Document 6wVgZ331v5gE9MbM5rZYQnYK9

pt Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPCL/MS n CPlrioejnetc:t: Sample Matrix: LaSabmpCloedeN:ame: Analytical Report BaCraomnp D&reBsusderdP&.CM/e9K5e7e7,0-I7n5co3r1p9orated (CDM) Water FKi1e0ld00B9l1an1k00#11 P2 SeDravtieceCoRlelqeucetsetd:: K2/10101009019143 DateReceived: 2/210 BUansiitss:: NnAp Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLCIMS APnraelpytMiectahloMde:thod: MPeFtOhAod Analyte Name PPerfleuoroo-ni-reinddeceacnaoincoacciaded Porfluarobuanesufonate PPeerrflluuoorrcobduecaannoeiScuAlfcoindate PerfluorodecanoicAcid PPeerrflluuaarroohdeopdeicaanniocieAcAicdid Perluorohexancsulfonate PePrelrufolrooronhoenxaannaciicc AAcciidd Perfluorooctanesulfonate PPeerrfflluuoorrooopcetnatnaonicciAccAicdid PerfluoroundecanaicAcid Rest@ NNDUU NDU [ENwU DU NNDUUT eR) 0N34DU 039) N0D0 1U NU MRL MDL DFialctwoorn ExtDraatceted AmDlayteed ExtrLaocttion AnaLloytsisNote 5300 005%5 T 1 i 2an0 uTmiR02O0sNe Tloossiaz T10o3a6 50 omy 1 Jamo 28nooeis isi isi 5500 000I95 11 22w4ln0o 2am9i0002604s6 1lo0s5i4e6z2 11950033662 50 08 1 4no amiss si loess: T5s0o 000858 11 2u4n0o0 a29m10o06s46 Il0ossiic2z 1190036s2 50 000 1 2410 29100686 losic2 looser SS000011 50006 11 1 u24o10 1290020604s6 1l0o5s2e 11930033662 2410 uss iosi2 looser 5S00 000066111 2244Nm00 21n002060d46 l100s5i4s6z2 115900336622 50 13 1 Jano moss losis 1o0s Surrogate Name %Rec CoLnimtirtosl AmDlatyeed Q Nowe PaPrefrlulolrioo-rno-a{1.1223344.51-31043)03b]utnanooi maacdd 8105 SS001100 I29O/1N00S6: PePrefrlfulouroor-on-.n(-1{.1221334C-21)3dCe4c]aoncotiacnaoiccidacid Perfluoro-n-[12-13C2] hexanoic acid 0100 1015500 228m110022005544 5 50150 29000646 PPeerrfflluucorroo--nn--{{11.22--1133CC22Jludnoddeeccaanncciic AAcciidd Solum pero 1,234.130H onesie a5 77 0000500 22110022005544 S150 M0208 Sodiumperhuoro--hexane{1802sulfonate 0 S150 200646 Comments -_-- -_ Fd im S 22u1013m35ss fomia Soames toms 12 Client: SPraomjpeclte:Matrix: Sample Name: Lab Code: Analytical Report BCaarmopn &DBruded&sPM.scCK9eSeTerT.0-I7nSc3or1p9orated (CDM) Water EKl1ly0s0o0n91"1R-a0w0"2 p.3 SeDravtieceCoRlelqeucetsetd:: K21010/1009111002 DateReceived: 2/210 Units: Basis: nglL NA Perfluorinated Sulfonic Acids and Perflsorinated Carboxylic Acids by HPLC/MS PAnraelpytMiectahloMde:thod: PFOA Method APnerae fllyvtoreo-e Nna-tmeetradecanoicacid. PPeerrfflluuoorroob-unt-atniedseuclafnooniactaecid PePrelrufoluroorboudteacannoeicSAulcfiondate: PefluordecanAsicd PPeerrfflluuoorroohdeopdteacnaoniocicAcAicdid Perfluorohexancaulfonate PePrefrlfulouroorohneoxnaanncoiiccAAcciidd Perfluorooctanesulforate PePrefrlfulourooroocpetnatnacniociAccAicdid Pefluorowndecanoic Acid Remlt Q MRL MDL Dilution Date Factor Extracted Date Analyzed Extraction Lot Analysis Lot Note NNbD UU 530 000%95 11 2Z41000 WmII002210011 1100554662 11990036622 160 500m 1 410 2900636 10562 1032 19) ND U 50 50 oul 0095 I 1 240 20400 U2M9I00020L605I6 103462 105462 190362 190362 NDU 50 048 1 2410 2102101 10562 190362 ND U 271 50 08s 50 008 T2400 1 2400 2102101 29100656 10562 105462 190362 190362 93 50 0W0 1 2402900636 l08i62 10362 421 a1 50 50 oun on 1T24214000 U2M9I10020I605L6 105462 10562 190362 190362 B50 opi1 2410 2802101 l0si62 190362 8 ar) 50 006 50 oll 1 1 2/410 2400 2mI02101 291006356 105462 105462 190362 190362 NDU__ 50 13 1 2400 U802101 105462 190362 Surrogate Name %Rec CoLinmtirtosl Date Analyzed Q Note `PPeerrffliuuoorroo--nne-{[11,.22,33.44-,153-C143]Cb]nuotannaoniociacciadcid 3% i oa 5005 wool 29/1006:56 PPeerrfflluuoorroo--nn-{{11..22-,1334C-21]3dCe4c]anocotiacnaocicidacid 104 100 5005 S050 228m110022110011 PPeerrfflluuoorroo--nn--{{11,,22--1133CC22]]dhoedxeacnaoniccicacAicdid 2 59 50.150 50150 22/m91/1002016:0516 SPeordfiluumorpoe-rnl-i{o1r.o2--11{31C.22]3u4n-d1e3c0a4n]ooiccanAccsiudlfonste 5704 5S0015500 22ww01202110011 Sodium perfuoro-1-hexane(180Z]sulfonate 2 S005 291006:56 I Comments: ee Pf ra22310-- 1335 -- Fomia 13 -------------- Sth: OTN0 PCrloijenetc:t: Sample Matrix: LSuambpCloedeN:ame: Analytical Report `BCaarmopnD&rBuedds&P.MsCc/Ke9e57er7,9.I7n5c3or1p9orated (CDM) Water K1E0l0ly0s9o1n1"-T0re0a3ted b.4 SDearvtiecCeolRleeqcuteesdt:: K2/110/01009111015 DateReceived: 2/2/10 BUansiitss:: NngAlL Perfluorinated Sulfonic Acids and Perfluarinated Carboxylic Acids by HPLC/MS PAnraelpytMiectahloMde:thod: PFOA Method Analyte Name PPerefluooro-nntriicdreacdaencoaincoaicciadad Perfluorobutanesulfonate PPeerrfflluuoorroobduetcaannoeiSculAfcoindate Pofliorodecinoic Ad PPeerrfflluuoorroohdeopdteacnaoniccicAcAicdid Pefluorohexanesulfonate PPeerrfflluuoorroonhoenxaanncaiiccAAcciidd Perfliooocunesulfonae PPeerrflluuoorroocpcetnatnaoniocicAcAicdid PerfluoroundecancicAcid_ Rewlt @ MRL MDL Dilution Date Factor Extracted Date Analyzed Extraction Lot AnaLloytsisNote NN D UUD 3500 0%09s T12w40n 0 2T1R02I10O9 T1o0S5462 1T903o62i L650 009 1 wu 2m00705 10542 190362 161 ND U 50 S00 oll 0095 I 1 240 24M0 12501201070095 108462 105862 190362 190362 NDU__ 50 08% 1 2410 2102109 10sic2 looser ND U 271 50 SO 0os0s 811T24214100 2298010002710059 10562 108462 190362 190362 92 50 0030 1 2400 290100705 108462 190362 4a 457 50 50 oll on IL2324010 229110020170095 105462 105862 190362 190362 12 000d 1 2410 2102109 105462 190362 6 a7 5500006ol6l 1 I 24M0 2400 21901200170095 105462 105462 190362 190362 _NDU 50 13 1 40 8102109 10si62 190362 Surrogate Name PPerfeluorro-n{-1f{21.,32l3.44-51o-3C340]rbuntooannoai-ncoaccianded PPeerrfflluuoorroo--nn{-11,223-1,34C-21)3dCe4c]anooctiacnaociicdacid. PePrefrlfulourooro--nn{-1{,122--1133CC22]JdhoedxeacnaonicciaccAicdid SPoedrifulmupoerrol-inc{r1o,-21-{113.2C32,u4n-d1e3cCa4n)coiccaAmcesiudlonste Sodium perfluoro-1-hesane{1802]sulfonate: %Rec CLoinmtirtosl 90 8 S010 5015 9 100 5045 50450 2 61 50150 50050 471 9+ s5e0a1s5 8 50450 AnaDlaytzeed Q 229w10l07o05 e 2288110022110099 22987110020170059 u81002211:0099 29100705 Nowe ------------ C_om--ments _-- ProendS22a3e10L1i3m35 ree aaUaamam4m4nm9mnm Famia Soest 1 10m Client: PrSoajmepclte: Matrix: Sample Name: Lab Code: Analytical Report B`aCraomnp &DrBuded&sPM.sCcIKe9eSe7r,79-I7n5c3or1p9orated (CDM) Water KDa1v0i0s09"1R1a-w0"04 p.5 SeDravtieceCoRlelqeucetsetd:: K2I/10/01009111040 Date Received: 2/2/10 Units: Basis: nglL NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLCIMS APnraelpytMiectahloMde:thod: PFOA Method A APnearile uyotreo-Nnaimeteradecanoic acid. PePreflrulouroo-rno-btrudneecsanlcfiocancaied PPeerrffllvuoorraobduetcaannceicSuAlcfiodnate PeDrfeluofroidoadencatnoiAccAkcid PePrefrlfulouroorhoheexpatnaensouilcfAocniadte PePrefrlluuoorroonhoenxaannooiiccAAcciidd Perfluorooctanesulfonate PPeerrfflluuoorroopoecnttaanniocicAAccidid PefluoroundeAcadnoic Rest @Q MRL MDL Dilution Date Factor Extracted Date Amlysed Extraction Lot Analysis Lot Note N0D7U 5300 00945% 11 2244100 J2WWII002ILLII66 110055446622 11900336622 0913 50 009 1 2402900075 10542 10562 0891 0231 50 50 oul 09s 1 1 22a4l000 U29M0I00027L1I56 11005546622 119903062362 NNODU U S5O0 0085ds 1 1 2244000 2A2NmI00221L0I66 101055446622 11990033622 147 301 50 50 008L 000 1 1 2400 2/410 22991/000077155 105462 105462 190362 190362 211 036 1 50 50 oul on IT24204000 2298010002711056 105462 10562 190362 190362 410 50 00461 240 2MI02LI6 1062 19032 a204 5500 0o0l6l6 I1 220441000 22m9I00027L1156 110055446622 119900336622 NDU0 13 1 240 2102106 105462190362 Surrogate Name Control %Rec Limits Date Analyzed Q Note PPeerrfflluuoorroo--nn--{112,,2,3344,-51-31C33C]b3u]tnaonnoaincoaicciadcid % oa S05 wma 29100715 PePrefrlfulouroor-on--n{-1{.12,2-.1334C-21)3dCe4c]aoncotiacnoaicciadcid 110006 S50014550 228810022111066 PPeerrfflluuoorroo--nn--{{11,,22--1133CC22]]dhoedxeacnaoniocicacAicdid 81 55 50150 S05 2298110002711156 SPoedrfiluumopreor-fnu-o{1-.12--(113.C22,J3u4n-d1e3c0a4n)ocitcaAnecsiudlforate 7510 S50a15s0 22801201211066 Sodium perfluoro-1-hexane(1802slfonate 8 50150 29/100715 Comments: ee PVriedo2S2m9t10 13s3h5e An Femi SoR p t 10 0 ) 15 PCrloijeenctt:: Sample Matrix: SLaambpCloedeN:ame: Analytica Report BCaarmopn &DrBueddP&s.MCsc/K9ee5e7r7,9-I7n5co3r1p9orated (CDM) Water KIO0l0i0ve91"1Ra-w0"06. P-8 Service Request: Date Collected: K1000911 2/1/10 1115 DateReceived: 2/2/10 Units: Basis: nglL NA Perfluorinated Sulfonic PrAneaplyMtiectahloMde:t~hod~: PFOA Method Analyte Name PPeerfflluuoorroo-nnt-etirridaedceacnaoniccaicciadcd Perflurobutanesulforate PPeerrfflluuoorroobduetcaannaeiScuAlcfoindate PerfluorodecAacnicdic PPeerrflluuoorroodhoepdteacnaoniccicAcAicdid Perfluorohexanesulforate PPeerfflluuoorroonhoenxaanncoiiccAAcciidd Perfluorooctanesulforate PPeerrfflluuoorroopoecnttaannociiccAcAicdid Perfluoroundecancic Acid Result NY ND U 255 29) ND U ND U ND U 9464) 73 19 91 7190 ND U Acids and Perfluorinated Carboxylic Acids by HPLCIMS MRL MDL 30 S00 046 095 SO 009 50 S00 oar 0095 SO 048 55000800s8L 50 000 50 50 onl on 50 0046 550000on6 so 13 DFialcuttioorn ExtDraatceted 1 1 90 240 1 240 1L41240N0 1 240 1 1 2410 2410 1 2410 IT2421400 1 240 11 22441100 | 2410 AnaDlaytzeed UJMWII0022U1351T 29100734 B29I701200173314 y102u31 22W9I00020173314 29100734 2289100020173314 2102031 22m9I0002713341 u102131 ExtrLaocttion 1052 105462 108462 103462 l1o0s5i46622 105462 1lo0s5i6e622 10562 105462 108462 110055446622 105462 AnaLloytsisNote T0567 190362 190362 190362 190362 150362 190362 190362 190362 190362 190362 190362 190362 190362 190362 Surrogate Name %Ree Control Limits AnaDlaytzeed Q Note PPeerrfflluuoorroo--nn[-1[,12,,233.44-51-3134C]3]butnanoaicracaaidcndeic 971 50-1530405 JW29I10007I34T -- PPeerrtflluuoorroo--nn-i{-1{,122:31,34C-21]3Cd4e]caoncotiacnoaiccidacid 9 100 50450 50450 288110022113511 PPeerrfflluuoorroo--nn-{{11,.22--1133CC22]}dhoedxeacnaoniccicciAcdid. 8 51 S010 S050 22987110020173314 PeSrofdliuuomrop-enr-l{u1o,t2o--1113,C223],u4n-d1e3c0a4n)ciocctAacneisdlfonste. 4676 rs50s450 u2m1n0022113311 Sodiumperfluoro-I-hexanef I802lsulfonate 8 5045 29100734 C-o_mm--ents -_-- Prifmeod2n23d10s13m35esmo 0mm Fam 1a 1" Ser Belen: 10000730) Client: Project: Sample Matrix: Sample Name: Lab Codes AnalyticalReport CampDres& MscKeegr, Incorporated (CDM) Baron &BuddP.C/95779-75319 Water KO1l0i0v0e9"1T1re-a0t0ed7" pT Service Request: K1000911 Date Collected: 2/1/10 1125 DateReceived: 2/2/10 Units: ng. Basis: NA `Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA PrepMethod: Method Analyte Name Per-f_--luoro-nictradecanoicacid Perfluoro-n-tridecanoicacid Perfluorobuanesulfonate PPeerrfflluuoorroobduetcaannoeiScuAlcfoindate PeruorodAeccidancic PerfluorododecancicAcid PerfluoroheptanoicAcid Perfluorohexanesulfonate PerfluorohexanoicAcid PerfluorononanoicAcid Perfluoroocanesulfonate PerfluorooctandicAcid PerfluoropentanoicAcid PerflvoroundecanoicAcid. Dilution _ Date Date Extraction Analysis Result @ ~~ MRL MDL Factor Extracted Analyzed Lot Lot Note ND U ND U 50 046 50 09s T 1 2/4/10 2802139 105462 190362 24/00 28102139 10462 190362 25 J 50 009 1 24/10 25100743 105462 190362 307 ND U 50 oll 50 0095 1 1 2410 29100743 105462 190362 2400 28102139 105462 190362 NDUU 50 048 1 410DAM02L39 10562 190362 ND U 45) 50 085 50 0081 1 1 2400 2400 28102139 29100743 105462 108462 190362 190362 96 50 0030 12410 2900743 105462 190362 73 18) 50 on 50 on 1 1 2410 29100743 105462 190362 2400 2BI021:39 105462 190362 95 50 0046 1 2400 2/RN021:39 105462 190362 96 8.1 50 0066 50 oll 1 1 2410 28102139 105462 190362 2400 297100743 105462 190362 NDU 50 13 124M0 2102139 105462 190362 Control Date Surrogate Name %Rec Limits Analyzed Q Note Peruoro-n{1,2,3.4,5-13C5]nonanoic acid Perfluoro-n-{1,2,3,4-13C4] butanoic acid. 9% 2 Soo moa 50-150 2/9/1007:43 PPeerrfflluuoorroo--nn--{{11,,22,+31,34C-21]3Cd4e]caoncotiacnoaiccidacid 100 100 50-150 50-150 2/81021:39 28102139 PPeerrfflluuoorroo--nn--{{11,,22--1133CC22]]dhoedxeacnaoniocicacAicdid 8 50-150 49+ S050 2971007:43 2E02139 S`oPdeirufmlupoerrof-lnv-o{r1o,-21+{113,C22,J3un-d1e3cCa4n]ocitcanAecsiudlfonate 46+ S0IS0 68 50-150 2B02139 8102139 Sodiumperfluoro-1-hexane] 1802]sulfonate: 80 50-150 2091007:43 pr--. ee Pnrimoed2n23e10 m 1338 A Fom 1A Supe Reece. 