Document 8JQL383xLgdrkOkke2LV9vqo

en RESEARCH Precise Research. . Proven Results. Analytical Report Fluorochemical Characterization of Aqueous Samples Decatur Outfall 001 FC Monitoring (E05-0774) Exygen Research Laboratory Report No. L0007003 Testing Laboratory Exygen Research 3058 Research Drive State College, P A 16801 Requester Gary , Hohenstein Environmental Manager, Special Projects, E H S Operations 3M Bldg, 42-2E-27 St. Paul, M N 55133 exygen.com 1 Introduction Results are reported for the analysis of aqueous samples received by Exygen Research (Exygen) from PACE Analytical. The Exygen study number assigned to the project is L0007003. Specific fluorochemical characterization by liquid chromatography / tandem mass spectrometry (LC/MS/MS) was requested for all samples. A total of 8 samples (including field duplicates, blanks, and spikes) were received for analysis. The samples were prepared and analyzed by LC/MS/MS for the following list of fluorochemicals: Table 1: Target Analysis Compound Name Perfluorobutanesulfonate (PFBS) Perfluorohexanesulfonate (PFHS) Perfluorooctanesulfonate (PFOS) Perfluorobutvric Acid Perfluoropentanoic Acid Perfluorohexanoic Acid Perfluoroheptanoic Acid Perfluorooctanolc Add Perfluorononanoic Acid Perfluorodecanoic Acid Perfluoroundecanoic Acid Perfluorododecanoic Acid Perfluorobutanesulfonamide (PFB Amide) Perfluorooctanesulfonamide 2-(N-methvlperluorobutanesulfonamido)ethvl alcohol Acronvm C4 Sulfonate C6 Sulfonate C8 Sulfonate C4 Acid C5 Add C6 Acid C7 Acid C8 Acid C9 Add C10 Acid C11 Acid C12 Acid FBSA FOSA Me-FBSE-OH The analytical methods used were originally developed for groundwater samples and were validated by Exygen. The validation protocol and results are on file with Exygen. Only the C8 Sulfonate, FOSA, and C8 Acid were included in the original method validation. It should be noted that the quality control elements included In this analysis demonstrate the applicability of the method to the additional analytes. 2 Sample Receipt The water samples were submitted in plastic containers. Samples were received at ambient temperature. Samples were stored at 4C from receipt until analysis. Eight individual containers were received. Field samples were collected on 12/13/05 and 12/14/05. Samples were received on 12/15/05. Chain-of-custody information is presented in Attachment C. PAGE 2 OF5 3 Holding Times Field and laboratory spikes of these fluorochemicals have shown stability for periods greater than 90 days. Samples were analyzed within 60 days of collection. 4 Methods - Analytical and Preparatory 4.1 LC/MS/MS 4.1.1 Sample Preparation for LC/MS/MS Analysis Water samples were initially treated with 200 uL of 250 mg/L sodium thiosulfate solution to remove residual chlorine. Solid phase extraction (SPE) was used to prepare the samples for LC/MS/MS analysis. A 40 mL portion of sample was transferred to a C i8 SPE cartridge. The cartridge was eluted with 5 mL of 100% methanol. This treatment resulted in an eight-fold concentration of the diluted samples prior to analysis. 4.1.2 Sample Analysis by LC/MS/MS In HPLC, an aliquot of extract is injected and passed through a liquid-phase chromatographic column. Based on the affinity of the analyte for the stationary phase in the column relative to the liquid mobile phase, the analyte is retained for a characteristic amount of time. Following HPLC separation, ES/MS provides a rapid and accurate means for analyzing a wide range of organic compounds, including fluorochemicals. Electrospray is generally operated at relatively mild temperatures; molecules are ionized, fragmented, and detected. Ions characteristic of known fluorochemicals are observed and quantitated against standards. A Hewlett-Packard HP1100 HPLC system coupled to a PE Sciex API 4000 MS/MS was used to analyze the sample extracts. Analysis was performed using selected reaction monitoring (SRM). Samples were extracted on 1/20/06. Samples were analyzed on 1/27/06 and 1/31/06. Raw analytical data is provided in Attachment D. 5 Analysis 5.1 Calibration A 9-level calibration curve was analyzed at the beginning and throughout the analytical sequence for the compounds of interest. The calibration points were prepared at 0, 25, 50, 100, 250, 500, 1000, 2500, and 5000 ng/L (ppt) for LC/MS/MS analysis. The instrument response versus the concentration was plotted for each point. Using linear regression with 1/x weighting, the slope, y-intercept and correlation coefficient (r) and coefficient of determination (r2) were determined. A calibration curve is acceptable if r >0.985 (r2> 0.970). Calibration standards are prepared using the same SPE procedure used for samples. All calibration criteria were met for this analysis. 5.2 Blanks Extraction blanks were prepared and analyzed with every extraction batch of samples. The extraction blanks should not have any target analytes present at or above the concentration of the low-level calibration standard. For these samples, the extraction blanks were compliant. PAGE 3 OF5 Instalment blanks in the form of clean methanol solvent were also analyzed after every highlevel calibration standard, and after known high-level samples. Again, the blanks should not have any target analytes present at or above the low-level calibration standard. For the samples presented here the instrument blanks are compliant. 