Document 71oVk0RmyqNwmE9Y7aNnVE7wj
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CenGt4re8 RAesneaarlchyDtircailvLeaboraSttatoeCrolileeges,,PATGI3n0cT-. Phone: (814)231-6032 Fax: (814) 231-1253 or (814) 231-1580
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Fluorochemical Characterization of Drinking Water Samples
Decatur, Alabama (W1879)
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Centre Analytical Laboratory Report No. 023-0078
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es------ ees Testing Laboratory
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Centre30An4a8lyRteicsaelarLacbhorDartiovrey, Inc.
State College, PA 16801
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3M Environmental Laboratory Contact
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KeBnldtg., 2L-i3nEd-st0r9om
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P.O. Box 33331
St. Paul, MN 55133-3331
Phone: (651) 778-5362
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etree --ree-- Requester
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3M EnvironmenKtiaslJT.eHcahnnsoelno,gyPh&.DS.afety Services
Bldg, 2-3E-09
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P.O. Box 33331
St. Paul, MN 55133-3331
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00338
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Pacerors
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1 Introduction
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The samplesweropreparedandanalyzed byLCIMSMS forthefolowingisoffuorochemicais:
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Table :TargetAnalysis:
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[Perfuoroocene Sufonsle [Pertuorooctane Sufortarmide
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aiPDnrmaadetc.artigceensee(rGaaLrtsPeesod)n.iuni"esTwuhspieptaohnratClyeotnfitctarhl.isDmeastttuhadopydrweuassseendgtewendaehsrearvtaeelfdisdaattcheecdhobirygdihCneegsntttroqeuUa.lSitTEyhPdeAatvaGaalovioaadiiaoLbnalbepoorrfoatttoohcrsey
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2 Sample Receipt
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Tcinohdleiviiscdauimanlpldseaastmepwslewerceoornsetuanbiomtniestruseppdwleiiernden.crvCeihcdaeuiiavnel-do.pflcaSsutasitmcopcdloyensianwifenoerrrmeasrteaiconnediwivseeprdreeosnneont0t2ep/dr15ei/sn0eA0rt.vieadTc.hhmeFeosnuattmAopelne
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3 Holding Times
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sTtahbeilatnyaolyfttihceaalnmaeltyhtoesdoufsientdewreasstfvoarlliodnagteerdpaegraiiondsshtaasmnaoxtibmeuemndheotldeirnmginteidm,eof 14days. The
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4 Methods - Analytical andPreparatory
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444414 SLaCm/pMloS/PrMeSparation for LMSIMS Analysis
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TdhiseccaarrdteiddgaendwahsefrSsPtEekceolduwminthwasmLthoefn4e0b%temdetwhiahno1l0i0n%wamtearnsaoulion.A Thpeigopoennseon:
`mceotnhcaenntorlatwioansofcotlhleecstaemdpfloersapnrailoyrstiosabnaylyLsiCsI.MSIMS. This treatment resulted in an eightfold
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412 SamploAnablyyLOsMiSMsS
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omkHrniPgodaLwnCntiecsfmelpcpueoaorrmraaptotouciruhoennes,rd;isEc,maSosiMlnrceSlecuipdoeirbnossgveiafrdrleveuseodroaoiaczrhnaeedpmdiiq,dcuaaaflnnrsiad.rgaamEtcelecnedutcreatadgrt,aoeisamnpnesrdiaassndytsaognlefdnocaerreraca.nslallyylozopinenegracathewdairdartereerltaatntigeveeoloyf
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AraHehwaietPacskaamrpdlHePe11s0a0cH,PLACnsaysstemwacsoupplaedrotomaodMicsrionmgassseUltelmca MaStIoMSrwas used fo
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found in attachment D. (SRM).
2119100.
Samples were extracted on 2/18/00 and The HPLC and MS/MS methods used for
analyzed by MSMMS between 2/18/00 and `analysis andinstrument parameters can be
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5 Analysis
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51 ACaTl-ipbarinatciaolnbraon cuwarsanvalyezadal thebegining andendofthe anslytal sequence
50fo0r,thaendco1m0p0o0unngds.(opfpitn)tTerheset.reTshpeoncsaeliobrfatthioen qpuoainntttsatwieorneiopnrevpearrseuds tathe0,co2n5,ce5n0i,at1i0o0,nw2a50s,
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Calbratonstandardsaepreparedusingthe sameSPEprocedureusedfor samples.
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Calbration check standards wereanalyzedperiodical
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For theresuls reportedhere, calbrationcriteriawero met.
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52 Blanks
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`samples presented here the instrument blanks are compliant.
53 Surrogates
`Surogale spikes are nota component of the LCIMSIMS analytical method.
54 `MMcaatotrmirpxiouxsnpdSkspeiosfkiwenetserreestp.reMpaatrriexdsfpokreerveecroyvesriaemspalreeagtivaenicnoAnctetnatcrhatmieonnt oCf. 100 nglL using all
cFioemldposupnkdessofweirnteeraessto.Fpireeldpasrpiakeonrseevecraol svaarmeepallressoiagetivasencoinncAatnatcathomneonCft.100 nolL using al
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ADlul pslaimpclaetseswere analyzed in duplicate. tachment .
Resulsaregiven along with the sample resus in
56 2ML5aaibnaogwrLaatLetCroSwraysshCosowpnektderdloowlwitrSh aaelmlccpolomfepovsoruPenFdrOSoyf.inTfheeststaatn2d5aradnwda2s50renlngje.cieIdiaenldanwaalsysfisouonfdtthge 1ha3v0e%aicnceeaplcahblLeCSr.ecovery (70-130%). Al herrecoveries for all compounds were between 70.
57 tFShiaerlomdupgbhllaaenkhRysepaelmrapctalreebsdccCaornotsrmiisdmtgeeedwnaotfsseamdpdteydctoonttahieneerms.ptyFocrolnytamiinlertearnsdoafntaylpyeze|dwiantetrheistearmeed mame as the other samples,
6 Data Summary
Please see Atchment B for a detated listing ofth analytical resus,
7 Data/Sample Retention
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8 Attachments
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9 Signatures
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