Document 6w9vDx7GkRByzrmrq0L635K06

STOO I 2923 just '-** tm mrm DUST PRODUCING OPERATIONS IN THE PRODUCTION OF PETROLEUM PRODUCTS AND ASSOCIATED ACTIVITIES A MEDICO-SAFETY SURVEY BY Re; $. Bcroib.U. A..E.U. . iW/fr UPCTY HSPCCTO* HANOaJK) Oft COMPANY (N. JLf FOREWORD BV Willard J. Dnho, hi. CCHCRAL UCDtCAL OtBCCTOfi S7AN0*0 Oft COMPANY tN.JLf. STANDARD OIL COMPANY !^N. J.) 30 ROCKEFELLER PLAZA* NEW YORK.N. Y. JULY - 1937 396319 STO O I2 9 2 U FOREWORD Because it la the duty of industry to proteot Its employee* and because no comprehensive survey of the hazards incident to oc cupational dust problems had yet been made, it was felt that here was an opportunity to render a serivce to the petroleum industry and its employees by making such a survey. It is hoped that the information presented in this bulletin will assist in finding proper answers to same of the many, questions which have recently arisen concerning the health hazards of employ ees whose work involves exposure to dusts of various origin. An attempt has been made to consolidate opinions from the most experienced students of occupational-dust problems to show the relative hazards of dusts and the duration of exposure which may prove harmful to the worker. Furthermore, a study of the prevalence of dust partioles ooourrlng in various operations in the petroleum industry has been, made and included in this report} also a description of the pro tective devices and equijsaent provided for the protection of the workmen. This report should serve as a guide to operating executives and safety engineers in handling personnel and in providing adequate protection in dusty occupations. It should also resolve many of the fears and questions of industrial workers in these occupations. The study confirms an opinion that dusty occupations, thor oughly understood and intelligently handled should result in no serious disability. General Medical Director Standard Oil Company (N. J. ) 396320 MEDICO - SAFETY MEMORANDUM DUST PRODUCING OPERATIONS IN THE PRODUCTION OF PETROLEUM PRODUCTS AND ASSOCIATED ACTIVITIES CONTENTS INTRODUCTION PART I - DUST AS A HEALTH HAZARD I - WET IS THE DUST PROBLEM SO IMPORTANT?................................................. . II - WHAT IS MEANT BY "DUST"?............................................................................. . III - WEAT ARE TEE PHYSIOLOGICAL EFFECTS PRODUCED BY The Inhalation of Dust............................................................................ Silicosis in General.................................................................... First National Silicosis Conference....................................... Silicatosis.............................................. ............................................. Asbestosls.................... .......................................... ............................ . 17 - WEAT IS TEE MAXIMUM PERMISSABLE DUST CONCENTRATION? Formula For Determining Maximum Permissible Concentration of Silica in The Air Breathed........................................................... Safe Dust Concentrations, Impringer Samples.................. 7 - SOW MAY TEE CONCENTRATION AND CEARACTZR OF INDUSTRIAL DUSTS BE DETERMINED?....................................................................................... The Impinger Apparatus.......................................................................... . The Zeiss Eonimeter................................................................................... The Bausoh & Lamb Dust Counter...................................................... PART II - DUST PRODUCING OPERATIONS STUDIED WEAT ARE TEE PRINCIPAL DUST PRODUCING OPERATIONS? I - SAND-BLASTING..................................................................................................... II - FILTERING OPERATIONS................................................................-................... . A - Filter Clay or Fillers Eartht What is Filter Clay or Fullers Earth?................................. . How is Filter Clay Mined and Prepared?............................... Eon is Filter Clay Used.?............................................................. "Burning" Clay............................................................... .. Charging Filters........................................................................ Dumping Filters.................................................. ...................... Composition of Filter House Air Borne Dust...................... Control of Filter Clay Dust....................................................... S - Contact Clayi Main Constituents of Contact Clays........................................ What is "Filtrol" and Eow is it Produced?........................ What is the Chemical Composition of Filtrol?.................. Eon is Contact Clay Used?........................................................... PAGE 2 2 3 4 4 6 7 7, S 9 9 10,11 11 11 CO --H a CD ro CD ro cn 13-15 15-27 15.16 16.17 17.18 18.19 19.20 20.21 21 22 22.23 23.24 24.25 25.26 CW CO CD O) CO -2- PAGE C - 3ore 31ack or Charred Bore; How is Bone Black Used................................................................................... 26 III - INSULATING OPERATIONS; A - What Physiological Reactions are Provoked by Instating Materials?........................................................... ........... .. 27 B - What Are The Principal Insulating Operations and How- Much Dust is Produced During SuchOperations?....................... Insulating 12" Steam Lines.................................................................... Insulating a 750-Pound Cracking Coil Accumulator.................... Insulating Treating Plant Acid Suction Line...................... .. Insulating Cracking Coil Hot Oil Lines.......................................... Dismantling or Removing OldInsulation............................... Crushing Scrap Asbestos.......................................................................... Crushing Old Cork Insulation.................................. ....................... 17 - GUNITING CPZRATICNS; 27 27,28 28 28 28 28,29 29 29 '/hat Is Gunite and How Is It Applied?.................................................. 29,30 Removal of C-unite Lingirs............................................................................ 30 "7 - WELDING AND CUTTING OPERATIONS; A - Welding Operations; 1. Electric Arc Welding.............................................................................. What are Coated Electrodes?...................................................... What do These Electrodes Contain and Wha.t Products Result From Their Use?............................................... Whan is The Amount and What Are the Characteristics of Fumes or Dust Produced By The Various Electric Arc Welding Operations............. What Physiological Effects on Welders is Produced by The Use of Coated Electrodes........................ 30 30,31 31,32 32-35 35-37 2. Oxy-Acetylene Welding........................................................................... Fumes or Dust Produced by Cxy-Acetylene Welding............... 37 37 B - Burning or Cutting Operations; 1. Viith Cxy-Acetylene.................................................................................. Fumes or Dust Produced by Oxy-Acetylene Burning.................... 2. With Natural Gas...................................................................................... 37,38 38 38 C - Health Hazards Produced by Welding and Cutting Operations.... 38 VI - GRINDING OPERATIONS; What is The Composition of Grinding Wheels?..................................... 39 Is Abrasive Dust ............................................................................................. 39,40 1 - What are the More Frequently Used Types of Grinders, the Quantity and Character of the Dust they Produce?......... 40 396322 o o ro ro cr> 5* i> I UU 12927 A - TANDEM FLOOR TOCL GRINDERS........................................................................... Dust Produced by Tandem Floor Grinders.............................................. B - TANDEM BENCE GRINDERS...................................................................................... Dust Produced by Tandem Bench Grinders.............................................. Characteristics of Dust Produced by Tandem Bench Grinders............................... ............................................................ .. C - SINGLE FLOOR TOOL GRINDERS........................................................................... Dust Produced by Single Floor Grinders.............................................. Characteristics of Dust Produced........................................................... D - UNIVERSAL GRINDERS........................................................................................... Dust Produced By Universal Grinders..................................................... Charactersitics of Dust Produced.......................................................... E - SURFACE GRINDERS................................................................................................ Dust Produced by Surface Grinders.................. ...................................... F - LANDIS TOCL GRINDERS............................ .......................................................... Dust Produced by Landis Tool Grinders............................................ .. G - YANKEE DRILL GRINDER...................................................................................... Dust Prodded by Yankee Drill Grinder............................................... S - AUTOMATIC CIRCULAR SAW SHARPENING MACHINE........................................ Dust Produced by Yankee Drill Grinder........................................ I - AUTOMATIC BAND SAW GRINDER......................................................................... Dust Produced by Automatic Band Saw Grinder................................. J - AUTOMATIC BAND SAW LAP GRINDER................................................................ Dust Produced by Lap Grinder............................... .................................... K - PLANING KNIFE BLADE GRINDER....................................................................... Dust Produced by Blade Grinder.......................................................... .. L - LINDEHMAN CUTTER GRINDER............................................................................. Dust Produced by Cutter Grinder.......................... *................................ M - GANG SAW BLADE GRINDER...................................... Dust Produced by Gang Saw Blade Grinder. N - EDGER SAW GRINDER.................................................. Dust Produced by Edger Saw Grinder........... 0 - CIRCULAR SLAB CUT-OFF SAW GRINDER..... Duat Produced by Cut-Off Saw Grinder. P - "HOG KNIFE" GRINDER...................................., Duat Produced by "Hog Knife" Grinder, Q - CUTTER GRINDER...................................... Dust Produced by Cutter Grinder, 2 - What Precautions Should Be Adopted For Safeguarding Those Who Use Grinding Wheels?............................................. PACE 40,41 41,42 41 41 42 43 43 43 44,45 44 45 45 45 45,46 45 46 46 46 46 46,47 47 47 47 47 47 47 47 47 47 47 47 47,48 48 48 48 48 48 48 00 CM 00 CO CD 00 PAC-E Control of Dust from Grinding Wheels.......................................................... 48 m - EAUDIIMG POWDERED OR FULVERIZZD MATERIALS; A -- LDCEr (1) .Hydrated Lime............................................................................................... (2) Lump Quick Lime................................ What Physiological Effect ia Produced by Lime Dust................... 49,50 50,51 51 B - METALLIC ZHIC DUST; Typical Screen Analysis................................................................................... Dust Produced................................................................................................. What Physiological Effect is Produoed by Zinc Dust....................... 51 51 51 C - ASBESTOS "FLOAT"; Dust Produced........................................................................................ Physiological Effect of Asbestos Particles....................................... 51,52 52 D - GROUND MICA; Dust Produced.......................................................... Physiological Effect of Mica Dust......... ........................... ..................... 52 52 E - SULPHUR; (1) Sulphur Flour........................ (2) Crude Sulphur....................................................................... Physiological Effect of Sulphur................................................................ 52 52,53 53 7 - LITHARGE; Dust Produced.................................................................................... Necessary Precautionary Measures When Eandllng Litharge....................................................................... 53 53,54 G - SODA ASH: Dust Produced*.............................................................................. 54,55 H - TALC or "SOAPSTONE"; Dust Produced................................................................ Physiological Effects Produced by Talo Dust.................................... 55 55 I - GRAPHITE; Dust Produced......... .............. 55,56 <7 SLATE FLOUR: Dust Produced........................................ ................... ......................... .. Effect of Slate Flour on the Lungs......................................................... 56 57 K - GRINDING DERRIS ROOT; Dust Produced................ ..................... ......................................... ................... To What Extent is Derrls Toxio?............................................................... 57 57 L - GRINDING PYRETHRUM FLOWERS: - Dust Produced.................................... M - MIXING AND PACKING "FLIT" POWDER: Dust Produced.................................. Filling Cans....................................... 57,58 58 58 "dCM 00 CD o 00 ST00I2928 -5- ST00I2929 Till - CLEANING TUBES AND DRUMS: I - CRACKING COIL SOAKING DRUMS Dust Produced*....................................................... ................... ......................... .. II - CRACKING COIL TUBES: Dust Produced........................................................................................................ III - WATER HEADERS AND BOILER TUBES: Dust Produced........................................................ Composition of Dust from Front Water Wall Eeader............................. U - FOUNDRY OPERATIONS: A - POURING MOLTEN METAL INTO SAND MOULDS.................................................. B - "SHAKING OUT" CASTINGS................................................................................... C - CLEANING CASTINGS: (a) Preliminary Cleaning................................ (b) Tumblest.................................................... (c) Sly Tumbling Mill................................................................................. (d) Tumbling Barrels......................................... (e) Air-Blasting.................................................... (f) Rough Snagging Wheels............................................. (g) Fine Snagging and Polishing Wheels........................................... (h) Cone Grinding Wheels.......................................................................... Average Dustiness of Cleaning Room Air.............................. ............ D - CORE MAKING........................................................................................................... E - SEPARATION OF BRASS FOUNDRY SKIMMINGS.................................................. I - MASON'S OPERATIONS: I - TEARING OUT STILL FIRE BOXES............................................................................... II - CHIPPING OR CUTTING CONCRETE............................................................................... III - CHIPPING MORTAR FROM BETWEEN BRICK................................................................. IV - CRUSEING FIRE BRICK................................................................................................... V - SHAPING FIRE BRICK ON 3TERY WHEEL.................................................................... VI - DISMANTLING MASONRY................................................................................................... XI - WOODWORKING OPERATIONS: A - BOX SHOOK MANUFACTURE (a) Resawing.................................................. (b) Ripsawing.................................................................................................... (e) Cut of Sawing............................................................................................. (d) Planing.......................................................................................................... Dustiness of Shook-FactoryAir................................................................ B - BELT SANDERS, SAND DISCS AND SPINDLES OR CYLINDERS: (a) Belt Sanders................................. (b) Sand Discs orWheels.................... (c) Sand Spindles orCylinders.................................................................. C - MAKING WOODEN CRATES: (a) Band Saws.... (b) Railroad Saws 396325 PAGE 58,59 59 59 60 60,61 61 61 61,62 62 62 62,63 63 63,64 64 64 64,65 65 - 65 65 65,66 66 66 66 67 67 67 6^,68 68 68 68,69 69,70 70 70 TOO I 2930 XII ROCK EXCAVATION; A - DRILLING............................................................................................... B - BLASTING............................................................................................... C - MUCKING................................................................................................. D - DUST CONTROL MEASURES: (a) Wet Drilling and Wetting Down Roclc Walls and Muck Piles........................................................................... (b) General Ventilation........................................................ . (c) Dust Exhaust Hoods on Drills and Other Mucking Operations and Local Sources of Dust.................. (d) Personal Protection by Means of Respirators and Positive - Pressure Masks................................. PAGE 70 71 71 71 71 71,72 72 PART III - MEASURES FOR REDUCTION OF THE DUST HAZARD HON CAN THE DUST HAZARD BE REDUCED? A - DESIGN PLAIN1 ?CR DUST CONTROL....................................................... B - PROVIDE BUILDING VENTILATION........................................................... C - STORE DUSTY MATERIALS IN DUST-TIGET BINS................................ D - ENCLOSE MATERIAL HANDLING EQUIPMENT........................................... E - ISOLATE DUSTY PROCESSES................................................................ F - PROVIDE WET METHODS OF OPERATION.................................................. G - DESIGN EQUIPMENT TO CONTROL DUST.................................................. H - PROVIDE EXHAUST SYSTEMS..................................................................... I - ESTABLISH MAINTENANCE AND GOOD HOUSEKEEPING PROCEDURE... J - PROVIDE RESPIRATORS.............................................................................. 74 74 74 74 74 74 75 75 75 76 (a) Air Purifying Types of Respirators............................ (b) Supplied Air Respirators........................................................... The Air Line Respirator........................................................ Abrasive Blasting Respirator............................................ (c) Acceptance and Use of Personal Respiratory Protection by Workmen............................................................ (d) Use, Maintenance and Care of Respirators......................... 76,77 77 78,79 79 79,80 80 WHAT MEDICAL CONTROL SHOULD BE EXERCISED IN THE SELECTION AND SUPERVISION OR MIN WORKING ON UUSTY JOBS?................................... 80,81 PHYSICAL EXAMINATIONS.......................................................................... DESIRA3LE FHVSICAL QUALIFICATIONS................................................ RE-EXAMINATIONS........................................................................................ Till: LIMITATIONS 80 81 81 CONCLUSION, 81,82 396326 STANDARD OIL COMPANY (Incorporated in New Jersey ) 30 Rockefeller Plaza New York, N. Y. MEDICO - SAFETY MEMORANDUM lsto o 2 9 3 1 DUST PRODUCING OPERATIONS IN THE PRODUCTION OF PETROLEUM PRODUCTS AND ASSOCIATED ACTIVITIES ITTPCIUCTICIT - Long looked upon as objectionable, dust today is also reoognized as dangerous - especially with regard to occupational disease (Pneumoconiosis) and dust explosions. Since the dust encountered in the production of Petroleum products and associated operations are non^explosive under ordinary working conditions, no further attention will be devoted to this phase of the dust hsisard. Studies have repealed that the time element (exposure) and the concentration and size of the dust particles are major factors in producing health hazards. Here tofore difficulty has been encountered in determining actual dust concentrations and sizes of the particles, but recently developed instruments such as the Zeiss Kanimeter and the Bausch 4 Lamb Dust Counter make it possible to obtain dust counts and. estimate size of dust particles which, while not absolutely accurate, are indicative of the dustiness of the area. The data presented in this memorandum are based upon material taken from the available literature on the subject, upon field investigations and conferences with technical specialists and upon 1008 actual dust counts made with a Zeiss Konimeter, using a 20 to 20 micron (a micron is about l/25,000 of an inch) porcelain filter. In the report of the Preventive Engineering Committee of the Air Hygiene Foundation, Professor Philip Drinker of Earvard, chairman, and other technical specialists on the Coamiittee writet "If the breathing of dust causes disability of any sort - silicosis is only one manifestation - then it follows that there must be some degree of air cleanliness from which no disability will result to the average man during the average working period. "There is no satisfactory medical answer at present to this question, but the engineer is making a bad mistake if he lets men breathe heavy dust concen trations of any material. If no other reason for dust control oan be found, then one should read transcripts of some of the recent suits at oomnon law in which fantastic damages for alleged silicosis were granted to men who breathed dust containing little or no silica. The Courts and Compensation boards are not impressed with subtle distinctions between dusts with 10% and 40% quartz, especially when medical experts are reluctant to make definite statements as to the comparative significance of such differences. "It would be well to realize that men working in du3ty trades suffer far more from respiratory troubles of all kinds than do men who work in clean air. The evidence that excessive dustiness of any kind is harmful is beyond argi^ ment". OJ CO CO O 00  2- PART I - DUST AS A HEALTH HAZARD * I - WET IS TEE DUST PROBLEM SO IMPORTANT? - Although the subject of the health of workers in dusty trades has been receiving considerable attention froa students ofindustrial hygiene-for a nunber of years, the seriousness of this problem was not fully realised until' it was brought sharply to our attention by the constantly growl ing country-wide wave of lawsuits instituted in behalf of the victims in our ocmman law courts, by the magnitude of the generous verdiots awarded by the juries awa by a recent decision of the Federal Cirouit Court reversing the substantial award of a jury in a New Jersey case (Pennsylvania Pulverising Company vs. Eldred G. Butler), Owing to these developments, the problem cannot be Ignored or brushed aside as merely another fora of "racketeering" by unscrupulous lawyers and conspiring doctors- Dodging the issue cannot provide the needed solution because even the most unscrupulous lawyers cannot create a pathologic lung at will and, furthermore, even the most ske^> tio of toroners frequently finds himself corroborating a diagnosis by his postmortem examination. Enlightened industrialists and the medical profession as well as the bench and bar, have came to the realization that exposure to certain kinds of dust, such as those containing considerable amounts of quartz (silica), has increased the unhealthy bodily condition and death rate from respiratory diseases} while metallio dusts, such as lead and its compounds, have been associated with general systemio poisoning of workers. "Silicosis" is now a definitely recognized disease whieh is destined to become one of the foremost and most serious of occupational diseases of the future because the number of workers in dusty trades is larger than almost any other group exposed to a single known industrial hazard. The McCaffrey Ant, whioh became effective September 1, 1935, amending the New fork Compensation Law, included silicosis as an occupational disease subjeot to compensation. Sixteen states, as well as those of the Federal Government and of Hawaii, Puerto Rico, and the Philippine Islands (U. S. Dept, of Labor Bull. No. 625,Bur.Labor Sta tistics), have Workmen's