Document 6wDzOGrr1kBDEL0z2JjQQ10a6

U.3. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET omb no^rust Required under (JSDL Safe'-v anu health Regulation: *or Ship Repairing, Shipbuilding, and Shipbreaking (29 CRR 1915, 1916, 19171 September, 1978 SECTION 1 manufacturers name PPG Industries, Inc. 1 emergencv telephone NO* (304 ) 843-1300 address tSumber. Stree:. City, Stit and ZIP Cjgc One Gateway Center, Pittsburgh, P4 15222 TTJCHEM.ICAL NAME ANO SYNONYMS /bio t)V VO i UfTlfc J trichloroethane and 25% perchloroetnv ene i trade ^S^ONVMS zLl!cl1^iY&r'lna^ecT hydrocarbons, ^XTYrichloroethane-CH^CCl 3;Perchl or- SECTION PAINTS, PRESERVATIVES, & SOLVENTS PIGMENTS HAZARDOUS INGREDIENTS TLV (Unn;l ALLOYS AND METALLIC COATINGS BASE METAL TLV lUmwl CATALYST I ALLOYS VEHICLE SOLVENTS ADDITIVES METALLIC COATINGS filler metal I PLUS COATING OR CORE FLUX others others HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASES (" by Vol UlUe) Stabilized 1,1,1 Trichloroethane Stabilized Perchloroethylene TLV (Units) 75 B50 (ppm) 2L 100 (oon) SECTION III PHYSICAL DATA BOILING POINT (F.) (81.2C) 178,2 ! SPECIFIC GRAVITY (HjOen VAPOR PRESSURE (mm Hg.) VAPOR DENSITY (AIR>1) 100 2g/solubility in water g of H O .. , Unknown 4 . OD 0.35 ! PERCENT, VOLATILE i by volume ! EVAPORATION RATE 1 ( l) appearance and ooor Colorless, clear liquid, ethereal odor 1.381 100 UNKNOWN SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH PQINT (Method ut#d) , , None (tag, open or closed, flammable limits N.. -oLn*'e H. onuei extinguishing media Water, dry chemical, or COg (for fires involving CSM- 32Q)_ SPECIAL FIRE FIGHTING PROCEDURE? ______ Weal" a Nir)SH/rtHS4-approvgd, Self-contained brpflthina annaratiK during fire fighting. ^Ta^o^'cln^DeEiqVfteNdH^yARgh intensity heat sources (above 1300F) forming hydronen chloride gas and traces of phosgene. PAGE (1) (Continued on reverse side) Form OSHA-20 Id*. May 72 SL 074484 'hRESnOLO LIMIT VALUE (See attached sheet) EFFECTS OF OVEREXPOSURE SECTION V HEALTH HAZARD DATA See attached sheet emergency ANO FIRST AID PROCEDURES See attached sheet STABILITY UNSTABLE SECTION VI - REACTIVITY DATA i 1 CONDITIONS TO AVOID , , .. , 1 'Avoid fiamPR. hot. olnwina surfaces, electrical STABLE ' X. arcs. INCOMPATABIUTV 'Maienais to avow See attached sheet HAZARDOUS DECOMPOSITION PRODUCT? Hydrogen chloride gas, anti traces of phosgene. HAZARDOUS polymerization MAV OCCUR 1 WILL NOT OCCUR i l , CONDITIONS to avoid 1 i None ! Xi SECTION VII - SPILL OR LEAK PROCEDURES 1.TEPS TO BE TAKEN IN CASE MATERIAL 15 RELEASED OR SPILLED _______See attached sheet__________________ WASTE DISPOSAL METHOD EPA-aoproved incineration or contact local waste disposal contractor. SECTION VIII - SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION 'Specify rvpei See attached sheet ventilation local exhaust special mechanical iCfNera/vbufficlent to maintain , other workplace concentration below TLV_________ ;______ PROTECTIVE GLOVES I EVE PROTECTION Polyethylene, neoprene or polyvinyl alcohol___________ Splash-proof googles OTHER protective equipment Eye-wash fountain SECTION IX SPECIAL PRECAUTIONS PRECAUTIONS TO BE taken in 1-iANOliNG AND STORING _ . .. . See attached sheet other precautions See attached sheet PAGE (2) SPO 931-tlO Form OSHA-20 R#r. M*y 72 SL 074485 ADDENDUM TO MATERIAL SAFETY DATA SHEET ON CSM-320 (SEPTEMBER, 1978) SECTION V - HEALTH HAZARD DATA Threshold Limit Value The individual TLV's are 350 ppm for 1,1,1-trichloroethane and 100 ppm for perchlor. Consult 29 CFR 1910.1000 for details or the method for calculating permissible exposure limits for mixtures. Acute Toxicity Values No tests have been run on this blend of solvents. The following is data on the toxicity of the individual components. 