Document 7Rpea18D9nJmkvg8wL1NzDon6

SEVERN TRENT STL STL Chicago 2417 Bond Street University Park, IL 60466 Tel: 70S 534 5200 Fax: 70S 534 5211 www.stf-inc.com SEVERN TRENT LABORATORIES ANALYTICAL REPORT JOB- NUMBER: 244550 Prepared For: Weston Solutions, Inc. 1400 Weston Way Building 5-2 West Chester, PA 19380-1499' Project: Confidential Decatur. - F C i I n v e s t i g a t i o n Attention: Sue Stefanosky Bate: 03/09/2006 Tille: Project Manager E - M a i l : rwright@stl-i n e .com This Report Contains Leaders in Environmental Testing Date ........ STL Chicago 2417 Bond Street University Park, IL 60466 PHONE: (708) 534-5200 F A X . .: (708) 534-5211 Pages Severn Trent Laboratories* Inc. WET CHEMISTRY DATA PACKAGE CONFIDENTIAL DECATUR - FC INVESTIGATION JOB# 244550 Data Summary............................................................... 1 Chain of Custody......................................................... 36 Case Narrative............................................................. 43 Raw Data...................................................................... 45 STL Chicago is part of Severn Trent Laboratories, Inc. .... . - S A M P L E ' I N F O R M A'.T. r.O. N :: Date: 03/09/2006 Job Number. C u s t o m e r . .,, A t t n ....... 244550 Weston Solutions, Inc. Jai Kesari Project Number......... : 20004891 Customer Project ID___ : CONFIDENTIAL DECATUR Project Description.... : Confidential Decatur - FC Investigation ....Laboratory'. Sample ID ' 244550-1 244550-2 244550-3 244550-4 244550-5 244550-6 244550-7 244550-8 244550-9 244550-10 244550-11 244550-12 244550-13 244550-14 244550-15 244550-16 244550-17 244550-18 244550-19 244550-20 244550-21 244550-22 244550-23 244550-24 244550-25 244550-26 Customer' . . Sample ID'.' DF11-SS-SS02-Q-Q000 DF11-55-5502-0-0003 DF11-SS-SS03-0-0000 DF11-SS-SS03-DB-0000 DF11-SS-SS03-0-0003 DF11-SS-SSQ4-Q-QQ0Q DF11-55-SS04-0-0003 DF11-SS-SS05-0-0000 DF11-SS-SS05-0-0003 D F05- SS-SSOI-0-0000 D F05-SS-SSOI-0-0003 DF05-SS-SS02-0-0000 DFQ5-SS-SSQ2-0-QQQ3 DF12-SS-SS01-0-0000 DF12-SS-SSOI-0-0003 DF12-SS-SS02-0-0000 DF12-SS-S502-0-0003 DF12-SS-SS03-0-0000 DF12-SS-S503-0-0003 DF12-SS-SS04-0-0000 DF12-SS-SS04-0-0003 DF12-SS-SS05-0-0000 DF12-SS-S305-0-0003 D F13-SS-S 501-0-0000 DF13-SS-SS01-0-0003 DF13-SS-SS02-0-0000 Sample :: ::: ' ! Date.!-. Sairtpted . Soi L 02/21/2006 Soi L 02/21/2006 Soi L 02/21/2006 Soi L Soi L Soi L 02/21/2006 02/21/2006 02/21/2006 soil 02/21/2006 Soi L 02/21/2006 Soil 02/21/2006 Soi L Soi L 02/21/2006 02/21/2006 Soi L 02/21/2006 soil 02/21/2006 Soi L Soi L Soi L 02/22/2006 02/22/2006 02/22/2006 Soi L Soil Soi L 02/22/2006 02/22/2006 02/22/2006 Soi L Soil SoiL 02/22/2006 02/22/2006 02/22/2006 Soi l Soi L Sen L Soi L 02/22/2006 02/22/2006 02/22/2006 02/22/2006 Time Date Time' ! Sampled'. . -.Received... Received 14:54 02/23/2006 10:25 14:55 02/23/2006 10:25 15:12 02/23/2006 10:25 15:12 15:13 02/23/2006 02/23/2006 10:25 10:25 15:28 02/23/2006 10:25 15:29 02/23/2006 10:25 15:48 02/23/2006 10:25 15:50 02/23/2006 10:25 16:03 16:05 02/23/2006 02/23/2006 10:25 10:25 16:15 02/23/2006 10:25 16:17 02/23/2006 10:25 13:25 02/23/2006 10:25 13:27 02/23/2006 10:25 13:40 02/23/2006 10:25 13:41 02/23/2006 10:25 13:50 02/23/2006 10:25 13:52 02/23/2006 10:25 14:10 02/23/2006 10:25 14:11 02/23/2006 10:25 14:26 02/23/2006 10:25 14:28 02/23/2006 10:25 14:40 14:41 02/23/2006 02/23/2006 10:25 10:25 14:52 02/23/2006 10:25 S'I L Chicago Page 1 1 STL Chicago is part of Severn Treni Laboratories, Ine. SA.MPLE INFORMAT. IQN Data:;.;.' Job Number. C u s t o m e r . .. A t t n ....... 244550 Ueston Solutions,, Inc. Jai Kesari Project Number......... : 20004891 Customer Project ID.... : CONFIDENTIAL DECATUR Project Description.... : Confidential Decatur - FC investigation Laboratory Sample ID 244550-27 customer . Sample ID. . . . DF13-SS-SS02-0-0003 Sampif Matrix Soi L Date Sampled 02/22/2006 Time''.' Sampled' - -.Received 14:54 02/23/2006 Time: . .Received 10:25 STL Chicago Page 2 2 STL Chicago is part of Severn Trent Laboratories, Inc. Job Humber: 244550 ."CUSTOMER: Weston Solution,; Ins. Customer Sample ID: DF11-SS-SS02-0-0000 Date S a m p l e d ....... :02/21/2006 Time S a m p l e d ....... :14:54 Sample M a t r i x ...... :Soi L . T E S T METHOD Lloyd Kahn : ' PARANETER/TEST D ESCHIP TOH ' T o ta l O rg an ic Carbon ( S o ils ) TOC Average D u p lic a te s , S o lid LABORATORY TEST RESULTS PROJECTS COHFiENTAL DECATUR ' Laboratory Sample ID: 244550-1 Date R e c e i v e d .........:02/23/2006 Time R e c e i v e d .........:10:25 Date:03/09/2006 ATTN: Jai Kesarv-.' 1 SAMPLE RESULT Q FLAGS 1 12000 ! j 1! HDL 440 RL 1900 j -:--:. f ] BILUTIQHj U N ITS'- :BATCH DT DATE/TIHE T E 1 mg/Kg 174520 03/01/06 1139 c La * In Description = Dry Vlgt. Page 3 ____ ,, _______________ c cod U ---II cn STL Chicago is part af Severn Trent Laboratories, Inc. Job Humber: 244550 :CUS TOME R :i Weston :So lut iOns,.;Inc. :::!:1- : :: : : :. Customer Sample ID: DF11-SS-SS02-D-0003 Date S a m p l e d ....... :0 2/21/2006 Tie S a m pled....... :14:55 Sample M a t r i x ...... :Soi l TEST METHOD ; "PARftHETER/TEST DESCRIPTION; ' Lloyd Kahn Total Organic Carbon (Soils) TOC Average Dupti cates, Solid LABORATORY TEST RESULTS .PROJECT: CONFIDENTIAL DECATUR ; Laboratory Sample ID: 244550-2 Date Received......... :02/23/20Q6 Time Received......... :10:25 Da te :03/09/2006 ;ATTN: Jai ICesari -SAMPLE ^RESULT-:: Q FLAOS 7400 mdl; 440 RL 1900 DILUTION UNITS- ' /BATCH:: DT DATE/TIttE TEC! 1 g/Kg 174520 03/01/06 1152 jels 3 \1 i j : : * In Description = Dry Wgt. Page 4 O uts 3 CJ Vi STL Chicago is part of Severn Trent Laboratories, Inc. Job Nuriber: 244550 CUSTOMER: '.tfeston Solutions, I n c I. Customer Sample ID Date S a m p l e d ...... T i m e S a m p l e d ...... Sample M a t r i x .... DF11-SS-SS3-0-0000 02/21/2006 15:12 Soi L TEST MTH0D Lloyd Kahn 'P A R A M E T E R/.TEST: D E S C R 1 P T I O M : Total Organic Carbon (Soils) TOC Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT;/C O N F I D E N T I A L E C A T U R Laboratory Sample ID: 44550-3 Date Re c e i v e d .......: 02/23/2006 Time Re c e i v e d .......: 10:25 Date:03/09/2006 ATTN;; Jai Cesari S A M P L E " RESULT: FLAGS 4900 :HDL: 510 RL: 2200 DILUTION :UNITS BATCH. DT DATE/TIME! TECH mg /Kg 174520 \ 03/01/06 121S els * In Description = Dry Ugt. Page 5 otao s * In Description = Dry Wgt. Page 6 =yd U U Hcn STL Chicago is part of Severn Trent Laboratories, Inc. Job Humber: 244550 'CUSTOMER: Ueston Solutions, Ifit.;;. Customer Sample ID: DF11-S5-SS03-0-0003 Date S a m p l e d ........:02/21/2006 Time S a m p l e d ........:15:13 Sample tfatrix...... :Soil TEST METHOD Lloyd Kahn -RARAHETER/tEST::1DESCRIPTION' ' Total Organic Carbon CSoiLsJ TOC Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID: 244550-5 Date Rec e i v e d ......... :02/23/2006 Time Rec e i v e d ......... :10:25 Date:03/09/2006 ATTM: Jai K e s a H SAMPLE.RESULT' 'G FLAGS 2300 MDL 310 RL .. : .&ILUTI0N UNITS BATCH DT d a t e /t i h e :.- TCF 1300 1 mg/Kg 174520 i 03/01/06 1327 els * In Description = Dry Wgt. Page 7 ___________ ^ STL Chicago is part of Severn Trent Laboratori es, Inc. Job Humber: 244550 CUSTOHER:;:Heston:Solutions^ Inc^ Customer Sample ID: DF11-SS-5S04-0-CKXJ0 Da t e S a m pled...... : 02/21/2006 Ti m e S a m pled...... : 15:2S S a m p l e M a t r i x .....: Soi L TEST NETHQD ' PARANETER/TEST .DESCRIPTION Lloyd Kahn Total Organic carbon (Soils) TOC Average Duplicates, Solid 3C LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID: 24455CH6 Date Received....... : 02/23/2006 Time Received....... : 10:25 Date:03/09/2006 ATTN:.' Jai Kesari r :S A M P L E :R E S U L T :QjjFLAGS 1800 NDL 270 ' R L _ DILUTION UNITS b a t c h ;; BT 'BATE/.TIME T.ECt 1200 1 mg/Kg 174520 03/01/06 1339 els A In Description = Dry Wgt. Page S p a O i STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 244550 ;CUSTODE: -Westpn Solutions,- Inc;. Customer Sample ID: DF11-$S-SSO4-Q-000i3 D a t e S a m p l e d ....... :02/21/2006 Ti m e S a m p l e d ....... :15:29 Sample M a t r i x ......:Soi L T E S T "METHOD ' PARAMETER/TEST' DESCRIPTION ' LLoyd Kahn Total Organic Carbon (SoiIs) TOC Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR' ' Laboratory Sample ID: 244550-7 Date Rec e i v e d ......... :02/23/2006 Time Rec e i v e d ......... :10:25 Date:03/09/2006 ATTN : 'Jai (Cesari ..SAMPLE RESULT li FLAGS ' 2. 1200 MDL 170 RL .- DILUTION UNITS . BATCH- DT -DATE/TIME' ' TECH 740 1 mg/Kg 174520 03/01/06 1351 els : i j i ! * In Description = Dry Wgt. Page 9 , c STL Chicago is part of Severn Trent Laboratories, Inc. ; Job Number: 244550 ii .CUSTOMER: Weston Solutions,-.Inc.-. Customer Sample ID Date Samp l e d ...... Time S a m p l e d...... SampLe M a t r i x ..... DF11-S5-SS05-0-0000 02/21/2006 15:48 Soil TEST METHOD Lloyd Kahn :PARAMETER/EST::D ESC R I P T 10 Total Organic Carbon (Sollst TOC Average Duplicates, Solid LABORATORY TEST RESULTS '"PROJECT':" COMF1 DEMTIAL DECATUR .. Laboratory SampLe ID Date Rec e i v e d ....... Time R e c e i v e d ....... 244550-8 02/23/2006 10:25 Date:03/09/2006 ATTH: Jai Ksrf ;- SAMPLE RESULT6200 FLAGS ! :HDL: 200 :RL DILUTION U M ITS BATCH DT DATE/TlHE TECF 870 H g/Kg 174520 03/01/06 1405 els * In Description = Dry Ugt. Page 10 o o O sH-J t/ STL Chicago is part of Severn Trent Laboratori es, Inc. Job Number: 244550 CUSTOM ER :.Wes ton Sol ut ion's, InC. Customer Sample ID: D F11-SS-SS05-0-0003 D a t e S a m pled....... :0 2/21/2006 T i m e S a i l e d ....... :15:50 Sample M a t r i x...... :Soil TEST. METHOD LLoyd Kahn .-PARAHETER/TEST DESCRIPTLOW " Total Organic Carbon iSoils) TOC Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT: CONFI;DENTIAL;DECATUR Laboratory Sample ID: 244550-9 Date Received......... :02/23/2006 Time Received......... :10:25 Date:03/09/2006 ATTN: Jai Kesari :SAMPLE: RESULT;:;: Q FLAGS . 4000 HDL 230 RL 980 DILUTION ^ UNITS .BATCH BT d a t e /t i m e TEEI 1 mg/Kg 174520 03/01/06 1437 els 1 J______ ___________________________________________________ * In Description = Dry Wgt. Page 11 c rui H iTi STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 244550 CUSTOMER:-.West on Solutions, Inc.-' Customer S a m p l e ID Date S a m p l e d ...... Time S a m p l e d ...... Sample M a t r i x ..... DF 0 5-SS-SS01-0-0000 02/21/2006 16:03 Soi L t e s t :m e t h o d Lloyd Kahn :PARAMET R/TE.ST D ES CRI P.TIOH Total Organic Carbon (Soils) TOC Average Duplicates, Solid (N LABORATORY TEST RESULTS . PRO jECTl';CON FI D E N TIAL::DECATUR Laboratory Sample ID: 244550-10 Date Rec e i v e d ........ : 02/23/2006 Time Rec e i v e d ........ : 10:25 Date:03/09/2006 ; ATTN: Jai! Keaari SAMPLE RESULT 1800 FLAGS MDL- 180 RL. 770 DILUT LOW IIW I T S BATCH DT DATE/TIME- TECl g/Kg 174520 03/01/06 1511 c Is * In Description = Dry Wgt. Page 12 Ciytffl Jo3 -I on STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 244550 CUSTOMER:.1Jeston 'Solutions, Iiicv Customer Sample ID: DF05-SS-SS01-0-0003 Date S a m pled...... : 02/21/2006 Time S a m pled...... : 16:05 Sample M a t r i x..... : Soil TE S T METHOD PARAMETER/TEST DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils? TOC Average Duplicates, SoLid LABORATORY TEST RESULT S P R O J E C T : CON FI DENT IA L DECATUR Laboratory Sample ID Date Received....... Time Received....... 2445 5 C M 1 02/23/2006 10:25 Date:03/09/2006 ATTN: Jai 'Kesari \ SAMPLE RESULT :q f l a g s :; 940 MDL 150 : -r l - DILUTION UNITS BATCH DT j DATE/TINE TECh 670 1 mg/Kg 174520 03/01 / 0 6 1521 c Ls * In Description = Dry Wgt. Page 13 o <z O Hco STL Chicago is pari of Severn Trent Laboratories, Ine. Job Humber: 244550 CUSTOMER: H e a t o n 5 tutians, .;Inc.. Customer Sample ID: DF05-SS-SSQ2-0-0000 Date S a m p l e d ....... :02/21/2006 Time S a m p l e d ....... :16:15 SampLe M a t r i x ...... :Soil LABORATORY TEST RESULTS PROJECT: COMFIBENTIAL DECATUR Laboratory Sample ID: 244550-12 Date R e c e i v e d ......... :02/23/2006 Time R e c e i v e d ......... :10:25 Date:03/09/2006 ATTHt- Jai Kesari . U c/i STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 244550 CUSTOMER:-.Heston Solutions, Inc; Customer Sample 10: DFQ5-SS-SS02-0-0003 Date S a m pled....... :02/21/2006 Time S a m pled....... :16:17 Sample M a t r i x ...... :Soi l TESt ETH0D ; .RARAHETR/TEST DESCRIPTION. Lloyd Kahn Total Organic Carbon (Soils) TOC Average Duplicates, Solid l/ LABORATORY TEST RESULTS PROJECT;; CONFIDENTIAL DECATUR Laboratory Sample ID: 244550-13 Date Re c e i v e d ........ :02/23/2006 Time Received........ :10:25 Date:03/09/2006 A T T N : ''J a i 'Kesari .SAMPLE .'.'RESULT 0 FLAGS 7600 M D L ' 230 RL . 900 DILUTION UNITS BATCH DT :-DATE/TINE TECf 1 ng/Kg 175263 03/07/06 0911 rn ' * In Description = Dry Ngt. Page 15 j ii oSowra U _Hl tn STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 244550 CUSTfflfER-::Weston iSotutions, Inc. Customer Sample ID: DF12-$S -SS01-0-0000 Date S a m p Led........:02/22/2006 Ti m e S a m p l e d ........:13:5 Sample M a t r i x ...... :Soil TEST: METHOD. Lloyd Kahn :PARANETE F/ T E S T -DES CRI PT ION : Total Organic Carbon CSoi Is3 TOC Average Duplicates, Solid se LABORATORY TEST RESULTS PROJECT:. CONFIDENTIAL DECATUR Laboratory Sample ID Date Re c e i v e d ....... Time Re c e i v e d ....... 244550-14 02/23/2006 10:25 Date:03/09/2006 ATTNi- Jai Kesari SAMPLE-RESULT 4300 FLAGS MOL 210 GL DILUTION] UNITS- :BATCH DT DATE/TIME TECH 900 mg/Kg 175263 03/07/06 0925 A In Description - Dry Wgt. Page 16 oo3s U hHJ 00 STL Chicago is part of Severn Trent Laboratories, Inc. Job Humber: 244550 CUSTOMER:1 W e s t o n So Lut ions,- ;Inc. Customer Sample ID: DF12-SS-SS01-0-0003 Date S a m p l e d ....... :02/22/2006 Time Samp l e d ....... :13:27 Sample M a t r i x ...... :Soil TEST METHOD Lloyd Kahn PARAM ETER/TE ST =:D ES CRIP T EON : Total Organic Carbon (Soils) TOC Average Dupli cates, Solid T- LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL PECATUR ; . Laboratory Sample ID Date Received....... Time dec e i v e d ....... 244550-15 02/23/2006 10:25 Date:3/09/2006 ATTN: Jat Kesari SAMPLE R E S U L T Qj FLAGS 7400 MDC- 200 RL DILUTION U N I T S : BATCH PT .DATE/TINE TEC 8SO mg/Kg 175263 03/07/06 0943 * In Description = Dry Ngt. Page 17 o to ai JZ O Fc/-: STL Chicago is part of Severn Treni Laboratories, Ine. Job Humber: 244550 CUSTOMER: W e s t o n Solutions,:;Irte. Customer Sample ID: DF12-SS-SS02-0-0000 Date S a m p l e d ......: 02/22/2006 T i m e S a m p l e d ...... : 13:40 Sample M a t r i x..... : Soil T E S T METHOD*: PARAM.ETIR/TEST DESCRIPTIOM ' Lloyd Kahn Total Organic Carbon (Soils) TOC Average Duplicates, Solid LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL .DECATUR' Laboratory Sample ID: 244550-16 Date Received. 02/23/2006 Time Received. 10:25 Date:03/09/2006 .ATTN:>'Jai^Kesari SAKPLE RESULT 8400 ELA&S1 :HDL^ 310 .RI 1400 DI LUTI 0.M :u r i t s BATC H: DT DATE/TIME TECh mg/Kg 175263 03/07/06 1001 * In Description = Dry Wgt. Page 18 o oGjo j=l U H on Os STL Chicago is part of Severn Trent Laboratories, Inc. Job Number; 244550 CUSTOMER:' Weston Solutions, Inc. Customer Sample ID: DF12-SS-SS02-0-0003 Date Sampled....... :02/22/2006 Tie Sampled....... :13:41 Saaple M a t r i x ...... :Soi L LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR .. Laboratory Sample ID: 244550-17 Date Received....... : 02/23/2006 Time Received........: 10:25 Date:03/09/2006 ;;'ATTN: Jai Kesari TEST METHOD-' . .P ARANEJER/TEST DESCRIPTION " ' Lloyd Kahn : A \ \ Total Organic Carbon (SoiLs TOC Average Duplicates, Solid 's a m p l e r e s u l t ' ' Q FLAGS 7400 HDL 460 RL 2000 DILUTION UNITS BATCH DT DATE/TIME TECh 1 g/Kg 175263 03/07 / 0 6 1038 rtim * In Description = Dry Wgt. Page 19 u IUS S-l STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 244550 .CUSTOMER: "Weston Solutions^ Inc: C u s tomer Sample ID: DF12-SS-SSO3-O-QO0Q D a t e S a m p l e d ....... :02/22/2006 T i m e Samp L e d....... :13:50 S a m p l e M a t r i x ...... :Soil LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR Laboratory Sample ID: 244550-1S Date Rec e i v e d ....... : 02/23/2006 Time R e c e i v e d . 10:25 Date:03/09/2006 ATTN; 'Jai Kesari * In Description = Dry Wgt. Page 20 3 U Hon1 STL Chicago is pari of Severn Trent Laboratoriesf Ine. ts S u- STL Chicago is part of Severn Trent Laboratori es, Inc. Job Humber: 244550 CUSTOMER:- Weston Solutions, Inc. '; Customer Sample ID: DF12-SS-SS04-0-0000 Date S a m p l e d ...... : 02/22/2006 T i m e S a m p L e d ...... : 14:10 Sample M a t r i x .....: Soil TEST METHOD' PARAMETER/TEST! DESCRIPTION Lloyd Kahn Total Organic Carbon tSoils) TOC Average Duplicates, SoLid IS IS LABORATORY TEST RESULT S PROJECT: CONFIDENTIAL DECATUR ' Laboratory Sample ID Date Re c e i v e d ....... Time Re c e i v e d ....... 24455CK20 02/23/2006 10:25 Date:03/09/2006 ATTN:- ::Jaf K e s a r i k . "SAMPLE RESULT a FLAGS:: 5100 HDL 200 :'.Rk 070 DILUTION UNITS BATCH DT .DATE/TIME TECh 1 mg/Kg 175263 03/07/06 1205 rnm i * In Description = Dry Wgt. Page 22 tnj STL Chicago is pari of Severn Trent Laboratories, Ine. Job Number: 244550 ::COSTONE R :Weston :Soluti on S, :Inc. Customer Sample ID :DF12-SS-SS04-G-0003 Da t e Sampled....... :02/22/2006 Time Sampled....... :14:11 Sample Matrix...... :Soil TEST METHOD. :PARAMETER/TE S DESCRIP TI0N LLoyd Kahn TotaL Organic Carbon (Soils) TOC Average Duplicates, Solid m m LABORATORY TEST RESULTS ' PROJECT. CONFIDENTIAL DECATUR Laboratory Sample ID Date Re c e i v e d ....... Time Re c e i v e d ....... 244550-21 02/23/2006 10:25 Date:03/09/2006 ATTN: !Ja.i- (Cesari. SAMPLE RESULT 12000 FLAGS: HDL 270 RL. 1100 DILUTION. UNITS' ^BATCH D T DATE/TLME TECh mg/Kg 175263 03/07/06 1219[rnm * In Description = Dry Ugt. Page 23 J________ L o Li a; STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 244550 CUSTOMER: Heston Solutions, Inc. Customer Sample ID: DF12-SS-SS05-0-0000 Date S a m p l e d ...... : 02/22/2006 T i m e S a m p l e d ...... : 14:26 SampLe K a t r i x .....: Soi L TEST METHOD.;-:: . PARAMETER/TEST DESCRIPTION LLoyd Kahn Total Organic Carbon CSoiLs) TOC Average Duplicates, Solid Trii LABORATORY TEST RESULTS .. PROJECT CONFIDENTIAL DECATUR Laboratory SampLe It): 244550-22 Date Rec e i v e d ........: D2/23/2D06 Time Rec e i v e d ........: 10:25 Date:03/09/2006 ATTWt Jai K e s a M . SAMPLE RESULT iG FLAGS 2700 HDL 160 : RL-. 700 DILUTION LfNITS ' BATCH DT DATE/T1HE ' TEC) 1 a/Kg 175263 03/07/06 1245 rnm i * In Description = Dry Wgt. Page 24 i________ g, PC_3> iu-e3 STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 244550 CUSTOMER: Weston Solutions,-"Inc..' -' Customer Sample ID Date Samp l e d...... Time Samp l e d...... Sample M a t r i x ..... DF12-SS-SS5-0-0003 02/22/2006 14:28 Soi L TEST METHOD Lloyd Kahn PARAKETER/TEST DESCRIPT0H : Total Organic Carbon tSoiIs) TOC Average Duplicates, Solid VI LABORATORY TEST RESULTS PROJECT: C0NFID EN TIAL- 'DECATUJR Laboratory Sample ID Date Rec e i v e d ....... Time Rec e i v e d ....... 244550-23 02/23/2006 10:25 Date:03/09/2006 ATTN: Jai Kesairi SAMPLE RESULT 5000 FLAGS; :MBL: 83 DTRL ;D I L U T I O N UNITS BATCH DATE/TIME TECt 360 mg/Kg 175263 03/07/06 1310 * In Description = Dry Wgt. Page 25 ocOodc Jo3 K-l E/1 STL Chicago is part of Severn Trent Laboratories, Inc. Job Humber: 244550 ! CUSTOMER: Weston!-So lu t io n s , In c .- Customer Sample ID: DF13 - SS-SS01- 0-0000 Date S a m p l e d ....... :02/22/2006 Ti m e S a m p l e d ....... :'14:40 Sample M a t r i x ...... :Soil TEST METHOD- .-PARAflETER/TEST DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) TOC Average Duplicates, Solid sO LABORATORY TEST RESULTS PROJECT: CONFIDENTIALDECATUR. . . Laboratory Sample ID: 244550-24 Date Received........ :02/23/2006 Time Received.........:10:25 Date:03/09/2006 A TTN :. : .J a i ::kes&r i :.;SAflPJLE;RE3ULT 0 F L A G S 1: 13000 HDL. 170 RL740 DiLUtiaw] UNITS ' : BATCH DT D A T E / T I N E ' TECF 1 mg/Kg 175263 03/07/06 1346 rnm . * In Description = Dry Wgt. Page 26 ________ ; 1 ___________ o Hon STL Chicago is part of Severn Trent Laboratories, Inc. Job Humber: 244550 CUSTOMER; lieston Solutions, !I n c . Customer Sample ID: DF13-SS-SSQ1-0-0Q3 Date Samp l e d...... : 02/22/2006 Time Sampled...... : 14:41 Sample M a t r i x .....: Soil TEST METHOD : . PARAT1ETER/TEST DESCRIPTION " Lloyd Kahn Total Organic Carbon ISoiIs) TOC Average Duplicates, Solid j r- LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL DECATUR. Laboratory Sample ID: 244550-25 Date Rec e i v e d ....... : 02/23/2006 Ti me Recei v e d ....... : 10:25 Date:03/09/2006 ATTN: Jai (Cesari SAMPLE RESULT 0 FLAGS 4900 m i .- ; . ; R L ' - D I L U T I O N : . UNITS'.; BATCH DT DATE/TIME TEC 150 670 1 9 /Kg 175263 03/07/06 1417 rnffl j * la Description = Dry Wgt. Page 27 co3 au Hm STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 244550 CUSTOMER: Weston SoUrtionst; .Inc. Customer Sample ID: DF13-SS-SSQ2-O-O0QQ Date S a m p l e d ...... : 02/22/2006 Time S a m p l e d ...... : 14:52 Sample H a t r i x .....: Soi L l. ---- --- --rrt 'TE S T METHOD PARAMETER/TEST DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils} TOC A vera g e Duplicates, Solid 00 (S LABORATORY TEST RESULT S !"PROJECT: CONFIDENTIAL'DECATUR Laboratory Sample ID Date Re c e i v e d ....... Time Rec e i v e d ....... 244550-26 02/23/2006 10:25 Date:03/09/2006 ATTN: Jai Kesari SAMPLE RESULT'- Q FLAGS 9600 NDL ' 140 BL. 590 ! DILUTION i'UNITS 'BATCH' DT DATE/TIME TECH 1 mg/Kg T75263 03/07/06 1430 rnm ! i! :; __________________ * In Description = Dry Wgt. Page 28 1 ; i | i U hJ Eo-n STL Chicago -is part of Severn Trent Laboratories, Inc. Job Number: 244550 CUSTOMER;-.Westort Solutions^i.Inc. Customer Sample ID: DF13-SS-SSO2-0-0Q3 Date Sampled. 02/22/2006 Time S a m p l e d . ... 14:54 Sample M a t r i x . .. Soi L TEST: METHOD: :PARAMETER/TEST :D E S C R I P T 1 N : LLoyd Kahn Total Organic Carbon (Soils) :T0C Average Duplicates, Solid O'. LABORATORY TEST RESULTS PROJECT: CONFIDENTIAL D E CATUR Laboratory Sample ID Date Rec e i v e d ....... Time Rec e i v e d ....... 24455027 02/23/2006 10:25 Date:03/09/2006 . ATTO: Jai Kesarn -;' SAMPLE RESULT B200 f LAG Si UDII 140 RL DILUTION :LIMITS :BATCH DT ATE/TTOE TECH 620 mg/Kg 175263 03/07/06 1444 rnm * In Description = Dry tfgt. Page 29 o&codo pud 1fo---n41 STL Chicago is part of Severn Trent Laboratories, Inc. Job Number: 244550 LABORATORY CHRONICLE Date: 03/09/2006 CUSTOMER: Weston Solutions, Inc. ' PROJECT; CONFIDENTIAL DECAtUR ' -ATTN.:'.Jai. Kesari . Lab ID: 244550-1 METHOD EDD Lloyd Kahn Client ID: DF11-SS-SSQ2-0-0000 DESCRIPTION Electronic Data Deliverable Total Organic Carbon (Soils? Lab ID: 244550-2 METHOD Lloyd Kahn Client ID: DF11-SS-SS02-0-0003 DESCRIPTION Total Organic Carbon (Soils) Lab ID: 244550-3 METHOD LLoyd Kahn CLient ID: DF11-S5-SSQ3-0-DQ00 DESCRIPTION Total Organic Carbon (Soils) Lab ID: 244550-4 METHOD Lloyd Kahn CLient ID: DF11-SS-SS03-DB-0000 DESCRIPTION Total Organic Carbon (Soils) Lab ID: 244550-5 METHOD Lloyd Kahn CLient ID: DF11-SS-SS03-0-0003 DESCRIPTION TotaL Organic Carbon (Soils) Lab ID: 244550-6 METHOD LLoyd Kahn CLient ID: DF11-SS-SSQ4-0-0000 DESCRIPTION Total organic carbon (Soils) Lab ID: 244550-7 METHOD Lloyd Kahn Client ID: DF11-SS-SS04-0-0003 DESCRIPTION TotaL Organic Carbon (SoiLs) Lab ID: 244550-8 METHOD LLoyd Kahn CLient ID; DF11-55-SS05-0-0000 DESCRIPTION TotaL Organic Carbon (Soils) Lab ID: 244550-9 METHOD Lloyd Kahn CLient ID; DF11-SS-SS05-0-0003 DESCRIPTION TotaL Organic Carbon (SoiLs) Lab ID: 244550-10 CLient ID: D F05-SS-5501-0-0000 METHOD DESCRIPTION LLoyd Kahn Total Organic carbon (soils) Lab ID: 244550-11 CLient ID: DFO5-SS-SSO1-O-0003 METHOD DESCRIPTION LLoyd Kahn TotaL Organic Carbon (SoiLs) Lab ID; 24455Q-12 CLient ID: DF05-SS-SS02-0-000 METHOD DESCRIPTION LLoyd Kahn TotaL Organic Carbon (Soils) Lab ID: 244550-13 CLient ID: DFO5-SS-SSO2--0003 METHOD DESCRIPTION LLoyd Kahn TotaL Organic Carbon (SoiLs) Lab ID; 244550-14 CLient ID: DF12-SS-SS01-0-0000 METHOD DESCRIPTION LLoyd Kahn TotaL Organic Carbon (SoiLs) Lab ID: 244550-15 CLient ID: DF12-SS-SS01-0-0003 METHOD DESCRIPTION LLoyd Kahn TotaL Organic Carbon (SoiLs) Date Recvd: 02/23/2006 Sample Date: 02/21/2006 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 1 174520 174520 03/01/2006 1139 DILUTION Date Recvd; 02/23/2006 Sample Date: 02/21/2006 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 174520 174520 03/01/2006 1152 DILUTION Date Recvd: 02/23/2006 