Compensation Acts which include compensation for occupational, diseases, either expressly or by judicial interpretation, or specifio occupational disease aots. II - WHAT IS MEANT BY "DUST"? - According to Webster's Unabridged Dietionary, "Dust" nay be defined as fine, dry particles of earth or other matter so comminuted that they may be raised and wafted by the wind; that vhioh is orumbled to minute portions; fine powder. As pointed out by Philip Drinker in a paper read before the Chenioal Section of the National Safety Congress (held in Atlantio City, October, 1936), dusts include all types of dry earthy particles small enough to be blown about by ordinary air currents. Dust suspensions may be generated as the result of grind ing blasting, or comminuting process; or they may result from the handling of fine ly divided materials as in mixing .processes, in sweeping, or the blowing about of wood flour, plant pollens, or conaon road dust. There is no chemical limitation im plied by the term "dust" while the range in size of dust particles extends from the sub-microseopio to small sand grains. Mr. D. Harrington, Chief Health and Safety Branch, U. S. Bureau of Mines advises that dust as applied to health and respiratory conditions may be wet as well as dry. Under same conditions, such for example as in wet drilling in mines, the escaping air from the drill hole may (in fket generally does) contain a certain amount of entrapped solid material which undoubtedly is wet rather than dry, yet it remains in the air sufficiently long in some instances at least to be breathed by the workers to contribute to possible health trouble. The size of dust of importance from a hygienic standpoint are those under ten microns. In fact, the sizes', found in industrial atmospheres are under two microns for the larger majority of particles, say 90 to 95 per cent. Physiologically, there are al most as .many different classifications of dust as there are authors on the subject, Eowever, according to Professor Drinker ("Dust, Fumes end Smoke". International La bor Office, Occupation and Eealth7ol.l, 930, P.603) all of these classifications O CD PO CD CO PO t -3- ST00I2933 are without much practical importance, since in daily practice in industry the harmful effect is exercised more frequently by dusts mostly of mixed origin. Besides, what is most important is the physical and chemical constitution of the dusts and consequent ly their action on the system. Ill - WHAT ABE THE PHYSIOLOGICAL EFFECTS PRODUCED BY THE INHALATION OF DUST? - To "be harmful fronra respiratory viewpoint, dust must be of sufficient finess to pass through the nasal filters and be retained in the alveoli (minute air saos) of the lungs. Particle's found in autopsied lungs are of the order of one micron (a micron is l/lOOO of a millimeter or about l/25,000 of an inch) or leas in size - about the size of the common baoteria. Some dust partioles found in lungs are as large as five or six microns although these sizes are rather exceptional. _ There are five distinct types of reaction produced in man as the result of inhal ing dust. These reactions may be broadly classified, based on the primary oause, as followst (a) Those which result in lung fibrosis, commonly referred to as pmeu moconiosis. These dusts contain free silica, asbestos, eto. Ho*m ever, it is not necessary for fibrous tissue to be formed in order for the disease to be olassed as "Pneuaooomiosis". (b) Those which are toxic and are absorbed into the blood stream such as lead, cadmium, eto. (c) Those whioh result in what is commonly referred to as metal fuse fever; such as zino oxide, eto. (d) Those whioh are allergic in character, such organio dusts as pollen, pulverized wood and flour, eto. The breathing of pulverized wood end flour is frequently associated with tuberculosis. (e) Those eonsaonly referred to as "nuisance dusts". These may oause ir ritation of the respiratory tract or passages and may oause con siderable discomfort, also headaches of the dry "nasal" passage or sinus type and exposure to them may be assoolated with a high lz*> cidence of respiratory illness. The rate and extent of these reactions are dependent upon the resistanoe of the indi vidual, the exposure period (concentration of partioles and length of expoeure) tem perature and humidity of the air, rate of work, and the percentage of ingredients which are harmful. Owing to the length of time required to obtain a reaction by inhalation meth ods, the United States Bureau of Mines and the Public Health Service adopted about twelve years ago, a method of injecting small quantities of the dusts to be studied into the peritoneal cavity of guinea pigs. ("Response of Peritoneal Tissue of Dusts Introduced as Foreign Bodies" by Dr. John W. Miller, Dr. R.R.Sayers and Un.P.Yamt, Jour.Amer.Med. Assoc. Sept. 22,1934 - Vol103,pps* 907-911). It was found that idezw tical reactions occur in each animal injected with the same dust under the same con ditions and examined in the same time interval after injection. These reactions were essentially the same microscopically as that produced in the lungs and the gross appea ranee of the dust nodules was sufficiently differentiated to afford a means of classifying the physiological response to the dusts. There are three types of reaction* An absorption or dissolution of the dust. A proliferative reaotion. An inert reaction. 396329 In the inert reaction, the dust neither caused an increase in the size of the nodules nor disappeared from the tissues; instead there was more or less a change in its dis tribution. Soapstone, carborundum (Silicon Carbide), jeweler's rouge (Ferric Oxide), anthracite coal, bituminous coal and certain filter clays have inert reactions* Cal- cite, limestone, precipitated caloium carbonate, gypsum, and Portland Cement exhibit ed an absorption reaction. Quartz, chat, certain filter clays flint produced a proliferative reaction. . The physiological response to the injected dusts were found sufficiently well marked in 90 days to determine the type of reaction, particularly where the reaotion was one of absorption or proliferation. Since the reaotion elicited by dust was oonstant and uniform in all of the animals injected with the dust, it is believed that this response of peritoneal tissue to various dusts can be used as a test to de termine the possible harmfulness of industrial dusts. The fibrosis-producing properties of a Georgia filter clay (30-60 mesh grade) a sample of American contact clay and a German contact day were tested by the Intraperitoneal Method, under the direction of Dr. R. R. Sayers, Medical Offioer in Charge, U.S. Public Health Service. The Georgia filter clay showed an inert reaotion with a slight tendency towards a proliferation in the 90-day test. The Americanooz^ tact clay showed an inert reaction with evidence of sane slight absorption or dis appearance of same part of dust in the 180-day tests. The German contaot day oauaed the formation of light yellowish-brown nodules and as the interval between the Itw. jection and the examination increased the nodules became somewhat flattened, but the amount of dust and the approximate size of the nodule remained the same throughout" the entire period (90-days) of the test. This can be considered an inert reaotlani but as the dust does not disappear from the peritoneum it should be considered as po tentially harmful though not as dangerous as pure silica. In commenting on the results of the tests with the Georgia filter day and the American contact clay, Doctor Sayers advised that the results of the test indicated, that the filter clay is more harmful than the American contact clay because the dust remains inert in the tissues as this was the largest portion of the dust and the izv> ert appearance of the lesions was the most prominent. The modification of the reac tion in the filter clay can be attributed to the presence of 5-10 per cent, quartz (Petrographic), Gypsum in the American contact clay may account for the slight ab sorptive reaction. Doctor Sayers advises that an inert dust, if breathed in suffi cient concentration, may be harmful. These tests were made in accordance with the procedure described in Reprint #1608, Publio Health Reports, Yd. 49, No. 3, January 19, 1934, pps. 80-89. The inhalation of dust gives rise to "Pneumoconiosis" a term derived from the Greek pneumon, lungs and konls, dust, and used to designate a pathologioal condition of the lungs caused by the inhalation of any dust. It includes SILICOSIS, a chronio disease of the lungs caused by the inhalation of minute particles of free silioa (SiC2) dust which produces a permanent incapacitating alteration of the lung tissue; ANTHRACOSIS, the black lung of the miner due to coal dust; ANTHRACQ-SILICOSIS, the newest of our mineral dust affections and introduced by the United States Publio Health Service as a result of their studies in the Anthraoite Distriot of Pennsyl vania. This affection is the result of breathing anthracite coal dust that oantains silica. The common name for the affection is "Miners' Asthma"; CHALICOSIS, the gray-black lung of the stone-cutter due to stone dust; ASBESTOSIS; in asbestos workers due to asbestos dust; SIDEROSIS, due to breathing dusts of iron ore (The lungs are yellow or red from metallic oxides generally of iron. ); BYSSINOSIS, due to cotton particles and vegetable fibre dust, and FNEUMONOULTRAKICROSCOPICSILICOVOI-- CA2J0K0NI0SIS, a special form of silicosis caused by ultra-microscopic particles of . siliceous volcanic dust. Silicosis, Asbestosis, and Silico-Anthracosis are the only three forms of pneumoconiosis which require practical attention. 396330 -5- While the type of pulmonary lesion depends on the particular dust inhaled, the underlying pathological principle is the same in all forms of the disease, namely, an ultimate fibrosis and replacement of the elastio lung tissue by a hard unyielding fi brous tissue. All occupations that expose men to large amounts of dust may give rise to pneumoconiosis but not necessarily to silicosis. It is now generally agreed that in order to produoe the latter, (silicosis) Inhaled silica dust must reach the lungs in a chemically unoomblned condition, in very fine particles not more than ten orons (10/25,000 inch) in diameter and in sufficient amount and over a sufficiently long period of time. In relatively recent literature it appears that the proponents of the idea that only "free silica" is harmful are beginning to have sene doubts and to have the thought that possibly same silicates may under sene conditions be hanw fUl. Generally speaking, the necessary length of exposure to produoe silicosis is in direct proportion to the site of the dust particles and inverse proportion to the dust concentration and the amount of free silica in the dust. Silicosis is char acterized anatomically by a generalized fibrosis of the lungs and cllnieally by short ness of breath, decreased chest expansion and a progressively lessened capacity for work which is out of proportion to the objective physical findings. The effeot of ex posure to dust such as silica is cumulative, the rapidity of development of the dis ease depending upon the time and amount of inhalation. Silicosis may develop to the point of causing symptoms only after several years exposure to silicious dust, but it may be progressive in same cases even after exposure has ceased and may cause eym^ . tarns or become disabling long after the workman has left the environment that caused the condition. Some may improve or at least remain stationary in the absenoe of in fection. Watkins-Pitchford (J. Ind.Eyg. 9,109 -- 1927) tells of Welsh miners who passed the physical examination for enlistment in the British Army, fought through the World War, then came back to England, and died of silicosis. Unfortunately, it is not stated whether these persons died from sllioosis complicated with tuberculosis. Brit ton and Head (J.Am.Med.Assoc. 96, 1928 - 1931) give more detailed descriptions of similar latent cases in the United States. Silicosis in General - It is generally agreed that silioosis may be defined as "A ohronio disease due to the breathing of air containing silioa (S102), characterized anatomically by generalized fibrotio changes and miliary nodules in both lungs, and clinically by shortness of breath, decreased chest expansion, lessened capacity for work, a^> sence of fever, Increased susceptibility to tuberculosis (some of all of which may be present), and by characteristic roentgenolo gical findings." In other words, silicosis is a disease of the lungs in which the normal lung tissue is replaced by soar tissue due to breathing air containing silioa dust. Uafortunately there is no known cure for silicosis - but SILICOSIS and nearly all other forms of dust diseases CAN BE PREVENTED. Recognizing the wide interest and even hysteria among apprehensive employers against whom claims had been filed by alarmed workers, and the necessity of thought ful consideration of the silicosis problem, the Secretary of Labor on April 14, 1936 called the First National Silicosis Conference attended by more than 300 persona representing workers, employers, State and Federal Agencies, Insurance companies, and other interested groups. Four Committees were organized to study specific phases of the silicosis problem; and assemble the essential facts about silicosis in a series of reports; also to present specific suggestions for silicosis prevention and straighten out other difficulties that silicosis has created. Reports made oy these Connnittees were formally adopted at a second conference held February 2nd and 3rd 1937 in Washington, from which we quote* 396331 SG6/I001S e-6- "While a few persons may still be of the opinion that such workers" (Workers having silicosis)*"are 'through' and doomed to an early death, every study conducted thus far confirms the fact that the great majority of these men will not necessarily progress from bad to worse. Perhaps it may be wise to transfer some workers to other employment, but many may be continued at their regular occupations if known methods are applied to control the dust and if special care is employed to prevent the development of tuberculosis, pneumonia and other lung complications", c ST00I2936 "Contrary to popular belief, silicosis is slow to develop. Usually it takes seven years or more of exposure to silica dust for a worker to contraot the disease. It is said that a few cases have been known to develop in as short a period as l-l/2 years, but these were under extreme and unusual conditions. On the other hand, many workers have labored under ordinary exposures to silica for more than 30 years without demonstrating any trouble whatever that could be diagnosed as silicosis". i: For the convenient diagnosis of silicosis or of silicosis complicated by tr> berculosis, the pulmonary changes are classified in three stages by Drinker k Hatch ("Industrial Dust" - 1936). In the first stage, the disease produces no diability. The victim can work just as well as ever. In the seoond stage, his respiration is affected; he is bothered by dyspnea or labored breathing. In the third stage dys pnea becomes severe and he is likely to contract pulmonary tuberculosis, generally with fatal results. Whether he contracts tuberculosis or not, the advanoed silloetio is far below normal and is very susceptible to all respiratory diseases. = C I= These three stages of silicosis can be distinguished by X-ray. A comparison of the X-ray plates of a siliootic with those of a normal person of like age and physique shows, in the first stage, distinctive shadows, evenly distributed in both lungs. These may be missed or misinterpreted by any but an expert; but the ohanges in the second and third stages are obvious even to a layman. It is, of course, es sential that the X-ray plates be properly made. Dr. Pancost and Dr. Pendergrass of the University of Pennsylvania have given extensive study to the influence of X-ray technique on the diagnosis of silicosis. Pendergrass is of the opinion that shadows and appearances of fibrosis can be actually produced by the technique employed. Under other conditions, existing fibrosis can be entirely missed by use of improper technique. Silicates as a class are by no means harmless. It was pointed out by Dr. R. JL Sayers (U.S. Public Health Bulletin 221) that Miners' Consumption was rather com mon in the Broken Hill district of Australia where the rock contains considerable sillimanite (Alg S1O5), fibrous silicate, and a rather low percentage of quarts (12.23#). The studies of Badhair. (Rept. Dir. Gen. Pub. Health, New South Wales) give con siderable support to W. R. Jones' (J.Hyg. 15,307-1933) contention that silicates, particularly the fibrous varieties, may well be the cause of pulmonary disability. Badham in 1927 coined the word SILICATOSIS to cover disability from the inhalation of silicates. Other silicates such as Talo (H2 Mg (Si03))4; Shale; Kaolin (H4 Al?. Si2 Og); Feldspar; Cryolite, (Na3 A1F6 ); and pure Mica give much less specific changes than quarts. A moderate fibrosis may appear after exposure to numerous materials but this fibrosis is usually not disabling. According to Dr. Laura, "Silicatosis" is not a recognised term in this country and disability from the inhalation of sili cates has not been proven. Dr. Cary P. McCord (Ind.I'ed. July 1933, pps.4-12) states that all silicates taken into the lungs, of particle siie capable of passing the oellular membranes, are likely to induce some fibrosis in excess of normal but the progress of such silioatosis is not nearly so rapid as for silicosis. Tuberculosis rates are high in sili cate using industries. Antecedent tuberculosis, quiescent, may flare up as a result C e c c c c c c c c c c cCM CO CO CD O) CO -7- of exposure to silicate dust. Asbestosls - According*to authorities cited by Drinker 4 Hatch in their book "Industrial Dusts", the pathology produced by asbestos is not like that of silicosis. Dr. L. U. Gardner of Saranac Lake is of the opinion that the asbestos fibers group about the neck of an alveolus and shut it off, oausing what is known as "Atelectasis". There is no definite migration or transportation of the dust particles to the lynph nodes and no fibrous nodules. As the atelectatic areas increase the reduction in lung area causes, serious dyspnea or laborered breathing. Dr. A. J. Lanza (U.S. Health Repts. , 50j 1 - 1935) suggests that the enlarged hearts noted frequently in his eases of second stage Asbestosls may be due to the increased load on the heart. It takes more work to pump blood through the fibrosed than through the normal lung. Re cent pathological studies from human lungs iVam oases of asbestosls have indicated a diffuse type of interstitial fibrosis with a certain amount of emphysema. OO --l CD IV - WHAT IS THL' MAXIMUM PERKISSABLL DUST CONCENTRATION? - There appears to be a CD wide variation in the maximum concentration of dust which might be inhaled without subsequent injury to workmen. Some dusts (as lead) are determined by ohemioal methods and the concentrations in air are recorded gravimetrically as milligrams per cubic meter. However, the available information on the amount of lead dust that is ro co CD harmful and the methods of determining lead are better and more accurate than those for silica dust. It is rather well agreed that an intake of about 1.5 milligrams of lead a day, whether this is acquired by breathing dust or by drinking water that oon- tains lead, is the maximum allowable quantity. Others (as silica, where size is a factor in determining dangerous particles), are usually given by count. Neither ,, method tells the whole story, but in both cases it may be possible to secure the in formation necessary for the purpose. The maximum silica dust concentration considered permissible in the air breath ed by a workman at any point in the normal breathing zone has not been definitely es tablished. There is considerable difference of opinion regarding the range of par ticles that are counted when using the Public Health Service technique end light field illumination. Bloomfield of the United States Publio Health Servipe and Brown of the United States Bureau of Hines contend that they count particles from one mi cron and upward, or even 0.7 micron and upward. The Industrial Commission of Wis consin and its Advisory Committee, composed of both employers and scientists, how*, ever, agreed in 1932 on a tentative figure of 15 million countable particles under 10 microns in longest dimension with free silica content of 35 per cent in a cubic foot of air as determined by United States Public Health Service technique. Varia tions in free silica content will make proportional inverse changes in this standard. In the case of practically pure silioa, the permissible dust count should probably never exceed 5,000,000 countable particles. By countable partioles is meant those particles between 0.5 to 10 microns in the longest dimension. Particles of this size are the ones that are believed to cause the greatest damage and form no visible cloud. Dust particles smaller than 0.5 miorons in the longest dimension are not ordinarily countable. Dust particles larger than 10 microns in longest dimension do not ordinarily reach parts of the lung where they can produce injury of a respira tory nature. Host industrial dusts have but few particles above two or three mi crons in size. They are usually about 90 to 95 per cent, below two or three micron, and 50 per cent, below about 0.5 to 0.7 microns. An exception to this would be a ^ dust sample taken close to the point of generation of dust and before the larger particles had time to settle out of the air. CO 2 CD In South Africa the figure is 1 milligram per cubic meter (or 300 particles 00 per cubic centimeter, or approximately 8.5 million per cubic foot. ) Dr. Lanza found in 1917 in the Joplin, Hissouri district that with good engineering practice, a figure of 1 milligram per 100 liters of air could be attained. This value attribut ed to Lanza appears too high in comparison with the South African standards. As there -8- ' are 1,000 liters in a cubic meter, it would indicate that Lanza's estimation repre sents something of the order of 80 million particles per cubic foot. With good en gineering practice, lower concentrations than this can be obtained. In fact the ex perience in South Africa and also the present experience in this country indicates that it can readily be kept below one-tenth of this value by using ordinary good practices. The United States Public Health Service in its recent study in the an thracite region of Pennsylvania, found that 50 million particles per cubic foot with 5 per cent, quarts in the coarse dust and 10 million particles per cubic foot with 35 per cent, quarts were apparently satisfactory and often were attained. The figure of 10-20 million particles per cubic foot for granite dust with 35 per cent, quarts content is often quoted lYam the Vermont granite studies of the United States Publio Health Service. From a consideration of general experience, Cummings suggests 6 mil lion particles per cubic foot as a threshold for dusts high in quarts. This figure is besed upon a combination of South Africa, Australian and American experience but lacks entirely any published data in its support. According to studies quoted by Philip Drinker and Theodore Hatch in their book "Industrial Dusts" 10 to 20 million particles per cubio foot by the impinger sampling method, light field counting is a reasonable figure for cement and limestone. Reoent work by ETeessen confirms the universally accepted opinion that dusts high in calclte and low in quarts do not produce disabling fibrosis. The threshold figure of 0.15 milligram per cubic meter is given for lead dust, presumably litharge and white lead, or othei soluble lead salts. It should be noted that many of the data were not determined as the Medical requirement, but as being attainable in good practice and apparently satisfactory from a safety standpoint. It should be further noted that the accepted figures are only relative due to the indefinite powers of resistance of an individual which are an unknown quantity. One individual might resist a proportion of 200 particles per cubic centimeter, while another would react unfavorably to 50 particles. The work er's physical condition prior to the exposure is of great importance, since a young, healthy individual usually can stand a higher concentration or longer exposure before the first stage of silicosis is developed. However, far greater influence than physical condition might be the ability of the no6e and respiratory passages to ar rest dust. In their report to the National Silicosis Conference the Ccraaittee on Pre vention of Silicosis through Medical Control pointed out that since standards of safe atmospheric dust concentration, based on medical findings have been established for only a few industrial dusts, and in view of the fact that considerable study and in vestigation will be required to establish standards for other industrial duats, same tentative standard would be useful. It was also stated that this arbitrary standard should be based upon what is believed to be within the limits of good engineering practice provided, it will largely control the silicosis hazard for most industrial exposures. They, therefore, suggest that "The maximum permissible concentration of silica in the air breathed might be expressed by the following formula. (Determination of dust concentration according to technique described by United States Public Health service in Reprint No. 1520 from Public Health Reports. March 18, 1932)j Multiply the percentage of free silica by the total particle dust count. If the result is under 5 million, the condition may be considered permissible. If the result is over 5 a: llion, the condition, may be considered too high. For example. 