5.3 Surrogates Surrogate spikes are not a component of the LC/MS/MS analytical methods. 5.4 Matrix Spikes Field and laboratory spikes were prepared using all compounds of interest. Field spikes were prepared by adding a measured volume of field sample to a container spiked with the target analytes by the laboratory prior to shipping containers for sample collection. Laboratory spikes consisted of aliquots of un-spiked field samples that were fortified at the laboratory at the time of extraction. Field blank spikes consisted of laboratory water fortified at the laboratory and shipped with the sample containers to the field and back to the laboratory for analysis. Laboratory control spikes (see section 5.6) are samples of laboratory water spiked at the time of extraction. Each type of spike provides information needed to assess analyte stability, extraction efficiency, and matrix effects that may impact analytical results. Matrix spike recoveries are given in Attachment B. Please see Section 5.7 for additional discussion of matrix spike recoveries. 5.5 Duplicates Field and laboratory duplicates were prepared for each field sample. Duplicate results are given along with the sample results in Attachment A. 5.6 Laboratory Control Samples For LC/MS/MS analyses, Milliq water was spiked with all compounds of interest at 100 and 500 ng/mL during each extraction set. All recoveries for all compounds were between 70 130% in each LCS. Results are given along with the raw data in Attachment D. 5.7 Statement of Accuracy Based on results of field blank spikes and laboratory control spikes, the analytical method accuracy for all analytes is 30%. Based on the results of field and laboratory matrix spike samples, the overall accuracy for the analysis is as follows: C6 Acid, C7 Acid, C10 Acid, C11 Acid 50% C4 Acid and C5 Acid are considered as screening quality because of high and variable spike recoveries All others 30% All spike recovery data are reported in the data tables. 5.8 Data Summary Please see Attachment A for a detailed listing of the analytical results. Results are reported in parts per billion (ppb) (ng/mL). Please note that the limit of quantitation is 1.0 ng/mL for all compounds except MeFBSE-OH and C4 Acid, which have a quantitation limit of 4.0 ng/mL. PAGE 4 OF 5 6 Data/Sample Retention Samples are disposed of one month after the report is issued unless otherwise specified. All electronic data is archived on retrievable media and hard copy reports are stored in data folders maintained by Exygen. 7 Attachments 7.1 Attachment A: Results 7.2 Attachment B: Matrix Spike Recoveries 8.3 Attachment C: Chain of Custody 8.4 Attachment D: Raw Analytical Data 9 Signatures Other Lab Members Contributing to Data Chrissy Edwards Date PAGE5 OF5 Section A Report 1Analytical ^ Sum m ary o f Fluorochem ical Residues in Outfall 001 Effluent fo r E05-0774 Sample ID Outfall 001 Effluent \ Outfall 001 Effluent* Outfall 001 Effluent Dup Travel Blank Equipment Blank C4 Acid** Perfluorobutyric Acid 13.6 12.6 . 12.0 \ ND , ND Analyte Found (ng/mL) C5 Acid Perfluoropentanolc Acid C6 Acid Perfluorohexanoic Acid 1.96 2.06 1.94 ND ND 1.97 2.10 2.12 ND ND C7 Acid Perfluoroheptanoic Acid ND ND ND ND ND Sample ID Outfall 001 Effluent Outfall 001 Effluent* Outfall 001 Effluent Dup Travel Blank Equipment Blank C8 Acid Perfluorooctanoic Acid 3.59 3.56 3.70 ND ND, Analyte Found (ng/mL) C9 Acid Perfluorononanoic Acid C10 Acid Perfluorodecanoic Acid ND ND ND ND ND ND ND ND ND ND C11 Acid Perfluoroundecanoic Acid ND ND ND ND ND Sample ID Outfall 001 Effluent Outfall 001 Effluent* Outfall 001 Effluent Dup Travel Blank Equipment Blank Analyte Found (ng/mL) C12 Acid C4 Sulfonate C6 Sulfonate Perfluorododecanolc Acid Perfluorobutanesulfonate Perfluorohexanesulfonate ND 151 1.11 ND . 159 1.04 ND 156 1.08 ND \ ND ND ND . ND ND C8 Sulfonate Perfluorooctanesulfonate 11.0 11.5 11.6 ND ND Analyte Found (ng/mL) Sam ple ID Outfall 001 Effluent Outfall 001 Effluent* Outfall 001 Effluent Dup Travel Blank Equipment Blank FBSA 27.3 25.8 24.6 ND ND FOSA ,1.24 1,24 1.20 ND. ND , Me-FBSE-OH** ND ND ND ND ND ND = Not detected = Response between 0 and 1 ng/mL. **ND = Not detected = Response between 0 and 4 ng/mL. ' Laboratory Duplicate 0006 J ^ 3 .03055f8 Research Drive State College, PA 16801, USA VJ : 814.272.1039 F: 8 1 4 .2 3 1 .1 5 8 0 exygen.com Section B CH R ecovery S um m ary o f Fluorochem ical Residues in O utfall 001 E ffluent fo r E05-0774 Sample Description Outfall 001 Effluent LowFMd Splks C4 Acid* C5 Acid CSAcid C7 Acid Amount Amt Found Amount Amt Found Amount Amt Found Amount Amt Found Amount Spiked in Semple Recovered Recovery in Sample Recovered Recovery in Sample Recovered Recovery in Sample Recovered Recovery (ng/mL) (ng/mL) (ng/mL) (%) (ng/mL) (ng/mL) (%) (ng/mL) (ng/mL) (%) (ng/mL) (ng/mL) (%) 10 13.6 83.4 698 1.96 45.4 434 1.97 16.7 147 ND 13.6 136 Outfall 001 Effluent HighFMd Spika 100 13.6 1210 1196 1.96 331 329 1.97 142 140 ND 154 154 Outfall 001 Effluant SpkC Low Lab Spika 1 13.6 26.8 ' " 1.96 5.12 316 1.97 2.51 54 ND 1.50 150 Outfall 001 EfRuant Spk D High Lab Spika 100 13.6 89 , 877 1.96 399 399 1.97 130 128 ND 154 154 Field Blank Low Fiald Spika 10 ND 8.01 80 ND 8.53 85 ND 10.9 109 ND 10.4 104 Field Blank High FialdSpika 100 ND 76.7 77 ND 84.3 84 ND 115 115 ND 95.6 96 ^ Sample Description Outfall 001 Effluent Low Fiald Spika Outfall 001 Effluent