Document 6wNOeYBJk12mGDwK3YKgBJ05R

Monsanto Industrial Chemicals Company Product Acceptability Practices Paper No. 9 - THE DISPOSAL OF BY-PRODUCTS AND RESIDUES Date: November 1, 1974 fiiiniony MANAGING DIRECTOR DIVISION MANAGERS/BUSINESS MANAGERS MARKETING DEPARTMENTS Directors, Managers, Product Managers/Specialists, Supervisors and Field Salesmen. MANUFACTURING DEPARTMENTS Directors, Managers, Plant Managers, Production/PTS Superintendents, Chief Chemists RESEARCH 6, DEVELOPMENT DEPARTMENTS Directors, Managers, Group Leaders, Fellows COMMERCIAL DEVELOPMENT DEPARTMENTS Managers, Supervisors PLANNING & CONTROL DEPARTMENTS Directors, Managers ENGINEERING DEPARTMENTS Directors, Managers , DISTRIBUTION DEPARTMENT Managers ' PRODUCT ACCEPTABILITY DEPARTMENT Managers LAW DEPARTMENT Director, Attorneys ADMINISTRATION Director, Director/Manager Marketing Services, Manager COP TECHNOLOGY PLANNING & EVALUATION Director, Managers, Group Leaders, Fellows, Senior Research Specialists UTILITIES & ENVIRONMENT Director 0066532 TOWOLDMONOQ56450 Monsanto Industrial Chemicals Company Product Acceptability Practices Paper No. 9 Date: November 1, 1974 SUBJECT: THE DISPOSAL OF BY-PRODUCTS AND RESIDUES Page 1 of 5 I. POLICY MICC policy is to dispose of unavoidable by-products and residues in the most economical manner possible to Monsanto consistent with all legal requirements of federal state and local government agen cies and consistent with due care and concern for potential injury or damage to people, animals and the environment. II. RESPONSIBILITIES The business group responsible for the process that generates a by product and/or residue is responsible for disposal of the by-product and/or residue. Each department of a business group (R&D, Commercial Development, Manufacturing, and Marketing) has the same responsibilities in the disposal of by-products and residues as it has in the develop ment, manufacture, and sales of the desired product(s) of a given process. General Manager approval of a proposed program must be ob tained by the business group. All other Company and Corporate functions have the same review and approval responsibilities in the disposal of by-products and/or, resi dues as they have in the development and sale of the desired product(s). III. RATIONALE We recognize and accept the knowledge of increasingly more stringent requirements of safety, toxicity, environmental compatibility, etc. for our products. An ideal process would not generate by-products or residues, but we have no ideal processes! By-product and residue problems have been handled without the benefit of any published guide lines that describe what is necessary before a plan of action is put into practice. The risks involved with by-product or residue disposal may be more serious than with the sale of product. It is necessary that we know a great deal about the possible customer, the use to which he intends to put our residue, how he plans to dispose of his residue, his financial resources, etc. if we are to avoid significant financial responsibility or adverse publicity for Monsanto. Disposal of by-products and residues requires use of resources just as does the search for new products, development of processes, or applied 00t><^3I.3* * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * Paper No. 9 Date: November 1, 1974 Page 2 of 5 product research. Business groups are responsible for management of resources devoted to their products, and they also are respon sible for providing the resources necessary to dispose of by products and residues. Basically the rationale is that all facets of a manufacturing and marketing operation require whatever atten tion is needed to stay in business. IV. PROCEDURE The initiative for recommending action may be taken by any