10fC free silica with an average total dust concentration of 30 million particles per cubic foot would give .10 times 396334 STOOIZ93U I I f t c C t t C t t c c c c c c c c c c c c c f= -9- 50 million, which equals 3 million (good practioe)j 30^, with average total dust concentration of 50 million, would'equal ,3 times 50, or 15 million 9 (unsatisfactory). This formula is not applicable to any dust containing less than 6% free silioa. " Theodore Hatch fli his artiole "Some Fundamental Data on Mechanical Dust Traps" (Teoh. Pub, No, 63 7-A. 60, Amer. Inst. Min. it Met. Engrs. , Aug., 1935) gives these Safe Dust Concentrations. Impinger Samplest (Light Field, Low Power Counts.) Hind of Dust Maximum Permissible Concentration Containing no Silica.................................................. 60 millions per oubio foot Containing any small amount of silioa, free combined............................... 30 " "" " Containing 20 to 40 per cent. Free Silica......................................................... 10 " "* " Greater than 40 per cent. Free Silica......................................................... 5" "" " (Preferably as much less as possible) ST00I2939 Dr. R. R. Sayers, Medical Officer in Charge, Industrial Hygiene and Sanitation, U.S. Public Health Service in answer to a question as to permissible dustiness writesi "During recent years, it has been cus ternary to recommend threshold or permissible dust limits ranging from five to ten million partloles per cubio foot as determined by Public Health Service technique, especially with dust in which the percentage of free silica is above five per cent. There is no basis for the application of this criterion to all dusts, but it is generally considered a safe practice and one which can be attained in most industries by exhaust ventilation, wetting, or other methods of dust control." As pointed out by Drinker and Hatch ("Industrial Dust" - 1936) it is unforti*. nately impossible to evaluate dust exposures with the arithmetical nieety that we should have liked yet it is commonly olaimed - by laymen - that prolonged exposure to low concentrations is Just as serious as short exposures to heavy concentrations. This claim is oontrary to a fundamental law of physiology. In disoussing the sub ject Clark and Drinker ("Industrial Medicine" - 1935) remark that ".....a sub-thres hold stimulus (dust inhalation) for a long time produces no reaction whereas a rela tively brief super-threshold stimulus may cause a reaction". If workers are exposed to sudden heavy concentrations, the threshold values suggested previously would be correspondingly lowered. However, most threshold values are weighed -- an average of the ranges. 7 - HOW MAY TEE CONCENTRATION AND CHARACTER OF INDUSTRIAL DUSTS BE DETERMINED? The properties of a dust which determine its harmfulness have been shown to be its composition, concentration (the quantity suspended in the industrial atmosphere), its particle site. The methods used for the determination of the concentration character of industrial dusts vary from a routine dust tount for the purpose of evaluating the efficiency of dust control methods to a detailed study of both the concentration and the character of the dust in connection with medical and engineer ing surveys. 396335 -1D- The Impinger Apparatus developed at the United States Bureau of Mines, Pittsburgh Experiment Station by George Smith and Leonard Greenburg, (Described in Reprint No. 1528 from the Publio Health Reports Vol-47, No. 12, Maroh 18, 1932 pp. 654-675) has been employed for more than 13 years as a standard instrument for dust studies. In this apparatus samples of air are drawn into an lmpinger tube and flask where the dust partioles are thrown or impinged on a prepared wetted glass colleoting plate. The rate of air flow is fixed at one cubic foot per minute while the duration of the sampling period is dependent upon the dust concentration. The air passes through an orifice in the bottom of the impinger tube and strikes glass col lecting plate which is submerged in 3 cm. depth of distilled water or some other fluid with satisfactory wetting properties, (if water is used as the fluid in the impinger, silica particles are dissolved--hence not available for oounting -- unless the laboratory (counting) work is done within a few hours of taking the sample, ) This affords, the means for accurately determining the quantity and else of the par tioles. The liquid is then thoroughly shaken to obtain a uniform distribution of the particlesi filtered to remove those over 40 microns in size and again agitated. Samples of approximately 1 cc. are taken by means of a pipette and plaoed in Sedgwick-Rafter counting cells. The use of a suitable mlcrosoope equipped with a Whipple micrometer disc to aid in counting, will permit the determination of the number of particles in one quarter of the microscopic field. From this figure, the number of particles of dust in 1 cu. ft. can be calculated. One special advantage of this ap> peratus is the fact that analysis of the sample can be determined by counting, by weighing or by chemical analysis. The impinger method is neither simple nor extreme ly complex} however, reliable results can be obtained only by well trained, ocmpetent and experienced investigators. However, owing to the wide vise of the impinger in previous investigations that have been correlated with the pathological findings, an impinger should be used for any investigation which is to inolude pathological findings or where the results are to be Introduced as evidence in court. Same state oodes on dust control recognize the impinger method. The United States Bureau of Mines has practically completed the development of a "Midget" impinger which has most of the good characteristics of the impinger but lacks most of its drawbacks. This midget impinger will soon be available and will greatly simplify both sampling and oounting. Other devices are also available for sampling of dust over a continuous period, namely, the electric precipitator, the paper thimble, the electroBtatio preoipitator, and the hot wire thermal precipitator. The English are working on a dust sampling instrument which precipitates the dust fton the air by thermal means ("Physical Methods for the Estimation of the Dust Hazards in Industry", by H, L. Green H. 2. Watson, Privy Council, Medical Research Council, Special Series No. 199, His Majesty's Stationery Office, London, (1935)). The U.S. Bureau of Mines has been us ing an electric precipitator similar to those described by Drinker ("Alternating Current Precipitator for Sanitary Air Analysis} I - An Inexpensive Preoipitator Unit" by P. Drinker, Jour. Ind. Hyg. , Vol. 14, 1932, p.364) for collecting samples of the test suspensions used in testing mechanical filter respirators for permissibility. A number of instruments are available for makirg dust determinations for co&. trol purposes. Among these is the Konimeter which calls for but little skill in sampling. It is light, simple and quick to handle, needs no power for operation requires only a microscope for counting the particles. The Zeiss Konimeter consists of a microscope which gives a magnification of 200X, an air pump, a dust filter to remove very coarse dust particles, a sample disc and a micrometer ruled in square millimeters. The air pump drives a measured quantity of air against the sample diso which is covered with a sticky substance (glycerine jelly). This sample fo.*ma a dust spot which can be examined under the microscope for a general idea of the nature of the dust and the relative quantities present, or for an actual measure, a "dust count", which shows how rany dust particles are present in one oubio centimeter or in one litre of the air samples examined. The Konimeter has been used very widely in 396336 n n n n n n n n n n n n n n n w w nifiZinnis I I n 6 Z I0 0 1 S -11- South Africa (Pinal Report of the Miners' Phthisia Prevention Committee, Johannes burg, 1919, p.10) and also in Canada. The U.S.Bureau of Mines has also used it in some of its dust studies. In discussing the value of the Konimeter in their recent book "Industrial Dust" (McGraw-Hill Book Co., New York and London - 1936) Philip Drinker and Theodore Hatch of the Harvard School of Public Health writer "It .is the most compact and simple sampling device. Space is provided for thirty samples on a single diso and no auxiliary source of power is required for its operation. Grab samples can be collected with speed and the fluctuations in dustiness and the development of dust floods can be revealed in a way that is impossible with more cumbersome apparatus. South African experience involving the collection of thousands of samples has shown that the figure of merit given by the Koni meter is dlreotly related to the amount of phthisis - produc ing dust in the air. It is a valuable routine sampling in strument but because of its low and selective efficiency, the counts reported are probably considerably below the true level and they are not easily compared with data obtained in England, for example, with the Owens apparatus, or in the United States with the impinger." Experience has shown that contrary to Drinker's statement, the Konimeter if properly used, will give results that agree very well with those obtained by the use of the Impinger. The U. S. Bureau of Mines Experiment Station at Pittsburgh in maV-twg same comparative studies with the Konimeter and the Impinger found that an average of five Konimeter determinations was within about two per cent, of one impinger determi nation. The reason for taking an average of individual results obtained by the Koni meter, for comparison with those of the Impinger, is due to the faot that th Koni meter takes an instantaneous grab sample of small volumes and owing to the hetrogeneous nature of dust in air grab samples do not represent the average conditions. The Impinger takes a continuous sample of rather large volumes and is thereby representa tive of the average. For these reasons, if it is desired to compare Konimeter re sults with Impinger results it is necessary to take several Konimeter samples during the course of the Impinger sample, in order to obtain average conditions. We have no correlating information of the Konimeter with the 20 to 30 micron porcelain filter against the standard impinger method, A Zeiss Konimeter, using a 20 to 30 micron poroelain filter was used in making actual dust counts in our various dust producing operations. The partlole size and size classification was estimated rather than accurately measured and computed. Only particles ten microns or less in size were counted since it is generally agreed that dust particles larger than ten microns in size are not particularly pathogenic. Other methods in common use are the Owens Jet dust sampler ("Jet Dust Counting Apparatus" by J.S.Owens, Jour. Ind.Hyg. ,Vol. 14,1932,P, 522), which has recently been manufactured in this country and the photographic dust counter, developed by Ficklei and Ott. The Owens jet dust counter is used in this country to collect samples for particle size distribution determinations. It is used principally in Australia for determination of number concentration of atmospheric dust of industrial hygienic im portance. The latest device for determining dust concentrations is the Bausch 4 Lamb Dust Counter which vas placed on the market a few months ago. This instrument con sists of a dark-field microscope magnifying 200X, and an impinging apparatus mounted on a common base. The base is a hollow chamber with the bottom hinged to provide easy access to the dark field condenser and a circular glass specimen slide. Bymeans of a hand pump, which is part of the impinging device, a sample of air is drawn 396337 "STO O I 2 9 4 2 -12- ' through a moistening chamber which has at its lower end a narrow slit. The dust is deposited through this slit on to the circular specimen slide in the form of a ribbon. The slide can be rotated until the sample comes into proper position for viewing with the microscope, or a maximum of twelve samples can be collected on the slide and then viewed. The slides are quickly removable and replaceable. This dust counter is not designed for accurate dust determination but rather as an inexpensive devioe for roughly checking .dust conditions. It has not been available long enough for a thorough test in actual practice. The principal objection to instruments like the Bausoh k Lamb Dust Counter the Owens Jet dust sampler for determining number concentration is that their dust collecting efficiency decreases with an Increase in the atmospheric dust concentra tion and the fact that they take grab samples. Sinoe the major portion of dust present in industrial atmospheres is small enough to gain entrance to the lungs, very little attention need be given to determina tions of the exact sizes of particles. | f B B E E 396338 C C c c c c c c c c e -13- PART II - DUST PRODUCING OPERATIONS STUDIED / STOOI 2943 what ARE THE PRINCIPAL DUST PRODUCING OPERATIONS? - la order to determine to what extent if any, workers in the production of petroleum products and associated activities are exposed to the hazard of breathing dust, a surrey of all dust produo ing operations was made at the various plants concerned. These operations, listed in order of their' apparent degree of dustiness, are: I SAND BLASTING Due to the large amount of finely divided silica dust produoed by the impact of the grains of sand on the surface of the object being cleaned, sand-blasting is the most dangerous silicosis hazard encountered in our survey. Sand-blasting is used rather extensively at oil refineries for cleaning Inside soaking drums, bubble towers, tar separators, run-down pans and storage tanks for metal inspection nd to permit the application of gunite lining as a means of preventing corrosion. Header boxes or other similar parts, tubes in cracking coil fire boxes and return bends are sand-blasted to permit a detailed and thorough examination for cracks ti^ de fects. Sand-blasting is also employed in the removal of corrosion from under float ing roof tanks; for removing roughness or rust from steel shapes or rods; for oleaxw ing bell caps, bubble plates, trays, and pipe prior to putting them back in servioej also on the ends of tubes preparatory to placing them for rolling/ and for cleaning castings which are too large or fragile to withstand being tumbled. It has been used, to a limited extent for cleaning buildings and rendering window glass opaque.. The cracking coil tubes, pipe, bell caps, trays, header-boxes and similar ob jects are usually sandblasted out-doors in the open air or in a more or less open shed, both locations being as far removed as feasible from any shops, process units or other working places. Coarse river sand is discharged through a one-half to threequarter inch nozzle with compressed air under a pressure of 30 to 90 pounds per square inch. The men at the nozzles stand to the windward side of their work wear a "Healthguard" (Chicago Eye Shield Company) mask, a Sly Sand Blast Helmet or a Fresh Air Hose Mask covered with a canvas hood. The men at the Sand Blast Machines wear "Dust Safe" goggles and a M.S.A."Comfo" Respirator. The Mine Safety Appliances Company now has a sand-blast hood that is meeting with considerable approval by 4-n-- dustry and also by the United States Navy Departaaent, A blower is available for supplying air to these hoods that cleans the air. This same blower can be used in connection with air-line respirators. When sand-blasting is done inside of drums having more than one opening, such as soaking drams, an air siphon is placed in the lower manhole which draws out the dust and allows "a continuous circulation of fresh air through the drum. In drums where the siphon cannot be used, the air circulation is poor and the men work in shifts ranging from 30 minutes to an hour, depending on the size of the drum and the amount of air circulation inside. They also wear an approved sand-blast helmet. These sand-blasting jobs are not continuous routine operations but are per formed when necessary by men selected from the Common Labor gangs or the Mason's De partment. The work is rotated so that in most cases it occupies less than twenty per cent, of the worker's time and there is an interval of IS to 20 days between sand-blasting Jobs. Consequently, on the average, no one man is exposed to more than a combined total of 400 hours during the course of a year. In discussing rotation of men on sand-blasting jobs. Dr. Gehrmann, Medical Director of the du Pont Company wrote: " It r.us therefore, t be the borne in rotation mind that silicosis of men in this type is of a cumulative work cannot be disease and, considered 396339 -14- *1*162 I 00 JLS- as entirely preventive. Assuming that a nan works in an atmosphere of sil ica dust for several months, during whichtime he is bound to absorb a cer tain amount of the dust *iich produces permanent damage in his lungs; he is then removed and the possibilities are that the damage which is already done will be sufficient to continue on and progress to the point where in later years he will develop symptoms. "Therefore, if we take to rotating men in this type of work we are facing the possibility of, in later years, developing a large nunber of cases of a moderate silicosis with some permanent disability. The only safe expedient which can be used is complete prevention and this can only be done by eliminating the dust." During our survey we found that men engaged in sand-blasting, that is handling the nozzle or attending the sand-blast machine, were more or less properly protected while actually doing the work but often times they removed their protective equip ment before getting completely away fi*om the working area. A large amount of very small particles is produced by sand-blasting. In an analysis of dust samples collected both outdoors and indoors during sand-blasting, the following distribution (Public Health Bulletin No. 217 - p.52) an a size fre quency basis was foundt Size Group in Microns Per Cent of Total 0. 00 0. 49................................. ...................... 0.50 0. 99................................. ...................... 1.00 1. 49................................. ...................... 1.50 1. 99................................. ...................... 2.00 2. 49................................. ...................... 2.50 2. 99................................. ...................... 3. 00 3. 49................................. ...................... 3. 50 3. 99................................. ...................... 4. 00 4, 49................................. ...................... 4. 50 4. 99................................. ...................... 5.00 5. 49................................. ...................... 6.50 mm 5. 99................................. 1.4 19.7 34.7 20.3 12.6 5.2 2.8 1.6 1.1 0.2 0.2 While it has been estimated that free silica dust particles, 1 mioron in diameter, re quire 8 hours to fall 6 ft. in still air; particles 5 microns in diameter require less than 1 hour to fall the same distance. Considering this fact, it is apparent that the dust hazard from a particular operation may, even though carried out for short periods, be acute throughout the working day. In view of the fact that the con dition of still air is rarely, if ever achieved, and that dangerous particles exist in sizes below one micron, it is evident that a hazard exists. Fortunately most of the outside sand-blasting is done in more or less isolated locations which makes it rather improbable that there will be any unsafe silica dust exposure to other worlanen. However, should it become necessary for any work to be done in the vicinity of sand-blasting operations either on process units or the sand blast sheds or yards, it should be remembered that there may be silica dust in the air even though it can not be seen. i)ust counts as high as 5,344,160 particles ten microns or less per cubic foot were found in samples taken about 50 feet "downwind" (w-.nd blowing about 15 to 20 miles per hour) while sane-blasting cracking coil tubes; about 95,t of these dust particles appeared angular crystalline voider the Konimeter microscope ar.d were about five microns or less in size. Samples taken about 100 feet "downwind" from sand-blasting operation had counts as high as 1,812,480 particles tsar cubic foot. 396340 -15- ST00I2945 Dust counts as high as 13,933,440 and as low as 453,120 partioles per cublo foot were found in samples taken during the filling of the Send Blast Machine feed hoppers. The high counts were found when sand was shovelled into a small circular screen and shaken by hand, the lower counts, when the sand was simply shovelled ix^ to the hopper. The average dust produced by filling or charging the Sand-Blasting Machines was 4,950,316 particles, ten micrcns or less, per cubic foot. Dust counts as high as 4,954,320 particles, ten microns or less, were foimd in samples taken insj.de a Sand-Blasting Room while cleaning castings. The average dust in this room during sand-blasting was 3,873,625 particles per cublo foot. About 80# of these particles were angular crystalline three microns or less in site and about 20# appeared rounded, quartz-like crystals about ten miorons in size. There were a few rust-like scales over ten microns in size and a very large number of minute dark metallic particles too small to be counted accurately. The dustiness of this^opertution could be greatly reduced by the use of steel abrasives exclusively. All of the samples for dust counts referred to above were taken at face level in the vicinity of workmen. 6,000,000- dust particles per cubic foot is the tentative maximum allowable limit of dust particles containing free silica of a size less than 10 microns reo<s>> mended for sand-blasting. U - FILTERING OPERATIONS The process of filtering is extensively used in the refining of petroleum products to improve the color stability and to remove impurities from motor lubri cants and paraffine waxes. The three materials most commonly used for this purpose are Filter Clay or Fullers Earth, Contact Clay and Bone Black. Considerable dust is produced by the handling, charging and reconditioning of these materials. A - FILTER CLAY CR FULLERS EARTH: What is Filter Clay or Full era Earth? Filter clay camnct be identified from chemical composition but consists of silica, alumina, iron and alkaline earths in varying percentages. The distinguishing properties are lack of plasticity and the power to remove color from oils. There are numerous deposits of this clay and other filtering earths in the United States; the oldest and among the most extensive are those foimd close to the Florida-Georgia line. One of these, at Attapulgus, Georgia, supplies a major portion of the clay used by the affiliated Standard Oil Company (New Jersey) organizations. At the mine this material contains on an average approxi mately 32# silica and 45# moisture. The average composition after being processed and prepared for- shipment is approximately* S102....................................................... Al20g..................................................... Fe203..................................................... MgO......................................................... Combined Moisture........................... Free Moisture................................... 67.46 per cent 10.08 " " 2.49 " " 4.09 " " 6.61 " " 6.28 " " The comparatively low dust counts found even in places where there was cleaning and sweeping is no doubt due to the fact that this filter clay is of a rather coarse na ture and without apprecieble amount of fines. There appears to be a wide variation in the composition and free silica con tent of filter clays used in European refineries. "Torrana" a German Filter clay used in Poland shows: 396341 9 *16 2 1 0 0 1 s -16- Lobs In calcination.......................... .. 6.05 per cent Tree Silich (Si02)................................ 83.27 " " AI2O3 and FC203...................................... 