Sample Date: 02/21/2006 RUN# BATCH# PREP BT #<$) DATE/TIME ANALYZED 1 174520 174520 03/01/2006 1218 DILUTION Date Recvd: 02/23/2006 Samp Le Date: 02/21/2006 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 174520 174520 03/01/2006 1230 DILUTION Date Recvd: 02/23/2006 Sample Date: 02/21/2006 RUN# BATCH# PREP BT #(5) DATE/TIME ANALYZED 1 174520 174520 03/01/2006 1327 DILUTION Date Recvd: 02/23/2006 Sample Date: 02/21/2006 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 174520 174520 03/01/2006 1339 DILUTION Date Recvd: 02/23/2006 Sample Date: 02/21/2006 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 174520 174520 03/01/2006 1351 DILUTION Date Recvd: 02/23/2006 Sample Date: 02/21/2006 RUN# BATCH# PREP BT #(S> DATE/TIME ANALYZED 1 174520 174520 03/01/2006 1405 DILUTION Date Recvd: 02/23/2006 SampLe Date: 02/21/2006 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED 1 174520 174520 03/01/2006 1437 DILUTION Date Recvd: 02/23/2006 SampLe Date: 02/21/2006 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 174520 174520 03/01/2006 1511 DILUTION Date Recvd: 02/23/2006 Sample Date: 02/21/2006 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 174520 174520 03/01/2006 1521 DILUTION Date Recvd: 02/23/2006 SampLe Date: 02/21/2006 RUN# BATCH# PREP BT #(S> DATE/TIME ANALYZED 1 174520 174520 03/01/2006 1452 Date Recvd: 02/23/2006 Sample Date: 02/21/2006 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 175263 175263 03/07/2006 0911 DILUTION DILUTION Date Recvd: 02/23/2006 Sample Date: 02/22/2006 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 175263 175263 03/07/2006 0925 DILUTION Date Recvd: 02/23/2006 Sample Date: 02/22/2006 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 175263 175263 03/07/2006 0943 DILUTION STL Chicago Page 30 30 STL Chicago is part of Severn Trent Laboratories, Inc, Job Number: 244550 LABORATORY CHRONICLE Date: 03/09/2006 CUSTOMER: Weston SoLutions, Inc. PROJECT: CONFIDENTIAL-DECATUR ATTN: JaKesan Lab ID; 244550-16 Client ID; DF12-SS-SS02-0-0000 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (Soils) Lab ID: 244550-17 CLient ID: DF12-SS-S502-0-0003 METHOD DESCRIPTION Lloyd Kahn TotaL Organic Carbon (SoiLs) Lab i d : 244550-18 Client ID; DF12-SS-S503-0-0000 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (SoiLs) Lab ID: 244550-19 CLient ID; DF12-SS-SS03-CKI003 METHOD DESCRIPTION Lloyd Kahn TotaL Organic Carbon (SoiLs) Lab ID: 244550-20 CLient ID: DF12-SS-SS04-Q-QQQQ METHOD DESCRIPTION LLoyd Kahn TotaL organic Carbon (SoiLs) Lab ID: 244550-21 CLient ID: DF12-SS-5S04-Q-QQ03 METHOD DESCRIPTION LLoyd Kahn TotaL Organic carbon (SoiLs) Lab ID: 244550-22 Client ID; DF12-SS-SS05--000 METHOD DESCRIPTION Lloyd Kahn Total Organic Carbon (SoiLs) Lab ID: 244550-23 CLient ID; DF12-SS-SS05-0-0003 METHOD DESCRIPTION LLoyd Kahn TotaL Organic carbon (Soils) Lab ID: 244550-24 CLient ID: DF13-55-SSQ1-Q-QQQ0 METHOD DESCRIPTION LLoyd Kahn TotaL Organic Carbon (Soils) Lab ID: 244550-25 Client ID: DF13-55-SS01-0-0003 METHOD DESCRIPTION LLoyd Kahn Total Organic Carbon (SoiLs) Lab ID: 244550-26 CLient ID: DF13-SS-SS02-0-0000 METHOD DESCRIPTION LLoyd Kahn TotaL Organic Carbon (SoiLs) Lab ID: 244550-27 CLient ID: DF13-SS-5502-0-00Q3 METHOD DESCRIPTION LLoyd Kahn TotaL organic Carbon (SoiLs) Date Recvd: 02/23/2006 Sample Date: 02/22/2006 RUN# BATCH# PREP BT #(S> DATE/TIME ANALYZED 1 175263 175263 03/07/2006 1001 DILUTION Date Recvd: 02/23/2006 Sample Date: 02/22/2006 RUN# BATCH# PREP BT #<S> DATE/TIME ANALYZED 1 175263 175263 03/07/2006 1038 DILUTION Date Recvd: 02/23/2006 Sample Date: 02/22/2006 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 175263 175263 03/07/2006 1132 DILUTION Date Recvd: 02/23/2006 Sample Date: 02/22/2006 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 175263 175263 03/07/2006 1149 Date Recvd: 02/23/2006 Sample Date: 02/22/2006 RUN# BATCH# PREP BT #<S) DATE/TIME ANALYZED 1 175263 175263 03/07/2006 1205 DILUTION DILUTION Date Recvd: 02/23/2006 Sample Date: 02/22/2006 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 175263 175263 03/07/2006 1219 DILUTION Pate Recvd: 02/23/2006 Sample Date: 02/22/2006 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 175263 175263 03/07/2006 1245 Date Recvd: 02/23/2006 Sample Date: 02/22/2006 RUN# BATCH# PREP BT #(S> DATE/TIME ANALYZED 1 175263 175263 03/07/2006 1310 DILUTION DILUTION Date Recvd: 02/23/2006 Sample Date: 02/22/2006 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 175263 175263 03/07/2006 1346 DILUTION Date Recvd: 02/23/2006 SampLe Date: 02/22/2006 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 175263 175263 03/07/2006 1417 DILUTION Date Recvd: 02/23/2006 SampLe Date: 02/22/2006 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 175263 175263 03/07/2006 1430 Date Recvd: 02/23/2006 SampLe Date: 02/22/2006 RUN# BATCH# PREP BT #(S) DATE/TIME ANALYZED 1 175263 175263 03/07/2006 1444 DILUTION DILUTION STL Chicago Page 31 31 Job Number.: 244550 CUSTOMER: l'eston Sol ut ions y Inc. ; QUALITY CONTROL RESULTS PROJECT: CONFIDENTIAL DECATUR; Report Date.: 03/09/2006 ATTN: Jai KesarT... ... Test Method........ : Lloyd Kahn' Method Description. :: Total Organic Carbon' (Soils). 'Parameter.,....*.,, Organic Carbon, Tot, ( T O O ' QC Lab ID Reagent U n its ICV 174520-002 IQ6BSTTC2 MB 174520-003 ccv 174520-017 I06B5TTC2 CCB 174520-018 CCV 174520-017 I06BSTTC2 CCB 174520-018 mg/Kg mq/Kq mg/Kg mq/Kq mg/Kg mg/Kg QC ResuLt QC ResuLt 2007.42 29.00 2119.46 29.00 2110.86 29.00 U U U Batch.', Equipment Code:. 174520 TC4: ' Analyst.,, cLs : . . Test Code, TOC . True VaLue 2000.00 2000.00 2000.00 Orig. Value QC CaLc. F * Limits Date Time 100 X 85-115 03/01/2006 0816 03/01/2006 0819 106 X 85-115 03/01/2006 1208 03/01/2006 1212 106 X 85-115 03/01/2006 1536 03/01/2QQ6 1539 Test. Method......... : Lloyd Kahn Method ;Description. Y Total Organic. Carbon CSoi Ls) ;:::' Parameter.... .... : Organic Carbon, Tot. (TOC) Batch............ ' : 175263 Equipment Code.,. :J O C 4 Analyst,',.: nnm Test Code.: TOC QC Lab ID Reagent Units ICV 175263-002 I06BSTTC2 ICB 175263-003 LCS 175263-004 I00FSTLK3 CCV 175263-015 I06BSTTC2 CCB 175263-016 CCV 175263-015 I06BSTTC2 CCB 175263-016 mg/Kg mg/Kg mg/Kg mg/Kg mg/Kg mg/Kg mg/Kg QC ResuLt QC ResuLt 2034.92 29.00 4866.02 1903.97 29.00 1930.38 29.00 U U u True VaLue 2000.00 4780.00 2000.00 2000.00 Orig. VaLue QC CaLc. F * Limits Date Time 140.61 102 U 102 95 97 X 85-115 03/07/2006 0849 03/07/2006 0852 % 53-140 03/07/2006 0658 % 85-115 03/07/2006 1259 03/07/2006 1302 % 85-115 03/07/2006 1457 03/07/2006 1500 Test Method._____ _ Lloyd Kahn \ .::.Method.:Description. ..Total Organic Carbon CSOiLs) : : Parameter.... .... Organi c:Carbon, T.ot.. (T0c2) Batch.... .': 175263- Equipment Code....: T0C4 ' AnalystT: rnm ' .Test Code.: TQC2 QC Lab ID Reagent U nits LCS 175263-004 I00F5TLK3 mg/Kg QC ResuLt 2975,28 QC ResuLt True Value 4780.00 O rig, Value QC C alc- F * L im it s Date Time 62 % 53-140 03/07/2006 0B55 Test M e t h o d........ : Lloyd K a h n ..... ..... ......... Method Description.: .Total Organic Carbori ( s d U s ) Parameter.......... : TOC Average Duplicates Batch. ..... 174520 Equipment Code.. h.;.TOC4 AnaLyst...' '.cL's:. . Test Code. TOCAV2 QC Lab ID Reagent Units LCS 174520-004 I00FSTLK3 mg/Kg QC ResuLt 4046.99 QC ResuLt True VaLue 4780.00 Orig. VaLue QC CaLc. F * Limits Date Time B5 % 53-140 03/01/2006 0827 Test M e t h o d ..... , : LLoyd Kahn ::Method Desc ription. : Total Organic Carbon (SoiIs).... Parameter.., iv-j : TOC Average'Duplicates 'Batch... h ....... : 175263. ::.E q u ipment- Code.v .. T0C4 Analyst. .!. : rnm Test Code, : T0CAV2 QC Lab ID Reagent units LCS 175263-004 IFSTLK3 MS 244550-23 I06BSTTC2 MSD 244550-23 I06BSTTC2 mg/Kg mg/Kg mg/Kg QC Result 3920.65 8007.34 8950.58 QC ResuLt 8950.58 True VaLue 4780.00 2000.00 2000.00 Orig. VaLue 8007.34 8007.34 QC CaLc. F * Limits Date Time 82 % 53-140 03/07/2006 0358 142 N % 53-140 03/07/2006 1329 103 % 53-140 03/07/2006 1353 32 * R 30 STL Chicago Page 32 * X=X REC, R=RPD, A-ABS Diff., D=X Diff. 32 ; a u a i i T y 'A-.'S U'ft a n c e :'m .e t h -s R E F E R E N 5 A N D ! .N 0 T E S ' Report Dat: :03/09/2006 REPORT COMMENTS 1) A U pages oT this report are integral parts of the analytical data. Therefore, this report should be reproduced only in its entirety. 2) Soil, sediment and sludge sampLe resuLts are reported on a "dry weight" basis except when anaLyzed for Landfill disposaL or incineration parameters. ALL other solid matrix samples ar e reported on an "as received" basis unLess noted differently. 3) Reporting Limits are adjusted for sample size used, dilutions and moisture content if applicable. 4) The test resuLts for the noted analytical method(s) meet the requirements of NELAC. Lab Cert. ID# 100201 5) According to 40CFR Part 136.3, pH, Chlorine Residual and Dissolved Oxygen analyses are to be performed immediately after aqueous sampLe collection. When these parameters are not indicated as fieLd (e.g. pH F ie ld ) they were not analyzed immediately, but as soon as possibLe on Laboratory receipt. G lo ssa ry o f f la g s , q u a lif ie r s and a b b re v ia tio n s (any number of which may appear in the re p o rt) In o rg a n ic Q u a lif ie r s (Q-CoLumn) U Analyte was not detected at or above the stated limit. < Not detected at or above the reporting Limit. J Result is Less than the RL, but greater than or equal to the method detection Limit. B Result is Less than the CRd L/RL, but greater than or equal to the IDL/MDLS Result was determined by the Method of Standard Additions. F AFCEE: ResuLt is Less than the RL, but greater than or equaL to the methoddetection Limit, inorganic Flags (FLag Column) ICV,CCV,ICB,CCB,ISA,ISB,CRI,CRA,MRL: Instrument reLated QC exceed the upper or Lower controL Limits. * LCS, LCD, MD: Batch QC exceeds the upper or Lower controL Limits. + MSA correlation coefficient is Less than 0.995. 4 MS, MSD: The analyte present in the original sample is 4 times greater than the matrix spike concentration; therefore, controL Limits are not applicable. E SD: SeriaL dilution exceeds the controL Limits, H MB, EBl, EB2, EB3: Batch Qt is greater than reporting Limit or had a negative instrument reading Lower than the absolute value of the reporting Limit. N MS, MSD: Spike recovery exceeds the upper or Lower control Limits. U AS(GFAA) Postedigestion spike was outside 35-115^ control Limits. Organic Qualifiers (Q - Column) U Analyte was not detected at or above the stated Limit. ND compound not detected. J R e su lt i s an estim ated v a lu e beLou the re p o rtin g Lim it or a t e n t a t iv e ly id e n t if ie d compound ( T I C ) . Q ResuLt was qualitatively confirmed, but not quantified. C Pesticide identification was confirmed by GC/MS, Y The chromatographic response resembles a t y p ic a l fu e l p a tte rn . Z The chromatographic response does not resemble a typical fueL pattern. E ResuLt exceeded c a lib ra tio n range, secondary d ilu tio n required. F AFCEE:ResuLt is an estimated value below the reporting Limit or a tentatively identified compound (TIC) Organic Flags (FLags Column) B MB: Batch QC i s g re a te r than re p o rtin g L im it . * LCS, LCD, ELC, ELD, CV, MS, MSD, Surrogate: Batch QC exceeds the upper or Lower controL Limits. EB1, EB2, EB3, MLE: Batch QC is greater than reporting Limit A Concentration exceeds the instrument calibration range a Concentration is below the method Reporting L im it (R L) B Compound was found in the blank and sample. D Surrogate or m atrix sp ike re co v e rie s were not obtained because the e x t r a c t was d iLu ted f o r analysis; also compounds analyzed a t a diLution wiLL be fLagged with a D. H Alternate peak selection upon analytical review I Indicates the presence of an interfence, recovery is notcalculated. M ManuaLLy integrated compound. P The Lower of the two values is reported when the Ji difference between the resuLts of two GC coLumns is STL Chicago Page 33 33 .U A L I T Y A - S S U R A N C E ' . K I T H 0 D S'. REFERENCES AND NOTES Report. Date: 03/09/2006 greater than 25%, A b b re v ia tio n s AS Post Digestion Spike (GFAA SampLes - See Note 1 be Low) Batch Designation given to identify a