Document 7RrROLrjpkgbGo5VenVd7n6zE

O QG Laboratories' I S4. ly Analytical Report PETER TYRRELL UNITED WATER CITY OF ORANGE CHESTNUT STREET PLANT AT 632 BEACH STREET ORANGE, NJ 07050 Account No: C00927, UNITED WATER CITY OF ORANGE Project No: C00927, * Sample Number L25WS60^r * Sample Description CHESTNUT ST POE TREATED TP001001 Received Temp: 38 F Iced (Y/N): Y Parameter PFOA Method Sample Number LW? Sample Description ORANGE PARK POE TREATED TP002008 Received Temp: 38 F Iced (Y/N): Y Parameter PFOA Method Sample Description GIST PL POE TREATED TP003010 MCL MCL Regarding: PETER TYRRELL UNITED WATER CITY OF ORANGE CHESTNUT STREET PLANT AT 632 BEACH STREET ORANGE, NJ 07050 P.O. No: PWStad*EK."fr71r7e01% Samp. Date/Time/Temp 01/15/08 11:45am NA F Inv. No: 945295 Sampled by Customer Sampled Result ATTACHED Samp. Date/Time/Temp 01/15/08 08:30am NA F RLs Test Date,Time Sampled by Customer Sampled Result ATTACHED Samp. Date/Time/Temp 01/15/08 09:30am NA F RLs Test Date,Time Sampled by Customer Sampled - A result of "ND" indicates the concentration of the analyte tested was either not detected or below the RLs. - Definitions: ND=not detected; NEG=negative; P0S=positive; COL=colonies; RLs=laboratory reporting limits; L/A=lab accident; TNTC=too numerous to count; NL=No Permit Limits. - A result marked with "DRY" indicates that the result was calculated and reported on a dry weight basis. - All analysis, except field tests are conducted in Southampton, PA unless otherwise identified. - The test"pH lab"is analyzed upon receipt at the laboratory, the result will not be suitable for regulatory purposes. - Actual times of analysis for parameters reported <24 hours are available upon request. All testing is conducted within the required holding time unless otherwise noted. - QC NELAP ID's-.PA 09 00131 ,NJ PA166.FL E87954.NY 11223,CT PH-0768,DE PA-018,KY 90228,MD 206,EPA PA00018.Bioassay:PA 09-03574,NJ PA034.FL E87953,KS E10373,SC 89020001. - QC STATE ID's:Wind Gap.NJ PA001.PA 48-01334;E RUTHERFORD NJ02015;Vineland NJ06005; Reading PA 06-03543. - MCL= is the recommended EPA "Maximum Contaminant Level" for a parameter. PLs=customer specific permit limits. Regulatory authorities are assessing substantial fines for testing omissions. Please track your sample collections and results on a weekly, monthly, or quarterly basis to ensure compliance. QC's internet program 'LIVE ACCESS' will provide you with real-time access to collection dates and results. Please contact Customer Service for further information on acquiring LIVE ACCESS. Page 1 of 2 Serial Number: 931169 Thom as J. Hines, P re sid ent 1205 Industrial Blvd., P.O. Box 514, Southampton, PA 18966-0514 Phone: 215-355-3900 Fax: 215-355-7231 www.qclahoratories.com DEP2-SDWB-000136 QC Laboratories Analytical Report Account No: C00927, UNITED WATER CITY OF ORANGE Project No: C00927, UNITED WATER CITY OF ORANGE Received Temp: 38 F Iced (Y/N): Y Parameter PFOA Method P.0. No: PWSID No: 0717001 W1A C C O ,, 4S& o#02708/1 pm Inv. No: 945295 MCL Result ATTACHED RLs Test Date.Time - A result of "ND" indicates the concentration of the analyte tested was either not detected or below the RLs. - Definitions: ND=not detected; NEG=negative; POS=positive; COL=colonies; RLs=laboratory reporting limits; L/A=lab accident; TNTC=too numerous to count; N U N o Permit Limits. - A result marked with "DRY" indicates that the result was calculated and reported on a dry weight basis. - All analysis, except field tests are conducted in Southampton, PA unless otherwise identified. - The tesr'pH lab"is analyzed upon receipt at the laboratory, the result will not be suitable for regulatory purposes. - Actual times of analysis for parameters reported <24 hours are available upon request. All testing is conducted within the required