Document 85EnkDM31zOaG71470GNaG1oK
P -1 ; 4 /U Z '- 3 1 Z 2 J
AXYS METHOD MLA-031 Rev 01
PFOS S i m
Fon 1AI2
~ PERFLUCffUNATEO SURFACTANT ANALYSIS RETORT
C L IE N T I):
Sampla Collection:
OB-Mar-2005 11.-00
Lab Name: AXYS ANALYTICAL SERVICES
Contract No.:
191
Lab Sample 10:
L7652-27R2
Matrix:
SERUM
Sample Size:
100 mL
Sample Receipt dele: 10-Mar-2QQS
Initial Calibration Dale:
BRACKETING CAL
Extraction Oats: Analysis Date:
21-Apr-2005 22-Apr-2005
Time: 1:37:18
Im liumani ID: LC Column ID:
LC-MSVMS CIB.ZorbaxXDB
Extract Volume (mL): 2
Sampla Daiaflle:
PFSSG_858S047
Injection Volume (jjL): 30 0
Blank Data Filename:
PFSSGJD58S026
Dilution Factor: Concentration Units :
N/A ngML
Multiple CaL data FBenamss:
PFS5G_058S029 PFS5G 0S8SO38 PFS5G_058S050
COMPOUND
LAB FLAG'
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFPaA
PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS
U U
0839 786 1.07 0.488 0.198 0044 0.117 173 112
0312 0.103 00608 00510
00417 0.0168 00079 00102 00588 0.128 0204
387 538 5.73 606 6.40 6.76 304 552 622
LABELED COMPOUND
13C-PFOA 13C-PFDA
LAB FLAG'
SPIKE CONC.
|ng)
120 120
CONC. FOUND
(09)
8.80 9.43
R I*)'
RETENTION TIME
733 536 786 60S
(1) U = notdetected (2) R (%) = Percent recovery
1SS2SPF01_Z>I9.S1S
Approvedby;.
.QA/QC Chemist
MM&2D0S diLnan-jyyy
AXYS /Mvl/\.LVTIOM_ SERVICES LTD u totjir.aM15uaftl c.UMWUStltt(HRSS5S00FU(ttfflttHIll
AXYS METHOD MLA-031 Rev 01
pfos_s i_db
Forai IAO
PERFLUORtNATEO SURFACTANT ANALYSIS REPORT
CUENTiD;
Lab Name: AXYS ANALYTICALSERVICES1
Sample Collection:
08-Mar-200511:00
Contract No.: Matrix: Sample Receipt data: Extraction Dale: Analysis Dale: Extract Volume (mL): Section Votame (pL): Dilution Faeton Concentration Units :
4191 SERUM 10-Um-2005 21-Apr-2D0S 22-Apr-2005 2 300 N/A ng/mL
Time: 1:24:26
Lab Sample ID:
L7652-25R2
Sample Sbe:
100 mL
Initial Calibration Date:
BRACKETING CAL
butnanent ID:
LC-MS/MS
LC Column ID:
C1B, ZobaxXDB
Sample Dotatile:
PFSSGJBS8S046
Blank Data Filename:
PFS5G_058S026
Mutopia Cal. data Filenames:
PFS5GJD58S029 PFS5GJD5BS038 PFS5GJS58S050
COMPOUND
LAB FLAG'
CONC FOUND
DETECTION LIMIT
RETENTION TIME
FFPeA PFHxA PFHpA PFOA PFNA
PFDA PFUnA
PFDoA PFBS PFHxS PFOS
U U
0117 693
112 0.288 0.115 U U 189 102
0.181 0.114 00734 0.0541 00129 00157 0.0159 00377 00519 00749 0171
307 534 5.73 60S 038
500 622
LABELED COMPOUND
13C-PFOA 13C-PF0A
'
LAB FLAG'
SPIKE CONC.
(ng)
120 12.0
CONC. FOUND
(ns)
999 11.7
R fltf
RETENTION TIME
83.2 634 079 006
(1) U = notdetected <2) R (%) =Percent memory
15BZ5FF01_2*.S1S
Approvedby:.