High Fiald Spika Outfall 001 Effluant Spk C LowLabSpika Outfall 001 Effluant SpkD High Lab Spika Field Blank Low Fiald Spika Field Blank High FialdSpika C8 Acid CSAcid C10 Acid C11 Acid Amount Amt Found Amount Amt Found Amount Amt Found Amount Amt Found Amount Spiked in Sample Recovered Recovery in Sample Recovered Recovery in Sample Recovered Recovery in Sample Recovered Recovery (ng/mL) (ng/mL) (ng/mL) (%) (ng/mL) (ng/mL) (%) (ng/mL) (ng/mL) (%) (ng/mL) (ng/mL) (V.) 10 3.59 15.1 115 ND 18.3 183 ND 15.5 155 ND 15.6 156 100 3.59 96.3 93 ND \ 140 140 ND 138 138 ND 127 127 1 3.59 100 3.59 4.41 95.3 82 92 ND ,1.53 153 ND 126 126 ND ND 1.10 110 111 111 ND 0.979 98 ND 94.8 95 10 ND 11.1 111 ND 11.7 \ 117 ND 11.0 110 ND 12.0 120 100 ND 115 115 ND 111 111 ND 102 102 ND 124 124 ND = Not detected = Response between 0 and 1 ng/mL. *ND = Not detected = Response between 0 and 4 ng/mL. . "Sample residue exceeded the spiking level by more than 4 times; therefore an accurate recovery cannot be calculated. 0007 ,^^3 005588 Research Drive V^ m sState College, PA 16801, USA J: 800.281.3219 F: 8 1 4 .2 7 2 .1 0 1 9 exygen.com CH R ecovery S um m ary o f Fluorochem ical R esidues in Outfall 001 E ffluent fo r E05-0774 Continued Sample Description Outfall 001 Effluent Low Field Spike Outfall 001 Effluent High Field Spike C12 Acid__________________ C4 Sulfonate__________________ C6 Sulfonate_________________ C8 Sulfonate Amount Amt Found Amount Amt Found Amount Amt Found Amount Amt Found Amount Spiked in Sample Recovered Recovery In Sample Recovered Recovery In Sample Recovered Recovery in Sample Recovered Recovery (ng/mL) (ng/mL) (ng/mL) (%) (ng/mL) (ng/mL) (%) (ng/mL) (ng/mL) (%) (ng/mL) (ng/mL) (%) 10 ND \ 13.1 131 151 140 .. 1.11 9.78 87 11.0 19.8 88 100 ND 113 113 151 251 100 1.11 94.6 93 11.0 105 94 O utfall 001 Effluent Spk C Low Lab Spike O utfall 001 Effluant Spk D High LabSpIka Field Blank Low Fiald Splka 1 100 10 ND ND ND 1:20 120 116 , 116 11.9 ,119 151 151 ND 135 ** 279 128 9.85 99 1.11 1.11 ND 1.76 65 11.0 9.20 " 95.3 94 11.0 98.0 87 10.5 105 ND 11.4 114 Field Blank High Fiald Splka 100 ND 95.8 96. ND 83.4 83 ND 112 112 NO 110 110 I-------------------------- Sample Description Outfall 001 Effluent Low Fiald Splka Amount Spiked (ng/mL) 10 Amt Found in Sample (ng/mL) 27.3 FBSA___________ j,__________ FOSA____________________M-FBSE-OH* Amount Amt Found Amount Amt Found Amount Recovered Recovery InSample Recovered Recovery in Sample Recovered Recovery (ng/mL) (%) (ng/mL) (nn/mL) (%) (ng/mL) (ng/mL) (%) 32.6 53 124 12.0 108 ND 9.23 92 Outfall 001 Effluent High Field Splka 100 27.3 105 78 1.24 105 104 ND 81.0 81 O utfall 001 Effluent Spk C Low Lab Splka 1 27.3 23.9 ** 1.24 1.85 61 ND 2.23 223 O utfall 001 Effluent Spk D High Lab Splka 100 27.3 126 99 1.24 108, 107 ND 79.3 79 Field Blank Low Field Splka 10 ND 10.9 109 ND 10.0 100 ND 9.29 93 Field Blank High Field Splka 100 ND 117 117 ND 85.9 86 ND 78.2 78 ND = Not detected = Response between 0 and 1 ng/mL. *ND = Not detected = Response between 0 and 4 ng/mL. "Sample residue exceeded the spiking level by more than 4 times; therefore an accurate recovery cannot be calculated. 0005 ,^^3 005588 Research Drive State College, PA 16801, USA YJ: 800.281.3219 F: 8 1 4 .2 7 2 .1 0 1 9 exygen.com Section C 3058 Research Drive State College, P A 16801 RESEARCH Phone: 814-272-1039 Fax: 814-231-1580 Loain r Login Group: L0007003 Login #: Project: Company Name: Submitted By: Login Type: 7114 P0000522 3M Kent Lindstrom Immediate Receipt of Samples Conform COC Sample: Conform COC: Conform Sample: Conform Request: Started: True Date Start: 12/15/2005 Due Date: 12/25/2005 Received Date: 12/15/2005 Received By: Ammerman, Mark Spread Sample: Label: Exygen SD/PI: Risha, Karen Project Title/Type: Groundwater Sampling, Decatur AL / ROUTINE Login Notes: True True True True Packaae PK0008101 Carton Date / Condition Packaaes / Containers ShiDDer/ ID Received Date: 12/15/05 10:30 Package & Contents Uncompromised FEDEX 8540 9614 7422 Temp. Control/Temp. None 20.2 Container # '129216 C0129217 C0129218 C0129219 C0129221 C0129222 CO129223 C0129224 Gross Weiaht dH Container TvDe 609.10 g 500 ml Clear Plastic Narrow 611.70 g 500 ml Clear Plastic Narrow 240.70 g 500 ml Clear Plastic Narrow 250.30 g 500 ml Clear Plastic Narrow 257.80 g 500 ml Clear Plastic N arro w 258.50 g 500 ml Clear Plastic Narrow 258.20 g 500 ml Clear Plastic Narrow 609.10 g 500 ml Clear Plastic Narrow Preservative NONE NONE NONE NONE NONE NONE NONE NONE Mfg. Lot Direction / Handled Bv RECEIVED Ammerman, Mark Mfg. IP 12/15/2005 Login.rpt 0009 Report Version: Dec 13 2005 1:43PM Page 1 of 2 Instance: R0214957 lllilllHIMRIH SamDle ID L0007003-0001 j|^ L0007003-0002 L0007003-0003 L0007003-0004 L0007003-0005 L0007003-0006 L0007003-0007 L0007003-0008 Container C0129216 C0129217 C0129218 C0129219 C0129221 C0129222 C0129223 C0129224 Matrix LIQUID LIQUID LIQUID LIQUID LIQUID LIQUID LIQUID LIQUID Login Fraction Water Samples Sample Outfall 001 Effluent Water Outfall 001 Effluent Dup Water Outfall 001 Effluent Low Spike (10 ppb) Water Outfall 001 Effluent High Spike (100 pbb) Water Field Control/Travel Blank Water Field Control/ Travel Blank Low Spike (10 ppb) Water Field Control/Travel Blank High Spike (100 ppb) Water Equip Blank Date SamDled 12/13/2005 12/13/2005 12/13/2005 12/13/2005 12/13/2005 Date Due 12/25/2005 12/25/2005 