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AR226-3169 TRADE SECRET Study Tide H-24615: Static, Acute, 96-Hour Screening Test with Pimephales promelas Laboratory Project ID: DuPont-5019 AUTHOR: Robert A. Hoke, Ph.D. STUDY COMPLETED ON: October 10,2000 PERFORMING LABORATORY: E.I. du Pont de Nemours and Company Haskell Laboratory for Toxicology and Industrial Medicine Elkton Road, P.O. Box 50 Newark, Delaware 19714-0050 WORK REQUEST NUMBERi^fl STUDY CODE NUMBER:|^^P ^^ >al"c?""'^,, -^ca i- H-24615: Static, Acute, 96-Hcmr Screenmg Test to Pimephales promelas DuPont-5019 STUDY INFORMATION Substance Tested: Synonyms/Codes: Haskell Number: Composition: Known Impurities: Physical Characteristics: Stability: Sponsor: m-Life Initiated/Completed: Not supplied by the sponsor Milky to tan liquid The test substance appeared to be stable under the conditions of the study. E.I. du Font de Nemours and Company Wilmington, Delaware 19898 U.S.A. September 25,2000/September 29,2000 Aooe8"o^eo^TSO|CBI .2- H-24615: Static, Acute, 96-Hour Screening Test to Pimephales promelas DuPont-5019 SUMMARY The acute toxicity of H-24615 to the fathead minnow, Pimephales promelas was determined in an unaerated, 96-hour, static test. The study was conducted with 4 concentrations of H-24615 and a dilution water control at a mean temperature of 21.5C. One test chamber was used per test concentration with 10 test organisms in each chamber. Based on visual observations, the water control and the 1,10 and 100 mg/L test concentrations were clear and colorless at test start. The 1000 mg/L test concentration was a cloudy, whitish/tan color at test start. All water quality parameters were within acceptable limits during the test. Exposure of fathead minnows to the water control and nominal H-24615 concentrations of 1,10,100, and 1000 mg/L resulted in 0,0,0,0, and 100% mortality, respectively, at the end of 96 hours. No mortality or sublethal effects were seen in the water control test organisms. The highest nominal concentration causing no mortality at test end was 100 mg/L. The lowest mean, nominal concentration causing 100% mortality at test end was 1000 mg/L. Nominal H-24615 concentrations were used to calculate the LC5o value using the binomial procedure. The results are summarized as follows: Nominal concentrations of H-24615, mg/L 96-hour LCso (95% confidence interval) for H-24615, based on nominal concentrations, mg/L" dilution water control, 1,10,100, and 1000 316 (100 to 1000) H-24615 exhibited low concern for aquatic hazard a in an unaerated, 96-hour, static, acute test using the fathead minnow, Pimephales promelas. Smrchek, J., Clements, R., Morcock, R., and Rabert, W. (1993). Assessing ecological hazard under TSCA: methods and evaluation of data. Environmental Toxicology and Risk Assessment, ASTMSTP 1179. (W.G. Landis, J.S. Hughes, and M.A. Lewis, Eds.), pp 22-39. American Society for Testing and Materials, Philadelphia. ---- Qoapacy seaSeos Does not contain TSCA CBI H-24615: Static, Acute, 96-Hour Screening Test to Pimephales promelas DuPont-5019 CERTIFICATION We, the undersigned, declare that this report provides an accurate evaluation of data obtained from this study. Work Completed by: ^G^v^/^--^- ^^-S^w^ Darnel J.C. Peterson Associate Scientist /^ s^- ^<ao? Date Issued by Study Director: ^6u^/f / ^ toerfA.Hoke,Ph.D. Senior Research Scientist /> C^(. -^600 Date Company Sanitized. Does not contain TSCA CBI H-24615: Static, Acute, 96-Hour Screening Test to Pimephales promelas DuPont-5019 TABLE 1 DISSOLVED OXYGEN AND pH OF TEST AND CONTROL SOLUTION SAMPLES Nominal H-24615 Concentration (mg/L) Test Initiation (0 hours) Dissolved Oxygen (mg/L) PH Test Completion (96 hours) Dissolved Oxygen (mg/L) PH Water Control 8.7 7.5 6.4 7.3 1 8.7 7.5 5.3 7.3 10 8.7 7.5 5.8 7.3 100 8.7 7.5 5.2 7.3 1000 8.7 7.5 7.4s 7.42 a Measurement taken at 48 hours due to total mortality TABLE 2 MORTALITY OF Pimephales promelas, IN AN UNAERATED, STATIC, ACUTE, 96-HOUR TEST WITH H-24615 Nominal H-24615 Concentration (mg/L) Water Control 1 10 100 1000 Number Dead/ Number at Test Initiation 24 Hours 48 Hours 72 Hours 96 Hours 0/10 0/10 0/10 0/10 10/10 0/10 0/10 0/10 0/10 , 10/10 0/10 0/10 0/10 0/10 10/10 0/10 0/10 0/10 0/10 10/10 coinpanysa"^.^ ^^rac^ 5-