specific extraction,, digestion,preparation set, oranaLysis set CAP CapiLLary Column CCB Continuing Calibration Blank CCV Continuing Calibration verification CF Confirmation analysis of original Cl confirmation analysis of A1 or Di C2 confirmation analysis of A2 or D2 C3 Confirmation analysis of A3 or D3 CRA Low Level standard Check - GFAA; Mercury CRI Low LeveL Standard check - ICP CV CaliLbratioh Verification Standard DiL Fac Dilution Factor - Secondary diLution analysis D1 DiLution 1 D2 Dilution 2 D3 Di Lution 3 DLFac Detection Limit Factor DSH DistiLLed Standard - High LeveL DSL DistiLLed Standard - Low LeveL DSM DistiLLed Standard - Medium Level EB1 Extraction Blank 1 EB2 Extraction Blank 2 EB3 DI Blank ELC Method Extracted LC5 ELD Method Extracted LCD ICAL InitiaL calibration ICB InitiaL Calibration BLank ICV InitiaL Calibration Verification IDL instrument Detection Limit ISA Interference Check Sample A - ICAP ISB Interference Check Sample B - ICAP Job No. The first six digits of the sampLe i d which refers to a specific client, project and sample group Lab ID An B number unique Laboratory identification LCD Laboratory ControL Standard Duplicate LCS Laboratory ControL Standard with reagent grade water or a matrix free fromtheanalyte ofinterest MB Method Blank or (PB) Preparation BLank MD Method Duplicate MDL Method Detection Limit MLE Medium Level Extraction BLank MRL Method Reporting Limit Standard MSA Method of Standard Additions MS Matrix Spike MSD Matrix Spike Duplicate ND Not Detected PREPF Preparation factor used by the Laboratory's Information Management System (LIMS) PDS Post Digestion Spike (ICAP) RA Re-analysis of original Al Re-analysis of Di A2 Re-analysis of D2 A3 Re-analysis of D3 RD Re-extraction of diLution RE Re-extraction of original RC Re-extraction confirmation RL Reporting Limit RPD Relative Percent Difference of duplicate (unrounded) analyses RRF ReLative Response Factor RT Retention Time STL Chicago Page 34 34 Q U A L . I T Y A i 5 U.R A N C E-' H E. T H t> S : R E F E R E N C E S A N D . N 0 f S .. .. Repart Dat;. 03/09/2006 RTW Retention Time Window Sample ID A 9 digit number unique for each sampLe, the first six digits are referred as the job number 5CB Seeded ControL BLank SD Serial Dilution (Calculated when aampLe concentration exceeds 50 times the MDL) UCB Unseeded ControL Blank SSV Second Source Verification Standard SLCS Solid Laboratory ControL Standard(LCS) PHC pH Calibration Check LCSP pH Laboratory Control EompLe LCDP pH Laboratory ControL SampLe Duplicate MDPH pH SampLe Duplicate MDFP FLashpoint SampLe Duplicate LCFP FLashpoint LCS Gl GeLex Check Standard Range 0-1 G2 GeLex check Standard Range 1-10 G3 GeLex Check standard Range 10-100 GU GeLex Check standard Range 100-1000 Note 1; The Post Spike Designation on Batch QC for GFAA is designated with an "S" added to the current abbreviation used. EX. LCS S=LCS Post Spike (GFAA); MSS-NS Post Spike (GFAA) Note 2: The MD calculates an absoLute difference (A) when the sample concentration is less than 5 times the reporting Limit. The control Limit is represented as +/- the RL. STL Chicago Page 35 35 CHAIN OF CUSTODY STL Chicago 36 CHAIN OF CUSTODY / ANALYSIS REQUEST FORM 54455os Severn Trent Laboratories T: 708-534-5200 F: 708-534-5211 2417 Bond Street University Park, IL 60466 PAGE 3 o f 5 PROJECT INFORMATION Client: Weston Solutions, Inc. 1400 Weston Way, BEdg. 5-2 West Chester, PA 19380 T: 610-701-3761 F: 610-701-7401 Project Manager. Jai Kesari enn:ari: i.kesarfo)westonsolutions.com Project Name: Reference No: Decatur, AL FSEA G P Investigation 02181-129-081-0001 ANALYSES REQUESTED 1 Sampler: T. Frinak, T. Wails, D. Armstrong P.O. #: Quotation #: SAMPLE ANALYSIS ExyLIMS # Client Sample Identification | D F 1 1 SS SS02 0 0000 M W z im D F 1 1 SS SS02 0 0003 xc : S DF 1 1 SS SS03 0 0000 DF11 ss S S 03 DB 0000 DF11 ss SS03 0 0003 -- - DF11 :vs: DF 1 1 i si DF11 DF11 ss ss ss ss SS 04 SS 04 SS 05 SS05 0 0000 0 0003 0 0000 0 0003 DF05 ss SS01 0 0000 C o lle c tio n Date 21-Feb-06 21-Feb-06 21-Feb-06 21-Feb-06 21-Feb-06 21-Feb-06 21-Feb-06 21-Feb-06 21-Feb-06 21-Feb-06 C o lle c tio n Tim e 14:54 14:55 15:12 15:12 15:13 15:28 15:29 15:48 15:50 16:03 X X X X X X X X X X S a m p le M atrix 1 Soil 1 Soil 1 Soil 1 Soil 1 Soil 1 Soil 1 Soil 1 Soil 1 Soil 1 Soit CHAIN OF CUSTODY Cooler ID No.: Rei inquL&hed^y : Djite, Time zArzf& f?3< Z> '7 Received By: Fed Ex \m t Cooler Temp. (C): Date Time Jr ft Grab Sample C o m po site No. of C o n ta in e rs TOC Comments 0 - 3 Inches 3 - 6 inches 0 - 3 inches 0 - 3 inches 3-6 inches 0-3 inches 3-6 inches 0 - 3 inches 3- 6 inches 0- 3 inches iX :X ;X X X X X X X X PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: Sample Results Only Add Case Narrative Add Quality Control Summary Add Calibration Summary Add R a w Data Other: STL Chicago CHAIN OF CUSTODY/ ANALYSIS REQUEST FORM <34-4550 Severn Trent Laboratories T: 708-534-5200 F: 708-534-5211 2417 Bond Street University Park, IL 60466 PAGE 4 of 5 PROJECT INFORMATION Client: Weston Solutions, Inc. 1400 Weston Way, Bldg. 5-2 West Chester, PA 19380 T: 610-701-3761 F: 610-701-7401 Project Manager: Jai Kesari em ail: f.kesaritweston so Iuti ons. co m Project Name: Reference No: Decatur, AL FSJA G P Investigation 02181-129-081-0001 ANALYSES REQUESTED 1 Sampler: T. Frinak, T. Walls, D..Armstrong P.O. #: Quotation #: Grab Sample Composite No. of Containers STL Chicago SAMPLE ANALYSIS _________________________________________ I C ollection Collection ExyLIMS n Client Sample Identification Date Tim e DF05 SS SS01 ! 0 0003 21-Feb-06 16:05 X DF05 SS SS02 0 0000 21-Feb-Q5 16:15 X DF05 SS SS02 0 0003 21-Feb-OS 16:17 :X D F 12 SS SS01 0 0000 22-Feb-06 13:25 X DF12 SS n M & M M DF 12 SS SS01 0 0003 22-Feb-06 13:27 X SS02 0 0000 22-Feb-06 13:40 X DF12 SS SS02 0 0003 22-Feb-06 13:41 X DF12 S S SS03 0 0000 22-Feb-06 13:50 X ID F 12 SS SS03 0 0003 22-Feb-06 13:52 X DF12 SS SS04 0 0000 22-Feb-05 14:10 X S a m p le M a trix 1 Soil 1 Soil 1 Soil 1 Soil 1 Soil 1 Soil 1 soil : 1 Soil 1 soil : 1 Soii CHAIN OF CUSTODY Cooler ID No.: Re 1inqu D a te , Time Received By: f 7 />3& F$dx \K* Cooler Temp. (C): Date Time t ir GP03 Comments 3 - 6 inches 0- 3 inches 3- 6 inches 0- 3 inches 3 - 6 inches 0- 3 inches 3 - 6 inches 0- 3 inches 3- 6 inches 0- 3 inches O O1X X X X X X X X X X PROJECT REQUIREMENTS Results Deadfine: Laboratory Report Options: Sample Results Ontv Add Case Narrative Add Quality Control Summary Add Calibration Summary Add R a w Data Other: CHAIN OF CUSTODY / ANALYSIS REQUEST FORM 2 44S0 Severn Trent Laboratories T: 708-534-5200 R 708-534-5211 2417 Bond Street University Park, IL 60466 PAGE 5 of 5 PROJECT INFORMATION Client: Weston Solutions, Inc. 1400 Weston WayTBldg. 5-2 W est Chester, PA 19380 T: 610-701-3761 F: 610-701-7401 Project Manager: Jai Kesari ermaiI: i.kes ariiwesto nso Iut ions. com Project Name: Reference No: Decatur, AL FSIA G P Investigation 02181-129-081-0001 ANALYSES REQUESTED 1 Sampler: T. Frinak, T. Walls, D. Armstrong P.O. #: Quotation #: Grab Sample No. of Containers SAMPLE ANALYSIS ExyLIMS # Client Sample Identification | Collection Collection Date Time 'SoD. oEQ Sample Matrix DF12 SS SS04 0 0003 22-Feb-06 14:11 X 1 : Soil I '.Z L - DF12 SS - "'-v DF12 ss SS05 SS05 0 0000 22-Feb-06 14:26 0 0003 22-Feb-06 14:23 X X 1 Soil ! 1 Soil DF 1 3 ss SS01 0 0000 22-Feb-06 14:40 X 1 Soil DF 1 3 ss SS01 0 0003 22-Feb-06 14:41 X 1 Soil DF13 ss SS02 0 0000 22-Feb-06 14:52 X 1 Soil DF13 ss SS02 0 0003 22-Feb-06 14:54 X 1 Soil Comments 3-6 inches 0-3 inches 3-6 inches 0-3 inches 3-6 inches 0 - 3 Inches 3 - 6 inches uo 1X X X X X X X .......-._7-___ - CHAIN OF CUSTODY Re 1inQ d y s fa p f? By : Date :7 / Time Cooler ID No.: Received By: Fed Ex a& GP03 Cooler Temp. (C): Date Time Jj PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options: Sample Results Only Add Case Narrative Add Quality Control Summary Add Calibration Summary Add Ra w Data Other: u .-J E-- Samp l e Lot#:_ Internal Sam ple Custody Transfer Record Client:______ _________________________________ S a m p l e No, Analysis Relinquished by: , n r i ' -7^ j / - 7 . z _______________ -7f ^ > ^ f-------------- c yJ ^/ ./lp^ A D e * ? . ----------- ------- --------------------- ------ Received by: cT h______ Date f .. Time Comments 9 \3 o ------------------ ---- ------- -------- ------- ~ ~ ------------------- ~ - t? ----------------------- ------------ ----- 3 --------------I -------------- --------- r I I i ! i .A CHI-22-1 1 - G G 1 / C M (\ rpjsekL Job sampLe Receipt checklist Report Job Number.: 244550 Location.: 57222 Check List Number.: 1 Description.: Customer Job ID.... : Job Check List Date.: 02/24/2006 Project Number.: 0004891 Project Description.: Confidential Decatur - FC Investigation Customer.......: Weston Solutions, Inc. Contact.: Jai Kesari Questions ? (Y/N) Comments V2 Date of the Report..: 03/09/2006 Project Manager.... : rcw Chain-of-Custody Present?........................... Y Were samples dropped off at or picked up by STL?.. N custody seal on shipping container?............. . Y ...If "yes", custody seal intact?.................. Y Custody seaLs on sample containers?..... ..... .... N ...if "yes", custody seal intact?.................. SampLes iced?--- ............................... Y Temperature of cooler acceptable? (4 deg C +/- 2). Y 4.4 samples received intact (good condition)?......... y Volatile sampLes acceptable? (no headspace)....... Correct containers used?.......... ,,,............... Y Adequate sample volume provided?................... Y SampLes preserved correctly?........................ Y SampLes received within hoLding-time?... ........... Y Agreement between CQC and sample Labels?.......... Y R a d io a c t iv it y a t or beLow background L e v e L s?.............. Y A sample D iscrepancy Report (SDR) was needed?........... N Residual Chlorine Check Required? If sampLes were shipped was there an air bill tf?.. Y Sample custodian Signature/Date................... ,, Y Page 1 STL Chicago 41 nrr U S A ir b ill Express 354D =ib37 fit.55 R ecipient's C opy 4a Express Package Service ra satiwxvrwswr. sfl>ns, fbekagssBptoia&s. Sender's t ^^ HTM _ .. 7 7 &l___& j./ W i ^_ Compairr A/ -**& 2 S k - 3 V ' M t - i y i(rDt^fHtaifd&tacstPesri*ority.Overnight r' iI-- II FNteedbEutxtSe&isndtaorrdumO"varright |I-- I1FEJecdtEetxaFtAirbsutstGesvaeramnrirrfiiil Itf^ttiriw tkca rt n t* tawssite-- 1-- ITIFtfeMtMduEtnuxsniEdaxfdpynr.ei's'rs Sauer Pi%iirrjwrttqtDwmtlftft. Sonico PtSinMHIhftirr.mMiH[ Package-sTeo.ver fS ttb s ft* p~l Rwjfa'fflgyFrejgbt '' ' |^'F6fl&^ta^Freigitf Adcfress / f ' o o < r r # r tL T % c /:s ' f t A ' City C A ^T id J*L^ State A l z ip 2 YbrInternal BillingReference 02 3 To te c ip ie rrfs Name , S A $ / - - u t _ /i c /2 y yJ: )j? / Fhtwe t R etripienft Address rfe______ Wt c$4me M i n n P.(L4aiii jj^fcOL ATndldeqrejisvstQp*cbhiif2beoatb^*e httffUJclttLiK % Hch ;;FFk /j EeLhiM j vpnrfME^ntt-iiihit. 5 -r oerofkHKawiiHti n FedEx snnJaprr*f.3ui> PiJi Box fctlaiadw**irtJM FedEx Tube Other hd W Fejfa mMt-- to S r i n l I-- I SAIUtDAVOeAny U 1D.0-rBrrrFireJiVs.iF.K*fjiidSFtnaric&TSHQDri# FiigN tasetoaPcodas. r~-i HOUiVUeefatay l J atFedExIx ca liin fIfttllMjtttfefthlrTjt r-- 1 HOLDSotesitau |_ j Matt--FeCdUErxi-lifi-ciaUiE*a-iinntr DefectbeeanjJotraeC.i:Stay Om s few tM p *e ttt ca s s ie rfanganm jtradtT OM-IitntnmbBA t c M No 1P--IIYSsepKswtfWldailcWhrt^-tni. * Dry fca iH.'ka.Ml O itft w i k O i w l it t t ib 'ia ic in e h A f f t i riFtrO P I Cargo AircraftOnly 7 Payment Bfffte MerFaExAm.Nl vCndtCWN*.Mpw Sender Arm*HniivInj naHtal O Flecfpent l I I Wm) Party Q CraddCerd Otter RenpJ Acd.No. ' l l CaatVCheck City t 'V / ' s ' A / ' l State ZTP & & Tutti Packages TbttlW aighl Tatti DeclaredUafned Totardtarpaa / _____ ___________ *___________ JO W Is tft^ u toXtodln SUCintatoYOuteefere h'0Kr usta. Sea bscthrdatofe. * N E W Residential Delivery Signature Options r)WJH H(BtixEtadOvsiorMnct L 8540 9637 S665 WoSignatura D irect .Signature IAcks*3s*nSvrbLBl(tiit.t.v D . _ u H m u tifw n '" HP" trM i< r ,-- , Jndfrwtffianatcuro iHthsitwair^iitieamh')sf.JismlismmHu*nntn-i * Qgniit-ihn eirai^iigii-iDBfai.c-fWiiai fie ei. srr j---------- fI *S* *E" OM l1 1 4 OuestionsTGotoourWdhsita atfadexxmnerciill re. GoFed&rieoo.Jff5.5lB, o- DffOi U S u -j H ert CASE NARRATIVE STL Chicago Wet Chemistry Case Narrative Client: Job #: Weston - Confidential Decatur 244550 Date Rec'd: 02/23/06 This narrative covers the analysis o f the samples in the above Job # for TOC by the Lloyd Kalin Method. The samples were analyzed for TOC in duplicate by furnace combustion and non-dispersive infrared detection on a Dohrmann Phoenix 8000 TOC analyzer, after acidification to remove inorganic carbon, and low-temp drying. No correction was made, therefore, for moisture content. The average o f the sample bums is reported. 