Document 7O54vpjOYEEy2Y3MZyEMREY0j

Shell Oil Company Shell Chemical Company Interoffice Memorandum JUNE 29, 1987 FROM: J.E. BARTON, INDUSTRIAL HYGIENE ASSISTANT, HEALTH & SAFETY DEER PARK MANUFACTURING COMPLEX TO: J.W. OVERMAN, PROCESS MANAGER CAT CRACKING & GAS DEER PARK MANUFACTURING COMPLEX SUBJECT: MONITORING RESULTS FOR INORGANIC LEAD AND HEXAVALENT CHROMIUM DURING ABRASIVE BLASTING AT CC&G Attached are Industrial Hygiene monitoring results for total dust, inorganic lead and hexavalent chromium which were collected downwind of the abrasive blasting at the Cat Cracker and Gas Fractionator Units. The sampling results may be compared to the following exposure guidelines: Eight-hour time-weighted average Inorganic Lead Hexavalent Chromium Total Dust 0.05 mg/m3 0.05 mg/m3 10.0 mg/m3 One personnel sample wascollected on the CCU Compressor Operator to evaluate exposure potential to personnel working in the vicinity of the abrasive blasting area. The compressor operator was monitored because it was primarily the compressor area being affected by the abrasive blasting at this time. All of the area samples were positioned within 1-5 feet of the barricade tape which identified the abrasive blasting area. All of the area sampling results received to date are below the exposure guidelines for inorganic lead, hexavalent chromium and total dust. The results of both area and personnel monitoring should be posted in an aria accessible to the personnel who work in the Cat Cracking and Gas Fractionator areas. Your cooperation with Industrial Hygiene in establishing and following requirements relative to the abrasive blasting is appreciated. If you have any questions regarding these monitoring results please call me at 7342. ^^J.E. Barton Attachment CHBT8718104 LAM 006137 DPMC-18019 cc: W.B. Austin A.F. Schmit P.M. Spicer T.A. Roberts R. Snodgrass JEB Chron ECB Satellite CHBT8718104 LAM 006138 DPMC-18020 MONITORING RESULTS FORM in d ica te s th a t the sample re s u lt is a measure o f the e ig h t-h o u r tim e-weighted average exposure, in d ic a te s th a t a re s p ira to r was worn during the sampling period. Q_ CO Cd * ZD <c ii -00 I3--: X *T3 ro <D X3 r--~ c to #0 4- a> <o 4- SZ .* O 4-> to U> L- ** i- COO CD C o O 4-> CO ad o I-- c Cd C **" to O r-- to CL C to LU 4-> CD <X> r- QJ X to C L- 13 CL O cd O fO **" aero i- LU r- aE O CL Q_ T- o t- O. O Cd O a. u >> O <0 C to Cd >*0 4- <0 to o o to to LaU: az:. 