Document 8VrQKDXznbK90ab3Y0ymwMory
FILE NAME Firestone FIRE DATE 1969 1963
DOC FIRE017
DOCUMENT DESCRIPTION Firestone Corporate Health and Safety Manual BC Ex 317
000014894
0 0 14894
SUBJECT TO DISCLOSURE RESTRICTION
4063
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
THE FIRESTONE TIRE & RUBBER COMPANY AKRON OHIO
SUBJECT TO DISCLOSURE RESTRICTION
40638
Pages
Section I Pages
Section II
Pages
Section III
Pages
Section IV
Pages
Section V
Pages
Section VI Pages
ADMINISTRATION
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION CURRENT PAGES AND DATE OF ISSUE
12/29/69
Manual Outline and Table of Contents
i thru vii - 12/9/63 vii - 10/22/63 Home
*
viii - 8/29/62 (
ixx 10/22/63 (
Office
Office
*
Akron
Akron
-
manuals
manuals
.
only
only * )
Administration
1.1.1 - 9/11/62 1.2.1 - 9/11/62
Responsibility For Safe Plant Operation
2.1.A.1 11/4/63
2.1.B.1 - 11/4/63
2.1.8.2 - 11/16/64
2.1.B.3 - 12/29/69
-
2.1.C.1 and 2.1.0.2 - 11/4/63
2.1.C.3 - 11/5/63
19/21/62 2.2.A.1 thru 2.2.A.4
2.2.A.5 and 2.2.A.6 - 9/20/62
2.2.B.1 thru 2.2.B.5 - 9/21/62
Safety and Fire Inspection Program
3.1.1 - 9/26/62 3.1.A.1 and 3.1.A.2 - 11/13/62 3.1.B.1 and 3.1.B.2 - 11/14/62 3.1.C.1 and 3.1.C.2 - 11/14/62 3.2.1 thru 3.2.3 - 9/26/62
Interplant Releases
4.1.A.1 and 4.1.A.2 - 11/5/63 4.1.A.3 - 5/18/65 4.1.A.4 thru 4.1.A.7 - 12/29/69
Engineering
5.1.1 thru 5.1.7 7/10/67 5.3.A.1 thru 5.3.A.4 - 1/7/65
Industrial Hygiene
6.1.1 thru 6.1.5 - 6/17/68 6.1.A.1 - 10/3/62 6.2.A.1 and 6.2.A.2- 6.2.A.2- 5/8/69 6.2.A.3 thru 6.2.A.5 - 2/8/66 6.2.A.6 - 4/30/68 6.2.A.7 - 4/18/63 6.2.A.8 thru 6.2.A.11 - 12/13/66 6.2.A.12 thru 6.2.A.15 - 6/5/67 6.2.A.16 thru 6.2.A.19 - 7/16/68 6.2.A.20 thru 6.2.A.24 >> 8/1/69
6.2.B.l and 6.2.B.2 - 4/5/67 6.2.B.3 - 3/24/65 6.2.8.4 and 6.2.B.5 - 7/26/67
cont'd
SUBJECT TO DISCLOSURE RESTRICTION
406406339 940639 40639 40639
Section VI Pages
Section VII Pages
VOLUME
ee ey Section VIII
Pages
Section IX Section X
Pages
Section XI Pages
Section XII Section XIII
Pages
-
cont'd
6.2.C.15 6.2.C.16 6.2.0.17 6.2.C.18 6.2.C.19 6.2.C.21 6.2.C.22 6.2.C.24 6.2.C.25 6.2.C.27 6.2.C.31 6.2.C.33
- 4/26/65 - 8/19/65 - 6/23/66 - 9/15/66 and 6.2.C.20 - 9/22/66 = 12/13/66 and 6.2.C.23 - 6/26/67 - 11/29/67 and 6.2.C.26 - 1/23/68
4/16/68 4/16/68 thru 6.2.C.30 -
and 6.2.C.32 - 4/19/68
thru 6.2.C.35 - 5/3/68
Property Protection
7.1.A.1 thru 7.1.A.8 - 7/18/63 7.1.B.1 thru 7.1.8.3 - 7/18/63
7/19/63 7.1.C.1 7.1.C.1 thru 7.1.C.16 -
7.2.A.1 thru 7.2.A.8 - 7/19/63
7.2.A.9 - 2/25/66 7.2.A.10 thru 7.2.A.19 - 7/19/63 7.2.A.20 thru 7.2.A.89 - 7/22/63 7.2.B.1 thru 7.2.B.9 - 7/22/63 7.2.C.1 thru 7.2.C.3 - 7/22/63 7.2.D.1 thru 7.2.D.3 - 7/22/63 7.2.E.112 7.2.E.112 29 7.2.F.1 and 7.2.F.2 - 11/7/62
7.2.F.9 thru 7.2.F.ll - 10/3/62
12/29/69
Safety
8.1.1 8.2.A.1
8.2.B.3
9/11/62
11/6/62 thru 8.2.A.3 -
and 8.2.B.4 - 10/24/66
8.2.C.1 thru 8.2.C.4 - 10/25/62 8.3.A.1 and 8.3.A.2 - 11/6/62
Nothing
Accident Producing Physical Conditions and Their Control
10.1.H.15 10.1.H.15 17
10.2.D.1
10.2.E.1 10.3.A.1 10.4.A.1 10.5.A.1
10/2/162 thru 10.2.D.5 - 11/7/62
and 10.2.E.2 - 11/7/62 - 11/7/62 thru 10.4.A.12 - 11/7/62 - 8/25/65
Explosive and Flammable Materials
11.2.1 thru 11.2.8 - 10/29/62 11.2.13 thru 11.2.16 - 11/15/62
Nothing
Property Safety Medical and
Protection Forms
13.1.1 thru 13.1.37 - 3/8/63
SUBJECT TO DISCLOSURE RESTRICTION
40640
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
;
-
Section
MANUAL OUTLINE AND TABLE OF CONTENTS
Part
TABLE OF CONTENTS
VOLUME
Pago
Date Cancels
I i
12-6-63 None
|
ede.
SECTION I ADMINISTRATION - INTRODUCTION Part 1. The Need for Employee and Property Protection
A. Employee Protection B. Property Protection
Part 2.
Preparation of The Manual A. Joint Home Office Departmental Corporation B. Custom Manual
SECTION II RESPONSIBILITY FOR SAFE PLANT OPERATION
Part
Communication System
A. Departments issuing Instructions and Procedures B. Operation of the System
C. Content and Form of the Release
Part 2. Functional Responsibilities
A. Responsibilities of Home Office Departments
1. Production Management Function 2. Safety Management Function 3. Engineering Management Function 4. Insurance Management Function 5 Medical Management Function 6 Technical Management Function 7. Purchasing Management Function 8. Controlling Management Function 9. Interplant Management Function
B. Plant Level Responsibilities
1. Plant Management Function
3. Production Function Safety Function
4.
5.
Engineering Function Controlling Function
Technical Function
Medical Function
Purchasing Function
Plant Protection Function
2.12.1 . A.
2. 1. A. 12.2.
1.
2.
1.
2.
1.
2.2 2.2
A.
2.2.A.12.2.A.1 2.2.A.1 2.2.A.1
2.2.A.1 2.2.A.1
2.2.A.2
2.A.A. 2.2.A 2.A
2.2 2.2
2. 2.
1
2. 2.
1
2.2
2 B.
2.2 2.2
4
2. 2.
B. 4
2. B.4 2.2 2.2 5
5 2.2
2.2 5
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40641
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
section
MANUAL OUTLINE AND TABLE OF CONTENTS
Part TABLE OF CONTENTS CONTINUED
SECTION III SAFETY AND FIRE INSPECTION PROGRAM
VOLUME I
12-6-63 Cancels None
Page
3.1.1
Part 1.
Mandatory Inspections
A. Determination of Inspections Required
A Domestic Tire Plants and Canada B Foreign Tire Plants C Licensee Tire Plants
B. Additions to the Required Inspections C. Frequency of Inspections D. Program Improvements
Part 2.
Inspection Scheduling and Reporting
A. The Firestone Record System
1. Introduction
2. Scheduling and Reporting 3. How the System Works
4. The Basic Form
5. Handling Safety Inspection Work Orders 6. Responsibility Assignment
SECTION IV PLANT RELEASES
Part 1.
Interplant Releases A. Summary of Releases
SECTION V ENGINEERING
Part 1.
Government Regulations A. Radioactive Type Gages
Part 2. Equipment Design and Operation
SECTION VI INDUSTRIAL HYGIENE
Part 1. Part 2.
Definition Scope Function and Organization
Health Hazards and Their Control
3.1.1
A. 3.1 3.1
3.1.1 3.1.1 3.1.1
3.2.1 3.2.13.2.1 3.2.1 3.2.1 3.2.1
3.2.1
3.2
1
3.2
1
3.2.1 3.2.2
3.2
4.1
A.
4.1
5.1.1 5.1.1 5.1.1
Future Future
_ 5-4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40642
section
Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
MANUAL OUTLINE AND TABLE OF CONTENTS
VOLUME I Page
=.
.
_
Dato
12-6-63
7m
Cancels None
TABLE OF CONTENTS CONTINUED
.
:
A. Environmental Control of Health Hazards
Page
Future
.1 2.
3
4. 5. 6 7. 8 9 10
Industrial Health Hazards
Types of Environmental Controls of Health
Substitution of Less Toxic Materials
Hazards
Process and Operations Changes Segregation of Hazardous Processes
Industrial Ventilation
Building Design and Maintenance
General Ventilation
Noise Control
Radiation Hazards and Controls
Future Future
Future
Future Future A. Future Future Future Future
B. Personal Protection Equipment
1. Eye Protection 2. Face and Eye Protection 3. Finger Hand and Arm Protection
Toe
4. Foot and Leg Protection 5. Head Safeguards 6. . Noise Safeguards
7. Respiratory Protective Equipment
8. Safety Belts 9. Special Equipment
C. Common Industrial Hazards
Future
----
_
.,
Future Future Future Future Future Future Future Future Future
6.2
SECTION VII PROPERTY PROTECTION
Part
Fire Protection Engineering A. Automatic Sprinkler Systems
1 Additions and Repairs
2. Care and Maintenance
B. Hand Fire Extinguishing Equipment
C. Miscellaneous Fire Protection Equipment 1. Trimethoxyboroxine TMB for Extinguishment of Metal Fires
2. Fire Protection Recommendations For
Rolling Steel Fire Doors
7.1 7.1 A.1 7.1 7.1 7.1 7.1
7.1
-4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40643
Section
Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
MANUAL OUTLINE AND TABLE OF CONTENTS
VOLUME I
Page
iv
Date
Cancels
12-9-63
None
TABLE OF CONTENTS CONTINUED
Page
3. Procedure For Inspecting and Maintaining Fixed High Pressure Carbon Dioxide Extinguishing Systems
7.1
Part 2. Protection of Property Hazards
A. Special Fire Hazards 1. Fire Protection Recommendations For Handling
and Storage of Pigment R. P. 12572 Elastopar
2. Fire Hazards of Benzoyl Peroxide 3. Fire Protection Recommendations for Liquefied
Petroleum Gas powered Industrial Trucks
4. Post Dip Unit
5. Electrostatic Hazards
6. Fire Protection - Horizontal Spreaders
7. Fire Protection Recommendations For Research
Chemical Physical and Testing Laboratories 8. Compressed Gases in Cylinders 9. General Safeguard For All Gases
10. Fire Protection Recommendations For Dust
Explosion Hazards in connection with Synthetic
resins 11. Fire Protection Recommendations For Salt Bath
Heat Treating
A.
A.
A.
7.2.A. 7.2.A. A.
7.2.A. 23 S
7.2 A. 7.2
7.2 43 A. 51
12. 13. 14. 15
16
Suggested Fire Emergency Organization Program
Fire Production Recommendations to avoid Physical Damage due to water in hot oil storage tanks List of Rubber Compounding Ingredients Chemical Chemicals and solvents showing Fire Hazards
Fire Protection Aspects and Maintenance Data Connected with Liquid Filled Askarel Insulated
Transformers
Potential Fire Hazard Associated with Automatic Narrow White Sidewall Grinders .
7.2.A.
7.2.A. 70 7.2 A. 73 7.2.A. 77
:
7.2 83
5-4279
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40644
Section Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
MANUAL OUTLINE AND TABLE OF CONTENTS
VOLUME I
Page
V
Date
Cancels
12-9-63 None
TABLE OF CONTENTS CONTINUED
17. Prevention of Gas and Oil Fixed Boiler and
Over Explosions 18. Identification of Compressed Gas Containers
Boilers and Pressure Vessels
1. Boiler Explosions
2. Mandatory Inspection For Pressure Vessels
C. Construction Hazards
1. Welding and Cutting Operations 2. Preventing Cutting and Welding Fires
D. Insurance 1. Standard Procedure For Insurance Claims
E. Plant Security
Page
A. 7.2 88 B. 7.2 7.2 B. 6 7.2 7.2 7.2
7.2 2 7.2 1
SECTION VIII SAFETY
Part 1. Factory Safety Manual
A. Distribution of Manual
B. Table of Contents of Factory Safety Manual
1. Safety and Accident Prevention
2 Fire Protection 3. Plant Protection
Part 2.
Safety Procedures A. Banburys
B. Hazardous Materials
C. Bagomatic and Autoform Presses
SECTION IX TECHNICAL
Part 1. Standard Operating Procedures
SECTION X
ACCIDENT PRODUCING PHYSICAL CONDITIONS AND THEIR CONTROL
Part 1. Layout and Design
A. Layout and Design B. Construction and Remodeling C. Building Exits and Stairs D. Floor Openings and Platforms
E. Hazardous Operations or Conditions
4273
The Firestone Tire & Rubber Company
8.1.1 1.1 8.1.1
8.1.1.
8.1.1 8.1.1 8.1.1
8.2. 1
C. 1 8.
2. 8.
1
Future
Future Future Future Future Future Future
SUBJECT TO DISCLOSURE RESTRICTION
40645
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section Part
MANUAL OUTLINE AND TABLE OF CONTENTS
TABLE OF CONTENTS CONTINUED
F. Lighting
G. Ventilation
H. Painting I. Piping Systems
VOLUME I
Page
vi
Date 12-9-63 Cancels None
Page
Future Future Future Future
Part 2.
Machinery
A. Mechanical Hazards
1. Pierce Tire Wrapping Machine 2. DeMattia Tube Curing Stands 3. Horizontal Heater Door Safety Devices
B. Enclosure and Barrier Type Guards
C. Specific Hazardous Equipment
1. Powder Actuated Hand Tools
D. Operation Hazards 1. McNeil Shear Strip Tire Presses 2. Fatality in Tire Assembly Department 3. Drum Rotation Direction - Method of Making Tread Splices
E. Automation
1. Curing Room Accident BOM Shaping
10. A. 10. A. 10. A. 10. A.
Future
10. 2. C. 10. C. 10. .10 D.
10. D. 200
& 10. D. 4
10. 2. E.1
Part 3.
Electricity
A. Electric Hazards
1. Bagomatic Tire Safety
B. Hazardous Hand Powcred Tools
Part 4. Part 5.
Storage of Materials and Chemicals
A. Rubber Products
Material Handling
A. Power Trucks
B. Conveyors
SECTION XI EXPLOSIVE AND FLAMMABLE MATERIALS
Part 1 Properties of Explosive Materials Part 2. Properties of Flammable Materials
10. Future Future Future
Future Future
Future 11. 2.1
The Firestone Tire & Rubber Company SUBJECT TO DISCLOSURE RESTRICTION
40646
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section
MANUAL OUTLINE AND TABLE OF CONTENTS
Part _
TABLE OF CONTENTS CONTINUED
SECTION XII SPECIAL PROBLEMS
Part 1.
Waste Control
A. Scope of the Problem
B. Definitions C. Use of Public Sewers D. Polution E. Chemical Hazards
F. Liquid Disposal Measures
G. Atmospheric Polution
H. Air Cleaners
I. Disposal of Flammable Wastes
1. Solid
2. Liquid
3. Gaseous J. Radioactive Wastes
VOLUME
Date Cancels
vii
12-9-63 None
Page
Future
Future Future Future
Future
Future Future Future Future Future
Future Future Future Future
Part 2.
Control of Catastrophes A. Forethought for Safety B. Catastrophes not limited inherently to Hazardous
:
Operations
C. Disaster Control Organization
D. Communications
E. Training
F. Floods
G. Sabotage
H. Windstorm
I. Atomic Attack
Future Future
Future Future Future Future Future Future Future Future
SECTION XIII SAFETY MEDICAL AND PROPERTY PROTECTION FORMS
Part 1. Part 2. Part 3 Part 4
Safety Inspection Program Forms Safety Forms
Medical Forms
Property Protection Forms
1.1 Future Future Future
mr,
The Firestone Tire & Rubber Company
SUBJECT SUBJECT TO DISCLOSURE RESTRICTION
Administ
Administ
on
SUBJECT TO DISCLOSURE RESTRICTION
40648
Section Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
INTRODUCTION 1. THE NEED FOR EMPLOYEE AND
PROPERTY PROTECTION
VOLUME
Page
Date
Cancels
I 1.1.1
9-11-62 None
A. EMPLOYEE PROTECTION
Industrial accidents present a problem that merits serious consideration and attention Approximately 15,000 15,000 people are killed by work accidents in the United States each year There are annually close to 2,000,000 2,000,000 2,000,000 disabling injuries from occupational activity of which nearly 10,000 involve some permanent impairment
In addition to pain and possible crippling effects an injured worker and his family often suffer a serious financial loss dispite workmen's compensation payments Of course no payment is an adequate compensation for a death or a permanent impairment
As an aid to help insure and improve the excellence of the Firestone Safety Program this manual has been prepared The information and contents of the manual present the work of the many Firestone Departments which work actively toward the protection of Firestone employees
B. PROPERTY PROTECTION
The value of Firestone plant equipmeanntd property runs into many millions
of dollars The protection of this property from hazards of fire catastrophes and damage are a prime necessity and is closely linked with the problems of employee protection Experience dictates the necessity of coordinating the problems of employee and property protection
4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40649
Section Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
I INTRODUCTION
PREPARATION OF THE MANUAL
VOLUME Page
Date
Cancels
I
121
9-11-62
None
ow
A. JOINT HOME OFFICE DEPARTMENTAL COOPERATION
The Administration Manual - Health Safety Engineering and Property Protection is the product of the coordinated efforts of
the Safety Medical Insurance Technical and Engineering Departments These departments prepared the various sections
of the manual under their control and is the result of many years
of Firestone experience and activities in these areas
In making future additions and deletions each department is charged with the responsibility for keeping its sections pertinent and date in keeping with the policies and instructions of management All individual plants are urged to present their ideas suggestions corrections and improvements in the manual to the Home Office Departments concerned
B. CUSTOM MANUAL
Because of the wide variety of products and type of plants operated in Firestone's organization it is necessary that manual be custom to fit plant groupings These groupings are presented as follows
the
1. Tire Plants
a Domestic
b Foreign
C. Licensee
Textile Plants
3 Industrial Products Plants
4
8.10.
Steel Products Plants
Foam Rubber and Polyurethane Plants
Plastic Products and Plastic Resins Plants Defense Products Plants
Rubber Reclaiming Plants Synthetic Rubber Plants
Research
The master copy of the manual will be kept by the Home Office Interplant Department It will contain the complete edition of the Administration Manual The manuals sent to each plant will contain only the information which applies to the particular plant
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40650
Responiblty
Responsiblity
ba
SUBJECT TO DISCLOSURE RESTRICTION
4065410651 40651 40651 40651
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
VOLUME
I
~ - Section II RESPONSIBILITY FOR SAFE PLANT OPERATION __ Page
A.
Date
11-4-63
Part
1 COMMUNICATION SYSTEM
Cancels None
A. DEPARTMENTS ISSUING INSTRUCTIONS AND PROCEDURES
Within the Firestone organization many departments are charged with
responsibilities concerning problems of Health Safety Engineering and Property Protection and with the issuance of instructions standard practices and procedures The departments most directly involved within the Home Office include the Safety Insurance Production Technical Medical and Engineering
departments
The purpose of this manual is to coordinate consolidate and collect into one manual for company and plant use the cooperative efforts of these departments in
dealing with the problems in this management area Each department is responsible for the subject matter presented in its section of the Manual
New additions to the manual should be approved by the following managers for
those sections under their control
Technical
Insurance
Director of Research
Insurance Manager
Safety Medical Engineering
Plant Protection
Safety Director
.
Medical Director
Chief Engineer Plant Protection Manager
B. OPERATION OF THE SYSTEM
As is the current practice all important matters dealing with Health Safety Safety Engineering and Property Protection should be released to the plants using the Interplant Release Method - Code 10 A Communication System Chart is presented on the following page to outline the release method
Within the Home Office the various departments work and cooperate on problems of employee and property protection after a problem has been investigated and discussed with top management a formal release is made The release method
insures that the contents of the release are directed to the attention of the proper
plants and Plant Personnel
5-4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
4065240652 40652 40652
5
Section II
Part
1.
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
RESPONSIBILITY FOR SAFE PLANT OPERATION
COM UNICATION
COMMUNICATION SYSTEM
VOLUME Page
Dato
Cancels
I B.1 11-4-63 None
PROTECN
PROERTY
&
ZWODGHERIN
SAFETY
BRALTE
1-4771
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40653
Section II Part I
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
RESPONSIBILITY FOR SAFE PLANT OPERATION COMMUNICATION SYSTEM
VOLUME I
Page 2.1.B.3 Dato 12/29/69
Cancels None
INTERPLANT RELEASE RESPONSIBILITY FOR ADMINISTRATION MANUAL
ISSUED TO
PLANT MANAGERS SAFETY ENGINEERS ALL PLANTS - DOMESTIC & OVERSEAS
NO
IP.10-38 IP.10-38
PAGE_
1 of 1
PAGE_
ISSUED 12/29/69
M. R. BATCHE
ISSUED BY H. WEATHERBE
APPROVED BY T. CAHOON_
SUBJECT
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Until this release information and additions for the Administration
Manual Health Safety Engineering & Property Protection Volumes I and II have been released to the plants through Interplant Department Akron by means of the Interplant Release system as noted in Section II Responsibility
for Safe Plant Operation Communication System Volume I Pages 2.1.C.1 thru
_ Effective with this release Home Office
responsibility for the Administration Manual
essential Master Copy content
releases of
additions and revisions information
Corporate Safety is assuming Volumes I and II including
and the distribution of all
Until further advised all communications relating to the Administration
Manual should be directed to Corporate Safety Personnel Relations Akron
Although there are no extra copies of the Administration Manual pre-
sently available Corporate Safety is updating and revising the manual to
reflect latest in topics of industrial hygiene safety and fire prevention
Additional Additional copies can be made available upon completion of the planned
revisions
revisions
4273
The Firestone Tire & Rubber Company
RECEIVED
8 1969 JAN
WILSON
G. L. WILSON
SUBJECT TO DISCLOSURE RESTRICTION
406406554440654 40654 40654
II Section
Part 42 1
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
RESPONSIBILITY FOR SAFE PLANT OPERATION COMMUNICATION SYSTEM
VOLUME
Page
Date Cancels
I 2.1 11-4-63 None
C. CONTENT AND FORM OF THE RELEASE
1. Additions To The Manual
This manual has been written incorporating the code 10 releases issued up to the manual was released To help insure that the manuals are kept up to date
and are accurate all releases will be distributed in the brown Firestone Mail envelope Form 3060M When new pages are received the new material should
be correctly inserted into the manual the cancelled pages placed inside the mailing envelope and returned to the Akron Interplant Department This department will use the returned material for a feedback check to assure that manuals are kept up to date
For the manual to provide maximum service and usage the manual must be accurate and up to date It will be the policy to continually remove and
replace pages which become obsolete
2. Form 4273
All releases should be typed on yellow mats Form 4273 using an electric typewriter After typing the Ediphone Department will multilith the required number of copies These should then be given to the Interplant Department for
distribution
Distribution of Materials Releases
Distribution will be made to those persons as indicated on the distribution list
on pages viii ix and The release should be custom made and issued only to the plants for which it applies
Master Copy
The Interplant Department copy will be the Master Copy against which titles page numbers and dates etc. should be checked
5. Use of Names
It is recommended that person's names not be used throughout the manual except in the distribution listing and in the issuing and approval of release
5-4278
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40655 40655 40655
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
section II RESPONSIBILITY FOR SAFE PLANT OPERATION
VOLUME Pago
I 2.1
Part 4 COMMUNICATION SYSTEM
Cancels 11-4-63
C. CONTENT AND FORM OF THE RELEASE CONTINUED
This recommendation is made because of the change retirement and relocation of personnel and the need to keep names and locations up to date Instead of personal names it is recommended that job titles be used such as Plant Manager Plant Engineer Chief Chemist
etc.
6 Title Page
This page should be separate from the text pages which are to be inserted into various sections of the manual It should have the
following necessary information in addition to comments upon the
release The title page is usually presented on plain paper as shown
in the example which follows
Drawings
Large drawings and bulk printed matter issued with the release which are not included in the manual should be accurately described for
references purposes
tn
The Firestone Tire & Rubber Campeny SUBJECT TO DISCLOSURE RESTRICTION
40656 40656 40656 40656
-
Section
Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
II RESPONSIBILITY FOR SAFE PLANT OPERATION
1. COMMUNICATION SYSTEM
VOLUME
Date Cancels
I 2.1
11-5-63 None
INTERPLANT INTERPLANT RELEASE
. Issue To Example
All Tire Plant Managers Domestic and Foreign as per approved list
Example Synthetic Rubber Plants as per approved list
No Interplant Release Number Page
Issued Effective
Issued By Approved By Approved By
SUBJECT
Title of the release
Page No.
Manual page numbers
COMMENTS
Comments concerning the release
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HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
VOLUME
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Date
2. FUNCTIONAL RESPONSIBILITIES
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A. RESPONSIBILITIES OF HOME OFFICE DEPARTMENTS
The chief executive has the responsibility for the performance of company policy determined by the Board of Directors and he in turn delegates areas of responsibility to the various functional executives The functional groups cooperate with each other to prepare and assemble instructions procedures and standard practices which are presented to the Plant Managers and plant level managers for performance and execution
1 PRODUCTION MANAGEMENT FUNCTION
The Home Office production management function is to direct the operation and production of the plants in producing Firestone products It is the responsibility of this function to develop coordinate originate direct and administer programs covering the protection of employees and property
2. SAFETY MANAGEMENT FUNCTION
The following is a resume of the responsibilities of the Home Office Safety Department
a The Manager of the Safety Department reports to the Director of Industrial Relations and is responsible for coordinating and managing the Safety Program in all company plants He originates develops and coordinates the accident prevention activities of domestic and foreign Firestone plants The manager of Safety acts in an advisory capacity to the Plant Safety Engineers
b The Safety Manager formulates safety procedures and refinements on Safety Policy for use in all Firestone plants to prevent and reduce the frequency and severity of accidents
C. The Safety Manager develops and maintains an expert knowledge of the principles of Industrial Safety He maintains expert knowledge of safety procedures and instructions and supervises the preparation and distribution of all necessary safety and accident reports and the supplying of safety information to all plants He further serves in an advisory capacity to management and subsidiary plants with respect to safety work
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HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
VOLUME I
-
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Part
2. FUNCTIONAL RESPONSIBILITIES
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d The Safety Manager has the responsibility to keep up to date in development and research in the field of safety
e The Safety Manager has the responsibility to keep up to date on the Safety operating conditions in all plants He inspects Akron and subsidiary plants analyzing operating conditions from a Safety viewpoint and confers with the plant management upon his findings
f The Safety Manager is responsible for the control and functioning
of the Union Management Safety Committee The work of this
committee pertains to safe work practices sanitary and healthful working conditions
3. ENGINEERING MANAGEMENT FUNCTION
The engineering management function is responsible for directing the engineering department activities as they relate to the problems of
protecting employees and property Included in these responsibilities
are the following
a The engineering design and installation of new and existing plants processes equipment and machinery based upon recognized safe engineering practices
b Cooperation with Home Office departments in the development and maintenance of an effective Safety Inspection Program To further check upon the effectiveness and operation of the program by means of feed back inspection reports and on the site inspection
C. To initiate corrective action to correct unsafe conditions as they
are discovered or made known
d To assist and cooperate with the Production Safety Medical Technical and Insurance departments their responsibilities
4. INSURANCE MANAGEMENT FUNCTION
The following is a resume of the insurance management responsibilities as they relate to the protection of employees and property
}
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ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
VOLUME I
II RESPONSIBILITY FOR SAFE PLANT OPERATIPOagNe
2.2
2 FUNCTIONAL RESPONSIBILITIES
Cancels None
Purchase and maintain adequate insurance coverage in accord with company policy at the lowest possible cost
Process and negotiate all claims resulting from insurable risks Maintain loss statistics by individual property
Review and evaluate inspection reports made by both our plants and insurance companies Review and evaluate plans and processes for fire protection and pressure vessel safeguards for new properties and additions to present properties
Responsibility for preparation of standards and procedures relating to fire protection safeguarding boilers and pressure vessels and other hazards covered by property insurance
Make recommendations to Management of suggested improvements in company policy procedure and techniques appertaining to
Insurance and Fire Protection
Knowledge of operating conditions in all properties and up to date developments in the field of fire protection engineering throughout
the world
g At Management request visit our properties to review property protection program assist in loss adjustment and procurement of
insurance coverage
Coordinate with Engineering and Purchasing Departments in the procurement of approved equipment and devices so as to secure maximum protection at minimum cost
i Coordinate with Laboratory Safety Engineering Medical and Purchasing Departments when new hazardous chemicals or materials are to be used by assisting in preparing a safe procedure
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HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
II RESPONSIBILITY FOR SAFE PLANT OPERATION 2. FUNCTIONAL RESPONSIBILITIES
VOLUME
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Date Cancels
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5 MEDICAL MANAGEMENT FUNCTION
The responsibility of the Medical Department can be divided into four main categories
I. Care of the Injured
It is the responsibility of this department to direct the care of all injured persons This is to be accomplished either by direct care within the plant dispensary or by the use of expertly trained
consultants The selection of these consultants and their use on
any particular case is the sole responsibility of the Medical Department Department
II
Employee Health Protection and Maintenance
It is the responsibility of the Medical Department to maintain a program of preventive . medicine for the protection of the Company and the employee This program should provide for
III
1. Preemployment placement examinations 2. Physical rechecks on rehire and following sick
leaves
3. Work capacity evaluation to guide the Employment
Office in placement of individuals who have developed physical limitations 4. Evaluation of partial and total disability applicants
Industrial Hygiene Department
In order to safeguard the work environment of the employee the Medical Department must maintain an adequate Industrial Hygiene Department The detailed responsibilities of this department are described in another section of this manual
IV
Miscellaneous
It is the further duty of the management in all medical
the subsidiaries
Medical matters
Department
in Akron as
to advise well as in
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ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
II RESPONSIBILITY FOR SAFE PLANT OPERATION
2
FUNCTIONAL RESPONSIBILITES
VOLUME I
Page 2.2 5
Date
9-20-62
Cancels
None
6 TECHNICAL MANAGEMENT FUNCTION
The technical management function is responsible to advise aid cooperate and instruct the other functional areas in the safe handling
storage use and processing of all chemicals and related materials
used in Firestone Plants The department is also responsible for the issuance of Standard Practice Specification and advising of the fire explosive health hazards and technical information concerning the materials and chemicals used It is the responsibility of the
management to report to the Medical Department the names and information available on all chemicals pigments and materials with
known health hazards
PURCHASING MANAGEMENT FUNCTION
a Purchase of Chemicals
When new chemicals and materials are purchased for use in the plants the purchasing department is responsible to aid the other management functions in learning the health and safety hazards
involved in the use of these materials This may often be
accomplished by requesting the vendor to supply complete handling instructions and technical data concerning their product and delivering this information to the appropriate persons to receive it
In most cases the vendor is the best source of this information
and has it readily available
b Purchase of Approved Equipment
It is the responsibility of the purchasing department to purchase only safety equipment items approved by an accredited national safety organization as meeting the necessary safety requirements
CONTROLLING MANAGEMENT FUNCTION
The controlling management department has the responsibility to process insurance claims accurately and quickly working with the Insurance Department
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Date
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2 FUNCTIONAL RESPONSIBILITIES
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9
INTERPLANT MANAGEMENT FUNCTION
Issuance of Interplant Releases
It is the responsibility of the Interplant Department to make the formal issuance of Interplant Releases concerned with Health Safety Engineering and Property Protection The Interplant Department has the responsibility to determine that the release form is correct and that the releases are typed using an IBM
Executive typewriter on form 4273 The release should
clearly indicate the name of the person or persons and the plants to which is sent The department is responsible to keep the approved distribution list up to date and correct
Record System for Releases
It is the responsibility of the Interplant Department to keep the Master Copy of the Manual in the permanent interplant file under
Code 10 Health Safety Engineering and Property Protection formerly Safety It is further the responsibility of the depart-
ment to maintain an up to date listing of Code 10 releases by Title person issuing date issued and to whom sent and to revise
this list in the Manual as necessary
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ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
RESPONSIBILITY FOR SAFE PLANT OPERATION FUNCTIONAL RESPONSIBILITIES
VOLUME
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B. PLANT LEVEL RESPONSIBILITIES
Plant level functional managers are charged with the responsibility of execution and performance of the Health Safety Engineering and Property Protection Programs developed directed and administered by the Home Office To clarify these responsibilities each plant level function is considered separately
1
PLANT MANAGEMENT FUNCTION
The Plant Manager is the manager of the Plant Management Function He has the prime responsibility for the safe operation of the plant The word plant in this instance includes the physical plant the employees and outside personnel working in it also the management mechanics involved In filling these responsibilities the following are some of the things he will
want to do
a Present the Firestone Safety Program to the functional managers
b Make periodic inspections of the plant to determine if the policies instructions Inspection program test program and the issuance of reports are effectively and promptly being carried out
C. Make recommendations to Management of suggested improvements in company policy procedure and techniques
d
familiar with the contents of the Administration Manual
and the Factory Safety Manual
e As part of the continuing Inspection Program in each plant is located a file containing the Firestone Inspection and Preventive Maintenance System The record system is used to schedule instruct and record test and inspection procedures which are mandatory in Firestone Plants Included in the scheduling is an Annual Plant Inspection Report to be submitted by the Plant Manager to the President This very brief report is automatically
scheduled for attention once each year
2 PRODUCTION FUNCTION
The manager of the production function is the Production Manager Among this manager's responsibilities are included the following
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VOLUME I
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Date
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2 FUNCTIONAL RESPONSIBILITIES
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a The responsibility to determine that the Safety Programs are integrated and coordinated with the Production Programs This executive who is responsible for low production cost and high efficiency is also responsible for carrying out the accident prevention program
b The determination that Safety Instructions are included among the written operating instructions including check lists charts and drawings where required Specific safety instructions should be included to assure protection of personnel and equipment from designated hazards
C. A knowledge of the contents of the Factory Safety Manual and this
Administration Manual
d Responsibility for the training of employees in safe working habits
e Responsibility to determine that Safety & Health Hazards as they become recognized are corrected This responsibility includes
the correction of mechanical hazards fire hazards chemical hazards health hazards
SAFETY FUNCTION
The Manager of the Safety Function is the Safety Engineer included in his responsibilities are the following
a He is employed in a staff capacity and his authority is to advise the managers and supervision on problems encountered in providing safer working conditions processes and practices
b The Safety Engineer has authority to issue orders to supervisors when a definite hazard exists that endangers the Safety of employees
C. The Safety Engineer is responsible for the quality and reliability of the service advice and assistance that he gives to line management
E
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HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
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2. FUNCTIONAL RESPONSIBILITIES
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d The Safety Engineer's role in liason with the Plant Engineer and Staff Engineers performs the following services
1 Advise the engineer of personnel and safety requirements
2 Assist the engineer in complying with applicable safety codes and local state and national law requirements
3 Be thoroughly informed concerning current design and installation work and approve it from the Safety viewpoint so that all Safety questions and requirements may be comprehen-
sibly and quickly answered and any deficiencies found corrected
The Safety Engineer has the responsibility in installation Programs and processes to ascertain prior to the installation
phase that the program will meet the necessary safety
requirements
4 Assist the engineers in obtaining operating organization approvals involving Safety design early in the project
5 Assist the engineer by making analysis to determine economic justification of changes or inclusions in design of construction recommended for Safety Reasons
e Responsibility for knowledge of the full contents of the Factory Safety Manual Use this knowledge to assist the functional managers in carrying out their responsibilities
f The Safety Engineer's responsibility is to keep the Plant Manager informed on the effectiveness and operation of the Safety program
g The Safety Engineer has the responsibility to assist in the writing of Safe Practice Procedures for the plant
h The Safety Engineer has the responsibility to accurately report to the Plant Manager the status of mandatory Safety Inspections required by the Administration Manual
i Responsibility for the inspection of such safety equipment as is
not covered by the inspection program This would include such items as safety tools safety masks etc.
-
= ry
W.. @ O..LL Frases.
