Document 7RqRBO8pDYQ5R6oKVaRv6GoM8

FILE NAME: Warning Labels (WL) DATE: 1946 DOC#: WL001 DOCUMENT DESCRIPTION: Industry Warning Labels STATE OF PENNSYLVANIA CITY OF PHILADELPHIA, to wit: NOW COMES JAKE LAUGHLIN, who after being duly sworn, makes oath as follows: 1. I am a paralegal employed by the Locks Law Firm of Philadelphia, Pennsylvania. 2. On November 18, 2014 I traveled to the Othmer Library of Chemical History, located at 315 Chestnut Avenue, Philadelphia, Pennsylvania. 3. While at the library, I reproduced the following publications: Warning Labels, 1946, Pages 1-63 4. These digital images were captured from the original publications housed at the archival section of the Othmer Library of Chemical History, The original publications are the property of the Othmer Library of Chemical History, and were returned to their custody following their reproduction. Each of these documents is over 20 years old and were found at a library of chemical history, where they would be expected to be maintained. I declare under penalty o f perjury under the laws of the State o f Pennsylvania that the foregoing is true and correct. Executed this 19th day of November, 2014. NOTARY: Subscribed and sworn to this 19th day of November, 2014, before me, the undersigned, a notary public in and for the City of Philadelphia and State of Pennsylvania, and as witnessed by my hand and official seal. My commission expires the ' / day of Notary Signature and # ^COMMONW EALTH O F PENNSYLVANIA ,, ,, . N O T A R I A L SEAL INIECE D. GOSHA, Notary Public City of Philadelphia, Phila. County M y Commission Expires June 14,2016  io w MANUAL L -l--A GUIDE FOR THE PREPARATION OF WARNING LABELS FOR HAZARDOUS CHEMICALS Adopted 1945 Revised April 1946 The development of new chemical products and th8 introduction of chemical processes into ever-widening fields has accentuated the need for furnishing appropriate information in those cases where special precautions are nece33ary. Many chemicals present no hazards in normal handling and storage and for these products no precautionary labels are necessary. The education of employees regarding chemical hazards is, and must remain, the direct respon sibility of their employers. However, such hazards are not confined to employees alone, and infor mation concerning them should, so far as practicable, reach every person using, transporting, or storing chemicals. The most practical means for. the seller to disseminate this information appears to be by labels affixed to containers of hazardous chemicals, bearing appropriate precautionary statements and instructions stated as simply and briefly as circumstances permit. In the interest of uniformity and more adequate labeling of chemical products, the Manufac turing Chemists' Association has prepared this Manual for the benefit and guidance of its members. A series of definitions is included in Schedule 1 in order that the terms used may be clearly under stood. In addition to the general recommendations contained herein, the MCA has prepared sug gested labels for Specific products. These have been printed as Manual L-2, which will be supple mented from time to time as additional recommended labels'are developed. A precautionary label doea not take the place of safety equipment such as airline respirators, gas masks, clothing, shoes, etc. goggles. Individual statutes, regulations or ordinances may require that particular information b included on a label or that a specific label be affixed to a container. In each case, the requirements of these laws should also be studied. The warning labels suggested in this Manual should be used in addition to, or in combination with, any label required by law.9 \V . h r*5 . i I s :- M 16 m THE CHEMISTS' CLUB A --------- LT8RAHY--------- WARNING LABELS PART 1 GUIDE FOR THE PR EPA R A TIO N . OF W ARNING LABELS FOR HAZARDOUS CHEMICALS PART 2 ILLU STRATIVE W ARNING LABELS FOR HAZARDOUS C H EM IC A LS THEOTHMER LIBRARY OF CHEMICAL HISTORY CHEMICALHERITAGE FOUNDATION * Federal statutes include; Food and Drug Administration, Federal Security Agency, , Federal Security M ANUFACTURING CHEMISTS' ASSO CIA TIO N OF THE UNITED STATES BOB W o o d w a rd , Bldg/ W a s h in g to n 5 , D. C, I PREPARATION OF PRECAUTIONARY LABELS The basic considerations in the preparation of a precautionary label for any chemical product (includingmixtures) are: 1) Determination of the hazards present in the particular chemical product, 2) Selection of appropriate statements for each significant hazard inherent in the product. 3) Arrangement of statements in the order of emphasiB desired. The moat frequently encountered hazards have been classified by the MCA into 10 types as listed in Schedule 2. Set opposite each class are statements illustrating characteristic precautions usually required for that type of hazard. Many chemical products will have more than one type of hazard, in which case appropriate statements for each significant type should be included on the label. Most chemical products con tain impurities. When these are present in harmful quantities, appropriate warnings and precau- * '1 be included on the labels. As each chemical product must be treated individually, there will be many instances in which the illustrative statements will not be applicable either because.they do not accurately express the degree of hazard or because they fall to cover the particular characteristics. In such cases, suitable statements should be selected from Schedule 3. This Schedule presents a more comprehensive list of statements arranged in columnar form, and grouped as follows: A Signal Word B Hazards Precautionary Measures Instructions, in Case of Accident Column A--The degree of hazard can bo expressed only In relative terms. The purpose is two-fold : to Indicata to the reader the comparative seriousness of the danger involved in handling a given product and to call attention to th precautionary instructions which should immediately follow. The "signal words" recommended are, in the order of dimin ishing severity of hazard, (1) DANGER; (2) WARNING; (3) CAUTION. Example: WARNING! Column B--From this column should be selected the phrase (or phrases), that moat accu rately describes the principal hazard. This la placed on the same line as the "signal word." Example: WARNING! FLAMMABLE If other significant hazards are present, they should be tabulated under, the principal hazard. Column C--The appropriate statement of "precautionary measures" shonld be chosen from Column C and should follow on subsequent lines. Example: WARNING! FLAMMABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with 3kin. Mipuncturing Giemiia' Anacinion oi ihe (tailed Soin GENERAL PRINCIPLES In the preparation of any precautionary label the following principles should first be con sidered : 1) Each chemical product (including mixtures) presents a distinct problem and must be treated individually, in the light of its own characteristics. 2) Extreme care should be exercised in the choice o1terminology. Statements should be brief and simple. 3) On labels'for different products, uniformity in language to indicate the same hazards is most desirable in order to gain greater understanding through standardization. 4) Precautionary statements must be accurate, selectively chosen, and expressed in clearly defined terms. To be effective they should be used only when and to the extent necessary. Labeling of a relatively harmless product so as to indicate that it is hazard ous, as well as the .failure to give adequate notice of a hazard, will develop a disregard for labels and defeat their purpose. For example, if the word "POISON" is to retain its usefulness on a label, it should be applied exclusively to those jfroducts (1) which are poisons according to a definite toxicity standard*, or (2) with which it is associated through common usage, or (3) for which its use is prescribed by law. In all other cases the relative degree of the hazard can .be better indicated by the use of signal words such-as: "DANGER" to cover extremely serious hazards; "WARNING" to cover less serious hazards; and "CAUTION" to cover minor hazards, together with a descriptive statement of the hazard. 5) Chemical names should be those recommended by the American Chemical Society. 6) The use of a non-descriptive code designation or trade name as the only identification . of a hazardous chemical should be avoided. If for any reason, it is undesirable toshow the chemical name, or if the chemical name is so complex as to be meaningless except to the trained chemist, the label should state the type of chemical, e.g., "corposive acid,", "lead compound." 7) The following subject matter should be considered for inclusion on a precautionary label: * ' . . 1. Chemical name 2. "Signal word" (DANGER-WARNING-CAUTION) designating degree of hazard (Column A, Schedule 3) 3.. Affirmative statement of "hazard" (Column B, Schedules) 4. "Precautionary measures" covering actions to be followed or avoided (Column C, Schedule 3) 6. "Instructions in cose of accident," where advisable (Column D, Schedule 3) 8) Warning labels should be printed in easily legible type, which ia in contrast by typog raphy, layout, or color with any other printed matter on the label and should be placed conspicuously on containers. Legibility may be preserved with a suitable protective coating. to Include only chemicals cnpable of causing acute effects b y ingestion and inhalation, the principal modes of entry into the body. This definition excludes chemicals capable of cousin? injuries as a result of skin absorption o r of chronic, exposure by inhalation, because the variable actions and effects of chemicals' with these characteristics preclude a practical mean of measuring th iir hazards. I I ! i Schedule 1 DEFINITIONS Manual L-l Flammable Liquid1--An inflammable1 liquid is any liquid which gives off inflammable vapora (aa determined by flash point from TagUabue's open-cup tester, as used for teat of burning oils) at or below a temperature of 80* F. Extremely Flammable Liquida--An extremely flammable liquid is a liquid which gives off flam mable vapors (as determined by flash point from Tagliabue's open-cup tester, as used for test of burning oils) at or below a temperature of 20 F. Corroaius 2--(Physiological)--A corrosive is an agent which In contact with living tissue will cause more or less severe destruction of tissue by chemical action. Irritant---(Physiological)--An irritant is an agent which in contact with living tissue will induce either immediately or after prolonged or repeated contact a more or less severe local tissue reaction not leading directly ,to destruction of tissue. Sensitizer ---(Physiological)--A sensitizer is a material which as ordinarily handled does not necessarily caus any discernible reaction in living tissue but which after initial or re peated contact with the tissue of. some individuals may, at a later date, produce a