holding time unless otherwise noted. - QC NELAP ID's:PA 09-00131.NJ PAI66.FL E87954.NY 11223,CT PH-0768,DE PA-018.KY 90228,MD 206,EPA PA00018.Bioassay:PA 09-03574,NJ PA034,FL E87953.KS E10373.SC 89020001. - QC STATE ID's:Wind Gap,NJ PA001.PA 48-01334;E RUTHERFORD NJ02015;Vineland NJ06005; Reading PA 06-03543. - MCL= is the recommended EPA "Maximum Contaminant Level" for a parameter. PLs=customer specific permit limits. Regulatory authorities are assessing substantial fines for testing omissions. Please track your sample collections and results on a weekly, monthly, or quarterly basis to ensure compliance. QC's internet program 'LIVE ACCESS' will provide you with real-time access to collection dates and results. Please contact Customer Service for further information on acquiring LIVE ACCESS. Page 2 of 2 Serial Number: 931169 Th om as J. Hines, Presid e nt DEP2-SDWB-000137 ANALYTICAL REPORT PFOA/PFOS Analysis Lot#: D8A170291 Nicki Smith QC Laboratories, Inc. 1205 Industrial Highway Southampton, PA 18966 TestAmerica Denver Michelle A. Johnston Project Manager February 4, 2008 L 3 S Q S ( oD 4955 Yarrow Street Arvada, CO 80002 tel 303.736.0100 fax 303.431.7171 www.testamericainc.com DEP2-SDWB-000138 Table Of Contents Standard Deliverables Report Contents Standard Deliverables The Coyer Letter and the Report Cover page are considered integral parts o f this Standard Deliverable package. This report is incomplete unless all pages indicated in this Table o f Contents are included. T able of Contents Case Narrative Executive Summary - Detection Highlights Methods Summary Method/Analyst Summary Lot Sample Summary Analytical Results QC Data Association Summary QC Evaluation and/or Data Reports Chain-of-Cnstody Total Number of Pages TestAmerica i DEP2-SDWB-000139 Case Narrative D8A170291 TestAmerica Denver utilizes USEPA approved methods in all analytical work. The samples presented in this report were analyzed for the parameters listed on the methods summary page in accordance with the methods indicated. Dilution factors and footnotes are provided on each datasheet to assist in the interpretation of the results. The results relate only to the samples in this report and meet all requirements of NELAC. All data have been reviewed for compliance with the laboratory QA/QC plan and have found to be compliant with laboratory protocols with any exceptions noted below. Please note that Non-Detect (ND) results have been evaluated down to the Method Detection Limit (MDL) and should be considered ND at the MDL. Unless otherwise noted, results for solids have been dry weight corrected. This report shall not be reproduced except in full, without the written approval of the laboratory. Sample Arrival and Receipt The following report contains the analytical results for three samples received 1/17/08, according to documented sample acceptance procedures. The samples were received in good condition at a temperature of 3.1C. No anomalies were encountered during sample receipt. Standards Analytical standards were prepared using the acid form of the compound perfluorooctanoic acid (PFOA). PFOS is a commercial prepared and certified solution. Perfluoro-n-[1,2,3,4-'3C4]octanoic acid was introduced at the extraction step and was used as an internal standard for quantitation of PFOA. Perfluoro-1-[1,2,3,4-13C4]octanatesulfonate was introduced at the extraction step and was used as an internal standard for quantitation of PFOS. Sample Extraction and Analysis The sample presented in this report was analyzed for the target analyte by TestAmerica Denver's SOP DEN-LC-0012A. For water samples a 250 mL aliquot of each sample is acidified with 1 mL of 6N HCI solution and it is extracted using solid phase extraction technique with methanol conditioned C18 cartridges. Each sample