group having knowledge of the problem or opportunity involved in disposing of a by-product or residue. For example, in the case of existing processes it is likely that plant personnel will first recognize the need to dispose of by-products or residues. This need should be brought to the attention of the business group Manager, Manufacturing who will then involve other business group functions and initiate whatever activities are necessary to obtain General Manager approval of the disposal method recommended. A marketing man may recognize a sales opportunity for disposing of residues or by-product; in this case he should bring it to the business group Marketing Director who will involve other business group functions and initiate whatever activities are necessary for General Manager approval of the disposal method recommended. The following table lists key activities necessary for arriving at a method for disposing of by-products and residues. Opposite each activity, the function responsible is indicated. No attempt is made in the table to indicate the position responsible within each function. For example, Manufacturing could include any one or several of these: Director, Manager, Plant Manager, Production Superintendent, PTS Super intendent, Chief Chemist. R&D could include: Director, Manager, Sec tion Manager, Group Leader. OObb^ TOWOLDMONOQ56452 ACTIVITY A. Select and recommend disposal method Provide data on quantities If new or purchased process If existing process Page 3 of 5 RESPONSIBLE Business Group Comml 1 R&D Dev. Mfg. Mktg.; Env. Protect. MICC Prod. Accept. Law X X Provide chemical composition data X Evaluate alternates and recommend preferred choice to Business Director X XX X GENERAL MANAGER APPROVAL OF RECOMMENDATION IS REQUIRED BEFORE FOLLOWING ACTIVITIES ARE BEGUN B. If recommended disposal method requires movement out of generating plant 1. Before sending samples outside Monsanto: a. Submit EC-201 Questionnaire to Medical (Exhibit I) X b. Respond favorably to EC-201 c. Provide data for Temporary Shipping Authorization (G-1979 Rev. 2/74) to Corporate Distri bution (Exhibit II) X d. Issue Temporary Shipping Authorization e. Review and approve each of above XX Corporate Medical Distr. X X X SES9900 TOWOLDMONOQ56453 ACTIVITY Page A of 5 RESPONSIBLE Business Group MICC Cotmnl. R&D Dev. Mfg. Mktg. Env. Protect. Prod. Accept. Law Corporate Medical Distr. 2. Before Sale is made: a. Submit EC-202 Questionnaire to Medical (Exhibit III) b. Respond favorably to EC-202 c. Provide information on physical and chemical properties Hazardous Property Data X X X X Toxicological Data Ecological Data X Use XX d. Provide Material Safety Data Sheet (OSHA 20) X e. Set Specifications (G-2598 or G-2599) Exhibits IV & V) XX X X f. Provide information for label and Freight Classification Request (TF-837, Rev.7/74) (Exhibit VI) XXX g. Provide DOT classification, labels, Shipping Instructions, etc. ' (TF-837, Rev.7/74) (Exhibit VI) h. Prepare Sales Contract that recognizes customer's ability to handle material X X XX X X X X 9ES<>900 TOWOLDMONOQ56454 Page 5 of 5 ACTIVITY Business Group RESPONSIBLE MICC Comml. R&D Dev. Mfg. Mktg Env. Protect. Prod. Accept. Law i. Review and approve each of above j. Obtain proper signatures on sales contract 3. Before contracting for disposal Complete steps 2 a, b, c, f, g, above Prepare Contract Review and approve each of above Obtain proper signatures on contract C. If recommended disposal method is to handle inside generating plant Obtain process Engineer and design facilities needed Prepare capital project Review and approve above Obtain proper authorizations Corporate Medical Distr. Eng. X X 6653J TOWOLDMONOQ56455 EXHIBIT I MEDICAL DEPARTMENT BULLETIN Data Sheet EC-201 NEW PRODUCTS Preliminary Environmental