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i i . AR L296 - 0679 1 MULTI-CITY STUDY 1 FINAL FIELD REPORT FOR COLUMBUS GEORGIA AND 1 PORT ST. LUCIE FLORIDA - BATTELLE DUXBURY ACTIVITIES . 1 For Project Number 1 N100672-01 0 Submitted to 1 x . October 26, 1999 1 Prepared by " Kelly A. Irizarry | Battelle 397 Washington Street 8 Duxbury, MA 02332 (617) 934-0571 g a 001034 i --P--age: 1 : TABLE OF CONTENTS [| LO 11"iSURVEYSPECIFIC A-- PPROVAL -- cra ane ss | | 4.1" SAMPLEMATRIX AVAILABILITY cross rnemessinesssenssssnssssesssssnsmmerns & 1 2432 ONNSTLRTOTMEONBTIATIINONINRENSULc T rs eams o 0 . 4.4 COMMUNICATIONS... -- 1 FY 1 LIST OF TABLES `TABL|E MUNICIPALITIES SAMPLED AND APPROVALS GRANTED DURING SURVEY... 1 `TABLE 2 CHROONFEVOENTLSOONJUGLY2Y6, 1999... 3 1 `TABLE 3 CHROONFEOVELNTSOONGJUYLY 27, 1999... n--0 `TABLE 4 CHRONOOLFEOVEGNTYS ON JULY28, 1999. snsm------_ `TABLE 5 CHROOFN EVENOTSOLNJO ULYGY 29,1999....ccvcnsnnsnes 3 1 `TTAABBLLEE 76 CCOHLLRECOTEDNSOOAMLFPELOVESEGNFTYRSOMONCJOULLUYM3B0U,S1G9A9.9..... - wd3 `TABL8E COLLECTED SAMPLESFROM PORT STLUCIE FL... Nn `TABLE9 SAMPLING SITEPOSIITNICOLOUMNBUSS GA crevasses LL `TABLE 10 SAMPLING SITE POSITIONISN PORTST-LUCIE FL. 11 `TA1B1LGPESPOSITION VERIFICATIONRESULTS nsmm--------. 1 ft Final Field Rpt Columbus GA Port St. Lucie FL. o 00103! Bafielle i ariFaagent i 1. INTRODUCTION The objective of the sampling task in this study is to collect representative samples for trace- | elenvveilraonnamleynsti,s aonfdFOhSuEm-abnaesxepdosfulrueorvoicahethmeicfaolo(dFcCh)airne.siTduhaelsc,ittoesassseelsesctseodurfcoerss,admipslpeercsoilolnecitnitohne. [] will be considered `study' or `control' cites. production facilities or large FC consumers. `Study' cities are considered those areas with FC "Control" cities do not contain FC production or . canodnsdurmipntkiionng wfaactielritseosuracned. are matched to study cities based on general location, population size, i Dacucreisnsgttohveairniitoiuasl mpahtarsieceosfofthientsetruedsyt,.phBoanseedcaulplsonwetrhee.lmeavdeleotfocmouonpiecriaptailonagreencceiievsedrefqruoemsttihneg 1 `PmruonjieccitpPallaange(nQciAePs,)apapnrdoptrhieaStuersvaemyplPlianngcsotrnattaeignietshewearpperodperviealtoepeidn.foTrhmaetiQounalciotnyceArsnsiunrgantchee `matrices for collection and methods to be utilized for this process. 1 `PTehresofnulnleplrcoojlelcetctsadmrpilnikinnggswcaotpeer,isPaOcTcoWm,plliasndhfeidlluasnindgutrwboanfiaeilrdstaemapmlse:s,1)anBadtt2e)lBlaet'tseDlluex'sbuMrayrine 1 Ssacmipelnecse.s LTahbiosrartepoorryt(sMuSmLma)rpiezressontnheelDcuoxlbleucrtysutrefaamceefwfaortte.rAmsiecpraolraaytere,rbeuplorktwsautmemraarnidzefisnftihseh MSL activities. | 11 Survey Specific Approval 1 WInoCroklsu(mPbOuTsWG)A,,maupnpircoivpaall wdraisnkoibntgaiwnaetderfoprlasnatm,ptlheecmoulnliecctiipoanlaltantdhfeiPlu,balnicdltyhOewCnoeludmTbruesatFmierent DPeOpTaWrt,memnutni(cfiopraaltdmroisnpkhienrgicwastaemrplpilnagnt),.thIenmPuonritcSitp.alLulcainedfFilLl,aanpdprtohveaPlorwtaSst.obLtuaciineedFirfeo:r the | `aDnedpathretmaepnptro(vfaorlsatgmroasnptheedrbiyc sampling). municipal Table 1 highlights departments. the cities visited during this survey un `Table 1. Municipalities Sampled and Approvals Granted During Survey City Study or| Fire Department Drinking | Municipal || Control_| (Air Sampling) Water Plant | Landfill [Columbus GA [Comeol | Port St. Control -- VT v7 | 7] v7] tf Lucie FL. 8 2. METHODS `The collectionofenvironmental samples was conducted according to Standard Operation Pursoecdetdourtreasin(SpOePr'sso)n.nelThperiSorOPto'sfiuelsdedactiintvihteieMsualntdi-aClistoysSetrvuedyaswererfeerwernictteednobcyumBeatnttesllweahinldeairnethe. ] Final inal Field Rpt Coi lTuAGAmMPboErtuSt.sLuuccie eter FL eeeeeeeereseeeeeme 001031 WwBatielle | 1 JFaget 1 field. These documents, along with the QAPP, serve as the guidance documents for the. collection of field samples. The methods used for collection are summarized below. 