECHNICAL NO. I 0-0 Mol. Wl. 199 Characteristics: Light yellow to reddish crystalline solid; crystallizing point 34.5C. min. R.R. Classification: Dye Intermediate INOIBN. General Information t Used as an intermediate in chemical synthesis where it is useful in some applications as an alternate lot substituted nitrobenzene*. May be partially reduced and rearranged to give 2.2'*diphenyl benzidine (NHj-1). "NITRON" (See Plastic). para-NITROPHENOL (Also known as pora-hydrozynitrobeotene and l-bydrosy-4-nitrobemen*.) OH Mol. Wt. 139.11 NOs Standard Form: Granules Specifications: Brown granular mass; m. p. (dry basis) 112.0C. min.; assay, 96.5% min.; water insoluble material 0.20% max.; alcohol insoluble material 0.20% max. (Continued) Page 84 MONSANTO CHEMICALS 068382** TOWOLDMON0041908 WATER_PCB-00026377 ft.H. Classification: l>ye Intermediate. General Information) para*Nitrophenol has the following uses: as ao inter* mediate in the production of dyestuffs and photographic chemicals such as paraaminophenol and methyl para-aminophenol; as a fungicide to prevent mold growth on chrome tanned leather. CAUTION: This product is toxic. Avoid breathing its Hunt or vapors and at<oid contact with the skin. OIL ANTIOXIDANTS (See Stntolube). OIL OF VITRIOL (See Sulfuric Acid). OLEUM (See Sulfuric Acid). "OPALON" (See PUttvcs). ORTHO-AMINODIPHENYL (See ortho-Aminodipbeoyl under A). ORTHO-ANISIDINE (See orthoAnisidine under A). ORTHO-CHLOROANILINE (See ortho-Chloroaniline under C). ORTHO-CHLORO-PARA-TOLUENE-SOD1UM-SULFONATE (See Monsanto Salt.). ORTHO-CHLOROPHENOL (See ortbO`Chlotophenol under C). ORTHO-CRESOL (See ortbo*Creol under C). ORTHO-DICHLOROBENZENE TECHNICAL (See ortho-DichW- bensene Technical under D). ORTHO-NITKOANILINE (See ortbo-Nitroaniline under N). ORTHO-NITROANISOLE (See ortbo-Nitroanieole under N). 2STB (DITION Page BS 068362$ TOWOLDMON0041909 WATER_PCB-00026378 ORTHO-NITROCHLOROBKNZENE (See ortbo-Nitrochloiobenzene under N). ORTHO-NITRODIPHENYL (See ortbo-N'itrodiphenyl under N). ORTHO-PHENETIDIX (See urtbo-Pbenetidin under P). "OXYNONE'* (See AntioxidaDt^, Rubber). PAINT, acid and alkali reaiatant lor plant maintenance; (See Mertec). PAINT ANTISKINNING MATERIALS, available to fit varied trade requirement*; (See Santovar A). PAPER LACQUERS (See Lacquer*). PARA-AMINODIPHENYL (See paraAminodiphenyl under A). PARA-ANISIDINE (See para>Ani*idine under A). PARA-CHLOROANILINE (See para-Chloroaniline under C). PARA-CHLORO-META-CRESOL (See para>Chloro.meta*Creaol under C). PARA-CHLORO-META-XYLENOL (See para-Chloro-meta-Xylenol under C). PARA-CHLOROPHENOL (Seepara-Chlorophenol under C). PARA-CRES0L (See para-Cre*>l under C). PARA-NITROANILINE (See para-Nitroaniline under N) Page 86 Monsanto chemicals 0683626 TOWOLDMON0041910 WATER_PCB-00026379 PARA-NITROCHLOROBENZHNE (See para-Nitrochlorobenxcne under PARA-NITROPHENOL (See para-Nitrophenol under N). PARA-PHENFTIDIN (See [lara.l'henrliclin under P). PARA-TOLLENESL'LFONA.MIDE (See para-Tnluenesulfonamide under T). P\RA-TOLLENESULFONCHU>RIDE (See para-Tulueneutfurw cMoriiie under T). PENETRATING AGENTS (See Areslcap, Aresket, Aretklene, Santornevae). PENTACHLOROPHENOL (Set Santophen 20 and Permaaanj. PERCHLORIDE OF IRON (S<e Ferric Chloride Solution). "PERMANOL" _____________ ______________________ Gradeat Permanol; Permanol 7. Propertieei Viscous liquid. Inorganic *alt crystalliiea out at temperature* below 40 F. R.R. Classification! Liquid Tanning Extract NOIBN. General Information! Permanol i* . synthetic tanning agent is liquid form. It baa the special property of being exremely ligbtfast. Information on uaet for Mertanol applies. See Mertanol. "PERMASAN" Characteristics! Consists of 5% ptntachlorophenol, min., 5% nonvolatile solvent and 90% petroleum distillate; light amber color, lew than 4.5 NPAS; characteristic petroleum odor; flash pqint, 140F. min. by Tagliabue closed cup method; sp.g. approx. 0.8785 at 15.5C.; wt. per gal., 7.2 Lbs. (Continued) 26TB BDITION Page 87 066382? TOWOLDMON0041911 WATER_PCB-00026380 R,R. Classificationx Liquid Wootf Preservative N'OIBN. General Information: Used for pi cservation of wood against termites, Lyvtua (powder-post) beetles, decay, and a wide range of other wood-attacking insects and organisms. Does not adversely affect the feel and appearance of wood, and surfaces properly treated may be satisfactorily glazed, painted or otherwise fin ished. Permasan conforms w ith the specifications of the Western Pine Associa tion's Bulletin No. 6 (revised) and Is accepted by the National Door Manufact urers Association. Permasan is irritating to the skin and mucous membranes if sufficient contact is pcrmilled. The precautions for handling given in literature listed below should be observed. Available Literature: 6-page Monsanto Technical Bulletin 0-20, "Permasan for the Preservation of Seasoned Wood." 5-page Monsanto Technical Bulletin 0-14, "Permasan for Lyctu* (Powder-Post) Beetle Control." "PERMASAN 116'* Characteristics! Consists of 5% pentachloropbenol, min., and 95% mixture of water repellents, organic solvents and diluents; light amber color, less than 4.5 NPAS; mild, not unpleasant odor; flash point, 1009F. min, by Tagliabue closed cup method; sp. g. approx. 0,855 at 15.5C.; wt. per gal.. 7.13 lbs. R.R. Classification! Liquid Wood Preservative NOIBN. General Information! Used same as ordinary Permasan (see above) except gives added advantage* of water repellency. Conforms with specifications of Western Pine Association's Bulletin No. 6 (revised). Permasan is irritating to tbe skip and mucous membranes if sufficient contact is permitted. Tbe precautions for handling given in literature listed below should be observed. Available Literature: 8-page Monsanto Technical Bulletin 0-21, "Permasan 116 A Water-Repellent Preservative for Wood." PETROLEUM CHEMICALS* (See Santolene, Santolubes, Santopoid, Santopour). PHENACETIN (See Acetopheietidin). ort/io-PHENETIDIN _____ (Also kaowo as ortho-aminophenyU tbylether, ortAo-aminophenetole, and 1-amino-2-ethoxybensene. (Continued) Page88 Monsanto cbbuicals 0683828 TOWOLDMON0041912 WATER_PCB-00026381 HCjHi 0 NHt Mol. Wt. 137.18 Standard Forms Liquid Specifications: Dark red liquid: crystallizing point (as received) --4.0eC. min. Distillation range: first drop 231.0'C, min.; 95% (1-96 ml.), 2.0C. max.; dry juiint, 234.0C. min. Solubility in I.CCI, complete. It.li. Classification; Dye Inlermtdiate. General Information! trt/io*Phnetidin is used as an intermediate in the production of dyestuffs. CAUTION: This product is toxic. Avoid breathing its tnpors and contact with the skin. pora-PHENETIDIN ______ _____________ .. (Also known as para.aminopfienyletJiyiether. panj-amirtophenetoie, sad l-amino-4 -iboxybenzene.) OC,H Mol. Wt. 137.18 NHi Standard Form: Liquid Specifications: Dark red liquid; crystallizing point (as received) 4.0*C. min. Distillation range: first drop 248.0C. min.; 95% (1*96 ml.), 2.0C. max.; dry point 251.0C. max. Solution in HOI, opalescent. R.R. Classification: Dye Intermediate. General Information! porn-Phenetidin is used as an intermediate in tbe pro* duct ion of dyestuffs and pharmaceuticals. CAUTION: This product is toxic. Avoid breathing its vapors and contact uith the skin. PHENOL-FORMALDEHYDE RESIN (See Plastics, Resiaox). PHENOLIC RESIN, CAST (See Plastics, Opaloo). PHENOL ________________ _____________________________ (Also known as carbolic acid and by droxybenzene.) oa 26TH EDITION 'Continued) Page 89 0683829 J TOWOLDMON0041913 WATEFLPCB-00026382 Standard Forms* Crystalline solid, U.S.P.; ''quid 85%; liquid 88%. Specifications of Crystalline Solid, L'.S.P.i White crystalline solid; melt, colorless mobile liquid; solution in water (1:15), clear and colorless; non-volatile residue <100C.). 0.04% max.; crystallizing point 40.0'C. min. Distilling range: first drop, 180.0C. min.; 100% (first drop to dry point), 2.0'C. max.; 50% to dry jHiint, 0.2C. max. Specifications of Liquids: Colorless mobile liquids. Assav: liquid 85%, 85.0. Wmj%; liquid 88%. 88.0 - 8>>.0%. ' II.H. Classification! Phenol. General Information! Used as an intermediate for the production of dyestuffs; in production of resins for molding and in the preparation of varnishes, enamels, lacquers and paints; as a selective advent in the manufacture of lubricating oils; as a disinfectant; in textile printing; in the production of explosives, synthetic tanning materials, pharmaceuticals and medicinals. antiseptics, germicides and preservatives, deodorants, soaps, embalming fluid, vermin exterminators, rubber compounds, and photographic chemicals. PHENOLPHTHALEIN, U.S.P. OH OH Mol. Wt. 318.31 O Specifications! White powder; m.p. SS^O'C. min.; solubility in alcohol (1:15), complete; acidity (cc's N/1000 NaOU/2 g. sample), 3.0 cc. max.; ash 0.05% max.; arsenic 0.001% max.; conforms to U.S.P. test for fluorine and heavy metals; trace max. retained on 100 raesh screen; 21.0% max. on 325 mesh screen. R.R. Classification! Chemicals NOIBN. General Information! Used in pharmaceutical preparations. PHENOLPHTHALEIN, YELLOW, Not U.S.P Standard Form! Powder. Specifications! Yellow powder; m.p. 2$7.0C. min.; loss on drying, 0.50% max.; ash, 0.10% max.; acidity (cc's N/1000 sodium hydroxide per 2 gm. sample). 5.0 cc max.; solution in ethyl alcohol 95% (1:15), clear; sp. g. (apparent) 0.500 0.600; none retained on 20 mesh screen. (Continued) Page 90 MONSANTO CHEMICALS 0683630 TOWOLDMON0041914 WATER_PCB-00026383 K.K. Classification: Chemicals >OIBN. (General Information: L'sed in pharmaceutical preparations. PHENOL-FORMALDEHYDE (See Plastics, Resinox Molding Com* ...... '"Is). PHENYL SALICYLATE (See Salicylates). PHOSPHATES (See Ammonium Phosphate, Calcium Phosphate, Magnesium Phosphate, Potassium Phosphate, Sodium Phosphate) PHOSPHOLEUM (See Tetraphoephoric Acid). PHOSPHORIC ACID (Orthophoaphoric Acid) IIjPO Mol. Wt. 98,004 Standard Forma: 50%, 75% and 85% HjPOs. Other concentrations supplied nn request. Specifications: Clear, water-white liquid miscible with water in all proportions. Grades! U.S.P.; food, meets all U-S. Pure Food Law requirements: commercial, clear water white liquid; Phoailage, meets ail U.S. Food Law requirement*; special. K.R. Classification: Phosphoric Acid. General Information! Principal usee -- Ceramics: To increase translucencv and improve the color of porcelains; as a vitrifying agent and flux. Chemicals and Intermediates: In manufacture of sodium phosphates, calcium phos phates, and other phosphates: in manufacture of ethylene gas: in making albumen derivatives. As a drying agent in the synthesis of various intermediate chemicals. Dyes: As a drying agent tn the synthesia of various dyes. Engraving: In pro cess engraving and litho trades. Envelopes: As a penetrant to aid in the ab sorption of the gum. Fertilizers: In manufacture of double and triple super phosphates; in manufacture of ammonium phosphate. Gelatin: ]q manufacture of gelatin. Glass: As opacifier. Jelly ana Preserves: As a substitute for tar taric and citric acids. Metals: For pickling and cleaning. Pharmaceuticals: In manufacture of certain pharmaceutical chemicals; in making dental cements: in manufacture and purification of hydrogen peroxide; in manufacture of glycero phosphates. Rope and Twine: For brightening the finish. Rubber: As a coagulant of rubber latex. Rust Proofing: In the manufacture of rust proofing compounds. Silage: For silage pieservatton. Soft drinks: As a substitute for (Continued) 26TB EDITION Page 91 0683831 TOWOLDMON0041915 WATEFLPCB-00026384 (<*riaric and ciiric acids. Sugor; As a defecating and clarifying agent. Textiles: In brightening the color of silk; in the dyeing of cotton; in calico priming. (Taler treatment: In water softening and correction of alkalinity. 15C. Density and Composition of water solutions of Orthophoiphoric Acid ( ~'o ~ Density Decrease g./cc. uoo 1.150 1.200 1.250 1.300 1.339 1.350 1.400 1.150 l.SOO 1.550 1.581 1.600 1.650 1.693 per 1C. 0.00030 0.00035 0.00045 0.00050 0.00055 O.OOOS5 0.00060 0.00060 0.00060 0.00065 0.00070 0.00077 0.00075 0.00075 0.00080 %HjPO, 17.52 25.25 32.52 39.22 45.51 50.00 51.22 56.85 62.27 67.35 72.11 75.00 76.75 81.30 85.00 %PA 12.69 18.29 23.55 28.41 32.96 36.21 37.10 41.17 45.10 48.78 52.23 54.32 55.59 58.88 61.56 %P 5.54 7.98 10.28 12.40 14.39 15.81 16.19 17.97 19.68 21.29 22,79 23.71 21.26 25.70 26.87 1.700 1.750 1.800 1.8S0 1.874 0.00080 0.00080 0.00080 0.00080 0.00080 85.63 89.88 94.15 98.13 100.00 62.02 65.10 68.19 71.07 72.43 27.07 28.41 29.76 31.02 31.61 The density of more concentrated acic^a increases approximately linearly (within the range 72.-14% to B5% PjOj) with the excess PjOj over 72.44% according to the equation: Density1-q5rC". "= 1.874 + 0.0171 (%P,0| -- 72.43). PHOSPHORIC ANHYDRIDE (See Phosphorus Pentoxide). PHOSPHORUS, ELEMENTAL (Also known as yellow phosphorus and white phosphorus) Grades! Monsanto process of manufacture provides over 99.9% purity. Properties! Light yellow, wax-like, semi-transparent solid; bums spontaneously in air to form PiOi; m.p. 44.1`C.; insoluble in water but very soluble in carbon bisulphide. K.ft. Classificationi Phosphorus, Yellow. General Information! Used in manufacture of pbosphorui alloys, phosphoric anhydride, phosphorus compounds, phosphoric acid, rodent poisons, flares, smokescreens, etc. PHOSPHORUS OXYCHLORIDE _________ (Also known as phosphoryl chloride). POC1, Pago 92 Mol. Wt. 153.35 (Continued) MONSANTO CHEMICALS 0683832 TOWOLDMON0041916 WATER_PCB-00026385 Standard Forms Liquid. Specifications* Water-white to vctlow liquid; crystallizing point 0.8C. min.; assay 09.0% min. Distillation ranger first drop, 106.0C. min.: 95% (1-06 ml.), l.5C. max.; dry point. 108.5C. max. PCIj, 0.20% max.; PClj, trace max.; HjPO,, 0.30% max.; HCI, 0.30% mat.; free chlorine, trace max.; iron. 0.0005% R.R. Classification; Phosphorus Oxychloride. General Information! Used as a chlorinating agent and catalyst in the prep aration of various intermediates nd dyestufTs and as a reagent in the prepara* tion of acetic anhydride and organic phosphates. CA U'T/O.V; Care must be ex ercised in handling this product. Avoid breathing its vapors; avoid contact with the skin. It reacts with water with explosive violence. PHOSPHORUS PENTOXIDE_____________________ (Also known as phosphoric anhydride; phosphoric oxide; solid P,Oj.) Pt0s Mol. Wt. 141.96 Standard Formt White amorphous powder. Characteristics! Vapor Pressures: (after J. C. Southard and R. A. N'elaon--J.A.C.S. 59. 911 (1937) p == vapor pressure in cm. of mercury. T = absolute Temperature). A (low temperature form) Log|op= 9.792--(5000/T) B (high temperature form) Logjo/>= 11.113--(7930/T) L (liquid) Logiop = 6.809--(4320/T) Atmospheric sublimation temperat ure: 3S8.9C. Beat of vaporization: A--22,800 calories per gm. molecule. B--362200 calories per gm. molecule. L--19,700 calories per gm. molecule. Heat of fusion: 16,500 calories pet gm. molecule. Probable molecular formula of vapor: P4On>. R.R. Classification! Phosphoric Anhydride. General Information! Used in the manufacture of organic and phosphorus compounds and as s cayalyst. It is a vigorous drying and dehydrating agent. PHOSPHORUS TRICHLORIDE PCI, Mol. Wt. 137.3S Standard Formi Liquid. Specifications! Water white liqvid: ap. g. at 15.5/15.59C., 1.582*1.587. Dis* (Continued) 24TB EDITION Page 93 0663833 TOWOLDMON0041917 WATER_PCB-00026386 tilling range: first drop .TUS'C. min.: dry point. ?9.0C. max.; total range, 3.0C. max. K.R. Classification: Phosphorous Trichloride. General Information i Used as a chlorinating agent and catalyst in the prep, aration of various intermediates and dvestuffs; as a reagent in the preparation f acetic anhydride and organic phosphates; in the manufacture of phosphorus oxychloride and phosphorus pentachlotide; and in producing iridescent metallic rleponiis. CAL TfON: Care mutt be exercised in handling this product. Reacts with n tucr. 4 mid breathing its vapors; avoid contact uiith the. thin. PHTHALIC ANHYDRIDE Mol, Wt. 148.11 Standard Form! Flakes Grades! Three grades with crystallizing points of 13l.2C., 131.0C., and 130.7n respectively. Specifications* White flakes; solution in benzene (1:20) clear; ash 0.03% max. Maleic acid; 131.2C., 0.10% max.; 131.0C., 0.15% max,; 130.7'C., 0.13% max. R.R. Classification* Phthalic Anhydride. General Information: Uses; As an intermediate in the production of dyestuffs, perfume bases, alcohol denaturants, pharmaceutical products, plasticizers--such as dibutyl phthalate, dimethyl pbthalate, diethyl pbthalate, phtbalyl glycollates --and alkyd retina. PHTHALYL CHLORIDE IT'iCOCl l Jcoci Mol. Wt. 203.03 Standard Formi Liquid, Characteristics! Yellowish liquid; assay, 95.0% min.; crystallizing point, 7.5C. R.R. Classification! Chemicals NOIBPi. Corrosive liquid (white label required). General Information* Used in the manufacture of plasticizers and resins. PICKLER'S ACID (See Inhibited Acid). Psge 94 MONSANTO CHEMICALS 068383A TOWOLDMON0041918 WATER_PCB-00026387 PIPERIDINE______________ (Alsu known as hexaliydropyridine). Mol. Wt. 85.14 Standard Form: Liquid Specifications: Clear. water-wbitt liquid of characteristic odor; assay, 98% min.; pyridine, 1.0% man.; 8p. g. 25'/25'C., 0.860 0.003. Distillation range: lOLO'CJ. min. start; 107.0C. max. dry point. K.it. Classification: Chemicals NOIBN. General Information: Used as an intermediate in the manufacture of phar maceuticals, wetting agents, and getmirideB. "PIP"PIP" (See Accelerators, Rubber). PLASTICIZERS (See Santicizrrs, Dibutyl Pbthalate, Diethyl Phtbalate, Dimethyl Pbthalate, Diphenyl Phtbalate, Tricreeyl Phosphate, Triphenyl Phosphate). PLASTICS (See individual materials below.) i-- CAST PHENOLIC (See plastics, Opalon). CELLULOSE ACETATE (See Plastics, Fibestos). CELLULOSE NITRATE (See Plastics, Nitron). "FIBESTOS"* (Cellulose Acetate) The most widely-used thermoplastic, cellulose acetate, ia distinguished by a flexible range of properties and formulations. In the form of molding compounds, Fibestos is adapted to either compieasion or injection molding. Sheets, rods, tubes and continuous length rolls ate other forms in which it ii produced by Monsanto. Mechanical Properties: Specific gravity.................................................................... 1.27 1.37 Specific volume, cubic inches per pound.................... 20.2 -21.8 (Continued) 26TH EDITION Page 95 P L A S T IC S 0663835 TOWOLDMON0041919 WATER_PCB-00026388 I P L A S T IC S 1 1.30Kcfrartivc index ,N o ........................................................ . IT 3,500 11 0Tensile strength, lbs., sij.in..................... . 5-55I'.!i>n;iilioii, |iiTi enl ............................................ . 13-33Unrsiing sireusih (rupture) lbs,. <|.iii., mil. . . . 10 3.5Mmliilns ,if rltieiiriiy, lb*. -n-iti x s........................I . (H) ImpiK t slri'iiylli, l/.ml, f(. lbs. in. itf iiolrl 0.7 4.2(V-S.T.M.) ............................................................. 2.5 10 13ItriiK'l! liiKclne-s, nun. li.il! ky. hud ... . 25 35Ko.hu.ll hardness ............................. '.............................. \t . M Machinin'' <in:ilili<>H............................ ...............................ImuxI 1Molding Properties: >}<.........................................................................................Thermoplastic Molding tpnjlittes............................................................... I'.xrcllent Molding Temperature F. 21(1 350(!<iiii|iresiiin............................................................ 300 10Injection................................................................... I Molding Pressure )l>s. sq. in. 500 5000Compression........................ ................................... ,?)000 30000Injerlinn............................................. . - Preforming......................................................... . Verv <*<>ml Tendency toroid Him . .Might Processing cellulose nl Springfield plant for manufacture of Monsanto plasties. 0683636 TOWOLDMON0041920 WATER_PCB-00026389  Molding methods applicable......................... ................. Compression, injection, trillion, *h aging Mold shrinkage, inches/nch: Povtive........................ 002 .003 Setiii-positive..............005 .007 Flash............................. 008 .009 Extruding quality............ ............................................... Excellent ei* Thermal Properties! Horning rate. in. min. (.060') ....................................1.5 - 2.0 Slow burning Thermal conductivity, 10--1 calo'ies/sec,/sq.cm./ 0, cm......................................................................4.5 7.8 Specific heat. ca!ories/C. gram.....................................0.3 0.4 Thermal expansion, 10--* C.......................................... 10 16 Resistance to heat, "F. (continuous)........................... 140 - 250 Softening point. F.............................................................110* 260 Effect of heat, dry .......................................................... Little or noDe moist.......................................................... Slight swelling Heat distortion, F. (A.S.T.M.).................................... 122-212 Electrical Properties! \ olume resistivitv, ohms-ems. (S')%R.H. and 25C.). . ............................................................... (0.7 1.4)xl0> Breakdown voltage, 60 cycles volts mil......................600- 1.800 Dielectric constant, 60 cycles......................................... 3.5 - 7.5 10# cycles................................ 2.0 5.0 Power factor, 60 cvcles..................................................... 0.007 0.07 100 cycles....................................................0.007 0.03 Chemical and Physical Properties: Odor.........................................................................................None to mild aromatic Taste........................................... ........................ . . None Effect of age........................................................................ .. Slight Effect of sunlight........... .................................................. Gradually become brittle-- some colors fade Effect of ultraviolet light............................. .. ................ Gradually become brittle-- some colors fade. Effect of metal ineerta...................................................... None Effect of weak mineral acids...........................................Fair resistance Effect of strong acids......................................................... Decomposes Effect of weak alkalis ....................................................... Slight Effect of strong alkalis .................................................. Decomposes Water absorption 24 boura.............................................. 1.5 3% Solubility: Softens in-- ............................................... Alcohols, esters Swells in-- ................................................. Chlorinated hydrocarbons Insoluble in-- ............................................... Aromatic and aliphatic hy drocarbons, animal, mineral, and vegetable oils, ethers Colors Available in an extremely wide variety of transparent, translucent, pastel and opaque colors, at well as in many mottles, pearls and decorative configurations. Forma: Sheets, rods, tubes and molding compounds. Trade Mark Reg. U. S. Pat. Off. 26TH KDITION Page 97 0663837 TOWOLDMON0041921 WATER_PCB-00026390 P L A S T IC S - "LUSTRO.N"* (Polystyrene Molding Compounds) Lustron is Monsanto's formulation of polystyrene molding compound. Tbe rapid expansion of uses for Lustron since its introduction in 1939 is excellent proof of its versatility and broad range of useful properties. It is unexcelled among thermoplastics fur electrical characteristics, chemical resistance, low moisture absorption and dimensional stability as the following table of properties indicates. Molding quality ... ........................................................ Excellent Coni|>re>sion molding temperature, UF...................... 275 350 Compression molding pressure, Ibs./sq.in................... 1000 5000 Injection molding temperature, eF................ ............... 300 500 Injection molding pressure, Ibs./sq.in.......................... 10.000 and up Compression ratio.................................... ........................ 2.0 2.3 Mold shrinkage.................................................................... Compression 0.002 0.005 in. per in. Injection 0.002 0.008 in. per in. Specific gravity , ........................................................... 1.054 1.070 Specific volume, cu.in./lb................................................ 20.3 25.9 Refractive index .............................................................1.59 Tensile strength, lbs., sq. in..............................................5000 9000 Elongation, %...................................................................2*5 Modulus of elasticity, in tension, Ibs./sq in..............1.7 2.6 x 10s Compressive strength, lbs. sq. in................................... 11.500 - 13.500 Flexural strength, Ibs./sq. in.. ....................................... 14,000 19,000 Impact strength, Izod, ft. Ibs./in. of notch (A.S.T.M.)............................................................... 0.35 - 0.50 ft.lbs./ia. of notch Brinell hardness (2.5mm ball, 25kg. load)................ 20 - 30 Rockwell hardness...............................................................M87 - M90 Light transmission, % ................................................88-90 Thermal conductivity, cal./sec./sq.cm./C./cin. 1.9 x 10-- * Specific heat, cal./"C./gram . . ............................... 0.32 Thermal expansion, C.......................................................(6 - 8) x 10--* Softening point, F.......................... ................................. 190 230 Distortion under beat, F. (A.S.T.M.) .................. 170 180 Tendency to cold flow ................................................. Slight Volume resistivity, ohm-ems. (50% R. R. and 25C.) ion . lot* Dieletric strength, short time, in. thickness volta/mil........................................................... 500.700 Dielectric constant, 60 cycles................................. 2.5 -2.6 Dielectric constant, 10s cycles.............................. 2. 5- 2.6 Dielectric constant, 10* cycles............................... 2.5 -2.6 Power factor 60 cycles.............. ..................... . .. 0.0001 0.0002 Power factor 10* cycles............................................ 0.0001 -0.0002 Power factor 10* cycles............................................ Water absorption, immersion 24 brs.................... Burning rate................................................................. Effect of age................................................................ Effect of sunlight......... .............................................. Effect of weak acids and atrong acids................. Effect of weak alkali* and strong alkalis.......... Effect of organic solvent#...................................... .. Machining qualities................................................. 0.0001.0.0004 0.00 Moderate Very slight Yellows slightly None None Soluble in aromatic and chlorinated hydrocarbons Fair to good (.Continued) Page 96 MONSANTO CHE MIC A t r 0663636 TOWOLDMON0041922 WATER_PCB-00026391 P L A S T IC S - Color possibiliiic* ...................................................... Unlimited Effect oq metal inserts...................................................... None Available Literature: 16-psgc booklet "Lustron--A Monsanto Plastic.'* Trade Mark Re?. U. S. Pat. Off. ".NITRON"* (Cellulose Nitrate Sheets, Rods, Tubes)_______ Nitron is a cellulose nitrate plastic which continues as the moat auitable material for many exacting uses such as drawing instruments, fountain pens, tool bandies, tooth brush handles, heel coverings, watch and instrument crystals. The raoge of colors and special effects obtainable in Nitron plastics is unlimited. It is easy to fabricate and can be molded, drawn, or blown. Mechanical Properties! Specific gravity ..................................................................... 1.3S 1.40 Specific volume, cu.in./lb.................................................19.8 20.5 Refractive index No ........................................................ 1.50 Ultimate (ensile strength, Ibs./sq. in............................5,000 10,000 Elongation, %...................................................................... 10 40 Modulus of elasticity, in tension Ibs./sq. in...............200.000 400.000 Impact strength, Charpy, ft. lbs /in. of notch (A.S.T.M.)................................................................3-12 Brinell hardness, 2.S m.m. ball, 10 kg. load................8 11 Rockwell hardness............................................................M25 MOO Machining qualities.......................... ................................. Very good Molding Properties: Type........................................................................................Thermoplastic Molding quality.................................................................. Good Compression molding temperature............................... 185 250*F. Compression molding pressure, Iba./sq. in................. 100 500 Preforming. .................................... ............................... Very good Tendency to cold flow........................................................Slight Molding methods applicable........................................... Swaging, shearing,blowing-- All very good Thermal Properties Burning rate............................................................ ......... Rapid Thermal conductivity, B.T.U./br./sq. ft./F. temp. diff./in. thickness.................................................. 0.90 1.48 Specific beat, calories/<C./gram................................... 0.34 0.38 Thermal expansion, 10-- VF.......................................... 6.5 - 8.9 Resistance to heat, F. (continuous).......... ..............Approximately 140 Softening point, (A.S.T.M.) ...................................... 160 195F. Decomposes at 272F. in 30 minutes Effect of beat, dry ........................................ ................... Discolors on continued heat* icg at 212F. Electrical Properties: Volume resistivity ohms-cms. (50% R, H. and 25C.) ...........................................................(2-30) x 10* Dielectric strength, 60 cycles, volta/mil..................... 600 - 1,200 (Continued) 26TH BOITION Page 99 0663639 TOWOLDMON0041923 WATER_PCB-00026392 -PLASTICS- Dielectric constant, 60 cycles................. Dielectric constant, 10* cycles............... Power factor, 60 cycles............................. Power factor, 10* cycles........................... Chemical and Physical Properties! ()ilor................................................................ Taste............................................................... Cffect of age............................................... .... PfTcct of sunlight.......................................... CITect of ultraviolet light.................... Kffect of weak mineral acids..................... Effect of strong acids................................... Effect of weak alkalis.................................. Effect of strong alkalis....................... . . Water absorption 24 hours immersion . Effect of hot water....................................... Effect of cold water............................. .. . . . Effect on metal inserts................................ Solubility! Soluble in................................ Insoluble ii .6,7 7.3 .6.2 0.06-0.15 0.07-0.10 . None or rampborous .Tasteless to slight .Slight hardening . Discolors and becomes britile . Yellows and decomposes on extended exposure .Good resistance . Poor resistance, derompom * . Very slowly decomposes Decomposes 0.6.2.0% Softens, slight shrinkage None None . Alcohols, ketones, esters Aromatic and aliphatic hydrocarbons, mineral, animal and vegetable oils. Color! Available in an extremely wid< variety of transparent, crystal, translu cent, pastel and opaque colors., as well as in many mottles, pearls and oroamental configurations. Format Available in sheets, rods, tubes and special shapes. "Trade Mark Reg. U. S. Pat. Off. "OPALON*** (Cast Phenol-Foimaldehyde) A cast pheuol-formaldebyde resin. Option is noted for its beauty and the ease with which it can be fabricated* together with the ability to take a high and lasting polish. Special abapes and castings can be produced with low investment in molds. The size of casting ranges fropi handles for brushes and razors to large parts for coin machine housings, and complete radio cabinets. Restrictions on raw materials now limit the use of Opalon to essential civilian needs and to military applications. Mechanical Properties! Specific gravity................................... ................................. 1.27 - 1.32 Specific volume, cu. in./lb.................................................20.0 21.8 Refractive Index Np ......................................................... l.S 1.7 Tensile strength, Ibs./sq.in................................................5.000 12.000 Elongation..............................................................................Very Slight Modulus of elasticity, Ibs./sq.in.xlO*.......................... 5*15 Compressive strength, Ibs./sq.in................................ . 13,000 30,000 Impact strength, Izod ft. Ibs./in. of notch (A.S.T.M.) .................................................................0.1-0.4 Brinell hardness, 2.5 turn, hall, 25 kg. load..............30-43 (Continued) Page 100 MONSANTO CHEMICALS 0683640 TOWOLDMON0041924 WATEFLPCB-00026393 Rockwell hardness............................................................. M80 M130 Machining qualities............................................................Excellent Shrinkage, % ......................................................................0-1 Molding Properties: Tvpe........................................................................................ Thermosetting, non-moldable Thermal Properties: Hiirning rate........................................................................ Will not support combustion Thermal conductivity, 10~4 calorie/second/sq.cm C. cm............................................... ......................3-5 Specific heat, calor>es/C./gram.................................... 0.3 0.4 Thermal expansion, 10-3/C.......................................... 2.8 Resistance to heat, F. (continous).............................. 160 Effect of heat, dry ............................................................. Hardens slowly moist...........................................................Whitens Heat distortion..................................................................... Above normal temperatures Electrical Properties: \olume resistivity, obms-cms. ($0% R.H. and 25C).......................................................................... 10- 10i Dielectric constant, 60 cycles.........................................5-10 10* cycles.......................................5.0 7.0 Power factor, 60 cycles.................................................... 0.025 0.20 10 cycles..................................................0.005 0.08 10* cycles..................................................0.01 0.045 yb Chemical and Physical Properties: Odor................................................................. None Taste . ............................................................. None Effect of age.................. ........................... Hardens slightly Effect of sunlight....................................... J Yellows slightly on exposure Some colored materials fade Effect of ultraviolet light......................... Yellows slightly on exposure Some colored materials fade Effect of weak acids................................... None or slight Effect of strong acids................................ Decomposed by oxidizing acids. Reducing and organic acids have leas effect Effect of weak alkalis................................ Slight to marked, depending on alkalinity Effect of strong alkalis.............................. Decomposes Water absorption, 24 hours immersion 0.01 0.5 Effect of hot water..................................... Softens and whitens Effect of cold water................................... None Effect od metal inserts.............................. Inert Solubility: Insoluble in-- ......... .. Most organic solvents, alco hols, ketones, esters, aro matic and aliphatic hydro carbons, mineral, animal and vegetable oils Color: Available in an extremely wide variety of transparent, crystal, trans lucent, pastel snd opaque colors, as well aa in many mottles and orna mental configuration*. Form: Available in sheets, rods, tubes and a very extensive variety of cast shapes and objects. 'Trade Mark Reg. U3. Pat. Off 2ATB EDITION Page 101 0663841 TOWOLDMON0041925 WATER_PCB-00026394 P L A S T IC S - "RESINOX"* (Phenol Formaldehyde Molding Compounds,). Over period of years the range of Resinox molding material* has grown to encompass almost every important industrial demand. Shortages of metals and the extremely exacting requirement* of the nation's armed forces have stimulated the development of new types of Resinox materials having particularly high impact atrengthe. Since fillers vary (be properties of Resinox, the following table gives the range attained by the moat common fillers of wood flour, cut fabric, cotton flock, mica and asbestos. Molding quality...................................... ........................... Fair-excellent Compression molding temperature, "F........................ 290 400 Compression molding pressure, Ibs./sq.in......... 2000 4500 Compression ratio (bulk factor).....................................2.02 10.0 Mold shrinkage, inches per inch...................................... 004 .010 Specific gravity....................................................................1.34.1.75 Specific volume, cu. in./lb................................................13.3 22.2 Tensile strength, Ibs./sq. in.............................................. 4200 9500 Modulus of elasticity, Ibs./sq. in x 10*.......................8 45 Compressive strength, Ibs./sq.in.....................................20,000 35,000 Flexural strength Ibs./sq. in.............................................8,000 15,000 Impact strength, ft. Ibs./in. of notch, Izod (A.S.T.M.)