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VOLUME I
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2 FUNCTIONAL RESPONSIBILITIES
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4 ENGINEERING FUNCTION
The manager of the engineering function is the Plant Engineer a resume of his responsibilities ris as follows
a Responsibility for engineering specifications designs construction maintenance and utilities The engineering work in these areas should conform to Firestone Engineering Standards and recognized safety standards
b Responsibility for the maintenance and operation of a reliable
safety Inspection record system Responsibility for those items
in the inspection program as are assigned to the maintenance
department All items to be inspected and tested are included in
detail in this manual their responsibility assigned
They
include such regular inspection items as boilers pressure vessels
electrical equipment relief valves and others
c Responsibility for the knowledge of the contents of this Manual which apply to the engineering function The knowledge is important
in the instruction of foremen and craftsmen
5 CONTROLLING FUNCTION
The manager of the controlling function is the Controller In the area of Health Safety Engineering and Property Protection the responsibility of this manager is to accurately and promptly prepare loss and insurance claim reports as prescribed by standard practice procedure The information going into these reports is generally supplied by the Cost Accounting and Engineering departments
6 TECHNICAL FUNCTION
The manager of the technical function is the technical manager
operation of the laboratory this manager is responsible for the following
In the
FE,
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a The safe handling of chemicals and hazardous materials
b The responsibility to communicate his knowledge of the hazardous materials to the plant and members of the laboratory
C. The responsibility to make regular chemical safety checks and analysis as may be required
d The responsibility to prepare Standard Practice Specifications Specifications for plant operations
7. MEDICAL FUNCTION
The medical function on the plant level is the responsibility of the Plant Doctor in subsidiary plants he is usually employed on a part time basis dependent upon the medical services required in each particular plant His responsibilities include those outlined in the section under Home Office Medical Department Counsel and information on Medical problems should be obtained from the Firestone
Medical Director in the Home Office
8. PURCHASING FUNCTION
The manager of the purchasing function is the Purchasing Agent This manager is responsible to ascertain that only nationally approved safety equipment is purchased for plant use When purchasing chemicals and materials known to be hazardous the agent should secure safety and
medical instructions literature and recommendations from the vendor
The vendor is usually an excellent reference on these problems and has the information readily available
9. PLANT PROTECTION FUNCTION
The Industrial Relation's Manager is responsible for the management of the Plant Protection and Fire Fighting groups These include the plant guards and firemen Counsel and information on this function should be obtained through the Home Office Industrial Relations Department
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HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
III SAFETY AND FIRE INSPECTION PROGRAM
. MANDATORY INSPECTIONS
VOLUME
Page
Date Cancels
I 1.1 9-26-62 None
A. DETERMINATION OF INSPECTIONS REQUIRED
Because many equipment items are required to be inspected periodically by the insurance carriers and the laws of local state and federal government
it is necessary to establish in detail a Standardized Program of Regular Inspections The items specified for inspection by the program are the result of a coordinated determination made by the Safety Insurance and
Engineering departments The determination was made following a Survey of Safety Inspections made in Firestone Domestic Tire Plants The following charts list the items to be inspected the department accounts to be charged with labor and materials the departmental responsibility for making the
inspection the frequency with which the inspections are to be made and the
form number of the Inspection Report
ADDITIONS TO THE REQUIRED INSPECTIONS
Plants which require additional safety or fire inspections not shown on the list should notify the Home Office Safety Insurance or Engineering Departments immediately Inspections should not be added or deleted from the program without Home Office Approval
FREQUENCY OF INSPECTIONS
The frequency with which the inspections are to be made is based upon current practice in the plants or as required by legal requirements Frequency will be revised as the records indicate whether the frequency period should be lengthened or shortened It is the desire of management to make inspections as infrequently as possible consistent with legal requirements and sound safety and engineering practice
PROGRAM IMPROVEMENTS
All plants are requested to submit suggestions for improvements in form design instructions procedure and test methods to the Home Office in order that worthwhile suggestions may be adopted into the Inspection
Program
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HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section III SAFETY AND FIRE INSPECTION PROGRAM
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Part
2 INSPECTION SCHEDULING AND REPORTING
Cancels None
A. THE FIRESTONE RECORD SYSTEM
1. INTRODUCTION
A working safety inspection program is a vital necessity in the overall Safety Program in the Firestone Organization The Safety Inspection program insures that the plant operating facilities and equipment are under a systematic regular inspection program times This reliability provided by safety inspections reduces the possibility and probability that accidents will occur and therefore provides a plant in which it is safer for employees to work
To provide this thoroughly reliable inspection system the methods of scheduling and record keeping are combined with the Firestone Preventive Maintenance program All safety inspection records are coded in the Safety green color to keep them separate and distinct from preventive maintenance items Using this color coding system it is possible at all times to follow the items and records under Safety Inspection Control
2. SCHEDULING AND REPORTING
The Firestone Safety Inspection System and the Firestone Preventive Maintenance System are custom made around the Le Speedex system The three preventive maintenance forms and the Safety Inspection Report Forms are housed in a permanent easily accessible file for quick visual inspection and ready reference The system is simple and may be installed with a minimum of explanation and a minimum of supervisory time No slow or cumbersome paper work The System is designed to provide automatic scheduling of All Safety Inspections and Preventive Maintenance items with a maintenance history record and complete nameplate data for each major piece of equipment These forms were designed to provide for the proper data and to facilitate and simplify the recording of maintenance work and safety test and inspection reports
3. HOW THE SYSTEM WORKS
For each Safety Inspection Item or piece of equipment to be given a safety inspection or safety report to be prepared there is a Safety Inspection Work Order form which provides scheduling for that item This card is used for all scheduling regardless of nature of frequency
other than daily or weekly check list routines
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HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
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III SAFETY AND FIRE INSPECTION PROGRAM
2 INSPECTION SCHEDULING AND REPORTING
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Date
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A. THE FIRESTONE RECORD SYSTEM
3. HOW THE SYSTEM WORKS CONTINUED
All safety inspection items are filed under a main file divider entitled
SAFETY INSPECTION PROGRAM Behind this divider in the file is
located the Speedex inner guide The inner guide contains the alphabetical listing of the mandatory safety inspections This inner guide is used to easily locate the desired inspection record Complete information concerning the operation of the record system may be found in the Plant Engineer's Manual under Section II part 5 beginning with page 5.
THE BASIC FORM
The system provides for one card for each Safety Inspection or report
to be made A basic form is used for all items across the top of this form is located the months and weeks of the year A visible moveable
signal is attached to the form to mark the date of the inspection Along the right hand side of the form is located an area in which the plan for inspection is recorded by frequency code number of times a year the inspection is to be performed by a person or craft In the body of the form is printed the Instructions and Procedures to be followed in making the inspection Also included in the body is the record and report data to be completed during the inspection In the lower right hand corner is a distribution list specifying to whom a copy of the inspection report form is to be forwarded It is important that the distribution be made promptly as specified because the distribution is part of a feed back system of checking the regularity and quality of the inspections being made Note that no provision is made for scheduling recurrent daily or weekly inspections these highly repetitive operations are scheduled by the System but are checked on only a monthly quarterly or annual basis Each inspection item specifies the frequency with which the inspections
are to be made
HANDLING SAFETY INSPECTION WORK ORDERS
Each week all cards are scanned and the Safety Inspection Work Orders having a signal for current week are pulled This scanning and withdrawal require only a minute even in quite large systems The pulled Safety Inspection Work Orders are then used to reproduce work orders
needed as per schedule e one for each craft or person scheduled to perform the inspection The reproduction can be accomplished on a
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ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section III SAFETY AND FIRE INSPECTION PROGRAM
Part
2 INSPECTION SCHEDULING AND REPORTING
VOLUME
Page
Date
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A. THE FIRESTONE RECORD SYSTEM
5. HANDLING SAFETY INSPECTION WORK ORDERS CONTINUED
Bruning or similar type diazo process Distinctive color paper is used in making reproductions --- blue mechanics yellow miscellaneous green safety pink electrical and orange for lubrication This provides automatic routing by color An alternate method uses the color to indicate the day of the week rather than the craft )
As the Safety Inspection Work Orders are completed copies are made of the completed report and distributed to the persons specified in the distribution list At this time a new work order is refiled the signal in the visible margin is moved to the next week in the year that the inspection
is scheduled
6. RESPONSIBILITY ASSIGNMENT
It has been found helpful in establishing the Safety Inspection Program to assign the responsibility for conducting and following the inspections to a definite person The Safety Inspection Program - Responsibility
Assignment form is provided for this purpose The Safety items to be
inspected or reported upon are listed across the top of the report the names of persons assigned to follow the inspection are listed along the left hand side it is not unusual to have several persons following an important inspection however the number should be controlled A copy of the inspection report should be distributed to those persons
assigned to it usually one copy is sufficient in cases of joint responsibility
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Section III SAFETY AND FIRE INSPECTION PROGRAM
Part
1 MANDATORY INSPECTIONS
VOLUME
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Date Cancals
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A. DOMESTIC TIRE PLANTS AND CANADA
Item
Charge
M
C. Motor and Control
BOM & NAF Curing Presses
Cables
)
Safety trips
)
Pins
)
Pressure Switch
1 Form
BOM train
)
Safety Stops
)
.
Chain Blocks & chain links Inspect when used
Conveyor Belts Colson Jacks Inspect when used Calender & Mill Inspect when used
M M M M M
sss
sss sss
SSSS
SSSS SSSS SSSS
C. Motors and Control
Doors powered overhead
M M
Responsibility
M M M M M M M M
M M M M
M M
Frequency
Annually Quarterly Monthly Quarterly Quarterly
Quarterly Weekly
Quarterly
Quarterly Monthly
Quarterly
Monthly
Annually Quarterly
Form Number
S 4356
1 222 222 222 NNNN NNNN NNNN 2
35 4 35 6
78
Elevators Annual State
Electric Cables & Manholes
M
M
M
M
Annually 9
Annually
10
Fire Protection & Equipment Inspection S
Flap Mold Press Inspection
M
Grinding Equipment All Kinds
M
Hoists All Kinds
Hand Powered Tools Electric ground
M M
F.D. M
M M
Monthly
=
Quarterly
12
Quarterly
13
Quarterly
14
Semi Annually
15
Instruments Employing Radio Active
Source
Ladders Safety Aluminum
S
M
M
Annually
16
Annually
17
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A. DOMESTIC TIRE PLANTS AND CANADA CONTINUED
Item
Machine Feed Screws & Conveyor Safeties Inspect when used
Mold Breaker Inspection
Mold Hold Down Bolts
Charge
M
S S M
Pressure Vessels internal
ss
Pressure Vessels external
S
Pressure Vessels internal &
external
SS
Propane Bulk Storage weekly
SS
Report on Accidents & Happenings
S
Safety Manager's Inspection
S
Safety Shower & Eye Wash Fountains
Weekly
SS
Safety Relief Valves
S
Sewer Manholes Explosion Test
Weekly
ss
Safe Handling of Hazardous Materials
S
Respon-
sibility
Frequency
Form Number S 4356
M M M
M M
Quarterly Quarterly Quarterly
Annually
Annually
M F.D.
S
Annually
Quarterly
Occasion
S
Annually
E. M
Semi Annually
Annually
F. C.
Quarterly Annually
18 19 20
22 21
22 22
23
24 Sy
25 26
27 28
Trucks & Tractor Inspection Inspect when used
Tube curing Presses Transformer Inspection Report
M M M
Vulcanizers Safety Inspection Ventilation Post Cement Units
M M
M
Bi Monthly
29
M
Quarterly
30
M
Annually
31
Annually
32
Monthly
33
Welding Equipment Gas Inspect
when used
Window Washer Lag Screws Multi Plants
M M
M
Annually
34
Annually
35
CODE
M
S
-
M
-
Labor & Materials
Safety
Maintenance
F.D. -- D
- Fire Department
-- Production
- Departmental
E. C.
- Safety Engine
- Chief Chemist
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Section III
SAFETY AND FIRE INSPECTION PROGRAM
1
MANDATORY INSPECTIONS
VOLUME Page
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3. B. 11-14-62 11-14-62
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B. FOREIGN TIRE PLANTS
Item
Charge
M
C. Motor and Control
BOM & NAF Curing Presses
Cables
)
Safety Trips
Pins
) ) 1 Form
Pressure Switch )
BOM train
)
Safety Stops
)
M M M M M
SSS
SSS
SSS
Chain Blocks & Chain Links
Inspect when used
SSSn
Conveyor Belts
SSSn
Colson Jacks Inspect when used
S
Calender & Mill Inspect when used
S
C. Motors and Controls
Doors powered overhead
M M
Elevators Annual State Electric Cables & Manholes
M M
Responsibility
M M M M M M M M
Frequency
Annually
Quarterly Monthly Quarterly
Quarterly
Quarterly
Weekly
Quarterly
Form Number S 4356
1 N 2 2 2 2 2 N
M M M M
M M
M M
Quarterly
3
Monthly
4
Quarterly
5
Monthly
6
Annually
F
Quarterly
8
Annually 9
Annually
10
Fire Protection & Equipment Inspection
Flap Mold Press Inspection
Firestone Jacket Molds
S M M
Grinding Equipment All Kinds
M
Hoists All Kinds
M
Hand Powered Tools Electric ground
Instruments Employing Radioactive
Source
S
Ladders Safety Aluminum
M
F.D. M M
D. M. M
M M
Monthly
11
Annually
12
Quarterly
36
Quarterly
13
Quarterly
14
Semi Annually
15
Annually
16
Annually
17
/
4273
The Firestone Tire & Rubber Campany
SUBJECT TO DISCLOSURE RESTRICTION
40677 40677 40677
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
VOLUME I }
Section _III
SAFETY AND FIRE INSPECTION PROGRAM
Pago
3.1 B.
Part
1
MANDATORY INSPECTIONS
Date
Cancels
11-14-62
None
B. FOREIGN TIRE PLANTS CONTINUED
Item
Charge
M
Machine Feed Screws & Conveyor safeties Inspect when used
Mold Breaker Inspection
Mold Hold Down Bolts
S
S M
Pressure Vessels internal
ss
Pressure Vessels external
ss
Pressure Vessels internal-
external
S
Propane Bulk Storage Weekly
SS
Report on Accidents & Happenings
S
Safety Manager's Inspection Safety Showers and Eye Wash
Fountains
Safety Relief Valves Sewer Manhole Explosion Test
Weekly
Safe Handling of Hazardous Materials Shear presses
S
S
S
S S M
Responsibility
Frequency
Form Number S- 4356
M M M
Quarterly Quarterly
Quarterly
M
Bi Annually
M
Annually
M F.D.
Annually Quarterly
S
Occasion
S
Annually
S. E. M
Annually
Annually
F.D. C.
M
Quarterly Annually Quarterly
18 19 20
21 21
22 22
23
24 aa
25 26
27 28 37
Truck & Tractor Inspection
Inspect when used
M
M
Bi Monthly
29
Tube Curing Presses Inspection
Report
M
M
Quarterly
30
Transformer Inspection Report
M
M
Annually
31
Vulcanizers Safety Inspection
M
M
Semi Annually
32
Welding Equipment inspect
when used
M
M
CODE
M -
S
-
M
va
Labor & Materials
Safety
Maintenance
D. -
P
+
D
-
Fire Department
Production
Departmental
Semi Annually
34
E. C. -
Safety Engineer
Chief Chemist
5-4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40678 40678 40678
Section III
Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
SAFETY AND FIRE INSPECTION PROGRAM
VOLUME Page
I C.
MANDATORY INSPECTIONS
Cancels None
C. LICENSEE TIRE PLANTS
Item
Charge
M
Alternating Current Motor & Control M
BOM & NAF Presses
Cables
)
Safety Trips
)
Pins
)
Pressure Switch )
BOM Train
)
Safety Stops
)
M M M M
S sss sss
Chain Blocks & Link Chain
ss
Calenders & Mills Inspect when used
ss
D. Motors & Controls
M
Responsi bility
M
M M M M M M
M M
M
Frequency
Annual
Quarterly Monthly Quarterly Quarterly Quarterly Weekly Quarterly
Monthly Monthly
Annually
Form Number S 4356
1
2 2 2 2 2 2 N
3 6
7
Elevators Monthly
Electric Cable & Manholes
M
M
Annually
9
M
M
Annually
10
Fire Protection Equipment Inspection
S
F.D.
Monthly
11
Grinding Equipment All Kinds
M
M
Quarterly
13
Hoists All Kinds
M
M
Quarterly
14
Ladders Safety Aluminum
M
M
Annually
17
Mold Hold Down Bolts
M
M
Quarterly
20
Pressure Vessels Unfired internal
S
M
Annual
21
Pressure Vessels Unfired external
S
M
Annually
21
Pressure Vessels Fired internal &
external
S
M
Annually
21
f
4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
4067940679
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section
III
Part
1
;
SAFETY AND FIRE INSPECTION PROGRAM
MANDATORY INSPECTIONS
VOLUME I
Page
3.1
Date
11-14-62
Cancels NoneNone
C. LICENSEE TIRE PLANTS CONTINUED
Item
Safety Relief Valves Tube Curing Presses Inspection Transformers Inspection Report
Vulcanizers Safety Inspection
Charge M
S
M M
M
Responsi-
bility
M M
M
Frequency
Annually
Quarterly Annually
Annual
Form Number S- 4356
26
30 31
32
CODE
M
-
S
-
M
-
F.D. -
P
-
D
-
E.
-
C.
-
Labor & Materials
Safety
Maintenance
Fire Department
Production
Departmental Safety Engineer
Chief Chemist
ae
f
-4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
4068400680 40680 40680 40680
Interplanteus
InterplanteuseInterplanteuses
Interplanteus
SUBJECT TO DISCLOSURE RESTRICTION
40681
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section IV INTERPLANT RELEASES
Part
1. INTERPLANT RELEASES
VOLUME Page
Date
Cancels
I 4. A.
11-5-63
11-5-63
A. SUMMARY OF RELEASES
The following is a complete list of the Safety Interplant Releases issued to date by the various departments concerned with issuing Safety releases All formalized Health Safety Engineering and Property Protection instructions and information will be issued using the Interplant Release method When new information and instructions are received they should be immediately placed in their proper location in the manual
5-4273
'
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40682 40682 40682 40682
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
-
Section
IV INTERPLANT RELEASES
Part
1 INTERPLANT RELEASES
VOLUME
Pago
Date Cancels
I 4.1
11N-o5ne-63
A. SUMMARY OF RELEASES CONTINUED
Number
Title
Date Issued
Manual Location
_ 10-0
Welding and Cutting Operations
4-9-58
7.2
10-1 10-2 10-3
Pierce Tire Wrapping Machine
2-6-58
Storage of Materials in Outside Warehouses 3-18-58
Powder Actuated Hand Rem Stud Driver
6-2-58
10. A. 10. C.
10-4
Fire Prevention Factory Trucks and
Tractors
7-24-58
7.2.A.
10-5 10-6 10-7 10-8 10-9 10-10
10-11
Fire Prevention Factory Trucks and
Tractors
De Mattia Tube Curing Stand Safety
Hazard
Bagomatic Tire Press Safety
De Mattia Tube Curing Stand Safety
Hazard
Serious Accident
Banbury Safe Operating Procedure
Purple K Powder for extinguishing Flammable Liquid Fires
C 8-1-58
A.
1-30-58
10.
11-4-58
10. A.
3-4-59 5-25-59 9-25-59
10. Deleted 2. A.
12-3-59
Section VII
10-12 10-13
f
Fire Protection and Industrial Hygiene Recommendations for Handling and Storage of Pigment 12572
Safety Procedure Shear Strip
Tire Presses
4-6-60
A.
9-22-60
10.
4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40683 40683 40683
Section
Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
INTERPLANT RELEASES
1. INTERPLANT INTERPLANT RELEASES
VOLUME Pago
Date
Cancels __
1 4.1.A.3
5/18/65
11/5/63
11/5/63
A. SUMMARY OF RELEASES CONTINUED
Number 10-14
Title Curing Room Accident BOM Shaping
Date Issued
Manual
Location
1-17-61 10.2.E.1
10-15 10-16
Fatality in Tire Assembly Dept. -
Pratteln
Fire Protection - Storage and Handling
of Gaseous Hydrocarbons
4-10-61 4-12-62
10.2.D.2 7.2.A.31
10-17
Frequency of Pressure Vessel
Inspections
10-18
Horizontal Heater Door - Safety Devices
4-17-62 7.2.B.1 4-19-62 10.2.A.6
10-19
Fire Prevention Recommendations for
Research Chemical Physical and
Test Laboratories
4-27-62 4-27-62 7.2.A.25
10-20 Safe Handling of Hazardous Materials
4-22-62 8.2.B.1
10-21
Mandatory Inspection for Pressure
Vessels
6-20-62
10-22 Powder Actuated Hand Tools
11-28-62 10.2.0.1
10-23 Issuance of Administration Manual
11-15-63
10-24
Fire Hazard - Mark IV Narrow WSW Grinder
10-23-63 7.2.A.83
10-25
Fire Protection - Outside Storage of Propane Cylinders
10-26
Fire Protection - Post Dip Unit Operating Hazards
10-27 Tire Curing Press Safety and Insp
10-28 /
Spec 8575-280
Calibration on
Presses
Pressure Switch
BOM & NAF Tire Curing
4-3-64 4-3-64
4-13-64 4-13-64 1-4-65
7.2.A.10 7.2.A.10
12/31/64
477LM
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40664 40664
Section
Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
IV INTERPLANT RELEASES 1. INTERPLANT RELEASES
VOLUME
Pago Date
Cancels
1
4.1.A.4 4.1.A.4
12/29/69 5/18/65
A. SUMMARY OF RELEASES CONTINUED
Number
Title
10-29
Safety Rules & Procedures for Contractor's Employees
Date
Issued
1-7-65
Manual
Location
5.3.A.I
NOTE Certain releases from March 1965 through July 1968 although
pertaining to the Administration Manual were numbered in the Index
Number Series IP.O under Interplant Release Method of the Plant
Engineer's Manual Section V Part 1
to complete the list of Health Safety
Page 5.1.1 but are recorded here Engineering and Property Pro-
tection releases for the Administration Manual
.
IP.0-80
Adm Manual - Vol I Ind Hygiene -
Health Hazards & Their Control Pages
IP.0-82 IP.0-82
IP.0-83
Adm Manual - Vol I. - Ind Hygiene Health Hazards & Their Control Page 6.2.C.15 Section VI Part 2
Adm Manual - Vol I - Ind Hygiene Health Hazards & Their Control Pages
5/3/65 = 6.2.0.15
IP.0-84
IP.0-85
Adm Manual - Vol I - Interplant
Releases - Pages 4.1.A.3 & 4.1.A.4 Section IV Part 1
Adm Manual - Vol II - Accident Pro-
ducing Physical Conditions and Their Control - Page 10.1.H.l Section X
Part 1
5/19/65 4.1.A.3
5/19/65
.
10.1.H.1
IP.0-87
Adm Manual - Vol II - Page 10.1.H.1 Section X Painting Standards Correction 6/15/65
10.1.H.1
10.1.H.1
IP.10-30 IP.10-30
Plant Engineer's Manual - Vol II
Safety Warning Lights for Plant
Vehicles - Page 7.2.C.l
8/20/65 = 7.2.C.1
/
5-4273
The Firestone Tire & Rubber Company
RECEIVE
8 199
JAN
INDUSTRIAL
SUBJECT TO DISCLOSURE RESTRICTION
4068540685 40685 40685
Section IV
Part
1.
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
INTERPLANT RELEASES INTERPLANT RELEASES
VOLUME 1
Page 4.1.A.5
Dato 12/29/69
Cancels None
A. SUMMARY OF RELEASES CONTINUED
Number
TITLE
Date
Issued
IP.0-89
Adm Manual - Health Safety Engineer-
ing & Property Protection - Letter on
Training Program & Safety Inspections
8/24/65
IP.0-90
Adm Manual - Vol I - Ind Hygiene -
Health Hazards & Their Control Page
6.2.C.16
8/24/65
IP.10-31
Administration Manual - Vol II Safety Warning Lights for Plant
Vehicles - Page 10.5.A.1
8/26/65
IP.0-92
Adm Manual - Vol I - Property Pro-
tection Protection of Property Hazards
Page 7.2.A.9 Section VII Part 2
-
1/17/66
IP.0-93
Adm Manual - Vol I Health Hazards & Their
6.2.A.3 thru 6.2.A.5
Industrial Hygiene Control - Pages
2/18/66
IP.0-95
Adm Manual - Property Protection Protection of Property Hazards - Vol I
Manual
Location
6.2.C.16 10.5.A.1 7.2.A.9
6.2.A.3
~
IP.0-97
Adm Manual - Ind Hygiene - Vol I Health Hazards & Their Control - Page 6.2.0.17
IP.0-100
Adm Manual - Vol I Health Hazards & Their 6.2.C.18
Ind Hygiene Control - Page
IP.0-101
Adm Manual - Vol I Health Hazards & Their
6.2.C.19 & 6.2.C.20
Ind Hygiene Control - Pages
IP.0-102
Adm Manual - Vol II - Safe Handling of Hazardous Materials - Pages 8.2.B.3 and 8.2.B.4
6/28/66 9/21/66 9/26/66 11/7/66
6.2.C.17 6.2.0.18 6.2.C.19 8.2.B.3
(
4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40636
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section IV
Pert 1
INTERPLANT RELEASES INTERPLANT RELEASES
VOLUME 1
Page 4.1.1.6
Cancels 12/29/69
A. SUMMARY OF RELEASES CONTINUED
Number
TITLE
IP.10-32
Radiation Type Instrument - Survey to Plant Engineers
IP.0-104 IP.0-104
Adm Manual - Vol I - Ind Hygiene Health Hazards & Their Control - Pages
Date Issued
12/8/66
Manual
Location
6.2.1.8 &
IP.10-33
Radiation Type Instruments - Instruction
to all plants on procurement
3/3/67
IP.0-106
Adm Manual - Vol I. - Ind Hygiene Health Hazards & Their Control - Pages 6.2.B.1 and 6.2.B.2
4/12/67
IP.0-107
Adm Manual - Vol I Health Hazards & Their
6.2.A.12 thru 6.2.A.15
Ind Hygiene Control - Pages
6/5/67
IP.0-108
Adm Manual - Vol I Health Hazards & Their 6.2.C.22 & 6.2.0.23
Ind Hygiene Control - Pages
6/27/67
IP.0-109
Adm Manual - Vol I - Engineering Govt
Regulations - Pages 5.1.1 thru 5.1.7
7/19/67
6.2.B.1 6.2.A.12 6.2.0.22
5.1.1
Health Hazards & Their Control - Pages
IP.0-111 IP.0-111
Adm Manual - Vol I Health Hazards & Their
6.3.0.24
Ind Hygiene Control - Page
IP.0-112
Adm Manual - Vol I - Ind Hygiene
Health Hazards & Their Control -
Pages 6.2.C.1 thru 6.2.C.12
IP.0-113 IP.0-113
Adm Manual - Vol I - Ind Hygiene
Health Hazards & Their Control -
12/4/67 6.3.0.24 12/13/67 6.2.C.1
/
5-4279
The Firations Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40687
40687 40687
Section IV
Part
1.
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
INTERPLANT RELEASES
VOLUME
Page
1
4.1.A.7
INTERPLANT RELEASES
Cancels 12/29/69
A.
SUMMARY OF RELEASES CONTINUED
Number
IP.0-115 IP.0-115
Title
Adm Manual - Vol I - Ind Hygiene Health Hazards & Their Control - Pages 6.2.A.6 & 6.2.0.27 thru 6.2.C.32
IP.0-116 IP.0-116
Adm Manual - Vol I - Ind Hygiene
Health Hazards & Their Control -
Date
Issued
4/30/68
Manual
Location
6.2.1.6 &
6.2.0.27
IP.0-117 IP.0-117 IP.0-118
Adm Manual - Vol I - Ind Hygiene Definition Scope Function & Organization - Pages 6.1.1 thru 6.1.5
Hygiene Adm Manual - Vol I - Ind
Health Hazards & Their Control -
.
6/17/68
6.1.1
IP.10-34 IP.10-34
Adm Manual - Vol I - Ind Hygiene
Health Hazards & Their Control -
oa
Sea8
IP.10-35 IP.10-36 IP.10-36 IP.10-37 IP.10-37
Adm Manual - Vol I - Ind Hygiene
Health Hazards & Their Control -
Pages 6.2.A.1 & 6.2.A.2 revision
5/8/69
6.2.A.1
Adm Manual - Vol I - Ind Hygiene
Health Hazards & Their Control -
Pages 6.2.A.20 thru 6.2.A.24
8/1/69
6.2.A.20
Adm Manual - Vol I - Interplant Releases - Pages 4.1.A.4 thru 4.1.A.7 and - Property Protection Plant
12/29/69
4.1.A.4
IP.10-38 IP.10-38
Adm Manual - Vol I - Responsibility
For Safe Plant Operation Communication
System - New Page 2.1.B.3 - Manual
12/29/69 responsibility assumed by Corporate Safety
Personnel Relations Dept. Akron
2.1.B.3
.
1
4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40683 40683
maniduith
Engiering
Engine ring
SUBJECT TO DISCLOSURE RESTRICTION
Section
Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
V ENGINEERING 1. GOVERNMENT REGULATIONS
VOLUME I
Page
5.1.1
Date 7-10-67
Cancels 9-12-62
LECEIVED LECEIVED LECEIVED
1 Atomic Energy Commission Regulations
C. L. WILSON
The subject of General Licensing Specific Licensing and
that part of the current Atomic Energy Commission Regulations regarding the posting of Form AEC is complex therefore to clarify the overall understanding of the subject in all its aspects the following summary is presented The purpose of this summary is to
a Present in one document the essential features of
General Licensing Specific Licensing and requirements relative to the posting of Form AEC
b To explain to the Plant Engineers their responsibility
with respect to radioactive gauges that are used in the
plant plant
C. To inform the Plant Engineers their responsibilities with respect to the maintenance of records as required by AEC regulations
It is pointed out that there is and will be increased activity on the part of the Atomic Energy Commission in making inspections at the plants of various users of radioisotope gauges These inspections cover a check of the radioactive gauge and its surroundings to determine that radiation levels are within certain limits and checking the records that
must be maintained
2. General
Licensing
Following is a general summary of licensing requirements and portions of the Atomic Energy Regulations that apply to Fire-
stone's use of radioactive gauges
General Licensing is a type of licensing procedure which has been established to simplify the distribution of certain radioactive gauges It applies to gauges that contain the radioactive source in a sealed capsule form which emits radiation at a level considerably below that which is harmful to human beings if subjected to such radiation for prolonged periods of time Under this system a vendor is permitted to distribute such gauges to various customers at his discretion
5-4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40690
Section
Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
V. ENGINELRING 1. GOVERNMENT REGULATIONS
VOLUME
I
Page
Date
7-10-67 7-10-67 7-10-67
Cancels 9-12-62
A. RADIOACTIVE TYPE GAUGES Continued
but to do this it has been necessary for him to obtain a Specific License In order that he may qualify for the Specific License required he has had to satisfy certain stringent requirements relative to the manufacture and safety of the radioactive material in question Once a user has obtained a radioactive gauge under the General Licensing procedure he has certain
responsibilities as follows
a To
Insure
Insure that Annual Source Inspections are Conducted
In this case the inspection must be made by persons licensed to do so The most straight forward method to handle this is to have the vendor conduct the tests
b Maintain Records of All Tests Which Have Been Performed
Such records should show the date on which the test was
performed the name of the person who conducted the test
and the results Other records which must be maintained are
those pertaining to the results of initial radiation surveys that were made at the installation site These records should have been furnished by the vendor at the time when the gauge was put on the General Licensing basis
c To Report any Incidents which May Have Damaged the Radioactive Source and To Report the Theft or Loss of Such Radiation Material
The specific responsibilities of the user in this connection are outlined in Part 20 titled Standards for Protection Against Radiation Title 10 Atomic Energy Rules and Regulations reprinted from the Federal Register An todate copy or these Rules and kegulations should be maintained in your files
Specific Licensing
Radioactive type instruments which do not qualify for General Licensing usually because of their inability to meet the requirements of radiation limits may be obtained on a Specific
License Under this system it is necessary for the user and
not the vendor to make application to the Atomic Energy Commissior for such a license Usually the vendor of such equipment will provide the necessary forms and most of the information that is to be included in these forms If the application is approved a Specific License is granted for a two year period Renewal of
4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40691
Section Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
V. ENGINEERING 1. GOVERNMENT REGULATIONS
VOLUME I
Pago
5.1.3
7-10-67
Cancels 9-12-62 9-12-62
A.
A. RADIOACTIVE TYPE GAUGES continued
the license is generally a routine matter of an application form in which the basic the original application is repeated
requiring submission
data as included in
When a radioactive
basis the user is
Title 10 of Atomic
gauge has been obtained on a Specific License bound by all of the regulations of Part 20 Energy Rules and Regulations
A gauge under Specific Licensing carries the same requirements
for annual source inspections as those obtained under
General Licensing However in this case it is the user's direct responsibility to have such tests made and to maintain
complete records relative to these tests Also as in the case
or the General License gauges it is necessary to report thefts
outlined or loss of radioactive material
to damage of the source as
and any incidents which may lead in Part 20
Regulations Covering the Posting of Form AEC
The section titled Instruction of Personnel Posting of Notices to Employees of Part 20 applies to the posting of notices to employees With respect to General Licensed Gauges the following is quoted from Part 31 General Licenses for Certain Qualities of Product Material and Product Material Contained by Certain Items Section titled Certain Measuring Gauging or Controlling Devices
Persons who own receive acquire possess or use a device pursuant to the general license in this Section shall be exempt from the requirements of Part 30 of this chapter except that certain persons shall comply with the provisions of section Reports of theft or loss of licensed material and Notification of incidents of this chapter From this it is apparent that posting of Form AEC is not required for General Licensed Gauges
In the case of gauges which are obtained on a Specific Licensing basis all sections of Part 20 will apply
In regard to the posting of Form AEC in relation to Specific Licensed Gauges the following is quoted from Part 20 Section titled Instruction of Personnel Posting of Notices to Employees
The Firestone Tire & Rubber Company SUBJECT TO DISCLOSURE RESTRICTION
40692 40692 40692 40692
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
;
V ENGINEERING
1 GOVERNMENT REGULATIONS
VOLUME
Page
I
5.1.4
Date 7-10-67
Cancels 9-12-62
A. RADIOACTIVE TYPE GAUGES continued
Form AEC shall be conspicuously posted in a sufficient number of places in every establishment where employees are employed in activities licensed by the Commission to permit employees working in or frequenting any portion of
a restricted area to observe a copy of the way to or
from their place of employment
Thus by reverse definition i.e. an unrestricted area
is defined as an area which is not classified as a restricted
area it is clear that posting of Form AEC is not required
in an unrestricted area
To further define an unrestricted area from Part 20 section titled Permissible
unrestricted areas
the following is quoted
Levels of Radiation in
Except as authorized by the Commission pursuant of this section no licensee shall possess use
licensed material in such a manner as to create unrestricted area from radioactive material and
sources of radiation in his possession
to Para a
or transfer in any other
a
Kadiation
tinuously receiving one hour
levels which an individual were conpresent in the area could result in his
a dose in excess of two millirems in any
or
b
Radiation levels which if any individual were tinuously present in the area could result in receiving a dose in excess of 100 millirems in
seven consecutive days
con-
his any
Therefore to avoid the necessity of personnel monitoring posting Form AEC Firestone's policy has been to insure all areas containing radioactive gauges can be classified
and that
as
unrestricted by keeping the radioactive levels below two
millirems per hour In order to confirm this independent third
party radiation surveys have been made on all gauges obtained
under a Specific License
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
4069340693 40693 40693
Section
Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
V. 1.
ENGINEERING
GOVERNMENT
GOVERNMENT
REGULATIONS
REGULATIONS
REGULATIONS
VOLUME
I
Pago
5.1.5
Date 7-10-67
Cancels 9-12-62
A. RADIOACTIVE TYPE GAUGES continued
5 Form
AEC
As previously outlined Firestone's policy has been to avoid the requirement of posting Form AEC however there may be
future installations where it may be necessary For this reason
certain sections of Part 20 are quoted below for your information
a Date of Revision
Form AEC has been
should be necessary current edition
subject to some revision to use subject form check
If it for
b
Reports on Your Radiation Exposure History
1
The AEC regulations require that your employer give you a written report if you receive an exposure in excess of any applicable limit set forth in the regulations or in the license The basic limits for
exposure to employees are set forth in Part 20 of the Regulations These sections specify limits on exposure
to radiation and exposure to concentrations of radioactive material in the air
c
2
If you work where personnel monitoring is required Pursuant to Part 20
2 Your employer must give you a written report of
your radiation exposures upon the termination
of your employment if you request it and
b Your employer must advise you annually of your exposure to radiation if you request it
Posting Requirement
Copies of this notice must be posted in a sufficient number of places in every establishment where activities licensed by the AEC are conducted to permit employees working in or frequenting any portion of a restricted area to observe a copy on the way to or from their place of employment
5-4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40694
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
VOLUME
I
Part
1 GOVERNMENT REGULATIONS
Date 7-10-67 Cancels 9-12-62
c
A. RADIOACTIVE TYPE GAUGES continued
d Unrestricted Areas
As indicated requirements for personnel monitoring are outlined in Part 20 of the Regulations It can be seen that monitoring is required for certain circumstances in restricted areas Thus it is not necessary for unrestricted areas Similarly the posting of Form AEC is not required
in unrestricted areas
6 Firestone Policy
Firestone's policy in compliance with
follows
relative to the use of radioactive gauges and
Atomic Energy Commission Regulations is as
a b
Whenever possible radioactive gauges are to be obtained on a General License basis Generally all calender beta gauges are on this basis Liquid level gauges and density gauges for the most part emit radiation levels that are too high to qualify for General Licensing and therefore require Specific Licenses
In order to avoid the posting
personnel monitoring devices
no restricted areas exist
of Form AEC
each gauge is
and the so made
use of that
7. Summary
Title 10 of the Atomic Energy Rules and Regulations which governs the use of Madioactive Type Gauges is frequently revised and updated Pursuant to Interplant Release No. I.P. 10-33 The Engineering Laboratory is responsible for checking compliances with subject Rules and Regulations and will notify the individual plants if revisions are made to the subject rules which will affect Firestone's policy in regards to radioactive instruments
It should also be the responsibilitoyr those using gauges to
keep the Engineering Laboratory fully informed of any rules and regulation changes on a state of local level which might affect Firestone's policy
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
4069540695 40695 40695
Section
Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
V. ENGINEERING
1. GOVERNMENT REGULATIONS
VOLUME
I
Page
5.1.7
Date
7-10-67
Cancals 9-12-62
A. HADIOACTIVE TYPE GAUGES continued
The above information is based on Federal AEC control within
the state Some states California Texas etc. have an agreement with the AEC under which the state assumes part of AEC's regulatory authority over the use of radioactive materials in that state Generally the state regulations are basically identical to the Federal regulations however where a user is within a state which has regulatory control the user must obtain and follow that state's regulations
5-4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
4069640696 40696 40696
DR L. H. BALLOU
MEDICAL MEDICAL
ADMINISTRATION
MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section
V - ENGINEERING
Part
3 - HAZARDOUS AREAS
VOLUME I
Page
5.3.A.l
Date
Cancels
1-7-65 None
A SAFETY RULES ANDPROCEDURES FOR CONTRACTOR'S EMPLOYEES IP 10 29
In order to promote uninterrupted progress to both the regular plant operations and new installations and provide maximum safety to all personnel the following plant rules are to be observed by the Contractor's employees
1. Smoking is prohibited at all times within or adjacent to the plant An
area at a safe distance from plant will be designated for this purpose Lighters or matches are not to be struck except in designated smoking
area
2. Safety glasses and hard hats provided by Contractor are to be worn at all times in the plant Protective clothing should also be worn as
necessary
3. Keep working area as clean as possible at all times Do not allow refuse and debris to accumulate Pile materials neatly and safely at safe distance from hot piping and off roadways and walkways Do not leave tools or materials on steps walkways platforms or elevated equipment or pipes Remove lumber with protruding nails to safe area and remove
or bend nails over
4. Materials are not to be thrown or dropped from scaffolds or other over-
head areas
5. Oily rags and waste are to be disposed of in metal containers and removed daily
6. Spills of any materials creating hazards are to be cleaned up immediately
FERRER EHHESA SE
7. Fire lanes and aisletso fire fighting equipment are to be left unob-
structed at all times
8 Material is never to be piled in front of fire extinguishers fire doors
hydrants or manhole covers
9. All electrical equipment used must be properly grounded
10.
