Document 8VE2o3d1BZ34rK9gq5z6D9V2e

AR R26 _ 060 ACUTE TOXICITY TO AQUATIC INVERTEBRATES (ACARTIA TONSA) IEsTsuesyANCE Identity: A mixture containing perfiuorooctanesulfonate, which may also be OrecftearnreesdutlofoansicPFacOiSd,) (FCCA-9S5,# o2r79a5s-3a9-c3o)m.ponent of FC-603EF. (1- RFeC-m6a0r3kEsF:. CuTrhreen3tMinpfroordmuacttiioonnilnodtincautmebseirtisisanomtixntoutreed.ofT1h.e30te%stPFsaOmSp,le10is% dpireotphaynleesnuelgtloynceolfobuatmyelr,et5he%r,A5lk4y.l1e5th%erwastuelrf,ate2,2.05.%1%etNh-y(l3e-ne glycol, 2.6% tCrhileotrhoaanlollaymhihneex,aaminndi0um.0c5hl%ortioldye!,t0ri.a9zo%leX.anthan gum, : 0.9% starch, 1.0% cThhaerafcotlleorwiiznegd scounmcmeantrryataipopnlsieosfaimmpiuxrtiutrieesw.itDhatiancmoampylnetoetlayccurately reflect toxicity of the fluorochemical component of the test sample. METHOD: lMeetthahlotdo:xicity tIoSOm/aDrIiSne1c4o66p9e-p1o9d9s7:(CWoapteeprodqaua,liCtryu~stDaecteea)r.mination of acute Type: Acute static GLP: No Year completed: 2000 SSuppepcliieesr:: ATceasrttioartgoannsiasms cultivated from eggs, supplied by the Marine ABinoalloygtiiccaallLamboonriattoorriyn,gU:niDveirsssiotlyveodf oCxoypgeennhaagnedn,pHDenmark. TEexsptosourrgeanpiesrmioadg:e:48-Lhaorugrescopepodites and adults. SStwaetdisitsihcaElnmviertohnomde:ntaLlCPsrovtaelcuteisoncaBlocaurldat(eVdebrsyiPonRO2.B3I,T19A9n0a)l.ysiCsa,lcNualtaitoinoanlof NOEC is by single factor ANOVA followed by Bonferronis procedure. Test coDnidliuttiioonnsw:ater: Filtered natural seawater (34 ppt salinity) from an uDniploultliuontewdastietericnhBeymfijsotrdr,y:NorNwoatyg.iven. mLiagihnttianign:edAthdraoiluyghpohuottotpheertieosdtionfg1p6erhiooudr.s light and 8 hours dark was oo wStaoscpkraepnadretdesbtysodilluuttiiongn 1p.r0e0p0a2ragtioofnt:estAs1u0b0s0tamngc/eLinpr1iLmaorfywastteorck. sAolliutqiuoonts were then added directly to water in test vessels to create test solutions. Exposure vessels: 28 mL rolled rim vials containing 25 mLoftest solution 002373 Number of replicates: 4 Number of organisms per replicate: 5 Number of concentrations: seven plus a blank control Water pchHemriasntgrey(d0u4r8inhgoutrhse):study: 8.28.2 (control exposure) 8.1 --8.2 (1000 mg/L exposure) Temperature range: 20 1 C Dissolved oxygen range (0-48 hours): 7.37.4 mglL (control exposure) 6.47.6 mg/L (1000 mg/L exposure) R0 ESOL0 TS 00000000000 Nominal concentrations: Blank control, 32, 56,100, 180, 320, 560, and 1000 mg/L. Reference substance (3,5-dichlorophenol) at 1.0 mg/L. Element values: 24-hour LCs = 610 (490 - 790) mg/L 48-hour LC = 280 (220 -- 360) mg/L. 48-hour NOEC = 180 mg/L. Element values based on nominal concentrations Remarks: Testing was conducted on the mixture as described in the Test Substance Remarks field. The values reported apply to that mixture and not the fluorochemical proportion alone. CONClusions 0000000 "The test sample 48-hour LCsy was determined to be 280 mg/L with a 95% confidence interval of 220 to 360 mg/L. The 48-hour No Observed Effect Concentration (NOEC) was 180 mg/L. Validity criteria fulfiled and reference substance was in normal range. `Submitter: 3M Company, Environmental Laboratory, P.O. Box 33331, St. Paul, Minnesota, 55133 patAQUALTY Reliability: Kiimisch ranking = 2. This study meets the criteria for quality tleasctkinsg.anaHlyotwiecvalerc,onsfiarmmpalteipounroiftytwheasamnooutnptroofpefrlluyorcohcahreamcitcearlizperdopaonrdtitohneisn ttuhedy _ solution. R0 EFER0 ENCE0 S 00000000 00237: Test was conducted by RF Rogaland Research, of Stavanger, Norway at the request of 3M Norge, Lab reference number 99312-4, 2000. o0 mMER 0000000 Last changed: 6/26/00 002375 "lr a "FC-603 EF Light Water TM ATC TM 3%" Toxicity tests . Report RF-2000/004 [ee me The following test results were obtained with "FC-603 EF Light Water TMATCTM 3%": I oer-- r , ere E o i . Acartia tonsa 48hLC, (mgh): 280 "Nopar of thisdocumentmaybereproducedinanyformwithoutpermission inwringbyRF - RogalandResearch. = uCg Ar ym blruoebsso 00237 | ooaiia - CONTENTS: 2. TEST FORTOXICITY WITH SKELETONEMACOSTATUM .cvvvvvvsesssmssssssiassssssssssssssssssssssssssssssssss & 3. TEST FOR TOXI WIC THI ACATRTY IA TONSA cccvvevvesssssssssssnsfissssssssssssssssassssssssssssssssssssssssssssssass 10 4. TEST FOR TOXICITYWITHCOROPHIUM VOLUTATOR..cvvvvrrssssrssssssssssssssssssssssssssssssssssssssssss 15 002377 9L9a3br1e2f4ro. Page3of 31 PREFACE: Ecotoxicological tests were performed on "FC-603EFLight WateTMr ATCTM 3% in agreement with Novatech. The sample is a concentrate that normally will be used in a 3% AFFF/3A%R Solution. Tests were conducted in accordance with the "Harmonised Offshore Chemical Notification Format" (OSPARCOM 1995 /SFT 1998). The project was carried out at RF - Rogaland Research for 3MNorge. All the tests were `performed by RF - Miljglab. Study director was Senior Engineer Inger Lisa Andersen. The test results are presented in separate sections. The results relate 10 theproduct as supplied by Novatech. This test report is issued by a laboratory accreditbeyd Norwegian Accreditation (NA). The accreditation states that the laboratory meets the NA requirements concerning competence, equipment and working proceduresfor all the test methods contained in the accreditation. Iitnatelrsnoasltqautaelsitthyactotnhterollabsocrhaetmoersy,hpaasrtaicsiaptaitsifoacntionryinqtuearlliatyboarsastuorryanccoempsaysrtiesmo,nsw,hiacnhditnhceluusdeesof certified reference materials and secondary reference materials. The tests performed are covered by the accreditation. This test report may not be reproduced in anyform other than infull, without the permission in writing by RF - Miljplab. 002378 L5a9b3r1e2f4no. Page dof31 TEST FOR TOXICITY Marine alga: Skeletonema costatum 002379 L9a9v3r1a24 rageast TEST REPORT GROWTH INHIBITIONTEST WITHTHE MARINE ALGA Skeletonema costatum QA =. TRE Te RESEARCH TEST SUBSTANCE: "FC-603 EF Light WateTMr ATC TM 3%" TEST RESULT: `The 72 hours ECso was calculated to ~170 mg/l. "The test substance was supplied by Novatech, and the test results relate to this product. TEST DETAILS: em METHOD: NS-EN ISO 10253, 1998: Water quality - Marine algal growth inhibition test with Skeletonema costatum and Phaeodactylum tricornutum. `TEST ORGANISM: Skeletonema costatum, strain NIVA BAC 1. A stock cultureofthe test organism is kept at RF - Rogaland Research. PREPARATIONS: Natural seawater (salinity: 34 %o) from an unpolluted site in Byfjord was used as basis for the growth medium. The water was filtered through a GF/C filter, anuntdribernitesflaychceoatredditntoogabIoSuOt 170525C3,prainodr troeucsoem.meTnhdeatsieoawnastferrowmatsheenPraircihsed .w.i.th Commission. : . "Test solutions were prepared from a stock solution. A stock solution of 1020 ``mmge/dliwuma,s pOrtehpearrecdonbcyensttriarrtiinogns1.w0e2r0egprraempsaorfedthferopmrotdhuisctstionc1k lsiotlruetoifong.rowth INCUBATION: "Test culturesof 50 ml were incubated in 100 ml flat-bottomed flasks on an Jorabtietdaltosahabkoeurt,2300re0plcieclaltse/smifofrreoamchancoenxcpeonnternattiiaolnl.y gTersotwicnulgtuirneoscwuelruem cinuolctuu-re "The test was run under continuous light (> 50 jE/m sek) from fluorescent--- tubes of universal natural white type, at a temperature of 20 2C. . `The test was run for about 72 hours, and subsamplesof 5 ml were taken from the test flasks each day for growth measurements. Algal growth was measured `by fluorescence. pH measurements were performed as indicated on data sheet. "002880 ) La59b3r1e2f4 Page6of31 DATA ANALYSIS: CALCULATIONS: Gverroswutshtirmaet,esawsedreesccrailbceudlaitneNd Sby-EloNglIiSnOea1r0r25e3g.ression on biomass (fluorescence) ECs: Tcohneceinnthriabtitioornoyfeffaepcrtoodnuctthegigvrionwgth50of%Srkeedluecttoinonemoafcgorsotwatthumraitsee(xEp,Crseos)s.edThaissthe effect concentration 320mg. was calculated by interpolation between 100mg/ and NOEC: fCaacltcourlaAtNioOnoVfANfOoEllCow(eNdobyObBsoenrfveerdroEnfifsecptroCcoendcuernetrfaotricoon)mpiasrdionngeebaychsingleconcentration mean with the control mean. TESTRESULTS: COMMENTS: VALIDATION: Table 1. EC and NOEC values obtained with Skeletonema costatum. Test substance ECi W"FaCt-e6r0TM3 EAFTLGiTMght304" - EC ECo 1m 100<EC,0<320 NOEC: 100 VaGVlarluauepeshPaiarndediicncaseltceaou3nl0c.tbeenydtirneaptotigaiovtiinnogsn.1N0%OE5C0%aaredca9l0c%ulnaitbebiydiowinnogftgnrocwompruattee.r