Document 7M9pXzdMrZxaDneD2ReXRJxo

F-233* |NI ROYAL, Inc. 1230 (Location) J.M. Poynter ^^punesville Plant April 18, 1969 &*) j* With reference to our telephone conversation of April 14th, the Institute of Industrial Health, The University of Michigan, just released J** its confidential report to the Occupational Health Committee of the Manu facturing Chemists1 Association entitled "Epidemiological Investigation of the Polyvinyl Chloride Industry in Reference to Occupational Acroosteolysis. The over 5,000 subjects of this study were employed by 19 corporations, including 32 plants in the United States and Canada which are involved in the production of PVC resins and/or compounding and fabricating operations . involving these resins. MCA will hold a meeting of representatives of these companies on May 6, 1969 to discuss the findings of this study. I will represent UNIROYAL at this meeting. Also, a member of the Institute of Industrial Health will give a paper on this study this month at the annual American Industrial Health Conference, and next month at the annual American Industrial Hygiene Conference, to acquaint the interested scientific com munities with the findings. As you are well aware, UNIROYAL was a participant in this study and, fortunately, no cases of acroosteolysis were found among our. studied employees. Enclosed is a copy of this report, a copy of the letter which accompanied it and a copy of the letter announcing the May 6, 1969 MCA meeting. Dr. Fletcher will be interested in reviewing the report. For reasons explained in this detailed and somewhat lengthy report, it will be necessary to (1) minimize the exposure of employees in volved in the hand cleaning of reactors, and (2) continue regular periodic medical surveillance of these same employees. cc: Messrs. F.A. Hopkins G.A. Anderson W.E. Fletcher R.E. Lowell INTERCOMPANY CORRESPONDENCE UNIR0002169 A BIBLIOGRAPHY ON VINYL CHLORIDE Prepared by the Office of Occupational Health Surveillance and Biometrics and Office of Research and Standards Development National Institute for Occupational Safety and Health February 28, 1974 / UNIR0002075 H-iy, 222 ACG1H'! Docl^etfta^Jfee^sKoTij- 'Limit.V&luds 'for Substances in 210 Albright, L.F.: Vinyl Chloride Processes. Chem Eng 74:123-130, 1967 211 Albright, L. F.: Manufacture of-Vinyl Chloride. Chem Eng 74:219-226, 212 Albright, L.F.-: Polymerization of Vinyl Chloride. Chem Eng 74:151-153, 1967 ^ -*,? i . . ' 213 Albright, L.F.: Vinyl Chloride Polymerization by Suspension Process Yields Polyvinyl Chloride Resins. Chem Eng 74:145-152, 1967 214 Albright, L.F.: Vinyl Chloride Polymerization by Emulsion, Bulk . and Solution Processes. Chem Eng 74:85-92, 1967 220 Ambrosi, L., Rantuccio, F. and Armeli, G.: Skin Hazards and Their Prevention in Various Plastics Industries. Atti del Symposium Sulla Prevenzione Delle Dermatosi Professional! Conf. Paper pp.275-293, 1970 156 Anghelescu, F. et al: Clinico-Pathogenic Considerations of Raynaud's Phenomenon in the Employees of Polyvinyl Chloride Industry. Medicina Interna 21(4):473-482, 1969 178 Anon: Vinyl Chloride Survey Starts. Chemecology p.5, Aug 1973 032 Antonyuzhenko, V.A.: Professional Intoxication with Vinylchloride. Gig Truda 12(3):50-52, 1968 176 Antonyuzhenko, V.A., Golova, I.A. and Alieva, N.K.: The State of the Analysors Function in Chronic Occupational Poisoning with Some Narcotic Substances. Gig Truda 9:19-22, 1972 181 Arena, J.M.: Vinyl Chloride Poisoning; Toxicology...Symptoms... Treatment (BOOK) 2nd ed, Charles C. Thomas, Springfield, 111. pp.676249, 1970 088 Autian, J.: Toxicity, Untoward Reactions, and Related Considerations in the Medical Use of Plastics. 