1- a> O - O "O to +> 1-- S- *r- +-> c tV r Q. tO 4S- -f- <D X E +J *" -Q (0 L- 3 O DC C CL A3 O O to oCJ> UJ o JCl O-- Z^ C\J <squ:jms to a. --- ao: co ( II cd ca o o cOn' rheo---O=0h>OO0LmUU-*Z1J-O0 to h_J ZD to LU Cd ii CD e O LU C5<QU c to aO: tJu Z--^z:Oto CD __I * O LU to o<C CD Oo CL * s; o LU Z to to LU O o a: Q_ CO o o o ou -H CO o *- r>. CO I tco\ i <a: Q_ LAM 006139 DPMC-18021 H icxo H CrocO C\J 00 to G Q. CO Q 13 "CO H- oo: to oa: LU O -QZJ- Omo: Z^- <UJE OO Q. w =Z> o 0) o "O <0 0 o to u r* U a> ft) 00 u > IA tA C IA -H 10 f-- C <u ft) -P W XI to 0 0) 0 0J 10 *- a) s. C U X 4-> S- . ^3 if)-Oo) +> <oo0 O Eoow QO"_- QO't-.X*?0 XI co u o. c o CO Z> -C O 4-> C0 O 1.0 0) r-~ O. I *4- 000 ! jCD <4- CD C 0 c a; o i~ o O *" X *- r-- U w *4- 4-> O 2 e -t-> > 01 (A t- c E <0 oc o1- <--10 O > O. CO CO -- O- 2 O. O to o O A. C0 4-> X5 *0 T3 0 CO C 03 O lA C 5 1- 4- XOO 0) O O S- -- jO O S- U -r- 0 rH Q. 3 to 4-> Q. O 4-> C CO (A <A C ft) X Q) ___ - T5t-I- oat# 0)00 i-Ol(J -4-> 3) 3 Q-->- 10 -o 0)0 O' o V- oc*c--oai I *1-0 r-- 2 T3 *4- T3 X) O. C O C "O 0) 3 10 CO 4) 0) r-- c-- X 4-> -O CL+J 4- V) E 014) 3 O CO tA 0 0) /> 0 Oc-- C If) <4- .-- 4/1 01 1 "O E -c co tA CD +-> U X CO C. OJ C- r--`1- O CD 0 -O O E S- U 4- -4J C O S- D. O 4-> <0 = *-- O CD a. (0 C *-- CD 0) -co "O _ Os t CIA -- 0) T3 -r- O 4-> 4-> (C O "O 0)2 S- 4D*4- S- <-> c 3 Or- 4-> D) 40 2 O 4- C C 4-> o -o00 <)-Cn- O 3 O <4- O <- CD >, 4-> C U T3 *4- >4- 4-> 0)0)4-0)0)000) 1-- <D *-> > -4-> 0) 0-<4- O) 0 C 4-> -4-> <4- AU3WVI Or-- 0)0400)0 i/iir j3d:e o) 2<-< to r-~ 0 *o3* CM CVJ CO CO MONITORING RESULTS FORM O to LU I II \ O IfcC I-- OLiJ lx! OEl CoO Oi -- t/> -- z IODDhO "-OC3-J o to 00 CVJ -- I II ^oEr <OOLU <a: to CoD: <tut *z-o Z in O --I O -J o t<o o CD oo a. o UJ z to to oocUcJ o_ 00 C\1 O tr> 0 r-H O 0"1 to 0^ 00 to CM 1 to c z <C fO a. O) s< r>* 1* rH O O O V CO to CO 0 *0-H t*--oH r00 to CM to CO a> sc 0 CO 0 0 to to to --c 0^ to O -H f**x 001 CM 1 to LAM 006140 DPMC-18022 CO a; u < o r-H CO tH r^ 00 C3D CJ MONITORING RESULTS FORM CHBT8718107 CO c to CC Q_ to *aDCci c3 'CO I-- ex to ex o UJ o JOa.cOI--a n2^: C UJ to D_ *-- oXu CL o to a. t- o> to </> o oc (/> 'P" <D tn t- cn S E 41 3 C o "O O i- "O f- o c "O o CL -4-> a; s- E E tn 4-> * 4o<u->c *--ou Ou M- wo <4+J --<0 ^ -- 4-> O tO 0J to C t/> o oC "O'"* 0J co P-- u CL E Z3 -- > S- CL-r- qj in CO (O S- QJ u f+-j <U0 a> 4*oa4-->) aio*--O>; < otn^tO O O C -O CLO -- (O O