Any lights carried into and used in hazardous locations must
explosion type These areas use only Class I Group D
equipment
be approved type
11
Use of Powder Actuated tools is prohibited
keene RHEE EE F
RECEIVED
JAN 11 1965
ATLU
The Fracture Tire & Rubber Campeny
DR H. BALLOU
SUBJECT TO DISCLOSURE RESTRICTION
40697
Section Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
V - ENGINEERING 3 = HAZARDOUS AREAS
I
VOLUME 5.3.A.2
Date 1-7-65
Cancels None
12. 13.
All ladders scaffolding hoisting equipment fork lift trucks must conform to ASA Safety Code and State Codes Ladders should be marked with Contractor's identification to prevent mixing with ladders belonging to the Company as well as any other equipment All Contractor's
equipment must be removed on completion of job
Before any hot work is started in an operating area approval must be
obtained from Plant Protection Hot work includes
a All welding
b Torch cutting
c Soldering
d Melting of metals
e Any operation where open flames or sparks are present
f Electric drills and air hammers
14
A Company fireman will stand by whenever it is necessary to do hot work in an operating area He is authorized to stop the work if conditions so warrant until it is safe to proceed again
15. Burning and welding is to be done by personnel skilled in these trades properly equipped and aware of safety requirements
16.
Whenever welding or cutting is done proper shields are to be used to
protect all other personnel within the dangerous area from eye injury
17
Necessary precaution and protection is to be exercised to prevent fires and damage from falling sparks from welding and cutting operations This must be done before the Plant Protection Department's O.K. will
be given for any hot work
18
All acetylene and oxygen cylinders that may be used must be properly supported when standing upright When hoses and valves are removed from cylinders the protective cap is to be installed on all tanks whether empty or full Acetylene cylinders when in use must have
a wrench on the valve
-
REHEEEREER HEE
19
Areas where overhead hazards excavations or other unsafe conditions exist must be properly blocked off with appropriate warning signs
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
4069408698 40698 40698 40698
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
V - ENGINEERING
VOLUME
I
Page
5.3.A.3
3 - HAZARDOUS AREAS
Cancels None
20. 21
In the case of excavations
shall be provided
barricades must be
provided
Night lights
Precautions must be exercised to prevent injury to regular plant em-
ployees This applies particularly to any operation of trucks and
power equipment
In the event a leak of oil gas or vapor is caused or discovered report it at once to nearest plant employee with request that he
immediately inform proper Fire Department and Safety Department
Written authorization shall be obtained from Fireman and Project
Engineer together with instructions regarding special precautions to be taken in the event any of the following operations become
necessary
a Entering any tank or closed vessel b Entering any deep pit trench or other enclosed area
C Cutting into a pipeline of any kind whatsoever
d Drilling chipping grinding or any other work which may produce flames or sparks
e Making air or water connections to any line containing
^ ils or chemicals
f Operating gas engine open electric motor switch or
plug connection in any area
KHE H ER N SE
23.
Employees will enter Company property and proceed to job site through gate and over road to be designated to Contractor prior to starting job
24.
Parking area for Contractor's employees will be designated to Contractor prior to starting job
25.
Contractor's employees will not enter Company property prior to twenty 20 minutes before scheduled starting time
26
Identification badges for all employees must be secured and displayed to Gate Guard on duty
27. Employees entering or leaving job site other than at shift change
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40699
Section Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
V - ENGINEERING 3 - HAZARDOUS AREAS
VOLUME
I
Pago VOLUME 5.3.A.4
Date
1-7-65
Cancels None
will require a gate pass approved by authorized personnel
28
A Package Pass properly approved must be secured to remove any per-
sonal property other than lunch boxes and clothing from the job site
Any personal article must also be accompanied by a Package Pass Packages lunch boxes clothing may be inspected by Guard at Gate as employee leaves
29.
Contractor's employees must stay in assigned area at job site and not visit other areas unless authorized to do so by Company representative
30
Use of toilet and washroom facilities is restricted to those designated
for Contractor's use
31.
Soliciting selling of
for any cause without property
any merchandise or distribution of any literature permission of Management is forbidden on Company
32.
Gambling or intoxicating liquor in any form are forbidden at any time on Company property
33.
Use of Company telephones is restricted to business calls only and is not to be used for personal calls
34. Horseplay throwing any object and scuffling are dangerous and strictly
forbidden
35
Contractor is to designate Hospital to which his personnel are to be taken in the event of an injury
Hee ERE HEE SE
Due regard for good safety practice is to be exercised at all times Work should be done in a manner so as to protect fellow employees and equipment Safety equipment only should be used and used in a safe manner Unsafe conditions such as obstacles in walkways improperly made electrical connections unstable piling of materials loose material overhead and tripping hazards
should be avoided
The foregoing rules are for the protection of both Contractor's employees and
those of the Company Full cooperation in observing all rules is required
PFK
1-7-65
THE FIRESTONE TIRE & RUBBER COMPANY
AKRON OHIO
5-4273
The FirestTo irne e& Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40700 40700
/
IndustrialIndustrial
Industrial
Hygiene
Hygiene
Hygiene
r
SMae. ad.
020D0 -20C00I 81RCASS1LSRANG,O MEUEERER, Z GROVE GA
Cea,
SUBJECT TO DISCLOSURE RESTRICTION
40701
VI Section
Part 1
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
INDUSTRIAL HYGIENE
VOLUME
Page
I 6.1.1
DEFINITION SCOPE FUNCTION & ORGANIZATION
Date Cancels
6-17-68 None
DEFINITION SCOPE ORGANIZATION AND
. FUNCTION OF
INDUSTRIAL
HYGIENE
Ir vest wa
~
Geurt
DEFINITION
.
Industrial Hygiene is the science and art devoted to the recognition
evaluation and control of those environmental factors or stresses
arising in or from the workplace which may cause sickness impaired
health and well being or significant discomfort and inefficiency among
workers The emphasis is on prevention of illness
SCOPE
.
The scope of industrial hygiene includes
;
1 Knowledge and r^cognitionof the environmental factors which
affect the worker This includes knowledge about the toxicity
and expected effects of excessive exposure to solid liquid and gaseous chemicals in the form of dusts gases mists fumes and vapors It also includes knowledge about physical agents such as noise heat light and ionizing radiation
2 Evaluation of these factors by quantitative measurement of their magnitude
3 Recommendations for methods of control or reduction when
"
necessary
In actual practice it is impracticable unnecessary and may be impossible for the user to avoid all contact with chemicals The practical approach is to keep exposure to a minimum This can be
accomplished by
1 Engineering control
2 Good housekeeping
3. Careful handling on the part of the individual user
5-4273
fy
SS
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40702
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section VI INDUSTRIAL HYGIENE
VOLUME I
Page
6.1.2
Date
6-17-68
Part
1 DEFINITION SCOPE FUNCTION & ORGANIZATION Cancels None
LIMIT =
4 THRESHOLD LIMIT VALUE
For many chemicals there is a guide used to evaluate whether a
concentration hazardous air
Limit ValueIt ValueIt is used as
is
an
present This guide is the aid in determining whether
Threshold
1. There is an inhalation hazard
1 he
Oe
The
2 Skin and mucous membrane absorption from direct contact may
contribute to overall exposure
X
Threshold Limit Value
V
1 Refers to the airborne concentration of a substance and
represents conditions under which it is believed that nearly all workers may be repeatedly exposed day after day without
adverse effect
2 Is used as a guide not as a fine line between a safe and a dangerous concentration
JTOXICITY HAZARD to It is important to make a distinction between TOXICITY and HAZARD
1. The TOXICITY of a chemical is defined as its capacity for
a
producing injury
2 HAZARD is the possibility that injury can result from the
-
quantity use of a chemical in the
term carries the connotation of
quantity and manner proposed
risk or chance
The
,
The industrial hygienist must take the position that all chemicals
have some degree of toxicity and that all chemicals can be used without
hazard if proper precautions are taken
.
Ar
esp
SUBJECT TO DISCLOSURE RESTRICTION
40703
Section VI
Part
1
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
INDUSTRIAL HYGIENE
DEFINITION SCOPE FUNCTION & ORGANIZATION
VOLUME
Page
Date
Cancels
I
6.1.3 6-17-68
None
Toxicity is often expressed as the quantity of a material required
to produce a given effect One scheme reference used by the Industrial
Hygiene Department as a frame of reference is
Commonly
Used Tera
hour
Vapor Exposure Causing 2 to 4 Deaths in Group
of 6 Rats ppm
Probable Lethal Dose for Man
Extremely toxic
Less than 10
Taste 1 grain
Highly toxic
10 to 100
1 tsp 4 cc
Moderately toxic
100 to 1,000
1 oz 30 gm
Slightly toxic
1,000 to 10,000
1 pint 250 gm
Practically
nontoxic
10,000 to 100,000
1 quart
Relatively
harmless
More than 100,000
More than 1 quart
ppm - parts per million parts of air
The hazard associated with the use of a chemical depends on
1. Its toxicity
2 The physical state under conditions of use
3. How much is being used
4 The manner of use which determines the dose and the route by which it enters the body
4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40704
Section VI
Part
1
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
INDUSTRIAL HYGIENE
DEFINITION SCOPE FUNCTION & ORGANIZATION
VOLUME
Pago
Date Cancels
I
6.1.4
6-17-68
None
Following are two examples which illustrate these factors
1 A pint of carbon tetrachloride in the hands of a bull in the china shop may be much more hazardous than a barrel of carbon
tetrachloride properly handled by an experienced cautious
worker When the quantity used is one drop the hazard is practically existent even for the bull in the china shop The important thing is not how much is used but how much goes
onto and into the user
2 A warehouse is filled with lead metal in the form of pigs The
total quantity of lead in a warehouse with 1 million cubic feet
of space might be 170,000 tons The lead is highly toxic As -
long as these lead pigs just sit there no hazard arises Now
presume that some of the lead is ground up into very fine dust
and becomes airborne throughout this same space Only about
1/100 of a pound tenths of an ounce is required to produce
an air concentration which is the maximum safe level for prolonged
inhalation exposure 8 hours each day Thus it is seen that a very
large quantity of a toxic chemical may produce no hazard but
that under different conditions a very small quantity of the
if. aus
same one may be hazardous
ORGANIZATION AND FUNCTION
ae
The Industrial Hygiene Department is organized as part of the
Medical Division in the Home Office in Akron
It makes industrial hygiene surveys on its own initiative and
upon request by management These surveys include air sampling and
analysis for air contaminants and spot consultation with management personnel followed by a written report of findings which
includes recommendations for correction of hazardous conditions
5-4273
-
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40705
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section VI INDUSTRIAL HYGIENE
Part
DEFINITION SCOPE FUNCTION & ORGANIZATION
VOLUME 6.1.5 Cancels 6-17-68
CAPS
and physical physical agents agents
industrial
hygienist
be
in advance
specific
chemicals
that
should
evaluated
visit The reason for this is simply that he must select and
bring to the plant the proper
matters instruments agents chemicals inin question .
+
instruments required to evaluate the
Department the The Industrial Hygiene
invites written or verbal
inquiries about specific chemicals their toxicity and handling precautions which should be used to minimize the hazards With sufficiently detailed description about the manner in which they
will
For
be used we a more complete
advise about the hazards which can arise
discussion refer to SAFE HANDLING OF HAZARDOUS
MATERIALS in Section 8 Safety of this Manual)
~ Le
5.4273
3 3
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40706
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section
Part
A.
VI INDUSTRIAL HYGIENE 2 HEALTH HAZARDS AND THEIR CONTROL
ENVIRONMENTAL
CONTROL OF
CLEANING SOLVENTS |
VOLUME 6.2A.1 6.2.A.1
Date
Cancels
Industrial hyper Part
General
There are many solvents some of which are mixtures of two or more chemicals marketed for machinery cleaning and general cleaning
Health and fire hazards develop when they are used in a manner
other than as intended
Control of Hazards Hazards ***
Cleaning solvents shall have a low health and fire hazard be used in a manner which minimizes the hazards Spraying
and shall shall be
increases done only with local exhaust ventilation spot ventilation as
spraying normally produces a large quantity of vapor Spraying the inhalation hazard and the fire hazard of flammable
solvents
When practical the items to be cleaned should be removed to a central cleaning station provided with local exhaust ventilation Where cleaning must be done in place the possibility of inhalation
exposure increases
*** Approved Cleaners
Code 321 11371
12045
12400 13020 259
CHEMICALS WITH A FLASH POINT BELOW 105 CLOSED CUP WILL NOT BE
USED AS CLEANING SOLVENTS
The above materials should be evaluated before more expensive
commercial mixtures are considered
Revised layout 5-4273
Revised
The FirestTo irne e&
SUBJECT TO DISCLOSURE RESTRICTION
40707
Section
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
VOLUME
VI
Page
6.2.A.1
CONTROL
Date
5-8-69
A. ENVIRONMENTAL CONTROL OF HEALTH HAZARDS -not repeated on every page page
3-4 fines CLEANING SOLVENTS -Alon't -Alon't underline underline
Approv1ed Cleaners Center-
12045
12400
RP 13020
259
CAIS CAIS
Chemicalswith a flash point below 105 closed cup will
not be used as cleaning
solvents
expensive expensive
2
not solvents unloated before be used
cleaning cleaning 2 General Commercial
solvents
mixtures
are
before considered considered
more expensive expensive expensive
There are many solvents some of which are mixtures of two or
more chemicals marketed for machinery cleaning and general cleaning Health and fire hazards develop when they are used
in a manner other than as intended
.
Control of Hazards
Cleaning
shall be
shall be
solvents shall have a low health and fire hazard and used in a manner which minimizes the hazards Spraying done only with local exhaust ventilation spot
ventilation as spraying normally produces a large quantity
Inhalation of vapor Spraying increases the
hazard of flammable solvents
Inhalation
hazard and the fire
Inhalation
When practical the items to be cleaned should be removed to a
central cleaning station provided with local exhaust ventilation Where cleaning must be done in place the possibility of
inhalation exposure increases
3-6-69 3-6-69 3-6-69 3-6-69
Old layout
The Firestone Tire & Rubber Company
RECEIVED
JUN 1969
G. L. WILSON
INDUSTRIAL HYGIENIST
/
SUBJECT TO DISCLOSURE RESTRICTION
40708
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section VI INDUSTRIAL HYGIENE
Part
A.
2 HEALTH HAZARDS AND THEIR CONTROL
-
ENVIRONMENTAL
CONTROL
VOLUME I
Pago
6.2.A.2
Date Cancels
5-8-69 6.2.A.2 6.2.A.2 6.2.A.2 2-12-69
dated
CLEANING SOLVENTS continued
Whether overexposure occurs depends on many factors
a Evaporation rate
b Chemical composition
C. Quantity and manner in which used
d Length of time involved
8 Frequency of use
f The size and general ventilation of the workplace
Exposure can be reduced or prevented by the most favorable combination of the above factors and by prevention of spillage
ees
devices
Inhalation can be prevented by the but workmen should not be expected prolonged periods when other means
use of respiratory protection to wear such equipment for
of control are practical
4. Special Operations
This directive does not apply to degreaser tanks manufactured
for use with a specific solvent and used in production operations
for metal
degreasing Dogrensery Dogrensery page Presently
Dogrensery See Metal
there are materials
Dogrensry
a
oe ~~ ae
:
those
than those listed above
which have been approved for specific cleaning operations
Those uses may continue but such materials must not be
diverted to other uses without approval from the Industrial
Hygiene Department
4273
The Firestone Tire & Rubber Campany
SUBJECT TO DISCLOSURE RESTRICTION
40709
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section
INDUSTRIAL HYGIENE
;
Part
A.
2
HEALTH HAZARDS AND THEIR CONTROL
ENVIRONMENTAL CONTROL OF HEALTH HAZARDS WA
| INDUSTRIAL RAY UNITS
lid General -:
=
ee
tS
VOLUME
Page
Date
Cancels
I
6.2.A.3 6.2.A.3
2-8-66 2-8-66 None
}
Part cs Hippe
Part
FEB 25 1966
G. L. WILSON
INDUSTRIAL HIGIMIHTIGIMIT
No threshold no effect level for ionizing radiation has been
generally accepted There is a normal background radiation to which man is always subjected Radium and uranium in the
earth's crust cosmic rays and naturally occurring radio-
active potassium contribute to background radiation It varies
with geographical location and altitude
a
In recent years there has been an increase in potential ion-
izing radiation exposure from the use of made radioisotopes and from equipment such as ray units which also produce ionizing radiation It is desirable to limit exposure from all man-
made sources to as low a level as is practical
Permiss Lei veb lsl+ e
-
we
At present the maximum permissible exposure for radiation workers in the United States is 100 millirem mrem per week
For others it is 10 mrem per week This maximum permissible
exposure for radiation workers has been lowered twice in recent
changed
again it is likely there would
iiff ther there there wwaa be a further reduction
Applicabk3 Applicabk3 Safe Operation Rules
-
Government
egulation 2.
2. ki National National Pub Sta
Pub
/ Sta
Government Government
Upon installation vendor shall make a radiation survey
instal ation the of the ray
insure that personnel are not over-
exposed applicable regulations recommendations
National
Bureau
of
Standards
Standards Standards
Standards
HanHadndbob ok Hoano dbokok
bak Si
miurken miurken
ittenh ittenh for ;
fat ...
Valen/t ele Valent
Hygiene :
5
beze uarduard dae!
. abt
rerepoprtort to to thethe IndIunsdutstrriiaal l HygiHygieneene DeDeppaarrttmmeenntt in Akron Akron
As soon as practicable after installation survey will be made by the Industrial or by an independent qualified expert
a radiation
Department
3. Radiation surveys shall
^Be made with an instrument capable of accurately
measuring radiation well below 2.5 mr
.
oa
measurements lets
XRAY
UNTESS y
(2)
Include measurements and below the
unity
floor UNTESS unit on the ground ground
floor
flo r H
When located ac flatre flatre
4273
.
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40710
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section
VI
Part
2
INDUSTRIAL HYGIENE HEALTH HAZARDS AND THEIR CONTROL
VOLUME I
re
Pago
6.2.A.4
Date
Cancels
2-8-66 None
Subsequent surveys shall be made as required If changes
are made in the unit or enclosure housing it report them
to the Industrial Hygiene Department as a survey may
enclosure be desirable A survey is Also required if the
housing
the unit is damaged
enclosure
Wy housing housing e The doors to the enclosure
the ray unit
shall be equipped with adequate interlock device which
make the unit inoperable unless the door are completely
closed The door shall be provided with knobs or handles
on the inside of the enclosure so that anyone locked inside
| accidentally can leave the enclosure without delay
@. Normally only the operator will be permitted in the control room while the ray unit is activated
~
\
Operators shall wear a device which measures exposure
en
Usually this will be a film badge changed at regular inter- *.-
vals The period of time between changes will be determined
by the Industrial Hygiene Department Prior to the installa
tion of a unit contact the Industrial Hygiene Department
stating the number of operators involved and the necessary
forms will be furnished so that the purchasing department
can order the badges
Federal state or local government regulations take dence over this guide where 1 there is a conflict
the regulations are more binding
prece-
or 2
5-4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40711
F
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section Part
VI
INDUSTRIAL HYGIENE
2
HEALTH HAZARDS AND THEIR CONTROL
VOLUME
Paga
I
.-
6.2.A.5
Date
2-8-66
Cancels Rome val
FEB 25 1566
In addition to the
requirements
Requirements and INDLETAJAI Requirements
WILSON INDLETAJAI +++ Regulations Regulations Regulations
WILSON
established by the United States
Atomic Energy Commission
bodies have
Regulations some other governmental covering devices which emit
ionizing radiation These requirements may cover
radioactive rays isotopes including radium and equipment which emits
centain They sometimes
registration of such equipment Make
centain
Regulations include with gauges that suchsuch Regulations Regulations are complied complied
Typical devices include level
thickness
and active substances industrial
ray units ray
using radio-
diffraction
units and devices used in systems for fire protection
should Make
izing radiation
certain that your operations involving ion-
-government comply with regulations
.
-government -government -government -government
requirements Refer to Vol I Sec V Part 1
Commission licensing
page 5.1.1 for Atomic Energy
relative to radioactive gauges
and to Vol I Sec VI Part 2 page 6.2.A.3 page
ments on industrial x'ray units
for
other
require-
5-4273
The FireTisret&oRunbbeer Company
SUBJECT TO DISCLOSURE RESTRICTION
40712
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section VI INDUSTRIAL HYGIENE
Part
2 HEALTH HAZARDS AND THEIR CONTROL
VOLUME I
Page 6.2.A.6 6.2.A.6
Date
4-30-68
Cancels
6.2.A.6
dated
10-29-62
hy _SIVPROM ENT CON TRUL FOR ETH
INDUSTRIAL VENTILATION
The standards of industrial ventilation to be followed in engineering design are presented in the manual -
INDUSTRIAL VENTILATION - A Manual of Recommended Practice
'
This publication is available from
Committee on Industrial Ventilation
American Conference of Governmental Industrial Hygienists
P. O. Box 453
Michigan 48902 U.S.A.
Lansing The 9thEdition Editioon f this ma{fnrual
f
#
1 iad
U
has recently been published
It
the library is a valuable addition to
ventilation problems And
The cost is 4
all
of engineers concerned with
plants should should Athe heyy
4273
The Firestone Tire & Rubber Company
RECEIVED RECEIVED
MAY 3 1968
G. L. WILSON
INDUSTRIAL HYCIENIST HYCIENIST
SUBJECT TO DISCLOSURE RESTRICTION
40713
Section
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
VI INDUSTRIAL HYGIENE
VOLUME
Page 6.2.A.7
Part
2. HEALTH HAZARDS AND THEIR CONTROL
Cancels None
A. ENVIRONMENT CONTROL FOR HEALTH
average concentrations of
Particulate load is one of the most Important factors Influ-
the
encing selection cleanen which ream inclinucludingding on this
of air a graph
which
that shows the
we are average
borne concentration of air
particulate matter under a wide
range of industrial conditioni
Particulate loads are commonly classified as
1. Light Laad to 1 grain per 1000 cu ft 2. Medium Lond to 1000 grains per 1000 cu ft
3. Henry Land
^/ndup
1000 cu ft 1 grain
grains 1000 cu - per
2.3 2.3
per cubic meter micro-
milligram grams per liter One milligram is equivalent to 0.015432
rains As a comparison the concentration of the U. S.
Bureau of Mines silica dust test is approximately 22 grains
per 1000 cu ft of air .
Normal load ranges may be listed as follows 1. Country 0.2 grain per 1000 cu ft
borne particulate matter
2. Small Town to 0.4
grains per 1000 cu ft
3. City Res to 0.8 grains per 1000 eu ft
City grains 4. City Ind to 2.0 grains
3.
Operations to 8.0
grains1 lb.
1000 cu ft
per 1000 cu ft 7000
In general the Particulate Cleaner types can be grouped
as follows with respect to load condition
1. Heavy Gravity Separators Cyclone Separators
Sonic Collectors
2. Medium Loada of the above plus
Filters Im-
pingement Type Box Filters and Wet Collectors 3. Light Lonch Filters of both types and
Precipitators
When MSA Ultra Filters are used in conditions of
heavy or medium loads one
be used ahead of it to reduce
or more
the load
of
to
the other types
a practical
types
must
EXPLOSIVE CONC OF BORNE OUSTS
FLOUR COAL
100000
DUST STORM
BALTIMORE ACME STD | MILWAUKEE
FLY ASH EFFLUENT
1000
MINE
MUCKING MUCKING pA COAL CUTTING
RAULING
ORIZZLE
BREAKING Ong
COTTON MILL
FICKING
WORKROOM AIR
= CARDING SPINNING WEAVING
' INDUSTRIAL DISTRICT AIR
|
VISCOUS FILTERS
Tf.
EFFLUENT AIR
FILTERS =f AIR CONDITIONING
POLLEN
:
INDUSTRIAL CLOTH FILTERS
FABRIC FILTERS
.001
1000000
LOW PRESSORE PNEUMATIC CONVETING
SAND AND
10000
STACK EFFLUENT
|| CONCENTRATION
STONE DRYING
BLAST FURNACE GREY FOUNDRY
CLOODBORST
OPEN HEARTH
ELECTRIC
SMELTERS | BRASS FOUNDRY
NAIN
MODERATE
FOR AND MIST
$ FOUNDNTFOUNDNT Ly
SHAKEOUT
SHAKEOUT
POURING MOLDING
WORKROOM AIR
WELDING COAL
Fe
ZO
^
| RENAL AND
SUBURBAN AER
CITY AIR
SILICATES 228
228 THRESHOLD LIMITS FOR
MINERAL DUSTS AND
.01-
TOXIC METALS
ELECTROSTATIC
FCIPITATORS FCIPITATORS
CELLULCOELUSLOSEE ASABESSTOSBESTOS
3000 .00001
.000001
THRESHOLD OF
QDORS
.0000001
.000000001
.0000000091 MILLIGRAM PER CUBIC METER The Firestone Tire & Rubber Company
THRESHOLD LIMITS FOR RADIOACTIVE ELEMENTS
. 2.4x10-
SUBJECT TO DISCLOSURE RESTRICTION
40714
DRAFT
August 25 1970
ra The following will replace the present issue on calibration
in Administration Manual
)
CALIBRATION
CALIBRATION - COMBUSTIBLE GAS DETECTORS
Combustible gas detectors should be checked for proper response at least every six months or whenever inaccurate response is suspected Instruments which do not show proper response should
be repaired
The response of such instruments can be checked in a few minutes
by using commercial test kits two of which are
1. W Gas Indicator Test Kit complete Cost 5.60 Catalogue No. 550-075 Williams Inc. Mountain View California
2. MSA Calibration Test Kit Part No. 454380 Cost 7.50
Mine Safety Appliances Company Pittsburgh Pennsylvania
safety safetysafety safety
Contact your local supply houses to obtain one
the Either of these test kits can be used to check (4
calibration of
combustible gas indicators of any manufacturer with reasonable
accuracy
a
~
ee
a
^>
GLW
SUBJECT TO DISCLOSURE RESTRICTION
40715
404707115 540715 40715 40715
> V
Section VI
_ ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROTEPC ROT TEICTOIONN
INDUSTRIAL HYGIENE
VOLUME Page
I
6.2.A.8
Part
2 HEALTH HAZARDS AND THEIR CONTROL
Cancels None
A. ENVIRONMENTAL CONTROL OF HEALTH HAZARDS
CALIBRATION OF GAS DETECTION INSTRUMENTS
Many brands and types of gas analyzing instruments which show the results by a needle reading are in use for the purpose of determining the air concentration of flammable gases Many plant protection departments have one It is important that the instrument manufacturer's instructions be followed closely in the use of these instruments in order to obtain valid results It is also important to make certain that the instrument is in calibration
A calibration should be made at least once a year either in the plant or by the manufacturer It may be made more often particularly if malfunction is suspected It is entirely possible for instruments to respond in an apparently normal fashion but to give erroneous readings
If the instrument is checked on a known vapor concentration of one sub-
stance say hexane and found to be in calibration it is highly likely that it is also in calibration for other flammable vapors for which it is
useful This is because one calibration checks the filament as well as
the other instrument components
Outlined herewith is a calibration procedure which may be used in your plant You should consult with your Chief Chemist on its use
CALIBRATION PROCEDURE
This procedure outlines a method for checking the calibration of gas analyzing instruments by passing a known concentration of a vapor mixture through the instrument The method is approximate and usable only with liquids which vaporize easily at room temperature Good and sistent results can be obtained when the proper consideration is given
the variables involved
con
to
The known sample mixture is prepared in a vessel of a size suitable to produce a volume of vapor in air considerably in excess of the flow requirements of the instrument being calibrated It has been found that a gallon carboy has sufficient volume for most instruments but in some cases where the instrument requires a flow as high as 0.2 CFM it is
necessary to make up the known concentration in two vessels and arrange
the flow of sample so that the atmosphere from one vessel is used to
replace the atmosphere in the second vessel
5-4273
The Firestone Tire& Rubber Gampeny
SUBJECT TO DISCLOSURE RESTRICTION
40716
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
;
Section VI INDUSTRIAL HYGIENE
Part
2 HEALTH HAZARDS AND THEIR CONTROL
VOLUME
Pago
Date
Cancels
I
6.2.A.9 12-13-66
None
A. ENVIRONMENTAL CONTROL OF HEALTH HAZARDS
CALIBRATION PROCEDURE -
Continued
The volume of the container Vc in the formula below is obtained accurately
by determining the amount of water required to fill it up to the bottom of the rubber stopper The container should be dry and purged of any combustible contaminants before it is used Purge the container by blowing compressed air through it for about 10 minutes between succeeding sample mixtures Place strips of cardboard 4 or 5 about " wide and " long in the container after the liquid material has been injected and vaporized
A convenient means of sealing the container while the sample mixture is being prepared is to disconnect the rubber tubing used for conducting the sample from the bottle to the instrument from the instrument and connect
it to the inlet tube of the container
The following sketch illustrates the recommended arrangement of the paratus when two carboys are used The inlet and outlet tubes from the
ssels are shown arranged for a vapor which is heavier than air as are
the vapors of the substances shown below
" I.D. Rubber Tubing Sample
Line to * Instrument
5-4277
Position of Tubing for Sealing Vessels
Vessels
~
ot
-
We
5/16 0.D.2
Copper Tubing
Hole
Rubber
Stopper
"
he 5 Gallon =>
<> el
Carboy
u
a
bard <->
Cardboard Strips for
Agitation of Sample
The Firestone Tire & Rubber Company
Air
_
Inlet
SUBJECT TO DISCLOSURE RESTRICTION
40717
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
.
Section VI INDUSTRIAL HYGIENE
Part
2 HEALTH HAZARDS AND THEIR CONTROL
VOLUME
Page
Date
Cancels
I
6.2.A.10 12-13-66
None
A. ENVIRONMENTAL CONTROL OF HEALTH HAZARDS
CALIBRATION PROCEDURE - Continued
When the container is ready for introducing the liquid which is to be vaporized the rubber stopper is lifted out and the desired quantity of
liquid is measured with pipette into it Replace the rubber stopper
immediately and allow to stand until all the liquid has vaporized Pick up container and turn it up and down for a minute or two The falling cardboard will mix the vapor and air The rubber tubing is then disconnected from the container outlet and connected to the instrument sample inlet As sample from the container is aspirated through the instrument air is drawn into the container and gradually displaces the vapor mixture This displacement or dilution is apparent by a gradual decrease in the instrument reading The instrument reading is compared with calibration
data in the instrument instruction book
The volume of liquid desired concentration
Vof
formula:
to be vaporized in the container to give the vapor in air is computed from the following
VVi = (
D1 x 2441,200
) * 27373-3-1-
)
27373-3-1- 27373-3-1-
) * ( 760
)
( 760 )
Where
V1 = Volume of liquid material in milliliters
= Desired vapor concentration in air in per cent by volume
Vc = Volume of container in cubic centimeters
M = Molecular weight of material D1 = Density of liquid material in grams per cubic centimeter
= Room temperature in C P = Barometric pressure in mm Hg
EXAMPLE
Required
The amount of liquid pentane to be introduced into a vessel of 30 liters capacity in order to produce a mixture which is
100 of the lower Explosive Limit L.E.L. of pentane in air
4273
The FirestTo irne e& Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40718
Section VI
Part
2
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
.
INDUSTRIAL HYGIENE
HEALTH HAZARDS AND THEIR CONTROL
VOLUME
Page
Date Cancels
I
6.2.A.11
12-13-66
None
A. ENVIRONMENTAL CONTROL OF HEALTH HAZARDS
EXAMPLE - Continued
D1 - Density of liquid pentane - 0.6262 grams per cubic
centimeter
M - Molecular Weight of pentane - 72.15
LEL- of pentane in air - 1.4 by volume
T - Room temperature - 23 C.
P - Barometric pressure - 739 mm Hg
Solution
= 100 of the L.E.L. of pentane = 1.4
Vc = 30 Liters = 30,000 cubic centimeters cc
Substituting in the above formula
x x V = 1.4
30,000
72.15
0.6262 x 2,241,200
X
273
) * (
)
273 273 23
( 760 )
or V1 = 1.93 cc This quantity is placed in each container
75 of L.E.L. Mixture would require 75 of 1.93 1.35cc 60 of a L.E.L. mixture would require 60 of 1.93 1.16 cc etc.
e.
The necessity for evaluating this formula for different conditions of temperature and barometric pressure can be determined by substituting
the maximun and minimum values of these variables encountered in the
laboratory It may be possible to considerably simplify the computation
by deriving a constant for the quantity
22,,224411,,22000 0
X
227733
273 T
x"by substituting average 760
temperature and pressure conditions
The following substances are suitable for use in calibration work
Substances
Molecular
Weight
Density in grams per cc
L.E.L.
% by volume
hexane
pentane
acetone
cyclohexane ethyl acetate
86.18
72.15
58.08 84.16
88.11
0.6594
0.6262
0.7908
0.7791 0.9005
1.2
104 2.5
1.3 2.2
-4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40719
Section
Part
- ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
VI INDUSTRIAL HYGIENE 2 HEALTH HAZARDS AND THEIR CONTROL
VOLUME Pago
Dato Cancels
I
6.2.A.12 6-5-67
None
A. ENVIRONMENTAL CONTROL OF HEALTH HAZARDS
Correction
Correction
HEAT STRESS
STRESS
THE EFFECTS OF HEAT CAN BE LESSENED
:
temperature 1 Cooling the man by blowing air over him provided the bulb temperature is not above body 98.6 F. If the bulb temperature of the air is above body temperature blowing air over the worker does not cool him it heats him even more and increases his discomfort An air movement rate up to 500 fpm may
not be objectionable
2. Lowering the temperature of the workplace
3 Limiting exposure time by rotating men or spelling
them off with replacements
L 4 Placing the man in a more hospitable environment For
example etc.
air conditioning in crane cabs control booths
5. Decreasing radiant heat exposure by use of shields between the radiating body and the man Aluminum
reflects 90 - 95 of radiant heat
60 Increasing intake of salt provided there is ample intake of water and providing this does not violate specific medical instructions
7.
