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FIRE AND EXPLOSION INDEX MANUFACTURING UNIT LIGHT HYDROCARBON H PROCESS UNIT PROPYLENE DEHYDRATORS 2C-30 A&B BACKGROUND INFORMATION FOR PROPYLENE DEHYDRATOR AREA: The 2C-30's are dehydrators for drying propylene from the Well. The vessels are 6 feet 6 inches in diameter and 45 feet in height. The dehydrator are filled with activated alumina as drying raeduim. 2C-30A is filled with Alcoa 1/4 x 8 mesh F-l (flakes). 2C-30B is filled with Kaiser 1/4 x 8 mesh A-20I (balls). The bed were lasted changed out in September of 1983. The beds are filled with 1200cf of alumina. The external void fraction is approximately 0.25. (take from an article by titled Gas Adsorption by James R. Fair. The material of construction of the vessel is SA-212 GR B FBX. The design pressure is 400 PSIG at 650F. The normal operating conditions are amibent temperature and 300 PSIG. Volume for the drum is calculated below: V=(7tr2H) V=(Jt(3.35)2 (45) = 1493 cf The volume of alumni was subtracted from the vessel volume. Material Factor (from Appendix A of Fire & Explosion Index Hazard Classification Guide) Compound ' Propylene He MF BTU/LB xlO3 21 19.7 Na V Nr 141 Flash Potato* F) : -162 Boiling Point <F) -54 General Process Hazards: (Information) The only penalty of 0.5 was taken for drainage and control. Special Process Hazards:(lnformation) A penalty of 0.2 for toxic material using the Nh of propylene. No penalty was taken for sub*$tmospheric pressure. No penalty was taken for operation in or near flammable range. No penalty was taken for dust explosion. The operating pressure penalty was 0.4836. The set pressure penalty was .6116. A factor of 1.2 for compressed gas was used. The final pressure penalty was .45. A low temperature penalty of .3 was taken. The penalty for quantity of flammable/unstable material was .77. The quantity was calculated with only one dehydrator in service.The flammable penalty was .36. Penalties of 0.1 was taken for both corrosion and erosion and leakage. No penalties were taken for use of fired equipment, hot oil exchange system, or rotating equipment. Loss Control Credit Factors 7/10/95 FEI.doc HWR DOW CONFIDENTIAL 00 A 031 CONFIDENT Process Control Credit Factor (Ci) Emergency Power -0.98 A credit was taken for Emergency Power due to the UPS system. Cooling-1.0 Explosion Control-1.0 Emergency Shutdown-1.0 Computer Control-1.0 Inert Gas-1.0 Operating Instructions/Procedure-1.0 Reactive Chemical Review-0.91 A credit was taken for reactive chemical review. Reactive chemical concerns are listed on MOC sheet and plant personal are trained and tested on reactive chemical concerns at LHC II. Other Process Hazard Analysis- 0.98 for Management of Change Review Material Osolation Credit Factor (C2) Remote Control Valves-1 Dump/Blowdown-1 Drainage-1 Interlock-1 Fire Protection Credit Factor (C3) Leak Detection -.94 LHC II is protected by Bacharach gas detectors. A project is being worked on the elevalate the gas detector system and replace with a more relible system. Structural Steel-1 Fire Water Supply- 0.94 (supply pressure will be approximately 100 p$ig without pump and 150 psig with pump.) Sprinkler Systems-,97 A credit was taken for the deluge systems at LHC II. Water Curtains-1 No credit was taken for the furnace water curtain due to its height and that furnace 1-6 and 19-25 are unprotected are the lower level. Foam-1 Hand Extinguishers/Monitors-.97 Cable Protection-1 (This credit would change after completion of the Instrument Upgrade Project) 7/10/95 FEI.doc HWR DOW CONFIDENTIAL Do 4 Co^TD 103 COMMAND ==> INQUIRE FIXED EQUIPMENT 05/30/95 12:22 Equip ID Cost Center Serial 0 "ssoc Ser 0 Parent ID PSV 2C-30 AA 0000063 2809--X 2C-30 A Eq Desc: SAFETY VALVE #807999 Unit: Criticality: 01 Area: 2C-30 Project: Equip Code: _____________ Type: ________ Equip Cond: ____ ______ Spec: Grid: Fleet MGMT?: nstall Dt MFR Abbrev ANDRSN Model Type 33310H23/S GEMTS-> Prod / Process: Eqp Group / Type : Model #: Model Size; 2" X H X 3" PRODUCT DISTRIBUTION 2D-30 A/B PRESSURE VESSEL/VALVE PRESSURE R k * * SPECIFICATION TEXT * * * INSPECTION SCHEDULE: 60 MONTHS OPERATING TEMP: 50 DEG. F BACK PRESSURE: 0 MTD Cost: 0 YTD Cost: Last PM: 0 Sel: 0 Last Updated By: VALVE SET PRESSURE: 400 P8IG OPERATING PRESSURE: 250 PSIG PRODUCT: PROPYLENE VAPORS 0 LTD Cost: Date Installed: NPL0467 