Compatibility Assessment The following Environmental Compatibility Assessment Scheme Includes some procedures similar to those now used by the Medical Department to assess the potential hazard of new materials to humans. This systematic scheme is being adopted to ensure Insofar as possible that our products are not hazardous to the public or the environment. The scheme is designed to elicit the Information needed to protect people who come In contact with large or Bmall amounts of a material, occasionally or continually, and all aspects of the environment which may contact or accumulate It or its degradation products. It takes the form of a series of ques tions to be asked about the material which can be answered simply "yes" r "no". However, as will be obvious from consideration of the questions, considerable knowledge will be required to provide satisfactory answers. As provided for in corporate procedures (D-II-8 In Manage-' ment Qulde), the division in the company responsible for a new product must obtain a preliminary environmental eval uation, as soon as the proposed product Is identified and the end uses visualized. To Initiate this evaluation the individual responsible for the product consults the literature and obtains the best answers he can by consultation with others and completes data sheet EC-201. He sends this to the Medical Department along with a statement of his principal sources of Information and a request for a preliminary environmental evaluation. The Medical Director will respond as to the environmental problems foreseen and information required, if any, before sending out trial samples. 0066538 Medical Department Page Two Environmental Compatablllty Assessment - Data Sheet EC-201 (cont.) Description of tfrf Prnrtnnt - Probable End Uses - A. Is the acute toxicity (via oral ingestion, Bkln absorption, lnhalatlonl known or can It be estimated by analogy based on data for chemically related compounds? Indicate below: oral IT>rn-rats skin abSWrptlon MLD-rabblts Inhalation effect skin Irritation potential eve irritation potential Known Estimated or mg/kg or __________mg/kg or or or B. Are harmful effects from repeated or chronic exposures known or can they be predicted by analogy? C. Will 1) wastes from manufacturing 2) anticipated use, and/or 3) ultimate disposal of end product create environ mental problems because product falls to readily degrade , or decompose? D. Is there an Indication based on data or analogy, that the product can be stored or concentrated In biological systems? E. Is It likely that harmful secondary reaction products will arise from a harmless-appearing parent as a result of chemical, biochemical, or biological activity In the environment? NOTE: The Medical Department should be consulted for answers to Questions A and B. Questions C - E require speculation by people know ledgeable about the process and end use. TEMPORARY SHIPPING AUTHORIZATION -- for all materials not previously classified date----------------------------------------------- ORIGINATOR OF THIS FORM MUST HAVE TECHNICAL KNOWLEDGE OF THE ITEM AND ACCESS TO TOXICITY DATA IN ORDER TO COMPLETE THIS FORM. INDICATING THE HAZARDS OF THE ITEM CONSIDERED FOR SHIPMENT. CERTIFICATE MUST BE SIGNED AT BOTTOM OF APPROPRIATE COLUMN BY ORIGINATOR.