Evaluation
Lowering the humidity which has the effect of allowing
perspiration to evaporate more rapidly This has a
cooling effect
.
HEAT STRESS EVALUATION*
It must be emphasized at the outset that if there are medically recognized heat stress cases there is a problem regardless of results calculated from temperature measurements and work performed however the
use of a Simplified Effective Temperature S.E.T. is a simple means
by which an approximate evaluation of heat stress is made
* This simplified method of heat stress evaluation is applicable in temperate zones but may not be applicable in extremely hot climates
;
5-4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40720
Section
Part
~
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
VOLUME I
VI INDUSTRIAL HYGIENE
2 HEALTH HAZARDSAND THEIR CONTROL
Page
Date
Cancels
6.2.A.13
6-5-67
None
A. ENVIRONMENTAL CONTROL OF HEALTH HAZARDS
HEAT STRESS Continued
The S.E.T. is calculated according to the following scheme
Wet Bulb Temp
70 - 75 F.
Simplified Effective Temperature
0.7 tw + 0.3 tg
Note
-
Above 80 F.
0.9 tw + 0.1 tg
where tw = wet bulb temperature in F tg = black globe temperature in F
The use of this scheme assumes air movement of at least 50 linear feet per minute
EXAMPLE
Problem The wet bulb temperature black globe temperature is 131 F. effective temperature
is 79 F. and the What is the simplified
Solution
Solution F.
0.8 tw
: Since the wet bulb temperature is
and 80 F. the correct formula see
+ 0.2 tg
79 F. between above
.
0.8 tw = 0.8 x 79 = 63.2
0.2 tg = 0.2 x 131
Total
89.4
The S.E.T. is 89.4
- See 6.2.A.14 6.2.A.14 and 6.2.A.15 for
measurements
-needed -needed andinstructions
^'
of equipment measurements 7
Application of the S.E.T. is as follows
The upper limit for light work is The upper limit for moderate work is The upper limit for heavy work is
90 88 80
SUBJECT TO DISCLOSURE RESTRICTION
40721
8
ee ee
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section VI INDUSTRIAL HYGIENE
Part
2 HEALTH HAZARDS AND THEIR CONTROL
VOLUME I
Page
6.2.A.14 6.2.A.14 6.2.A.14
Date
6-5-67 6-5-67 6-5-67
| Cancels None
A. ENVIRONMENTAL CONTROL OF HEALTH HAZARDS
HEAT STRESS Continued
Following are examples of light moderate and heavy work which may be used as a guide in evaluation of the operation in question
1 Light Work
plant tractor operation Green tire inspection Desk work such as typing Elevator operation Reactor operator Sitting with moderate arm
and
leg
movements
2 Moderate Work
a Banbury operator b Hand welding and cutting C. Cement mixer in adhesives operations d Splicer in tire plant 8. Building passenger *.--
Standing light wo
TEE. wef
Mee
=.
lift 1 Intermittent heavy lift
Fi Pick and shovel work
ashing or pulling
3 Loading tires into boxcar or trailer
THE BEST GAUGE IS THE MAN HIMSELF IF THERE ARE MEDICALLY RECOGNIZED
HEAT STRESS CASES THERE IS A HEAT STRESS PROBLEM
Determination
Determination SIMPLIFIED EFFECTIVE TEMPERATURE EQUIPMENT AND af
ITS
USE
1 Equipment
a Wet bulb thermometer
The wet bulb of a psychrometer such as Matheson Scientific Inc.
Catalog No. 31792-10 or equivalent may be used
insert proper pargem b Black globe thermometer See sketch on 6.2.A.^ 5
1 Thermometer graduated to about 150 F.
2
Copper toilet tank float painted flat black The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40722
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section VI INDUSTRIAL HYGIENE
Part
2 HEALTH HAZARDS AND THEIR CONTROL
A. ENVIRONMENTAL CONTROL OF HEALTH HAZARDS
VOLUME
Page
6.2.A.15
Date Cancels
6-5-67
None
HEAT Continued
3
Handle for copper float Use the brass rod which is
ordinarily a part of a toilet tank float assembly and
which screws into the float A wooden handle may be fitted onto the other end of the brass rod
4
A brass the end hole to
ring approximately 11/16 I.D. is soldered into of copper float opposite the brass rod after a accommodate the ring has been made
5
'
a
A # rubber stopper or cork with one hole in its
center into which the thermometer is inserted Adjust position of thermometer so that when the stopper is inserted into the brass ring the thermometer bulb is centered in the copper float
:
Wooden handle
SKETCH - Not to scale
<x Copper float ~ ee
Brass ring and stopper
oe
Brass rod
y
-
S
Thermometer Ss
C. A velometer or anemometer to check air movement
2
Use of equipment
a Hold wet bulb thermometer in the atmosphere to be tested
Follow the instructions for the instrument which is used
Make certain It dries out
that the wick on
rapidly when the
the air
thermometer
temperature
bulb is wet is high
particularly when hot objects such as tire molds are radiating
heat to the surrounding atmosphere
b Hold black globe thermometer in atmosphere to be tested 20 to 40 minutes may be required for it to reach equilibrium
C. Velometer or anemometer Follow manufacturer's instructions
4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40723
_ ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Ne
Section VI INDUSTRIAL HYGIENE
Part __ 2 HEALTH HAZARDS AND THEIR CONTROL
A.
ENVIRONMENTAL CONTROL
HEALTH
HAZARDS
VOLUME I
Page
6.2.A.16
7-16-68
Cancels 7-16-68
LABELING OF HAZARDOUS
SUBSTANCES
4-4 + General +++
author
.../
precautionary Manufacturers often use
industrial materials The most
labels on containers of hazardous
guide used is Manual 1 Guide
to Precautionary Labeling of Hazardous Chemicals published by
Manufacturing Chemists Association Inc. MCA
Manufacturing a
RWOE e,
TANG TANG tte
An understanding of the MCA system is an aid in determining the degree
of hazard An explanation of it follows
The following information may be included on the label
1. ProofdPu roc dut ct
Usually stated
The chemical name of the substance often given If the
complete chemical name is not shown the label will probably state the type of chemical for example Corrosive acid or
lead compound
2 The
Word
The signal words are
A. DANGER
B. WARNING
Co CAUTION
DANGER is the strongest of the three words and is used products presenting the most serious hazards CAUTION recommended for compounds presenting the least serious
WARNING is intermediate between danger and caution
for is hazards
RECEIVED
JUL 19 1968
G.
L.
-4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40724
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section VI INDUSTRIAL HYGIENE
Part
2 HEALTH HAZARDS AND THEIR CONTROL
A.
VOLUME
Page
Date
Cancals
I
6.2.A.17 7-16-68
None
3 Statement of Hazards
This statement will give notice of the hazards in connection with the customary or reasonably handling or use of the product Examples are
that are present anticipated
CAUSES BURNS
VAPOR EXTREMELY HAZARDOUS
Many chemical products will present more than one type of hazard the most serious hazard will usually be stated first
40 Precautionary Measures
These instructions are intended to supplement the statement of hazards by setting forth briefly measures to be taken to avoid injury or damage from the stated hazards Examples are
KEEP AWAY FROM HEAT SPARKS AND OPEN FLAME
AVOID BREATHING DUST
Precautionary
Measures sufficient
of hazards
may be included for hazards
importance to require mention in the ,
not considered statement of
Statements such as Do not take internally deserve special attention They are seldom necessary where the precautionary
measure to be followed is obvious For example when the
statement of hazards contains the words "
fatal
fatal
swallowed or when the word POISON is used this is considered
sufficient
4273
The Firestane Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40725
40725
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section VI INDUSTRIAL HYGIENE
Part
A.
2 HEALTH HAZARDS AND THEIR CONTROL
7
ENVIRONMENTAL
ENVIRONMENTAL
CONTROL
HAZARDS
VOLUME
Page
Date Cancels
I
6.2.A.18
7-16-68
None
LABELING
,? HAZARDOUS
SNUBSTANCES
continued
continued
5
Instructions
Case of Contact
Exposure
Although the primary purpose of labeling is to prevent injury
in or damage
included
instructions in case of contact or exposure may be instances where the results of contact or exposure
are severe and immediate treatment is highly desirable These
instructions are ordinarily limited to recognized first aid
procedures Instructions for medical treatment are usually
omitted except when specifically required by law or indicated
by special circumstances Because of the serious and lasting
effects which may result from eye injuries a recommendation to get medical attention usually accompanies any specific
instructions directed to treatment of the eyes highly toxic AND OR
The word PCISON was
crossbones on a label
used above This word accompanied
is limited to cases where the product
the skull and
is especially
addition
legend o Cht agh eoeusrwhweraerniitnsgu ssWehiesnpruseesdcrtihbeidsby law
take the place of the signal wind
addition
has it should should not
Care should always be exercised
in handling and storing containers of
hazardous materials and in removing the contents Instructions are
sometimes given in combination with the precautionary labels but are
sometimes on a separate label
A hazardous substance is defined as any substance or mixture of
substances which is
17 17 17 HiTgohxliyc hTiozxic
: Corrosive
23
3
An irritant
4-5 A strong sensitizer
6. A strong oxidizer Flammable Flammable
extremela
extremela
extremela
the
extremela
firmer
tiguid
78 Dangerously Dangerously Reactive Reactive
e
RACEIVED RACEIVED
** 19 1968
6. L. WILSON
INDUSTRIAL HYGIENIST
-4273
The FireTs iret&oRunbbeer Company
SUBJECT TO DISCLOSURE RESTRICTION
40726
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
.on VI INDUSTRIAL HYGIENE
Part
A.
2 HEALTH HAZARDS AND THEIR CONTROL
ENVIRONMENTAL CONTROL OF HEALTH
HEALTH
HEALTH HAZARDS
VOLUME I
}
Page 6.2.A.19
Date 7-16-68
Cancels Nore
Some
The
|
LABELING OF HAZARDOUS SUBSTANCES continued
9 Pressure generating generating generating ,
G PROVIDED
Or
which
which
.
generates
decomposition
decomposition
heat
or
other such substance or mixture of substances may
cause substantial injury or illness during or as a direct
result of any customary or reasonably anticipated handling
or use
of the
terms listed above are further defined
toxic on high substance further
7.
A corrosive substance causes destruction of
is one which in contact with living the tissue by chemical action
tissue
ay
7
An irritant is a substance which on
repeated contact with normal living inflammatory reaction
will immediate
tissue
prolonged or
induce a local
er
43. 43.
%
tissue A sensitizer is a substance which will cause on normal living
a sensitivity which becomes evident on reapplication
of the the same substance
K
Flammable y
the . within within ANY of
divided intoatent atent categories categories
folowing folowing following
.@
An extremely flammable flammable vapors at or
determined by open cup
liquid is one which
below a temperature testing
gives off of 20 as
b A flammable liquid is one which gives off flammable vapors above 20 to and including 80 as determined by open cup
testing liquid
which
C.
combustible liquid point Above including by open cup
80 to testing .
is one which has
and including
150
As
Salis
flash determindeetermdined
Manual
from page CA e I cop A tannadele gas ---
tannadele
Strong
gas
Mand Mand
MCA
. )
rapid rapid chelucent chelucent chelucent
changes nislead creption TheFirestone
|
Comperfeci iubstances
iubstanceiusbstances 8 c essent
essent
neay
of
Rubby
it contest contest
Comperfeci
Comperfeci
-- --nniissleald eandislead
atly
creption crecrepptiontion
creption
SUBJECT TO DISCLOSURE RESTRICTION
40727
40727 40727 40727
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section
VI INDUSTRIAL HYGIENE
Part
A.
2 HEALTH HAZARDS AND THEIR CONTROL
ENVIRONMENTAL
ENVIRONMENTAL
OF
VOLUME I
Page
6.2.A.20
Date Cancels
8-1-69 6.2.A.20
dated 7-16-68
4273
The Firestone Tire & Rubber Company
AUG111999 AUG111999
G. L. WILSON
INDUSTRIAL HYGIENIST HYGIENIST
SUBJECT TO DISCLOSURE RESTRICTION
Section VI
Part
2
A.
ENVIRONMENTAL
=
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
INDUSTRIAL HYGIENE
HEALTH HAZARDS AND THEIR CONTROL
ON
CONTROL
OF
HEALTH HEALTH HAZARDS
VOLUME
Pago
Date
Cancels
I 6.2.A.21
8-1-69
None
aa a
GENERAL GENERAL
Exposure to excessive noise permanent hearing loss
GENERAL for
ad
GENERAL GENERAL Oe
prolonged periods of time causes
that iN
tee 1.0.20
A Threshold Limit Value TLV established by the American Conference
of Governmental Industrial Hygienists in May 1969. Essentially the
same TLV has been adopted as
the U. s Department of Labor
Safety and Health Standards promulgated under the authority of the
Healey Act Noise is covered in Section 50-204-10 Subpart B
Part 50-204 - Safety and Health Standards for Federal Supply Contracts
The TLV has been adopted by Firestone as the guide to determine hazardous exposure and is as follows
PERMISSIBLE
NOISE
EXPOSURES
Duration of Daily
Exposure - Hours
8 6
3
2
1-1
1
3/4
3/8
1/44
Sound Level
Weighted
Network
dBA
90 92 95 97
100 102
105 107
112
115
No exposure allowed at any level over 115 dBA)
eal
-4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40729
SUBJECT TO DISCLOSURE RESTRICTION
40730
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section VI INDUSTRIAL HYGIENE
Part
A.
2 HEALTH HAZARDS AND THEIR CONTROL ENVIRONMENTAL CONTROL OF HEALTH HAZARDS
audiometer
continued
VOLUME
Page
Date Cancels
I
6.2.A.24
8-1-69
None
calibration and s
Octave band measurements no longer needed for determination of hearing loss hazard may be useful for determination of
1. The exact source of certain frequencies
2 Community noise nuisances
3. Speech and telephone interference
4273
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SUBJECT TO DISCLOSURE RESTRICTION
40731
Section
Part
A.
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
VI INDUSTRIAL HYGIENE 2 HEALTH HAZARDS AND THEIR CONTROL
VOLUME
Page
Date Cancals
I
6.2.A.25
5-7-70
None
ENVIRONMENTAL
HAZARDS
!
!
FIRESTONE TOXICOLOGICAL
DATA SHEET
The Firestone Data Sheet for Toxicological and Safe Handling Information was developed as an aid in securing toxicological and safe handling data A copy is reproduced as Appendix A to this page
A Data Sheet must be completed by the supplier before a new material is brought in even a small sample
The simplest and best procedure is that the plant purchasing department send out the forms for completion
Blank forms are available from the Home Office Industrial Hygiene
Department
not order
them from
Stationery
Stationery
. Completed
forms are necessary whether the material is to be used in production
laboratory research and development or pilot plant or as cleaning
Janitorial maintenance and engineering supplies
The name of the individual and the plant requesting data must be filled in first item on form prior to its submission to the supplier for
completion
Completed Data Sheets must be returned directly to the Home Office Industrial Hygiene Department Address is at the bottom of second page The reason for this is that in many cases confidential informa-
tion is involved
After review of the completed form the Home Office Industrial Hygiene
Department will make a write which covers handling precautions and
forward it to the plant Safety Department except that on RP numbers assigned in Akron the write will be forwarded through General Factory Technical Management
Some judgment must be used Following are typical situations in which
a Data Sheet is or is not needed
RECEIVED
JUN 5 1970 G. L. WILSON
INDUSTRIAL HYGIENIST
5-4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40732 40732
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
) VOLUME I
Section VI INDUSTRIAL HYGIENE
Page
6.2.A.26 6.2.A.26
Part
2 HEALTH HAZARDS AND THEIR CONTROL
Date
Cancels
5-7-70 5-7-70
None
SA.ENVIRONMENTAL CONTROL OF HEALTH HAZARDS
._
FIRESTONE TOXICOLOGICAL DATA SHEET continued
1.
Needed
a. Chemicals
b Mixtures of chemicals
c Unusual chemicals on which data are not likely to be available in our standard toxicology references
d Proprietary mixtures
-- Materials identified only by manufacturer's trademark
name or code number
2 Not Needed
a. New RP numbers where the proposed use originates in Akron Home Office Industrial Hygiene Department
will secure one)
b Materials such as steel machinery nylon or other materials which are physiologically inert
If there any doubt have a Data Sheet completed and returned
c;
5-4273-44
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
48733 48733 48733 48733
3341 REV 5-70
APPENDIAPPEXNDIX A FIRESTONE DATA SHEET
FOR TOXICOLOGICAL AND SAFE HANDLING INFORMATION Please Complete Applicable Sections on Both Sides
INFORMATION REQUESTED BY
Name
1. Product name chemical name number synonym
2. Physiological Properties Do not use numerical toxicity ratings unless the reference is given
a Acute oral toxicity
b Local effects upon eyes c Local effects upon skin d Acute & chronic inhalation toxicity
.
e Warning Properties Odor irritation to eyes nose or throat
Plant
f Estimated Threshold Limit Value if not on current list by American Conference of Governmental Industrial Hygienists __
3. First Aid Treatment
f
in contact
~
b Eye contact C. Inhalation
d Antidote in case of swallowing 4. Precautions for Normal Conditions of Use
5. Recommended Protective Equipment
6. Chemical and Physical Properties
a Specific gravity water
b Vapor density air
c Vapor pressure mm Hg at 25
d pH
e Corrosive action on materials such as aluminum magnesium plastics rubber lacquers enamels fabrics etc
f Does the material decompose violently when exposed to air Water Heat Strong Oxidizers
SUBJECT TO DISCLOSURE RESTRICTION
40734
. List percentage composition of ingredients including impurities
NOTE Proper chemical names must be known Generalizations such as petroleum hydrocarbons alcohols ketones
hlorinated hydrocarbons etc. are not adequate for toxicological evaluation
Compound
Percent
. Does the material generate heat through polymerization or condensation
. Flash point F Closed Cup :: Open Cup-
If F.P. changes during evaporation give data
.
j . Explosive limits % vol air Lower Upper
k . Susceptibility to Spontaneous Heating Yes
: No.
1. Fire Point F.
; Auto ignition temperature F
Vapor density
n . What products might be formed in the event of fire or abnormal temperatures
. Suitable extinguishing agents
7. Procedure in Case of Breakage or Leakage
8. Transportation and Storage Requirements
9. Has this product received acceptance by FDA or is work in progress to obtain such acceptance Give regulations where listed
10. IF THIS PRODUCT IS TO BE CONSIDERED ITS LABELS MUST BE ATTACHED HERETO
11. Information Furnished By
Title
Company
Address
Date
N
Information in regard to this material's composition will be treated as confidential and used only for
the purpose of protecting the health and safety of Firestone employees and the safeguarding of its property
Mail completed form to
INDUSTRIAL HYGIENE DEPT , MEDICAL DIVISION THE FIRESTONE TIRE & RUBBER COMPANY 1200 FIRESTONE PARKWAY AKRON OHIO 44317
SUBJECT TO DISCLOSURE RESTRICTION
40735 40735
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section
VI
INDUSTRIAL HYGIENE
=
' VOLUME I
Page
6.2.B.1
Part
2
HEALTH HAZARDS AND THEIR CONTROL
Cancels6.2.B.1 Cancels6.2.B.1 4-567 dated 3-24-65
B. PERSONAL PROTECTION EQUIPMENT ...
RESPIRATORY --
GENERO : 4 sua
PROTECTIVE EQUIPMENT .
While engineering controls should ordinarily be the first line of attack in preventing excessive exposure to air contaminants personal respiratory protection is useful for short periods of time or as an emergency measure until engineering controls can be installed
The U. S. Bureau
certain types of
of Mines has had a program of testing these devices for many years
thetreetre in queste ion question quesquesttionion question hashas
and approvingequipment
approved equipment
equipment
of Mines
The effective use of respirators requires a planned program with res-
ponsibility
ponsibility specifically person
~e
1 Selection RESPIRATORS WAS APPROVED BY BUREAU .
assigned to an adequately trained experienced
The following folowing are essential parts of the program
BY
BUREAU
-:
REFER TO
-
MINES
"
OF WHICH WAS WAS FOFORRWWARADERDDED
FORWARDED FORWAFRORDWEARDDED
TO
ALL
OF
device MINES COPY Select a devicedevice
inant present
that will protect adequately against the air contam-
There are several vital points which must always be
considered in the selection of equipment
Air
weconsidered Dust Respirators Are of No valve equipment The Air
i le Chemical cartridge respirators and gas masks used inside tanks and other enclosures where
high concentrations of toxic gases
is contaminant
than
contaminant than contaminant other must not be
there may be
it is A gas
Ok Vapor Vapor Vapor
30
de
Chemical cartridge respirators are emergency devices and
used in must never be
gas
masks
Gas masks and
used
To life
chemical
immediately atmospheres immediately
life
chemical cartridge respirators are of no value
where the atmosphere may be deficient in oxygen
immediately
immediately imediately imediately
Sedo Sedo
- -
7
qt
Gas masks with the proper canister are satisfactory for protection against low concentrations of many highly toxic chemicals but where chemical cartridge respirators are unsatisfactory Example acrolein aniline arsine carbon monoxide phosphorous trichloride ketene and many others
where
Supplied air respiratory protective equipment will be used where
there may be an oxygen deficiency or where high concentrations of toxic gases preclude the use of chemical cartridge respirators
or gas masks
Consult with the Industrial Hygiene Department in Akron prior to the installation or use of respirators fed by compressed air
from factory air lines
4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40736
eee
ee
ee
2
2) ADMINISTRATION MANUAL HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
;
Section
VI INDUSTRIAL HYGIENE
VOLUME I
;
Pago
6.2.B.2
Part
2 HEALTH HAZARDS THEIR CONTROL
Dato
4-5-67 4-5-67
6.2.B.2 dated 3-24-65
Va
B. PERSONAL PROTECTION EQUIPMENT
Consult with the Industrial Hygiene Department in Akron if any doubt
exists
+a 2. Instruction {77
5
"
3
Instruct the wearer in the need for using the device and the means by which protection is afforded Demonstrate and have
the
wearer practice obtaining proper facepiece fit and adjusting
manufactuRER'S manufactuRER'S for comfort and effective protection Follow the the
NS directions
manufactuRER'S
Supervision ...
Supervise to assure that the proper device is being used for
each exposure condition and that the device is complete and in
proper operating condition Supplemental safety precautions such as a life line and standby rescue personnel should be pro-
vided where needed
.
+ Cleaning 1-2: -*
Routinely used respirators should be cleaned after each use
Cleaning is best
the shift When
practical method
accomplished at a central point at the end of
a respirator is used by only one individual a of cleaning is as follows
a Remove filter or cartridge
23 Wash with detergent or soap in warm water 120 F.
3 Rinse thoroughly in clean warm water
4d Air dry in a clean area
5e 6.
p InasrpetcsItnspect valves headstraps and other parts replace defective
Insert filter or cartridge
There is no reason to require special sterilizing when a respirator
is used by only one individual When the same respirators are used
by different individuals a good public health policy is to disinfect
them before they are reissued The compounds generally considered
me
reliable for disinfecting are
4
4273
____ The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40737
40737 40737 40737 40737
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
~~ Section VI INDUSTRIAL HYGIENE
Part
2
HEALTH HAZARDS AND THEIR CONTROL
VOLUME
Page
Date Cancels
I 6.2.B.3 6.2.B.3 6.2.B.3
3-24-65
None
B.
PERSONAL PROTECTION EQUIPMENT
ppm a
a A hypochlorite solution 50 parts per million
of
chlorine immersion time 2 min or
b An alcoholic solution of iodine 50 ppm iodine 2 min immersion
7
Inspection and Maintenance - +
Devices used routinely can be inspected during cleaning and worn or deteriorated parts replaced with parts specifically designed for the particular respirator Filters or cartridges may be changed after each use or according to schedule
Emergency equipment shall be periodic intervals to assure
times
thoroughly inspected at scheduled
first condition at all
T
++
7
6. Storage
++
Store equipment in dustproof containers original cartons cases or plastic bags are suitable away from sunlight heat extreme cold and excessive moisture
If there are questions about respiratory protection contact the Industrial Hygiene Department in Akron
4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40738 40738
4073840738 40738
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section VI
INDUSTRIAL HYGIENE
VOLUME I
Page
6.2.B.4
Part 2
HEALTH HAZARDS AND THEIR CONTROL
Date
7-26-67
None
PERSONAL PROTECTION EQUIPMENT __ =
, +
L
GONEKAL GONEKAL 201 CONTAINED
BREATHING
EQUIPMENT
3
contained breathing equipment is useful where there may be insufficient oxygen or high air concentrations of toxic materials
14 1. Oxvzen deficiency -+ +-
1 Enclosures may be oxygen deficient because of
~~
1 a
Oxygen consumption by chemical or biological reaction with residues in the enclosure Even an
empty steel tank may lack sufficient oxygen to support
life because of rusting AiR
Water from the AiR over
2 in -
absorption of oxygen over the water a well
3 Oxidation during the curing and drying of paint
4
Partial or complete displacement of air by gases
vapors of volatile materials
----
Enclosures such as tanks vats silos pits and sewers may be
oxygen deficient and immediately hazardous to life even if toxic
are gases are absent The warning properties of an atmosphere de-
ficient in oxygen are completely inadequate The average individual fails to recognize the danger until he is too weak to
save himself especially where the return to good air involves
climbing stairs or a ladder One of the earliest effects of an
oxygen deficient atmosphere is an increased rate of breathing The increased breathing rate depletes the oxygen normally available in the lungs by ventilation so that even less is available for absorption into the blood
3 The normal oxygen content of air is about 21 Increased breath-
ing and pulse occur when it is reduced to about 16 Dis-
turbed respiration abnormal fatigue upon exertion inability
to move freely nausea and vomiting occur when it is reduced
to 14 More serious symptoms occur when the oxygen content of
although air is 10 The affected individual may collapse and although
aware of circumstancebse unable to move or cry out Below
respiration stops and heart action ceases in a few minutes
%
When
the oxygen in the lung atmosphere falls below 10 the arterial
blood supply to the brain becomes insufficiently oxygenated to
maintain consciousness This occurs in seconds not minutes
Respiratory failure and cessation of heart action soon follow
unless the subject is returned to respirable air Certain areas
4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
4073490739 40739 40739
Section VI
Part 2
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
INDUSTRIAL HYGIENE HEALTH HAZARDS AND THEIR CONTROL
VOLUME
Page
Date Cancels
I
6.2.B.5
7-26-67
None
_
i
B. PERSONAL PROTECTION EQUIPMENT
CONTAINED BREATHING EQUIPMENT Continued
of the brain are damaged if the oxygen supply is interrupted
for more than five minutes even though breathing may not
\
have stopped
14
. ~ 3.
7 In many cases when an individual has collapsed in an enclosure
the natural course of events is for a fellow workman to enter without respiratory protection in a rescue effort Often two
or more workmen enter compounding the initial tragedy
-
~
Potential Uses
Situations where contained breathing equipment may be needed .
include
a Fire fighting
b Tank cleaning operations
C. Cleanup of large leaks or spills of solvents or other volatile chemicals especially in enclosed areas
d Entry into underground carbon black handling areas
e. Entry into sewers wells and silos
Chemical cartridge respirators and gas masks
~~
we
Ge
Chemical cartridge respirators and gas masks are not suitable for
protection against high concentrations of toxic gases Chemical
cartridge respirators are U. S. Bureau of Mines approved only for
gases and vapors up to 0.1 by volume in air 1000 ppm Gas masks
approved are approved only for concentrations up to % except % for chlorine
and
for ammonia) Neither protects
insufficient oxygen
oxygen
Local safety equipment suppliers can advise on the type of equipment
most suitable for specific applications Suchequipm she aln l t be
U. S. Bureau of Mines approved If assistance is needed contact
the Home Office Industrial Hygiene Department
5-4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40740
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section
VI
INDUSTRIAL HYGIENE
Part 2. HEALTH HAZARDS AND THEIR CONTROL
VOLUME
Page 6.26.C.1.2.C.1
Date 12-11-67
Cancels 4-18-63
COMMON INDUSTRIAL HAZARDS
ChemicalSUBTANCES IMPORTANT PHYSICAL PROPERTIES AND PRINCIPAL USES OF CERTAIN TOXIC SUBSTANCES WITH CHIEF DIAGNOSTIC SIGNS OF INJURY OR OTHER DISABILITY
Taxic Ordinary Fire Haza = Hr azadrd
DangeDranogeurosus
Processes Producing Potential Hazard
of Entra Enn trc ane ce Inte Bady
Diagnostic Signs and Symptoms
disinfectants ir itation Organic synthesis in the form of vapor
the respiratory organs
disinfectants
and mucani mom
rubber mfg : explosives branes
night
of mucous
of
respiratory tract dyspneansd
pro of f heau rt s profe use
White leaf None
crystals
The and respiratory
, digestive organs
or Cyanasia blueness of lips and finger
fipe mental conlusion dizziness
Amine Compounds Also
Organie synthasis
mig varnishes chloroform air- solvent
le Direct action en skin
quermaig of eelufold the respiratory organs
mig of chloroform
plane
Ibrrriatantieonosf
of skin and mucous
eyes and respiratory
mem-
track
Organic synthesis illumination exy acetylene welding and
cuttinogf metals
Headache nausea general malaise
feeding of suffocation vertige
Oyomfg Oyomfgacriding
Irritation of skin and mucous mem
branes of eyes and respiratory tract
MINI-
violent sneezing
Organie synthesis mig of military poisen 823 refrigerants map end vanish mig
Metal alloys palat
Excessive
Irritation of skin and ma-
direct cous membrofaen yeseas nd respiratory tract bronchial calarth dyspnea
Not generally regarded as an industrial
poison
Pafter followed by cyanosis especially
of lips and Anger tips weakness
somnolence
irritability mental con-
fusion headache
and vertigo muscular
tremor and convulsions eczematous
eruptions weak
pulsa brownish dis-
celeration of
and urine disorders
of the bladder tumors ste
Amyl Arganiz
sug .: saugrar
Preparation of flavoring
bronzing compounds metalic
liquids metallic paints ; scap
brewing mfg brewing
synthesis synthesis
;
and rub
lacquers
.;
mig rabber
industry
paint and varnish mig
disinfectants ax-
plosives
Metallurgy points mordani storage bat
leries electrolypers
emeling lead and
mining and small
Medicine salts
metallurgmyetalurgy ciopnesrecti
bing muning and smell
ing
Invitation dyspnea pulmonary mugh and
pulmonary edema,
bronchitis severe irritation ofskeyiens
conjunctivitis caustic action en
cough nausea Irritation of mucous membranes of
eyes nese throat andbronchial ;
beadache and vertigo drowsiness
expression in chest
Imitation headache
track of eyes and respiratory and vertigo dyspnea
cough Reuses vomiling diarrhea
fainting rise cyanosis Muscularweakness vertige of lips slow fainting possible death
-Nervous Chronic
and disturb-
saces of sensibility and equilibram
nausea vomiting diarrhea eczema
Inflammation of mucous membranes of nese mouth and throat Intestinal disorders Imitation and eczematous
dl-
arsenic erupotfithoe n susn Metal and
fever usually associated with lead and in most of its industruisaelt
TaxTiacxTiaxcic effect ondigestivedigestive system kvar kudneys hair circulatory nails Perforation al septum Local ulceration Motal tre
The Firestone Tire & Rubber Compery
SUBJECT TO DISCLOSURE RESTRICTION
40741
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section
VI INDUSTRIAL HYGIENE
Part 2 HEALTH HAZARDS AND THEIR CONTROL C. COMMON INDUSTRIAL HAZARDS
VOLUME I
Page 6.2.C.2
Date 12-11-67 Cancel 4-18-63
= Tank
Suitlsnce
State State
Fire Hazard
powder Esregi Arsive
ArstesArstes Arses. reited
Slightly
Berlum
Comprends
crystalline
crystalline Explosive
=~
Bengine Mogh gas = Liquid = Explosive |
Bence
Liquid Explosive
Beryllium
Metal = Fient powder
Oracs(Zim)
Metal
Fince
Liquid ens
Butonen
methylatbyl Liquid Siem
Butyl Acetate Liquid = Dongerent
Butyl ditahel Liquid = Dangerous
Batanel
PHYSICAL PROPERTIES
PrPorcienscsiepsal Uses & Producing Fetentist Producing
of Entre Enn trc ene ce
Intu Body
;
Analytical chemistrychemistry
Weather lead Industry : min See Als
ing and smelting dre
varnifaschquers mfg
Organic
Organic synthesis; m~ l An ges thre respiratory
itary pos pos
tars
Paintmz ing
works refin
ing Are insecticides
Direct action on skin
affable affable
sails
varnish absorption and Solvent motor Igal
paint dry cleaning
paint
Vapor thre
respiratory
times by
;
;
Solvent and melor fuel
stasttaitoinosnsairpolrgaanicne prep-
stations industry
welders dry cleaning
reabsorption Vaper Ihre
organs
Ihre skin
respiratory
Diagnostic Signs and Symptoms
esophagus blush headache Faim- Acute poisoningpoisoning
esophagus
-Csotnostmraicchtionofversatingthe
persistent sleeplessness headache gastric disturbances vomiting di^,r-
vomiting and diseases
nas
weakness of the
chilliness
disorders SevereSevere headache nausea
vomitng
hemoglah~-noria gastric
shivering and chills jaundice
Ommals whitening and loss of hme
paralysis acceleration of the heart
cyanosis of the skin gastric pain and
Headache verl~go nausea vomating
irregular resporation weakness
rough heartmusculartwitching drow
Headache and vertigo zastrminipslinal
disturbances hemorrhages purpura
Injury to forming organs with
marked but warted changes in the
blood picture polycythemia
followed by leukopenia
injury blood and so anemia
forth
Fessels heart
marked susceptibility infection susceptibility ;
erythropenia in
susceptibility
focal irritation susceptibility conjunctivitis gingivitis and so
in acute poisomag inchriation stag-
paring loss gait consciousness
-The effects of tolnol and xylol
differ from those of benzol particularly
as reg theia r efr fectsdons the blond and forming organs Neitheorf these
compounds produce the changinetshe
characteristic blood
of benzol It is
Importantto note however that the tolual and xylol used in Industry Industry are
frequently mixed with benzal
Metalalloys
Melallergy Melallergy
brass
:: organic
welding
Fumes
Fumes
thru
respiratory
As a dust or hums
respianrdaetntoerrinyg plimentary canal
been from Metluanglmjrurey porrtepoertedd from the
extraction
of
, but this is
thought to be dos berylium the fluorine COM-
pounds used in the process of extrac-
of Headache general malassa irritation slight
throal cougshlight nauses severe
profese chills with leves
perspiration
pains fume
;
;
a
plosives
paint Pyroxylin mit
cial leather Cosmetic
FEMOVEIS
mig straw
Lacquer; leather
a vapor
respir-
atory system
Absorption by Absorption Absorption tract
skin re-
and mo-
Mucous and membranus Mucous
membranus ;
respiratory
arti- atory vapor Mfg Fruit
;
otanic essences Direct action on skin
Gicial leather perfumes
system thru respir
conjunctialis shin
eruptions skin conjunctialis branes
Ir itation
Irritation Irritation eyes and nose WarningWarning
See Amyl Acetate
No case of industrial poisoning has been reported but it has been considered a
cause contributing
experimentation
showed marked dermatitis early fiveer
degeneration a dekmte decrease in
blood cells mlh an absniyle and
relative lymphocytosis
TheFirestone Tire & Rubber Company
SUBJECT TO DISCLOSUREDISCLOSURE RESTRICTION
40742
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section
VI INDUSTRIAL HYGIENE
Part 2. HEALTH HAZARDS AND THEIR CONTROL
VOLUME
I
6.2.0.3
Page 6.2.0.3
Date 12-11-67
Cancels 4-18-63
C. COMMON INDUSTRIAL HAZARDS
PHYSICAL PROPERTIES
SubSusbsttaancnece
Ordinary State
Fitt Kazard
Cadmium
Metal = None
takium Gyanamida
Crystals Newe
Carbon Dioxide Gas Hone
Carber Dianighife
Liquid
Explosive
=
MoMonnssrirdeide
Explosive
Liquid Mone
Tetrachloride
Ce2.albelzalkmal lesstra2.albezalkamal Liquid Slight
2.albezalkamal
of ChieriLdimee Powder Explosive
Diphenyls
Chiericated Hydrocarbam
Salids = 1
Negribaiens Chlorinated
Solids
Negribaienes
Move
Chierte liquid Explosive
Chlorobenzon Manackime = Calorless Sligh ) Maud
nitrabenzel
Principal Uses &
Processes ProducingProducing
Potentis Hazard
MadeIntoof BEondtryance
Diagnostic
DiagnosticDiagnostic Signs and Symptoms
elec- dental amalgam
;
elec-
cadmstiouramge platingstorage ro
fertes lead
halzinc
smelters
Fertilizers nitrogen
products farming
Fumes thru respiratory
Tract
Direct action a as dust tthhrurustkheirne-
spiratory
organs
diges-
spiratory tract visible and
mucous membranes
vomiling appetite vomiling
tion of
rapid
pulse falty degenera- degenera- degenera-
liver inflammation of kidneys
inflammationinflamation langs cough chest
ofMetal
tume fever
soreness
Severe of throat eyes Severe iirrrriitattaiotnion of nose throat
and skin Conjunctivalis tonsilitis laryngelis bronchitis dermatitis
Aerating water wine
of
dridnrksinektsc
meixgtin
soh extin
chemicalguisher refrigerant rem friigenra-nt
ing
insecticides ; varnivasrnhisehess prainsecticides
servative mig of carbon tetra-
chloride enameling
Not on article of com
caused by in-
mmpiria combustion
Solvant fire extin-
shers cleaning pounds airplane dope
dye paint and lacquer
Industries
halation of In In formof gas by in-in-
In respiration respiration Absorption thru .
respiration respiration
As
thru respir
atory system
As vapor vapor thrmthrm respirrespir--
story organs story
Large quantities cause sudden death by sullocation Smaller quantities verliga disturbances of respiration ringing in ears headache dyspnea drowsiness, muscular weakness
Headache vertigo weakness psychical
effects disturbances of sensation
digestive disturbances polyneuritis
Irritation of skin
pulsevertigo headache -Slaw headache Aculo
,
and of nausea redness
suffusion
skin
dyspnea fever marked leukocytosis
and
Chrome Headache : paliabon Chrome Headache
, nauseavomiling vomiling
palpilabon insomnia failore
anemiamemormy emory
Irritation of nese throat and eyes
Nausea cough headachs marked ez-
citament vomiling verligo mental dullness confusion Injury to liver
jaundice nephr~ldeirmatiss
naICONS
Bureau 0.6fines found U.
exposed to 0.6
for a
that men few seconds
reported the almosphere to irritating
Lacquer mig paint
mig solvent for nitro-
cellulosa
Textile bleaching or-
ganic
synthesis disin
Tectant deodorizer
mig
Electrical equipment
lacquer rayon mig lacquer mig
paint
wax
makers
Mucous membranes
vapor thru respiratory
tract
As a gas thru inhala-
Item vapor an
and dust
irritaling eyes lungs
and skin
Direct action on skin; respiratory thru respiratory
vapors
able the eyes However However . , actual examaneaxam-ana-
tions of workers in lacquer and paint manufacture by the British Factory
denco any injury of Dept. In 1934 revealed very little evito health from the
cellosalve 00.