............................................................... 0.26 4.00 Rockwell hardness.............................................................. M85 MI25 Thermal conductivity, 10--* cal./sec./#q.cm./*C./ cm................................................................................ 3 20 Specific beat, cal/C./gram . . .........................................0.25 0.36 Thermal expansion, 10-- */#C ....................................... 2.0 7.5 Resistance to heat F. (continuous)............................. 225 450 Softening point, *F................................................... .. None Distortion under heat F..................................... ............. 240 285 Tendency to cold flow....................................................... None Volume resistivity, ohm-cms. (50% R. H. and 2S4C.).......................................10 -10** Dielectric strength, ebort time, volte/mi), in. thickness.......................................................250 500 Dielectric strength, step-by-etep, volts/mil, Y* in. thickness....................................................... 200 - 400 Dielectric constant, 60 cycle*......................................... 5-20 Dielectric constant, 10* cycles.......................................4-20 Dielectric constant, 10* cycle*....................................... 4.5 20 Power factor 60 cycles....................................................... 0. 04- 0.30 Power factor 10* cycle*.....................................................0.04 0.20 Power factor 10* cycle*.....................................................0.005 0.10 Water absorption, immersion 48 hour* (%)..............0. 01 1.5 Burning rate......................................................................... Very low Effect of age.......................................................................... None Effect of sunlight.................................................................Light shades discolor Effect of weak acids............................................................None to slight Effect of strong acids......................................................... Decomposed by oxidising acids Effect of weak alkali*.......................................................Slight to marked Effect of strong alkalis.................................................... Decomposes Effect of organic solvents................................................. None on bleed-proof materials (Continued) Page 102 MONSANTO CBKM1CAIS 06B36V2 TOWOLDMON0041926 WATER_PCB-00026395 P L A S T IC S Machining qualities............................................................Fair Color range............................................................................Limited Available Literature: 12-page booklet "Resinoa--A Monsanto Plastic." Trade Mark Reg. U. S. Pat. Off. "SAFLEX"* (Luminating Plastic) Saflrx is a polyvinyl acetal sheet plastic used as the interlayer in making "HiTest" laminated safety glass. The Saflex plastic sheet, .01$ gauge, acts as the bonding agent holding the two sheets of glass firmly together and prevents scattering of the glass in case one or both surfaces of the glass are broken. The tough, elastic Saflex interlayer gives full protection at all temperature ranges encountered in winter or summer driv ing. For military vehicles and aircraft, multiple-layer laminations of Saflex and glass give protection against small-caliber bullets, bomb or shell fragments and flying debris. Trade Mark Reg. U. S. Pat. Off "VUELITE'** (Embossed Fluorescent Lighting Shields)_____ . Vuelite is tbe trade name for embossed cellulose acetate, developed by Monsanto to serve as diffusing panels for flucicescent lighting fixtures. Clare and brightness are eliminated by a suitable design that spreads tbe light evenly. Tbe excellent light transiaission factor of tbe material assures highly efficient light distribution. Although a fluorescent fixture my be large in size, tbe addition of a Vuelite diffusing panel adds very little to its weight thereby allowing tbe design of a low- weight fixture. Tbe danger of breakage of Vuelite as compared with glass of tbe same size is very small. Vuelite is easily formed to shape Fixtures that require more than a six-inch radius are fitted with diffusing panels by slipping flat eheeta into position. Smaller sites and intricata shspea are formed without expensive molds or tools while punching, drilling aod cutting operations are carried out with ordinary tools. Vuelite sheets are 20'x SO' in size, available in the following designs; Number 4B 6B 8B 9B SOB 27B 42 B 44B Name "H" Lina Whipcord Silk Cobra Large Cuba Mesh Axtee Glow Word Limiting Csuge Not tinder ,o;so' .040' ,osor .0$0' .050' .oso* .040' .040' ('Continued) Direction of Sise Design 20x47 Lengthwise 20x47 Lengthwise 20x49 Lengthwise 20x47 Lengthwise 20x47 Both ways 20x49 Lengthwise 20x49 Crosswise 20x49 Lengthwise 26TB BDITION P.g 0683843 TOWOLDMON0041927 WATER_PCB-00026396 P L A S T IC S 54B 55 B 65B Sahara No. 5174 Large Crackle .050' .050' .040' Trade Mark Reg. 1`. S. Pat. Off. 20x47 20x47 20x49 Boih nays Both ways Both ways ``VUEPAK"* (Rigid Transparent Packaging Material) Vuepak is produced as a clear transparent sheet plastic in continuous length rolls 3Mo inches wide. It is extensively used in the manufacture of durable rigid transparent containers, packages and displays for all types of consumer goods products. Originally- used chiefly for luxury items. Vuepak container* have now become a successful packaging medium for food products, candies, household appliances, beverages nd dry bulk products of all tvpes. An im* portant contributing factor to the broader use of Vuepak containers has been the improved efficiency of fabricating equipment and techniques in the plants of the more than two hundred firms now established as Vuepak fabricators. The properties of Vuepak are covered by the properties of Fibestos cellulose acetate materials in the preceding table. Standard gauges of Vuepak are .005', .0075', .010*. .0125'. .015' and .020'. In addition to continuous length rolls, Vuepak is sold in standard size sheets or in pieces cut to order. Vuepak can be drawn, scored, beaded, folded or stitched. With suitable inka the surface of Vuepak can be readily piinted in one or more colors. For special requirements Vuepak containers can be made witb metal bottoms and lids or in combinations witb box-board, paper, wire frames or wood. `Trade Mark Reg. L\ S. Pat. Off. POLYSTYRENE (See Plastics, Lustron). POLYVINYL ACETAL SHIIET (See Plastics, Salfei). POTASSIUM AMMONIUM PHOSPHATE (Also known as potassium ammonium phosphate; ammonium potassium phos phate.) KNHtHtfPOt), Mol. Wt. 251.128 Standard Forms White crystals. Grade i Technical crystals. Page 104 (CotMnued) MONSANTO CHEMICALS 06838VV TOWOLDMON0041928 WATER_PCB-00026397 R.R. ClaBsification: Potassium 5alt NOIBN. General Information: Used in pharmaceutical products for special medicinal purposes, and in the fermentatim of \*ines. POTASSIUM AMYL XANTHATE It.It. Classifiestion: Potassium \amhate. (.oiieral Information: Flotation agent used principally in the mining industry. POTASSIUM ETHYL XANTHATE R.R. Classification: Potassium Xantbate. (General Information: Flotation agent used principally in the mining industry. POTASSIUM GLYCEROPHOSPHATE (75% SOLUTION) (See Glycerophosphates). POTASSIUM PHOSPHATE, DI _ KjHPO, Mol. Wt. 171.18 Standard Form: 60% solution in water. Typical Analysis: Bluish, odorless liquid: sp.g. 1.7 at 25C.: 14.6 lbs. per gal.: pH 9.9 10.3: viscosity 33 centipoises at 25C.; water solubility 71 grams per 100 gms. solution. H.R. Classification t Chemicals, NOIBN. General [nformationt Used as an antistatic agent for wool and in fermentation and nutrient solution!. POTASSIUM PHOSPHATE, MONO_________________ (Also known as potassium diphosphate and potassium biphotphate). KHjPO, Mol. Wt. 136.09 Standard Form: White crystals. Gradesi Technical containing about 0.50% SOj; sulfate-free containing about 0.01% SO,. {Continued) 26TB coition Page 105 0663845 TOWOLDMON0041929 WATER_PCB-00026398 K.R. Classificationt Potassium Sails. General Information: Used to control pH of culture media and for special medicinal purposes. POTASSIUM PYROPHOSPHATE, TETRA k4p2o, Mol. Wi. 330.34 Properties: White powder, hygroscopic in air: pH value in 1% solution at 25'< 10.6: solubility, 190 grams in 100 gr*ms water at 25C. R.lt. Classification: Cleaning Com|<ound. General Information: Used for incorporation in textile oils and soaps to increase emulsifying values and to prevent formation of insoluble bard water soaps: as clarifying agent and to improve cleansing action of soaps. POTASSIUM SALICYLATE (See Salicylates). n-PROPYL PHOSPHORIC ACID (See Alkyl Phosphoric Acids). PYRIDINE, pure waterwhite liquid; used as a solvent and chemical reagent; as a denaturaDt for alcohol, and in special medicinals; made by Monsanto Chem* irala Limited. PYROXYLIN CEMENTS (Se< Celluloid Cements and Belt Cements). PYROCATECHOL__________ _______________________________ (Also known as brenzcatechin, catechol or 1, 2*dihydroxy benzene). OH Mol. Wt. 114.1 Specifications: Fine white needles (may contain a few dark specks); assay, 99.5% min.: odor, practically none; crystallizing point, 104.08C. min. Solution in cold water, (1:10): color, APHA 40, max.; turbidity, essentially clear. Solution in alcohol (1:10): color, APHA 40, mac. K.R. Clasaificatlont Chemicals NOIBN. General Information: Used as a developer in fur dyes, antioxidant in printing inks, and as intermediate in chemical synthesis. Page 106 MONSANTO CHBMIC4LS 06638^6 TOWOLDMON0041930 WATER_PCB-00026399 "R-2" CRYSTALS (See Accelerators, Rubber). REODORANTS, RUBBER Monsanto provides, but does not manufacture, the following types of rubber reodorants for the convenience of its customers. Curodex No. 19--Pale yellow liquid; deodorizes: percent used in 100 lbs. of rubber, 0.15 - 0.20; standard package, 5 lb. bottle. Curodex No. 188--Pale yellow liquid: odor, lily; percent used in 100 lbs. of rubber, 0.20 0.50; standard package, 5 lb. bottle. Curodex No. 19B--Pale yellow liquid; odor, musk; percent used in 100 lbs. of rubber, 0.20 0.50; standard package, 5 lb. bottle. RESINS (See Santolites and Plastics). "RESINOX" (SeeunderPlaat.es). RUBBER LACQUERS (See Lacquers). "SACCHARIN MONSANTO" Saccharin Monsanto is available in the so-called insoluble form (complies with L.S.P. requirements for Saccharin) and in the soluble or sodium form (complies will) L.S.P. requirements for Saccharin, Sodium). Descriptions of both forms are given below. SACCHARIN, U.S.P________ _________________________________________________ (Also known as ssccbarin insoluble; ortho sulfobenzimide). f\-c^ IJ-S^ NH V 0, Standard Form i Powder Mol. Wt. 183.11 Specifications! White crystalline powder: assay 98% min.; m.p. 227.0C. ruin,; loss of drying 0.50% max., solubility in 10% NajCOj(l:5) complete. R.R. Classificationi Chemicals NOIBN. General Information! Saccharin has approximately 500 times the sweetening power of sugar. Used as a sweetener in tooth pastes, mouth washes, and phar maceutical preparations, and in beverages and foodstuffs in place of sugar for diabetics. 2f.TR EDITION Page 107 06838*7 TOWOLDMON0041931 WATER_PCB-00026400 SACCHARIN. SODIUM, U.S.P._________________ (Also known as soluble saccharin; sodium ortho-,ulfobenzimide). <v O C>,s>.'\a.2HtO Mol, Wt. 241.13 Oj Standard Format Crystals; powder. Specificationst White crystals or j-owder; solubility in water (1:8), complete. Loss on drving at I2SC.: crystals U.0% min. --14.35% max.; powder. S.3% min. -5.8% max. H.H. Classification Chemicals NOIBN. General Information! See under Saccharin, U.S.P. ''SAFLEX" (See Plastics). SALICYLATE, AMMONIUM - COONH* 0OH Mol, Wt. 135.08 Standard Formt Powder, 80 mesh, Specifications! White crystalline powder; assay, 98.0% min.; solubility in wsier (1:5), complete, colorless; solubility in ethyl alcohol 95% (1:15), complete; cod* forms to N. F. test for heavy metale. No powder retained on 80 meeb screen. R.R. Classification! Chemicals NOIBN. General Information! Pharmaceutical product. SALICYLATE, CALCIUM __________________________________ Mol. Wt. 314.16 Standard Fortni Powder. Speciflcationai Fine white powder; solubility in water (1:50), complete, colorless; free salicylic acid. 0.25% max.; conforms to U.S.P. test for heavy metals. R.R. Classification! Chemicals NOIBN. General Information! Pharmaceutical product. Page 108 MONSANTO CHEMICALS 06838,6 TOWOLDMON0041932 WATER_PCB-00026401 Pilot plant operation at St. Louis plant. SALICYLATE, LITHIUM, N.F. COO Li Oil Mol. Wt. 143.98 Standard Form i Powder. Specifications! White or slightly grayish powder: assay 98.5% min.; solubility in water (1:20), complete, colorless; conforms to N.F. test (or heavy metal*. R.R. Classification! Chemicals NOI8N. General Information! Pharmaceutkal product. SALICYLATE, MAGNESIUM COO 0 Mg OH - ------12 Mol. Wt. 298.54 Standard Form j Powder. Specifications! Fine while powder; solubility in water (1:10), complete; con forms to U.S.P. lest for heavy metal*. R.R. Classification! Chemicals NOIBN. Ceneral Information! Pharmaceutical product. 2CTH BDITIOl Page 109 0663849 TOWOLDMON0041933 WATER_PCB-00026402 SALICYLATE, METHYL, U.S.P. COOCHi OH Mol. Wt. 152.lt Standard Form: Liquid. Specification*) Clear, colorlee* liquid, assay 98.0% min.; solubility in 70%ethyl alcohol (1:7). complete; solubility in N KOH (1:10), complete; ap. g. 25/2SC., 1.180 1.185; free phenols, 0,010% max.; conforms to U.S.P. test for heavy metals. It.R. Classification) Oil of Wintergreen. General Information) Used as a pharmaceutical product, as a flavoring agent in foodstuffs and beverages, ami as an odorant in printing inks and insecticides SALICYLATE, PHENYL, U.S.P. (Salol) Mol. Wt. 214.21 Standard Forms: Crystals; powder, 80-mesh. Specifications) While crystals or powder; solubility in ethyl alcohol 95% (1:6), complete; m.p. 41.0C. min.; conform) to U.S.P. tests for chloride, sulfate, free acid, free phenol, and free salicylic acid. 1.0% max. retained on 80 mesh screen. R.R. Classification) Chemicals NOIRN. General Information) Pharmaceutical product. SALICYLATE, POTASSIUM. ( \ COOK JoH Mol. Wt. 176.21 Standard Formt Powder. Specification*) White or very slightly pinkish powder; assay (dry basis), 99.0% min.; solubility in water (1:10), complete; conforms to U.S.P. test for heavy metals; free alkali, negative. K.R. Classification) Chemicals NOIRN. General Information: Pharmaceutical product. Page 110 MONSANTO CHEMICALS 0683BS0 TOWOLDMON0041934 WATER_PCB-00026403 SALICYLATE, SODIUM, U.S.P. 0 COON* OH Mol. Wt. 160.11 Standard Format Powder, crystals. Specifications! White powder or crystals; assay (as received) 99.5% min.! Riilnbility in water (10:100), complete, APHA 15 max.; solubility in ethyl alcohol 95% (1:10), complete, colorless; conforms to U.S.P. tests for heavy metals and rarhonizahle impurities; trace max- powder retained on 60 mesh screen, 1.0% on 80 mesh screen, 2.0% on 100 inesb screen. R.R. Classification t Sodium Salts. General Information! Pharmaceutical product. SALICYLATE STRONTIUM, N.F.-_____ Mol. Wt. 397.74 Standard Form: Powder. Specificationst White crystalline powder; assay (as dihydrate), 99.0% min.; solution in water (1:20), complete; conforms to N.F. test (or heavy metal* and barium. R.R. Clasaifications Chemicals NOFBN. SALICYLIC ACID, (Ortho-Hydroxybenzoic Acid). Mol. Wt. 138.05 Gradest U.S.P. and "B" Grade. Specifications of U.S.P. Grade; White needles or powder. 100*meah; assay 99.5% min.; m.p. 158,0eC. min.; conforms to U.S.P. test lor carbomzsble sub* stances; ash 0.05% max.; powder trace, max. retained on 100-mesb screen. Specifications of "B" Gradei White needles; assay 98.75% min.: m.p. 158.0C. at start. (Continued) 26TB COITION Page 111 0683851 TOWOLDMON0041935 WATER_PCB-00026404 H.R. Classification: Salicylic Acid. Ceneral Information: l sed in the manufacture of medicinals and dvestuffs, * an industrial preservative and as an intermediate in many organic syntheses. SALOL (See Salicylate, Phenyl). SALT CAKE (Sodium Sulfate, Technical) . Na,S04 Typical Analyaist 94 95% Na*SO< available. K.R. Classification< Salt Cake. Ceneral Information: Used in (he manufacture of sulfate pulp, glass, sodium Mtlfule, and (or treatment of boilei feedwaters. "SANTAMINE1 Cbaracteristicsi White powder, readily soluble in water, will not decompose on standing if kept in clean dry place. R.R. Classification: Disinfectant Other Than Medicinal NOIBN. Ceneral Information: Santamme is a sterilizing and deodorizing agent de veloped especially for the dairy industry, where it is used in water solution for washing utensils, equipment and bottles as well as the udders and teata of the cows. It also (mdi use in other industries where ao efficient chemical sterilizing agent is required. It contains no poison or acid and will not harm rubber or metal. "SANT1CIZER 8"__________________________________________ (Mixture of ortho and para-toluene ethyl sulfonamides). OH HI O-- S--N- CiH, II O Mol. Wt. 199.2(5 Specifications: Light yellow, viscous liquid; odor, slight, characteristic; free amide, 9% to 13%; acidity (as acetic acid) 0.1% max. K.R. Classificationi Lacquer Solvents NOIBN. General Information! This plasticizer is readily miscible with all common organic solvents except the petroleum hydrocarbons in whirb it is only very 'Continued) Page 112 MONSANTO CHEMICALS 0683652 TOWOLDMON0041936 WATER_PCB-00026405 elightlv soluble. It is soluble in castor oil. slightly soluble in china wood oil and insoluble in linseed oil. In water it is soluble to ihe extent of about 0.13% at 23C. and 0.21% at 48C. Its solubility in water is decreased by the presence of ammonia but is increased by other alkalies. Its retentivity in acetyl cellulose is about 90 parts by weight to 100 of acetate, and it imparts a high degree of plasticity. It is a solvent for both nitrocellulose and acetyl cellulose. Santicizer ti is an excellent plasticizer for cellulose acetate, giving a brilliance and polish not obtainable with other plasticisers. This product, being practically insoluble in petroleum hydrocarbons, is a valuable plasticiser for coatings designed to withstand gasoline and related products. Santicizer 8 has some plasticizing action on such protein compounds as casein, glue, soybean protein and corn protein. It may be used alone or in conjunction with other materials such as glycerine or similar compounds. Santicizer 8 greatly increases the flexibility of khellac, having at the same time a considerable softening effect. Available Literatures fO-page booklet, "Plasticizers and Resins". "SANTICIZER 9"_______________ (Mixture of ortho and para-tolueaesulfonamides) OH HI O-S-N-H O Mol. Wt. 171.16 Specifications: Fine granular particles; m. p. 105C. min.; melt, clear and light vellow; aciditv, pH 4.6 win. in dilute acetone (2 gram sample in IS cc A. R. Acetone and 35 cc of CO] free distilled water). H.R. Classificationi Lacquer Solvent IS'OIBN. General Information: Solubility of this plasticizer is quite low in coal-tar hydrocarbons and negligible in p<troleum hydrocarbons. It is readily soluble in most other solvents, and in hot linseed, china wood, and caster oils. It is soluble in water to the extent of only about 1.0% at 34C., but this is increased by the presence of alkali. It is the least soluble of the Monsanto plasticizers in ethylene dichloride and in benzene, its solubility in ethylene dicbloride being about 4% at 30C. and in benzene about 1.5% at 30C. Santicizer 9 differs greatly from other plasticizers in its action. Relatively small amounts impart a glosa to polished articles and give smooth working and uniform curing of molded products. It blends readily with most synthetic resins and does not impart the aofiening action of liquid plasticizers. It is particularly valuable to the makers of molding compositions. In some phenol-aldehyde resins it appears to act not only as a lubricant but also as a promoter, giving more uniform and thorough curing. In amounts of about 20 parts per 100, it has a temporary plasticizing action on protein compounds such as com protein and soybean protein. Available Literature: 40-page booklet, "Plasticizers and Resins". 