100801593ev) 18 Client: PSraomjepclte:Matrix: Sample Name: Lab Code: Ansytca Report Ba`Craomnp D& rBuedd&sPM.sCc9Ke5e7er7,9-I7n5c3or1p9orated (CDM) Water CarriageHills "Raw" K1000911-008 p.8 SeDravtiecCeoRlelqeucetsetd:: K1000911 2/1/10 1156 DateReceived: 2/2/10 Units: nglL Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name PePrefrlfuoiruoo-rno--trnd-eecraandoieccaacn3iodidc Perfluorobutanesulfonte. PPeerrfflluuoorroobduetcaannoeiSculAfcoindate PerfluorodecanAocicd PPeerrfflluuoorroohdeopdteacnaoniccicAAcciidd Perfluorohexanesulfonate PPeerrfflluuoorroohneoxnaannooiiccAAcciidd Perfluorooctanesulfonate PPeerrfflluuoorrooopcetnatnaoniccicAAcciidd PerfluoroundecanoicAcid Rest Q ND U| ND U 032 036 J NNDDUU ND U 013627 0791 ND U 16d 137 084 NOU Dilution Date ~~ MRL MDL Factor Extracted 50046 50 095 1 1 Zl0 2400 50 009 1 2410 50 oll 50 0095 I 1 2400 2400 50 048 1 2410 50 08s 50 0081 1 1 2400 24M0 50 0030 1 2410 50 oll 50 on T2410 I 2400 50 0046 1 2400 50 0066 50 on 1 1 240 2410 50 13 | 2410 Date ExtractionAnalysis Anlzed Lot Lot Note 8I002LH46 10% 105462 Doe 190362 2900753 10462 19032 2900075 2102146 105462 105462 190362 190362 102146 108462 190362 2102046 2900753 105462 105462 190362 190362 2900753 105462 190362 29100753 28102146 105462 10562 190362 190362 2102146 105462 190362 2102146 2900753 108462 105462 190362 190362 02146 105462 190362 Surrogate Name PPeerrfflluuoorroo--nn-{{11,.22,.33.,44,-51-31C34C]3b]untoannoaincoiacciadcid. PPeerrfflluuoorroo--nn-{{11,.22-,13,34C-21]d3Ce4c)anooctiacnaociicdacid PPeerrfflluuoorroo--nn-{{11,,22--1133CC22]]dhoedxeacnaoniocicacAicdid. PSeordfiluumopreor-fnu-a{o1-,12{-11,32C,23J4u-n1de3cCa4n]coicctaAnceisdulonste Sodium perfluoro-1-hexane[1802Jsulfonate. Control %Rec Limits E23 0150 " 108 50150 50050 7100 5500115500 av 2+ sas S010 7 50050 5005 AnDaaltyseed Q ZWI02146 29/1007:53 28102146 229811000271:4536 202146 22180022114466 291007:53 Note -- Comments: Pied22S23101335 Ameen fom13 SoRp ts 100001993 0000 10 CPlrioejenctt:: SampleMarri: LSaambpCloedeN:ame: Analyica Report `BaCraomnp D& Bruded&sPM.sCeeSsTr,07I5nc3o1rp9orated (COM) Water CK10a00r91H1ri.l0li0s9"aTregateed" vo SeDravtieceCoRlelqeucetsetd:: 2K/1010009111206 DateReceived: 2/2/10 UBnaistiss:: nNAg Perfluorinated Sulfonc Acids and Perfluorinated Carboryic Acids by HPLC/MS PrAneaplyMtiectahloMde:thod: PMeFtOhAod Analyte Name Rel @ MRL MDL DFilauctoiorn ExtDraatceted AnaDlaytzeed ExtrLaocttionAnalLoytsisNote PPereflfuooroo-rn-erddeecaanmciocacciidd Perfuorsutanesulfonate PPeerrfflluuoarrocdbeucaannoeicSAuclfiodnate Perfluorodecancic Acid NNDDUU 3500 009%5 11 J2u4I100 J2WIW021I5s 1T0o5s6e2 1W0o36w2 031 J 50 0m 124i 2900803 105462 100362 00233111 55000 0o0l9l5 11 a24nno0 2uIm0020LsSes 1L0ossiie 1100%% NOU 50 ous 1 ano amionsi 10s 15062 PPeerrfflluuoorroohdeopdteacnaoniociAccAicdid. Perfluorohexanesulfonte PPeerrffllaoorraohneosnaannooiicc AAcciidd Perfloroccianesulforate PPeerfrlfulourooroocpteanntoaicnccAAcciidd Perfluoroundecanoic Acid N0D341U 55000 008s0811 22440000 229110020185043 110055446622 119903062362 153 50 0030 1 2410 29100803 105462 190362 0N6D7U 5500 0012111 224a1n00 u2MmIi002oLssess Lloosii 1100%% 141 50 0046 1 240 ami02nss 10462 190362 017267) 550 00oo111 2a4iMo0 Ua9mMi0o0z8i0s3s l10o34s6e2 119900336622 NOU 50 13 1 240 ami0znsi 10462 190362 Surrogate Name %Rec CoLinmtirtosl AnDaaltyeed Q Note PPeerrfluuoorroonn--({1122.,3344.-31-31C34C]3]buraovroaincoiacci0d d 5i8or 0S011550 22901200185083 PPeedrlluuoorroo--nn.-[[11.22,:1334C-21)3dCe4c]aoncoaincoaiccidacid 1u0s0 000a m ma1 ns PPeerrflluuoorroo-nnn.|11..22--1133CC22]}dhoedxeacnaoniocicacAdcid 26 0015a0 2290020810s3 PSeordfiluumopreorl-tnr1o-.121-.21.33C,42-]1unde3c0aHn]aoiceuAnceisdlfonse 30 SS1a5s0 2280022115884 Sodium perloro-1-hexane{1802sulfonate 3 50150 2900803 Comments: ress22t310e1335am Fomia Soars. mT 20 Client: PSraomjpeclte: Matrix: LSaabmpCloedeN:ame: Analytical Reprt Camp Dre&sMscKeeer, Incorporated (CDM) BWaartoenr & Budd P.C/95779-75319 KW1a0t0s0o9n1"1R:a0w1"0 p.10 ServiceRequest: DateCollected: 1000911 2/1/10 1225 DateReceived: 2/2/10 Units: Basis: nell NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS PrAneaplyMtiectahloMde:thod: PFOA Method. APnearlriyutoereoNna-meteradecanci_ c acid_ PPeerrflluuoorroob-unttarniedseuclafnooniacteacid PPeerrflluuoorroobduetcaannoeiScuAlcfoindate PerllvorodecanAocicd PPeerrflluuoorroodhoedpetcaannociciAccAicdid Perflvorohexanesuforate PPeerrfflluuoorroonhoenxaanncoiicc AAcciidd Perfluoroocianesulfonate PPeerrfflluuoorrooopcetnatnaoniocicAAccidid PerfluoroundecanAocicd Rest @ ND U ND U 0.46 J 0391 0N14DUJ ND U 0531 281 008900 11 31 191 N1D01U Dilution Date Date ExtractionAnalysis MRL MDL Factor Extracted Analyzed Lot Lot Note To 50 od 095 50 009 50 50 onl 0095 50 048 50 50 08s 00BI 50 00% 5500 oonnl 50 004 S00 0066 5500 o1l3l 1 1 JU 2400 1 2410 T2410 L1 4124010 U1T ual0 2400 1 2410 11 22441100 1U4I0 1 I 2400 2400 1 240 22WWII002222002 1052 103462 29000812 105462 229110020280122 10562 105462 28102202 10562 22981002080122 105462 10562 29100812 losie2 2290102008122 110055446622 8102202 105462 M291000028102 105662 105462 102200 108462 190362 190362 190362 190362 119900363262 190362 190362 190362 190362 119900336262 190362 190362 190362 Control Date Surrogate Name %Rec Limits Analyzed Q Note PPeerfrlulolrou-no-[r1o.2-3,n4-11.3C24]3bu.tn4aon,naa5inco-aic1cia3dcCid3] 103 8 O5011500 289110020280122 -- -- PPeerrfflluuoorroo--nn--[[11,.22-31,34C-21]3Cd4e]caoncotiacnoaiccidacid m 100 50050 50050 22811002222002 PPeerrflluuoorroo--nn--[{11.,22--1133CC22])dhoedxeacnaoniccicciAdcid % 51 50050 50050 22011002082:0122 PSeordfiluomrpoe-fnu-{o1r,o21--1{31C22,J3u4n-d1e3cCa4n]cicccanAecsiudlforsie 877 + Ss0o0a5 2m80102222002 Sodiumperfluoro-1-hexane{ 1802lsulfonate: 9 5005 29000812 -- Proodn2u2s3101335 Anrep Fomin Sept 100300 2 PCrloijeentc:t: SampleMatrix: SLaambpCloedeN:ame: AvalyticlRepot B`aCtaompnD& rBuedds&PM.scCHKeSeTerI,9-ITnSc3or1p9orated (CDM) Water WK1a0t0s0o9n1"1T.r0e1a1ted" ptt DSeartvieceCoRlelqeucetsetd:: K2/110101009111235 DateReceived: 2/210 UBnaistiss:: nNgA. Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS PrAueaplyMtiectahloMde:thod: MPeFtOhAod Analyte Name PePrerlfulobroor-on--nrtiedteracdaencoaincoaiccadcid Perflorobutancsulfonae PPeerrffllouroorboudetcaannceicSAlcfoindate Perfluorodecanaic Acid PePrelruuoorroohdeopdteacnaonicciAccAicdid Perflorohesanesulfonate PFeerrfflluaorroonhoensaannoiiccAAcciidd Perfluoroocianeslforate PPeerrfflluuoorroopoecnitaannooiiccAAccidid PeluorowndecanAociicd Rewlt Q NNDDUU_ 0x) sNiDU NDU 0N30DU 0s J 00825611 06) 081s2) ND UU MRL MDL DFilauctoiron ExrDaactteed AnaDlaytseed ExtrLaocttion AnaLloytsisNote 3500 004965 1 1 Z244Il00 50 009 1 240 S5000 0G0l5 11 224a1n00 50 048 1 240 55000m08l5 11 2va4n0o 50 000 1 240 55000 O0I111 z24l0 50 00% 1 weno 55000 00 066 11 2240n0 50 13 1 u410 T2WMI00T2E2009 uomoosz: a28v10o22:09 am102209 w2m0i0o2s2029 moos: 229M0000280292 umn m2i002020s9 28102209 T1o05562T11500362 isi 1 1lossis 119003662 10562 190362 1w054s62 1150036%2 isi 10 110056422 119900336622 ws 10 1100ssiic22 1190036%2 i0sie2 190362 Surrogate Name %Rec ConLitmriotls AmDlatyeed Q Note PPeerffiluoorroo-nn-11,223.34.4-S13TC4C] btmaonmoiacnoacciaded 8107 S0105800 m20m0o8m2e2 PePrefrlfulouroor-onren1{.12,.23',143-21]3Cd4e]cacntaaincoaicidacid m100 SS011500 228110022220099 PePrefrlluuoorroonn[{11,,22--1133CC22]]dohdeeacannociicacAicdid 51 05011500 229100020280292 SPoedrifulmupoerrot{1,2-11-31C.22J,u4n-d1e3c0a4n]coiccAfcoidrste 5767 5500115500 228810022220099 Sodium perfluoro-1-hexane] 1802 sulfonate 8 0150 2900822 Comments: PoetS223101335 AmRn1k foim Sesto 0mmD 22 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytica Report CampDresser &McKee,Incorporated (CDM) Baron &Budd P.CI95779-75319 Water KingsRfoaid"eRlawd" K1000911-012 p12 Service Request: Date Collected: K1000911 2/1/10 1340 DateReceived: 2/2/10 UBnaistiss:: nNgAlL Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLCIMS Analytical Method: PFOA PrepMethod: Method Analyte Name Perfluoro-ntetradecanoic acid Perfluoro-ntrdecanoicacid Perfluorobutanesulfonate PerfluorobutanaicAcid PerfluorodecaneSulfonate PerliorodeAcadncic Perfluorododecancic Acid PerfluoroheptanoicAcid Perfluorohexanesulfonate Perluorohexanoic Acid Perfluorononanoic Acid Perfluorooctancsulfonate PerfluorooctanoicAcid Perfluoropentancic Acid Perfluoroundecanoic Acid Dilution Date Date Extraction Analysis RestQ MRL MDL Factor Extracted Amlyzed Lot Lot Note TE 50 T 086 1 ND U 50 095 1 244000 2ZMIW02:17 1100554662 1190053662 012 5 50 009 1 2410 29000831 105462 190362 0147 50 oan T2410 2900831 10462 190362 016 J 50 0095 1 24M0 280217 105462 190362 ND USO 048 1 2410 102217 10562 190362 ND U 50 08s 1 2410 2102217 105462 190362 ND U 50 008L 1 2410 29000831 105462 190362 017 J 50 000 1 2410 29000831 105462 190362 ND U 50 oun T2410 29100831 105462 190362 ND U 50 on 1 2410 202217 105462 190362 0.2J2 50 004 1 2410 210217 105662 190362 ND U 50 0066 1 2400 2102217 105462 190362 0317 50 on I 2400 29100831 10562 190362 ND U 50 13 12400 2102217 105462 190362 Control Date `Surrogate Name %Rec Limits Analyzed Q Note Perflooro-n-{1.2,3.4,5-13C3] nomanoicacid BT 150 W017 Perfluoro-n{12,3,4-13C4] butanoic acid 102 50450 297100831 Perfluoro-ni{1,2,3,4-13C4] octanoic acid 133 50050 2102217 Perfluoro-n-{1,2-13C2] decanoic acid Perfluoro-n{1,2-13C2] hexanoic acid 100 104 5500045500 22811000282:3117 Perfluoro-ne{1,2-13C2ldodecancic Acid n S045 28102217 PSeordfiluumopreor-lni-o{r1o,-21--1[31C.223],u4n-d1e3c0a4n)ooitcaAncesiadfonate n100 5500405500 28102217 281022:17 Sodium perfluoro-1-hexane{1802}sulforate 106 50050 29100831 piroieed2S2t31n01335epAny Fomin Spheres 00ND 23 Client: SPraomjpeclte:Matrix: Sample Name: Lab Code: Analytical Report B(aCarmopnD&rBuedds&PM.sCcIKe9eSerT,.I7n5c3or1p9orated (CDM) Water KIKi0n0gs0f9ie1l1d0R1o3ad "Treated" p13 Service Request: DateCollected: K1000911 2/ 1/10 1355 DateReceived: 2/2/10 UBnaistiss:: nNgA/L Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA PrepMethod: Method Analyte Name PPeerrfflluuoorroo-nmtircitdredceacnaoniocaieciadcd Perfluorobutanesulfonate PPeerrfflluuoorroobduetcaannociSculAfcoindate PerfluorodecanoicAcid PePrefrlfulouroroodhoedpetcaannoicciAccAicdid Perfluorohexancsulfonate PPeerrfflluuoorroonhoenxaannooiiccAAcciidd Perfluoroocanesulfonate PPeerrfflluuoorroopoecnttaannoioeicAcAicdid Perflvoroundecanoic Acid Rest Q ND D UU 013 1 N02D51U ND U N02D8 U1 026 1 N06D0 U1 033) N09D6 1U ND U MRL MDL DFialuctiioorn 3500 0009% 5 11 50 00% 1 5500009Ol5 11 50 048 1 550000 0008851 11 50 000 1 55000 0 OI 11 50 obs 1 55000006011 50 13 1 ExtDraatceted AnaDlaytzeed waulno duMwI02n28 410 2900041 2244lM0 2M/00202841 u4n0 022s u44Ni00 229110020282441 vio uvmoosal 2wa4l0) 22600200282441 40 ymin 22441N00 M291000038441 uno uwi022e ExtrLaocttion 1los0ie52 iosi2 11005546622 10562 lloossise2 isi 1lo0s6e2r los lloossiie22 10462 AnaLlaytsisNote B1903o62 e 10362 119900336622 190362 119900336622 ise 119900336622 iv 119900336622 150362 Surrogate Name %Rec CoLnitmritosl Date Analyzed Q Note PPeerrfflluuoorroo--n{{11.,22.,33,44,-51-31C34C]3b]umtaonroaincoiaeciadcd. 57 0501100 I290I008E41 -- -- PPeerrfflluuoorroo--nn--{{11.,22,-31,34C-21]30d4e]caoncotiacnaociidacid 8100 SS001100 22m1i0022222244 PPeerrfflluuoorroo--na--{{11.,22--1133CC22]ldhoedxeacnaoniccicacAicdid 649+ SS005100 1200020282441 PSeordfiluvmopreos-lni-o{r1o,-21--{113.C223J4un3d0ecKa]nooiccnAecsildfonte. 