QA/QC Chemist
100S-20BS dd-mm-yyyy
AXY5 ANALYTICAL SERVICES LTD ltd.KBHU.2W5I8USMLVISISUD.IC.UUUVtl3Sm(ISO)US-SIOOMX(2S0)SS-SS11
P-3
Form 1A
A. vXYv So MuErTrHuODTM M.L. A, .-04,2, Rev 0 08
PERFLUORINATED ORGANICS ANALYSIS REPORT
AXYS ANALYTICAL SERVICES
P.O. Box 2219, 2045 MILLS RD. WEST. SIDNEY, B.C., CANADA V8L 3S8 TEL (250) 655-5800 FAX (250) 655-5811
Contract No.:
4191
Lab Sam ple I.D .:
M atrix:
SERUM
Sam ple Size:
Sam ple Receipt Date:
21-Sep-2006
Initial Calibration Date:
Extraction Date:
26-Sep-2006
Instrum ent ID:
Analysis Date:
27-Sep-2006 Tim e: 00:48:24
Column ID:
Extract Volum e (uL):
2000
Sam ple Data Filenam e:
Injection Volum e (uL):
15
Blank Data Filenam e:
Dilution Factor:
N/A
Cal. Ver. Data Filenam e:
Concentration Units:
ng/mL
L9303-3 0.500 mL 26-Sep-2006 LC MS/MS C18 FC6G_399 S: 24 FC6G_399 S: 21 FC6G_399 S: 14
COMPOUND
PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA
LAB FLAG 1
U U
u u
u u
U
U
CONC. FOUND
23.8 1.43 0.905
7.74 40.3
DETECTION LIM IT
0.576 0.544 0.476 0.556 0.556 1.21 0.504 0.512 0.576 1.41 1.29 1.16 0.480
RETENTION T IM E
4:45 5:04 5:24
4:57 5:34
(1) Where applicable, custom lab flags have been used on this report; U = not detected.
Approved b y:___________ H e n r y H uang____________QA/QC Chemist
For Axys Internal Use Only (XSL Template: FC-Form1A.xsl; Created: 27-Sep-2006 13:19:27; Application: XMLTransformer-1.7.13; Report Filename: PFC_FC_LC_PFOA_L9303-3_Form1A_SJ593458.html; Workgroup: WG20188; Design ID: 261 ] These pages are part of a larger report that may contain information necessary for full data evaluation.
Page 1 of 1 (WG20188 - PFC_FC_LC_PFOA_L9303-3_Form1A_SJ593458.html)
P-4
AXYS METHOD MLA-042 Rev 08
Form 1A
PERFLUORINATED ORGANICS ANALYSIS REPORT
AXYS ANALYTICAL SERVICES
P.O. Box 2219, 2045 MILLS RD. WEST, SIONEY, B.C., CANADA V8L 3S8 TEL <250) 655-5800 FAX (250) 655-5811
Contract No.:
4191
Lab Sam ple I.D .:
M atrix:
SERUM
Sam ple Size:
Sam ple Receipt Date:
24-Aug-2006
Initial Calibration Date:
Extraction Date:
20-Sep-2006
Instrum ent ID:
Analysis Date:
23-Sep-2006 Tim e: 01:21:08
Colum n ID:
Extract Volum e (uL):
2000
Sam ple Data Filenam e:
Injection Volum e (uL):
15
Blank Data Filenam e:
Dilution Faeton
N/A
Cal. Ver. Data Filenam e:
Concentration Units:
ng/mL
CLIENT SAMPLE NO Sam ple Collection: 22-Aug-2006 17:55
L9208-2 R 0.500 mL 22-Sep-2006 LC MS/MS C18 FC6G_394 S: 22 FC6G_394 S: 21 FC 6G .394 S: 14
COMPOUND
LAB FLAG 1
CONC. FOUND
DETECTION LIM IT
PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA
U 0.576
U 0.544
u 10.9
u 0.556
14.9 0.556
u 0.468
u 0.504
u 0.512
u 0.576
u 1.41
4.44
1.29
23.6
1.16
u 0.480
(1) Where applicable, custom lab flags have been used on this report; U = not detected.