26TH EDITION Page 113 0683053 TOWOLDMON0041937 WATER_PCB-00026406 "SANTICIZER E-15" (Ethyl Phthalyl Ethyl Clycollate)_____ 00 --O --C,H, O Mol. Vt. 280.13 Specifications* Color, (APRA), 20 max.; sp. g. at 25'72S,C,, 1.1800.0O5; irfrac. index at 2SC., 1.4980.002; acidity (as acetic acid) 0.02% max.; odor, alight; sulfur (copper strip test), negative. R.K. Classificationi Lacquer Solvei t NOIBN. General Information; This plastkizer is miscible with the common organic solvents except the petroleum hydrocarbons. It is miscible with vegetable oils when heated but partially separates oii cooling. Its solubility in water is 0.0175% at 30CC. Santicizer E-15 is a solvent for both nitrocellulose and acetyl cellulose rid for most resins. It is lightest, and does not evaporate even from the thin* nest films. With both acetyl 8nd nitrocellulose it gives clear, tough, flexible films which have greatly increased resistance to moisture penetration. It is highly recommended for use with cellulose acetate and vinyl resins. Available Literature: 40-page booklet, "Plasticizers and Resins". "SANTICIZER B-16" (Butyl Phthalyl Butyl Clycollate)_____ OO II II 0 -- c-o--CH,-C-0--C,H -C-0-C,H, II O Mol. Wt. 336.19 Specifications: Color (APHA), 45 max.; sp. g. at 25V25C., 1.0970.005; refrac. index at 25C., 1.490 0.002; acidity (as acetic acid) 0,02% max.; odor, essentially odorless; sulfur (copper strip test), negative. R.R. Classification i Lacquer Solveni NOIBN, General Information! Santicizer B-16 is a practically colorless liquid plastic izer which boils at 219C. at 5 mm. a(td does not crystallize at temperatures as low as --35C. Its water solubility it> 0.0012% at 30C. It is extremely lightstable. It darkens upon heating above 290,C. Sancticizer B-16 is a solvent for nitrocellulose and is compatible with most resins, imparting good flexibility. It probably embodies more desirable properties (Continued) Page 114 MONSANTO CHBMICALS 068365*1 TOWOLDMON0041938 WATER_PCB-00026407 than any other single nitrocellulose plasticizers, fire retarding action being about the only property it does not have. Santicizer B-16 is a solvent for and imparts plasticity to many resins both synthetic and natural. It has especially interesting properties when used with resins of the glycerol-pbthaiate and phenol-aldehyde tvpes in which is may be incorporated at various stages of resin formation. It is miscible with castor, linseed and china wood oils and somewhat retards gel formation in the latter on healing, it swells crepe rubber but appears to have no effect on vulcanized rubber. It is an excellent plasticizer for chlorinated rubber, from 10 to 25 parts per 100 usually being required. It is an exceptionally good plasticizer for polystyrene. Mixtures of Santicizer B-16 and Santoiite resins may he used to plasticize casein and coi'o protein. Vtailable Literature: 40-page booklet, "Plasticizers and Resins". "SANTICIZER M-17" (Methyl Phthalyl Ethyl Glycollate) _ OO o Specifications: Color, (APHA) JO max.; sp. g. at 25/25C., 1.2200.005; refrac. index at 25C., 1.5040.0011; acidity (as acetic acid) 0.02% max.; odor, slight characteristic; sulfur (coppet strip test), negative. K.R. Classificationt Lacquer Solvent NOIBN. General Information! Santicizer M-17 is a solvent for both nitrocellulose and acetyl cellulose. It imparts a bigb degree of plasticity which is maintained un. dimished even in extremely thin films exposed to air currents for a long time. It is very light stable and may be used in transparent or tinted articles without danger of yellowing. This product is not miscible with castor, linseed, or china wood oils or with petroleum hydrocarbons hut is readily miscible with other organic advents. Its solubility in water is 0.09% at 30C. but it imparts a con siderable degree of resistance to moisture penetration to both nitrocellulose and acetyl cellulose films. Santicizer M-17 is probably the best cellulose acetate plasticizer available, It dissolves Santoiite resins, and as both are very resistant to petroleum products and compatible with so many film-forming materials, they make an excellent combination for producing gasoline resistant coatings. Available Literature: 40 page booklet, "Plasticizers and Resins". "SANTICIZER 127" (Butyl Benzene Sulfonamide). 0H II I 0 26TB EDITION Continued) Page 1 IS 0683655 TOWOLDMON0041939 WATER_PCB-00026408 Characteristic*: Essentially colorless, oily liquid; crystallizing point --20C. (approx.); sp. g. 1.146 at 253/25C ; rcfrac. index 1.522 at 25C. K.R. ClassiQcationt Lacquer Solvents NOIBN. General Information! This plasticizer is almost identical in characteristics with Santicuer 8 for which it may be substituted in most formulations. It has slightly less solvent action, lower compatibility, and is less soluble in water (0.003% at 31C.). When used with small amounts of active solvent plasticizers it produces hard but flexible and tough compositions. ``S.ANTICIZER 128" (Ethyl Benzene Sulfonamide)__________ O FI il I O- S -N - C.H, O Mol. Wt. 185.25 Characteristics! White crystalline solid; m. p. 51.9C.; sp-g., 1.208 at 60C. R,K. Classifications! Lacquer Solvents NOIBN. General Information! The plasticiriog properties of this product are of the same general character as Sancticizer #. It has less compatibility and should not be used in amounts greater than 50 parts by weight to 100 parts of base plastic. Its chief value is as an auxiliary plasticizer to be used with others in order to extend the supplies of less av aiiable materials and at the same time impart the properties of gloss, workability, etc., < haracteristic of the sulfonamide plasticizers. "SANTICIZER 129" (Benzene Sulfonamide) . o o- u -S--NH* II 0 Mol. Wt. 157.18 Characteristics! White crystalline solid; crystallizing point 152C. R.R. Classification! Lacquer Solvents NOIBN. General Information! Santicuer 129 is similar in properties to Its toluene analog, Santicuer 9. The principal difference is a slightly lower compatibility with most plastic materials. See Benzene Sulfonamide Technical for um where color ia not a factor. "SANTOBRITE" (Sodium Peatachlorophenate Technical)___ Standard Format Powder; 1-oz. briquettes. (Continued) Page 116 MONSANTO CBKMICALS 0683856 TOWOLDMON0041940 WATER_PCB-00026409 Characteristics: Brownish gray powder; non-volatile at ordinary temperatures; practically odorless; non-bygro<opic under ordinary atmospheric conditions. Solubilities in water are: 4C. (395F.) 20.8% by weight; 25C. (77F.) 26,1% by weight; 35'C. (OS'F.) 28.0% by weight. Santobrite is a stable, relatively un reactive chemical and is not spent on organic matter. Its water solutions do not attack metals and under ordinaiv conditions do not decompose to form acid materials. It can be supplied as substantially neutral material containing from 0.2 to 0.6% free alkali or as a more alkaline product containing 3 4% alkali. Conversion to pemachlorphcnol o c'irs at pH's below 6.8. It.It. Classification: Agricultura Insecticide or Fungicide NOIBN. Ceuerul Information: A water'Soluble industrial preservative ami fungicide. Card for manufacture of termite-resistant cellulose insulating board and for ''ontrol of microbiological activity m paper, paperboard, leather, adhesives, latex and cold water paints; for control of sap stain in green lumber; and for control i>f slime and algae in water systems where the water is cot used for drinking or bathing. Santobrite and its solutions are irritating to the skins and mucous membranes of many individuals and are somewhat toxic to man and the higher animals. Fur detailed information on uses tod methods of handling, write for literature listed below. Available Literature: Technical Bulletin No. 0-1, "Santobrite for the Preservation of Adhesive*." Technical Bulletin i\o. 0-2, "Santobrite and Santopben 20 for Paint Preser vation." Technical Bulletin No. 0-5, "Santobrite for Microorganism Control in the Pulp and Paper Industry". Technical Bulletin No. 0-15, "Santobrite for the Control of Slime and Algae." Technical Bulletin No. 0-17, "Santobrite for the Preservation of Rubber Latex." Technical Bulletin No. 0-19, "Santobrite in the Tanning Industry." Technical Bulletin No. 0-22, "Santobrite--Methods of Handling and Applica tion." "Sap Stain Control by Monsanto" (24 page booklet). "Preservation of Cellulose Insulating Materials by Monsanto" (24 page booklet). "Instructions for Handling Santobrite." "SANTOCEL". Standard Form: Light weight port us solid. Properties! Santocel is silica gel from which the water baa been removed by a process wbicb does not destroy tbe original gel structure. Apparent density 7.5 lbs. per cubic foot; bulking value in liquid 17.1 lbs. per gal. Typical Analysis! 26TH EDITION SiO, Volatile Sodium Sulfate FeyOs and AljOj 90% 5.5% 3.5 1. (C'JOtinued) Page 117 0683857 TOWOLDMON0041 WATER_PCB-  Types: (1) Santocel 45, high oil absorbing. (2) Saniocei 58, low oil absorbing. (5) Santocel "O", designed lor use as a thermal insulator. All but Santocel "O'* are white and translucent. Crudest The three types are each available in two grades. Fine and All Size. Thru 60 80 100 200 APPROXIMATE MESH Fin* All Sixe On Thru On 20 mlC*h 71%%, 40 6% 60 12% 80 n% 100 9% 3 6 10 20 3 minesh ;2?0n .77% 6 20.7% 10 17.2% 20 14.7% 40 13.0% 200 28% 40 60 4.2% 27% 60 80 2.5% 100 7.0% R.R. Classificationt Insulating Material NOIBN. General Information t Santocel 4i> and Santocel 58 are used principally as (1) Flatting agents for paints, varnishes and lacquers. (2) Thickenin'/ :ents for volatile and non-volatile liquids; particularly useful in printing ink ;) Anti, caking agents. (4) Dry dispersing agent for pigments and dyestuffs. (5 ouree of highly reactive silica. (6) Stiffening agent in crepe rubber. Santocel ''O'* is designed for use as a thermal insulation material. "SANTOCHLOR" (para-Diohlorobenzene) (Also known as 1,4-dichlorobenzene) Cl Mol. Wt. 147.00 Cl Characteristics: White crystals; crystallizing point, 52.8C. min. Standard Crystal Sizes: No. 2. (large)--For shaker top cans. No. 5 (small)--For peach tree borers and for insecticide and miscellaneous No. 34 (medium)--A combination of two uniformly sized crystals. For shaker top cans and for compressing into cakes. K.R. Classification: Paradichlorobeuzene. General Information: Para-dichlorobenzene is used as an intermediate in the production of dyeituffa; as a deodorant; mothicide, larvacide, and in control of peach tree borers. (Coniinued) Page 118 MONSANTO CHEMICALS 0683858 TOWOLDMON0041942 WATER_PCB-00026411 Available Literature: 3 page Technical Bulletin No. 0*18, "Santochlor for the Control of Peach Tree and Stone Fruit Borer*." "SAN'TOCURE" (See under Accelerator*) 'SANTOFLEX B" (See under Antioxidants, Rubber), "SANTOFLEX BX" (See under Antioxidant*. Rubber). "SANTOLITE BA," almost identical in properties with Santolile MS, of which it is the benzene analog. -SANTOLITE BH," almost identical in properties with Saotolite MHP, nf which it is tbe benzene analog. "SANTOLITE BK " almost identical in properties with Santolite K, of which it is the benzene analog. "SANTOLITE BK5," almot identical in properties with Saotolite K5. of which it is tbe bentene analog. "SANTOLITE K" Specifications! Clear, light yellow sticky resin: color, not more than No. 2.5 by Monsanto Santolite K Standard (comparable in depth of color but not in shade to No. 5 of the Gardner 1933 standard): acid number, 10 max.; refractive index at 50C.. 1.5330 to 1.5390. R.R. Classification i Synthetic Resin. General Information: Saotolite K if a reainooa condensation product of tolueneaulfonamide, formaldehyde, and alkyd resins. It is a soft sticky resin with tbe qualities of both tbe sulfonamide and alkyd types. It is compatible with cellulose esters and ethers. Santolite K has plasticizing properties itself but for most purposes additional plasticiser is desirable and Santiciser M-17 ia recom* mended, although others may be used advantageously. Santolite K ia soluble in practically all common organic solvents except the petroleum hydrocarbons. It is not compatible with drying oil* so cannot be used in oil varnishes. Santolite K has a better light stability than the other Sentolites and is of special value for increasing the resistance to moisture penetration of cellulose ester compositions. Available Literature! 40-psge htoklet, "Platticizers and Resina." 2ATB 1D1TION Page 119 0663859 TOWOLDMON0041943 WATER_PCB-00026412 T "SANTOLITE KS". General Information: A modification >f Santolite K having (he same general characteristics except that it is harder. 'SA.NTOLITE MHP" specificationsi Hard, practically colorless resin: refractive index (25 grams in "> grams n.irmal Hntyl Acetate), (.1280 to 1.4310; penetration, (200 gram load for 5 seconds at 23C.) 2.0 mm. max. K.H. Classification! Synthetic hesin. General Information! Santolite MHP is an aryl sulfonamide-formaldehyde resin and is similar to Saniolite MS in characteristics, except that it is much harder, softening at about 62C. and being brittle at normal temperatures. It is nearly colorless and is well adapted to specialty lacquers, fabric coatings, molding compositions and. the (ike. Being incompatible with drying oils it cannot be used as a varnisb material. Exceptional features of this resin are the ease with whjrh it may be worked into practically any formula using a cellulose ester and the wide variation of properties obtained by its use. Its high degree of solubility makes very conceit* trated solutions possible, and its extreme compatibility with plasticizer* and cellulose esters removes much of the dangerof blushing, sweating and separation. Santolite MHP can be used in spraying, dipping or brushing lacquers to make clear, colorless, odorless coatings ofgood gloss and adhesion. It does not material ly increase the viscosity of the solution and permits the building up of a high solids content in the lacquer. It is compatible with all the common plasticizers. Available Literature! 40-page booklet, "Plasticizers and Resins". "SANTOLITE MS" Standard Formal Viscous Resin; Solution T.B. Specifications of Viscous Resin i Pale yellow viscous resin; solution in benzene (l :5), clear; solution in benzene (4:6), no crystalline depoait in 24 hr*.; refractive index at 50C., 1.5690 1.5720; color of benzene solution (25 gnu. in 50 cc.). APHA 70 maximum. Specifications of Solution TBs Light colored, viscous liquid, free Bowing at temperatures above SOX. Composition: 85% Santolite MS; 15% solvent (95% toluene and 5% butyl acetate), tolerance from 14 to 16% solvents; refractive index t 2SSC., I.S630.002. R.R. Classifications Synthetic Retin. General Informations Santolite MS is a soft, practically colorless resin made (Continued) Page 120 HOHStVTO CHKUICALS 683860 TOWOLDMON0041944 WATEFLPCB-00026413 by the condensation of formaldel-yde with aromatic sulfonamides. Like all the Santolites it is compatible with both nitrocellulose and acetyl cellulose and, being a solvent for both, it can b< used in any proportion. It forms brittle com* positions with both these esters but the addition of a piatticizer makes such combinations permanently flexible. It is readily miscible with all the common organic solvents and thinners except petroleum hydrocarbons. It is not miscible with varnish and paint oils. Santolite MS is excellent for water-white lacquers which will not be exposed to extreme weather conditions, its high gloss and lack of color being unusual in the resir field, Available Literature! 40-page b>oklet, "Plasticizers and Resins." "SANTOMASK" Specifications! Clear, light yellow liquid; faint vanilla-like odor; sp. g. at 25/25C., 1.04. 1.06. Additional Properties! Flash point, 210F, (by Cleveland open cap method); flow point, below 0C.; lbs. per gal., 8.7. (Continued) 26th edition Page 121 0683661 TOWOLDMON0041945 WATER_PCB-00026414 R.R. Classification: Chemicals NOIIiN. General Information) Odor-masking ingredient for interior paints, printing nks and similar products having objectionable natural odors. In addition to masking odors, may reduce or eliminate irritation to eyes, nose and throat caused by volatile components of some interior paints. Will not affect drying time, color durability and other characteristics of paints and inks. "SANTOMEKSE" Standard FormsJ The Santomerses are highly efficient surface active wetting agents and detergents. The Santomerse series consists of six products. Each is distinctive in character and has been developed to meet a certain industrial need. Suntomerse D--neutral powder. Santomerse S--30% aqueous solution of Santomerse D. Santomerse No, 1--neutral flakes. Santomerse No. 2--alkaline flakes. Santomerse No. 3--neutral powder. Santomerse No. 3--paste (75% Santomerse No. 3 in water). R.R. Classificationt Washing Compound NOIBN. General Information! The Santomerses are the salts of a homologous aeries of substituted aromatic sulfonic acids. They are used as wetting, spreading, pene trating, emulsifying agents and detergents in the following industries: textile, paper, leather, adhesive, rubber, insecticide, dust collection, soap, cosmetic, ceramic, detergent, metal cleaning, plating, emulsionB, dyes, pharmaceutical, embalming fluid, laundry, steel, paint, cement, glue, felt and color, etc. Available Literature! 32 page booklet 'Santomerse". . "SANTOPHEN 7" (ortho and para-Benzyl Phenol.)_________ Standard Form! Fused solid. Specifications! Light yellow, semi-crystalline mass: faint phenolic odor; sp. g., 1.088 - 1.098 (55C./55C.); refrac. index, 1.579 1.589 (S5C.); crystallising point, 40C. min. K.R. Classification: Agricultural Inseciicides. General Information) Santophen 7 is used us the active ingredient in disin fectants and antiseptic formulations; as an industrial preservative and as an enhancing agent for coal tar and creeylic acid disinfectants. It is higbly toxic to bacteria. CAUTION: This product is (oxic. Avoid contact with the skin, Available Literature! Monsanto Technical Bulletin 0-3, ''Santophen 7--A Germicide and Industrial Preservative." Page 122 MONSANTO CHEMICALS 0683862 TOWOLDMON0041946 WATER_PCB-00026415 "S.