O t/> to coo CSJ coOcO I II CD Oo CT ^hOUJ --D-DtODMwZO o-- O CD --J CO UJ (X M | || 0> c 0O<QwZ e to CX LU CD ` tO D-JC3-JC CO C\J CO oCSJ o OCOO tOtoo tco CO I cd oo C O CNtJ to 02E. O* to to ooUJ cx CL <ac: a. <<0v UoJ < LAM 006141 DPMC-18023 CL CO LU cl CL 'Z <c i3 '00 h- c CO ol OC CO CL o ZD 4o 44->0 053 "+aO>> TUO o O) o. E C<O0 LU CO z4a->> Co EOo&. p_ o +uJ c oo +J Qj 40-3 03 -o to u o(L0O CLD- Cl Eoo 4o Lact o u r-H Xo wLTO (0 o>> to TLO. X) TO QtQo.-. *Oc30 J+0O->> EC ai-m- 44oT-O-> OJ > o *a. xj (0 o 0Q3. TO 1 C or-- 4-> TSO0o3. o c 44T-O>0 X3 +-> oC>D 4o i LO X osoo.. TO ouj l_ oto 4o -o c *r~ 5 c 5 ToD OCO co CT/OD> oE oS- 44<a-D-> X oL- <D u u CCTOLL o3to 4Co-D> 4O TO u U O cf-- Q. r--CD CL 3 4U ETO CO 03 40-) OL- f-- r 4TC-O>O 4- oS4-> cou O cr* o 4- rTc"O 4-/>) o J4-Z> 3 O40 o C a> <4-> C 03 CEfL cr 0J *o TcO X oL. CL a. TO 1 o 404->0) fT--O *CoD TCrO-J LU TO X) 03 *T4o"0 Cr- LO cf* 4-> X to U oL- TO C>D CLJ3 CL TO 4- OCJ 0) "O O -40-3> TD C TCOJ ro-- 0J *c x3o>e Q. 4-> QC to TO +> TO <ULD- TEO CO 03 OJ 4- O430 40U3 C 3O z w +o-> TO c o TULO- 4O tMo TQOJ TEO 0) s : 4-> (A Co 4- 4-> O 0J +-> 4o-> to 03 -C 4S->- iH * o *wc' "e ooi- to c 4TO- os- 4-> C 4- ooc * 0a3 ToO SL-TO "O0tro34-> 3O c LU CD -u O- M-< Z z e: <UJZ CD o TO" r- o CSJ CSJ CO CO CO Q- ' MONITORING RESULTS FORM ac CO LU I II o uu E C h Q UJ CD co z O DOOM - O CD -I O CO ZD CO <o Z -E I II LxJ Z O LU E *- Z CO tf a d *-h id X I CD J O LU UJ Csj LO o o o LO O *"H O vo H COI c VO CO c o CSIJ CD VO o a. zo CO CO LU CL CL LU cz z <CcL CL LU csTaO>- CO 00 CO oo o S/ 00 cn CO O VO CO LO CSJ 1 LO LO o V cr> in LO i--* LO o - ooi CSiJ LO LAM 006142 oo TO TO DPMC-18024 CO <uD <c cou> CzO MONITORING RESULTS FORM CHBT8718107 LO OO Cd C OCM OO a: c i3 'CO I-- a: o oo Ui o a: o 7 UJ o JO^ O- -- z Z a: m < lu S ooa --' ZD o s- O CJ c 4-> L- U < 4-) O O r~ to O o. a> 4-> -- -M > CA 4> U IA UJ -O *r- c a> a> 0J OO O IA ov+j .c <o f-- CO c (A U +JO IO o o -O ro m r4J c. <o C- i 4-> E o a> C O lA CD Cl X H- O O (A C o o o O u QJ r" s- r-- s- u cn Cl-u a. 3 C CL c o o B 'O 0 1-- w o -t->--' s Q.4-> o E /) c EC C (0 => 2 C O H- O <-- o o OO o O <4- -O <_> T3 o CO CM ad o OO ro t ii cn _ uj e cthDW CO D-OOhZO o " DD=>t-< -QC5-IO OO ZD oo a> co => ii --^ ___*--* uj a> eCSIOUJ c :> o*-z oo < QC ZD --I tD xia_io Jj o U0 o o o V oo CO --< in UJ co CO i <c <c o o CM I o in o Q- r: o oo oo UJ CD o Od CL Cd c ro CL a> s- < LAM 006143 DPMC-18025 