12/25/2005 12/25/2005 12/25/2005 12/25/2005 12/25/2005 12/25/2005 Login Reviewed By: Date/Time: /oL 12/15/2005 Login.rpt 0010 Report Version: Dec 13 2005 1:43PM Page 2 of 2 Instance: R0214957 R0214957 aceA nalytical' /Section A ' Required Client Information: Company 3M B r 4 ss Address Section B Required Project Information: Report To: Copy To: CHAIN-OF-CUSTODY / Analytical Request Document The Chain-of-Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section C Invoice Information: Attention: Company Name: Address: NP0ES UST Page: / of / 896768 REGULATORY AGENCY GROUNDWATER RCRA DRINKING WATER ^ Other Email To: Purchase Order No.: Pace Quote Reference: Fax Requested Due Date/TAT: ffiS T S L Project Number: w F t a n t Pace Project Manager: Perno Profile #: ftrf LAfi fefM Atf - ft _ _. ^ Valid Matrix Codes S e c tio n D Required Client Information m a t r ix code DRINKING WATER DW SAMPLE ID WATER WASTE WATER PRODUCT WT WW P SOIl/SOUD SL One Character per box. OIL OL (A-Z, 0-9 /.- ) WIPE AIR WP AR Samples IDs MUST BE UNIQUE OTHER OT TISSUE TS LL O 71 3 *i\ qirvi Le# V3 / 3 O n tfA u . 00[ Ol SL 4 IS U<iieO J4l < i/* 3 3 CL lu.5O f-tl UjO $ wit/ u IvkJ COLLECTED COMPOSITE START COMPOSITE END/GRAB DATE TIME DATE TIME 5 V 1 W oM l*fyfloS c ftH S Sg O ol M # )o s cR H S f iC i.b t g \ \ r o \ / f 35 *i*k x T te u il W -P 0y\ fe L /r * ve! lu tx u m ?Z3 * r o?3o Additional Comments: C t\/o rirtt- W e T ^ % jR E L IN Q U IS H E D B Y / A F F IL IA T IO N D A TE I TIM E A C C E P T E D BY / A F F IL IA T IO N | D A T E | T IM E SAMPLE CONDITION SEE REVERSE SIDE FOR II ORIGINAL ALLQ020rev.3,31 Mar05 Instructions for completing Chain of Custody (COC) , I. Section A and B: Complete all Client information at top o f sheet: company name, address, phone, fax, contact (the person to contact if there are ' questions, and who will receive the final report.), e-mail address (if available), PO#, Project Name and/or Project Number as you would like to see it appear on the report. , ; > 2. Section C: Invoice Information: Billing information is included in this section. This information should include the name and address of the person receiving the invoice. 3. Quote Reference should be completed if a quotation was provided by Pace Analytical. The Project Manager, and Profile No. will be completed by Pace Analytical Services. ,,. . ' .` 4. Site Location: A separate COC must be filled out for each day of sample collection. Record the two letter postal code tor the US state in which the samples were collected. ' I ' 5. Regulatory Agency : List the program that is guiding the work to ensure proper regulations are followed. 6. Section D: Complete a Sample Description in the "SAMPLE ID' section as you would like it to appear on the laboratory report. The following information should also be included: the sample matrix, sample type (G (grab) or C (composite). When collecting a composites, the start time and end time should be documented in the respective boxes. The collection time' for a grab (G) sample should be entered in the boxes marked `Composite End/Grab'), Sample temp at collection (if required by state), the total number o f containers, and preservative usfcd. ; 1' ' ' ' 7. Mark if the sample was filtered in the field by marking Y or N in Filtered' row by the Analysis requested. . ' :0" 8. Requested Analysis: List the required analysis and methods on the lines provided and place a check ih.the column jtbr. the samples requiring the J analysis. Additional comments should be referenced in the bottom left hand comer or include attachments fo/extehded lists;of parameters. . 9. The sampler should print their name in the space provided and sign their name followed by the date of the sampling"event at the. bottom o f the COC in the spaces designated f o r `SAMPLER NAME AND SIGNATURE'. > * ; 10. When relinquishing custody of the samples to a representative of the laboratory or other organization, indicate the Item Numbers o f those samples being transferred; sign relinquished by, date and time, and include your affiliation. im p ortan t Note: Standard Turnaround Time is 2 Weeks/10 business days. Results will be delivered by end o f business, on the date due unless other arrangements have been made with your project manager. * . Special Project Requirements such as Low Level Detection Limits or level of QC reported must be included on the chain of custody in the Additional Comments section. .. C .. ' ' C 1 v' c ace A n a lytica l' /Section A 1Required Client Information: ComPany3 ^ ) T Address ^ SS Email To: i Section B Required Project Information: Repf r t r . K Y > Copy To: Purchase Order No.: CHAIN-OF-CUSTODY / Analytical Request Document The Chain-of-Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section C Invoice Information: Attention: i Company Name: Address: Pace Quote Reference: I I NPDBS UST Page: / of / f t ' 896768 REGULATORY AGENCY GROUNDWATER DRINKING WATER RCRA f Other O A D IL G IN G M I GM N GNC O H D SC G W I rfrbH ER F E ? / ) 9 - ? 0 - S 3 f f A Fax Requested Due Date/TAT: { S S f S L O u t A . o / F c n t Pace Project Manager: H Project Number: y p-oS - O i*-? V Section D Required Client Information SAMPLE ID One Character per box. (A-Z, 0-9 /.-) Samples IDs MUST BE UNIQUE LL OO i n fA k iU boli MATRIX C0D| DRINKING WATER DW WATER WT WASTE WATER WW PRODUCT P SOIL/SOLID SL OIL OL WIPE WP AIR AR OTHER OT TISSUE TS > 11 ih WU/ mS O0\ u< iO 33 COLLECTED COMPOSITE START COMPOSITE END/GRAB DATE TIME 0?