Date: 06/06/94 GN-10 < RESET COMPLETE > 00048 17 434 174 PF1 = VIEW SPEC PF2 = PF3 = BROWSE PF4 PF5 = PF6 = MENU PF7 = PREV RECORD PF8 = NEXT RECORD PF9 = PF10 = PF11 = PF12 * DO A 031044 CONFIDENT! Al INQUIRE FIXED EQUIPMENT 05/30/95 12:23 Equip ID: FSV 2C-30 AB Eq Desc: SAFETY VALVE #808000 Unit: Cost Center: 00 63 Criticality: 01 Ar a: 2C-30 Project: Serial #: 2810-K Equip Code: _______________ Type: 'ssoc Ser #: Parent ID: 2C-30 A Equip Cond: ________________________________ Grid: ________ Fleet MGMT?: nstall Dt: MFR Abbrev: ANDRSN Model #: Model Type: 33310H23/S Model Size: 2" X H X 3" GEMTS-> Prod / Process: PRODUCT DISTRIBUTION 2D-30 A/B Eqp Group / Type : PRESSURE VESSEL/VALVE PRESSURE R * * * SPECIFICATION TEXT * * * INSPECTION SCHEDULE: 60 MONTHS VALVE SET PRESSURE: 400 PSIG OPERATING TEMP: 50 DEG. F OPERATING PRESSURE: 250 PSIG BACK PRESSURE: 0 PRODUCT: PROPYLENE VAPORS MTD Cost 0 YTD Cost: 0 LTD Cost: Last PM: Date Installed: # Sel: 0 Last Updated By: NPL0467 Date: 06/06/94 GN-10 < RESET COMPLETE > 00048 17 434 139 PF1 = VIEW SPEC PF2 = PF3 = BROWSE PF4 = PF5 as FF6 = MENU PF7 = PREV RECORD PF8 = NEXT RECORD PF9 = PF10 = PF11 = PF12 s MAIN MENU \ i 103 COMMAND ==> ______ INQUIRE FIXED EQUIPMENT 05/30/95 12:23 Equ'^ ID Cost Ct-.cer Serial # 'ssoc Ser # PSV 2C-30 BA 0000063 2811-K Eq Desc: SAFETY VALVE #808001 Criticality: 01 Area: 2C-30 Equip Code: _________ Equip Cond: ____ ______ Unit: Project: Type: Spec: Parent ID 2C-30 B Grid: Fleet MGMT?: nstall Dt MFR Abbrev ANDRSN Model #: Model Type 33310H23/S Model Size: 2" X H X 3" GEMTS-> Prod / Process: PRODUCT DISTRIBUTION 2D-30 A/B Eqp Group / Type : PRESSURE VESSEL/VALVE PRESSURE R * * * SPECIFICATION TEXT * * it INSPECTION SCHEDULE: 60 MONTHS VALVE SET PRESSURE: 400 PSIG OPERATING TEMP: 50 DEG. F OPERATING PRESSURE: 250 PSIG BACK PRESSURE: 0 PRODUCT: PROPYLENE VAPORS MTD Cost: 0 YTD Cost: 0 LTD Cost: Last PM: ___________ Date installed: # Sel: 0 Last Updated By: NPL0467 Date: 06/06/94 GN-10 < RESET COMPLETE > 00048 17 434 0 PF1 = VIEW SPEC PF2 = PF3 = BROWSE PF4 * PF5 = PF6 = MENU PF7 = PREV RECORD FF8 = NEXT RECORD PF9 = PF10 = PF11 = PF12 = MAIN MENU DO A 031345 CONFIDENTIAL 103 COMMAND ==> INQUIRE FIXED EQUIPMENT 05/30/95 12:23 Equip ID: PSV 2C-30 BB Eq Desc: SAFETY VALVE #808002 .Cost Center: 0000063 Criticality: 01 Area: 2C-30 Unit: Project: Serial #: 2812-K 'ssoc Ser #: Parent ID: 20-30 B _________ Equip Code: Typ : Equip Cond: ____ _________ Sp c: Grid: _____ . Fleet MGMT?: nstall Dt: MFR Abbrev: ANDRSN Model Type: 33310H23/S Model #: Model Size: 2" X H X 3" GEMTS-> Prod / Process: PRODUCT DISTRIBUTION 2D-30 A/B Eqp Group / Type : PRESSURE VESSEL/VALVE PRESSURE R * * * SPECIFICATION TEXT * * * INSPECTION SCHEDULE: 60 MONTHS VALVE SET PRESSURE: 400 PSIG OPERATING TEMP: 50 DEG. F OPERATING PRESSURE: 250 PSIG BACK PRESSURE: 0 PRODUCT: PROPYLENE VAPORS MTD Cost: Last PM: # Sel: 0 YTD Cost: Last Updated By: NPL0467 0 LTD Cost: Date Installed: Date: 06/06/94 GN-10 < RESET COMPLETE > 00048 17 434 153 PF1 = VIEW SPEC PF2 = PF3 = BROWSE PF4 = PF5 PF6 = MENU PF7 = PREV RECORD PF8 = NEXT RECORD PF9 = PF10 * PF11 = PF12 = MAIN MENU ( 031346 DO FIRE & EXPLOSION INDEX AREA/COUNTRY DIVISION LOCATION DATE USA SITE Louisiana PREPARED BY: Louisiana MANUFACTURING UNIT Plaquemine PROCESS UNfT June 19,1995 Light Hydrocarbon II Propylene Econfmlzer (2D-120) APPROVED BY: (SupMtntondit) Building NO. Holly Rood REVIEWED BY: (ManapvnMM) 7 REVIEWED SY: (Technology Contoi) B4801 REVIEWED BY: (Stffty A Lon Pwtntlon) 7 MATERIALS IN PROCESS UNIT 7 7 Propylene STATE OP OPERATION BASIC MATBRIAUS} FOR MATERIAL FACTOR __DONN .WART UP _X.lNNUML OPOUtMN Propylene MATERIAL FACTOR (See Table 1 or Appendices A or B) Note requirements when unit temperatures over 140 ! 21 1. General Process Hazards Penalty Fac Penalty Fac tor Range tor Used (1) Base Factor..................................................... ......................................... 1.00 1.00 A. Exothermic Chemical Reactions 0.30 to 1.25 0.00 B. Endothermic Processes 0.20 to 0.40 0.00 C. Material Handling and Transfer 0.25 to 1.05 0.00 D. Enclosed or Indoor Process Units 0.25 to 0.90 0.00 E. Access 0.20 to 035 0.00 F. Drainage and Spill Control 0 gallons 0.25 to 0.50 0.50 General Process Hazards F actor (FI).......................................................................... 