Approved b y:___________ H e n r y H uang____________QA/QC Chemist
RETENTION T IM E
4:45
4:57 5:34
For Axys Internal Use Only ( XSL Template; FC-Fonrtl A.xsl; Created: 03-0ct-2006 10:15:16; Application: XMLTransfofmer-1.7.13; Report Filename; PFC_FC_LC_PFOA_L9208-2_FoimlA_SJ594693.html; Workgroup: WG20I59; Design ID: 472 ]
These pages are part o f a larger report that may contain information necessary for full data evaluation.
27
Page 1 o f 1 (WG20159 - PFC_FC_LC_PFOA_L9208-2_FormlA_SJ594693.html)
P-5
Form 1A
. . . . ,, ,,,,,, ,, AXYS METHOD M LA-042 Rev 08
PERFLUORINATED ORGANICS ANALYSIS REPORT
AXYS ANALYTICAL SERVICES
P.O. Box 2219, 2045 MILLS RD. WEST, SIDNEY, B.C., CANADA V8L 3S8 TEL (250) 655-5800 FAX (250) 655-5811
Contract No.:
4191
Lab Sam ple I.D .:
M atrix:
SERUM
Sam ple Size:
Sam ple Receipt Date:
21-Sep-2006
Initial Calibration Date:
Extraction Date:
26-Sep-2006
Instrum ent ID:
Analysis Date:
27-Sep-2006 Tim e: 00:19:47
Colum n ID:
Extract Volum e (uL):
2000
Sam ple Data Filenam e:
Injection Volum e (uL):
15
Blank Data Filenam e:
Dilution F ac to r
N/A
Cal. Ver. Data Filenam e:
Concentration Units:
ng/mL
L9303-2 (A) 0.500 mL 26-Sep-2006 LC MS/MS C18 FC6G_399 S: 22 FC6G_399 S: 21 FC6G_399 S: 14
COMPOUND
PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA
LAB FLAG 1
U U u u
u u u u
u
CONC. FOUND
10.5 0.963
6.00 35.2
DETECTION UM IT
0.576 0.544 10.5 0.556 0.556 0.468 0.504 0.512 0.576 1.41 1.29 1.16 0.480
RETENTION TIME
4:45 5:07
4:54 5:31
(1) Where applicable, custom lab flags have been used on this report; U = not detected.
Approved b y:___________ H g I I IT y H U c tn g ____________QA/QC Chemist
For Axys Internal Use Only [ XSL Template: FC-Form1A.xsl; Created: 27-Sep-2006 13:19:27; Application: XMLTransformer-1.7.13; Report Filename: PFC_FC_LC_PFOAJ.9303-2_Form1A_SJ593456.html; Workgroup: WG20188; Design ID: 261 l These pages are part of a larger report that may contain information necessary for full data evaluation.
Page 1 of 1 (WG20188 - PFC_FC_LC_PFOA_L9303-2_Form1A_SJ593456.html)
P-6
AXYS METHOD MLA-042 Rev 08
Form 1A
PERFLUORINATED ORGANICS ANALYSIS REPORT
AXYS ANALYTICAL SERVICES
P.O. Box 2219. 2045 MILLS RD. WEST. SIDNEY. B.C.. CANADA V8L 3S8 TEL (250) 655-5800 FAX (250) 655-5811
Contract No.:
4191
Lab Sam ple I.D .:
M atrix:
SERUM
Sam ple Size:
Sample Receipt Date:
27-Apr-2006
Initial Calibration Date:
Extraction Date:
06-Jul-2006
Instrum ent ID:
Analysis Date:
08-Jul-2006 Tim e: 09:08:11
Column ID:
Extract Volum e (uL):
2000
Sam ple Data Filenam e:
Injection Volume (uL):
15
Blank Data Filenam e:
Dilution Faeton
N/A
Cal. Ver. Data Filenam e:
Concentration Units:
ng/ml
L8363-2 0.500 ml 07-JUI-2006 LC MS/MS C18 FC6G_277 S: 23 FC6G_277 S: 21 FC6G_277 S: 14
COMPOUND
LAB FLA G 1
CONC. FOUND
D E T E C T IO N LIM IT
RETENTION TIME
PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA
U 0.604
U 0.472
u 0.484
1.08 0.532
133 3.07
1.15
0.680
u 0.536
u 0.476
u 0.568
u 1.20
32.7
1.01
155 1.00
u 0.460
4:17 4:45 5:08
4:56 5:33
(1) Where applicable, custom lab flags have been used on this report; U = not detected.