pUrognrianimmmseg Tduhreinrgeswulhtiscahrethbeasgerdowotnhgirsocwotnhsirdaetreesfdotrotbheeteixmpeonesnptainal0-in7t2heb,cotnhterpoelrciuoldtures (see growth curves). cTehlel dveanlsidiittyyicnrcirteeraisaedgibvyenaifnactthoertoefstmporroetotchoalna1re6fiunlftihleletde,stinpetrhiatodthe control v(acroyrrbeyspmoonrdeintghtaona1,g0rounwitths rdautreionfg mtoheretetsthaannd0,t9hde)7,2 hthoeurcsonttersotlrepsHultdsidwintoht 3,5-dichlorophenol was in the range normally found. Lab. ref. no.: TSeasmtppleeriroedc:eived.: Report date: 993124 07-2100..0192..9999 10.01.2000 El Bonn EEnligninHoerevre Analytical technician Fel SeniAorgeReseMaorlcvherSscmiyerntist Quality Assurance . Enclosed: Data sheets Tfhorimseottherepthratn ien flnl, widhoutatbherpierrmiwsione in wroyieNnogrbwyedgRiFon MIsLSaIiS.onOR).Th oprmymo bereednny 002381 L9a9b3r1e2fn4o.: rage 70151 PRIMARY DATA: Growth inhibition test with Skeletonema costatum Test substance: FC-603 EF Light Water TM ATC TM 3% StLaarbt.dartele:: 9079.31122949 MeasCuornce.meunntt:: mThge biomass was measured by fluorescence; values in fluorescence units 07.1295] 06.1299] 09.1293 10.1299 |Grroawtteh|] Corre atptHan Concentration | 1450 | 0930| 1025| 11:55| |day-1] tation |oftest 0 0 02 | 02 | os | 4 01 | oss | 17 | 97 112529|| 01.909080 0 0 01 | 033 | 11 6 00s | 03 | 11 | ea 114428|| 00.999s8| 82| 82 0 009 | 02 | 088 | 146| 0995 0 009 | 026 | 0s | 7 151 | 0904 3322 00009s || 004238 || 11725|| 613 116478|| 019.09080 32 008| 023 | 1 47 1.42| 1.000 1100 000089 10 ot 118619|| 00999959 166| 1.000 322 0011 || 00238 2 011| 03 9932 115577|| 00999%8 88 152| 0999 110000 001019 || 00331s || 00777|| ssi4 0039816 100 01 | os| ors | sa 0987 320 007 | 004 | 003 | cos 000 320 009. 003 | 001 | 004 000 82 - 320 006 | 00s | 002 | 006 000 1000 009 | 007 | os | 00s 000 11000000 0001s|| 00003s || 000033 || 0o0cse 000000 Refer1e5ncmegsnubs|tance00(935-dichiorophenol): ois | 02 11.55 mgmg | 000088 001128 || 00222 Mean val0ues: 00 | 03 7 3210 000099 || 0034 37 1020 001100|| 0033 95 1302000 000079 || oo 00 0 0 [Referencesubst|008 |013 | 02 | 02| 028| 0908 003352|| 0o9s6t8 45| 05% ied 115722|| 00999%9 115368|| 00.999898 | ames 000 000 soa nrioen 2% normaly fund wen 002382 Lapbrietiaro. ragesossi GROWTH CURVES: Growth inhibition test with Skeletonema costatum Test substance: FC-60E3FLight WaterTH ATCTH3% Lab. ot; 990124 i" Control Ii i2.6Ss = 3 snionton i, 32mon 3 {5------ La on 2 sino riliA 10mg is rilji 32mgt 3 + sorte 3 enimpom hi | 100 mg I.s i i1 i. "= 3 ron # 320 mon i |s || i1 i. we = ala drainposse ? 1000 mg bi Lew = ) 002383 4 La9b9.3r12e4f. Page9of3l wIinthhi:bition of the growth of Skeletonema costatum mg/l ( FC-603 EF Light Water TM ATC TH 3%) Experimental data: CFCo-n6c0e3ntrEaFtiLoinghtinWater TM ATC TH 3% Growth rate CCoonnttrrooll 12 CCoonnttrrooll 31 Ccoonnttrrooll 5& Control mean : 33..2200 3120 1100..0000 10.00 33221.0000 32.00 101000..0000 100.00 332200..0000 320.00 11000000.20000 1000.00 11.12529 - 11882 - 11s6 1.5 11.4687 12 11.l8619 16s 11.5577 152 11.3432 13% 0.0.0000 0.00 00..0000 0.00 iInnhpiebricteinotn ---- 0o.o0 18 0l.o0 - ol 0o.o0 oo 18.18 3s 110000..00 100.0 110000.00 1000 002384 L9a9b3r1e2i4no.: Page 100f31 3 - @ 3 El TEST FOR TOXICITY &z Marine herbivore: Acartia tonsa od Loy & -- 002385 p 9Le9b3.1r2e4no Page 11of31 TEST REPORT J AcumeToxicrry Test wt THE MARINE COPEPOD Acartia tonsa TEST SUBSTANCE: "FC-603 EF Light Water TM ATC TM 3% TEST RESULT: ; i The 48 hours LCso was calculated to 280 mg/l. `The test substance was. `supplied by Novatech, and the test results relate to this product. | TESTDETAILS: METHOD: ItoSOm/aDriInSe1c4o6p6e59p-od1s99(7C:opWeaptoedra,quCarluisttya-ceDae)t.ermination of acute lethal toxicity TEST ORGANISM: Acartia tonsa (Dana), supplied University of Copenhagen, by the Marine BiologicaLlaboratory, . CULTIVATION: Thetest organisms were supplied as eggs, and were cultivated in `accordance a`wnidthatdhuelt"sPawreirseCuosmemdiinssthieo-tnestR.ing Test Protocol" (VKI). Largecopepodites: prior to use. PREPARATIONS: Natural seawater (salinity: 34 %o) froman unpolluted siteinByfjord was used as basisfor the dilution water. The water was filtered through a GF/C filter i INCUBATION: oR i `Test `mg/l solutionswereprepared was prepared by stirring from a stock solution. A stock solution of 1000 1.0002 gramsofthe product in 1 litre ofdilution water. Other concentrations were prepared from this stock solution. 2T5hemlteosft tweasst rsuolnuitniognlaasnscdo5ntaaniinmerasl(s42,8rempllircoaltleesfdorriemavcahlsc)onccaecnhtrcaotnitoani.ning `vials were kept under a 16h/8h light/dark photoperiod at a temperature Tre of "~~~ 201C. data sheet. pH and oxygen measurements were performed as indicatoend the 002386 9La9b31r2e4f. Page 12031 i "8 DATA ANALYSIS: CALCULATIONS: 2Thperoedfufcetctloetnhatlhetosu5r0vi%vaolfotfheActaesrttiaanitmoanlssa(isLCeox)p.resTsheed caosmtbheinceondcmeonrttraaltiitoyn of LpeCritevstalcuoensceanntdratthieo9n 5we%rceounsfeiddefnocreclailmciutlawteirone.caTlhceul2a4tehdobuyrsusainndg4t8hehours PsrtoatnedcatridopnrBoocaerddur(eVPerRsOioBnIT2.3A,na1l9y9s0i)s., TNhaitisopnarlogSrwaemdmieshalEsnovciarlocnumleantetatlest concentrations lethal to 10% and 90%of the test animals. TETISSATS. kt, 161 tt i von NOEC: fCaacltcourlaAtNioOn VofANfOoEllCow(eNdobOybBsoenrfveerrdoEnfifsecptroCcoendcuernetrfaotricoonm)piasrdingobeyacsnhingeleconcentration mean with the control mean. ~ i -- AT cAcoarroiaiotornssas od2h6 ohoT wurTss TRTon Wars4T8hAbooTwEssTaw LC 280 (130-380) 8 (54-120) ; Loo 610 (490-790) 280 20-360) i 1= c o>10m 00 s8o80E(062-0-i15s00m) cVNaOlouEeCsil:ndeibcyeuPsRl1O0B%aIT3ta0na%elaynsdids5,a0n%de9h5%aclcyoafenr32f240aininider4dv3alseeaurresn.dUicctneediin.mN eg Vea1tO r8oe0essateeC dby hecompute programeGraphod InSio 30. VALIDATION: oTxhyegveanliCdointcyecnrtirteartiiaogniavtetnheinetnhdeoftetsht eprotetsotcwolasagrreefautlefriltlheda,ninortheaqtutahlteodi4smsoglv,ed 1 LthCespeorfce3n,t5a-gdeicmholrotraolpihteynionlt(hreefceornetnrcoel)s wwaass ilnestshtehraanng1e0%n,oramnadlltyhefo4u8ndh.ours Lab. ref. no.: r A l8 TSeasmtppleeriroedc:eived. | Report date: 993124 10-2102..0191..9999 07.01.2000 QL Vor EElnigniHnoerevre Analytical technician Te [ SenioArgReesMeoalrvcehrsSmcyirenti_s_t Quality Assurance + 8 Enclosed: Data sheets & 4h boJJ Tfiosmeotthretphoann inafslla,dwbityhoaubtothreapteramrissyscioneinrebiyinNgoerbwdyegRiEa-n MAicpcteadbi.aion (VA).Thereportmay rb mprodoccndny 002387 i L9a9b3r1e2p4ro: Page 1331 PRIMARY DATA: Acute toxicity test with Acartia tonsa Testsubstance: "FC-603 EFLight Water TM ATCTM 3%" LaStba.rtrdeatt:e: o10s.1112.499 Measurement: Numobfdeeard [ Tow | Nspuemcbimeeornf| NUMOBF DEEARD number |pr.vessel 24hours 4Bhours l { || concoentnration | Sprp.eccoinmce.n ABCDFE | Toa A[BCDEF | Tom { 000 000 001 l 000 i{ 00 00 00 00 ( 000 0 I 0000 {1 01 11 6 54 5 l I IISISFH FEI EE Reference substance S5dctorophenc; : 3.31 T a The result wth the1 refe=rence su1bstance is within the range normal foun-d. -i : _ = ib 002388 7 Lab.ref.: 99312-4 CCe a e e o er=eos omoT[T m nneaaTT a e e e e Ta TT TT e aae] aa] ]]]: Con(cemngtr)ation [o wen mT e] (Omxygg)en PH - Oxygen (mg) PH - Oxygen (mg) PH - i el 002389 5La9b3r1e2f4in.: Page 15of31 i ~ : TEST FOR TOXICITY Marine Amphipode: Corophium volutator i} -- 5 002390 ! Labrefno 5 Fi Page 16of 31 ase l09/ % TEST REPORT ACUTE TOXICITY SEDIMENT TEST WITH THE MARINE AMPHIPOD Corophium volutator i TESTSUBSTANCE: "FC-603 EF Light Water TM ATC TM go, TEST RESULT: - The 10d LCso was calculated to >3060 mg kg dry weight sediment. `The test substance was supplied by Novatech, and the test results relate to this product. TEST DETAILS: METHOD: ASTM E1367-90, Standard Guide For Conducting 10 day Static Sediment Toxicity Tests with Marine and Estuarine Sediments, . TEST ORGANISM: Corophium volutator, from an unpolluted site near Trondheim, CULTIVATION: The test organisms were supplied a adults (4-8 mm in size) and were held in aerated seawater at 15C. feeding. A small amount ofnatural seaweed was used for PREPARATION: . NSaatstauvruaasnlegedsrefawowraapstreuerspae(srdailfniognrittdeyis:ltu3st4eido%inm)weanfttersro..m TaShneeduinsmpeeodnliltmuectnoetldliessctateemdiunadtBydafnyjuosnrapdnoedlnlauonutdteswdiasdisete. analysed Each test for organic content and proportion silt concentration was prepared by adding for the each test. product in 600 grams of b4du0ac0mkmpeltsweodafsismcseahnwataiktneenrawfpaolsa3rsatdihcdouebrudsct.koeTteh.a1ec5hs,e0daminlmdeotnfhteswbaeesaakdweiravsitdwweeeadrrseinaatdeotdrheardteeadenbodetvaehkreers, ntihgehdt.am1p0 saendiimmaelnstwwearse tahneanlyrsaendfdoomrlwyatseerleccotnetdefnotr, eaancdhablleackoenrc.enAtrsaatmiopnlseaoref calculated as mg kg"! sediment dry weight. INCUBATION: H s`Tehdeimteesnttw,aasppr.u4n0i0n gmllasosf csoenatwaaitneerrasn(d60100maln)imeaalcsh,c3onrteapliinciantges20fo0rgsoafcthest ctinoednmicpceeanrttaertdautroienonot.fheT1d5hae+tab1esahCke.eetr.PsHwearned koexpytguenndmeeracsounrteimneuonutssaweerraetpioenrfatoramedas 002391 iof t53b12r4 : Pagew1el7roefl31 z DATA ANALYSIS: ; CALCULATIONS: mTtroharettiaeolfnioftefyctpaeoprnrtotedhsuetccstounrlcveeithvnaatllratotofi5oCno0r%woeporlfheituuhrsesetdevsoftlouartncaiatmloacrullsias(eLxCpxrce)s.seTdheasctohmebcionnecden. { VPaRlOuBeIanTdAtnhaely9s5is%, cNoantfiiondaelncSewleidmiitsharEencvailrcounlmaetendtablytPuirosonit.negcTtthihoeens1Bt0oaanddraadyrdL(VCesrsion 23. 