4675+ SS00000 2u8m1i002222244 Sodiumperfluoro-1-hexane(1802lsulfonate 90 50150 200841 Comments: ------ ---- -- -- ee --------r--mm Prbedo223i101s335e 6 fom1a Sasa tomo) 2 Client: PrSoajmepclte:Matrix: Sample Name: Lab Code: Analytical Report CampDres&MscKeeer, Incorporated (CDM) Baron & Budd P.C/OSTI975319 Water Cantonment "Raw" K1000911-014 ne Service Request: Date Collected: KI000911 2/ 1/10 1415 Date Received: 2/2/10 Units: nll Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Pefiooro-nietradecancicacid Perfluoro-ntridecanic acid Perluorobutancsulforate PerfluorobutanoicAcid PePrfelfuoorroodedceanceaSnulcAfcioincdate Perfluorododecancic Acid Perfluoroheptanoic Acid PPeorrfltuuomrsohheexiasnmoticuAlciindts oe Perfluorononanic Acid Perfluorooctancsulfonate PerfluorooctanoicAcid Perfluoropentanoic Acid PerfluoroundecanoicAcid Rewlt @ MRL MDL No U 50 046 ND U 50 09s 0.41J 50 0020 02) 50 on U NNDD U 0 500 0004985 ND U 50 08s 029 50 008 i0i4}88)1 350 500%11 ND U 50 ol C0195 50 004 ND U 50 006s 028) 50 on Wu 50 13 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note 1 240 1240 W022 20232 10562 10862 190362 19062 1 4/10 29100850 105462 190362 T2310 1 2400 29000850 023 103462 10562 190362 190362 1 2/410 M0102 462 3 190362 1 1 240 2410 mi02232 29000850 10462 10562 19032 19032 3T24B1u0bd2i90s00s850 M10o5862 190362 1 1 2410 2400 2My0I022332 11005566622 119900336622 1 I 240 240 M1023 29000850 105662 105462 190362 190362 1 ano amn0n3 10s 19036 SurrogateName Control %Rec Limits AnaDlaytezed Q Note PPeerrflluuoorroo--nn-{[11..223,,34.-413,C54-]13buCnt3oa]mnaoniociacciadcid so 46 + sam moze SAO 29100850 PePrefrlfulouroor-on-{n1{.12.2-31,34C-21]3dCe4c]anooctiacnaociicdacid 1i00 SS005500 2102232 102232 Perfluoro-n-[12-13C2] hexanic acid Perfluoro-n{1,2-13C2Jdodecancic Acid st 52 550005500 22981100082530 SPeordfiluumoproe-rnf-u{o1r,o2--(113,C22,J3u4n-d1ec3aCn)ooicctaAmceisidllorste a77 + sS0e5a0s un0232 10232 Sodium perfluoro-1-hexane(1802]sulfonate. 80 5010 29100850 Comments: Pines 223101335 indi Se AR Fomia Spr Rte 1080035310 2 Analytica Report Client: Project: BCaampr&DBorudned&sPM.sCc9KeSe7er7,9-I7n5c3or1p9orated (CDM) Sample Matrix: ~~ Water LaSabmpCloedeN:ame: C1an0t0o0n9m1e1n0t1"5Treatment" nis SeDravtieceCoRlelqeucetsetd:: 2K/110/01009111426 DateReceived: 2/2/10 UBnaistiss:: nNgAlL Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLCIMS Analytical Method: Prep Method: PFOA Method Analyte Name Reslt MRL MDL Dilution Factor ExtDraatceted AnaDlaytzeed ExtrLaocttionAnaLloytsisNote PePrfeluforlo-un-otrrdeocannotiecaiciandcddecanoNNiDDc U U 0 S00 009%5 1 1 Z 2400WT 8102W239I10T 5462 T19O03R62 Perfluorobutancsulfonate 012 500029 1 2410 2900900 105462 190362 PPeerrflluuoorroobduetcaannceicSuAlcfiodnate 0297 ND U 5500009ou5 1T24204000 2M9M0I10020293090 105462 105462 190362 190362 PerfluorodecanoicAcid ND U 50 048 1 y4no 2mn02239 10562 190362 PPeerrfflluuoorroohdeopdteacnaoniociAccAicdid N01D5 JU 55000800SSL 11 22441N00 2289110020293090 110055446622 119900336622 Perfluorohexanesulfonate 0430 50 000 1 410 29100900 108462 190362 PPeerrflluuoorroohneoxnaannooiiccAAcciidd 026 ND U 50 500 l0n121T24214100 2W9M0I000293090 105462 105462 190363 190362 Perfluorooctanesulforate: 03s J S00 006 1 2410 8102239 l0si62 190362 PPeerrfflluuoorroopoecnttaanncoiiccAAccidid ND U 032 J 550000o6n 1 1 2410 2410 2289110020293090 10562 losie2 190362 190362 PerfluoroundecancicAcid ND U 50 13 1 2410 28102239 losie2 190362 Surrogate Name PePrfelurorfo-ln-u{1o,2r,3o4-5-1-3n1C43{]0b1]ut,maon2oria,cnao3ciic.dac4d PePrefrlfulouroor-o-nn--{{11.,22,-3143-C123)Cd4e]coacntoaincoaicciadcid PPeerrfflluuoorroo--nn--{{11,,22--1133CC22]}dhoedxeacnaoniocicacAicdid PSeordfiluumopreor-lnu-o{r1,o2--11{31C223}4u-nd1e3c0a4n]ociccanAccsiudlfonste Sodiumperfluoro-1-hexane[ 1802slfonate %Rec 8ol0 8 100 a4+v 67 8 CoLnimtirtosl 050145500 50450 50050 50150 ssddss 50050 50050 Date Amlyrd _Q I20W97010B09H00 22m8110022223399 2291701202093090 1m10022223399 2/9/1009:00 Note -- Ce ommentse_e--e _e --m --------------------ee-- e -- N Pedo 22310a1335kes Fania Super Rterms: 100007030 2 PCrloijeenctt:: Sample Matrix: Sample Name: Lab Code: Analytical Report BCaampr&DrBeosusdnerd&P.MCc/K9e5e7,79-In7c5o3r1p9orated (CDM) Water KNi1n0e0M0i9k1e1-R0o1a6d "Raw" p.16 SeDravtieceCoRlelqeucetsetd:: K1000911 2/10 1457 Date Received: 2/2/10 Units: nll Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLCIMS Analytical Method: PFOA Prep Method: Method. Analyte Name PPeerrfflluuoorroon--nttertirdaedceacanniocraecaicdid. Perfluorobutanesulfonate PePrefrlfuluoorroobduetcaanneicSuAlcfiodnate Perfluorodecanoic Acid PPeerrfflluuoorroohdeopdteacnaoniocicAcAicdid Perluorohexanesulforate Perluorohexanoic Acid PPeersfflluuoorroooncoinaannccsuilcfAocniatde PPeerrlflluuoorrooopcetnatnaoniccicAcAicdid PerfluoroundecancicAcid Dilution Date Date Extraction Analysis Rest @ MRL MDL Factor Extracted Analzed Lot Lot Note No U 50 ND U 50 0d 095 1 W 240 00 105 4 1806 I 2410 2004 10s 190362 024 50) 009 1 2410 29/009010562 190362 0347 ND U 50 oll 50 0095 I 1 2410 2410 229110020294079 10346 105662 190362 190362 ND U 50 043 1 240 2102247 105662 190362 ND U 060 J 50 08s 50 008L 1 1 2410 2400 229110020294079 105862 105462 190362 190362 086) 50 000 1 2/400 2900909 105462 10362 11) ND U 50 oir 50 01 I 1 2u440100 0292102049079 11005544622 119900336622 0570 50 004 1 2/400 210247 105462 190362 05815 1 5500 0o0n6 L1 242400 21901200294079 11005546622 119900336622 ND U 50 13 | 2410 210247 10462 190362 SurrogateName PPeerrffluloorro-on--n[1-.[21,3.,243-,134C,45]-b1un3toaCmn3ao]nicoiaeciadcid. PPeesrflluuoorroo--nn--{{11,,22-31,34C-21]3Cd4e]caoncotiacnoaiccidacid PPeerrflluuoorroo--nn{-1[1,.22--1133CC22]]dohedxeacnaoniccicacAicdid SoPdeiruflmuopreorf-lnu-o[r1o,-21--1{31C,22,J3u4n-d1e3cCa4n]coiccunAecsiudlonate `Sodium perfluoro-1-hexane(1802sulfonate %Rec CoLnitmirtosl AnaDlaytezed Q To 40 + 0S011 0 0 29010n09d09 100 5500105500 228110022224477 46+ 53 5S0005500 229110020294079 757 550000550 2288110022224477 80 50450 29100909 Note -- Comments PreSd2e2310e133s5 csRepon famia Sphere 10m 27 Client: Project: Sample Matrix: SampleName: Lab Code: Analytical Report `BCaarmopnD&rBuedds&P.MsCc/K9e5e7sr7,5-I7n5c3o1r9p.orated (CDM) Water NKiIn0e00M9i1l1e.R0o1a7d"Treated" 17 ServiceRequest: DateCollected: K1000911 2/1/10 1508 DateReceived: 2/2110 Units: Basis: nl NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLCMS Analytical Method: PFOA Prep Method: Method Analyte Name PPerefflluouroo-rno-ntrtiedeicnadnosiccaancaiodidc Perfluorobutancsulforate Perfluorobutanoic Acid Perfluorodecanc Sulfonate PerfluorodecanoicAcid Perfluorododecanoic Acid Perfluoroheptanoic Acid Perfluorohexanesulforate Perfluorohexanoic Acid Perfluorononanoic Acid Pedluoroocanesalonate P`ePrefrlfulourorooopcetnatnacnioiccAAcciidd PerfluoroundecanoicAcid ResulQt MRL MDL Dilution Date. Factor Extracted Date Analyzed Extraction Analysis Lot Lot Note WNDU 30 ND U 50 0461 09s 1 W 241I0 0J ABN0W2SSI100554662 T19o03T62 024) SO 009 1 2410 25100919 105462 190362 0.40 J 013 J 50 on SO 0095 I 1 2410 2410 2100919 2102255 105462 105462 190362 190362 _NDU 50 048 1 2400 2102255 105462 19032 ND U 059 1 50 oss SO 00BL 12410 1 2470 2802235 290100919 105462 105462 150362 190362 090) 50 0030 1 2410 2/9/100%:19 105462 190362 107 ND U 50 on 50 on T2410 1 24100 29100919 28102255 105462 105462 190362 190362 076) 50 O06 1 2410 INOS losic2 190162 78 059 1 50006 50 on 1 1 2400 2400 28102255 29700919 105462 105462 190362 190362 NU 50 13 1 2410 20225 105462 190362 Surrogate Name PPeerrflluuoorroon-{n1{.12,2,,33.,44,-51-31C34C]3]buntoanroaincciacciad cid Perfluoro-n-{1,2,3,4-13C4] octanoic acid Perlluoro-n-{1,2-13C2]decanoicacid PPeerrlflluuoorroo--nn--{{11,,22--1133CC22]}dhoedxeacnaoniccicacAicdid SPeordfiluumopreor-fnl-i{o1r,o2--11-3{C122,J3u4n-d1e3cCa4n)ooiccanAccsiudlfonac: `Sodium perfluoro-1-hexane(1802Jsulfonate: %Rec 63 39+ ES 100 430 36 40 7 L Control Limits Sos 5040 50-10 50-150 S010 50-150 S010 S150 50-150 Date Analyzed _Q Note mons 29100919 RN02255 2219012020:91595 281022355 28102255 281022555 29100919 Comments: -- ------------ -- ee -- Pirnedd2S23i10133S8epAen Fem 1A Supers Refs. 10000100 28 Cleat: PSraomjpelcte:Matrix: Sample Name: Lab Code: Analytical Report `CampDres&MscKeeer, Incorporated (CDM) BWaartoenr & BuddP.C/95779-75319 No 6 Well Plant "Raw" KI000911-018. p.18 Service Request: DateCollected: K1000911 2/2/10 1404 DateReceived: 2/3/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acidsby HPLC/MS Analytical Method: PFOA PrepMethod: Method Analyte Name Result @ MRL MDL PPerefrlluuoorroo-nnttertirdaedceacnaoniociacciadcid NW D U U5500 0% 09s ------ C120 50 009 PPeerrfflluuoorroodbeuctaanneoiScuAlcfoindate 161 0273 50 on 50 0005 PePrfluforodtodeocancrihc dAociddeem0N6Dm0)UoiSc5O0 O0488s PePrefrlfulouroorhoheexpatnaenscuilcfAocniadte 211 62 50 008 50 0030 PePrefrlfulouorroonhoenxaannooiiccAAcciidd 271 089 J 50 oan 50 02 PPeerfrltuoirooocptamnodiciAocind, 7E 9 SR50 J00.66 PPeerrfflluuoorroopuenndteacnacniccicAcAicdid 261 ND U 50 on 50 13 Dilution Date Date Extraction Analysis Factor Extracted Analyzed Lot Lot Note T yUI0 mono: 106 P06 I 1 2400 J400 2102302 29100929 105462 10542 190362 190362 T2400 1 2400 29100929 JWI02302 105462 105462 190362 190362 i1 W2o 400 M2O81I02S300 |10O5S4e622 L19i0e36r2 1 1 2410 2410 29100929 29100929 105462 103462 190362 150362 I 1 240 2400 29100929 102302 105462 105462 190362 190362 O1 O.2.40. MI023502 105i462 T1903c62 Lo 2400 L410 29100929 28102302 105462 105462 190362 190362 Surrogate Name PPeerrflluuoorroo--nn{{11,.22,,33.,44,-51-31C34C]5b]untoamnaoniocraccaidcid PPeerrfflluuoorroo--nn--{{11,,22.-31,34C-21]3dCe4c]aoncoticaanceidacid PPeerrfflluuoorroo--nn--{{11,,22--1133CC22]]hdeoxdaencoainccaicciAdcid PSeordfiluumorpeor-lnu-o{r1o,-21-{113.C223J,u4n-d1e3c0a4n)oioccunAecsiudlfonste Sodium perfluoro-1-hexane{ 1802]sulfonate: %Rec wn 6 %100 79 st B67 r 8 CoLnitmritosl T0050 50150 5500115500 50150 50050 s50a45s0 S005 AnDlaytzeed Q 20530 2/9/100929 2288110022330022 2/9/1009:29 2102302 02/8/310230:02 29100929 Note -- Pred22101338 a] Fomin SeptRte 100 00 2 Client: Project: Sample Matrix: Sample Name: Lab Code: Analytical Repart `CampDres&sMceKere, Incorporated (CDM) Baron & Budd P.CI95779-75319 Water No. 6 Well Plant "Treated" K1000911-019 p19 Service Request: K1000911 Date Collected: 2/2/10 1417 Date Received: 2/3/10 Units: ng/L Basis: NA Perfluorinated Sulfonic Acidsand Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA Prep Method: Method Analyte Name Perfluoro-n-teradecanoicaed Perfluoro-n-tridecanoicacid Perfluorobuancsulfonate Perfluorobutanoic Acid PerfluorodecaneSulfonate. Perfluorodecanoic Acid `Perfluorododecanoic Acid PPeerrfflluuoorroohheexpatnacnsouilcfAocniadte Perfluorohexanoic Acid PerfluorononanoicAcid Perfluorooctancsulfonate: PerfluorooctanoicAcid PerfluoropentanoicAcid PerfluoroundecanoicAcid Result Q ND U_ ND U 0.18 J 127 012 J ND U ND U 0.25 J 035 J 072 ND U oss) 0437 0.66 1 ND U MRL MDL 50 0%6 50 095 SO 0029 50 on 50 0095 50 048 50 08s 50 0081 50 0030 50 oll 50 002 50 0046 500.066 50 oil 50 13 Dilution Date Factor Extracted 1 FU 12400 1 24/10 12410 12410 1 24/10 1 2410 1 240 1240 12410 12400 1 2400 1 410 1 2400 I 2400 Date Analyzed TROT 28102310 29100938 29100938 28102310 28102310 28102310 257100938 297100938 297100938 28102310 202310 28102310 257100938 28102310 Extraction Lot ToT 105462 105462 105462 105462 105462 105462 105462 105462 105462 105462 105462 105462 105462 105462 Analysis Lot Note 106 190362 190362 190362 190362 190362 190362 190362 190362 190362 190362 190362 190362 190362 190362 Surrogate Name Perluoron{1.2,3.4,5-13C3] nomancicacid PPeerrfflluuoorroo--nn-{{11,,22,,33,,44--1133CC44]]obcuttaannooiiccacaciidd Perfluoro-n-{1,2-13C2]decanoic acid Perfluoro-n-{),2+13C2]hexanoicacid Perfluoro-n-{1,2-13C2]dodecanoic Acid ``SPoedrifulmupoerfol-uno-{r1o,-2--{113,C22,J3u4n-d1e3cCa4n]ocicctAacncisdul.fonate Sodium perfluoro-1-hexane(1802]sulfonate: %Rec 92 61 95 100 6 30 480 7 36 Control Limits S010 SO-150 S0-150 50-150 50050 50-150 S050 50150 S050 Date Analyzed Q 00 2097100938 2871023:10 21023:10 2/9/1009:38 28102310 2B102310 28/102310 2/9/100938 Note -- Comments: -_-- Prnleod2S23o10a13p35sAAR Fom 1A 30 Supers Reece. 