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HYDROLYSIS (ALKALINE) AR 226-0364 TEST SUBSTANCE Identity: NN--eEtthFylOpSeErfAilucoorhooolctoarneFMs-u3l4fo2n2a.mi(d1o-eOthcatnaonle;sumlafoynaamlisodeb,eNr-eeftehryrle-d to as 1,12,2.3.3,4.45,5,6,6,7,7,8,8,8-heptadecafluoro-N-(2-hydroxyethyl)-, CAS # 1691-992) Remarks: Material is an off-white, waxy solid of uncharacterizedpurity. METHOD TMeytpheod(t/egsutitdyeplei)n:e foAllklaolwiende:poPtraoscseiduumrehyddervoexliodpeesdolbuyti3onMexposure YGeLaPr:(Y1I9N)7:7 orNobefore Remarks field: -Test medium (air, water, potassium hyrdoxide. soil, other - specify): 20% alcoholic - Duration: 24 hours - Positive Controls: None - Negative Controls: None RESULTS Concentration of Temperature C: Substance: 50C 362 mg/L. Degradation %: 92% after 24 hours Rbreomkaernkdsofwineldt:o IpeRrafnludorNoMocRtasnteudsiuelsfocnoantfeiurnmdederthtahtestehecoNn-diEttiFonOsS.E Alcohol was CONCLUSIONS Under the conditions of this test, N-EtFOSE alcohol partially degrades to form perfluorooctane sulfonate. Submitter: Minnesota, 3M Company, 55133 Environmental Laboratory, P.O. Box 33331, St. Paul, DATA QUALITY. Reliability: Kiimisch ranking 2. Purityofthe test substance was not characterized. 006466 REFERENCES 3FiMuoTreocchhneimciaclalRse,poPratg"eAn1a1l,ytPircoajlecMte9t9ho7d0o6l1o2g6y43o,n NFoMve3m42b2e.r" 1A5., M1e9n7d7el, Fate of OTHER Last changed: 5/18/00 006467 " Fomerariay TECHNICAL REPORT SUMMARY JP TECHNICAL COMMUNICATIONS cenTER -- 201.20 Important - report sprinted both sdofpsp,sen wo opis TCC.) W1s/77 : Environmental Laboratory (EE PC) Fate of Fluorochemicals 0. L. Bacon Analytical Methodology on FM 3422 re A Mende1 mOnroatRnrhsionuQ,O cCoomim)e oRcoTIivE evotenion |RCRA Tam . AFBnElauloyrePoiCcc-haDelinvi.cal Progress Report 0222 5970612643 $ er 393 rar 13 LoShammori > E AATe RGR Tay EAWoyT=ohCommiGnors . A 006468 : Co ne Revised 12/27/77 sau aorsis oF si Tsdhoievsetrisaltllasbyielaainrtdsybeoacgraouisnuensdteoarfbilaiitqtsuyeoluoascfk cFooMnfd3wi4ta2it2oenrtso.wsaorlduBbeibclaaisutesye,watshtihseappRsaattraeebriniltailltyyssottfuedaimFeud 3422 toward base in alcohol was studied in the present work as follows: SpAioxtsaasmspsalimepulaweashsyderatocaxhkiednoefawfaatse2r5kem0l.p5t-s,oinlulta-i,o50n7-ofoainld36b22a4-tphpahfroosfr,. FvaManrdy3i4nn2ge2utileneantg2it0h%zsedaolwcfioththoinlei.c cailonlntocekersnfterprareteecwdiiptinhtiatttrhiieocnEaCoc/fiGdCpotatonaastlhsyesieusmp.henintoGrlCapthaetnhaaallnyedsiinmsinoiinfmdiitzcheaestoawrlacteoenhrdolwpohsiionclthu;ttietonhndissgatvoe the results in TABLE V. TABLE V HYDROLYSISSTUDIES OFFu 3422 Tine (in hrs.) 0 0.5 1. 7 24 3422 (in ppm) 2 580 w2 26 28 ) Ancerusatitrxeatdlhitzoseadmdprlyaesmeswasabsovaenadllaontdhweedfrietlsotiedrrueeedmaiwtnaosirnaenmaotlvhyeezeosdiollbidbysa.tThLC,Tfhoearnd5f0iIlhtRrrsaa/ntSde0MwaIsRC.c(oRneIqct.enw.as wCFa4Cs6-794b59r)os.kheonwAeddocwotnhmepyatroiwseForCne-95otfheuntdhseeamrcR.ethvesaIelRueacnoodndfNitMtiRhoensstr.uedsiiedsue cwointfhirmtheadtthoaft atuthheenFtHic3422 AS CHHOMATOGRAVIIY OF PLRFLUOROOCTANE SULFONAMIDE AND FC-128 (4194745) > `cFMoCen-d1i2rt8oitopenonssteidodnesasctriimabneedoifnetaeFrrMlfie3cr4re2.n2cweaTsotod2.eF8tMemr3im4n2i2un,teeswdhiolitusthoeethresrotslhaeultiaobantosve1(6si0nulfmuoesntihanamgniodtleh)eawnedre mcthhdreeormmaaftloolrgyrtahaptohsee2d00.tyoT(hmaeabrtoeeufrtoira3el.,s3. tmhienTruheetosissulrnefotoennaitmniitodener)focwroheunilcdleebFepCr-oc1bhl2re8omm.actoousgdrapnhotedbeiso TCUTHLINNI-:LLARAYEORR CWIROAMATOTGRAOPITGY SSTRTUUDDIAIEESSPOOFFIFFMMI3344Y2222 OpMlfaadtsieaomlwpbaloseleweadxspoFssMepdo3t4t2t2eod a(on5)n Xw-aarsapylaeftxiealmmwihniefcdohrbwyaabsTouLtCtheofnnoerdwepeuvreeikltoypa.endd Ainbouetthytlen amcietcartoeg.ramsThe the Film was developed. RItg arnedveoanleedcotmhpatonetnhte material, nearly 1.7 grf,temwa3ai4sn2i2nc-go'lCautmatdhcehrtoohrmriaegotiongi.rmappuhArecidctoireodsni,nsgtilwlyoi,ccaotmghopelonoebnnyttiscrehloofrragodrfieooaratmcetrive ) gwrihasudtiiocogonrr.abpihnyeA.dbouatnPdurfcorretmcyahtreo{r5miaamtllogwrFaarspahcectdioonnbasisnweaedbroevfeorcounlftluiotlcutreeedsssetanundtdiicamslo,lnyitoIarlmlepdurobefyFtTMhLeC3-m4aa2ut2te-g1ry3ica,l was rendered pure (6). 006469