MONITORING RESULTS FORM l/> LU DC oc ^-zc c i-H I 3 '--CO H- 0 a> O E P 0 o> 0 p to "OTO C0 TO O O 00 O 0) O) LO C r-- <4- <4- LU to u TO s_ tf- * P ?o-o O <4- p TOo O OO X 0) 0 X 00 L. TO O TO TO&- s- 1 0 0 S- r*-- O O TO TO -P +-> TOQ. P 0) 0 0 J- > </> .3 (/) t-H r- C -P to fc- S- *r- O CHi-h Q. 3 TO s- 3 S- f-- > c </) P Q..O O 3 TO </) H-- to 4-> in JO (/) O 0) to Q. O 4-> 4-> *r- CL O O TO TO O TO oc * to TO r- TO S~ TO t/> </> 3 to X TO TO <u z: * - *0 o TO3 s- X P J- +-> <f- 3 O X3 O "O O OC E xr oo "O 0 CL O TO .3 TO 0 dh-h- TO S- TO "D TO +-> LU to E TO s- 0 in to 0 0 P O. (J TO 'O OO TO s- *r~ cn CL. 2: c in O >C oc o to r-* TO O 0 0-3 TO O. 1 <P 0 r--0 0 i- r-_ *4- O TO LE- 3 O ^P 00in0 S- o> "O o>4- 3 0 rT--O Oi- Q.-P TEO 3 O 1- 0 a> c 4+-- a>) i~ (0 0 O r- JQ 0 *-pi- TO Q. CTOO TO 1-- X 'r O? PC Q- 5 a. 0 => 3 CL-r- TO TO 0)0 TO TO U U O Cr- C" O r- 5 "O M- E Q. 1 _TSQO- TO 03 .3TO 0 f-- i-- .3 Cl -P -p c3r "OTO TO TO -<P/) "pO E TO TO -P TO (/) 3 O "CO rT-O CCO TO TO f2 0 0 +-> = rO- 3 +-> to ra >--1 c. = c' 0 O sTO to S- JD O nT--O "O a> *0r- +j c -- TO ns O "O O +J V) M- t- -r- Q.-P t- 0 -P CO E a> 3 <0 c 3 -P TO TO O l- C 1- O 3 OC OO O u am P XI TO XI (/) 4- 1-- in TO XJ *r- OO H- 01 O TO O c LU O Q- Z 2: oc *--1 <LJ2 00 CL. in 0 O C\J CSJ CO CO O OC co O OO aLU fO 1 II O) E ocxo> 0>cohlh(=/>)Qh=Lh> UZ- O QC5 JO 00 :z> 00 OC h- fo z 2: E JD 1 II O. J M U CD c21 QIZOLU E > O -- 2C 00 ct oc LO X ^ O --1 0 LU O XO LU s: 1-- LU 1-- ct <o00 O Oo o_ 2: o LO O O O V* LO O rH O o\ m 0 - r*'* CO 1 CO CSJ LO 00 00 LU OO OC Q_ <OC Q_ TTOO Q ss- CO in 0 0 0 sy 00 LO CO 0 0 VO 1--1 --H 00 1 VO CSJ in TTOO est- in 0 0 0 V in in in i-H OS LO . ' 00 1 r^. CSJ in ^W006^ DPMC-18026 TTOO ic- CO CO h-- CO ozc MONITORING RESULTS FORM (2) X in d ica te s th a t a re s p ira to r was worn during the sampling period. CL cnj oo CsL cn cr> ---'Z <c c j- f-- 1 3 r-- QJ l-- ---00 1-- 4-3 4-> c z to QJ 1-- lO *r- to S- o 4-> cr> UO 1 z 4-> C _C co o CD 4-> QJ co QJ c *- c ID -O Q to 1--i c QJ 3 QJ 4-3 i-- i- jd EC O *r- z i-h <D LU C CO C LlJ L f- O XJ LU S- QJ o "O 4-> Z -D Z QJ OO o Z 4-> Z cc OO 4- --4 QJ to O 4-> X to O co 1-- 4-> CD 4-3 C O QJ 4-> CD 4-> tO 4-3 - CD CL O a. 4- C CO *r- s- c (O Q. 4- C CO CO o c -a z a--1 a? O -r- CO CL 4-> O O - CD ID *r- O' -- oS 4J CL'r- TD "D 0 4-3 o C CO 4-3 4-3 o -- 3 to <u CO C 0) 3 to QJ *r- QJ to !