Document 7OoDv1Rn4bgvV1ggO756x2k16

ACUTE TOXICITY TO AQUATIC INVERTEBRATES (COROPHIUM VOLUTATOR) TEST SUBSTANCE Identity:A mixturecontainingperfluorooctanesulfonawthei,ch may alsobe referredtoas PFOS, FC-95, or as a component of FC-603EF. (1Octanesulfoniaccid)(CAS # 2795-39-3). Remarks: The 3M productionlotnumber isnotnoted.The testsample is FC-603EF. Currentinformationindicatesitisa mixtureof 1.30% PFOS, 10% diethyleneglycolbutylether,54.15% water,22.5% ethyleneglycol,2.6% propanesultonefoamer,5% Alkylethersulfate0,.1% N-(3Chloroallyl)hexaminiucmhloride0,.9% Xanthan gum, 0.9% starch,1.0% triethanolaminea,nd 0.05% tolytlriazole. The followingsummary appliesa mix-turewith incompletely characterizedconcentrations ofimpurities.Data may not accurately reflecttoxicityof the fluorochemicalcomponent of the testsample. METHOD: Method: ASTM El367-90,Standard guide forconducting10 day static sediment toxicittyestswithmarine and estuarinesediments. Type: Acute static GLP: No Year completed: 2000 Species: Corophium volutator Supplier:Fieldcollectefdrom an unpollutesditenearTrondheim,Norway. Analyticalmonitoring: pH and dissolvedoxygen. Exposure period: 10 days Test organism age: Adults(4-8mm size) Statisticamlethod: LC50 valuescalculatebdy PROBIT Analysis,National Swedish EnvironmentalProtectioBnoard (Version2.3,1990). Calculatioonf NOEC by single-factAoNrOVA followedby Bonferronisprocedure. Test conditions: Dilutionwater: Naturalseawater (34 pptsalinitfyr)om an unpolluted siteinByfjordenoutsideofStavanger,Norway. Sediment collectedat an unpollutedsite.The sediment isa muddy sand and had an organic fractioonf0.7% and a silftractioonf0.8%. Dilutionwater chemistry: Not given. Lighting: Not given. Stock and testsolutionpreparation: Each testconcentrationwas prepared by adding the testsubstance to600 g damp sediment and 150 mL of seawater,then shaken for3 hours. The sediment was splitintothree subsamples, withan overlayof400 mL seawater added toeach, and aerated overnightbeforestudy initiation. Exposurevessels:600 mL glassbeakerscontaini2n0g0 g oftestsediment and -400 mL ofseawater withcontinuousaeration. Number of replicates:3 Number of organisms per replicate:10 Number of concentrations: fourplusa blankcontrol Water chemistry during the study: pH range (0-10days): 8.1- 8.1 (controelxposurf,,) 8.0- 8.1 (3060 mg/kg exposure) Temperature range: 15 1 OC Dissolved oxygen range (0-10days): 90 - 97% (controelxposure) 93 - 100% (3060 mg/kg exposure) RESULTS Nominal concentrations:Blankcontrol2,22, 457, 1060,and 3060 mg/kg (dryweight).Reference substance(fluoranthenea)t20.9 mg/kg dryweight. Element values: 10-day LC50 = >3060 mg/kg (sedimentdryweight) 10-day NOEC = 3060 mg/kg (sedimentdry weight) Element valuesbased on nominal concentrations Remarks: Testingwas conducted on the mixtureas describedintheTest Substance Remarks field.The values reportedapplytothatmixtureand not the fluorochemicalproportionalone. CONCLUSIONS The testsample 10-day LC50 was determined tobe >3060 mg/kg (sediment dryweight).The 10-day No Observed EffectConcentration(NOEC) was 3060 mg/kg (sedimentdryweight).The 3060 concentratiownas the highest concentrationtestedand caused -17% mortality. Validitcyriterifaulfillaendd referencesubstance obtainedmortalitoyf 16.7%. Submifter: 3M Company, EnvironmentalLaboratory,P.O. Box 33331, St. Paul,Minnesota,55133 DATA QUALITY ReliabilityK:limischranking= 2.This studymeets the criterifaorquality testing.However, sample puritywas notpropedy characterizedand the study lacksanalyticaclonfirmatioonftheamount offluorochemicalproportioninthe solution. REFERENCES Testwas conductedby RF Rogaland Research,of Stavanger,Norway atthe requestof3M Norge,Lab referencenumber 99312-4,2000. OTHER Last changed: 6/26/00 Lab.ref.tio.: 99312-4 Page IolJi na ROGALAND A 4G RESEARCH "FC-603 EF Light WaterTm ATCTM 3%gg Toxicitytests Report RF-2000/004 Lab. ref.no.: 99312-4 No. of pages: 31 ISBN: Author ElinHorve Client(s): 3M Norge Distributiornestdction: Version No. date: Vers. 1114.012000 Research Program: Open from(date): Summary. The followingtestresultswere obtained with "FC-603 EF Ught Water TmATC im 3-k- Toxicity.Skeletonema costatum Acartiatonsa Corophium volutator 72 h ECSO 48 h LCSO 10 d LCSO (mgA): -170 (mgA) : 280 (mg/kg dry weight): >3060 The resultsrelatetothe product as suppliedby Novatech. Key-words: Toxicity,Skeletonema costatum, Acartia tonsa, Corophium volutator. No partofthisdocumentmay 6e reproducedinany formwithoutperrifissIinowndbng by RF -RogalandResearch0. A TStudodiredor lnger Usa Andersen forRF -Roga-landResearchK&re Netland 99312-4 CONTENTS: I.PREFACE ............................................................................3 ........ 2. TEST FOR TOXICITY WITH SKELETONEMA COSTA TUM ........................................................4........ 