1 "The collection of position data (latitude and longitude) was completed at the Columbus and Port St. Lucie sampling location using a Garmin 12XL GPS unit according to Battelle SOP 3-164-01. Instrument accuracy was validated by comparing an acquired position versus a position of 1 known location. The collection of air samples was completed usinag General Metals Model PS- T1haetmuossepohfetrhiicsssyamsptleemr.alTlhoewssathmeplsiepnagrwataesccoollnedcutcitoendofacpcaorrtdiciunlgatteo aBnatdtevlalpeoSrOphPasMe3-cMoCm-pFo-uLn.d1s. . 1 using a glass-fiber filter for particulate matter and Polyurethane foam (PUF) for the vapor phase. `Water samples from drinking water supplies, POTW's, and landfills were collected according to SOP M3-F-2.0. Surface water samples were collected via direct submersion, tap water and i drinking water supplied by the municipal plant were collected via a valve system, and effluent was collected using either a bucket or small sampling beaker. Sediment samples were collected Biusn ing a ss tainlessisteel spuoomn,,accSorhduineg tion PSBaotttel.leLSOuPeMv3a-sF-c7a.0l.leSdluvdogenin Csomlaulmlbcuoslweaison bucket. 3. CHRONOLOGY 1h Tables 2 through 6describethe events that occurred each day of the survey. Sample matrix collection times have been transcribed from the sample log; all other times have been estimated 1 Tbaismeed. on the events that transpired during the survey. All times are recorded in Eastern Daylight BR `Tabl2e. Chronology of Eveats on July 26,1999 ~ Battelle Duxbury personnel depart Boston n [ [TPicT kuA prentm alvehiv cleane dprocm eed tC o Federo al Exw pressm to picb kup suu pplies s __G ___A _|| Proceed to meet with Chief Waters, Columbus Fire Department. Discuss location of un Atmospheric sampler, we agree on Station #1 ] c"Aorlrlievcetiaotnfire station #1 and place air sampling unit behind building for sample `Conductcalibrationofairsamplerandstart sampling for 12hr period [1650 "Madephone calls forthecollectionofwater samples on July27" | h A satsCom TiFie TrcineDFE " Table 3. Chronologyof Events on July 27, 1999 020 "Aive quality at Fire Station #1; control samples collet filer and PUF sample. Cleaned sampler and collected CL] s`Saimtepl2intagp' water samples collected at Station #1 following the completion of air . wpautmeprinsgampsltesa.tFaiitntoihnseheDdawmater collected at the facility, untreated water collected at the I) Final Field Rpt Columbus GA Por St. Lucie FL. 1BWasnT elll eTo ck 0010- 1 anwys VI o Tr T SStihie Darimgvvari Gtm sme W lscl Mes a | 1 "Artived at the Pine Grove Land fill. With the assistanceofMr. Ralph Jackson, sample. 1 | was merepe collected from leachate well, directly oeTe into sample bottle TRB I hm ninbonbrcotpme ronto e 1 `Table 4. ChronologyofEvents on July 28, 1999 Phage] 1 | C e [ air1 sampe l-- eE rE set up --r -- hm oeE a-- Ram ro-- mr mpuia -- soS m m-- ] en m-- e| Table 5. Chronology of Events on July 29, 1999 ' control samples I E| EER T ro E E TYeC -- . e lab 'u RTE from Chlorine contact chamber via small collection bucket 2 Sn Boe r Stuart FLt. e o eo n dra | I ae] 1 Final Field Rpt Colombus GA Port St Lucie FL BBaraeltlee .001038 1 P--aed i Ta6.bChrolnoloegyofEventsonJuly 30,1999 1[ [DriveioW. PaimBeach fora 10amflighttoOrlandoFlorida [[ T| TAewamivveeOatrlLaongdaonFIlnotreimdaatfioornaBlosAtiornportBoston 4. RESULTS 1 `This survey, as part of the Multi-City Study, resulted in the collection of the samples described in Tables 3-5 of the QAPP and Amendment 1 to Revision 1. The following sections describe the 1 results of the sample collection effort that occurred during this survey. 1 4.1 Sample Matrix Availability Per client instructions no food items were collected during survey. Due to scheduling and permit 1 issues no finfish were collected during this survey. The collection of POTW influent did not occur at either Columbus or Port St. Lucie due to health concerns. Both POTW influent streams available for sampling contained biological hazards. The staff at facilities in both cities indicated 1 that the chlorination process occurs following secondary treatment. 