Document 820rrR1EOv2r4KN7ReNG701Ro
FORM N0.45A 202-11
DRY HCL HCL
HCL
CO;
CO "2
H;0
1968
Avg.
VOL. %
56^75
2.70 XL050.07 0.12 0.30
JAN
PPM 26
WET' HCL HCl from tce rx EDC
TCE HCL
Ethyl Chloride Ethyleme Ethane
FEB
PPG INDUSTRIES
CHEMICAL DIVISION LAKE CHARLES, LOUISIANA
LABORATORY OPERATIONS REPORT
MAR
APR MAY JUNE JULY
AUG
SEP
OCT
NOV
DEC
1969
Avg*
HCl to EC Rx weak Acio Strong Acid
Vol. % wt. * Wt. %
22.5 32,0
22.2 20.9 32.3 30.1
20.7 19.8 3176 32.8
33.0
3279" 3IjT 327T
35.2
20.9
32.7-
00
i -OHFIO entia
"Si ibject to Pr^tecti ve Qr< fir
ho J 4th J^diciajt Dist ric.-Court GO No. 9 -1145
hO
tFORM 0.45 A 2 11-1
GENERAL DEPARTMENT
62A DRY HCL .hcl Solo
Chlorine to 62a Hydrogen to 62A
T/o
T/D MCF/0
1968 Avg.
PPG INDUSTRIES
CHEMICAL DIVISION LAKE CHARLES, LOUISIANA
HYDROGEN CHLORIDE DEPARTMENT OPERATIONS REPORT
JAN FEB MAR APR MAY JUNE JULY AUG
SEP
OCT
NOV
DEC
1A9v6g9.
29.0 20..4 50.7 30.5 "2T$- A9-7 345.1 ''24476' 567.2
50.2 51.0 42.9 27.8 42.2 44.0 48.8 52.5
Aft-ft 49.3 44.9
52.9 50.1 41.5 27.3 A2.P 44.0 Aft-ft 52.5
J,ft,A AQ.-l 44-3
605.5 587.0 482.0 T09.3 A7P.7 500.5 AAQ -O 589.0 5P1t .2 S-TO.ft 496 ,ft
Cl7 Efficiency
.Clj Yield
Hydrogen Efficiency Hydrogen Yield Excess Hz
% 93.6 * 93.5
% 89.6 % 89.2 * 3.8
95.0" 97.0 -
99.0 99.0 99.0 99.0 99.0 99.0
-- -
4.1 4.8
-- -
7.0
99.0 99.0
6.2
99.0 99.0
3.6
99.0 97.2 99.0 97.2
2.5 3.9
97.2 97.2
-- -- 2.7
97.2 97.2
-- 2.5
97tp 97-p
97.2 97.2
pp
97.9 97.9
97.0
4.1
Tons Cl,/Ton HCl Sold mcf H,/ton HCl Solo
kwh/Ton Well- water m Gal/(Ton H2S04Lbs/TON
1.048 1.091 0.989 1.053 0.982 0.968 0.982 1.000 1.000 1.000 1.000 1 -OOO 1.000 1.005 11.9 n .0 11.2 "1271 11.5 . 11.2 11.1 11.2 11.4 11.2 11.2 10.7 10.8 11.2
155.5 nTo 0.0 0.0 "0.0 " 0.0 0.0 0.0 0.0
0.0 0,0 0.0
16.9 20.2 9.8 9.6 9.2 ~ 8.5 8.5 4.7 5.1
A. 5 4.0 4.2
24.4 TQ.l 12.0 15.3 1577" 13.6 1376 11.1 10.9 6.5 7.4 5.6
-
0.0 4.4 7.7 9.7 11.7
MAN HOURS/TON HCL Production
*
Maintenance Salaried Total
Contract Maint. included in Above
0.500
0.539 1.87
1.226
o.n7
o.m 0.199
0.275 0.025
0.237 0.096
0.923 0.320 0.000 0.000
-
0.202 0.185 O.PAP 0.355
0.061 0.095 0.176 0.144 0.092 0.066 : 0.076 0.121 0.355 0.346 ; 0.49L 0.620 0.000 0.000 0.000 0.000
0.230 0.028 0.081'
0.339 0.000
0.226 0.219 0.052 0.161
0:074" 0.069 0.352 0.449 o;ooo" 0.000
0.200
0.064 0.068 0.332 0.000
0.205 3.076 3.062
3.343 3.000
0.196 0.072 0.066
0.334 "0^505
0.239 0.102 0.092
0.433 0.000
-- fn -- r"
'
o ho oo --- to
--con: ''I DENT IAD Sub 3^ iCt to Profce ct ive utuer1 c 14 tl p JUdi ;ial D istric t uOUj
No , 91-1 -----
--------
FORM N0.45A2! I- 2
PPG INDUSTRIES
CHEMICAL DIVISION LAKE CHARLES, LOUISIANA
HYDROGEN CHLORIDE DEPARTMENT OPERATIONS REPORT
Subject to Protective order
o 14th Judicial District Court GV 31--1145
GENERAL DEPARTMENT
PRESSURE
Line
Comp. Comp.