3.TEST FOR TOXICITY WITH A CARTIA TONSA ...........................................................1.0........... 4.TEST FOR TOXICITY WITH COROPHIUM VOLUTATOR .............................1.5......... 5.DATA SHEETS ...............................................................2.0......... Lab.ref.no.: 99312-4 Page3 of31 PREFACE: Ecotoxicologitceasltwsereperfor7neodn "FC-60E3F LighWtaterYuATC "w3%m inagreementwith NovatechT.he sampleisa concentratheatnormallwyillbe usedina 3% AFFF13% AR solutionT.estswereconducteidnaccordancweiththe"HarmoniseOdffshorCehemical NotificatiFonrniat("OSPARCOM 1995/SFT 1998). Theprojecwtas carrieodutat RF -RogalandResearchfo3rM Norge.Allthetestwsere performedbyRF -MiljolabS.tudydirectowras SeniorEngineeIrngerLisaAndersen. ThetestresultasrepresenteidnseparatseectionsT.he resultrselatteotheproductassupplied byNovatech. Thistesrteportisissuebdya laboratorayccreditbeydNorwegianAccreditati(oNnA). TheaccreditatisotnatetshatthelaboratormyeetstheNA requiremenctosncernincgompetence, equipmenatnd workingproceduresfoarllthetesmtethodscontaineidntheaccreditation. Italsostatetshatthelaboratohraysa satisfactqouraylitayssurancseystenw4hichincludes internaqlualitcyontroslchemesp,articipatinoinnterlaboratcoormyparisonasn,d theuseof certifireedferencmeaterialasnd secondarryeferencmeaterials. Thetestpserformedarecoveredby theaccreditation. Thistestrepormtay notbereproduceidnanyfor?ontherthaninMI,withoutheper?nissiionn writinbgyRF -Miljolab. Lab.ref.no.: 99312-4 page 4 of31 TEST FORTOXICITY Marinealga:Skeletonemcaostatum 99312-4 I-age oj J TEST REPORT GROWTH RIMMON TEST WrrH THE WAINE ALGASkeletonemacostatum an Nr.P"l ROGALAND RESEARCH TEST SUBSTANCE: "FC-603 EF Light Water ATCrm 3%" TEST RESULT: The 72 hoursEC50 was calculatetdo -170 mg/l. The testsubstancewas suppliedby Novatech, and thetestresultsrelatetothisproduct. TEST DETARS: ME,RHOD: NS-EN ISO 10253, 1998:Water quality- Marine algalgrowth inhibitiotnest with Skeletonema costatwn and Phaeodactylum tricomutum. TEST ORGANISM: Skeletonemacostatum,straiNnIVA BAC 1. A stockcultureof the test organism iskept atRF - Rogaland Research. PP,EPARAnoNs: Naturalseawater(salinity3:4 %o) from an unpollutedsiteinByfjordwas used as basisforthe growth medium. The waterwas filteretdhrougha GF/C filter, and brieflyheatedto about 75*C priortouse. The seawaterwas enrichedwith nutrient@accordingto ISO 10253, and recommendations from theParis Conunission. Test solutionswere preparedfrom a stocksolution.A stocksolutionof 1020 mg/l was preparedby stirrin1g.020grainsof theproductin I litroef growth medium. Other concentrationswere preparedfrom thisstocksolution. INCUBANON: Testculturesof 50 ml were incubatedin 100 ml flat-bottomedflaskson an orbitalshaker,3 replicatefsoreach concentration.Test cultureswere inoculatedtoabout 2000 cells/mlfrom an exponentiallgyrowing inoculum culture. The testwas run under continuouslight(> 50 PEIM2.sek)from fluorescent-,tubesof universalnaturalwhite type,ata temperatureof 20:t 2*C. The testwas run forabout 72 hours,and subsamples of5 ml were taken from thetestflaskseach day forgrowth measurements. Algal growth was measured by fluorescence.pH measurements were performed as indicatedon datasheet. Lab.ref.no.: 99312-4 Page6of31 DATA ANALYSIS: CALCULANONS: Growth rateswere calculatedby log linearregressionon biomass (fluorescence) versustime,as describedinNS-EN ISO 10253. EC50: The inhibitoryeffecton the growth of Skeletonema costatum isexpressed as the concentrationof a product giving50% reductionof growth rate(E,,C50)T.his effectconcentrationwas calculatedby interpolatiobnetween 100mg/l and 320mg/l. NOEC: Calculationof NOEC (No Observed EffectConcentration)isdone by singlefactorANOVA followedby Bonferronisprocedureforcomparing each concentrationmean with the controlmean. TEST RESULTS: COMMENTS: VALI]DATION: Table 1. EC and NOEC valuesobtainedwith Skektonema costatum. Testsubstance .FC-603 EF Uotm Waterrm ATC 3DA' FCio Fc5o -170 E@Cw 100<ECgo<320 NOEC: 100 Valuesindicatceoncentrationgsiving10% 50% and 90% bthibitioonfgrowthrate.Unitsinmgll ValuesarecalculatebdyinterpolatioNnO.EC arecalculatebdy usingthecomputerprogramme GraphPad InStat3.0. The resultsare based on growth ratesfor the time span 0 - 72 h,the period duringwhich the growth isconsideredto be exponentialin thecontrolcultures (seegrowth curves). The validitycriterigaiven inthetestprotocolarefulfilledi,n thatthecontrol celldensityincreasedby a factorof more than 16 in the testperiod (correspondinct,o a growth rateof more than 0,9 d 1),the controlpH didnot varyby more than 1,0 unitsduring thetestand the 72 hours testresultswith 3,5-dichlorophenolwas in therange normally found. Lab. reL no.: Sample received.: Test period: Report date: 99312-4 20.09.99 07-10.12.99 10.01.2000 E@@ \@oN-"Elin Horve Engineer Analyticaltechnician @ge%@versmy@r Senior Research