1 Also collected, but not included in the QAPP, was a sampleof quiet/undisturbed surface water. `This sample is intended for use in a long-term transport study that is currently being conducted. `The sampling location in Port St. Lucie was altered, with the approval of the project manager 1 (Marcia Nishioka), from the original site due toadistanceof40 miles each way to the sample site. In Columbus, the sample site was located on private property. Permission was granted by ' one of the residents of Stone Woods Farm. 4.2 Onsite Observations Columbus, GA: The POTW diffuses its water 100 feet from the river. The landfill leachate: pond is gravity fed into a confined manhole, which was not accessible due to safety reasons. & 1 Leachate was collected using modified collection methods. Quiescent water was collected from private property afte receiving permission from a resident of the property. Mr. Jesse Eldridge 3 (3M client) was present at all sampling sites. The POTW sludge is dried and put out in the fields 10be mixed with soil on site. Drinking water influent was sampled from a pumping station about 1.5 miles from the drinking water plant . Port St. Lucie, FL: Surface water was taken from brackish (slightly saline) waters, indicating. `some tidal/seawater influence at this location within the riverlestuary system. Multiple oyster a shells and mangrove were observed. The WWTP is a much smaller facility than the drinking `water plant. Mr. Gary Basham is the director of both facilites. With complete cooperation, all 5 samples were collected successfully. 1 Final FieldRpt Columbus GA Port S. LuciieeFL Batielle 00103: dBatielle 1 i 1 1 1 8 1 1 B 0B _ nm || n ns I-- "Table 7. Cllected Samples from Columbus Georgia [ve] eR [Drinking WaterUnprocessed |MCS15B [Drinking WaterUnprocessed|MCS168 [DrinkingWaterUnprocessed|MCSI7B [DrinkingWaterUnprocessed |MCSI8B [DrinkingWaterUnprocessed |MCSI98 ee *SedimentMass (g [1 | PumpingSutonGtheDam | [1 |PumpinzSttin@theDam | [1 | PumpingStation @ theDam | [1 | PumpingStation @theDam | [1 | PumpingStation @theDam | [Drinking WaterUnprocessed |MCSISK_______[1 [DrinkingWaterUnprocessed|MC-SI6K_______[1 [Drinking WaterUnprocessed |MCSI'K [1 [DrinkingWaterUnprocessed|MCSISK [1 [Drinking WaterUnprocessed |MCSIK________[1 | PumpingStation @theDam | | PumpingSationtheDam | | PumpingStation@ theDam | | PumpingSutin@theDam | | PumpingStation @theDam__| [DrinkingWaterUnprocessed |MCSISH [1 | PumpingStation@ theDam | [DrinkingWaterUnprocessed |MCSI8H [1 [Drinking WaterUnprocessed |MCSISH [1 [Drinking WaterUnprocessed |MC520H | Blank [Drinking WaterProcessed __[MC521B________[1 [DrinkingWaterProcessed [MC522B [1 [DrinkingWaterProcessed __[MC-5238 [1 [DrinkingWaterProcessed |MC524B [1 [DrinkingWaterProcessed |MCS25B [1 [DrinkingWaterProcessed [MCS2IK [1 [Drinking WaterProcessed |MC522K [1 [Drinking WaterProcessed |MC523K [1 | PumpingStation @theDam | | PumpingSution@theDam | | PumpingStation @ theDam | | ColumbusWaterWorks | | ColumbusWaterWorks | |ColumbusWaterWorks | | ColumbusWaterWorks | | ColumbusWaterWorks | | ColumbusWaterWorks | | ColumbusWaterWorks | | ColumbusWaterWorks | [DrinkingWaterProcessed__[MC525K_______[1 [DrinkingWaterProcessed __[MC-s21H [1 [DrinkingWaterProcessed__[MC-523H [I [DrinkingWaterProcessed__|MC-524H [1 |DrinkingWaterProcessed |MC525H [1 [TapWaterSiewi |Mcs2eB [1 [TapWaterSiewt-- |MCsoB [1 [TapWaterSiewl_[MCse8 [1 [TspWaerSiewi [mcseoB [1 [TapWaterSue#l_ [mcssoB [1 |ColumbusWaterWorks | |ColumbusWaterWorks | | ColumbusWaterWorks | |ColumbusWaterWorks | | ColumbusWaterWorks | |Holdaylm | [Holdaylm | |Holdaylm | Holdaylm | Hohdaylm | PapWarBlane T-- MEsT B holamyim [TapWaterBlank [MCs3aB| THoldaylm | [TapWaterSiewr [MCS26K [1 IHolidaylm | [TopWaterSiewt |MCs7K [1 THoldaylm 7] [TopWaterSiewl [MCsasK [1 [Hobdaylm | [TepWaterSuewl [MCso0K [1 Hohdsylm | [TspWaterSuewl_ [MCS3K___ [1 [|Hohdayfm 7] [TapWaterBlank __ [MCS3K| Hohdylm 1] [apWater plank [Mess Trolamyim [TapWaerSiewt [MCszeH _ |T -- IHoldaylm | [TopWaerSie#t [MCsasH [1 |Holidaylm | [TapWaterSite#1 [MCsooH |v Holidaylm | [TapWaterBlank |MCs33H| |Hohdaylm | in Final Field Rpt Columbus GA Port St.LucieFL. 