Document 8V7eR7Eygp7w46VMgxJ1JJRvm

AR 226 0671. Centre Analytical Laboratories, Inc. : 3048 Research Dive State Coleg. PA 16801 Phone: (814) 231-8032 Fax: (814) 231-1253 or (814) 231-1580 Analytical Report Fluorochemical Characterization of Surface Water Samples Cleveland, Tennessee (W1973) Centre Analytical Laboratory Report No. 023-014A Testing Laboratory Centre Analytical Laboratory, Inc. 3048 Research Drive State College, PA 16801 3M Environmental Laboratory Contact Kent R. Lindstrom Bldg. 2-3E-09 P.O. Box 33331 St. Paul, MN 55133-3331 Phone: (651) 778-5352 i Requester Kris J. Hansen, Ph.D. 3M Environmental Technology & Safety Services Bldg. 2-3E-09 P.O. Box 33331 St. Paul, MN 55133-3331 paceroes 000955 1 Introduction Resulls ae reported fr the anys of a series of surface water samples recohed by Conte AcGniaaall,ycttiecadlfLoabmorCalteovreileasn,dI,ncT.e(nCneentsrsee).froTmhteheCo3MnElnveiryonnmuenmtbaelrLaabsosriatgonryei.do Thepseamepsles owesre S(peLciC.IfuMowraSoschIreeiMqcueaSstc)headraocrtaalriszaatmoennb,y uAicdahovmSalogerapphy/etandrem maasstspecetrometry Thesampleswere prepared and anably LyOMSzIMeSfoth owoiffucrn ocharig cals: + Table :Target Anes Perfluorooctane Sulfonate Perfluoroociane Suifonviamide [PFOS| TonhfelaonwaiyniGcaarmie.thoDdatuasperdeshernteewdhasrvsalda3tedibgyhnesie.alyTcheovvaiadattonaparntoticvsoarnd.ess are 2 Sample Receipt icTnhieovsilaamllpdlsioeaesmpcswlweeterrcooaonsnuontbitmnsirutpsepdlwieeidne.irCnedhhicinedu,fa puSslaiamopstlyecfosnwlteoaimrneertrseocnafonsvderwdoeosnee0n3aot03pr0le0seorTvhceed.asosEmte HaSnamspelno oMnC-$110620H0)was not ansaad as per clan request", (Ema cammuniaton fom Kis 3 Holding Times The anaiyical method used wes vaidaled agains a maximum hong ime of 14 days, The stabiolfitthye analytes ofinterestforlongerperiods has not been determined. pacezors 000956 4 Methods -Analytical and Preparatory 44111 SLaCmpMleSPMreSparation for LG/MSIMS Analysis `Samples were nll vested with 200 ul. of 250 mol sodium tiosulate solton to remove TLrehCseiMdScuaaIlrMticShdlgaoenraiwlnyeas.sis.fSroslAtidfeovrpimheiadslweitieex5tproamrcLttioioofnno4(f0Ss%PaEmm)peltwehaawsnaoslusiaenndwsaftteoemrepsrdoelpfuoai.roaen.CtehTeShePsEaemlcpusloteorswtofiosr discardedandthe SPEcolumnwosthenelutedwih 100% metianol. A 5miportoonf cmoentcheanntorlatwioansofctohlleecstedaformparniapolrystilosanbaeylyLssiCs/.MS/MS. This treatment resulted in aneight-fold 412 Sample AnablyyLCsMiSMsS In HPLC, an aliquotof extract is injected and passed through a liquid-phase chromatographic: HtchoPelLuumCin.sdepmBaaroasbteiidoeno,pnhEatSshIee,MaStffhpienrtaoynvaioldfyettsheeasarnarapelitydatiaenfneoddrfatochrceuarscathtaaetriamocnetaearryrisspthifcaorsaeamnoianulnytzthioenfcgot2lmuwemi.nderFerolalalntiogvweeinotgfo kmornigodawnntiecfmpceuormaoptourruenosd;sc,mhionealcrlemeuociibnusgcearfarlvueelodriooacnhinezdremdq,iucaafnsrt.aigtEmaeltenedtcetadog,sapianrnsatdysidtseatgneedcnateerrdda.lsly lpoanrsactheadarafcrteelrastoorf (aAnSHaRelMyw)z.eetSttahmPepaclskeaasmrwpdelreHePee1xx1tr0aa0ccttHse.PdLAnCoanlsyy5ss/it1se6mw0a0casonudppearltoeomnadedMaibcuyrsiolMnmgaSsysseSlUeolzcitnem5dae/M1re8ad0c0Sti,onSw/aammsopnuMlisetoe1rSdiGnf.og u0s8edHfworaasnealxystainrsdoianns5tc2ru2mte0n0etapndad raanmacaelnotbyneefz52or3eu1ns0dd0,inTathteacHhmenPtaDn.dLMS/CMS methods 5 Analysis 51 ACaTl-ipboriantciaolbnratoncurvewas analyzed at thebeginingand end of the analytical sequence 5fo0r0,thaencdo1m0p0o0unndls o(fppitn)teTrehset.rTehspeocnasleiborfathioen pqouianntisiwaetorne oprnepvaerresudsatte0, c2o5n,ce5n0,tr1a0l0o,n 2w5a0s,. c`pcuormlovleasoftooarnteccaotecfhfce piociifeed nntrt.p>(1U)0sa.tin9nd8ga5lc(ionsbe2faf0rclr9e7ent0eg)or.fedsetseirwmioitnnhatiixonwe(i7g)htwienrge,tdheetselrompien,eyd-inAtecracetprtaatnodn