prompt', inflammatory reaction on contact, even in minute amounts, with the tissue of the same individuals. Dusts8--Solid particles generated by handling, crushing, grinding, rapid Impact, detonation and decrepitation of organic or inorganic materials Buch as rock, ore, metal,, coal, wood, grain, etc. Dusts do not tend to flocculate except under electrostatic forces; they' do not diffuse in air but settle under the influence of gravity. Fumes 3--Solid particles generated by condensation from the gaseous state, generally after volatili zation from molten metals, etc., and often accompanied by a chemical reaction such as oxidation. Fumes flocculate and sometimes coalesce. Mists *--Suspended liquid droplets generated by condensation from the gaseous to the liquid state or by breaking up a liquid into a dispersed state, such as by splashing, foaming, and atomizing. Gases 8--Normally formless fluids which occupy the space of enclosure and which can be changed to the liquid or solid state' only by the combined effect of increased pressure and decreased temperature. Gases diffuse, ^ Vapors *--The gRseoua form of substances which are normally, in the solid or liquid state and which can be changed to these states either by increasing the pressura or decreasing the the temperature alone. Vapors diffuse. Poison2--Poison means a substance which, when taken by mouth in amounts of 60 grains (4 grams) or less, or when inhaled in concentrations of less than 200 parts per million by volume in th air, rapidly (within 6 or 10 minutes) jeopardizes life by other than mechani cal or physical action. . Note: This definition of "Poison" is based on practical considerations only, as an aid in determining, generally, when the word "Poison" should Lb included on a warning label. Sea General Principles 4. Mixture 2--A physical commingling of two or more substances which may or may not bear a fixed.. proportion to one another and which have not reacted chemically with one another. . S, 1ICC dfinition. While the term `'inflammable" is used by the ICC, the preferred form "flammable" I* used in this Manual. a MCA definition. 3 As defined in Chapter II "Engineering Control of the Air Contamination of the Working Environment" (Allen D. Brandt, D.Sc.) page 198, "Manual of Indoetrial Hygiene," USFHS. 5 Manual Mr.ufai.tiin Chcmim1 Aodion of iht TJniirf Saia Column D--When it is advisable to Include instructions in case of accident, the appropriate statements may be selected from this column. Instructions in case of accident to indi viduals are valuable but should be limited to recognized first aid procedures based upon simple methods and commonly available materials. Instructions for strictly medical treat ment should be omitted except when specifically required by law. Because of the serious and lasting effects that may result from eye injuries, a recommendation to obtain medical attention should accompany any specific instruction directed to the treatment of the eyes. I f th e statem ents fro m Schedule 3 fa il to m eet th e exact needs, they should be modified to ' suit. In the example shown, toluene, no phrase from this column appears to be necessary. While every compound carries some hazard, if improperly used, it is impractical to cover every possible contingency on a label.. Efforts should be directed toward naming the serious hazards, and warning against such abuses and accidents as are likely to be encountered under normal con ditions. There Hre scarcely any means of measuring in absolute terms the relative seriousness of hazards, and the recommendations in Schedule 3 only contemplate their division into two or three degrees of. intensity. It follows that of two compounds one may be less hazardous than the other and yet may carry the same warnings and cautions. Instruction for handling and storage of containers should be included where conditions indi cate their need. These instructions should take into consideration both the characteristics of the chemical product and the limitations of the type or types of container in which it ia packed. Schedule 4 presents suggested labels for samples of experimental products for which full data regarding hazards are not yet known. Schedule 5 illustrates the application of caution statements to three specific products. In the case of toluene, the statements used are similar to those given in Schedule 2 for a compound or mixture having hazards in classifications I-B and IV. The second example, aqueous hydrofluoric acid, represents a very special case where the particular hazards require modification of the stand ard statements. The third example is that of a label for a proprietary compound or mixture. l ! i I Manu*l L-l V. Gases and Vapors Physiologically Inert. CAUTIONI VAPOR REDUCES AVAILABLE FOR ING Use with adequate ventilation, Keep container closed. OXYGEN BREATH- VI. Harmful, Dusts. CAUTION! HARMFUL DUST Avoid repeated breathing or skin contact. Wash thoroughly before eating or smoking. Keap away from feed or food products. VII. Skin Irritants--Corrosive. DANGER! CAUSES SEVERE BURNS Do not get in eyes. Do not get on skin. Do not get on clothing. In case of contact, immediately flush skin or eyes with plenty of water; for eyes, get medical attention. Remove and wash, clothing before re-uae. VIII. Materials Causing Skin Irritations after Repeated or Continued Contact. CAUTION1 MAY CAUSE SKIN IRRITA TION Avoid prolonged or repeated contact. IX. Materials Toxic through Vapor Inhala tions or Skin Absorption. WARNING! ABSORBED THROUGH SKIN VAPOR HAZARDOUS Avoid contact with skin or clothing. Avoid breathing vapor. In case of exposure, remove to fresh air. Immediately wash with soap and plenty of water. Remove and wash clothing before X. Toxic if Taken Internally. Applies to ma terials covered by statutory definition of poison "liable to be destructive of human adults in doses Df 60 grains or less (4 gma.)1' or to any material toxic in amounts likely to be taken internally through easily anticipated errors. POISON If not covered by regulation or definition (ace Gen eral Principles 4) a typical label might read: DANGER! MAY BE FATAL IF SWALLOWED Do not take internally. Mnmial L-l Mjouhnnrin Chimiiti* Anocblion of ih> Untirt Staci ' Schedule 2 CLASSIFICATION OF HAZARDS Class Typical Label I. Flammable Liquids and Oxidizing Agents which Support Combustion. (Flash points for liquids are determined by Tagliabue's Open-Cup Method). A. Flash point 20 F. or below. / DANGER f EXTREMELY FLAMMABLE Keep away from heat and open flame. Keep container closed. B. Flash point above^O" to 80 F. in clusive. WARNING! FLAMMABLE. . Keep away from heat and open flame. Keep container closed. - II. Flammable Solids and Oxidizing Agents as Classified by the ICC. CAUTIONI EXPOSURE MAY CAUSE FIRE OR CREATE FIRE HAZARD Keep away from heat and open flame. Keep container closed. In case of contact, immediately flush with plenty of water; remove and wash clothing before re-uae. III. Vapors Immediately Toxic or Extremely Irritating Even on Exposure for a Short Time or to Low Concentrations. DANGER! VAPOR EXTREMELY. HAZARDOUS Do not breathe vapor. Do not get on akin. Do not get in eyeB. Keep container closed and away from heat. Keep away from feed or food products. Have air line respirator or gas mask ap proved by U. S. Bureau of Mines specifi cally for (name of chemical) available for emergency. IV. Vapors Hazardous from Prolonged or Repeated Exposures, or Exposure to Higher Concentrations. WARNING! VAPOR HARMFUL Use only with adequate ventilation.. Avoid prolonged or repeated breathing of vapor. Keep container closed and away from heat. 6 . Minuriaotmn Chtmim Aodnior of lhe United Suiti Schedule 4 LABELS FOR EXPERIMENTAL SAMPLES Manual L-l The labeling of experimental samples of new products presents unusual problems. All of the properties or possible uses of a product are seldom known. The following safeguards are therefore recommended : 1. Samples of a product already on the market should carry the same warning label as a commercial shipment. 2. The following label is suggested for samples of any material that has never been in commer cial production unless (1)- the material is known to be wholly innocuous, or (2) the dangers are limited to known hazards and appropriate cautions are submitted. SAMPLE ( ---------------------------------------- -- ) Name or Description of Product FO R EXPERIMENTAL USE ONLY CAUTION! The chemical, physical and toxicological properties of this product have not been fully investigated and its handling or use may be hazardous. Exercise due care. 3. The identity of the sample, indicated in parentheses above, should be as clear as possible. Wherever feasible, it should be the name of the compound or mixture, and in any case it should be the best possible identification to aid the user in knowing with what he is concerned.. 4. Where there are significant known hazards they should be so indicated. 5. The above label may be used in the case of old products being considered for new uses. Schedule 5 SPECIMEN PRODUCT LABELS The following specimen labels illustrate the application to specific products of the principles set forth in this Manual: Product Combining Hazards of Class I-B and IV (Schedule 2) Chemicals. TOLUENE WARNING! FLAMMABLE. Keep away from heat and open flame. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with akin. Manual L-I Minwficturint Gicniiia' Awoniiion of the Uniicd Sam Schedule 3 RECOMMENDED LABEL CAUTIONS A. Signal Words B. Hazards c. Precautionary Mcasarea D. Instructions in Cose of Accident Flammability a. Extremely Fiammablefflash point 20 F. or below.) b. Flammable (fiseh p o i n t above 20e to RO* F. inclu sive). c. Exposure May Cause Firs . or Create Fire Hazard. a. Keep a w a y f r o m heat (sparks) and open flame. b. Keep container closed (and away from heat). Volatility a. Highly Volatile. i>. Volatile (Solvent or Liquid), a. Keep out of aim'and away from heat. b. Keep container closed (and swey from heat). Inhalation a. DANGER I b. WARNING! c. CAUTION I a. Vapor Extremely a. Do not breathe vapor (or) Hazardous. Avoid breathing vapor. b. May be Fatal if Inhaled. b. Avoid prolonged or repeat c. Vapor Harmful. ed breathing of vapor. d. Vapor Reducecs. UOsex y(gonelyn) with adequate Available for Breathing. ventilation, e. Harmful D ust d. Avoid prolonged breathing f. Causes Irritation to. Eyes, of dust. Nose and Throat. Contact a. In case of exposure remove to fresh air. b. Have air-line respirator or gas mask approved by U. S. Bureau of Mines specifi cally for (name of chemi cal) available for emer gency. .Corrosive Liquid. b. Causes (Severe) Burns. c. Dangerous Because (Rap idly) Absorbed Through Skin. d. Causes Skin Irritation. e. May Cause Skin Irritation. a. Do not get (1) in eyes, (2) on skin, (8) on clothing. b. Avoid contact with (1). eyes. (2) skin, (a) clothing. c. Wash thoroughly beforo eating or smoking. a. Toison (skull A eroash. May he Fatal if Swallowed