33BBataiteilellel_e 001.04 I = 1 =-_ *Sediment Mass (; [TopWaterBlank |Mcssan 1 THohdaylm | 1 [TapWaterSitewz [MCs3B___ JT [CPDSton#l | [TapWaerSiewz [MCS3IK___ [1 [CFOSmtion#1 | 1 [[aToppWWaateerrSSihee#d2s_ [TMMCCss33tH [[11 |CMFeDrSouptoliioannB#olarFamp || [TapWaterSite#s [MCs32K [1 | MeuopolianBoatRamp | [TapWaterSite#s _|MCssaH 1 |MewopolitanBoatRamp____| 1 [Surface Water Site#1 [MC-solB 1 | Pumping Station behind the Dam_| [SurfaceWaterSte #l_____[MCs02B [1 | PumpingStationbehindthe Dam_| [SurfaceWater Ste #1 |MC5038 [1 | PumpingStationbehindtheDam| [SurfaceWater Sie#l_____|MC5048 [1 | PumpingStationbehindtheDam| 1 [SurfaceWater Sie#1____[MC505B_____ [1 | PumpingStationbehindtheDam| [Surface Water Blank [MC-5088 | | PumpingStationbehindtheDam| [SurfaceWaterBlank [MC5098 | | PumpingStationbehindthe Dam_| 1 [Surface Water Site#1_____[MCSOIK______ [1- | PumpingStationbehindtheDam| [SurfaceWaterSite #1_____[MC50K [1 | PumpingStationbehindthe Dam| [Surface Water Sie#1 [MC-s03K [1 | Pumping Station behind the Dam _| [SurfaceWaterSite#1 [MCS04K [1 | PumpingStationbehindtheDam_| 1 [SurfaceWaterBlank_____|MCS08K | |PumpingStationbehindtheDam | [SurfaceWater Blank _____[MCS9K | | PumpingStationbehindtheDam | 1 [SurfaceWater Site #1_____|MCSOIH IT | PumpingStationbehindtheDam| [Surface Water Sie#1 [MCS03H [1 | PumpingStationbehindtheDam| [SurfaceWater Sie#1 [MC-s04H [1 |Pumping Station behindthe Dam _| 1 [SurfaceWater Site #1 [MC-S0SH [1 | PumpingStationbehindtheDam_| [SurfaceWaterBlank [MCS08H | | PumpingStationbehindthe Dam_| [SurfaceWaterSie#2_____[MCS06B [1 [MunicipalMarine | [SurfaceWater Site#2 [MCS06K [1 [MunicipalMaima | 1 [SuffaceWater Sie#2__|MCS06H [1 |[MunicipalMarina | [SurfaceWaterStews [MCS07B [1 |MunicipalMaria | [SurfaceWaterSie#3 [MCSO7K [1 | MunicipalMaria | 1 [SurfaceWater Sue#3 [MCS [1 | MunicipalMaria_______| [SedimentSite#1 [MCS10B [200+ Pumping Station behindthe Dam _| [SedimentSite #1 |MCSIOK [200 |PumpingStationbehindtheDam| nN [SedimentSite#2______|MCsSIIB [200 | MunicipalMarina| [SedimentSite#2 _[MCSUK 1200 |MunicipalMaria | [[SSeeddiimmeennttSSiittee##33 __[ _M _C _S [[I 2M 00 Z CK S_ I||M[ Mu2 unniiccii2 pB paallMMaa0 r_ riiaa 0 _" _|| 0 [[SSeeddiimmeennttBBllaannkk [TM[ MCCs1S3IBK| I [MMuunnicciippaallMMaarriina || [SedimentBlank |MCsW4B | | MunicipalMarim | 1 [SedimentBlank |MCSWK | | MunicipalMaria | [POTWEMMuen |MCsB___[T |CoumbusWwrP | [POTWEMuem |MCsd0B [1 |CombuswWwrr | 1 [POTWEfMuem |MCs4B__ [1 |CombuswWwrr | [POTWEMuem |MCs#B [1 |CobmbwswWwrr | [POTWEfMuemBlank___[MCs438 [1 |CombuswWwrr | [POTWEfflvemBlank [MCs43K [1 |CombusWwrp | [POTWEffemBlank [MCsa3H [1 [CombwsWwrr | [POTWEMuem ____|MCs9K [1 [Combuswwrr | N [POTWEMuem __[MCSK JU [CoumbuwswWwwre |] 1 --_-- FinalField Rpt Columbus GA Port St. LucieFL. 3$BBaattlellele 001.04: . I 1 aos ----------------------------------------------------------e--e----S--E--} ! *Sediment Mas(sg JW [ blen CollcedSamplstrom Poert Stn. Lu[cFeL | my weer] [POTWEMven __ TMCseik 11-- TColmbuswwip | i [POTWEfuew_ [MCs&K [1 ColmbusWwrp | [POTWESMuew [MCS [1 [Combwswwrp | [POTWEMuew [MCSatH [1 TCombwwWwrp | 1 [POTWEMwem [MCsih [1 [CoumbuswWwwrp | [[PPOOTTWWSSiuudggee-- [[mMMCCSs@&RB [[220000F-- Co| mCobmubsuWsWwwrrpp || [POTWSludgeBlank [MCSasB____ | |CoumbuswWwwre | 1 [POTWSludgeBlank __ [MCsasK| [ColmbuswWwrp | [UtbanAir(Vapo) ___ [MC546B [IPO [CFDSanon#l | [UrbanAir(Particulate) [MC-547B | IFiter [CFDSuation#l | || [Urban Air FieldSpike |MC548B_ |WPUF___ | CFDSwtion#l | [UrbanAirFieldSpike [MC-549B | WFiter | CFDSmon#l | [UrbanAirFieldBlank [MCS50B____ [IPUF__ [CFDSaton#l | 1 [UrbanAirFieldBlank [MC-SSIB_ |IFilter |CFDSwton#l | [LandfillLeachate [MCs35B [1 |PineGroveLandfll | [LandfillLeachate [MCS35K____ [1 |PineGroveLandfll | [LandfillCeachate____ |MCS3SH [1 [PineGroveLandfl | 1 [LandfillLeachateBlank |MC-536B____ | [PineGroveLandfl | [LandfillLeachateBlank [MC-536K | [PieGroveLandfl | [Condfill Leachate Blank |MC53H| |PineGroveLandfill | 0 [Quiet SurfaceWater |MC584B 11-- |SwneWoodFarm | [[QQuuiiettSSuurrffaacceeWWaatteerr ___|[MMCC-Ss8B4#KH [[11 [|SSotnoneeWWooooddFFaarmm || [QuietSurfaceWater" [MCB |ITripBlank |SwneWoodFarm | n [QuietSurfaceWater"____[MC-586B________|ITripBlank |StoneWoodFarm | `Samples are not part of this study *SedimentMass [DringWaterUnprocessed|MC61SB [1 [DrinkingWaterUnprocessed [MC-616B [1 [Drinking WaterUnprocessed [MC617B______[1 [DrinkingWaterUnprocessed [MC-6188 [1 [|DrDirninkkiinnggWWaatteerrUUnnpprroocceesssseedd||MMCC-661159K8 [| 11 [DrinkingWaterUnprocessed |MC-616K______[1 |DrinkingWaterUnprocessed |MC6I7K [1 |Drinking WaterUnprocessed|MC-618K______|1 (g) | St LucieDrinkingWaterFacility | | StLucieDrinkingWaterFacility| [StLucieDrinkingWaterFacility | |StLucieDrinkingWaterFacility | [|SSttLLuucciieeDDrriinnkkiinnggWWaatteerrFFaacciilliittyy || | St LucieDrinkingWaterFacility | | St LucieDrinkingWaterFacility | | StLucieDrinkingWaterFacility | [Drinking WaterUnprocessed [MC-620H [Blank | DrinkingWaterUnprocessed |MC-618H [1 [[DDrriinnkkiinnggWWaatteerrPPrroocceesssseedd [[MMC-C621BB [[11 [DrinkingWaterProcessed |MC-623B |1 Final Field Rpt Columbus GA Port St. Lucie FL | StLucieDrinkingWaterFacility| |'StLucie DrinkingWaterFacility | [|SSttLLuucciieeDDrriinnkkiinnggWWaatteerrFFaacciilliittyy|| |StLucie DrinkingWaterFacility | 2BDaotntelele... 00104 1 nos ------------------------------------------A-- Y, [| Matrix `Volume Collected (L) Location Collected *Sediment Mass (g [DrinkingWater Processed |[ MC-624B TLuct ie DrinkingWaterFacility| 1 [DrinkingWater Processed |MC-6258 [DrinkingWater Processed |MC-621K [1 [1 | StLucie DrinkingWaterFacility | | st Lucie Drinking WaterFacility| 1 [DrinkingWater Processed __[MC623K [1 |'stLucie Drinking WaterFacility| [DrinkingWater Processed __[MC624K [1 [DrinkingWaterProcessed |MC-625K____ [1 |'stLucie Drinking WaterFacility| | StLucieDrinkingWaterFacility| 1 [DrinkingWater Processed |MC-621H [1 | StLucieDrinkingWaterFacility| [DrinkingWater Processed |MC-623 [DrinkingWater Processed |MC-624H [1 [1 | StLucieDrinkingWaterFacility| | StLucie DrinkingWaterFacility | [DrinkingWater Processed |MC-625H 1 | St LucieDrinking WaterFacility| 1 [TapWaterSiewl |MC626B [1 [Holdwyim | [TapWatersiesi |MceaB [1 THohdaylm | [TapWaterSite#l______[MCG2B [1 |Hodaylm | 1 [TopWaterSie#l_ |MceoB [1 [TopWaerSie#l ___[Mceos [1 IHoidaylm | THoldaylm | [TapWaterSie#l__[MC626K [1 [Hoidaylm | [TapWaterSte#l______[MC6mK || [TapWaterSite#l |MCe2K [1 [1 [Hoidaylm | [Hoidwylm | [TapWaterSite#l_____|MC62K [Top WaterSite#l___|MCG3K [1 [1 [Hohdwim | [wWohdwim | 1 [TapWaterSitewl |MCe26H 1 |Wohdwim | [TipWaerSies _[mMcesH [1 [TipWaterSie#l____[MCGOH [1 [Hohdaylm | [Hoidaylm | 0 [TopWaterSite#l_|Mce30H [TspWaterSite#2 MCB [1 THoldsylm_______| [|1PonStLueFDSutionds| [TspWaterSite#2 |MCIK [|1PonStLucieFDSution#| s [Tsp WaterSite#2 [MCI 1 | PonStLuceFDSuion#s | 1 [Tap Water Site#3 _[MC632B [1 | Pendarvis ParkMartinCounty _| [TapWaterSites [MC632K [1 [TapWaterSite#3__ [MC632H [1 | PendarvisParkMartin County | | PendarvisPark Martin County _| n [TspWaterBlank [TapWaterBlank [MC-6338 | [MC63K | | PendurvisPukMartinCounty | | Pendarvis Park MartinCounty _| [Top WaterBlank |MCe33H | | Pendarvis Park MartinCounty _| nN [Top WaterBlank |MC634B | | Pendarvis Park Martin County _| [TapWaterBlank-- |MC63K | [SuficeWater Sie#l_____[MCGOIB [1 | PendarvisPukMartinCounty | | PendarvisParkMartinCounty _| [[Suface WaterSite#1 [MC6028 [1 [[Suface WaterSite #1 [MC6038 [1 | PendarvisPark MartinCounty _| | PendarvisPark MartinCounty _| [Surface WaterSite #1 |MC6048 [1 | Pendarvis Park Martin County _| [Surface WaterSite #1 [MC605B [1 | Pendarvis Park Martin County _| [] [SurfaceWaterFieldBlank |MC-6088 | | PendarvisPark Martin County _| [SurfaceWaterFieldBlank |MC-G08K | | Pendarvis Park Martin County _| [Suface Water FieldBlank |MC-608H | [Surface Water FieldBlank |MC-6098 | | Pendarvis ParkMartin County _| | Pendarvis ParkMartin County _| [Surface Water FieldBlank __|MC609K | | Pendarvis ParkMartin County _| [Surface WaterSite#1 [MC60IK [1 | PendarvisPark Martin County__| [SurfaceWaterSite #1 |MC602K [1 | PendarisPark Martin County _| [SurfaceWaterSite#1 [MC603K [1 | Pendarvis Park MartinCounty _| [Surface WaterSite#1 [MC-G04K [1 | PendarvisPark MartinCounty _| 8 [SurfaceWaterSite#1 [MC60SK [1 | PendarvisParkMartin County | i Final FieldRptColumbus GA Port St. LucieFL rBBpaatNeetrei.e...0010a 1 psPaes pl = "Sediment Mass (& [SurfaceWaterSite#1-- [mc60tH TT TPendarvisParkMartin County | i [SurfaceWaterSite#1 [MC603H [1 | PendarvisParkMartin County | [SurfaceWaterSite#1 [MC604H [1 | PendarvisParkMartin County | [SurfaceWaterSite #1 [MC60SH [1 |PendarvisParkMartinCounty | i [Surface WaterSite#2 [MC-6068 [1 | MarinCountyMarina | [Surface Water Site#2 ___[MC606K [1 |MartinCountyMaria | . 1 [SurfaceWaterSites [MC-607 [1 [SwanHawbor | [SurfaceWaterSites [MC607K [1 |SwanHubor | [SurfaceWaterSite#3 [MC607H [1 |SwanHabor | [SedimentSite [MC610B_____1200+ | PendarvisParkMartinCounty | [SedimentSite#1 [MC6IOK___ |200+ | PendarvisParkMartinCounty _| [SedimentSites [MC6IIB [200 MartinCounty Marina | [SedimentSite#2 [MC6LIK_ [200" [MarinCountyMarina | [SedimentSite#s [MC6I2B____ [200F [SwamMabr | [SedimentSite#s_ [MC6I2K [200F | SwanMabor | [SedimentFieldBlank [MC-6138 |-- [StanBabor [[SSeeddiimmeennttFFiieellddBBllaannkk [[MMCCo613aK5| | [[SSwuaannHHaubboorr || [SedimentFieldBlank [MC-61K [ |SwanHaubor | [POTWEwen [MC639B IT [NomhPotwwrp | [POTWEfMuent [MC640B [1 INomhPomwwrp | [POTWEMuew |MC641B [1 ~~ INomhPomwwrp | [POTWEMvent [MC642B [1 [NomhPonwwrp | [POTWEfMuent [MC39K [1 [NomhPonwwrp | [POTWEMuent [MC64K [1 [NomhPonwwrp | [POTWEMMuent---- [MC64IK [1 [NomhPonwwrp | [POTWEMMuent---- [MC6a2K [1 | NomhPomwwip | [POTWEMMuent -- [MCG30H [1 |NomhPomwwrp | [POTWEffluentBlank [MC6438| [NomhPonwwrp | [POTWEffluentBlank [MC643K_ | [NomhPonWwre | [POTWEMMuentBlank [MC-643H| I NomhPomWwIP | [POTWEMuent -- [MC6d0H [1 [NomhPonwwrp | [POTWEMuent [MC6alH [1 [NomhPonwwie | [POTWEMuent [MC6d2H [1 [NomhPonwwrp | [[PPOOTTWWSSlluuddggee---- [[MMCC6o4aaBK [[220000++ |[NNoosmhhPPoonnWwwwrrpp || [POTWSludgeBlank [MC645B| [NomhPomwwrp | [POTW SludgeBlank [MC-645K| [NomhPonwwrp | [UrbanAir(Vapor) |MC646B |TPUF [PontLucieFDSons | ' [UrbanAir FieldBlank [MC6508_ [1PUE [CandiLeachate [MC6358 [1 [CandfillCeachate ----[MC635K [1 [LandfillLeachate [MCe3SH [1 [Londfil Leachate Blank [MC636B | [andlCeachateBlank [MC-636K| n [Condfil LeachateBlank [MC636H | [PonSt LucicFDSttion#5 | |PonStLucieLandill | [PonStLucielandil | |PonstLucieLandfil | |PonStLucieLandfll | |PortStLucieLandill | | PonStLucieLandill | a Final Field Rpt Columbus GA Port St. Lucie FL 3Batielie 001044 Batlle, i bw 1 [[Q[uQiueiteSSuurrffaacceeWWaatteerr 1 [QuietSufoceWater [[MMCC6G848HK [MC665B ye= rages *Sediment Mass (g [[11 | ITapBlank |MMaappppRRaAJ/SSWWCChhaappmmaannWWaayy ||,-- |MappRa/SWChapmanWay | 1 43 Instrumentation Results Air samples were collected using a General Metals Model PS-1 air sampler. According to SOP 1 TMo3-dMeCt-eFrmLi.n1e,tthheeaacicrespatmabplleerrecsaullitbsraatciaolnibisraatcicoenpwtaabslecoifndituicstweidtihninDu1x0b%uroyf tphreioerxtpoecttheedinrietsiualttiso.n i goefntehreastteuddyi.n CTohleuminbiutisalacnadliPborrattiSotn.cLuurcvieerheasdulRt?edvianluaeRs?ofva0l.u9e9o9f and0.9095..99T5hreescpaelcitbirvaetliyo.n Tcuhreves. percent difference in recorded values from the initial calibration ranged from 0.0% to 6.73% for Columbus and 0.0% to 5.26% for Port St Lucie. . Site locations were determined using a Garmin 12X L GPS. The accuracy of the GPS unit was. verified prior to departure from Duxbury by comparing a verified location