100015ev 3 Client: Project: Sample Matrix: LaSabmpCloedeN:ame: Analytical Regort B`aCraomnpD&rBuedds&P.MsCc/Ke9eSer77,9.I7n5co3r1p9orated (CDM) Water Method Blank KQI00053204 p-20 Service Request: Date Collected: K1000911 NA DateReceived: NA Units: nglL Basis: NA Perfluorinated Sulfonic Acids and Perfluorinated Carboxylic Acids by HPLC/MS Analytical Method: PFOA PrepMethod: ~~ Method. Analyte Name ResultQ MRL MDL Dilution Date Factor Extracted Date Amlyzed Extraction Lot Analysis Lot Note PPeerrfluuoorroo--nn--tcrtirdeacdaencoiacnaociicdacd Perluorobutancsulforate PPeerrfflluuoorroobduetcaannoeicSuAlcfiondate PerfluorodecanoicAcid PPeerrflluuoorroohdeopdteacnaoniccicAcAicdid Perfluorohexanesulfonate PPeerrfflluuoorroonhoenxaannociiccAAcciidd Perfluorooctanesulfonate PPeerrfflluuoorrooopcetnatnaoniocicAcAicdid PerluoroundecanAdcicd NNDDUU 0.13 1 0271 0221 ND U ND U 0.097 021) 027 J ND U 03 ND U 060 J ND U 3500090456 1 1 Z2W4I00 IUWMII002B3HI 11005554662 190033662 50 0029 1 2410 209001007 105462 190362 50 oul 500095 T2410 1 2400 29001007 28102332 105862 10562 190362 190362 50 ods UL 2400 2WI02332 109462 190362 50 08s 50 0081 T2410 1 2410 2810232 29101007 lose 105462 190362 190362 50 000 1 2400 29001007 105462 190362 50 oun 50 on T2410 12410 2001007 202332 105462 10462 190362 19062 SO 0046 1 20028102332 losi62 190362 50 006 50 on 1 I van 2410 um102332 29101007 10562 105462 190362 190362 50 13 I J4n0 usn02332 lose 190362 Surrogate Name Control Date %Rec Limits Analysed Q Note PePrefrlfulouroor-on--n[{11..223,44-,153-C143C]3]buntoamnaonicoiacciadid 93 81 5S000150 mI29010%130027 PPeerrfflluuoorroo--nn-{{11,,22-,13,34C-21]3Cd4e)caoncotiacnaociidacid ot 100 5005 50050 28102332 28102332 PPeefrlfulouroor-o-nn-{{11,.22--1133CC22]]hdeoxdaencoaincciacciAdcid 8 65 50-10 5010 2970 1007 202332 SPeordfiluumopreor-lnu-o{r1o,-21--1{31C.223],u4n-d1e3c0a4n)ooiccmAecsuildfonste 756 5500115500 2288110022333322 Sodium perflvoro-1-hexane{ 1802]sulfonate 80 50150 29101007 -- Comments: B -_-- oUnUBUmm Pnroars 2S2t3e1r0n1L33i8pArt Fmin Sips betes: 000080 3 Pclrioejnetc:t Sample Matrix: LSiabmpCloedNeame: AnalyticalRepart BCaamrpo&Dn Biuded&PsMCe9eSkrT,ISInIcoS1r3p9orated COM) War LKaQbICo0o0o53l20S5ample p21 SeDravtieceCaRelqeuceesdt:: NKIA00011 DateReceived: NA UBnaistiss:: gNAl Perfuoriated Sulfnic Acids nd Peruorinated Carboylc Acids by HPLCIMS PArnealpytMiectahloMde:thod: PMeFtOhAod Analyte Name PFefeuooronn deecmaneoacsa Peaoropuanesilonic PPeetfluuoorroodbeucaannoeicuAlcaidte Peuorodecancio Acid PFeerruuoorroohdeopdteacnacniociAccAcdid Perluorohoanceutonte PPeeurolorrtoenosmnaenciiccAAcdidd Pefuoascancaiionte PPPeeefrffluluauororrooopuonncdttoaacnnaccinicccAiccAicAdicdid Rew@ MRL MDL DFialctoorn ExtDraatceted ADmated ExtLroatcinAnalLoytsisNote wTs 050So W 0% T1 a7i9o0 aTAmOiSn Tloossee oe ns 50 omy 1 yi moors losis 1506 sauos 5S0o oomus 11 wwaul m amio0mas lloossiee i1o0wa6: 860 50 os 1 vaio amon lose ime s0u2s 5500 ooossm 11 2a41w0 2a9mMi00o%nens l1o03k2 110503s62 2s 50 ooo 1 ui vyioosss 1osie2 10s 9e5r0 S50 oo0;a 11 w2a4n1o0 mwoonons l10ossie2 w103e62 80 So ome 1 vino amionin lose ime 91s50u0s6 S5S000010o30N6 111 2v24a40m00 0m28o100n2%1n7 su10s54ie62 1m159003e36622 Surrogate Name wRe CLoinmtirtosl AmDatied OQ Note PePFteeurrfoTlrouoroor-onn-{1n1-..{.213.,23.,.434-,-411,335-CC14H3]]Ca5cb]tunatonnaoaninceoiaacciiaddcid 90 5SS0-1115050 ma287om10oa23:sn17 PPeelluootroonn{{11..22--1133CC22]]dhexcaannoeiaacciidd 8sWw Ss1e0o a29m0n0o9s418 PPeefflluuoorroonn.{1122--1133CC2a]lduonddesccaannciisAAcciidd a5 ssiss a2mmii0022331177 SSocdiiaummppeefolruroo-ML1-heSxa1n5c{018]Oo2laslnfotnoatmee 76 SSais amomoorns Comments: em233--00--13--5 ---- -- [TT -- = CPlrioejnetc:t: Sample Matrix: SLaambpCloedeN:ame: p-- BCaarmopnD&rBuedds&P.sMCe/eK9eSTrsI,0I-nTcSo3r1p9orated (CDM) Water LKaQbUCOo0nstr3o2l.0S6ample Dup .2 SeDravtieceCoRlelqeucetsetd:: KN1A000911 DateReceived: NA UBnaistiss:: nNAg Perfluorinated Sulfonic Acids and Perfuorinated Carboxylic Acids by HPLC/MS PrAneaplytMiectahloMde:thod: MPeFtOhAod Analyte Name PeFrlouorroo-nn-rrddeecaanoniocaecisdd Perfluarobuancslfonatc PPeercflfuuoarrocdbeucaannoeiScuAlcoindate PerflorodecanoicAcid PPeerrfflluuoorroohdeopdteacnaaniocicAAccidid Perluorohexancsulfonate PPeerrflluuoorroohneoxnaannooiiccAAcciidd Perflorooctancsulfonae PPeerrfflluoorrooopcetnatnaoniocicAAcciidd Perfluoroundecanoie Acid Remit @ 99450 94s 91700 855 912008 955 986850 980 110020 930 MRL MDL DFialscttioorn ExtDraatceted 3500 0049%5 11 U24Un0 50 009 1 2410 55000009on5 11 2244100 50048 1 240 5500 0o0m8 11 a24nno0 500030 1 2410 S 50 00 01 1 224000 50 004 L240 550 00000s 111 22a4n000 50131 2400 AnDaabtzeed ExtrLaocttion AnaLloytsisNote I02W3I2N5 2900957 2M5I00020392557 102325 m2i00029a5s7 29000957 2u90I000292557 y102325 a29m1i000n9a5s7 3102325 T10o54s2 e19e03n62 losie2 150362 I10s84i6c2 115500336622 10846215032 il0osisc2 1190033662 0sic2 150362 T10o8k6e2 115900336622 108462 150362 ilossii62 11590035662 sic 1s0362 Surrogate Name Rec CoLnitmritosl AnDaaltyeed Q Note PPeerrflluuoorroonn-({112.,2334,,43--13TC33C)S]bumtaonroiaanid 57 T501510 002002957 PPeerrfflluuoorroo-nn--{{112.-21334C-21]3Cd4e]caoncotiacnaociicdacid 1%00 S50115500 22801203232255 PPeerrfflluuoorroonn--{{11.22--1133CC22}]dhoedxeacnaoniccicaiAdcid 8 5500115500 228910002935275 SoPdeirfulmupoerroao-n{o1-21-{113.C223]4u-n1de3c0aHnconiesAcuildonste 277 S50a15s0 22m0022332255 Sodiumperloro-1-hexane(1802lsulfonate 50150 2900957 [-- Piinet2a 2310133-- 5 -- fom a Spb 16am m0 3 Client: Project: Sample Matrix: QUOC Report p23 `BCaampr&DrBoeusdnsde&rP.MCc9K5e7e7,9-I7n5c3or1p9orated (CDM) Service Request: Date Analyzed: K1000911 2/8/10 Water 290 Perfluorinated Sulfonic AcLiadbs aCnondtPreorlfSluaomrpilneatSeudmCmarabroyxylic Acids by HPLC/MS. PAnraelpytMiectahloMde:thod: MePtFhOoAd Units: nglL Basis: NA Extraction Lot: 105462 Analyte Name PPeerrfflluuoorroo--nn-ettirdaedceacnoaincoiacciadcid Perfluorobutanesulfonate PPeerrfflluuoorroobduetcaannoeicSuAlcfiodnate PPeerrfflluuoorrooddeocdaencoaincoiAcciAdcid PePrefrlfulouroorhoheexpatnaensouilcfoAncaitde PPeerrfflluuoorroohneoxnaannociicc AAcciidd Perfluorooctanesulforate: PPeerrfflluuoorroopoecnttaanncoiiccAAccidid Perfluoroundecanoic Acid LabKQCIon0t0r0o5l3S2a0m5ple Result Expected %Rec 104100 5 10 104 8 9s 8s 110000%9 00 80 100 10 6 8 02 98s 00 10 10 9 2s 950 10 10 9 os 95s %0 100 10 9 90 s 10 10 9s 9 06 100 16 DuplicatKeQIL0a0b0C5o3n2t-r0ol6 Sample. % Rec Result Expected %Rec Limits 995 %0 100 10 100 50-150 9 50-10 945 90 10 10 95 9 50-150 50.150 60 8S 10 100 6 8% 0-10 0.150 08100 20 10 108 92 50-150 0-150 9s %5 10 10 9% 50-10 9 50-150 80 BO 10 100 88 50.150 8 0-150 0020101000 12 0-150 10 0-10 930 100 9 0-10 RPD RPD Limit 4 30 17 30 4 30 2 30 2 30 1 30 5 30 73 3300 2 30 8 30 0 30 7 30 123 3300 Comments -- -- -- -- ee -------------- Plrisoca2a301m0 13L35 ACS LabConeSample Sry 3a Sopher 00001000 LS CSoloumbeia services PriCnrteeadt;ed14w0it2h12A0n1a0l6yp:42R1e4:p0o0rtPeMr PDraotjaecFtile RienssutlrtumTeanbtleName_ [Sample Mame [injection iat E00w22a00n88'11s000SP\arSomajpemlcpetlssePLsoFLnCognsg1bwif _ RAiPGIo500[ 0o0T00m 7 ectonv[8atume| 2/8/2010 8:54:09 PM SampleType [Unknown| PFClinetexLong dam ar | Weightto Volume 1[0..0000 Results Summary pnraatyePeak shame - | sara | BAraReTRT|| pnapoiye mes | GamleercCoene: Hodrea a | PFOA 1 | 13C-PFOA | 3080900 | 0.00(1.36) 0 | Na No | [[PPENRAAY [Tproes | |[v113oaccPppreTonAsa |||a2e7wi5e3r0mo0o0 = 0 ||a2m0m0303ee(@22s4ms2|y|) w4wm | NA oors | PFDA1 13C-PFOA | 2512500 | 0.00(334|) 0 nA | Pr[FPFroUowstl1 [TTaceerrunam| 13CPFOS | e1asei0 6362700 ||| ra00rm0i4ew1o0l)m|yT| sain ~ 0010 NA t| | [proo on1_|| T1cO eroRon|| emem so | omoewen| 0 | wa fPfeoPFrrETnTrAA 1r 1 a[[r11a3ccr .pPrFoDo oonA||n71w4oT e3m0s6es0o| --0|~0o0o5.01s47)e| 0 T NA Noe| No|| No. wNol Ne --| No|| No--| Na o $e ZAS. oljulie, peal Page 50of 242. ES 3s 4 folarmbleServices: CrweithAanatsReepss Printed: 14/02/2010 6:41:00 PM WeSummary Sperm [rronz [sore.rron oraz Spr free 2 [s.10sros [rove [[oeoruomreron [scrim Toros2 we| wwe ann|Hg|ins| wi| 0 | me|omesm| imam|w|e ow | owen | amas| ww mam| mm | wn | ows | we 234253) 8668 No em| eww | wo |waanve || owes| 0| we| wom| wm | |Tsomwoa||me0w | wo |oom | w-e | wow | we | wera | we wo || me | omaem | we | [From TT | + 77 (4.64) 2367 No 0.00(0.29), No formas S_13C-PFDoA [pera ow 4.75(4.64) | ww148980 | No | 0.00(3.08) | --] No. t sues we [| No | omem |we| oages1 01202 5 Columbia 8 Roem services QuantitativePeakReview CT Created vith Analy&2Re6porter Printed: 14/02/2010 6:41.00 PM K1000911-001 a 413P0/F1O6A301 0a _ Baseline Missed | 41137C0-3P7F2O0A02 Baseline c Missed | 463P01E4N1A90| 0a Baseline c Missed | 461830C1-4P23F0NADa Baseline 0 Missed | | | . o ~ A ph | _ 499P.F0O8S001 Da 50133.0C/-8P0F.0OSDa Baseline _ Missed | Baseline Missed 5130P/F4D6A9.01 0a 511530C4-7P0FO0ADa Baseline Missed | Baseline c Missed | 63.P0/F5U19R.A0 1 0a 15635C,-01P2F7U00RADa 599P.F0O/8S010 a 50133.0C/-8P0F.0OS0a Baseline Missed | Baseline c Missed | Baseline Missed| Baseline . Missed 3 a wpe el A 6130P1F5D69O.A 10a 61135C01-1P6F9.DO0Aa C-Baseline Missed | B: aseline:[Missed | i he 663P0E6T1A901 0a Baseline Missed | = a 61153.C0-1P1F6O090A.a0 Baseliionenc MiPesa sed 713.P0F18T6E9A.01Da 51135C0-/PF1D6O90A0a < Baseline - Missed | c Baselineo Missed 0 Before O After a7 Page 52.01 262 7 ASnoalluymtibciaalServices~ p27 PriCnrteead:ted14w/i0t2h1A2n0a1l0ys6t:4R1e:p0o0rPteMr IonRatio Confirmation K1000911-001 boy ] Eo P| heen| ZAR | ledde 413.P0F/3O6A9.20 0a <BasecMiisnseed | 463P0E2N1A920 Da BaselciMinsseed | 499.P0F1O98S.02Da Baselc Miisnseed | 513P0F26D92A002 BaselMiisnseed Wrong Peak Wrong Peak Wrong Peak Wrong Peak -| = 3 = inten| ges hate dus 5630P1F2U6D9A02Da BaselciMinsseed | 5P99F.0D19S9.20 Da Baseline Missed | 513P0F/D1O6A920 Da BaselcMiisnseed | 663P0F/T1A629D0a BaseliMinsseed Wrong Peak Wrong Peak = Wrong Peak Wrong Peak =A1 baI 71P3F0T/e1A6203a0 BaWisoeng.lPeMiiasnkseed 0 Before 0After Pa53g012e02 3 ACAonlaulymtbiicaal Services 28 Created with AnalySi Reporter Printed: 15/02/2010 2:34:00 PM FrDaatmaeFrile cFz0sBt0PSamRplePsshCorwit RnoetsruunmTenatlNeame__APG1a0580t00S0amplesShortedt [sample Name scionvia Tk1000s11-001 2/9/2010 6:46:38 AM {1 InjectionVolume! |vito vgolumme U[00n00k0nown Results Summary . `Analyte Peak Ts `AnalyteRT f prant m | wsorrea| swsen| 12sa2n | P[[FrprrPoes:esoAte1 at||| w1owo3oCpe-rrrPFnmHsXsA| |||ss5w8ae3e12wze00 |[|[s3so.o6o0moq(3eu.m6n0)m||] [[brraatt | | ucOera||smwaamn|[smsems|e| |Epperrpseat1 | 13CPFHxA | 5831200 | 6256.23) Teor | samo | essen| |e0prs | vaceron | samo [ssn| -- Calc. Conc. --] seetee | 000s | = | 0 56s2e04z4ss ||| 0.08 wwea | No owvo || jmenm || ow || W ne wos | oot | No ses we | seo ww] | S_13C-PFDA 13C-PFDA 4639400 | 7.68 (7.65) 4839400 1.00 No. 1 Hu!o evne Poge 4001245 w Lm nCrseatedTvoitsh aAna0hSiRarer RC Summary "Snares [roca pr rroonssz [prrpa2 [orrusz [reo es orn[SH|eEctRs mam| swan| swe smn | we ve | wo | [omen| ves ow] Temwmeewm||emw [|wew | [owoowwe||m ve 624622) | ue| 155200 mo | No | sean | wo me wo Cimam| smo | we| mmm| wo fp 5 AGnoallaytmibciaal Services" PrCinrteead:ted15w/i0t2h1A2n0a1l0ys2pt:.3R34e:0p0o0rPteMr Quantitative Peak Review K1000911-001 | 3 -- 1 -3 oT ser x 360 Fl ? i od he] ba2s1e3l.Pi0Fn11eB6A8.10Mi0sased | cBa21s13e7lC0i-n1Pe7F2B0MA0is0sed || B2a6se3Pl0iFn2Pe1A901Mi0s8sed| 311530C-2P7F0H0XA0a aseine : Missed na pea - T bop I " " iE a wef CAS eB LA Bas2e9l9Pi.n0Fe8S0(0|Mi0ssed | Ba4s0e13l80i0n1-e0P:F3H0MSi0s2sed || | Ba3s1el3PiR0nH2eX6AM9i10s0s8ed | cBa3s11e53l0Ci1n-2eP7F0H0MxiADsased EE ogee ongPea y ol | ia : | iL | | PFHpA 1 13C-PFHXA PFHXS 1 180-PFHS _ BaselinereMissed | Baselines. Mzissed || cBa"sellinieveMissed | cBasetlinoe CeMissed | RB | L i Bl | S4_0138.00/-1P0F3H0S0.a Baseline Missed | Ba5s1e15l30iC4n-e7P:0F0OMAiDsased ! | Ba5sS7e_5l10i31nC4e-7P0F0MDi0Asased | Ba5se11l53i0Cn4-e7P0F0DMAi0sased 0 Before O After Page 51 01 205 a 8 ASnoalluymtibciaalServices- Created wih Analyps3t1Reporter Printed: 15/0212010 2:34:00 PM fon Ratio Confirmation 7 |= =n :4 350 | meeeLIT TA K1000911-001 oT T a=| 2ol h5 esti| hen? EY 2130/P1F6B6A.200a BaselcMiisnseed | 2630PF2P1e9A020a Baseline Missed | 269.P0/E99S.02Da BaseloMiisnseed | 313P0F1H1X92A002 Baselc iMinsseed - _ Wrong Peak---- Wrong Peak* Wrong Peak Wong Peak ~ A - hi I a Dito ids TA = mn " . 