a. Strong Oxidant. b. Contact with Combustible Material May Cause Fire. Ingestion a. Do not take internally. General b. Keep away from feed or food products. b. Keep dry. c. Store in cool place. d. Keen away from combus tible materials. a. In cose of contact: (1) Immediately flush (sltin or eyes) with plenty of water (for a t leeBt 15 min utes). (For eyes, get med ical attention). (2) Immediately wash with soap and plenty of water. (3) Remove and wash clothing before re-use. a. Get medical attention.. b. In case of spillage, flush with plenty of water. c. In case of spillage, absorb with sand, ashes or oorth. The use of any warning or other statement listed shove is not necessarily limited to the hasard under which it is grouped. The grouping merely indicates tho type of hazard to which given statements most frequently apply. Tho small letters are not Intended to Indicate a correlation botween similarly lettered statements in adjacont columns but are for identification only. The parenthetical word indicsto optional statements. Mnwlwarim Qitmiin' Ancriiilan of ihc Uniied Sam Product Requiring Modified Cautions and First Aid. HYDROFLUORIC ACID, AQUEOUS DANGER! CORROSIVE LIQUID VAPOR HAZARDOUS CAUSES SEVERE BURNS WHICH MAY NOT BE IMMEDIATELY PAINFUL OR VISIBLE Do not breathe vapor. Do not get in eyes, on skin, on clothing. In case of contact' or suspicion of contact: Immediately flush skin with plenty of water until whiteness dis appears, paying particular attention, to skin under nails. Soak affected areas with crushed ice in 70% ethyl alcohol until physician arrives. FlUBh eyes with plenty- of water for at least 15 minutes. In all cases get medical attention. Remove and wash clothing before re-use. Avoid use of greasy ointments. Proprietary Product (e.g., containing fluorine salts) (PROPRIETARY NAME) Contains Fluorine Compounds. WARNING! POISONOUS IF TAKEN INTERNALLY Avoid breathing dust. Flush spillage to sewer with water. .L ' IO / / ! v' Manual L-2 PART II MANUAL L-2 -- ILLUSTRATIVE WARNING LABELS FOR HAZARDOUS CHEMICALS Adopted 1945 Revised 1946 PREFACE This Manual contains warning labels suggested by the Manufacturing Chemists' Association to cover the significant hazards inherent in a large number of industrial chemical products. These products have been selected so as to provide illustrative labels for each major type of hazardous chemical which is of commercial importance. In many cases these labels are applicable to other products which are listed only in the index with appropriate cross references. These labels do not cover impurities which may be present in the products and, except in a few instances, do not include precautionary information regarding the handling and storage of the containers. The manufacturer or packer should in each case include on his label additional warn ings to cover the hazards due to impurities which may be present in harmful quantities and, where the facts so indicate, to cover container handling and storage. Suggested first aid treatment has been included for a few products only. The omission of first aid treatment for other products should not in any case be interpreted to mean that it may not be desirable. Individual statutes, regulations or ordinances may require that particular information be included on a label or that a specific label be affixed to a container as in the case of the Interstate Commerce Commission Regulations for Transportation of Explosives and Other Dangerous Articles. In each case, the requirements of these laws should also be studied. The warning labels suggested in this Manual should be used in addition to or in combination with any label required by law. These labels haveJseen prepared in accordance with the procedure outlined in Part I, M.C.A. Manual L -l "A Guide for the Preparation of Warning Labels for Hazardous Chemicals." The user should familiarize himself with Manual L-l before adapting any of the label statements con tained in Manual L-2 to his products. It is anticipated that Manual L-2 will be supplemented from time to time as additional illustrative labels are suggested or revisions are made. II ACETALDEHYDE DANGERI EXTREMELY FLAMMABLE Keep away from heat and open flam. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing o f vapor. Chill thoroughly before opening. CARBOY LABEL ACETIC ACID, G LACIAL DANGER! CAUSES SEVERE BURNS Do not get liquid or vapor in eyes, on skin, on clothing. . [n case of. contact, immediately flush skin or eyes with plenty of water for a t least 16 minutes; for eyes, get medical attention. C A R BO Y H AN D LIN G A N D STO RAG E G la c ia l A c e tic A c id freezes a t 62 F , form ing hard lumps which may break carboy when moved. Store in area maintalnod above 6 2 F . If frozen, thaw b y carefully moving carb oy to warm area. ALUMINUM DRUM LABEL ACETIC ACID, G LA CIAL DANGER! CAUSES SEVERE BURNS Do not get liquid or vapor in eyes, on skin, on clothing. in case o f contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. DRUM H AN D LIN G AN D STO RAG E G la c ia l A cetic A c id freezes at 62 F , forming hard lumps. S tore in area maintained above 62 F. If frozen, thaw b y moving to warm area. BARREL LABEL ACETIC A CID (80%) DANGER! CAUSES SEVERE BURNS Do not get liquid or vapor in eyas, on skin, i. on clothing. In case of contact, immediately Rush slan or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. j. . BARREL H AN DLIN G A N D STO RAG E Keep out of sun and away from heat. ' Store with bilge bung up. N ever use pressure to em pty. Drain completely. Keep barrel moist; shrinkage may causa leaks. In case o f spillage, flush w ith plenty of w ater. BARREL LABEL ACETIC ACID (56% and 70%) WARNING! MAY CAUSE BURNS Avoid contact with eyes, skin, or clothing. In case of contact, Immediately flush skin or eyes with plenty of water for at least 15 minutes; . for eyes, get medical attention. BARREL H AN DLIN G AN D STO RAG E (U se ante intiructlona at fo r Acelic Acid 80% ) BARREL LABEL ACETIC ACID (28%) CAUTION! MAY CAUSE BURNS Avoid contact with eyes, skin, or clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention, BARREL HAN DLIN G AND STO RAG E (U ie la m a inilrnclioni at fo r Acttic Acid 80% ) Manual Minufmurini Chonito' Aitodtiioa oi ih l/nlicd Sum ACETIC ANHYDRIDE DANGER! CAUSES SEVERE BURNS Do not get liquid or vapor in eyes, on skin, on clothing. Do not breathe vapor. In case o f contact, Immediately flush skin or eyes with plenty o f water for a t least 15 minutes; fo r eyes, get medical attention. ACETONE DANGER! EXTREMELY FLAMMABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged or repeated contact with skin. ACETONYLACETONE CAUTION! VOLATILE SOLVENT Keep away from heat and open flame, Avoid prolonged breathing of vapor. Use with adequate ventilation. Avoid prolonged or repeated contact with skin. Note; Contact with this material stains the skin. A CETYL CHLORIDE DANGER! FLAMMABLE CAUSES SEVERE BURNS Do not allow water to get in container. Keep away from heat and open flame. Keep container closed. Do not get in eyes, on skin, on clothing. Avoid exposure to concentrated vapor. In case o f contact, immediately flush skin or eyes with plenty o f water fo r a t least 15 minutes; for eyes, get medical attention. 14 i ( l " CG M>nufiCiiirta|t Chemin' Anocitrioa ol the Waited Sate, Manual L*2 A C R Y LO N IT R ILE DANGER! FLAMMABLE POISON Do not breathe vapor. Do not get In eyes, on skin, on clothing. Use with adequate ventilation. Keep away from heat and open flame. Keep container closed. # POISON %- FIRST AID TREATMENT .Carry patient to fresh air. Have him lie down. Remove contaminated clothing but keep patient warm. Start the following first aid treatment immediately and C A L L A PHYSICIAN . If patient is conscious and breathing: [1] Break an amyl nitrite pearl ih a cloth and hold lightly over the nose . fo r not more than 15-20 seconds. Repeat every 5 minutes for 25 minutes if recovery is not forthcoming. (2) If this product has been SW ALLO W ED , give patient one pint of 1% Sodium Thiosulfato solution (or soapy water o r mustard water) by mouth every 15 minutes until vomiting occurs, If patient has stopped breathing: G ive artificial respiration until breathing starts. Break an amyl pifrite. a pearl in a cloth and hold lightly over nose for not more than 20 seconds, repeating every 5 minutes for 25 minutes or until, breathing starts. If patient is unconscious but breathing: Break an amyl nitrite pearl in. a cloth and hold lightly over nose for not more than 20 seconds, repeating every 5 minutes for 25 minutes if. recovery is not forthcoming. G ive oxygen from an inhalator. Never give anything by mouth to an unconscious person. In all cases keep patient quiet and warm until a physician arrives. Manual L-2 Mamftaurins Q u ain t' Aiioa'm'on of iht United Sum ALLYL ALCOHOL DANGER! RAPIDLY ABSORBED THROUGH SKIN VAPOR EXTREM ELY HAZARDOUS FLAMMABLE Do no)- get in eyes, on skin, on clothing. Do not breathe vapor. Keep away from h eaf and open flame. Keep container closed. In case of contact, immediately flush skin or eyes with plenty of water for a t least 15 minutes; for eyes, get medical attention. Remove and wash clothing before re-use. Do not take internally. A LLY L CHLORIDE DANGER! HARMFUL AND FLAMMABLE Do not get in eyes, on skin, on clothing. Do not breathe vapor. Keep, away from heat and open flame. Keep container closed. VAPOR CARBOY LABEL ` AM M ONIA, AQUA WARNING! LIQUID CAUSES BURNS VAPOR EXTREM ELY IRRITATING Avoid breathing vapor. Avoid contact-with eyes, skin, or clothing. In case o f contact, immediately flush skin or eyes with plenty o f water for a t least 15 minutes; for eyes, get medical attention. C AR BO Y H AN D LIN G AND STO RAGE Before moving carboy be sure closure is securely Loosen closure carefully. Reap out of sin and away from heat. N ever use pressure to em pty. C om pletely drain carboy before returning, In case o f spillage, flush w ith plenty o f water. fa ttened. 16 G 'C Min(>cn.'cint Qirmii' Anariuian of the United Sow DRUM LABEL AM M ONIA, A Q U A WARNING! LIQUID CAUSES BURNS VAPOR EXTREMELY IRRITATING Avoid breathing vapor. Avoid contact with eyes, skin, or clothing. In case o f contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. DRUM HAN D LIN G AND STO RAG E Keep plug up to prevent leakage; Keep drum out o f sun and away from hash Before removing plug, loosen slowly to relieve pressure. N ever use pressure to empty. Keep lights, fire end sparks away from drum openings. Drum must not be washed out or used fo r other purposes. Replace plug after each withdrawal end return with em pty In case o f spillage, flush with plenty o f w hter. drum. CYLINDER LABEL AM M ONIA, ANHYDROUS WARNING: HAZARDOUS LIQUID AND VAPOR UNDER PRESSURE LIQUID CAUSES BURNS VAPOR EXTREMELY IRRITATING Do not breathe; vapor;Do not get in eyes, oh skin, on clothing. In case o f contact, immediately flush skin and eyes with plenty of water for a t least 15 minutes. Call a physician a t once in case o f bums, especially to the eyes, nose and throat, or if the victim is unconscious. CYLIN DER HAN D LIN G AN D STO RAG E Keep aw ay from heat. Do not store in sunlight, N ever drop cylinders'. Be sure connections are tight. N evar refill cylinder. I. C . C . Regulations prohibit refilling without permission of owner. H a ve gat maiV approved by U . S. Bureau o f Mines' specifically for ammonia service available fo r em ergency. 