on Batelle property 1 versus the location determined by the instrument. The distance between the benchmark and / instrument value was 32.19 meters. `The GPS operation was verified in Columbus GAusing a benchmark at the Pine Grove Landfill. Following shipment to Georgia the instrument was reinitialized automatically. This was dciosnpdluacytiendgamtatphse afinrde lstoactaitoinonosnoJfutlhye26l"o.calWairteha,inwhsievcehrailndmiicnauttedesthoafttihtewparsocweosrsk,itnhge purnoiptewrlays. `The results of the verifications for each sampling day are presented in Table 11. `The coordinates for the benchmark were in northing and easting. They were recorded on the log forms in this format and were converted to latitude and longitude by Ned Morse of Battelle: Duxbury Operations. The result of the verification for Columbus was a difference of 10 meters GbePtSweaenndtchaelcbuelnactehdmainrklavtaitluudeeaannddtlhoengiintsutdreu.ment value. The readings were then entered into the `NOopebraetnocrhsmMaarnkuraelfetraetnecsetvhearlifiifctawtioonciwtiaess aorbetawiintehdinfr5o0m0 mPoirltesSto.fLeuaciceh.otThhere, Gaasremcionnd12XL verification is not needed. Because Port St. Lucie FL is within 500 miles of Columbus GA, a second verification was not conducted and no position for this city was obained. According the QAPP, the minimum distance between sediment sampling site positions should be: 2500 feet. The following results have been calculated using the Garmin GPS. The distance from Columbus Site 1 to Site 2 is 1378 ft, the distance from Site 2 to Site 3 is 787 ft. and the fdii.sttahnecedifsrtaonmceSiftreoImtSoiStiet2e t3oSisit2e1332isft.78T0h8e.8difts.taanncdetfhreodmisPtoarntceStf.rLoumciSeitSeit1eto1 StoitSeit3ei2s 6is491657f4t. Final FieldRpt Columbus GA Port SLLucieFL HT BRastTloekliioeTowk 00104: i - teen Table 9, Sampling Ste Positions in Columbus GA 1 Somplng Location iodey Ion,Tap water sie #1 |N__iTaside |N525157 |[ WsdrLso5W nrg2i0t0u"dn e || [_1W_I5_VAedtAedrravnesesPsEWY| 1 NIT" i MuMVnac rriainTSotpecwa72rp eiSiep|[NN3322311192.80"" ||WWEk4s590'239.456" | OverLabo verRA . NIRS [Wear "Columbus Water Works (influent) | N 3231'02.1" DamWives Ra [ColmbusWWTP [N3224352" |wsdss4a7 |S. LumkinRd. N3228'56.3" W84S I17.0" "Table 10. Sampling Site Positions n Port St. Luce, FL Tomfion |Ustad | Longitude N2T16'46.2" N271621.8" WS0I8'14.6TM orp wate QPuoi rtWatLeucreFLaandCty FL [N7or NNN2I7FE18T32OL.1T" |Wbarer 0WW870H52E50'537710.84" [Penddalrvissie [N21I'I52" [Mun Marii nasicte #i2 pal|N271100.1" N2PI2Z136" W8016'12.9" W801608.7" W801543.07 | Adare S. FederaHly 1616PortSt. Lucie Bivd onPalkSime hve | N6i1a2p0pRGaadSeWCCuhfafpRmaEn W: - dNorratwhbsiidde of Roosevelt "Table 11. GPS Position Verification Results: hpeaeCnodliPbroattiioonnsLoLcaantidoins IF TSC9o6 WloSSmGT:ATO | iNor mleoftesadchcioetsere wih 500 E[ (S essay -- np OoYrmr Ti VISeT|I -- 4.4 Communications There were no pertinent conversations surrounding the collection of samples at the various hfaecliplfiutilestothoautrwsearmeplsianmgplperdo.ceCsosn.taDcutrsiangndtheempcoluoryseeesofocfotlhleecftaicnilgitsiuersfaincebowtahtecritsieasmpwleerse ivnebroyth Final Field Rp:Calamoes GAPortSt. LaciFeL TALE dBattelle| 1 DEVAIDACORTRECITIVOE ACNFTIeOSNzS 1 ICnolcaucmhbucsasaenadgPeonretraSlt.aLnuscwiee,r wmaesmboefrfesreodf athnedgaelnleirnatlerpeusbtleidcpiarntqiueisrewderaebosuattitshfeiesd.ampling effort. 