-- oo UJ o oo orz to CJ 4-3 -- ro - -Q QJHOOh 4-> 4-3 3 CD U to S- C QJ CO QJ h- *r- f-- LU i-- Z 0) PZ <0 U 4-3 i-- QJ 00 - .O -- t-H O 4-3 LCJ 3 QJ "O r-- 4-> CO c U X f-- 3 0) O S-TJh -- ID C Z r-- O 1 -- o c r- h- -- acx a.DC CL 4- CNJ fC O O 4- cO o <4- t-H CO O Z O co o Q_ o Eo 00 u o S- CD u o to u o o co OO z 3- ro * c 4-> O C c <E to U X o QJ U - QJ S. X CD QJ 4- QJ z o to Q> o r- 0) XT4J t-- QJ O C -- O o CO C i- 4-> QJ CL C QJ 4-> tO ac s-t- o. 0.0 4-> QJ <c QJ U Q-r- C E S- C S- CO E l aL E "O E r- C UJ U O CL C O (O o C O f-- to O CL 3 co C (O M- C O cc ct U <C 3 -O Irt u< cn 00 U CO "O 00 0) OO O 3T3 UJ o -J o -- a. i-h z tD o 00 CNJ O'* saw 00 r**. 00 <LUS CNJ CNJ CNI CNJ CNJ OO Q- -- o LU O 00 oo cC I II LO UJ CD fl-OUJ E CD cd 00 - Z O E ZDDmO rO DO-J O t-H -- O 00 oc UJ O <n E Q. Z LU CD cC Q O LU E < LD <C -- Z oo KUDwiO D _1 O -1 O O O0 < LU CD z -- oS 1-- CD LU O k-- <C < c* Q CJ cC O o. zo Ul z 00 00 UJ CJ o DC CL CC CL UJ O ID O v/ f--H o o o V CNJ 00 CO O 00 CO O 1--1 f-* 00 1 CO CNJ 1 1--4 I4 QJ r-- CL E r0 tD ro OJ U c ID O V CO o o 1--t 1--1 ro w oo ro O f-H r*^ 00 i CO CNI I l-H <u Q. E ro to ro QJ U =t ID CO ID O t-H O N/ V l---4 o o o * V t--i ro o oo ro OH co 1 ro CNJ i 1--4 --4 QJ r-- CL E <0 OO ro QJ S< ID r--i r-* o f-H o oo > CO o CNJ r-- 00 co O f-H cnj r^ co o oo co oH r^ 00 co ii 00 CO CNJ CNJ 11 1--1 t--4 1--4 t-H LAM 0061 DPMC-18027 OJ f-- CL E ro OO 03 QJ J- QJ i-- Cl E ro OO ro a; u QJ U 3 to O CL X QJ QJ CD <o U QJ > CO "O QJ 4-> .c: CD rQJ OJ 4-3 u 3 O -C I OJ <D o OJ s3 to QJ r0 to 3 to CL) U QJ CL E CO to <D CO CO QJ +-> to CJ MONITORING RESULTS FORM Q_ CO LU OC ""----"ia0n0i: i3-- o D--.( QL O CO CO LU O zcQ_ a: o co cLcUn lu o _j o Q- --* Z S a:- <LJZ CO CL. --" o--H h" Z \E ZO Cn O. d*H i ii E 4--4 > s: lu a: <c O O LU IT) o XQ^mZO to XDh . ruouo CO o*3 CzD: cn to eC l-- O LU E 1-- 1-- OO t-- z _J 033i-i O :z> 1-- Q O _l to o LU p--4 QC tn LU LJ _I i-- E 1 II Q_ Z LU cn z ci o O LU E c CJ < M z to C LU ZD * in O --! C3 --1 o z 1--1 o LU coCO z t-- 1-- o<c LU h- oa: ct Q <c a. s: o -C S- <O4- -3O(M/) +-> +J ottoo X 0CL).L CoL.L to <0 B av to 5 "0 oB0 oo < 4-- o "O C +0->) s- O EC 3<C- foC ro- as>- 4o- sc 1--o 4uc-> r--aa>. oU Eto =o> CO o e +-> o OOi- rr--Qe. -O 4-> +<IO/>> 00) 4O a> </> ui +S<-U>- rr-ol .a -C s- 4O 4t-o> o3to co ottoo X C0sE-)L o CCLL 4- 0) 2 "D 4a->> tuO o <u oEO&_ r-- O*-> oCu OC O CJ "O <O4- E C!