Approved bv:
.... '
QA/QC Chemist
For Axys Internal Use Only { XSL Template: FC FcrmlA xsl. Created: 12-JuI-2006 16:32:12; Application: XMLTransforrner-1.7.4; Report Filename: PFC_FC_LC_PFOA_L8863-2_FonnlA_SJS71307.html; Workgroup: WG19474; Design ID: 332 ]
These pages are part of a larger report that may contain information necessary for full data evaluation
Page 1 of 1 (WG19474 - PFC_FC_LC_PF0A_L8863-2_FormlA_SJ571307.html)
AXYS METHOD MLA-042 Rev 03
pfo s_s i _d u
Form 1A/2
PERFLUORINATED ORGANICS ANALYSIS REPORT
CLIENT ID:
Lab Nome: AXYS ANALYTICAL SERVICES
Sample Collection:
31-Aug-2005 10:32
Contract No.:
4191
M atrix:
SERUM
Sample Receipt date: 01-Sep-2005
Extraction Date:
21-Sep-2005
Analysis Date:
23-Sep-2005
Extract Volume (mL): 2
Injection Volume (pL): 10 0
Dilution Faeton
3
Concentration Units : ng/mL
Time: 1:09:49
Lab Sample ID:
L7932-53 i
Sample Size:
100 1
Initial Calibration Date: 22-Sep-2005
Instrument ID:
LC-MS/MS
LC Column ID:
C IS
Sample Datafile:
FC5G181S056
Blank Data Filename;
FC6G_181S070
Cal. Ver. Data Filename: FC5G_181S04B
CAL VER ID:
PFC-LN-055CS-F
COMPOUND
PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA
LAB
CONC
FLAG ' ' FOUND
DETECTION LIMIT
uo UD O 1 95 D 110 D 2 92 0 1 32 UD UD UD D 20 0 0 lit UD
0 639 0 620 0 626 0618 0 670 0 648 0641 0 638 0 635 0 638 0 645 0 625
RETENTION TIME
4 18 4 65 5 05 5 36
4 80 5 46
LABELED COMPOUND
13C2-PFOA 13C4-PFOS (80) 13C4-PFOS (99) 13C2-PFDA
LAB FLAG
D D D D
SPIKE CONC.
(n9)
120 120 120 12 0
(1) U = not detected; D = dilution data (2) R (% ) = Percent recovery
IB982PF01_1*Js.ss
Approvedby:
CONC. FOUND
(ng)
121 120 12 7 10 8
R (V.)2 RETENTION TIME
101 99 6 106 90 0
4 65 5 46 5 46 5 36
QA/QC Chem ist
2-09-2D0S dd-mm-yyyy
AXYS ANALYTICAL SERVICES LTU f.OH0X221.7015tttUSM.IHSII.. JUKI 1 1 . CUMMvai 351 Ifl 050) <55-5800 MX(250) 4555811
A X YS METHOD MLA-0 42 Rev 03
p ro s si_oia
Form 1A/2
" PERFLUORINATED ORGANICS ANALYSIS REPORT
CLIENT ID: >
Sample Collection:
31-Aug-2005 10:03
Lab Nome: AXYS ANALYTICAL SERVICES
Contract No.:
4191
Lab Sample ID:
L7932-52 I
M atrix:
SERUM
Sample Size:
1 00 r
Sam ple Receipt date: Extraction Oate: Analysis Date:
01-Sep-2005 21-Sep-2005 23-Sep-2005
Time: 0:55:34
Initial Calibration Date: Instrument ID: LC Column ID:
22-Sep-2005 LC-MS/MS C18
Extract Volume (mL): 2
Injection Volume (pL): 10 0
Dilution Fncton
3
Concentration U nits: ng/mL
Sample Datafile:
FC5G_181S055
Blank Data Filename:
FC6G_1B1S070
CeL Ver. Data Filename: FC5G_1B1S048
CAL VER ID:
PFC-LIN-055CS-F
COMPOUND
LAB FLAG'
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA
UD UD UD D 72 9 D 1 51 D 0 739 UD UD UD D 125 D 87 6 UD
0 639 0 620 0 628 0 618 0 670 0 648 0 641 0 638 0 635 0 638 0 645 0 625
4 65 4 99 5 36
4 80 5 46
LABELED COMPOUND
13C2-PFOA 13C4-PFOS (80) 13C4-PFOS (99) 13C2-PFDA
LAB FLAG'
D D D D
SPIKE CONC.