Bronchitis dyspnes asihma conjunctivitis eczema ulcers of the skin
skin
of Acnoform skin eruptions jaundles and
atroplhivyer
hydmcarbon bobonntteettrracahlcohrildeoride
such as car-
paint
mfg ; DDeeggreraesiansg ingmwiagx -
quipment quipment elecmitgrical
action ;
vapor Direct actionresopnirsatkoirny
skin eruptions Acneform
of alroplhivyer
and jaundice
synthesis
porification Organic bleachingwater
military
poison gas chlorination
acetate forresins cellulosa
acetate and a ois ls
day
day
leaming leaming compound
system As a gas thru respir-
alory
Vapors Vapors
thru thru rersepsirpaitroraytory
paralysis quantitiescause cardiac
parlysi paralysis
smaller quantities CAUSO
burning and stinging of the skin with
formation of blisters papules cough
bronchial Gastritis anemia and pulse bronchitis the dyspnes bronchial
calarth
leeble naza
furunculosis "
cayed -Severe Acute -Severe
somnolence Blood CONSCIOUSNESS with
somnolence to loss of cyanosis
as to changes described
benzol derivatives
similmialern-
Headache giddineza
See Nitrobenzol
The Firestone Tire & Rubber Company
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ADMINISTRATION MANUAL
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Section VI INDUSTRIAL HYGIENE
Part C.
2. HEALTH HAZARDS AND THEIR
=
COMMON INDUSTRIAL HAZARDS
CONTROL
VOLUME 1
Page 6.2.C.4
Date 12-11-67
4 4 18 1463 818 4 186633
63
Tank
Schstance
Ordinary
Fite
State = HazardHazard
Cherr Cherr
Trichters_metkanu
Chiersal
Liquid = Nene
Chiarggrens
hutadione Liquid None
Chromica campezadi
Metal
crystals
:
| Dengar
Conelt
Meta Mone '
tappet
Metal
ene
Liquid
Cresyte Aul
Danger
Cyanogen and
COMPETREI
G: es
Dengersas
PHYSICAL PROPERTIES
Principal Uses & Processes Producing
_Potential_Hazard_
Salvent for fats olla tubber wares and res
Ing artificial sithentg
Mode Diagnostic Signs and Symptoms
Into Body
Vepor thre respiratory
tract
Fouling of warmth Irritation of nose
and skin loss of throat
reflexes shallow
respiration unconsciousness paralysis
cardiac and respiratory failure
Sea Nitrobenzol
Synthetic rubber
Narcotic properties mainlychar- acterized
Direct action on skin
bol is
its injurious injurious kidneys
and
vapor thru respiratory cwiirtchulaaitrion Chloroprene kidneys Irritation of cause a primary
fumes dyeing mela^ urg As dust and
Irri-
lectroplating chromi- tating respiratory mi
fm sails printing cous membranes and
tenning
skin
Gmlaaksesrmsipotgery steeallloy
VaporVapor
Vapor
thru
respirarestpiratoory ryrespiratory
equipment Metallurgy electrical
chemical
ap aratus copper ; coinage
Wood preservative dis-
Infectants synthetic resins explosives in-
As dust from Alings
respir irritating the
branes and thru the
alimentary canal
As a vapothrru the tt
risible mucous organs mem
branes Direct action
the respiratory
olitis
Bronchilis branchopneumonia olitis
conjunctivitis gastritis anemia
mucous membranes ulceration and
perforation of the nasal seplom
A case of poisoning with severe dansage
liver Animal and liver
from factory French
life
factory
polycythemia polycythemia
erepxort-ed
Metal
periments reveal Tume f. ever ses Zinc has been re-
Bronchitis vomiting gastritis See Zinc
Toxic effects resemble those of phenol The chief symptoms are irritation und
erosionnephrils nephrils and mucous membranes
-Exposure to large amounts of kydragen cyanide causes death from sphyxia almost immediately Ex posure to lesser amounts causes irrita-
print of
Esxiltvrearction
gold
and
d; yeing
print
ing slectroplating
gas in-
secticidesteel mig
spiratory system thru
spiratoryspiratory system as
liquid or salid form
the skin
dizziness nausea membranes membranes dizziness
nausea
vomiting
diarrhea shoriners of breath palpria-
heart shalow tion at
cramps shallow unconsciousness
cobreanthingvcuonlvsulisoionnss
Hydrogen cyanide
earunpldioncs yanule solutions also cause skin
-Exposure to small amounts
of cyanide compounds over a long
cause loss period of time la reported to
of appetite weakness nausea muscle cramps unsteady gail paralysis of
arms and legy psychoses
er
LoS hee
sikticne sikticne
Liquid Sight
Dickdernethyl 'Liquid Ether
Dimethyl
Sulphata
Ulexid = Nowe
Dinizebenzal
Dinitrophes 1-2-4
Crystaline
Crystalline Nana
Varnishes tayon mig
dry cleaning perfume t
Mucous membranes
vapor thro respiratory
of the vapors findings dichlorethylene dichlorethylene show an
excess fat in the blood suggesting
death from embolism rather than
asphyxiation
Textile industry Ireat-
in lubricatingchens-
syincthaeslis
new
compounds
Vapor respiratory Vapor thru respiratory muchuS
Irritation of eyes and nesa nausta
marked irritation of respiratory pas-
sages and lungs
.
Burns neck and thorax photophobia edema conjunctivitis agent for As gas thru theas and Mellylating
a
re-
amines
phenols spiratory organs a
perfume mig
fluid irritating the skin
painn ecks
thorax lacrimation
conjuctivs photophobia
aspiration pneumonia convulsions
paralysis coma death
Explosive mig dye mig wood preserving
See Nitrobenzel
Thru direct
digestive
action
tract
skin ;
Burning thirst sweating panting ex-
aitement high fever patchy yellow
and skin
convulsions After ingestion
endence of liver and blood damage
have been observed Bilateral cal-
araz~ shave also occurred as a sequella
8-4773
The Firestone Tire & Rubber Company
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Section
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2
VI
INDUSTRIAL HYGIENE
HEALTH HAZARDS AND THEIR CONTROL
10.2.C.5 VOLUME
Page
10.2.C.5
Date 12-11-67
Cancals 4 18 63
C. COMMON INDUSTRIAL HAZARDS
Eee
PHYSICAL PROPERTIES
Principal Uses & Symplams
Mazrd Principal Mode of EntranGE Toric Ordinary Producing Substance
Ordinary State
Fire Mazard
Potential Heard
Inta Sody
Diagnostic
Signs and Symplams
robines ~
rr
They mucousmam Headache vertigo drowsiness Irrita-
Laequor mig robines robines rapat Ihru re- tion of eyes nose throat and lungs
mig dye mig varnish spitatory disturbances Injury Explosive
spitatory Iract aboarp gastric
to liver and
-
Diezen Blatty Liquid = Jena D iazide
mig Poa
leon thru skin
~
kidneys
Causeswarning knock gasoline
Mucous membranes
symptoms such as irritation to the eyes and respiratory
Elbyt Bourne Liquid Explosive
passagesbefore dangerous vapor lacquer mig general
thra respiratory
tions are reached
.
concentra
TO
Elbyl Grid Liquid Explosive
Ethyl Chloride Bri Bri
Explosive
Refrigeration nesthelic
Vapor the respiratory
;
tract mucous mem-
branes
Chloride
See Melhyl Chloride
;
Dizziness drunkenness spalhy per
Medicine
Medicine organic mes- thesis refrigeration refrigeration
As a gas thru the repiratory organs
sistent somnolence loss of power in uncertain gail disturbances
the legs solvent perfume mig
__
See Melhyl Chloride
Ethylome Dichierkle
Liquid None Uqaid Explosive
Ethylamide Ethylamide Ethylamide
Bas
room
Explosive
~~ Gasoline blending plas-
the mig fire extinguisher mfg
Organic Organic synthesis sol-
vents anesthetic; thin
Vapor hra respiratory tract muters mom-
branes
atory tractthe As a respri esptit
membrance tract cous
Mucous membranes
Insecticides reffosolve synthesis
ganic vapor :
of ar-
ganic compounds
thru respiratory
eyes and Irritation of
respiratory tract
vomiting headache anorexia pallor
weakness vertigo
~ ratation of eyes and nose werligo
conscimusness death exposure static and motor ataxia relching un
if
is
Headache vomiling dyspnea diarthen of vertien lympho- Irritation
membranes onse
and eyes vertien nausea lympho-
cytosis dullness disturbances of res
piration edema of heart action gul
Ethyl Ether
Sutpharte
Caloriess Dangerous
liquid
Ethyl Suteates Liquid Slight
diluent Sovent
maturant
extracting
extexrtraacctitnging
agen;t aannesethestictheticextracting
Silica wig wateragent glass
prouting
VaporsVapors the the respiratoryrespiratory
tract
Macaes membranes
vapor tract respir-
also
membranes slight appetite hondache hondache membranes
and loss in
of loss appetite hondache an-
weight Anesthesia consciousness paralysis death
Animal experimentation shows these
compounds to be torse but no cases
compounds compounds reported from Industrial
exposure
Florize and it
Formaldehyde Liquid Home Formic hald = Liquid = Explesiva
Organic synthesis dye-
goods
Organic synthesis and ;
lanning
H
spiratory membranes phenol and
synthetic resins creosol
As thru the vapor spiratory
ergens
skin irritant
Lacquers
Dyeing industry Vapor thrusters thrusters
rubber
tanning agent
mig
membrane
thrusters
See Hydrofluoric Acid
rn
junetratis froolites membranes of junetratis froolites froolites dyspnes finger dermatite destinition destinition
con-
dyspnes severo
nails
degeneration n^ te hung
of thrustersSee also thrusters
Formaldehyde Dermalilig
nirmations necrosis Irrita-
tion murmus membranes eyes
nose and throat
84272
Explosive
Ermine
Mathpl
Liquid = -Sight
Mathpl
com- Fuel for internal
vent paint mixing
varnish
Lacquer mig varnish removers solvent
~
See Benzine
Yaper thru mucous
membranes
7
oe
See Benzine
According to U. S. Aureau of Mines men exposed to 0 73 0 65 and 2.0 percent vapor in air pronounced the at-
mosphere extremely disagreeable even
for a
short time odor and irritation be- cause strong
and nasal
odor and
irritation
passages tenth of
to have a strong
eyescent wasfound oder and moderateyse and nasal ~-rt~-la-
Itan Concentrations producing no
mashed symplums and apparently
ONA harmless in quines digs aller
EZ-
posure of several hours have distinct
warming properties of bath odor and
irritation that are very disagreeable
le human beings
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HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
VI
INDUSTRIAL HYGIENE
VOLUME
I
Page 6.2.C.126-1 -67
Part 2
HEALTH HAZARDS AND THEIR CONTROL
Cancels -18-63 -18-63
C. COMMON INDUSTRIAL HAZARDS
Taxic
Subalance
= State
Fire
Hazend
HIecreoOnuetpMlethyl Liquid Sight
Liquid None
Hytrachter
Hydroyants Liquid = None
Hydratuuri Liquid None
Hydrogen
Indine
Crystan Mode
Izan Carbonyl Free Oxide
Faris
None
Lest
Metal =Hone
Land Compounds Crystals Dangerous powder Nitrates
Magnesium Metal Explosive
Mentonese Dierido
Satid
None
powder
Moreary
Liquid
metallic element
Hone
Metkane Bas Explosive
Methyl Alcabal Chapak = Explanive Meikanel
PHYSICAL PROPERTIES Continued
PrincipalPrincipal Uses & Producing
ProcesesProcesses Producing Potential Hazard
Mode of Entrance Into Body
Solvent lacquer mig
As a vapor thru nasal mucous
Diagnostic Signs and Symptoms
Irritation of conjunctival and nasal
mucosa
Cerhroimnedutsatnrnyingorogrgaanniicc synthesis dyestuffs chlorides medicine in
organic preparations
Chemical analysia medicine insecticide organic synthesis military poison gas
brewing ;
Cyeeraamsitcs brewing and elching glass
the direct As gas thru
smratory system direct
action on the skin and
visibln mucous mem branes
As fumes thru the resp.ratory system Dues nol irntale the respir alory mucosa
As gas thru the respir
action organs
action on membranes
branchils ViolVeiolnentt coucchouchinig ng dyspneadyspnea brbarnacnhcihiilillsls
destruction of teeth contraction
throat coma causlic action on skin
In fatal doses Verligo marked pallor great prostration feeble puise
and voice and cold sweats The urine and exhaler breath may possess an odor of bitter almands fching in the nose with watery discharge and Irridation of the throal Large doses are Instantly lalal
Conjunctivitis bronchial catarrh ulceraling of the nostrils, gums and oral mucous membranes ulcers of the culics suppuration under the finger nails Caustic action on skin
Seo Sulphuretted bydrogen
Dye mig soaps kor-
micide pharmaceutical
As a vaper larg re-
spiratorymebranes syslem and
Iritation
of mucous
of
and nose inflammation of lungs
See Nickel Carbonyl
Welding
;
lead
storage balleries pigments solder
piping
;
;
:
piping
Insula
pigments for mining
ing mining ing
and smelt- smelt-
Fomes thru respiratory
vapor or dust thru
the resprespiriatory ratory digesto ive r pans and digestive
rael
Metal fume fever
in the
Weakness pallor metallic taste mouth and
fetid
breath lack
appe
tile deposit of land line on Rums and
prosence of lead in urine These symp
toms are associated with anemia tas-
toms
Intis constipation loosening of teath
abdominal pain in the joints paralysis
cramps and colic Stippled red blood
carpuscles
Medicine
;
weighing lead paint
pigments lasecticides ;
Alloys paint mig.mar .
nesium rubber nesium refining nesiumairplane parrtesfining
As vapor or dust thru
and respiatoy the respiratory organs digestive tract Thru the skin
As dust and fumes thru
respiratory tract par
ficles under sk~-n~-
Seo LLeaedad
:
Metal fumo tevor
See Zinc
Languor and sleepiness slold maskliko facial expression low monalongus voice inuscular twitching varying from
mig mig match glass mig
drydry coll batteries
Tumes and dust thru respiratory tract
hands arms mical movements gross trunk
and head cramps and stillness of
muscles in legs increase in lendon reflexes anki and patellar clonus
retropulsion and propulsion slapping
gait uncontrollai ie laughter and crying
Metal lume lever
See Zine
: ther-
Mercury salts thervapor lamps; chemical
PROCESSPSPROCESSPS
As vapor and dust thru respiratory organs As solid thru the skun
Chinnic
mucous
imnefmlbarmamanteionof
the gums
the mouth
und
af teeth necrosis of the juw ulcers in
the mouth and pharyna chronic gas-
Initis enteritis anemia furunculatis
anesthesia mental depression tremors
of the hands and muscles of the face
Coal mining processing of cual
SoSollvveenntt for for varnisvahrnish
gums Thesis
Difanit SYNI
fuel general
solvent dye mig
Gas theu respiratory
tract
As vapor vapor by inhalation
Headache drowsiness (chiel dangdangeer r is firm explasman
fatal Irritation of eyes and respiratory
Saget vomiting vertigo dyspnea fatal paralyss of the heart chills thirst ditated immolite pupils optic neurilis biinilures abominal cramps paralysis Peknum roma
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VI
INDUSTRIAL HYGIENE
VOLUME I
Page 6.2.C.7
Part 2 HEALTH HAZARDS AND THEIR CONTROL
Cancels 4-18-63 4-18-63 4-18-63
C. COMMON INDUSTRIAL HAZARDS
=
'
PHYSICAL PROPERTIES
Substance Ordinary Herard
Processes Producing
TT
ee
and-
Mode Into Entrance
Asgan thru the respir
Diagnostic Stems and Symploms
of feritation respiratory passaget mus
disturbandcisteurbancetwitchings
eramos convulsions ,
sight
lever
dehisaims
acuity loss of memory irritable temper
may persis for a long time
See note under Melkyl Chloride )
ee
Melbyl Caffeselve
Ethylene Liquid Sight
Elkar
mig
Selvent lacquer recent studies studies positively established ; var-
wish making dye spiratory mig sirplane dope solvent
resin cellulose
spirastoryystem
it
affect and recent studies
cellosolve may
suggest that me the blood
forming organs and the nervous
system
~
Progressive drowsiness InsomAIS
.
headache vertigo ^-auses anorexia
spalhy staggering gait mental con fusion weakness visual disturbances
tramos presence of formates and
scelone in grims
Malhyl Chioride Gas None
Methylene DMeithyclekneeCrh-ier- Liquid = None
methuro
a
Malkyl Formats Liquid == Dangerous
refrigeration
refrigeration
Medicine refrigeration
mig ; thermometers
7
Sooillsvenrtecseilnlsulorsuabrbubeberr
anestholic cleaning fluida artificial silk
__ Bit
Fumigants refrigerant
As a gas thru the respiratory organ
Vapor thre respiratory
re-
spirspairatotryorvyapor thru
Nate U. S. Bureau of Mines
studied the scule response of goines pigs to a single exposure to vannes ol
methyl chloride melhyl bromide ethyl bromide and ethyl chloride According to this Bureau all four produjene similar
symptoms including excitement loss of equilibrium inability to walk rapit pulse convuluve rapid respiration wilk rates Irnthy often blond finged re udate from nostrils The signs of lung irritation were not as gr^,nnuneed for exposire to ethyl chloride as for the other compounds The gross pathningy was quite similar for all four of these alkyl halides and was characterized by congestion hemorrhage and edema of the lungs and by injury to the vasc~-llar system as shown by the tendency loward hemorrhage Congestion was pret en in the organs of all grm p^ but parenchymal degeneration was mod marked in those exposed to methyl
bromade A distinct delayed elfect of exposure was noted with methyl bromide and methyl chloride ^fina lester extent with ethyl bromide hul was nol observed with ethyl chloride
Headache
numbness
giddiness irrifabduly
and ungling in the limbs
labored breathing ragid weak pulse
cyanosis and possibly some degree of
chronic anemia
According to the U. S. Bureau of Mines men exposed for one minute to 0 15
vapor in air noticed the formate pleasant
ethereal odor of methyl formate but
experienced no nasat or Pye rifilation or other signs or symptoms Winie the
ador of methyl formule is distinct and noliceable in concentrations which are
relatively safe from the standpoint of producing acule porsoning owing la ris pleasant nature and the occurrence of olfactory falique it is doubtful whether the odor of methyl formale will serve as an effective warning of harmlul condi
lions of exposure
_.
.
1
Naghiba
Liquid
.
Naghihais Crystalline tone
Dye mfg chemical
skin
Direct action on skin may be absorbed thru
Irritation of skin and kidneys Injury
to cornea and lens In addition rest
delirium
convul
spiratory organs
coma and death
-4273
The Firestone Tiru & Rubber Company
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ADMINISTRATION MANUAL
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;
Section
VI
INDUSTRIAL HYGIENE
Part = 2. HEALTH HAZARDS AND THEIR CONTROL
C. COMMON INDUSTRIAL HAZARDS
VOLUME I
Page 6.2.06.8.2.0.8 Date 12-11-67
Cancels 12-11-67
Micht Carbonyl Liquid Explosive
f
Dual
Nitrasillas
Explosive
GERZENDKIN Other Com-
Glytris Liquid Explacive
Mitze- Crystels Explosive
Qualls Adid Cryptalline Non^
Drone UT Gas
Perta
Methy
Prophy Ketome
Parchiarelkylene
Explosive|
PHYSICAL PROPERTIES Continued
Principal Uses &
Processes
Potential Hazard
Entorf aEnntrcanece
Into Body
.
Perfomemsig of ani-
#no m^'gof dust pre-
rentives; mig
;
explosives gasuline
sb
Diagnostic Signs and Symptoms
See smiline and other amine compounds
of benzol and its homologues
toxic to be The only lesion reported nickel apart from the
caused effecta
nickel carbonyl is nickel eczeme
This condition is reported mostly among
nickel platers who are exposed in many
dermalis producing substances Some
authorities question whether nickel is
the responsible agent
Giddiness headache nausea constipa-
edema of lungs lion dyspnes cough refrosternal sore-
Cnyeasnsoasnids epigastric paisnleplesnespain in the
foim bemorrhages in the brain and the adrenals Metallume
fever See Zinc
Acute cases may be fatal In less severa
cases there may be severe prostration
gastric upsets vascular collapse
precordial distress dyspnea Toxic
has been amblyopia
reported by some
authorities to be a chronic effect of
ricolinepoisoning
SeeAniline)
Irritation of air passages
spasmodic cough dyspnea pulmonary
suffocation pain bronchitis feeling of
pain
in chest digestive disturbances pe-
ripheral vaso dilatation methemoglob-
frama and its sequelae and depression
of the central nervous system COROSION
on of teeth severe burns the skin
Continued exposure to diluted fames is
said to cause chronic inflammation of
the respiratory tract and a general dis-
characterized by headache sleeplessness anorexia gradual losasl
dyspepsia dyspepsia sirength dyspepsiaconstipation and
uicers on
lips and mucous Mari-
branes of the mouth and pharyNE
Cyanotic face and lips somnolence
and headache vertigo vomitvoimintigng
oder af bitter almonds in breath un-
steady gait Ing
Tramors muscular twitchother manifestations of nerve
Injury anemia visual disturbances
methemoglobin formation presence
hematoporphyrin albumin and some-
times free prison in urina eczematous
eruplicas
Redness of fare and conjunctivae intense hra, arkemental disturbancos
vertigo ainling tremors burning
sensation in thrnal and stomach na-
sea vomiting colic Chronic Digestive disturbances and neuralgia
See Nitro benzol
Local caustic action on skin blush dit-
coloration and brittleness of mails
cluding those of esophagus s omach
troublecardiac weakness nervousness
Irritation of eyes and respiratory tract
.
headache cough pulmonarypulmonary edema depression and coma
ac-
Irritation af eyes and nasal passages
MER-
larger doses cause narcosis
See Tetra Chlorethylene
*
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VI INDUSTRIAL HYGIENE
Part
2. HEALTH HAZARDS AND THEIR CONTROL
C. COMMON INDUSTRIAL HAZARDS
VOLUME
Page 6.2.0.9 6.2.0.9
Cancels 4-18-63 4-18-63
Turk
Substance
Ordinary Hazard Firg
State
Hazard
PetrYoallaetiun m
; Dangerous
Acht Crystalline Carble Carble
Crystalline
Sighi
Sighi
hosted
Phenyl Hydrazion
Phosgene
Carbondi ChlorChiloridde eChloride
Crystals = None
dr Ha
Liquid Kone
Phosphorus Crystal = Explosivo
Phosphing Phosphorefted Gas Hydrogen
Dangerous
Plerie Aeld
Crystal = Explosive
Trinitrnghenel
PoHtaysdsiruomxide
Deliques-
Deliques- Dengeras
W slicks
Pyridios
Liquid Dangerous
Selenium
Compornda
Semi
= metallic
crystals
ene
S^/ver& Ita
Compounds
Met: = Neng crystals
PHYSICAL PROPERTIES Continued
Principal Uses & Processes Producing
Polential Hazard
Mode of Entrance Into Body
Diagnostic Signs and Symptoms
Motor fuels lubricants
As soild direct action on skin as a vapor thru respiratory organs
Ser alts Brazine) Trainion ja tun
and respirater arptrs May EP
acute inliammaven inliammaven to the lungs and
headache senterad senterad styrha- C
Works in petin sym refers are
subject to acme kevytan~- edibenama and metinestrem metinestrem patre rum paraffin
and petroleums res dye Workney en-
posed le pellets any out
and greates in
a number of indiches are subvert lo
fat aur thens thens and
omer
Phenal formaldehyde resins .. germicides chemical mig
As a vapor thra diges-
live track and respit
atory tract direct ac lion on skin and mu-
cous membrane absorption thru skin
Eretion of the skin reprima reprima gar cere,
irritation of big respiratory organs and
Free plams of arui peng peng
folowing folowing
splashing splashing wila plenat orani orani
baling is vapors include Hendiche
verb hautes kinnitut fainting
Gysanra ezatement convulsions re-
spiratory paralynis
Symplams of gazanie naposure include
Emac alian vemilise diarrhea amaret
ja br dache wil~ga bit nasky
pralios
Organic synthesis re-
agent in analytical chemistry
Lethal cas dyestuff mig chlorinating agents bleaching sand for glass mig
Absorption thru skin
As a vapor thru respleatory system
Mfg mt poison production of phosphorus alloys explouves fire
works insecticides
As a vapor thru respir
atory system as a salid thru digestive system
Vesicular re
dian^a multe peger sess 0 101
rare oeslen
Nm Weta et
Irulation of .et, penne 3 er oe
lung tissue intense mysanna are .-
monary monary edema Cyanos s emble mear
death in com
tetreatingly severe has has t dights bur disturbances sweiney and prestav
lion of the gums and burca mempiing mempiing
loqtening and fawing out of the teeth
suppuratiaonnd destruction of jawbone
with fistulo chan- +
Throug's the elinga elinga mas
mating ration
The
baers ather than the jawbone bat anto been reported
A different type of phitoring marked by genera and systemet eflent is also recognized
Blast furnaces weld-
ing acetylene work
phosphorus extraction organic preparations
As a gas thru reapis atory organs
Opplection verligo.teto
nex gentia
in tres n^n^-anteand
electralinaelnectratlinant electralinant andand
Geb^"ty banibus autem
Tremors and rere sons ptt in the
forting
region of the Gusturarm
Gusturarm 3P
chil Symplant Semical to these of phosphorous po taning are said to have resulted fram prolencen pressure 13 lo congratest in of poor on
Explosives medicine dyeing silk disinfect ant dya mig photos raphy lzoning
Soap mig bleaching medicine reagent in analytical chemify ink mfg metal mig
Denaturant f^r alcohol medicina solvent in rubber paint and ather industries explosives paint mig
As dut thru sesair atory system direct action on sket
Direct action on the skin as dust attacking the visible mucous
membranes and diges
live organs
^ s^ vapor thru the respiratory organs direct action on the skin
~ arinilis von
diatones verbes
toivra decent of the b LF
com.xls.oms yi oseniorationof Na
shin and chr.unclivac chr.unclivac inkarimation of
muroy membranes membranes
Deadly if swallowed Severe chemical burning of the skin and muerus mam branes Formalson of deep scaled and persistent ulcers loss of naus
Hoarseness laryngitis headache ver go Iremors chair weakness of the extremities eczema
Glass mig paint mir alloys oxidants lead and zinc smelting welding cement mig
Mitter silvening coin mfg salverware Indelible ink mfg pho lography
Direct artion on skin as dust fumes or vapors thru respiratory tract and digestive tract
Absorption thru and
direct actioonn skin
Dermatitis pakkar gastrowniTAITA OS turbances gas gas odor of bream and perspiration irritation of onse and throat coaling of tongue metallic faste in mouth and nervousons
Dermatitis canistic action Argyrosis a grayran blue or blark disenioration of the skin and muchus membranes is the chief effect reported in industry
8-4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40749
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section
VI
INDUSTRIAL HYGIENE
Part 2.
HEALTH HAZARDS AND THEIR CONTROL
bc
c COMMON INDUSTRIAL HAZARDS
VOLUME
}
Page 16,2 10
Cancels4 18 63 112-211--6171-67
PHYSICAL PROPERTIES
Substance
Sesium Ny^'rezide
Ordinary Razard
Deliquet
cent Dangerous
places,
and sticks
Sulpher Chiaride Liquid Ment
She Did bas
None
Butchersited on
Hydrogen HydrogenHydrogen
Sulphide Hydrogen
Explosive
Geigherie Aal^' Dense city Denorm
Tor Pitch
Solid i
hene
Stata
Principal Uses &
Processes Producing
soap industry Petroleum refining
ning
Industry
Synthesis medicina
vulcanizingdyeing Rubber mig Inseell
cids
textiles w ;
bleaching i;cs preservative
lar beer , and meria
meria cellulose mining
and smelting
Reagent analytical
tanning coal frequently
mixed other frequently
gases mining and
ful smeltinsgmelti;ng paper makers
Made Entrance
As attacking Direct action on the
skin dust the visible mucous
membranes digestive
tract eyes of and As mutc hruomuucos us
membranes respiratory
As gas thre the raspiratory organs
As a gua thru the respiratory system
Diegnestle Signs and Symptoms
Severe chemical membranes of Formation Formation
of
sealed and persitn ulcers
of nainlais ls Deadlyif swallowed
Irritation al mucous membraneosf eyes
and respiratory tract
dyspnea bluish discolora-
Bronchitis Spasmodic laryngitis angina pneumonia
bloody sputum digestive dis-
Acute poisoning Disorganization of
blond burning pains conjunctivtis conjunctivitis Ras- in
and
throat cough conjunctivitis Ras-
tritis dyspnea dumbness slow puise
headache
perspiration contracted pu-
pils convulsions paralysis
Chronic kaustion poisoning Chronic
poisoning
ConjunctivitConjunctivtiis s expallor slow pulse
explosives rgeafniincinsgynthesis
of inor-
gunic preparations
dustries metallurgy
chemicals
Preservingwood read
cresante cresante mrfepgair Itract
As vapor thru the re-
spiratory system local-
fy * 6 culaneous irri-
taal
Acute and chronic bronchills bronche-
pneumonia decay of leath On the
skin local pain redness edama ulcers-
lich skin sezuma Mpseolrainaossiissaallcceersrs of the skin
or
and cornea
warls loss of Vapers thru respiratory
epitheliomatous cancer
Itract fired
diarrhes handacht vertigovertigo
albuminuria track conjunctivitis
respiratory
nda
madschurin
Sese
ee
cass
Compounds Telferium Compounds
crystals & crystals
;
Co;leringol, zinc and copper
AbsAbsoorptrionption thruthru sskkinin
the respiratotrracyt
direct contact with skin
of breath and of
tions excretions excretions breath sacra tions
excretions
mouth sIwenagtskin
mmeetatlallilcic
Dry lich-
taste anorexniaua-
sea vomiting indigestion constips-
tion and somnolence
Tiruchirkan
Misstylema Liquid Tetrashlari^'s
Hone
Severe headache nausea insomnia
spiratory vaser of abdominal pains fatigue enlargement :
for greases wares andarti-
ficial airplane
;
;
ficial airplane mig
thru
spiratory
.
abnormal
vomitiblnoogd
intestinal disorders
content and nervousness
death
and general dis-
coma and
Tetrachlorethy-
Tetrachlorethy- Liquid Nene ePtehryclhelnosr
;
:
Salvent; pdreimgbriengaser
.
As vapor thru upper respiratory possagus and mucous mem
brenes
Imitation
sinuses
lightness of eyes increased
perspiration
perspiration
frontal
hands and increased secretion mer- passages
O-
nauseZ tion faintness dizziness dyspnes
relarded mental activity headache
and visual disturbances
-
TeiranthTylTeeiirraanntthhyyll Lazd Liquid
pounds ses
pounds
Dangers
Added to motermoter ffuuelel
Highly absorbed vapor in order to iminals iminals the knack in
Thru the respiratory
the internal combustion system
engine
slight temperature slippled Insomnia and
in
body temperature
slippled
red
blend calls tremors sudden valent
itching excretion of lead in the urine
vertigo and headache nausea and
vomiting tremors loss of weight
andrezia lesd encephalopathy
Tetryi Trinitrephonyizalkyl- Powder
nitramino crystals
Explcahre
Thullem 6 Compounds
Metal ; Rone = erystals
powder
As a dust thra respir Abdominal pain asthmatic attacks
Mfgof explosives
atory tract and direct action sa skin
hemorrhage from mucosa headaches
and giddiness dermatitis
i
class
mig
salts
color
fami-
tnhoaullsium mig insec-
Hadedsye mig
As vapor or dust thru the respiratory organs
and digestive tract organs
Loss of appetite faligus albuminuria
of joint pain loss
and blindness
hair optic neuritis
The Firestone Tire & Rubber Campany
SUBJECT TO DISCLOSURE RESTRICTION
40750
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section
VI
INDUSTRIAL HYGIENE
Part
2.
HEALTH HAZARDS AND THEIR CONTROL
C. COMMON INDUSTRIAL HAZARDS
VOLUME
I
Pago 6.2.C.11
Date
12-11-67
Cancels 4-18-63 4-18-63
Turkc Substance
Trichiurethylene Lirold Nene
thanhd Liquid = Expicsive
Trinitrotoluene
TMTMitre
Temp Triorthecrazyl
Phosphate Terpenting
Vaurtiem
PHYSICAL PROPERTIES
PrinciUpseas li
Processes Produang
Mude of Extrance Inle Body
Diagnostic Signs and Symptoms
Tin plate slik weigh Ing dye merdant
Paint mig
Paint mfg steel alloys
As fumes Ihre respir story organe
Not generally regarded as industriat poison Reported to cause feeling of chilliness in the chest pain in the throat heaviness in the stomach anemia and traces of lin in urine and feces
Used us a substitute for while lead in
The manufacture of paint No ill effects
have heen reported usa in industry
as a result of its
Ses Benzol
Degreasing
dyn mig
solvent mInfsgectipcaiidnet
varnish
bmelrgworkers
mig
rub-
As a vapor thru the
respiratory system
Effects not fully established Symptoms of acute poisoning include excitement drunkenness dullness nausea vonuit Ing inconsrinusness sequelae include bradarhe vertigo anorena disturbed
heart action Severe irritation of the
respiratory passages has al~-n hem reported hul this effeel is ascribed by
some authorities to the action of es
decomposition pendurts phosgene and
hyrtenellore hyrtenellore and Chinnic #ranture is
sand in cosailt erjury in the lapominal and optic nerves Impunidies in fuighidroslhylene it has been suggested may be the cause of these injuries Other affects are addiction and sein ar~-lal~-n~-r
lEexaptlhoesrimvefsgmmatchagtlcahssmmiigg
Explosives
As dust or fumes thru
the respiratory = mu-
cous membranes and thru the pores of the
skin Intestinal Thru gastro
Intestinal tract
See Pieric Acid
Bitter taste in the mouth headsene nausea with white frothy vamaling griping abdominal pain increase in blood pressure s^'v^renote bined dermatitis gastritis unne dark cointed and contains blood
Lacquer mig plastic wie
Solvent paints ver-
nishes lacquers medkeine wax mig print
idnysgmpihogtogIrnakphmeris gdrdyry
deaning
-
Thry digestive tract
As a vapor thru the repassages As
seppidierrmiastoryit acts on the
No clear cases have been reported fram industry is not highly volat e but if absorbed may cause paralysis of extremities This was the cause of the epidemic of called lake Leg several years ago
Irritation of mucous membranes eyes nose and upper air passages bronerval
inflammation salivation headarno vomiting shdominal pain and vertigo state of excitement resembling drunk enness irritation of kidneys and bladder sirangury odor of violets in urine severe irritation of skin
Dye mfg He mig paint mig uranium mining photography
Steel allaying dye
mig glass and per
Direct action of radiant rays on skin Thru respiratory organI
Fumes and dust thru respiratory tract Diteslive tract and mucous membranes
Uramum reported to be one of the most
toxic of melais is a source of radiant energy A high frequency of canere of The lungs in Crechoslovakian muners of granium is believed lo ha due to the
activity of the are Very pille has been published on the offerts on man of exposure to uranuim sall The con ditions reported include purpura of the Irgs reduction of leuknevies as well as diminution of red corpuseles a zeduc lion in urinary elimination of hidrated salts and an increase in lie chinrilles
Experiments on animals with uranium mitrate are reported to show aerlintis glycosuria albuminuria castro infesti nal disorders degeneration of liver affections of nervous system
Anemia cachexia irritation of respris
alory hemorrhages requiling dry cough
in
diarrhea constipation
or hemorrhages
emaciation involvement of kidneys
hysterical manifestations melancholia
SUBJECT TO DISCLOSURE RESTRICTION
40751
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section
VI INDUSTRIAL HYGIENE
Part
2. HEALTH HAZARDS AND THEIR CONTROL
VOLUME 6.2.C.12 6.2.C.12
Date 12-11-67
Cancels 4-18-63
C. COMMON INDUSTRIAL HAZARDS
_
.