17 Manual L-2 Mnnunl L-2 Minuliovrin* lic n in i Auotaiion of the Untied AMM ONIUM BICHROM ATE WARNING! FLAMMABLE HARMFUL OUST MAY CAUSE RASH OR EXTERNAL ULCERS KEEP A W A Y FROM H EAT. SPARKS. AND FLAM E. KEEP CONTAINER CLOSED. Avoid contact with skin or eyes. Avoid breathing dust or solution spray. Do not take internally. In case o f contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. Remove and wash clothing before refuse. Use fresh clothing daily. Take hot shower after work using plenty o f soap. AM YL ACETATE CAUTIONI VOLATILE SOLVENT Avoid prolonged breathing of vapor. Use with adequate ventilation. Avoid prolonged or repeated contact with skin. A N ILIN E DANQERI RAPIDLY ABSORBED THROUGH SKIN VAPOR HAZARDOUS POISON Do not get on skin, on clothing. Avoid breathing vapor. Use with adequate ventilation. In case o f contact, immediately flush skin with plenty of water. Remove and wash clothing before IS i C GC o-ANISIDINE WARNING! HAZARDOUS LIQUID AND VAPOR ABSORBED THROUGH SKIN Avoid contact with skin. Avoid breathing vapor. p-ANISIDINE WARNING! HAZARDOUS SOLID AND VAPOR ABSORBED THROUGH SKIN Avoid contact with skin. Avoid breathing dust or vapor. ANTIM ONY TRICHLORIDE DANGERI CAUSES SEVERE BURNS VAPOR HAZARDOUS Avoid contact with eyes, skin, or clothing. Avoid breathing vapor. Keep container closed. In case of centaet, immediately flush skin or eyes with plenty o f water for at least 15 minutes; for eyes, get medical attention. Remove and wash clothing before re-use. A RO M ATIC INDUSTRIAL SOLVENT (F or tolvenU having an initial boiling point not belom 1003 C, and' having n (lath p o in t BOF. o r BELOW , Tagliabue O pen Cup Method t specified by Inlertlale Commerce Commission,) WARNING! FLAMMABLE Keep away from heat and open flame; Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. I? Mianhtw irn Q ualm ' Anocinio of ihi Uniud Saw ARO M ATIC INDUSTRIAL SOLVENT (For solvents having an initial boiling point not below 100C, and having a flash point ABOVE 80F., Tagliabao Open Cup Method at specified by Interstate Commerce Commission) CAUTION! VOLATILE SOLVENT Use with adequate ventilation. A v o id p ro lo ng ed b reath in g o f vap o r. Avoid prolonged or repeated contact with skin. ARSENIC TRICHLORIDE DANfiERI CORROSIVE LIQUID VAPOR EXTREMELY HAZARDOUS POISON `ifc Do not get. in eyes, on skin, on clothing. Do not breathe vapor. Keep container dosed. In case of contact, immediately flush skin or eyes with plenty of water for a t least 15 minutes; for eyes, get medical attention. Remove andwash clothing before re-use. BARIUM NITRATE CAUTION! STRONG OXIDANT CONTACT WITH COMBUSTIBLE MATERIAL MAY CAUSE FIRE Keep container closed and away from combustible material and heat. Sweep up and carefully remove spilled material. Avoid repeated contact with skin. Do not take internally. ( ! (' GO ' ' ii G M.oufaquring Chcmim' Auociixioa of ihc Ututri Sum Manual BARIUM OXIDE CAUTIONI MAY CAUSE SKIN IRRITATION Avoid contact with skin. Keep away from feed or food products. Do not fake internally. BARIUM PEROXIDE CAUTIONI STRONG OXIDANT CONTACT WITH COMBUSTIBLE MATERIAL MAY CAUSE FIRE Keep container closed and away from combustible materia! and heat. Sweep up and carefully remove spilled material. Avoid contact with skin. Do not take internally. BENZENE (BENZOL) DANGER! EXTREMELY FLAMMABLE VAPOR HARMFUL --POISON Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. BENZIDINE WARNING! HAZARDOUS SOLID AND VAPOR RAPIDLY ABSORBED THROUGH SKIN Avoid breathing dust or vapor. Avoid contact with skin. In case of contact, immediately wash with soap and plenty of water. Manual CARBOY LABEL BENZOYL CHLORIDE WARNING! CAUSES BURNS VAPOR IRRITATING A v o id c o n ta c t w ith skin .or e y e s . Avoid breathing vapor. In case o f contact, Immediately flush skin or eyes with plenty of water for a t least 15 minutes; for eyes, get medical attention. C A R B O Y HAN D LIN G A N D STO RAG E v Before moving carboy be sure closure is securely fastened. Loosen closure carefully. Keep out o f sun and away from beat. Never use pressure to empty. Com pletely drain carboy before returning. In case of spillage, flush with plenty o f water. CARBOY LABEL BENZYL CHLORIDE WARNING! CAUSES BURNS Avoid contact with eyes, skin, or clothing. Avoid breathing vapor. In case o f contact with liquid, immediately wash skin with soap and plenty of water; fliish eye* with water fo r at least 15 minutes and get medical % attention. . Do not transfer to ordinary metal containers without first adding stabilizer. S e t instructions from manufacturer. DRUM LABEL BENZYL CHLORIDE WARNING! CAUSES BURNS Avoid contact with eyes, skin, or clothing. Avoid breathing vapor. In case o f contact with liquid, immediately wash skin with soap and plenty o f water; flush eyes with water for a t least 15 minutes and get medical attention. The Benzyl Chloride in this drum contains a stabilizer. Before transferring, get instructions from manufacturer. 22 Minufmuiitit CjjMMnT Anoditioa ai dw United Sara Manual r BROMINE DANGERI CAUSES SEVERE BURNS Do not get on skin or in eyes, Do not breathe vapor. In case o f contact, immediately flush skin or eyes with plenty of water for at least 15 minutes: keep skin area wet with crushed ice in 70% ethyl alcohol until physician arrives. BUTYL ACETATE (normal) CAUTION! VOLATILE SOLVENT Avoid prolonged breathing of vapor. Use with adequate ventilation. Avoid prolonged or repeated contact with skin. BUTYL ALCOHOL (normal or secondary) . CAUTION! VOLATILE SOLVENT Avoid prolonged breathing of vapor. Use with adequate ventilation. Avoid prolonged or repeated contact with skin. BUTYL ALCOHOL (tertiary) WARNING! FLAMMABLE Keep away from heat and open flame. Keep container dosed. Use with adequate ventilation. Avoid prolonged breathing o f vaporAvoid prolonged or repeated contact with skin. 23 Manual L-2 Mmuhgmim Chcnim* AjKXinion of ihc Dniitd Saw BUTYLAM INE (normal) WARNING: FLAMMABLE MAY CAUSE SKIN IRRITATION Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid exposure to vapor. Avoid contact with skin or eyes, in case of contact, immediately flush skin or eyes with plenty o f water for at feast 15 minutes; for eyes, get medical attention. p-tert. BUTYLCATECHOL WARNINGS CAUSES SKIN IRRITATION CAUSES BURNS WHEN MOIST Do not get in eyes, on skin, on clothing. In case of contact, immediately wash skin with soap and plenty of water; flush eyes with water for at least 15 minutes and get medical attention. BUTYL CHLORIDE (normal) DANGER! EXTREMELY FLAMMABLE Keep away from heat and open flamo. Keep container closed, Use with adequate ventilation. Avoid prolonged breathing o f vapor. Avoid prolonged or repeated contact with skin. BUTYL ETHER (normal) WARNINGI VOLATILE SOLVENT Use with adequate ventilation. Avoid prolonged breathing o f vapor. Avoid prolonged or repeated contact with skin. C A U T IO N ; Dry ethers tend to form explosive peroxides. Do not use material if it liberates iodine from acidified aqueous iodide solutions. 24 M inna] L-a CALCIUM CYANIDE DANGER! LIBERATES POISONOUS GAS A v o id breathing gas o r dustAvoid contact with skin .' Keep away from acids. Store away from feed or food products. Keep container tightly closed and dry. POISON FIRST AID TREATMENT ( V ie tam e f i n l aid ircnimenl at recommended fo r Inorganic C ytm idet). CARBON DISULFIDE DANGER! EXTREMELY FLAMMABLE VAPOR HARMFUL HIGHLY VOLATILE POISON <# Keep away from fire, sparks, or heated surfaces. Store in cool place and keep container closed. Avoid breathing vapor. Avoid contact with skin. CARBON TETRACHLORIDE ' WARNING! VOLATILE SOLVENT VAPOR HARMFUL Use with adequate ventilation. Avoid prolonged or repeated breathing o f vapor. Avoid prolonged or repeated contact with skin. Do not take internally. CHLORINATED NAPHTHALENE Avoid repeated contact with skin. Avoid repeated inhalation of the fumes and dust. il Ch(milu' Anodukm of the United 5atw CAUSTIC SODA (SODIUM HYDROXIDE) t WARNING! CAUSTIC SODA IS CORROSIVE BURNS SKIN AND EY ES Avoid contact with body or clothing. Do ro t take internally. PRECAUTIONS When handling Sodium Hydroxide wear goggles or face shield and avoid all contact with skin. While making solutions, add Sodium Hydroxide slowly to surface o f solution to avoid violent spattering. In ease of accidental contact with skin, immediately flush affected-parts with water and wash with vinegar. For eyes, flush, freely with water for a t least 15 minutes and get medical attention. IN THE CASE OF PROPRIETARY COMPOUNDS CONTAINING CAUSTIC ALKALI: U - r ------------ ----- ) Name of Product WARNINGI CONTAINS CAUSTIC A LK A LI WHICH IS CORROSIVE BURNS SKIN AND EYES Avoid contact with body or clothing. Do not taka internally. PRECAUTIONS (U te tam e precaution at fo r Sodium Hydroxide, ubttUuling name o f product for S o d iu m Hydroxide.) CHLOROBENZENE, MONO WARNINGI VAPOR HARMFUL Use with adequate ventilation. Avoid contact with skin or clothing. Avoid prolonged breathing o f vapor. Mmnfanm'PA Chenuw' Auodnioo ct the United Sam ______ M lM t l CHLOROFORM WARNING! VOLATILE SOLVENT VAPOR HARMFUL Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. Do not take internally. CHLOROTOLUENE, MONO ? CAUTION! VAPOR HARMFUL Use with adequate ventilation. Avoid prolonged breathing of vappr. CHROMIC A CID WARNINGI CONTACT WITH COMBUSTIBLE MATERIAL MAY CAUSE FIRE CAUSES SEVERE BURNS KEEP CONTAINER CLOSED. Avoid contact with skin or eyes. Avoid breathing dust or solution spray. Do not take internally. In case of contact, immediately flush skin or eyes with plenty of water for at least IS minutes; for eyes, get medical attention. Remove and wash clothing before re-use. Use fresh clothing daily. Take hot shower after work using plenty of soap. COAL TAR CREOSOTE (CREOSOTE OIL) CAUTION! MAY CAUSE SKIN IRRITATION Use only with adequate ventilation. Avoid prolonged or repeated contact with skin. Avoid prolonged breathing of vapor. i M u tu m l CYANIDES, INORGANIC (excluding Liquid Hydrocyanic Acid and Calcium Cyanide) Name o f Product DANGER! CONTACT WITH ACID LIBERATES POISONOUS GAS Avoid breathing gas or dust. Avoid contact with skin. Keep away from feed or food products. Keep container closed and store in a dry place. ffc POISON ^ FIRST AID TREATMENT C a rry patient to fresh air. Have him lie down. Remove contaminated clothing but keep patient warm. Start the following first aid treatment immediately and C A L L A PH YSIC IAN . If patient is conscious end breathing: ( 1) Break an amyl nitrito pearl in a doth