(ng)
120 120 120 12 0
(1) U = not detected: D - dilution data (2) R (% ) = Percent recovery
169B2PF0i_i *ts. S5
Approved by:
CONC. FOUND
(ng)
122 12 9 13 2 10 3
R (%)*
RETENTION TIME
102 4 65 108 5 46 110 5 46 B5 6 S 36
QA/QC Chemist
28-09-2005 dd-mm-yyyy
J[( A X Y S A N A L Y T I C A L S E R V I C E S L T D CO I0Xim.20t5HlSW) W51 SIIHtfT. 8( . CMAMVil 3S8III (250) 6SHM0 f (250) 455 5B11
P-9
AXYS METHOD MLA-042 Rev 03
PFOS S I 012
Form 1A/2
~ PERFLUORINATED ORGANICS ANALYSIS REPORT
Semple Collection:
CLIENT ID: 31-Aug-2005 10:30
Lob Nome: AXYS ANALYTICAL SERVICES
Contract No.:
4191
M atrix: Sam ple Receipt date:
SERUM 01-Sep-2005
Extraction Dote: Analysis Date:
21-Sep-2005 23-Sep-2005
Time: 1:24112
Extract Volume (mL): 2
Injection Volume (pL): 10 0
Dilution Factor.
3
Concontration Units : ng/mL
Lab Sample ID:
L7932-54i
Sample Size:
100 n
Initial Calibration Date: 22-Sep-2005
Instrument ID:
LC-MS/MS
LC Column ID:
C18
Sample Datafile:
FC5G_1B1S057
Blank Data Filename:
FCSGJB1S070
Cal. Ver. Data Filename: FC5GJ81S048
CAL VERIO:
PFC-LN-055CS-F
COMPOUND
LAB FLAG
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA
UD UD UD D 55 4 D 2 36 UO UD UD UD
D 6 59 D 60 0 UD
0 639 0 620 0 628 0 618 0 670 0 648 0 641 0 638 0 635 0 638 0 645 0 625
4 65 5 05
4 80 5 46
LABELED COMPOUND
13C2-PFOA 13C4-PFOS (80) 13C4-PFOS (99) 13C2-PFDA
LAB FLAG 1
D D D D
SPIKE CONC.
(ng)
120 120 120 120
(1) U ~ noi delected; D = dilution dala (2) R (%) = Percent recovery
B2PFD1 1xte S7
Approved by:
CONC. FOUND
<ng)
11 8 150 134 10 1
R (V .f
RETENTION TIME
98 2 4 65 125 551 112 5 46 844 5 36
QA/QC Chemist
23 03-2005
dd'ienvyyyy
JK(0 A X Y S / X r ^ l / X L Y T ICSYXI S E R V I C E S L T D PO iOX2211. 20 WU5 H VIE51- SIOHtY IC . 08MM013S8 1012501655-5800 HX (250) 6555011
AXYS METHOD MLA-042 Rev 02
pfos st D12
Form 1A/2
' PHRFLUORINATED ORGANICS ANALYSIS REPORT
Sample Collodion:
CLIENT ID: 28-Jun-2005 10:27
Lab Nome: AXYS ANALYTICAL SERVICES
Contract No.:
4191
Matrix: Sample Receipt Date:
SERUM 29-Jun-2005
Extraction Date: Analysis Date:
04-Aug-2005 05-Aug-2005
Tune: 21:17:29
Extract Volume (ntL|: 2
Injection Volume (pL): 30 0
Dilution Factor:
N/A
Concentration Units : ng/mL
Lob Sample ID:
L7932-1
Sample Size:
100 n
Initial Calibration Data: 05-Aug-2005
Instrument ID:
LC-MS/MS
LC Column ID:
C18. Zorbax XDB
Sample date Filename: FC5G_131S040
Blank data Filename:
FC5Q_131S024
CaL Ver. data Filename: FC5G_131S037
CALVER ID:
PFC-N-039CS-F
COMPOUND
LAB FLAG'
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFQSA
u u u
30 9 260 0 510 0 290
u u
6 03 88 6
u
0 638 0 620 0251 0 247 0 268 0 259 0 256 0 255 0 254 0 255 0 258 0 250
4 70 5 07 538 5 67
4 90 550
LABELED COMPOUND
13C-PFOA 13C-PFDA
LAB FLAG 132
SPIKE CONC.