90% 1990). of the tTehstisanpirmoalgsr.amme also calculate test concentrations lethal to 10% and NOEC: fCaacltcourlaAtNioOnVofANfOoEllCow(eNdobyObBsoenrfveerrdoEnfifsecptroCcoendcuernetrfaotricoon)mpiasrdionngeebaychsingleconcentration mean with the control mean. TESTRESULTS: Table 1. LC and NOEC values obtained with "FC-603 EF Light WateTMr ATC TM 56+ CCooprohpihsiummvvooltutaateorr o100oays ---------- LCs 99 ( -760) Leo >3060 L= os w306e0 i NoEc: 3060 VacVlaulaueelsairnledcibecyaattdhe1cl0o%mcp3bu0tyue%PaRlpnOrBdoaIg9Tr0ta%memeheldGlsryanaaleysfanedp5r51h%0dcteoanyedf.idUennciee nemm1ssedihmeemntedsyWmeoirne VALIDATION: OTxhyegveanlicdointcyecnrtirtaetriiaongaitvtehneinetnhdeotfestt hprtoetsotcwoalsagrreefautlefirltlheda,nionrethqautatlhetdoi6s0so%l,ved the percentage mortality in the controls were less than 15%. The percentage. fmsooerrdtioamrlgeiantntyiiwcnaacsonr1te6ef.ne7tr%eb.nucteTthshueebsssietldatnifcmreeaocnftt2iuo0ns.ei9sdrmiesfgcooFumlnmudoetrnoadnebtdehewhniiegthhkeigrn".!adcWrceyepwhteeaidvgehlitmits osebdsiemrevnetd)absuitgtnihfeimcoanrttamloirttyaliinttyheinhoignheecsotnccoenncternattriaotnio(n10w6a0smngotksgigndirfyicwaenti.ght T--a_b--l2e. CharT aocftthe eseedrimeintussi etdfoirftcestss ing Organic content (%) Sit fraction (%) i E 07 E 0s Lab. ref. no.: TSeasmtppleeriroedc:eived. Report date: 993124 02-01.00.91.29999 07.01.2000 E i Enclosed:Data sheets oi EEnlgininHeorevre Analytical technician Felblosgsy SeniAorgeReMsoelavrcehrsSmciyerntist t `Quality Assurance 002392! 5La9b3r1ef2i4no.: Page 18.0731 PRIMARY DATA: Acute toxicity test with Corophium volutator Testsubstance: ~~ "FC-603 EF Light Water TM ATC TM3%" SLtaabr.tdraot:e: 917%.1122949 i Measurement: Numobfdeeard ii ! nTuomtbaelr|| pNrsu.pmevcbeisemsreeonlf NUMBER OF DEAD Says 10days l (Cmoncoednrtyfrwaetkiigohngt)||Sppre.ccoinmce.n|| AB DF Teal | [8 ADcFE| Tom 0 10 1100 1100 000000 [ 457 I 1080 lL 10 10 10 10 10 | 10 10 10 T i TT 1 zg xi Referencesubstance(fuoranthene): 2 0 10 10 il _ l 002393 { Stabere. Page 190f31 Testsubstance: "FCa03EFLight Water TH ATCTHI" 5J LaSba.nrcets.:e 978.3112249 MeasurofeoxmygeenanndtpsH. Corcontaton [Oogen |omm [w (mg/kg dry weight) (%) oH | mg ph . (%) - o[w 0 v a] [[=C==o[[ [o eeoeTTo e eoou a o o eo e e e] ] ] ] TT TT eeTT Beteroncesubstance (tuoranthens): _ ; i 002394 | LSaib rsefi, Page 200f31 i ~ DATA SHEETS i . : 002395 | La5b9r3e1fi2n4o. Page 21 of31 ENS-DATASLAD (Helse-, Miljo- og Sikkerhetsdatablad) S=ooksucneesnctears. : 072-37/20947/-907 USskgriecvses ue +: 0131//1111//9988 VSiedzesjon lav: 03.010 TsemlSe-fcoant:abl63ade8s4 7e5r u00tar/bTeeildeef:axa:v H63ilj84eav1d7el88ingen ved IN Norge A/S. : I IDEVTIFIXASION AV KISHIXALIST 0G ANSVARLIG FIRWK: : tagoster: 3 Norse A/S i Eandelsnavn: C-60327 LIGHT WATER (TM) ATC 31 AR-AFEF i Dektarasjorsnunmes, Produksregisteret: | Telefo2n2,59G. if1c3 in00fornasjonssentralen: { 2 0PPLYSNINGER OM KIZMISK SAMMENSETNING. : Inforaasjon on enkeltkomponenter, faresymbol(er) og risikosetninger storauav cas-nr VEXT-2ROSENT 1v,a2m-2ANDIOL 7710372--2118051 52-"5262s 2-(2-3F0aTr0eKsSyYmZbToOlKeScY/)ri-sZiTkAoNsOeLtni/nges: Xn; Ri22 112-345 -10 (DIZFTaYrLeEsNyGnLbYoKlOeLrM/OrNiOsBiUTkYoLsEeTtEnRi)nger: Xi; Rid6 :i FSYLNUTOERTAILSKKYLOOVVEERRFFLLAATTEEAAKKTTIIVVTESTSOTFOFFFER TTrraaddee SSeeccrreett a1i-s5 i TFRLIUEOTRAKNIOELNAINSIKNAKRYLAT Tr1ad0e2-Se7c1r5et 1--31 { TRrEuSETRERE AV ORGANISKE FLUORKJEMIKALIER rade secre: Trade Secret 1-3 Tkke kjeat 002396 p9r93134 rege 20s FC-6032F LIGHT WATER (TW) ATC 3% AR-AFTE BEST COPY AVAILABLE 1] 3 vixerosts razewonzazea. - Viksigase skadevickninges i EelsefKaarne:vase faslig ved svelging. Kan irritere oynene. !| Sikker2hocs |i HidjatSepsees:ialavtall. 4 FORSTEEJILPSTILTAX. | TileakSKYoLyLne:straks umiddelnare, oynens med rikelige mengde: vamn. Kontekt lege Tiicak nud: | ttSoikylyslloflostrtrdtaoeykt.sbrEhuvukidseesnsmylemapdgtenosmiopeegr KoopgapsstrtidSksie,llsiegkteoentmekeknotgtdoelrre.gev.annV.askFjferinlselt | TiltaksEvkisiapnondnsneydsmiionntggo:snkei:ldoepnp.s- tSde,rgbrfionrgfvreidskkoaLmueftn.dsSubiosrtsyfmrpatonsne vedvarer, | kontaks lege. T1cakmKeodnsitvsaeiklntgianklge:pgaesswoaniedldle.lbaGris.aldFrrieaknaosllgjbernenkosminmgewrnneknuntiil seanmcbddavimeesdcies i |: | person. | TILTAK VED BRANWSLORNING. ZgnetPbrroadnunkstleukneixngsstabidrdaenln:slukkingsmiddel. } Ikke egnet brannslukningsmiddel: 1 i Eksponeringsrisiko ved brann: - | i . Le wd : 002397 La5b5.3r1ef5n4o.: Page 23of 31 & F-G03EF LichT WATER (m4) Ate 3% AR-nzrE ] Forbreaningsprodukzer vedbraan: Peosadyzes ved siukking av bran: BEST coryAVAILABLE : TILT VED Uriistares grein, | PersoSnelivgeeraveecrinleeceiklcaukn:der andre punkses 1 dotes -His-datablader. TltektVhensvtoeicdlbeeuszsetnoldmsscidkdmseseccr.asuiSeapslileli.lop:Saovgirlelnsseasaleusmidodppelbuemcitc.ierbneekrks.ilBemnedinec | FezniSonemgsuiadnvektskjmee13nd,tkvaFalainie.ezanviPinlagalslassverkejsemitkeenliesgsnvettalble.holder med lokk. RANT 7 EANDTERING 0G OPPBZVARING. . i BetinC2Hge24el%lssiieekulrksle.ef:olLraaglgzestegiaseksnki{evdreloednoszp.iptdbeeeLmrvapgaerrrheiavsntougrrsveepsdroodsvuoekmrtpeescaktaenr knoemmse 45Koenrtraokrss med beholderen test lukke: ns produkeet ik0kegraecdeir bernukt.er eory | Uforenelige materiales: VentilOapssjhoenv:as esballasjen ph et gods vencilese sted. i Sikkeshesstileax for & forhindze bras: SikkeTcihkeetbsrtainlnebaakc.for A forhindze eksplosons i Sikkerhetstiltak for & fochindre statisk elektrisitet: i ForhoPpldEesoazdcdeUamgko)SlreerrtivKaearndiecbrrouyksk:eixnsg fsuokrkkeess.akeReyfhoirnugenfsoasibnugte:avuSndeem:aibnreukomatvalter00R398||| iQAl twrile: Page 240o7s:31 ? FC-603E7 LIGHT WATER (TM) ATC 3% AR-AFFF 8 EXSIOVERINGSKONTROLL 0G PERSONLIG VERNEGTSTIA, | oyavesn: Uvnenzgndebr&ill3erdammpe,d vseparcaiyleerl.le: tdke i oynene. Bruk tette ii andveBz2nu:k egnede vernehansker hindering av producer. Vaevrnheehnasnisktksemresasvigfolmgaetnedrsialmeatevseidsle(s) anbefales: Butylgumni. ~ Annet.Unhnugdhvezhnudkeoannzahkien.cvesn: | AndedrUaeyvsz5ntegls(huv5fe)Lcraongnr:doundzdkeiennnsgtaianvAgaedlreudfzeiebclaezrsebv:eeismdnas:taetrnhioaasllfveam.arsein3eavs.meeelrdgtespdilenvkeornasvmeonfttorrasgjeodnen organise damper og vaskeforaige paztixiec: A/ZISL. i Svelging: : Ti Dper:odumkdteitk.keVesspkiseuss,sstdtreikkoensciceelrlergrurnodykiessmeudndesripsarboegidvammae.d Vask i| hendene etter hindtering og for spising. AnbetSaaolvideskjveeunattcsiuldgannsdijenodgnrs:evce|tnssvielransjobnenyiikskees.erSotrislssfzoerkkteillissi,remkdkeleiggnet ventilasion slik ac dampiorsentrasjonene holdes administrative normer og/elle kontrolier spray under eller agbefalts tike. | | Ada. normes for forurensning i arbeldsatmostare, Februar 1996: van A(u7m73e2c-k1n8i-n3g5e)z: Inger ada. norm. i 1,2-ETANDIOL (107-21-1) T8Sa--kttviiemnzeedrsiss vvppeemrr:ddit25mpgom/:a(dd:a-mp(1)0stev()ssev) | || Takverdi mg/ad:- (dame) += 2-(2-B8U-TtOiKnSeYrEsTOvKeSrYd)l-pEpTmA:NOL35/ (DIZTYLENGLYKOLMONOBUTYLETER) (112-345) A(n2snegceknninnogzesrk: adAmm.erinkoarnm)s.k grenseverdi asbefalt av produsenten. i SYNTEATnImSeKckOnViEnRgFeLrA:TEAIKnTgIeVnTadSmT.OFFnor(aT.rade Secret) ati 002399 |i L5a9b3.1re7f4no.: Page 25 of 31 