and hold lightly over the nose fa r not more than 15-20 seconds. Repeat every 5 minutes for 25 minutes if recovery is not forthcoming. (2) If this product has been S W A LLO W E D give patient one pint o f 1% Sodium Thiosulfate solution [or soapy water or mustard water) by mouth every 15 minutes until vomiting occurs. [Eliminate this for liquid H C N ). If patient has stopped breathing: G ive artificial respiration until breathing starts. Break an amyl nitrite pearl in a cloth and hold lightly over nose for not more than 20 sec onds, repeating every 5 minutes for 25 minutes or until breathing starts. If patient is unconscious but breathing:. . . Break an amyl nitrite pearl in a cloth and hold lightly over nose for not more than 20 seconds, repeating every 5 minutes for 25 minutes if recovery is not forthcoming. G ive oxygen from an inhalator. Never give anything b y mouth to an unconscious person. In all cases keep patient quiet and warm until a physician arrives. ( ( Manusl L-2 CRESOL (CRESYLIC ACID) DANGER! RAPIDLY ABSORBED THROUGH SKIN CAUSES SEVERE BURNS Do not get on skin or in eyes. Do not breathe vapor. Do not take internally. In case o f contact, immediately flush skin or eyes with plenty of water for a t least 15 minutes; for eyes, get medical attention. Remove and wash clothing before re-use. CYCLOHEXANE DANGER! EXTREMELY FLAMMABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. CYCLOHEXANOL CAUTION! VAPOR HARMFUL Use with adequate ventilation. Avoid prolonged breathing o f vapor. Avoid prolonged or repeated contact with skin. DICHLOROETHYLENE WARNING! FLAMMABLE VOLATILE SOLVENT Keep away from heat ahd open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with skin. Do not take internally. I Manual L-2 Mlnuft.until Clunuii' /uodalion of the Uiilini Sate* DICHLOROETHYL ETHER WARNING! VOLATILE SOLVENT VAPOR HARMFUL Use with adequate ventilation. Avoid prolonged or repeated breathing of vapor. Avoid prolonged or repeated contact with $iun. Do not ta le internally. DICHLOROPHENOL (For nil itom enc dichlorophenols) WARNING! MAY CAUSE BURNS Avoid contact with skin. ..Avoid breathing vapor. Do not take infernally. In ease of contact, immediately wash with soap and plenty o f water. DIETHYLAM INE DANGER! EXTREMELY FLAMMABLE MAY CAUSE SKIN IRRITATION Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid exposure to vapor. Avoid contact with skin or eyes. In ease o f contact, immediately flush skin or ayes with plenty o f water for a t least 15 minutas; for eyes, gat medical attention. 30 . ( f Miaufanccini ChnnUii' Allocation of the United Smn M inn ] L-2 D IO X A N E (1,4-DIETHYLENE DIOXIDE) WARNING! FLAMMABLE VOLATILE SOLVENT Keep away from beat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. C AU TIO N I Dry ethers tend to form explosive peroxides. Do not use material if i f liberates iodine from acidified aqueous iodide solutions. ETHYL ACETATE WARNING! FLAMMABLE VOLATILE SOLVENT Keep away from heat and open flame. Keep container closed. Ufa with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. ETHYL BROMIDE WARNING! VAPOR HARMFUL Use with adequate ventilation. Avoid prolonged , breathing of vapor. Keep out o f sun and away from heat. Keep container closed. ETHYL CHLORIDE DANGER! EXTREMELY FLAMMABLE Keep away from heat, sparks, and open flame. Use with adequate ventilation. Keep container closed, out of sun and away from heat.. Mmafiouriin Qitmim' Aiioanioa of the Caned Sum ETHYLENE CHLOROHYDRIN DANGER! RAPIDLY ABSORBED THROUGH SKIN VAPOR EXTREMELY HAZARDOUS Do not- get on skin or clothing. Do not breathe vapor. Do not take internally. In case of contact, immediately wash with soap and . plenty o f water; remove ana wash clothing before re-use. POISON ^ FIRST AID TREATMENT If swallowed, make patient vomit immediately (finger down throat) or give warm mustard water or salt water freely. General: Keep patient warm; if conscious give black coffee. C all physician. Note: Do not give adrenalin. ETHYLENE DIBROMIDE WARNING! VAPOR HARMFUL Avoid breathing vapor. Avoid contact with eyes, skin, or clothing. In case of contact, immediately wash skin with soap and plenty of water; flush eyes with water for at least 15 minutes and get madical attention. Remove , and wash clothing before re-use. Do not take internally. ETHYLENE DICHLORIDE WARNING! FLAMMABLE VOLATILE SOLVENT VAPOR HARMFUL Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged or repeated breathing o f vapor. Avo id prolonged or repeated contact with skin. Do not take internally. 32 i c ( c c o. o Minufaciniintt QieoJit)' Aisocinioa of tie United Sum STannnl L-2 ETHYLENE GLYCOL M ONOMETHYL ETHER CAUTION! VOLATILE SOLVENT Avoid prolonged breathing o f vapor. Use with adequate ventilation. Avoid prolonged or repeated contact with skin. ETHYL ETHER DANGER! EXTREMELY FLAMMABLE HIGHLY VOLATILE Keep away from heat and open flame. Keep container tightly dosed. C AU TIO N ! Dry ethers tend to form explosive peroxides. Do not use material if it liberates iodine from acidified aqueous iodide solutions. ETHYL FORMATE DANGER! EXTREMELY FLAMMABLE Keep away from heat, sparks, and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing o f vapor. ETHYL METHACRYLATE MONOMER WARNING! FLAMMABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing o f vapor. Avoid contact with skin or-clothing. MiniTiccuriftg Ornai)' Auoduios al ibt Unirei Sorte FORMALDEHYDE WARNING) CA USES IRRITATION OF SK IN, EYES, NOSE AND THROAT Avoid prolonged or repeated contact. Avoid prolonged breathing o f vapor. Use with adequate ventilation. POISON CA LL A PHYSICIAN AT ONCE FIRST AID Internally; G ive milk freely, or one glassful of water containing I table spoonful of ammonium acotate. Produce vomiting with a pint or more of warm salt water (I cupful per quart) or warm soapy water. Repeat throe times. Follow with milk ond raw eggs. BARREL LABEL FORMIC ACID WARNING! CAUSES BURNS Avoid breathing vapor. Avoid contact with skin or eyes. In easB of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes, get medical attention. BARREL H AN D LIN G AND STO RAG E Keep out o f sun and aw ay from heat. Store with bilge bung up. N aver use pressure to empty. Drain com pletely. Keep barrel m oist; shrinkage may cause leaks. In cate o f spiilage, flush w ith plenty o f w ater. 34 ( . ( oc o Macuftnoo* Qicmlm' AnocJmon of iKt UniitJ Si CARBOY LABEL FORMIC ACID WARNINGI CAUSES BURNS Avoid breathing vapor. Avoid contact with skin or eyes. In case of contact, immediately flush skin or e y e s . with plenty o f water for a t least 15 minutes; for eyes, get medical attention CARBO Y HAN DLIN G AND STO RAG E Before moving carboy be sure closure is socuroly fastened. K e e p out of sun and away from heat. N ever use pressure to empty. Com pletely drain carboy before returning. In case of spillage, flush with plenty of water. CARBOY LABEL HYDROCHLORIC A CID WARNING! CAUSES BURNS Avoid breathing vapor. Avoid contact with skin or eyes. In ease of contact, immediately flush skin or eyes with plenty of water for at laast 15 minutes; for eyes, get medical attention. C ARBO Y HAN D LIN G AND STO RAG E Before moving carboy, be sure closure is securely fastened. Loosen closure carefully. Keep out of sun and away from heat. . A N ever use pressure to empty. Com pletely drein carboy before returning. In case of spillage, flush with plenty of w ater. Manual L-2 Mtrmliaurini Cbrmiili' Aliodilion of [he United Sam HYDROCYANIC ACID, LIQUID DANGER! POISON GAS Do not breathe gas. Avoid contact with skin. Do not drop container. Keep cool and away from open flame. POISON FIRST AID TREATMENT (V ie same first aid treatment at recommended fo r fo rg an ic Cyanides) HYDROGEN PEROXIDE (stronger than 2 5 volume and not exceeding 130 volume) CAUTIONI STRONG OXIDANT Avoid contact with eyes or skin-- wear goggles and rubber gloves. Avoid contact with combustible materials. Drying of this concentrated product on clothing or other combustible materials may cause fire. In case o f contact, immediately flush skin or eyes wifh plenty of wafer for a t least 15 minutes; for eyes, get medical attention. Avoid contamination from any source, including metals, dust, e tc .. Such contamination may cause rapid decomposition, generation of large quantities of oxygen gas, and high pressures. C O N TAIN ER H A N D LIN G AN D STO RAGE Star in original closed container. Kesp out of sun and away from heat. 6 sure that the container vent Is working satisfactorily. Do not add any other product to this container. W han empty, rinse thoroughly with clean w ater. 36 ( I Minu/inufin Chemin' Auctiuipt ol ihc Unmd Suit HYDROGEN PEROXIDE (25 volume) CAUTION! STRONG OXIDANT Avoid contact with eyes or skin-- wear goggles. and rubber gloves. Avoid contamination from any source, including metals, dust, etc. Such contamination may cause rapid de composition, generation of large quantities o f oxygon gas, and high pressures. & CON TAIN ER HAN D LIN G AND STO RAG E ' Store in original closed container. Ba sure tha t the container vent is working satisfactorily. Do not add any other product to this container. W hen em pty, rim e thoroughly with d ean w ater. Manual L-2 HYDROFLUORIC ACID, AQUEOUS DANGER! CORROSIVE LIQUID VAPOR HAZARDOUS CAUSES SEVERE BURNS WHICH MAY NOT BE IMMEDIATELY PAINFUL OR VISIBLE Do not breathe vapor: Do not get in eyes, on akin, on clothing. In case of contact or suspicion of contact: Immediately flush skin with plenty of water until whiteness disappears, paying particular attention to skin under nails. Soak affected areas with crushed ice In 70% ethyl alcohol until physician arrives. Flush eyes with plenty of water for at least 15 minutes. In all caies get medical attention. Remove and wash clothing before re-use. Avoid use of greasy ointments. 37 Manual IrZ i LEAD ACETATE WARNING! HARMFUL DUST Avoid breathing dust. W ear dust mask approved by U . S. Bureau of Mines for this purpose. W ash thoroughly before eating or smoking. Keep aw ay from feed or food products. M ALEIC ANHYDRIDE WARNINGI CAUSES BURNS Avoid contact with eyes, skin, or clothing. ' Avoid exposure to concentrated vapor. In case o f contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; for eyes,, get medical attention. MERCURY BICHLORIDE (MERCURIC CHLORIDE) DANGER! MAY BE FATAL IF SWALLOWED POISON Do not breathe dust. Keep away from feed or food products. W ash thoroughly before eating or smoking. Use fresh clothing daily. Take hot shower after work using plenty of. soap: ' METHYL n-AM YL KETONE CAUTION! VOLATILE SOLVENT Avoid prolonged breathing of vapor. Use with adequate ventilation. Avoid prolonged or repeated contact with skin. . I o METHYL BROMIDE DANGER! HIGHLY VOLATILE CAUSES BURNS VAPOR EXTREMELY HAZARDOUS Keep away from heat, Keep container closed. Avoid breathing vapor. Avoid contact with skin, eyes, or clothing. ON CAN LABEL ADD: POISON $ FIRST. AID Remove to fresh air: Ke e p lying dow n and w arm . Use artificial respiration if breathing has stopped. G e t immediate medical attention. Oxygen inhalator should be used only at the direction o f a. physician.... ; C A U TIO N ] The contents of this can are under pressure. Do not use ordinary can opener'. Special . handling equipment is available. Contact ............................................) for Name of Manufacturer information on equipment and proper use. METHYLENE CHLORIDE CAUTION! VOLATILE SOLVENT Uce with adequate yms^adk^n^. Avoid rpolbrigd' 6r repeated breathing " ';~' Avoid prolonged or repeated contact with skin. Do not take internally. Manual L-2 Manu.