1.50 2. Special Process Hazards Base Factor.................................................................... ........ ....__ ...... 1.00 A. Toxic Material^) 0.20 to 0.80 B. Sub-Atmospheric Pressure (< 500 mm Hg) C. Operation In or Near Flammable Range ___ INERTED _X_ NOT INERTED 0.50 1. Tank Farms Storage Flammable Liquids 0.50 2. Process Upset or Purge Failure 0.30 3. Always in Flammable Range D. Oust Explosion (See Table 3) 0.80 0.25 to 2.00 E. Pressure (See Ftaure 21 Operating Pressure 300 psie Relief Setting 220 twifl F. Low Temperature 0.20 to 0 30 G. Quantity of Ftammabie/Unstabte Material Quantity 33.620 lb HSi ISJOfiL Piyzii? 1. Liquids or Gases in Process (See Figure 3) 2. Liquids or Gases in Storage (See Figure 4) 3. Combustible Solids in Storage, Dust in Process (See Figure 5) H. Corrosion end Erosion 0.10 to 0 75 1. Leakage - Joints and Packing 0.10 to 1.50 1.00 0.20 0.00 0.00 0.00 0.00 0.00 0.76 0.00 1.21 0.00 0.00 0.10 0.00 J. Use of Fired Equipment (See Figure 6) 0.00 K. Hot Oil Heat Exchange System (See Table 5) L. Rotating Equipment 0.15 to 1.15 0.50 0.00 0.00 Special Process Hazards Factor (F2)........................................................................... 3.27 Process Unit Hazards Factor (FI x F2) F3............................................................. Fire and Explosion Index (F3 xMF F&Ef)................................................................. 4.90 103 (1) For no penalty use 0.00. 00 A 031347 CONFIOFNTlAi FORM C-22300 Rw/01-M (47140036). (FIE-7 SyMwn Var-2.1 </31W4| Print Date: 7/12/95 LOSS CONTROL CREDIT FACTORS 1. Process Control Credit Factor (Cl) Feature a. Emergency Power b. Cooling c. Explosion Control d. Emergency Shutdown *. Computer Control Credit Factor Range 0.98 0.97 to 0.99 0.84 to 0.88 0.96 to 0.99 0.93 to 0.99 Credit Factor Used (2) 0.98 1.00 1.00 1.00 1.00 Feature f. Inert Gas ? Operating Instructions/Procedures h. Reactive Chemical Review i. Other Process Hazard Analysis Credit Factor Range 0.94 to 0.96 0.91 to 0.99 0.91 to 0.96 0.91 to 0.98 Credit Factor Ueed(2) 1.00 1.00 0.98 0.98 Cl Valua (3) | 0.941 | 2. Material Isolation Credit Factor (C2) Feature a. Remote Control Valves b. Dump/Blowfewn Credit Factor Range 0.96 to 0.98 0.96 to 0.98 Credit Factor Used (2) 1.00 1.00 Feature c. Drainage d. Interlock C2 Valua (3) | 1,000 | 3 Fire Protection Credit Factor (C3) Feature a. Leak Detection b. Structural Steel c. Fire Whter Supply d. Special Systems e. Sprinkler Systems Credit Factor Range 0.94 to 0.98 0.95 to 0.98 0.94 to 0.97 0.91 0.74 to 0.97 Credit Factor Used (2) 0.98 1.00 0.94 1.00 097 Feature f. Water Curtains 9 Foam h. Hand Extinguishers/Monitors 1. Cable Protection C3 Valua (3) | 0.867 1 Loss Control Credit Factor Cl x C2 x C3 (3) I 0,818 **") Credit Factor Range 0.91 to 0.97 0 98 Credit Factor Used (2) 1.00 1.00 Credit Factor Range 0.97 to 0.98 0.92 to 0.97 0.93 to 0.98 0.94 to 0.98 Credit Fector Uaed (2) 1.00 1.00 0.97 1.00 PROCESS UNIT RISK ANALYSIS SUMMARY 1. Fire and Explosion Index (F6EI)........... (See Front) 103 2. Radius of Exposure..................................... <fig tj 86 3. Area of Exposure......................................................--........ 23436 4. Value of Area of Exposure (1994 Dollars)....................... 5. Damage Factor.......................................................... 0.73 6. Base Maximum Probable Property Damage - (Base MPPD) (4 x 5].................... 7. Loss Control Credit Factor ......................... (See Above) 0.82 8. Actual Maximum Probebl# Property Damage (Actual MPPD) [6x7].... 9. Maximum Probable Days Outage (MPDO) (Ftg<n ) 96 10. Business Interruption - (Bl).................................................... ft sq.ft. SMM $MM $MM days $MM 21 43 15.73 12.83 67.12 | | | | (2) For no credit factor enter 1.00 (3) Product of all factors used Refer to 'Fire & Explosion Index Hazard Classification Guide* (Form #471-00001) for details BACK OF FORM C-223*0 Rwx)1-#4 (471-00036) - (F1E-7 SyMam Vr-Z 1 - 40)294) Print Date: 7/12/95 00 A 031346 CONFIDFNTTAi. FIRE & EXPLOSION INDEX DATA AND COMMENTS MUtdsLEeslef Matenai It Fram Otitbttt Materiel Name - Propyien. Bttt Material Factor II A4|uated Material Factor 21 Haat at Cernfeuation (BTUA>) > 1*700 Hr * a Nr* 1 Fiat* Pott rF)*-lC2 BOdngPoM(*F)*-54 Piooaaa On* Temperatue pp). 