Sachstance Ordinary Hazard
Vinyl Chloride = Gas
Slight
PHYSICAL PROPERTIES Continued
,
Processos Producing Mode Entrance
Organic synthesis prin As a gas thin ipper
cipally resins
respiratory tract
Diagnostic Signs and Symplems
The S. Bureau of Mines reports that
men exposed to 2.5 for approximately
3 minutes soon began la feri dizzy and disoriented as to space and size of s^,rrounding objects and complained of a burning sensation in the soles of the feet They immediately recovered on leaving the chamber and complained only of a slight headache which lasted shoot 90 minutes
Tytees
Liquid
Explosive
Zim
Matal Dengerus
desi
Metallurgy gulvamzing Metallurgy organic ;
boiler plates ring
smelling brass found
As dust and as a vapor thru the respiratory System
See Benzal
Metal ome lever Characterized by
Irritation of respiratory tract dryness of throat dry cough malaise headache nausea severe chills with fever pains
in limbs shaking in limbs swentong
leukocytosis Motal fever may also be caused
of by luines lead mercury manganese
cadmium arsenic antimony and many other metals Metal fever resull
ing from metals which may cause
regarded systemic poisoning should be continued
as
warning that
exposure
may have more serious effect
5-4273
SUBJECT TO DISCLOSURE RESTRICTION
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section
VI INDUSTRIAL HYGIENE
Part
2 HEALTH HAZARDS AND THEIR
CONTROL
_
_
COMMON B.
Nae
INDUSTRIAL HAZARDS
VOLUME Page
I
6.2.C.15
Date
4-26-65 4-26-65
Cancels NoneNone
Chronic poisoning by benzene is so serious in nature that it
is to be used in production if no other material perform
satisfactorily Its use even in small quantities normally requires
a closed system or excellent local exhaust ventilation ventile-
Under no condition will general ventilation be relied upon
to control benzol vapor
Air concentrations in the workplace must be kept below 25 ppm Benzol
vapor can be determined by simple colorimetric devices but not by
Department needle type instruments such The Industrial Hygiene
combostible indicators able instruments
suchsuch
explosimeters
explosimeters
OR
has
suit-
indicators indicators
gas
The Industrial Hygiene Department is to be informed well in advance
of a proposed factory use
5-4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40753
section
Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING &
VI INDUSTRIAL HYGIENE 2 HEALTH HAZARDS AND THEIR CONTROL
PROPERTY
PROTECTION
VOLUME
Page
Date
Cancels
I
6.2.c.16 8-19-65
None
C. COMMON INDUSTRIAL HAZARDS
ee
og a
foe?
DIMETHYL SULFOXIDE SULFOXIDE DMSO Lae
A chemical relatively new to industry Dimethyl Sulfoxide DMSO
is coming into use particularly in the Synthetic Fiber industry Very
little is presently known about its toxicity and there is
avail-
about toxicity if nothing able
inhaled
PRECAUTIONS ***
little
ON its inhalation toxicity-
** PRECAUTIONS PRECAUTIONS
toxicity- Make certain that if this chemical is introduced into your Plant that
the Industrial Hygiene Department is notified Make every effort to
prevent all skin contact Inhalation should be held to a minimum by
use of exhaust ventilation
It is known that DMSO penetrates the intact skin readily sometimes
produces skin irritation and markedly increases skin absorption of
other materials which are on the skin Herein lies one of the potential
dangers many chemicals which have little effect on the skin may have
a serious when they
having been carried
by DMSO
OR lethal penetrate it though the skin
5-4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40754
Section
Part
-CEIVED DR -CEIVED MANUAL ADMINISTRATION
PROTECTION HEALTH SAFETY ENGINEERING & PROPERTY
JUN
1966
VI INDUSTRIAL HYGIENE 2 HEALTH HAZARDS AND THEIR CONTROL
VOLUME
Pago
Date Cancels
I
6.2.C.17
6-23-66
None
( HYDROGEN SULFIDE ssen ssen
Hydrogen sulfide is a colorless gas with a rotten egg odor Inhalation
of high concentrations causes unconsciousness and collapse within
seconds and concentrations above 600 ppm are rapidly fatal
~
P" RECAUTIONS
PRECAUTIONS PRECAUTIONS
+
a
+
A factor which contributes to such tragedies is the fact that inhalation of the gas deadens the sense of smell rapidly leading to a false sense of security Indeed above about 200 ppm the disagreeable odor initially appears less intense than at lower concentrations and lethal quantities produce immediate paralysis of the sense of smell
For these reasons many persons have lost their lives attempting to save a workman who has collapsed from exposure The fatal collapse of a first
victim often initiates a chain of similar tragedies as heroic fellowworkers rush unprotected into the contaminated area in an attempt to
rescue those who have already fallen victim Not infrequently two or
~
three deaths occur because of the natural desire to help a fellow
Exposure to hydrogen sulfide may occur in many ways
common ones are
Some of the more
1 In sewers
2. From laboratory use of the gas
3. From contacotf water or acid with sulfides
4 In wells
5 In excavating in swampy or filled ground
side product many 6.
See Vol
As
I Sec
VI
product product in
douged chemical reactions and processes
page 6.2.B.1 6.2.B.1 for guidance on respiratory protection
cartridge Chemical
respirators must not be used for protection and gas
masks must not be used inside tanks and other enclosures where there may
be high concentrations in which case only supplied air equipment is
satisfactory
4273
The Firestone Tire & Rubber Company
RECEIVED
JUN 30 1966
6. L. WILSON INDUSTRIAL HYGIENHET
SUBJECT TO DISCLOSURE RESTRICTION
40755
Section Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
HYGIENE
VI INDUSTRIAL HYGIENE
2. HEALTH HAZARDS AND THEIR CONTROL
VOLUME
Pago
Cancels
6.2.C.18
9-15-66
9-15-66
C. INDUSTRIAL HAZARDS
RP
\
13947 is a skin eye and respiratory irritant
In case of contacts
1 Remove from skin with mineral oil then wash thoroughly
charge charge with soap and water
th feet) Yotecle.
2 For flush immediately with copious quantities of
J
. water for at least 15 minutes and get medical attention
3 Remove contaminated clothing and launder before wearing 3+ -
again
13947 is handled in unopened bags and inhalation should not be a
problem if the Banbury is effectively ventilated
No health hazard is likely after 13947 is incorporated into the rubber compound If respiratory protection is needed for example in disposing of broken bags a respirator approved for dusts that are not significantly more toxic than lead is satisfactory
live
Check stefusing
stefusing stefusing stefusing
stefusing stefusing
this
lust
,
Rows
Rows Rows
4273
The Firestone Tire & Rubber Company
Ge
8
Q
Ls
SUBJECT TO DISCLOSURE RESTRICTION
40756
Section Part
ADMINISTRATION PROTECTION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
VI INDUSTRIAL HYGIENE 2 HEALTH HAZARDS AND THEIR CONTROL
VOLUME
Pago
Date Cancels
I
6.2.C.19
9-22-66
None
C.
COMMON INDUSTRIAL
HAZARDS
CADMIUM OXIDE =
.
FUME
~
"
GENERAL
GENERAL GENERAL GENERAL GENERAL GENERAL GENERAL
nee
Great care oxide It
must be taken to prevent the is an insidious chemical as
inhalation of fumes of cadmium
lethal quantities may be inhaled
without sufficient irritation to give warning at the time of exposure
A single exposure can cause
have been numerous fatal or
lung irritation which may be serious poisoning cases from
fatal There inhalation of
universally cadmium oxide fume there were at least two deaths in the United States
during 1965. The Threshold Limit Value of cadmium oxide fume is 0.1 mg
per cubic meter of which is half The Threshold Limit Value of for
lead a more
recognized serious metallic poison
It is produced
awed CRUE OES tT
1. During silver brazing Some silver brazing alloys in common use contain large percentages of cadmium
2. During welding or cutting metal's plated with cadmium
3 From heating cadmium plated nuts bolts and rivets
4 From the use of a blow torch on flanged cadmium plated
steel pipe
5. Whenever cadmium metal is heated
sufficiently
-
X2
of When there are operations such as those described above
ventilation which captures the fume is the best means
local exhaust
preventing
inhalation Where there are infrequent exposures which last only a
few minutes a fume respirator prevents inhalation Dust respirators
do not afford adequate protection
They Cadmium plated shaft collars
use some of our plants
used for locking shafts in place are in are ordinarily locked in place with
set screws but occasionally they are welded to the shaft As pointed
out above welding produces cadmium oxide fume
Early symptoms of intoxication include dryness of the throat coughing a feeling of constriction in the chest shivering and headache Nausea and vomiting are less common Symptoms are delayed and usually appear
after significant exposure has occurred Later a
difficulty develops with excruciating pain in the chest
and
In fatal cases the intensity
chemical pneumonia in breathing
of respiratory distress
prostration RECEIVED maymay increase for a few daydayss followed byby recoveryrecovery in 8 10 days
5-4273
The Firestone Tire & Rubber Company
SEP 27 1966
INDUSTRIAIINNDUDSUTRSIATRWIAIHLYGSIOERNA
SUBJECT TO DISCLOSURE RESTRICTION
40757
Section
Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
VI INDUSTRIAL HYGIENE 2 HEALTH HAZARDS AND THEIR CONTROL
VOLUME I
Page
6.2.C.20
Date Cancels
9-22-66
None
C. COMMON INDUSTRIAL HAZARDS
CADMIUM OXIDE FUME - Continued
Cadmium is quite toxic in the stomach it causes symptoms similar to those of food poisoning within half to one hour after ingestion Eating and storing food in work areas must be prohibited and workmen should wash thoroughly before eating smoking or leaving work Good housekeeping is important
ae
7
8-4279
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40758
40758 40758 40758 40758
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section VI INDUSTRIAL HYGIENE
;
Part
2 HEALTH HAZARDS AND THEIR CONTROL
VOLUME
Paga
Date Cancels
I
6.2.0.21
12-13-66
None
C. COMMON INDUSTRIAL HAZARDS -
Change tand tand typ
Change
tand
:
Change
!
tand
CARBON TETRACHLORIDE
ONLY The danger of carbon
used in production
tetrachloride poisoning is so great that it is to be WHEN NO OTHER MATERIAL will perform satisfactorily
Either a short exposure to a high concentration of this material or re-
peated exposures to low concentrations may result in serious injury or
death It affects the liver and kidneys principally through inhalation
although skin contact with the liquid contributes to overall exposure Alcoholics and persons who have consumed significant amounts of alcohol
are more suspectible to this type of poisoning
.
a
Air concentrations in the workplace must be kept below 10 ppm therefore
its safe use even in small quantities normally requires either a closed system or excellent local exhaust ventilation Laboratory use must be
confined to a well ventilated hood
Safe air concentrations of carbon tetrachloride are
odor in fact if the odor is noticeable upon first excessive exposure is occurring
not detectable by entering the workplace
The Industrial Hygiene Department is to be informed well in advance of any
proposed factory use even temporary use the Industrial Hygiene Depart-
ment has the equipment
chloride vapor in air formed well in advance
required for the determination of carbon tetra-
It is recommended
of a proposed use
plant
iks
Safety also be
ENGINOOK ENGINOOK
ENGINO K ENGINOOK
in-
The use of carbon tetrachloride fire extinguishers is illegal in some governmental jurisdictions including the State of Ohio
5-4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION'
4075409759 40759 4075940759
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
section VI INDUSTRIAL HYGIENE
Part
2 HEALTH HAZARDS AND THEIR CONTROL
VOLUME I
:
Pago
6.2.C.26.2.2C.2
6-26-67
Cancels 6-26-67
C. COMMON INDUSTRIAL HAZARDS
| CARBON MONOXIDE eee
GENERAL
GENERAL
gena a e
GENERAL GENERAL
Of all the gases that have effects upon man carbon monoxide is the most
widely encountered It exerts its effects by combining with the hemoglobin of the blood and interrupting the normal oxygen supply to the body
tissues Carbon monoxide is taken up by the blood 200 times more readily
than oxygen This prevents the oxygen from combining with the hemoglobin
and being carried to the cells The effect is termed carbon monoxide asphyxia and involves the prevention of gaseous exchange between the air breathed and the body transport system as opposed to suffocation which
is a mechanical blockage of air intake Although the resulting oxygen
deficiency is a reversible chemical asphyxia nevertheless damage from
severe asphyxia from any cause may not be entirely reversible
The effect of carbon monoxide on man is enchanced by many environmental
factors such as heavy labor high temperatures and high altitudes
Symptoms such as headache fatigue and dizziness appear in healthy workers engaged in light labor when about 20 percent of the hemoglobin
s combined with carbon monoxide Such degree of saturation is achieved
by continuously breathing air containing 100 parts per million ppm
carbon monoxide
threshold
for 6 to
value
8 hours
aa.
f
141 141
L
I
L
a
v
eel
is
The threshold Limit value for carbon monoxide been 50 ppm
$y J)
Workmen affected by carbon monoxide should be removed environment immediately and given medical attention
from
the
contaminated
Exposure to carbon monoxide a tasteless odorless colorless gas may
is occur whenever carbonaceous matter such as carbon black
paper oil gas gasoline or any other organic material
coal wood
burned It is
a product of incomplete combustion
Carbon monoxide is commonly produced by
1 Internal combustion engines
2 Furnaces other than electric
3 ) Water heaters other than electric
4 Stoves
5 Overheated compressors
RECEIVED
x
JUN 29 1967
G. L. WILSON INDUSTRIAL HYDIFRISK HYDIFRISK
4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40760
-
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
rection VI INDUSTRIAL HYGIENE
VOLUME I
|
Page
6.2.C.23 6.2.C.23
Part
2 HEALTH HAZARDS AND THEIR CONTROL
Date Cancels
6-26-67
None
C. COMMON INDUSTRIAL HAZARDS
Cigarette
smoke as
CARBON MONOXIDE - Continued
monoxide carbon .
of smoking is a source of
Pa = carbon
.
exposure
inhaled contains 200 to 800 ppm carbon monoxide
Cigarette
Many operations involving the use of tractors and lift trucks in industry take place in limited areas often having poor ventilation and little air movement The carbon monoxide produced can become a serious hazard
especially when workers in the area are performing hard labor
Removal of carbon monoxide from the work atmosphere can be accomplished
by
1
General ventilation to control
from tractors lift trucks and
combustion vehicles
exhaust fumes other internal
2 Venting of furnaces heaters and stationary internal
combustion engines to the outside atmosphere
a a propane
ns
Contrary to popular opinion LPG propane fueled prod do u prc odue ce
carbon monoxide It is generally accepted that an LPG engine in good
adjustment will produce less carbon monoxide than a gasoline engine in
good adjustment In a normal state of repair LPG engines produce amounts
of carbon monoxide comparable to their gasoline counterparts and will not
serve to eliminate the health hazard They produce less carbon monoxide
than gasoline engines only with excellent maintenance of the engines
Carbon monoxide intoxication has been caused by contaminated air taken into compressors Intake openings of air compressors used for supplying air to breathing equipment should be located at sites or in positions that offer the least possible likelihood of carbon monoxide intake and well away from exhaust outlets of fuel burning equipment
The home office
carbon monoxide
needed
Industrial in air and
Hygiene Department has equipment to check
should be called upon for any assistance
4279
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40761
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
S
Section VI INDUSTRIAL HYGIENE HYGIENE
Part
2 HEALTH HAZARDS AND THEIR CONTROL
VOLUME
Pago
Date Cancels
I
6.2.C.24 6.2.C.24 6.2.C.24 6.2.C.24 6.2.C.24
11-29-67
None
C. INDUSIT NDUSTR RIAL I HAZA ARL DS
Ozone
and
ozone
OZONE
_
Alt
-
en re GEAER GEAER
generators shall not be used in occupied
for odor control
areas
them
Ozone does not destroy odors but masks odor and appears to freshen the air by lowering the perceptibility of odors Odors of high intensity cannot be successfully masked by concentrations
of ozone which are safe for prolonged inhalation
Ozone is a toxic chemical It is very irritating to all mucous membranes and significant exposures cause lung irritation
is Oe
The threshold limit value is 0.1 ppm
4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40762 40762 40762
:
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section VI INDUSTRIAL HYGIENE
Part
2 HEALTH HAZARDS AND THEIR CONTROL
VOLUME I
Pago
6.2.C.25 6.2.C.25
Cancels Date
Cancels
1-23-68
NONE
Co COMMON INDUSTRIAL HAZARDS
o
-- GENERAL
~
~
~
ISOCYANATES
Isocyanates sold under various trade names are widely used as raw
materials in the manufacture of polyurethane elastomers foams castings
and coatings and in adhesives Two of the most commonly used ones arecastings toluene diisocyanate TDI and methylenebis phenylisocyanate MDI
TDI is a liquid at room temperature with a vapor pressure of 0.05 mm Hg at 77 MDI is a solid at room temperature Heat is generated when
isocyanates react with other ingredients
. ~ PHYSIOLOGICAL PROPERTIES
- ~
1. The acute inhalation toxicity of isocyanates is high They are severe respiratory irritants Long term overexposure to excessive air concentrations results in bronchial irritation
C in some individuals an asthma sensitivity develops
Individual sensitivity varies widely Once an individual is sensitized the slightest exposure triggers a severe respiratory response The affected individual must usually be medically
restricted from all further exposure
The Threshold Limit Value of both TDI and MDI is 0.02 ppm
Limits for others have not been established Temporary
excursions above 0.02 ppm are undesirable Workmen may be affected if the air concentration exceeds 0.06 ppm for as
little as 15 minutes
2 Skin irritation may occur from contact with TDI or MDI Eye contact may cause injury An air concentration of 0.5 ppm TDI
irritates the eyes
--
~*
ODOR -
should must
Odor
not be relied upon as an index of overexposure since the
air concentration of TDI which produces a detectable odor is approximately
0.4 ppm far above the Threshold Limit Value Detection of TDI by odor
indicates acute overexposure
4273
The Firestane Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40763
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
section VI INDUSTRIAL HYGIENE
Part
2 HEALTH HAZARDS AND THEIR CONTROL
VOLUME
Page
CDaatnecels
I
6.2.0.26.2.60.26
1-23-68
1-23-68
a
C. COMMON INDUSTRIAL HAZARDS
ISOCYANATES - Continued
- ENVIRONMENTAL CONTROL + ~ ~
Local exhaust ventilation is necessary at all phases of manufacturing up to the point where polymerization is virtually complete When formulations containing isocyanates are sprayed supplied air respirators are usually necessary in addition to ventilation
~
STORAGE AND ~ HANDLING
Water and acid generate carbon dioxide gas when mixed with isocyanates This may cause violent rupture of closed vessels Moisture must never be allowed to enter storage or transfer systems Contact with strong alkali may cause uncontrollable polymerization
WORKPLACE EVALUATION
Industrial hygiene surveys for airborne isocyanates are to be made by one Home Office Industrial Hygiene Department Ask for them prior to the start phase of all new operations so that potential trouble spots can be located early and any necessary corrective action taken before workmen are affected Follow surveys will be made as needed and should be asked for when substantial process changes are made
4273
The Firestone Tire & Rubber Company
~
SUBJECT TO DISCLOSURE RESTRICTION
40764
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
(
Section VI INDUSTRIAL HYGIENE
VOLUME Page
I
6.2.0.27
Part
2 HEALTH HAZARDS AND THEIR CONTROL
Cancels None
C. COMMON INDUSTRIAL HAZARDS
owe ve fet
oo
The
The current Threshold Limit Value is
should be handled in a closed system
_ . - SKIN CONTACT ~~~ .
. Preferably Code 327
Code 327 is a skin irritant A small percentage of individuals who have repeated contact acquire a sensitivity Sensitized individuals must usually be medically restricted from all further work with the material In case of contact remove from the skin immediately with copious
quantities of water
.
standard
recommendation
Two or three ppm in air causes a very mild tingling in the eyes
5 ppm discomfort increases rapidly and some mild lachrymation occurs in
most people If the liquid is splashed in the eyes
copious
quantities
minutes
Extremely prompt action is required to prevent coagulation of
surface of the cornea Permanent damage may result All eye
report to the Medical Department
the
cases
must
INHALATION INHALATION 1 ;
. Two three ppm causes a very mild tingling in the nose and back of the throat Long exposures at 5 ppm are decidely unpleasant Ten ppm causes almost immediate irritation and it becomes difficult to inhale normally
'
+ FIRE HAZARD
% to 73
The vapor is explosive from 71-73 by volume in
stabilized with 15 methyl alcohol has a flash point
air Code of 122
327
{
5-4273
The Firestone Tire & Rubber Company
RECEIVED MAY 3 1968
HIDUSTRIAL WILSON
SUBJECT TO DISCLOSURE RESTRICTION
40765
ADMINISTRATION MANUAL
section
Part
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
VI INDUSTRIAL HYGIENE
THEIR HEALTH
2 HEALTH HAZARDS AND
CONTROL
VOLUME
Pago
Date
Cancels
I
6.2.C.28
4-16-68
None
C. COMMON INDUSTRIAL HAZARDS
*
Pr a
od
CODE 775
Because of the potential toxicity Code 775 should be handled and
used with caution
A Threshold Limit Value has not been established
SKIN CONTACT
It is a skin irritant Solutions are readily absorbed through the
skin In case of contact wash thoroughly with copious quantities of
water A small percentage of individuals will develop a skin sensitivity
to Code 775
EYE CONCONTTAACTCT
It may cause eye damage
Sharon entry
In case of contact
amplete use
standrs standars standrs standars
sentsi enti
ie copious
dantities of water 15 minutes medical attention
INHALATION
Causes local damage by direct irritation of the tissues
TOXICITY TOXICITY
May cause damage to liver kidneys lungs and spleen '
a3
"
5-4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40766
RESORCINOL 775
e
men
a
ee
er
Oren
ee
Pe
L
L
GENERAL
Because of the potential
and used with caution
toxicity
resorcinol
should
be handled
A Threshold Limit Value
^ SKIN CONTACT +++
has
not
been
established
It is a skin irritant Solutions are readily absorbed through
the skin In case of contact wash thoroughly with copious quantities of water A small percentage of individuals will develop a skin sensitivity to resorcinol Sensitized individuals
must usually be medically restricted from all further contact
EYE CONTACT +++
It may cause eye damage In case of contact hold eyelids open and wash immediately with a gentle stream of water for at least 15 minutes preferably at an eye fountain Get medical attention
INHALATION tta
Avoid inhalation of dust and vapor Causes local damage by direct irritation of the tissues Excessive exposure may cause damage to liver kidneys lungs and spleen Hazardous vapors occur only at elevated temperature and are not a problem at room temperature
- -
INGESTION +++
Harmful if swallowed Do
large quantities of water patient is unconscious or
not take internally If swallowed drink
immediately Induce vomiting unless in shock Get medical attention immediately
~~ FIRE HAZARD 4t
Flash point is 335 open cup No danger of explosive vapors at
ordinary temperature Material will burn
Home Office Industrial Hygiene Department The Firestone Tire & Rubber Company
GLW
10/2/69 cancels issue of 4/12/68
SUBJECT TO DISCLOSURE RESTRICTION
40767 40767 40767 40767
Section
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
VI INDUSTRIAL HYGIENE
VOLUME Page
I
6.2.0.29
THEIR Part
2 HEALTH HAZARDS AND
CONTROL
Cancels None
C. COMMON INDUSTRIAL HAZARDS
os
C
CODE 303 9158 11l12
The current Threshold Limit Value is 100 ppm toxic for both acute and chronic exposures
It is moderately
INHALATION
Exposure to 400 ppm causes fatigue insomnia restlessness and mental confusion Exposure to 600 ppm causes nausea headache and
dizziness in three hours
Chronic overexposure may cause some blood changes but these are
much less severe than those seen in cases of benzene intoxication
SKIN CONCONTTACTACT
The chemical causes a defatting action which results in dermatitis if there is repeated and prolonged contact
EYES
An air concentration of 200 ppm is distinctly irritating In case of contact with the liquid quantities
minutes
Flash point
63-77
Standard
ashefore
Standard Standard Standard Standard Standard
to .
:
wenke wordinwogrding
Explosive limits 16.6 by volume in air
Since the commercial product is a mixture of isomers the physical properties may vary somewhat depending on the composition
vey
5-4273
The Firestone Tire & Rubber Company
RECEIVED
MAY 3 1968
G. L. WILSON
INDUSTRIAL HYGIENIST
SUBJECT TO DISCLOSURE RESTRICTION
40768
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section VI INDUSTRIAL HYGIENE
Part
HEALTH
THEIR
2 HEALTH HAZARDS AND THEIR CONTROL
C. COMMON INDUSTRIAL HAZARDS
_ a
VOLUME I
Page
6.2.0.30
Date
4-16-68
Cancels 6.1.A.l dated _
10-3-62
RP 12437
-
.e
vo Va em Lrn ee
12437 is a chlorinating agent described in a data sheet by the
Wyandotte Chemical Corporation
Ra
-PA -PA
les
r
12437 decomposes and releases free chlorine when milled and in
the presence of moisture releases hypochlorous acid hydrochloric acid and some free chlorine gas Since 12437 and these chemicals are eye nose throat and lung irritants precautions should be used in handling
Use rubber gloves goggles and respirators together with adequate ventilation Protective equipment and ventilation are mandatory if 12437 is milled
Guard against spilling and getting the dust on the skin Wash
minutes get thoroughly with water if skin contact occurs
wash with copious quantities quantities
water
If eye contact occurs
standard
attention
wording
& }
12437 is an oxidizing agent Do not
a large scale without testing on a small stability including storage testing STORE
mix with other chemicals on
scale for compatibility and IN A COOL DRY AREA
5-4271
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40769 40769 40769 40769
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section VI INDUSTRIAL HYGIENE
Part
2 HEALTH HAZARDS AND THEIR CONTROL
VOLUME
Pago
Date
Cancels
I
6.2.0.31
4-19-68
4-19-68
C. COMMON INDUSTRIAL HAZARDS
14339 CODE 443
\os8
? .
Cae eet ile
.
14339 Code 443 has been used as an accelerator in the rubber
industry for many years A number of years ago it was observed that employees manufacturing this compound experienced severe reactions following the consumption of alcoholic beverages The reactions took
the form of headaches marked flushing of the skin palpitation of the heart and nausea
Perhaps stimulated by these observations in industrial employees investigations were started with a similar compound a number of years ago by medical research personnel in its use to treat alcoholism This research resulted in the development of the drug Antabuse for this problem
The physiological mechanism by which the effects of discomfort and
the more serious symptoms following the consumption of alcohol occur are
not completely known but it is believed to be the result of the
production of acetaldehyde in the body Because of the severity of these
reactions the use of the drug Antabuse is carefully controlled and
although it has not proven to be the cureall for alcoholism it does have
Code higher some value in some individuals...
4 - toxicity toxicity 14339 143 9
443
The systemic toxicity of Antabuse is somewhat lower than that of AnAtntabuas bus
) In the manufacture and use of both of the compounds moderate precautions need to be taken to prevent systemic effects apart from any responses to alcohol from occurring The principal type of
injury that may result with overexposure is liver damage
In the use of 14339 Code 443 employees should be forewarned about the effects from alcohol and medical personnel should also be aware of these peculiar responses so that prompt treatment of any severe
reactions can be made
The above is adapted from an article in the April 1968 Safety
Newsletter Rubber & Plastics Section National Safety Council
5-4273
The Firestone Tire & Rubber Company
WILSON
INDUSTRIAL WILSON WILSON
SUBJECT TO DISCLOSURE RESTRICTION
40770 40770
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
VI INDUSTRIAL HYGIENE
Section
Part
2 HEALTH HAZARDS AND THEIR CONTROL
VOLUME
Page
Date
Cancels
I
6.2.C.32
4-19-68 4-19-68
None
c COMMON INDUSTRIAL HAZARDS
12328 & 12862
No Threshold Limit Value has been established for this chemical
Both of these materials produce large quantities of airborne dust when mixed on open mills It is extremely difficult if not impossible to ventilate a mill well enough to keep the air concentration at a
;
satisfactory level
sore
dust
Excessive exposure to 12328 or
throat For that reason if dust
respirators should be required
12862 has caused nosebleed and is not controlled by ventilation
-4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40771
Section
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
VI INDUSTRIAL HYGIENE
VOLUME
Page
Date
I
6.2.C.33 6.2.C.63.2.C3.3
5-3-68
C. COMMONINDUSTRIAL
LEAD AND LEAD COMPOUONTHDESR THAN TETRAETHYL LEAD
- GENERAL a
Lead and its compounds are toxic Taken into the body in excessive
amounts lead and lead compounds cause a serious form of poisoning intoxication which is one of the oldest industrial diseases known
The
most probable cause of lead intoxication in industry is from excessive
qtuiamnetities taken into the body by inhalation over a prolonged period of
The Threshold Limit Value of lead is 0.2 mg per cubic meter of air
This is a very small air concentration
++ ++ PREVENTION +- -- _
&
The prevention of lead intoxication is principal means used are
1. Adequate local exhaust ventilation CAN could become airborne
relatively
where lead
simple
or lead
The
compounds
2 Prevention of ingestion of lead from food and tobacco which have become contaminated in the workplace or by inadequate cleansing of the hands prior to eating or using tobacco
3. Good housekeeping
principal Ale eae EAE A Hm
There are two principal means by which lead exposures are measured to determine whether the preventative measures are adequate
1. Periodic air sampling for lead
2 Periodic examination of blood for lead
16 It is relatively simple to determine whether harmful quantities of
lead have been absorbed This is done by a chemical determination of the concentration lead in the blood Specialized sampling equipment and a sophisticated analytical technique are necessary but this test is the best
means for the determination of absorbed lead
r
5.4273
The Firestone Tire & Rubber Company
RECEIVED
MAY 21 1968
G. L. WILSON
INDUSTY HIGIENST
SUBJECT TO DISCLOSURE RESTRICTION
40772
4077420772 40772 40772
(7 : ADMINISTRATION MANUAL HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section VI INDUSTRIAL HYGIENE
VOLUME I }
Page 6.2.0.36.24.0.34
Part
HEALTH HAZARDS AND THEIR CONTROL
C. INDUSTRIAL HAZARDS
Cancels 5-3-68
LEAD
COMPOUNDS
continued
INHALATION =. -
via the
The most probable and most hazardous route for entry of lead is inhalation lungs and its subsequent transport throughout body by the circulating blood
Metallic lead when heated sufficiently gives off a fume of very
small particle size which is readily inhaled Molten lead is easily
oxidized its surface when it is skimmed stirred poured or otherwise agitated in the presence of air variable quantities of finely divided
lead oxide may be thrown into the air
Dusts of finely divided lead and many lead compounds become airborne readily despite their high specific gravity
paints Cutting
earing
welding and reshaping of
generate airborne lead
nazardous condition
metal surfaces coated
Lead burning may also
with lead-
cause a
oF.
rd
Lead compounds are also thrown into the atmosphere within droplets of mist and when bearing paints enamels and glazes are sprayed - INGESTION - ~
Lead that
taken into the
contaminates the mouth may not be
hands food
ignored as a
tobacco or other objects
source of exposure
and lead Where lead
should be observed
compounds are handled the following precautions
1 Keep food beverages and all forms of tobacco out of the workplace
2 Wash hands thoroughly prior to eating and before using tobacco
in any form
4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40773 40773
40773 40773
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
VOLUME I
Part
2 HEALTH HAZARDS AND THEIR CONTROL
C. COMMON INDUSTRIAL HAZARDS
Date
5-3-68
Cancals None
COMPOUNDS continued
, +> SKIN CONTACT + +
Lead and inorganic lead compounds are not skin irritants nor are
they absorbed through the skin in significant quantities Certain other
regarded compounds of lead
have been
such as salts of fatty acids and complex organic acids with distrust and apprehension from the aspect of skin
absorption while definitive information is incomplete the preponderance
of evidence is that these compounds are not absorbed through the skin in
potentially dangerous quantities
~
~
. ~ - HOUSEKEEPING
-
Good housekeeping is essential in order to prevent lead and lead compounds from becoming scattered about Once scattered about they can more easily become airborne
5-4273
The Firestone Tire& Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40774 40774
DRAFT
April 21 1970
TRICHLOROETHYLENE & TETRACHLOROETHYLENE
PERCHLOROETHYLENE
PERCHLOROETHYLENE
GENERAL These are chlorinated hydrocarbons which have moderate inhalation toxicity They are commonly used in metal degreasers See Solvent Degreasers in this section of Manual
INHALATION
INHALATION
The Threshold Limit Value of both is 100 ppm Exposure to high
concentrations causes irritation of the nose and throat There
may be nausea and gastrointestinal upset as well as dizziness
Severe acute overexposures have caused deaths Chronic over-
exposure to low concentrations may cause liver or kidney injury but not as serious as that caused by carbon tetrachloride
If patient is unconscious call a physician at once While waiting for a physician Carry patient to fresh air If breathing is stopped carefully apply artificial respiration Preserve patient's body heat by over and under wrapping with blankets If the clothes are wet with solvent remove them and apply olive oil to patient's skin removing the oil as soon as convenient with soap and warm
water
If conscious patient should I not be allowed to walk Use stretcher to carry patient to hospital If patient is taken home he should be taken by car put to bed and a physician called This also applies to persons have been sufficiently exposed
to be unsteady on their feet sleepy dopey or excessively fatigued)
SUBJECT TO DISCLOSURE RESTRICTION
40775 40775
(
ta ARE)
-2-
Use with adequate ventilation Local exhaust ventilation for
degreasers is sometimes required
SKIN CONTACT
Repeated and prolonged exposure causes drying and defatting
The skin may become reddened Prevent skin contact Use
neoprene gloves as appropriate Remove from skin with soap
and water
EYE CONTACT
NXNE Prevent contact
Irritates the eyes
Causes a
burning sensation Not likely to cause injury if removed promptly
oo
*
In case of contact hold eyelids open and wash immediately with a
gentle stream of water for at least 15 minutes preferably at an
eye fountain Get medical attention
Harmful or fatal if swallowed
Approx Approx one one fourth fourth of an ounce
Five has caused death Affects
vomiting attention niting ver and GM kidneys
NOT induce
A physician at onconece , vomiting then follow the procedure procedure
. outlined above for at inhalation
FIRE HAZARD
flammable except that under certain conditions trichloroethylene
vapor
has
been
known
And
thexplode to
when the
temperature is
vealpeovratedcon. centration
is
as
airR high as 90 in This phenomenon is rare
If involved in a fire chlorine hydrochloric acid and other highly
toxic decomposition products are produced
SUBJECT TO DISCLOSURE RESTRICTION
407470776 640776 40776
DRAFT
|
Sharon Sharon Sharon Hald
10424
March 17 1970
10424 contains several percent of a chemical which is a skin irritant and sensitizer and which is not physiologically inert
if inhaled
the following precautions should be observed
1. Prevent skin contact
2 Avoid prolonged breathing of vapor or dust 3. Exhaust ventilation to prevent inhalation should be
used where dust may become airborne
Repeated skin contact may not cause difficulty until after sensitization occurs Once sensitized XXX the affected individual may develop a rash following the slightest skin contact and may have
to be medically restricted from all further contact with 10424
Trouble is more likely to arise during hot humid weather Therefore
At elevated temperatures 10424 may generate heat by polymerization or condensation The reaction begins at temperatures below the fusion point which is about 194 Practically this should not be a problem in normal handling and storage If the material has been exposed to fusion temperatures in the drum it could burn
spontaneously
GLW
SUBJECT TO DISCLOSURE RESTRICTION
40777 40777
DRAFT
March 4 1970
Deaths continue from improper operation or improper operating
practices involving solvent degreasers Trichloroethylene and
perchloroethylene tetrachloroethylene are commonly used degreaser
solvents Procedures and safeguards
turers must be followed for safe and
supplied by equipment manufac-
efficient degreaser operation See
section Trichloro ethylene ethylene & tetra-
in this
of MANUAL
To insure safe degreasing the following must be a part of the
original installation
1 Trichloroethylene and perchloroethylene degreasers must
be equipped with condensing coils of water or refrigeration type with sufficient capacity to absorb the heat input For optimum efficiency the water outlet temper-
ature from the coil should be maintained between 100-110 A thermostatic control valve on the water outlet is recommend-
ed Where water supply or water disposal facilities are a problem it is suggested that a cooling tower be used to
provide water of the proper temperature
2. All degreasers must be equipped with a thermostat in the boiling solvent to regulate heat input and prevent overheating
SUBJECT TO DISCLOSURE RESTRICTION
40778 40778
-2-
3. Trichloroethylene and perchloroethylene degreasers must be provided with a high vapor level control safety thermostat
4. Spray pumps if provided must be electrically interlocked
with a vapor level control to insure that the solvent is
at proper temperature before use This control must be installed in the board zone just above the normal ^ KKEvapor level and should be of the manual reset type Under no circumstances is this control to be used to regulate the vapor level within the degreaser
5. Racks or baskets must be of open lightweight constructions and no larger than necessary
6. Electric hoists are essential for heavy work to insure & controlled rate of entry and removal of the cleaning load Hoisting speed must not exceed 10-12 feet per minute
Under certain circumstances an exhaust ventilation system may be
required to maintain solvent vapor concentrations within the
4100PPM 4100PPM
Threshold Limit Value in the working environment
'
This is particularly
true where drafts cannot be controlled or agitation is required
for parts cleaning
SUBJECT TO DISCLOSURE RESTRICTION
407470779940779 40779
The use of solid metal parts baskets with insufficient openings in the bottom to drain the solvent
b Baskets which fit tightly into the degreaser causing solvent vapor to be expelled to the atmosphere by displacement
Overloading the degreaser to exceed the pound per hour capacity specified by the manufacturer This procedure lowers the vapor level rapidly and has a tendency to pull room air into the degreaser creating a solventair mixture Unless the parts being degreased are left in the tank for an extended time period the solvent condensed on them will not have evaporated sufficiently before they leave the degreaser
d A poor racking system for parts which have indentations
where liquid solvent can be trapped Parts with
hollows or depressions must not be randomly racked but must be placed in a position to drain the liquid while
in the confines of the degreaser This not only saves solvent and reduces solvent exposure to employees but
achieves a cleaner part
SUBJECT TO DISCLOSURE RESTRICTION
40780
040
e, Mechanical hoisting devices which usually operate
attrice the recommended speed of 10-12 feet per minute
When excessive lifting speeds are used the hoist must
be stopped with the parts basket or rack at the top of the vapor level to allow all liquid to drain and evaporate before removal
2. Conveyorized Degreasers
a. Faulty controls any of the above which prevent proper
degreaser operation
b Excessive conveyor speed This drags air into the
degreaser inlet and draws solvent out of the unit
ce
chimney effect where inlet and outlet openings are
at different heights This causes a convective flow
of air through the degreaser carrying solvent out
through upper openings
+
3 All Degreasers
a. While rare there have been cases of solvent substi-
a
tution i.e. use of trichloroethylene in a machine
designed for use with perchloroethylene Due to the
widely differing physical characteristics of these
solvents such substitution can safely be made only after a complete overhaul of the machine and its
controls
SUBJECT TO DISCLOSURE RESTRICTION
40781
-50 -50
b Dirty solvent This results in poor degreasing and
:
will produce ^ disagreeable odor
c, Air currents near open doors or in drafty areas
This will likely siphon solvent vapors from the degreaser into the workroom Solvent lost into the
air serves no useful purpose and is dangerous This loss exposes employees to excessive solvent vapor It increases cleaning costs and may result in severe corrosion to the space heating equipment or
nearby combustion equipme~n ~~t-
^ degreaser must be cleaned regularly to avoid sludge build Safety equipment and caution must be employed when cleaning a degreaser If a unit must be entered for cleaning it should be done only after all the solvent liquid and vapors have been removed or dissipated and then only when at least one other workman is present on the outside The person descending into the degreaser must have a lifeline attached to him by means of a safety harness This should be coupled with adequate outside means with which to quickly haul the worker to safety A chemical cartridge respirator approved by the U. S. Bureau of Mines must be worn by the man inside
GLWISS
SUBJECT TO DISCLOSURE RESTRICTION
40762 40762 40762 40762
-60
FIRST AID
Inhalation If patient is unconscious call a physician at once While waiting for a physician Carry patient to fresh air If breathing I has stopped carefully apply artificial respiration Preserve patient's body heat by over and under wrapping with blankets If the clothes are wet with solvent remove them and apply olive oil to patient's skin removing the oil as soon as convenient with soap and MAEEKX warm water
If conscious patient should not be allowed to walk Use s stretcher to carry patient to hospital If patient is taken
C
home he should be taken by car put to bed and a physician
called This also applies to persons who have been sufficiently
exposed to be unsteady on their feet sleepy dopey or
excessively fatigued
Eve Contact
Prevent eye contact
Causes a burning sensation
Not likely to
cause injury if removed promptly In case of contact hold
eyelids open and wash immediately with a gentle stream of water
for at least 15 minutes preferably at an eye fountain Get
medical attention
.