8,27 " n The filter clay used in Rouoania is reported as having 60.4 per cent, free silica or 75.3# total silicates. "Granosil" clay used in Belgium contains A total percentage of 73-1/2 per cent, of silicates expressed as Si02. The percentage of free silica was not determined. How is Filter Clay Mined and Prepared? - The deposit varies from 2 to 12 feet in thickness, probably averaging about 7 feet. There is an overburden of about 35 feet which is removed by an electrically operated drag line or a steam shovel. The clay is loaded into small cars, transported to the wet clay shed where it is dunped on to the drying floor and dried for three days. It is then pioked up by orange peel buckets, loaded into portable distributors and delivered to belt conveyors which dis charge the earth into roller crushers where it is reduced to sizes up to a maximum of two inohes. From these crusher* the clay goes to secondary crushers where it is re duced to a maximum of one inch. Since the clay is more or less damp very little dust is produced. The clay is then transferred to tandea oil-fired rotary dryers, 50 to 60 feet long and six to seven feet in diameter. In the 20 minutes required for the clay to pass through the dryers the volatile and moisture content is reduced 40 to 50 per cent, to a maximum of 15 per cent. The average dust ten microns or less in size in samples taken at various points around the dryers and conveyors was 1,564,969 particles per cubic foot. This rather low dust count is the result of the installation of hoods with ducts to exhaust fans plaoed over the discharge pointsto the conveyors or elevators. About 85# of these dust peLrtioles were angular crystsdline in appearance under the Kor.imeter microsoope and about five microns or less in size) about 15# were aver ten microns in size. The larger particles had rough edges and appeared to contain several small air bubbles. The clay is removed from the dryers to hot rock cooling tanks, then to a vibrating screen. The oversize is next pulverized in a roller mill and the product conveyed to a sifter. An exhaust system for the mills and elevators has been installed. This process may be repeated until the desired size material has been obtained and graded to standard mesh sizes, the better known of which are 15-30, 30-60, 60-90, and the 200 mesh. The 60-90 grade is probably the most commonly used in the petroleum industry vrhen decoloring by percola tion, and the 200 when contacting. However, the 30-60 is preferred by most of our refining units in the United States. The size selected is apparently determined largely by the type of reburning equipment. Screen tests are made hourly to insure that the sizes are within the specifi cations. Here -are two typical screen analyses* 30 - 60 GRADE FILTER CLAY Mesh Per Cent. Over 30........................................................... 30 - 40......................................................... 40 - 60......................................................... 60 - 82......................................................... Thru 82........................................................... 9. 7 47.5 40.3 1.5 1.0 Total 100.0 396342 -17- FIIJES (100 - up) GRADE FILTER CLAY Mesh ' * Per Cent. Over 97............................................................ 97 - 157....................................................... 1K7 - 200....................................................... Thru 200.......................................................... 0.6 22.7 8.0 68.7 Total 100.0 There is very little dust produced by the sifting operation. All of the ooa>> nections are designed to be dust tight but there is some leakage. Samples of air taken at various points around the sifters while in operation had an average of 2,1:08,960 dust particles less than ten microns per cubic foot. About 85# of these dust particles were slightly angular crystalline in appearance and five microns or less in size; about 15% were slightly rounded semi-opaque ten microns or over in size. The larger particles had small cracks or fissures and several small air bubbles. Men spend about two hours a day cleaning, repairing or replacing silk screens in the sifters. Samples taken during this operation contained an average of 2,039,040 dust particles less than ten microns per cubic foot. About 97# of these dust particles were angular crystalline in appearance and five microns or less in size; about 3# were opaque over five microns in size. After being sifted and graded the clay is ready for shipnent. The 30-60 mesh grade is placed in burlap bags holding 128 pounds and loaded into railroad box oars; about 400 bags to a car on an average. Dust counts of samples taken during the fill ing of the bags with the 30-60 mesh grade show that there are tram. 7,589,760 to 9,968,640 dust particles less than ten microns per cubio foot i&leh indicates that all men engaged in bagging and handling bags in this area should wear approved respi rators such as the "M. S. A. Comfo". About 80% of the dust partloles in samples taken during the filling and handling of the bags appear slightly angular crystalline under the microscope and are five microns or less in size; 20# are rounded crystalline, ten microns or over in size. Bulk Loading of railroad box cars with the 30-60 mesh grade produces clouds of dust, but a major portion of this dust is apparently larger than 30 microns in size as samples taken during this bulk loading had an average of only 6,853,440 particles, ten microns or less in size per cubic foot. The Fines.(100-up) grade is put into 128-pound cotton bags. Dust counts in samples taken during this operation showed that there were from 4,644,480 tol4,216,640 dust particles less than ten microns per cubic foot in the air being breathed by the fillers, weighers, sewers and truckers. About 80# of these partioles were rounded, semi-opaque crystalline in appearance under the Konimeter microscope and five microns or less in size; 20# were semi-opaque crystalline from about seven to fifteen microns in size. There were also a large number of very small particles about one micron or less in size. How is Filter Clay Used? - Upon arrival at the refinery, the bags of clay are removed from the box cars by a crew of men usually from the General Labor Department) the job being rotated so that the same men do not do this particular operation more than perhaps twelve hours twice a year on an average. Goggles and "M. S. A. Comfo" respirators are generally provided. The clay is either trucked or dragged to an elevator or conveyor hopper and dumped and the baps are piled for storage. At points where the clay is received in bulk, it is unloaded by a large wooden scoop pulled by a motor driven drag-line. Unloading, handling, and dumping the clay is one of the 396343 -18- c dustiest parts of the filtering operation. The amount of dust produced is of course dependent on how the work is dcfae, the ventilation provided, and the care used by the men doing the Job. Here are same average dust counts of partioles less than ten adcrons in samples taken during the unloading of bags of 30-60 mesh Attapulgus clay Particles Per Cubie Foot Unloading and disnping bags (128 lbs* ) into Hopper at a Southern Refinery............................................... Dumping clay from Bags into Elevator Hopper at a Northern Refinery................................................ Handling bags from Storage and Dumping into Elevator Hopper at another Northern Refinery........................ Inside Box Car During Unloading................................................ ............................ Outside " " " !I In Filter House Passageway being used to Truck Clay to Elevator hopper........................ Average Dust Produced while sweeping up inside car after unloading................................................................. 6,403,466 2,237,280 755,160 1,110,144 372,924 339,840 651,360 Apparently unloading clay in the bulk is less dusty than handling and dumping of the clay in bags. Samples taken during the unloading of bulk clay gave these average counts of dust under ten microns in sizer Inside car during unloading......................................... 962,880 partioles per cubio foot Outside " " " .............................................. 623,040 " """ There is of course more dust produced in the vicinity of bulk unloading than is pro duced when handling and dumping clay in bags. After dumping, the new clay is taken by elevators and conveyors to storage bins which hold about 20 tons each. This is also a dusty operation due to the failure to cover the storage bins or to place hoods over the Junction points of elevators nri belt conveyors. Samples taken during the filling of storage bins with new clay had these average dust counts of particles less than 10 microns in sizet Dust over Bins around elevators and conveyors during filling at a Northern Refinery.................... "n "4 Conveyors while filling at another Northern Refinery....................................................................... "" " 4 Conveyors while filling at a Southern Refinery.......................................................................... " Pace Level on Walkway over Storage Bins Northern Refinery while Filling Bin..................................................... 1,910,432 4,275,842 4,531,200 2,307,776 Dust Counts as high as 8,609,280 particles per cubic foot were found in Bamples taken near the discharge of one belt conveyor into the top of a storage bin. About 90% of these dust particles appeared angular crystalline under the Konimeter microscope and were five microns or less in sizej about 10# were black, opaque, many scale-like in appearrnce and ten microns or over in size. "BURNING" CLAY - From the storage bins the clay is conducted by chutes and/or conveyors and elevators to gas or oil fired Wedge Burners or Rotary Burners or Kilns in which it is "burned" or roasted, and then discharged into rotary ooolers where it is cooled. 'Where all openings, chutes and elevator outlets as well as the ends of rotary coolers are properly enclosed and an exhaust duct is placed over the burner, very little dust (an average of only 604,160 particles, ten microns or less in size GO a CD PO GO CO WZ c c c 1= c c g C C -19- 6 k7 inn i^ per cubic foot) is produced and no respiratory protection is necessary. Three types of burners or kilns are used to recondition filter clay. Average dust counts of samples taken during the operation of these burners give a comparison of the amount of dust (particles ten microns or less per cubic foot) produced by each: Type of Furnace Feeding About Furnace Coolers Total General Average Hermaj^Frasoh Oil or Gas Fired................. Wedge Gas Fired. Rotary .... 2,624,320____ 5,399,680____ 2,067,360.... 3.700.480.... 1.522.459.... 1.070.046.... 2.732.880..... 2,108,590.......... 3.115.200..... 2,990,542 2,395,971 1,818,206 The present practice of using a compressed air hose to clean up the clay on the various floors of the Furnace House at one of the Refineries is particularly o^ Jectionable due to the excessive dust (12,687,360 particles ten microns or less per cubic foot) which is stirred up. About 90?. of the dust particles in samples taken during the burning of filter clay were angular transparent crystalline in appearance and five microns or less in size* 5^ were round opaque, ten microns or over and 5% were rounded semi-opaque, ten microns or over in size. Exposure to dust produced by burning or reconditioning clay is rather limited. Usually there is one fireman for each shift of eight hours, three shifts per 24 hours nd a porter for the day shift only. Since one of the porter's main jobs is to "clean-up" he is exposed more continuously to dust than are the firemen. CEARGING FILTERS - The cooled, burned clay (30-60 grade) is conveyed to the filters by means of elevators and belt conveyors and charged through chutes fi*om the conveyor belt tripper at a rate of from one and a quarter to eight tons per hour. These vessels hold from seven to fifty tons each. The amount of dust produced during the charging operation depends upon the grade of clay being handled, the'rate of charging, the position of the clay on the conveyor belt, the condition of the convey or belt, tripper and charging chutej also whether the top manhole of the filter is left open during the filling. A general average of 54 dust counts made of samples taken during the charging of filters at all of our plants using 30-60 mesh Attapulgus Filter Clay was 3,717,884 particles ten microns or less in size per cubic feet. The amount of dust produced by the charging operation varies considerably at the various plants as is shown by these averages: Refinery Charging Rate Particles per cubic foot Baton Rouge Bayway Bayonne Eagle Works 8 tons per hour 1-1/4 3-1/2 n n tt n tt n n tt n 4,271,413 2,435,520 2,242,944 1,042,976 It is the general belief that the more times a clay has been used and reconditioned, the less dust is produced during its handling. Our study does not confirm this be lief as applicable to dust produced while charging filters. Averages of dust counts in samples taken during this operation were: # 1 Clay..................................... # 3 " ..................................... if 10 " ..................................... 2,242,944 particles per cubic foot 4,604,832 3,896,832 " "" " 396345 -20- According to an analysis of particle sire made by the Bayonne Laboratory of a sample of Raw (30-60 grade Attapulgus Clay) No.1, No, 3, and No. 8 Wedge clays, the following is the sire classification or distribution Raw Clay #1 Clay #3 Clay #8 Clay Coarser than 100 me<h 98. 5#................... 99. 4%................... 98. 7#................ 98. 3# Diameter of particles Raw Clay #3 Clay #8 Clay Millimeters Microns Per Cent Per Cent Per Cent .149 to .074 .074 " .044 .044 " . 035 .035 " .025 .025 " .015 .015 " . 005 .005 " . 001 149 to 74 74 ft 44 44 n 35 35 n 25 25 n 15 lb n 5 5 rt 1 0.14355 0. 55095 0. 29760 0. 21555 0.17550 0.11640 0. 00045 1.00750 0.17186 0.05369 0.03887 0.01729 0. 01027 0.00052 0. 54159 0. 06449 0. 04585 0.01603 0. 00847 0.00336 0. 00021 About 85/S of the dust particles in samples taken during the charging of #3 clay were slightly angular in appearance and five microns or less in sirej 15# were rounded semi-opaque, ten microns or over in sire. About 75# of the particles in samples taken during the charging of 7/IO clay were slightly angular crystalline, five microns or less in sirej about 20# were over ten microns in sire and were semi-opaque about 5# were round semi-opaque between five and ten microns in sire. All of the larger particles appear to contain small bubbles. There are numerous small black specks about one-quarter micron in sire. Charging of filters is usually done by one man per shift for each filter house. There are three shifts a day. These men have an average service of about 20 years and work eight hours a shift, nine shifts out of fourteen. Ventilation is provided in the newer filter houses by eighteen-inch roof ven tilators extending about twelve inches above the roof and also by windows which 60cupy about 80# of the wall space in front of the top of the filters. DUMPING FILTERS - After the filters are charged with clay they are plated up and the oil is allowed to percolate through the clay for several hours, the length of time depending upon the nature of the oil run and the "yield" of the clay. The oil is all drained off and the clay is then washed with naphtha or "Varsol" and steamed to remove all trace of the naphtha. After this the filter is dumped on to a canvas belt conveyor and the clay returned to the kiln for burning or reconditioning. Filter clay is used as many as fourteen times before it is finally discarded. In order to determine what effect the reconditioning of filter clay had on its free silica con tent samples were analyzed by the New York State Department of Labor, Division of In dustrial Hygiene with this result* Times Eurned # Free Silica Raw Clay................................. Once......................................... Three....................................... Eight....................................... 6. 30 6.50 1. 20 9.30 Considerable steam is usually given off during the dumping which probably 396346 K K K nr CO --\ CD a no CD cn CD IE C E i % C c (E 1C c c c ic c c c c -21- { explains the smaller dust count (a general average of only 2,518,781 partiolea ten microns or less in site per cubic foot) than would be expected. The dustiest part of the filter dumping operation Is sweeping up the floor under the filters after dumping is completed. Samples taken during this sweeping or cleaning up had as high as 16,538,880 particles per cubic foot, although the general average of samples taken during dumping at the various refineries was 2,514,816 particles per cubio foot. About 95# of these dust particles are slightly angular crystalline in appearance under the Konimeter microscope and are above five miorons or less in size) about 5% are rounded semi-opaque over five microns in size. Occasionally the clay doesn't "flow" when the filter is opened' and must be started "flowing" by means of an iron bar. This aotion causes some dust (2,888,640 particles per cubic foot) but not as much as pounding the bottom and lower sides with a sledge (4,248,000 particles per oubio foot) as is sametimes done. After the clay has run out, the Inside of the filter is swept out with a broom which produces a little dust (an average of 792,960 particles per cubio foot). The filter is then plated up and is ready for recharging. ST00I295I The work of dumping filters is done by one man per shift, for eaoh filter house. These men have an average service of about ten years and work eight hours a shift, nine shifts out of fourteen. They are exposed to dust less than 60 per cent, of their working time. Spent clay is used to a limited extent for packing around valves rid fire hy drants to prevent freezing) also for certain other small absorbing Job such as on the warehouse floors of seme of the larger bulk sales plants where lubricating oils are transferred from barrels or drums to smaller containers, or loaded into five gallgn cans from bulk. Most of the spent clay is disposed of, however, by dumping it on nearby Company property and, to a lesser extent on railroad property near river banks. Composition of Filter House Air Borne Dustt Samples of dust from Attapulgus Clay, which had settled on the tops of elevator housings and on girders over the storage bins in filter houses, were submitted to the United States Bureau of Mines Ex periment Station for petrographic examination. Ordinarily positive results are not obtained In petrographic tests for the identification of minerals in atmospherio dust. However, the samples submitted were coarse enough to give results in most oases. In studying the results of the petrographic examinations it should be borne in that the samples submitted were settled dust, and that they are not representative of the composition of the dust that would be breathed generally owing to the differential settling rates and the ease with which the various mineral constituents oan be crual^ ed to a powder. "Montmorillonite" ((Mg, Ca) 0.A12 03. 5Si 02. nH20 -- n6to8)isthe miner al that is characteristic of many types of fullers earth. Not all of the less important minerals found were fully identified. Clay dust from top shell of elevator - Top #2, Herman-Frasch Furnace. Quartz - 10# Montmorillonite - 80# Calcite, Microcline and Unidentified - 10# Dust from accumulation on girder over clay storage bins - #4 Filter House. Quartz - 10# Montmorillonite - 70# Possibly other clay minerals present, opaque - 20# Dust from accumulation on girder over clay storage bins - #1 Filter House. Quartz - Over 1# Opaque - 40# Montmorillonite - 55# Unidentified - 5# 396347 ST00I2952 -22- Control of Filter Clay Dustt Dust in a filter plants results principally from the operation of the clay handling machinery. The condition is aggravated by the present practice at some refineries by using an air hose to blow accumulated dust and spilled clay from equipment, walls and floors. Handling a fine light dust producing material, such as filter clay, in a system which includes open belt conveyors is in^ herently a dusty operation. (12,687,360 particles, ten microns or less in size, per cubic foot). It is difficult to prevent some dust fVan being generated at unloading points where the-clay falls into chutes or bins, but it can and should be controlled by means of hoods*, enclosures, and adequate exhaust systems with effective dust oolleotors. There will alv.ays be cm irreducible minimum of spillage and dust settlement wherever dusty material is handled in systems such as exist in most refinery filter houses. This is an economic waste and Increases the difficulty of the dust control problem. Unless the present practioe of cleaning dust spillage by blowing with eaapressed air is changed, the necessary periodio cleaning will continue to be a very dusty and unhealthful operation even though all precautions have been taken to pre vent the escape of dust from clay handling equipment. A modern industrial vacuum cleaning system would do the job efficiently, without creating any dust. The principal source of dust in filter buildings is the belt conveyor vdiich is usually located at the top of the building. Gusts of wind from the monitor blow the day and dust from the belt. A certain amount of dust is also generated by clay fall ing into the tripper chute (6,060,480 particles per cubic foot) and discharging from the tripper chute into the chute leading to the various filters (7,306,660 partioles per cubio foot). This could be considerably reduced by inserting canvas or sheet iron connections between the ends of the tripper chutes and the chutes to the filters, and by using a properly designed belt tripper on the conveyer belt. Bins for the storage of filter clay should be closed with steel decks having the smallest possible openings in the form of chutes to receive clay from the oonveyers. If care were taken not to overflow the bins, the dust and spillage could be greatly reduced. For complete control of dust, an exhaust system equipped with dust collector, fan, ducts and hoods should be installed to remove dust from the points of origin, such as, all unloading points (except movable trippers) of each belt conveyer in the building, new clay bins and burned clay bins. One estimate which has been prepared for such an installation calls for an exhaust system with a capaoity of appropriately 15,000 cubic feet of dust laden air per minute, and is based on maintaining an inward flow of air at openings into hoods and bins at a recommended velocity of 200 feet or more per minute. -In considering dust collectors, it should be borne in mind that the cyclone type will not remove the fine dust particles (ten microns or less in size) which are most injurious to health, and that the cloth bag type filter has been proven to be more successful in removing these fine partioles. Under existing conditions at most plants it is almost impossible to keep the plants clean, regardless of how carefully the equipment is operated. However, the in stallation of a vacuum system and adequate dust collectors should encourage operators to exercise more care in the operation of equipment and thus cut down the amount of dust and spillage. B - CONTACT CLAYi i Host contact clays, particularly in the United States, are acid treated "Ben tonite". Bentonite is a non-refractory clay, a double silicate of iron and aluminum, derived from the shale of the Fort Benton formation in the upper Missouri vallev. 396348 -23- ST00I2953 There appears to be a wide variation in the exposition and free silica con tent of American and European contact or activated clays. "Filtrol" an extensively used American contact clay id reported to contain about 67# free ailioa (silioa which is insoluble in concentrated hydrochloric aoid). "Milwhite", another extensively used Ameriean contact clay, contains 65# free silica. The contact clays listed are those most extensively used in Europe* Insoluble in Insoluble in Canoentrated ~ Concentrated HCL HCL and 6# KA? CO3. "Ivry" Clay (French).............. "Terrana Extra" (German).... "Clarit" (Italian)................... 76.0#........................... 64.4#......................... 49.5#........................... 64.6# 27.2# 60.6# "Tonsil AC", another FVench oontact clay, has 61.75# free silioa. The main constituents of "Petrisil", a German contact olay, are* Total Silica................................. 61.57# Lime (CaO)...................................... 0.63# Aluminum and Iron Oxides.... 18.83# Loss on Ignition (Water).... 23.62# The balance probably consists of potassium and sodium oxides. The following is the result of a petrograph!0 examination of "Petrisil" which was made at the United States Bureau of Mines experiment station* Quartz................................................. 6# Montmorillonite........................... 90# Unidentified Minerals................ 