1,1,1 -Trichloroethane^)--Oral LD50 (rat): 10-12 gm/kg Oral LD50 (rabbits, guinea pig): 5.6-9.5 gm/kg Inhalation LC50 (rat): 8000 ppm/7 hours Perchlor^1)--0ral LDLg (rabbit): 5000 mg/kg Inhalation LCLq (rat): 4000 ppm (4 hours) Effects of Overexposure Acute: Irritant and central nervous system depressant. Inhala tion can cause irritation of the respiratory tract, dizziness, nausea, headache, loss of coordination and equilibrium, uncon sciousness and even death in confined or poorly ventilated areas. Fatalities following severe acute exposure have been attributed to ventricular fibrillation. Ventricular arrhythmia may be induced with sensitization to epinephrine. Eye contact can result in discomfort, pain and mild conjunctivitis. Prolonged or repeated contact with the skin can cause irritation and dermatitis. Chronic: May damage the liver and kidneys upon prolonged or re peated inhalation of vapors. Emergency and First Aid Procedures Inhalation Overexposure: Remove to fresh air. If not breathing, give artificial respiration, preferably mouth-to-mouth. If SL 074486 -2- CSM-320 breathing is difficult, give oxygen. Cali a physician. Note to Physician: Avoid use of adrenalin in any case where a person has been overcome by perchloroethylene or 1,1,1-trichloroethane. Eye Contact: Flush with plenty of water for at least 15 minutes. If irritation occurs, consult a physician. Skin Contact: Wash thoroughly with plenty of soap and water. If irritation occurs, consult a physician. Swallowing: If conscious, drink a quart of water then induce vomit ing by placing a finger far back in the throat. Call a physician. If vomiting cannot be induced, take inmediately to a hospital or physician. If unconscious, or in convulsions, take inmediately to a hospital or physician. DO NOT induce vomiting or give anything by mouth. SECTION VI - REACTIVITY DATA Incompatabllity Avoid contact with caustic soda and Gaustic potash (may react to form explosive compounds), acids and water (may cause decomposition of the solvent.) SECTION VII - SPILL OR LEAK PROCEDURES Steps to be Taken in Case Material is Released or Spilled Immediately evacuate area and provide maximum ventilation. Only per sonnel equipped with proper respiratory and skin/eye protection should be allowed in area. Collect spilled material on sawdust or vermiculite and sweep Into closed containers for disposal. Then flush area with plenty of water and maintain ventilation until vapors are eliminated. SECTION VIII - SPECIAL PROTECTION INFORMATI ON Respiratory Protection NIOSH/MHSA-approved organic vapor respirator for concentrations below 1000 ppm. For 1000 ppm and above, use air-supplied respiratory protection. Consult 29 CFR 1910.134 for details. SECTION IX - SPECIAL PRECAUTIONS Precautions to be Taken in Handling and Storing o Do not use in poorly ventilated or confined spaces, o Keep containers tightly closed when not in use. Si 74487 -3- CSM-320 c Do not store in open, unlabeled or mislabeled containers. Other Precautions o Avoid prolonged or repeated breathing of vapor. o Use only with ventilation sufficient to limit employee exposure as far below OSHA permissible exposure limit as practical. o Avoid contact with eyes. o Avoid prolonged or repeated contact with skin, o Do not take internally. REFERENCES 1. NIOSH Registry of Toxic Effects of Chemical Substances, 1975 2. Industrial Hygiene and Toxicology, Volume II, Second Edition, F. A. Patty, 1963 3. Dangerous Properties of Industrial Materials, Fourth Edition, Sax, 1975 4. Industrial Toxicology, Hamilton and Hardy, 1974 5. Toxicity and Metabolisms of Industrial Solvent, Browning, 1965 6. Toxicology, The Basic Science of Poisons, Casarett and Doull, 1975 SL 074488