Disch.
Suct i on
PSIG PSIG " HjO
1968
AVG.
32 46
-24
JAN
FES MAR
APR MAY JUNE JULY
AUG
SEP
OCT
NOV
DEC
1969 Avg,
18 19 19
18 18 18 ~T7---- 19 39 19
18
89 41 41
i.n 41 m-- ' 48 45 37----- 37------ 37
--82 -35 -37 p-35 -32 -25
-25 -29 -35 -36
-35
18 18
38 40 _ -34 -33
TEMPERATURE 6F Ho. J) Burner
Gas from Primary Gas from Secondary
2No- Burner
Gas from Primary
Gas from Secondary
Compressor Discharge
111** 64 61 61 43 ** 29 36 37 92 ** 91 97 92 43 ** 34 35 36 282** 269 279 279
73 78 37 42
87 40
101 104 102 40 43 53 283 290 "233
~92 "59
102 ~53
~9l----- 88 "55----- 48
101 100
39-----
3or_
53 295
74 23
104 33 285
66 62 897** 19 22 390**
99 95 1188** 25 24 478** 273 282 3430**
Cell Liquor
Lbs/.Ton hCl
41.2 0.0 32.6 "U70 0.0 2.9
Kell Water To HCl
GPM 330 268 351 341 318 257
OPERATING TIME
No. 1 Burner No, 2 Burner
Compressor No., 5
Compressor Wo. 3 Compressor No. 4
Nn. Riimer
*4380 mt
-
*5846 487 672 744 719 655
*6713 533 672 ~~wr~ 719 661
*4309 478 463 ~J5T~ 719 744
*5147 869 576 744 719 744
184 672 744 710 596
No. 2 Absorber
__ No. 3 Absorber
No. 4 Absorber
*3796 i5i61r 588
______ *1242
521
--
715
462
--
719 693 695 738 717 643
12.2
223
T5T6" 0.0 258 242
-- 498 744 *607-- 744 720 744 720 744 369 744
677 726 711 742 708 742
744 706 735 744 744
"755 750 "755
0.0
248 259
47.4 285
--
"672
689 475 664 689
-
715--
745 734 54 724
-
634
720"
659 720 633
475 682 493 715 "59l~ 701
712 719 720
0.0 14.7
243 274
-744 7981* 744 8284* 730 "7559* 744 8036* 744
707 7999* 689 7740* 697 -.6213*
_ SL 012814
Totals
FORM
45A 211-3
GENERAL DEPARTMENT
62B WET HCL
Wet hCl Produced
Chlorine to 620
HVDRilGEN TO1 62B
t/o
1 T/D
MCF/D
1968 Avg.
4.6 -- -
HCl from TCE Rx , . (
HCl to MC Rx HCl to 62A(dry HCl)
HCL TO EC
",
T/D T/D
T/D
T/D 0.0
HCl Sold as Muriatic
T/D 0.15
Chlorine Efficiency Chlorine Yield
% 87.2 % 85.2
Hydrogen Efficiency Hydrogen Yield Excess
% 77-? * 76.0
% 12.1
PPG INixJSTRIES
CONFIDENTIAL^ Subject to
of 14th Judicial District Court
CHEMICAL DIVISION LAKE CHARLES, LOUISIANA
No. 91-1145
HYDROGEN CHLORIDE DEPARTNE NT OPERATIONS REPORT
JAN
FEB MAR
APR MAY JUNE JULY
AUG
SEP
OCT
NOV
OEC 1969 Avg.