6# The use of contact clay for improving the color of lubricating oils is a reoent development. At present the price of contact clay is so low that it is used only onoe then discarded. Although there are many contact clays on the market, a large percentage of that used by the Standard group is known as "Filtrol", consequently this was included in our dust studies. What is "Filtrol" and How is it Produced? "Filtrol" is a pulverized acid treat ed Bentonite, used as a decolorizer, absorbent and deodorizer in the refining and preparation of both organio and inorganic oils. It comes fVom "open cut" mines in Mississippi and California, and occurs in beds about two and one-half feet thiok under an over-burden of some eighteen to twenty-five feet. There has been some doubt as to its origin, but it is now believed to have been voleanic dust transported by the air and deposited under the waters of either a lake or a sea. Raw Bentonite is mined and loaded onto trucks with steam shovels, and then taken to the preparation plant. A tractor scoop lifts the raw material from the storage shed floor and plaoes it in a hopper out of which it is fed into an elevator by means of a steel pan feed- . er. The elevator discharges into a crusher which breaks the material down sufficient ly to enable it to pass through a screen (three meshes to an inch) onto a belt con veyer which takes it to a pre-mixer where it is mixed with water to form a "slurry". This slurry is passed into large wooden tanka and treated with dilute sulphuric .*. 396349 -24- agitated with air and steam. It is then dumped into thickeners, washed, and deliver ed to an Oliver filter. From there it goes in turn to a pug mill, drying tower, cage and imp mill, and classifier. ' The finished product is placed in a bin where it is put into fifty pound Bates Valve paper bags by means of a Bates Bag Packer. It is shipped in railroad box cars, each having a capacity of from 1600 to 2000 bags. The three grades of "Filtrol" in greatest demand are* c c t t ST00I2954 GRADE (Per cent, thru 200 mesh) 86 - 88 76 - 88 90 - 93 Per cent, of Total Production 80 15 5 Coarser Than 200 Mesh 14.0* 23. 0* 8.0* 200 - 325 Mesh 16.0* 24.0* 23.0* Finer Than 325 Mesh 70.0* 63.0* 69.0* The only real dust producing operations in the production of Filtrol are the filling, stacking and handling of the fifty pound bags. Samples of dust taken during these operations, revealed the following* c c Operation Particles per cu ft. t Average dust filling bags with 85-88 grade " " packing room while filling bags " " produced in handling of filled bags 10,416,096 9,572,180 5,845,248 c s An exhaust system has been installed to reduoe and control the dust produced during the packing of Filtrol. This consists of a metal hood above the filling tubes in front of the machine, with a basin below. A seven-inch duct leads from the basin and a six-inch duct to a canopy in back of the packer, both connecting with a teninch main duct vdiioh runs to a Sturtevant Fan (1750 R.P.M.) designed to handle 1,620 cubic feet of air per minute against four-inch water static pressure. A cyclone dust collector removes the larger particles from the air before delivering it to a tubular doth dust collector. About sixty per cent, of the dust particles of samples taken during the fil ling operation are slightly angular crystalline in appearance under the Konimeter mi croscope, and are about two microns or less in site} approximately twenty per cent, appear to be rounded crystalline, gla6s-like, but with rather smooth edges, and over ten microns in size. There are a large number of very small gray partioles (about twenty per cent. ) too minute and too numerous to count aoourately. c c c c c c c c What-is the Chemical Composition of "Filtrol"? Below is the result of an an alysis by a commercial chemical laboratory in Los Angeles, California, of a sample of Filtrol from the Jackson (Mississippi) plant-* c c Per Cent. c Silica (Si02)........................ Alumina (A1203).................... Ferric Oxide (Fe203)......... Titanivan Oxide (Ti02).... Calcium Oxide (Cal)........... Magnesium Oxide (MgO).... Manganese Dioxide (MnOj)Carbon Dioxide (COg)......... Potassium Oxide (KgO)**** 56. 90 13. 97 1.44 0. 10 2. 82 3.55 - 0. 03 396350 C C "c c c E -25- ST00 I 2955 Per Cent. Sodium Oxide (Na20)............................................. Chlorine (Cl).......................................................... Phosphoric Anhydride (P2O5)........................... Sulphuric Anhydride (SO3)............................. . Total ignition loss............................................ -fVee Moisture......................................................... 0.04 0.63 20.00 12.23 "It is customary to separately report materials such as Silica (Si02) and Alumina (AI2O3) in ultimate analysis although the elements are known to be in combination with one another. It is difficult to get ar. analysis of free Silica, and since the quantity contained in Filtrol would be very small, we have not attempted to have this par ticular analysis siade." The following is the result of an analysi: of "Super-Filtrol" which was made in Frencet Per Cent. Moisture at 120 degrees C............................. 16.6 Loss on ignition........................... ..................... 33.5 Insoluble in concentrated KCL..................... 55.0 (Total Silica and unattncked crystals) Insoluble in HCL and in a 5% Na2C03 solution. 15.0 (Siler, quartz and unattacked crystals) A microscopic examination shows a few particles with "acute angles". An examination made by the United States Bureau of Mines Experiment Station in Pittsburgh, Pennsylvania showed that Filtrol contains more than 1% quartz, 95% Montmorillonite ((Mg, Ca) 0. Al203-5Si02-nH2&--n-5 to 8) and 5% unidentified minerals. A similar examination of Attapulgus Fines (200 mesh) showed 5% quartz and 95% Montmcril Ionite. How is Contact Clay Used? The clay is mixed with oil, agitated and heated, and either allowed to settle or run through a filter press. It is then discarded. The clay is either dumped directly into the oil or placed in a hopper from which it flows into ird'ioi ors or mixing chambers where it is mixed with the oil and then pumped to a filter tank. . The only dusty operations are the unloading of the material and dumping it into the hoppers or nixing chambers. The higher dust counts with the contact clay as compared to filter clay is probably due to the fact that it is a finer material, or at least disintegrates more easily than the filter clays studied. Samples taken during the dumping of Filtrol and Attapulgus Fines into a reaotion chamber gave the following dust counts. Operation Particles per cu. ft. Avornse cust produced while dumping 50 pound bags of "Filtrol"....................................................... 6,768,480 Average dust produced while dumping 100 pound bags of "Attapulgus Fines"................................... 9,260,640 396351 -26- ` Under the Konimeter Microscope the particles were rounded in appearance. The "Attapulgus Fines" appeared more crystalline and angular, and had a greater proportion of particles fire microns or less in size than did the "Filtrol", The counts indicate that more dust results from dumping Attapulgus Fines than from dumping Filtrol aotivated clay. Dumping fifty pound "bags of "Wilwhite" (90# through 200 mesh), a Texas contact clay, into the feed hoppers to the inductors or mixing chambers is an exceedingly dusty operation. .Samples taken during this operation had as high as 14,046,720 par ticles ten microns or less in size per cubic foot. Samples taken in the middle of the roam just after thirty bags had been dumped into the hopper had 55,847,040 par ticles per cubic foot. Under the Konimeter Microscope, about 90# of these particles appeared slightly crystalline, and were five microns or less in size; 10# were round, semi-opaque, ten to twenty microns in size. There were also a few scale like par ticles. Fourteen men with an average service credit of six years are involved in this operation. Three men are exposed to the dust during six hours of each eight hour shift for nine of the fourteen shifts during the 85# of the time the filtering plant is in operation. They wear H. S. A. "Comfo" respirators. After extensive study and investigation the local management has made arrange ments to receive the clay in tank cars similar to those manufactured by the General American Tank Car Company. These cars are self-unloading and will discharge into an enclosed hopper. The clay will then be transported to storage bins by means of ft * screw conveyor completely enclosed in ten-inch tubing. It will be w- -awn from the bottom of the bins, passing through weighing scales, into the inducts. iere it will be mixed with the oil. This will provide a completely closed system ana should eliminate all air contamination. C - BOUT BLAC7. CK CHAFUZD BOlEi Refined wax is filtered through bone black or charred bone to improve its color. This material is obtained from various meat packing firms in finely woven cof fee bags that hold about 150 pounds each. An open belt conveyer and elevator carry the tone directly from the reactivating furnace to the covered filter charging hopper. Metal chutes lead directly from this hopper into filters which hold about 3,000 pounds of bone black. Upon completion of filtration the bone is washed with "Varsol", steamed for about 24 hours, washed with hot water, steamed for two hours more, and then dumped upon belt conveyers which carry it to the reactivating furnace which is gas fired. The bone goes through the furnace at a temperature of about 1100 degrees Fahrenheit and at the rate of about 250 pounds per hour. Bone black oan be used over and over again. Three men one on each shift, with an average service credit of fifteen years, are engaged in this operation. Their period of exposure to dust is about one hour per shift. The greatest amount of dust produced results from the open conveyers, particularly in dumping the material from the furnace onto the conveyer belt. Samples taken during this operation had as high as 11,044,800 particles of ten microns or less in size per cubic foot. Considerable dust (14,273,280 particles per cubic foot) also arises from the open hatch of the filter charging hopper during filling. An eight-inch motor driven exhaust fan has been installed to suck back the dust from where the elevator buckets dump the reactivated bone into the chute to the charging hopper. The dust loss from this filtering operation is estimated to be about 1500 pounds per month. Under the Konimeter Microscope about 65# of the dust particles of samples taken during the reactivation of bone black appear to be black, opaque, scot-like, and are five microns or less in size; 5# are rounded, seni-opaaue, ten microns,or more in size. The angular crystalline and light grey particles which constitute about 30# are probably 3ST00 I2956 01 u u U~TJnrU ITU u y u y u U IC iE (C (C bone ash. -27- > ST00 I 2957 Ill - INSULATING OPERATIONS Insulation plays an important part in the processing of petroleum produots. The two types of Insulating material most frequently used are "Sponge Felt" (asbes tos with ground! sponge to give dead air space and thus inorease the effectiveness of the insulation) and a mixture of 85# magnesia and 15# asbestos. Rock wool is used to a considerably lesser degree. In the ordinary cannr.ercial fora. Rock Wool, as used at our refineries, does not present a dust hazard. It is also used for house insulation, and is available in small nodule form which can be blown into place. "85# magnesia" is a mixture of magnesia and granulated asbestos and pressed into blocks of various sizes and shapes (usually 16" x 16" x 1-1/2"). The most dust comes from dismantling old Insulation and grinding scrap material for use as a plas ter or "ganiater". The average service of men engaged in Insulating operations is about fifteen years. Most of these men have been transferred from the Common Labor Department. They work nine out of fourteen eight-hour shifts, in gangs of from two to six men, and are actually exposed to dust for less than sixty per cent, of their working time. Goggles are sometimes provided, and occasionally MSA "Ccmfo" Respira tors, but this equipment is not used as muoh as it should be. Generally speaking, about 65% of their work is with sponge felt and 15% with 85# magnesia insulation. At one of the larger southern refineries about 300,000 square fee$ of sponge felt and 50,000 square feet of 85# magnesia are handled a year. A - What Physiological Reactions are Provoked by Instil ating Materials? According to Dr. Leroy U. Gardner (Journ. Indust. Hyg. Mar, 1937,Vol. 19, No. 3, P.121) asbestos dust with its fibrous particles does not seem to be readily handled by the protective meohanism of the lungs. Quoting from his articles "They are not removed to the lymphoid tissue but remain in o ontact with the delioate walls of the air spaces. They beoome surrounded by an iron-containing coating that fractures and gives rise to the pecu liar structures known as 'asbestosis bodies'. The fibers are irri tating, perhaps because of their fora, and they excite a fibrosis which begins about the terminal bronchioles and spreads to fora dif fuse patches in the parenchyma. Often the distribution is sub-pleural. In the presence of infection, the reaetion to asbestos dust is muoh more severe than that caused by the dust alone." There is nothing in the pertinent literature, nor does the Bureau of Mines know of any evidenoe, which would demonstrate magnesite (a natural magnesium carbon ate ) to be harmful. It would fall in the class of "nuisance dusts" such as gypsim. While many of the so-called "nuisance dusts" have never been found to be harmful, it is the opinion of most investigators in the field of industrial hygiene that no work er should be exposed to any dust in a concentration exoeeding 75 or 100 millions of partioles per cubic foot of air. B - What are the Principal Insulating Operations and How Much Dust is_ Produced During Such Operations? There is, of course, a wide variation in the amount of insu lation work and the amount of dust produced. A few examples, however, will give a good general ldeat INSULATING 12" STEAM LINESi 6" x 18" x l-l/2" blooks of 65% mag nesia are tied on the steam line with 14-gauge galvanized wire and covered with roofing paper to make it waterproof. Often times this work is performed on scaffolds twelve to fifteen feet above the ground, with men lying on their backs under the line part of the time. 396353 -28- Considerable duat (as high as 18,124,800 particles of iess than ten microns per cubic foot) results from tapping the blocks into plaoe. Samples taken during the entire operation had an average concentra tion of 6,881,760 particles per cubic foot. About 90# of these dust particles were slightly angular, crystalline in appearance and above five microns or less in site (as seen under the Konlmeter Mioroscope)j 5# were rounded opaque, ten microns or more in site} and 6# were opaque scale-like, five microns or more in site. Samples taken while applying asbestos sponge felt to a 12" steam line had a dust concen tration as high as 23,786,800 particles of ten microns or less in site per cubic foot. The average was 12,574,080 particles per cubic foot. These dust concentrations are considered too high for work ing without adequate protection. INSULATING A 750-POUND CRACKING COIL ACCUMULATOR* 6" x 36" blocks of Johns-Manville "Fire Felt" are first applied and plastered with extra AA Rubberoid Asbestos Cement and waterproofed with JohnsManville "Insulkote". The dustiness of handling these materials has been considerably reduced since the manufacturers began shipping the "Fire Felt" in cardboard cartons containing thirteen or twenty blocks, and the plaster in hundred-pound paper bags. Samples taken during this operation had an average dust concentration of 4,602,880 particles, ten microns or less in size per cubio foot. About 76# of these dust particles were slightly angular in appearance, five mi crons or less in size* 10# were seale-likej opaque* and 15# were rod-like and fibrous. INSULATING TREATING PLANT ACID SUCTION LINE* Sections of "Sponge Felt Pipe Cover" are cut to fit pipe lengths with an ordinary carpen ter's hand saw. This operation produces on an average 821,280 par ticles of dust, ten microns or less in size, per cubic foot. Under the Konimeter Microscope all of these particles are slightly angular, crystalline in appearance, and five microns or less in size. The blocks or sections of the pipe cover are held in place by wrapping #16 gauge galvanized wire about each one. INSULATING CRACKING COIL HOT OIL LINES* All hot oil lines at erack ing coils are insulated with 2" asbestos tubing (85# magnesia and 15# asbestos) held in place by fine copper wire. Sections of the tubing are cut to fit particular areas by means of an ordinary carpenter's hand saw. This produces 7,788,000 partloles of dust, ten microns or less in size, per cubic foot. Under the microscope, 90# of these dust particles appeared to be rounded crystalline and about three mi crons or less in size. Each section of tubing is pounded into plaoe with the open hand so that it fits snugly against the pipe, and then wired into position. The dust produced from both of these operations averages about 3,379,520 particles per cubic foot. Voder the micro scope, approximately 80# or 9CNJ of the dust particles appear crystal line, more or less angular, and five microns or less in size* the re maining 10# or more are rounded in appearance, and over ten microns in size. DISMANTLING OR REMOVING OLD INSULATION* As a general rule, the dismantling or removal of old insulation is a more dusty operation than the application of new insulation. The old insulation is chopped or cut with a hatchet or small hand-axe, and pried loose and pulled off with the hands. This produces dust concentrations as high as 5,890,560 particles, ten microns or less in size, per cubic foot. In i I CO --I O CD ro cn CD xh io 00 cCnD CO -29- dismantling an old cracking coil 4" tar line, the average duet concen tration was 2,322,240tpartioles per cubic foot. In appearance these particles were clear crystalline, rather rounded, and five microns or less in site. No fibres were observed in any of the dust samples from dismantling operations. After a few weeks or months service, insulatlon on hot lines dries out and appears to disintegrate. This Is probably due to the fact that suoh Insulation is usually covered with a weather-proof material which prevents absorption of moisture from the air. / STOO!2 9 5 9 CRUSHING SCRAP ASBESTOSt Scrap asbestos Insulation, usually the 85% magnesia type, is crushed in a belt-driven Williams orusher to pass through a soreen with one-inch holes or slots, and is then mixed with new asbestos to make insulating plaster. This operation, which is a very dusty one, Is performed by two men, with an average servloe credit of about twelve years. Goggles and USA. "Comfo" or Willson Dust Respi rators are worn. Considerable dust is produoed in breaking up the scrap Insulation by hand prior to erushlng (10,195,200 partioles, ten microns or less, per cublo foot), and also when feeding the crusher whioh is done by shovelling the broken-up pleoes into the hopper and poking them down with a short wooden stick (14,839,680 partioles per cubic foot). Dust counts as high as 27,527,040 partioles per cublo foot were found in samples taken from over the hopper. These dust con centrations are dangerously high. About 95# of these particles are sharply angular, crystalline in appearance and five microns or less in size) 5# are opaque scale-like, six microns or more in site. Crushing sorap asbestos is not a steady routine operation, the exposure varying from eight hours a month to about twelve hours a week. CRUSHING OLD CORK INSULATION* This operation is performed approxi mately twice a year and takes about twenty or thirty minutes. The iiw sulatlon is crushed on a belt-driven Williams crusher, by the same men who orush the scrap asbestos. This crushed oork is used for Insulating lines in the cold settling plant. The average amount of dust produoed is 20,016,178 partioles, ten microns or less in size per cubic foot. About 80# of the particles are slightly angular, crystalline, in ap pearance, nd five microns or less in sizej 20# are round, semi-opaque, ten miorons or more. There are also a large ntmber of very small blaok or dark grey speoks. IV GUNITING OPERATION What is Gunite and How is it Applied? - Gunite is a mixture of approximately one part (one 94 pound bag) of Portland Cement and two parts (twelve scoop shovels) of clean sharp sand. The sand and cement are mixed dry, shoveled into the hopper of a Gunite machine, using water under about 40-pounds per square inch pressure and compressed air at thirty to ninety pounds per square inch. It is applied under pres sure, as a semi-fluid, against the surfaoe to be protected (usually process equipment, such as, cracking ooil soaking drums and storage tanks). In practically every case where guniting is done, it follows immediately, after the sand blasting Job used to clean the surace. In most cases, the work is performed by the same crew. The indi vidual holding the gunite nozzle is provided with the same protection as is the operator of the sand blast nozzle, and the men tending the gunite machines are pro vided with respirators and are required to use them while actually handling the sand and cement. This involves mixing the materiale and charging them into the machines (the two dustiest parts of a guniting Job). Samples taken during these operations showed the following dust counts of particles ten microns or less in sizei 396355 -30- Operatlon Particles per cu. ft. Screening sand prior to mixing with cement.. Mixing batch................................................................. Shoveling mix into hopper...................................... 2,493,160 1,699,200 6,485,280 About 40?! of the dust partioles in samples taken while mi-ring the batoh and filling the hoppjpr were crystalline, quartz-like in appearance, and about five mi crons in size. The remainder were dark grey in color and below one micron in sizew The dust particles in air coming out of the bottom manhole of a soaking drum being gunited averaged 528,640 particles per cubic foot, and were slightly angular, crystalline in appearance and four miorona or less in size, A gunite crew consists of six men. The average servloe oredit of the men in the Crews studied was eight years. Two "nozzl^men" who "spell" each other every two or three hours apply the gunite. There is one man at the gunite maohine, three men screen the sand and mix it with cement. Only about ZS% of their working time, or nine hours per week per man, is devoted to guniting. Removal of Gunite Lining? Pneumatic chisels are used to remove gunite lining. Samples taken from inside a cracking coil tar separator during this operation as high as 16,595,520 particles of dust, ten microns or less in size, per oubio foot, and an average of 10,804,080 particles per cubio foot. About 75?! of these partioles were rounded, angular, more or less opaque, in appearance, one mioran or less in size, and 25% were angular, quartz-like, about ten microns or less in size. A chemi cal analysis of the gunite lining showed that it contained 68.2?S free siliea. Four men from the Plant Labor Depar-bnent, with an average servioe of seven years, spend about twenty hours per week removing gunite linings from process equipment. An air syphon provides ventilation, and the men are required to use the goggles respira tors which are furnished them. V - WELDING AND CUTTING OPERATIONS Welding has never been considered a dust-producing operation. However, our studies and those of others indicate that the use of the modern ooated electrodes or rods produces a large amount of dust in addition to the fumes which are evolved. An electrio arc is used for most of the welding around refineries. There are a number of welding Jobs, however, for which oxy-aoetylene is used. Oxy-acetylene is also used for practically all burning or outting. A - WELDING OPERATIONS? 1. ELECTRIC ARC WELDING? Electrio arc welding is used m all types of oaxstruction and repair work. The average service of the electrio welders is about two years and most of them came from the Labor Department, having been developed into welders at the individual plants. They are exposed to particulate matter generated by the welding operation on an average of six hours per shift, nine shifts out of fourteen. This particulate matter is ordinarily referred to as "fumes or smokes". The particles when found have a much smaller size range than that of dust, suoh as silica. With same operations there may also be some dust present, but the product formed ft*cm volatilizing the metal and rod coatings is commonly termed a "fane". All welders are provided with approved hand shield or helmets equipped with #10 Noviweld lens. Welding in slops is done in canvas or wooden booths. A steam or air syphon is installed when any arc welding is done inside of closed vessels such as drums or towers. 