* Minufiguring Chrgiai' Asierittion at ih> Ufiiifd 5um METHYL ETHYL KETONE WARNING! FLAMMABLE VOLATILE SOLVENT Keep away from Heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of yapor. Avoid prolonged or repeated contact with skin. METHYL METHACRYLATE MONOMER WARNING! FLAMMABLE MAY CAUSE SKIN IRRITATION Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing o f vapor. Avoid contact with skin or clothing. METHYL iso-PROPYL KETONE W ARNING! FLAMMABLE VOLATILE SOLVENT Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing o f vapor. Avoid prolonged ,oy repeated contact with skin. c oo ----- MnabaariDi Chemins' Assocution of the UniieJ Sain -- : " ` M tnoal U-2 CARBOY LABEL MIXED ACID (Sulfuric and Nitric) DANGERl CAUSES SEVERE BURNS VAPOR EXTREMELY HAZARDOUS MAY CAUSE NITROUS GAS POISONING Do not breathe vapor. Do not get in eyes, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of water fo r at least 15 minutes;. for eyes, get medical attention. C ARBO Y H AN D LIN & AND STO R A G E Befora moving carboy be sure closure is securely fastened, Loosen cloiure carefully. Keep out o f sun and away from heat. N ever use presilire to empty. Com pletely drain carboy befora returning. In case of spillage, flush with plenty o f w afer. (U nder l. C. C. Regulations carboys are permissible shipping containers fo r mixed acid containing not m ore than 2 7 % Nitric A cid and ul least 33% water.) ' DRUM LABEL MIXED ACID (Sulfuric and Nitric) DANGERl CAUSES SEVERE BURNS VAPOR EXTREMELY HAZARDOUS MAY CAUSE NITROUS GAS POISONING Do not breathe vapor. Do not get in eyes, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of. water for a t least 15 minutes; for eyes, get medical attention. DRUM HAN D LIN G A N D STO RAG E K e e p plug up to prevent leakage. Keep drum out of sun and away from Heat. Relievo internal prenure wheri received and a* le a st weekly thereafter by slowly loosening plug. Rettghten immediately. N ever use pressure to empty. K eep lights, fir# and sparks away from drum openin gs. Drum must not bo washed out or used fo r other purposes. Replace plug after each withdrawal and return wHb empty drum.. In case o f spillage, flush with plenty o f w ater. f Manual L-2 M u a to ttl g tTiftram* Attagliici of tht Uniml Saia M O R PH O LIN E WARNING! HAZARDOUS LIQUID AND VAPOR MAY CAUSE SKIN IRRITATION Use with adequate ventilation. Avoid exposure to vapor. Avoid contact with shin or eyes. b-N A PH TH YLA M IN E CAUTION! CONTENTS HARMFUL REPEATED ABSORPTION MAY RESULT IN BLADDER TUMORS Avoid breathing dust or vapor. Avoid contact with shin. Do not take internally. o CARBOY LABEL NITRIC A CID DANGER] CAUSES SEVERE BURNS VAPOR EXTREMELY HAZARDOUS MAY CAUSE NITROUS GAS POISONING Do not breathe vapor. Do not get in eyes, on shin, oh clothing. In case of contact, immediately flush skin or eyas with plenty of water for a t least 15 minutes; get medical attention. C A R B O Y H AN D LIN G AN D STO RAG E Before moving carboy be sure closure is securely fastened. Loosen closure carefully. Keep out o f sun and away from haat. Never use pressure to empty. Com pletely drain carboy bofore returning. In case o f spillage, flush w ith plenty of w ater. 42 DRUM LABEL NITRIC ACID DANGER! CAUSES SEVERE BURNS VAPOR EXTREMELY HAZARDOUS MAY CAUSE NITROUS GAS POISONING Do not breathe vapor. Do not get in eyes, on skin, on clothing. In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes; get medical attention. DRUM HAN D LIN G AND STO RAG E Keep plug up to prevent leakage. Keep drum out a t sun end away from heat. Relieve Internal pressure whan raceived and o t least weekly 6 th a ra ifte r by slowly loosening plug. Retighten im m ediately. N ever use pressure td em pty. Keep lights, tire and sparks aw ay from drum openings. Drum must not be washed out or used fo r other purposes. Replace plug a fter each withdrawal and return with em pty drum. In case of spillage, flush w ith plenty of w ater. m -N ITR O A N IU N E WARNING! HARMUL BECAUSE ABSORBED THROUGH SKIN Avoid contact with skin. Avoid breathing dust. In case of contact, immediately wash thoroughly with soap and plenty of water; remove and wash clothing before re-use. NITROPHENOL, M ONO WARNING! MAY BE ABSORBED THROUGH SKIN Avoid breathing dust. Avoid contact with skin, in case o f contact, immediately wash with soap and plenty of water. 43 Manual L-2 Mimiftguring Chemin' Auodufpn cf du Uniitd Sittrt DRUM LABEL OLEUM DANGER! CAUSES SEV ER E BURNS Avoid breathing vapor. Do not get in eyes, on skin, on clothing. In case o f contact, immediately flush skin or eyes with plenty o f water for at least 15 minutes; get medical attention. Do not odd water to contents while in a container because o f violent reaction. DRUM H AN D LIN G A N D STO RAG E Keep plug up to prevent laakage. Keep drum out or sun and aw ay from heat. Relieve internal pressure when received and a t least weekly thereafter by slowly loosening plug. Retighten immediately. N ever use pressure to empty. Keep lights, tire and sparks aw ay from drum openings. Drum must not be washed out or used for other purposes. Replace plug a fter each withdrawal and return with .empty drum. In case o f spillage, flush with plenty of w ater. O XALIC ACID WARNING! HARMFUL IF TAKEN INTERNALLY CAUSES SKIN IRRITATION Avoid breathing dust. Avoid contact with skin. , In case o f contact, immediately flush with plenty o f water. Do not take internally. Keep away from feea or food products. PARALDEHYDE CAUTIONl VAPOR HARMFUL Use with adequate ventilation. Avoid prolonged or repeated breathing o f vapor, Do not take internally. Solidifies a t about 54F. (I2 DC .) and may break container. Store in'a moderately Vrtrftn place, O OO Mniifnuring Qitmiia' Auotmion of the Uniitd Sain PENTACHLOROPHENOL WARNING! HARMFUL DUST Avoid breathing dust. Avoid contact with skin or clothing. In case o f contact with dry material or its solution, wash at once with soap and plenty o f water. Do not take Internally. PENTACHLOROPHENOL O IL SOLUTIONS OF CAUTION! CAUSES SKIN IRRITATION ABSORBED THROUGH SKIN Avoid breathing vapor. Avoid contact with skin or clothing. In case of contact with skin, wash a t once with plenty of soap and warm water. D o not take internally. See instructions for use before handling. PETROLEUM NAPHTHAS AN D SOLVENTS, INDUSTRIAL (F or solvents having a flash point 20F . o r BELOW, Tagliabile Open Cup Method as specified by Interstate Commerce Commission) Name o f Product DANGER! EXTREM ELY FLAMMABLE Keep away from heat and open flame. Keep container closed.Use with adequate ventilation Avoid prolonged breathing o f vapor. Avoid prolonged or repeated contact with skin. 45 Mimificturint Cbtaiiu' Aedition of the United Satci PETROLEUM NAPHTHAS AN D SOLVENTS, INDUSTRIAL (F ar solvents having a flank point ABOVE 20F. but not above 80 F., Tagliabile Open Cup Method at specified by In fe rito le Commerce Commission) Name o f Product WARNING! FLAMMABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. PETROLEUM NAPHTHAS AN D SOLVENTS, INDUSTRIAL (For solvents having a flash point ABOVE 80F,,, Tagliabue Open Cup Method at specified by Interstate Commerce Commission) Name of Product. CAUTION! VOLATILE SOLVENT Use with adequ ate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact, with skin. p-PHENETIDINE CAUTION! HAZARDOUS LIQUID AND VAPOR ABSORBED THROUGH SKIN Avoid contact with skin. Avoid breathing vapor Oo Uo DANGER! PHENOL RAPIDLY ADSORBED THROUGH CAUSES SEVERE BURNS POISON SKIN Do not get on skin or In eyes. Avoid breathing vapor. Do not take internally. In ease of contact, immediately flush skin or eyes with plenty of water for at least IS minutes; for. eyes, get medical attention. Remove and wash clothing before re-use. p-P H EN YLEN ED IA M IN E CAUTION! MAY CAUSE SKIN IRRITATION Avoid breathing or contact with dust. CARBOY LABEL PHOSPHORIC A CID CAUTION! CAUSES SKIN IRRITATION Avoid contact with skin or eyes. In case of contact immediately flush skin or eyes with plenty o f water for at least 15 minutes; for eyes, get medical attention. CARBO Y H AN D LIN G AND STO R A G E Before moving carboy be sure closure Is securely fastened, loosen closure carefully. Keep out of sun and aw ay from heat. N ever use pressure to em pty. Completely drain carboy before returning. In case of spillage, flush with plenty o f w ater; Mutinai L-2 Minurmtiring Oirmim' Aiiociiiian tif ihr United Sara 1 ' PHOSPHORIC ANHYDRIDE WARNING! CAUSES BURNS Avoid contact with skin or eyes. When using, protect eyes with goggles end wear rubber gloves. In case of contact, immediately flush skin or eyes with plenty o f water for at least IS minutes: for eyes, gat medical attention. Do not add water to contents while in container because o f violent reaction. Open carefully. PHOSPHORUS DANGERI CAUSES SEVERE BURNS POISON jfe. Contents packed under water and will ignite if water h removed. Keep drum out of sun and away from heat. Do not get on skin or in eyes. Protect eyes with goggles or face shield and wear heavy rubber gloves. In case o f contact, immediately flush skin or eyes with plenty o f water for at least 15 minutes; keep skin area wet until medical attention is obtained. PHOSPHORUS PENTACHLORIDE WARNING! HAZARDOUS DUST CAUSES BURNS Do not breathe dust. Do not get on skin or in eyes. Protect eyes with goggles and wear rubber gloves. In case o f contact, immediately flush skin or eyes w ith p le n ty o f w a te r fo r a t least 15 m inutes; for eye, get medical attention. Do not add water to contents while in a container because o f violent reaction. Open carefully. 48 (' , f iUnutjuuring Uitmin' Aimciaiina cl the United 5ntet Manual L-2 PHOSPHORUS OXYCHLORIDE DANGER! CAUSES SEVERE BURNS t: VAPOR EXTREMELY IRRITATING , Do not breathe vapor. b Do not get on skin or in eyes. In case of eontact, immediately flush skin or eyes with plenty o f water for a t least 15 minutes; I for eyes, get medical attention. Do not add water to contents while in a container because of violent reaction. CO N TAIN ER H AN DLIN G AND STO R A G E fj 0 o not open unless you have been instructed in the propar mannsr. N ever m e pressure to em pty. j Do nof U1B this container fo r any other product. j In ease o f spillage, flood carefully with L A R G E . V O LU M E of water end provide adequate ventilation. iso-PROPYL ACETATE WARNING! FLAMMABLE VOLATILE SOLVENT Keep away from heat and open flame. Keep container closed. Use with, adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. PYRIDINE WARNING! FLAMMABLE Keep away from heat and open flame. Keep container closod. Use with adequate ventilation. Avoid prolonged breathing of vapor. I Mapuficmn'm Chtnim' Auodidca of Ac United Sate* SAMPLE* t ...........