363,P01E3H1D9A.200a 399P.F0/H9I9.S020a 5_11530C47F0F0D0A2 NA BaWsroenlgcPMieiasnkseed | BaWsroenlgoPiMeianskseed | BaseWlrionneg PMeiasksed | BaWsroengl.PMieiasnkseed NB PFBA and PFPeA do nol ave qualiying on ransiions 0 Before OJ After Page 52 0f 245 a 4Columbia Analytical Services Created vith Anal}32Reporter Printed: 14/02/2010 6:41:00 PM DaPtraojeFcitle 0Ev2a0n8's10PbrSoeacmipslPeFCssLownigf InRessturlutmTeanbtleName __ AcP2I05801000SamplesLodnbg [SameName | Ricoos11-002 SampleType | U5nison LAcquoisitjion Meethocd[at2 onvial|wWeightovoiome [ "00 000] TI CEN [TewTw Results Summary mAenatlyete Peak [| timeame |1[5wAamnaa |An[aAbRItSeTR]T mavens[| CaGleOCoHne || ooaltesr |PPRFOOAAT1 h[rirrt | 313ocP-EprNoAa||d22a10E 26e49s510000 |||22120.3025e(n1|9.3t 84)| 19t1e1a1s00 || o oo1w3s6ss0 ||| WM Nwoo o| pros 1 10PFos| S050 | 20325| two | 2360 No [pron | aceron | asm| oman 0 NA | me | PrUnA 1 1SCPFUA| sti | 410608)| 5997 bse 0aet ND No [Prosi ["aceros | soso| oooro)| o NA No [Prooar t T Tr| ewssce-- roo|s momo |ooowen| 0 | wa T No [[pprreiaE ntt L||T 1waoceeerooO no||n TrnIoR otoOo o| o|R omowosesrte)e|| 0 | [w7aLA| No wm > S ee mestmmtemte cet -------------------- 7 Ao\ns LSikits Pa56gof2e62 a 3 Sombia Analytical Services PrCerdea:ted1w4it0hA2na2l0fs1i 0Re08p0o4PrtI1erA RCSummary [rronz | 5_13c_PFOA [pra [[rSso_mrsroassc, _prA emer ss EF (Ey alc (Exg [mam | wow | ne | seem [=ome | 134(1.368) | 2969100 ene No 15.54 (50.17) No | omozs T asaaan|| awrwea |[wo|| Tooawo0.m17) amam| wm |wo [mmm atio Confirms. ves No ves .| |wo ]| |e | r s_racProA m aw | wesw | Ne | ooo ~o wom |wo| [SPr_urcerumA | crown || sez Tes0a001200) ro ros Tomar| wo |wo [owom | | Fro Temmm | [wo [owom | = p[r mem [arsusn | mom | wo | owes --~----| = vom|wm| we | owem| Pa55gor2e62 " 8 Schum Analytical Services Quantitative PR eakeview = 5g 5 Ea PrGinrtaedt:ed14w/i0h2/A20n1a0i6s:4R1e:p0o0rtPeArA K1000811-002 5 z 413P0/F1O6A801 0a 41137C.-0P87F2O0A0a 463P0E4N1A901 02 4681.30C/4-2P3F.N0A0a _Baseliie c Missed | Baseline cMissed | Baselinec Missed | oc Baseline o Missed 499.P01R8O0.S0 1 Da uBaseline c Missed | 50133.0C/.8P0F.0OSDa Baseline c Missed | 513.P0F/D46A91.0 Da Baselines Missed | 511530C4-7P0F0OADa Baseline u Missed an =| > 5630P/F51U9R.A0 1 0a 51635C0-2P7F0U0RADa 599P.F0O8S010 Da 5013300/-80P.F0OSDa Baseline _ Missed | oBaselinec Missed | Baseline Missed | c Baselinec Missed ~ Lils= Eo ast aia f = 613P.0F1D5O69A.01 Da 61135C01-1P6F8.DOA0a 663.P0E6T19A.01 Da 611530C/-1P6F9D0OADa CBaselne Missed | uBasolne cMissed | Baseline: Missed | Baseline c Missed | 713.P0F/T8E69A.01Da 61135C0-/PF1O609DAa0 Baseline c Missed | Baselineo Missed O Before 0 After as Page 56 of 242 4 SAnoalluymtibciaalServicesTM Created vith Anaifit35Reporter Printed: 14/0212010 6:41:00 PM Ch fonRatio Confirmation T! TE iaA7 fE: N e | K1000911:-002 4130/P3F6O9A.20 0a 46P3E0N21A920 0a 499.P0F/9O9S.02Da 513P.F02O62A0.00a BaseWlrionnegcPMeiasksed | BaseWlrionnegoPMeiasksed | BaseWlrionneg:PMeiasksed | BcasWerlionnegcPMeiasksed - -| ~ 1 = = = a pel | 7] RT a av 563P0F/U26M9A020a 50P9.F0/O99S.02Da 613P0F/1O6A902 0a 663P.0F/1T6290.0a CBaseWlrionneg PMeiasksed | Ba< WsroenglcPiMeiasnk,seed | BaseWloinnge PMeiasksed | BaWsroenlgc PMieiasnkseed lHh oin, 71P3E0T/e1A629D0a BasWeloinnegc PMeiasksed O Before 0 After Pa57gof2e42 as 4 lumi Analytical Services PriCntedr: 1v5e/i0t2h:Aa2n0a10t2:13Re48e.p0o0drPeMr POraotjaecFtile E0v2a0n8'1s0\PSraomopcliessSPhFoCrst if inRessturlutmTeanbtleName__ A0P2I0851000S0amplesShorted ab [[SAacqmupilsietRioanmbeate ||2i0o7o2o0e11016-50062TSA [[inAjceacuitsiiotnivoinMaelthod[|4&Pr2CKnetexShortdam [|inSjaemcptlieonTVyopleume|| Unknown ||DWileuitgihotntFoaVcotlourme | [100000 [rr | cores .| ARneasultPesakSummariyshame | tsares | RAoRtEeRTRT | vay area | CGoatee CCoonne odeos?r]| ([PPrReAerTr [ros [Prat || taceRun| szse00 |3sece0)| emei0| oss| Ne || | reopens | soso |s2s2m | sem | om | ne | | iscprma| samo | saan| seo | os No | | prripa 1 TSCPRA | 5204800 | 624629 | a1l21l740 054 >|| [sores | noeroa | wwe onan| www | om | ne | saceron | orion | seam | 7esqes| wwe|wo ww Te | ZY paste Sl Page 5301245 a A ollaServices: CrweithAanatis Reepodrter Printed: 15/02/2010 2:34:00 PM RC Summary orenar vmaz| - www |ow | wa [srriss | mammaso|oswosn|[wo|moevon|]= || Prine cae sam | ve [soermroon |siomeamm||awemro | we ||warm |e . 8 Solambia Analytical Services" Quantitative Peak Review Ie Tims| | rT Created with Anas38Reporter Printed: 150212010 2:34:00 PM K1000911-002 1 To sp| 2130/P1F6B9A.01 0a 21137C0-1P7F2B0A08 263P0F21P8A010a 31135C-0P2FH7IX00A0a Baseline. Missed | Baseline: Missed | Baseline Missed | Baseline - Missed 209P.R0/B8S001 Da 40138001-0PF3H0S08 |{ 313PE0H2X6A901 0a 311530C-2P7F0H0KA0a C Baseline - Missed | .Baselinec Missed | Baseline oMssed | Baselinec Missed 2 : o | 3 | EE = Trl el Sp] Spe, mrp || ssPoFnHtpaA01oa J1e3gCa-PmFoHX0As || swPFoHeXoS 01 s 40138001-0P5F0HS0a | -BaselineI: Misised | mBasrelineI . 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Missed | Baseline u Missed A I~- ; |ol | 499P.0F1O8S001 Da 50133.C0-8P0F0OSDa 513.P0F/4D6A9.10 0a 511530C4-7P0F0OADa cBaseline Missed | cBasclince Missed | Baseline Missed | c Baseline c Missed HE i - -- 3A 563P0F5U1RA901 0a 15635C0-2P7F0U0RA0a Baseline Maiisesed | uoBaswelite u Missed a 3 . f= 599P.F0/D8S001 0a | :Baseline Maiissed | | i wife 501330C/-8P0F.OSDa Baseline omMaiessed ' 612.P0F1D56O9A.01 Da Baseline Missed 6151.30C/-1P6F9D.00A0a + Baseline Missed 663.P0E6T61I9A.01 0a Baseline c Missed 61153C0-1P6F9D000A0 | Baseline Mot | 713P0F1T8e6A90| a 611530C1-6P9F.D0O0Aa Baseline. Missed | Baseline 0 Missed O Before O After 53 Page 60 of 262 VASACnoalluymtibciaal Services- Created with Anapt43Reporter Printed: 14/02/2010 6:41:00 PM hikes lon Ratio =Confirmation 0 = K1000911-003 B4a1s3iP0nF3gO8Ac62V0i0s8sed | Ba46s3lP0Fe2N1A(3ZM0i0s0sed| B4o5s5oPnF0eO0S5o02Mi0s0sed| c B5a1s3Pi0F2eD692A0i0vo0ed Wong Peak Won peak Won peak Wong Pek ; 3 somtewe | B5a6s3eP.lFi0Un2eR68A M2i0ssed | Wong peak 1 fhe 713P0r1o69s008 BWasohinnggopieasked Saar 5B9a5sPs0Fi9nO9S02M0i0ssed | Wong peak meine B6a13sP.lF0/De1G6oA8M.20i0sed | Wong Peak Toh Ne Baa6s3eP0lF/iT1ni6e.0A.2M0a0c0ed Wong Peak 0 Before 0 After Page 61 01202 se 4 GAnoaltytaicnal Services- PrCinrteesd:ted15w/i0n27a20n1a0f2i.t3e4.p0o0rPeMr PDraotjaecFtite EGv2a0n8'1s0.PSacmpsesPSRnosr wi RienssutlrtumTeanbtleName _ AGPa05e0100S0amplesShoredt a> [AScaqmupilsietNioanmDeate |TR2o/0200o1707700055.45 A [ecStaimpoienTVyopetama|[5Unkoovn Liniecion Via [4P5FCrmeiexShort dam | vDiluitiongoFvancotourts|[r1o.0r0 | Results Summary - AnHaolayte Peak |[isname | sawn | AAnaBlMyStReTRTT anaieA s | CaSlac.eCcoone. o-- uted? [[[FpPe rrRoaAennsTt r ||[rWraOe acPeFcrBesAr||| wssvsaammawoo1| s[0s1e22o0s200||| oasE memoie h ||| oosmei [N:0o= 1| [pres tsoprs | 3005300 | 42020)| wazrso 0 | mw [PPat | vscemma| swoao |sa1Ga|n swrio oar No | i Pra | acerca | srE o e242| y tae | os | enoe]| [PFs | topes | a0osa0 | 034602| teeio0 | 16 No | [s00o rrmS s [Tscpron | mwaesn | 6oeean| ssosssse0 o 081 N No | SISCPFDA | 13CPFOA | 435800 | 76065)| 4335800 wo | Ne | N4C{I s ZTe Page 57of 265 5s [Gomis Analytical Services' PrCintedr. 15we,it0h2Aa2n01a0t2.3Re4e.p0o0rdPtHeAr `RCSummary avapepeakname | RTE0RT|) ar | Moditesr| Cae(D8U)M | RatioContime PFBA2 1.26(1.27) 201100 No 1.00(1.00) ves Torasz Cemam| [res[een | PrHpA2 eae | [[seorres m [Tossa2 | [s_tacorron ssrsa0 | wm | we|om|ovem| om sm No | ame@oy | ves | R 7eae0 E | NoE0T 400.40) = smo | No | 007030|8 te Pasagof2e45 5 4 Solumbia Analytical Services Quantitative Peak Review [ Tig 33 EE Greated with Analyps.t4R8eporter Printed: 15/0212010 2:34:00 PM - ~ K1000911-003 | Tam Te sat - | 213.P01E6A9.T0a 21137C0-1P7F2B0A0a Baseline Missed| c Baseline c Missed | 263.P0E2P1e9.A010a Baseline Missed | 311530C/-2P7F0H0XA0a Baselineo Missed a rE Ei .5 209P0F/B8S001 Da 4013800/1-0P3F.H0S0a 313P0R1H2X6A910 Da 311530C-2P7F0H0XADa cBaselneo Missed | cBaselnecMssed | cBaselnco Missed | oBaselnoc Missed 363P.0F/H16p9A.01 0a 311530C1-2P7F0H0XA0a 309P.E0H/X8S0010a 4013800/-1P0F3H0S0a 'Baseline2aMissed | w uBasa elinp oc Missed | BaselinercsMissed | BasewlainnegoprMiassed : pro i =z IE L in| IE | : lL 4S63_.108/010-3P.F0HDSa. 511530C4-7P0FO0Aa 5S1_51034C7-0P0FDDAa 51135C0-4PF7O0DA0a Baseline o Missed | Baseline c Missed | Baseline o Missed | Baseline o Missed O Before O After Page 59 0f 245 57 5 SAneallytmicial Services* PrCinrteead:ted15w/i0t2h1A2n0a1t0fs2i:$3f4e.p0o0rPteMr fonRatio Confirmation K1000911-003 - 7% gw JT =T | |i [4 = FC ue i =) p|e 2130P/F1B6A920 Da 2630P/E2P1e9A02 0a 209.P0F19E9S.02 Da _ BasWerlionneg PMeiasksed| oBaseWlrionnegoPMeiasksed | BasWeolinneg PMeiasksed | 7 = 313P01H1A92002 B=asWeloinnegc PMeiasksed | * | a =o | Tipit 363P0F3H1P9A020a 309P.F0/H9X9.S02Da S5_1153.C0-47P0F0O0Aa U Baseline Wong PMeiasksed | B=asWelrionnegoPMeiasksed | Bas=eWliionneg PMeiaskseg | NB. PFBA and PFPeA do not have qualifying ion transitions. 0 Before OI After NA BasWelrionnegoPMeiasksed Page 60 0f 245 58 4 lumi AnalyticalServices- Greated with Analyps.t4R8eporter Printed: 14/02120106:41:00 PM Project Evans ProjecisPres Data File 0208100\SampiesLong wif InRessturlutmTeanbtlNeame__ A0P2I0851000S0ampiesLong 1db [SemeleName TR-- io0Go1T 1-00f imje Votuc me [ ti 5o] n A`cAqcuquiissiittiioonnMDeattheod||2/P6F/C20h1i0n9e:1l6:e45xoPdnaMgm [Dilution Factor | 1.00 LinjectionVial Ts | WeighttoVolume|0.00 `Results Summary - Nnaamie. peak ishame || sam"a| | A(ExRpRT)T| | PFOA 1 13C-PFOA 3433000 | 1.36 (1.36) [Prat | rscrma | aeamoo | 2m@en| prroar[oercs| san [asa| E | PFDAA 1 Tfo he | 2069800 | 3.31 (3.34) | P[rutFURA 1 |W13COPFUPN||A U110013M6010 || 4096409608) || P[ FDSE 1 0|1 T1O3CPPOFOSS ||sseae ed00d |41010)| [ ProcA 1 | 13CPFDO|A 120460 | 475463)| [prran 13CPFD0|A tza0 | s2s1| PFTeA cero | 120460 | 573574)| antes | 126150 vss amo | 12517 east | =t=es | 10245 Tiss | esse | (CngH/mSLC) 0.791 aos oon 0.079 oo oe 0112 012s 0201 | yog"nes | No. | wo | No 1No | Mne e No|| No No | | A fo ze" 2! ite Pa62gof2e62 59  Qumbia nalyticalServices Rosanna PriCnrteead:ted14wi0t2h2A0n1a0lf6i:t41e:p0o0rtPeMr r[srzomsazrron [rne [[rsewsrson sores ros [r[oosmceerins rn [rromz somo [perez [| rrormnm[|wsmamo | | seam| ve= | aman| on | [ammaasm||wwowm || vwee[|mmeemme|| w || vas| own | wo|ma | wm e | a|ovww[meweewm] Iw | weno ||[ww[oowemm| w|]| oa| om| msem ||[ ewe |oomw om||evvws e || | armas| we |wo|amen[ve | [smem[am | wo|omom[ ve | " rossnoratz 8CAonlaulymtbiciaal Services Created with Analypst.5R0eporter Printed: 14/02/2010 6:41:00 PM `Quantitative Peak Review 5a TI . K1000911-004 Tg A "| BE a23e1 f[Ti A --] 4130P/F1O69A.01 0a 41137C0-3P7F2O0A02 463.P01E4N1A9.10 Da CBaseli0nge. Missed | BasleliinegseMissed | cBaselin10.e62c Missed | 461830C4-2P3F0NADa Baseliannegc 2Missed i; :A 1] El 1 499.F018O0.S0 1 0a 50133.0C/-8P0F.0OSDa 513.P0F14D6A9.10 Da 511530C4-7P0F0DADa cBaselite Missed | oBaseline c Missed | Baseline. Missed | c Baseine c Missed . L i 563P0F/5U1R9A.10 0a 51635C0-2P1F0U0RA0a 509.P0F/8O0S.01 Da 50133.0C/-8P0F.0OSDa _ Baseline _ Missed | oBaselinev Missed | Baseline c Missed | Baseline . Missed 613.P0F1D56O9A.10 Da 61135C0-1P16F9D0OA0a 663P0F6T1A9A.01 Da Baselinec Missed | Baseline Missed | c Baselinec Missed 