1JO Exotherm Temperature (*F) 1000000 AitedpidonTainpemlua (*F)* HI Date For Uaw Specified Maleml Qmimi Procaaa HbmkI* A. Exothermic Chemical Reacdone Prooaaa Ura NOT A REACTOR antUor NO EXOTHERM aeon (Peney*0) Comma 0 B. Endodiermlc Proeaaaaa prooaaa Una NOT A REACTOR --> Panay-0 Comma 0 C. Matertel Handteig and Trineler Nona 7 tea Mowdig atuadona appRr (PenetyO) Comma 0 0 Enctoeed or Indoor Proceed Uni procaaa la NOT ENCLOSED (Peney*0) Comma 0 E. Accaaa Accaaedatennlned adequate ter emergency equipmerdfftetteayO) Comma 0 F. DmkageandSpBCotaiol FNt, iM*lmd a mtiMi atom aptte to apread on (Panaty*0.90) comma o Soactel Procttt Haxarda A Trade MaterMW E^ate tern tends or die Nh B SufrAonoaphortc Praaaiaa (< *00 mm Hq) Oraalar than 500 mmHg (Per*ly*0) Comma 0 C. operation In or Naar Ftemmaete Range Procaaa W nonaach the ttemimtte range (PonatyO). Comma 0 D. OuatExMoator Prooaaa doaa not PcMte duels (pana*y*0) Comma 0 E. Praaaue Comma 0 F. Lo* Temperature Tempanturoa remain eteely eeoue the mjaaemmo* Comma 0 0. CXandty 0l FtemmaMaUreraMe Material In Prooaaa Comma 0 K ConaaionandEroHon Cormalon rama below 05 mmryr WITH flak or pktrnQ endlor Gamma 0 1. LaaMga doarta and PacMng Leakey of IterwmUtealiiaiilmolMao a taardart Comma 0 4. Uaa ot Fbad Equlpmard DOES NOT ardrttidio part addi die Pmnoot Ur* Comma 0 K. Hot 01 Heat Exchange Syetem Procaaa doaa not uaa a hot oi aorchanga ayatem, or the hot ol Comma 0 L RotatXig Egutpmart No rotating equipment oaamafl to Da a tmxerd (No Penalty) Comma 0 re-T mm w-21 * mvm) 00 A 0:iJ349 CONFIDFNT T Al prlrtDM*: 7/12/95 LOSS CONTROL CREDIT FACTORS - DATA AND COMMENTS Process Control Credit Factor IC1I a) Emergency Power Automatic switch to emergency power tar CRITICAL SERVICES Comme 0 b) Cooling No credit (Faetor-1,0) Comme 0 c) Expkxon Cortrol No credit (Feetor*1.0) Comme 0 d) Emergency Shutdown No credit (Factor-1 0) Comme 0 e) Computer Control No credit (Fsetor-1 .0) Comma 0 I) Inert Gas No credit (Factor-10) Comme 0 g) Operating Inatructions/Procedures Comme 0 h) Reactive Chemical Review Reactive Chemical reviews done only on an occasional basis Comme 0 i) Other Process Hazard Analysis Management of Change Review (Fsdor-0.98) Comme 0 Material Isolation Credit Factor (C2) a) Remote Control Valves No credit (Factor-1.0) Comme o b) DumpQJowdown No credit (Factor-1.0) Comme 0 c) Drainage No credit (Factor-10) Comme 0 d) interlock No credit (Factor-1.0) Comme 0 Fire Protection Credit Factor (C3> a) Leak Detection Gas detectors alarm and identity a zone only (Factoi-0.98) Comma 0 b) Structural Steel No credit (Factor-1.0) Comme o c) Fire Mater Supply Firefighting water can be supplied tor 4 hours at 100 psig (7 Comme 0 d) Special Systems No credit (Factor-1.0) Comme 0 a) Sprinkler Systems Deluge system protects process (Factor-0 97) Comme 0 f) water Osteins No credit (Factor-1.0) Comma 0 g) Foam No credit (Factor-1.0) Comme 0 h) Hand Exbnguishers/Monltois The process a protected by monitor guns (Factor-0.97) Comme 0 i) Cable Protection No credit (Factor-1 0) Comme 0 tns-l Sy-M vtr.JJ . KIWI] DO A 031350 CONFIDENTIAL Print Date: 7/12/95 ... iHim nnruivi fUK UNMKEO PRESSURE VESSELS Alternate Form for Single Chamber Completely Shop-Fabricated Vessels Only 1. Manufactured by. 2. Manufactured for. AMF BEAIRD. IHC.r SHREVEPORTT LOUISIANA___________ * (Nine and address of Manufacturer) 3. Type- lorU^ .Vessel No, (. lima (Horn. or Vert ) (Mfrr. Sena!) (State * Stat* No.) _Yr. Built. 1967 4. SHELL: Marl limlH-BwllW T.S 70,000# Th"`ajjp^fln. DiamJ___Ft.j5__ In. Length*# Ft. S__ In. (Kind and Spec. No.) (Fig. or F.B. & Spec. Min. T.s#4d(| 1/1$ j. SEAMS: Long.]ftl. htt_____ H.T_____ SBOft_______XX.RR___yfyaoftgt_SeScetciorinntued____ IQ___ Efficiency -M (WeldedI, Dbl , Single, Lap, Butt) (Yi or N) (Spot or Complete) (Yet or No) Girth. PM. Butt -M______ x.r.. -Spot. .Sectioned_____ No. of Courses. If riveted or brated describe east* fully under remarks. . HEADS: (a) MateriaL --TJi. 70,000# Material jrs^ Location (ToptJ>ottnm, cods) (a) _____ l______ j2!S Crown Radio* Knuckle Radius Elliptical J3EL Conical Hemispherical Apex Angle Radio* Plat DiaractCt Side to Prc**ure (Coovet of Concave) __ Coacevt . . <b)---------------------------If removable, bolts used- (Material. Spec. No., T.S., Site, Number) .Other fastening. (Deacribc or Attach Sketch) 7. Constructed for mu. allowable working press'. _509_ -psi. at mu. temp. -A5S. |. SAFETY OR RELIEF VALVE OUTLETS: Number. Min. temp, (when F. less than --20*). -Size. J!L -LocationTop of. tank la shell. 