Document 87nBwnB4n1DmKzo1n5xn4JxZ

U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET Form Approved OM0 NO. 44-R1387 Required under USDL Safety and Health Regulations for Ship Repairing, ______ Shipbuilding, and Shipbreaking (29 CFR 1915, 1916, 1917)______August, 1977 SECTION 1 MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. PPG Industries* Inc* address (Number, Street, City, State, and ZIP Code) One Gateway Center, Pittsburgh, CHEMICAL NAME AND SYNONYMS Sodium Hydroxide CHEMICAL FAMILY Alkali PA . 15222 (304) 843-1300 TRADE NAME AND SYNONYMS ,, Liquid Caustic Soda* 50% FORMULA NaOH SECTION II - HAZARDOUS INGREDIENTS PAINTS. PRESERVATIVES. & SOLVENTS TLV % (Unit*! ALLOYS AND METALLIC COATINGS PIGMENTS BASE METAL CATALYST VEHICLE SOLVENTS ADDITIVES ALLOYS METALLIC COATINGS FILLER METAL PLUS COATING OR CORE FLUX OTHERS OTHERS HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS. OR GASES Sodium Hydroxide TLV % (Unit*) TLV % (Unit*) 50 2mg/M^ SECTION III - PHYSICAL DATA BOILING POINT (P.) 5Q% ^ VAPOR PRESSURE (mm Hg.) VAPOR DENSITY (AIR-1) SOLUBILITY IN WATER 288-298 <1 ___ N/A____ SPECIFIC GRAVITY (HjO-l)06gOF PERCENT, VOLATILE BY VOLUME (%) EVAPORATION RATE ( *D Appreciable(>10%) 347 g/lOOe water @ 100C appearance and poor Water . white t0 slightly turbid liquid, no odor. 1.525 N/A....... N/A SECTION IV - FIRE AND EXPLOSION HAZARD DATA Fi_ASH POINT (Method used) None EXTINGUISHING MEDIA N/A SPECIAL PIPE FIGHTING PROCEDURES N/A FLAMMABLE LIMITS n/a Lei UNUSUAL FIRE AND EXPLOSION HAZARDS None PAGE (1) (Continued on reverse side) Form OSHA-20 R"-M,y7'sL 074462 SECTION V - HEALTH HAZARD DATA THRESHOLD LIMIT value TFPecTToF"ovEWIxROsURE 7. n;/w^ (OSHA) Contact with bodv tissue causes severe burns; eye contact may cause blindness, swallowing can pe ratal, inhalation or mists causes severe irritation oi respiratory tract. EMERGENCY AND FIRST AIO PROCEDURES Contact: Immediately flush eyes or skin with plenty of water for at least 15 minutes. Call a physician. Swallowing: Give large amounts of water to drink and call a physician. DO NOT induce vomiting. stability unstable SECTION VI - REACTIVITY DATA CONDITIONS TO AVOID stable X incompatabiuty iMatcriak to amid) Organic materials, concentrated acids and some metals (see Section IX)--mav cause violent reaction. hazardous decomposition products Ndne hazardous POLYMERIZATION MAY OCCUR WILL NOT OCCUR X CONDITIONS TO AVOID SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO 9E TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Dike area to contain spill. Use vacuum trucks (where practical) to pick up spill for controlled disposal or recovery. Neutralize any remaining materials with dilute acid. Use caution--heat release occurs; could cause violent spattering. WASTE DISPOSAL METHOD . Neutralized solutions should be diluted with plenty of water and flushed to tne sewer. Contact local waste disposal contractor for disposal of unneutralized material. SECTION VIII . SPECIAL PROTECTION INFORMATION respiratory protection (Specify type) , , MIOSH/MSHA-approved mechanical filter type for exposure to mists above TLV ventilation local exhaust X SPECIAL MECHANICAL (Central) OTHER PROTECTIVE GLOVES _ , . Rubber Gloves closeeye protection fitting chemical safety goggles and face shield______________ other protective equipment Rubber apron, rubber boots, plastic hard nat, rvu clothina, eve-wash fountain, safety shower SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING ANO STORING Do not get in eyes, on skin, on clothing; avoid breathing mists; do not take internally; wear protective equipment whenever handling. OTHER PRECAUTIONS Do not store in magnesium, zinc (galvanized), tin, chromium, brass, bronze or aluminum. Maintain storage temperature between 75? and 14QF, in steel equipment PAGE (2) 93).