61135C0-/PF1D6OD9A0a . Baseline . Missed 7130P/F8T6e9A010a 61153.C0-/P1F6DO9DA.0a Baseline = Missed | Baseline o Missed 0 Before OJ After 61 Page 64 of 242 5AnlaulymtbiciaalServicesTM PrCinrteead:ted14w1i0t2h1A2n0a10l6f:s4H1e:p0o0rtPeMr lonRatio Confirmation 0g o |= b= |= oN K1000911-004 1 | -f TM la Eo . |1 PFoeOA2 PENAC2e Pa FOS2 paPiFOgAe2 | Ba4s1e3l.i0/n3e69.0MiDsased | Ba46s3e.l0i/n2e19o.0MiDsased | Ba4s9e9l.i0n/e99.0MiDsased | B5a1se3l.i0ne/2:6M9Di.sa0sed Wrong Peak Wrong Peak Wrong Peak = Wrong Peak -I = Cobb a f"| e f| e hbo | Sle | owing | hee allen 563P,0U12T69A.20 0a 50P9F.0O/9S9.20 Da 6P13F0/1O69A.20 0a 663.P0F/T16I9A.20 0a | BaWsroenglcMPieiasnkseed | BaWisoneglcPMieiasnkseed | BaseWlrionneg:PMeiasksed| Ba WsroengloPiMeianskseed ) sip Senet 713P.F0T6e920A Da BaWsreloinneg.PMeiasksed 0 Before OJ After Page 65 of 242 6 3 Goumbia Analytical Services" Created with Analyst.5R2eporter Printed: 1502120102:34:P0M0 PDraotjaecFtile 0E2v0a8n1'0siPSraomjpelciessPShFoCrst wif InRessturlutmTeanbtleName __A0P2I0851000S0amplesShortedit db [SampleName Kioooe0r% s AcquisitionDate |2/6201075:17AM____S_am_ple_Ty|pe U1n0k0nown [injectionVial 7J44~~ | Weightto Volume|6.00 Results Summary -- fiAnniat Peak [name x[isan |AAnEaEisRRTTT|pannatonres | CaCloec oCoonne: Modifpieod? [rEanL t (nTaecrreea || eszmeoo | E12d7e02n0|) emzmo o | e oe [ | we PFPeA 1 13C-PFHX|A 5317500 | 360(360|) 251660 | 047 | No [([rrraaasastt || c1e8oe0fpFnHsa||| 3224300 sus | | 426428) swea| 187200 mem {|| oo0e1m8 | | tNNeooo| |=[PprrHrpnsA 1 1 | | racer | tsopens | --2s2a6r3s0000 || 6823= 33662382))| e901 651470 | --00_201 --| ----Nnoo -- iSie0PrHSON|WhTCiPFOA|0i 4aman0 Y|osmil anA|Osszizeil0 0%L | L re [s13cpron | 1acproa| a3ste00 | 7678)| 4suren wo he | uf Gt te Pag6e1 of 245 6 nalytical Services Crweit AanatBeeposrer IRC Summary arse pesctiame [eranz = pros oraz rpnz | RTEspRT)| aves | ites |Co (Exp) RM | RatioConfirms 12ran | 120210 No | 1000100) es | ae0@e0 | 2st60 |Nvoo || otomo(orowo||, vvees | essen| wen | ne | aman| ves [o| m momo|wme| sma| ve sem LseenL|a oov |w[oe no L| we] - 8 Anoaulymtbiicaal Services Quantitative Peak Review Co p54 PrCinrteeadt:ed15w/i0t2h/A2n0a1l0ys2t:3R4e:p0o0rPteMr K1000911-004 i 1 . CL 1 a|A | A. |. 213P0/F1B6A901 Da 211730C1-7PF2B0A08 263P0E2P1e9A010a 311530C-2P7F0H0XADa Baseline . Missed | oBaselne Missed | Baseline c Missed | Baseline c Missed 1 i . 7 ei i u:T l rg - | Gin 4 I L i > | er do A) KR 299.P0F18E0S.01Da 40138001-0P3FH0SDa 313P.F0H2X69A.01 0a 311530C-2P7F0H0XA0a u Baseline c Missed | oBaselinec Missed | Baseline Missed | co Baseline c Missed | 363P.R0/H1P6A8.10 Da 31135C0-1P2F70H0XA0a C Baseline Missed | cBaselineu Missed i Gan =H f e -| ol 399P.0H80.01Da 4108300-/1P0F3H0SDa | Baseline Missed | Baseline o Missed |= ae I= | Heed Lo = 4S6_3108/01-0P3F0HDSa. 511530C4-7P0F0OA0a 5S1_51.30C4-7P0F0D0Aa 511530C4-7P0F0OADa Baseline Missed | Baseliiec Missed | Baseline Missed | Baselinec Missec O Before O After Page 63 01 245 6 4 CAnoalluymtibciaal Services PriCnrteeadt:ed15w/i0t2h/A2n0a1l0yps2.t:53R45e.p0o0rPteMr fon Ratio Confirmation T 5m - Po| | ne " B2a1s3e0lPi1nF1eB6A820M0isased | B2a6s3e0lPiF2Pn1ee9Ac.20Mi0sased Wrong Peak Wiong Peak oa wo - | : +i K1000911-004 7 = |das 1! Fd: 2J | Bas2e69l.Pi0Rn1Be9S9c.20MsDased | Wiong Peak |== i B3a1se3Pl0iF1nH1e 1Io92AM0i0s2sed Wrong Peak et | Tapsidace Ba3s6e3PlFi0Hn3Pe1A920Mi0sased | Bas3e9l9P.iR0nH9eI9S.C0M2iDsased | Ba5sS7e_5l1.i3n0Ce4-7cP0FM0Oi0Asased| NB Wrong Peak PFBA and PFPEA do nol Wrong Peak have qualfying on transitions. Wrong Peak 0 Before OJ After NA BasWerloinnegoPMeiasksed Page 64 of 245 6  Solumbia Analytical Services Created with Analyps.t56Reporter Printed: 14/0212010 5:41-00 PA Project Data File Rosult Table Instrument Name Ewart Projects PFCs 020810bSamplesLong iff 020810SamplesLong. db API 5000 [[SameteName--Tii00200867270110-96:0245:16 PM [AcquisitionMethod| PFCKinetexiong dam [injection Vial 45 [inSjaemcptlioenTVyopleume TUSnknown | ilutionFactor | 1.00 | WeiogVohlutme [000 [[rom r|woorms| aean[awa|onow| s o | oronr [creo azo [oman | we ResultsSummary TRaveTra r|eonvae m|ei[s,oe [Rma IE senor | aotc SCon | ouwtowe|r [proat 13C-PFOA | 3217400 [135(13)| 120090 | ost No | PENA 1 [I Pros To| r113Co0PPRFsNOAS ||| 2%000 | 22742| tzso 5543200 | 232259e | e 4901e 60 | oon os | he |+ wo Lull 0[mes Se PFOA 1 13C-PFOA | 2521100 | 0.00(334) | 0 NA No | PTFUoRAr1 ont1oacPrUn|A 120270 |a 410608) | e705 0036 _ Neo y| FOr S 1 f | 1acpros | sso | apoasn)| sos c|onoodm e reee eNo d] | = | PETA 1 | 13C-PFDO|A 128020 [ome| 0 Pf FTeA 1 1 13C-PFDOAt oon|| 128020 | 000(50.007(54.74) o NA [Ne -- wyA -- No A =% pile Pa66gof2e42 67 PASSombie,Services: Created with Analy@t Reporter Printed: 14/02/2010 6:41:00 PM SRCummary E-- RT@ORT) | Area | Modfedr| C4 EXB)MRM| RioConfirms Ims 1arc_proa [src pra [ost <orros mTaaawm|| men me | | Ne we | assem) | omom ~o [omae| awe | we | weeds| te Tamas| wm| wo| omom | ve| vas| wo |wwe |we| we [rrumaz Tomuon | | wo | wom| we | [sb.13coprumss| 4a1m0a00n8 | 12m42e70 | wNeo || 1o820m01e86)| owNo a Tomaso |r| ne | omom| w Fomsoron [asa| ws [wo [wom | forma [emam|se| we | owom| w 68 4 SAnoaulymtbiciaal Services p58 PriCnrteead:ted14w/it0h2A/n2a0l1y0st6:R4e1p:0o0rtPeMr Quantitative Peak Review 785 " 1 K1000811-005 or] - 228 " - | = 227 : = d elec ol 413P01F1O6A901 0a cdaseine ised| 41137C0-3P7F2O0A08 Basoino Missed | 463.P01E4N1A9.|00a c@aseinecMssed | 4681.30C14-2P3F.N0ADa Baseline Missed | 499P.0F8O0S.0 Da Basie c Missed | 15033C.0-1P80F.O0 SDa Baseline Missed | 513P01F4D6A901 Da Baselinec Missed | 515103/4C7-0P.0FOADa c Baseline o Missed | = nl 4 "08 b: A 63P.F05U1N9A.01 0a Baseline Missed | 56153C0-2P7F0U0RA0a Baseliie Missed | 99.P0F/8D0S.01 0a c Baseline Missed| 50133.0C/-8P0F.G0S.Da Baseline o Missed Vicon Peak ona pen Hh apes 613.0P/F5D6O9A.01 Da 615103/C-1P6F9D000Aa cBaseline c Missed | oBaselinec Missed | 663P0E6T1A901 0a 61135C0-/P1FD6O09A0a Baseline c Missed | Baseline - Missed 713.P0F1T86e9A.100a 611530C/-1P6F9D0OA0a | Baseline Missed | Baseline Missed 0 Before O After 69 Page 68 of 242 [4 lumbia Analytical Services" PrCinrteead:ted14w1i0t2h1A2n0a10ly6t:4p1o.0r0tPeMr Cow |: lon Ratio Confirmation I : K1000911-005 A itn| a de 4130P/F3O6A9200a 463P0F2N1A920 Da 499P.0F/O99S.20 Da 513P.0F2D62A90Da BaseWliionnegcPMeiasksed | BaseWlrionnegoPMeiasksed | BaseWliionnegcPMeiasksed | c BasWelrionnegoPMeiasksed methooone| 563P,F01U2N6A902 Da BasWerlionneg0PMeiasksed | ApA \ 713p0r/r1a6n902 0a BasWerlionneg.PMeissksed : Ltt| 599P.0F1O99S.20 Da BasWelrionnegcPMeaiks.sed | | oe erie| hesdin 513P0F/1O6A902 Da 663.P0E/1T6I9.2A0 Da oBasWerloinngecPMeiasksed | BaseWlrionneg PMeiasksed 0 Before 0 After Page 69 01 262 70 5 lumi Analytical Services: Created wih Analyps.t6R0eparter Printed: 150212010 2 34.60 PA PDraotjaecFtile E02v0a8n1s0:PSarmpolcesPShFaCrSt wif InRsesturlutmTeanbtleName __ A0P2I08510000Samplesshortedciot [SampleName Kico6517-008 2/0/2010 7:24:50 AM [niectonvier JoPsFCiinetexShdoarrt Sample Type | wWeighitovoume[000] Results Summary Analyte Peak | swame [sae | AAnaTlyetRe TRT| anaie aren PFBA1 | 13CPFBA | 5145200 | 128127)| 127840 Caalic.. CCoonnc. 018 Moditea? | No | PFPeA 1 | tac-prrxa| e0s0s00 3.60 (3.60) 271900 045 No | [[eCraosl [PHrAasT |T180-O PFHS||M T320m 5000 |s42m6(6e26)| 196680 | tacprha || cocoso0 | satan| 2ssee0 -- 01s SNo e 0> 39 No | [prripas | ceria | sososoo |s20629| [rrro|re|smows Tamem| 712s | 02s | No mew || om we] [[TsRsoOpTris || BaOcTeHon || ddsesems00|[e6R3e3631| 3305000 081 No*| (S-BSCFDA_1C-PFOA || W1O3PCPPFODAA || do48s5e8s500 ||T7e6770(7e6n5|)| d4e65s85e0o0 || 11000 N o] $2e = =tio Pa65gof2e65 n 3 olumbia Co Analytical Services PrCinrteead:ted15w/i0t2h/A20n1a0l2y:3R4e:p0o0rPteMr RCSummary rrr Pronz fone [eros2 at| en mum te|S |g No | ao | ves | wo | owom | ves | [prez | PFHxA2 Pripa2 |'s_13c-pFBA [emem| mmo |w |omowm | mom| mem 5315.31) 27335 No | to 0.10(0.10) | 121028 5145200 No 40.31(13.55) YES we | No 5=_.13C-PFHAA 531(530) 6060500 No 21.22(13.08) No 7 ASnoalluymtibciaal Services `Quantitative Peak Review [ Ee 1 ro | [I Created with Analyps.t6R2eporter Printed: 15/0212010 2:34:00 PM K1000811-005 | I oT 213.0P/F1B6A9.100a 271031C-7P2F0BA02 i| 263P0F2P1A90108 Baseline _ Missed | Baseline Missed | Baseline. Missed | 31135C0-P2F7HX0A0a Baseline . Missed Pras 299.0/80.0 Da wos 4030/1030 0a | pew 313012690 Da 13cpitin 31502700 Da c BwasoelninegPeMaissed | WoBaseeliy e Missed | oBaseglinegc Missed | aBanseligne .eMissed . ~[ 363P,0F/H1p69A.01 Da BaSsoeluiannegc 2Maissed - i CL 13135C0-2P7F0H0XA0a | i.Baselinewgu :Missed | " A]: or] 39P9.E0H/I8S0100a u Basen liney u Missed 4013800/-1P0F3H0S0a a Baseline c Missed - ~ I = ~ Be -- | -- IL 1 -- 4S0_3108/01-0P3F0H0Sa 51135C0-4P7F0O0A0a Baseline Missed | cBaselnec Missed | 5S1_51034C7.0P0FD0Aa Baseline Missed | | er] 511530C4-7P0F0OADa Baselinec Miseeo 0 Before O After Page 67 of 245 7 Columbia LS Sotservices: PrCinrteead:ted15w1i0t2h1A2n0a1l0yl2i:3B4b:p0o0rPteMr Ton Ratio Confirmation = Tw EE |- EEll | "pa 5 K1000911-008 p a - EE Elp: J st _ 2130P/F1E6A920 0a 263P0E2P1E9R0202 269.P0F1E99S.20 Da _ BasWelrionnegoPMeiasksed | BasWerlionnegcPMeiasksed | BaseWlrionnegoPMeiasksed | Tn aeo p d=] iEH : r 4 a i -- fy | 313P0H/1A1820Da BasWerlionneg:PMeiasksed - Tinpertasit 363P0E1H3G19A02 Da 30P9.F0H9Y9S02Da 55115304C7F0F0DDAa _ BasWerlionneg PMeiasksed | BasWerlionnegoPMeiasksed | BaseWlrionnegoPMeiasksed | NB PFBA and PFPeA do nol have qualifying on ramsitons. 0 Before[J After NA BaseWlrionnego PMeiasksed Page 68 of 245 p 6 Aonlaulymtbiciaal Services: PriCnrteead:ted14w/i0h21A2n0a1l0 6:4R1e:p0o0rPteMr PDraotjaecFtile Result Table Instrument Name E02v0a8n1s00P\rSojaemcptisePsFLConsg vi AGP2I0851000S0amplesLong [SampleName--TKic2o8o2e01170-90301850 Pl [inSfaemcptiloen TVyopreume |[5Unknown Lo`Accqtuiosintvioan rMe_thodT|4P6FC-- linsi-- extdoanmg----|vioighitovawume 700 [000 `Results Summary 3 Analy pek oname [isan | AAnTaiEsRRTTT anatearea | GCoaciGSeo |p- oMondneea? r|| [proat 1CPFOA | 0sa00 |135139)| 220 | 19s0 No P | PENA ee 13C-PFNA | 2154900 | 232 (2.42) 89642 0.387 +H No PFOS 1 =X 13C-PFOS| 4825800 | 2.33 (2.53) | 13CPFDA | 2224100 | 000(334) | PFUnA 1 [acer| see | aren| Prost |worros | smo |omeio | | PFooA1 13C-PFDOA| 110730 | 0.00(463) e [pFTia er 13CPFDOA| 110730 | 0.00(5.14) [PrTeat ncero| tome [0670| o22080 | 1810 | wa gaard hi pot? 7) A NA NA | 0 | wa No. no | No | wo No | N~ e ~ No | tlA [asd Luli Page 70 01 242 7s CoS a rns on n65i IRC Summary oo [ nwaoenrtesuanee[m [wmrioeoe mnw||[ansmseomeewn [weston| | wo | aGmReImN||Aotvegom|:| | ve [omn| [Feomewremn [aewvaam||w wows |w |wweo|[ommomo||wv=w n|| [[roomren mvaamm|| wm |wo| wom| wom |wo | mm | vw | | [fsomorrrmon: [foroom [s=mmrron pra Prien: ram | mw |e[www| = T[oamwawmm|| 5 wow ||wwoo |m[oowemm || w| Tcarmaanm| mn we | | | we | oowweemm | | [emmwean|| om|| ewe [ewe |e~ | [sem| wr |wo[owe | wo] nee 8 olmbia AnalyticalServices Quantitative Peak Review TE 3 rd I Created wih Analyps.t68Reporter Printed: 14/02/2010 6:41.00 PM "K1000911-006 - 75 A : A EY 413.P0F/1O6A9.01 0a 41137C0-3P7F2O0A0a 463P0E4N19A.100a Baseline CMssed | Baseline. Missed | Baseline Missed | i 4681.30C14-2P3F.N0A0a Baseline c Missed 33 A |i A >5 4 Mii : _- 489P.R0O5S010 Da 50133.0C/-8P0F.0OSDa oBaseline Missed | Baseline o Missed | 513.0P/F46D9.A0 1 0a Baseline: Missed | 511530C1-4P70F0DADa Baseline 0 Missed - tf A| 563P.E05U1N9A.01 Da Baseline Missed | 51635C0-1P2F70U0nADa Baseline Missed | 599P.0F/D8S001 Da Baseline Missed | 50133.0C/-3P0.F0OSDa Baseline . Missed = =0 3" LE= 613.P0/F5O69A.01Da cBasoline Missed | 6151.30C/-1P6F.D0O0Aa Baseline c Missed | 663P06E1T9A.100a uBaselnec Missed | 61135C0-1P1FD6O80A0a Baseline c Missed Z7 = | 713P.0F/T6e69A.01 Da Baseline _ Missed| 611530C/-1P6F9D0oADa Baseline Missed 0 Before OJ After Page 72.01 242 " Pa Columbia Analytical