(ng)
120 120
CONC. FOUND
(no)
7 69 10 3
R (V .f
RETENTION TIME
64 t 85 8
4 70 5 34
(1) U = nol delected (2) R (%) = Percent recovery
16535PF02_I Ms. S 2
A p p ro v e d by:
QA/QC Chemist
24-08-2005
dd-mm-yyyy
(3) Concentrations are blank-corrected
iKC<? A X Y S A N A L Y T I C A L S E R V I C E S L T D PO BOX2219. 2045 ttIUSID W5I.SIOHEIT. C. CAIIAOAVOI3S8IEL 1250) 4S5-5800fW (250) 55H11
AXYS METHOD MLA-042 Rev 02
pros S1 0(2
Form 1A/2
" " PERFLUORINATED ORGANICS ANALYSIS REPORT
Sample Collacllon:
CUENT ID: 28 Jun-2005 10:30
Lab Name: AXYS ANALYTICAL SERVICES
Contract No.:
4191
M atrix:
SERUM
Sample Receipt Date: 29-Jun-2005
Extraction Date: Analysis Date:
04-Aug-2005 05-Aug-2005
Time: 21:4208
Extract Volume (mL): 2
Injection Volume (|iL): 30 0
Dilution F acto r
N/A
Concentration U n its: ng/mL
Lob Sample ID:
L7932-2
Sample Size:
100 mL
Initial Calibration Dato: 0S-Aug-2005
Instrument ID:
LC-MSiMS
LC Column ID:
C18. Zorbax XDB
Sample Datafile:
FCSG_131S042
Blank Data Filename:
FC5G_13IS024
CaL Ver. Data Filename: FC5G_131S037
CAL VERIO:
PFC-UN-039CS-F
COMPOUND
LAB FLAG'
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFPoA
PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA
U U U
24 2 1 48 U U U U 6 23 38 0
U
0638 0 620 0 251 0 247 0 268 0 259 0 256 0 255 0 254 0255 0 258 0 250
4 70 5 07
490 550
LABELED COMPOUND
13C-PFOA 13C-PFDA
LAB FLAG '
SPIKE CONC.
(ng)
120 120
CONC. FOUND
(ng)
8 09 11 2
R (% )1
RETENTION TIME
67 4 93 0
4 70 5 34
(1 ) U = not detected (2) R (% ) = Percent recovery
I6S3SPF02 t ids S4
Approved by:_
QA/QC Chemist
2408-2005
dd-rore-yyyy
.))]((. A X Y S A N A L Y T I O A L S E R V I C E S L T T O *0 Ml 271. BUS MUS Kl. SIOtIF. I ( . GUIMAMJSJ IH (HO) 455-5800FAX<75814555811
AXYS METHOD MLA-042 Rev 03
pfos_s i_012
Form 1A/2
PERFLUORINATED ORGANICS ANALYSIS REPORT
CU EN T ID:
Semple Collection:
31-Aug-2005 09:56
Lab Name: AXYS ANALYTICAL SERVICES
Contract No.: M atrix:
4191 SERUM
Lab Sample ID: Sample Size:
L7932-511(A) 1 00 i
Sample Receipt date: Extraction Date: Analysis Date: Extract Volume (mL|:
01-Sep-2005 21-Sep-2005 23-Sep-2005 2
Time: 0:27:07
Initial Calibration Date: Instrument ID: LC Column ID: Sample Datalile:
22-Sep-2005 LC-MS/MS C18 FC5G_181S053
Injection Volume (pL): 10 0
Dilution Factor
3
Concentration Units : ng/mL
Blank Oata Filename:
FC5G_181S070
CaL Ver. Data Filename: FC5G_1B1S048
CAL VER ID:
PFC-LIN-055CS-F
COMPOUND
LAB FLAG'
CONC FOUND
DETECTION U M IT
RETENTION TIME
PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA
UO UD UO 0 27 0 D 1 55 UD UD UD UD D 5 27 D 28 5 UO
0 639 0 620 0 628 0 618 0 670 0 648 0641 0 638 0 635 0 638 0 645 0 625
4 65 4 99
4 60 5 46
LABELED COMPOUND
13C2-PFOA 13C4-PFOS (80) 13C4-PFOS (99) 13C2-PFDA
LAB FLAG
0 D D D
SPIKE CONC.