___________________________________________________ CENTRAL DISTRIBUTION DEPARTMENT WILL REVIEW THE FORM. INSERT SHIPPING INSTRUCTIONS. AND RETURN THE ORIGINAL TO THE ORIGINATOR FOR RETENTION. THIS MUST BE PRESENTED TO THE SHIPPING ROOM FOR SHIPPING INSTRUCTIONS ON SUBSEQUENT SHIPMENTS UNTIL THIS ITEM IS PUBLISHED IN THE PRODUCTS SHIPPING CLASSIFICATION MANUAL - IDENTIFICATION OF PRODUCT SALES NAME___________________ CHEMICAL NAME_____________ COMMON NAME_________________ GASLIQUIDSOLID. QUANTITY__________________________ HEALTH HAZARDS DANGEROUS^: IF ONE OR MORE HAZARDS IN THIS COLUMN IS CHECKED YES, SHIPMENT IS NOT AUTHORIZED WITHOUT SIGNED AP PROVAL FROM ST. LOUIS. THE ORIGI NATOR MUST MAIL THIS FORM TO ST. LOUIS G.O., CENTRAL DISTRIBUTION DE PARTMENT, PACKAGING DEVELOPMENT SECTION (G4EC) FOR SHIPPING IN STRUCTIONS. CAUSES SEVERE BURNS TO SKIN OR EYES POISON-HARMFUL OR FATAL BY SKIN CONTACT OR INHALATION______________ ORAL TOXICITY (RATS) EXTREMELY IRRITATING OR SICKENING ODOR____________________________________ PHYSICAL HAZARDS FLASH POINT F TAG. CLOSED CUP FLAMMABLE LIQUID COMBUSTIBLE LIQUID________________ FLAMMABLE SOLID. BURNS READILY YIELDS OXYGEN TO STIMULATE COMBUSTION OF OTHER MATERIALS COMPRESSED GAS RADIOACTIVE EXPLOSIVE_______________________________ POLYMERIZABLE________________________ CAUSES DAMAGE TO ALUMINUM OR STEEL__________________________________ OTHER POTENTIAL HAZARDS 0066540 YES Q_________________NO ___________ YES SPECIFY COMPARABLE NO Q______ PRODUCT ON BACK 50 MG/KG OR LESS YES 0 BY TEST ______ ESTIMATED 0 NO 0 ' FLASH POINT IS0F _ LESS THAN 100F YES 100F TO 2O0F YES NO NO YES Q_______________ NO 0 YES Q _____________ NO 0____________ YES 0 ____________NO 0___________ YES Q _____________ NO 0____________ YES Q _____________ NO Q____________ YES 0 _____________ NO 0____________ YES 0 _____________ NO 0____________ YES O NO 0 (SPECIFY ON REVERSE SIDE) 11-------- SIGNATURE TO BE COMPLETED BY CENTRAL DISTRIBUTION DEPT. ' 2 RESTR1CTEpjlgg|g| TH SHIPPING ROOM WILL SHIP THIS ITEM PER THE APPROPRIATE PUBLISHED PACKAGING PROCEDURE. INCLUDING THE ADDITIONAL CLASSIFICATION (IN PARENTHESIS) TO THE NORMAL SHIPPING CLASSIFICATION FOR AIR SHIPMENTS. SELECTION OF APPROPRIATE PACKAGING AND CLASS'FICATfON WILL BE DETERMINED BY THE HAZARD CHECK YES NEAR EST THE BOTTOM OF THIS COLUMN. THE SHIP PING ROOM MUST THEN MAIL THIS FORM TO ST. LOUIS (SEE INSTRUCTIONS FOR DANGEROUS ITEMS). DO NOT MAIL ANY ITEM HAVING A HAZARD NOTED BY THIS COLUMN. 50MG/KG TO 500 MG/KG (ORA.A) BY TEST [~| YES 0 NO 0 ESTIMATED 0 YES Q NO 0 [ORA.A SHIP BY CARGO AIRCRAFT ONLY) _ SIGNATURE.i=3 IF THE COLUMN IS SIGNED. THE SHIP PING ROOM WILL SHIP THE ITEM PER THE PUBLISHED PACKAGING PROCE DURE FOR NON-REGULATED ITEMS. THE WORDS "NOT RESTRICTED" WILL BE ADDED TO THE NORMAL SHIPPING CLASSIFICATION FOR AIR SHIPMENTS THIS FORM WILL BE MAILED TO ST. LOUIS FOR COMPLETION AND FINAL APPROVAL THE ITEM IDENTIFIED DOES NOT POSSESS ANY OF THE HAZARDS LISTED IN THE DANGEROUS OR RESTRICTED COLUMNS. NO OTHER POTENTIAL HAZARDS ARE CONNECTED WITH THIS ITEM. 3 .SIGNATURE. ORIGINATOR'S LOCATION________ DIV./DEPT__________ STA. NO__________ |h NOTE TO SHIPPING ROOM: PRESENTATION OF THIS SIGNED FORM IS AUTHORIZATION TO MAKE G-l7* REV. 2/74 DATE IF SIGNED APPROVAL IS INDICATED AT LEFT. THIS AUTHORIZATION GOOD UNTIL DATE TOWOLDMONOQ56458 Monsanto EXHIBIT III Data Sheet EC-202 NEW PRODUCTS Final Environmental Compatibility Assessment As provided for In corporate procedures (D-II-8 in Manage ment Guide and Medical Department Bulletin EC-201) the division In the company responsible for a new product must obtain a final environmental evaluation before commercial ization. To obtain this evaluation, the individual responsible for the product reviews the Preliminary Environmental Compati bility Assessment (EC-201) form, consults the literature, obtains the best answers he can by consultation with others, and completes Data Sheet EC-202. He sends this to the ' Medical Director along with a statement of his principal sources of information, the Intended product uBes and a request for a final environmental evaluation with Intent to commercialize. The Medical Director will respond as to the environmental acceptability, restrictions, or additional information needed, if