Services" PrCinrteead:ted14w/i0t2h/A2n0a1l0f6s:i4H1e.p0o0rtPeMr Ti = lon Ratio Confirmation - = = K1000911-006 | f | & E = S TL E |] Aee = i| "benef _B4a1so3Pi0Fn3Oe8A0_.2M0i0ns8ed | B4a6se2Pl0iFn2Ne1Ao92M0i0s8sed| B4a0se8Pi0Fn9Oe8Sc.20M0is8sed | Ba5s1e2l.Pi0nF2e6D9.2A0Mi0sased Wiong Peak Wong Pea = Wrong Peak Wrong Peak -Lotion| 5Lu | :unit | Elttl _ B5a6s2Pti0Fn2Ug6R9oAv02in0saed | oBa5s9e9Pi0Fn1eD9S0M2.i0s0s8ed| B6a1se3Pl0Fi1nDe6O9A02Mi0sased | o B66a3sP.e0E1lT6cI92.AM0i0s8sed Wrong Peak Wrong Peak Wiong Peak Wrong Peak netpidled oR fd B7as1eP3lFi0nTe1EcA62W90s0s0ed Wiong Peak 0 Before O After page 73 of 242 n 4AnSaollyutmibciaalServicesTM Created with Analyps.t6R8eporter Printed: 15/0212010'2:34:00 PM PDartoajeFcitle Ears ProRCEPRCS 020810Sampiesshowrit InRessturlutmTeanbtlNeame __A0P2I0851000S0ampiesshortedt db [SampleName [Ki2c19o7o2o01107-70:0348:22 AM I Sample Type | Unknown Acquisition Method| PFCkinetexShaormt [ojecat6 onviat|Weightto Votume 700 [000 Results Summary re Analyte Peak PFoA 1 = shame - | Ssan | AnAalEySteT]RT anaes | Calnce.iCcoenc. odined? ] | nacerea [asmoo [12802n| zero | ose | ne | 19CPRHA| 5302300 | 36080)| 813450 Tw | we PFBS 1 | 180-PFHS | 3133500 |426426) | 541850 ost | No PFHXA 1 _-- | 13cPrHiA | 5302300 | 531531)| es19s0 146 yy No | [prripa 1 racer | sooo [62362| eez0 | C ossL| Cne { |([PsrPiHsxIsoeS1r1ns ||| 1wM8o0eOprroPnnsS||| Ss3s1se3s3ao50om0 | s632w632e)|| te87900 smo | 1 om | soceron | moeron | mee | easy| www | wm | wNoo|| we | BAlwe rs 2157 Pa69ogf2e45 79 4 Solum Analytical Services" IRC Summary Created with Anal. 5R9eporter Printed: 150212010 2:34:00 PM - Prea2 Prpeaz [(prras2es | pera2 |PTFHapAe2 5_13C-PFBA S_13CPFHA [msazn |au |n we| tooaon ves 360060) | 813450 No | 100(100) ves | ase [ 2020 | no 0370.40) ves sss|mes | Nt e| omen) ves ocar@e2w2|| smeasseo ||Nweo|| ao0ms@oomy | ves 126 (1.26) No | 147301355) ves 531530) | 5302300 No | asso | te | Page 70 of 245 8 7 SAnoalluymtibciaal Services Quantitative Peak Review [-- 1 1 Tw Created with Analfi7l 0Reporter Printed: 15/0212010 2:34:00 PM - K1000911-006 [oT 213.P0r/1o6i9.T0 0a 21173001.76728008 263P0r2P1o9A0s0a 31153001Pr2H7Da0a0 "Baseline Missed | Baseline - Missed | Baseline Missed | c Baseline Missed 299.P01E80B.S0 1 Da (Baseline Missed | 41083001-1P0F3H0SDa | Baselnec Missed | 313P0F2H5XA001 0a cBasoinecMssed | 311530C1-2P7F0H0XA0a Baselineo Missed 363P0F/1H6p9A.01 Da 31135C0-2P7FH0R0A0a Baseline. Missed | oBaseline. Missed | 309P.E/H8X0.S010a Baseline c Missed | 4013800/-1P0F3H0SDa cBasoline - Missed 46S3_.1018100-3P.F00HaS UBaseiine c Missed | 5151.30C4-7P0F.OA0a Baseline Missed | 51S5_0143C7.0P0FDDAa Baseline. Missed | 51135C0-4PF7O0A0a Baseline. Missed 0 Before 0 After Page 71 of 245 a1 8 ASnoallytuicmal ServicesTM PrCinrteead:ted15w/i0t2h/A20n10a2t34H.ep0o0rPteMr lon Ratio Confirmation K1000911-006 | Ei | aq 2 i - - 1 bs 2 i 4 The A 213.0P1F6E9A.200a _ Baseline . Missed | 263P0r2P1e8A0208 Baseline c Missed | 2090P/R9B9S.020a Baseline o Missed | 313P0FH1G1A90202 Baseline u Missed Wrong Peak Wrong Peak Wong Peak Wong Peak = 525 = | = ~ dum I} | Tt suse 363P.F03H1p9A.020a _Baseline Missed | 399P.0F1H99I.S02Da Baselinec Missed | 5S1_513.C0.4P7FD0DA0a Baseline Misseg | NA Baseline Missed Wrong Peak Wrong Peak Wrong Peak Wrong Peak NG PFBA and PFPEA Go nol ave qualiing on ransiions. 0 Before 0After Page 72.01 245 8 4 olumbia Analytical Services Creat with Analpy72Roporer Printed: 1410212010 6.41.00 PI PDraataeFtle Result Table aE zos1onSE amplesLiong Gaosiosamplestong Instrument Name API $000 [S[amApclqeuNiasmbieatt--ieTow|nio200G20@1T005037.24 PF [ecAtcqiuiosintiVoinaWethad147 STrajmepclteonTVyopleume [5] | WoighttoVolumeTom [rox worn | wm | vs] men | ton || Results Summary nays Analyte Peak hme T| sas | AR Analyte RT | praemes | SIS Calc.Conc | Wioodgrneinerds | opp T fe] [PPPrTFoNsAt1 13C-PFNA 130PFOs | 2455900 S070 | | 22.0217 @(e25.a342))||| t9o3d6s2260[O|| 801.307507 Nwoo ||| fm worron | zm owen| 0 | wa | p[rr ns | coro| wise | so1 on| sore oor we | o--lt [[Fpprrromsot | 1ceros | somo sceroon| mea ||2aoowoaA wieon, || 50T|e awa T | wo Neoo | -- [orras --1ocProon| 1s | o--wen| 0 A a ---- | -- Teron 1aceroon| 11230 | oooh| 0 Aa ~-- df ec Spiele? Page 7401262 o 8 Slumbia Co Analytical Services* RCSwmmary Printed: 14102120106:41.00 PM croron foruae sam| swam | wa | wwe| we [ewe | wma | wo| omom [ w [sero amam| worm |w [ammo| ow s[.p1r3u0nnPzron Tomcerm swam| 0 | we | owom|e- |1 |amam| emi |we| seam| to [pros2 | 4104.10) 628 No 000(032) | The |FPFDeoA r2 man|Ta47m44a88s)||vmom | wNs oo. |o 0.00 (0w .29) |oN=om [pron sme | wm | we| owom| o 3 Golumbia Analytical Services Quantitative Peak Review 2I =7 Created with Anal7Reporter Printed: 14/02/2010 6:41:00 PM ~ Ktooosi1-007 CRT z 413P0/F1O6A901 0a cBaseline c Missed | 41137C0-5P7F2O0A00 Baseline u Missed | 463P0E4N1A901 Da Baseline. Missed | 461830C4-2P3F0NA0a c Baseline . Missec ugg pea ugg es " a : igen Coke To | 498P.F0O8S001 0a 50133C0-/P8F0O0S0 c Baseline Missed| oBaselie Missed | 513,P0F4D69A.01 Da Baseline c Missed | 5151.30C4-7P0F.0OADa Baselinec Missed - 5 = I 0 - | ; 563P,0F/U5N19A.01 0a UBaseline u Missed | 51635C.-0P2F70U0RADa Baseline 0 Missed 599P.0F1D80S.01 Da |. Baseline Missed | 50133.0C/-8P0F.0OSDa Baseline - Missed - 2 3 , bogeys nb A) beta yA 613P0/F5D69A.01 Da Baseline Missed | 511530C/-1P69F.D00A0a uBaselnec Missed | 663.P0F6T5G19A.01 0a Baseline: Missed | 61153.0C/-1P6F9.D0OADa Baseline c Missed 7130PF6T6e9A01 0a 61153C0-/P1F6D9O.DA0a Baselinec Missed | Baselinec Missed 0 Before O After 8 Page 76 of 262 4 lamba AnalyticalServicesTM PrCinrteead:ted14w0it2h12A0n1a0l6y.t4H1s.p0o0rPteMr fon Ratio Confirmation = = 2 | Jed += TN FE 3 K1000811-007 So = El _ mn 413.0P3F6O0A.20 0a BaseclMiisnseed | 4630P2E1N9A20 0a Baseline oMssed | 499.P0F/9O9.S02Da Baseline Missed | 513P0F2O62A9D0a BaseloiMinsseed Wrong Peak WrongPeak WrongPeak WongPeak - = - |= Lobos | se| stone| gine 563,0P1F2U6R0A.02 Da Baseline o Missed | 5P09F.0D/9S9.20 Da Baseline Missed | 6130P/F1O6G9A020a oBaselinec Missed | B6a6se3Pl.iE0nT/e1Ic6AM9iD.sa0sed Wiong Peak Wrong Peak = Wrong Peak Wong Peak byeohih 71P3F0T1eA62900a BaWseolinnegPMeiasksed 0 Before OAfter Page 77 of 262 8 4 Slams Analytical Services Created with Analfsi78Reporter Printed: 1502/2010 2:34:00PAA Project Evans ProcPECs DReastualFtilTeable 0G2200881100S1aSmapmlpelsesshSohrotretdwiitfab instrument Name __API 5000 [SamusName Tio00077607 2/0/2010 7:43.55 AM EE -- o0w ResultsSummary "AnnaaiisPeak shame |Tesmaea || AS AnTWeSRRTT | napee area | CatCalee.CCoonne Woditear =| [on -- = | PFBA1 | 13c-PrBA | so0s700 | 126(1.27)| 344000 | 058 | No | [prrent [eras | 13cPFHxA| 5090800 | 359360) | 039100 162 [reopens| sso | szsezm| ssw | ost No | No | PRHXA 1 | 13cPrHxa| seses00 | 530(s31|) sessa0 | 14s No | [promt rota|sn [az 0m | oa os w prs 1 Tepes| 20as0| 632632) | 2035000 one [stores | raceron | sma | estean| sams I) | [S-_119SCCPPFFDAOA||1 13CPC FDA|P | 445577T 2200000 D ||T7e6s5A (e1e6m5)|| 4T572a00w0 |t1w.00 | M || il 0 C 2 1n Page73 of 245 7 Lome PC redr1i50e h27A2n0aa102t 3R4ep3o0ertPeMr Ee RCSammary wrens [owas| woo | we | tone | ves | rrisz [prrpaz [prs s_aceren [enermos 622022 | es0m0 | No | 2930303 ves [swem| mm | wo | omem| ve | mom| seem | No | soos | ves | |sme | mmm |vo|emosm| ow | Pa74g012e45 4 lamba Analytical Services Quantitative Peak Review --I :I Created vith Anahi7R8eporter Printed: 15/022010.2:34:00 PM - K1000911-007 oo 0 Ts| p 213P0F1B6A91008 21137C0-1P7F2B0A08 263P0E2P1e9A01 0a 311530C1-2P7F0H0XA0a --_BaselineT c Missed | :BaselT ine Missed || BaselineT c Missed | .Baselineo22Maissed | pmsi 10s peri scotia UBa2s0c9l0in/o800M0isased | Ba4s0e3l.i0/n1e0s3.M0iDsased | Ba3s1el3i0n2e69M0is0saed | B3a1s5el0i1n2e7:00Mi0sased 363P,0F/H1p69A.01 0a 31153C0-2P7F0H0XADa 396P.0H/S200|Da 4013800/-10P3F0HSDa Baseline Missed | Baseline Missed | Baseline. Missed | Baselinec Missed 4S0_31.80010-3P.F0H0Sa 511530C4-7P0F0OADa 5S7_51034C7-0P0FD0Aa 511530C4.7P0F0DA0a Baseline oMissed | Baseline Missed | Baseline.Missed | Baseline Missed 0 Before O After Page75 of 245 8 AColumbia Analytical Services Created with Analy79Reporter Printed: 15/02/2010 2:34:00 PM lon Ratio Confirmation = 7% [3" :1 go ; K1000911-007 T 2 =i : si 21P3F01B6A920 0a "Baseline Missed | 263P0F2P1e9A02 0a Baseline: Missed | 209.P0/R99E.S02 Da 313P0H11A80208 Baseline Missed | u Baselineo Missed Wrong Peak Wrong Peak Wrong Peak Wrong Peak . oz =od . Geese | I Depa 363P0F1H3O1A902 Da 309P.0/H99S.0 2Da 5S1_5130C4P7F0DDA0a Baseline c Missed | Baseline c Missed | Baseline Missed | NB PFBWAraonndg PPeFaPkA do nol Wrong Peak have qualifying on ransiions Wrong Peak O Before O After NA Baselineo Missed Wrong Peak Page 76 of 245 0 40 CAonlaulymtbiicaal Services Created win Anal5y.8R0eporter Printed: 14/02/20106:41:00 PM Frage Data File InRessturlutmTeanbtlNeame PEa1r5s00PrRCIPRC 002200881100Sba\mSpalmepslLeosnLgo.nrgdwbif LSampile Naeme c{atK81000o611-0n08 vir[j|ewScatomipilomenoTVyvopleoummee[ |[0U0i00fown5]| TE| me Results Summary "Analyte Peak |a| EE | Analyte RT [pront 1aCrFOR | wsa00 | 138130)| [prvi | cern | zm Joma| Pros Tscpros | swiss |2ss@sy| Pe ronl1 LRTacrron| 2wee0 || owoan| [prim [acrruna| ros | e110)| [pros [Taceros| seo |owowrw| er | SS Calc. Conc | wearer - em | ozss wo 0 | wa | wm 1st oa No 0 | wa weerNomed 3500 sheto ozs 40 No | 0 | wa No _] [| PbFrDaOs1A Pron 1 | r13sCc-ePFrDoOmA| 93855 swss crros| ows ome| 0.00 (4.63) | |ooeTa| 0 | 0| NA No wa - wa |me A4o ent Laut? Page8 01202 a 4 obi Services Created wih AnalRonee Printed: 14/02/2010 6:41:00 PM Resummay ren Fo [cpruoonrron [ rmaosasn |s|m we | seam | prne [jporopsermm Ts ncrros Jemaw [| en |w [omem| we | [ammaaws|| mwow || vnw |[ommoemn||ewe | seo | no | wma| no [pronz o No | 000015 | mn | [| S ProCm RA [omoron [orosz [prounz [o33w13e34m)| o2106600 [arom| om saw| ws | reso | re woONo 0.00 (22.10) we | wom Nwo o| = | w| ~ [5.150670 Fa] To mem Prinz [omen| wn |w |owes|w | {pren2 [s|mwoo[| wm| owem | w | 3 Anoallyutmibcaal Services Quantitative PeakReview = == PrCinrteeadt:ed14w0it2h12A0n1a0h6i:4B1e:p0o0rtPeMr K1000911-008 -- Er ai = A "| A 413.P0F/1O6A0.01 0a 41173.C05P7F2O0A00 463.P0E4N19A.01 0a 4661.30C/-42P3F.N0DA a cBasclive Missed | Baseline c Missed | Baseline: Missed | c Baseine o Missed A ee] A i, Jail Sc Re Be 498P.F0O6S001 Da 5031.30C/-80P.F0O0Sa 5130P4F6D9A01 Da 51135C0-4PF7O0AD0a CBaseline c Missed | Baseline: Missed | Baseline Missed | c Baseine o Missed : SLata~ == ar F=E )= FRea 563P0F/5U1N9A.01 Da 56153,C0-1P2F70U0RADa 509P.F0/D8S001 a 50133,0C/-8P0F.0OSDa Baseline o Missed | Baseline oMissed | Baseline Missed | Baseline . Missed 613P0F/O5O6A9.10 Da 6151.30/C1-6P9F.D0oA0a 663.P0E/6T1A9.01 0a 611530C/-1P6F9D0OADa cBaselinec Miassed | -Baseline c[Missed | BaselMiinaen. MiPseaksed | Baselpiinceau Missed 713.0P1F6T6E9A.10 Da 61153.C0-/P1F6D090A.0a Baseline - Missed | Baselinec Missed O Before OJ After 2 Page 60 of 242 LSC0 oluma bia services: PrCinrteead:ted14wi1t0h2A2n0a1R0e4p1o6r0tPeMr lonRatioConfirmation (f 2g f 7] 2d Le K1oo0e11-008 =n - Ba1sPe2l0Fi3nOe6A92.M0i0sased | G4a6s3eP0iFn2Ne1Ao520Mi0s0sed | Bas5eP9lFi0nO5eS9s20M0isased | B5as1ePl3iF0nDe2A82M0i0s0ased "Wong Peak = Wong Pea Wong Peak rong Peak 3: i i:} |il 33 EMIRSTEdLie tTtli,|i.|Thorittytiet|i|cihsi B5a6se3Pl0Fin2Ue8R0A0M2i0s0sed | oBa5s0e3Pi0nR/eO88S.?0Mi0sased | o B6a1seP3lFi0nD1eO8Ao0M20is0sed | o B6a6s3eP0li1Fn6Te0I.2AMi0sased Wong Peak Wong Peak Wiong Peak rong Peak Alo leld G7a1ssP3iF0nTg/e1-A62Mi90s0ased WiongPeak O Before 0 After Pag8e1 or 262 0 3 SAnoalluymtibciaal ServicesTM PriCnrteead:ted15w0it2h1A20n1a0l2by3.48R:esp0o0rtPeMr PDraotjaecFtile Result Table 0E022v0a08n81'10s0SSPaarmmoppjileecessssPShohFroCtrsetdiw.ifrab Instrument Name__API 5000 [S``aAAccmqqpuuiilsseiittNiiooannmDMeaettehod||K2Pi/Fo0C/02k60io1n707e7-l:05e30x.82S7hdAoarMmt [miectionVial [4s ISnjaemcptlieonTVyopleume || Unkaown [ifutionFactor | 1.00 |WeighttoVolume| 0.00 | sen| we [| sree| ity [wea RneastueltPesakSummary Anate RT |pr PFBA1 | 1acerea | snesad0 | 126012n| esore Gile Cone oor | me] | prea t [ems | 1136C0-1PP80RR-HpHrxSA||3s41t78000|3|4352s60(0a62s060u))|l||e570r5e5t0 a0m17 | Noa 006 I Noo P--HA--1 PEHDA 1 | 1acprrea| sa-- t7e0 | s31(s3n| 2230 -- | 018 | No | | 13C-PFHIA | 5417800 | 623623)| 25656 0.06 RY No | [[[bsplsaronspdI rrs.