'What are Coated Electrodes? Coated electrodes are metal welding rods covered STOOI 2960 [ I I I ( II -31- ST00I296I vrith a composition which prevents oxidation and permits the formation of stronger and more uniform welds. What Do These Electrodes Contain and What Products Result From Their Use? In general, the coatings used in modern coated welding electrodes are patented or trade secrets, with special virtues attributed to each. Obviously, it is inadvisable to put into these coatings materials which might produce products harmful to man. Nevertheless, chemical analyses of both the coatings and their products Indicate that the continual use of sane of these rods might possibly lead to compileations. Most of the arc welding at our affiliated plants is done with #5 Fleetweld coated electrodes which come in two sires (5/32" and 3/l6") and with General Eleotric W-20 5/32" coated rods. Other rods sometimes used are #4 Stainweld EfcgS *11 oy welding rod, 5/32" Stainweld A rods for stainless steel, and Murex Niokel Steel coat ed rods. Among the constituents of some of these electrodes coatings are Coated Electrode Brand Si02 Per Cent. Fluorine Calcium Fluoride "Fleetweld", Lincoln Electric Co.............. "Murex". American Metal 4 Thermite Co.. "USS Cr-Ni 18-8", Amer. Steel 4 Wire Co. mm 37# 20 "Stainweld", Lincoln Electric Co.............. "Rezistal K-A-25", Cruoible Steel Co... 21. 20 13.40 - 14.60 43. 50 present All of the above coatings also contain Iron Oxide (Pe203) Manganese Oxide, " either Kn203 or MnO or both, and Aluminum Oxide (AI2O3), in varying per*, oentages. The composition of the fluxes or coatings used in G 4 E types W-20, W-22 and W-23 is not available, but it is known that they contain amounts of iVee silleates and free silica. According to determinations made by the General Electrie Company, the maximum concentration of fbee silica on any of their electrodes under a particular set of conditions is 1,575,000 particles per cubic foot of air with W-20, 778,0Q0 with W-22, and 1,093,000 with W-23 under other conditions the concentrations might be higher or lower than those given. The maximum permissible concentration as listed by the Metropolitan Life Insurance Company is 7,000,000 particles per cubic foot of air. Coatings also contain cotton fiber, cellulose, or other organic pulp which creates fumes, but since we are only concerned with dust in this study all fume pr^ ducing materials will receive no further consideration. V.'elding corrosion-resisting s+eel with coated corrosion-resisting steel eleotrodes forms a slag, among the major constituents of vtfiich are* "Stainweld" USS CR-N1 18-8 "Rezistal" Fluorine (F)............................... Silica (Si02)..................................................... Ir on. Chromium andIlangane s e Oxides... Calcium Oxide (CaO)...................................... 11.4%................................................ 6.6%.14.9% 25.1%. *3 8. 6%...........13. 3% 22. 3%. .......24. 2%. ..........15. 2% 60.7%................................................. 28.0%.26.7% .. The major constituents of dusts separated from atmosphere by gravity and col- . leered from the bottoms of welding charters after welding corrosior-resisting steel plates with coated corrosion-resisting steel welding rods are* 396357 -32- "Stalnweld" USS CR-N1 18-8 "Rezistal" Silica (S10 )...................... '........................ 11. 0%.................. 19.6#................ 10. 0# CalcIns fTuorido (CaF ).....*..* 40....*. 11. 4^ ........ 23. 4^ Oxides of Iron, Aluminum and Nickel. 30.2#................. 52.1#................ 36.6# The following is an interesting comparison between the compositions of dust formed vhen using bare mild steel electrodes and when using coated electrodes for welding galvanised steel: Brand "Fleetweld" "Wilson" "Murex" Bare Electrodes # ZnO # F02O3 79.2 62.6 6a 5 20.0 60.5 40.0 Coated Electrodes # ZnO # F203 67.5 78.8 72.0 31.9 21.5 28.0 STOOI 2962 Investigations have shown that there may be as much as a five per cent, varia tion in composition of dust produced by the same make and kind of electrode when used under constant conditions but by different operators. Ferric oxide (Fe2D3) which emanates from all welding arcs, regardless of the type of coating, is disagreeable but not harmful. Concentrations of iron oxide of about ten milligrams per cubic meter are said to be entirely non-injurious to the respira tory organs. Breathing the dense clouds of fumes of zinc oxide, formed when the zino of the galvanized coating is boiled off by the heat of the welding arc, causes what is ccomonly known as "fume fever". This is evidenced by nausea followed by chills and un pleasant fever. The fume fever does no lasting harm except after prolonged exposure, and the effects are not cumulative. Ordinary ventilation, which is necessary in any welding operation, is considered adequate to prevent fume fever. What Is The Amount And What Are The Characteristics of Dust Produced gy The Various Electric Arc Welding Operations? There is a wide variation in the amount character of dust produced by different types of rods on different materials under different operating conditions FDME, OR DUST PRODUCED BY ARC WELDING Material Being Electrode Size of Particles Welded Used Electrode Per cu. ft. Rivets inside Cross Coil Drum. G-E W-20 Coated 5/^2" 20,050,560 Mild Steel Blanks Inside Booth. G-E W-20 Coated 5/32" 14,839,680 Characteristics of Dust Particles. (Sizes and Per centages Estimated) About 98# angular crystal line, 5 microns or less in size) 2# rounded semi-opaque, 10 microns or more in Biz2. About 80# round black or red dish brown specks, 1 microns or less in size; 20# slightly angu lar crystalline, 10microns or less but mostly about 5 microns and large number reddish brown specks too small and numerous tc count. 396358 I I I 1 t E C c c c c ST00 I 2963 -33FUIL OR DUST PRODUCED BY ARC WELDING (Ccmtlimed) / Haterial Being Electrode Size of Partioles Welded Used Electrode Per cu. ft. 1/4" Boiler " 7/^5 Fleet- Plate Inside* weld Booth. Coated 5/32" 11,441,280 Characteristics of Dust Particles. (Sizes and Per centages Estimated) About 80# angular crystalline, 3 microns or less in size) 10# round semi-opaque, 10 microns or more in size) 10# opaque scale like, 10 mi crons or less in size. Count less number of minute par ticles, reddish brown smudge. 1-1/4" ::iid Steel Expan sion Joint In side Booth. #5 Fleet- weld Coated 3/16" 19,861,793 About 95# angular crystal line, 3 microns or less in size) 5#rounded semi-opaque, 10 microns or less. Count less number of partioles reddish brown smudge. 1/2" Rolled Steel (55,OCX)# per sq. in. Tensile strength) In side 6+Foot Dia. drum near head of closed end. #5 Fleetweld Coated Welding Flange on 4" Steel Line Pipe, In side Booth. Ilurex Coated 5/8" Boiler Plate Inside Booth. #5 Fleetweld Coated 3/16" 2,265,600 All partioles 5 microns or less in size) about 10# angular semi-opaque. 3/32" 5/32" 2,756,480 490,880 All particles 2 microns or less in size) slightly angular, glass-like) dark grey smudge. About 75# round, metallio opaque, 5 microns in size) 25# semi-opaque, crystal line. Countless number of minute particles Welding Riv ets in Courtney Edge Inside Crack ing Coil Soaking Drum. #5 Fleetweld Coated 5/32" 6,456,960 About 90# sharply angular crystalline, about 1 micron or less in size; 10# rounded semi-opaque, 5 mi crons or more. Countless number of minute particles. 396359 ST00 I 2964 -34- FOKE OR DUST PRODUCED BY ARC WELDING (Continued) Materiel Being Electrode Site of Particles Welded Used Electrode Per cu. ft. 18-8 Stainless Steel Band it Top of Soaking Drum Kanhead Stalnweld A Coated 5/32" 849,600 1/Zn Boiler Plate to 6" Pipe Inside Booth. G-E W20 Coated 3/16" 23,222,400 1/2" Boiler Plate to 6" Pipe Inside Booth. Roebling Iron Rod 5/32" 26,592,480 Back Welding a Flange on 6" Standard Pipe in Out side Welding Shop. Eaok Welding a Flange on 6" StandardPipe Inside Booth. Fleetweld #7 Coated Fleetweld #7 Coated Welding Riv ets Inside Cracking Coil Vapor iser (Ilild Steel Alumi num Coated). Jleetweld #7 Coated 5/32" 362,496 5/32" 1,000,640 5/32" 6,253,056 Charaoteristics of Dust Partioles. (Sites and Per centages Estimated) About60# slightly angular semi-opaque, 5 microns or less in sitej 20# rounded, over 10 microns) 20# very glass-like, 10 mi crons or less. . About 80# semi-opaque, red dish brown rounded, crystal line, 5 microns or less) 20# round globules of metal 5 microns or more in site. Countless number of small particles. About 90# black opaque, 1 micron or less in site) 6#. rounded metallic globular, 5 microns or less) 5# slight ly angular, semi-opaque, crystalline, 3 microns or less. Countless number red dish brown particle?. ` About 95# black opaque metallic, 2 microns or less) 6#angular'orystalline, 5 microns or less. Count less number of reddish brown particles. About 95# black opaque metallic, 2 microns nr less; 5#angular crysta lline, 5 microns or less. Countless number of black particles. About 95# angular crystal line, 5 microns or less, mostly around 2 microns)5# semi-opaque, round, 5 mi crons. Countless number of black particles. 396360 j ST00 I 2965 FUME CR DUS P.ODUCED BY ARC_ WELDING (Continued) i Material Being Electrode Size of Particles Welded Used Electrode Per cu. ft. Characteristics of Dust Particles. (Sizes and Per centages Estimated) Welding 2" Ring on 1" Mild Steel Boiler Plate Inside Booth. Fleetweld #7 Coated 3/16" 27,662,976 All particles less than 2 microns. 70% round, opaquej 30% slightly angular, crystal line. Countless number of black particles, reddish brown smudge. Mild Steel Sorap Plates Inside Booth. Stainweld A Coated 5/32" 2,605,440 All particles black opaque, 2 microns or less in size. Xa2S Steel Inside Booth. Stainweld A Coated 5/32" 12,460,800 About 80?! angular opaque, 2 microns or less) 20% slight ly angular crystalline, 5 microns or less. Countless number black particles, brownish grey smudge. The U. S.Navy recently conducted some extensive tests with coated electrodes, and found that the quantity of dust or fumes developed while welding on galvanized steel plate was greater than when hare steel plates were used and the dust remained in suspension for far longer periods of time. It was also found that the average size of the dust particles was 0.27 microns and that there were 130,000 partides under four microns diameter per cubio centimeter. Quoting the Navy report* "It is apparent that considerable quantities of dust are found in any aro welding operation. The dust formed when operating on plain mild steel or corrosion resisting steel is largely derived from the flux coating on the electrodes, as is shown by the composition of these dusts". What Physiological Effect on Welders is Produced by The Use of Coated Electrodes. According to a study made by Doctors A. T. Doig and A. P. G. McLaughlin on lungs of Electric Arc Welders (Lancet - V.20j 771 - 775 (April 4, 1936)), defi nite pulmonary lesions which gave rise to striking X-ray changes in the appearance of the lungs were found in welders which had breathed +he dust or fume from coated electrodes. Quoting Doctors Doig and McLaughlin* "The electrodes or welding rods which contain a core of metal and an outer covering are consumed gradually by the heat generated (about 1500C. ) during the welding operation. The metal in the core of the rod becomes molten and, assisted by the flux contained in the covering, spreads over the surface of the metal which is being welded. The fume is therefore made up of the volatilized constituents of the coverings of the rods together with fine particles of oxidized metal, usually in the form of iron oxides. In addition the fumes probably contain gases auoh as nitrogen peroxide *nd ozone which are formed by the action of an electric spark on the air. The composition of the coverings of the electrodes or welding rods becomes, in the circumstances, a matter of some importance. Many substances, all of which we do not propose to enumerate, are used. The basis of the majority of the coverings is sodium silicate which acts as a flux. Again, the 396361 -36- coverings of a certain type of electrode contain asbestos. The rods are sometimes dipped in a mixture containing powdered asbestos and sodium sili cate, or asbestos yarn is wound round the rod and fixed by sodium silicate. In same cases the asbestos completely covers the rods, and in others it is merely a cord which is wound spirally about the rod, "The oomposition of the fisnes arising from electric welding electrodes has not yetibeen fully investigated, Mr. L.C. McNair, H.M. Engineering In spector of Factories, has however had partial analysis made of the fumes evolved from an asbestos-covered electrode and some asbestos fibres were found. When the particulate matter of the fumes was collected in an Owen's dust-counter. it was seen that a large proportion consisted of iron oxide particles, with an occasional asbestos fibre. "The X-ray appearances in the well-marked cases differ from the usual picture of asbestos!s. In none of the positive cases and in only one of the suspicious cases was there any blurring of the diaphragmatic shadow, and in no case was the heart outlined blurred. The line of the interlo bar septum (a feature present in a number of films of cases of asbestosis) is seen in only one positive case. The opacities in the films are not aocentuated at the bases of the lungs, but on the contrary the upper lung fields appear to be the earliest, and in established cases, most markedly affected. Before asbestosis can be eliminated from the differential diagnosis it must be remembered that the asbestos fibres are being subjected to intense heat and are not in the same physical state as the fibres which are inhaled by workers in an asbestos factory. It is possible that a typical picture of asbestosis might be produced by the inhalation of alter ed asbestos. Merewether. says that - the radiographic appearances of the developed or advanced states of asbestosis are distinctive, although they are not specific. While, as is the case with silieosls, certain radio graphic appearances may be looked upon as typical of the disease, frequent ly modifications of and departure from the typical picture occur'. The X-ray appearances in our cases most closely resemble those of a fine silioosls, but the clinical features show two important differences. In the first place, the electric welders wham we examined are all in good health md are fit to work. The only symptoms observed fiere slight cough and morning expectoration, and in the first case a small haemoptysis ocourred. This Tnaw has not been away from work even for a day since he was first seen in June, 1933, and his health at the present time is good. None of the men suffers from dyspnaea. Secondly none of them has concomitant pulmonary tuberculosis. "Miliary tuberculosis can be ruled out of the differential diagno sis for clinical reasons, and to same extent on the radiological appear ances. None of the cases shows the dyspnaea, cyanosis, and tachycardia of acute or subacute miliary tuberculosis. Chronic or healed miliary tuberculosis is rare and it is difficult to imagine that a condition of such rarity would be found in 6 out of one group of 16 men. In the X-ray films of the welders' chests the fine opacities are irregular in site and shape, whereas in miliary tuberculosis of the lung the shadows are more uniform. "A further possible explanation of the X-ray appearances in this series of cases is that the inhalation of small quantities of nitrous fumes together with the svperadded effect of fine iron oxide dust might set up small areas of chronic inflairaratory change, congestion, or fi brosis in the lungs. Again, the iron oxide particles might be opaque to the X-rays and produce the picture without the associated presenc 396362 STOOI2966 c t c c c c -37- STOOI 2967 of fibrosis and congestion." ' CXY-ACETYILNE '.ULDINGi (fxy-acetylene welding is more or less confined to snail repair jobs or to certain emergency operations where arc welding is not available or practical. Exposure of men doing welding is more or less irregu lar. They usually wear American Optical Company or Willson Welding Goggles with #4 Noviweld lens. The amount of dust produced by oxy-acetylene welding is considerably less than that caused by the use of coated electrodes in are welding, and varies considerably with the style tip and welding rod being used as well aV the material welded, as is shown by' the following tablet DUST PRODUCED BY OXY-ACETYLENE WELDING Material Being V.'elding Rod Tip Used Particles Per Characteristics of Dust Welded Ctu Ft. Particles (Sizes and Per centages Estimated) C-alvani z ed I.'etal Hood Welding Shop. Norway 5/32" Airco #4 396,480 About 70?. slightly angular, semi-opaque, greyish, 5 mi crons or less 1 20#rounded semi-opaque, greyish crys talline, 10 microns or more} 10# amorphous, soale-like) 10 microns or more in size. l/4" x 2" Bar Iron, '.-.'elding Shop. Oxwelc cop- Airco perized #8 steel 3/16" 509,760 About 80# black opaque, 1 micron or less in size) about 20# rounded, crystallinej 5 microns or less in size. 1/2" Boiler Plate, Soft Steel, Weld ing Shop. Oxweld cop- Oxweld peris ed #6 steel l/8" 1,019,520 About 80# round, semi-opaque, 5 microns or less in size) 10# angular crystalline. Countless number of small black particles. 1/8" Galvan ized Sheet Iron, Weld ing Shop. Oxweld copperized steel, 1/8" Oxweld #6 1,359,360 About 80# rounded, semi opaque, dark grey, 1 micron or less in size) 10# slightly angular crystalline, 3mi crons or less) 10# sharply angular crystalline, 5 mi crons or less) countless number of small dark grey particles. '..'elding Teeth on Band Saw. Simmons Saw VJelding Rod. 3/64" Aero plane #2 1,472,640 About 98# round black opaque, about 1 micron or less in size) 2# slightly angular, crystalline, 3 microns or less in size. B - BURNING OR CUTTING OPERATIONS; 1. 'WITH CNY-ACETYL-DIE; The oxy-acetylene torch is used both in the construction 396363 -38- and the demolition of process equipnent and works structures. It also plays an inportant part in emergency and rescue work. Goggles with shade #5 Noviweld lens are provided and their use is required. At the larger plants men with an average service credit of six years spend about three-fourths of their working time on cutting or burning operations (about half their time is given to "burning steel" for new construction). The amount of dust pro duced is usually greater than that caused by oxy-acetylene welding. DUST PRODUCED BY OXY-ACETYLENE BURNING Material Being Particles Characteristics of Dust Particles Burned Tip Used per cu. ft. (Sizes and Percentages Estimated) Burning 6" Flues (1-1/2" thick) Out of Shell Still. Oxweld #2 1,869,120 About 75?! round black, 2 microns or less in size; 20% slightly angular, crystalline, 2 microns or less; 5% opaque, scale-like, various sizes. 1/2" Boilor Plate (soft steel) Oxweld *4 2,718,720 About 90% semi-opaque, black, 2 microns or less 10# round, dark grey, over 5 microns in size. 2. WITH NATURAL GASt A large part of the burning or cutting at one of the larger southern refineries is done with oxygen and natural gas (60 pounds per square inoh pressure). A special torch with a l/l6" x 6/l6" tip made in the refinery shops is used. Two men with sn average service of thirteen years spend a major portion of their working time on this natural gas. They wear goggles with =^5 shade Ncrviweld lens. Samples taken while burning holes in 3" standard pipe in the yard outside of welding shop with oxygen apd natu ral gas had a concentration of 471,811 particles, ten microns or less in size, per cubic foot. About 75?S of these particles were slightly angular orystalline in appearance under the Konimeter microscope, and were five microns or less in size; 25% were rough scale-like, opaque, ten microns or less in size. There were also many minute particles. - HEALTH HAZARDS PRODUCED BY WELDING AND BURNING OPERATIONS!Although our study was confined to the fumes or dust produced by Welding and Cutting opera tion the possibility of lead poisoning from welding or cutting iron plates that have been previously coated with red lead should be pointed out. Lead poisoning from this source is rather common, especially in cutting up old scrap, bridges, tanks, and other iron structures that have through many years of use received protective coatings of red lead. The action of the flame volatilizes this lead material and creates a smoke that is poisonous. The same hazard exists in cutting out rivets in new structures. It should also be pointed out that same of the welding rods contain manganese which is very poisonous when taken into the body. There is an apparent hazard from volatilizing this material, or rather changing it to tho oxide of manganese, and breathing the fumes produced. There are further dangers from carbon monoxide and oxygen deficiency owing to the use of gas-cutting or welding flames inside small tanks or similar confined spaces. It is becoming more and more recognized that persons engaged in cutting and welding operations, either by arc or flame, should have respiratory protec tion, in all work where there is a possibility of the workmen breathing fumes and dusts created. 396364 ST00I2968 C t c c t c E C d d e i c i i i -39VI - GRINDING OPERATIONS i Power grinders ere perhaps the most universally used of the small powerdriven tools. The usual power grinder, commonly known as the emery *4ieel, consists of a cast metal stand and two abrasive wheels mounted on a through shaft which is either belt or motor driven. There are also several grinding wheels, such as are found on machine tool equipment where grinding takes the place of lathe and planer work. All grinding operations produce dust to a greater or lesser degree, depending on the composition and construction of the wheel, the material being ground and the ventilation or exhaust hoods provided. What is the Composition of Grinding Wheels? Grinding wheels are made of . either bauxite which is mined, or silicon carbide whioh is made by heating a ture of quarts sand, coke and cannon salt in an electrio furnace. The bauxite or silicon carbide are crushed to the desired grain site, mixed with an adhesive substance called a bond, and formed into wheels, discs, canes or cylinders. There are many wheels in which the binder is shellac, rubber, bakelite and other organic ocn^ pounds. Bauxite wheels are known in the shop as "Alundum" and "Aloxite", while silicon carbide wheels are known as "Crystolon" and "Carborundum". Alundum wheels should be used on material of low tensile strengths such as cast iron, brass, aluainum, copper and marble* _ (-- c__ |"0 lO CH <0 Is Abrasive Dust Harmful? According to Dr. W. Irving Clark in a paper read at a meeting of Government Officials in Industry (Boston - May 21, 1931) the artlflcal abrasives, aluminum oxide and silicon carbide do not contain free silica their dust cannot produce silicosis. The dust, like aiy other Inorganic dust, oan, however, if breathed for a long period of time in large quantities, produoe an X-ray picture similar to that of early silicosis. This picture ohanges very slightly as years of exposure increase, and at no time are the nodules, characteristic of sili cosis, evident. Unlike silioosis, there is no progress in the prooess after expo sure ceases and there appears to be no marked physical disability. Although there is no silicosis, the X-reys do show signs of pneumoconiosis* Carborundum dust, chemically, is silicon carbide. According to Killer and Sayers (U. S. Pub. Health Rep. Vol. 49 #3 of Jan. 19, 1934) carborundum dust when in jected into the peritoneal cavity of guinea pigs produced no reaction and was termed "inert". Dusts such as quartz and flint - silicosis producing dusts - produced a proliferative reaction. Leroy U. Gardner (U.S. Pub. Health Rep. Vol. 50 #21 of May 24, 1935) reports that carborundum produces practically no reaction when inhaled by guinea pigs in high concentrations aver a period of time. Quoting from Dr. Gardner's article, the part pertaining to carborundum dustt "The dust which does reach the tracheobronchial lymph nodes apparent ly lacks the proper physiochemical properties to stimulate any but a very slight proliferation of connective tissue. In the lungs, there is prac tically no fibrosis." The Journal of the American Medical Association (Notes and Queries 103, 1472, 1934) makes this statement regarding the health hazard of breathing dus$ from arti ficial abrasivest "Only silica (Si02) is capable of inducing silicosis, but any other mineral dust under conditions of prolonged and gross exposure may cause some increase in puLmonary fibrosis. If the relative potential harm of silica is rated as 100, these other non-toxic mineral dusts may be rated m CD co ^ -40- only on the order of 6 or 10." Despite this comparatively low rating of harnfulness of these dusts it is generally considered advisable to use dust hoods and exhausts wherever practical as there is clinical evidence that workers exposed to heavy concentrations of dust of any kind are more liable to develop diseases affecting the nose, throat and chest during the winter months than those not exposed to dust. Dr. Clark believes that an effort should be made to keep the dust count below twenty million particles of less than ten microns per cubic foot of air. 1. What are the More Frequently Used Types of Grinders, the Quantity and Character of the Dust They Produce? The grinders most commonly found in the refineries and as sociated activities are: A - TANDEJl FLOOR TOCL GRINDERS i Tandem floor tool grinders, the most fre quently used type, are in most cases motor-driven and operate at a speed of from 1450 to 1850 RIM. The type of wheel or grinding media selected depends upon the ma terial to be ground. Generally speaking, the wheels found in most of the machine shops and wood working shops around our refineries usedi 1-1/2" x 10" Norton Alundum (Grade P, Grit 46) wheels for sharpening tools and for general service grinding. 