-VNTOPHEN 20" (Peutachlorophenol)_________________________ Characteristics: Dark grayish brown flakes; chlorphenolic odor: crystallizing point, I75M80C.; bulking value, 45.45 lbs. per cu. ft.; dispersible in soaps and sulfonaled oils. R.R. Classification: Agricultural Insecticides Other Than Liquid NOIBN. General Information: Sant<rphen 20 is highly toxic to fungi and many bac teria and is used industrially where such growths must be prevented or con* trolled. Frequently used in oil solution (See Permasan) or as the sodium salt (see Sanlobrite). SOLI BILITY DATA Solubilities e [pressed as percent Santophen o i weight of solution Water Pine Oil 95% Ethyl Alcohol (Ethanol) 100% Ethyl Alcohol Methyl Alcohol (Methanol) Or thodicblorbenzene Stoddard Solvent No. 9 Refined Oil Gas Oil Diesel Oil Carbitol Ethylene Glycol Diethylene Glycol Beutol Cellosolve Butyl Carbitol Dioxan Diethyl Ether li.S.P. Acetone U.S.P. Linseed Oil (Raw) Tung Oil Dipentene Turpentine Carbon Disulfide Carbon Tetrachloride Glycerin 0* c. 0.00049 24.5 39.0 46.0 40.5 5.5 0.4 0.3 1.9 8.0 34.S 20 C. 0.0014 32.0 47.5 53.0 57,0 8.5 1.5 1.1 2.4 3.1 30.0 6.0 27.5 11.0 27.0 48.0 11.5 52,9 21.5 13.9 11.2 8.4 3.0 3.0 2.0 40 C. 00025 39.0 56.5 60.0 72.0 15.5 3.5 2.5 5.2 5.7 51.0 21.0 62.0 19.5 50.0 62.0 22.0 60 C. 0.00S3 46.5 65.5 67.0 77.5 26.0 7.5 5.6 9.3 11.3 38.5 3LS 65.0 37.5 Santophen 20 and its solutions and formulations are irritating to the skin and mucous membranes and are ftomewbat toxic to man and the higher animals. Precautions suggested in "Instructions for Handling Santophen 20" should be observed. Available Literature: 3-page mimeographed bulletin "Santophen 20." Mimeographed bulletin "Instructions for Handling Santophen 20." 26TH EDITION Page 123 0663863 TOWOLDMON0041947 WATER_PCB-00026416 "SA-NTOPOID S". Standard Forms Oily, homogeneous liquid Specifications! Dark brown liquid; sp. g. 1.20 1.30; flash, (open cup method), 250F. min.; fire, (open cup method)' 290 * 300F. min.; pour, below --35F. viscosity, S.U. ui 100JF.. 134.5- 1 li1.5 seconds. It.lt. Classifications Chemicals NOIBN. General Informations Used up to 10% mixed with mineral oil to form extreme pressure lubricants for bypoid and other gears. "SANTOPOIR" Specificationss Gravity, 26.7A.P.l.; flash, 485F.; pour, 10F.; viscosity, S.U. at 210F., 156.4; carbon residue, 1.4; color, NPA (85 and 15), 6; neutralization number, 1.20. R.R. Classifications Petroleum Lubricating Oil. General Informations An improved pour point depressant for lubricating oils. Lowers tbe pour point of wax-bearin)' oils as much as 50F. Stable under extreme service conditions. Available Literatures Application Data Bulletin No. 120, "Santopour." "SANTOSITE" (Sodium Sulphite Anhydrous, Technical)____ Specificationss Tan to slightly pink crystalline powder; assay (NsjSOj) 93.0% min.; foreign odor, very faint, max.; solution, filtrate from a 10% solution in water is not darker than APHA 150 max, R.R. Classifications Sodium Sulphite Anhydrous, Technical. General Informations Used as a depressant in ore flotation and rubber, paper and cordage manufacture, and as a reducing agent for removing oxygen from boiler feed water. "SANTOTAN-KR" (Basic Chrome Sulfate) Contains approx. $0% of Crj(SO<)j(OH)i Standard Forms Crystals. Specifications! Dark green crystal*; solution in water (S:500), clear; baaicity (CrjOj/SOj), 101-105; basicity (Scborlemmer), 37.3%-39.7%; chromium as CrjOj, 23.9% min. (Continued) Page 124 Monsanto chbmicals 068386* TOWOLDMON0041948 WATER_PCB-00026417 R.R. Classifications Dry Tanning Extract NOIBX. General Information: Used in chrome tanning of calf, cow, and horse hides and sheepskins. Available Literature: 16 page booklet "Chemicals for the Tanning Industry." ``SANTOYAR A" (See under Antioxidants, Rubber). SA.NTOWAX, REGULAR______________________________ _ Standard Form: Yellow waxy solid. Properties: Roiling range: first drop, 365eC.; 80%, 402C. Freezing point: primary hold point, 140C.; secondary hold point, 56C. Apparent sp.g., 1-10 (approx.) at 2SC. Slightly soluble in alcohol and more soluble in benzene. R.R. Classification: Coal Tar Resin. General Information: Used in compounding polishes and waxes when a high melting wax is desirable. Also a plasticizer and resin. "SANTOWAX M" Standard Form: Yellow waxy solid. Properties: Micro-crystalline hydrocarbon wax of unsual stability toward heat: melting point, 83 85C.; flash point, 207C.; hardnesa (ASTM D-5-25) 250 gm. load, 0.23 mm. R.R. Classification: Coal Tar Resin. General Information i Used as an opacifier for paraffin candles and at a partial substitute for Carnauba wax. "SANTOWAX O" Properties: Oily, crystalline hydrocarbon; hold point, less than 50C.; flash point, 171C.; flame point, 193C. Hardnesa (ASTM D-5-25): 50 gm. load, 0.13 mm.; 150 gm. load, 0.40 mm.; 250 gm. load, 1.07 mm. R.R. Claaaification: Coal Tar Resin. General Information: Semisolid plasticizer for soft wax or resin compositions. 26TB EDITION Page 125 0683865 TOWOLDMON0041949 WATER_PCB-00026418 T "SANTOWAX PM Standard Forms Flaky crystals. Properties! Nearly white, crystalline high-melting hydrocarbon; first crystals, 209 2I3C.; flash point, 207C.: flame point. 238C.: hardness (ASTM D-5-25) 230 gm. load, 0.33 mm. It.K. Classification! Coal Tar Resna. General Information: Used to riise softening point and hardness of other w axes and resins. SODIUM ACETATE CHsCOONa CHjCOONa. 3H0 Mol. Wt. 82.02 Mol. Wt. 136.07 Standard Formsi Crystals, 60%, N. F.; anhydrous (not N.F.) Specifications of N.F. Gradei White crystals or granules; assay (as tribydrate), 99.5 104.0% solubility in ter (1:2), complete; alkalinity (as NajCOj), 0.025% max., conforms to N.F. te^t for heavy metals; no crystals retained on 10 mesh. Specifications of Anhydrous (not N.F.)t White or grayish crystalline ma terial; assay, 99.0% min.; solubility in water (1:2). complete; carbonate (as NajCOj), 0.5% max. K.R. Classification) Sodium Acetate. General Informations Used in tbt manufacture of dyestuffs as a condensing component and buffing agent in coupling reactions; in dyeing operations as a mordant; in the manufacture of pharmaceuticals; in the soap and tinning indus tries; and as photographic chemical. SODIUM ACID PYROPHOSPHATE (Also known as disodium dibydrogeo pyrophosphate and acid sodium pvrophospbate). NajHjPjOj Mol. Wt. 221.97 Gradest Food and commercial. Food grade meets all U, S. Pure Food Law requirements. Properties) White powder, soluble in water and having min. neutralizing value of 74; pH of 1% solution, 4.2. (Continued) Page 126 Monsanto chimicals 0683666 TOWOLDMON0041950 WATER_PCB-00026419 R.R. Classification: Sodium Phosphate. General Information: Used in oil well drilling muds and as a leavening agent in baking powder and flour. SODIUM ALUMINATE NaAUO, Mol. Wt. 164.2 Standard Form: White soluble powder; contains 90% soluble sodium aluminate. Properties: Readily soluble in water and extremely low in iron and insoluble material. Stable for at least 24 hours in 10% solution* although contains a max. of only 5% free caustic soda. R.R. Classification: Sodium Aluminate. General Information: Used in papermaking: With aluminum sulfate for airing at higher pH's. Also to help se| color and filler and to improve paper formation. In treatment of municipal and industrial water: With aluminum sulfate as a coagulant. In thelime>soda soft<ning process for silica removal and floe formation. Miscellaneous: As an alkaline source of alumina in tbe manufacture of certain pigments, catalysts and casein paints; in processing glycerin lyes; in chrome tanning; in cleaning solutions; to aid set of the frit in vitreous ensmeling. SODIUM AMMONIUM PHOSPHATE (Also known as microcosmic salt; sodium ammonium hydrogen phosphate; salt of phosphorus; phosphorous salt; fusible salt of urine.) NaNHHP0<.4H,0 Mol. Wt. 209.09 Standard Formi Crystals. Properties: Transparent, white, efflorescent, monoclinic crystals. Gives off water and ammonia on beating, leaving NaPOs: contains above 32% P,Oj. 7.5% NH) and 14% NajO. Grade: Commercial. R.R. Clasaificatiom Disodium Phosphate. Principal L'scai Used principally in analytical laboratories for standardizing uranium solution; determination of Mg and Mo; as reagent in blow pipe analysis. SODIUM BENZOATE. [ >COONs Mol. Wt. 144.11 26TB EDITION .Continued) Page 127 066366? TOWOLDMON0041951 WATER_PCB-00026420 Grades) U.S.P. and Technical. Specifications of U.S.P. Grade; 'Chin white flakes ot white powder, solubility in water (1.0:1.8 at 2SCIC.), complett; solubility in 90% ethyl alcohol (1:50), com plete; N/10 alkali or acid per 2 grain sample, 0.2 cc max.; pH 6.8 10.4; loss on drying at 110C., 0.50% man.; assay, 99.0% ruin.: chlorides (as NaCI), 0.05% mas.; organic chlorine, none; sulfates (as NajSO*), 0.05% mas.; oitro compounds, none. Specifications nf Technical Grade: White or slightly tinted powder; assav, 99.0% min. (dry basis): solution in * a ter (1:1.8), essentially complete but slight jv inferior to U.S.P. quality: chlorides (as NaCI), 0.6% mar.; sulfates (as Na^O^. 0.6% max.: phthalic acid. 0.1% mat.; heavy metals, none. R.R. Classification i Pood Preserving Compound, General Informations Used for preserving foods, tobacco and medicinal pre parations. SODIUM BISULFATE (See Nitre Cake). SODIUM BISULFITE Standard Formsi Liquid--33s B4. coniaining approx. 21% SO}; wt. per gal., 10.78 lbs. Anhydrous (Sodium Metabisulfite)--66% SO] (approx.) Typical Analysis) SO, NajSO* Fe Liquid 21.5% S.00 .006 Anhydrous 66% l.S .002 R.R. Classification) Sodium Bisulfite Dry or Sodium Bisulfite Liquid. General Information! Used in dy< manufacture.as source of SO, for reducing sodium bichromate to basie chrome ^ulphate in tanning, bleaching of vegetable tan extracts, production of hydrosulfite for vat dyeing, antichlor in bleaching of groundwool, bleaching dyes out of wo:>den coloring drums used for dyeing leather, antichlor in pulp bleaching, antichlor in laundries, bleaching of straw, rabbit fur, sugar syrups, glue, glucose. (See table in general data section) SODIUM FERRIC PYROPHOSPHATE NsjFe.fPjO})* . XHjO Properties) A finely subdivided powder, insoluble in water, soluble in hydro* chloric acid; contains min. of 15.5% Ton. General Informations Used in food fortification as a mineral supplement. Page 128 IONSANTO CHEMICALS 0683668 TOWOLDMON0041952 WATER_PCB-00026421 SODILM GLYCEROPHOSPHATE (See Glycerophosphate*). SODIUM HYDROXIDE (See Caustic Soda). SODIUM HYPOCHLORITE (See Merclor). SODIUM PENTACHLOKOPHENATE (See Ssntobrite). SODIUM PHOSPHATE, DI_ (Also known as phosphate of soc'a; sodium phosphate di.basic; secondary sodium phosphate; exsiccated sodium phosphate). NajHPO* Mol. Wt. 141.982 Properties! Soluble in water, insoluble in alcohol. On exposure to air will absorb 2 to 7 mola HjO depending on humidity and temperature. Loses molecular water at 240C. forming tetrasodium pyrophosphate. pH of 1% solution at 25C.. 8.8. Onelb.anhydrousproduct ieequivaient to 2-5 lbs. of crystalline (dodecahydrate)* Gradest Technical, Food (Regvlar, Granular, Powdered), Medicinal, I'.S.P. R.R. Classification: Disodium Phosphate. General Information! Used in making glazes for potteries, porcelains and china ware; as an emulsifier in iqalcing process cheese; in various chemical pro. cesses; in manufacture of dyestuffs such as Schnitzler's green; in the preparation of enamels; in tinning and soldering; in leather tanning; as a bath ingredient in galvanoplastic work; in the manufacture of pigments such as cobalt phosphate; in the weighting of ailk and impregnating of textiles in dyeing and calico printing; in the adjustment of condensed milk; conditioning boiler water; medicinal. otNSirr of *0OSOOt</M PHQSPHAre SOLUTIONS 0683S69 TOWOLDMON0041953 WATER_PCB-00026422 SODIUM PHOSPHATE, MONO (Also known as sodium phosphate, monobasic; sodium dihydrogen phosphate; sodium biphosphate; monosodium ortho phosphate; acid sodium phosphate.) NalJjPO, Standard Forms White powder. Mol. Wt. 119.993 Proprrtiesi Contains not less (ban l8% PjOj; pH value of 1% solution, 4.5. tirades: Food: commercial. ICIG Classifications Sodium Phosphate. General Information: Used for conditioning boiler water and in electroplating. 0683670 TOWOLDMON0041954 WATER_PCB-00026423 SODIUM PHOSPHATE, TRI ( Vlso knov.li as normal sodium phosphate; Bodium phosphate, tri-basic; tertiary sodium phosphate; T.S.P.) NajPOj. 12H}0 Mol. Wt. 380.16 Specifications: 'Shite crystalline Material, uniformly sized: quickly soluble in water giving an alkaline reaction: pII value of 1% solution, 11.8. Ii.it. Classification: Trisodium Pnosphate. Genera! Information: Used principally in cleaners and detergents for both household and industrial use. Fruit Cleaning: To remove insecticide spravt and inhibit growth of fruit mold. Water Treatment: For softening and eonditionme water. SODIUM PHOSPHATE, TRI, MOMOHYDRATE NajPCVHjO Mol. Wt. 181.99 Standard Forms White powder. Propcrtie:- Soluble in water: one lb. is equivalent in NajPO, content to 2.10 lbs. of trio, iin phosphate crystalline. Gradet Commercial. II.R. Classification! Trisodium Phosphate. Principal Uses: Used for the same purposes as crystalline T.S.P.; in the manu< facture of compounds containing caustic soda it permits the production of dry SODIUM POTASSIUM AMYL PHOSPHATE (Mixture of sodium and potassium salts of the amyl phosphoric acids). Standard Form: 60% solution in water. Properties: Straw colored liquid with slight Pentasol odor; sp. g. 1.339; wt. per gal. 11.2 lbs.; pH 7.0 7.3; slightly hygroscopic; anhydrous form gelatinous. 11.11. Classification: Chemicals N'MBN. General Information: Used as ingredient in vat printing pastes and as a spin* ning agent for wool. SODIUM PYROPHOSPHATE, TETRA (Also known as sodium pyrophosphate, pyrophosphate of soda, normal pyro* sodium phosphate, alkaline sodium pyrophosphate and TSPP.). Grades: Crystalline and Anhvdroui. Properties: White crystalline material and white granular or powder; pH value of 1% solution, 10.2. R.R. Classification! Sodium Phosphate. (l,on finned) 26TH edition Page 131 0683871 TOWOLDMON0041955 WATER_PCB-00026424 General Information! Used in bleaching, especially for straw, and as an ink eradicator; in manufacture of iroQ pyrophosphate and other pyrophosphates; household and industrial cleaner and detergent: in dye bath for putting certain types of dye in complete solution; electroplating; metal cleaning; electrolytic separation of various metals; oil drilling muds; as emulsifier in process cheese manufacture; soap builder; degumming textiles. SODIUM SALICYLATE (See Salicylates). SODIUM SULFATE, ANHYDROUS Xa*S04 Mol. Wt. 142.05 Typical Analysis! White granular crystals; 99% NaySOj available. For crude Sodium Sulfate, see Salt Cake. R.R. Classificationi Sodium Sulfate. General Information! Differs from (rlaubers salt only in sodium sulfate con tent, Glauber's salt contains 43% sodium sulfate and 56% water of crystalliza tion. Anhydrous sodium sulfate contains 99% sodium sulfate and no water of (Continued) Page 132 Monsanto chemicals 0663872 TOWOLDMON0041956 WATER_PCB-00026425 crystallisation. t- sed for diluting; dry dyestuffs and in tanning. Other use same js fur Glauber's salt. For crude Sodium Stilfate, see Salt Cake. SODIUM St'LFHYDRATE* NallS \lol. Wt. 56.06 Standard Form: 33! 2% NaHS, liquid. H.K. Classification) Sodium 5u fhydrate. General Information) Sodium Sulfbydrate is chemically similar to sodium sulfide. Where a sulfide with a lower caustic content is desirable Sodium Sulfhy. Irate may be used. The main application for Sodium Sulfbydrate is in dehairing leather where its lower caustic alkalinity makes it more desirable than sodium sulfide for certain leathers. A lower caustic alkalinity causes less swelling of the hide* or skins, thus producing leather with a finer, smoother grain. It can be said that Sodium Sulfbydrate affords a means of controlling plumping (swelling). I nlike sodium sulfide. Sodium Sulfbydrate will not dehair by itself. Lime must be used with it to give a sufficiently high pH for dehairing. * Not manufactured by us, but furnished for the convenience of our customers. SODIUM SULFIDE Standard Format Crystals (NajS.9HjO): concentrated--flakes.* (NajS.nHjO); liquid (20% JS'ajS solution). Typical Anal) sis t Crystals, 31% Na*S; concentrated,60-62% NajS; liquid, 20% Na,S. H R. Classification) Sodium Sulfide. General Information) Sodium Sulfide is a salt of the weak acid, hydrogen sulfide, and the strong alkali, caustic soda, and consequently its solutions are strongly alkaline. Reacts with mttal salts to form metal sulfides, nearly all of which are colored. Reacts with acids, precipitating sulfur and liberating hydrogen sulfide. Is a reducing agent, and solutions are ready solvents of sulfur to form polysulfidea. Principal use is in tanning, to remove hair from calfskins and cowhides, and from sheepskins from which the wool has already been removed. Other uses are in the manufacture and application of sulfur dyea, degumming of silk, deoitrat> ing of nitrocellulose rayon, sodium polysulfide solutions, leaching gold ore tailings, dissolving cresol* from coal tar oils, boiling out linen, and depositing mineral pigments on cotton. Not manufactured by ua but furnished for the convenience of our customers. SODIUM SULFITE (See Sai.tosite) SOLVENTS (See Etbyl, Butyl and Amyl Acetates, Diacetone Alcohol). 26TB EDITION PaSe 133 0683873 TOWOLDMON0041957 WATEFLPCB-00026 "SOPANOX" General Information: Sopaijox ia an amino compound, effective in minute quantities in restraining the oxidation of soap and the resulting rancidity, dig. coloration and other adverse qualities, all of which must be avoided in pro* ducing a product of highest grade. Our experience shows that Sopanox satisfies the exacting demands of manufacturers of soaps produced from animal or vege table oils, filled or unfilled. It is particularly valuable in preventing discoloration of refined toilet soaps. R.K. Classification: Chemicals !\OIBN. Available Literature: Technical bulletin "Sopanox.