(nfl)
12 0 12 0 120 12 0
(1 ) U = not detected: O = dilution data (2) R (%) = Percent recovery
B2PFD1_1 xfs S3
Approved by:
CONC. FOUNO
(ng)
114 14 E 135 10 1
R(% )s
RETENTION TIME
94 9 122 113 83 8
4 65 546 546 5 36
______
QA/OC Chemist
28-09 2005 dd-mm-yyyy
)]((AXYS ANALYTICAL SERVICES LTD CO t o t HIT. 2045 Mills 10 WISE SIOWY. 0 C. UIUOA VOI 358 III (2501155-5800 FA* (250) 1555011
AXYS METHOD MLA-042 Rev 08
Form 1A
PERFLUORINATED ORGANICS ANALYSIS REPORT
AXYS ANALYTICAL SERVICES
PO . Box 2219, 2045 MILLS RD. WEST, SIDNEY. B.C.. CANADA V8L 3S8 TEL (250) 655-5800 FAX (250) 655-5811
Contract No.:
4191
Lab Sam ple I.D.:
M atrix:
SERUM
Sam ple Size:
Sample Receipt Date:
27-Apr-2006
Initial Calibration Date:
Extraction Date:
06-Jul-2006
Instrum ent ID:
Analysis Date:
08-Jul-2006 Tim e: 09:22:30
Colum n ID:
Extract Volum e (uL):
2000
Sam ple Data Filename:
Injection Volum e (uL):
15
Blank Data Filenam e:
Dilution Factor:
N/A
Cal. Ver. Data Filename:
Concentration Units:
ng/ml
CLIENT SAMPLE NO. Sam ple Collection: 26-Apr-2008 09:15
L8863-3 0.500 ml 07-Jul-2006 LC MS/MS C18 FC6G_277 S: 24 FC6G_277 S: 21 FC6G_277 S: 14
COMPOUND
LAB FLAG 1
CONC. FOUND
DETECTION LIM IT
RETENTION TIME
PFBA PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA
U 0.604
U 0.472
U 0.484
U 0.532
20.1 0.484
3.46
0.680
0.768
0.536
0.642
0.476
U
u
0568 1.20
7.74
1 01
u 53.5
1.00 0.460
4:48 5:08 5:27 5:47
4:59 5:37
(1) Where applicable, custom lab flags have been used on this report; U = not detected.