Scientist QualityAssurance Enclosed: Data sheets Ibistestreportisissuedby a laboratorayccreditebdy NorwegianAccreditati(oNnA). The reportmay notbereproducedinany form otherthaninfullw,ithoutthepermissioinnwritingbyRF - Miijolab. Lab.r.f(t.io,.: 99312-4 tage 7 oj-11 PRIMARY DATA:GrowthinhibititoenstwithSkeletonemacostatum Testsubstance: FC-603EF LightWater TM ATC TM 3% Lab. ref.:99312-4 Startdate: 07.12.99 Conc. unit:mgA Measurement: The biomass was measured by fluorescence;values influorescenceunits Time: 07.12.99108.12.99 09.12.99 10.12.99 Growth pH pH rate Corre- atstart atend Concentration 14:50 09:30 10:25 11:55 day -1 lation oftest oftest 0 0.12 0.26 0.93 4 1.22 0.998 0 0.1 0.34 1.7 9.7 1.59 1.000 0 0.1 0.33 1.1 6 1.42 0.998 8.2 8.2 0 0.09 0.3 1.1 6.4 1.48 0.998 0 0.09 0.26 0.88 6 1.46 0.995 0 0.09 0.26 0.9 7 1.51 1 0.994 3.2 0.09 0.43 1.75 11 1.67 0.998 3.2 0.09 0.28 1.2 6.3 1.48 1.000 8.3 8.2 3.2 0.08 0.23 1 4.7 1.42 1.000 10 0.08 0.4 3.4 14.5 1.81 0.995 10 0.09 0.4 2 11.5 1.69 0.999 8.3 8.3 10 0.1 0.4 2.2 12 1.66 1.000 32 0.1 0.28 2.05 9.3 1.57 0.998 32 0.1 0.3 1.9 9.2 1.57 0.999 .8.3 8.2 32 0.11 0.3 1.65 8.8 1.52 0.999 100 0.09 0.31 0.77 5.4 1 42 0.991 100 0.11 0.35 0.75 5.1 1.* 33 0.986 8.3 8.2 100 0.1 0.36 1 0.78 5.4 1.39 1 0.987 320 0.07 0.04 0.03 0.04 0.00 320 0.09 0.03 0.01 0.04 0.00 320 0.06 0.04 0.02 0.06 0.00 8.3 8.2 1000 1000 1000 0.09 0.09 0.1 0.07 0.08 0.03 0.03 0.03 1 0.03 0.05 0.05 0.02 0.00 0.00 0.00 8.3 8.2 Reference subsmitacRe(3,5-dihlorophenol): 1.5 MgA 0.09 0.15 0.15 1.5 mg/i 0.08 0.1 0.12 1.5 mgll 0.08 0.14 0.18 Mean values: 0 0.10 0.3 1 3.2 0.09 0.3 1 10 0.09 0.4 3 32 0.10 0.3 2 100 0.10 0.3 1 320 0.07 0.0 0 1000 0.09 0.0 0 Reference subst.1 0.08 0.13 0.2 0.2 0.22 0.2 7 7 13 9 5 0 0 0.-2- 0.28 0.35 0.32 0.908 0.968 0.921 1.45 1.52 1.72 1.56 1.38 0.00 0.00 0.998 0.999 0.999 0.999 0.988 The resulotfthe reference substanc(e2M inhbiboni)s vAtNntherange normallfyound (20-8(r/.) Lab.i-efiio.: 99312-4 PageN oj31 GROVVTH CURVES: GrowthinhibititoenstwithSkeletonemacostatum TestsubstanceF:C-60E3FLighWtaterTM ATCTM 3% Lab.ref.:99312-4 7 Control 5 S0? 31 0 E 0 :5 -1 0 48 72 -3 0000,@testduration(hours) J 7 5 E 3- 3.2 mgA E0o .1 ID@ @4 E 48 72 -3 testdu@alion(hours) 51 e 31 0 10 mg/i E -i p @4 48 72 -3 testduration(hours) 7-. 5 03 32 mg/i 48 72 -3 testduration(hours) 7 5 31 E01 .3 100 mgfi 48 72 testduration(hours) 7 5 E3 01 E0 i :5 t 0 320 mg/i 24 48 72 testduration(ho 71 1000 MgA 5 E 0 24 48 72 Lab.refno.: 99312-4 Page 9 of31 Inhibition of the growth of Skeletonema costatum with: mg/l ( FC-603 EF Light Water TM ATC TM 3%) ----------------------------------------------------------------------------- Experimental data: ---------------------------------------------------------------------- Concentration in Growth rate FC-603 EF Light Water TM ATC TM 3% Inhibition in percent --------------------------------------------------------- C-o-n-t-ro-l---1----Coonntrol 2 C trol 3 Control 4 CCoonnttrrooll 5 6 1.22 1.59 1.42 1.48 1.46 1.51 Control mean 1.45 0 3.20 3.20 3.20 1.67 0.0 1.48 0.0 1.42 1.8 10.00 10.00 10.00 1.81 0.0 1.69 0.0 1.66 0.0 32.00 32.00 32.00 1.57 0.0 1.57 0.0 1.52 0.0 100.00 100.00 100.00 1.42 1.8 1.33 8.1 1.39 3.9 320.00 320.00 320.00 0.00 0.00 0.00 100.0 100.0 100.0 .1000.00 0.00 100.0 1000.00 0.00 100.0 1000.00 0.00 100.0 ---------------------------------------------------------------------- Lab.refno.: 99312-4 Page 10 of31 TEST FORToxicITY MarineherbivoreA:cayWatonsa Lab.reflio.: 99312-4 Page 11 of31 TEST REPORT ACUTE Toxicrry TEST WITH THE MARINE COPEPOD Acartia tonsa TEST SUBSTANCE: "FC-603 EF LightWater Tm ATCrm 3%" TEST RESULT: The 48 hoursLC50 was calculatetdo280 mg/l. The testsubstancewas suppliedby Novatech,and thetestresultrselateto thisproduct. TEST DETAILS:, ME-RHOD: TEST oRGANism: CULTIVATION: PRF-PARANONS: ISO/DIS 14669 - 1997:Water quality-Determinationof acutelethatloxicity tomarinecopepods (Copepoda,Crustacea). Acartiatonsa(Dana),suppliedby theMarine BiologicalLaboratory, Universityof Copenhagen. The testorganismswere suppliedas eggs,and were cultivateidn accordance withthe"ParisCommission -Ring TestProtocol"(VKI). Large copepodites and adultswere used inthetest. Naturalseawater(salinit3y4: %o) from an unpollutedsiteinByfjordwas used as basisforthedilutiownater.The waterwas filteretdhrougha GF/C filter priortouse. INCUBANON: Testsolutionwsere preparedfrom a stocksolutionA. stocksolutionof 1000 mg/l was preparedby stirrin1g.0002grams oftheproductin 1litroef dilution water.Otherconcentrationwsere preparedfrom thisstocksolution. The testwas run inglasscontainer(s28ml rolledrim vialse)achcontaining 25 ml oftestsolutionand 5 animals,4 replicatefsoreach concentrationT.he vialswere keptunder a 16h/8hlight/darpkhotoperiodata temperatureof 20 I *C. pH and oxygen measurementswere performedas indicateodn the data sheet. Lab.ref.