2. The method-recommended holding time o f 2 weeks was met. Refer to the Laboratory Chronicle Page for dates of sampling, receipt, and analysis. 3. The TOC calibration curve and the initial and continuing verification standards and blanks met acceptance criteria. 4. The method blanks were less than the reporting limit. For this test the ICB and method blank are the same. 5. The LCSs were within acceptance limits, 6. The MS on sample 23 was biased high, at 142% recovery. The initial MSD attempt was over the range of the calibration curve and was repeated, at which time it was in control, at 103% recovery. Several of these samples, including sample 23, contained small black bits, which may have contained significant carbon. The samples were well-homogenized prior to analysis, but the matrix apparently affected the reproducibility of the MS and MSD, Wet Chemistry Section Manager STL Chicago Date 44 RAW DATA *** RUN LOG *** <V2 ) 3/9/06 11:42 Total Organic Carbon (Soils) Method Code--: TOCS Batch Code...: 174520 Status........ : RVWD Batch Date,..: 03/01/06 Batch Time...: 934 User Name...... : els QC Code......... : TOCS Calc Code......: TOCS Location Code..; 57222 Equipment Code.: TOC4 Import Code---- : TEST CODE TTTrrTTTTTT TT 0000000CC C 1II C cC cccC S S S C cc 234AAA 2A S ss VVV V 2A 234 2 2 SAMPLE: Grp Pos 11 12 Sample ID ICAL 106ASTTC1A __ J C \ M Q 6 B S T T C 2 _ Dilution t e s t POS Date / Time 12 3 45 6 7 1 1 12 2 2 7 89 0 12 0 3/1/06 1 0816 13 __MB_ 3/1/06 1 0819 0 14 15 ___L C SJ00F S T L K 3 _ 3 244549_13^S___ 3/1/06 1 0827 3/1/06 1 0853 0 0 1 6 17 18 19 244549_14_S___ 244549_14_S_MS_I06BSTTC2_6 244549_14_S_MSD_I06BSTTC2_6 244549_15_S___ 3/1/06 1 0908 3/1/06 1 0923 3/1/06 1 0932 3/1/06 1 0947 0 0 0 0 1 10 1 11 1 12 1 13 1 14 1 15 1 16 1 17 1 18 1 19 1 20 1 21 1 22 1 23 1 24 1 25 1 26 1 27 1 28 244549^16^5___ 244549_17_S___ 244549_18_S___ 2 4 4 5 4 9 J 9 _ S ___ 244549_20_S___ 2 4 4 5 5 D _ 1 _ S ___ 244550_2_s___ ___ CCV_IQ6B5TTC2_ ___ CCS__ 244550^3^3___ 244550_4_S___ 2 4 4 5 5 0 ___ 244550,,6_S___ 244550_7_S___ 244550_8_S___ 244550_9_s___ 244550_12_S___ 244550_10_S___ 244550_11_S___ STL Chicago 1 Pane 1 3/1/06 1 1000 3/1/06 1 1022 3/1/06 1 1035 3/1/06 1 1106 3/1/06 1 1119 3/1/06 1 1139 3/1/06 1 1152 3/1/06 1 1208 0 3/1/06 1 1212 0 3/1/06 1 121a 3/1/06 1 1230 3/1/06 1 1327 3/1/06 1 1359 3/1/06 1 1351 3/1/06 1 1405 3/1/06 1 1437 3/1/06 1 1452 3/1/06 1 1511 3/1/06 1 1521 -- 0 0 0 Q 0 0 0 0 0 0 0 0 0 0 0 0 0 46 *** RUN LOG *** CV2 3/9/06 11:42 STL Chicago Page 2 47 QC S um m ary *** <V2 Total Organic Carbon (Soils) Method C o de ..: TOCS Batch Code.. . : 174520 S ta tu s .............: RVUD Batch Date.. : 03/01/06 Batch Time.. : 934 User Name... : els QC c o d e ........ TCS Calc code....,. TOCS Location Code,, 57222 Grp Grpp Sample ID Pos Test Result Known O rigina l 1 2 ___ICV_I06BSTTC2_ 1 TOC 2007-42 200D 13 MB 1 TOC -2,47 1 4 ___ L C S J 0 0 F S T L K 3 J 5 TQCAV2 4046.99 4730 17 244549_14_S_MS_I06BSTTC2_6 5 T0CAV2 9925.13 2000 4354.99 10 244549_14_S_MSDJ06BSTTC2_6 5 TOCAV2 12323.75 2000 4354,99 1 17 ___ C C \ M 0 6 B S r r C 2 _ 1 TOC 2119.46 2000 1 15 CCB 1 TOC -2.85 1 29 ___ CCV_IQ6BSTTC2_ 1 TOC 2110.06 2000 1 30 ___ CCB__ 1 TOC -2.72 Report Date: 3/9/06 11:42 Equipment Code.: T0C4 Import Code___ : A lte rn a te QC Res 100 F QC Rea F 9925.13 35 96 123 106 23 106 STL Chicago Page 1 48 *** RAW TEST DATA **+ (V2 ) Total Organic Carbon (Soils) Method Code,,: TCS Batch Code,,.: 174520 S ta tu s ___ . . . : RVWD Batch Date,,.: 03/01/06 Batch Time...: 934 User Name : e ls SAMPLE: Grp Pos Sample ID 11 12 13 14 15 16 17 18 19 1 10 1 11 1 12 1 13 1 14 1 15 1 16 1 17 1 18 1 19 1 20 1 21 1 22 1 23 1. 24 1 25 1 26 1 27 1 28 1 29 1 30 ICAL 10ASTTC1A ICV I0BSTTC2 MB LCS I00FSTLK3 3 244549 13 S 244549 14 S 244549 14 S MS I06BSTTC2 6 244549 14 S MSD 10BSTTC2 6 244549 15 s 244549 16 S 244549 17 S 244549 18 S 244549 19 S 244549 20 S 244550 1 S 244550 2 S CCV I06BSTTC2 CCB 244550 3 S 244550 4 S 244550 5 S 244550 6 S 244550 7 S 244550 8 S 244550 9 S 244550 12 S 244550 10 S 244550 11 S CCV I06BSTTC2 CCB C Co d e ......... : TOCS Calc Code...... : TOCS Locatoh Code..: 5/222 Dilution TOC mg/Kg T0C2 mg/Kg Report Date: 3/9/06 11:42 Equipment Code.: T0C4 Import Co d e ---- : TOC3 mg/Kg TOC4 mg/Kg T0CAV2 mg/Kg 2007.42 -2.47 4240.74 7665.14 4822.98 9925.13 12323.76 14009.53 11528.97 7574.23 4809.36 5667.75 3603.97 12839.22 6967.66 2119.46 -2.85 5074.86 5050.17 2313.37 2123.92 1307.35 6595.55 4016.41 4291.48 2244.25 972.65 2110.86 -2.72 3853.24 8282.06 4887.00 13337,73 13223.70 7160.53 4140.13 3251,05 3270.29 12030.20 7904.67 4771.18 4820.93 2327.90 1512.04 1122.36 5834.92 3926.51 2816.10 1391.78 906.96 4046.99 7973.60 4854.99 9925.13 12323.78 13673.63 12376.33 7367.38 4474.74 4459.40 3437.13 12434.71 7436.26 4923.02 4935.55 2320.64 1817.98 1214.86 6215.24 3972.46 3553.79 1818.02 939.80 STL Chicago Page 1 49 *** RAW TEST DATA lk-itA (V2 Total organic carbon (Soils) Method Co d e . .: TOCS Batch C o d e . ..: 1745?n Status....... : RVWD Batch D H t e . 03/01 /OA Batch Time...: 934 User Na m e ___ : els SAMPLE: Grp Pos Sample ID 11 ICAL I0ASTTC1A 12 ICV 06BSTTC2 13 MG 14 LCS I00FSTLK3 3 1 5 244549 13 S 1 6 244549 14 S 1 7 244549 14 S MS I0B5TTC2 6 1S 244549 14 S MSD J0BSTTC2 6 1 9 244549 15 S 1 10 244549 16 S 1 11 244549 17 S 1 12 244549 IS S 1 13 244549 19 S 1 14 244549 20 5 1 15 244550 1 S 1 16 244550 2 S 1 17 CCV I06BSTTC2 1 IS CCB 1 19 244550 3 S 1 20 244550 4 S 1 21 244550 5 S 1 22 244550 6 S 1 23 244550 7 S 1 24 244550 S S 1 25 244550 9 S 1 26 244550 12 S 1 27 244550 10 S 1 28 244550 11 S 1 29 CCV I0BSTTC2 1 30 CCB QC Code... Cfltr. Code. TOCS TOCS Location Code..: 57222 Di lut ion TDCAV3 mg/Kg TOCAV4 mg/Kg Report Date: 3/9/06 11:42 Eauibinent Code,: TC4 Imnnrt Code. TOCR1 ug TOCR2 ug TOCR3 ug 100.3711 0.3954 129.3425 318.869 B.813 187,5849 211.9691 319.4173 144.1121 111.3412 40.S79 105.9869 56.2220 138.6636 73.1625 105.9729 -0.4567 45.6737 66.6623 29.6111 24.4251 29,1538 130.5918 74.7425 81.9673 52,5154 23.6355 105.5431 -0.4357 103.2669 223.6155 95.7852 265.4209 198.3555 8D.1979 49.2676 56.2431 52,6516 123.9111 83.7895 44.3720 75.2065 40.5055 34.4746 36.0278 151.7080 87.5611 47.0289 39.5266 32.3784 STL Chicago Page 2 50 +** RAW TEST DATA * (V2 ) Total Organic Carbon (Soils) Method Code . Batch code. S t a t u s . .... TOCS 174520 RVWD Batch Date.. : 03/01/06 Batch Time.. : 934 User Name,,. : els SAMPLE: Grp Pos Sample ED 11 12 13 14 15 16 17 1Q 19 l 10 1 11 1 12 1 13 1 14 1 15 1 16 1 17 1 18 1 19 1 20 1 21 1 22 1 23 1 24 1 25 1 26 1 27 1 28 l 29 1 30 ICAL 106ASTTC1A ICV IQ6BSTTC2 MB LCS ]Q0FSTLK3 3 244549 13 S 244549 14 S 244549 14 S MS I0BSTTC2 6 244549 14 S MSD I06BSTTC2 6 244549 15 S 244549 16 S 244549^17" S 244549 IS S 244549~19~S 244549^20 S 244550 1 S 244550 2 S ___ C C V J 0 B S T T C 2 _ CCB 244550 3 S 244550 4 S 244550 5 S 244550 6 S 244550 7 S 244550 8 S 244550 9 S 244550"12 S 244550 10 S 244550 11 S ___ C C V J 0 6 B S T T C 2 _ CCB C Code.. TOCS Calc code TOCS Location Code..: 57222 Dilution TOCR4 wg UT1 9 Report Date: 3/9/6 11:42 Equipment Code.; T0C4 import Code___ : WT2 WT3 09 WT4 0 0,05 0.16 Q.0305 0.0416 0.01B 0.01B9 0.0172 0.0223 0.0125 0.0147 0,0085 0.0187 0.0156 0.0108 0.0105 0.05 0.16 Q.009D 0,0132 0.0128 0.0115 0,0223 0.019 0.0186 0.0191 0.0234 0.0243 0.05 0.16 D.268 0.0270 0.0196 0.0199 0.0150 0.0112 0.0119 0.0173 0.0161 0.0103 0.0106 O.D093 0.0156 0.0174 0.0228 0.0321 0.0260 0.0223 0,0167 0.0284 0.0357 STL Chicago Page 3 51 *** RAW TEST DATA *** (V2 ) Total Organic Carbon (Soils) Method Code,,: TOCS Batch Code...: 174520 Status.......: RVWD Batch Date, 03/01/06 Batch Time., .: 934 User Name,, els SAMPLE: Grp Pos Sample ID 11 12 13 14 15 16 17 18 19 1 10 1 11 1 12 1 13 1 14 1 15 1 16 1 17 1 18 1 19 1 20 1 21 1 22 1 23 1 24 1 25 1 26 1 27 1 28 1 29 1 30 ICAL I06ASTTC1A ICV I06BSTTC2 MB LCS I00FSTLK3 3 244549 13 S 244549 14 s 244549 14 S MS IBSTTC2 6 244549 14 S MSD I06BSTTC2 6 244549 15 S 244549 16 S 244549 17 S 244549 13 S 244549 19 s 244549 20 S 244550 1 S 244550 2 S CCV I06BSTTC2 CCB 244550 3 S 244550 4 S 244550 5 S 244550 6 S 244550 7 S 244550 3 S 244550 9 S 244550 12 S 244550 10 5 244550 11 S CCV IQ6BSTTC2 CCB QC Code........ : TOCS Calc Code.,.,,, : TOCS Location Code..: 57222 Dilution DLFAC N/A TCS mg/Kg Report Date: 3/9/06 11:42 Equipment Code.: TQC4 Import Co d e --- : C52 mg/Kg TCSAV2 mg/Kg TICS mg/Kg 3.2000 1.0000 5.5846 4.6647 8.5106 8.4656 9.3023 7.4941 11.6364 12.3552 15.6863 . 8.8889 ID.0946 15,1659 15.1659 3.2000 1.QD0 17,4863 11.1111 10.5960 9,3294 5.8824 6.9369 7.8240 8.9385 6.1776 5.3333 3.2000 1.0000 STL Chicago Page 4 52 Calibration Report Print Date/Time: 2006/03/01 7:15:27 Cal. Curve ID: SO ItCURVE Created: 02/20/200612:00 Calibration Factor (m): 1070e+05 Y Intercept (b): -296565 r-squared: 0.99773 Standard ID Y X Expected Measured Message Date& Raw Data ug C ug C Time 0 ugram C -2378 0.000 2.748 No Sample Det 02/20/2006 09:53 10ugramC 1395589 10.000 15.809 02/20/2006 10:07 20 ugram C 2153844 20.000 22.893 02/20/2006 10:23 40 ugram C 4050968 40.000 40.617 02/20/2006 10:38 80 ugram C 7850154 80.000 76.111 02/20/2006 11:14 120 ugram C 12399791 120.000 118.615 02/20/200611:24 200 ugram C 19561260 200.000 185.521 02/20/2006 11:34 300 ugram C 31645466 300.000 298.418 02/20/200611:43 400 ugram C 43510584 400.000 409,268 02/20/2006 11:54 STL Chicago 53 Multiple Analysis Report Print Date/Time: 2006/03/01 15:49:09 Sample ID Result Std, Dev. RSD Mode ALT ICV ICB-MB 100.3711 -0.3954 TC TC LCS 129.3425 TC LCS......................... ........103.2669.............. ,,,TC .. 244549-13 318.8698 TC 244549-13 223.6155 TC 244549-14.............. ............ 86.8136... ........... TC . 244549-14 244549-14m$ 95.7852 187.5849 TC TC 244549-14msd....... .................2119691... ........... TC 244549-15 319.4173 TC 244549-15 265.4209 TC 244549-16.............. .............144.1121... ........... T C 244549-16 198.3555 TC 244549-17 111.3412 TC 244549-17.............. ............ 80.1979... ........... TC 244549-18 40.8796 TC 244549-18 49.2676 TC 244549-19.............. ............ 105.9869... ........... TC 244549-19 56.2431 TC 244549-20 56,2220 TC 244549-20.............. ............. 52.6516... ........... TC 244550-1 0,3544 TC 244550-1 138.6636 TC 244550-1................ ............ 123.9111... ........... TC 244550-2 73.1625 TC 244550-2 83,7895 TC c c v ........................ ......... 105.9729.............. ...TC .. COB -0,4567 TC 244550-3 45,6737 TC 244550-3................ ............ 44.3720... ...........TC . 244550-4 66.6623 TC 244550-4 75.2065 TC 244550-5................ ............ 29.6111... ...........TC . 244550-5 40.5055 TC 244550-6 24.4251 TC 244550-6............... ............ 34.4746... ........... TC , 244550-7 29.1538 TC 244550-7 36.0278 TC 244550-8............... ............ 130,5918... ........... TC 244550-8 151.7080 TC 244550-9 74.7425 TC 244550-9............... ............ 67.5611,. ........... TC 244550-10 819673 TC 244550-10 47.0289 TC 244550-10............. ............. 52.5154.,. ........... TC 244550-10 39.5266 TC 244550-11 23.6355 TC 244550-11............. ............. 