F-SOEF LIGHT WATER (74) Ate 38 anearrr Aametkninges: Ingen adm. mown, TRIZTANOLAMIN (102-71-6) 88--ttiinmeessss vveerrad:i mpeosm:ma;- 5 1 ! TIERASnme(zTkrnaidnegeSre:creItn)gen ada. norm. i: | i RISTIRB-tAiVmeOsRsGAvNeIrSdKiZ gF/LUmOlR:KJ0Z,I1KALGIrZenRse(vTerraddse Saemcbreerte)lt av In. | 9 FYSISKS 0G XJEZMISKE EGzwsxaren, i Tilstandstomm, fazge, luke: os: Gul/brun vaske. : Sokepunke/-iatervall: 150s <1s0c : Smeltepunks/-incervall: Tike relevant : ! lacmepunk : Zagen (Setatlash) Selvantennelighat: Tkke kjeat Eksplosjonsgrenser, ovze: * Ikke relevant { | Demptrykk: Loselighet i vaan: ce. 15.8 mig (Kalkulert v/2oc) - | Fullstendiq Spesitikk veke: Damptetchet: ca. 1.06 (vanas1) | Shalt ste) v/20c) rable Flrkeise organiske forbindalser (VOC): = 355 9/1 scaqMD vi20c) (Kalkulere |= | Fordampningshascighes: Ikke kjent : Viskositet: 4 < 5000 centipoise ih Gaon. 002400 La9b3r1e2.f4ro: Page 26of31 FC-603EF LIGAT WATER (TH) ATC 3% AR-arrr 10 STA3ILITET 0G ReaXTIVITET, Forhold som skal usaghs: MateriIakkleeskjseoamt.skal unngds: | Faslige spaleningsproduktes: i1 gKaeszsbeosnaeolnloekrsicpes0t5ikklaezrb.ondDieokkosmlpdo.nerRiyndzgogaevntblruuokrsifde.cdiGsifbtiioendsdnasmper, StebilSfitoatrbevitelneto.egsFraeirsklkkisesiv&piotrelesypsmreessiesnatsejroennvoieln irikseikof.ore-k-ome. || : e P I orre ree ype p-- e Rei 2efeksSiekxa,oyonree:teisesion: smosone: ken vase sadhet, hevelse, smertes og | 1! tires. | Eetexser hud: ! HSiylmdptohmuedrickraincevsajzoen r(oedshceesr, lhaenvgevlasreigogelkliesre:giencate kontakt): |i || Langvazig elles gentatt eksponering kan fore ils oAgllKelresei.sk hudsesksjon: syaptomer kan vare rednet, heveise, blammer | Bffeks2ereniknenlbtadionvge:ssisgonaing nomes, ken fore til: som overstiser anbefalte adninistrasive i i FoPceltsuekitsz,jkoaniSsnoegvvnniaegv,hestse,lsosrmzeaasnlgnletearlavede,esyssktoveoinrnsdmiten:ldhsesi:yomnopsgteov|nneeer,ksktemrneedmveeasrifsnilhfoedlelpienre, bevisstloshae. -- aIvoejlgs,eshoonstilnogveoeglnuyfstivnegi.en): symptone: kan vaze shehet L nese og EffektOeyrrefsovreslsgikngu:tfort med organiske dette produktet, viser effekter sfolmuorlkejveemrifkoarlsiteyrr,relssoemr,fianes i oJH mbuaknsgplyetned,e abpipneytrietto,g hselmeavthoeltogsia.mtDeetffefkotreerllsmoomnrpAfvmimrenkeriimnvmeeoukrrtotlaopg,y, * 02401 ! !  Large | 99312-4 Page 7os31 Po reesoser nicer waten (mo) ane 3% anoarrr veiledning. PSleuulriizgnkieannlaoskganevryfnosyrpceeemneceri:s:ers,ympromer ken vare edusert urinmengde, bled 0BKAos2o3p5mtiXaer5:e05s0in1geo:dnbslpsionydslmuutossoggomenentlseu.n(gkLeaZunnbnegtveaaabinrenentieenlnhneneeessltliisysneegnA,eskeoapannuksssvkceeyivrlleadsesssi1kliesavrtta.atnfrisrielecnasvmieenndgl,egemer sie Inforsasion oa sllesgi, ovesfolsoshet: Krefstreakationde egenskapas: Arvessoffskedalige egenskapes: Rezzoduksjonsskadelige egenskaper: AndreoDfvelsesuk:soaesdkeLjvapeisrargoikzdkneuaiilnitigeieedr,sr,,a`neshenoesclneosnlemd:useloirmgeeunntsgaenlKglaiepnrealbfeslxoayrriseeerraersgsaloniseirsk1easgoenes i kroppen i Sfsioeerenbtmreeytnssnaeeisnkgeeskrssipooftnraieasarixnag(pemoren.searbDioenltgitfeooevrree)rlsfiogrgoegorraginanngieasnkkec.Kiimefinlicoaeceersnhoivtesedeneifnftoiketer RAS de brukes som forussait og i hamhold il veileduins VsFeoEnrCeeskpeoulablsiesiesnbeertasovtsokirndsieannngetns1x97eo0g fAulrnuedonersrk.pjoepmssiilkseaslsjipoeinrdsesn{iosbtolenogdiaesrtkbeetiidlseerdaead,nienhaarv ene asheiders vises ingen skadelige ebfeuer. Pp ---- SersidDseettletvneiss/asinteoodlfofgeiicstkeexsnteierkdkbeefyocrlhealsrtehtatbsi:boilootgoigsiksknednberdybtshyairste,rhemre.n brytes -- RDEielltujtooeertpkrio(edpauakirtkseietiel:sicsnenonemeh)noulldiegrenesn eilklkeererfineersdbroyrigoaanriesk0e3 forbliz { i 7 OkotokDseitkteolosgtiosfkteecdaetxa:minimale gisig ovestor akvasiske organismer (100002402 La9b3r1e2f-r4o.: Page 28.0f31 FC-603EF LIGHT WATER (TM) ATC 3% AR-AFFF Andze skadevizkninger, miljo: bata on biologisk nedorytbarhet: oD (Chemical Oxygen Demand): 740000 mg/kg: 500 5 dagess (3iochemical Oxygen Demand): 216000 mg/kg; 300 10 dagess: 376000 mg/kg; 80D 20 dagers: 446000 mg/kg; 80D 28 dagers: 602000 mg/kg. Akvazisk giftighes: 96 timers ECS0 for fisk (Fathead Minnow (Pimephales promelas)): > 148000timmge/zLs;ECS0 daphnia (Water Flea (Daphnia-magna)): 480 mg/l; 30 minutcess ECSO Microtox: 124 ag/ly 24 timers ECS0 Alge (Selenastrum capricornutem)): 170 mg/l. Behendling i renseanlegg: 3 times C30, Activated Sludge Respiration Iahibition: > 1000 ag/t. Sery for avfallshindtering int. gjeldende forskrifter. 13 FJZANING AV KIENIKALIZAVFALL. MetodeS:pesfiosrlafvjearlnli.ngLaevverkjeamvifkaalllietaivlfeelnl:offentlig godkjent innsemler, mottaks- eller behandlingsanlegg for spesialavfall. Anbefalte avfallsgrupper: HOVEDKATZGORI 07: AVFALL FRA ORGANISKZ PROSEZSSIR. UrNeDnZgRjEeArTiEnGgOsRmIidl0e7r,06:desAivnffaelklsjfornasaPiSdDBleravogfektotsstmoefsfiekrk,. spe, EAX-kode 07 06 03: Halogenerte organiske leseaidler, vaskevaskes oAvgfmaoldleszsloufsi.nummer: 7151 Organisk avfall med halogen. Spesielle komponenter: inneholder fluorforbindelser. 14 OPPLYSNINGER OM TRANSPORT. AOR-Klasse: - i sitter: - 0024d3 . Lab.ref.no.: 993124 Page 29of 31 se s: FC-GOIEF LIGET WATER (TH) ATC 3% AR-ATEE bokstavs sazgnummes: caricors: enemas: scao-ilasse: 0G-klesse: roc-sies - . - - - - - - EMS-nI.: - - MEAG: : - ouziseTicoepsltyrsannisnpgoerse:teslis gods. 15 OPPLYSNINGER OM LOVER OG FORSXKRIFTER. veskeestkese: symbolm(sets)s:aoELic (xn) IanehoEledyelze:nglykol 22,5 4, 2-(2-butoksyetoksy)-etanol 10 3, Teiecanolania 14 a-setnTianlgiess: ved avelging. S-secninger: Uovnnncgnke.inaTdhitndmiengn asvtodfafmepr/sipreeyynteented;kes.kylUlangshtrkeoksntagkrtundmieds hmueddenstoogre aSeihlqiekeermevdansscoogrekmoenntagkdterlesgiep.e PoAgTvamaann.sVceofdfspvhelghiundge,n, Kvoanstkaekst Galena og vis denne benolderen eller etiketten. lege - raa-- Yorz. yrkeshyg. luftbehov: B ; ovrigeGvoapnpnleyvsnntiengmeerrkoinmgmeorrkebsatsiekrettoe tpehn:tidligere ` 002404 meckeforskeifter og vil L9a9b3re1f2r4o.: Page 30of31 FC-6032F LIGHT WATER (TM) ATC 3% AR-APFF zevidesse meskeforsiriftes av januar 1998. Symbol: Ingen zIianeezhaonlodleas:nin1,2-etandiol, 2-(2-butoksyetoksy)-etanol, xaavndvaanzpe/spfraarylciegchvkeed. sUvnenlggihngk.ontKaakneimrerditehruedenoynoegneo.yneUnnen.gkFAi:nnkmaadning s=offes Konseks i oynene; lege. FAr mseknyllstosfcfrakpsh hgurduennd,igvamesdkesstosrtezakmsengmdeedrstvoarnes og mdeennndeesbehsohpledeorgenvaerlnl.erVeedtiksevtetlegni.ng, kontake lege onglende og vis T00i-grugoe:g } Spesielle lover og bestenmelser: S1.ixFkoercshiezsisfdtatoamblaudtazfboeridfealrsleigoegkjdeimsitkrailbiuesrj.on av Kelse-, Milje- og 2. Forsirife om klassifisering og merking av farlige kjemikalier. 3k.inFmoerdsfkorriefcmoimljoKflaazsss.ifisering, merkia B.v. av stoff som 4. Forskrife om stoffkartotek. - 55. Fzeoer.skzifc om spesialaviall. 16 ANDRZ 0PPLYSNINGER AV 3ZTYONING FOR BRUKERNES SIKKERSST OG HELSZ. AaveadTeillsnedseonnnzeinddees:skumkonseatra: for slukking av bran. Vikeigste kilde(r) ved usarbeidelsen av HMS-databladet: Datablad fra 3 General Offices, St. Paul, Minnesots, USA. Azsak til oppdatering: HBeilSe-ddaattaabbllaaddfeotrskerrifrceevri,derfta.stsTaitltpasisejtannuyaez m1e99r8k.e-Ztocg. Egne opplysninger: le IonpfpolrymsansijnogneernogphbdeesttteeopHpufSa-zdnaitnagblaadnegtlenedrsiFhieknthiogldbrutkilogvhzheindntievrairnegnedxe aivkkedetetreiprsoadnuskvtaerrmuedndedrettneormEaMlSe-daftoarbhloaldd.et,Enhevlelrerbrsuokm maevdfporroedruktbertuksoamv perrodburkukseezteniskoamnsbvianra.sjon med andire produkter eller enhver annen prosess i 002405 L5a5b3r1e3n4a: Pagetof31 Fo-03er Licer WATER (TW) ATC 3% Am-arre FOLGENDE PRODUKTER DEXKSS AV DETTE MNS-DATABLADER: a Toone. + 3xMe-A00F0F8E-/0I2C23-F1-60327 Brannslukn Gagaskun | Produkagen Toone. + F3eiM-g0Lh0ie0gi8hn-tg02WF0oa9at-me,0rdF/C3-NgA0r3F5E7/)a10c00Fir1e 0 oon, + 3xe-L0i0g0h8t-02W0a8t-e2r3/3NATrE/aTe ~Fire Fighting Foam, FC-80357, 200 1 3M ID-nr. +: F5Xi3Fs-Lh0e0ii0gn8hg-02WFo0aa7tm-e,4r3/FIo-NgA0T3EtZt/,A: TC20Fi1re 0024p6 AR 226 -- 0861 ACUTE TOXICITY TO AQUATIC INVERTEBRATES (COROPHIUM VOLUTATOR) IESTSUBSTANCE ~~~ 0000 Identity: ArefmeirxrteudretocaosntPaiFnOiSng, pFeCr-f9l5u,oroorocatsanaescuolmfponoanteen,twohficFhC-m6a0y3EaFl.so (b1eOctanesulfonic acid) (CAS # 2795-39-3). FRCe-m6a0r3kEsF:. CuTrhreen3tMinpfroordmuacttiioonnilnodtincautmebseirtisisanomtixntoutreed.ofT1h.e30t%estPsFaOmSp,le10is% dpireotphaynleesnuelgtloynceolfobautmyelr,et5he%r,A5lk4y.l1e5th%erwastuelrf,at2e,2.05.