9, NOZZLES: OPuurtpleots,i,eeDr((1rIanilne)t, Number Dieam,. or Size Type 1-1/2" 300# Lone Veld lack Pie. S J'jj L10. INSPECTION Manholes, No------------- OPENINGS: Handholes, No__________ Threaded, No.__________ 6.TaL, JtJ-r -Size. -Size. -Size. JXL Material Thick acss JA.-1BW .Location Irtfatinn .Location. Reinforcement Material How Attached Welded Welded SUPPORTS: Skirt___________ Luge -Legs. _Othe (Y or No) (Number) (Number) (Describe) Attached. (Where A How) .12 REMARKS: 3-l/i" O.A. Lattgth 13,703 V.C. Btorege tSahp-yr leetrd (Brief description of purpose of the vessel as Air Tank, Water Tank, L.P.C., Etc.--State Content*. ` If postweld beat-treated, 1 List other internal or eztemal pressures with coincident temperature when applicable mruitWWe eertlfy that the statement* made in this report are o, conform to the ASMS Code for Unfired Pressure Vestel*. details of design, material, construction, and workman*: Date- 7-3 .19. 7______ R-.r^ AMF BEAIRD. INC. (Manufacturer) Certificate of Authorization Expires. 31. 1970 of this vessel CERTIFICATE OF SHOP INSPECTION VESSEL MADE BY AMF BEAIRD. INC. at SHREVEPORT. LOUISIANA I, the undesigned, holding a valid comiaiiiion iaaued by the National Board of Boiler and Ptetaure Veaaet Inapectora and/or tbe State of N. B. ,,d employed by THE COMMERCIAL UNION INSURANCE COMPANY of data report On 7*3 _ NEW Y0RK beve inapected tbe preature veaael deacribed in tbia manufacturer's ld7 _ end ,tate tbit to the beat of my knowledge end belief, tbe manufac turer haa conitructed thia preaaure veaael in eccorduce with the applicable aectioni of the ASME Boiler and Preature Veaael Code. By aigning tbia certificate neither tbe Intpector nor hia employer makea any warranty, expretaed or implied, concerning tbe preature veaael deacribed in tbia mmiufecturcr*! data report. Furthermore, neither the Intpector nor hia employer ahall be liable in nny manner for any peraontl injury or property damage or a loaa of any kind ariaing from or connected with thia inapection. D0 A 031 351. oonftdfnttai 103 COMMAND ==> INQUIRE FIXED EQUIPMENT 05/30/95 10:46 Equip ID Cost Cenlcr Serial # ;oc Ser # Parent ID P5V ZD-120 A 0000063 34852 M6 2D-120 Eq Desc: SAFETY VALVE #803051 Unit: Criticality: 01 Area: /ECK Project: Equip Code: ______ Type: _________ Equip Cond: ____ ___ Spec: Grid: Fleet MGMT?: install Dt MFR Abbrev CROSBY Model #: ________ Model Type JO-35A GEMTS-> Prod / Process: Eqp Group / Type Model Size: 2 1/2" X J X 4" REFRIGERATION 2TK-120 SYS PRESSURE VESSEL/VALVE PRESSURE R * * * SPECIFICATION TEXT * * * INSPECTION SCHEDULE: 60 MONTHS VALVE SET PRESSURE: 300 PSIG OPERATING TEMP: 100 DEG. F OPERATING PRESSURE: 220 PSIG BACK PRESSURE: 0 PRODUCT: PROPYLENE VAPORS MTD Cost: 0 YTD Cost: 0 LTD Cost: Last PM: # Sel: 1 Last Updated By: U432414 Date Installed: Date: 10/30/89 00048 17 434 191 PF1 = VIEW SPEC PF2 = PF3 = BROWSE PF4 = PF5 = PF6 = MENU PF7 = PREV RECORD PF8 = next RECORD PF9 = PF10 * PF11 = PF12 = MAIN MENU ( * ( 00 A 0333 conftdfnttai 103 COMMAND ==> INQUIRE FIXED EQUIPMENT 05/30/95 10:47 Equip ID Cost Center Serial # oc Ser # PSV 2D-120 B 0000063 34852 M6 Eq Desc: SAFETY VALVE #803052 Criticality: 01 \rea: 71DBCK Equip Coats: _________ Equip cond: ____ _________ Unit: Project: Type: Spec: Parent ID 2D-120 Grid: ____ Fleet MGMT?: .nstall Dt MFR Abbrev CROSBY Model Type J0-35A GEMTS-> Prod / Process: Eqp Group / Type : Model #: ________ Model Size: 2 1/2" X J X 4" REFRIGERATION 2TK-120 SYS PRESSURE VESSEL/VALVE PRESSURE R * * * SPECIFICATION TEXT ** INSPECTION SCHEDULE: 60 MONTHS VALVE SET PRESSURE: 300 PSIG OPERATING TEMP: 100 DEG. F OPERATING PRESSURE: 220 PSIG BACK PRESSURE: MTD Cost: 0 0 YTD Cost: PRODUCT: PROPYLENE VAPORS 974 LTD Cost: Last PM: # Sel: o Last Updated By: U432414 Date Installed: Date; 10/30/89 GN-10 < RESET COMPLETE > 00048 17 434 1316 PF1 = VIEW SPEC PF2 = PF3 = BROWSE PF4 = PF5 PF6 = MENU PF7 = PREV RECORD PF8 = NEXT RECORD PF9 = PF10 = PF11 PF12 = MAIN MENU FIRE & EXPLOSION INDEX MAjCQWTRY CXVtSfDN location GATE USA SITE Louisiana MANUFACTURING UNtT Plaquemlne PROCESS UNIT 7/5/95 Louisiana PREPARED BY: Light Hydrocarbon II Acetylene Reactors (2R-1 A/B) APPROVED BY: (SupBUwtwidtot) BUILDING Holly Reed REUCWED SY: (Menegemetrt) 7 REVIEWED BY: fTtcrfinotoW Cwrt*r) B4S01 REVIEWED EY: (SMsty S Lee* Prevention) 7 MATERIALS IN PROCESS UNIT ? 