32.3784... ........... TC CCV CCB 105.5431 -0.4357 TC TC STL Chicago 54 Detailed Analysis Report Print Date/Time: 2006/03/01 15:49:18 Sample ID: ICV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 03010810 Timestamp: 03/01/2006 08:16 Sample Type: Cal, Verification ! y Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 100.3711 100.3711 10446953 4.394 5.391 304 Sample ID: ICB-MB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 03010817 Timestamp: 03/01/2006/08:19 Sample Type: Sample ( ) , Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.3954 -0.3954 -16560 4.739 4.542 120 Last Message: No Sample Detected Sample ID: LCS Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 03010821 Timestamp: 03/01 /2OO0 08:27 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Baseline Baseline Time 1 129.3425 129.3425 13870319 4.607 5.605 308 Sample ID: LCS Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 03010834 Timestamp: 03/01/2006 08:40 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 103.2669 103.2669 11079244 4.542 5.540 292 Sample ID: 244549-13 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC :ilename: 03010846 Timestamp: 03/01/2 ample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline BaselinV Time STL Chicago Sample ID: 24454^-20 Method: boat Cal. Curve; SOILCURVE Operator ID: CAROL Mode: TC Filename: 03011113 Timestamp: 03/01/2006 11:10 Sample Type: Sample R e p # ppm C ugC Raw Data Beginning Ending Integration B a rlin e Baseline Time 1 56.2220 56,2220 6043653 5.012 6,012 272 Sample ID: 244549-20 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL lode: TC Filename: 03011120 Tihqestamp: 03/01/2006 11:25 SamplfeJype: Sample R e p # p p m C u g C Raw Data Beginning\Ending Integration Baseline Baseline Tii 1 52.6516 52.6516 5661480 4.987 5.986 260 Sample ID: 244550-1 Method: boat\ v L/ Cal. Curve: SOILCURVE *} Operator ID: CAROL if Mode: TC Filename: 03011126 Timestamp: 03/01/2006 11:28 Sample Type: Sample Rep # ppm C uX C Raw Data Beginning Ending Integration \ Baseline Baseline Time 1 0.3544 0 .3 5 4 4 \ 63695 4.983 5.983 37 Sample ID: 244550-1 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 03011134 Timestamp: 03/01/200 11:39 Sample Type: Sample V R e p # p p m C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 138.6636 138.6636 14868029 5.193 6.190 292 Sample ID: 244550-1 Method; boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 03011140 Timestamp: 03/01/2006 11:46 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 123.9111 123.9111 13288957 5.193 6.193 289 STL Chicago 56 Sample ID: 244550-2 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 03011146 Timestamp: 03/01/201 Sample Type: Sample R e p # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 73.1625 73.1625 7856928 5.273 6,273 269 Sample ID: 244550-2 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 03011155 Timestamp: 03/01/2006 12:01 Sample Type: Sample R e p # p p m C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 83.7895 83.7895 8994417 4.937 5.933 280 Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 03011202 Z' Timestamp: 03/01/2006 12:08 Sample Type: Cal. Verification / Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 105.9729 105.9729 11046556 5.088 6.087 312 Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 03011209 Timestamp: 03/01/20' Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.4567 -0.4567 -23119 5.394 5.101 120 Last Message: No Sample Detected Sample ID: 244550-3 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC _______ Filename: 03011212 Timestamp: 03/01/20(fe 12:18 Sample Type: Sample V R e p # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 45.6737 45.6737 4914583 5.025 6.020 254 STL Chicago 57 Sample ID: 244550-3 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 03011219 Timestamp: 03/01/2006 12:24 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 44.3720 44.3720 4775251 5.047 6.044 256 Sample ID: 244550-4 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode. TC ^ Filename: 03011225 / Timestamp: 03/01/200642:30 Sample Type: Sample l. } R e p # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 66.6623 66.6623 7161161 5.109 6.108 266 Sample ID: 244550-4 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 03011231 Timestamp: 03/01/2006 12:36 Sample Type: Sample R e p # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 75.2065 75.2065 8075713 5.214 6.212 272 Sample ID: 244550-6 Mode: TC Method; boat Cal. Curve: SOILCURVE Operator ID: CAROL Filename: 03011323 Timestamp: 03/01/2006 13'27 Sample Type: Sample ( ( ' R e p # ppm C ug C Raw Data Beginning Ending Integration__ Baseline Baseline Time 1 29.6111 29.6111 3195271 5.271 6.264 222 Sample ID: 244550-5 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 03011328 Timestamp: 03/01/2006 13:33 Sample Type; Sample R e p # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 40.5055 40.5055 4361394 5.014 6.012 253 STL Chicago 58 Sample ID: 244550-6 Method: boat Cal. Curve: SOIL-CURVE Operator ID: CAROL Mode: TC Filename: 03011334 \ '\ Timestamp: 03/01/2QCI613:39 / Sample Type: Sample V ___ R ep # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 24.4251 24.4251 2640177 5.080 6.074 235 Sample ID: 244550-6 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 03011340 Timestamp: 03/01/2006 13:44 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 34.4746 34.4746 3715856 5.273 6.272 239 Sample ID: 244550-7 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 03011346 Timestamp: 03/01/2006 13:51 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 29.1538 29.1538 3146326 5.024 6.020 247 Sample ID: 244550-7 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 03011351 Timestamp: 03/01/2006 13:56 Sample Type: Sample R e p # p p m C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 36.0278 36.0278 3882103 5.231 6.229 247 Sample ID: 244550-8 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 03011400 Timestamp: 03/01/; Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Baseline Baseline Time 1 130.5918 130.5918 14004037 5.005 6.003 STL Chicago 59 Sample ID: 244550-8 Method: boat Cal. Curve: SOiLCURVE Operator ID: CAROL Mode: TC Filename: 03011425 Timestamp: 03/01/2006 14:31 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 151.7080 151.7080 16264278 4.898 5.895 304 Sample ID: 244550-9 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 03011432 Timestamp: 03/01/21 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 74.7425 74.7425 8026043 5.195 6.190 277 Sample ID: 244550-9 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 03011439 Timestamp: 03/01/2006 14:44 Sample Type: Sample R e p # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 87.5611 87.5611 9398125 5.180 6.179 286 |V Sample ID: 24455^!K U A ^ /fl Method: boat a) * Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 03011447 Timestamp: 03/01/2006 14:52 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending integration Baseline Baseline Time 1 81.9673 81.9673 8799371 5.094 6.093 287 Sample ID: 2 4 4 5 5 0 -^ 9 ^ j f ( f i Method: boat ^ Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 03011459 Timestamp: 03/01/2006 15:04 Sample Type: Sample R e p # ppm C u g C Raw Data Baseline 1 47.0289 47.0289 5059638 Beginning Ending Integration Baseline Time 5.091 6.089 258 S l'L Chicago Sample ID: 244550-10 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 03011506 Timestamp: 03/01/201 Sample Type: Sample R ep# ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 52.5154 52.5154 5646902 5.118 6.118 262 Sample ID: 244550-10 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 03011511 Timestamp: 03/01/2006 15:16 Sample Type: Sample R ep # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 39.5266 39.5266 4256607 5.414 6.409 252 Sample ID: 244550-11 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 03011516 "\ Timestamp: 03/01/2006 15:21 / Sample Type: Sample V / R ep # ppm C u g C Raw Data Beginning Ending Integration Baseline Baseline Time 1 23.6355 23.6355 2555661 5.348 6.347 232 Sample ID: 244550-11 Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC Filename: 03011524 Timestamp: 03/01/2006 15:29 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 32.3784 32.3784 3491478 5.083 6.081 267 Sample ID: CCV Method: boat Cal. Curve: SOILCURVE Operator ID: CAROL Mode: TC ^ Filename: 03011531 y Timestamp: 03/01/2006 15:36 Sample Type: Cal. Verificavon Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 105.5431 105.5431 11000544 5.141 6.139 301 STI. Chicago til Sample ID: CCB Method: boat Gal. Curve: SOILCURVE operator ID: CAROL Mode: TG Filename: 03011537 ^ Timestamp: 03/01/2006 15:39 Sample Type: Sample Rep # ppm C ug C Raw Data Beginning Ending Integration Baseline Baseline Time 1 -0.4357 -0.4357 -20872 5.471 5.232 120 Last Message: No Sample Detected STL Chicago 62 STL Chicago TOC in Soils 3(V Page Nq.:_ Book No,: rn > Method: Lloyd Kahn Instrument: Phoenix. 8000 (TQC4) LabNet Batch: Calculations: Date of Standard Curve: P2 f ^ / O TOC (mg/kg) = ug C / grams sample Book # ^39 T P~" Page # y $ MS, MSD Known Cone, (mg/kg) = 100 ug C / grams sample MS, MSD Observed (mg/kg) = ug C / grams sample MS, MSD Rec. = fobserved mo/kq ^ ava. sample result (mg/kg)] x 100 known concentration in mg/kg Standard Traceability: (Note: Working Standards are prepared daily from the noted Stock Solutions.) Stock I (Curve) C O & A 'C r T T L . / f r Stock II (ICV/CCV) C n C S S T T C T - " ft LCS Source ID 13? 0 f t K 3 True Value V? Y O Acceptance Range 5~1 - / i / f % Sample ID: Sample Weight (g) ug C Comments: 'c a s A) . o f P b A 'W fi . / A /. 7 7 / / - 6.3f< r/ uec L-C S' o .o sor 9 . 0 6Z /c.lccyc ~ cPTSTTq ; - / \ O . 5 2 . 7 6 -- -m f -ip ! LP l^ 7 Z Z ,0 >.0 ( <o f i /;'. O ! Y ? a , o i ? "o 3 6 <p/J A \ V 3 . : 7c 7 f r z / f 7 , i f A 7 3x7 6fL3` ` .oo\ T iT f6 1 7" /X32-C Y -A H ' /Y " . OZ H H n o / / y o 6a i C - IG 31 ~ l7 o. o i r z 'O IH f O'Olie . < o o ice ~(F o > o t i ? - / A 0 <o ! % 7 o &( 7 s / -<1.0 Z A * / A 6 / - 7 > O O fQ ( A /A V/ 7 ? 3A <r/V?-0 ? 3f, 3t p t / / / , 7V /? - *W,/9l? l( 0 . S-7% V ? 2A 7 6 /0 5 3 m TG, 2/ 1/ 66. ~ , (SI %% I ^: S Date: p /4 s: { <:6c Date: t%/ i f C Date: ?j)/Jh CHU22-12JWfi/R STL Chicago Page No. ;5 TOC in Soils Book N o "~J? ? Y P Method: Lloyd Kahn Instrument: Phoenix 8QQ0 (TOC4) LabNet Batch;_______________ Calculations: Date of Standard Curve:________, TOC (mg/kg) = ug C / grams sample Book # _________ Page #___________ MS. MSD Known Cone, (mg/kg) = 100 ug C / grams sample MS, MSD Observed (mg/kg) = ug C / grams sample MS, MSD Ree, = [observed mo/ka - avo, sample result fmo/kai x 100 known concentration in mg/kg Standard Traceability: (Note: Working Standards are prepared daily from the noted Stock Solutions.) Stock I (Curve)___________ Stock II (ICV/CCV) i r i ) STL.jpiicago LCS Source ID ^ r 7LCS True Value Acceptance Range Sample ID: Sample Weight (g) ug C 6 6 6 6^0- t - 7/6 -r^rrV-- , o / o' 73?; <i }6 I "/ "i 0-0 103 nr*. 9 >/ / O . fOK~ -7 3 / P 66 - 2 _ 0 10 6, 7 7 C C' ( / , o r ' /O t 772-6 no fb O . ! 6 L . y . ^ 7 6 / 7 < 6 ^^ 67 o o t o 6 6 / 7 3 7 ____ \ . o . O O' ?~l \ r r o - y y 7 7 2c7 \ - h o O /<r6 7c; 2 d 6 T - r ' a to -v 36,01/6 'r ______ --0 r>- .o m ~ 0,06/ --1 0 - O) -z_2- - 7 O 2. ^ . 3 y<?TH r n ./z rT / 3.76667/6 9 3 , /C?J> __ _____l - 7 3 ^ / 36. - 7 o . O /<? P- no. sy<j> , ~ -6rL 7. 7 7 16/, 7tO ov/yzs- 7.a ?7 i'Z // J / - V ` r v o <7 / X J 7 /C O Comments: / Prep Analyst: sI'l i : 7 ? ------------ x Ivi ft--l-&--c--Z---* y-----------------7 ^ ^ ---- ---P---//? / ---6--- Analyst: _________________ Date: ^ / / / 6 C Reviewed by:. 0 _ Date: s / f / t <v4 STL Chicago Page No.:_ G6 TGC in Soils Book No.: Method: Lloyd Kahn instrument: Phoenix 800D (TOC4) LabNet Batch:______________ _ Calculations: Date of Standard Curve;____________ _J TOC (mg/kg) = ug C / grams sample Book # _________ Page #,___________,, MS, MSD Known Cone, (mg/kg) = 100 ug C / grams sample MS, MSD Observed (mg/kg) = ug C / grams sample MS, MSD Rec, = fobserved mo/ko - avo. sample result (mg/kg)! x100 known concentration in mg/kg Standard Traceability: (Note: Working Standards are prepared daily from the noted Stock Solutions.) Stock I (Curve) Stock II (ICV/CCV) LCS Source ID ________ y ? LCS True Value____________Acceptance Range 4SampleID: ^ SampleWeight(g) ugC -iV1lrr.Mo- ^ V'0"-V9.0/0C37y Hi.at?? TX.3L Y _ r n- G ixv ^ 9 S 2 C T -ii 0 02J 23 63*r: Z - h '0,03 r7 3 2 4C C n.o 01 yy o. ( Q rO, ir?