$40 Form OSHA-20 Rv. Miy 72 SL 074463 U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET Form Approval OMB No. 44-R1387 Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 1916, 1917)_______ December, 1977 SECTION 1 MANUFACTURER'S NAME EMERGENCY TELEPHONE NO. PPG Industries, Inc. ADO R ess (Number, Street, City, State, and ZIP Code1 , ,,, One Gateway center, Pittsburgh, PA CHEMICAL NAME AND SYNONYMS Sodium Hydroxide CHEMICAL FAMILY Alkali (304) 843-1300 15222 TRADE NAME AND SYNONYMS Liauid Caustic Soda 73% FORMULA ______________mm__________________________________ SECTION II - HAZARDOUS INGREDIENTS PAINTS, PRESERVATIVES, & SOLVENTS % TLV (Units) ALLOYS AND METALLIC COATINGS PIGMENTS BASE METAL CATALYST ALLOYS VEHICLE SOLVENTS ADDITIVES METALLIC COATINGS FILLER METAL PLUS COATING OR CORE FLUX OTHERS % TLV (Units) others HAZARDOUS MIXTURES OF OTHER LIQUIDS. SOLIDS, OR GASES __ Sodium Hvdroxide TLV % (Units) 73 ?me/M3 - SECTION III - PHYSICAL DATA BOILING POINT (F.) 73% NaQH VAPOR PRESSURE (mm Hfl.) NaOH VAPOR DENSITY (AfR-1) SOLUBILITY IN WATER 370 <1 N/A SPECIFIC GRAVITY <H2"l>(194/1940F') PERCENT* VOLATILE BY VOLUME (%) EVAPORATION RATE ( -1) 1.706 N/A N/A Appreciable(">10%) 347 g/lOOg water @ 100C appearanceanoodor Water - white to slightly turbid liquid, no odor. SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT (M*tfto4 u$*d) EXTINGUISHING MEDIA None SPECIAL FIRE FIGHTING PROCEDURES N/A N/A flammable limits N/A Lai Ual UNUSUAL FIRE AND EXPLOSION HAZARDS None PAGE (1) (Continued on reverse side) Form OSHA-20 R*v. May 72 SL 074464 SECTION V HEALTH HAZARD DATA threshold limit value 2 mg/M3 (OSHA) effects of overexposure Contact with body tissue causes severe burns; eve contact mav cause blindness, swallowing can be fatal. Inhalation of mists causes severe irritation of respirators tract.---------------------------------------------------------------------------------------------------------__-- ------- EMERGENCY AND FIRST AID PROCEDURES Contact: Immediately flush eves or skin with plenty of water for at least 15 minutas. Call a physician. Swallowing: Give large amounts of water to drink and call a physician. DO NOT induce vomiting. STABILITY UNSTABLE SECTION VI - REACTIVITY DATA CONDITIONS TO AVOID STABLE X INCOMPATABIUTV Materials to avoid) organic materials, concentrated acids (see Section IX)--mav cause violent reaction. HAZARDOUS DECOMPOSITION PRODUCTS None HAZARDOUS POLYMERIZATION MAY OCCUR CONDITIONS TO AVOID WILL NOT OCCUR X and some metals SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO 36 TAKEN IN CAS MATERIAL IS RELEASED OR SPILLED Dike area to contain spill. Use vacuum trucks (where practical) to pick, up spill for controlled disposal or recovery. Neutralize any remaining materials with dilute acid. Use caution--heat release occurs; could cause violent spattering. WASTE DISPOSAL METHOD ' ,, , ~ "" ' ' Neutralized solutions should be diluted with plenty of water and flush to the sewer- Contact local waste disposal contractor for disposal of unneutralized material. ____ _____ _____ SECTION VIII * SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (Specify type) NTOSH/MSHA-aooroved mechanical VENTILATION LOCAL EXHAUST MECHANICAL (Central) filter X tvoe for exDOSure to SPECIAL OTHER mists above TLV. PROTECTIVE GLOVES eye protection Close litting cnemical Rubber Gloves safety eoeeles and face shield other protective equipment Rubber apron, ruober boots, plastic nard bat, fvc clothinz, eve-wash fountain, saretv shower. SECTION IX - SPECIAL PRECAUTIONS precautions to as taken in handling and storing Do not get in eves, on skin, on c'nothing; avoid breathing mists: do not take internally; wear protective equipment whenever handling.___________________ _______ OTHER PRECAUTIONS Dc not store in magnesium, zinc (galvanized), tin, chromium, brass, bronze or aluminum. PAGE (2) $P c ? X .*o Maintain storage temperature between 180F and 200F in lined steel equipment Form OSHA-20 R*t. May 72 fcfc*5 ol