58.1 n.n n.n
55.5 0.0 0.0
65.3 0.0 0.0
68.6 0.0 0.0
83.6 0.0 0.0
56.7 ' 0.0
0.0
43.5 0.0 0.0
44.0 0.0 0.0
23.5 0.0 0.0
23.6 0.0 0.0
0.0
-
--
0.0
-- -
0.0
-
0.0
--
0.0
-
- -
------- U7Z
*
a
0.0
- "27.0 35.9 --JHt 25.0
--
-
0.0
32.6
w
a.
0.0 26.5
--
0.0 36.5
-----
_ ---
- a. -*
-
43.2
0,0 nn
41.8 0.0 0.0
-- -- _
0.0
0.0
50.3 37.4
_a
50.6 0.0 0.0
.a. -
ta
0.0
33.6
a
-
-
- a.
- a.
-- ---
- --
-
-.
-
--
-
--
-
-- -- --
--- --- -- aa -
-- -- -
Cl^ Tons/Ton Wet HCl Prod
hz MCF/Ton N, Tons/Ton Steam (actual) M Eb^Ton Well Water M Gal^Ton H?SOa Lbs/Ton
kwh Aon
1.180 14.5 0.058 3958 10.9 13.1 325.1
-
-
0.042 3351 3.3
3.1 40.9
n,n6j.
?f,n 9T7 ?.5 1?'. 9
-
-
0.049 0.049 2482 2072
2.5 32.0
7.3 1.2 31.4
--
0.04-1 1918 5.8 1.5 24.7
--
--
0.059 07093
3256 8.8 2.3 42.2
351511.1 2.4 w: 7
0.099 3270 11.0 4.2 45.6
a.
0.505 3785 9.4 6.9 122.8
-
0.420 4362
20.5 8.2 91.2
--
-
0.280 2150 11.6
0.234 2271 11.6
.-
0.161 2895 10.2
1.3
9.3
3.8
52.2 XI------- "5871"
operating time
No 3 Burner No 4 Burner No 5 Burner No 1 Stripper
No 2 Stripper No 1 Compressor No 2 Compressor No 3 Compressor
(f)
1
0 --* z-n -- 01
-&Q
&12L
*1601 *5571 *63IJ3 *7250 *1742
0 0
-
602 "596
610 610
0
totals
n o
TOO '601 li,3
0
"o-- u--
--
0
0 .
684
546
162
719
O'
LOo
707
636
719
353
0
0 0
mm
743 734 744 744 0
0 0
719 720 404
720
0
00 00
-
0
0 --
744 563
711
J2k____
433
712
744
744
"5----------- 0
482 480 178 516
0
u 15
638 284 137 505 0
0 0 --
0 720 576 720 0
13 0
?8 699 378 711. 6
0*
0*
----------- w~
6487* 6791* 611?* 751 <;* 353 *
FORM F45A 211-4
GENERAL DEPARTMENT
62B WET! HCl
REFRIGERATION UNIT
Pressure
PSIG
Suction
Dt SCHARGE
Seal Temperatures
Brine In Brine Out Amps
Op
1968 Avg
PPG INDUSTRIES
CHEMICAL DIVISION LAKE CHABLES, LOUISIANA
HYDROGEN CHLORIDE DEPARTMENT OPERATIONS REPORT
JAN
FEB MAR
APR MAY JUNE JULY
AUG
SEP
. CONFIDENTIAL:
OCT
--------------1 O. 91 NOV DEC
Avg
Ct C
-25.; 6.0 21.6
-24.4 -71.. 7
7.1 6.0 22.0 22.1
-23.5 4.4 22.0
-24.1 9.1 21.9
-23.8 -24.1
9.1
8.7
21.6 21.6
-24.0 8.9 21.7
-23.9 10.9 21.7
-24.0 7.5 21.4
-24.2 7.1 20:9
-24.9 -24.9
5.6
6.7
21.6 21.9
26 12 139
18 17 137
22 20 135
-----------
~2I-------"125
21 19 141
24
77
141
28 37 26---------- 36
135
138
44 "55---------
142
39 39 136
12 11 134
12
1
133
14 10 147
-24.2 7.6 21.7
25 23 137
NO- 1 STRIPPER
Flows
Strong Acid Feed
qpm
Steam Temperatures
Top Bottom Tertiary
Lbs/Hr Op
40.3 5294
40.9 34.9 6128 (4566
234 261
26
220
-
26
220 33
43.9 7051
24.1 3573
218
-
29
225
--
33
29.4 4932
39.5 5765
224
-
36
231 37
32.7 5062
232
-
47.