_ Comments: \XZ Prep Analyst:, Analyst: ( S STLcfiSpwed by:T \ \ \ . -\ \ \X. \ zz,\X Date: c Gate: , ? A / fa Date: s J lT M ' PUI `l A AKam **# RUN LOG <V2 ) 5/9/06 12:16 T o ta l o rg an ic Carbon t S o iL s ) Method Code..: TOCS Batch Code,,,; 175263 S t a t u s ....... : RAW Batch Date...: 03/09/06 Batch Time...: 1007 User Name.............. : rnm QC Code___ TOCS Calc Code......: TOCS Location C o d e ..: 57222 Equipment Code.: TOC4 Import C o d e --- : TEST CODE TT TTTTTTT TTTT 0OOOOOOCC C 11I c cC CCcCsssCCC 234AAA 2A SsS VVV V 2A 23 4 2 2 SAMPLE: Grp Po sampLa ID Di Lution TEST POS Date / Ti me 12 3 4 56 7 1 1 1 22 2 7a 9 0 12 11 ICAL IQ6ASTTC1A 0 12 13 14 ___ ICV _ I Q 6 B S T T C 2 _ ___ ICB__ ___ L C S _ I 0 D F S T L K 3 _ 3 3/7/06 1 0849 0 3/7/06 1 0B52 0 3/7/06 i oasa 0 0 0 15 16 17 1a 19 1 10 24455QJ3_S_ 244550J 4 _ S ___ 2 4 4 5 5 0 _ 1 5 _ S ___ 24455QJ 6 _ S _ 244550^17^5.___ 2 4 4 5 5 Q _ 1 S _ S ____ 3/7/06 1 0911 3/7/06 1 0925 3/7/06 1 0943 3/7/06 1 1001 3/7/06 1 1038 3/7/06 1 1132 0 0 0 0 0 0 1 11 1 12 1 13 1 14 1 15 1 16 1 17 1 18 1 19 1 20 1 21 1 22 1 23 1 24 1 25 2 4 4 5 5 Q _ 1 9 _ 5 ___ 2 4 4 5 5 0 _ 2 0 _ S ___ Z44550__21_S.___ 2 4 4 5 5 0 _ 2 2 _ S ___ ___ C C V _ I 0 6 B S T T C Z _ .___ CCB__ 244550J 3 _ S ___ 244550^23^S_MS_106BSTTC2_18 244550_Z3_S_MSD_106BSTTC2JB 2 4 4 5 5 0 _ 2 4 _ S ___ 2 4 4 5 5 0 ^ 2 5 ^ 3 ___ 2 4 4 5 5 0 _ 2 6 _ S ___ 2 4 4 5 5 0 _ 2 7 _ S ___ ___ C C V _ I 0 6 B S T T C 2 _ ___ CCB__ 3/7/06 1 1149 3/7/06 1 1205 3/7/06 1 1219 3/7/06 1 1245 3/7/06 1 1259 0 3/7/06 1 1302 0 3/7/06 1 1310 3/7/06 1 1329 3/7/06 1 1353 3/7/06 1 1346 3/7/06 1 1417 3/7/06 1 1430 3/7/06 1 1444 3/7/06 1 1457 0 3/7/06 1 1500 0 0 0 0 0 0 N * 0 0 0 0 Patip 1 66 *** QC Summary *** (V2 ] Total Organic Carbon (Soils) Method Code.. Batch Cod e . .. S t a t u s ....... rocs 175263 RAW Batch Date...: 03/09/06 Batch Time...: 1007 User Name.... : rnm QC Code........ Calc Code..,,,, Location Code., TOCS TOCS 57222 Grp Sinp Sample ID 1 lev I06BSTTC2 Pos Test Result TOC 2034.92 Known 2000 O riginal ICB TOC -4.61 LCS IOOF5TLK3 3 TOC 4866.02 4780 -4.61 TC2 2975,28 4780 TQCAV2 3920.65 4780 1 15 CCV 106BSTTC2 TOC 1903.97 2000 1 16 CCB TOC -3,19 1 18 244550 23 S MS J06BSTTC2 18 T0CAV2 8007.34 2000 8007.34 1 19 244550 23 S MSD I06BSTTC2 18 T0CAV2 8950.58 2000 8007.34 1 24 CCV 106BSTTC2 TOC 1930.38 2000 1 25 CCB TOC 2.53 Report Date: 3/9/06 12:16 Equipment Code.: TQC4 Import Code___ : A lt e r n a t e QC Res 102 F QC Res F 102 62 82 95 8950.58 142 103 97 32 STL Chicago Page 1 67 Ifi*# RAU TEST DATA +** <V2 ) Total Organic Carbon (Soils) Method C o d e . .: TOCS Batch Code. . : 175263 S t a t u s .... RAU Batch D a te...: 03/09/06 Batch Time...: 1007 User Na m e ___ : rnm SAMPLE: Grp Poe Sample 10 11 [CAL I06ASTTC1A 12 ICV I06BSTTC2 13 ICB 14 LCS I0OFSTLK3 3 1 5 246550 13 S 16 244550 14 S 1 7 244550 15 S 15 244550 16 S 19 244550 17 S 1 10 244550 16 S 1 11 244550 19 S 1 12 244550 20 S 1 13 244550 21 S 1 14 244550 22 S 1 15 CCV I06BSTTC2 1 16 CCB 1 17 244550 23 S 1 IS 244550 23 S MS ID6BSTTC2 18 1 19 244550 23 S M5D JQ6BSTTC2 18 1 20 244550 24 S 1 21 244550 25 S 1 22 244550 26 S 1 23 244550 27 S 1 24 CCV I06BSTTC2 1 25 ___ CCB QC Code... ___ : Tocs Cale Code. ___ : Tocs Location Code..: 57222 Dilution TOC mg/Kg TOD2 mg/Kg Report Date: 3/9/06 12:16 Equipment Code.: TOC4 Import Co d e ___ : T0C3 mg/Kg T0C4 mg/Kg TOCAV2 mg/Kg 2034.92 -4.61 486.G2 7553.64 4452.55 10803.44 8187.14 7695.64 5306.12 3273.47 4584.27 9768.60 2790.67 1903.97 -3.19 4783.78 8007.34 8950.58 11227.54 5111.25 10312.73 10D72.42 1930.38 -2.53 2975.28 7664.42 4091.49 4075.79 8652.68 7017.96 4914.94 2906.44 5666.24 14739.40 2656.B4 5160.51 15687.58 4752.96 8910.63 6386.48 3920.65 769.03 4272.02 7439,61 8419.91 7356.80 5110.53 3089.95 5125.26 12254.00 2723.76 4972.15 8007.34 8950.58 13457.56 4932.10 9611.68 8229,45 STL Chicago Page 1 68 k-kic RAW TEST DATA k'k'k <V2 ) Total Organic Carbon (Soils) Method Code..: TOCS Batch C o d e ,..: 175263 Status,....... : RAW Batch Date...: 03/09/06 Batch T im e ...: 1007 User Name :rnm S A M E LE: Grp P05 Sample ID 11 ICAL I06ASTTC1A 12 ICV 06BSTTC2 13 ICB 14 LCS I00FSTLK3 3 15 244550 13 S 1 6 244550 14 5 1 7 244550 15 S 1 B 244550 16 S 19 244550 17 S 1 10 244550 18 5 1 11 244550 19 S 1 12 244550 20 S 1 13 244550 21 S 1 14 244550 22 S 1 15 CCV IQBSTTC2 1 16 CCB 1 17 244550 23 S _ 1 18 244550 23 S MS 106BSTTC2 18 1 19 244550 23 S MSD IQ6BSTTC2 18 1 20 244550 24 S 1 21 244550 25 S 1 22 244550 26 S 1 23 244550 27 S 1 24 CCV I06BSTTC2 1 25 CCB Report Date: 3/9/06 12:16 QC C o d e ......... : TOCS C a lc Code...............: TOCS Location Code..: 57222 Equipment Code.: TOC4 Import Code______: Dilution OCAV3 mg/Kg T0CAV4 mg/Kg TCRl ug TOCR2 ug T0CR3 ug 101.7459 -0.7377 162.5252 164.6693 93.0583 281.9698 180.935B 67.7216 181.4694 66.7787 115.0653 173.8811 56.0925 95.19B4 -0.5099 254.4972 375.5441 232.7152 376.1225 158.4489 360.9456 338.4332 96.5192 -0.4054 96.9942 145.6240 95.7408 79.8855 64.8951 78.6011 143.5162 86.0306 119.5577 253,5177 97.5059 301.3738 323.1641 137.S359 290.4867 194.7875 STL Chicago Page 2 69 *#* RAW TEST DATA <V2 ) Total Organic carbon (Soils) Method Code..: TOCS Batch code...: 175263 Status....... : RAW Batch Date..,; 03/09/06 Batch Time...: 1007 User Name...,: rhm SAMPLE: Grp Pos Sample ID 11 ICAL I06ASTTC1A 12 ICV I6BSTTC2 13 ICE 14 LCS I0F5TLK3 3 15 244550 13 S 16 244550 14 S 17 244550 15 S 1a 244550 16 S 19 244550 17 S 1 10 244550 10 S 1 11 244550 19 S 1 12 244550 20 S 1 13 244550 21 S 1 14 244550 22 S 1 15 CCV I6BSTTC2 1 16 CCB 1 17 244550 23 S 1 IS 244550 23 S MS I06BSTTC2 IB 1 19 244550 23 S MSD I06BSTTC2 18 1 20 244550 24 S 1 21 244550 25 S 1 22 244550 26 S 1 23 244550 27 S 1 24 CCV I6BSTTC2 1 25 ___ CCB QC Code ......... : TOCS Calc Code...... : Toes Location Code..: 57222 Dilution TOCR4 ug Uri g Report Date: 3/9/06 12:16 Equipment Code.: T0C4 Import Code,,.,: WT2 WT3 WT4 g9 g 0.05 0.16 0.0334 0.0218 0.0209 0.0261 0.0221 0.0088 0.0342 0.0204 0.0251 0.0178 0.0201 0.05 0.16 0.0532 0.0469 0.0260 0.0335 0.0310 0.0350 0.0336 0.05 0.16 0.0326 0,0190 0.0234 0.0196 0.0075 0.0112 0.0292 0.0296 0.0211 0.0172 0.0367 0.0584 0.0206 0.0290 0.0326 0.0305 STL Chicago Page 3 70 *** RAW TEST DATA *** Total Organic carbon (Soils) Method Code Batch code. Status... TOCS 175263 RAW Batch Date.. : 03/09/06 Batch Time.. : 1007 User N a m e . .. : m m SAMPLE: Grp Pos Sample It) 11 ICAL I06ASTTC1A 12 13 ICV ID68STTC2 ]CB 1A LCS 10DFSTLK3 3 1 5 2AA55Q 13 S 1 6 244550 1A S 1 7 2AA55D 15 S 1 8 2AA550 16 S 1 9 2AA550 17 S 1 10 24A550 18 S 1 11 24A55D 19 S 1 12 244550 20 S 1 13 2AA550 21 S 1 1A 2AA550 22 S 1 15 CCV I6BSTTC2 1 16 CCS 1 17 244550 23 S 1 IS 244550 23 S MS I0BSTTC2 18 1 19 244550 23 S MSD I06BSTTC2 IB 1 20 244550 24 S 1 21 244550 25 S 1 22 244550 26 S 1 23 244550 27 S 1 2A CCV I06BSTTC2 1 25 ___ CCB__ QC Co d e ........ : TOCS Calc Code. TOCS Location code..: 57222 Dilution DLFAC N/A TES mg/Kg 3.2000 1.0000 4.8A85 7,8431 7.2235 7.0022 10.8108 16.0000 5.0473 6.4000 6.9264 9.1429 5.633 3,2000 1.0000 2.8674 3.4115 6.1538 5.9150 5.3333 4.7337 4.9922 3.2000 1.0000 (V2 > Report Date: 3/9/06 12:16 Equipment Code.: TOCA Import Code___ : TCS2 ing/tig TCSAV2 mg/Kfl TICS mg/Kg S TL Chicago Page A 71 Cali br at io n Report Print Date/Time; 200(5/03/07 15:11:47 "ai. Curve ID: Created: Calibration Factor Y Intercept {b ): r-squared: <m) SOILCURVE 02/20/2006 1.0706 +05 -296565 0.99773 12:00 Standard ID 0 ugram C lugramC 20 ugram C 40 ugram C 30 ugram C 120 ugram C 200 ugram C 300 ugram C 400 ugram c Raw Data -2373 1395589 2153844 4050968 7850154 12399791 19561260 31645466 43510504 x Expected ug C 0.000 10,000 20,000 40.000 80,000 120.000 200.000 300.000 400.000 Measured ug C 2.740 15.809 22.893 40.617 7 6 . Ill 118.615 185,521 298.410 409-268 Message Nq Sample Dot Date & Time 02/20/2006 02/20/2006 02/20/2006 02/20/2006 02/20/2006 02/20/2006 02/20/2006 02/20/2006 02/20/2006 09 :53 10:07 10:23 10 :3 8 11:14 11:24 11:34 11:43 11 :54 STL Chicago 72 Multiple Analysis Report Print Date/Time: 2006/03/07 15:15:23 Sample ID Result Std, Dev. RSD Mode ALT ICV 101.7459 ICES -0.7377 LCS 162.5252 5 C S .................................... 96.9942 ... 244550-13 164-6693 244550-13 145.6240 244550- 14 ............................. 93.0533... 244550'14 95.7408 244550-15 231.9693 244550-15 .............................. 79,8855-,, 244550-16 ' 180.9353 244550-16 507.3456 244550-16 ............................. 64,8951... 244550-17 67,7216 244550-17 78,6011 2 4 4 5 5 0 - 1 3 .............................. 18 1. 4694... 244550-18 143.5162 244550-19 66.7787 244550- 1 9 ............................. 86,0306... 244550-20 115.0653 244550-20 119,5577 244550-21 ....................... 173.3311... 244550-21 253.5177 244550-22 56,0925 244550-22 ............................. 97.5059,., CCV 95,1934 -CB -0,5099 2 4 4 5 5 0 - 2 3 ..............................2 5 4. 49 72 ,, , 244550-23 301-3738 244550-23 MS 375,5441 244550-23 M S D ........................ 463.3333.,, 244550-24 376.1225 244550-2 MSD 232,7152 2445 50 -2 4..............................323.1641,,, 244550-25 158.4439 244550 25 137.3359 2445 50 -2 6..............................360,9456... 244550-26 290.4367 244550-27 33B ,4332 2445 50 -2 7..............................194.7375... CCV 96,5192 CCB -0,4054 .. .. ,, .. .. .. .. ,. .. ,. .. ,. .. TC TC TC ..,TC TC TC . ..TC TC TC ...TC TC TC ...TC TC TC r,,TC TC TC ...TC TC TC ...TC TC TC ...TC TC TC ..,TC TC TC ...TC TC TC ,.,TC TC TC ...TC TC TC ...TC TC TC STL Chicago 73 Detailed Analysis Report Print Date/Time: 2006/03/07 15:15:26 Sample ID: ICV Method: boat Cal, Curve: SOILCURVE Operator ID: Rebecca Rep # PPm C ug C Raw Data 1 101.7459 101.7459 159419 Mode : TC Filename : 03070844 Timestamp : 03/07/200^,08:49 Sample Type: Cal, Verification Beginning Baseline 7.396 Ending Baseline 8.395 Integration Time 252 Sample ID: Method: Cal. Curve : Operator ID TCB ///| boat ' SOILCURVE Rebecca Rep # ppm C ug C Raw Data 1 -0,7377 -0,7377 -53196 East Message: No Sample Detected Mode ; Filename : Timestamp : Sample Type TC 03070849 03/07/2006^08:52 Sample Beginning Baseline 6.014 Ending Baseline 5.447 Integration Time 12 Q Sample ID: Method : Cal. Curve : Operator ID DCS boat SOILCURVE Rebecca Rep # ppm C ug C Raw Data 1 162.5252 162.5252 17422128 Mode : Filename : Timestamp : Sample Type: TC 03070853 03/07/2006 Sample -- Beginning Baseline 5.337 Ending Baseline 6.336 Integration Time 309 Sample ID: DCS Method: boat Cal, Curve : SOILCURVE Operator ID : Rebecca Rep # ppm C ug C Raw Data 1 96.9942 96.9942 10407B19 Sample ID: 244550-13 Method : boat Cal, Curve: SOILCURVE Operator ID: Rebecca Rep # ppm C ug C Raw Data 1 164.6693 164.6693 17651626 sample ID: 244550-13 Method: boat Cal, Curve: SOILCURVE Operator ID: Rebecca Rep # ppm C ug C Raw Data STL Chicago Mode : Filename : Timestamp : Sample Type TC 03070859 03/07/200i|509'1 Sample Beginning Baseline 5.751 Ending Baseline 6.750 IntegrationX Time 271 Mode : Filename : Timestamp : Sample Type TC 03070905 03/07/200 Sample B e g i n n ing Baseline 5.635 Ending Baseline 6.635 Integration Time 293 Mode: Filename: Timestamp: Sample Type: TC 03070911 03/07/2006 Sample 09:17 Beginni ng Ending Baseline Baseline Integrati on Time 74 1 145.6240 345,6240 15613052 5,627 6.624 285 Sample ID: 244550-14 Method: boat Sal, Curve; SOILCURVE Operator ID: Rebecca Rep # ppm C ug c Raw Data 1 93,0583 53.0533 9986532 Mode : TC Filename : 03070520 -7-- . Timestamp : 03/07/20(fe..09 :25 Sample Type : Sample " Beginning Baseline 5.094 Ending Baseline 6.092 Integration Time 203 Sample ID: 244550-14 Method: boat Cal. Curve: SOILCURVE Operator I D : Rebecca Rep ppm C ug C Raw Data 1 95.7408 95.74OB 10273662 Mode : Filename : Timestamp : Sample Type TC 03070926 03/07/2006 Sample 09:31 Beginning Baseline 5.370 Ending Baseline 6,369 Integration Time 275 Sample ID: 244550-15 Method; boat Cal, Curve s SOILCURVE Operator ID: Rebecca Rep # ppm C ug C Raw Data 1 281.969B 281.9698 30207226 Mode: TC Filename: 03070937 Timestamp: 03/07/2006^09:43^""^) Sample Type: Sample " Beginning Baseline 4.B70 Ending Baseline 5.876 Integration Time 351 Sample ID: 244550-15 Method: boat Ca l. Curve: SOILCURVE Operator ID : Rebecca Rep # ppm C ug C Raw Data 1 79. 