7 Ethylene, Ethane, Methane, Hydrogen, Acetylene STATE OP OPERATION ASIC MATERIAL!*) FOX MATERIAL FACTOR _0nww TART UP .XHOMMlPPBRATMN UlTPCMM Ethylene MATERIAL FACTOR (See Table 1 or Appendices A or B) Note requirements when unit temperatures over 140 "I 24 1. General Process Hazards Penalty Fac Penalty Fac tor Range tor Used (1) Base Factor....... ,....................................................................................... 1.00 1.00 A. Exothermic Chemical Reaction* 0.30 to 1.25 0.30 6. Endothermic Processes 0.20 to 0.40 0.00 C. Material Handling and Transfer D. Enclosed or Indoor Process Units 0.25 to 1.05 0 25 to 0.90 0.00 0.00 E. Access 0.20 to 0.35 0.00 F. Drainage and Spilt Control 0 gallons 0.25 to 0.50 0.50 General Process Hazards F 1.S0 2. Special Process Hazards Base Factor................................................................................................ 1.00 A. Toxic Materlal(s) 0.20 to 0.80 B Sub-Atmospheric Pressure (< 500 mm Hg) 0.50 C. Operation In or Near Flammable Range ___ INERTED _X_ NOT INERTED 1.00 0.20 0.00 1. Tank Farms Storage Flammable Liquids 2. Process Upset or Purge Failure 3. Always in Flammable Range D. Dust Explosion (See Table 3) E. Pressure (See Figure 2) F. Low Temperature O. Quantity of Ftammable/Unstable Material 0.50 0.30 0.80 0.25 to 2.00 Operating Pressure 350 osk Relief Setting 475 Data 0,20 to 0.30 Quantity 6.158 lb 0.00 0.00 0.00 0.00 0.60 0.00 He- 20.80Q_ BTLMb 1. Liquids or Gases in Process (See Figure 3) 2. Liquids or Gases in Storage (See Figure 4) 3. Combustible Solids in Storage, Oust in Process (See Figure 5) H. Corrosion and Eroaion 0.10 to 0.75 1. Leakage Joints and Packing 0.10 to 1.50 0.22 0.00 0.00 0.10 0.10 J. Use of Fired Equipment (See Figure 6) 0.00 K_ Hot Oil Heat Exchange System (See Table 5) 0.15 to 1.15 0.00 L Rotating Equipment 0.50 0.00 Special Process Hazards Factor (F2)..................... -...................................................... 2.23 Process Unit Hazards Factor (FI x F2) F3.......--................................................... Fire and Explosion Index (F3 x MF - F4EI)............................................... ................. 4.01 96 (1) For no penalty u*o 0.00. DO A 031354 CONFTDFNTT A1 FORM C-22380 Rn/01-M (471-OOOM) - (PIE-7 system Ver-Zt /3US4| Print Date: 7/13/95 ">SS CONTROL CREDIT FACTORS 1. Process Control Credit Factor (Cl) Feature a. Emergency Power b. Cooling c. Explosion Control d. Emergency Shutdown t, Computer Control Credit Factor Range 0.98 0.97 to 0.99 0.84 to 0.88 0.96 to 0.99 0.93 to 0.99 Credit Factor Used (2) 0.98 1.00 1.00 1.00 1.00 Feature f. Inert Gas f Operating Instructions/Procedures h. Reactive Chemical Review i. Other Process Hazard Analysis Credit Factor Range 0.94 to 0.96 0.91 to 0.99 0.91 to 0.98 0.91 to 0.98 Credit Factor Uaed (2) 1.00 0.97 0.91 0.96 Cl Value (3) | 0.848 | 2. Matartal Isolation Credit Factor (C2) Feature a. Remote Control Valves b. Dump/Blowdown Credit Factor Range 0.96 to 0 98 0.96 to 0 98 Credit Factor Used (2) 1.00 1.00 Feature c. Drainage d. Interlock C2 Value (3) 1 1.000 j Credit Factor Range 0.91 to 0.97 0.98 Credit Factor Used (2) 1.00 1.00 3 Fire Protection Credit Factor (C3) Feature a. Leak Detection b. Structural Steel c. Fire Water Supply d. Special Systems a. Sprinkler Systems Credit Factor Range 0.94 to 0.98 0.95 to 0.98 0.94 to 0.97 0.91 0.74 to 0.97 Credit Factor Used (2) 0.98 1.00 0.94 1.00 0.97 Feature f. Wbter Curtains 9 Foam h. Hand Extinguishers/Monitors i. Cable Protection C3 Value (3) I 0,867 | Loss Control Credit Factor Cl x C2 x C3 (3) | 0.733 | Credit Factor Range 0.97 to 0.98 0.92 to 0.97 0.93 to 0.98 0.94 to 0.98 Credit Factor Used (2) 1.00 1.00 0.97 1.00 PROCESS UNIT RISK ANALYSIS SUMMARY 1. Fire and Explosion Index (F&EI)........... (See Front) 96 2, Radius of Exposure...................................... tnwi 81 It 3. Area of Exposure......................................................--........ 20493 sq.ft. 4, Value of Area of Exposure (1994 Dollars)............................................................................... $MM 5. Damage Factor.......................................................... 0.74 6. Base Maximum Probable Property Damage (Base MPPD) [4 x 5].................... 7. Loss Control Credit Factor ..........................