Approved b y:__________________ ______________ - - - ______________ QA/QC Chemist
For Axys Internal Use Only [ XSL Template: FC-FormlA.xsl, Created: 12-Jul-2006 16:32:12; Application: XMLTransformer-1 7 4
Report Filename: PFC_FC LC_PFOA L8863-3 FormlA SI571308 htrcl. Workgroup. WG19474, Design ID: 332 |
'
These pages are part of a larger report that may contain information necessary for full data evaluation
Page 1 of 1 (WG19474 - PFC_FC_LC_PF0A_L8863-3_FormlA_SJ571308.html)
p . 14
AXYS METHOD MLA-042 Rev 02
pfos s i 013
Form 1A12
~~
p e r f l u o r in a t e o o r g a n ic s ANALYSIS REPORT
Sample Collection:
CLIENT IO: 18-Aug-2005 18:15
Lab Name: AXYS ANALYTICAL SERVICES
Contract No.: M atrix: Sample Receipt date: Extraction Date: Analysis Date: Extract Volum e (roL):
4191 SERUM 23-Aug-2005 29-Aug-2005 13-Sep-2005 2
Time: 0:1B;25
Injection Volume (pL): Dilution Factor: Concentration U n its:
30 0 N/A ng/mL
Lob Sample ID:
L7932-39 Y4
Sample Size:
1 00 IT
Initial Calibration Date: 12-Sep-2005
Instrument ID:
LC-MS/MS
LC Column ID:
C18
Sample Datafile:
FC5G_167S056
Blank Data Filename:
FCSGJ67S031
Cat. Ver. Data Filename: FC5G 167S044
CAL VER ID:
PFC-LIN-044CS-F
COMPOUND
LAB FLAG 1
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA
U U U
9 66 t 35 0 375
U U U
4 52 26 6
U
0 256 0 248 0 251 0 247 0 268 0 259 0 257 0 255
2 54 2 55 0 258 0 250
4 70 5 05 5 36
4 87 5 51
LABELED COMPOUND
13C2-PFOA 13C4-PFOS(80) 13C4-PFOS(99) 13C2-PFDA
LAB FLAG
SPIKE CONC.
(ng)
120 12 0 120 120
( 1) U = not detected (2) R {%) = Percent recovery
iE 7 5 SP F _D 2_ t kIc s i 2
Approved by:
CONC. FOUND
(ng)
9 15 13 8 128 128
R(% )'
RETENTION TIME
76 2 4 70 115 5 56 107 5 56 106 5 36
OA/OC Chemist
13-09-2005 dd-mm-yyyy
.-jt](fe A X Y S A N A L Y T I C A L S E R V I C E S L T T D PO BOX72IS.HM MULSH) KSI. SIIHIf.0 C. IMAMBl 350 Ul RSO) 655-5800FAX(2501 *55 5B11
37
p . 15
AXYS METHOD MLA-042 Rev 02
pfos_s i 012
Form 1A/2
~ PERFLUORINATED ORGANICS ANALYSIS REPORT
Sample Collection:
CLIENT ID: 15 Aug-2005 13:54
Lab Name: AXYS ANALYTICAL SERVICES
Contract No.: M atrix: Sample Receipt date: Extraction Date: Analysis Date: Extract Volume (mL):
4191 SERUM 17-Aug-2005 29-Aug-2005 12-Sep-2005 2
Time: 22:10:04
Injection Volume (pL): 30 0
Dilution Factor:
N/A
Concentration Units : ng/mL
Lob Sample ID:
L7932-28 Y2
Sample Size:
100
nr
Initial Calibration Date: 12-Sep-2005
Instrument ID:
LC-MS/MS
LC Column ID: Sample Datafile:
C18 FC5G_167S047
Blank Data Filename:
FC5GJ67S031
CaL Ver- Data Filename: FC5GJ67S044
CAL VER ID:
PFC-LIN-044CS-F
COMPOUND
LAB FLAG'
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFPeA PFHxA PFHpA PFOA PFNA PFDA PFUnA PFDoA PFBS PFHxS PFOS PFOSA
U U u
5 92 1 32 0 486 0 272
u u
3 76
29 5
u
0 256 0 248 0 251 0 247 0 268 0 259 0 257 0 255 254 2 55 0 258 0 250
4 70 5 05 541 5 75
4 87 5 56
LABELED COMPOUND
13C2-PFOA 13C4-PFOS(S0) 13C4-PFOS(99) 13C2-PFDA
(1) U = nol delected (2) R (%) = Percent recovery
16755p f _ 0 2 _ i n s S 3
A p p ro ve d by:
SPIKE CONC.
(ng)
120 12 0 120 120
CONC. FOUND
(ng)
10 5 11 3 10 4 13 6
R (%)*
RETENTION TIME
87 2 94 4 86 4 113
4 70 5 56 5 56 541
QA/QC Chemist
19-09-2005 dd-mm-yyyy
A X Y S /A T '-I/A L Y I ICSASl S E R V I C E S L T D f.O BO*22H. 2045 WHS(0 WEST. SI0HY BC-CMIMMYl358 IH (2S0J 455-5*00FMt(2501 655-5811
3$