- ............. N irrw o r D escription o f Product FOR EXPERIMENTAL USE ONLY C A U TIO N ! The chemical, physical and toxicological r, properties o f this product have not been fully investigated and its handling or use may be hazardous. Exercise due care. *See M,C.A. Manual L J . SILVER NITRATE WARNING! CAUSES BURNS POISON S ta in : skin. Do not got on skin or in eyes. In case o f contact with eyes, get medical attention. SODIUM CH LORATE WARNING! CONTACT WITH COMBUSTIBLE MATERIAL MAY CAUSE FIRE A ll clothing contaminated with chlorates is DAN G ERO U SLY FLAM M ABLE. Remove and wash, thoroughly with water. Do not get on floor. Spillage may cause fires with combustible material. Sweep up and remove immediately. When not in use keep tightly closed in original metal container. Keep away from fire. Store separately from flammable material. F O R PACKAGES OF AGRICULTURAL CHLORATES, ADD: Keep Animals O ff Freshly Treated Areas The label m utt be tecurely affixed to the exterior o f each package. Litho graphed or trnnifer labeli are preferred. ( ; ( O oo Minuiaanrinj Omniiu' Anouiiira of tii Uoked Sutf SODIUM BICHROMATE WARNING! HARMFUL DUST MAY CAUSE RASH OR EXTERNAL ULCERS KEEP CONTAINER CLOSED. Avoid breathing dust or solution spray. Avoid contact with skin or eyes. Do not take internally. In case of contact, immediately flush skin or eyes with plenty of wafer for at least 15 minutes; for eyes, get medical attention. Remove and wash clothing before re-use. Use fresh clothing daily. Take hot shower after work using plenty of soap. SODIUM FLUORIDE WARNING! POISONOUS IF TAKEN INTERNALLY Avoid breathing dust. Flush spillage to sewer with water. IN THE CASE OF PROPRIETARY COMPOUNDS WHERE FORMULA DISCLOSURE IS NOT MADE ON THE LABEL: (Name o f Product Contains Fluorine Compounds WARNING! POISONOUS IF TAKEN INTERNALLY Avoid breathing dust. Flush spilage to sewer with water. NOTE: All inargunic fluorine compound* told for insecticidal use which are acutely toxic to m an should he colored. SODIUM HYDROSULFITE CAUTION! SUBJECT TO FIRE IF ALLOWED TO BECOME DAMP Keep container tightly closed. Use only, dry, clean utensils in handling. Store in a cool, dry place. MhWUKIK!l >' Aliodirion of the Unilrf Si SODIUM SULFIDE (Granular) DANGER! CONTACT WITH ACID LIBERATES POISONOUS GAS BURNS SKIN AND EY ES FLAMMABLE EXPOSURE MAY CAUSE FIRE OR CREATE FIRE HAZARD Avoid breathing dust. Avoid contact with shin and eyes. , Keep container closed and away from acids, com bustible material and heat. Sweep up spillage. Do not flush to sewer which may contain aeid. STYRENE MONOMER WARNING! VAPOR HARMFUL Use with adequate ventilation. Avoid prolonged breathing o f vapor. Avoid prolonged or repeated contact with skin. SULFUR CHLORIDE DANGERI CAUSES BURNS VAPOR IRRITATING Avoid contact with eyes, skin, or clothing. iii case o f contact, immediately flush skin or eyes with plenty o f water for a t least 15 minute*! for eyes, get medical attention. Do not add water to contents while in a container because o f violent reaction. DRUM H AN D LIN G A N D STO RAG E Keep plug up to prevent leakage. Keep drum out or sun and away from heat. Relieve in ternal pressure when received and a t least weekly thereafter b y slowly loosening plug. Retighten immediately. N ever use pressure to em pty. Keep lights, fire and sparks aw ay from drum openings. Drum must not be washed out or used for other purposes. Replace plug a fte r each withdrawal and return with empty drum. In case or spillage, flush w ith L A R G E V O L U M E of w afer. oo O CARBOY LABEL SULFURIC ACID DANGER! CAUSES SEVERE BURNS Do not got in eyes, on skin, on clothing. In case o f contact, immediately flush skin or eyes with plenty of water for at least IS minutes; for eyes, gat medical attention. Do not add water to contents while in a container. because of violent reaction. C A R BO Y HAN D LIN G AND STO RAG E Before moving carboy ba sure closure is securely fastened. Loosen closure carefully. Keep out of sun end away from heat. N ever use pressure to empty. Com pletely drain carboy before returning. In case o f spillage, flush with plenty o f w ater. DRUM LABEL SULFURIC ACID DANGERI CAUSES SEVERE BURNS Do not get in eyes, on skin, on clothing. In case o f contact, immediately flush skin, or ayes with plenty of water for at least 15 minutes; for eyes, get medical attention. Do not add water to contents while In a container because of violent reaction. DRUM HAN D LIN G AND STO RAG E Keep plug up to prevent leakage, Keep drum out of sun end aw ay from heat. Relieve internal oressure when received and a t least weekly thereafter by slowly loosening plug. Retighten immediately. N ever us* pressure to empty. Keep lights, fire and sparks away from drum openings. Drum must not bo washed out o r used fo r other purposes. Replace plug a fter each withdrawal and return with empty drum. In case o f spillage, flush with plenty of waters Mmuficiuri Chtmfaa' Ajicdulog ot ika II SULFUR DIOXIDE (Under Pressure) WARNINGI EXTREM ELY IRRITATING GAS AND LIQUID Avoid breathing gas. Do not drop cylinder. D o not allow c y lin d e r tem perature to re ach I3 0 'F . TETRACHLOROETHANE DANGER! VAPOR EXTREM ELY HAZARDOUS VOLATILE LIQUID POISON Use only in completely enclosed system. Do not breathe vapor. Do not get on skin or clothing. Do not take internally. TETRACHLOROETHYLENE (PERCHLORETHYLENE) WARNING! VOLATILE SOLVENT Use with adequate ventilation. Avoid prolonged or repeated breathing o f vapor. Avoid prolonged or repeated contact with skin. Do not tako internally. TOLUENE (TOLUOL) WARNINGI FLAMMABLE Keep away from heat and open flame. Keep container closed. Use .with adequate ventilation. Avoid prolonged breathing of vapor. Avoid prolonged or repeated contact with skin. < . OO QO Mmuftoudoi Oxmnn' Auociaiioa ol die Untied S m-TOLUIDINE WARNING! HAZARDOUS LIQUID AND VAPOR RAPIDLY ABSORBED THROUGH SKIN Avoid contact with skin and clothing. Do not breathe vapor. Use with adequate ventilation. In case of contact, immediataly wash thoroughly with soao and plenty o f water; remove and wash clothing before re-use. TRICHLOROETHYLENE WARNING! VOLATILE SOLVENT Use with adequate ventilation. Avoid prolonged or repeated breathing o f vapor. Avoid prolonged or repeated contact with skin; Do. not take internally. TRICHLOROPHENOL (Fr a ll ixomcric Trichorophenol*) CAUTION! MAY CAUSE SKIN IRRITATION Avoid prolonged or repeated contact. Do not take internally. V IN YL CHLORIDE DANGER! EXTREMELY FLAMMABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing of vapor. vTSEEFSEifST'*' Manual XYLENE (XYLOL) WARNING! FLAMMABLE Keep away from heat and open flame. Keep container closed. Use with adequate ventilation. Avoid prolonged breathing o f vapor. Avoid prolonged o r repeated contact with skin. ZINC CHLORIDE (Granular, Fused or Solution) CAUTION! MAY CAUSE SKIN IRRITATION Avoid prolonged or repeated contact. 56 oo OQ Mmutiaurini Quailm* Aimtiiloa of ibc United Sum Manual L-2 MANUAL L-2 INDEX Many o f the products listed in this index do not appetir specifically in the label listings. T he labels applicable to such products are indicated by the cross-reference "s .l.n" (same label at-- ) . Acetaldehyde . A cetic Acid Glacial Carboy ... 12 Drum ____ 12 80% 13 5 6 % and 7 0 % ............ 13 2 0 % ----------------------- 13 A cetic Anhyride .,.-- 14 Acetone --------------- 14 . Acetonylacetone ___ 14 A cetyl Chloride ......... 14 Acrylonitrile -------..-- 15 Ally! Alcohol _____ ..... 16 Ammonia, ....................... 18 Aqua ....................... 16 ........ .............. 17 ....................... 18 Ammonium Hydroxide-- See Ammonia, A q u a......................... ......____ 16-17 ....................... IB ....................... 18 ....................... 19 ........................ 19 ........................ 19 ................ 19-20 ........................ 20 ...... .............. 21 ....... 20 ....................... 21 ....................... 21 57 Minutoiurlrif Chtmisu* Allocution pf rTiv United Sum ............. 21 21 ............ 22 Benzyl Chloride 22 Drum ............................................................... ............................................... 22 Bichloride o f Mercury-i-See Mercury Bichloride.............................. .............. 38 Bichromates---See Sodium Bichromate................................................ ............ 51 Bromine ............................................................................................................ ............... 23 Butyl Acetate (Normal)............................................ .............. ............... 23 Butyl Alcohol Normal or Secondary............................................................................... ............... 23 Tertiary .................................................................................................. .............. 23 Butylamlne (Normal) ............................................................................ ........... .............. 24 p-tert. Buty(catechol ............................................................................. .. ......... 24 Butyl Chloride (Normal)................................................................................ .............. 24 24 23 ........... ; 3 i C-- Chlorinated Diphenyl-- s.I.a. Chlorinated Naphthalene .........r _ _____,, . 25 Chromates and Bichromates o f Sodium and Potassium 27 51 ...............27 ............. 38 ............... 27 58 (r 0 0 ^ o.... o Mlniifaiviniii Chraim' Aiiotiaiian of the United Suia 29 29 -D - 31 29 30 30 30 31 23 18 23 -- E-- 31 23 31 23 23 31 31 32 42 32 32 33 33 33 2-Ethylhexanol--s.I.a. Butyl A cetate........ ........... .-- ...-- 23 23 33 34 Formic Acid 34 . 35 59 Manual of the Unilri 5oio --G -- G lycol Diacetjite-- s.l.a. Butyl A ce ta te ..................................................... i... 23 Glycol Diformete-- s.I.o. Butyl Acetate................................................... .............. 23 --H-- Heptano)-2-- s i a . Butyl Acetate................................................................................ 23 Hexanol-- s.l.a. Butyl A ce ta te ........................................................ 23 Hydrochloric A c id _________________________ 35 Hydrocyanic Acid, L iq u id ........................................................... 35 Hydrofluoric Acid Aqueous ..................... 37 Hydrogen Peroxide Stronger than 25 volume and not exceeding 130 volume......................... 35 25 Volume ..........1___________......................................................................................37 Industrial Petroleum Naphthas and Solvents See Petroleum Naphthas and Solvents, Industrial............................... 