%1%etNh-y(l3e-ne glycol, 2.6% tCrhileotrhoaanlollyalm)ihneex,aamnindi0um.0c5hl%ortiodley, t0ri.a9zo%leX.anthan g~um, 0.9% starch, 1.0% cThhaerafcotlelrowiiznegd csounmcmenatrryataipopnlsioefs aimmpiuxrtiutirees.witDhatiancmoampylnetoetlayccurately reflect toxicity of the fluorochemical componentof the test sample. MewwoD: 00000 Method: ASTM E1367-90, Standard guide forconducting 10 day static sediment toxicity tests with marine and estuarine sediments. GTyLpPe:: NAocute static SYpeeacriceosm:plCeotreodp:hi2u0m0v0olutator ASnuaplpyltiiecra:l Fmioenlidtcoorlilnegct:edpfHroamndandiusnspoollvleudteodxysigteenn.ear Trondheim, Norway. TEexsptosourrgeanpiesrmioadg:e:10Addualytss (4-8 mm size) SStwaetdisitsihcaElnmviertohnomde:ntaLlCsPorovtaelcuteisoncaBlocaurldate(dVebrysiPonRO2.B3I, T19A9n0a)l.ysiCsa,lcNualtaitoinoanlof NOEC by single-factor ANOVA followed by Bonferronis procedure. Test coDnidliuttiioonnsw:ater: Natural seawater (34 ppt salinity) from an unpolluted asinteuninpoBlylfujtoerddesniteo.utTsihdeesoefdSitmaevnatngiesra, mNuodrdwayys.anSdedainmdenhtadcoalnleocrtgeadnaitc fDrialcuttiioonnowf a0t.e7r%cahnedmiastsirlyt :fraNcotitongiovfen0..8%. SLitgohctkinagn:dNtoetstgisvoelnu.tion preparation: Each test concentration was prepared--= by adding the test substance to 600 g damp sediment and 150 mL of sseuabwsaatmeprl,est,hewnitshhaakneonvefrorla3yohfou4r0s.0 mThLesseeadwiamteenrtawdadsedsptloiteianctho,tharnede aerated overnight before study initiation. 002407 Eanxdpo~s4u0r0emvLesosfelsse:awa6t0e0rmwLithglcaosnstibneuaokuesrsaecroanttiaoinn.ing 200 g of test sediment Numofrbepliecatres: 3 Numberof Number of organisms per replicate: concentrations: four plus 10 a blank control Water chemistry during the study: PH range (0-10 days): 8.18.1 (control exposure) 8.0 - 8.1 (3060 mg/kg exposure) Temperature range: 15% 1C Dissol9v0ed- o9x7y%ge(nconrtarnogl eex(p0o-s1u0rdea)ys): 93 - 100% (3060 mg/kg exposure) R0 ESwys 0000 N(dormyiwneaiglhtc)o.ncReenfterraetnicoenss:ubBsltaannkcceon(tfrloulo,r2a2n2t,he4n5e7),at102600.,9 amngd/k3g0d6r0ymwge/igkhgt. Element values: 10-day 10-day LCso = NOEC >3060 = 3060 mg/kg mg/kg (sediment dry weight) (sediment dry weight) Element values based on nominal concentrations RSuebmsatraknsc:e TReesmtianrgkwsafsielcdo. ndTuhcetevadlouenstrheepmoirxtteudraepapslydetosctrhiabtemdixitn utrhee aTnedstnot the fluorochemical proportion alone. c0 onclusion0 s 000 Tdrhyewteeisgthts)a.mpTlhee1100--ddaayyLNCosoOwbasserdveetderEmfifencetdCtooncbeen>tr3a0t6i0onmg(/NkOgEC(s)ewdiamsent 3060 mg/kg (sediment dry weight). The 3060 concentration was the highest concentration tested and caused ~17% mortality. Validity criteria fulfiled and reference substance obtained mortality of 16.7%. Submitter: 3M Paul, Minnesota, C5o5m1p33any, Environmental Laboratory, P.O. Box 33331, St. p0 ataQu0 auty0000000 Reliability: Kiimisch ranking = 2. This study meets the criteria for quality ~~~ testing. However, sample purity was not properly characterized and thestudy lsoalcuktsioann.alytical confirmation of the amount of flucrochemical proportion in the 002408 REFERENCES ~~~ 0000 rTeeqsutewstaosfc3oMnduNcotregde,bLyaRbFreRfoegraelnacnednuRemsbeearrc9h9,3o1f24S,ta2v0a0n0ge.r, Norway at the FC = Last changed: 6/26/00 002409 . Labrepro. - rage 1 a > RFE woogie R2SENRER "FC-603 EF Light Water TM ATC TM 3%" Toxicity tests . Report RF-2000/004 No.of pages: 3 Ahr Elin Horve Gente): 3M Norge Version No. / date: Vers. 1/14.01 2000 Resoarch Program: Summary: The following test results wor obtained with "FC-603 EF Light WateTMr ATC TM 3%: Toricty: Skelotonema costatum ~~ T2hEC,, (mon: -170 Acartia tonsa 48hLC, (mon: 280 Corophium volutator ~~ 10d1C,, (mgcry/weikghtg): >3060 The resus relate o the product as supplied by Novatech. Rey-words: Toxic, Skeletonema costatum, Acari tonsa, Corophium volutator. A Nortof document ay 5 produced naryfomwihtpareson i itingbyFF -FogaiandResearch . fSurfracer ise Soneson, ingerLisa Andersen bfo i- RbogansRessarch Karo Natiand 002410 : 993124 CONTENTS: 2. TEST FOR TOXWII THC SKEI LETT ONEY MA COSTATUM ....covcrvcmsersssesinsssssssessssssssssessmsssssssesss & 3.TEST FOR TOXI WIC THI ACATRTY IA TONSA c.c.cvvvssesrsseesnnsmssssssssssssssssssssassssssssssessssessssees 10 4. TEST FORTOXICITYWITHCOROPHIUM VOLUTATOR.....cocvvsssrrsssssssssssssmsssssssssssssssssssssnees 13) 002411 L9a93b1r2e4f, Pagike3ofal PREFACE: Ecotoxicological tests were performeond "FC-603 EFLightWater TM ATCTM 3%" in agreement with Novatech. The sample is a concentrate that normally willbe used in a 3% AFFF/3% AR solution. Tests were conducted in accordance with the "Harmonised Offshore Chemical Notification Format" (OSPARCOM 1995 /SFT 1998). The project was carried out at RF - Rogaland Researchfor 3MNorge. All the tests were performed by RF - Miljglab. Study director was SeniorEngineer Inger Lisa Andersen. The test results are presented in separate sections. The results relate 10 the product as supplied. by Novatech. This test report isissuedby a laboratory accreditbeyd Norwegian Accreditation (NA). The accreditation states that the laboratory meets the NA requirements concerning competence, equipment and working proceduresfor all the test methods contained in the accreditation. Italso states that the laboratory has a satisfactory quality assurance system, which includes internal quality control schemes, participation in interlaboratory comparisons, and the use of certified reference materials and secondary reference materials. The testsperformedare covered by the accreditation. This test report may not be reproduced in anyform other than infull, without the permission in writing by RF - Miliglab. 002412 LEabrteinos Pagedoft TEST FOR TOXICITY Marine alga: Skeletonema costatum 002413 sore rages arn TEST REPORT GROWTH INHIBITIONTESTWITH THEMARINE ALGA Skeletonema costatum (@)]iil A mw wa RESEARCH TEST SUBSTANCE: "FC-603 EF Light WateTMr ATC TM 3%" TEST RESULT: . `The72 hours ECso was calculated to ~170 mg/l `The test substance was supplied by Novatech, and the test results relate to this product. TEST DETAILS: Se 1 METHOD: NwiSt-hESNkeIlSeOto1n0e2m5a3c,o1s9t9a8t:umWaatnedrPqhuaaeloitdyac- tMyalruimnetrailcgoarlngurtuomw.th inhibition test `TEST ORGANISM: oSkreglaentiosnmeimsakceopsttaattuRmF, -stRroaginalNaInVdAReBsAeaCrch1.. A stock cultureofthe test sc PREPARATIONS: Naastbuarsails sfeorawtahteegrr(oswaltihnimtye:di34um%.)TfhreomwaatneruwnaposllfuitletderseidttehirnoBuygfhjaorGdFwCasfuilseerd, nauntdribernitesflaychceoartdeidngtotoabIoSuOt 170525C3,prainodr rtoecusoem,me`nTdheatsieoanwsatferrowmatsheenPraircihsed..w.ith Commission. y . ``mTge/slt wsoalsuptiornseweprbeayprsretiprearriedndg 1f.r0o2m0agstroacmksosfoltuhteiponr. oAdustciotnck1sloiltruetoiofngorfow1t0h2,0 `medium. Other concentrationswereprepared from this stock solution. INCUBATION: oTrebsittaclulsthuarkeesr,of35r0epmliicawteersfeoirnecaucbahtecdonicnen1t0ra0timoin.flaTte-sbtotctuolmtuerdefslwasekrseoinnoacnu`JTahteedtetsotawbaosutr2un00u0ndceerlsc/omnitifnruoomusalnieghxtpo(n>e5nt0iaplEl/ymgrsoewki)nfgrionmocfulluuomrecsulcfeanrte--, tubes of universal natural white type, at a temperature of 20. 2C. `tThheetteessttfwlaassksruenacfhordaabyofuotr7g2rohwotuhrsm,eaansdurseumbesnatmsp.leAslgoafl grmoiwwtehrweatsakmeenasfurroemd by fluorescence. pH measurements were performed as indicated on data sheet. 