@to.: 99312-4 Page 12 of31 DATA ANALYSIS: CALcuLAnoNs: TheeffecotnthesurvivoaflAcartitaonsiasexpressaesdtheconcentratoifon a product lethalto 50% of the testanimals (LC50). The combined mortality per testconcentration were used for calculation.The 24 hours and 48 hours LC 0 values and the 95% confidence limitwere calculatedby using the standard procedure PROBIT Analysis, National Swedish Environmental ProtectionBoard (Version 2.3, 1990). This prograrrunealsocalculatetest concentrationslethalto 10% and 90% of the testanimals. NOEC: Calculationof NOEC (No Observed Effect Concentration) isdone by singlefactorANOVA followed by Bonferronis procedure forcomparing each concentration mean with the controlmean. TEST RESULTS: Table 1. LC and NOEC valuesobtained with "FC-603 EF LightWaterrm ATC Tm 3ok!'. Acartiatonsa 24 hours 48 hours Lcio 280 (130- 380) 89 (54-120) LCSO 610 (490-790) 280 (220- 360) LC90 >1000 880 (620- 1500) NOEC: 320 180 Valuesindicate109k 50% and 90% lethalitayfter24 and 48 hours. Unitsinmgll Valuesare calculatedby PROBIT analysisa,nd 95% confidenceintervalasre indicatedNOEC are calculatedby thecomputerprogramm GraphPad InStat3.0. VALIDANON: The validitycriteriagiven in the testprotocol are fulfilledi,n thatthe dissolved oxygen concentration at the end of the testwas greaterthan or equal to 4 mg/l, the percentage mortality in the controlswas lessthan 10%, and the 48 hours LC50 of 3,5-dichlorophenol(reference)was inthe range normally found. Lab. reE no.: Sample received.: Test period: Report date: 99312-4 20.09.99 10-12.11.99 07.01.2000 Elin Horve Engineer Analytical technician kge Molversmyr Senior Research Scientist Quality Assurance '-- Enclosed: Data sheets nis testreportisissuedby a laboratorayccreditebdy Norwegian Accreditatio(nNA). Tle reportmay notbe reproducedinany form otherthaninfullw,ithoutthepemiissionin writingby RF -Miljolab. Lab.ref.no.: 99312-4 Page 13 of31 PRIMARY DATA: AcutetoxicityestwithAcartitaonsa Test substance: "FC-603 EF LightWater TM ATC'rm 3%" Lab. ref.: Startdate: Measurement: 99312-4 10.11.99 Number of dead Concentration (mgA) Control 32 56 100 180 320 560 1000 Total number Specimen pr.conc. 30 20 20 20 20 20 21 20 Number of specimen pr.vessel A CE BDF 5 56 4 55 5 55 5 5 55 5 5 55 5 5 55 5 5 65 4 6 54 6 555 5 NUMBER OF DEAD 24 hours 48 hours A CE B DF Total A cE B DF Total 0 00 001 0 00 0 000 1 000 000 0 0 0 0 000 001 0 0 0 1 0 00 111 1 1 1 4 0 00 212 0 0 1 6 011 0 24 1 3 2 8 213 533 3 9 5 16 4 54 555 3 16 5 20 -Reference substanc (3,5-dichlophenol): 1.0 mg/i 555 1 10 3 31 30 64 5 0 01 3 0 11 The resulwtiththereferencseubstancieswithitnherangenormallfyound. @9] Lab.i-efno.: 99312-4 Page 14 of31 Test substance: Lab. ref.: Startdate: "FC-603 EF Light Water TM ATC TM 3%" 99312-4 10.11.99 Afe8surementS of oxygen and pH. Concentration (mgA) Control 32 56 100 180 320 560 1000 Start Oxygen pH (mgA) - 7.3 8.2 7.6 8.1 7.7 8.1 7.8 8.2 7.7 8.2 7.7 8.2 7.6 8.2 7.6 8.2 24 hours Oxygen pH (mgA) 48 hours Oxygen (mgA) 7.4 7.1 7.1 7.1 6.8 6.8 6.5 6.4 Reference substanc (3.5-dichlorophenol): 9A 7.3 8.2_ 7.4 pH 8.2 8.2 8.2 8.2 8.'2 8.2 8.1 8.1 8. Lab.refno.: 99312-4 Page 15 of3l TEST FOR TOXICITY MarineAmphipode: Corophiumvolutator Lab.relji,o.: 99312-4 Page 16 of31 TEST "PORT ACUTE TOXICITY SEDIMENT TEST WITH THE MARINE AMPHIPOD Corophium volutator TEST SUBSTANCE: "FC-603 EF LightWater T' ATC 3%" TEST RESULT: The 10d LCsowas calculatteod>3060 mg kg-1dryweightsediment. The testsubstancewas suppliedby Novatech,and thetestresultrselatetothisproduct. TEST DETAILS: METHOD: ASTM E 1367-90,StandardGuide For Conducting10 day StaticSediment ToxicityTestswithMarine and EstuarineSediments. TEST ORGANISM: Corophium volulator,from an unpollutedsitenear Trondheim. CULTIVATION: The testorganismswere suppliedas adults(4-8nim in size)and were heldin aeratedseawaterat15'C. A smallamount ofnaturalseaweed was used for feeding. PREPARATION: Naturalseawater(salinit3y4:%o) from an unpollutedsiteinByfjordenoutside Stavangerwas used fordilutiownater.Sedimentcollecteadtan unpollutedsite was used forpreparingtestsediments.The sedimentisa muddy sand and was analysedfororganiccontentand proportionsilftoreach test. Each testconcentratiownas preparedby addingtheproductin600 grams of damp sedimentina plastibcucket. 