45-46 Industrial Solvent, Aromatic - ........ ......................-- ... . -- .......... 19-20 Inorganic Cyanides (See Cyanides, Inorganic}............................................... 28 Isophorone-- s.I.a. 8utyl Acetate ______ ____........____ ___ ______________23 -- L-- Lead Acetate ............................... ....................................................................................... 38 Litharge-- s.l.a. Lead Acetate................,, ............................................................... 38 -- M-- Maleic A nhydride............................................................................ _ ............................. 38 Mercuric Chloride-- See Mercury Bichloride....................................................... 38 Mercury Bichloride_________________________ _____ _________ _________ __ 38 Mesityl Oxide--s.l.a. Butyl Acetate 23 Methyl Acetoacetate-- s.I.a. Butyl Acetate. ................................................... 23 Methyl Amyl Acetate-- sJ.a. Methyl n-Amyl Ketone................................... 38 Methyl Amyl Alcohol-- s.I.o. Methyl n-Amyl Ketone..................................... 38 Methyl n-Amyl Ketone............................ .......................................................... ............ 38 Methyl Bromide .............. ...................... ...................................................................39 Methyl iso-Butyi Ketone-- s.l.a. Methyl Ethyl Ketone................ ......... .......... 40 Methyl Cyclohexano!-- s.l.a. Cyclohexanol................... ..................... ................29 Methyl Cyclohexanone-- s.l.a. C y c lo h e x a n o l...........................................29 Methylene Chloride ...................... .......... ......................................................... .............. 39 Methyl Ethyl K e to n e ___ ....................................................!___ __________________ 40 XfimifacniritiR CTicmlm* Aiiomiioa cf the United San Methyl Methacrylate Monomer....................... ..................................... :-------- 40 Methyl Morpholine--s.l.a. Morpholine... ............ .............. ..........................42 Methyl iso-Propyl Ketone ................................ ........ .......................... ....... .............. 40 Mixed A cid (Sulfuric and Nitric) Carboy ...........__........... ..................... ............................................ ...............................41 Drum ________________ ______________________________________________ ____ 41 Monochlorobenzene-- See Chlorobenzene, Mono........ ............. ;................... 26 Monochlorophenol--s.l.a. Phenol . _____ ...______________________________ 47 Monochlorotoluene-- See Chlorotoluene, M ono__________ ______ ;______27 Mononitrophenol-- See Nitrophenol, Mono........................ ................... ............ 43 Morpholine ...L.......................... ...................I..............-- ___________ -......................... 42 Muriatic A cid-- See Hydrochloric A cid ---- ---- --------------- ;------- 35 -- N-- Naphthas, Industrial Petroleum, and Solvents See Petroleum Naphthas and. Solvents...............................-- ................ .45-46 a-Naphthylamine (containing 5 % b-Naphthylamine) . s.l.a, b-Naphthylamine ............................................-- ....................... ...... _ .......... 42 b-Naphthylamine 1....-- ........ ............ ....................... .................................. .............-- 42 Nitric Acid Carboy ..;...............;__ _-- .............. ..1---------------- ............... -- ................ 42 , m-Nitroaniline ___ i................-- .................................. -------- u ._ .................-- .43 p-Nitroaniline-- s.i.a. m-Nitroaniline ...........-- ..................................................... 43 Nitrobenzene-- s.l.a. Aniline ....... ________ __________; . i -- .......... ................. 16 m-Nitro-p-Anisidine-- s.l.a. m-Nitroaniline ....'...................... ....................1... 43 p-Nitro-o-Toluidine--i.I.o. m-Nitroaniline ____ ____________:................43 Nitrophenol, Mono -- ............... ------------- ----------------------- -- 43 tt. O il o f Vitriol--See Sulfuric A cid ...-- :-- ........ .....---- .:-- 53 Oil Solutions of Pentachlorophenol-- See Pentachlorophenol, Oil Solutions o f ............. ......... ...............-.........--------- -------- Oleum ....... .......... ................. :-- --------- ...............................----- Oxalic A cid ____________________________ ____ ___________ _______ -- P-- Paraldehyde -- ............................................-- --- -----Pentachlorophenol ........................................ ....... .............. Oil Solutions o f -- ........ ..............:................... .......... Perchlorethylene-- See Tetrachloroethylene..... Sfti Manual Manul Petroleum Naphthas and Solvents, Industrial...............................................45-46 o-Phenetidine--s .U . p-Phenetidine............................................. :...........................46 p-Phenetidine .................................................................................................... :_________ 46 Phenol _____________________________________ ___ ___________________________ 47 p-Phenylenediamine ........................ ......^............................... ............................. . . . 47 Phosphoric A cid ................................................................ ...................................... ........47 Phosphoric Anhydride ........ ..........................................................................................48 Phosphorus ................................1_____________________________________________ 48 Phosphorus Oxychloride ..................................... ............'............................................. 49 Phosphorus Pentachioride ........................................... .................. ................... 48 Phosphorus Trichloride--s.l.a. Phosphorus Oxychloride.............................. 49 Potassium Chlorate-- s.l.a. Sodium Chlorate............... ..................... ................ 50 Potassium Chromate and Bichromate-- See Sodium Bichromate............ 51 Potassium Hydroxide-- s.l.a. Caustic Soda.........................................................26 iso-Propyl Acetate _____ ......__ ______ _____ _______________________________ 49 Propylene Chlorohydrin-- sJ.a . Ethylene Chlorohydrin............-- ............. 32 iso-Propyl Ether-- s.l.a. Ethyl Ether......... ............................................. ................... 33 Pyridine . . . . . ___________________ ....____ _________ .............................. .......... ...... 49 -- S-- Sample--Label for Experimental Products_______________ ______________ 50 Silver Nitrate .. ... . . . . . . . . . . .................................... .......................................... 50 Sodium Chlorate ___ ;______ ________ _____ ___ _...................................................... 50 Sodium Bichromate ------------------ ------------- ------- -- : _________ 51 Sodium Fluoride .............. ................................................................................................. 51 Sodium Hydrosulfite ...................................................................................... ................. 51 Sodium Hydroxide-- See Caustic Soda.............................................. .................. 26 Sodium Orthosilicate-- s.l.a. Caustic Soda .................................................... 26 Sodium Sesquisilicate-- s.l.a. Caustic Soda....................................................... 26 Sodium Sulfhydrate-- s.l.a. Sodium Sulfide . . ............. :....................................52 Sodium Sulfide (Granular) ___ ; ................. ..................................................... 52 Solvents Aromatic Industrial ___ ................ ....... .......................................................... 19-20 Industrial Petroleum Naphthas and Solvents........................ ............ .. . 45-46 Styrene Monomer ......... ...................................................................................................52 Sulfur Chloride ........................................................... ....................................................... 52 Sulfur Dichloride-- s.l.a. Sulfur Chloride....................... ............ .......................... 52 Sulfur Dioxide___ _________________ ______________ _______ ___ ____________ 54 Sulfuric A cid ' Carboy ____ ____________________ ___________________ ________ ___________ 53 Drum .......................................................................................................... ...... ...................53 Sulfuryl Chloride-- s.l.a. Sulfur Chloride................... ........................................... 52 ( \ i Manual 1*2 Tar Acids-- s.l.a. C re s o t_____-- ...---- -- ---- ---------------- -------- 29 Tetrachloroethane ------ 54 Tetrachloroethylene ............ .............................- --- ----------------------------54 Tetraehlorophenol-- s.l.a. Pentachlorophenol ..................... .. .............. ........ 45 Tetraethylenepentamine-- s.l.a. Morpholine ......... .......................--..........- 42 Thionyl Chloride-- j.l,a , Sulfur Chloride................. .............................. -- ..........52 Toluene ....._______________________ _____ _________________ ________________54 m-Toluidine ----- -- ................................ ......................................--........... .................. 55 o-Toluidine-- s.l.a. m-Toluidino---- ------------- i......... .................-- ..........-- 56 p-Toluidine-- s.l.a. m-Toluidine------ --- ------------- --------------- ....-- 55 Toluol-- See Toluene------------ ---------------- --------------------- -- 54 Trichloroethylene --------- --------------------- -- ------ ---- .-- --------56 Trichlorophenol--------- -- --------------- :-- -- ----------------- ------ *-- 55 Triethylenetetramine-- s.l.a. Morpholine -------------------- 42 Trimethylcyclohexanol-- s.l.a. ButylA c e t a t ------------------ 23 -- V-- Vinyl C h lo rid e .....................-- ............. ........ ............... ..-- -- ........... 55 ' -- X-- Xylene ... . -- ........-- --............................ .--: -- .............-- -............... .-- .........56 Xylidines-- sJ.a. m-Toluidine -- ....................... r ------- -- ;... 55 Xylol-- See Xylene -- .................... .......................-- ------ ----------- 56 f '. --z-- ; Zinc Chloride (Granular, Fused or Solution)..... .......... .............................56 Thl* Mcmni'l. Inrfodlnr 1*1 add 1*% h HUipIlod hr Mami/aclurteB ChtmUU' Ajanelalbn o tfc Uoltad Stalo 01 Woodward Building Wnihfogton S. D. a : TJ. 3. A. Fric, $LG0 ncfe PRINTED IN U.9.A.