<t DATE TIME *s O W S' V /Ik l Itin jo i P i/fto i HI H- Z i oo LL Oq I P|/3lO'i llfth fT o l i S Preservatives f cr^Vr?) Y W j t l an\ < 0 l /Tftf B k.lt l ~ l l C ' C>i f. As t/**X LW H *r itlu -k r ?30 Additional Comments: v MaiTjA-W C.r{i '3 c M tK .rs t SEE REVERSE SIDE FOR I F i A aJ0 6 r * ( j o .e ? V UCTIONS R E LIN Q U ISH ED BY / AFFILIA TIO N DATE I TIME ! \d 5 x i vj t h A / M k SAM PLER N A M E A N D SIG N ATU R E A C C E P T E D B Y / A F'-T LIA T IO N I D A TE I TIM E SAMPLE CONDITION Z 'w m f a s z *N> > z >, <> 3I E CD I= ALLQ020rev.3,31 Mar05 s 'V - %- - 1! ' s.i*~ Instructions for completing Chain of Custody (COC) ' \\ : 0 0 Y $ O n c tio n A and B: Complete ail Client information at top o f sheet: company name, address, phone, faxcontact (the person to contact if there are questions, and who will receive the final report.), e-mail address (if available), PC#, Project Name and/or Project Number as you ^vould like to see it appear on the report. o 4 '\/\i i r I 9/* ,kj 'j'i 2. Section C: Invoice Information: Billing information is included in this section. This information should include the name and address o f the person , receiving the invoice. * 3. Quote Reference should be completed if a quotation was provided by Pace Analytical. The Project Manager, and Profile No. will be completeij. bv '> Pace Analytical Services. ,. - .. .,, - > A A a r- ^^ ^ `` ' .I ' V ~ <t "V 4- Site Location; A sepaKhe COC must be filled out for each day of sample collection. Record the jjwo letter postal code for the US state in which f ile , ,, samples were collected. f _ "' 4 .1 ; '' j . '' . i; ' ; - " ." 5. RegulatprV AgencT: Irist the program that is guiding the work to ensure proper regulations are followed. , . 6 :... Section D: Complete a Sample Description in the "SAMPLE ID' section as vou would like it to appear on the laboratory report. The following information should also be included: the sample matrix, samplsGype (G (graj>) or C (cpmp^iW)3 VVl^qveplieiting a!y^prjsjtcj tfieTitaiCtiJtH^aftjdignd timtj should be documented in the respective boxes. The collection time for a grab (Q) sample shpuidiie. entered jn the bpxes marked `CJpom^poossiitte. End/Grab'), Sample temp at collection (if required by state), the'iotal numbet o f eontahrsTand pkrsdntivd fised . T ) i ""'jo P !' T,i 1 J '' '1 ' f e.> V"`:~t t i V ' J .-A fv4 *k,,0 7. Mar|< if the sample was filtered in the field by parking_Y or^ in 'Filtered1, rqw by the AnaLysisr^nested. \ . i > , - T ; - V : . ,-y 8. Reqjjeited Analysis: l ast the required analysis and methods on the lines'provided and places' cheek" ihitbe columh to^tfi&'^iHpleis'iwi|iHfihgithe) 4 1 analysis. Additional comments should be referenced in the hattorpTeft hand cOrtrcror inchide attachments.fijV`exJeni^d\liLsmi\pai'a)'nc^rs^-, l' i ` _ i ! .i , _: _ __ y. ., v , . , i v . y , '. a Theisatnpler should print their naiiie in the space provided and sign their name followed by the date oi^he'S^npltng^eveiif^fhie^fe'Httiirh of^hdC uC in the Spaces designated for `SAMPLER NAME |\N|>NKTNAT-URf7,T A--: <\ -Ki .! ! .; : ; : : h : : : ; : ' \ ! \ ;v : ;; ;i > 10. 'Whtjn relinquishing custody pt the samples to a representative of,the laboratory or other organization, indicate the Item Numbers of those samples being transferred; sign relinquished by, date and time, and include your affiliation. ( !j : i,! 1 !! ( ! .; : : ' .I ` ' 1 \ i : : .i: ', -mu 'Important Note: : ; . ,j ' .r ; ;; 'j ; : .:' !1 ' !_ ' Standard Turnaround Time is 2 Weeks/10 business days. Results will be delivered by end ofbusiness oij tbq date due unless other arrangements have been mafie vvifh^yourproject,manager. ,, T ^ ^ V* f; . ' .1 -T, Special Project Requirem ents such as Low Level Detection Limits or level of QC reported must be iri^ludied on .the chain of custody in the Additional Comments section. '< --j ^ j I o m e Analytical* [Section A ' Required Client Information: Company3 ^ ) Address if S S Email To: . CHAIN-OF-CUSTODY / Analytical Request Document The Chain-of-Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section B Required Project Information: RePM r . K e f t Copy To: ttv u ^ fe + ro ie a Purchase Order No.: Section C Invoice Information: Attention: Company Name: Address: Pace Quote Reference: NPDES UST Page: / of / .. 896768 REGULATORY AGENCY GROUNDWATER DRINKINGWATER RCRA W Other S'~F LOG-'---- : GA DIL DIN noH nsc nwi QMI MN DNC iXother Requested Due Date/TAT: fcqtAg g $ E 5 L o u V f A t u o / Pace Project Manager: / ,Project Number; S /,/. WoS- 0 T 7___________________________________ D a tT e V ^ I* ' 9 Section D Required Client Information MATRIX CODI SAMPLE ID WTDRINKING WATER DW WATER WASTE WATER WW PRODUCT P SOIL/SOLID SL One Character per box. OIL OL (A-Z, 0-9 /.-) WIPE AIR WP AR Samples IDs MUST BE UNIQUE OTHER OT TISSUE TS IM S o V f * LL O 0 \ UA ' ' W3 p wk/ COLLECTED Io lwagy COMPOSITE START COMPOSITE END/GRAB DATE TIME DATE ^ 7 C ^ 0 * T FA oo 031 Ff FT Ivj-T L. loJ 33 09V o9b f a ieU ODl kjtj i&jy l-'lw h '*' (/W S Preservatives 5/fr <-*s 1rI ~frfi / ? /< S 6 f t flC Hk,A h ! j t u ^ i (fut L ?