002414 L9a9b3r1ef2i4no. PageGef31 DATA ANALYSIS: CALCULATIONS: Gverroswutshtirmaet,esawsedreesccrailbceudlaitnedNSby-lEoNg IlSinOea1r0r2e5g3r.ession on biomass(fluorescence) ECs: The inhibitory effect on the growth of Skeletonema costatum is expressed as the concentration ofa product giving 50% reductionofgrowth rate (E,Cso). This e3f2f0emcgt/clo.ncentration was calculated by interpolation between 100mg/l and NOEC: TESTRESULTS: CfaacltcourlaAtNioOn VofANfOoEllCow(eNdobOybBsoenrfveerrdoEnfifsecptroCcoendcuernetrfaotricoon)mpiasrdionngeebayscihngle- concentration mean with the control mean. Table 1. EC and NOEC valuI es obT tainedEwithBSkrelottonemaccoossttaturn. e TTeessttwsbubssitaannccee EECCo EEGCew EEGCe "W_FaCt---e6r0TM3 EAFTLCiTMght35%" - 10 100<ECu20 NOEC: 100 GVVraaallupueehsPianarddeiccnaStiaeatclo1n0cc,enbutyrailtnitoaenrpstogliaetviiodnn.1N0%OE50C%aarencdl90e%anttibbiyiionnof gghreocwotmhpruatree.rpUrongrmmmeall `COMMENTS: `The results are based on growth rates for the time spa0n -72 h, the period during whichthegrowth is consideredtobe `exponential in the control cultures (see growth curves). "VALIDATION: `The cell validity criteria given in the density increased by afactor test protocol are of more than 16 fulfilled, in that the in the test period control (corresponding to vary by more than a growth 1,0 units rateof during more than 0,9 dTM', the test and the 72 the control pH did not hours test results with 3,5-dichlorophenol was in the range normally found. Lab. ref. no.: Sample received.: Test period: Report date: 993124 20.09.99 07-10.12.99 10.01.2000 Els Yorn Elin Horve, `Engineer Analytical technician Fell AgeMolversmyr Senior Research Scientist Quality Assurance Enclosed: Data sheets Tfhoimtsterrephoarnt ieul,dwbhyutbotrhetopreyisseicoendiesdwbryinNgorbwyegRiFan- MAcirsehd.iaon(NA) Toerepoertmapy orrboosndny 002415 L9a9b31r2e4f. age 7031 PRIMARY DATA: Growth inhibition test with Skeletonema costatum Test substance: FC-603 EF LightWaterTM ATC TM 3% Lab. rol: 993124 `Start date: 07.1299 MeasCounrce.meunnitt:: mThgeAbiomass was measured by fluorescence; values in fluorescence units Growth] Concentration| 1450| 00:30 |08.1102:.2959|] 11:55 | r|daatye-1 pH pH atofstteasrtt||oaft etensdt 0 012 | 028 | 0s | 4 122 | 08 0 o1 | 03s | 17 | 97 159| 1.000 0 01 | 033 [ 11 6 142 | 0998 0 009 | 03 | 11 | 64 148| 0998 0 009 | 028 | oss | 6 146| 095 0 009 | 026 | 09 7 151 | 0904 000 | oss | 175 | mn 009 | 028 | 12 | 63 008 | 023 1 a7 167| 0998 148 | 1000| 83 142| 1.000 10 008 | 04 10 009 | 04 10 01 | os 145 181 | 0985 115 169 | 0999 12 166| 1.000 2 028| 205 | 93 157| 0sss 2 03 | 19 | 92 157 | 0999 82 32 03 | 165 | 88 152 | 0999 100 009 | ost | 077 100 011 | 03s| 075 100 oi | os | om 142 | 0891 133 | 0988 139 | 0987 320 007 | 00s | 003 | oos 000 320 009 .[ 003 | 001 | oos 000 - 320 006 | 00s | 002 | ooe 000 1000 00s | oo7| oos | oos 000 1000 009 | 003 | oos | oos 000 1000 01 | 003 | 003 | o02 000 Reference substance (3.5-dichiorophenol): 1Smon | 009 | 015 | 015 15mg | 008 | 01 | 012 15mg 008| 014 | 018 Mean values: 0 010 | 03 7 32 009 | os 7 10 009 | 04 13 1020 005100 || 0033 59 320 007 | 00 0 1000 009 | 00 0 [Referencesubst]008|013|02| 02| 028[ 0908 035| 0968 032| 0921 745 [0558 em 152| 0999 172| 0999 113586|| 00999898||1eure+ 000 sireaz 000 noma ound wen (002416 5La9b3.1re2f:.4no. Page Sof 31 GROWTH CURVES: Growth inhibition test with Skeletonema costatum Testsubstance: FC-603EFLight WaterTM ATCTH3% Lab. rol: 993124 " Control I73 a 249 "= oF wnntonpou 7 10 mg 7s is Ii9 .= oF tecaton ur) " 00 wg IN3 s| g. i ZR 3 sorte liLeLj 32 mgt i + fae "= 3 tosaion por e"l| 52 mon Na iI2ay en oF tronpom " 520 mon kgs g Lee aba aontosse J Fs 1000 mg |3 i\ faa. Tm 3 Aero, w 002417 i Labrefno. 993124 Page 9of31 wIinthhi:bition of the growth of Skeletonema costatum mg/l ( FC-603 EF Light Water TH ATC TH 3%) Experimental data: CFoCn-c6e03ntrEaFtiLoinghtinWater TH ATC TH 3% Growth rate CCoonnttrrooll 21 CCoonnttrrooll 43 CCoonnttrrooll 65 control mean : 33..2200 3:20 1100..0000 10.00 3322..0000 32.00 110000..0000 100.00 332200.0000 32000 11000000..0000 1000.00 111.5229 - 114882 + 114561 1.45 11l.4687 1le2 11.l8619 i668 111.5577 152 11..4323 13% 00..0000 0:00 00..0000 0.00 iInnhpiebricteinotn --0 o0.l0 18 00..00 0.0 00..00 0.0 811.18 3 1100000.00 10000 111000000..0000 002418 L9a9b3r1e2fn4o.: Page 10of31 i 3 TEST FOR TOXICITY * Marine herbivore: Acartia tonsa Lo | 002419 L9a9b3r1e2f4io Page 11 of31 TEST REPORT ACUTE TOXICITY TEST `WITH THE MARINE COPEPOD Acartia tonsa TEST SUBSTANCE: "FC-603 EF Light WateTMr ATC TM 304" TEST RESULT: The 48 hours LCs, was calculated to 280 mg/l. The test substance was supplied by Novatech, and the test results relate to this product, | | TESTDETAWS: | + METHOD: ItoSOm/aDriInSe1c4o6p6e9po-d1s99(7C:opWeaptoedra,`Crqustua-cDa eeat)l .ermiinattiy on of acute lethaltoxicity : | TEST ORGANISM: AUcnairvterisaittoynosfaC(oDpaenan)h,agseunpp.lied by the Marine BiologicaLlaboratory, . | CULTIVATION: iThtehttehste o"rPagrainsiCsomsmmwiesrseisounp-plRieidngasTeegsgtsP,raotnodcowle"re(VcKuYl)t.ivaLtaerdgien caocpceoproddaintcees and adults were used in the test. PREPARATIONS: prior to use. Natural as basis seawater (salinity: 34 %c) from an for the dilution water. The water unpolluted `was filtered site in Byfjord was used through a GF/C filter T`megs/tl swoalsutpiroenspawreerdebpyrsetpiarrriendgf1r.o0m00a2sgtroackmssoolfuttihoen.prAosdutcotcikn s1olluittrieoonfodfil1u0t0i0on water. Other concentrations were prepared from this stock solution. |: INCUBATION:= The test was run in glass containers (28 mi rolled rim vials) each containing _ 3 2 25 ml of test solution vials were kept under and 5 animals4, rep a 16v8h light/dark licates for photoperio each concentration d at a temperature . The of "~~ ] F&S d2a0ta1sheCe.t. pH and oxygen measurements were performed as indicated on the i i " 002420 I L9a9b3r1e2f4o.: Page 120f31 +3 DATA ANALYSIS: "J CALCULATIONS: T2hperoedfufcetctloetnhatlhetosu5r0vi%vaolfotfheActaesrttiaanitmoanlssa(iLsCesx0p)r.esTsheedcaosmtbhienceodncmeonrttraaltiitoyn of pLeCrtsesvtalcuoensceanntdratthieo9n 5we%rceounsfeiddefnocreclalicmuiltawtieorne. caTlhceul2a4tehdobuyrsusainndg4t8hehous cPsrotonatcneedcnattrirdoapntriBooocnaserdludert(heaVlPerRtsoOiBo1nI0%2T.3Aa,nnad1l9y99s00i)s%.o, TfNhatithiseopntraelostgSarwnaeimdmmialessha.lEsnovicarlocnumleantetatlest NOEC: CfaacltcourlaAtNioOnVofANfOoEllCow(eNdobyObBsoenrfveerrdoEnfifsecptroCcoendcuernetrfaotricoon)mpiasrdionngebeyacshingleconcentration mean with the control mean. - iii TESTRESULTS: AcAa Tacmbalr--deiia1.ot--ownLsCaa and NOEC values btainehd24wwihtouhsr"sFC-603 E--0 F L--ight Wat4eTMh8rhoAowuTrCss TM a5, Loo i a 280 (130-380) 610 (490-790) 89 (54-120) 280 (220-360) :t L= on >10 00 = s8o80@6w20--1i50s00) VacNlaOulEecsCus:iinddibcyatPeR1O0B%ITS0a%naalyrsdis,0a%nde9t5h%licyonaffdeer2c2e04 nedr4a3shoruer.diUcebsnnNg/OLEVea1tr5oe0essaoeledby hecomputerprogrammeGraphod i5S 0. ' VALIDATION: Toxhyegveanlicdointycecnrtirtaertiiaongiavtetnheinetnhdeotfestthpertoetsotcwolasargerefaultfeirlltehda,nionrtheaqtutahletdoi4ssmogl/vle,d a tLhCe speorfce3n,t5a-gdeicmholrotraolpihteynionlt(hreefceornetnrcoel)s wwaass ilnestshethraanng1e0%no,ramnadltlhyefo4u8ndh.ours Lab.ref. no.: ul ` Sample received.: Test period: } Reportdate: 993124 20.09.99 10071.20.11.12.09090 Qu Vor Elin Horve AnalyEtnicgailnteeecrhnician a. Age Molversmyr SeniQouralRietsyeaArscshurSacniceenti~st~__ 58 Enclosed: Data sheets Tforomc ober or n in lel,dwshutrtheypermiessironeidwroiynRg ebyeRFs- MAiesiaeion VA Toer my se re = 002421 | N LEabrLgiro Page 130f31 PRIMARY DATA: Acute toxicity test with Acartia tonsa Testsubstance: ~~ "FC-603 EF Light Water TM ATTMC 3%" Satbar.t rdoate:: Measurement: s10o.r11z.949 Numobfdeeard i Total Number of specimen NUMBER OF DEAD number | pr. vessel 24 hours i 48 hours i; | concmenov)ation|| sppre.cciomneen 8A0CEF | Tom Total {| 000000 00 0001 [ 000 000 0 0 555 5 000 0 |Tr 000 0 0 11 21 2 i 1 i 1 3 3454 Reference substance @5dctoropheno): Lom ERE a lov]eo | 1 Theresultwiththereferencesubstanceiswithin therange normallyfound. = i& 002422 vlf Lwesbiriesdno: Page 14of31 Test substance: "FC-603 EF Light WaterTM ATCTH 3%" LaStbar.tdreatt:e: 9109.31112.949 by on MeasurofeoxmygeenanndtpHs. Ce e [ e oo>emrT [ vT e ee no e e e e TT e a] ao a a e 4 | con(cemnot!r)ation | O(xmygge)n PH- me me Ox(ymgohe)n P-H O(xmyogne)n PH- [owT[ o Ta] Referencesubstance(3,6dichiorophenol): __ _ 5 | | 002423 L9a9br3e1f2r4no.: Page 15of31 i TEST FOR TOXICITY Marine Amphipode: Corophium volutator | _ d 00242 of Lwaibusreepno Page 1631 7 TEST REPORT ACUTE TOXICITY SEDIMENT TEST WITH THE MARINE AMPHIPOD Corophium volutator TEST SUBSTANCE: "FC-603 EF Light Water TM ATCTM 30, TEST RESULT: - The The 10d test LCs was substance calculated to was supplied >3060 mg kgdry by Novatech, and weight the est sediment. resus relate o this product, TEST DETAILS: METHOD: ASTM E `Toxicity 1367-90, Standard Tests with Marine Guide For Conducting 10 and Estuarine Sediments. da y Static Sediment TEST ORGANISM: Corophium volutator, from an unpolluted site near Trondheim. _ CULTIVATION: The test organisms were supplied as adults (4-8 mum n ize) and were held in aerated seawater feeding. at 15C. A small amountofnatural seaweed was used for PREPARATION: Natural seawater (salinity: 34 %) from an bapolluted site in Byfjorden outside Stavanger was used for dilution water. `was used for preparing test sediments. Sediment collected at an The sediment is a mudd unpolluted site Edaanacamhlpytsesesedtdcfioomnrecnoetrngtiarnnaiatcipoclanoswnttaiecsnbtpuraceknpedatpr.reod1pb5oy0rmtaildodnoisfnislgettafhwoeraptereaorcdhwuatceststi.and6dy00sgarndamasndofwas. bucket was shaken for 3 hours. The sediment was divided into ed cad the three beakers, 400 mlofseawater was night. 