150 ml of seawaterwas added and the bucketwas shaken for3 hours.The sedimentwas dividedintothreebeakers, 400 ml of seawaterwas added toeach,and thebeakerswere aeratedover night.10 animalswere thenrandomly selectedforeachbeaker.A sampleof thedamp sedimentwas analysedforwatercontent,and allconcentrationasre calculateads mg kg-1sedimentdryweight. INCUBATION: The testwas run inglasscontainer(s600ml) each containing200 g of test sediment,app.400 ml of seawaterand 10 animals,3 replicatefsoreach concentrationT.he beakerswere keptunder continuousaerationata temperatureof 15 IOC. pH and oxygen measurements were performedas indicatedon thedatasheet. Lab.refno.: 99312-4 Page 17of31 DATA ANALYSIS: CALCULANONS: NOEC: TheeffecotnthesurvivoaflCorophiuvmolutatiosrexpressaesdtheconcentratioofnaproducltethatlo50% ofthetesatnimal(sLC50). Thecombined mortalipteyrtesctoncentratwieorneusedforcalculatiTohne.10dayLC50 valueand the95% confidencelimitarecalculatebdy usingthestandard PROBIT AnalysisN,ationalSwedish EnvironmentalProtectioBnoard (Version 2.3,1990).Thisprogramme alsocalculatteestconcentrationlsethalto 10% and 90% ofthetestanimals. CalculatioonfNOEC (No Observed EffectConcentrationi)sdone by singlefactorANOVA followedby Bonferronisprocedureforcomparing each concentratiomnean withthecontrolmean. TEST RESULTS: Table 1. LC and NOEC valuesobtainedwith "FC-603 EF Ught Water Tm ATC Tm 3%" Corophium volutator Lcio LC50 10 days 99 ( -760) >3060 LC90 >3060 NOEC: 3060 Valuesindicat1e0% 50% and 90% lethaliat.yfter]Oda),sU.nitsinmg kg-'sedinentdryweight. Valuesarecalculatebdy PROBIT analysisa,nd 95% confidencientervalasre indicatedNOECare calculatebdy thecomputerprogramme GraphPad histat3.0. VALIDANON: The validitcyriterigaiveninthetestprotocolarefulfilleidn,thatthedissolved oxygen concentratioanttheend of thetestwas greaterthan orequalto60 %, thepercentagemortalitiynthecontrolswere lessthan 15%. The percentage mortalitiyna referencesubstanceof 20.9 mg Fluoranthenekg-1dry weight sedimentwas 16.7%. The sedimentused isfound tobe withinacceptedlimits fororganiccontentbutthesilftractioinsrecommended higher.We have observeda significanmtortalitiynone concentratio(n1060mg kg-1dryweight sediment)butthemortalitiynthehighestconcentratiownas notsignificant. Table 2. Characteristicosf thesediment used fortesting Organic content 0.7 Siltfraction 0.8 Lab.ref.no.: Sample received.: Testperiod: Report date: 99312-4 20.09.99 0-10.12.99 07.01.2000 Enclosed:Data sheets ElinHor've Engineer Analyticatlechnician ,@XMolversmyr@ SeniorResearchScientist QualityAssurance Lab.refno.: 99312-4 Page18of31 PRIMARY DATA: AcutetoxiciteystwithCorophiumvolutator Test substance: "FC-603 EF LightWater TM ATC TM 3./,, Lab. ref.: Startdate: Measurement: 99312-4 17.12.99 Number of dead Total number Number of specimen pr.vessel Concentration Specimen A C E (mg/kgdryweight) pr.conc. B D F Control 10 10 10 60 10 10 10 10 10 10 222 30 -10 10 10 457 30 10 10 10 1060 30 10 10 10 3060 30 NUMBER OF DEAD 5 days ACE BDF Tofal 10 days A CE B DF Total 000 000 0 0 12 3 2 02 4 2 32 7 320 5 Referencesubstanc (fluoranthene): 1 10 10 10 20.9 30 122 57 Lab.refn.o.: 99312-4 Page 19of31 Testsubstance: "FC-603 EF Light Water TM ATC TM 301," Lab. ref.: Startdate: 99312-4 17.12.99 Aleasurements of oxygen and pH. Start Concentration Oxygen pH (mg/kg dryweight) (0/.) - Control 94 8.1 5 days Oxygen pH (0/0) 90 8A 222 96 8.1 92 8.1 457 97 8.1 93 8.1 1060 92 8.0 62 7.7 3060 100 8.1 93 8.0 10 days Oxygen pH 97 8.1 94 8.0 97 8.1 96 8.1 96 8.1 --------------- Reference substanc (fluoranthene): 20.9 95 8.1 92 8.1 83 8 -0 Lab.y-neof.: 99312-4 Page 20 of31 DATA SHEETS Lab.ref.no.: 99312-4 Page 21 of31 .=MS-DAT.kBLAD (Felse-, ,4iljo- og Sikkerhetsdatablad) Ookumentnr.: ':'rstatter 07-7297-0 Utg;-tt 24/04/97 Skrevet ut : 03/11/98 Versjon : 11/11/98 5;-de 03.oo 1 av 11 HMS-databladet er utarbe;det av M4-ljoavdelingen ved.3M Norge A/S. Telefon: 63 84 75 00 / Telefax: 63 84 17 88 ------------------------------------------------------------------------ 1 ID7-NTIFI-.<-kSJON AV OG ANSVARLIG FIRbw.- ------------------------------------------------------------------------ Importer: 3M Norge A/S Handeisnavn: FC-603E.T LIGH'!-'WATR-.R (TM) A'-rC3% AR-A.7FF Deklarasjonsnummer, Produk@.reg4@szeret: Tele46on, GLftinz6o--masjorssen-6ralen: 22 59 13 00 ------------------------------------------------------------------------ 2 OPPT-YSNT-NGE.1 OM SkMMENS=-TNT-NG. ----------------------------------------------------------------------- ---ifo--masjoonm enkeitkomponenter, faresymbol(er) og r4@sikosetninger STOFFNAV.N CAS-nr V-zX@4-PROSENT -------------------------------------------------------------------- VANN 1,2-ETANDZOL 7732-18-5 107-21-1 52 56 22.5 Faresymboler/ri-s;-kosetn;-nger: Xn; R:22 2-(2-BUTOKSY7'roKSY)-7T-A,.NOL / 112-34-5 10 (DIETYLENGLYKOLMONOBUTYLETER) Faresymboler/rLs;kosetn;-nger: Xi; SYNTETISK OV%-'RFLATEA.KTIVT STOFF FLUOP-kLKY'r- OVERFLATE;@-KTIV7- STOF@TER FLUORKJEMISK AKRYLAT TRZET.kNO"%IZN TYKNERE RF-STER AV ORGANISK-= FLUORKJEMIKALIER R:36 Trade Secret Trade Secret Trade Secret 102-71-6 Trade Secre-. Trade Secret 4 -6 1 -5 I- 3 13 Ikke kjent Lab.rej.no.: 99312-4 A4-lage2,; oj FC-603EF LIGHT WATER (TM) ATC 3% AR-A.FFF -----------------------------------------------------------------------3 VIKTIGSTT- FA-R-rMOMENTER. ------------------------------------------------------------------------ Vikz,-gste skadevirkninge.