/<3? Pk-tl t / i # * r fi3)0^ f3 Additional Comments: C.kf(K '^ E - M a it'iA -t" W i X ^ % R ELIN Q U ISH ED B Y /A F F IL IA T IO N 1 D A T E ] TIME iA C C E P T E D BY / A F F IL IA T IO N D A TE , T IM E SAMPLE CONDITION ct\f(K rv< . Pi A aP 6 f a ( } SEE REVERSE SIDE FOR UCTIONS ALLQ020rev.3.31 Mar05 Instructions for completing Chain of Custody (COC) \; 8 3 y 8 e ^ t! ^ A a "JdB ,: Complete all Client information at top o f sheet: "company name, address, phone, fax, tonfiact*(the person to contact if there are ^questions, and who wijl receive,the final report.), e-mail address (if available), PO#, Project Name and/or Project Number as you would like tcvsee it- appear on the report \\t 2. Section C: Invoice Information: Billing information is included in this section. This information should include the name and address o f the person t: receiving the invoice.,-. , 'A 1 3. Quote Reference should be completed T7a quotation was provided by Pace Analytical. The Project Manager, and Profile No. will be completed by , \ Pace Analytical Services..-!. - >.- ' ^ ' *' ' 1 4 ' ~ 1 r,,. , .. .*j, / a -t-*/-. 4 . Site Locations A separate COC must be filled Out ibr each day of sample collection. Record the two letter postal code for the US state in which the samples were collected. !y ; V\ ' d ,M j j, 01 7 f t . 0 5. RegulatorVAgencY: lis t tire progfam that is guiding the work to ensure proper regulation^are followed, c;: r . 6. Section D: Complete a Sample Description iriThe "AMPLE'ID' section as you would like it to appear on the laboratory' report. Tire following 7. Maijc if the sample w as filtered in the field by niarkfng Y o rN in, Filtered' row by the Analysis .rjpjju^: M : /" ! 8. ReqUegted Analysis: List the required analysis and methods on the lines provided and placeH chtjek jftktie columrifof the fiahiplek requiring-'the1<1 analysis. Additional comments should be referenced in the bottom left hand carter or includd attachments .for`exidnded )lii^.fgparametcr% >. v- ^ 1 | . 11 1! ^ \_ ' 1i ; ' ' \ \ . 1 .t S' 9. The*sajnpler should print their name in the 'spake provided and sign their name followed bv the datte'ohthe samplmg'evenf dithebbtforn ofthd fetjflc in the Spaces designated for `SAMPLER NAME jVN)j SIGNATURE'. - i C? v"-| , ' 10. When Relinquishing custody |>fthe saipples to a!representative o f the laboratory or other organize ion. indicate the Item Numbers o f those ampie) being transferred; sign relinquished byt date and tin|e, and include your affiliation. j ' , !' | , ; !:| !j | | : j | j ; , !! ; : ; l ' i i : 1 j | \ *Important)Npte: ` ! ' : > \ { ' [ ! \ \ Standard Turnaround Time is 2 Weeks/lO business days. Results will be delivered hv end ,j^ ln|siness op tifo date.-due unless other arrangements, have been made with, your project manager. \ . ., 1 i `l " i, . - <j J I", V jy j Special Project Requirements such as Low Level Detection Limits or level of QC reported must;be in^ludjed on the ,chain of custody in the Additional .Comments section. - i__ ' ___ L ace A n a lytica l* /Section A Required Client Information: ComPany 3 Address 0 T ^ SS Email To: CHAIN-OF-CUSTODY / Analytical Request Document The Chain-of-Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section B Repor^^). Copy To: - tV v ^ lfO '^ Purchase Order No.: Section C Invoice Information: Attention: Company Name: Address: Pace Quote Reference: Page: / of / NPDES UST 896768 REGULATORY AGENCY GROUND WATER RCRA DRINKING WATER K Other SITE LOCATION GA GIL GIN GOH G SC G W I GMI GMN GNC &THER * ^ Requested Due Date/TAT: Ou VTa LU Project Number: 00/ FCQXPace Project Manager: s, PaC-e r . u f f l g r t f L 1^05 - 0 7 -? y Section D Required Client Information SAMPLE ID Valid Matrix Codes m a t r ix code DRINKING WATER DW WATER WT WASTE WATER WW PRODUCT P SOIL/SOLID SL a. u0j*S0, wUjOr COLLECTED One Character per box. (A-Z, 0-9 /.-) OIL WIPE AIR OL WP AR $3ft? COMPOSITE START COMPOSITE END/GRAB Samples IDs MUST BE UNIQUE OTHER TISSUE l l 001 S E ? u J : OT MJMTS 3 h 1 tm W k/ DATE TIME /W ot <5 DATE Oct - 0 0 { F ( I 1t&t* lie t ifS > 3 n kW o9*/S (fin s CHLI y- z g o5 0 3o o 04 \O 0 f M w.< a ) w ij fr/olov yvs o 9 9 _ L* Oo { f M l 4 - C ' . K < 0 t W 3 \/r.r* f l fik t*N K # KP I // L C * (7>q f a ;/ j T t t V t t>tt 'll . < 7 4 '35 Ci J ? / < r3 6 / f^ A W |/i3 8 w f tsl&ju? y i > o rn S ufi!fa'* d?30 Preservatives Additional Comments: C M ofA ^ F*yt 4 G /'aG) SEE REVERSE SIDE FOR UCTIONS R E LIN Q U ISH ED B Y / AFFILIATIO N DATE ! TIM E ! ACCEPTED BY / AFFILIATIO N L i / Lu I D A T E ! TIM E i SAMPLE CONDITION 5 I f if a % kzZ ~ W f f / sD ^fE Signed (I z ? >, 21 v> I ALLQ020rev.3,31 Mar05 Instructions for completing Chain of Custody (COC) 8 C ~ 3 ' *Section A and B: Complete all Client information at top of sheet: company name, address, phone, fax, contact (the person to contact if there are ' ` ' questions, and who will receive the final report.), e-mail address (if available), PO#, Project Name and/or Project Number as you would like to see it appear on the report. ./ .. 2. Section C: Invoice Infonnation: Billing information is included in this section. This information should include the name and address of the person receiving the invoice. 3. Quote Reference should be completed if a quotation was provided by Pace Analytical. The Project Manager, and Profile No. will be completed by Pace Analytical Services. 