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Biochem J 114(1):6p-7p^ 1969 130 Clayson, D.B.: Chemical Carcinogenesis(BOOK). pp.101-112, 1962 126 Cook, W.A., Giever, P.M., Dinman, B.D. and Magnuson, H.J.: Occupational Acroosteolysis II. An Industrial Hygiene Study, Arch Env Health 22(1):74-82, 1971 077 Cylwik, B.: Histological and Histochemical Changes in liver During Experimental Poly (vinyl chloride) Pneumoconiosis. Rocz Akad Med Bialymstoku 17:93-111, 1972 208 D'yachuk, I.A.: A Contribution to the Hygienic Evaluation of PVC Floor Tiles for'Apartments. Hyg and Sanit 35(3):424-7, 1970 198 Danziger, H.: Accidental Poisoning by Vinyl Chloride. Can Med Assoc J 82(16):828-830, 1960 UNIR0002077 ;133;^` ''Deesey-^DiE.''and Joyner, R.E.: Vinyl Acetate: A Study of Chronic Human rr.. .* . ' Exposure. AXHAJ 30:449-457, 1969 058 Dehaan, R.L.: Toxicity of Tissue Culture Media Exposed to Polyvinyl Chloride Plastic. Nature(London), New Biol 231(20):85- . . r 86, 1971 184- - 125 - Deichmann,-W-.3.: Toxicology of._Drugs and Chemicals 4th_ed(B00K) Academic Press New York pp620-l, 1969 / - . W*v Dinman. B.D*.y>Cook, W.A.', Whitehouse, W.M., Magnuson, H.J. and Ditcheck, T.: Occupational Acroosteolysis I. An Epidemiological Study. Arch Env Health 22(l):6I-73, 1971 127 Dodson, V.N., Dinman, B.D.', Whitehouse, W.M., Nasr, A.N.M and Magnuson, H.J*: Occupational Acroosteolysis III. A Clinical Study. Arch Env Health 22(1):83-91, 1971 086 Fabiszewska-Gorna D., Kozakiewicz, A.: Plastic in Opthamology: I. General Characteristics of Plastics. Klin Oczna, 41(5):747-751, 1971 185 Fairhall, L.T.: Industrial Toxicology 2nd ed(BOOK) Hafner Publishing Co New York pp356-7, 1969 143 Filatova, V.S.: The Hygienic Evaluation of New Technological Processes in the Chemical Industry. Labor Hyg and Occ Diseases 11:1-6, 1966 151 Filatova, V.S. and Antonyuzhenko, V.A.: Hygienic Conditions of Work and Occupational Disease Incidence Among Workers Engaged in Production of Suspension Polyvinyl Chloride Reviewed Dynamically for a Number of Years. Gig Truda 4:32-34, 1971 157 Filatova, V.S. et al: Occupational Hygiene and Health Condition of Workers Engaged in the Production of Latex Polyvinyl Chloride. Gig Truda 8:9-14, 1965 202 Filatova, V.S. and Gronsberg, E.Sh.: Sanitary-Hygienic Conditions of Work in the Production of Polychlorvinylic Tar PVC and'Measures of Improvement. Gig Sanit 1:38-42, 1957 154 Fregert, S. and Rorsman, R.: Hypersensitivity to Epoxy Resins Used as Plasticizers and Stabilizers in Polyvinyl Chloride(PVC) Resins. Acta Dermato-Venereologica 43:10-13, 1953 162 Gabor, S. et al: Comments on the Biochemical Alterations in Workers of the Vinyl Chloride Synthesis and Polvmerization Industry, Igiena 13(5):409-lS, 1964 UNIR0002078 *<Ol33.V ry .sW*-.'058 ... t 184 I 125 ,v 127 086 185 143 151 157 202 154 162 Deese, D.E. and Joyner, R.E.: Vinyl Acetate: A Study of Chronic Human;Exposure. AIHAJ 30:449-457, 1969 Debaan, R.L.: Toxicity of Tissue Culture Media Exposed to Polyvinyl Chloride Plastic. Nature(London), New Biol 231 (20) :85-;/! 