any, or if unacceptable, the reasons why. TOWOLDMONOQ56459 -2- (Cont. EC-202) Environmental Compatibility Assessment Scheme Instructions: Answer each question in turn, "yes" or "no". Each answer is provided with a directive concerning the question to be answered next; the loqic of the scheme assumes that auestions skipped would be answered "no" and can thus be ignored. The last question, No. 12, should be considered if it is decided to make and sell materials which are very useful hut potentially danaerous to man or his environment. When aoplying this form, consideration must be given to the product Monsanto supplies, product impurities, as well as thefinal or end product that enters the environment. ITEMS 1 THROUGH 3 ARE TO ESTABLISH THE HAZARDS TO HUMANS OF PRODUCTS, PRODUCT IMPURITIES, BY-PRODUCTS OR MANUFACTURING AND DEGRADATION PRODUCTS. If Go to: 1. Is the material so physiologically inert that there need be no con cern about health hazards to humans? yes No 4 2&3 2. a) Is the material toxic to per sons as a result of a single contact with high concentra tions? b) Is the material toxic to per sons at lesser concentrations following repeated or prolonged exposure? c) Is the material likely to be carcinogenic, teratogenic or mutagenic? 3. Recognizing the hazards to people, can procedures be devised for safe handling at reasonable cost? Yes 4 No -Do Not Sell ITEMS 4 THROUGH 6 ARE TO ESTABLISH IF CONSIDERATION HAS BEEN GIVEN TO DISPOSAL, DEGRADATION PRODUCTS OF DISPOSAL AND ENVIRONMENTAL DEGRADABILITY. If Go to: 4. Can "closed-loop" disposal pro visions be developed for the product so it will never reach the environment? Yes No 5 6 0066542 -3- (Cont. EC-202) If Go to: 5. Is it likely the degradation products from the "closed-loop" disposal system could be harm ful to humans? Yes -Recycle Degra dation Products to 2. Continue at 6. Mo 7 6 Is it likely that the product Yes -Recycle Degra will degrade in the environment dation Products to or in anv of the currently used 1. Continue at 7. disposal systems? No 7 ITEMS 7 THROUGH 10 ARE TO ESTABLISH HAZARDS OF PRODUCTS AND DEGRADATION PRODUCTS TO PLANTS, ANIMALS OR ECOSYSTEMS. 7. Is it probable that the product or degradation products are harmful to plants and animals at concentrations to which they are likely to be exposed? Yes No 8 9 8. Recognizing the hazards to plants and animals, can proce dures be devised at reasonable costs to render the material innocuous? Yes 9 No -Do Not Sell 9 Is it likelv that harmful secondary reaction products could be formed from the harmless parent material as Yes -Recvcle the ' a result of a chemical, bio By-product at 1 & chemical, or biological activity 7. Continue at 10. in the environment? No 10 10 Is there reason to suppose that the material could have dele terious effect on the ecosystem, e.g., through concentration in the food chain, antagonism, synergism, abiotic reactions, chelation or plain physical con centration even though the ves -Recycle to 8. material was not directlv toxic Continue at 11. to the biota? No 11 11. Have procedures been devized to handle catastrophes in the production, storage, or trans portation of the product? .12 Is it necessarv to restrict sales to specific end uses? Yes -Sell OObbb*3 Characteristics Reject LIMITS Manufacturing Unrestricted Sales Method Number OObt-^*' NOTEi Thli ipaclflcation li tha proparty of tna Montanto Company and It for Intarnal um only. It may not lx ralaaiad without wrlttan approval by Dlvltlon Product Accaptablllty. ft 9COfi 1 /IA TOWOLDMONOQ56462 EXHIBIT V PROOUCT CODE MONSANTO INDUSTRIAL CHEMICALS COMPANV SALES CODE fDEPT. OR JOB ISSUE DATE FINISHED PRODUCT SPECIFICATION product (Trade Name) SUPERCEDES SPECS. DATED GRADE product (Chemical Name> CHEMICAL FORMULA AMPLE FOR ANALYSIS PAGE