1-1/2" to 3" x 14" Carborundum wheels for miscellaneous grinding. 3" x 16" Carborundum (Grit 30, Grade K) wheels for grind ing lathe and other machine tools. Sometimes two different wheels are used on tandem tool grinders; for example, a 2" x 14" grain 24, grade Q Norton Alundum vitrified wheel on one side and a 2" x 14" grain 44, grade M Alundum wheel on the other side. The amount of dust produced by the operation of tandem tool grinders depends primarily upon the composition of the wheel and the hardness and character of the object being ground. Theoretically, the operating speed and the pressure should also be determining factors, but these were not studied. The following are average dust counts of particles ten microns or less per cubic foot in samples taken in the breathing tone of the person using the grinder during the grinding of various ob jects on various wheels of tandem floor grinders: Operation Particles per cubic foot Grinding Cast Iron on 2" x 12" Aloxite (4611 Grit) Wheel................. 11,648,960 " a Steel Sleeve on a l/2" x 10" Carborundum Wheel.............. 8,127,840 " " Eard Steel Chisel on a 5/8" x 8-1/2" Alundum Wheel... 7,476,480 "" " " " l/2* x 10" Carborundum Wheel.. 1,670,880 ft nn n ti n it jj^ rt tt 906,240 " " Pneunatic Tool Steel Chisel on a 3-1/2" x14" Norton Alumdum (3836 - 0.5B) Wheel...................................................... 1,869,120 " " Chisel Bar on the same wheel (3836 - 0,5B Alumdum). 4,134,720 " " Tool Steel Chisel on s 1" x 10" Carborundum (Grain 46M) Wheel___ 2,594,112 tt T(>ol Steel on a 2" x 14" Alundum (24 grain,gradeQ) Wheel 396,480 n n n nn Tt TT (44 " " M) " 1,019. 520 n & Lathe Tool on a l/2" x 12" " (Grade P) Wheel............. 339,840 ft tt n n n TT TT tt ( " R) " ............. 1,331,040 396366 -41- Operation (Continued) Particles per cubic foot Grinding a Lathe Tool on a 3" x 16" Carborundum (grit 30.gre.de K) Wheel............... 362.496 " Mild Steel on a l-l/2n x 10" Alundum Wheel........................... 6,655,200 " Steel Dies on a 3" x 14" Carborundum Wheel............................... 56,640 " Squaring Shear Blades an a 1-1/2" x 16" Carborundum Wheel. 2,577,120 I L62 I001S Dust Produced By Operation of Tandem Floor Grinders. As would be expeeted, there is a wide variation in the appearance of the dust partioles under the Kanimeter microscope. These examples however, will give an idea of the characteristics of the dust produced during the operation of Tandem Floor Grinders* Material Being Ground 1" x 3" Mild Steel Bar Tool Steel Tool Steel (Same ma terial as above) Lathe Tool Chisel Bar Pneumatic Hand Tool Steel Chisel Lathe Tool Lathe Tocl (Same as above) Size of Wheel Type of Wheel 1-1/2" x 10" Alundum (Grit 46, Grade P) 2" x 14" 2" x 14" Alundum vit rified (Grit 44,Grade M) Alundum vit rified (Grit 24, Grade Q) 3" x 16" 2-1/2 x14" Carborundum (Grit 30 Grade K) Alundum (3836-0. 5B) 2-1/2" x 14" Alundum (3836-0. 5B) 1-1/2" x12" Alundum (Grade P) 1-1/2" x 12" Alundum (Grade R) Characteristics of Dust Partioles. (Sizes and Percentages Estimated) About 70# angular crystalline, 6 microns or less in size; 30# me tallic shreds) 10# white opaque, slightly angular, over 10 microns; many small blaok specks. About 90# angular crystalline, 2 microns or less in size; 10# opaque, 1 micron or less in size. About 60# round, semi-opaque, 10 microns or less in size; 40# angular opaque, 5 microns or less in size. About 75# round, crystalline, 5 microns in size; 25# sligitly angular. About 70# slightly angular, 3 microns in size; 30# blaok, opaque, metallio. About 98# round, blaok. opaque, one micron or less in size. About 50# angular crystalline, 2 microns or less in size; 50# round, black, metallio, 1 mi cron or less in size. About 75# angular crystalline, 2 microns or less in size; 25# round, black, metallic, 1 mi cron or less in size. 396367 -42- DUST IRODUCED BY TANDEM FLOOR GRINDERS (Concluded) Material Being Ground Cast Iron Size of Wheel Type of Wheel 2" x 12" Aloxite (Grit 46, Grade M) Characteristics of Dust Particles. (Sizes and Percentages Estimated) About 857* sharply angular, crys talline, 5 microns or less) 10# rounded angular crystalline, over 10 microns) 5% opaque scale-like metallic, 10 microns or less) large number of black metallic speaks. S T 0 0 I2972 Where "hard" wheels are used for grinding soft cast steel, about 98# of the duet paro tides are metallic and less than one-half micron in sise. With the exception of a very small number of men who devote about 95/5 of their working time to actual grinding, there is a very wide variation in the number of men exposed and the length of such exposure to dust produced by the operation of tandem floor tool grinders. In only one case was a respirator worn. Goggles have been provided and their use required in most cases. B - TANDEM BENCH GRINDERS* These grinders are small in sise tH are used-for sharpening small tools and light grinding. They are all motor driven and operate at about 3400 R.P.M. Different grade wheels are used, usually l-l/8n x 8" Carborundum (Grain #80) on one side, and on the other a 1" x 8" Carborundum (Grain #90). The amount of dust produced by the operation of tandem bench grinders varies with the ma terial being ground and the composition of the wheel, but these average dust counts are fairly representative* Operation Particles per cu. ft. Grinding Cold Chisel on l-l/8" Grain #80 Carborundum Wheel.... 5,909,440 " "" " 1" x 8" " #90 " " .... 8,401,600 " l/2" Boiler Plate on 1" x 8n#90 " * .... 12,460,800 " Eard Steel Chi sel on 5/8" x 8-1/2" Alundum (Grain 46., Grade P)...................................................... 7,476,480 Dust particles in samples taken during the operation of the tandem bench grinder have the following characteristics: Material Being Ground Size of Wheel Type of Wheel Medium Steel Cold Chisel 1-1/2 "x8" Carborundum (#80 Grain) Medium Steel Cold Chisel (Same tool as Above) 1" * 8" Carborundum (#90 Grain) Characteristics of Dust Particles. (Sizes and Percentages Estimated) Abort 75% slightly angular crys talline, 5 microns or less in size) 20% round opaque, metallic, one micron or less) 5% semi opaque, over 10 microns and look like chips of glass. About B0% round opaque, 2 microns or less in sizej 20# slightly angu lar crystalline, 5 microns or less in size. 396368 STOOI 2973 -43DUST PRODUCED BY TANDEM BENCH GRINDERS (Concluded / Material Being Ground Size of Wheel * Type of Wheel Characteristics of Dust Particles. (Sizes and Percentages Estimated) 1/2" Soft Steel Boiler Plate (Taking off rough edges) 1" x 8" Carborundum (#90 Grain) About 90# round, black, metallie, 2 microns or less in sizej 10# slightly angular crystalline, 5 microns or less in size. Hard Steel Chisel 5/8" x 8-1/2" Alundum (Grain 46, Grade P) About 85# round, black opaque, 2 microns or less in site; 15# rounded crystalline, 10 microns or over. C - SINGLE FLOOR TOOL GRINDERS* There are only a few single floor grinders in use. They range in site from 1" x 10" motor-driven (1750 RHlJ to 2-1/2" x 20" Belt-driven (1250 RFM). The larger size is used for heavy grinding suoh as blanks and large tools) the smaller sizes for sharpening tools and miscellaneous grind ing. The wheel on ths large grinder is Carborundum (#9C Grain). For the smaller size class Grain 46, Grade M Carborundum wheels are used on the 1" x 10" Grain 24, Grade*Q Alundum wheels in the l-l/2" x 14" size. Samples taken during the opera tion of Single Floor Grinders had dust counts as follows* Operation Particles per cu. ft. Grinding Tool Steel on 1-1/2" x 14" Alundum Wheel (Grain 24, Grade Q).................................... " Chisel on 1" x 10" Carborundum Wheel (Grain 46, Grade M)................................... " 1/2" x 4" Mild Steel Bar on 2-1/2 x 20" Carborundum Wheel (Grain 90).............. 679,680 2,594,112 4,451,904 The hoods which almost completely enclose these wheels act as practical dust collec tors. Dust particles produced by the foregoing grinding had these characteristics when examined under the Konimeter microscope* Material Being Ground Size of Wheel Type of Wheel Hard Steel Tool Eit 1-1/2" x 14" Alundum (Grain 24, Grade Q) 1/4" x 2" Mild 1" x 10" Steel Bar l/2"x4" Mild Steel Bar 2-1/2 "x20" Carborundum (Grain 46, Grade M) Carborundum (Grain 90) Characteristics of Dust Particles. (Sizes and Percentages Estimated) All particles were 2 microns or less in size. About 60# were an gular crystalline; 40# were rounded opaque. About 98#were black opaque, 2 mi crons or less in size; 2# slightly angular,5 microns or less in size. About 85#were slightly angular crystalline, 5 microns or less in size;about 15#black semi-opaque, angular metallic, 2 microns or less in size. ^ <T> CO -44- D - ^T'DRSAL jRI'TDZHS: As the name would indicate, universal grinders are used for a wide variety of purposes and therefore are in more continuous opera tion than are the other grinders, with the exception of the tandem floor tool grind, ers. There ore two types or makes, the Brown & Sharpe Universal Grinder which has an operating speed of 3750 RPM. and the Grand Rapids Universal Grinder which operates at about 3850 RRi. The following abrasive wheels are usedt l/?.""x 5" Norton Co. 3846 J 5B Alundum wheel for grinding hardened carbon tool steel. 1/2" x 7" Norton Co. 3846 I 8B Alundum wheel for grinding high speed tool steel. 2n x 3-l/2" Carborundum Co. grit 401-P-25, type 12 Aloxite wheel for grinding case hardened steel. l/4n x 10" Carborundum Co. wheel used for cutting, 1" X 10" " nn n " sharpening tools, reamers, dies and drill bits. Samples taken during the operation of the various Universal grinders had dust counts as followsi Operation Particles per cu. ft. Dressing l/2" x 7" Alundum (3846 I 8B) Wheel with a "Diamond Point"... ..................................................................................... (Evidently the clouds of dust which came off during dressing have particled larger than 30 microns) Grinding High Speed Tool Steel on 1/2" x 7" Alundum Wheel (3846 I 8B)............................................................... " Hardened Carbon Tool Steel on l/2" x 5" Alundum Wheel .(3846 J 5B )............................................................... " Case Hardened Steel on 2" x 3-l/2" Aloxite (Grit 401 - P - 25 Type 2).................... .. Cutting off Tool Steel with l/4" x 10" Carborundum Wheel.... 1,397,120 1,846,464 6,683,520 84,960 1,416,000 Dust particles in samples taken during the operation of Universal grinders have these characteristics: Material Being Site of Ground Wheel Type of Wheel Dressing VJheel 1/2" x 7" Alundum With a (3846 I 8B) "Diamond Point" ?-* K $ High Speed Tool Steel (a Landis Pipe Chaser) Alundum (3846 I 8B) Characteristics of Dust Particles (Sites and Percentages Estimated) About 80# slightly angular crys talline. About 3 microns in size; 20# black opaque, round, about 1 micron or less in size. About 60# opaque angular, about 2 microns or less in size; 40# slightly angular, crystalline, 5 microns or over in size. 396370 b I UU I zy / 4 I I ! I I I C E e c c e c c c c c c c c SL62I001S -**o- / Dust particles in samples taken during the operation of Universal grinders have these characteristics (Continued)* > Material Being Sire of Ground Wheel Hardened Car-,,, bonated Steel (Pipe Grip forPipe Machine) 1/2" x 5" Type of Wheel Alundum (3846 J 5B) Case Hardened Steel (Plung ers for Fill ing Machine) 2" x 3-1/2" Aloxite (Grit 401-P25 Type 12) Characteristics of Dust Partioles. (Sires and Percentages Estimated) About 30^ angular crystalline, about 2 microns or less in sizej 70% round black opaque, less than 1 micron in size. Numerous blaok speoks too small to count. Several large oblong blaok opaque par tioles about 20 microns wide 35 or 40 microns long. All particles blaok opaque, 1 mi cron or less in size. E - SURFACE GRINDERS* Surface grinders are used almost exclusively on valves and dies. They are equipped with either l/2" x 8" Norton Alundum (1946H) wheels or l/2" x 4" to 6" Carborundum (Aloxite) wheels. No dust collectors are provided, the dust being thrown out into the atmosphere. Samples taken during the operation of. surface grinders had the following dust concentration (10 microns or less)* Operation Particles per cu. ft. Grinding Soft Cast Steel Valve on l/2" x 6" Carborundum Aloxite Wheel......................................................... " Tool Steel Die on l/2" x 8" Alundum (1946H) Wheel..................................... Dressing Surface of l/2" x 8" Alundum Wheel with a "Diamond Point"......................................................................... 566,400 1,019,620 1,132,800 About 70% of the particles from grinding the steel die were metallic, 3 mi crons or less, whereas 98% of the particles from grinding the soft steel valve were metallic. Masy of the particles were too small to identify or count accurately. F - LANDIS TOOL GRINDERS* Landis tool grinders are usually equipped with two different types of wheels, one for side grinding and the other the ordinary type. 1-1/2" x 12" Carborundum Aloxite (Grit 40, Grade H, Bond 33) is used for general purpose grinding such as bull chisels, diamond points, cold chisels, flanges scrappers. The Side Grinding Type is usually a 2-1/2" x 1-1/2" x 12" Grit 46A-P P678 Aloxite brand AA wheel used for grinding Landis dies. At one plant the wheels of the Land is tool grinder are enclosed by hoods at the rear of each of which is attached a two-inch pipe connected to a three-inch pipe which discharges into a sewer. Suction is induced by a stream of compressed air from a half-inch pipe i&. serted in the two-inch pipe just back of the hand. This arrangement acts as a sy phon and pulls the dust away from the person using the grinder. Samples taken duz>ing the operation of Landis tool grinders had dust concentrations as follows* 396371 -46- Operation ' Particles per cu, Dresring 1-1/2" x 12" Aloxite Wheel (Grit 40,Grade H, Bond 33)................................. 226,560 (Evidently particles in the cloud of dust thrown off hy the 2-1/2" x 6" Metcalf Bnery Wheel Dresser are larger than 30 microns in site) Grinding "Diamond Point" Chisel on l-l/2" x 12" Aloxite Wheel (Grit 40, Grade H)........................................................................................ Grinding 2-1/2" x 6" Landis die on 2-1/2" x l-l/2n x 12" 2,067,360 Aloxite Wheel (Grit 46A-P P678)........................................................... 755,203 ft. Under the Konimeter microscope dust particles in samples taken while dressing the 1-1/2" x 12" Aloxite Wheel appeared slightly angular with a yellowish tinge were five microns or less in size. About 75# of the particles from grinding the Landis die were round, opaque, and less than 1 micron in sizej 25# were slightly angular crystalline, less than 2 microns. Partioles from grinding the diamond point chisel were less quartz-like than those from grinding the die. This difference is, of course, due to difference in the composition of the two wheels. On an average, Landis tool grinders are used about twenty hours a week, usually by different men. G - YANKEE DRILL GRINDER* Used for grinding all types of drill bits. Has a side grinding type 1" x 1-1/2" x 9" Carborundum Aloxite (Grit 30, Grade M, Bond 28) Wheel. Operating speed 1735 RHi. On an average a Yankee Drill Grinder runs about three hours a day and is used by four different men with an average servioe of twelve years. Samples taken during the grinding of a 2-5/1.6" high speed drill had an ave rage of 1,000,829 particles, ten microns or less, per cubic foot. About 70% of these dust particles are slightly crystalline in appearance, five microns or less*in sizej 50% were rounded, semi-opaque, over ten microns in size. There were also a few small metallic shreds. No exhaust or dust collector is used in this grinding. H - AUTOMATIC CIRCULAR SAW SHARPENING MACHINE* There are a number of these grinders in use in the wood working operations - such as in the production of wooden barrels, boxes and crates - closely associated with the refining of petroleum pro ducts. Since they are automatic when once put in operation, there is very little dust hazard except where no exhaust or dust collectors have been installed the dust produced is thrown into the filing room atmosphere. Automatic Ciroulax Saw Sharpening Machines are equipped with l/4" x 8" Norton Alundum Wheels (Grain 60, Grade N), 3/8" x 8" Norton Alundum (1946 M) wheels, or l/2" x 6" Carborundum wheels. The average dust produced during operation of these machines is* Wheel Particles per cu. ft. l/2" x 6"Carborundum................................................................................... 1/4" x 12" " 3/8" x 8" Alundum (1946M)........................................................................... 1/4" x 8" 0 (Grain60, Grade N)................................................... 1,923,280 3,668,320 2,095,680 1,461,312 About 95% of dust particles in samples taken while sharpening circular' saws on the Carborundum wheels were black metallic in appearance, and one micron or less in size. About 75# of the particles from the Alundum wheels were rounded crystal line, 5 microns or under in size, and 25# round black metallic, about one micron or less in size. There were a number of small metallic shreds in the samples from the thicker (3/8" x 8") wheel. I - AUTOMATIC BAND SAW GRINDER* After the Band Saw has been inserted and the t t CO --I CD O ro ao --i cn b ST00I297 7 -47- nachine adjusted, this grinder works automatically. The wheel ordinarily uaed la a l/2" x 8" Grain SO, Grade N Norton Company Alundum. The wheel is refaeed or dressed with a Metcalf Ekiery Wheel Dresser about twice a day. The average dust produced by this dressing operation is 2,284,480 particles less than ten microns per cubio foot. About 95# of these dust particles are sharply angular crystalline in appearance under the Xonimeter microscope, and about five microns or less in site. The dust produced during the sharpening or grinding of the band saw blade is on an average only 877,920 particles per cubic foot. About 50# of these partioles appear angular crystalline and .about 50# round black opaque. All of them are about two miorons or less in size. J - AUTOMATIC BAND SAW LAP GRINDER: Used to grind ends of band saw prepare-- tory to welding them together. The grinding wheel usually used is 5/8" jc 10" Grain 46, Grade li, Norton Company Alundum. No dust oolleotor is provided although a dust count as high as 16,142,400 particles, ten microns or less, was found in one sample taken in front of the wheel while it was in operation. The average dust produced by this lap grinder was 4,984,320 particles per cubic foot. About 80# of these dust particles were semi-opaque, slightly angular in appearance, and two miorons or less in size) 20# were black opaque, about one micron or less in size. K - PLANING KNIFE BLADE GRINDER: Uses a l/2" x 8" Grain 46, Grade N, Norton Company Alundum wheel. Operating speed 3000 RIM. No hood or any other protection. Average dust produced while sharpening a Planer Knife Blade was 566,400 partioles, ten microns or less per cubic foot. About 60# of these dust particles were slight ly angular crystalline in appearance and about two microns or less in size) 40# were opaque of various sizes from about seven microns or less. There were a few small metallic shreds. L - LINDERliAU CUTTER GRINDER: Sharpens cutters from the Linderman machine for tongueing and grooving. Grinder uses a l/2" x 6" Norton Alundum (Grain 60,Grade N) cup wheel. Operating speed 3000 RPM. There is a hood guard over the top of the grinding wheel, but no exhaust or dust collector, although dust counts as high as 14,386,560 particles, ten microns or less, were found at the front of the grinder in operation, and 12,574,080 particles per cubic foot in the back. The average dust produced was 9,137,920 particles per eubio foot. About 70# of these dust particles are round semi-opaque in appearance under the Konimeter microscope, and three crons or less in size; 20# are round, globular like particles, seven microns or less in size; and 10# are metallic shreds about two microns wide and 20 to 30 microns long. There are many minute crystalline particles too small and too numerous to count aocurately. M - GANG SAW BLADE GRINDER: Uses a 5/8" x 10" Grain 50, Grade M, Norton Company A1 undrum wheel, operating at 1800 RIM, A rather crude dust collector has been installed, but the average dust (8,760,320 particles per cubic foot) produoed by this grinder in operation indicates that it is inadequate. About 90# of the dust particles in samples taken during the grinding of a Gang Saw Blade were semiopaque in appearance and about two microns or less in size; 10# were black round, opaque, one micron or less in size. There were numerous minute black speoks too small to count accurately. N - EDGER SAW GRINDER: Uses a 3/8" x 8" Grain 60, Grade N, Norton Company Alundum wheel, operating at 1650 RIM, No hood or any other dust collector for this grinder. The low dust count, an average of only 453,120 particles, ten miorons or less per cubic foot, indicates that there is very little real need for such equip r.ent. The dust particles produced while grinding an Edger Saw Blade are angular crystalline, about two microns or less in size. 0 - CIRCULAR SLAB CUT-OFF SAW GRINDER: Uses a 3/4" x 10" Grain N, Norton eze96e -4 a- 'Company Alundum wheel operating at 1650 RH1, A rather ineffective dust collector has been installed, but the average-'hi gh dust concentration (10,931,521 particles per cubic foot) shows that it is inadequate. About 80% of the dust particles in samples taken during the sharpening of a Circular Slab Cut-off Saw were opaque in appearance, two microns or less in sirej 20% were sliglrtly angular crystalline, five microns or less in size. There were also a large number of minute black opaque particles. P - "HOG KNIFE" GRINDER: Uses a l-l/2" x 24" Carborundum wheel operating at 300 RR1. This grinder is completely enclosed by a metal hood, but the dust {ls dis charged onto the floor through an opening in the lower part of the hood. The average dust produced by the operation of this grinder is 1,869,120 partioles per cubio foot. About 75# of these dust particles were angular crystalline in appearanee under the Konimeter microscope and four microns or less in sizej 25# were round, black opaque, two microns or less in size. Q - CUTTER GRINDER: Uses a &-l/2" x 2-l/2n x l/2" Norton Alundum wheel (3846 X B 5). The amount of dust produced depends upon the material being ground as is shown by the followings t t t C C C C C STOOI 2978 Grinding a steel counter sink, " " " reamer............. 736,320 particles per cu, ft. 1,019,520 " """ The dust particles are about 98# opaque metallic in appearance and about one micron or less in size. What Precautions Should B_e Adopted For Safeguarding Those Who Use Grinding Wheels? Authorities generally agree (Jour. Indust. Eyg.Vol. VII No. 8 August 1925 p.351) that workers who habitually use grinding wheels will run but slight risk of developing pneumoconiosis if they use certified abrasive rather than sandstopewheels for all grinding operations and if the machines upon which the artificial abrasive wheels are mounted are properly hooded and excessive dust removed by suction. Control of Dust From Grinding, Polishing and Buffing Wheels. Exhaust systems for grinding, polishing and buffing wheels vary widely in design. In the case of grinding, the hoods used serve not only to provide means for capturing the dust but also act to protect the worker in case the wheel bursts. The chief difficulty to be overcame in grinding wheels, according to U. S. public Health Bulletin No. 217, "The Determination and Control of Industrial Dust" (1935), is the outward sweep of air, a fan action, due to the revolving wheel. This effect is very marked with high speed and rough wheels and is so strong that in many Instances it is sufficient to counter act the normal inward flow of air. The same effect exists with polishing and buffing wheels but to a less marked degree. Practically all industrial States have codes regulating the construction and dust connections for grinding, polishing and buffing wheels. They also regulate the air required for wheels of various sizes in terms of static suction in the connect ing ducts. These codes possess no uniformity. However, the requirements designated by State codes must be followed. In States where no codes have been adopted it is desirable to provide exhausts on all grinding wheels with a suction at the connection to the hood sufficient to produce a difference of level of at least two Inches of water between the two sides of a U-shaped tube. A number of the wheels have been provided with suction exhaust produced by a motor driven fan or a hood, with a twoinch pipe one end of which is immersed in a bucket of water. The dust is drawn in by the rapid revolution of the wheels (1750 RR1). This simple arrangement is particularly effective. Three samples taken near the discharge of a motor driven sucticn fan connected with the hood of 1-1/2" x 10" E E CZ E E E E E E E GZ i E E E * -%- ST00I2979 Alundum (Grit 46. Grade P) wheel while a tool was being sharpened had an average of 2,076,989 particles per cubic .