- Heise-'are: Kan vere farlig ved svelg4-ng. Kan irritere eynene. S;-kkerhet: Miljo-.oare: Spesi-alavfall. -----------------------------------------------------------------------4 -70RSTr-=Jr-LPSTILTAX. ------------------------------------------------------------------------ Ti-l-takoyne: Skyll s"@raks eynene med ri-kelige mengder vann. Kontakt lege um;-ddelbart. T@'.Itakhud: Skyll straks huden med s&oe og rikel4-ge mengder vann. Fjern %--4-1-solttoy. Evis symp--omer oppst&r, konl.akt lege. Vask t;-Isolt toy for det brukes ig4jen og kast ti-lsoltskotoy. T4-ltak innind;-ng: Evis symptamer opost&r, br;-ng vedko=ende bort fra eksmoneringski-l-den. Sorg for frisk lu@lt. Evis symptomene kontakt lege. vedvarer, Ti-Itak svelg;-ng: Kontakt lege umiddelbart. Fremkall brekn;-nger kun i samrid med medisinsk pirsonell. G;- aldr4- noe gjennom munnen til en bev4-sstles person. -----------------------------------------------------------------------5 TILTA.I< Vr-D BRANNSLUKNING. ----------------------------------------------------------------------- Egnet brannslukningsm;-ddel: Produktet er et brannslukkingsmiddel. Ikke egnet brannslukningsmiddel: Eksponeringsrisiko ved brann: Lab.refno.: 99312-4 Page 23 of31 FC-603EF LIGHT WATER (TM) ATC 3% AR-A.FFF Forbrenningsprodukter ved brann: Prosedvrer ved sluk.'.c;-gav brann: -----------------------------------------------------------------------6 TILTA.K Vro UTILSI.:(Tr-,U'RSLIPP. ------------------------------------------------------------------------ Personlige vernetiltak: Se vernetiltak under andre punkter i de-@te--F.MS-databladet. T;-I-takved utilsikte"6 u-'sli-mo: Ventiler omr&det. So;-'-Iavgrenses umiddelba=t. Dekk til med et absorbez-ende materi-'-. S.04-1-s1afnles Opp um;-ddelbar%,-.Rengjor om=!-dellm-ed vann. Plasseres i en egne,--beholder med lokk. Fjerni-ng av kiem;-kalieav!all: Se ounkl, 13, Fjern;ng av kje,"t4-ka!4-eav@zall. -----------------------------------------------------------------------7 F-jNDT7--@tT-NlO@G oppBr-vA_RT-,,qG. ------------------------------------------------------------------------ Betingelser for s;-kker ooobevar;ng: mi 4-!<kelagres i omz'_ider hvor crodukl--e-kan ko=ne i kontak@ med mat eller legem;-dlez. Lagres ved -@em-De6ra-,urunder 49 grader cels;-us. Lagres ved te.,,noeraturezover 0 grader celsius. Hold beholderen te@'t lukke,: nir produk=e-. ikke er i bruk. Uforenelige ma-@erial-er: Ventilasjon: Onabevar e.,nballasjen m& et godt ventilert s-@ed. Sikkerhel-stiltak for A L'orhind@--ebT--a-n: Sikkerhetstiltak for A @'orhindre eksolosjon: Ikkebrennbar. Sikkerhetstiltak for A forhindre sta-@isk elektrisitet: Forholdsregler ved bruk: Hold emballasjen tett produktet kan reyking lukket. Royking forbudt: Under bruk av for&rsake forurensning av tobakken 09/eller Lab.refn.o.: 99312-4 Page24of31 FC-603EF LIGHT WATER (T,,4A)TC 3% AR-AFFF ------------------------------------------------------------------8 EKS?ONE.@t-7NGSKONTROLL OG P'--rRSONLIG V-zRNEUTSTY@t. --------------------------------------------------------------------- Oyevern: unngi A f& damp, sprav eller t&ke i eynene. Bruk tette vernebriller med vent3*.ler. H&ndvezn: Bruk egnede vernehansker av hensiktsmess4-g materiale ved hindtering av produktet. Vernehansker av folgende ma-6eriale(r) anbefales: Butylguirn,;-. Annet hudvern enn h&ndvern: Unngl hudkontakt. Andedrettsvern: Unngi inn&ndi-ng av lu-ftb&zezmateri-ale.Basert pl konsentrasjonen av luftforurensn4-nger i ar*--4e-dsatmasfarea velges en av folgende type(r) godkjent Andedre-6tsvern: halvmaske med fi-l-@6emrot organiske da.-.ioeorg vaske-@@or--,i4p-agreti-ki-er:A/P2SL. Svelg'-ng: De@.mi i-kke so;-ses, dr4-kkes eller rovkes under arbeid med produktet. Vask utsatte or=ider grundig med sipe og vann. Vask henden'eetter hkndter;-ng og for spising. Anbefait ventilasjon: Fvis utsugningsve'nti-l-iaosn '-kkeer tils,@rekkelig,mi egnet godkjent Andedret-Isvern benvttes. Sorg -.totrils-@rekkelig ventilasjon sli-kaz damokonsentrasjonene holdes under anbefaite adninistrative no-@-,neorg/el-l-erkontroll-ers.orayeller tlke. Adm. nor-.nerfor forurensn;-ng i a=*--e;-dsa-Imaorsef, Februar 1996: VANN (7732-18-5) Anmerkninger'-: Ingen adm. nor-.n. 1,2-ETANDIOL (107-21-1) 8-timers verd4-ppm: - (stav) 8-timers verd;-mg/--i3:10 (szov) Takverdi ppm: 25 (damp) Takverdi mg/m3: - (damp) 2-(2-BUTOKSYETOKSY)-ETA-'40L / (Dl%-'-IYLENGLYXOLMON OBUTYLETER) (112-34-s) 8-timers verd4- ppm: 35 Anmerkninger: Amerikansk grenseverdi anbefalt av produsenten. (ingen norsk adm. no=). SYNTETISK OVERFLATEAXTIVT STOFF (Trade Secre,.) A=erkninger: Ingen aft. no,-=. Lab.refno.: 99312-4 Page 25 of31 FC-603EF LIGET WATER (TM) ATC 3% AR-AFFF Anmerkninger: Ingen adm. norm. TRI'@-'T-ANOLA_X7N (102-71-6) 8-t4-mers verdi pprl: 8-timers verd4- mg/m3: 5 TYK@NNE.-R=- (Trade Secret) FTY.