86, 1971 Deichmann, W.B.: Toxicology of Drugs and Chemicals 4th ed(BOOK) Academic Press New York pp620-1_, 1969 Dinman, B.D., Cook, W.A., Whitehouse, W.M., Magnuson, H.J. and Ditcheck, . T.: Occupational Acroosteolysis I. An Epidemiological Study. . Arch Env.'Health 22(l):61-73, 1971 Dodson, V.N., Dinman, B.D., Whitehouse, W.M., Nasr, A.N.M and Magnuson, H.J.: Occupational Acroosteolysis III. A Clinical Study. Arch Env Health 22(1):83-91, 1971 Fabiszewska-Gorna D., Kozakiewicz, A.: Plastic in Opthamology: I. General Characteristics of Plastics. Klin Oczna, 41(5):747-751, 1971 Fairhall, L.T.: Industrial Toxicology 2nd ed(BOOK) Hafner Publishing Co New York pp356-7, 1969 Filatova, V.S.: The Hygienic Evaluation* of New Technological Processes in the Chemical Industry. Labor Hyg and Occ Diseases 11:1-6, 1966 Filatova, V.S. and Antqnyuzhenko, V.A.: Hygienic Conditions of Work and Occupational Disease Incidence Among Workers Engaged in Production of Suspension Polyvinyl Chloride Reviewed Dynamically for a Number of Years. Gig Truda 4:32-34, 1971 Filatova, V.S. et al: Occupational Hygiene and Health Condition of Workers Engaged in the Production of Latex Polyvinyl Chloride. Truda 8:9-14, 1965 Gig Filatova, V.S. and Gronsberg, E.Sh,: Sanitary-Hygienic Conditions of Work in the Production of Polychiorvinylic Tar FVC and Measures of Improvement. Gig Sanit 1:38-42, 1957 Fregert, S. and Rorsman, H.: Hypersensitivity to Epoxy Resins Used as Plasticizers and Stabilizers in Polyvinyl Chloride(PVC) Resins . Acta Dermato-Venereologica 43:10-13, 1963 Gabor, S. et al: Comments on the Biochemical Alterations in Workers of the Vinyl Chloride Synthesis and Polymerization Industry. Igiena 13(5):409-18, 1964 UNIR0002079 sl52v'F 146 112 186 110 096 201 231 117 119 103 149 192 009 MGage,'J.C.: The.Subacute Inhalation Toxicity of 109 Industrial Chemicals. Br J Ind Med 27:1-18, 1970 Gallant, R.W.: Physical Properties of Hydrocarbons. Hydrocarbon Processing & Petroleum Refiner 45(6):153-60, 1966 L'*' Gavruseyko. O.M. and Filatova, V.S.: Hygienic Evaluation of __ Certain Types of Drying Units Used in the Chemical Industry. -Gig frida'1:32-39, 1959 Genkina, T.I., et al: The Evaluation of Harmful Substances from Some Polyvinyl Chloride Floor Coverings. Sb Tr Vses Nauch-Iss Inst Nov Stroit 14:13, 1966 Gleason, M.N., Gosselin, R.E..^.Hodge, H.C. and Smith, R.P. :Clinical Toxicology of Commercial Products(BOOK), The Williams and Wilkins Co., Baltimore, p.151, 1969 Gohlke, R. and Springer, E.: Toxicological--Ristochemical Investigation of Some PVC Stabilizers. Ztschr f dig Hyg u ihre Grezgebeite 11:437, 1965 Grigorescu, I. and Toba, Ch.: Vinyl Chloride; Industrial Toxicologic Aspects. Rev Chim 17(8):499-501 Gronsberg, E.Sh.: Determination of Vinyl Chloride in Air. Gig Sanit 11:43-44, 1954 Gronsberg, E.Sh.: Colorimetric Determination of Vinyl Chloride In Air. Rimieeskaja Promyslennost 42(7)30-31, 1966 Guess, W.L et al: Characteristics of Subtle Toxicity of Certain Plastic Components Uses in Manufacture of Polyvinyls. C.A. 68:20560q, 1968 Guess, W.L. and Haberman, S.: Toxicity Profiles of Vinyl and Polyolefinic Plastics and Their Additives. Tech Pap Reg Tech Conf Soc Plast Eng, NY Sec, 1967: C.A. 68:1706a, 1968 Harris, D.K.: Some Hazards in the Manufacture and Use of Plastics. Br J Ind Med 16:221, 1959 Harris. D.K.: Health Problems in the Manufacture and Use of Plastics. Br J Ind Med 10:255-268, 1953 Harris, D.K. and Adams, W.G.F.: Acro-osteolysis Occurring in Men Engaged in the Polymerization of Vinyl Chloride. Br Med J 5567:712-4, 1967 Horn, K-H., Pasternak, G. and Graffi, A.: Experiments on the Induction of Tumor-Specific Resistance Against Isologous Transplant of UNIR0002080 \J -\l" -%i;<? Sarcomas Induced by Implantation of Plastic Pellets* Archivon Immunelogiae et Therapiae Experimentails 14(6):737-742, 1966. .