||to1p3creFnOsA|| somo 4525200 | | e523| 632631 | sae 103500 I) 078 No> Nn | |sacproa | 1acproa | 4sasa0 | 7es es) | 4sasa00 100 No ABuull =Sreste Pa7 gof2e45 9 0 SolymblSaervices: retin profsBRore Printed: 15/02/2010 2:34:00 PM Woswmmary Caeretone | WERT)| ven |varus| Cong| mmr| [roe [wom | eon | ve | wam | ve | enor own| ve | [ross amen| wen es [ores swam| ww | | Fora mom| worm | wo | swam | we 20 [pres [oom|woe|w |omew | ves socom [imam| we |ow [mes| we | a sowm| w " Page2t Columbia LO SE servicer Quantitative Peak Review |-- 7 7% - of A Ba2s1e3l0Pi/Fn1B6eA9;.10Mi0sased | Ba2s1e1l73i0Cn1-e7P:F2B0MAi0s8sed | PrCirneteadted15v/i0t2h/A2n0a1l0ys2p!:.38R46e:p0o0rPteMr i- K1000911-008 " 5% aod | Ba2s6el3Pi0FnP2ee1Ac910Mi0s2sed | Ba3se11l53i0Cn-2eP7Fu0H0MXiA0sasec : Bas2e96l.Pi0Fn/Be3S0c.10MDisased | a = = | | 3" Ba4s10e83l00i-1n0Pe3F:.HM0Si0sased | Ba3s1e3lP.iF0Hn2Ie6Ac810Mi0sased | =% | % - | Ba3s1e153lC0i-n2Pe7F.0H0MXiADsased 7% | 363P.0R/H1P69A.01 0a Baseline Missed a |- 31153C0-2P7F0H0XA0a | 399P.R0H/X8S001Da Baseline c Missed | Baseline c Missed 3 4013800/-1P0F3H0S0a Baseline Missed. 0 2 bo = e 3 b = b [= bp i + bg 4S03_.t0/8100-3.p0H0Sa Baseline c Missed | Ba5s1eW5l0iO4nP7e0F=.O0MAi0sased | | 551510a4c7E0R0ODAa Baseline Missed | Ba5s1e15l30iCn4Pe7F:0O0MAiDsased 0 Before O After Page 79 of 245 o7 4 Aonlaalymtbiciaal Services- PrCinrteead:ted15w0it2h12A0na1f0f2s:P3R4e.p0o0rPteMr lon Ratio Confirmation K1000911-008 T: = 2 =7 -| | Sam i. = Lo Poe LE he| ee NES ERRE 2130P1F6B9A20 Da 2630P/E2P1e9A02 0a 20P9.F0/E99S.02 Da Ba_seWloinngePMeiasksed | BaseWliionneg PMeiasksed | BaseWrloinngcePMeiasksed | Ga 1S = -- ; Soo spo fo | 313P.F0H/1A1290.a0 Ba<seWlrioneng PMeiasksed Temps AE . me 363P0F1H3p1A902 Da 399H.09A0.S0 02a 5S1_51034C7.0P0FDDAa NA Baselines Missed | Baseline oMissed | Baseline Missed | BaselMiisnseed Wrong Peak Wrong Peak Wrong Peak Wrong Peak NB PFBA and PFPeA do not ave qualiying on iransiions. 0 Before OAfter Page80 of 245 9 8AnSaloyltiucamlServices PriGnrteead:ted14i/t0h21A2n0a1l0ys6pt:.48R18e:p0o0rtPeAr PrDoajtaecFtile Result Table 00Ew22a00r88t11s00PbSr1aoSmjapemlcptelssePLsoFLnCognsgrawdif Instrument Name AP 5000 [SampleName [K20i10 o9SoHTO0PH9700 [nection Volume G[5 on `Acquisition ethod|PFCinetexLodanrg injection Vial [46 |WeighttoVolumeJo7o00o Results Summary fAinavleyte Peak shame | isares | AnAaBlWyEtReTTRY naeaea | GaGleooGonne PFOA 1 | PFNA 1 | PFOS 1 [proA1 [runa 1 [pros [Fro |2 PPrErTeAaLt | 13cpron | 13C-PFOS| 13CPFDA | [tocpruma | 1cPros| 19CPFDOA| 13CPFDOA| serio [rasa| 2577600 |236242)| 6111900 | 2.32(253) 228400 | 320334)| ties | arian| 6111900 | 411610)| 148850 | 476(463)| 148650 | 52e7(5w18,)| 14g650 | 000574) sesiz | 49385 woloie 178340 | 11853 reer | 1a620 14918 5=320 oa pas JD | 0288 | 001 | ome | oor | 010 | 0065 | NA | Modif-- ied? No | No No | No no te | no | no | no | XN eSrueelo Page 82of 262 9 8 Solumble,Services CrweithAanatt eRepodrter Printed: 14/02/20106:41:00 PM ra RCSummary [roz sucrron [[psraer vros2 5 orr0s tans| wsmo [wo[m|eww e | [maw| we | we |wwe |e | [e[meosmoa[| emrne[|wewe [soem m || e e wvse m n|| Gates| sme | Ne | owes| ves 2s wl [rsosrc2eron ooeare[ t --0--| we [ew|ewer| [orumz coum| ew | we | omom| ves Sacer vo | swam | irre Cenwo| son | we |emom| ww | [proonz [esas | sw | we wl seroamas| a|wwe wo ] raz| sme|w|w we| omos faa S740 EEAR Page tor22 0 7AnSaollyutmibciaalServices Quantitative Peak Review T T PriCnrteead:ted14w/it0h2A/2n0a1i0s6:B4e1:p0o0rPteMr Ki000911.009 Er . >1 | _ BY236 FoLom 413P0F/1O6A901 Da Baseline c Missed | 41137C.-0P37F2O0A0a Baseline Missed | 463.P01E4N1A9.01 0a c Baseline Missed | 4681.30C4-23P.FNADa c Baseline Missed -A "] A g CeAm | 499P.F0O60S01 0a 50133.C0-8P0F0O0Sa oBascline Missed | Baseline: Missed | 513P0F4O6A901 Da 51135C0-4PF7O0AD0a Baseline Missed | Baseline u Missed 'L 563.P0F/U51R9A.010a bscBaselBine Miissed | ol 56153,C0-1P27F0U0RADa Baselionae.PeMaisssed | -1 599.P0F1O80S.01 0a .BaseowlinecIMissed | Lh 50133.C0-/P8FO0DS.a0 B_aseline 22Maisses 613P0F/D5O6A901 Da _Baseine Missed | 611530C/-1P69F.D00ADa cBaselinecMissed | 663.0P1ET5I1A6.10Da Baseline Missed | 61153.C0-/P1F6DO9DA.a0 BaseloiMinsseed 713.P0E/T6e6A9.10 0a Baseline Missed | 61153.C0-/P1F6DO90A.a0 Baseline c. Missed 0 Before 0 After 101 Page 84 of 242 4AnSalluytmibciaalServices" 91 Created with Analysi Reporter Printed: 14/02/20106:41:00 PM Foe fd, af of NL | : == lon Ratio Confirmation LZTAR =z K1000811-008 |e _4B1a2sa0Pi3Fn6OeA9M20i0ss8ed Wrong Peak Be| TL| hed lai |< B4a5se3Pl0iFn2Ne1A520Mi0s8sed | = B4as9eP9liF0nO5eS920M0i2ssed | ca5s1eP3iFn0D2o2AM0i0s0ased Wrong Peak Wrong Peak Wrong Peak 3 3 To Fo Ldn| TL | = ah FE as HE heen| Sly _B5a6s3Pl0Fi2Un6Do9oA0M20ssaed | Bas5e6l9Pi0Fn1eD9S820M0is3sed | Ba6s1el3Pi0Fn1De6O9oA02M0isased | B6a6s2eP0li/En1Te6I82A0Mi0s8sed =Wiong Peak Wiong Peak Wong Peak = Wrong Peak ]L 71P3E0T/e1R626008 BaWsaainnegPMeiasksed 0 Before OI After Page 85of 262 102 3 Goumie AnalyticalServicesTM Greated with Analypst.5R2eporter Printed: 15102120102:34:00PM Project Data File Result Table Instrument Name Evan's ProjectsPFCs 020810SamplesShort wif 020810SamplesShartedit db API 5000 [SampleName |K1000511-008 jection Volume | 5 `PFGhinetexShor dam Dilution Factor | G100io Injection Vial [45 |WeighttoVolume [000 | Results Summary "AnAarlayitePeak [oname [isan R[eASaERTRT|| == I 13CPFBA | 5070300 | 127(12D)| TacPRiA | seo | soso| pPFLEST |prrea 1 | m 100PFn HS| e335e6000 | 4244h2i6)d | | 19CPRHiA| ssee00 |s30(s3n) | [PPFTHrPoAh11 | PRHXS 1 |1| 1C 3C-PFP HAA|R | S5e8R 0s44n00A|| 6.6222(6.23) | 180PFHS | 3356000 | 631637)| |se0prrs | 1aceron | 421130| 63163n| [|oS1_1o3rCrPFoDRA ||v1e3CPRFDA | 4211300 | 765(765) || - anaan enes | GaGleeGoone| woaioteaarr] 4081 | 008 No ome | 01s | he 53329 om 0s |fwto 120520 | 014 | No 20132 381920 saseoon 0.07 LM1No 031 No | 00 | Ne 42n11e30m0 | W1.e00 No fue r= So 205 Page 81of 245 103 [amin nalyticalServices CPrrinatetd:e15w1i0t2h1A20n1a0i2s34R.e0po0rtPeMr RCSummary AnalytePeak Name. Preaz [prronz [pres fPrrroAmze I's rac.prria RTERRT)| Area Ratio Confirms [arazn | est | Mo |tooo| ves | [ssaen| wma | mo |tno| ves | [42 | 6 rom0|2w0 o| oatosn es | swan | 1122 No | oomoio)| ves Lemon|wn | we || mao |wo | 5305.3|0 seaes00 Lm No | Pa82gof2e45 108 8 ASnoallaymtibciaal Services- Quantitative Peak Review Tim Co - ro PriCnrteead:ted15v/i0t2h1A2n01a0fi2H3e4p0o0rtPeMr K1000911-009 oT % i} . 2130P1F6B9A.01 0a BaselwineIc Missed : te 1 21137C0-1P7F2B0A08 | -Baseline[- Missed | a [7] A 263PE0P2e1A01008 -Baseline[Missed | ls -- 311530C-2P7F0H0XA0a BaseBliine: Missed 269P0F8B0S01 0a Baseline u Missed 4108300-1P0F3H0S08 | 313P0RH2X6A9010a Baseline c Missed | Baseline Missed 311530C1-2P7F0H0XADa Baseline Missed. 1. |C nl e ah 1 ]| 1| 363P,0F/H1p69A.01 0a "Baseline: Missed | 31135C0-2PF7H0I0A02 Baseline Missed || 30P0E%H8X0S01Da Baseline Missed | 4031.6001-0P3F.H0S0a Baseline. Missed SE Le 4S0_3,108101-0P3.F0HSD.a Baseline o Missed | 51135C0-4P7F0O0A0a Baseline Missed | 5S1_51.30C4-7F0F0D0Aa Baseline c Missed | 511530C4-7P0F0DADa Baseline c Missed 0 Before 0 After Page 83 0f 245 105 8 Anoallyutmicbaal Services" Created with Analy:9R5eporter Printed: 15/02/2010 2:34.00 PM fon Ratio Confirmation ~ K1000911-009 - Ld TA "f ae = | [def Ia =5 2130P/F1B6A9200a 263P01F2P1E9A02Da 26P9.F0E19S9.20 Da 313P.R0H/1X12A90.a0 _ B-asWeiloinnge:PMeiasksed | BaseWliionneg=PeMaiks.sed | BaseWliionnegcPMesaks.ed | BaseWlrionnegoPMeiasksed 5, { "oYhdof =ti - - 1 4B [obs fo) Ditpsdite 363P.F03H1p9A.020a 3P09F.H0/Y99S.20 0a 5S1_51.30C/4P7F0DD.Aa0 _ Baseline c Missed | Baseline o Missed | Baseline c Missed | NG PRGWAroanndg PPFePaEkA 00 Wrong Peak nol ave qualiying on tansiions. 1 Wrong Peak 0 Before OJ After NA Baselineu Missed Wrong Peak Page 84 of 245 108 LC8ol5umb0ia services: Created with Analypst.%R6eporter Printed: 1410212010 6.41.00 PAA PDraotjaecFtile Evan's ProjecisPrCs G208106\SamplesLong wit InRessturlutmTeanbtleName __AGP2I0851000S0amplesLong ab [SampleName [Kiougo1r-010 Tnjection Volume [5 [Acqunisitijon Meethod[c|82P/F8t/C20K1n0oe10l.e0n2x.0od6anvPrgMn ia[Di[SlauWmtpileoenoiFTayVgcpoetlhourmte[[1o0o0 || Results Summary a natePR eak stoma | isanoT | AAReERYT | PFOA 13cPFOA| 3samo00| 1370136)| [oemnt cera | asa | soa| pros 1 130PFOS | 5925100 | 235253)| PFOA 1 f[Pruner || 130PFOA | taceruna |1 2355200 | 000(334) eses7 | at0wom| eTrOoRTs1NOTT| wUceMroAs |1 9687 |sele06w0nn || ero 1 Taceroo|s os |owasn| PETIA T 19CPFDO|A 120520 | 000514) PFTeA1 [cerA|oLYvozens0 [oo0sz|e ana arehes | CHBECeone ode; s? seer 0378 No wos aw | ne 381100 0616 No o 20 | wa | ooss --No]| oo | e sos|| ooe ws | Mweo | 0 | wa "o 0 | NA | No 00 | wa| | MmNe || %a er PRIUS Pa86gof2e42 107 A nalytical Services Ra Created with Anal Heporter RCS4mmary preos swoon SL ll = awa |sew |ws o| ween| ve | swceron Bm [scrum oronz [s_13cpFo0n | ama| mem Tosem [mm arie0s)| osesT w w [owen| w No | 15570186) ~ Cona|s om | we | aww |e | arswen | rs | No | ocoeoe wl Tesnaam|m m T wew |owmoenw||w] e 4 lami Analytical ServicesTM `Quantitative Peak Review - T 7 PrCinrteead:ted14w/i0t2h/A20n10a6l4B1p:o00rtPeMr K1000911-010 zi z-- 413P0/F1O6A901 Da 41137C0-3P7F2O0A08 463.P0E14N1A91.0 0a 4681.03/C42-3P.0FNADa _ Baseline Missed | Baseline o Missed | Baseline cMissed | Baseline c Missed | | Cd 499P.F0O0S.01 Da 50133,0C1-8P0F.0OSDa 513P0/F4D6A901 Da 51135C0.4P7F0D0ADa cBaselive Missed | oBaselineo Missed | Baseline: Missed | Baseline c Missed | wa oe { 56P3F0U/R51A901 Da _ Baseline Missed | 5 a2 = {Th 56153.C0-1P2F70U.R0ADa 599P.0F/D8S001 Da Baseline Missed | Baseline Missed | 4A - 50133.0C/-8P0F.0OSDa Baseline c Missed i = 475 - = 475 : : 3 i goin 2 cl sia = LAT 613.P0F5D6O9A.01 0a 611530C1-6P9F.D00A0a 663.P0F6T1G9A.01 0a 61135C0-/PF1D6O9DA0a Baseline Missed | cBaseinec Missed | c Baseline Missed | Baseline Missed SHTYLAOR N,AP Sptu] | 713P.F0T66E9A.10a 61153C0-/P1F6D9O0.A0a Baseline c Missed| c Baseline Missed 0 Before OI After Page 88 of 242 109 PAS CAnoalluymtibciaal Services" Created with Analys9t9Reporter Printed: 14/02/20106:41:00 PM fonRatioConfirmation rr Kfoossiiat - - S o4 o h EI R f Lo A CoA Re RL | ete oB4a1n3ip0nr3eo8k820M0is8sa | G4a6s3soi0rn2ei1c02h0i0o0sea | S19m5P0sr0o5sc0?b0o8sed |c B5o1s3v0or3n8i520i0s8ed Sons Pen rong Pes hong Pens Cons Pe ditfm 4 | | [ go | 3 | wisrtoene|| dZohe n B5a6rs3Pio0Fn2nUg0Rg8AP5s2e0nesad | oosassne5PnoFseDmSso2P0o0me8sed|c B6a1ts3Po0FemD1nsO6Ao0pm52ea0os0ed | cco6ts3Po0FennTs6ti0AP25sep0ais0ced B1a1s3Prol0Fn1Tege6PcA82e0n0e.8ed O Before OJ After Page89.1 242 io LSCoSluombtia services: PrCinrteeadt:ed15w0i2h12A0n1a0l2py.31R40e00p0arPtMr DPartaoFcile Result Table G0F22a0088s1100:SPSaoammpapiRleeFssSrsHChoorSredwii db Instrument Name __API 5000 [SaRReemtapuuliisesiNitooannmdWaeetein||P2GaF9gCGk2anr0eiio112enSx0ASd8rTros cianVal [86 ZT ES -- [waighitoVolumeTo] ES wie Results Summary Analyte Peak | mae | EIR Analyte RT | sens | eo| Calc. 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T[Dep -i! -- | Teh| 296.P0F/9B9S.20 Da | BasWerloinnegoPMeiasksed | p7epe 3 f= etl 31P3E0H/1X21A900a B=asWelrionnegoPMeiasksed = Dn slush 3630P/F3H1O9A02Da 399P.0F/99S.02Da 5s1_5130C4P7R0D0A0a NA < BasWcrlionneg PMeiasksed | BasWeliionnegcPMeiasksed | BaseWlrionneg PMeiasksed | B=asWerloinngcePMeiasksed NB. PFBA and PFPeA do nol have qualfying on transiions. 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