Calbration stanadreaprrepdaresd using thesameSPEprocuseedfdrsuamrplees. Calibrationcheckstandardswere analyzedperiodica ctohnrcoeungthroauttiontsahereawnialtyisnis+se-quoe2nfcteh.0acCt%oumapllviaalnec,e ll y is (every three obtained tofivesampleinjections) if the standard analyte Fortheresus reported here,calirberrawteriemoent. PAGE3IOFS 000957 52 ehBExteltalracaonctwtkoiesonnvbebaacnnakklsbsrsawhteiorounedspaorntedphaarra.edvFaaoenrdiaasnraoltyaszaenmdpalweietssh,pehrveeesreyexnteatxcaalocorniaobbnaovnbeaschwheerocfeosncacamempnpltelaso.tnotnThoe lFIeanvvseleiuamalenbynrtatlbalroganentksstaainnndatahreeds,foaprnrmdoosafeftSraaknnoomrwentahbgaonvhoelotvshoellvoesnwatimwpeelsresso.scaAoignaian,laolnhyzesedbaanafdesreeavenrFeyoshipogaah Samples presenisd herethe nsument blarencomkpiasnt 5.3 SSuurrorgoatgeastpeiskes arnot acomponoefnthte LGMSMS anayical methad, 5.4 AlM1Ml0aaa0tbironiirgxtshpoSiurcspyeiisnmgkwaaeletlsreecsop7rmiepkpoeausrsnenddoofwofer dvereerrceyosvef.riieMedaslsioafmapfslcpeiok(meeprxoecucuondvdiesnrgibeesbltarwneekeGs)neaTtn0a.i1c3Ao0na%ncthaetonnC.of cSFoimlphosuplnoiodewssrweowcfeoeivrneetrerpydernstet.phareFdifeileodlndsssppaikkmeep.lreeAcMovCoe-ri1iee0s1cHaormapt oiausnoccohngcvSeehnnotawItenidoAnrteohfvm1ee0rn0terbl&e..twuSseiEnnOgG6aA.1 Ta0%. 55 tnADleuspfalemidpcslaaetmerpselessus(ehxAcituadicnhgebnatrk5s.) vere analyzed in cuptcae. Resuls re given slong win 5.6 Laboratory Control Samples MAcitlziqcowramteenrmtww.aesrposbpeikotewdewieutnh70al-nl1c3o0m%dpionuensadcofhinLtCeSr,estRaetco2v5erainesd2a5r0enggv/eL.nwAiltlsrehecroovwedrfsoirea1sll 5.7 Sample Related Comments ough a Field blank psearmcplesccaorndsigsetedwaofseamdpdteydctoonthaieneermsp.tyFcoornttyaminielrtearnsd oafntayepeed| wiatehre fsiatemreed `manansethre other samples. - 6 Data Summary Pleasesoe tachBfmorednetated sting oftheanataosu. 7 Data/Sample Retention SefaocmltdpeolrresismcairnGeitaainpeiosdbsayerGcdheoinfvieedn,eonmornetihvaabflretmherdeaarnids ihsasrudedcoipsrsepoarotns voiesesstaerceidiend.dAal pacesors 000958 8 Attachments 81 AttaA:cChh ainm -ofe -Cun stotdy 82 Atachmont5:Resus. 83 AtachmentC: Mati Spike Recoveries(Fieldand LaboratorySpikes) 84 AtachmentD: LCMRawSAnayMtcalSData 9 Signatures ohZhen.Fi1ah1ery, Opgrato Manager Ke1LvoyidVincs Plesidont bytes Date o Datme OtherLab MembersContributtoDiantga KaErnaoknsShmaiWtihckromesinhe David Bal rcesces 000959 } Pr IN CAN Centre Analytical 570 eseecreh Drive, Sale CoLlleagabPAoT6r301at914o.29r7.8i03e2 sFA.X oTeI2n01c12.80 altdorticston on ue Cangas pt. aodOcionis n SaneDsrtn poss ee owictn <3 Ee cwtere 438 o He --i ----s <33 lo grin of25. Th nsdn. unw 25 F. o PEOS 1d PFOSA 337 1 orPORK PrOSAG) 3 3 33 POMS) " 3 3= x esr ee To a Gan a an. BEST COPY AVAILAI REET = VN, NaN) g | . :. . AL N3t PSRRI T MRE ] |NWiES. ZY HimesrTMesete |[7% 7% 7 NF il si. {3NS \f&< [Eb 7 RR YIogk > ford AN3 Rp LeLI Seal Ate $ WAT SRT RET {JEL RES hl 5 A ou lingo :y Se liasy = ip, 4 Eh 9 Ry. IY VY ?7 x3 a/| oA fo }\A & ANG3 EL A ee Yrs 2Sh Sh ~ pe AAR te) IN Ted Madd & Yee A Sg J 45 HHSeiginml A ud x | a Liye = Lo SEES EE gS ef : 7 `sohnsooutwhmnap Environmental Sampling Sites North of Cleveland, TN 000951 aa STV ES 2S rag ony RE J a 4 : Ween : B/;D 0 YJorX i7/A AT" piaNi sntsinJg/]AFdA > Wg& {wf IGiT. Rptee b{iwchen Tiga NSoorpese eas Af S[ioear,rno7 JSSl H So SA {oahu FFD wr L areent SE aysdCyflany rib fm lo / Fe Eplathagd oN J Se Ska 7 IL Gull i "7 AS& N NERr , rN wilh 4 SOY SIRES ne hod OSA ATES 27 / 2 wi2 Hlo AL OfEaia AgeAoNfreI Soy re amd, ER 7y A . SSEYS AIHS BI GR RBT II I LY Addons samplogHes Environmental Sampling Sites for Cleveland, TN 000962