5. DEVIATIONS AND CORRECTIVE ACTIONS 1 DQuArPinPgdtehveiactoilolnesctwioenreofenscaomupnlteesrefdrom Columbus, GA and Port St. Lucie, FL the following . { + POTW inlet samples were not collected in either city, de to health isks || Aperfiionda.l TIphmsreoandliyntghwaisnitnioatl vdaolcuuemweansteudsfeodrtthoedeatierrsmaimnpeltehrea"tatvheereanged"offltohwercaotlel.ection + The client requested that food items notbe collected. + Weather notations were not included in the field record. + Manufacturer labels were used because of problems with the Battelle labels. + "The air samples were not field spiked but rather laboratory spiked at Batelle Duxbury. "The following deviations were noted during the Columbus Georgia survey: Pine Grove Landfill in Columbus has gravity fed leachate pond, whichi accessible through Damuaenhtoolneox.ioAussifnugmleesatatnedmpctotnofcionleldescptascaemepnltersy,farnomalttheimsalteeacmhettehosdouwracse dweavseluonspuecdc,ewsisftuhlt.he. aheplpproovfetdhepascitkeisnugpetravpieswore,wMrr.eRaabllpehtJoaccoklsloenc.t tUhseisnagmjpulmepesurccceasbslfeusl,lsy.amApletebloetscloepsicanpdolpereand bucket was purchased for future situations. + bClounetriacer.y tTohethePUQFA,PfPilttehr,easnpdikbeldufeilitceerwaenrdePeUaFchfoirndCiovliduumablluyssweealreedsihnizpippedlotcoktbhaegfsietlhdatondid fnioltelreaankdaPnUdFsowbiltuhebiecesednitdonnotdcryomcee.in contact with th filer or the PUF- In the future the "The following deviations occurred during the Port St. Lucie Florida survey `sTihtesQwiAthPirnojaecsturPflaacne Sweactteirosno7u.r3.c5e. osftdatreisnkthiantg"wwatheorl,ea(nbdulakt)twhaetweartewirlltrbeeatcmoelnltecptleadntfrionfmlutehnrtee baencdololutefcltoewd..f.roImftahneydsreilnekcitnegd wlaaktee,rpsoonudr,ceorisrigvreoru.n.d."watInerPotrhtenStt.hLeuscuiref,acderiwnaktienrg swaamtpelreiss will spuupmplpieesd. frSoammpglrionugndswpeactiefricasnfdolslootwh:e surface wate collected docs not relate to drinking water FinalFieldRpt Columbus GAPortSt Lucie FL - 3BA attelle 00104 I E------ -- ------e-- e ------------------ 1 The project manager gave coordinates for surface water collection; these coordinates were. not accessible due to private property and needed to be modified. Surface water from Port 1 St. Lucie was collected from the Port St. Lucie River, which is brackish (partially mixed with seawater and slightly saline). Intake and outflow drinking water samples were collected from the municipal drinking water plant. 1 SlituwdagsedifsrcoomvethreedPotrhtatStp.laLnutcsiteafPfOdiTdWnotwatsakperes-lturdegaetefdrsolmudtghee. apApfrtoeprrisaatmeplsilundggaetcthhaemPbOerT.W, 1 THheeipnlfaonrtmmeadnuasgetrha,tMtrh.e sCalruldgNeowratsoncowlalsecctoendtfacrtoemdtthoecCohnlfoirrimnethCeonextaacctt sCahmapmlbienrg.location. ` | TnhotebaeccfuoruancdyaonfdtthheeGaPcScurwaacsynoofttvheeriGfPieSd iwnasPonrottStv.erLifuiceide.. TAhtethmiasncuiatyl afboerntchehmGaPrSk could indicates however that if two cities are within 500.miles than a second verification is not needed. Qsuaimepslcienngtswiatetseranwdatsinmoetwsaasmsphloerdt.atTthhee Bpartet-edlelseipgrnoajteecdtsmiatenabgeecrau,sMeairtcwiaasNfiasrhfiorkoamatphperootvheerd changing the location for this reason. " Final Field Rpt Columbus GA Port St. LucieFL 1paNotgectlioeTo ork00104488 1 Field Report Addendum ~ Columbus, Georgia and Port St. Lucie, Florida Surveys 1 AretsmpoescpthteorsiacmSplaemrplpiosnigtiDeotnaiinlgs.. The following details are included here to complete the field record with 1 Cstoaltuiomnbusst,atGioAn:#1T)hleocaiartesdaatm20p1alt10etthihrsSsteieet.ws positioned approximately 1 foot from the 2-story fire o PstoorrtyStf.irLeusctiaet,ioFnL(:staTthieona#i5r)salmopcalteerdiantP1or6t16StPoLrtucSit.e LwuacsiepoBsoiutlieovnaerdda.pproximately 3 feet from the 2- gta `Surface Water Sampling. The following details are included here to complete the field record with respect 1 Cwoalsucmoblulsec,teGdAw:itThhien s2umrfoafceswhaotreericnoclal.ec0t.e5dmatdaepcthh.ofT3hesitcelsielnotcaautdeidtweidtthhiins Osltiev.erSaLmapkleeisnweevreerycoclalseected aas5:retceaomm;meonndeepdebrysonthweacdleiednti.ntIontthheswawtaeyr,tthheefiseelcdocnrdepwerrseodnucperdeptahreerdisaknodfter-anssufseprerendditnheg ssaemdpilmeenbtost,tles Re-suspended bottom sediments were avoided. PSoyrsttSet.m wLuacsiec,olFlLe:cteTdhienscuarcfhacceasweatweirthcionl2lecmtoedfatsheoarcehionfcat.he0.35smitedsewpitht.hinReth-esuPsorptenSdt.edLubcoitetRoimver sediments were avoided in each case. Kelly, hlsg tel bury Operations Date. Chis atelle Duxbury Operations G7 001029