OF APPROVALS - DATE CHIEF CHEMIST MANUFACTURING SUPT. MGR.. MANUFACTURING RESEARCH GROUP LEADER MARKETING OR DEVELOPMENT PRODUCT MANAGER manager, product Acceptability Characteristics Reject LIMITS Manufacturing Unrestricted Sales Method Number 0066*^ NOTEi Thli specification is the property of the Monsanto Company and is for Internal use only. It may not be released without written approval by Division Product Acceptability. G- 2599 1/74 TOWOLDMONOQ56463 MonsantoI Initiated by (Individual's name) Company Date Initiated Division or Department LABEL AND FREIGHT CLASS/F/CA T/ON REQUEST 1 Docket Nu nber Date Completed 1. IDENTIFICATION OF PRODUCT - To be filled in by Chemist. Signature _______________________________ Product Code 1.1 Seles Name 1.2 Chemical Name Research number: 1.3 Common Names Previous Monsanto names and numbers used. Development names: Other trade names: 2. STRUCTURAL FORMULA AND COMPOSITION - To be filled in by Chemist. Signature Include impurities in statement of composition for mixtures, give per centage composition and structural formulas of principal components. For solutions, give percentage solids and composition of solvent and solids, separately, each on basis of 100 Where applicable, give percent age of residual intermediates or start ing materials, and unneutralized ecid o' alkali. Do not use sales names; identify substances by chemical name. 3.PHYSICAL PROPERTIES - To be filled in by Chemist. Signature .____________________________ 3.1 Appearance: Describe as powder, crystal, flake, granule, lump, paste, 3.3 Boiling Point: C volatile solid, viscous liquid, mobile liquid, volatile liquid, compressed 3.4 Vapor Pressurepsie at 100 F ges, self pressurized container, etc. 3.5 Solubility in water:_______ g/100 ml 3.2 Meiting/Freezing Pt. C Freeze Thaw Stable Yes D No D Solubility of water in:______g/100 ml Completely miscible D Immiscible D 3.6 Flash Point. (For liquids and con tents of self-pressurized containers): Tag Closed Cup_F Pensky-Martens o Closed TesterF 3.7 Viscosity_CPS @25 C 3.8 Specific Gravity 3.9 Coet. of Expansion Odor (Describe):_________________________ 4. PHYSICAL HAZARDS: REACTIVITY (Including but not limited to the following) -- To be filled in by Chemist. Signature 4.1 Is product a strong oxidizing agent or strong reducingagent? Yes L) NoD 4.2 Is contact of product with combusti ble material liable to cause fire? Yes No 4.3 Is product corrosive to inar surfaces? ' Yes No Fe --------------- Al ----------------------- (mpy) 4.4 Are there specific measures to be taken in handling, storage or use to assure safety? 4.5 Are there specific inc any other material mi concerned? ^ q-j No 4.6 If answer to one or more of the above is "Yes," explain here and give preventive measures: Yes No D 6. PHYSICAL HAZARDS: FLAMMABILITY - To be filled in by Chemist: Signature 5.1 Ignition Temperature (Solids): Will product ignite and burn at an am bient temperature of 80F. or less when subjected to friction, or to percussion, or to an electrical spark? 5.2 Flame Propagation Rate (Solids): Will product ignite and burn with a self-sustained flame at a rate greater than 1/10 inch per second along its major axis? Yes D NoD Yes D No D 5.4 (Solids): Will the product liberate vapor susceptible ignition by spark or open flame at or below 300F Yes D No D 5.3 Flame Projection (Contents of selfpressurized containers): Is a "flash back" (a flame extending back to the container) obtained at any degree of valve opening, or a flame projection exceeding 18 inches at full valve opening, when container is dit charged at a flame from a distance of 6 inches? Yes No 6. PHYSICAL HAZARDS: GENERATION OF PRESSURE - To be filled in by Chemist. Signature 6.1 Will product explode when subjected to an electrical spark, or to percus