*' "SOPET" (Sodium Potassium Ethyl Phosphate Solution)____ Mixture of sodium and potassium salts of the ethyl phosphoric acids. Standard Form: 60% solution in water. Properties: Water white liquid with slight ester odor; 11.4 lb. pee gal.; sp. g. 1.37 at 25C.; pH 7.0 7.4 in 60% solution; viscosity, 128 centipoises at 25C. R.R. Classification: Chemicals NOIBN. General Information: Used as fiber lubricant in spinning of wool. Being water soluble* is easily removed from yarn or cloth without soap scouring. SPRAT LACQUERS (See Lacquers). SPREADING AGENTS (See Areskap, Aresket, Aresklene. Santomerse). STEEL PICKLING INHIBITORS (See Hibitite). STRONTIUM SALICYLATE N.F. (See Salicylate*). SULFANILAMIDE* U.S.P. (joora-Aminobenzene Sulfonamide) NH, Mol. Wt. 172.20 NHi Page 134 Standard Forms: Crystals, 30-mesh; powder, 100-mesh, (Continued) MONSANTO CHEMICALS 0683874 | TOWOLDMON0041958 WATER_PCB-00026427 Specifications; hile crystals or powder; assay (dry basis) 99.5% min.; m.p. 163.O^C. min.; solution in N/2HCI (2:30) clear; asb 0.05% max.; rhlorides (* IICI) 0.011% max.; sulfate (as EUSO<) 0.04% max.; conforms to [j.S.P. test for heavy metals. MESH: Retained on-- 30 mesh screen 40 mesh screen 60 mesh screen 80 mesh screen 100 mesh screen 1 M mesh screen 200 mesh screen 30-mesh Trace max. 40.0% min. 75.0% min. 90.0% min. It.K. Classification: Chemicals XOIBN. l00-mesft 0.8% max. 10.0% nunc. 25.0% max. 20.0% min. 40.0% max. General Information: I'sed in pharmaceutical preparations and veterinary medicines. CALTIOiV: SulfanilanUde should be administered only under super vision of a competent physician. " SULFATE OF IRON (See Ferric Sulfate and Ferrisul). SULFUR 09.5% pure sulfur. Grades: Commercial rubbermaker*. commercial flour, 90% through 80 mesh: dusting, 93*95% through 325 mesh. II.ft. Classification: Sulfur. General Information: Sulfur is a brilliant yellow crystalline substance, ap proximately twice as heavy as water and melting at about 248 F. This ready fusibility permits casting into various shapes. It is highly acid resisting and is a j>oor conductor of heat and electricity. It combines with rubber to form polysu It ides. Sulfur is used as a source of sulfur vapor for manufacture of carbon bisulfide and sublimed sulfur; as a source of sulfur dioxide for fumigation, bleaching and manufacture of sulfuric acid, sulfitv and bisulfite for paper manufacturing; in formation of sulfides and polysulfides for oil refining, vulcanization of rubber, smelting, and manufacture of calcium sulfide and sodium polysulfide; as sn acid-resistant bonding material (or brick-lined acid tanks; as a water-resistant material for water pipe joints: as a non-conductor for the manufacture of insu lators; as a fungicide; in manufacture of fireworks and railway signals; in grain mixtures for poultry; as a toil disinfectant. 2STH EDITION Pagc 135 06838J5 TOWOLDMON0041959 WATER_PCB-00026428 Converter* lifted in manufacture of sulfuric acid at Everett. Maas, plant. SULFURIC ACID IIjSO, Standard Strengths! 58 B6; 60 B6.; 66 Be.; 98% HjSO^; Oleum. Typical Analyslsi 58 B4t 74.36% HjSO*; freezing point, below --40F. GO 114.! 77.67% min. HjS0<; freezing point, -f-12.6 F. approx. 66' Be.: 93.2% min. HjSO<; freezing point, --29 F. approx. 98%: 98.0% min. HjSO<; freezing poirt, 38 F. approx. Oleum--20% SO3: 104.50% min. HjSO<; freezing point, 22.8F. 25% SO3: 105.6% min. H2504; freezingpoint, 48.7F. 33% SOj: 107.88% min. H2SO,; freezing point,83,5F. 40% SOj: 109.00% min. HjSO|j freezing point, 91.5*F. 65% S05: 114.6% II2S04; freezing point, 38.0 F. Oleum freezing point data based on Manufacturing Chemists Association curve. 1941 R.R. Classification! Sulfuric Acid. General Information! Used extensively in steel mills, enameling works, oil refineries, pigment works, by-product gas plants, fertilizer plants, tanneries, and many other industries. (See tables in general data section) Page 136 MONSANTO CHEMICALS 0683876 TOWOLDMON0041960 WATER_PCB-00026429 SULFURIC ACID C.P. HjSO* Mol. Vi. 98.07 Specification** Colorless liquid; may, 95.5 97.0%; non-volatile material. 0.0005% mat.; chloride (Cl), 0.00006% mat.; nitrate (NOj), 0.0002% mat.; ammonium (NH,), 0.0003% max.; SOj, 0.0005% max.; arsenic, 0.000003% max.: heavy metals (as Pb), 0.0005% max.; heavy metals (as Fe), 0.0001% max. R.R. Classification! Sulfuric \eid. Corrosive liquid (white label required). Central Informations Used as a laboratory reagent and where an extremely pure material is required. SULFURIC COISTACT CATALYST (See Vanadium Catalyst). SULFURYL CHLORIDE SOjCI, Mol. Wt. 134.97 Standard Forms Liquid. Characteristic*! Light yellow liquid (may deposit precipitate on standing); sp.g. 15.5"/15.5C., 1.67 1.71. Distilling range: first drop. 50.0C. min.; dry point, 70.0C.; 20% 100% range, 2.0C. max.; total condensation, 95% min. R.R. Classifications Chemicals NOIBN. Corrosive liquid (white label required). General Informations Used as a chlorinating and condensing agent. SYiSTANS (See Mertanol). TETRAPHOSPHORIC ACID (Phospholeum) Properties! Clear, water white viscous liquid; PjOj content 83 84%; does not crystallize at --50C. Sp. g.: 2.060 at 20C.; 1.983 at 100C.; 1.960 at 125C. R.R. Classificationt Phosphoric Acid. General Information i Used for Industrial applications where a high strength phosphoric acid is desired and as t drying agent. TETRAPOTASS1TJM PYROPHOSPHATE (See Potassium Pyrophos phate, Tetra). [Continued) 26th edition page 137 06836?? TOWOLDMON0041961 WATER_PCB-00026430 TETRASODIUM PYROPHOSPHATE (See Sodium Pyrophosphate, Tetra). TEXTILE LACQUERS____________________________________ General Information! Clear and pigmented for waterproofing garment fabrics, raincoats, shower curtains, duck and balloon cloth. Can be supplied in cellulose nitrate, acetate, aceto butyrate, ethyl cellulose, and chlorinated rubber base. \ [iplied by machine coating. K.K. Classification: Lacquers, TEXTILE PRINTING LACQUERS General Information! Pigmented lacquers for engraved roll and stencil prim, ing on finished fabrics, cotton, silk, celanese, rayon taffetas, crepes, and voiles. R.R. Classification! Lacquers. THINNERS General Information! Thinners are supplied for reducing all lacquer products to required viscosity for apraying, dipping, and machine coaling. Can be adjusted to meet special requirements for flow out, drying time, moisture resistance, and solvent power. Retarding thinners, cleaning thinners, stripping thinners, re movers, resins and dye solvents are also available. R.R. Classification! Lacquer Thinning Compound. THIOCARBANILIDE (See under Accelerators). THIOUREA____________________ ________________________________________ (Also known as tbiocarbamide, sulfoearbamide, and sulfourea.) NHj.CS.NH, Mol. Wt. 76.12 Standard Formi Crystals. Specification*! White, free-flowing crystals; moisture 0.50% max.; aah 0.05% max.; solution (10% water at 25C.) turbid. R.R, Classification! Chemcials NOIBN. General Information! Used as an intermediate in the production of dyestuffs and pharmaceuticals; in the manufacture of vulcanisation accelerators; as an (Continue/*'' Page 138 Monsanto cbbmicali 0663678 TOWOLDMON0041962 WATER_PCB-00026431 ingredient of insecticidal compjsitions; moth-proofing agent in treating fun. feathers, skins and fabrics; and as an intermediate in the production of resins and wanes. "THIURAD" (See Acceleraiors) TOLUENE ETHYL SULFONAMIDE (See Santicizer 8). porn-TOLl ENESULFONAMIDE (Also known as para-toluenesulfonic acid amide, para-sulfonamidotoluenr, and -l-suifonamido toluene.) 0 Mol. Wt. 171.21 SO,NH Standard Forms Crystalline powder Specifications! Light brownish, crystalline powder; crystallizing point (dried material) 13S.CTC. min.; ash 0.60% max.; alcohol Insoluble material, 0.60% maa.; loss on drying, 0.50% max. R.R. Classification! Chemicals NOIBN. General Information! Used as an intermediate in the production of active chlorine bearing compounds, as an intermediate in the production of dyestuffs, as a plasticizer, and as a base ip the production of plasticizers and resins. Also see Santicizer 9, a mixture of ortho and para*toluenesulfonatnides. parn-TOLUENESULFONCHLORIDE CHi Mol. Wt. 190.64 SOtCl Standard Formi Crystals Characteristicst White or yellowish crystals; assay, 95% min.; crystallizing point, 65.5'C. min. R.R. Classifications Chemicals NOIBN. General Informations Used as a condensing agent and an intermediate it dyestuff synthesis. 26TH EDITION Page 139 0683679 TOWOLDMON0041963 WATER_PCB-00026432 TOLIENESLLFONIC ACID, TECHNICAL OH, 0 Mol. Wt. 172.19 SOjH Standard Form: Fused crystalline mass. Characteristics: Brown to black .rygullme solid: toluenesulfonic acid. 85.0% min.; II,SO,, 8.0% max. Composiiion: approx. 85.0% para and 15.0% ortho; contains up to 14.0% water; may contain 1.0 - 2.0% toluene. K.R. Classification: Chemicals NOIBN. General Information: Used in tl<e manufacture of dyestuff intermediates and at a catalyst in certain organic reactions. TRICALCIUM PHOSPHATE (See Calcium Phosphate, Tri). TRICHLOROBENZENE, TECHNICAL ______________ Mixture of 1, 2. 3* and 1, 2, 4-tricblorobenrene Mol. Wt. 181.45 Standard Form: Liquid. Characteristics: Practically clear, colorless to light yellow liquid; ep.g. 1S.5*/15.5C., 1.469 1.477; acidity as HC1, 0.01% max.; crystallising point, IO.OC. max. Distilling range; first drop, 20S.O*C. min.; 50%. 213.0*0. min.; 90%, 216.0C. min.; dry point, 250.0*C. max. R.R. Classification: Tricblorobemene. General Information t Used in organic synthesis, as a solvent, and as an insect icide. TRICRESYL PHOSPHATE. Page 140 (Continued) MONSANTO CHI MIC A La 0683880 TOWOLDMON0041964 WATER_PCB-00026433 Specification#; Clear practically colorless liquid; sp. g. at 20/20aC., 1.1620.005; acidity (as HjPO<) 0.01% mat. free phenols (permanganate test), a distinct purple color to be present after 3>) minutes, R.R, Classificationt Lacquer Solvents NOfBN. General Information; Tricresvl Phosphate is used principally as a plasticizer. It has a high boiling point and is relatively non-volatile, the evaporation loss in 100 hours at 100C. being less ih#n 0.10%. The refractive index is abo\it 1.556 at 2(tC. Viscosity increases rapidly at temperatures below normal until at about --35C. the product is a solid transparent mass without crystalline structure. It is miscible with all the common solvents and thinners, and with linseed, china wood, and castor oils. Its solubility in water is less than 0.002% at 85C. and it imparts good moisture resistance to nitrocellulose films. Being a solvent for nitrocellulose, it has a high retentivity and can be used in large proportions without danger of sweating or separation. Tricresvl Phosphate is the standard fire retarding plasticizer for nitrocellulose. It is compatible with most lacquer resins and gives firm, tough, flexible film# of excellent weathering qualities. The ortho isomer, which is reputed to be the toxic element in normal Tricrcsyl Phos phate, has been virtually eliminated from Tricresvl Phosphate Monsanto, there by reducing toxicity dangers to minimum and making the product more suit able for many applications. Elimination of the ortho isomer causes no impairment in plasticizing qualities. Available Literature; 40-page booklet, "Plasticizers and Resins". TRIETHYL PHOSPHATE___________________________________ (C,Hj),OsPO Mol. Wt. 182.2 Standard Form; Liquid. Characteristics: Water white liquitl; acidity (cc. n/100 NaOH per 5 cc.), 3.0 ec. max.; moisture, 0.20% max. Distilling range: first drop, 2009C. min.; dry point, 220C. max. R.R. Classificationi Chemicals MOIBN, General Information: Used as a solvent plasticizer and as a catalyst in chem ical syntheses. Available Literature! 40-page booklet: "Plasticizers and Resins." TRIMAGNESIUM PHOSPHATE (See Magnesium Phosphate, Tri). J4TH EDITION Page 141 0683861 TOWOLDMON0041965 WATER_PCB-00026434 TRIPHENYL PHOSPHATE. Mol. Wt. 326.31 Specifications! While flakes, faintly aromatic; m. p. 48.5C. min. start; solution in alcohol (10 gins. in SO cc), noI more tban faintly opalescent; permanganate test, distinct purple color to be present after 30 minutes; acidity (as HjPOj) 0.003% max. II.R. Classification! Lacquer Solvents NOIBN. General Information! The chief uses of Tripbenyl Phosphate are as a plastic izer and fire retarder. It is miscible with the common solvents and thinners and with vegetable oils. Its solubility itj. water is 0.001% at 34C. and 0.002% at S4C. and it imparts some moisture reeiftance to cellulose acetate films. Its retentivity in cast cellulose acetate films is nearly 80%; that is, it can be incorporated in tbe proportion of 8 parts to 10 of acetate without causing separation and blooming. It imparts good flexibility and gives clear, tough compositions without tendency toward tackiness. Triphenyl Phosphate is toxic and should not be used in articles such as foil, which are to come in contact with foodstuffs. One of the most valu able properties of Tripheoyl Phosphate is that of fire retarding. When used alone in cellulose Acetate films an amount of Tripbenyl Phosphate equal to 20% of the cellulose acetate weight producea films which will not support combustion. Available Literature; 40-page booklet "Plasticizers and Resins" TRIPHENYL PHOSPHITE . 0-\ o-- O-0" Mol. Wt. 31031 Specifications! A crystalline solid lightly below room temperature; at higher temperatures is an oily liquid weighing 9.8$ lbs. per gal. R.R. Classificationi Chemicals NOIBN. General Information! Used as s plasticizer and as a fire retarder for nitro cellulose. Page 142 MONSANTO CHIMICALS 0683882 TOWOLDMON0041966 WATER_PCB-00026435 TRISODIUM PHOSPHATE (SeeSodmm Phosphor, Tri). "I 'REKA". **L REK A BLEND B", "U REKA C" (S under Accele rators, Rubber). VANADIUM SULFURIC ACID CATALYST General Information s L*rd in manufacture of sulfuric acid by contact process. (Not suitable for other purposes). VANILLIN, ETHYL (See Ethevan). "VANILLIN MONSANTO" (Vanillin, U.S.P.) CHO \y)OCH, Mol. Wt. 152.14 OH Standard Form: Fine Crystals. Specifications: Fine, white crystalline needles: m.p. 81.5C. min.; no foreign flavor (in sugar solution): loss on drying, 9-03% max.; solubility in alcohol (1:2), complete. R.K. Classification: Chemicals NOIBN. General Information: Used as a flavoring agent in foodstuffs and beverages. Available Literature: Leaflet "Var illm Monsanto." VARNISH ANTISKINNING AGENTS (See Santovar A). "VUELITE" (See Plastics). "VUEPAK" (See Plastics). WATER-TREATING CHEMICALS (See Aluminum Sulfate, Ammonia, Chlorine, FertUul, Hypochlorite of Soda, Santobrite, Santosite, Sodium Alummate, Sodium Sulfate). iT* COITION Page >43 0683883 ] TOWOLDMON0041967 WATER_PCB-00026436 WETTING AGENTS (See Aretkap, Aresket, Aresklene, Santomerse). XANTHATES, (See Potassium .(myl Xanthate and Potassium Ethyl Xan* lhate). ZINC CHLORIDE Grudcst 25s He. and 52 Be. solutions. H.K. Classification! Zinc Chloride Liquid. General Information > I'sed as a flux in galvanizing and soldering since it has the acid properties of muriatic acid without being volatile at the temperature used. The following products are made by Monsanto Chemicals Limited, London, England, and are not at present available for sale bv Monsanto in the United States: "ACROSYL" ANTHRACENE OIL AURINE BENZENE BENZENE ABSORBING OIL COUMAR0NE RESIN CREOSOTE NAPHTHA, HIGH FLASH NAPHTHA, SOLVENT NAPHTHALENE PITCH PYRIDINE BASES TAR ACID OIL TOLUENE Page 144 Monsanto chemicals 0683864 TOWOLDMON0041968 WATER_PCB-00026437 Ktbavan. "Etbavan (Pure Ethyl Vanillin)." 4-page pocket size folder, giving properties and uses. Ferrisul. "Femaul for Metal Treatment.'' L2-page file size booklet, giving properties and directions for use of Ferrisul for pickling stainless steel and copper and for etching metal articles preparatory to galvanizing. Ferrisul, ''Ferrisul for Treatment of Water, Sewage and Industrial Wastes." 16-page file size booklet, giving properties and directions for use of Ferrisul for treatment of municipal water supplies, sewage and industrial wastes and for other industrial uses, Ferrophoaphorua. "Phosphorus-Iron Alloys, Bulletin No. 1." 36-page file e booklet, containing a report of general exploratory research upon influence of phosphorus in low carbon, low l)oy steel. Based on work done at Battelle Memorial Institute. Ferrophoaphorua. "Phoepborus-Iron AJbvs, Bulletin No. 2." 64-pagr hie size booklet. A report of experimental research investigation on corrosion and mechanical influence# on alloying elements in low alloy steel. Ferrophoaphorua, Pbosphorus-Iroo Alloys. Bulletin No. 3." 56-page file size booklet in two parts. Part one: Digest of U.S. Patents relating to phosphorus as an alloying element. Part two-: Lis) of U.S. Patents relating to steel production and treatment, Ferrophoaphorua. ' Phosphorus-Iron Alloys, Bulletin No. 4." 20-page file e booklet containing reports of experimental investigation on the influence of phosphorous in Cr.-Vfo steels and sttcls in high temperature service. lllbitlte. ' Hibittte and Its Uses." 4-page mimeographed bulletin. Lacquers. "Saflex Lacquers." 4-page mimeographed bulletin on Saflex fabric coating*. 26TB EDITION Page US 0683885 TOWOLDMON0041969 WATER_PCB-00026438 MONSANTO LITERATURE__Continued Lampblack. "Monsanto Uear Lampblack. Properties and Principal Uses." 12-page pocket size booklet, giving description and analyses of the various grades of Monsanto Lampblack. Latex. ' Latex Compounding." 36-page file size illustrated booklet containing comprehensive discussion of latex compounding methods and technique, com pounding materials and various test data. Manicure Lacquera. "Monsanto Manicure Lacquer." Pocket size color card folder, containing sample chips of the standard creme shades of Monsanto man icure lacquers. Mertec. "Maintenance Paints." Mimeographed bulletin. Methyl Salicylate. "Methyl Salrylaie Monsanto." 4-page pocket size folder giving specification* and use*. Permasan. "Chemicals for Termite Control." Monsanto Technical Bulletin No. 0-13, August 22. 1940. 4-page file size bulletin describing recommended chemicals for treatment of soil and wood. Permasan 116. "Permasan 116, A Water Repellent Preservative for Wood." Monsanto Technical Bulletin No. 0-21. February 15. 194\. 8-page file size bulletin giving properties and application d*t<<. Phosilage. "Crass Silage for Mor< Profitable Livestock Farming--How to Make It and How to Feed ft." 32-page pocket size booklet, describing procedure for making and feeding grass silage in which Phosilage is used as the preser vative. Plasticizer* and Reaina. "Plasticizers and Resina. Specifications and Applica tion Data." Revised May, 1940. 40-page file size booklet, giving comprehensive data on properties and application* of Monsanto plasticizers and resins, which include the Santicizers, phthalates, phosphates, Santolites, and Aroclors. Plastics. "Resinox, A Monsanto Plastic." 12-page illustrated booklet describ ing properties, manufacture, molding, and uses of Resinox phenol-formaldehyde plastic. Plastlca. "Lustron, A Monsanto PUatic." 16-page illustrated booklet deacrib. ing properties, manufacture, molding, ana uses of Lustron. Monssnto poly styrene. Plastic*. "A Wartime Guide to Monsanto Plastics." 15-page file size booklet describing the main groups ol Monsanto Plastics and some of their wartime applications. Potassium Pyrophosphate, Tetra. "Tetrapotaasium Pyrophosphate." Mon santo Technical Bulletin No. P-23, January 1, 1941. 4-page file size bulletin. Rubber Chemical*. "Monsanto Chemicals for the Rubber Industry." 44-page file size booklet giving properties and general characteristics and uses of Mon santo accelerators, antioxidants, softeners and miscellaneous materials for the rubber industry. Page 116 MO NS INTO CHEMICALS 0683886 TOWOLDMON0041970 WATER_PCB-00026439 MONSANTO LITERATURE__Continued Rubber Compounding. Rubber Compounding for the Wire Industry.'' 17-page file size booklet giving specifications and testing and compounding data <>n rubber \rire coatings. .Santobrite. ''Santobrite for the Preservation of Adhesives." Monsanto Tech nical Bulletin .No, 0-1, June I. 1940. 6-page file size bulletin. Sanlobrite. 'Santobrite and Ssntophen 20 for Paint Preservation," Mon santo Technical Bulletin 0-2. 2-page tile size bulletin. Santobrite. "Santobrite for Microorganism Control in the Pulp and Paper Industry," Monsanto Technical Bull-tin No. 0-5. April 1. 1940. fl-page file size bulletin. Santobrite. "Santobrite foe the Control of Slime and Algae," Monsanto Technical Bulletin No. 0-15, March 25, 1940. 6-page file size bulletin, describ ing Santobrite for the control of sbme and algae in industrial cooling water -ystems. Santobrite. 