55TT 4339
26.7 2529
38.6 4279
232
--
52
237
-
53
229 25
0 0
ft
0
50.3 196
236
--
11
33.0 4037
225
--
32
NO- 2 STRIPPER
Flows Strong acid Feed
GPM
Steam
Lrs/Hr
Temperatures Top
F
Bottom Tertiary
41.1 3983
39.4 33.7 8324 1935
239 268
24
238 25
234
-
53
37.3 822
31.1 3338
237
-
28
238
--
31
29.6 2807
36.6 3220
235
-
34
237
-
36
32.7 2819
255
-
45
35.0 2644
28.1 1799
32.0 709
236
53
238
-
50
239
-
26
48.7 45.4 4510 4597
239 14
239
-
16
35.8 2710
237
-
33
man HOURS/TON HCL Production Maintenance Salaried Total
Conthact Maint. Included in Above
0,635 1.337 0.218 2.190 0.000
0.239 0.308 0.083 0.630 0.000
0.232 0.353 0.088 0.673
0.000
0.187 0.035 0.317 0.000
0.178 0.135 0.049 0.362
0.000
0.354 n.127
0.039
0.320
n.ono
0.271 0.244 0.059 0.574 0.000
0.28? 0.205 0.078 0.570 0.000
0.276
0.187 0.074 0.537
n.nho
0.551 0.853 0.143 1.547 0.000
0,588 1.264 0.151 2.003
0.000
0.299 0.312 0.320 0.216 0.070 0.078 0.689 0.606 0.000 nTnnn
0.290
Ot36?
0.079
O.736 n.noo
SL 012816
^
FORM NO.45A 2U-5
COMPRESSION
No 1 Compressor Pressure
Suction Discharge Temperature Suction D ischarge ;
1968
Avg
psig .
is;, op
_
PPG INDUSTRIES
CONFIDENTIALi Subject to Protective Order
er
CHEMICAl DIVISION
of 14th Judicial District Court our
LAKE CHARLES. LOUISIANA
No. 91-1145
HYDROGEN CHLORIDE DEPARTMENT OPERATIONS REPORT
JAN
FEB MAR
APR
MAY
JUNE JULY
AUG
SEP
OCT
NOV
DEC
1969 Avg
_
--_
mm -- -
.
150 150 154 US 153 159 139 153 145 162 173 1m5j5j
--
-
--- --- -- -
-_ --
153
a.
No 2 Compressor
Pressure Suction Di scharge
Temperature
Suction Discharge
psig of
--
158
-
159
--
IS/,
mm
-
156
--
--
--
159
-
--
172
-
--
153 " 151
-----
181
-- -
-
180
1o6
--
--
151 183
*
157
No 3 Compressor Pressure Suction
Discharge Temperature
Suction
Discharge
psig Op
-- 87
73
-
--
15/, 155'" 75
-- **
.-
76 77
---- ---
82
<_
86
-
-
133 128
mm
129
-
-- 142
-
109
-
CD
1"
o
---- CO -- `'J
*