sion, or to flame? Yes D No D 6.2 Is product liable to formation of explosive peroxides O' other ex plosive decomposition products? Yes D No D 6.3 Will product expel the closure of its container, or burn its container, when held at or below 130F. for 2 days or less? Yes D No D TF 837 (Rev. 7/74) 6.4 Will product erupt from its opened container at a temperature of 130F. or less, after having been held in the closed container at 130F. for 2 days? Yes D No D 6.5 Will product generate heat or pres sure within its container through decomposition, spontaneous poly merization, exposure to light, heat, atmospheric moisture, or other me"ns7 Y. No (over) 6.6 If answer to 6-5 is "Yes," explain here and give preventive measures 6.7 Fire Extinguishing - is water m effective or dangerous? Yes D No If answer to 6.7 is "Yes," rocom mend an alternate generally available extinguishing agent. 006654b Product Seles Name 7. HEALTH HAZARDS: HUMAN EXPERIENCE ONLY. - To be filled in by Chemist. Signature To your knowledge, has skin or eye Irritation or Irritation or toxicity ol any kind, been observed in research oi manutacturing personnel exposed to this product, or in persons engeg ed in the transportation or use of this product? If so describe below. Check facts carefully. Do not repeat rumor or heresay: (If more space needed, attach sepa rate sheet.) 8. USES - To be filled in by Sales or Development. Signa< 8.1 Will label oi advertising make any claim for control of plants, animals, or micro organisms? Yes 0 No 0 8.2 Is product intended for use as an additive to food for humans or ani m,l,? Yes No 8.3 Is product intended for use component of container or ment in contact with food? Yes 0 No O 8.4 Is product intended for use as or a component of a drug for hi or animals? .Y.es nLJ No Un 8.5 Is product intended tor use as a cosmetic or a component of a cos me"C' Ye, No 8.6 Fertilizer Yes 0 No [J 8.7 Is product to be packaged in a container intended or suitable for household use? Yes fl No 0 9. PRESENT OR INTENDED USE - To be filled in by Marketing Group. Signature_____ Primary Use Secondary Uses For resale products give precaution ary statements and storage or han dling instructions, if any, used on label by supplier. Where produced by Monsanto Value per pound or gallon $ Competition Prodi Points of competu 10. HEALTH HAZARDS: ANIMAL TEST RESULTS. - To be filled in by Medical Department. Signature 10.1 Oral Toxicity: Albino rats: Single oral dose. LD50 10.2 Skin Toxicity, Albino rabbits: LD50 by single 24 hour continuous skin contact 10.3 Inhalation Toxicity, Albino rats 6 hour continuous inhalation of 25C saturated atmosphere. 10.4Skin Irritation, Albino rabbits: Pri mary irritation score 10.5 Eye Irritation: Albino rabbits: Score Classification 10.6 Corrosiveness: Albino rabbits: Is tissue at sight of contact destroy ed? Eyes Yes D No . Skin, 24 hr, contact Yes 0 No O Skin,4 hr. DOT Yes No 0 10.7 Source of preceding information. 10.8Any unique hazards, not apparent from shown data. 11. DEPARTMENT OF TRANSPORTATION CLASSIFICATION - To be filled in by Distribution Department. Signature______ Explosive: Poison: Class A 0 Class A 0 8cn0cd B0 Flammable Gas O Flammable Liquid 0 Flammable Solid O Oxidizing Material 0 Combustible Liquid 0 Corrosive Material 0 Compressed Gas 0 Radioactive 0 Etiologic Agent 0 Other (Please State) 12. LABELS REQUIRED. Signature, Hazard Info. No. (DOT) (Chemtrec), DOT Label________________ ______________________ _ Special MarkingMonsanto Label ______ _ 13. SHIPPING INSTRUCTIONS. Signature Mailable Yes 0 No D Max. by expressMax. by passenger aircraft.Max. by cargo aircraft 14. PROPER SHIPPING NAME, HAZARD CLASSIFICATION, SHIPPING DESCRIPTION. Signature.............. _ .... Waioi_____________ Air_____ 00 6654 7 TOWOLDMONOQ56465