4. Site Location: A separate COC must be filled out for each day of sample collection. Record the two letter postal code for the US state in which the samples were collected. * 5. Regulatory Agency: List the program that is guiding the work to ensure proper regulations are followed. 6. Section D: Complete a Sample Description in the "SAMPLE ID' section as you would like it to appear on the laboratory report. The following information should also be included: the sample matrix, sample type (G (grab) orC (composite). When collecting a composite, the start time and end time should be documented in the respective boxes. The collection time for a grab (G) sample should be entered in the boxes marked `Composite End/Grab'), Sample temp at collection (if required by state), the total number o f containers, and preservative used. ' 7. Mark if the sample was filtered in the field by marking Y or N i n `Filtered' row by the Analysis requested. 8. Requested Analysis: List the required analysis and methods on the lines provided and place a check ini(he column for the samples requiring the analysis. Additional comments should be referenced in the bottom left hand comer or include attachments for extended lists o f parameters. 9. The sampler should print their name in the space provided and sign their name followed by the date of the sampling event at the bottom o f the COC in the spaces designated f o r `SAMPLER NAME AND SIGNATURE'. 10. When relinquishing custody o f the samples to a representative o f the laboratory or other organization, indicate the Item Numbers o f those samples being transferred; sign relinquished by, date and time, and include your affiliation. *Important Note: Standard Turnaround Time is 2 Weeks/10 business days. Results will be delivered by end o f business on the date due unless other arrangements have been made with your project manager. Special Project Requirements such as Low Level Detection Limits or level of QC reported must be included on the chain o f custody in the Additional Comments section. : cA. 11/28/2005 Project: E05-0774 3M ENVIRONMENTAL LABORATORY Preliminary/Unauthorized Report Page 1 o f 4 Requester: Schnobrich, Dana M (223-1N-08) Department: 530711 Project Number: 0022674449 Date Received: 11/28/2005 Project Description: Decatur Outfall 001 FC Monitoring Quarterly Comments: Completion Date: Project Lead: Kent Lindstrom Phone Number: 651-778-5352 Email Address: krlindstrom@mmm.com Statement o f A ccuracy:_________________ ______________________________ Project Results/Activitv Pace Field Sampling Event 3M Sam ple N u m b er______Sam pled D ate E05-0774-91431 12/13/2005 LAB EXYGEN Analytical Method LCMS E05-0774-91432 12/13/2005 LAB EXYGEN Analytical Method LCMS Sam ple D escription____________ O utfall 001 Effluent - Composite Components PFOS PFHS PFBS FOSA PFBAmide MeFBSE-OH C4 acid C5 acid C6acid C7 acid PFOA C9 acid CIO acid C ll acid C12 acid Result O utfall 001 Effluent - Com posite Duplicate Components PFOS PFHS PFBS FOSA PFBAmide MeFBSE-OH C4 acid C5 acid C6 acid C7 acid PFOA C9 acid CIO acid C ll acid C12 acid Result RL Qualifier RL Qualifier 0012 11/28/2005 3M ENVIRONMENTAL LABORATORY Preliminary/Unauthorized Report Project: E05-0774 (cont) 3M Sam ple N u m b er______ Sam pled D ate______ Sam ple D escription__________________________________ E05-0774-91433 12/13/2005 O utfall 001 Effluent Comp -1 0 PPB Low Spike LAB EXYGEN Analytical Method LCMS E05-0774-91434 12/13/2005 Component PFOS PFHS PFBS FOSA PFBAmide MeFBSE-OH C4 acid C5 acid C6 acid C7 acid PFOA C9 acid CIO acid CU acid C12 acid Result O utfall 001 Effluent Comp -100 PPB High Spike RL_ LAB EXYGEN Analytical Method LCMS Components PFOS PFHS PFBS FOSA PFBAmide MeFBSE-OH C4 acid C5 acid C6 acid C7 acid PFOA C9 acid CIO acid Cl 1 acid C12 acid Result RL E05-0774-91435 12/13/2005 Field Control/Travel Blank LAB EXYGEN Analytical Method LCMS Components PFOS PFHS PFBS FOSA PFBAmide MeFBSE-OH C4 acid C5 acid C6 acid C7 acid PFOA ResuJ] 0013 Page 2 of 4 Qualifier Qualifier Qualifier 11/28/2005 3M ENVIRONMENTAL LABORATORY Preliminary/Unauthorized Report Project: E05-0774 (cont) 3M Sam ple N u m b er______Sam pled D ate Sam ple D escription__________________ E05-0774-91435 (cont.) 12/13/2005 Field Control/Travel Blank LAB EXYGEN Analytical Method LCMS (cont.) E05-0774-91436 12/13/2005 Components C9 acid CIO acid C ll acid C12 acid Result Field Control/Travel Blank Low Spike LAB EXYGEN Analytical Method LCMS Components PFOS PFHS PFBS FOSA PFBAmide MeFBSE-OH C4 acid C5 acid C6 acid C7 acid PFOA C9 acid CIO acid C ll acid C12 acid Result E05-0774-91437 12/13/2005 Field Control/Travel Blank High Spike LAB EXYGEN Analytical Method LCMS E05-0774-91438 12/13/2005 Components PFOS PFHS PFBS FOSA PFBAmide MeFBSE-OH C4 acid C5 acid C6 acid C7 acid PFOA C9 acid CIO acid C ll acid C12 acid Equipment Blank Result LAB EXYGEN Analytical Method LCMS Comnonents PFOS PFHS PFBS FOSA PFBAmide Result 0014 Page 3 of 4 RL Qualifier RL Qualifier RL Qualifier RL Qualifier 11/28/2005 3M ENVIRONMENTAL LABORATORY Preliminary/Unauthorized Report Project: E05-0774 (coot.) 3M Sam ple N u m b er_____ Sam pled D ate E05-0774-91438 (cont.) 12/13/2005 LAB EXYGEN Analytical Method LCMS (cont.) Sample Description Equipm ent Blank Components MeFBSE-OH C4 acid C5 acid C6 acid C7 acid PFOA C9 acid CIO acid C ll acid C12 acid Result Page 4 of 4 RL Oualifier 0015 Sample.Sa Test.Test_ Test.Replic Test.Analy! Result.Nan ResultRes Result.Entr R esultAttri Result.Unit 91431 980467 1 LCMS