-, Anmerkninger: Ingen adm. norm. R':'ST'z'ARV ORGANISKT FLUORKirm!KAT-17-.4 (Trade Secret) 8-timers verd@- mg/m3: 0,1 rrenseverdi- anbefalt av 3M. ---------- -----------------------------------------------------------------------9 FYSTSKE OG KJEMISK7- EGENS.-KA-DEtt. ------------------------------------------------------------------------ 74-1-stands4-Fo=,farge, lukt: Gul/brun vaske. Kokeounkt/-intervall: Smel'@e.ounkt/-intervall: .7laL%-,ieounk-, Selvantennelighe-6: Eksolosjonsgrenser, nedre: Eksolosjonsgrenser, evre: De-,n.otrykk: Loselighe-@ i vanni S.cesi--fikvkekt: Dam.otetthet: Flyktige organiske forb4-ndelser Forda.mpningshastighet: Viskositet: 7.5 - 8.5 < iso c Ikke relevant ingen (Setaflash) T-kke kjent Tkke relevant Ikke relevant ca. 15.8 mmHg (Kalkulert v/20c) .7ullstendi-g ca. 1.06 (vann-1) ca. 0.88 (luf,,=I) v/20C) (Kalkulert (VOC): - 355 g/l SCAQMD v/20C). (Kalkulert Ikke kjent < 5000 centipoise Lab.refno.: 99312-4 Page26of3l FC-603EF LIGHT WATER (T,%tA)TC 3% AR-A.FFF -----------------------------------------------------------------------10 ST.ABTILIT7-T OG R-7A:CTIV-TT7T. ------------------------------------------------------------------------ Forhold som skal unng&s: Materialer som skal unngis: Ikke kjent. Fazl;-ge s.naltnings-orodukter: Karbo=onoks4-d og karbondioksid. Hydrogenfluorid. G4ftige damper, gasser eller partikler. Dekomponering av bruksferdig blanding forventes ikke A represen-@ere noen ri-s;-ko. Stab;-lite-o@g reakt;v;tet: Stabilt. Farl;-gpol-v.-.,erisasjvoinl ikke "orekomme. -----------------------------------------------------------------------11 OPPLYSN-TNGER OM E-TLS-TFA.I=-. ------------------------------------------------------------------------ 7-f!ektez ovne: Mild eyeirri-tasion: syt-aptomerkan va!re redhe-1,hevelse, smerter og r-.lz6ektehrud: Mild hudi---=-itasj.o(.e--iter langvarig eller gjenta--tkontakt) sy.-,tptomerkan ve,?--e hevelse og kloe. Langvarig eller gje-i-@atteksponering kan fore til: Alleraisk hudreaksjon: symp-6omer kan vare redhet, hevelse, blemmer og klee. Effekter ;-nn&.,id;-ng: En enkelt overeksoonering normer, kan fare @il: som overst4-geranbe@Ialte administrative Pivirkn4ng av sentrainervesyslemet: symptomer kin vare hodepine, orhe%-, ;ovni-ghet, manglende ko6ordina'sjonsevne,nedsatt reaksjonsevne, sioret tale, svimmelhet og i ekstreme tilfeller bevisstloshet. Irritasjon (ovre luftveier): symptomer k.anvare s&rhet i nese og sveig, hosting og nysi-ng. Effekter svelging: Dyreforsok utfort med organiske fluorkjamikalier, som finnes i dette produktat, viser effektcr 30M leverforstyrrelser, vakttap, manglende appetitt, slovhet samt effekter som p&virker neurologi,' bukspytt, binyre og hematologi. Det forelicam- 4---- Lab.refno.: 99312-4 Page27 of31 FC-603EF Llr.HT WATER (TM) ATC 3% A.R-A.FrF ve4-ledn;-ng. Svelg4-ng kan fore t;-l: Piv4-kn4-g av nyrene: Symptome.- kan vare redusert uri=engde, urinen og rvggsmerter. blad .kso4ras4ionsoneumon4- (Lungebetennelse som skvldes at fremmedlege=,ez kom-,nerned i lungene. '-@'anlm;-nnelig irsak til tilstanden er opokast.): sv-npzomer kan vare host4-ng, pus'levansker, g;-soing, hos"-e oup blod og lungebetennelse som kan vare 14-vstruende. In@'o--.masjonom ailerg;-, over'"olsomhet: .<ze4-@t-frenkall---nedgeenskioer: -krves@,o@44--3kideil.igeegenskamer: Re-croduksjonsskade!4-ge egenskaoer: Andre skadev4-rkn;-nger, helse: Dezte ozoduktet i-n---'-olderen eller 16!ere organ;-ske :!Iuo=-kliem4-kal;-eszo,m mul4gens kan absorberes og lagres i kroppen over !--ngre t;-d, en,@@-ensom ul"-gangsmolekyl---teller som nedbry--n;-ngsstof@ger (metabolitter) , og kan akkumuleres ved gjentatte eksconer4@.qger. De@6 fore!4-gger ingen kjente helseeffek-6ez for mennesker fra 'eks-mone."ingoverfoz organiske fluorkjemikalier nir de brukes som -@-orutsattog i henhold til ve4@ledning. Forakoms-!-en av organ4ske fluorkjem4@kal-@er i bi-odet til den generalle begol-kn;-ngen og underpopulasjoner som arbeide--e, har V.Trz ou*zl-;-ser-s-;-den 1970 Arena. 3Ms ep;-dem:@ologi-skestud4-er av egne arbeidere v;-ser ingen skadelige e@gfekter. -----------------------------------------------------------------------@12 OPPLYSNINGE-R OM M-TLjO,7.k.:L-=. ------------------------------------------------------------------------ Persistens/Biologisk nedbry-@.barhet: Dette stoffet er ikke lett biologisk nedbrytbart, men brytes delvis ned i '@ester for lett biologisk nedbrytbarhet. Dette produktet inneholder en eller flere organiske fluorkjemikalier som muligens ikke er nedbrytbare og forblir i miljeet (persistente). Okotoksikologiske data: Dette stoffet er minimalt mc/l < lav-q-- giftig overfor akvatiske organismer (100 Lab.ref.no.: 99312-4 Page 28 of3l FC-603EF LIGHT WATER (TM) ATC 3% AR-AFFF Andre skadev;---kninger, miljo: Data om b4-ologisk nedbrytbarhet: COD (Cne.".i4-cOaxlygen Demand): 740000 mg/kg; BOD 5 dage=s (Bi-ochem4-cal oxygen Demand): 216000 mg/kg; BOD 10 dagers: 376000 mg/kg; BOD 20 dagers: 446000 mg/kg; BOD 28 dagers: 602000 mg/kg. Akva-.isk gi-f-6ighe"@: 96 t;-mers EC50 for f4-sk (Fathead Minnow (Pimechales promelas)): > 1000 mg/l; 48 timers ECSO daphn--& (Water Flea (Daphnia-magna)): 480 mg/l; 30 m4-nu*-tersECSO M;-crotox: 124 mg/l;. 