is spiked with the internal standard, prior to extraction. After the sample is passed through the cartridge, the analytes are eluted with 4 mL of methanol. The final volume is brought to 5 mL using methanol and the extract is analyzed by LC/MS/MS. Method QC Samples The Method Blank is processed reagent water spiked with surrogate and prepared with each batch of 20 samples of the same matrix. The method blank was non-detect at the reporting limit. Each batch is prepared with a Laboratory Control Sample (LCS). The recoveries of two concentration levels of Laboratory Control Samples were within control limits. TestAmerica 2 DEP2-SDWB-000140 Analytical Comments The LCS percent recovery associated with QC batch 8017446 was outside the QC control limits, biased high, for PFOS. This is an indicator that data may be biased high. The PFOS sample duplicate analysis for QC batch 8017446 showed an RPD result of 200. It can be noted that the RPD was calculated based on values below the reporting limit, and as such, could not be reliably calculated. No other anomalies were observed. TestAmerica 3 DEP2-SDWB-000141 EXECUTIVE SUMMARY - Detection Highlights D8A170291 PARAMETER 1.2512560-1 01/15/08 11:45 001 PFOA PFOS L2512560-2 01/15/08 08:30 002 PFOA PFOS L2512560-3 01/15/08 09:30 003 PFOA PFOS RESULT REPORTING LIMIT UNITS ANALYTICAL METHOD 0.037 0.013 0.010 0.010 ug/L ug/L DEN -LC-0012 DEN -LC-0012 0.061 0.011 0.010 0.010 ug/L ug/L 0.065 0.018 0.010 0.010 ug/L ug/L D E N ,,-LC-0012 DEN -LC-0012 DEN -LC-0012 DEN -LC-0012 I TestAmerica 4 DEP2-SDWB-000142 METHODS SUMMARY D8A170291 ANALYTICAL P A R A M E T E R ______________________________ _________________ M E T H O D _______ LC/MS/MS, PFOA DEN -LC-0012 References: DEN Severn Trent Laboratores, Denver, Facility Standard Operating Procedure. PREPARATION METHOD TestAmerica DEP2-SDWB-000143 METHOD / ANALYST SUMMARY D8A170291 ANALYTICAL METHOD ANALYST DEN -LC-0012 Jaqueline Bonnett References: DEN Severn Trent Laboratores, Denver, Facility Standard Operating Procedure. ANALYST ID 003601 TestAmerica DEP2-SDWB-000144 SAMPLE SUMMARY D8A170291 wo # SAMPLE# CLIENT SAMPLE ID KFPQV 001 L2512560-1 KFPQ3 002 L2512560-2 KFPQ4 003 L2 512560-3 NOTB(S) : _______ _____________________ _ _ ______________________________ - The analytical results of the samples listed above are presented on the following pages. - All calculations are performed before rounding to avoid ruund-off errors in calculated results. Results noted as "N D ' were not detected at or above (he stated limit. - This report must not be reproduced, except in full, without the written approval of the laboratory. - Results for the following parameters arc never reported on a dry weight basis: color, corrosivity, density, flashpoint, ignitability. layers, odor, paint filter test. pH, porosity pressure, reactivity, redox potential, specific gravity, spot tests, solids, solubility, temperature, viscosity, and weight. SAMPLED SAMP DATE TIME 01/15/08 11:45 01/15/08 08:30 01/15/08 09:30 TestAmeriea DEP2-SDWB-000145 QC Laboratories Client Sample ID: L2512560-1 HPLC Lot-Sample # -Date Sampled__ Prep Date..... Prep Batch # __ Dilution Factor D 8 A 1 7 0 2 9 1 - 0 0 1 Work Order # _.. 01/15/08 11:45 Date Received.. 01/17/08 Analysis Date.. 8017446 Analysis Time.. 1 Method........ KFPQV1AA 01/17/08 01/21/08 21:22 DEN -LC-0012 Matrix PARAMETER PFOA PFOS R E S U L T ______ _ _ _ 0.037 0.013 REPORTING LIMIT 0.010 0.010 UNITS ug/L ug/L SURROGATE 13C4 PFOA 13C4 PFOS PERCENT R E C O V E R Y ________ 109 71 RECOVERY LIMITS (50 - 200) (50 - 200) : WATER TestAmerica DEP2-SDWB-000146 QC Laboratories Client Sample ID: L2512560-2 HPLC Lot-Sanple #... Date Sampled... Prep Date..... Prep Batch #... Dilution Factor D 8 A 1 7 0 2 9 1 - 0 0 2 Work Order #... : K F P Q 3 1 A A 01/15/08 08:30 Date Received..: 01/17/08 01/17/08 Analysis Date..: 01/21/08 8017446 Analysis Time.. : 21:39 1 Method........ : D E N -LC-0012 Matrix PARAMETER PFOA PROS RESDLT 0.061 0.011 REPORTING _ LIMIT UNITS 0.010 ug/L 0.010 ug/L SURROGATE 13C 4 PFOA 13C4 PFOS PERCENT R E C OV E R Y________ 106 65 RECOVERY LIMITS (50 - 200) (50 - 200) : WATER TestAmerica DEP2-SDWB-000147 QC Laboratories Client Sample ID: L2512560-3 HPLC -r.. Lot-Sample # . . . : D 8 A 1 7 0 2 9 1 - 0 0 3 Work Order # .. .: K F P Q 4 1 A A Date Sampled__ : 01/15/08 09:30. Date Received. .: 01/17/08 Prep Date..... : 01/17/08 Analysis Date. .: 01/21/08 Prep Batch # ...: 8017446 Analysis Time. .: 21:55 Dilution Factor: 1 Method....... .: D E N -LC-00 Matrix. PARAMETER PFOA PROS RESULT 0.065 0.018 REPORTING LIMIT 0.010 0.010 UNITS ug/i< ug/L SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 102 65 RECOVERY LIMITS (50 - 200) (50 - 200) WATER TestAmerica 10 DEP2-SDWB-000148 QC DATA ASSOCIATION SUMMARY D8A170291 SAMPLE# 001 002 003 Sample Preparation and Analysis Control Numbers MATRIX WATER WATER WATER ANALYTICAL METHOD DEN -LC-0012 DEN -LC-0012 DEN -LC-0012 LEACH BATCH # PREP BATCH # 8017446 8017446 8017446 MS RUN# 8017259 8017259 8017259 TestAmerica 11 DEP2-SDWB-000149 METHOD BLANK REPORT HPLC Client Lot #...: D8A170291 MB Lot-Sample #: R8A170000-446 Analysis Date..: 01/21/08 Dilution Factor: 1 Work Order #...: KFP5Q1AA Prep Date......: 01/17/08 Prep Batch #...: 8017446 Matrix........ : WATER Analysis Time..: 19:30 PARAMETER PFOA PFOS RESULT ND ND REPORTING LIMIT UNITS 0.010 ug/L 0.010 ug/L SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 96 68 RECOVERY LIMITS (50 - 200) (50 - 200) NOTB(S) :_____________________________________ Calculations are performed before rounding to avoid round-off errors in calculated results. METHOD DEN -LC-0012 DEN -LC-0012 TestAmerica 12 DEP2-SDWB-000150 LABORATORY CONTROL SAMPLE EVALUATION REPORT HPLC Client Lot D8A170291 Work Order #...: KFP5Q1AC LCS Lot-Sample#: R8A170000-446 Prep Date..... : 01/17/08 Analysis Date..: 01/21/08 Prep Batch : 8017446 Analysis Time..: 19:46 Dilution Factor: 1 Matrix. PARAMETER PFOA PFOS PERCENT RECOVERY 91 91 RECOVERY LIMITS (70 - 130) (39 - 120) METHOD DEN -LC-0012 DEN -LC-0012 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 94 71 RECOVERY LIMITS (50 - 200) (50 - 200) MOTB(S) :_____________________ _____ __________ Calculations are performed before rounding to avoid round-off errors in calculated results. Bold print denotes control parameters WATER TestAmerica 13 DEP2-SDWB-000151 LABORATORY CONTROL SAMPLE DATA REPORT HPLC Client Lot # -- D 8A 1702 91 Work Order #. KFP5Q1AC LCS Lot-Sample# R 8 A 1 7 0 0 0 0 4 4 6 Prep Date..... 0 1 / 1 7 / 0 8 Analysis Date..: 01/21/08 Prep Batch #... 8 0 1 7 4 4 6 Analysis Time..: 19:46 Dilution Factor: 1 Matrix. WATER PARAMETER PFQA PFOS S P IK E AMOUNT 0.200 0.200 MEASURED AMOUNT 0.182 0.182 U N IT S ug/L ug/L PERCENT RECOVERY 91 91 METHOD DEN -LC-0012 DEN -LC-0012 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 94 71 NOTE(S): Calculations are performed before rounding to avoid round-off errors in calculated results. Bold print denotes control parameters RECOVERY LIM ITS (50 - 200) (50 - 200) TestAmerica 14 DEP2-SDWB-000152 LABORATORY CONTROL SAMPLE EVALUATION REPORT HPLC Client Lot #- -.: D8A170291 Work Order KFP5Q1AD LCS Lot-Sample#: R8A170000-446 Prep Date..... : 01/17/08 Analysis Date..: 01/21/08 Prep Batch # -- : 8017446 Analysis Time..: 20:02 Dilution Factor: 1 Matrix PARAMETER PFQA PFOS PERCENT RECOVERY 117 128 a RECOVERY LIMITS (70 - 130) (39 - 120) METHOD DEN -LC-0012 DEN -LC-0012 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 102 73 NOTE(S): ___________________________________ Calculations are performed before rounding to avoid round-off errors in calculated result1. Bold print denotes control parameters a Spiked analyte recovery is outside staled control limits. RECOVERY LIMITS (50 - 200) (50 - 200) WATER TestAmerica 15 DEP2-SDWB-000153 LABORATORY CONTROL SAMPLE DATA REPORT IIPLC Client Lot # -- : D8A170291 Work Order #... LCS Lot-Sample#: R8A170000-446 Prep Date..... : 01/17/08 Analysis Date.. Prep Batch #...: 8017446 Analysis Time.. Dilution Factor: 1 KFP5Q1AD 01/21/08 20:02 Matrix........ : WATER PARAMETER PFOA PFOS SPIKE AMOUNT 0.0200 0.0200 MEASURED AMOUNT 0.0234 0.0257 a UNITS ug/L ug/L PERCENT RECOVERY 117 128 METHOD______ DEN -LC-0012 DEN -LC-0012 SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 102 73 RECOVERY LIMITS (50 - 200) (50 - 200) NOTB(S) :____________________ ________________ Calculations are performed before rounding to avoid round-off errors in calculated results. Bold print denotes control parameters a Spiked analyte recovery is outside stated control limits. TestAmerica 16 DEP2-SDWB-000154 MATRIX SPIKE SAMPLE EVALUATION REPORT HPLC Lot-Sample # __ MS Lot-Sample # Date Sampled... Prep Date..... Prep Batch #... Dilation Factor D8A170291 Work Order #... D8A170279-001 0 1 / 16/08 07:05 Date Received.. 01/17/08 Analysis Date.. 8017446 1 KFPNT1AC 01/17/08 01/21/08 Matrix PARAMETER PFOA PFOS PERCENT RECOVERY 105 94 RECOVERY LIMITS (70 - 13D) (39 - 12D) SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 103 69 NOTB(S): ______ ____________________________ Calculations are performed before rounding to avoid round-off errors in calculated results. Bold print denotes control parameters METHOD________ DEN -LC-0012 DEN -LC-0012 RECOVERY LIMITS (50 - 200) (50 - 200) : WATER stAmerica 1' DEP2-SDWB-000155 MATRIX SPIKE SAMPLE DATA REPORT HPLC Lot-Sample # __ : D 8 A 1 7 0 2 9 1 Work Order #. MS Lot-Sample #: D 8 A 1 7 0 2 7 9 - 0 0 1 Date Sampled...: 0 1 / 1 6 / 0 8 0 7 : 0 5 Date Received Prep D a t e ..... : 0 1 / 1 7 / 0 8 Analysis Date Prep Batch #...: 8 0 1 7 4 4 6 Dilution Factor: 1 KFPNT1AC 0 1 /1 7 /0 8 0 1 /2 1 /0 8 Matrix........ : WATER PARAMETER PFOA PROS SAMPLE S P IK E MEASRD AMOUNT AMT AMOUNT 0.0060 0.200 0.215 HD 0.200 0.188 U N IT S ug/L ug/L SURROGATE 13C4 PFOA 13C4 PFOS PERCENT RECOVERY 103 69 HOTB(S) :_____________________________________ Calculations are performed before rounding to avoid round-offerrors in calculated results. Bold print denotes control parameters PERCENT RECOVERY 105 94 METHOD DEH -LC-0012 DEM -LC-0012 RECOVERY LIM ITS (50 - 200) (50 - 200) TestA rtverica 18 DEP2-SDWB-000156 DEP2-SDWB-000157 STL 'f QC Laboratories' 1205 Industrial Blvd. Southampton, PA 18966-0514 Phone: 215-355-3900 Fax: 215-355-7231 CHAIN OF CUSTODY Page l of ' Bill to/Rsport lo: (if different) Client/Acot. No. Address c 4 j U- yL-rv-L. Sampling Site Address: (if different) Lab LIMS No: 3JS 3 r L ^ !huqL : .-v wyT City/State/ZIp Phone/Fax P.O. No, -------------------------- -------------------- ---------- -- I B PROJECT !,!*'?* F IE L D ID M - /L j L s ~ ! - S ~ C ijL ^ t - tr i r b - s ----------------- Collection ;G C R 0 M atrix Date ; Military Time AM BP Code tfog / / v n | `Mo? f 3 `/rfo t 3 D T)U Number ol Containers T o ta l C C- I H C V s H N N '1 03 :, n A H; C Un0 Bi cT _L i I J _ j i-- i _--_-I1 rt _ Temp contro' rt> P f r l PU i 1 3/ M A TR IX C O D E S DW: DRINKING WATER GW: GROUND WATER WW: WASTEWATER SO: SOIL SL: SLUDGE OIL: OIL SOL: NON SOIL SOLID Ml: MISCELLANEOUS o CM riera pn, lemp u o r r j, DO, Cl2, o a. Li ce rr i '; I _ j qI Verbal/fax data due: Hardcopy due: / :----------------- n V/ / Standard + QC NJ Reduced Disk Sig: Please call tor pricing and availability on rush (<14-21 day) turnaround and on all but standard format. SAMPLE CUSTODY EXCHANGES MUST BE DOCUMENTED BELOW. 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