'Santobrite for the Preservation of Rubber l,ales," Monsanto Technical Bulletin No. 0-17. September 29, 1939. 8-page file size bulletin des cribing the use of Santobrite for preventing biological deterioration of raw late* and latex products. Santobrite. "Samobriie in the Tanning Industry," Monsanto Technical Bulletin No. 0-19, June 20, 19+0. 6-page file size bulletin describing the use of Santobrite for preserving hides, tanned leather, and tanning materials from mold and biological deterioration. Santobrite. "Santobrite--Methods of Handling and Application," Monsanto Technical Bulletin No. 0-22. 8-page file size bulletin. Santobrite. "Preservation of Cellulose Insulating Materials by Monsanto.'' 2+-page file size booklet describing the use of Santobrite for protecting cellulose insulating materials and fibre boards from attack by decay and termites. Contains much investigational and field data. Illustrated. Santobrite. "Sap Stain Control by Monsanto." Revised August, 1940. 24page illustrated file size booklet, describing the use of Santobrite for controlling sap stain and mold in green lumber. Santochlor. ''Santochlor for the Control of Peach Tree and Stone Fruit Borers." Monsanto Technical Bulletin No. 0-18. December 1. 1939. 3-page file size bulletin. Santolube. "Santolubes--Corrosioi. Inhibitors for Lubricating Oils." 20-page file size booklet giving properties and results of operating and laboratory testa. Santomaak. "Santomask for After-Odor Control of Interior Paint, Printing Inks and Some Other Odoriferous Formulations." Monsanto Technical Buelltin No. 0-16, July 26, 1940. 2-page file she bulletin, giving properties and directions for use. 26TII KDITIOI Page 147 0683687 TOWOLDMON0041971 WATER_PCB-00026440 MONSANTO LITERATURE--Continued Saniomerse. '.Saniomerse." 32-page tile size booklet, giving physical ami chemirul properties and applications of Saniomerse as a detergent and wetting, spreading, penetrating, cleaning and dispersing agent. Santophcu T, "Sartophrn 7, A Germicide and Industrial Preservative," Monsanto Technical bulletin No. 0-3 August 13, 1941, 7-page file size bulletin giving properties and application datti. Suntopour. 'Sanlopour, A Pour-Point Depressant for Lubricating Oils." 10-page file size booklet describing properties, method of application, and test and field service results. Sopanox. "Sopanox--An Antioxidant for Soaps." Monsanto Technical Bulle tin No. P-100, May 1, 1939, 3-page file size bulletin giving properties and direc tions for use of Sopanox, also methods of testing soap for oxidation and rancidity. Vanillin. "Vanillin Monsanto." 4-page pocket size leaflet giving properties and uses. Vuepak. "How Vuepak Helped 20 Manufacturers to Package for Greater Sales." 30-page file size booklet, giving case studies of sales gains resulting from use of Vuepak. Intermediates are made at the Norfolk, Virginia, plant. Page 148 Monsanto chemicals 0683686 TOWOLDMON0041972 WATER_PCB-00026441 GENERAL DATA TESTING LIQUDS WITH THE BALME HYDROMETER Monsanto products, when madft to a Baume specification, may vary 0.2 Be. above but never below llie specified strength. The hydrometer used should be of limited ranee, not more than 10 Bl.. and should be at least 10' in length. Its accuracy should be certified by the manufacturer. Our own hydrometers are tested against standard glasses certified by the U. S. Bureau of Standards. METHOD OF READING THE HYDROMETER* The correct method of reading tlie hydrometer is illustrated in Figs. I and 2. The 'ample of li<|uid is placed in a clrar glass jar or cylinder and (lie hydrometer carefully immersed in it to a point slightly below that to which it naturally sinks, and is then allowed to float freely. The reading should not be taken until the liquid and the hydrometer are free from air A- Method of Reading Biume Hydrometer In taking the reading the eye should be placed slightly below the plsne of the surface of the liquid (Fig. ]) and then raised slowly until this surface, seen as an ellipse, becomes a Straight line (Fig. 2). The point at which this line cuts the hydrometer scale should be taken as the reading of the instrument (Fig. 2). In case the liquid is not sufficiently clear to allow the reading to be made as above described, it will be necessary to read from above the liquid surface and to estimate as accurately as possible the point to which the liquid rises on the hydro* meter stem. It should be remembered, however, that the instrument is calibrated * U. S. Bureau of Stondordt, Circ. No. 37 26TH edition page 149 0683689 TOWOLDMON0041973 WATER_PCB-00026442 to give correct indications when read at the principal surface of the liquid. It Mill be necessary, therefore, to coirect the reading at the upper meniscus by an amount equal to the height to which the liquid creeps up on the item of the hydrometer. The amount of thia correction may be determined with sufficient accuracy for most purposes by taking a few readings on the upper and the lower meniscus in a sample of the clear liquid and noting the difference. The magnitude of the correction will obviously depend upon the length and value of the subdivisions of the hydrometer scale and must be determined in each case for (he particular hydrometer in question. CORRECTING FOR TEMPERATURE The Thermometer must be used along with the hydrometer in (eating any liquid. Hydrometers do not indicate the correct strength of a liquid unless read at the exact temperature indicated on the spindle, that is, at W'F. Accurate readings may be obtained by bringing the liquid to this terapersture by cooling or warming, but in most instance* a correction can be applied with sufficient accuracy by reference to the following tables. For all liquids listed in this booklet, except Ammonia, the correction is added when the teBt is made above 60F. and subtracted when made below 60F. For Ammonia the reverie is true. CONVERSION FORMULAE FOR DENSITY SCALES Heavy Liquids Degrees Twaddell = (Sp. Gr. --1)200 Deg. Tw. +200 Sp. Gr. *=------------------------------ 200 145 Degrees Bauml = 145- Sp. Gr, Sp, Gr. 145 145-- Deg. &6. Light Liquids Degrees Rauml 140 Sp, Gr. Sp. Gr. 140 130 +Deg. B6. Page 150 MONSANTO CHBMICALS 0663890 TOWOLDMON0041974 WATER_PCB-00026443 THE DILUTION AND CONCENTRATION OF LIQUIDS AND MIXTURES RECTANGLE METHOD The figures expressing (he percentage concentration of two solutions (or ihose of one solution, and the figure 0 Jor uxuer, where dilution with water is desired) are written in the two left hand corners of a rectangle, and the figure expressing the desired concentration is placed on the intersection of the two diagonals of this rectangle. Now subtract the figures on the diagonals, the smaller from the larger, and write the result at the other end of the respective diago. nal, These figpres then indicate what quantities of the solutions whos< concentration is given on the other end <>f the respective horizontal line, must be taken to obtain a solution of the desired concentration. For ex* FfG./ ample, to makv a 12% solution, by mixing an 8% and a 15% solution we prepare Fig. 1, which indicates that we have to take 3 parts by weight of the 8% solution, and 4 parts by weight of the 15% solution to obtain (7 parts by weight of) the 12% solution. Again, if we wish to dilute a 25% solution so as to obtain a 9% solution, we place the figure 2S in, for example, the upper left corner of a rectangle and place figure 0 (concentration of the solution in pure water) in the lover left corner, and then place the figure 9 (desired concentration) at the point of intersection of the diagonals, and subtracting across the diagonals, we obtain Fig. 2: 9 parts by weight of the 25% solution, if mixed with 16 parts by weight of water, will give 25 parte by weight of a 9% solution. In diluting to a given Baumd strength or Specific Gravity, the percentage composition, corresponding to the Bum6 or Specific Gravity, must be taken from the following tables. For instance, supposing a 32 .....................*?0Baum6 Chloride of Alumina solution is to be diluted to 6.50 8 Baurofi with yater. By reference to table on page 163 a 32 Baumt solution contains 27.88% AlfCls, and an 8 0.......must ' Baum6 solution contains 6.50% AljCl* These percentages u**d >n finding the weights of Chloride of Alumina "** and water to b< mixed by the above method. According to the scheme as outlined above, the percentages are arranged as in Fig. 3 and the subtraction# made along the diagonals, the lower from the higher. Thus when 32 Baumd Chloride of Alumina is mixed with water in the proportion 6.50 pounds to 21.38 pounds, 27.88 pounds of solution will be obtained at 8 Baum*. 20TB BDITION Page 151 068369 L TOWOLDMON0041975 WATER PCB-00026444 SULFURIC ACID* By V. C. Ferguson and H. P. Talbot DeP Itl* Specific Gravity 60/60* F. Per Cent HjSO Freezing (Melting) Point Dg. F. De< grees B<. Specific Gravity 60/60 F. Per Cent H,so4 Freezing (Melting) Point Deg. F. 0 I.0000 0.00 1 1.0069 1.02 2 1.0140 2.08 3 1.0211 3.13 4 1.0284 4.21 +32.0 +31.2 +30.5 +29.8 +28 9 36 1.3303 42 63 -70.0 37 1 3426 43.99 --60.0 38 1.3551 45 35 --53.0 39 1.3679 46 72 --17.0 40 1.3810 48.10 5 1.0357 5.28 +28.1 41 1.3942 49.47 --35 0 6 1.0432 6 37 7 1.0507 7.45 +27.2 +26 3 42 1.4078 50.87 --31.0 43 1.1216 52.26 --27.0 44 I 6 53.66 --23.0 8 1.0584 8 55 +25.1 45 1 9 1.0662 9.66 +24.0 55.07 --20.0 10 1.0741 10.77 +22.8 46 l. 56 48 --14.0 47 1. 57.90 -- 15.0 11 1.0821 11.89 +21.5 48 1.1 59 32 -- 18.0 12 1.0902 13.01 13 1.0985 14 13 14 1.1069 1S.2S +20.0 +18.3 +16 6 49 l.s; SO 1.52. 60.75 62.18 --22.0 -27.0 15 1.1154 16.38 +14.7 SI 1.5426 63.36 --33.0 16 1.1240 17.53 +12.6 52 1.5591 65 13 --39.0 53 1.5761 66.63 --49.0 17 1.1328 18 71 +10.2 54 1.5934 68.13 --59.0 18 1.1417 19.89 +7.7 5S 1 1611 69.65 f 19 1.1508 21.07 +4 8 20 1.1600 22.25 21 1.1694 23.43 +16 --18 56 1.6292 71.17 57 1.5477 72.75 58 1 6667 74.36 {t 22 1.1789 24 61 --6 0 59 1.6860 75.99 --7.0 23 1.1885 25.81 --11.0 60 1.7059 77.67 +12.6 24 1.1983 27.03 --16 0 25 1.2083 28.28 --23 0 61 1.7262 79.43 +27.3 62 1.7470 81.30 +39.1 26 1.2185 29 53 --30 0 63 1.7683 83 34 +46.1 27 1.2288 30.79 --39.0 64 1.7901 85.66 +46.4 28 1.2393 32.05 --19.0 29 1.2500 33 33 --61.0 64 1.7957 64^ 1.8012 86.33 87.04 +43.6 +41.1 30 1 2609 34.63 --74 0 64K 1.8068 87.81 +37 9 65 1.8125 88.65 +33 1 31 1.2719 35 93 --82.0 65 K 1.8182 89.55 +24 6 32 1.2832 37 26 --96 0 65 ^ 1.8239 90.60 +13.4 33 1.2946 38.58 --97.0 65H 1.8297 91.80 -- 1.0 34 1.3063 39.92 --91.0 35 1.3182 41.27 --81.0 66 1.8354 93.19 --29.0 This table hat been approved and adopted aa a Standard by the Manufact. uring Chemiat*' Association of tbe United State*. fBelow--40. Specific Gravity determinations wert made at 60 F., compared with water at 60*F. (Continued) Page 152 MONSANTO CHBMtCALS 0683692 TOWOLDMON0041976 WATER_PCB-00026445 SULPHURIC ACID_Continued From the Specific Gravities, the corresponding degrees Bauml were cal culated hy the following formula: Baume = 145--145/Sp. Gr. ALLOWANCE FOR TEMPERATURE At 10' Be.correction of .029 86. or .00023 Sp. G. for every 1"F. At 20 B6.correction of .036 Be. or .00034 Sp. G. for every lF. At 30 Be.correction of .035 B6. or .00039 Sp. G. for every I'F. At 10s B6.correction of .031 Be. or .00041 Sp. G. for every l'F. At 50" B6.correction of .028 Be. or .00045 Sp. G. for every I'F. At 60" B6.correction of .026 Be. or .00053 Sp. G. for every 1" F. At 63" B6.correction of .026 86. or .00057 Sp. G. for every 1"F. At 66" Be. correction of .0235' B6. or .00054 Sp. G. for every 1F. For temperatures above 60F., the correction is added to the observed in dication; below 60F. subtracted. % Oleum OLEUM % Free SO, Eauiv. % HjSO< Freezing Point F. 0 0 100 00 50.5 10 10 102.25 32.0 20 20 104 49 22.0 25 25 105 62 47.0 30 30 106.75 66.0 40 40 109 0 91 9 50 111 25 91.9 60 60 113 5 62.0 65 65 114 62 38.0 70 70 115.75 56.0 80 80 118 0 78.0 26TB BDITtON Page 153 0683893 TOWOLDMON0041977 WATER_PCB-00026446 Degrees Baum6 1.00 2.00 3.00 4.00 5.00 3 25 5.50 5.75 6.00 6 25 6 50 6 75 7.00 7.2S 7.50 7.75 8.00 8.25 8.50 8.75 9.00 9.25 9.50 9.75 10.00 10.25 10.50 10.75 11.00 11.25 11.50 11.75 12.00 12.25 12.50 12.75 13.00 13.25 13.50 13.75 14.00 14.25 14.50 14.75 15.00 Page 154 HYDROCHI ORIC ACID* (Muriatic Acid) By W. C Ferguson Specific 60760 F. Gravity 1 0060 1 0140 1 0211 1 0284 1 0357 1.0375 1.0394 1.0413 1.0432 1 0450 1 0469 1.0488 1.0507 1.0526 1.0545 1 0564 1.0584 1.0603 1.0623 1.0642 1.0662 1.0681 1.0701 1.0721 1.0741 1.0761 1.0781 1.0801 1.0821 1.0841 1.0861 1 0881 1.0902 1 0922 1.0943 1.0964 1.0985 1.1006 1.1027 1.1048 1.1069 1.1090 1.1111 1.1132 1.1154 Per Cent HCt. Degrees Bauml 1.40 2.82 4.25 5.69 7.15 | ' 15.25 15.50 15.75 16.0 16.1 7.52 7.89 8.26 B.64 9.02 16.2 16.3 16 4 16 5 16.6 9.40 9.78 10.17 10 55 10.94 17 ;i 1* 1 17.1 11.32 11.71 12.09 12.48 12.87 17.2 173 17 4 17.5 17.6 13.26 13.6$ 14.04 14.43 14.83 17.7 17.8 17.9 18.0 18.1 15.22 15 62 16.01 16.41 16.81 18.2 18.3 18.4 18.5 18.6 17.21 17.61 18.01 18.41 18.82 18.7 18.8 18.9 19.0 19.1 19.22 19.63 20.04 20.45 20.86 19.2 19.3 19.4 19.5 19.6 21.27 21.68 22.09 22.50 22.92 19.7 19.8 19.9 20.0 20.1 (Continued) Specific Gravity 60760" F. 1.1176 1 1197 1 1219 1.1240 1.1248 1.1256 1.1265 1.1274 1.1283 1.1292 1.1301 1.1310 1.1319 1.1328 1.1336 1.1345 1.1354 1.1363 1.1372 1.1381 1.1390 1.1399 1.1408 1.1417 1.1426 1.1435 1.1444 1 1453 1.1462 1.1471 1.1480 1.1489 1.1498 1.1S08 1.1517 1.1526 1.1535 1 1544 1.1554 1.1563 1 1572 1.1581 1.1590 1.1600 1.1609 Per Cent HCI. 23.33 23.7S 24.57 24.73 25.06 25.23 25.39 25.56 25 ` 25 26 26 26.,, 26.56 26.73 26.90 27.07 27.24 27.41 27.58 27.75 27.92 28.09 28 26 28 44 28.61 28 78 28.95 29.13 29 30 29.48 29.65 29.83 30.00 30.18 30.35 30.53 30.71 30.90 31.08 31.27 31.45 31.64 MONSANTO CHEMICALS 068389*1 TOWOLDMON0041978 WATER_PCB-00026447 HYDROCHLORIC \CID_Continucd Degree* Baum* 20.2 20.3 20.4 20.5 20.6 20 7 20.8 20.9 21.0 21.1 21 2 21.5 21.4 21.5 21.6 21.7 21.8 21.9 22.0 22.1 22.2 22.3 22.4 22.5 22.6 22.7 22.8 22.9 23.0 23.1 Specific 60 .60* F. Gravity 1.1619 1 1628 1.1637 1.1647 1.1656 1.1666 1.1675 1.1684 1.1694 1.1703 1.1713 1.1722 1.1732 1.1741 1.1751 1.1760 1.1770 1.1779 1.1789 1.1798 l.1808 1.1817 1.1827 1.1836 1.1846 1.1856 1.1866 1.1875 1.1885 1.1895 Per Cent HCI. 31.82 32.01 32. 19 32,38 32.56 32. 7> 32.93 33 12 33 31 33.5) 33.6) 33.83 34.07 34.26 34.45 34.61 34.83 35.02 35 21 35.49 35.59 35.78 35.97 36.16 36.3> 36.54 36.73 36.93 37.14 37.36 Degrees Baume 23.2 23.3 23.4 23.5 23.6 "3.7 23.8 23.9 24.0 24.1 24.2 24.3 24.4 24.5 24.6 25.7 24.8 24.9 25.0 25.1 25.2 25.3 25.4 25.5 Specific Gravity 60. 60 F. 1.1904 1.1914 1.1924 1.1934 1.1944 1.1953 1.1963 1.1973 1.1983 1.1993 1.2003 1.2013 1.2023 1.2033 1.2043 1.2053 1.2063 1.2073 1.2083 1.2093 1.2103 1.2114 1.2124 1.2134 Per Cent HCI. 37.58 37.80 38 03 38.26 38.49 38.72 38 95 39 18 39.41 39.64 39.86 40.09 40 32 40.55 40.78 41.01 41.24 41.48 41.72 41.99 42.30 42.64 43.01 43.40 This table has been approved and adopted as a Standard by the Manufact uring Chemists' Association of the tailed States. Specific Gravity determinations were made at 60F., compared with water at 60F. From the Specific Gravities, the corresponding degrees Baum6 were calcul ated by the following formula: 145 Baumi =145---------------- Sp. G. ALLOWANCE FOR TEMPERATURE At 10 to 15 B6. correction of ]/40 B. or .0002 Sp. G. for every 1F. At 15 to 22 B6. correction of 1/30 B8. or .0003 Sp. G. for every 1 F. At 22 to 25 B6. correction of ] /28 B6. or .00035 Sp. G. for every 1F. 24TH EDITION Page 155 0683695 TOWOLDMON0041979 WATER_PCB-00026448 NITRIC ACID* By W. ('. Ferguson Degrees Baume 1 10 O0 10.75 11.00 11.25 11.50 12.00 12.25 12.50 12.75 13.25 13.50 13.75 14.00 14.25 14.50 14.75 15.00 15.2S 15.50 15.75 16.00 16.25 16.50 16.75 17.00 17.25 17.50 17.75 18.00 18.25 18.50 18.75 19.00 19.25 19 50 19 75 20.00 20.55 20 50 20.75 21 00 Page 156 Specific Graviiv 60s 60s'F'. Per Cent HM>S Degrees 1 Baume Specific Gravity 60/60 'F. Per Cent HXOj l.OTH 1.0761 1.1*781 1.0801 1.0821 11 12.86 i 21.25 13.18 | 21.50 13.49 13.81 1 22.00 14,13 i 22.25 1.1718 1.1741 1.1765 1.1789 1.1813 28 02 28 36 29 07 29 43 1.0841 1.0861 1.0881 1.0902 1.0922 14.44 1 22.50 14.76 22.75 15.07 23.00 15.41 23.25 15.72 23.50 1.1837 1.1861 1.1885 1.1910 1.1934 29.78 30 14 31.21 1.0943 1.0964 1.0985 1.1006 1.1027 16.05 16.39 16. 72 17.05 17.38 23.75 24.00 24.25 24.50 24.75 1 1959 1.1983 1,2008 1.2033 1.2058 31.58 31.94 32.31 32.68 33.05 1.1048 1.1069 1.1090 1.1111 1.1132 17.71 18.04 18.37 18 70 19.02 25.00 25 25 25.50 2S.75 26.00 1.2083 1.2109 1.2134 1 2160 1.2185 33.42 33.80 34.17 34.56 34.94 1.1154 1.1176 1.1197 1.1219 1.1240 19.36 19.70 20.02 20.36 20.69 26.25 26 SO 26.75 27 00 27.25 1.2211 1.2236 1.2262 1.2288 1,2314 35.33 35.70 36.09 36.48 36.87 1.1262 1.1284 1.1306 1.1328 1.1350 21.03 21.36 21.70 22.04 22.38 27.50 27.75 28.00 28.25 28.50 1.2340 1.2367 1.2393 1.2420 1.2446 37.26 37.67 38.06 38.46 38.85 1.1373 1.1395 11417 1.1410 1.1462 22.74 23.08 23.42 23.77 24.11 28.75 29.00 29.25 29.50 29.75 1.2473 1.2500 1.2527 1.2554 1.2582 39.25 39.66 40.06 40.47 40.89 1.1485 1.1508 1.1531 1.1554 1.1577 24.47 24.82 25 18 25.53 25.38 30.00 30.25 30.50 30.75 31.00 1.2609 1.2637 1.2664 1.2692 1.2719 41.30 41.72 42.14 42.58 43.00 1.1600 1.1624 1.1647 1.1671 1 1694 26.24 26.61 26,96 27.33 27.67 31.25 31.50 31.75 32.00 32.25 ; 1 (Continued) 1.2747 1.2775 1.2804 1.2832 1 2861 43.44 43.89 44 34 44.78 45 24 MONSANTO CHEMICALS 0683896 TOWOLDMON0041980 WATER_PCB-00026449 NITRIC ACID_Continued Degree* Baum6 32.50 32 75 33.00 33 25 33.50 33.75 34.00 34 25 34 50 34.75 35.00 35 25 35.50 35.75 36.00 36.25 36 50 36.75 37.00 37.25 37.50 37.75 38.00 38 2S 38.50 38.75 39.00 39.25 39.50 39.75 40.00 40.25 40.50 40 75 41 00 Specific Gravity 60 60 F. 1.2389 1.2918 1.2946 l 2975 1 3004 3034 l 3063 1.3093 1.3122 1.3152 1.3182 1 3212 1.3242 1.3273 1.3303 1.3334 1.3364 1.3395 1.3426 1.3457 1.3488 1.3520 1.3551 1.3583 1.3615 1.3647 1.3679 1.3712 1.3744 1.3777 1.3810 1.3843 1.3876 1.3909 1.3942 Per Cent UNO, Degrees Haurm 45 68 46 14 46 58 47 04 47.49 41.25 41 50 41.75 42 00 42.25 47.95 48.42 48 90 49 35 49.83 42.50 42.75 43 00 43 25 43.50 50.32 50 81 51.30 51.80 52.30 43.75 44.00 44.25 44.50 44.75 52.81 53.32 53.84 54.36 54.89 45 00 45.25 45.50 45 75 46 00 55 43 55 97 56 52 57 08 57.65 i 46 25 46.50 46 75 47 00 47.25 58.23 58.82 59.43 60.06 60.71 47.50 47.75 48.00 48.25 48.50 61.38 62.07 62.77 63.48 64.20 Specific Gravity 60 60*F. 1.3976 1.4010 1.1044 1 4078 1.4112 1.4146 1 4181 i. 4216 1.4251 1.4286 1.4321 1.4356 1 4392 1.4428 1 4464 l 4500 1 4536 1.4573 l 4610 1 4646 1 4684 1.4721 1.4758 1.4796 1.4834 1.4872 1.4910 1.4948 1 4987 1.5026 Per Cent H\Oj 64 93 66.42 67 18 67.95 68 73 69 52 70 33 71. 