SUBJECT TO DISCLOSURE RESTRICTION
40783
Ingestion Induce vomiting Call a physician at once then follow the procedure outlined above for inhalation
Fire Hazard
flammable under ordinary conditions High concentrations
of solvent have been known to explode when the vapor concentra-
temperature tion is as high as 90 in air And And the temperature temperature
is
elevated .
SUBJECT TO DISCLOSURE RESTRICTION
40784 40784
DRAFT
March 9 1970
PHENOL CARBOLIC ACID
Phenol and its solutions are used as laboratory chemicals and as raw materials Refer to Manufacturing Chemists Association Chemical Safety Data Sheet SD for a detailed discussion
Phenol is rapidly absorbed through the intact skin to produce toxic effects Death within minutes has been caused by contact with a relatively small skin area The extent of absorption depends more on the skin area exposed than on the concentration
of the solution
SKIN CONTACT Immediate action is imperative in case of contact as follows
1. Instantly flood XI affected area with water an emergency shower is preferable
2
in
undineadodado
not use
ado
Remove contaminated clothing while under the shower
DO NOT DELAY USE OF WATER TO REMOVE CLOTHING Continue
washing until all odor of phenol has disappeared
3. Get medical attention immediately
Contact causes corrosive burns unless removal is prompt Use
rubber gloves to prevent contact
When handling large quantities
Neoprene Neoprene
such as drums or tank cars headgear and impervious clothing such
noopy are desirable
SUBJECT TO DISCLOSURE RESTRICTION
40785
-2-
EYE CONTACT Corrosive Contact is likely to cause injury
Wear chemical
goggles when handling Full length face shields may be worn in addition to goggles when complete face protection is
desirable In case of contact hold eyelids open and wash
immediately with a gentle stream of water for at least 15
minutes preferably at an eye fountain Get medical attention
immediately
INHALATION
Excessive inhalation of vapor is hazardous
It may cause
respiratory difficulties lung damage and affect the kidneys
The Threshold Limit Value is 5 ppm
FIRE HAZARD Flash point is 185 TOC
1.5 by volume in air
Lower explosive limit is approximately
GLW
SUBJECT TO DISCLOSURE RESTRICTION
40786
Safety
Safety
hey
SUBJECT TO DISCLOSURE RESTRICTION
Section
Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
VII
SAFETY
MANUAL
VOLUME Pago
Date Cancels
I 811
9-11-62
None
A. DISTRIBUTION OF MANUAL
The Factory Safety Manual is published by the Safety Department all plants were supplied with copies of the manual in 1960. Should additional copies be required contact the Home Office Safety Department
B. TABLE OF CONTENTS OF THE FACTORY SAFETY MANUAL
Section
Contents
I
Safety and Accident Prevention
A. Educating Employees To Use Safety Practices
B. Elimination of Unsafe Conditions
C. Inspection of New or Rebuilt Equipment and New
'
Materials and Processes
D. Safety Health & Fire Control of Raw Materials and
Compounds
E. Safe Clothing and Protective Equipment F. Housekeeping G. Reporting Factory Injuries and Getting First Aid
Treatment
H. Investigating Accidents
-
I. Figuring Accident Rates J. Training Aids and Interest Stimulators K. Firestone Safety Rules L. Safety Program of the Firestone Tire & Rubber Company
M. Handling Cases Involving Damage or Broken Glasses
N. Safety Engineer's Responsibility
II
Fire Protection
Plant Protection
.
|
Page
1 4
5
600 600 10
11 12 12 14 15 16 22 25
28
47
5-4273
-
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40788 40788
F
Section Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
VIII
2
SAFETY __
SAFETY PROCEDURES
VOLUME
I
Pago
B.2.A.2 B.2.A.2
Date
11-8-62
CanNc oneels
II
III
A. B.
Purpose Of These Standards
The purpose of this procedure is to give ways to
A. Guard against the improper use of dangerous materials now in use at the plant level
B. Insure adequate handling and protective measures for new
chemicals introduced as raw materials at the time of their introduction into production
C. Control exposures to products of the chemical reaction
of two or more raw materials
D. Guard against the use of raw materials for purposes other than those specified
E. Arrange for proper storage of materials which may be affected by heat humidity or temperature extremes
F. See that the method of disposal of dangerous materials does not create a fire or safety hazard
Procedure
When there is a possibility of any of the conditions noted in Part II existing the question shall be called to the attention of the Plant Safety Engineer by the Chief Chemist or the Development Head of the plant This does not preclude the matter being raised by some other division such as the production division the engineering division or the
purchasing division If it is possible to do so the question
of the safe use of any new material or process should be raised while in the planning or experimental stage so as to prevent excessive delay when the material or process is to be put into production Such a procedure will not only save time but also money and is highly desirable
To ascertain the hazard involved the Plant Safety Engineer
will consult with the Chief Chemist and will also check with the Plant Medical Department the Plant Fire Chief
and the Plant Purchasing Department Head The latter can often find from the supplier of the material or equipment
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
4078940789 40789 40789
Section Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
VIII
2
SAFETY SAFETY PROCEDURES
VOLUME Pago
Date Cancels
I 82A3 82A3 82A3 11-6-62
None
PLANT RELEASE NO 10-10 Continued
some idea of the hazard involved and the necessity for control Consideration should always be given to the possible substitution of less hazardous materials or processes for the ones contemplated before control measures
are considered
C.
Should the knowledge gained at the plant level be insufficient
to ascertain the extent of the hazard or the means of
control the Plant Safety Engineer shall directly or through the Plant Industrial Relations Division contact the Home Office Safety Department This department in
turn will discuss the matter with such other Home Office
departments as the Medical Department Engineering Department Development Department and Fire Department so as to be able to advise the plant concerned with the problem
D.
Once a procedure has been established and approved for
safeguarding the use of a hazardous material or process
it shall be the Plant Safety Engineer's responsibility in
cooperation with the management of the department involved
to see that the proper controls are put into effect and that
all personnel involved are properly informed of the necessary
safe practices to be followed Written copies of the
procedure should be supplied to all interested plant departments
The adequate labeling of hazardous material while in the
plant should be a part of this procedure
E.
A copy of all written procedures as established under Item
D shall be sent to the Home Office Safety and Medical
Departments so that such information may be passed on to
other plants where the hazardous condition may exist at the
present or at some future time
F.
When the question raised has to do with health of the user of
a product manufactured by us the matter may be referred
directly to the Home Office Medical Department which has
an established procedure for ascertaining the answer to
such questions
4273
The Firestone Tire & Rubber Campany
SUBJECT TO DISCLOSURE RESTRICTION
40790
F
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section
VIII
SAFETY
Part
2 SAFETY PROCEDURES
VOLUME
Page
I B.1
Date
11-8-62
Cancels
B. HAZARDOUS MATERIALS
SAFE HANDLING OF HAZARDOUS MATERIALS
Quoted below is Mr. J. V. Cairns letter dated
subject
May 1 1962
on this
Greater emphasis must be placed on our procedures for handling all materials some of which may present serious hazards In order that these procedures will be clearly understood and definite responsibilities assigned we are revising the previous instructions for the safe handling of hazardous materials You should see that the parties concerned in your plant are made aware of this procedure and its contents Copies are being sent to Chief Chemists Plant Engineers and Safety Engineers
Its basic function and purpose is to provide a workable method that entails a minimum amount of delay which insures the safety of all employees
The procedure entitled Safe Handling of Hazardous Materials dated May 1 1962 supersedes Safety Health and Fire Control of Raw Materials issued by Mr. J. A. Meek dated October 7
1957.
The purpose of this release is to place directly in the hands of each Plant Engineer for his close observance the attached copy of instructions on
Safe Handling of Hazardous Materials consisting of two pages dated May 1 1962
For record purposes we are informed copies of these instructions have been sent to your Plant Manager Chief Chemist and Safety Engineer Please give your full cooperation in complying with these instructions
5-4273
The Fractone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40791 40791
Section
Part
VIII 2
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
SAFETY SAFETY PROCEDURES
VOLUME
Page
Date
Cancels
B.
11-6-62
None
SAFE HANDLING OF HAZARDOUS MATERIALS
I.
Introduction
The introduction of new materials and manufacturing operations into our plants make it mandatory to exercise careful and continuing control over the materials and processes which may be a source of danger to the health and safety of our employees
II
Purpose
A.
To guard against the improper use of hazardous materials now in
use at the plant level
B.
To insure adequate handling and protective measures for new chemicals
introduced into production
C.
To control exposures to chemical reactions of these raw materials
D.
To arrange for proper storage of materials which may be affected by
heat humidity or temperature
E
To establish a method of disposal of hazardous materials so as not to
create a fire or safety hazard
F.
To guard against the use of raw materials for purposes other than those
specified
III
A.
Procedure
The question of the safe use of any new materials or process shall be raised while in the planning or experimental stage and shall be reported to the Home Office Industrial Hygiene Department by the Chief Chemist if new materials involved or the Chief Engineer if process is involved This will prevent excessive delay when the material or process is to be put into production Consideration should always be given to the possible substitution of less hazardous materials or processes for the ones contemplated before control measures are
considered
4273
The Firestone Tire & Rubber Company
ee
SUBJECT TO DISCLOSURE RESTRICTION
40792
(7
Section VIII Part 2
~
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
SAFETY
;
SAFETY
PROCEDURES
VOLUME
Page
Date Cancels
I
8.2.B.3
10-24-66 10-24-66
8.2.B.3 dated
11-6-62
SAFE HANDLING OF HAZARDOUS MATERIALS Continued
In order for the Industrial Hygiene Department to make a sound judgment about potential hazards and to outline proper means for their control the following information on new materials including those for research
and development is required
1. 2
3
Flash point and fire point
All available toxicological data particularly that on inhalation skin and eye contact
The chemical identification
4 Handling and storage precautions
5. Special medical procedures recommended in case of
exposure
6 A detailed explanation of how the material is to be
used including mention of any elevated temperature
involved
The supplier should supply the information in 1 through 5 not
all of it will be applicable to all materials In this event
the answer may be none particularly for items 1 and 5. If the
supplier is reluctant to divulge the chemical identification to plant personnel he may send it directly to the Industrial Hygiene Department In this case the chemical identification is kept confidential if requested and is marked as such when filed
B.
When question raised has to do with health of the consumer of a
product manufactured by us the Chief Chemist shall refer the matter directly to the Home Office Medical Department which has an estab-
lished procedure for ascertaining the answer to such questions
When hazardous materials are to be introduced into production in plant these steps are to be followed
1. The fact shall be called to the attention of the Plant Safety Engineer by the Chief Chemist of the plant This does not
preclude the matter being raised by some other division such as Development Production Engineering or Purchasing
2 To ascertain the hazard involved the Plant Safety Engineer
will consult the Chief Chemist the Plant Medical Department the Plant Fire Chief and the Plant Purchasing Depart-
ment Manager
4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
4079340793 40793 40793
F
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Sturion VIII
SAFETY
VOLUME I
j
Page
8.2.B.4
Date
10-24-66
SAFE HANDLING OF HAZARDOUS MATERIALS Continued
11-6-62
The latter can
equipment some
for control
often find from the supplier of
idea of the hazard involved and
the the
material or necessity
Plant 3 Should the knowledge gained at the plant level be insufficient to ascertain the extent of the hazard or the means of control the Plant Safety Engineer shall directly or through the Industrial Relations Division contact the Home Office Safety
Department
IV A.
Enforcement of Procedure
be Once a procedure has been established and approved for the safe
handling of a hazardous material or process it shall the Plant
Safety Engineer's responsibility in cooperation with the management of the department involved to
1 See that the proper controls are put into effect and maintained and that all personnel involved are properly informed of the necessary safe practices
2 Supply written copies of the procedure to all interested plant departments
3. Label adequately all hazardous material while in the plant
.
2
V. Approvals
A copy of all written procedures as previously outlined shall be sent to both Home Office Safety and Medical Departments for approval This will tend to establish and standardize similar procedures throughout our company It will prevent unnecessary duplication of effort It will promote a freer interchange of information
VI
Special
Problems
Materials and
handling will
will indicate
processes found by the Home Office to require special be listed under separate cover Application instructions
for each pigment the necessary safety precautions required
.EV
4273
G. L. WILSOWILNSON
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40794
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section
VIII SAFETY
Part
2 SAFETY PROCEDURES
YOLUME I
Paga = 8.2.B.5
Date 2-5-63
Cancels None
B. HAZARDOUS MATERIALS
TEFLON
The use of TEFLON for gaskets compressor rings packing and coatings
pipe seals machine parts and products material is becoming more wide-
spread in industry Sheet stock bar stock tape and other forms of
are
TElFubLrOiNcant
used
for machine
parts
and
occasionally
it
is
used
as
a
dry
The following information has been received and is sent use to instruct your personnel in the safe procedure of
as indicated
to you for your handling TEFLON
TEFLON
harmless unless exposed to extreme temperatures
of for higher TEFLON when unheated may be taken
in with food or drink without ill effect TEFLON RESINS
are toxic except when exposed to the high temperatures
as stated
Fumes from any resins paints solvents and elastomers as well as naturally occurring polymers like rubber coal silk
and wood may be toxic Therefor thee ventilation precautions
to be observed when heating TEFLON RESINS are the same as those that should be observed when heating other such conventional materials Ventilation is necessary and important as is a proper coolant when machining TEFLON
The ATTACHED RULES are felt to be adequate for the present operations however should a greater volume of work develop the need for an isolated shop area with proper exhaust equipment may become necessary
FIRESTONE SAFETY RULES FOR THE HANDLING OF TEFLON PRODUCTS
The following rules provide adequate protection for working personnel and shall be obeyed
1 DO NOT HAVE OPEN CIGARETTES CIGARS OR PIPE TOBACCO ON PERSON OR IN THE AREA WHILE GRINDING FILING SAWING MACHINING WELDING BURNING OR CUTTING TEFLON BY TORCH
20 DO NOT SMOKE OR PERMIT SMOKING IN AREA WHERE TEFLON IS BEING FILED GROUND SAWED MACHINED WELDED BURNED OR CUT BY TORCH
3. NATURAL VENTILATION IS ADEQUATE FOR MOST GRINDING & MACHINING OPERATIONS HOWEVER WHEN WELDING OR CUTTING COATED PARTS MECHANICAL VENTILATION SHOULD BE PROVIDED
4273
The Firestone Tire & Rubber Campany
SUBJECT TO DISCLOSURE RESTRICTION
40795 40795
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section VIII SAFETY Part 2 SAFETY PROCEDURES
VOLUME I
Page 8.2.B.6
Date Cancels 2-5-63
Cancels None
FIRESTONE SAFETY RULES FOR THE HANDLING OF TEFLON CONTINUED
4 MAINTAIN A CLEAN WORK AREA BY REMOVING TEFLON DUST OR PARTICLES FROM WORK SITE IMMEDIATELY AFTER COMPLETION OF JOB
5 BE SURE CLOTHES ARE FREE OF TEFLON DUST OR PARTICLES BEFORE LEAVING
WORK AREA
6 WASH HANDS AND REMOVE DUST FROM CLOTHING BEFORE SMOKING AFTER FILING GRINDING SAWING OR MACHINING TEFLON
7. ALL SCRAP TEFLON AND TEFLON MATERIALS MUST BE ACCUMULATED IN
A COVERED MARKED IN
METAL LARGE
CLOENTTTAEIRNSERSSCRAC P CROANTPATIENFELRONTOONLBYE
NOT BURNAND PAINTED YELLOW
-- DO
8 WHEN SCRAP CONTAINER IS FULL THE COVER MUST BE TIGHTLY SECURED
TO THE DRUM
9 THE DRUM OF SCRAP TEFLON WILL THEN BE REMOVED TO THE TRASH COL-
LECTION AREA THE CONTRACTING TRASH COLLECTOR WILL DISPOSE OF THE #3
COVERED SCRAP DRUM AS A UNIT
10.
A NEWLY PAINTED AND LETTERED DRUM MUST BE AVAILABLE AND USED WHEN A DRUM FILLED WITH TEFLON SCRAP IS SENT TO THE TRASH AREA
5-4973
The Proctone Tire & Rubber Compony
SUBJECT TO DISCLOSURE RESTRICTION
4079406796
40796
Section Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
;
VIII
2
SAFETY SAFETY PROCEDURES
VOLUME Pago
Date
Cancels
I C.1 10-25-62
None
C. BAGOMATICS AND AUTOFORM PRESSES
PROCEDURE IN CASE OF POWER FAILURE
When a power failure occurs there are 3 objectives -
1. Save the tires in the presses
2. Prevent injury to personnel 3. Prevent damage to the equipment
To accomplish these the following procedure should be followed
I. Safety Features
Considerable planning has gone into this phase of the operation and Bagomatic and autoform installations have the following features
a Pressure Switches to prevent presses opening with
pressure in bladders or domes
b An automatic emergency instrument air valve in the main factory air line which closes shutting off all air to the factory when the pressure drops to 65 lbs
and conserves it for instrument air only
c A Deisel generator is provided to supply emergency
power so that a limited number of presses can be
opened
d Steam driven hot and cold internal water pressure pumps are provided which can be started when the electricity goes off
e A Deisel or steam driven instrument compressor is provided to supply instrument air if the main compressors stop
4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40797 40797 40797 40797
Section Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
VIII 2
SAFETY SAFETY PROCEDURES
VOLUME
Page
Date
Cancels
I
C. 10-25-62
None
PROCEDURE IN CASE OF POWER FAILURE CONTINUED II What Happens When Power Fails
a Electric driven hot and cold water pressure pumps stop
b Hot water circulating pumps stop
c Timers on presses stop
d Power to open presses ceases
e In case of a prolonged power failure and inability to get the emergency compressor started the presses will all blow down if the pressure gets down to 30 P. S. I. This is the worst thing that can happen because many tires will be scrapped
f Because the hot water circulating pumps are electric
driven the tires will be undercured if the internal hot
water period on each press is not lengthened to compensate lack of circulation
g If presses are opened with insufficient internal cooling
and blowdown the bladders may swell and burst
III What To Do When The Power Fails
a In case of a momentary failure where the power is
off a few seconds and then comes back on first restart the electric driven pumps
This is usually all that is necessary because the timers automatically resume running and go thru the normal cure and will open automatically
b In case of a longer power failure do the following-
1 Note the time the power ceases
The Firestone Tire & Rubber Company SUBJECT TO DISCLOSURE RESTRICTION
40798 40798 40798
Section
Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
VIII 2
SAFETY
SAFETY PROCEDURES
VOLUME
Page
Date
Cancels
I
C.
10-25-62
None
PROCEDURE IN CASE OF POWER FAILURE CONTINUED
III What To Do When The Power Fails Continued
r
b Continued
2 Start the steam driven hot and cold water pressure
pumps
3 Start the Deisel Generator and the Emergency Compressor if they are not the type that start automatically
4 Stop laying tires even though the emergency power permits presses to be opened This power is intended only to save the tires in the presses
5 Follow the presses and if they are on the hot water internal portion of the cure stop the timer and allow additional time to compensate for the fact that the water circulating pumps are not running The Laboratory man should be there to tell you
how much time to add
6 Continue to follow the presses and put them on internal cold water at the proper time This usually means only turning the timer switch back on however if you have lost the emergency power also this can be done either by manually turning the cam shaft
in the timer or by latching up the internal hot water timer valves and unlatching the internal cold water
timer valve In such cases leave them on cold water
until you have power to open the presses them the normal blow down and open them
Then give
5-4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40799 40799 40799 4079 40799
Section Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
VIII 2
SAFETY SAFETY PROCEDURES
VOLUME
Page
Date
Cancels
I C. 10-25-62 None
PROCEDURE IN CASE OF POWER FAILURE CONTINUED
III What To Do When The Power Fails Continued
b Continued
It is important that all presses receive the proper internal cooling water time before opening because even though the pressure may have been blown down sufficiently to open the press there still may be some hot water remaining in the bladder and the clamping rings in a Bagomatic or the
well in an autoform would still be hot and when the
bladder elongates in M. or is pushed into
the well in F. this water strikes the hot metal parts and flashes into steam which causes the bladders to swell and even burst
IV Advance Precautions
a Sometimes you have warning of a power failure as for example the threat of a work stoppage at the power company or perhaps
there is a severe electrical storm in the area In such cases
put the steam driven pumps in operation in advance and be ready to start the Deisel Generator and the Emergency Compressor
on short notice
b Pressure switches on all presses should be checked every 6 months
c Emergency Instrument Air Valve should be checked periodically
d Deisel Generator and Emergency Air Compressor should be started once per week and operated for 5 minutes to insure that they are in satisfactory operating condition
5-4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
48800 48800 48800 48800 48800
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section
VIII
Part
3
SAFETY OPERATING SAFEGUARDS
VOLUME
Page
Date
Cancels
I 3. A. 11-6-62 None
A. COMPRESSED AIR EQUIPMENT
PRIOR RELEASE NO 35
SUGGESTED OPERATING SAFEGUARDS FOR COMPRESSED AIR
EQUIPMENT
GENERAL
All equipment should be designed to withstand the maximum pressure that might be required when in operation
Equipment should be installed at a location where the air intake to the
compressor will be as clean pure and cool as possible Keep it away from areas where flammable and explosive dusts vapors and gas fumes are heavy
All equipment should be located where it can be thoroughly and
conveniently serviced and inspected Always allow sufficient clearance
between bottom of air receiver tank and floor so as to permit proper inspection and maintenance
Follow the recommendations of the manufacturer for installation and
operation including lubrication
AIR RECEIVER TANK
For required maximum pressure tank should be built to Section 8 of M. Code or such other code that was jurisdication in the area
where tank is located
Tank must be provided with a drain valve or cock at the bottom Arrange to drain daily so as to remove moisture as fast as it condenses
Keep tank painted and clean as a means of preventing corrosion on
external surfaces
PROTECTIVE DEVICES
Automatic start equipment should have safety guards on all exposed moving parts
Test regulator manually at least every day Test safety valve to determine if it is in correct operating condition and clear of any dirt that might have lodged in volve or its opening
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40801
Section
Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
VIII 3
SAFETY OPERATING SAFEGUARDS
VOLUME
Pago
Date
Cancels
I 8.3 2 11-6-62 None
PRIOR RELEASE NO 35 Continued
SUGGESTED OPERATING SAFEGUARDS FOR COMPRESSED AIR EQUIPMENT
3
Never place a valve between the compressor and receiver
5-4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
1
40802
Qu.8.4 Qu.8.4 Ballow
:
ee
:
fe
pene ee ee ee
ree 6
cp eee eee ee ee
ee
IF
Py
WED wee tee ee ee ee
TO
TO
ADR
ADR ADR
oot cortae
MANUALE MANUALE MANUALE
&
&
ADMILIT - woe~ ADMILIT ADMILI ADMIT LIT
nd PLAN
PLAN
PLAN
ENGINEER'S MANUALA
INTELANTR INTELANTR INTELANTR
ot as:
cea,
o wad
oe
Marae
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=
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het
The 155 155 Preet
in your rutuali giok 1111 Tilver
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20 th is
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+
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RECEIVED
JUN
1965
a
RECEIVED
JUN 16 1965
DR H.
SUBJECT TO DISCLOSURE RESTRICTION
Canber
Canber
Canber Cost
Cost
,
hone
hone
hone
SUBJECT TO DISCLOSURE RESTRICTION
40804 40804 40804
Section
Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
ACCIDENT PRODUCING PHYSICAL CONDITIONS X AND THEIR CONTROL
1 PAINTING
VOLUME II
Page
10.1.H.1
Date Cancels 5/17N/65o5n/e17/65
PAINTING STANDARDS
New painting standards and specifications have been approved for immediate adaptation on all Firestone properties effective February 1 1965 The listed paint and types are in reference to one manufacturer's color codes and it is recommended where possible to use their products Some minor variations may be necessary due to availability of
these specific paints in your area therefore substitute
local manufacturer's products may be used However in no way should the general color scheme be changed Likewise
the quality of materials should not be lowered
The Janitor Service is to be scheduled on the basis
that equipment and facilities will be repainted every four
4 years During the interim period a scheduled cleaning
program is also to be effective in order to maintain equipment and facilities in a neat and orderly condition Touchup painting is to be done when and where required
4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40805
Section
Part
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
ACCIDENT PRODUCING PHYSICAL CONDITIONS
X
AND THEIR CONTROL
2 MACHINERY
ee
VOLUME _ Pago
Date
Cancels
I
10.
11-7-62 None
A. MECHANICAL HAZARDS
PIERCE TIRE WRAPPING MACHINE
We just have word Hamilton experienced a mechanical failure on their tire wrapping machine While no personnel injury occurred it is evident a serious
hazard exists and precautions should be taken
Machine involved was only recently equipped with wide shuttle Following is quoted from Hamilton letter 2-4-58 to Pierce Wrapping Machine Company
The three screws that fasten the paper roll holder attachment
to the side of the wide cap shuttle assembly sheared off while the machine was in operation The paper roll and holder attachment were thrown out of the machine narrowly missing
the operator
An examination of the screws that failed revealed that
are porous impregnated with a plastic material for approximately 1/2 from the end
they
We are sending under separate cover the top portion of one of the sheared off screws along with a lower portion which
had to be drilled out so that it could be removed from the
shuttle
If you will examine this with a light and glass you can
easily see the holes filled with plastic material especially
in the side of the lower portion The holes and plastic material may have been intentionally inserted during the manufacture of the screws designed to act as some sort of screw lock or the screws may have been made from contaminated material however all three screws sheared
off
flush with the surface of the shuttle
SUBJECT TO DISCLOSURE RESTRICTION
40806
Section X
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
ACCIDENT PRODUCING PHYSICAL CONDITIONS AND THEIR CONTROL
VOLUME
Pago
I 10.
Part
A.
2
MACHINERY
MECHANICAL HAZARDS
Cancals
None
_
DeMATTIA TUBE CURING STANDS - SAFETY HAZARD CORRECTION
Following is report of accident which recently occurred on DeMattia Tube Curing Stand in one of our plants
The operator's right hand was trapped between the two halves of mold due to the top half which is mechanically lifted suddenly falling He sustained fractures on all fingers and bones of hand also lacerations and 3rd degree burns
Upon a full Engineering investigation it was discovered the
accident was caused through the retaining nut on the piston shaft becoming loose and finally detaching itself allowing the
piston which operates the top half of the mold to become inoperative so that it was impossible to life the top mold except
by external force
The safety catch at the back of the mold was in good condition
and it would appear that he had laid a green tube and was not
satisfied so opened the mold by means of the safety pet cock
and attempted to take the tube away before the mold had fully
opened and allowed the safety to engage and at that moment
the nut came away with the results described
It
thread on shaft were in good condition
The nut and
The Firestone Tire & Rubber Company SUBJECT TO DISCLOSURE RESTRICTION
40807
40807 40807 40807 40807
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section x
Part 2
ACCIDENT PRODUCING PHYSICAL CONDITIONS
AND THEIR CONTROL
MACHINERY
_
VOLUME Page
Date Cancels
I 10.2 11-7-62 11-7-62
None _____
A. MECHANICAL HAZARDS
DeMATTIA TUBE CURING STANDS - SAFETY HAZARD CORRECTION
Subaquent to Interplant Release IP 10-6 dated 10-30-58
we have received from Brentford information on Safety Bar
which they have added to their DeMattia Stands
We attach photostat of their print 9128 and by way of
explanation we add their comment to the effect that the
Tee at the extreme end of the operating handle can
contact the projecting pin 4-3 long fixed on the side of
the safety ratchet This enables the ratchet to be disengaged
by operation of the hand lever
.
This information ispassed on to you for your use as you see fit In the interest of overcoming all potential safety hazards we believe you will be interested in taking advantage of this if your present stands do not have some similar safety device
.4973
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40808
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
X
Section
ACCIDENT PRODUCING PHYSICAL CONDITIONS AND THEIR CONTROL
Part 2 __ MACHINERY
VOLUME
Pago
Date Cancels
I 10.2 10.2 C. 12-3-62 None
C. SPECIFIC HAZARDOUS EQUIPMENT
POWDER ACTUATED HAND TOOLS
We quote below a Safety News letter issued 11/21/62 by Mr. M. R. Batche to Safety Engineers in all Firestone plants This additional release is being made to give broad coverage on this subject and to clarify information issued in the past so that it definitely will be understood that the Safety Department does not approve the use of powder actuated tools by Firestone employees or by employees of outside contractors working within Firestone property
This matter should be investigated at once in each plant and the use of such
tools eliminated if any are found in existence
We quote below
On November 10 1962 one of our employees an electrician in an overseas
plant was using a powder gun to drive screw nails to hold clamps for electrical
wire 1/4 1/4 angle
After driving two of them the third hit the ream of the angle and made its way up to a inch cast iron pipe where it split in two and rebounded
5-4271
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40809
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section x
Part 2
ACCIDENT PRODUCING PHYSICAL CONDITIONS AND THEIR CONTROL
MACHINERY
VOLUME
Page
Date
Cancais
I D.1 11-7-62 None
D. OPERATION HAZARDS
SAFETY PROCEDURE - MC NEIL SHEAR STRIP TIRE PRESSES
In recent years we have had several serious accidents where McNeil
Shear Strip Tire Presses opened with pressure in the bag in the dome or both The causes of all of these accidents has not been definitely determined but we feel some of them were caused by pushing the electric contactor in order to open the press and thus stop an overcured tire
To prevent accidents of this type all plants should advise their supervision operators and maintenance personnel of the following procedure
concerning these presses
1
Check at least monthly all the safety devices on the presses There
are three safety devices 1 the internal pressure switch 2 the
dome steam pressure switch and 3 the strain gauge safety If
these safeties are all operating the press cannot be opened when
there is any pressure inside of it unless someone takes a stick and
pushes the open contactor in manually This passes all the
safeties and should never be done
2
At the termination of a cure when a press will not open and the red
light is on indicating there is pressure inside the press turn off all
the services to the press Red tag the press and put a note with the
red tag indicating that there is pressure inside
3
The press should be left until it can be operated by using the normal
push buttom provided on the front of the press This means that
all safeties indicate no internal pressure
If every plant follows this procedure deligently we should be able to eliminate
this type of accident
4273
The Firestone Tire & Rubber Campany
SUBJECT TO DISCLOSURE RESTRICTION
4081400810 40810 40810 40810
Section X
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
ACCIDENT PRODUCING PHYSICAL CONDITIONS AND THEIR CONTROL
VOLUME
Page
I 10-2 3
Part
2
MACHINERY
Cancels None
D. OPERATION HAZARDS
As a result of this accident a meeting was held in Akron to determine the necessary action to avoid accidents of this type in the future This meeting
was attended by representatives of International Production Development
and Engineering
Action decided on is listed below
1
It is mandatory that the drum rotation during the tread stitching
operation shall be so that the top of the building drum is rotating
towards the builder This applies to all tire assembly machines
2
The Engineering Production and Development Departments must
work in close cooperation to be certain that there is no adverse
effect on the quality of the tread splice on those machines that
require reversing the drum rotation
3
Attached are Mr. S. W. Hoffmann's instructions for making tread
splices when the tread is applied from the builder's side of the
drum
4
Each plant shall write a report to Interplant not later than thirty
30 days after receiving this release advising the following
a.
Direction of drum rotation of each tire assembly machine
during the tread stitching operation
b
Side of drum from which tread is applied on each machine
Co
When tread is applied from builder's side of drum is method
A or B used as outlined in Mr. Hoffmann's instructions
d
Give details on any production or quality problems that
result from this release
-4973
The Prestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40811
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
ACCIDENT PRODUCING PHYSICAL CONDITIONS
X
Section
AND THEIR CONTROL
,
VOLUME
Page
Date
I
10.