24 timers.ECSO Alge (Selenastrum capricornu-,um)): 170 mg/l. Beha-idl;-ngi renseanlegg: 3 timers 7-C50, Activated mg/l. Sludge Res.airati-onln*@;-bi-ti-o>n: 1000 Sorg --o-a-v4,al.lshindteri-igiht. gjeldende forskri-fter. -----------:------------------------------------------------------------13 Fj7-.l-NlNG;V KJZ,41'<ALI 7-AVFAr.L. ------------------------------------------------------------------------ metoder for fjerni-ng av kjemikalieavfal-l-: Spes;-alav!all.Lever avfall til en O'.fentliggodkjent innsamler, mottaks- el-le@-b-ehandlingsanlegg for spesialav-fall. Anbefalte av.1alIsgrupper: tiOVEDY-:kT7-GORI 07: AVFALL FRA ORGALNISK-= PROSESS'@-R. UNDE.RKKTEGORI 07 06: Avfall fra PBDB av fetts@-o@s.4er,sipe, rengjori-ngdmidler, desinfeksjonsm'@dler og kos-,ne,.;-kk. EAK-kode 07 06 03: Halogen-erte arganiske lose-a;-dler,vaskevasker og moderlut. Av!allstof@znummer: 7151 Organisk av&'all med halogen. Spes;-elle komponenter: inneholder fluarforb;-ndeiser. -----------------------------------------------------------------------14 OPPLYSNTNGER OM TRANSPORT. ----------:------------------------------------------------------------- ADR-klasse: siffer: Lab.ref.no.: 99312-4 Page29 of31 FC-603EF LIGHT WATER (TX) ATC 3% AR-AFFY bokstav: margnurrmer: UN-nu.=er: ZCAO-klasse: TMOG-klasse: ZMDG-s;-de: MFAG: evri-Se opplysninger: !!c.'Kterans-oartf-arli-ggods. ------------------------------------------------------------------------15 OPPLYSN@@NGER OM LOV---R OG FORSXRIFTER. ------------------------------------------------------------------------ Symbol(er): F.'-77-SES'.<-ADELI(GXn) inneholdez: Etylenglykol 22,5 %, 2-(2-butoksyetoksy)-etanol 10 R-se@.-n;-nger: Farli-g ved svelgi-ng. S-setn;-nger: Unng& inn&nding av damp/ sproytetike. Uancli kontakt med huden og ey-,iene.rhr man stof fet i eynene; skyll straks grundig med store mengder vann og kontakt lege. Fkr man s-@off p& huden, vaskes straks med store mengder sipe og vann. Ved svelging, kontakt lege omg&ende og vis denne beholderen eller etiketten. YL-gruppe: 00 Korr. yrkeshyg. luftbehov: Ovrige opplysninger om merkeetiketten: Ovennevnte merking er basert p& tidligere merkeforskrifter og vil Lab.ref.no.: 99312-4 Page30of31 FC-603Er LIGHT WATER (TM) ATC 3% AR-AFFF rev;-dertemerkeforskrifter av januar 1998. S".bol-: Ingen -7-neholder:1,2-etandi-ol,2-(2-butoksyetoksy)-etanol, Tri-etanolam;-n Kan vere farli-gved svelging. Kan irritere oynene. Unng& inninding av de--im/sproytet&ke.Unngi kontakt med huden og eynene. F&r man sto,Lg-@lielo,ynene; sky!! straks grundig med store mengder vann og kontakz lege. Flr man stof.1pi huden, vaskes straks med store mengder s&pe og vann. ved svelging, kontakt lege cmg&ende og vi-s denne beholderen eller etiketten. YL-gruooe: 00 Soes;---l-lleover og bes@@emmelser: 1. Forskri-ftom utarbeidelse og d4-stribusjonav Helse-, Miljo- og Si-kkerhe-,sdatabladfor farlige kjemikaii-er. 2. Fors.*<ri-.o9m6tklass;-44iseringog merk;-ng av farl;-ge kjem;-kaii-er. 3. Fors<=-;-.Iotm klassi-fi-sering,merking m.v. av stoff som kan med---orem--ljofa=e. 4. Fors'<rift om sto-z@zkar-@atek. 5. 7orskri-4-6om spes@-*.alav-gall. ------------------------------------------------------------------------16 Ai4DRT-OF?--YSN-,-NGER AV B-7TYDNING FOR BRUK7-RNT-S SIK.-<7-RHET OG HELSE. ------------------------------------------------------------------------ Anvendelsesom--Ader: F;-'-Mdannendeskumkonsentrat for slukk4-ng av brann. Vikt;-gstek;-I-de(r)ved utarbe4.delsen av HMS-databladet: Da.tabladfra-3M General Offices, St. Paul, mi-nneso-4, USA. L-sak til ocadater;ng: Hele da@.abladet er revider-@. Tilpasset nye merke- og HMS-databladforskri-4ter, fas-@satti januar 1998. Etc. Egne opplysninger: informasjonen p& de-.te HMS-databladet er i henhold til v&re nlvarende opplysni-ngerog beste oppfatn;-ng anghende rikt;-gbruk og h&ndteringen av det,.eproduktet under normale forhold. Enhver bruk av produktet som ikke er i samsvar med dette HMS-databladet, eller som'medforer bruk av produktet i kombinasjon med andre produkter eller enhver annen prosess er brukerens ansvar. Lab.refno.: 99312-4 Page31 of31 FC-603EF LIGHT WATER (TM) ATC 31 AR-AFFF FOLGENDE PRODUKTER DEXK=-'S AV DETTE HMS-DATABLADET: 3M ID-nr. X.7-0008-0223-1 3,m AFFF/ATC FC-6032F ingsskum Produksjon Brannslukn 3M ID-nr. X:'-0008-0209-0 3,4Light Water3/3%ArFr/ATc Fire Fighting Foam, FC-603EF,1000 L 3M ID-ar. XF-0008-0208-2 3,4 Light Water3/3%ArrF/ATc Fire Fighting Foam, FC-603EF, 200 L 3M ID-nr. X'-:'-0008-0207-4 3M L4-ght Wate--3/3%AFFF/ATC F,'-ght;ngFoam, FC-603EF, Fire 20 L