(See Above)| 0.73 $MM 8. Actual Maximum Probable Property Damage - (Actual MPPD) (6 x 7].... 9. Maximum Probable Days Outage - (MPDO) tngunsil 84 ................. $MM days $MM 18.74 13.83 10.16 58.47 | | | | (2)Fornocreditfactorentor1.00 (3) Product of all factors used Refer to 'Fire & Explosion Index Hazard Classification Guido* (Form #471-00001) for details BACK OF FORM C-223S0 Rsv/01-M (471-0003S) - (FIE-7 SydMI Vsr-ZI W3US4] CONFIDENTIAL Print Date: 7/13/95 FIRE & EXPLOSION INDEX OATA AND COMMENTS muff**i Material I* Fram DAUM Maortal Nam* - Ethylene Baeo Material Factor-24 A^uatort Matortal Factor 24 Haat ol Camtouatton tBTWto) 20*00 NO" 1 Nf4 Nr * 2 Flaaft Poll* (*F) * Oat BoRng Potr* (*F) * -IS# Procaaa Ur* Tamparanaa CF)- 140 Eiotham Tampamtwa C*F) * 1000000 AiAragntoon Tanpanbaa (*F) (42 Data For Usar Spodfiod MatoM Ganoral Proctat Hazard* A Exothame Crtamlcal Raacwma REACTOR w*h MILD EXOTHERM (Panaty-0.30) Comma 0 B- Endothermic Praemn Procaaa On* NOT A REACTOR * PanaJty-0 Comma 0 C. MaterM HandUng and Tranafar Nana id the toKMdng aduetton* apply (Panady-0) Comma 0 D. Endoaad or Indoor Procaaa Unto Procaaa la NOT ENCLOSED (PenaltyO) Comma 0 E- Accaaa Aocaas datarmtoad adaqrmta tor amaigency apiipmant (Panaky>0) Comma 0 F. Drains and Sp* Cortool Flat, iai>d na mtacn aiowa apa to apraad out (Pana*p*0.90) Comma 0 Soactel Process Hazard* A. Tonic MitortK*) Equal* tom tartfv of tha Nh B. sutoAtmoapherte Praaaura (< 900 nun Hg) Gratae than 900 mmHg {Ptn*Ny*0) Comm* 0 C OpfiQun in or Naar Fkmmatto Rang* piocsaa wti not rach tha ftommabla rang* (P*n*y0). Comm* 0 D. CHdC ExpiowOn Procaaa doaa not Muda duat* (Panay0) Comma 0 E. Pmmn Comma 0 F, LO* Tamparatua Tamparaibaaa ramain aatoly abova tha ductMrttt* Comma 0 O Quantity or FtommatitoAinotobto Material Comma 0 H. Corroaton and Eroaton Conoaton mat batoar 0.9 mm^yr WTTH hak of pttng and/or Comma 0 I. Laakaga * Jowa and Pacung Mfrw teakaga Itaafy at punp and gland aaala (P*na*)r*0. 10) Comma 0 J. uaa ot Find Egutpmaft POES NOT axtt to tha p*rt arfth tha Procaaa Ur* Comma 0 K. Hot ON Haat Exchanga Syftam Proeaaa doaa not urn a hot o axehanga ayatem, or tha hot ci Comma 0 L Rotattog Equlpmart No rotating aqutmafltdaamad to baa hazard (No Panaly) Comma 0 re-7 *4*"i <- w QO A 031356 OONFTDFWTTAl PrMDato: 7/13TM LOSS CONTROL CREDIT FACTORS - DATA AND COMMENTS Process Control Credit Factor (Cl) ) Emergency Power Automatic switch to emergency power for CRITICAL SERVICES Comma 0 b) Cooling No credit (Factor-10) Comma 0 c) Explosion Control No credit (Factor-1 0) Comma 0 d) Emergency Shutdown No credit (Factor-1.0) Comma 0 e) Computer Control No credit (Factor-1.0) Comma 0 0 Inert Ga* No credit (Factor-1.0) Comma 0 g) Operating IratructionaTProceduree 1. Startup, 2. Routine Shutdown, 3. Normnl operating conditions, 9. Maintenance procedure* (wo Comma 0 h) Reactive Chemical Review Reactive Chemical program la a continuing part of operations Comma 0 i) Other Process Hazard Analysts Management of Change Review (Factor-0 98) Comme 0 Material Isolation Credit Factor (C2) a) Remote Control Valves No credit (Factor-1.0) Const* 0 b) DunsVBiowdown No credit (Factor-1.0) Comma 0 c) Drainage No credit (Factor-10) Comme 0 d) Interlock No credit (Factor-1.0) Conwne 0 Fire Protection Credit Factor IC3I a) Leak Detection Gaa detectors alarm and identify a zone only (Factor-0.96) Comma 0 b) Structural Steel No credit (Factor-1.0) Comma 0 c) Fire water Supply Firefighting water can be supplied Ibr 4 hour* at 100 psig (7 Comma 0 d) Special Systeme No credit (Factor-10) Comme 0 e) Sprinkler Systeme Deluge system protect* process (Factor-0 97) Comme 0 f) VStoter Curtain* No credit (Factor-1.0) Oomms 0 g) Foam No credit (Factor-1.0) Comme 0 h) Hand Extingunhers/Monitore The process is protected by monitor gone (Fector=0 97) Comme o I) Cable Protection No credit (Factor-1.0) Comme o r-.rv A (Fie-r Var-lt Mt/K| Pnnt Dvte: 7/13/95 103 COMMAND ==> INQUIRE FIXED EQUIPMENT 05/30/95 12:26 Equip ID c t Center Serial # ' 'oc Ser # Parent ID PSV 2R-1 AA 0000063 34857-M3 2R-1 A Eq Desc: SAFETY VALVE #803094 Unit: Criticality: 10 Area: PURIF Project: Equip Code: Type: _________ Equip Cond: ____ _________ Spec: Grid: Fleet MGMT?: nstall Dt MFR Abbrev CROSBY Model Type JO-35 A GEMTS-> Prod / Process: Eqp Group / Type : Model #: Model Size: 4" X P X 6" DISTILLATION