- C5 i- o c 0)4- 5 e +-> o UOS- i--rCol -O -+-> S40->) D. +->"0 4- to Etd o=> to o to (O0J a> to OLO to -Q to X rd L- otCL 4- CD +j -OrPo CL O to c ro TD -0o) *Cr- o tuio- -u*P- to 5c rOo- -5oO i--0) 4-> Q.4tEo o 3oto utSo.acr-> a>s>-> -tt4oo-> Oo> f-- 0) to in .o cc XoS- to oto i+o-> cm- +-> CL O to tco to "aO> -Cr- CCDJ 4orU" L. CJ 4-> tDo 5 C^ 3 Oto Ltsio.- r--o XoJ i--& 4-> 0.(4- cr> cf-- 4-> to >t-, d) o> cEtoo oin r--(0 X) <_> qo:j o o oo 1--l 1--4 CO CO CO CO CO CO to o o o V O" o 1 oo in o co ^r o *- r^co i p-H 1 to CO o 1--4 i--4 o o oo in o co <oO 1-H r*^ CO 1 11 1 to Lf> o o o V* CO o V o o o o V/ oo o CO ^3o f-H CO 1 1--4 1 to in --4 o 1 oo o CO ^3O 1-H CO 1 f--4 1 to to to LoU o cc Cl. LsU: LAM 006146 DPMC-18028 ro O) ci- ro cCLD. c<asd- re <sDc tOo i--H CNJ r*^ Cl--O 3C1O CU MONITORING RESULTS FORM CHBT87181C in 00 Q. < 00 < OH O Q00 UJ OH OH ct ^00 H- z o--* 1o----.1 QC o OOLUO o: oz LU O -Q2J1_ Oi-- O' Mz <uz OO CL'-' Co-> Sa? 1 4o 4<->/) cioo UJ +> r(--0 Q. <D "O >r- 4-> f0 in C a; (U L Q) 0) -<oD 4-> tn a ro-- r<--v E 00 00 oc oEoLr-- OLC 0 o 0) xto: V) so- Or* V4tJo 4J O (O U .4o0 1U0 in .rQ- oW Qi OO). X 4- t(uUo **cu-- o ou o cn cl*o o. a Eo "O cf (a0 c!-- 4->--- ^ u E& to (OD c 5 4--0 O 4- rX-UU "OO o0CN0J OH ro O 00 UJ n cn O LU E t KQUJ CD CD -I^mZO O E DDDf QO JO oo oo LU CH (*) JJ ZD I II ^ _j -- lu cn cflOliJ E C >O SH 00 aDMiD X 00 CD J o JU z o cr> 00 in o o d v oo CO f-H O in UJ oo oo c I-- c i r- CD o CVJ i o in O q. 21 O OO in LU O o or Q_ fTJ 0s>- < law 006147 DPMC-18029 MONITORING RESULTS FORM Oto cn <c t 3: '00 I-- -ma CD *o to c iD 4- 0) ro 3: O -C CO 4-> U ^ U C OO 1 c O <1) +-> CO cn o ocn h<- to cn *r-- to E <D to CL L cn cu r" CD X c S- 3 CL O r-- aero l UJ CL E <D CL Q- r-- O U Cl o a: ocn o LO tO CL CJ >, O to CD U to *0 4- <D to <d 0) 0 r- CD T3 4-> r-- S- *r- 4-> C <0 i-- CL to 4- UJ 0J X E cn CD s- 3 O 3 21D_ CL rO (D U O w oO UJ o --J o --* Q.MZ s: *-< OJ <us: to Q- CJ> CO 1 11 cn r UJ E <h-QUJ oCQ LO ^ Z O ODD*-' '"D (-a jo to UJ cn 1 11 cn e Q UJ E CD C O UJ < cn uj --1 2: to to O --I 13 *-H O CD --I * O c Q CD O CJ CooO O CM r-H CO r- *3O i"* r^. 00 1 to C\J I to t0o0 UJ Oocr: a. <U2cJ: <a: Q_ o au> ZJ CoO Q- X0) a> O) *uD Q) > n3 Xa3> cr> (D ctu E S- -D aO O -r-C S- I <D +-> CL -C cn cn r** C CL) - <D CL -C E P <0 to otf- <u -C uCD +-> 3 cn CO c. rO *rCD U E =3 "O ca c to Sr- O 1-- CO =3 ro cn 2 <L> s- os- CD +-> I-- 03 a- sE r0 Q. to to <d CD Sx: 4-> <D +J 4-> fD 03 LAM 006148 to to a) qj -4-> 4-> <D n3 UU r- 't-- TD ~0 CC DPMC-1B030 00 r-C0