15 71 98 72 82 73.67 74.53 75.40 76.28 77 17 78.07 79 03 80 04 81.08 82.18 83.33 84.48 85.70 86.98 88.32 89.76 91.35 93.13 95.11 Tbi* table ba been approved and adopted as a Standard by the Manufac turing Chemuta' Association of the United State#. Specific Gravity determination* were made at 60 F compared with water at 60F. From the Specific Gravities, the corresponding degrees Baumfi were calcu lated by the following formula: -- 145 Bautni=145-- ------------------ Sp. G. (Continued) 26TB EDITION Page 157 0663697 TOWOLDMON0041981 WATER_PCB-00026450 NITRIC ACID_Continued allowance for temperature At from 10 to 20 B4. correction of 1/30 B4. or .00029 Sp. G. for every IT. At from 20 to 30 B4, correction of 1/23 B4. or .00044 Sp. G. for every IT. At from 30 to 40 B. correction of 1/20 B6. or .00060 Sp. G. for every IT. At from 40 to 43.5 B6. correction of 1/17 B. or .00084 Sp. G. for every IT. ACETIC ACID 60,60 F. Oudemann* Specific Gravity 1.0000 1.0016 1.0047 1.0062 1.0077 1.0093 1.0108 1.0123 1.0137 1.0152 1.0167 1.0181 1.0195 1.0210 1.0224 1.0238 1,0252 1.0266 1.0280 1.0294 1.0308 1.0321 1.0334 1.0347 1.0360 1.0373 1.0385 1.0398 1.0410 1.0422 1.0434 1.0446 1.0457 Per Cent CjHA 0 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 Specific Gravity 1 0469 1 0480 1,0491 1.0502 1.0512 1.0523 1.0533 1.0543 1.0S53 1.0562 1.0572 1.0581 1.0590 1.0599 1.060? 1.061? 1.0625 1.0633 1.0641 1.0648 1.0656 1.0663 1.0670 1.0676 1.0683 1.0689 1.0695 1.0701 1.0707 1,0712 1.0717 1.0722 1.0727 1.0731 Per Cent CtHA 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 ' 60 ! 61 62 , 63 65 66 67 . Specific Gravity 1.0735 1.0739 1.0743 1.0747 1.0750 1.0752 1.0754 1.0756 1.0757 1.0758 1.0756 1.0758 1.0758 1.0757 1.0756 1.0754 1.0752 1.0749 1.0746 1.0741 1.736 1.0730 1.0723 1.0715 1.0706 1.0696 1.0684 1.0670 1.0654 1.0635 1.0614 1.0590 1.0563 Per Cent CjH40| 72 73 74 75 77 79 81 82 87 92 94 97 100 P*. 158 MONSANTO CBIMICALS 0663896 I TOWOLDMON0041982 WATER_PCB-00026451 AQUA AMMONIA* Hv W C. Ferguson Degrees Baum 10.00 10.25 10.50 10.75 11.00 11 25 M 50 11.75 12 00 12 25 12.50 12.75 13.00 13.25 13.50 13.75 14.00 14.25 14.50 14.75 15.00 15.25 15.50 15.75 16.00 16.25 16.50 16.75 17,00 17.25 17.50 17.75 18.00 18.25 18.50 18.75 19.00 19.25 19.50 19.75 Specific Gravitv 607604'. 1.0000 .9982 .9964 .9947 .9929 .9912 9894 .9876 .9859 .9842 .9825 .9807 .9790 .9773 .9756 .9739 .9722 .9705 .9689 .9672 .9655 .9639 .9622 .9605 .9589 .9573 .9556 .9540 .9524 .9508 .9492 .9475 .9459 .9444 .9428 .9412 .9396 .9380 .9365 .9349 Per Cent NHj ! Degrees | Batim6 .00 .40 .80 1.21 1.6* 20.00 20.25 20.50 20.75 21.00 2.04 2.4<. 2.86 3 30 3.75 21.25 21.50 21.75 22.00 22.25 4.10 4 50 5.05 5.45 5.81: 22.50 22.75 23.00 23.25 23.50 6.3] 6.74 7.17 7.61 8.OS 23.75 24.00 24.25 24.50 24.75 8.49 8.93 9.3? 9.83 10.28 25.00 25.25 2S.50 25.75 26.00 10.73 11.18 11.64 12.10 12.56 26.25 26.50 26.75 27.00 13. OS 13.49 13.96 14.43 14.90 27.25 27.50 27.75 28.00 28.25 15.37 15.84 16.32 16.80 17.28 28.50 28.75 29 00 Specific Gravity 60760*^. .9333 .9318 .9302 .9287 .9272 .9256 .9241 .9226 .9211 .9195 .9180 .9165 .9150 .9135 .9121 .9106 .9091 .9076 .9061 .9047 .9032 .9018 .9003 .8989 .8974 .8960 .8946 .8931 .8917 .8903 .8889 .8875 .8861 .8847 .8833 .8819 . 8805 Per Cent NHj 17.76 18.24 18.72 19.20 19.6H 20.16 20.64 21.12 21.60 22.08 22.56 23.04 23.52 24.01 24.50 21.99 25.48 25.97 26.46 26.95 27.44 27.93 28.42 28.91 29.40 29.89 30.38 30.87 31.36 31.85 32.34 32.83 33.32 33.81 34.30 34.79 35.28 *This table has been approved an<! adopted as a Standard by the Manufac* luring Chemists' Association of the l nited States. Specific Gravity determinations were made at 60F, compared with water at 60F. (Continued) 2flTH EDITION Page 159 0663899 TOWOLDMON0041983 WATER_PCB-00026452 AQl'A AMMONIA__ Continued uo Raume ==-------------------- 130. Sp. ti. ALLOWANCE IOK TEMPERATl'RE The coefficient of expansion for amnonia solutions varying with the temperalnri\ correction must be applied according to the following table: -- Degrees i Ratline I I Correct ions to be Added for Each Degree Udow 608F. KLE. 50CF. . 01 .V'136. .021 " .02 7 " .033 " <139 " .053 " .017*86. .U23 " .029 " .036' " .012 " .057' " (iorrer lions to be Subtracted for Each Degree Above 6UE. ):K. .OilO'He. U26: " .o$r " .037 " 043 ' 0f..7e ' 8(JF. ,022Be. .028" " .033 .038 " .015 " .059 " 90'F. ,024Be. .030 " .035 '' .040 " <U7 " 100E. .026B6. .032 " .037 " .042 " Central Hesearcb Department Laboratories. Dayton, Ohio Page 160 MONSANTO CHEMICALS 0683900 TOWOLDMON0041984 WATER_PCB-00026453 Temp. D.g. -- U) -35 - 3<l -J5 --20 -- 15 -- 10 --S 0 5 10 15 20 2S 30 35 40 45 50 55 60 65 75 85 00 95 110 1 IS 120 125 ANHYDROUS AMMONIA Pressure Lbs. per Sq. In. Abs. >pecific V olume of Liquid Cu Ft. per Lb. of Sal. \ apor, Cu. Ft. per Lb. 10.12 11.74 13.56 15.61 17.91 20.46 23.30 26.46 0.0234 0.0235 0.0236 0.0238 0.0239 0.0240 0.0241 0.0242 25.45 22.14 19,35 16.95 14.89 13.15 11.63 10.32 29.95 33.79 38.02 42.67 47.75 53.50 59.39 65.91 73.03 80.75 89.09 98.03 107.7 118.1 129.2 141.1 153.9 167.4 181.8 197.3 213.8 231.2 249.6 269.2 289.9 311.6 *3.0244 0.0245 0.0246 0.0248 0.0249 0.0250 0.0252 0.0253 0,0255 0.0256 0.0258 0.0259 0.0261 0.0263 0.0264 0.0266 0.0268 0.0270 0.0271 0.0273 0.0275 0.0277 0.0280 0.0282 0.0284 0.0286 9.19 8.20 7.34 6.583 5.920 5.336 4.820 4.364 3.959 3.599 3.278 2.992 2.734 2.503 2.2% 2.109 1.940 1.788 1.650 1.524 1.408 1.305 1.210 1.122 1.042 0.970 Sp. G. Liquid 0.6364 at 32F. Meat of "bTl.'"" 601.9 598.3 594.7 591.1 587.4 583.6 579.9 576.1 572.2 568.3 564.4 560.4 556.3 552.2 548.1 543.9 539.7 535.3 531.0 526.5 522.0 517.5 512.8 508.1 503.4 498.5 493.5 488. S 483.4 478.2 472.9 467.4 461.9 456.3 24TH EDITION Page 161 0683901 TOWOLDMON0041985 WATER_PCB-00026454 ALUMINUM CHLORIDE 60 60 F. Specific G ravity n ua r .00 so 1.00 1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50 10.00 10.50 11.00 11.50 12.00 12.50 13.00 13.50 14 00 14.50 15.00 IS 50 16 00 16 50 17,00 1.0000 1.0035 1.0069 l 0105 1.0140 1.0175 1.0211 1.0247 1.0284 1.0320 1.0357 1.0394 1.0432 1.0469 1.0507 1.0545 1.0584 1.0623 1.0662 1.0701 1.0741 1 0781 1.0821 1.0861 1.0902 1.0943 1.0985 1.1027 1 1069 1.1111 1.1154 1.1197 1.1240 1.1284 1.1328 .00 .35 .75 1.17 1.58 2.00 2.40 2.78 3.16 3.58 4.00 4.38 4.81 5.20 5.63 6.05 6.50 6 92 7.32 7.75 8.13 8.57 9.00 9.46 9.90 10.28 10.70 11.15 11.60 12.05 12.50 12.9S 13.37 13.83 14.30 *5 -- &fc + 11Lj i'S u l; -* t -* a. < IX) .038 .113 .178 .242 17.50 18.00 18.50 19 00 19.50 .307 .370 .430 . 190 .557 20.00 20 50 21 00 21 50 22.00 .625 .686 .756 .820 .890 22.50 23.00 23.50 24.00 24.50 .962 1.04 1.11 1.18 1.25 25.00 25.50 26.00 26.50 27.00 1.32 1.39 1.47 1.55 1.63 27.50 1 28.00 28. SO 29.00 29.50 1.70 1.77 1.85 1 93 2.02 30.00 30.50 31.00 31.50 32.00 2.10 2.19 2.27 2.35 2.44 32.50 33.00 33.50 34.00 34.50 1.1373 1.1417 1.1462 1.1508 1.1554 1.1600 1.1647 1.1694 1.1741 1.1789 1.1837 1.1885 1.1934 1.1983 1.2033 1 2083 1.2134 1.2185 1.2236 1.2288 1.2340 1.2393 1.2446 1.2500 1.2554 1.2609 1.2664 1.2719 1.2775 1.2832 1.2889 1.2946 1.3004 1.3063 1.3100 14 73 15.16 15.60 16.05 16.53 16.94 17.43 17.88 18.33 18.78 19.22 19.68 20.13 20.57 21.03 21.50 21.98 22.38 22.82 23.20 23.70 24 13 24.58 25.02 25.53 25.99 26 45 26.92 27.38 27.88 28.33 28.78 29.24 29.66 30.00 ~ 'm L+ "< 2.78 2.88 2.96 3.06 3.15 3.34 3 43 3 53 3.62 3.72 3.81 3.90 4.02 4.12 4.21 4.30 4 41 4.50 4 61 4.72 4.83 4.94 5 04 5 27 5 40 5 50 5 62 5 73 5.85 5.92 *AljCI* +12H*0, Chloride of Alumina Crystal. For Chloride of Alumina 32B6. twice the above pound* per gallon of solution. Page 162 MONSANTO CHEMICALS 0683902 TOWOLDMON0041986 WATER_PCB-00026455 ALUMINUM SULFATE 60 60 F. Beveridge ri 1\ 00 30 1.00 1.50 2.0 2.5 3.0 35 4.0 4.5 5.0 55 60 65 7.0 7.5 8.0 8.5 9.0 9.5 10.0 10.5 11.0 11.5 12.0 12.5 13.0 13.5 14.0 14.5 15.0 15.5 16.0 16.5 17.0 17.5 18 0 18.5 19.0 19,5 l 000 1.0035 1.0069 1.0105 1.0140 1,0175 1.0211 1.0247 1.0284 1.0320 1 0357 1.0394 1.0432 1.0469 1.0507 1.0545 1.0584 1.0623 1 0662 1.0701 1.0741 1.0781 1.0821 1.0861 1.0902 1.0943 1.0985 1.1027 1.1069 1.1111 1 1154 1.1197 1.1240 11284 1 1328 1.1373 1.1417 1.1462 1.1508 1.1554 16TB EDITION . 3` Sjj* 'til? 4^5 m .53 1.07 1.64 2.16 .00 .044 .090 .138 .181 2.70 3.28 3.79 4.40 4.97 .228 .279 .323 376 .427 5.52 6.10 6.73 7.31 7.98 476 528 .585 .638 .700 8 56 9 18 9.82 10.43 11.OS .751 .808 .860 .925 .980 11.65 12.26 12.90 13.53 14.13 1.04 1.10 1.16 1.22 1.28 14.71 15.32 15.98 16.60 17.25 1.34 1.40 1.47 1.53 1.59 17.90 18.48 19. IS 19.80 20.40 1.66 1.72 1.79 1.86 1 92 21.06 21.73 22.43 23.10 23.78 1.99 2.06 2.14 2.21 2.28 (Continued) ]jji| i S 'U-Ji .00 0.6 1.1 1.7 2.3 2.9 3.5 4.1 4.7 5.3 6.0 6.7 7.3 7.9 8.5 9.2 98 10.5 11 1 11.B 12.4 13.1 13.8 14.4 15.1 15.7 16.4 17.1 17.7 13.4 19.1 19.9 20.4 21.1 21.8 22.4 23.1 23.7 24.4 25.1 .00 .050 092 1.50 1.95 .246 .298 .350 .403 .456 .518 .581 .635 .690 .745 .809 .865 .931 .988 1.05 Ml 1.18 1.25 1.30 1.37 1.43 1.50 1.57 1.63 1.70 1.77 1.86 1.91 1.99 2.06 2.12 2.20 2.26 2.34 2.42 Ptge 163 0683903 TOWOLDMON0041987 WATER_PCB-00026456 ALUMINUM SULFATEL. Continued S jw cilic G ravity Si U> 3 i -2 20. u -0.5 21.0 22 5 23.0 23.5 24.0 24.5 25.0 25.5 26.5 27.0 27.5 28.0 28.5 29.0 20.5 30.0 30. S 31.0 31.5 32.0 32.5 33.0 33.5 34.0 34.5 35.0 35.5 36 0 36. S 1 16(H) 1.1647 1.1694 1.1741 1.1789 1.1837 l.1885 1.1934 1.1983 1.2033 1.2083 1.2134 1.2185 1 2236 I.2288 1.2340 t.2393 1.2446 1.2500 1.2554 1.2609 1.2664 1.2719 1.2775 1.2832 1.2889 1.2946 1.3004 1.3063 1.3122 1.3182 1.3242 1.3303 1 3364 1 HS \z 24.38 24.99 25.60 26.22 26 87 27.50 28.16 28 85 29.50 30.18 30.85 31.54 32.24 32.95 33.63 34.35 35.03 35.75 36.46 37.20 37.90 38.58 39.30 40.02 40.73 41.49 42.20 42.96 43.71 44.48 45.20 46.00 46.80 47.58 2.35 2.42 2.49 2.56 2.64 2.71 2.78 2.86 2.94 3.92 3.10 3.18 3.27 3.3S 3.44 3.52 3.61 3.70 3.79 3.88 3 98 4.06 4.16 4.25 4.35 4.45 4.54 4.64 4.75 4.86 4.95 5.07 5.18 5.29 25.7 26.4 27.1 27.7 28.4 i W i- ^ I r-1 2.79 31.7 32.4 33 1 33 8 34 5 35 2 35.9 36.7 37.3 38.8 39.7 40.3 41.0 41.8 42.5 43.3 44.1 44.9 45.7 46.5 47.4 48.3 49.2 SO 1 3.18 3.35 3.61 3.70 3.79 3.87 4.06 4 35 4.55 4.66 4.76 4.87 4 98 5.09 5.21 5.34 5.59 FREEZING POINTS OF 0.6% "BASIC ALUM SOLUTIONS Baun>6 at 60t1. 5 10 15 20 25 30 35 Freezing Points, degrees F. 31 30 29 27 24 21 38 Page 164 MONSANTO CHEMICALS 068390A TOWOLDMON0041988 WATER_PCB-00026457 SODIUM BISULFITE 6(1 60 F. H. B. Bischoff ~3 > <22 |JL 2 Sc 9 uzLz. JT'J tz Sm < .00 . 50 1.00 1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.SO 8.00 8.50 9.00 9.50 10.00 10.50 11 00 11.50 12.00 12.50 13.00 13.50 14.00 14.50 15 00 15.50 16.00 16.50 17.00 17.50 18.00 18.50 19.00 19.50 1 oooo 1 0034 l 0069 1 0104 1.0140 1.0175 1.0211 1 0247 1 0284 1.0320 1.0357 1.0394 1.0432 1.0469 1 0507 1.0545 1.0584 1.0623 1.0662 1.0701 1.0741 1.0781 1.0821 1.0861 1.0902 1.0943 1.0985 1.1027 1.1069 1.1111 1.1154 1.1197 1.1240 1.1284 1.1328 1.1372 1.1417 1.1462 1 1508 1.1554 .00 5L 1 02 1.53 2.04 2.55 3 06 3.57 4.08 4.59 5.11 5 63 6.15 6 67 7.19 7.71 8.24 8.77 9 30 9 83 10 36 10 89 11 42 11 95 12.48 13 02 13 56 1.410 14 65 15.20 15.75 16.30 16.85 17.40 17.96 18.52 19.08 19.64 20.20 20.76 .00 . 3i. .63 .94 1.26 20.00 20.50 21.00 21.50 22.00 1.5" 21..S88* 2.5] 2.8$ 22.50 23.00 23.30 24.00 24.50 3.15 3 41' 3 79 4 1) 4.43 25.00 25.50 26.00 26.30 27.00 4.75 5.01 5M 5.75 6.05 27.50 28.00 28.50 29.00 29.50 6.31 6.7Q 7.03 7.36 7.6t 30.00 30.50 31.00 31.50 32.00 8.02 8.35 8 68 9.02 9.36 ' 32.50 33.00 33.50 34.00 34.50 9.70 10.03 10.37 10.71 11.05 35.00 35.50 36.00 36.50 37.00 11.39 11.74 12.08 12.43 12.77 37.50 38.00 38.50 39.00 39.25 1 1600 1.1647 1 1694 1.1741 1.1789 1.1837 1 1885 1.1934 1 1983 1.2033 1.2083 1.2134 1.2185 1.2236 1.2288 1.2340 1.2393 1.2446 1.2500 1 2554 1.2609 1.2664 1.2719 1.2775 1.2832 1.2889 1.2946 1.3004 1.3063 1.3122 1.3182 1.3242 1.3303 1 3364 1.3426 1.3488 1.3551 1.3615 1.3680 1.3712 22.44 23.00 23.57 24.14 24.71 25 28 25.85 26.42 26.99 27.56 28.13 28.70 29.27 29 85 30.43 31.00 31 57 32.14 32.71 33.28 33 86 34.43 35.01 35.62 36.25 36 88 37.51 38.14 38.78 39.42 40.06 40 69 41.30 41.91 42.52 43.12 43.72 44.02 13 81 14.15 14.50 15.20 15.55 15.91 16.23 16 60 16.96 17.32 17.66 18.01 18.37 18.73 19.08 19 33 19.78 20.13 20.48 20.83 21.19 21.55 21.92 22.30 22.70 23 08 23.47 23.87 24.27 24.65 25.03 25.41 25.79 26.17 26.54 26.91 27 10 26TB EDITION Page 165 0683909 TOWOLDMON0041989 WATER_PCB-00026458 B4. .25 .50 .75 1.00 1.25 1.50 1 75 2.00 2.25 2.50 2.75 3.00 3.25 3.50 375 4.00 4.25 4.50 4,75 5.00 5.25 5.50 5.75 6.00 6.25 6.50 6.75 7.00 7.25 7.50 7.75 8.00 8.25 8 50 8.75 Tw. .34 .70 1.04 1.3B 1.74 2.10 2.44 2.80 3.14 3.50 3 86 4.22 4 58 4.94 5 30 5.68 6.04 6.40 6.76 7.14 7.50 7,88 8.26 8.64 9.00 9.38 9.76 10.14 10.52 10.90 11.30 11.68 12.06 12.46 12.84 MERCLOR Per Cent Available Cl by Volume .11 .21 .32 .43 .54 .65 .76 .87 .98 1.10 1-21 1.32 1.43 1.55 1.66 1.78 1,90 2.01 2.13 2.26 2.38 2.51 2.63 2.75 2.38 3.01 3.13 3.26 3.39 3.52 3.64 3.77 3.90 4.05 4. 18 ! Tw.a B*. 9.00 9.25 9.50 9.75 10.00 10 50 11.00 11.50 12.00 12.50 13.00 13.50 14.00 14.50 15.00 15.50 16 00 16.50 17.00 17.50 18.00 18.50 19.00 19.50 20.00 20.50 21.00 21.50 22.00 22.50 23.00 23.50 24.00 24 50 25 00 13.24 13.62 14,02 14.42 14.82 15.62 16.42 17.22 18.04 18 86 19.70 20.54 21.38 22.22 23.08 23.94 24.80 25.66 26.56 27.44 28.34 29.24 30.16 31.08 32.00 32.94 33.88 34.82 35.78 36.72 37.70 38.68 39.66 40.66 41.66 tc_ <? o . c 4.43 4.57 4.71 4.84 5.38 5 65 5.94 6.24 6 52 6.83 7.12 7.41 7.71 8.01 8.31 8.60 8.92 9.23 9.54 9.87 10.19 10.51 10.84 11.18 11.52 11.89 12.23 12.60 12.95 13.33 13.71 14.11 14.50 Pi| 166 MONSANTO CRBMICALS 0683906 TOWOLDMON0041990 WATER_PCB-00026459 WEIGHTS PER GALLON AT 60 F. Arctic Acid 28% ............................................... Arctic Acid 56% . ....................... Arelic Acid Glacial . . ................................................. Aluminum Chloride 32 B6 ............................................... Amyl Acetate...................................................................... Aqua Ammonia 18 B6........................................................... Aqua Ammonia 20 B6........................................................... Aqua Ammonia 26 B6............ ............................................... Battery Acid 1.400.................................................... Butyl Acetate.............................. ............................................ Diacetone Alcohol.................... ................................................. Ethyl Acetate............................................................................... Iron, True Nitrate 47 Bi........................................................ Iron, Copperas Nitrate 47 Bfi.............................................. Iron, Perchloride 40 B6........................................................... Merclor.......................................................................................... Muriatic Acid 18 B6............................................................... Muriatic Acid 20 Be................................................................. Muriatic Acid 22 B6.. ........................................................ Nitric Acid 36 B4....................................................................... Nitric Acid 38 B6. .................................................................... Nitric Acid 40 B6....................................................................... Nitric Acid 42 B6................................... . Oleum 25% (at 15 C.)............................................. Oleum 60% (at 15 C.) .......................................................... Phosphoric Acid 75%............................................................... Sodium Bisulfite 33 B4............................................................ Sulfuric Acid 66 B4........... ...................................................... Sulfuric Acid 98%..................................................................... Sulfuric Acid 100% (Monohydrate).................................... Zinc, Cholride 52 B6................................................................. Zinc. Cbolride 72 B6................................................................ Weight per gallon *= Sp. Gr. x 8.337 1 Cubic Foot r= 7.480 gallons 1 Gallon := 3.78S liters Pounds ft 66 8.90 8.81 10.70 7.89 7.78 7 48 11.67 7.3 7.6 7.4 12.30 12 30 11.51 9.7 9.52 9.67 9.83 11.09 11.30 11.51 11.74 16 12 16 84 13.2 10. 78 15.30 13.36 13 41 13.00 16 56 26th edition Page 167 0683907 TOWOLDMON0041991 WATER_PCB-00026460 INTERCONVERSION TABLES FOR TO FROM MCLTIPLY BY--------------- To - Cu. In. To Cu. Ft. To Cu. Yd. -------------------------------------- ------------------ -- - To FI. Oz. To Pint 1 T<> Quart T> Gallon Cu. In. Cu, Ft. Cu. Yd. FI. Or. Pint Quart Callon Crain Ob. Troy l-b. Troy O*. Av. l b. Av. 1.00000 1728.00 46656 0 1.80469 28.8750 57.7500 231.000 .003954 1.89805 22.7766 1.72999 27.6799 .0,5787 t.00000 27.0000 001044 016710 .033420 .133681 .0,2288 .001098 .013181 .001001 .016018 0,2143 037037 1.00000 .0,3866 .0,6189 .001238 .004951 Oj84i'5 .0,4068 .0,4882 .0,3768 .0,5933 .554112 957.505 25852.6 1.00000 16.0000 32.0000 128.000 .002191 1.05173 12.6208 .958608 15.3378 .034632 59.8442 1615.79 .062500 1.00000 2.00000 8 00000 .01369 .065733 .788800 .059913 .958611 017316 29.9221 807 896 .031250 .500000 1.00000 4.00000 .0,6850 .032867 . 394400 .029957 .479306 .004329 7 48052 201 974 .007813 . 125000 250000 1 00000 .0,1712 .008217 .098600 .007489 .119826 CC or Cram Liter or Kg. Cu. M. .061024 61.0237 61023 7 .0*3531 .035315 35 3146 .0,1308 .001308 1.30795 .033814 33.8140 33814 0 .002113 2.11337 2113.37 001057 1.05669 1056.69 .0,2642 .264172 264.172 NOTEi--The small subnumeral following a zero indicates that the zero ia to be taken that number of times, thus .0,1428 is equivalent <o .0001428. Values used in constructing table: 1 inch -- 2.540001 cm. 1 cu. in. 16.387083 cc. = 16.387083 g. H,0 at 4C.(39#F.) 1 lb. av. -- 463.5926 g. Page 168 MONSANTO CBBMICALS 0663908 TOWOLDMON0041992 WATER_PCB-00026461 UNITS OF VOLUME AND WEIGHT MULTIPLY BY I'o Crain To Oz. Troy To Lb. Troy to Oz. Av. To To ------- To-- Lb. Av. CC. or G. Liter Or Kg 252 891 436996 1179903 456.390 7302.23 1460 45 58417.9 1.00000 480.000 5760.00 437.500 7000.00 15.4523 15432.3 154320* .526857 910.408 24581.0 950813 .043905 75.8674 2048.42 .079234 15.2130 30.4260 121.704 .002083 1.26775 2.53550 10.1420 .0,1736 1.00000 12.0000 .911457 14.5833 .083333 1.00000 .075955 1.21528 .032151 .002679 32.1507 2.67923 32150 7 1 2679.23 .5780117 998.848 26968 9 1.043)8 16.6968 33.38 6 133 5^7 .0022^6 1 09714 13.1657 1.00000 16.0000 .035274 35.2739 35273.9 .036127 62.4280 1685.56 .065199 1.04318 2.08635 8.34541 .0,1428 ,068571 .822857 .062500 1.00000 .002205 2 20462 2204.62 16 3871 28316.9 764556 29.5736 473.177 946.354 37BS.42 064799 31.1035 373.342 28.3495 453.593 1.00000 1000 00 1000000 01638? 28.3169 761.556 .029573 .473177 .946354 3.78542 . 0*6479 031104 373242 028350 453593 001000 i ooooo 1000 00 1 lb. av. = 27.679686 cu. in 11,0 at 4C. (39F.). 1 lb. ar. *= 7000 grains 1 gal. = 8.34541 lb. 1 gallon * 58417.87 grain*. 231 cu. in. = 1 gal. = 3785.4162 g. To Cu. M. .0*1639 .028317 .0*2957 . 0*4732 .0,9463 .003785 0t64?9 .0*3110 Oj3732 . 0,2835 .0*4536 .000001 00 MOO 1 ooooo JTB EDITION pge 169 PRINTED IN U. *, A. 0683909 TOWOLDMON0041993 WATER_PCB-00026462 0683910 TOWOLDMON0041994 WATER_PCB-00026463 Monsanto Chemical Company was one of the Brat to be awarded the Navy "E" and Bureau of Ordnance flag and the All-Navy ``E'' burgee 'In recognition of production of ordnance materiel vital to our national defense.'* It was also one of the Bret to be awarded the joint Army-Navy "E" burgee "represent ing recognition by both the Army and Navy of especially meritorious production of war materials." 0683911 TOWOLDMON0041995 WATER_PCB-00026464 0663912 TOWOLDMON0041996 WATER_PCB-00026465