-> ^'X32 ^ -Ti.' `Hotta, J.DaS. Abbatt, J.D. liotta, L, Cayolla da, and Roriz, M.L.: Lancet 2:201-205, 1965 217 Hueg, W.C.: Occ & Environ Cancer of Urinary System I2T 216 027 Hueper, W7C." and Conway, W.D.: Chemical Carcinogenesis and Cancers(BOOK). Charles C. Thomas, Springfield, Mass. pp.353-365, 1964 _ " .a' Hunter, D: The Diseases of Occupations(BOOK), Little Brown & Co,, Boston, 1969 pp.578-642. - -^ Jaeger, R.J. and Rubin, R.J.: Migration of a Phthalate Ester Plasticizer from Polyvinyl Chloride Blood Bags Into Stored Human Tissues. NE J Med 287(22):1114-1118, 1972 021 Jensen, S., Jernelov, A., Lange, R., and Palmork, K.H.: Chlorinated ByProducts from Vinyl Chloride Production a New Source of Marine Pollution. FA0 (Food Agric Organ U.N.) Fish Rep 99:170, 1971 139. Juhe, S., Lange, C.E. Stein, G and Veltman, G: Deutsche Medizinische Wechenschrif t, 197 2 147 Kalfmanovich, F.L.: Sanitary-Chemical Characteristics of Polyvinyl Chloride Floor Coatings. Hyg and Sanit 33(2):274-280, 1968 135 Key, M.M.: Occupational Dermatitis from Plastics. JMA Georgia 57:421425, 1968 004 Kogan, A.K. and Tugarinova, V.N.: On The Blastomogenic Action of Polyvinyl Chloride. Vop Gnkol 5:540-545, 1959 006 Kogan, A.K, and Raikhlin, N.T.: Dynamics of Morphological Changes in the Connective Tissue Capsules Developing Around the Plastic Implants During the Malignization Process. Arkh Path 23(12):62-68. 1961 163 Kotulski, B.: Characteristics and Treatment of Waste Waters from Production of Vinyl Resins. Gaz Woda 38(10) :336-339, 1964 025 Kramer, C.G. and Mutchler, J.E.: The Correlation of Clinical and Environmental Measurements for Workers Exposed to Vinyl Chloride. AIHAJ 33(1):19-30, 1972 189 Lefauz, R.: Practical Toxicology of Plastics (BOOK) . CRC Press, Cleveland, Ohio pp8i-3, 1968 UNIR0002081 ro; s^-\ * - 7V i-*jr Leong. B.K.fee/Repeated Inhalation of Vinyl Brcmifl^in^aboratnry^^niinals with Reconunendations for Industrial'j~ lcingiv^AIHAJ "31:1-11, 1970 092 Lester, D., Greenberg, L.A* and Adams, W.R.: Effects of Single and Repeated Exposures of Humans and Rats to Vinyl Chloride* AIHAJ 24(3):265^27.Sj^ta63;k* . 134 A 190 Lewis, C.E. and Kerby, G.R.: An Epidemic of Polymer-Fume Fever, 191(5):375-3783965 ^/M.-sV- ' /V\C'*^ `4 . Little, K,: .VWhat's in PVC? Lancet 7563:351-2, 1968 JAMA 024 Markowitz, S.S., McDonald, C.J.. Fethiere, W. and Kerzner, M.S.: Occupational Acroosteolysis. Arch Derm 106(8):219-223, 1972 0S0 Mastromatteo, E., Fisher, A.M., Christie, H. and Danziger, H.: Acute . Inhalation Toxicity of Vinyl Chloride to Laboratory Animals. AIHAJ 21(5):394-398, 1960 206 McDonald, R.A., Shroder, S.A. and Stull, D.R.: Vapor Pressures of Freezing of 30 Organics. J Chem Eng Data 4(4):311-313, 1959 209 Meshkova, O.V., Dmitrieva, V.N. and Bezugly, V.D.: Polarographic Analysis of Waste Waters of Polyvinyl Chloride Production. The Soviet Chem Industry 47(4):252-5, 1971 240 Meyerson. L.B. and Meier, G.C.: Cutaneous Lesions in Acroosteolysis. Arch Derm 106(2):224-227, 1972 089 Morris, G.E.: Vinyl Plastics: Their Dermatological and Chemical Aspects. Arch I H & Occ Med 8:535-539, 1953 205 Morris, H.E.: Integrated Pollution Control. Petroleum Refiner 33(12):229-31, 1954 199 Nitti, G,, Petruzzellis, V. and Fasano, V.: Rheographic Observations Among Workers in The Plastics Industry. Securitas 55(8):683-694, 1970 123 O'Conner, R.B. and McCord*, C.P.: A New Occupational Disease is Born. JOM 12:234, 1970 141 O'Mars, M.M., Crider, L.B. and Daniel, R.L.: Combustion Products From Vinyl Chloride Monomer. 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Properties' and^Es^tlip^MorTaatiori for Safe Handling of ^h ,*%___ j_ln~ :4i'JL#^:fta-<i citAof . Manufacturing 124 1 Whit^"Fi-ngers^ 180 -----: Env Res 6:132-14^ ^1.3^ > v" " " #s*. . UNIR0002087