WVPFOS N NG/ML 91431 980467 1 LCMS_WV PFHS N NG/ML 91431 980467 1 LCMS WVPFBS N NG/ML 91431 980467 1 LCMS WVFOSA N NG/ML 91431 980467 1 LCMS_WV PFBAmide N NG/ML 91431 980467 1 LCMS WV MeFBSE-C N NG/ML 91431 980467 1 LCMS WV C4 acid N NG/ML 91431 980467 1 LCMS_WV C5 acid N NG/ML 91431 980467 1 LCMS_W VC6acid N NG/ML 91431 980467 1 LCMS WV C7 acid N NG/ML 91431 980467 1 LCMS_WV PFOA N NG/ML 91431 980467 1 LCMS_WV C9 acid N NG/ML 91431 980467 1 LCMS W VC10 acid N NG/ML 91431 980467 1 LCMS WVC11 acid N NG/ML 91431 980467 1 LCMS_WVC12 acid N NG/ML 91432 980468 1 LCMS WVPFOS N NG/ML 91432 980468 1 LCMS_WV PFHS N NG/ML 91432 980468 1 LCMS WVPFBS N NG/ML 91432 980468 1 LCMS WVFOSA N NG/ML 91432 980468 1 LCMS WV PFBAmide N NG/ML 91432 980468 1 LCMS WV MeFBSE-C N NG/ML 91432 980468 1 LCMS_WV C4 acid N NG/ML 91432 980468 1 LCMS_WV C5 acid N NG/ML 91432 980468 1 LCMS WV C6 acid N NG/ML 91432 980468 1 LCMS WV C7 acid N NG/ML 91432 980468 1 LCMS WVPFOA N NG/ML 91432 980468 1 LCMS WV C9 acid N NG/ML 91432 980468 1 LCMS WVC10 acid N NG/ML 91432 980468 1 LCMS_WVC11 acid N NG/ML 91432 980468 1 LCMS VWC12 acid N NG/ML 91433 980469 1 LCMS WVPFOS N NG/ML 91433 980469 1 LCMS WVPFHS N NG/ML 91433 980469 1 LCMS WVPFBS N NG/ML 91433 980469 1 LCMS_WV FOSA N NG/ML 91433 980469 1 LCMS WV PFBAmide N NG/ML 91433 980469 1 LCMS WVMeFBSE-CN NG/ML 91433 980469 1 LCMS WV C4 acid N NG/ML 91433 980469 1 LCMS_WV C5 acid N NG/ML 91433 980469 1 LCMS_WV C6 acid N NG/ML 91433 980469 1 LCMS_WV C7 acid N NG/ML 91433 980469 1 LCMS WVPFOA N NG/ML 91433 980469 1 LCMS WV C9 acid N NG/ML 91433 980469 1 LCMS WVC10 acid N NG/ML 91433 980469 1 LCMS WVC11 acid N NG/ML 91433 980469 1 LCMS WVC12 acid N NG/ML 91434 980470 1 LCMS_WV PFOS N NG/ML 91434 980470 1 LCMS WVPFHS N NG/ML 91434 980470 1 LCMS_WV PFBS N NG/ML 91434 980470 1 LCMS_WV FOSA N NG/ML 91434 980470 1 LCMS WV PFBAmide N NG/ML 91434 980470 1 LCMS_WV MeFBSE-C N NG/ML 0016 91434 91434 91434 91434 91434 91434 91434 91434 91434 91435 91435 91435 91435 91435 91435 91435 91435 91435 91435 91435 91435 91435 91435 91435 91436 91436 91436 91436 91436 91436 91436 91436 91436 91436 91436 91436 91436 91436 91436 91437 91437 91437 91437 91437 91437 91437 91437 91437 91437 91437 91437 91437 980470 980470 980470 980470 980470 980470 980470 980470 980470 980471 980471 980471 980471 980471 980471 980471 980471 980471 980471 980471 980471 980471 980471 980471 980472 980472 980472 980472 980472 980472 980472 980472 980472 980472 980472 980472 980472 980472 980472 980473 980473 980473 980473 980473 980473 980473 980473 980473 980473 980473 980473 980473 1 LCMS WV 04 acid N 1 LCMS WV C5 acid N 1 LCMS WV C6 acid N 1 LCMS VW C7 acid N 1 LCMS WVPFOA N 1 LCMS_WV C9 acid N 1 LCMS WVC10 acid N 1 LCMS WVC11 acid N 1 LCMS_WV C12 acid N 1 LCMS WVPFOS N 1 LCMS WVPFHS N 1 LCMS WVPFBS N 1 LCMS WVFOSA N 1 LCMS WV PFBAmide N 1 LCMS_WV MeFBSE-C N 1 LCMS WV C4 acid N 1 LCMS_WV C5 acid N 1 LCMS WV C6 acid N 1 LCMS WV C7 acid N 1 LCMS WVPFOA N 1 LCMS_WV C9 acid N 1 LCMS WVC10 acid N 1 LCMS_WV C11 acid N 1 LCMS WVC12 acid N 1 LCMS_WV PFOS N 1 LCMS WVPFHS N 1 LCMS WVPFBS N 1 LCMS WVFOSA N 1 LCMS_WV PFBAmide N 1 LCMS_WV MeFBSE-C N 1 LCMS_VW C4 acid N 1 LCMS_VW C5 acid N 1 LCMS_WV C6 acid N 1 LCMS_WV C7 acid N 1 LCMS WVPFOA N 1 LCMS WV C9 acid N 1 LCMS WVC10 acid N 1 LCMS WVC11 acid N 1 LCMS_WV C12 acid N 1 LCMS_WV PFOS N 1 LCMS WVPFHS N 1 LCMS_WV PFBS N 1 LCMS_WV FOSA N 1 LCMS WV PFBAmide N 1 LCMS WV MeFBSE-C N 1 LCMS_WV C4 acid N 1 LCMS_WV C5 acid N 1 LCMS WV C6 acid N 1 LCMS_WV C7 acid N 1 LCMS_WV PFOA N 1 LCMS WV C9 acid N 1 LCMS WVC10 acid N 0017 NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML 91437 91437 91438 91438 91438 91438 91438 91438 91438 91438 91438 91438 91438 91438 91438 91438 91438 980473 980473 980474 980474 980474 980474 980474 980474 980474 980474 980474 980474 980474 980474 980474 980474 980474 1 LCMS_WV C11 acid N 1 LCMS WVC12 acid N 1 LCMS_WV PFOS N 1 LCMS WVPFHS N 1 LCMS_WV PFBS N 1 LCMS_WV FOSA N 1 LCMS WV PFBAmide N 1 LCMS_WV MeFBSE-C N 1 LCMS_WV C4 acid N 1 LCMS_WV C5 acid N 1 LCMS WV C6 acid N 1 LCMS WV C7 acid N 1 LCMS_WV PFOA N 1 LCMS VW C9 acid N 1 LCMS_WV C10 acid N 1 LCMS WVC11 acid N 1 LCMS WVC12 acid N NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML NG/ML OOS Result.Attri Result.Has Attributes o o o F e d E x . 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Q FedEx ^^pOther Tube 6 Special Handing 1r -1 no to Weilu tar I I ferifefeeONLYforFedExPriority I__ I at FedEx Location OvernightFedEx2Dsy,FsdEx ID e/Fraigtit, and FedEx20ay Freight safestZSPcodes. FedExfirs tOvernight Domdtti | ! Vte I I Yds I--- 1 Asp* aasdieo I----1 Sfet|Mi's[ Shipper'sOeclarstion. notrequin is goods(includingdryice) cannotbe shippedin FedExpackaging. U MU&Majr at FedEx Locatori Avaitatafe ONLYter FedEx Priority Ovenifehl id radfei IQey rTihytee 1-- > tfyce,9,N low _ J^l CygeXhcratt^# l ** I I fat City ^ ___C o t _________ state f f t ___ Z|P_____ / ^ | 8540 9614 7422 8 NEW Residential D elivery Signature Options if you require asignature,checkDirectorIndirect I-- i No Signature -- .I uDriereccit_S,,ignature __ Required __ "(" > .. -- Pacing* maybeleftwiUi- -- a j* w in tardata* outobtaining asignature fordakwry. Rev. Date5/05Part#15828l1994-2005FedExPRlNTEDIN U.S.A. SHY Indirect Signature IfnoonatsevaSabie at redpferik address,anyone ata neighboring addressmay signfordrivery. foe appties. SSP! 1