10 animals were the damp sediment was added to each, and the then randomly selected analysedforwat beakers were aerated.over for each beaker. A sample o f . calculated as mg kg"sedimentdry er weight, content, and all concentrations are INCUBATION: sTehdeimteesnttw,aasppr.u4n0i0n mgllaosfs csoenatwaaitneerrsan(d60100maln)imeaalcsh,c3onrteapilinciantges20fo0rgeoafcehst ~~ 5 { 8 ticneodnmcipecenarttaretadutroioenno.tfheT1d5haeta1besaChek.eetr.psHwearned koexpytguenndemreacsounrteimneunoutsswaeerraetipoenraftoarmed as b 002425 Lolf rwnns: DATA ANALYSIS: Page 17731 : `CALCULATIONS: T`tmrhoaerttiaoelnfifoteycftapeoprnrtotedhsuetcsctuornlvceitehvnaatllratootfi5C0o%roopfhtihuemtevsotlautnaitmoarlsis (eLxCpxrce)s.seTdahestchomebcioensc.en- 3 value and the 95% on were used for calculation. The confidence limit are calculated by using the 10 day LCsy standard P29.R03,O%B1o9If9T0t)hA.entaTelhsytissiasnp,irmNoaalgtsri.aomnamle SawlesodicsalhcuElnavtiertoensmtecnotnaclenPtrroatteicotnisonleBtohaalrtd(oV1e0rs%iaonnd NOEC: CfaacltcourlaAtNioOn VofANfOolElCow(eNdobyObBsoenrfveerrdoEnfifsecptroCcoendcuernetrfaotri`ocno)mipsadrionngeebaychsingleconcentration mean with the control mean. TESTRESULTS: Table 1. LC and NOEC values obtained with "FC-603 EF Light Water TM ATC TM 3%" Corophium voluator 10dsys LCi 99 ( -760) 1a >3060 NLa ook: . >33006600 . cVVaaallleeessuadirieecbcady ttehae1c0o%mepSbu0tuye%PaRpanOrdBo5Igr0Tra%anemamleyesdtiGsrl,oapnfhdePr3d51h%0 cenonyfSidoeUnnceceilmsFgesehdoimmeents"3nmoerg e "VALIDATION: ``Tohxeygveanlicdointcyecnrtirtaertiiaongiavtetnhienetnhdeotfetstheprtoetsotcwolasargerefaultfeirlltehda,ninortheaqtuatlhetdoi6s0so%l,ved tmohretpaelricteynitnagaeremforetraelnicteysiunbstthaenccoenotfro2l0s.w9emreglFelsusotrhaannth1e5n%e.kTghedpreyrcweenitghatge fsoerdiormgeanntiwcacson1t6e.nt7%b.utTthhee ssieldtifmreacnttiounseidries cfoomunmdentodebde hwiigthheirn.acWceephteadvelimits obseasrignvifeicadnt mortality in one concentration (1060mg kg! dry weight sediment) but the mortality in the `highest concentration was notsignificant. `Table 2. Characteristicsof the sediment used for testing -- T_TOErO gaRnicE0cm o1EmeRnt w E(5) ic0 c o SSiiltn ftra0ckt8ione a(3%)) e ne ) &i Lab. ref. no.: Sample received.: `Test period: Report date: Enclosed: Data sheets 993124 20.09.99 0-10.12.99 07.01.2000 Ba Wer Elin Horve Engineer Analytical technician A Molversmyr Senior Research Scientist Quality Assurance 002426 L59a3b1r2e:fr4o. Page 18.031 PRIMARY DATA: Acute toxicity test with Corophium volutator Test substance: "FC-603 EF Light WatTMAeTrC TM3%" i: LStaabrtdealt:e: 3173.1122949 Measurement: Numobfdeeard ( Total | Nsupmecbiemreonf NUMBER OF DEAD | number | pr.vessel Sdays 10days [LCo(ncmcernoytarwtoikiognght|[pSrp.eccoinmce.n| 8A F|| AB C EF|| Tomi Total 1 Control 10 10 1100 1100 000000 10 10 10 7 3060 @ | 1 10 10 i Referencesubstance (fuoranthene): _ [| 3 10 10 10 ro a[1 | i 002427 | i `Startdate: om 17.1299 ee [oo [en Measurofeoxmyge enanndtps H. Tow we] o=emo [ [ [ ewTTo w eoeeo e oo o e e eer ] ] u (1 mg/kg dryweight) (%) . (%) - (%) . ow [wo[ewe e ie tTT] gi 002428 pLab.irefno. 7 Page 20 of 31 ! DATA SHEETS | B 002429 | L9a3b12re.f4ro.: Page 21of31 ENS-0ATASLAD (Felse-, Niljo- og Sikkerhetsdatablad) Soskcuanreaccears. :: 072-67/20947/-907 Svekgrieevses ue: 0131//1111//9988 SViedersiolna:v 03.0101 Tse5l-edfaotna:bl6a3de8s4 7e5x u00tar/bTeeildeef:axa:v K63ilj8oav1d7el8i8ngen ved I Norge A/S. : 1 IDENTIFIKASION AV RJZNIXALIZT OG ANSVARLIG FIRMG: : Importer: 34 Norge A/S i EandelFsCn-a6v0a3:EF LIGHT WATER (TH) ATC IV AR-AFEF ;i Deklarasjonsaunmes, ?roduktregisteret: i Telefo2n2,'59Gif1c3in0f0ornasjonssentralen: i 2 OPPLYSNINGER OM KJZMISK SAMMENSETNING. . : Informasjon on enkeltkomponenter, faresymbol(er) og risikosetainger storrmavy cas-nz vexn-paoszT 1v,a2m-ETM0L 1707372--211815 52-"526s 2-(2-8FUaTreOsKySaYb=oTlOeKsS/Yr)is-iZkToAsNOeLtni/nges: Xn; Ri22 112-345 0 (DIEFTaYzLeENsGyLmYbKoOlLeN/OzNiOsBiUkToYsLeEeTaEiRn)ger: Xi; R:36 }: SFILUNOTREATLIKSYKL,OOVVEERRFFLLAATTEEAAXXTTIIVVEESSTTOOFFTFZR TTrraaddee SSeeccrreett [1T0Es TFRLIUEOTRAKNIOELMAINSIKNAKRYLAT Tr1ad0e2-S7ec1r6e: 12-31 i TREvSuTzERReAV ORGANISKE FLUORKJENIKALIER TTrraaddee SSeecczree:t, Tkk1e -kj3ent 002430 Sirs Lab.rej.no. Page 220f 31 F-60327 LiGaT WATER (TN) ATC 3% Anearer P| 3 viens rasanonmvren. | EelsetKaarne:vase fazlis ved svelging. Kan ieitere oynene. || sikkos*hec: |J| MiljofSapzees:iataveall. soRsTERIzLSTITAR. i TiteakSiaiollydlndee:tsnsaeraek,s oynene med rikelige mensdes vam. Kontakt lege Tiltak hud: SStokiyyllelsfLosertrtdaoekyt.sbrhBuuukideaesnsmLyamevpdesnosmdaapr3e oskgpeosrritktiei,liisgeNereesmuseaknkogttdeedrre.sev.annv.skFjenriniselt | i|| TiltakHeKohinsistpnaonkdnssneydcmiiplnnotgggo:esn:keisldaapno.stSho,tsbrfionrgfvreidskkomuateen.dsSubiosrssfyrmapeosene vadvazer, ||| | TitaKBoesndvtieaslkigsnisnklga:gpeasuomniedldle.lbeGsL:.aldFrriesknaolslgbireenknaeimngseurnnkeunnSilseennchbdevmiesdcles i| | pezson. | i Tima vio sRaweLING, | Zonet.PbrroadmusiLtusknaixngostnibdrdaenln:slukkingsniddel. ] Ikke eqnet bransslukningsaiddels ! i Saporsningasiaive vot Brings - | i 002431 FLabhrein Page 23ep31 T FC-603EF LIGET WATER (TH) ATC 3% AR-AFFF 84 | rormreminsroroaeer ver orem Prosadyza: ved staking av brann: THT vis vriierene vreiin. PectonSteigveernvaetsinleiseikteauknsder andre punkier { deted-FHgdasantades, oSVRhezsnhaticieblreec:meanoddmsehvmiaenanrt..uriPSslolaias.lseraSevosoirleasosenasntsaousnmairdodpepBlosebaemriieso.breoneemZktnk;iesei hnomnedesov FiesniSnagsuanvkskje13m,tkeFllieecsnviinagrtasv kieatkatieevtall, EET 7 ANDTERING eee OG. OPPSIVARING. | setinCBHgaeAetllsiiieekulresi.efzToLaragLgzesregiaseksakteevrtaoedonrpc,phtbaeenfmvsapagecrrhieaonstrgu:rveapscreadsuvoxmetpreassanpknaosnaehkneioemmney 4b3oKoontnaket med beholderen test lukke: ndr produkzet ikke SFE er i bruk. | Uforenelige materiales: 1 Opghevas Ventilasjon: anba. llasien ok st godt vensiiese seed, Sikkerhezssileak for & foshindre beara: SikkeTrehreetbaeteinimeaaaks.for A forhindre sksslossons 4 Sikkerhetstiltak for & forhindre statisk elektrisitet: Forholdscegler ved bruks h PHorlodduekmtbeallkausnjesnorktiensgt lfuokrkherts.akeReyokrionrgenfeonribnugdt: Umndoernbnruk SaYv. ee odzaaz zi& 993124 Page 200731 : FC-60JEF LIGHT WATER (TM) ATC 3% AR-AFFF srocsronTRoLL 06 Pemsevie vemvRTILL | ----vGenrsahebr&iil4erdammpa,d vsepsrearyieerl,le tke oynene. Brak sects : stndveR3sh2an:kdsaatginnagdasvvaprrnoedheanntsokre.s rmeteien] Buchan vavechheenhsaimkssiannesasriyomravemriaisetveed er Annesunhnugdhvazmaocheonnncahtienscvern: AndedrCCaUevnEs"rnPtogTushsunvt)eitsrsfanegno:irodnotudcbtiapnneeginrnianB0vsu3edLravudfarerebsidaczcaeebtrseeitcmoenens:caemrmpoienavelmbsier.eciomems,eesvs.eerraastes,pFhieonkneernmseennepteoereasajloonnen | svetstPoaurgto:cinkkeairk.keVassphisesse,ssedtrsikkoeosciceelrlergeucraiyikeysmuusndsehresacobpeidvemme,d vask i; | hendenis etter hindtering og for spising. | snbesels vessitasson: VG#veoinossiniusat.sssuogInnnidsneigdirskevreaenstvielcraansmjpobhneonriiskackraesri.esrjSotonitalstsetbroerskokliedilesisigr,sennimbederneiagnpnpeattaite | . Ads. administrative normer nosser for forurensning og/eller kontrolle:r L arsaidsasaostare, spray eller tdke Febeues 1996: . | makninge,zs Tages sds. nora. | Laesravoron (107-211) | TTS8-kcvtvieiemrmseedscritss Tvpvaeyosrroedesis2apwp-rma:(hdd;ei-mmeL()ostev()heov) | = 2-(AS(moiran2iarnek-ennYrisEBsnTegOvUacKersSs:TYe)daAOtEbsTmeoKAmrNeisSOkoLa3esnms/'k(gDeIeSnTsYeLvEeNrGdLiYNOsLnHbeGfNaOlNsURYaLvETpErRo)dus(e1n2t-e3n6.