11-7-62 11-7-62
D. OPERATION HAZARDS
DRUM ROTATION DIRECTION
OF MAKING TREAD SPLICES Continued
Method A has been used by our Memphis Plant with Management's permission for several years on the basis that hand stitching operation is closely controlled Adjustment records prove that with this control the quality level is excellent and Memphis have had an excellent OTS record
Each plant will be responsible for setting up their own program-they should advise Akron They will also be responsible for setting up the proper controls and for watching the OTS adjustment record
Recognizing that introduction of tread trays offer in many cases major problems from the standpoint of cost design space etc. we know that tread trays offer the additional advantages of maintaining cleanliness freedom from contamination and uniform application hence are to be considered for each plant's long range program of building more precise and higher quality level tires
4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40812
5
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
C SectionSection
X
ACCIDENT PRODUCING PHYSICAL CONDITIONS
AND THEIR CONTROL
VOLUME
Page
Date
I
10.
10-4-62
Part 2 MACHINERY
Cancels None
D. OPERATION HAZARDS
METHOD B
FEMALE
oe MALE
BUILDER
-- ------ ----
------ FEMALE
BUILDER BUILDER
On
MALE
?
FEMALE
BUILDER
5-4273
BUILDER
an TREAD STITCHER
NOTE
<
MALE FEMALE
TREAD >
/// DRUM
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40813
Section X
Part 2
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
ACCIDENT PRODUCING PHYSICAL CONDITIONS
AND THEIR CONTROL
MACHINERY
_
VOLUME Page
Date
Cancels
I E.l 11-7-62 None
E. AUTOMATION
CURING ROOM ACCIDENT - M. SHAPING
One of our plants recently had an accident on a 40 bagomatic press caused by excessive steam pressure entering the bladders during the shaping operation resulting in bladders and tires bursting Fortunately the area was cleared of personnel and no injury occurred
Engineering Laboratory have reviewed the report on this accident and at their request we attach copy of R. C. Davis letter of 1/16/61 outlining steps which should be taken to safeguard against such an accident
_ CURING ROOM ACCIDENT - M. SHAPING - PLANT REPORT 1-5-61
The instance of the runaway high steam pressure in the shaping steam supply
header normal 35 pai indicates what can happen when controls fail In
this instance an air operated diaphragm steam valve opened wide due to air failure in the controlled air line to it The steam safety pop valve in the header was too small to hold the pressure down to within a few pounds of its set point Steam rushed into the bladder of the Matic press so fast and
expanded the tires so rapidly the operator no doubt became panicky and failed to push the shaping control valve button on the press which would have stopped
shaping The tires and bladders burst with explosive force Luckily no one
was hurt
We would like you to send a copy of their letter to all tire plants domestic and
foreign and emphasize that the following steps should be taken to safeguard
against such an accident
3-4273
The Firestane Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40814
ADMINISTRATION MANUAL
Section
Part
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
ACCIDENT PRODUCING PHYSICAL CONDITIONS AND THEIR CONTROL
3 ELECTRICITY
VOLUME
Page
I 10. 3. A.1
Date 11-7-62 11-7-62
Cancels
None
A. ELECTRIC HAZARDS
BAGOMATIC TIRE PRESS - SAFETY
A number of very serious accidents have occurred at the bagomatic tire curing stands when the presses opened up unexpectedly during the curing period while
the hot water was still under pressure inside of the bladder Such action
results in an explosion of the bladder and tire with damage to the press and
serious burning and injuries to any personnel present in the area
The false opening of the presses has been found to be caused by grounding faults or short circuits in the wiring system involving a bypass of the safety pressure switches The electrical circuit design has been reviewed with the McNeil Machinery & Engineering Company and they have revised the design to eliminate this obvious weakness They are changing the wiring on all future presses so that the available voltage at the contactor will be reduced by the resistance of a series pilot lamp to a value too small for operation of the contactor
The wiring changes requires for this purpose as shown by red markings on the following prints
Pratteln Plant - Bagomatic Press 230-40 Wiring Diagram 33729-1 Christchurch Plant - Bagomatic Press 230-40 Wiring Diagram 33729-1 Phoenix Plant - Bagomatic Press 275-45 Wiring Diagram 33542
In order to obtain satisfactory operation of the pressure switch contacts it
will also be necessary to change the wiring at the No. 3YST micro
switches as shown on the diagram so that the hot line and the ground line connections are positioned one directly above the other and not on diagonally opposite contacts
By means of the above minor changes in wiring we can remove the serious hazard that now exists and it is imperative that all plants take immediate action to make this change on their presses
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40815
Section Part
ADMINISTRATION MANUAL
X
4
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
ACCIDENT PRODUCING PHYSICAL CONDITIONS AND THEIR CONTROL
STORAGE OF MATERIALS AND CHEMICALS
VOLUME
Page
Date Cancels
I 10. 4. A. 11-7-62 11-7-62 None
A. RUBBER PRODUCTS
PRIOR RELEASE NO 3
RUBBER INDUSTRY NATION WIDE STANDARDS FOR STORAGE OF RUBBER PRODUCTS
FORWARD
Rubber products are readily combustible and fires in them are difficult to extinguish because of the intense heat and the heavy smoke which are produced Many large scale fire tests have been made with protection from automatic sprinklers These tests were made with different piling methods and height of piles The most common method of piling is to place tires horizontally one
on another
Tests have shown that fires may be controlled by systems employing either conventional or spray type sprinklers Final extinguishment may be accomplished by hose streams and probably by removing from the piles involved all tires in which fire is well established It is recommended that suitable and adequate fixed automatic fire protection be provided and also that the building and the tire storage be arranged so that hose stream protection may be used
1
WAREHOUSES
Fire resistive construction is preferred especially if the building is more than one story in height Noncombustible or mill construction is acceptable
Walls should be of masonry or at least of noncombustible construction Floors
and roof should not be of open wood joist or other light wood construction If a stored building is used all floor openings should have standard cutoffs It is desirable to provide some means of venting smoke and toxic vapors which are produced by the burning of rubber products The maximum area per building or fire division should be kept to reasonable limits considering the various factors of construction tire piling arrangements and values which may be exposed to a single fire but should not exceed 100,000 100,000 sq ft of net
storage space
2
TIRE PILING
Pile height should not exceed 20 feet in sprinklered buildings and 10 feet in unsprinklered buildings The area per pile should not exceed 8,000 sq ft The main unbroken aisle extending the full length or width of the fire
area should be at least 8 ft wide and cross aisles should have a minimum
4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40816
ADMINISTRATION MANUAL
Section
Part
4
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
ACCIDENT PRODUCING PHYSICAL CONDITIONS
= AND THEIR CONTROL
STORAGE OF MATERIALS AND CHEMICALS
VOLUME
Page
Dato
Cancels
I
3
10. 1 -7-6211-7-62 1 -7-62
None
A.
RUBBER PRODUCTS
PRIOR RELEASE NO 3 Continued
18 ft 20 ft
4
WATER SUPPLIES
.48 gpm ft .60 gpm ft
.40 gpm ft .48 gpm ft
Water supplies should be adequate to immediately supply the conventional or spray sprinklers on the basis indicated above They should also be capable of supplying 500 gpm at adequate pressure to hose streams The water supplies should be able to continue meeting these demands for at least one hour
5
SMALL HOSE PROTECTION
Small hose protection should consist of not less than one 1-1 inch hose line with approved hose and nozzle for each 10,000 sq ft of floor area In addition to the hand hose there should be provided in sprinklered buildings one hand extinguisher unit for each 5,000 sq ft of warehouse area and in unsprinklered buildings one extinguisher unit for each 500 sq ft of warehouse area
6
WATCH AND ALARM SERVICE
Watch and alarm protection should consist of recorded rounds and waterflow devices on all sprinkler risers or approval central station supervisory service may be employed supplemented in special cases by human supervision
7
GENERAL PROTECTION
General protection should include ample outside hydrant protection standpipes
with hose outlets in cutoff stair towers in storied buildings ample
supply extinguishers excellent housekeeping and enforcement of NO SMOKING
regulations
8
PRIVATE FIRE BRIGADE
and A private fire brigade should be well organized
ample supply of smoke masks
drilled and provided with an
5-4273
NOTE It is important that both the Private Fire Brigade and the
Public Fire Department fully understand the importance of beginning
the application of hose streams early in the fire while it is possible
to approach it closely and before smoke accumulates to such an extent
that
the
location
of the
fire
cannotbe exactly
determined
Company
SUBJECT TO DISCLOSURE RESTRICTION
4081407817 40817 40817 40817
Section X
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
ACCIDENT PRODUCING PHYSICAL CONDITIONS AND THEIR CONTROL
VOLUME
Page
I 10. A.
Part
A.
4
STORAGE OF MATERIALS AND CHEMICALS
RUBBER PRODUCTS PRIOR
RELEASE NO 21
Cancels None
P. BORDA E. H. HUNNICUTT J. C. BLUE A. J. DIMAGGIO J. H. FORMAN W. C. RANKIN J. S. GIEGEL R. L. BROWN G. J. PENFIELD
M. E. AKE JR G. L. ANDERSON J. MATTINSON J. TELLERIA A. H. FINNEY R. L. NOYES C. W. CAMPBELL A. C. KOENIG C. A. HILL
P. F. KRANS H. H. WIEDENMANN R. W. ELSASS
SPECIFICATIONS AND PROCEDURE FOR THE STORAGE OF CRUDE AND SYNTHETIC RUBBER
We quote following from Mr. H. Field's Insurance Dept. May 4 letter
We attach herewith copy of a recently revised bulletin Specifications and Procedure for the Storage of Crude and Synthetic Rubber This revised manuscript is the result of a joint and careful study made by our Rubber Purchasing Department Traffic Department and Insurance Department of the problem of storage of these high valued materials
It is our recommendation that copies of this manuscript be forwarded to each of our plants and subsidiaries who store and handle crude and synthetic
"
rubber
Questions concerning the numerous points set forth in the manuscript should be directed to the Home Office Insurance Department who will then contact the other departments involved for an answer
We attach copies of Specifications and Procedure for Storage of Crude and Synthetic Rubber
5-4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
4081480818 40818 40818 40818
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section
Part 4 4
ACCIDENT PRODUCING PHYSICAL CONDITIONS AND THEIR CONTROL
STORAGE OF MATERIALS AND CHEMICALS
VOLUME
Page
Date
Cancels
I 10.4 7 11-7-62 None
A. RUBBER PRODUCTS
Weight
Smoked Sheets Smoked Crepe
Crepe Rubber
250 lbs gross each 260 lbs gross each 224 lbs gross each 110 lbs gross each
C. Bags Balls Cases Wild Rubbers Varioud Coverings
Bags - 50 to 100 lbs
Balls - 80 to 150 lbs Cases - 400 to 500 lbs
d Synthetic Rubber various coverings 72-74 lbs
3 Specifications for storage of rubber
The following specifications are the result of many years of experience in the storage of crude and synthetic rubber and are also designed to meet insurance requirements They in no way relieve the warehouseman of his responsibility in following good warehouse practices
a Small fire areas are preferred for the storage of these materials wherever available The larger the area used for storage the greater the opportunity for fire loss Buildings having small areas or divided into small units by fire walls and fire resistive floors should be utilized in preference to large undivided areas
b The management of warehouses used for storage of these materials will be held responsible for the proper maintenance of the building and its equipment for the provision of adequate watchman service and other features of guarding where specified for the enforcement of the prohibition of smoking for the
elimination of combustible waste materials and for any other
potential sources of the start and spread of fire and for proper practices in the piling of materials
C. All outside openings in buildings shall be maintained secure against the access of unauthorized persons Fire walls and floors shall be maintained in good repair at all times to restrict the spread of fire from any area where it may originate
5-4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40819
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section X
ACCIDENT PRODUCING PHYSICAL CONDITIONS AND THEIR CONTROL
Part
4. STORAGE OF MATERIALS AND CHEMICALS
VOLUME
Page
Date
Cancels
I 10. A.
11-7-62 None
A. RUBBER PRODUCTS
j
Fire Resistive Walls The minimum recognized standard
for resistive walls shall be in cement plaster metal-
lath metal frame partitions
k Maximum Height and Size of Piles no case shall the
rubber be piled higher than 10 ft Due allowance should also be made for safe floor loading Clearance between top of piles and sprinkler heads shall be not less than 18 in and preferably 3 ft Storage piles should not exceed 2500 sq ft in floor area and should be separated from other piles by at least a 5 ft cross aisle Main trucking aisles should be
limited to not less than 10 ft in width
1
Cleanliness Floors shall be thoroughly cleaned of combustible
waste oxidizing oils and any other hazardous waste materials
11 Electrical Equipment shall be safely arranged Particular attention shall be given to switches junction boxes extension cords and other equipment capable of producing an arc or short
circuit
n Other Storages Crude and synthetic rubber storage should be
separated from other combustible storage as far as practicable
5-4273
The FireTs iret&oRunbbeer Company
SUBJECT TO DISCLOSURE RESTRICTION
40820
ADMINISTRATION MANUAL
Section X
Part 4
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
ACCIDENT PRODUCING AND THEIR CONTROL
PHYSICAL CONDITIONS
STORAGE OF MATERIALS AND CHEMICALS
VOLUME
Pago
Date
Cancels
I 10. 11-7-62 11-7-62 None
RUBBER PRODUCTS
P. Rubber must be kept perfectly dry at all times If there is any question of the absorption of moisture by rubber from floors side walls pipes and the like warehousemen must take necessary precautions to prevent damage to rubber from absorption of moisture
Frequent ventilation of premises in fair weather is required
Dry dunnage at least two inches in thickness must be used on any floors which show even the slightest tendency to dampness
Rubber must be stored by grade marks appearing on packages
OUTSIDE STORAGE
a Value of individuals piles should be limited to 50,000 50,000 This value of crude rubber at current market values could be stored in piles approximately 22 x 30 x 15 ft high Pyramided piles require greater areas
Storage piles in groups should have individual piles at least 30 ft apart and preferably 50 ft apart The limit for each such group should be 500,000 500,000
Groups of 500,000 value should be separated by 100
aisles or more
Water supplies hydrants and hose should be such that six to eight hose streams are available to combat a fire in any individual pile and to protect adjoining piles
4273
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40821
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
ACCIDENT PRODUCING PHYSICAL
Section X CONDITIONS AND THEIR CONTROL
Part
MATERIAL HANDLING
VOLUME
Pago
Date
Cancels
II
10.5.A.1
8-25-65
NONE
A - POWER TRUCKS
SUBJECT SAFETY WARNING LIGHTS FOR PLANT VEHICLES
REASON
To equip all plant rider type power vehicles with standard flashing warning lights Vehicles include platform and fork lift tractors utility vehicles such as sweepers power driven
welder units and personnel carriers
LOCATION
OF INFORMATION Information on this recommendation is contained
in detail in the Plant Engineers Manual - Volume II - Section VII Safety Engineering Part 2 Safety Standards C Material Handling page 7.2.C.1 This information was issued as an
Interplant Release No. IP 10-30 2 pages dated 8-10-65
5-4273
The Firestone Tire & Rubber Company
RECEIVED
SEP 7 1965
C.
L.
INDUSTRIAL WILSON
SUBJECT TO DISCLOSURE RESTRICTION
40822
Flammable ExEplxopsilvoe sive
FlambleExplosive
FlamableExplosive
and
Matorial
SUBJECT TO DISCLOSURE RESTRICTION
Section XI
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
EXPLOSIVE AND FLAMMABLE MATERIALS
. VOLUME
Page
I 2.1
Part
2
PROPERTIES OF FLAMMABLE MATERIALS
Cancels
None
NAME
Acetal
Acetaldehyde
Acetanilida
PROPERTIES OF FLAMMABLE LIQUIDS GASES AND SOLIDS
SYNONYMS
FORMULA
Mash Poin
F Explosive Uravity Clowed Cup Open | | | Cup
Explosive %
Explosive Limite
Air
Vol Air
lower Upper
Specifie
Specifie DemanlyDVaepermanly
| Water 100
Air 1.00
Bailing
Bailing
Print
F
Diethoxyethane Aldehyde
|
1.
Ethanal Acetyl Aldehyde |
Antilahrin '
Ethan Asli
ww 2.
es -
Orido
os
OCHD
OCHD ee CHO
se wees
CONIGH 2...
ee CODI
.-.
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ad
-%
wee
104
fal
| 2.
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1.68
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dare
sto}
nese
a
weve
| 267 | 1013
gaz 9709 T.28 .08 Von
aos 215
1s?
70
465
al
207
248
as2 | 24
Acatone
Acatonyl Acetonhan e
AcAecteytlylssccaattoonnaa
.
> |
eee
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Acetyl Chlorids
Acetylane
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-]
Acetyl feruile Acrolein Amylis Azid oo
Penpennne
Penpen ne Dimethylketone ...
| 5 leanedions . 5
- Phenylmethyl
Ketone - - |
Tolaidine
2...
.|
2. Pontanedinne
.
1...
- - - Ethanoyi Chloride 2. Elbyna Ethine 1. - . -
peaperal Acrylia
Alesha
Aldaby 2- of
PropantsAsid 2 ee
CHICOCH
CILCOCI.CR.COCK
CILCOI.CR.COK
CILCOCI.CR.COCK
ee
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2 ee CallCock ww
GILNHCOCH 2.40...
CIL.COCH.COCK
Q
174
zat 13 13
is
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COCI
eeeettee ee gee C
ilCOO
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CIL.CHEHO CIL.CHEHO wt CIL.CHEHO .
2
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ene CJI.COH
22. ee
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216
weer
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wees nese
13.9
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o7e2
ova 1a
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0.978
1.105
nee
uI u
1.062
Acrylonitrila
Adinia Arld Alind Alcohni Allyl Alcohni . Allyl Chloride
Propenenitrile ee
3-11ydroxybutanal Hexanediois Av 2. - - -
>:
|
Hool
2.
ee
Chloropropene os
GITHIEN
COOR
COOR
CODCIHOTLICIH CIT pee
eae
21000:
CHCHCHOR CICH
.. 2.ee
2.
ee
Aluminum Aluminum ew AllylanAluminumePowder Powder + Powder .
Rutanol
Aminosthylethanolamine
Aminosthylethanolamine
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Aminosthylethanolamine .
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ae
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SUBJECT TO DISCLOSURE RESTRICTION
40824
Section Part
2
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
EXPLOSIVE AND FLAMMABLE MATERIALS PROPERTIES OF FLAMMABLE MATERIALS
VOLUME
Page
Dato Cancels
I
11.
10-29-62 None
PROPERTIES OF FLAMMABLE LIQUIDS GASES AND SOLIDS
NAME
SYNONYMO
FORMULA
Flash Point
F
F
7 by Vol Specifie Density Rolling =Co)
| | 1 | Cup
Open
Paplosive Limite In Air
Lower Upper
Specifie | Vapor
=
1.00
1.om
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Rolling
F.
Cyclehernmona we 2. Ketohezamethylana 0...
oof
147
17947
20
, , ,
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delta ce
Texallin | Cyclaberyl Amtate .
5
1)
Adotat~
Texallin Adotat~ | |
Cyrinherylamine . .
Il] Aminneyelshessen |
CyclopentaneCyrinherylamine . . .
.|
Pentamethylme
.
.
.
03 124
tee see
|...
ves
oo
tee
aa
ewe
bees sess
0365
0.731
3.31
00
3.42
340 274
soos | 120.7
CyclopropuT w o e s Trimethylena Trimethylena
methylbenzene methylbenzene
|
|.
Darahydronaphthalene
Decyl Hydrida
Denatured Alcohol > || Dematured ethanol
Colla
ee
eee
ou
|
CH.C 11.
1]
CielClRa8. : aia
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117
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114
sae
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10.3
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0.87 5.0
0730
| | || Pop
0.87
a
082
1.4
a]
402 | 3834
| 4.00 244
no | 178
free Diseloom stone free --
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8
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138
|
124
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146
158
158 110
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..
328
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.
120 ane 302
Diamyl Amylphenozy Amylphenozy Ethanol DDiiaamymlyl Naphthalma Naphthalma vee | an Diamyl Phthalate . 0. we
Diamyl Phthalate
|.
DiantadineOnlode ss
Dibenzyl Ether
Dibulozymethane Dibulozymethane 2!
Dibutylamine
-
ee
Dibutylaminoethanol |
Dibutyl Ether
Oralate Dibutyl
Callyde Call .OGH
(
CallCOOC
:
CR es oe
te ae ee
245
mp
vee
216
and
340
| 340 | 15
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276
140
114
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136 200
| eee
T T
13 | 336
0-0 | 097-004
0969
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020 020
08
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824
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| 9.B|
860
Dibotyl Tartrate . . 2.
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.|
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195 | 220
1.00
9.03 | 660
Dishloendiarowethane -DichlorphenZADO -DichlorphenZADO
sees Phin
Dichlorobenzene
Dichlorobenzene
Dichlorabens Dichlorabens nue
Dishloendiarowethane
tie
Dichlorethylene 1.
=...
.|
|
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| 160 161
|
non
fi
105
103
03
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1.14 1 | 335
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07
3.07 4.31
354 258
co.
pa
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1.200
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Dichloroethylene Dichloroethylene 2 . Ether . Formul
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9.7
131
ff
i
189
230
| io]
::
12.0 12.0
1.282
| 2.38 | 141
413
862 B.D
424
| 8.20
Diaktoromopropyl Ether .
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Diablorpentas Diabloropentanes 1DiablorNopentianestro Promu
Mnerenane
: ob
en
183
181
vee 6.48
vee
255
| 201 || 206
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| 0.9440
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| | 0.710
2.83
134
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Diethylene Carbonata elber CICHOCHD OCCHOC^
ogg
Ethylene glycol diethyl elber OCCHOC^ 22222 |
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11D6 iDiooxanxe ao nw es |
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259
259
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|
140
180
144
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40
|| || 40
201
P
620
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|| || 1.40 314
2.65 | os
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|
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.|
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.
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4.17
4271
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40825
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section
.
EXPLOSIVE AND FLAMMABLE MATERIALS
Part
2
PROPERTIES OF FLAMMABLE MATERIALS
VOLUME I
Pago
11.2.5
__
Date
Cancels
10-29-62 None
NAME
GllyyccoerlinieTnrciemsetnteate |
soprene re srr]
PROPERTIES OF FLAMMABLE LIQUIDS GASES AND SOLIDS
FORMULA
Flash Point
Cloperi Open
140
167
188
wee
nee
Explosiva Limita
| Lower | Uppe |
1.1
ween
" anes
1.8
74
1.8
3t
az
3!
Speele | Density Being WALL Density 1.00 |
1.199
1.120
seas
2.31
337
22 340
tee
pew
aoe
Giyoral BEES Formate
HOCHI
RCDOCT.CCH.ICIOCCH HONCHOR
ase aoe wee
ito
4.8 0.0 20.7
9.0
135 13
73.7
68.0
FR^ N 309 a
FR^ N
a oe
SEEriiigs
COH CCHHIICCHciHrchCG HORCH
310 T
ia | wee
oo.
1.35
waae tree veer
cea
eee waa
dace
Jo
bas see wee
dn
i, it in
yoo | gor | 3g
| 176-199 0.847 3.45
ft 176-19
0.818 2.45 176-199
0.041
2.97
150
CH11 ee
CHOR .
CHICOOCH
CHICHI
'
.
:
CHOCHOCH HOCHOH CHAICH CHAICH
*
ae tit
ss terest : GRINCH
: wee
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1
Pr
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ae
170 |
pn
0.689 0.85.5
0.82
2.0 4.97 3.37
130 298 211
0.118 | 4.07 | 275
0.794
1.43 | 440
:
co
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48.4 1 | 3.01 | 45
1.227
10
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0
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93
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me
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12.9
peer
Methylamine Alenhel ss Methanal
Methylamine Amyl Ketana Methyl
Methyl Butadiene 3
Methyl
Rutyl Kelona
Butyrate
Methyl Carbital
Methyl Carbital Acetate
Methyl Cellsalva
Mathri Collanaire Asstate
Methyl Cyclebkerami |
Ce
4.0 ene
1.11
RBR
baie | asa | dak
RBR
1.78 8.27 a
aes
0.654
seas
11.3
0.0634 | ade 101.0
ves
0.003 | 1.43 | 316
| | 1.034
1.099
4.14
tree
STE
ww
0.005
ae
245
BASE ms
0.770 3.93
e]
20
104
SUBJECT TO DISCLOSURE RESTRICTION
40826
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
( Section EXPLOSIVE AND FLAMMABLE MATERIALS
Part
2
PROPERTIES OF FLAMMABLE MATERIALS
VOLUME I
Page
2.7
Date
Cancals
10-29-62 None
ms
e
aea
PROPERTIES OF FLAMMABLE LIQUIDS GASES AND Contnsed
NAME
Phenylethanolamine Phenylethanolamine Diamine oe
Phenyl Ethyl Alcohol 5)
BYNONYMS
FORMULA
Diaminobenzene
ot Bemyl
Bemyl PpNCiIlCicHiC.CHHOON 1. 8. Haptedien
Diaminobenzene 2...
00000!
Carblaal Carblaal lll
Dimethyl
0)
COCHC ...)
Flesh Point
Cloead Open
12
aa "/Pp
... fo 105
Explosive
Limits
% by Vel Air
Lamar Upper
| tt
bo
bin
7... f
|
AperiGravity do
Gravity Density 1.no
Boihna
Ai0 r-
|
Point
*
1.007
1.024
0.879
Bt7 8.73
~ ^i| 480
fo.
ane
Folyethylene
Glycol
200
FolyetFolyethhylen yPollyemneres lo
PolyeMtixhtyulreenoef PGolymlersycPoollym3e0rs0400
Mixture Polyethylene of Polymer
Polyethylene Glysol 600 Polyethylene
ey
Polyethylene
we Mixture Polymer
Folamiam
20
ee
Petium Xanthate > SS
COCHCCH.CH COCHCCH.CH CH
2014
Pilii.iiiiiiid!
F
CIF l! TID
and | 30
.
A NCHI
NOTCHKOH
ee
eee
85 -| NOTCHKOH ,..-.-2.2.
Expindes 5
ararintans
wleenenee
vey 178
172
285
in
er
370
430
120
| 144 | wf
258
8.
260
260
0923
1.87
3.01 1.377
4.77 419
omen
549 or | || &id
549
785 343
0.987
1.783
0.81
ee
0.34
| 7.00 | 7.00
287
tee
wee
PL
400 12
1.0 te 0.887 0.02-0.93
1.31
201
201
ves
348
ce ee ee beee s ee eaee Leena
390
'
rrr, [irr
ar
a
a
ary
nS [PaaS
535 488
478
1.17
1.11
1.17
1.13
t Pee wee te rw we
Ethylminthata
:
:
)
.
.|
GRINEUN .....
CHIC ! 2...
CHORCH.OH
175
ito
...
i
70 so
85
0 <P
vee
tore
wees
ry
I
| 21 | v8
|...
1.77
1.0
| | 1.78 2.18
7.3
18.1
| 2.6 | ....
PID
Pocaee
Plt
en
2.0
10.8
10.8
BD
2.0 go
10.7
| itl
po.
..
| |
120
68
*
210
fo.
| 14.3
nos
0.867 1.559
7 0.9019
1.oi^
1.oi^
| 0.860
0.877
0.804
| 0.789 0.680 0.887 0.864 0.690
Q.EBY
i
> i | 0.973
1.15
1.040
1396
| 2.89 | di8
1.50
| 4.49 | 1.52
3.87
-48
218 194
| 2.07 | 307
2.07
| TERZ 2.00 | | 4.14 | | 4.14 | | 2.71
181 TERZ
,> 311 114
2.71
| | 1.49 | 1.25
O85 -88 261
2.54
| | 3.5
240 2018
| 2.12 | 370
i
:| CHICHOCH
| -------- -- -- ------
CB
Fe]
UTM
[oan
0.900.0 900
|
2.03 3.03
| |
170 183
231 248 474
29 >ea0
1011
wee
1 of CHICHI
f
{ . Cid Diphenylbenzene
.
.
.
ae
a
| Ben
Con Chitmort
er)
ROCHLO
oe >>.
ll:
nae
Tetruethylenepentamine . . .
CATO.CHOE | Alesha
Tetrahydrofurfuryl ii ity 2
Tetrabydrampi af Tetralla cee ee ee 171 | Thieldine
ten
Thieldine 22 & NHCHCH :
2.
|
Tetralla
Dikydre
6.4 Dikydre
:
&
Trimet
Ditbissise
ee
NR^
, CH |... ilesival
Culius
.
828
|.
8D
200
5-4273
The Firestone Tire & Rubber Company
0.007
1.057
0.69.5
0.014
335
20
Lee
|... | oe
1.104
1.236 1.623
7.95 688
7.95 7a 6.72 269
0.535
1.120
v | Oa
0.098
0.873
0.873
[| 4.35 |
nee
da
1.08
6.61
d
SUBJECT TO DISCLOSURE RESTRICTION
40827 40827 40827 40827 40827
Section XI
Part
2
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
EXPLOSIVE AND FLAMMABLE MATERIALS
J
PROPERTIES OF FLAMMABLE MATERIALS
VOLUME
Page
I 11. 2.13
Date
Cancals
11-15-62 None
PRIOR RELEASE NO 37
PROPERTIES OF FLAMMABLE LIQUIDS GASES
AND SOLIDS
Flash Point of the liquid is the temperature at which it gives off vapor sufficient to form an ignitible mixture with the air near the surface of the liquid or within the vessel used By ignitible mixture is meant a mixture within the explosive range that is capable when ignited of the propagation of flame away
from the source of ignition By propagation of flame is here meant the spread
of flame from layer to layer independently of the source of ignition A gas or vapor mixed with air in proportions below the lower limit of flammability may burn at the source of ignition that is in the zone immediately surrounding the source of ignition without propagating spreading away from the source of ignition Some evaporation takes place below the above temperature when vapor does not go off freely enough to meet flash point classification requirements There are certain solids such as camphor and naphthalene that slowly evaporate or volatilize at ordinary room temperature and therefore have flash points which
still in the solid state
Ignition Temperature of a substance whether solid liquid or gaseous is
the minimum temperature required to initiate or cause sustained combustion independently of the heating or heated element Ignition temperature of a solid is influenced by its physical condition environment and the rate of heating
By ignition temperature of a vapoorr gas is here meant the lowest
temperature minimum ignition temperature to which any part of a flammable gas or vapor mixture must be raised by application of heat to cause combustion that will propagate itself The lowest of minimum temperature to cause ignition is also known as the auto or autogenous ignition temperature In most cases of ignition under practical conditions external heat is applied locally It is to be noted in this connection that if the external source of heat is a spark its heat capacity its mass multiplied by its specific heat must be sufficient to raise an appreciable amount of the substance to the ignition temperature to cause ignition and hence momentary contact of a minute spark if inert combustible even though at a high temperature may fail to cause ignition
By ignition temperature of a solid is here meant the lowest temperature
the minimum temperature to which any part of it must be raised by application
of heat to cause sustained combustion
5-4273
The Firestone Tire & Rubber Campatry
SUBJECT TO DISCLOSURE RESTRICTION
40828
ADMINISTRATION MANUAL
HEALTH SAFETY ENGINEERING & PROPERTY PROTECTION
Section XI EXPLOSIVE AND FLAMMABLE MATERIALS
Part
2. PROPERTIES OF FLAMMABLE MATERIALS
VOLUME
Page
Date
Cancels
I 11. 15 11-15-62 None
1
Flash Point
A. For hydrocarbon mixtures such as gasolines safety solvents
naphthas etc. Flash Point F 0 73 x initial boiling point F 122
Examples Sovasol 4 has an initial boiling point of 242 F. P. 73 x 242 -122 = 54 Actual test shows 48
Sovasol 6 has an initial boiling point of 368
P. = 0.73 x 368 -122 146 Actual test shows 142
B. For a chemical compound of known composition Flash Point = temperature at which the vapor pressure is equal to atmospheric pressure divided by 8 times the mols of oxygen needed for complete combustion
Example
Ethyl acetate is CH3COO CH3CH3
CH3COOCH2CH3 + 502 = 4CO2 + 4H O
=
760
19
8x5
From the vapor pressure curve on page 94
flash point temperature then is about 23
the
, , Lower Explosive Limit For a chemical compound of known composition Lower explosive limit = 10.8 divided by the mols of oxygen needed for complete combustion
Example Again taking ethyl acetate
10.8 = 2.16 5
The observed figure is 2.18
3. Vapor Density and Molecular Weight For a chemical compound of known composition vapor density air = 1 = Molecular weight x 0.0345 Conversely Molecular weight = vapor density divided by 0. 0345
LATTLM
The Firestone Tire & Rubber Company
SUBJECT TO DISCLOSURE RESTRICTION
40829
Standard
Standard
Standard
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SUBJECT TO DISCLOSURE RESTRICTION
40830
ADMINISTRATION MANUAL
HEALTH, SAFETY ENGINEERING & PROPERTY PROTECTION
C Section XIIZ SAFETY, MEDICAL AND PROFSRTY PROTECTION FORMS
Part 1. SAFETY INSPECTION PROGRAM FORMS
YOLUME
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13.1.1
3-8-63
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Section XIII SAFETY, MEDICAL AND PROPERTY PROTECTION FORMS
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I
13.1.2
Part 1, SAFETY INSPECTION PROGRAM FORMS
Dete Cancels
3-8-63
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7
ADMINISTRATION MANUAL
HEALTH, SAFETY ENGINEERING & PROPERTY PROTECTION
Section XIIT SAFETY, MEDICAL AND PROPERTY PROTECTION FORMS
Part 1, SAFETY INSPECTION PROGRAM FORMS
VOLUMEI
Page
13.1.3
Date Cancels
3-8-63
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ADMINISTRATION MANUAL
Section XIII SAFETY, MEDICAL AND PROPERTY PROTECTION FORMS
VOLUME
Page
I
13.1.4
Part 1. SAFETY INSPECTION FROGRAM FORMS
Date Cancals
3-8-63
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VOLUME Page
I
13.1.5
Date
3-8-63
Part 1. SAFETY INSPECTION PROGRAM FORMS
Cancels
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VOLUME I
Section XIII SAFETY, MEDICAL AND PROPERTY PROTECTION FORMS
Page
13 01.6
Date
3-8-63
Part 1. SAFETY INSPECTION PROGRAM FORMS
Cancels
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ADMINISTRATION MANUAL
HEALTH, SAFETY ENGINEERING & PROPERTY PROTECTION
Section XIII SAFETY, MEDICAL AND T. PROTECTION FORMS Part 1. SAFETY INSPECTION PROGRAM FORMS
VOLUME
Page
Date Cancels
1
13.1.7
3-8-63
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HEALTH, SAFETY ENGINEERING & PROPERTY PROTECTION
Section XIII SAFETY, MEDICAL AND PROPERTY PROTECTION FORMS
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VOLUME Page
Date DOOR
I
13.1.8
3-8-63
Section
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HEALTH, SAFETY ENGINEERING & PROPERTY PROTECTION
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13.1.9
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VOLUME
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Date Cancels
I
13.1.10
3-8-63
Part
ELECTRIC CABLE AND MANHOLE INSPECTION REPORT (FORM 4356-10)
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Section XIII SAFETY, MEDICAL AND PROPERTY PROTECTION FORMS
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13.1,12
3-8-63
Part 1. SAFETY INSPECTION PROGRAM FORMS
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ADMINISTRATION MANUAL
HEALTH, SAFETY ENGINEERING & PROPERTY PROTECTION
VOLUME I
Section XIII SAFETY, MEDICAL AND PROPERTY PROTECTION FORMS
Page
Date
13,1.13
3-85-63
Part 1. SAFETY INSPECTION PROGRAM FORMS
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3-8-63
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HEALTH, SAFETY ENGINEERING & PROPERTY PROTECTION
Section XIII SAFETY, MEDICAL AND PROPERTY PROTECTION FORNS
Part 1. SAFETY INSPECTION PROGRAM FORMS
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HEALTH, SAFETY ENGINEERING & PROPERTY PROTECTION
VOLUME I
Section XIII SAFETY, MEDICAL AND PROPERTY PROTECTION FORMS
Page
13.1.16
Date
3-8-63
Part 1. SAFETY INSPECTION PROGRAM FORMS
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Section XIII SAFETY, MEDICAL AND PROPERTY PROTECTION FORMS
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Pert 1, SAFETY INSPECTION PROGRAM FORMS
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13.1.18
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Part 1. SAFETY INSPECTION PROGRAM FORMG
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ADMINISTRATION MANUAL
HEALTH, SAFETY ENGINEERING & PROPERTY PROTECTION
VOLUME I
Section XIII SAFETY, MEDICAL AND J PROTECTION FORMS
Page
13.11.21
Part 1.
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SAFETY INSPECTION PROGRAM FORMS
Date Cancels
3-85-63
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13.1.22
Pert 1, SAFETY INSPECTION PROGRAM FORMS
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3- 8-63
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PROPANE BULK STORAGE SAFETY INSPECTION (FORM S-4356-22)
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13.1.24
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HEALTH, SAFETY ENGINEERING & PROPERTY PROTECTION
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VOLUME
Page
I
13.1.25
Date
3-8-63
Part 1. SAFETY INSPECTION PROGRAM FORMS
Cancals
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Section XIII SAFETY, MEDICAL AND PROPERTY PROTECTION FORMS
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3- 8-63
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13.41.37
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