8855 79,8855 8576547 Mode : TC Filename : 03070944 Timestamp -. 03/07/2006 09:49 Sample Type;; Sample Beginning Baseline 5.527 Ending Baseline 6,.522 Integration Time 266 Sample ID: 244550-16 Method: boat Cal. Curve: SOILCURVE Operator I D : Rebecca Rep # ppm C ug c Raw Data 1 180.9359 180.9358 19392760 Mode : Fileame : Timestamp: Sample Type TC 0307 0955 --- 03/07/2006^X0: 01 J Samp 1e --- ^ Beg.i nning Baseline 4.840 Ending Baseline 5.938 Integration Time 316 Samp 1e ID : 244'55D -..l6 Method: boat Cal. Curve; SOILCURVE Operator ID: Rebecca Rep # ppm C ug C Raw Data 1 507.8456 5 0 7 . 9 4 5 6 543 94500 STL Chicago Mode: TC Filename: 03071012 Timestamp: 03/07/2006 Sample Type: Sample 10:19 ^Begiitn-Lng Ending Baseline ""L'-sJa se1in e 4,696 ^ ^ . 6 94 Integration Time 339 75 Sample ID: Method: Cal. Curve: Operator ID 244550-16 boat SOILCURVE Rebecca Rep # ppm C ug C Raw Data 1 64.8951 64 .8951 6971998 Mode : Filename : Timestamp : Sample Type TC 03071022 03/07/2006 Sample 10:27 Beginning Baseline 5.108 Ending Baseline 6.105 Integration Time 260 Sample ID: 244 560 17 Method: boat Cal. Curve: SOILCURVE Operator I D : Rebecca Rep # ppm C ug C Raw Data 1 67.7216 67.7216 7274547 Mode: TC Fi l e n a m e :03 071033 Timestamp; 03/07/2006^1,0:38 Sample Type: Sample Beginning Ending Baseline Baseline 4.736 5.733 Integration Time 268 Sample ID; Method: Cal. Curve: Operator ID 244550-17 boat SOILCURVE Rebecca Rep it ppm C ug C Raw Data 1 78.6011 78.6011 8439068 Mode : TC Filename : 03071118 Timestamp : 03/07/2006 Sample Type : Sample 11:23 Beginning Baseline 4.591 Ending Baseline 5.591 Integration Time 279 Sample ID: 244550-18 Method: boat Cal, Curve: SOILCURVE Operator ID: Rebecca Rep fi ppm C ug C Raw Data 1 181.4694 181.4694 19449872 Mode: Fi 1ename : Timestamp: Sample Type: TC 03071126 03/07/2O O ^ l l :32^) Sample """ Beginning Baseline 4.766 Ending Baseline 5,763 Integration Time 330 Sample ID: 244550-18 Method: boat Cal- Curve: SOILCURVE Operator ID: Rebecca Mode : Filename : Timestamp : Sample Type: Sample TC 03071136 03/07/2006 11:42 Rep # ppm C 1 143.5162 ug C Raw Data 143.5162 15387444 Beginning Baseline 4,387 Ending Baseline 5.887 Integration T ime 298 Sample ID: 244550-19 Method: boat Ca l. Curve: SOILCURVE Operator ID: Rebecca Rep # ppm C ug C Raw Data 1 66.7787 66.7787 7173623 STl, Chicago Mode : Filename : Timestamp ; Sample Type: TC 03071143 03/07/200 Sample Beginning Baseline 4.943 Ending Baseline 5.939 Integration Time 280 76 Sample ID: Method : Cal. Curve : operator ID 244550 -IS boat SOILCURVE Rebecca Rep # ppm C ug C Raw Data 1 86,0306 86.0306 9234299 Mode: TC Filename: 03071149 Timestamp: 03/07/2006 Sample Type: Sample 11:54 Beginning Baseline 5.166 Ending Baseline 6.162 Integration Time 272 Sample ID: Method: Cal. Curve : Operator ID 244550-20 boat SOILCURVE Rebecca Rep # ppm C ug c Raw Data 1 115.0653 115.653 12342120 Mode : TC Filename : 0307115#^ Timestamp ; 03/07/0,0.6 _12 :05') Sample Type : Sample Beginning Baseline 4.810 Ending Baseline 5.809 Integration Tj me 336 Sample ID: 244550-20 Method: boat Cal, Curve: SOILCURVE Operator ID: Rebecca Rep # ppm C ug C Raw Data 1 119.5577 119,5577 12822971 Mode; Filename: Timestamp: Sample Type: TC 03071.205 03/07/2006 Sample 12:11 Beginning Baseline 5,595 Ending Baseline 6,590 Integration Time 272 Sample ID: 244550-21 Method: boat Cal. Curve: SOILCURVE Operator I D : Rebecca Rep # ppm C ug C Raw Data 1 173 . BB11 1 7 3 . 8 8 1 1 18637 64 0 Mode: TC Filename: 03071213 Timestamp: 03/07/200 Samp]e Type: Sample Beginning Baseline 4.992 Ending Baseline 5.988 Integration Time 301 Sample ID: 244550-21 Method : boat. Cal. Curve: SOILCURVE Operator ID: Rebecca Rep # ppm C ug C Raw Data 1 253.5 177 253.5177 27161768 Sample ID: Method: Cal. Curve: Operator ID 244550-22 boat SOILCURVE Rebecca Rep # ppm C ug C Raw Dat; 1 56.0925 56.0925 602979: STI, Chicago Mode : TC Filename : 03071225 Td mestamp : 03/07/2006 Sample Type :; Sample 12:31 Beginning Baseline 4.825 Ending Baseli ne 5..823 Integration Time 321 Mode : Fdleame: Timestamp: Sample Type TC 3071240 ..-- )03/07/2 Op 6\ 12 :45 Sample --- Beginning Baseline 4.743 Ending Baseline 5.738 Integration Time 263 77 Sample ID: . Method: Cal. C u r v e : Operator ID: 244550-22 boat SOILCURVE Rebecca Rep # ppm C ug C Raw Data 1 97.5059 97.5059 10452597 Mode: Filename: Timestamp: Sample Type: TC 03071247 03/07/2006 Sample 12:52 Beginning Baseline 4 .B15 Ending Baseline 5.813 Integration Time 280 Sample i d ; Method; Cal. Curve: Operator ID ccv boat SOILCURVE Rebecca Rep # ppm C ug C Raw Data 1 95.1904 95.1984 9893277 Mode : Filename : Timestamp : Sample Type TC 03071254 03/07/2 0 0 ^ 1 2 : 59 J Cal. V e r i f i'cftn B e g i n n ing Basel ine 5,192 Ending Baseline 6 .190 Integration Time 293 Sample ID: CCB Method: boat Cal. Curve: SOILCURVE Operator I D : Rebecca Rep # ppm C ug C Raw Data 1 -0.5099 -0.5099 -28817 Last Message; Mo Sample Detected Mode: Filename: Timestamp: Sample Type: TC 03071300 03/07/200 Sample Beginning Baseline 5.309 Ending Baseline 5.006 Integration Time 120 Sample ID: 244550-23 Method: boat Cal, Curve: SOILCURVE Operator ID: Rebecca Rep # ppm C ug C Raw Data 1 254,4972 254.4972 27266620 Mode : TC Filename : 03071304 Timestamp : 03/07/20 L6 13:10 Sample Type : Sample Beginning Baseline 4.076 Ending Baseline 5.873 Integration Time 326 Sample ID: 244550 23 Method : boat Cal, Curve: SOILCURVE Operator ID : Rebecca Rep # ppm C ug C Raw Data 1 301. 3738 301.3730 322B4194 Mode : TC Filename : 03071311 Timestamp : 3/07/20U6 Sample Type:: Sample 13:18 Beginning Baseline 5.304 Ending Baseline 6 :.303 Integration Time 360 Sample ID: 244550-23 MS Method: boat Cai, Curve; SOILCURVE Operator ID: Rebecca Rep # ppm C ug C Raw Data 1 375.5441 375,5441 40223224 STL Chicago Mde : Filename : Timestamp : Sample Type TC 03071322 03/07/2006 Sample Beginning Baseline 5.105 Ending Baseline 6.101 Integration Time 363 78 Sample ID: 244550-23 MSD Me'Chod:__ boat Cal. Curvr---SOILCURVE Operator ID : Rebecca" ....... 0 < J t r r Q n ... f o . f , i ' " Rep # ppm C ug C Raw Dat 1 463,3 803 463.3 883 4 9625880 Mode : TC Filename: 03071331 Timestamp: 03/7/20Q6 Sample Type: Sample 13:37 'Beginning Ending Baseline" ...Baseline 5.652 '"'6'.64 8 .. integration Ti me 350 Sample ID: 244550-24 Method: boat Cal. Curve: SOILCURVE Operator ID: Rebecca Rep # ppm C ug C Raw Data 1 376.1225 376.122 5 40285132 Mode: Filename: Timestamp: Sample Type: TC 03071340 03/07/200 1 3 : 4 6 Sample ) Beginning Baseline 5,437 Ending Baseline 6,434 Integration Time 329 Sample ID : 244550-2 MSD Method : boat Cal. Curve : SOILCURVE Operator ID : Rebecca Rep # ppm C ug C Raw Data 1 232.7152 232,7152 24935120 Mode : TC Filename : 03071347 ^ .-- Timestamp : 03/07/200Cf 13 :53_) Sample Type : Sample .. Beginning Baseline 5,807 Ending Baseline 6,804 Integration Time 326 Sample ID: Method: Cal, Curve : Operator ID: 244550-24 Mode : boat SOILCURVE Rebecca TC Rep # ppm C ug C Raw Data 1 323.1641 323.1641 34616576 Filename : 30714QQ Timestamp: 03/07/2006 1 4 :06 Sample Type: Sample Beginning Baseline 5.166 Ending Baseline 6.165 Integration Time 327 Samp]e ID: 244550*25 Method: boat Cal. Curve: SOILCURVE Operator ID: Rebecca Rep # ppm C ug C Raw Data 1 150.4489 158,4489 169B5904 Mode : Filename : Timestamp : Sample Type TC 03071412 03/07/2(M 14:17 Sample Beginning Baseline 5.002 Ending Baseline 6-001 Integration Time 296 Sample ID: 244550-25 Method: boat Cal, Curve: SOILCURVE Operator ID; Rebecca Rep # ppm C ug C Raw Data 1 137.8359 137,8359 14779434 STL Chicago Mode: TC Filename: 03071418 Timestamp: 03/07/2006 Sample Type: Sample 14:23 Beginning Baseline 5,278 Ending Baseline 6,277 Integration Time 283 79 Samp!l e ID : 244550-26 Method: boat Cal. Curve E SOILCURVE Operator I D : Rebecca Rep # ppm C ug C Raw Data 1 360.9456 360.9456 38660632 Mode: TC ___ Filename: 03071424 Timestamp: 03/07/2004-44 :30 J Sample Type: Sample Beginning Baseline 5.420 Ending Baseline 6.419 Integration Time 337 Sample ID: 244550-26 Method: boat Cal, Curve: SOILCURVE Operator I D : Rebecca Rep # ppm C iig C Raw Data 1 290.4867 2 90.4867 311188 52 Mode : F.i 1ename : Timestamp : Sample Type: TC 03071431 03/07/2006 Sample 14:37 Beginning Baseline 5,464 Ending Baseline 6.464 integration Time 318 Sample ID: 244550-27 Method : boat Cal. Curve: SOILCURVE Operator ID : Rebecca Rep # ppm C ug C Raw Data 1 3 3 B .4332 338.4332 36250952 Mode : TC Filename: 03071438 T i m e s t a m p : 03/07/2Q0?JL4 :44 J Sample Type : Samp]e Beginning Baseline 5,692 Ending Baseline 6..691 Integration Time 321 Sample ID: 244550-27 Method: boat Cal. Curve: SOILCURVE Operator ID : Rebecca Rep # ppm C ug C Raw Data 1 194.7875 194.7875 20875414 Mode : Filename : Timestamp : Sample Type TC 03071444 03/07/2006 Sample 14:50 Beginning Baseline 5,960 Ending Baseline 6.957 Integration Time 307 Sample ID: Method : Cal. Curve : Operator ID: CCV boat SOILCURVE Rebecca Fiep # ppm c ug C Raw Data 1 96.5192 96,5192 10034647 Mode : TC Filename : 03071452 Timestamp ; 03/07/200)l(SJl4 :57 Sample Type : C a l . Verd Beginning Baseline 6.638 Ending Baseline 7.686 Integration Time 259 Sample ID: Method: Cal. Curve: Operator ID CCB boat SOILCURVE Rebecca Rep # ppm C ug C Raw Data 1 -0.4054 -0.4054 -17633 STL Chicago Mode : Filename : Timestamp : Sample Type: TC ___ 03071458 0 3 / 0 7 / 2 0 0 5 ^ 5 :00 Sample ) Beginning Basel:ne 5.186 Ending Baseline 5,094 Integration Time 120 80 STL Chicago Page No.: .. .. 67 TOC in Soils Book No Method: Lloyd Kahn Instrument: Phoenix 30Q fTOC4) LabNet Batch: I a3 Calculations: Date of Standard Curve: TOC (mg/kg) = ug C / grams sample Book # _________ Page #___________ MS, MSD Known Cone, (mg/kg) = 100 ug C / grams sample MS, MSD Observed (mg/kg) = ug C / grams sample MS, MSD Rec, = (observed ma/kq - avq. sample result (mq/kqYl x 100 known concentration in mg/kg Standard Traceability: (Note: Working Standards are prepared daily from the noted Stock Solutions.) Stock I (Curve) f T C \ f t Stock 11(ICV/CCV) S- b T T Q l^ LCS Source IPIT 0 Q f '5 f l { L e s True Value H ' l i V Acceptance Range '5 3 ^ _______ Sample ID: Sample Weight (g) ug C X C n/ 0.0*5 JO L7*fO O -K - 0 3 3 4 LCS 0 .0 3 5 4 1CoQ. 5 2 *5 2 LCD 3 4 4 ty 5 9 0 -i3 w s 13 -14 ~14 ~ 15 0 * O 3 ^ L/> 0 , 0^ 1p , O .O IQ O O. 0 9 O q 0 ,0 3 3 4 - 2 ( | /(W , I4 -5 .S Z M O 45.o rm 0 5 .1 4 C R a e j.n u p fi 1 - 15 O -O IQ U I -Iti? -------- 1------- -/(J 0 * 0 tQS 1 le o .q /s B R 0> O + H - U -- - 1 -- / L? _______ 1 - n _ .r . O. 0 0 1 5 0. 0 0 8 8 0 - 0 1 1L 07 ris iiti 78- 4 0 (1 -Ift -/ . ~ /4 -S > i _0 , 0 3 4 4 . . O i3Q Q _o, 0 a o 4 0, 0 3^ 0 .0 6 )5 / I S 1,4 i_ fC i4 1 4 3 .5 /0 1 loO. n i s i &ln.CS>CXD . 1/ 5 . 0 t 3 SO * SI O.QI . (0.01 7 R J jO S dO X I nl.m Comments: * 0 , L r n i r rMi i g Prep Analyst* ) 'j/^ K U X t V Analyst: 0h j f f F/Cf\?fV\yvO ' Reviewed bv: ^ C / j O --- Date: O f ) v / ( s Date: sjl/CKO Date: /4 *** STL Chicago Page No,;________ GS TOC in Soils Method: Lloyd Kahn Calculations; Book No.: Instrument; Phoenix 8000 (TOC4) LabNet Batchy n y z j p s Date of Standard O / - '.X. ) O J 7 TOC (mg/kg) = ug C / grams sample Book # _________ Page #______ MS, MSD Known Cone, (mg/kg) = 100 ug C / grams sample MS, MSD Observed (mg/kg) * ug C / grams sample MS, MSD Rec. = [observed mo/kg - avo. sample result fmq/kq)1 x100 known concentration in mg/kg Standard Traceability: (Note: Working Standards are prepared daily from the noted Stock Solutions.) -- 1~ i Stock I (Curve) Stockai (ICV/CCV) -S ^ lA LCS Source ID ____________ LCS True Value ^"""flafcPtaftce-Bange, Sample ID: Sample W eight (g) ug c Comments: 3 ^ 1 5 ^ -3 1 o. oi l 'c f a 1 -3 B . 0 .0 3 0 1 .^ '< 3 3 0, 03p 1 <0^ **|/1(3P C aJ riJO_ J), 05' , l_ : O'iif ... t). 0 3 2 -- , li( -n. r p ^ < 7 _ 'fLti.ffy.. $ 0 -O 40*1 ----rj{ AHg L 0 - CLitiZ--------- 1 0. OB^y- 3>l O W Wf:>W/A- ^ ZI.MH / ^ 7 .3 o m i r e - ( o v&L(facMrU\i\it. 37 '/>;r -23M-, ) 0 - 0 } U D 7 ' / 0. 9?vi, -a s -2-S ....0 - 0 3 / 0 0 ' w . t.c r t'id.tf s ' i$ \ ^ - L --- 3 . / q ( i 5>?,h - l,( 0 - o J u & ^0-^Q.y 1 -Z 7 & 1 l i Q - o ^ $ S' r c \J (X - 0 0 ifa 7 ? / * ; , - - `T O"1if/ Prep Analyst; Analyst: S T L C t i ^ e W e d fay ; C H t.7 7 .1 5 JtO K iH .fte/n i