C2H2 REACTO PRESSURE VESSEL/VALVE PRESSURE R * # * SPECIFICATION TEXT * * * INSPECTION SCHEDULE: 60 MONTHS OPERATING TEMP: 200 DEG. F VALVE SET PRESSURE: 475 PSIG OPERATING PRESSURE: 350 PSIG BACK PRESSURE: MTD Cost: Last PM: # Sel: 0 0 0 YTD Cost: Last Updated By: PRODUCT: U432414 ETHYLENE VAPOR 0 LTD Cost: Date Installed: Date: 10/10/89 GN-10 < RESET COMPLETE > 00048 17 434 1935 PF1 = VIEW SPEC PF2 = PF3 = BROWSE PF4 = PF5 = PF6 = MENU PF7 = PREV RECORD PF8 = NEXT RECORD PF9 = PF10 = PF11 = PF12 = Nvr ( 00 A 031358 CONFTDFTNTTAl 103 COMMAND =-> INQUIRE FIXED EQUIPMENT 05/30/95 12:26 Equip ID Cost Center Serial # *.oc Ser # Parent ID P8V 2R-1 AB 0000063 4785-C 2R-1 A Eq Desc: SAFETY VALVE #804322 Unit: Criticality: 10 Area: PUF.IF Project: Equip Code: _____ Type: _________ Equip Cond: ____ _________ __ Spec: Grid: _______ Fleet MGMT?: .nstall Dt MFR Abbrev ANDRSN Model #: Model Type 32310P 46 GEMTS-> Prod / Process: Eqp Group / Type : *** Model Size: 4" X 6" DISTILLATION C2H2 REACTO PRESSURE VESSEL/VALVE PRESSURE R SPECIFICATION TEXT * * * INSPECTION SCHEDULE: 60 MONTHS OPERATING TEMP: 200 DEG. F VALVE SET PRESSURE: 475 PSIG OPERATING PRESSURE: 350 PSIG BACK PRESSURE: MTD Cost: Last PM: # Sel: 0 0 o YTD Cost: Last Updated By: PRODUCT: U431990 ETHYLENE VAPOR 0 LTD Cost: Date Installed: Date; 06/06/94 GN-10 < RESET COMPLETE > 00048 17 434 280 PF1 ss VIEW SPEC PF2 = PF3 * BROWSE PF4 - PF5 = PF6 = MENU PF7 = PREV RECORD PF8 = next RECORD PF9 - PF10 = PFll = PF12 = ( ( 3 00,^1 CO' 103 COMMAND ==> INQUIRE FIXED EQUIPMENT 05/30/95 12:26 Equip ID Cost Center Serial # '.oc Ser # Parent ID PSV 2R-1 BA 0000063 34857-M3 2R-1 B Eq Desc: SAFETY VALVE #803096 Unit: Criticality: 10 Rrea: PURIF Project: Equip Code: Type: _________ Equip Cond: ____ ______ Spec: Grid: ______ Fleet MGMT?: .nstall Dt MFR Abbrev CR08BY Model Type JO-35 A GEMTS-> Prod / Process: Eqp Group / Type : *** Model #: Model Size: X P X 6" DISTILLATION C2H2 REACTO PRESSURE VESSEL/VALVE PRESSURE R SPECIFICATION TEXT * * * INSPECTION SCHEDULE: 60 MONTHS VALVE SET PRESSURE: 475 PSIG OPERATING TEMP: 200 DEG. 7 OPERATING PRESSURE: 350 PSIG BACK PRESSURE: 0 PRODUCT: ETHYLENE VAPOR MTD Cost: 0 YTD Cost: 0 LTD Cost: Last PM: f Sel: 0 Last Updated By: U432414 Date Installed: Date: 10/10/89 GN-iO < RESET COMPLETE > 00048 17 434 2261 PF1 = VIEW SPEC PF2 = PF3 = BROWSE PF4 = PF5 PF6 = MENU PF7 = PREV RECORD PF8 = NEXT RECORD PF9 = PF10 PF11 PF12 = MAIN MENU ( 103 COMMAND ==> INQUIRE FIXED EQUIPMENT 05/30/95 12:26 Equip ID Cost Center Serial # oc Ser # t'ar nt ID PSV 2R-1 BB 0000063 4786-C 2R-1 B Eq Desc: SAFETY VALVE #804323 Unit: Criticality: 10 Area: PURIF Project: Equip Code: _____________ Type: _________ Equip Cond: ____ ______ Spec: Grid: _______ Fleet MGMT?: nstall Dt MFR Abbrev ANDRSN Model #: Model Type 32310P 46 GEMTS-> Prod / Process: Eqp Group / Type : *** Model Size: 4" X 6'* DISTILLATION C2H2 REACTO PRES8URE VESSEL/VALVE PRESSURE R SPECIFICATION TEXT * * * INSPECTION SCHEDULE: 60 MONTHS VALVE SET PRESSURE: 475 P6IG OPERATING TEMP: 200 DEG. F OPERATING PRESSURE: 350 PSIG BACK PRESSURE: MTD Cost: Last PM: _____ # Sel: 0 0 0 YTD Cost: Last Updated By: PRODUCT: U431990 ETHYLENE VAPOR 0 LTD Cost: Date Installed: Date: 06/06/94 GN-10 < RESET COMPLETE > 00048 17 434 249 PF1 = VIEW SPEC PF2 = PF3 = BROWSE PF4 = PF5 = PF6 = MENU PF7 = PREV RECORD PF8 = next RECORD PF9 PF10 PF11 PF12 s ( DO DOAJpr rr0313* t 103 COMMAND ==> INQUIRE FIXED EQUIPMENT 05/30/95 12:30 Equip ID: Cost Center: Serial #: oc Ser #: PSV 2RS-1 0000063 TE 74884 Eq Desc: SAFETY VALVE #808912 Criticality: 10 Area: PURIF Equip Code: _________ Equip Cond: ____ _________ Unit: Project: Type: Spec: Parent ID: 2RS-1 Grid: ________ Fleet MGMT?: ( install Dt: MFR Abbrev: CNSDSV Model #: Model Type: 1910-30QT Model Size: X Q X 8" GEMTS-> Prod / Process: DISTILLATION C2H2 REACTO Eqp Group / Type : PRESSURE VESSEL/VALVE PRESSURE R * * * SPECIFICATION TEXT * * * INSPECTION SCHEDULE: 60 MONTHS VALVE SET PRESSURE: 80 PSIG OPERATING TEMP: 180 DEG. F OPERATING PRESSURE: 25 PSIS BACK PRESSURE: 0 PRODUCT: STEAM/AIR VAPOR MTD Cost: o YTD Cost: 242 LTD Cost: Last PM: Date Installed: f Sel: 1 Last Updated By: U431990 Date: 06/06/94 00048 3" 434 282 PF1 = VIEW SPEC PF2 = PF3 = BROWSE PF4 = PF5 = PF6 = MENU PF7 = PREV RECORD PF8 = NEXT RECORD PF9 3= PF10 - PF11 PF12 = MAIN MENU ( 00 A 03I3&? < cNFT0frNTTA,