-51 ; STENATamSeckOaViEnRgFeLrA:TEATRagTeInVEaSinT.ORYmo(rTneade Sacies) |J whit) TT TT 0dza33 5La9b31r3e4po. Page25 ofl FO-603EF LIGET WATER (TH) ATC 3% Amarrr Asmeckainges: Ingen adm. morn, TRIZTANOLAMIN (102-71-6) 88--ttiinmeessss vveerzddii mppgm/:ms:- 5 TENERASnme(cTkrnaidnegeSre:creIsn)gen ada. norm. RESTIRS-AtiVmeOsRsGAVNeIrSdKiE oPgL/UmOdR:TE0N,I1KALGIrEenRse(vTerraddse aSmebcerefte)lt av 3x. i co :! i| :! 9HFeISrISKE a0eGm xyzuIsK:e somnsraTERr . ece | i oTsi:lstandstorn, farge, luke: G7al5/b-zu0n vaske. :; SXoekletpeupnuknek/s-/i-nitenstvoazlvla:lls T<i1kse0rcelevant :i: Flanmepunks: Ingen (Setaflash) : Selvantennelighet: : Ikke kjent Eksplosjonsgrenser, ovee: * ke relevant | Demperykic: Zeselighes 1 vane ce. 15.8 mig (Kelkulert v/20c) - | Spesieikk vexe: Fullstendiq ca. 1.06 (vanaet) Damptetthet: vizacl) t (uth) (Relides i FIyktise organiske forbindelser (VOC): w=/230505) g/L scaqid (Kelkulere == | Fordempningshastighes: Ikke kjent : i Viskosites: < 5000 centigoise 002434  Laeb9re2f4no Page 260131 | FC-6032F LIGHT WATER (TH) ATC 3% AR-APFF -- " Forhold som skal unaghs: MateriTaikleeskjseonmt.skal vnags: | Fazlise spaltaingsproduktes: i| Sfeoaarrsvbeeonrntneeoslnlsekiksrkiedpesoscirkeklpaers:eh.soenndDiteoekkrosemipdon.oneenrAiyndrgirsoisakevon.btlruu.okrsifde.rdiGsiftbilgoenddiaemper, | SeebiSltiacbeitleo.g Fraerslkissivoitleysm:esisasjon vil ikke forexomme. So I11o OPRLYSNINGEr R OM Exzszraa ns. te. i | =tfekUcelsaovyneei:rzicesion: prey sympoer ken vase rednet, hevelse, smerter og !i| Effekcer hud: ! HsyEmLpthomuedrizzKiacnasviaorne (reatdhteecr, lhaenvgvealrsiegogellKeisre:gjentatt kontakt): i Langvezig elles gjentatt eksponering kan fore til: oAglleklsosei.sk hudzeskajon: symptomes kan vase redhat, hevelse, blemmer Effekter innbading: : n2omeenzk,elkanovefroreekstgioln:esing som ovesstiser anbefalte administrative :i b2ofecevvhsiieksztssk,jtaolinsonsesegvhvnenisaeg.v,hes:se,lnocmrraeanslgnleteranlvede,esyskstoveoimrmedmiten:ldnsesjtyomnopsgreov|nneeer,kksamtnerdaemvseerrsetihlofdeelplienre, | wo Tsveecligs,ashioonsti(nogveoglnuytseivnegi,er): symptome: kan vase skrhet & nese og | EffektDeyrzesfvoerlsgsikngu:tfert med organiske detes Produkter, viser effekter sfolmuorlkejveemrifkoarlsiteyrr,relssoemr,finnes { i fbaunksgplyetned,e bsipnpeytziecto,g shelmeavthoelrogsia.mtDeetffefkotreerlismommrphivmimrokewr nievumeskoslteapn,t;' ! 00243k | L9a9b3r1e2f4no. Page 270/31 ! FC-603ZF LIGHT WATER (TM) ATC 3% AR-AFFE veiledning. Sfvheuligzikaagiagkanavfonryezentei:l: symptomer & urine: og ryggsmertes. ken vare redusert urinmengde, bled 0Ak0osPmakmiaezs:ets.ja)oe:dnsosinyelmuupnnigooenmntees.(kLaEunnngvaealbrmeeitnennhenosletilisgnegA,rssoapnkusstkteiyvlladnetssikleasrtt,anfdgreiensmpeiednrlge,geses Rosse ope blod og lungebetennelse som kan vare livstruende. Inforassjon om allesgt, ovesfolsomhet: efstrenkaliende egesskaper: Arvestoffskadelige egenskaper: Reproduks jonsskadelise egenskaper: AndzeDesksatdeevpirrakdniunkgeessr,inhneelrsoel:der en eller flere organiske : offvelecusdozriylcsejaaeignzniegksasltiiideo,sf,teesastoem(nmmeutslaoibmgoleuinttsgtaenkrga)in,moalobegskoyrklabenetseaskelkoluegmrsllesarogemrsesveidkzopoen gnfdiosrendtmeaesnbsnreeuskkeeeksrspsofonzmeas.ifenokgrseupsto.snaecrDtientgogfoovrieerlhfieognrgheoorlrdgiatnnigliesnkveekiilefenldtuneoirnhkgej.lesmeiekfafleiketrer gVFeoInrSeezkepolumlbseltiesnbeeraf:volosniridgneagnneins1k97eo0g fulhznuedonererk.pjoepmJuislkeaslejipoeinrdeesmiiobsllooondgeiatsrbkeetiidlsetsudede,nierharav este asbeidess vise: ingen skadelige effekter. . 12 OPPLYSNINGER OM MiLvoFans. ersisDeteletvntsie/s3sisnoeoldfofgeiitstkeexstneierkckberfyotrlbealtrtehtetbti:boiloolgoigsiksknendebrdybtrbyatrhta,rhemce.n brytes [== Dfeltutoerkpjreondiukkatleiterisnonmehmoulldiegrenesn ailjoet (persiscente). eilklkeererflenreedbroyrtgbaanrieskeog forblir i Ao OkotokDseitkteolosgtiosfkfeetdaetza:minimalt BC/L < lavacre fren mmen giafiereidg oovmeensfoor roatkrivoaitiiosekee Oo7r9geanndismer {100 00243 i L9a9b3.r1e2f4ro. Page 280f31 FC-603ZF LIGHT WATER (TM) ATC 3% AR-AFFF Andze skadevizkninges, milje: azz on biologisk nedbrytbarhet: COD (Cheatcal Oxygen Demand): 740000 mg/kg: 800 5 cagess (3iochemical Oxygen Demand): 216000 mg/kg; 300 80D 10 20 dagess: dagers: 376000 446000 mg/kg: mg/kg; 50D 28 dagers: 602000 mg/kg. Axvatisk giftighes: 96 tiness CSO for fisk (Fathead Minnow (Pimephales promelas)): > 1000 mg/L; 48 timers ECSO daphnia (Water Flea (Daphnia-magna)): 480 mg/l: 30 minustess ECSO Microtox: 124 mg/l; 24 timers .ECS0 Alge (Selenastrum capricornutem)): 170 mg/l. Benandling i renseanlegg: 3 timess 250, Activated Sludge Respiration Iaaibition:'> 1000 g/L. Sors for aviailshhndtering iht. gjeldende forskrifter. 13 FJZRNING AV KJZXIKALIZAVFALL. Hetoder for fjerning av kjemikalieavfall: Spesialavall. Lever avfall til en offentlig gockjent innsamler, motcaks- eller behandlingsanlegg for spesialaviall. Mabefalte avfallsgrupper: HOVEDKATZGORZ 07: AVFALL FRA ORGANISKE PROSESSIR. UNDERKATEGORI 07 06: Avfall fra P3DB av fettstoffer, sipe, rengjoringsnidler, desinfeksjonsaidler og kosmetikk. EAX-kode 07 06 03: Halogenerte organiske leseaidler, vaskevaskes og moderlut. Avfallstoffnumer: 7151 Organisk avfall med halogen. Soesielle kouponenter: inneholder fluorforbindelser. 14 OPPLYSNINGER ON TRANSPORT. ADR-klasse: - sitter: - 002437 L9a3b1re2f-r4o.: Pagease290/293/ 1 FC-603EF LIGHT WATER (TM) AIC 31 AR-AFFF bokstav: - : mazgaurnes: - cerrc-xors: - O-neames: - ca0-klasse: - H0G-klesse: - THDG-s ide: - Eus-nz.: -= ura: : - ovrige opslysninges: Ixke transporsferlig gods. 15 GPPLYSNINGER OM LOVER OG FORSKRIFTER. . seskeesikese: symbolE(EeLnS)I:SRADELIG . (Kn) Ianeholdes: Etyleaglykol 22,5 , 2-(2-butoksystoksy)-etanol 10 3, Triezanolamin 13 i R-setnFianrgleiss:ved svelging. S-setninges: Unngd inndading av damp/spreytetike. Ugh kontakt med huden og omyennegneee.r Fvainramoagn sktoonftfaekte ilecgey.nenFeA;r smkaynll3tosftfrakpsh grundig med store huden, vaskes sotnrgahkesndemedogstvoisredmeennngedebrehoslpdeereong vann. eller Ved svelging, etiketten. kontakt lege =| Yi-gru0ppe: Korr. yrkeshyg. luftbehov: i evrigeOvoepnpnleyvsnntiengmeerrkoimngmeerrkebsatsiekcetttpehn:tidligese merkeforskrifter og vil : ven 002438 Labrie: Page 00731 . i 993124 age 30. + FC-GOIET LIGHT WATER (TH) ATC 3% AR-ATFF cevidere maskeforsirifeer av jamuar 1993. Symbol: Ingen 2Iinneeshaonlodleas:nin1,2-atandiol, 2-(2-busoksyetoksy)-stanol, Xevan dvaamzpe/spfraazylsiegchvkeed. svUenlnggidngK.ontKaaknt imrerditehruecenoynoegnee.yneUnnea.gh Fiirnnmkernding sXtoanftfeekre ilegoey.nanFez; smeknyllstosftfrekpsh Shurduennd,lsvemesdkesstosrteramksengmdeedrsvtaonrse og mdeennndeesbeshiopledeorgenveeslnl.erVeedtiksevsatlegni.ng, kontake lege omslende of vis a : YL-gruppe: # Spesie1.lleForlsokvezriftogobnesutteanrmbeelisdeerl:se og distribusjon av Felse-, Mile og S2.ikTkoerrshiercisfdtatoamblakdlasfsorififsaerrliingge kogjemmiekrakliinegr.av farlige kjemikalier. 3k.enFmoerdstkazrietsmoimljoKfleasses.ifisering, necking a.v. av Soff som 5.. FFoozrssiizriitfec oonn sstpoefstiksalratvoitaelkl.. zee. 16 AOR OFPLYSNINGER AV SZTYDNING FOR SRUKERNES SIXKERHST OG ELSE. AavendFeillsaedsaonnncehnddeer:skunkonseatras for slukking av brasa. VikeigDsetseebklialddef(rra) 3vedGenuetsaarlbeOifdfeilcseesn, avSt.HHSPa-udla,tabMliandmeets:osg, USA. ArsakHetille odpaptdaabtleardientg:er revidert. Tilpasset nye mecke- og S-datadladforskrifuer, fastaate i januar 1998. Eee. Esme opplysaiages: 4 Infornasjonen pb deste S-databladet ox 1 heshold til vie nbvarends oaipvkpkledyestetnxeinigpersroadmuoskgvtaebrsesmtueedndeodrpeptftnaeozrnmGiaHnlSge-daaftnoagrbhlloelanddd.eet,Ernihkevtleilrgerbbrrsuuokkm omagevdfhpedrrnodedtruekrtbieenragkesnoamv | porodburkutkeeztenLskoamnbsvianra.sjon med andre produkter eller enhver snnen prosess t 00243] La9b9r3e1f2n4o.: Page 31of31 FC-603EF LIGHT WATER (TM) ATC 3% AR-ATFF FOLGENDE PRODUSTER DEXKZS AV DETTE HMS-DATABLADET: 3 10-ne. X-0008-0223-1 3M AFEF/ATC ingsskum PFrCo-d6u0k3sZjFonBrannslukn 3 1o-nz. 3 10-nz. 3 oor. X-0008-0209-0 3M Light Fighting WFaoatme,rd/F3CW-A60F3FEEF/,A1T0c00FiLre X-0008-0208-2 3M Light Waterd/IWAFFF/ATC " Fire Fighting Foam, FC-60327, 200 L +: X7-0008-0207-4 F3iMghLciignhgt WFoaatme,sd/FICS-6A0F3FEEF/,ATC20FiLre i 002440