-foot which would have otherwise been thrown into the machine shop atmosphere. As pointed out by Dr. W. Irving Clark in his paper "Dust Hazards and the Pre vention of Injury from the Same" read at a meeting of Government Officials in Indus try at Boston, Mass* on May 21, 1931, the most effective method of removing fine particles of duqt is by suction applied as close as possible to the point where they are generated and the amount of this suction is great enough to overcome the dis persing action upon the dust of the work being done. The velocity at the air duots of an efficient dust removing tube should be 1500 linear feet per minute. Quoting Dr. Clark* "Ho matter how well a workman is protected he should be kept under medical supervision and have a periodic examination of his heart and lungs. In addition, the X-ray should be employed freely in order to detect early signs of fibrosis in the lungs and to show ary signs of early pulmonary tuberculosis. In my experienoe with workers exposed to inorganic dust, non-silioous in charaoter, a yearly physical examination with an X-ray every second year after ten years exposure is sufficient but it must be remmbered that this is the result of work in a factory where the charaoter of the dust is relatively harmless and where excellent dust remov ing devices are installed on every machine where it la possible. Where free silica is present in large quantities the examinations should begin after two or three years exposure and an X-ray should be taken every year. Dr. Clark also states that men who are asthmatic, who suffer from chronlo bronchitis, or who have had pulmonary tuberculosis should not work at a dusty job. VII - HANDLING POWDERED OR PULVERIZED MATERIAL A large amount of powdered or pulverized materials are used in the treatment of petroleum products and boiler water and in the manufacture of greases inseo- ticides. In most cases approved respiratory protection is provided and its use re quired when handling the materials. Exposure to dust is usually intermittent ariH of short duration. Among the powdered or pulverized materials used in the refining of petroleum products and associated activities aret A - LIKE* Lime is extensively used in the hydrated form and to a much lesser de gree as lump quicklime. 1. Hydrated Limet Used in the preparation of lime soap grease and the manu facture of pressure gun and cup grease; also in the treatment of boiler feedwater to "soften it". It comes in fifty pound paper bags by railroad, usual ly about 1,000 bags to a car. According to a chemical analysis of a typical sample, hydrated lime contains* Fe203Al203.......................... CaO................................. MgO................................. Insoluble Silica Residue... .. 1.01 per cent. 11 n nn nn (Remainder mostly Moisture and Volatile Matter) Fl-om 150 to 350 pounds of lime are used per batch in the manufacture of greases. 396375 -50- Th sacks of lime are usually opened and dumped into the mixing kettle. Con siderable dust (as high as 34,890,240 particles less than ten microns per oubic foot in one sample) is produced by this operation. The average dust pro duced is 4,733,305 particles per cubic foot and the average exposure per batch is about five minutes. The number of batches made per week varies freni one to twenty-five. No respirators are worn by men dumping hydrated lime at any of the points where it is used with the exception of Baton Rouge where the wear ing of the MS.\."Comfo" respirator is required. About 85)2 of the dust particles in samples taken while dumping lime in mixing kettles are slightly angular, slightly opaque, crystalline, in appearance under the Konlmeter mlc rose ope, end five microns or less in sites 15% are rounded, semi-opaque, with a metallic greyish color, ten microns or over. There are also a countless number of very small particles. Only a small quantity of Hydrated Lime is used in the treatment of boiler feedwater. About 70 pounds of lime is mixed per batoh and about six batohes are made every day (24 hours). The mixing is done by one man on eaoh shift. Although the exposure is very short, the men at Ingleside Refinery wear Willson "Dust-tite" respirators while dumping lime. The average dust produced during this operation is only 657,024 particles, ten microns or less, per cubio foot. This low dust concentration is the result of a spray of water from a two inch pipe across the hatch of the mixing tank just below the opening while sacks are being dumped. Consequently, the material is wet almost as soon as the lime is introduced. About 95?J of the dust particles in samples taken while the lime was being dumped into the mixing tank were semi-angular crystalline in appear ance, and from five microns or less in size, and 5% were round opaque, two miorons or less in size. 2. Lump Qulcklimet Used to "soften" boiler feedwater. The lime used for this purpose is Oyster Shell Lump Quicklime (97^ CaO). It comes in fifty pound paper-lined burlap bags, and eight bags are usually used per batch. One batch is made per shift. The dumping and mixing requires about ten minutes per batch, and the man doing this work is protected by rubber type goggles, but no respi rator. The average dust produced by handling the bags of lump Oyster Shell Quioklime is 2,605,440 particles per cubic foot. The average dust produoed while dumping the bags of lump Oyster Shell Quicklime into the mixing tank is 294,528 particles, less than ten microns, per cubic foot. The handling and dumping of this Oyster Shell Quicklime produoes less dust than is produoed by the hydrated lime usually used. About 95% of the dust partioles in samples taken during the duaping of Oyster Shell Quicklime into the mixing kettle ap- pear slightly angular, crystalline under the Konlmeter mlcrosoope, are five microns or less in size) 2% are round, semi-opaque, over ten microns in sizej and 1% are black opaque scale-like, five microns or less in size. What Physilogical Effect is Produced by Lime Dust? According to the Inter national Labor Office (Occupation and Health, Vol. II, 1934) particles of lime mix with the sweat of workmen handling it andirritate the uncovered pores of the skin; lesions of the mucous membranes arealso set up. We are told thatt "The aotion of quicklime is duepartly to its avidity for water (dehydration), to the heat given off in its reaction with water, and partly to the peculiar causticity of the alkaline oxides or alkaline earths. Quicklime exerts essentially a local action (on the skin and mucous membranes) irritating and caustic, which is naturally less marked in the case of slaked lime. Milk of lime is a feeble caustic acting only on the mucous membranes. The dilute lyes are only caustic to the skin after prolonged ac tion and especially when they are warm. 396376 stoo129801jj u u u u u u u u u u u ^ ^ " inririiT jnuT iT J'u t fc fc -51- r9 00 I 298 I "In practice it is the dust of quicklime and slaked lime, given off in the course of manufacture and manipulation, which gives rise to the well known lesions. This very fine dust is deposit ed readily on the mucous membranes and skin. When inhaled it may penetrate as far as the respiratory traot. " Although lime has a tendency to irritate the mucous membranes of the respira tory tract, it. is not considered particularly hazardous when breathed in small quantities at intermittent intervals. However, complications may result when a large amount of*the dust is breathed more or less regularly. Therefore, it is desirable to wear an approved respirator such as the MSA "Ccmfo" or the Willson "Duat-tite". - METALLIC ZINC DUST; Metallic zinc dust (90% through 300 mesh) is an impo. iant constituent in Pipe Thread Coating Compound. About 1500 pounds of this material is used per batch, and about fifty batches are made per month. The zino dust comes in 400 pound wooden kegs or 500 pound steel drums. According to a chemical analysis, this zinc dust is 99. 20^metallio zinc and 0,60% zino oxide (ZnC). The partlole size distribution of a typical sample as determined by a standard screen analysis 1st All through 120 mesh soreen 3, 76% retained on 200 mesh 2.04% " B 250 " 22. ?A% " " 325 " The zinc dust is dumped from the keg or drum onto a metal sheet in front of the ket tle and shoveled into the kettle by two or three men (with an average servioe of about three months) from the General Labor Department. This is a very dusty opera tion. One sample taken during the shoveling of zinc dust had as high as 68,760,960 particles per cubic foot of air the average concentration being 28,331,328 par ticles, less than ten microns, per cubic foot. The workmen are exposed to this dust about thirty minutes per batch or approximately 2-l/2 hours per month. They wear dust respirators. About 95% of these dust particles are dark grey, opaque, ng-nlo-r in appearance under the Konimeter microscope, and about five microns or less in size; 5% appear slightly angular, crystalline, ten microns or less in size. The crystalline material is probably zinc oxide. What Physiological Effect is Produced by Zino Dust? Although zino oxide (ZnO) produces definite physiological effects, metallic zinc dust does not seem to affeot the person breathing it other than that caused by the inhalation of ajjy inert dust. Nevertheless some investigators are of the opinion that zino is not entirely inert and harmless. Certainly it is not as harmful as lead or arsenio, but the Uhited States Public Health Service has certain limitations on the amount of zinc that is permitted in drinking water. According to Nuck, E. Reray, and F. Foltzmann (Jour. Indust. Hyg. , Vol. 12, 1930, page 171 Ab. ) Zinc dust can cause lung trouble after being inhaled in large quantities. Zinc dust is also very definitely explosive. C_ - ASBESTOS "FLOAT"; Float asbestos is used in the manufacture of tractor lubri cants. It comes in 150 pound cloth bags by railroad, about 2000 bags to a car. From 200 to 3000 pounds are used per batch and from two to fifteen batches are made per month. The bags of asbestos float are dumped into the mixing kettle by three men with an average service of twelve years. These laborers are exposed to dust about forty minutes per batch. Dust concentration as high as 8,269,440 particles, ten microns or less in size, per cubic foot are produced during the dumping of as bestos float, the average being 3,058,560 particles per cubic foot. About 96% of these particles are slightly angular, round, transparent in appearance under the Konimeter microscope, and two microns or less in sizej 2% are round, saai-opaque. 396377 -52- plate like, five microns or over in site. ' v Recent investigations have indicated that the inhalation of asbestos particles ten microns or less in site is even more hazardous than was originally believed, and that in order to prevent harmful effects concentrations should be kept below five million particles (10 microns or less) per cubic foot. The physiological effects have already been discussed under "ASBESTOSIS" so need not be given any further con sideration. -Men handling asbestos float should be required to wear approved respi rators. D - GROUND MICAi Ground mica (80 mesh) is used in the manufacture of axle grease. It comes in 100 pound burlap bags. About fifty pounds of ground mica is used per batch and an average of five batches are made per month. The period of exposure will not exceed ten minutes a batch. Handling ground mica produces an average of 2,577,120 particles ten microns or less in sire, per cubic foot. About 60# of these particles are transparent Irregularly shaped scale like in appearance under the Konimeter microscope, and five microns or less in size; about 4C# are over ten crons in size. The transparent plates have small lines or fissures appear to contain small air bubbles. Although ground mica has never been considered a hazardous dust, seme recent studies made among the workers in North Carolina Indicate that continued exposure to large quantities of ground mica over a period of years will produee a fibrosis. How ever, there is very little probability of any trouble where concentrations are kept below 10,000,000 particles per cubio foot of air and where the exposure to jaioa-dust is such a small percentage of the employee's working time. E. - SULRHUKt Sulphur flour is used for sulphurizing cutting oils awl in the preparation of special lubricants for hypoid gesus. Crude sulphur is used in the manufacture of sulphuric acid and in the treatment of gasoline and naphtha for re moval of impurities such as the mercaptans. Sulphur FI ourt Sulphur flour comes in paper-lined wooden barrels, 100-pound cloth bags, or 150-pound burlap bags. About 2500 pounds of this sulphur is dumped into the melting kettle by two men with an average service of twelve years, once a day. Their exposure to the dust which results from handling and dumping the bags, an average of 1,540,608 particles, ten microns or less, per cubic foot, is about fifteen minutes per man per shift an an ave rage. No goggles or respirators are worn. About 90# of the dust particles in samples taken during the dumping of the sulphur flour were slightly angu lar crystalline in appearance under the Konimeter microscope, and five mi crons or less in size; 10# were semi-opaque, rounded, and over five microns in size. The larger particles appear to contain small air bubbles. There were also a number of very small specks. About 370 pounds of flour sulphur is used per batch in the preparation of hypoid gear lubricant. Two batches are made per week on an average. The exposure to the sulphur dust is only about two hours per week on an average. Since the sulphur is dumped into drums of oil being agitated by a rapidly revolving propeller type mixer more dust is produced than where the bags are simply dumped into a kettle. Samples taken during this opera tion had as high as 6,910,080 particles, ten microns or less in size, per cubic foot. The average was 3,783,552 particles per cubio foot. The dust particles had the same characteristics as those given in the preceding paragraph. Crude Sulphur? Crude sulphur comes in box cars holding about 90,000 pounds, usually from Freeport, Texas. Towers are filled with this sulphur by four oo ^ CD CD CO ST00 I 2982 b iu u iJ -53- aen with an average service of eight years. It requires about two hours to fill a tower with about 1Q,000 pounds of crude sulphur. Two towers are charg ed every week. Consequently, the men are exposed about four hours a week to the sulphur dust caused by breaking up the lvsnps (4,304,640 particles, ten mi crons or less, per cubio foot) and shoveling the crude sulphur into the tower elevator (an average of 3,357,640 particles per cubio foot). The amount of dust produced by this operation is somewhat reduced by the ateam turned on izw side the elevator shaft to prevent dust explosions. About 60# of the dust particles in samples taken while the tower was being filled were slightly Tg1*lar crystalline in appearance under the Konimeter mlcrosoope and five microns or less in site) 35# were rounded semi-opaque, ten microns or over in site; aai. .5# were opaque scale like, between five and twelve miorcns in size* Sulphur dust particles are explosive but otherwise are not considered hazard ous any more than any of the other "nuisance" dusts, although they will irritate the muoous membranes and the eyes after slight exposure. Consequently, it is advis able to wear rubber type goggles and approved respirators, suoh as the MSA Ccmfo type. In an artlole by Aldo Cestari (Arch. Intern, fharmacodynamie, 1933, vol* 46, pp. 300-314) it is statedt "Intratracheal injection of sulfur suspensions brings about ex cretion of hydrogen sulfide in a period of 50 hours. There are slight exudative and infiltrative reactions in the lungs. It is supposed that a substance similar to glutathione reduces the sulfur to hydrogen sulfide." F - LITHARGEt Litharge is added to the Plumbite or "Doctor" Solution to assist in the removal of mercaptans, other sulphur compounds and unsaturated hydrocarbons from gasoline and naphtha. From one to five 600-pound drums of litharge are used in a batoh, depending upon the stock to be treated and the condition of the "Dootor So lution". The litharge is removed from the drum a shovel at a time, and about fifteen minutes are required to dump one batch. A batch is made once a week on an average. The average servioe of the men involved in this operation is seven years. They wear KSA Camfo respirators with an approved lead filter and rubber type goggles. All of the work of adding litharge is done in the open air on a platform at the tops of the solution tanks. The Average dust produced during the dumping or shoveling of litharge into the solution tank is 3,077,480 particles, ten mlorons or less in size, per oubic foot, although there were as high as 9,288,960 particles per oublo foot during the operation. A rough estimation of this litharge concentration indicates the presence of from five to fifteen milligrams of lead per ten cubic meters - the amount that an average person doing moderate work would breathe in one day. This is in exoess of 1.5 milligrams in ten cubic meters which is the maxima allowable limit set by the United States Public Health Service. About 80# of these dust particles were.rounded, transparent, crystalline in appearance under the Konimeter microscope, and five miorons or less in size) about 15# were over ten microns and appeared to contain small air bubbles) 6# were dark opaque scale-like, from five to ten microns in size* Necessary Precautionary Measures When Handling Litharge. Litharge is a caskpound of lead, and consequently there is the possibility of lead poisoning unless a few simple precautions are observed to prevent the entrance of lead into the body by swallowing minute particles of the litharge dust, by inhaling the dust, or by absorption from the skin when handling the litharge. An effort should be made to cause as little dust as possible. Instructions issued by the Medical Department re quire that* 396379 -54- "1. No employee shall handle litharge until he has been examined and certified as jtfiysically qualified by the Company Doctor. "2. Eaployees must be sent to the Company Doctor for physical ex>> amination at least every six months or at the first sign of ill health. "3. Respirators - An approved type of lead dust respirator, proper ly adjusted, shall be worn when handling litharge. All respi rators shall be thoroughly cleaned with soap and warm water. "4. Clothing - Uhionalls, caps or some head covering and gauntlet gloves shall be worn when handling litharge. Upon the oampletion of this operation the outer clothing must be removed xnH placed in a locker used for this purpose only. Unions11s should be washed at least once a week. "5. Bathing and locker facilities - A conveniently located locker and was h room shall be designated for use of mployees haai ling litharge. Separate lockers should be provided for street clothes, work clothes, and one for Ualonalla worn when hand ling litharge. In plants where men are handling litharge throughout the shift, only two lockers need be provided. The floors of the locker roams where the men change their dust covered TJnionalls and the benches shall be thoroughly moisten ed before being cleaned, "6. Personal cleanliness - General personal cleanliness is of first importance. (a) Hands must be thoroughly washed on the completion of the litharge handling operation. Hands must also be thoroughly washed before eating or placing anything in the mouth. A special effort should be made to clean the finger nails so as to remove any litharge. (b) Never eat until litharge covered clothing has been removed and the hands washed. (c) Teeth should be brushed at least twice a day and the teeth and gums kept in good condition. (d) The mouth should be rinsed thoroughly before eating. (e) Never use tobacco in any form while working in and around litharge." The responsibility for the careful observance of ALL of these instruc tions should be placed upon the foreman. G_ - SODA ASHt Soda ash {58% Na20) is used to form a solution for neutralizing acid oil. Thirty 200-pound cloth bags of soda ash are dumped into a tank of water per batch by six men, with an average service of five years, from the General Labor De partment; three batches a wee'r. Men exposed to dust resulting from opening and dumping the bags of soda ash lbout five hours a week. Eight men spend about half a day a month unloading bags from railroad box cars. The men who do the unloading wear MSA Comfo respirators and are not the same men as those doing the mixing who do not wear any respirators or goggles. The average dust produced by the dumpine ar>H 396380 c t t t c/> --I CD CD PO cO 03 " C tz .55- s86z inn is mixing operation is 1,003,337 particles, less than ten microns, per cubic foot of air. These partioles are all slightly angular, crystalline in appearance under the Konimeter aioroscope and about five microns in size. Many are transparent, glass like. There are a number of small black specks. H, - TALC or "SOAPSTONE"t Pulverized talc or "soapstone" is used as a filler in the manufacture of "hot neck" greases used in the steel mills. According to R. B. Ladoo (0.S. Bureau-of Mines Bui. No. 213, 1919) ordinary talc or soapstone is Steatite (hydrous magnesivsn silicate - H2Mg3(Si03)4). In the form of powder, the talo is greyish white. Associate Chemist Frederick Goldman of the U.S. Bureau of Mines, who made a chemical analysis of samples of talc as marketed, reportst Si02................................. 46.04 per oent CaO.................................. 4.39 " " MgO................................... 28.20 " " Combined Oxides......... 15.64 " " Grease makers usually consider the composition of "soapstone" which they use as approximately 90# magnesium silicate and 10?! calcium carbonate. It comes in 90-pound paper bags, 700 bags to a box car. About 7200 pounds are used per batch and batch is made a day on an average. The "soapstone" is dumped into the mixing kettle by two men with an average service of ten years. This dumping which requires about an hour per batoh is a rather dusty operation. One sample taken at faoe level just after a bag had been dumped had as high as 22,995,840 particles, ten microns or less in size, per cubic foot of air. The average dust produced was 13,064,960 dust partides per cubic foot. About 98# of these dust particles were transparent, crystal line, Irregularly shaped plates and rods, in appearance under the Konimeter microsoope. Most of these particles (about 96#) were five microns or less in size, the rmainder being ten microns or over; about 2# were scal^like, semi-opaque, five mi crons or less in size. Physiological Effects Produced By Talo Dusts. About two years ago Dr. W. C. Dreessen, Passed Assistant Surgeon, and J. M. Dalia Valle, Assistant Sanitary Engi neer, United States PublicHealth Service, made a study to ascertain whether there is a connection between talc dust exposure and the relatively high tuberculosis death rate in Murray County, Georgia, where two talo mills and mines are located. They found (Reprint No. 1669 from the Publio Health Reports Vol. 50, No. 5, Feb. 1, 1935, pages 131-143)t "Physical and roentgenologic examinations were made of 66 men women who were exposed or had been exposed to talo dust. In the higher dust groups comprising 33 men, 8 were found to have Pneum^ coniosis I and 8 to have Pneumoconiosis II or III. Six of the thirteen examined were diagnosed as having Pneumoconiosis I. No advanced stages of the disease were found in this group. In the group exposed to low concentrations of dust, no Pnemoconiosis was found." The final conclusion of this study was that although Georgia talo appears to be "more injurious than tremolite talc" the high tuberculosis mortality rate in the County "oould not be attributed to the talc industry". Investigators have suggested, however, that for more or less continuous expo-sures concentrations of talc or "soapstone" dust should net exceei 15,000,000 par ticles, ten microns or less in size, per cubic foot of air. _I_ - GRAPHITEt Powdered graphite (80# to 85# graphitic carbon and 15# probably magnesium silioate) is used in the manufacture of sprin*' indicants. It 396381 -56- comes la metal drums or 100-pound paper lined bags. About 5700 pounds of powdered graphite is used per batch and tone batch is made per day on an average. The graphite is dumped into the mixing kettle by men with an average service of seven years. This operation requires about forty minutes per batch per on an average. Three men are usually engaged in this dumping. They wear respirators while hand ling and dumping graphite, which is not a particularly dusty operation. The average dust produced is 1,803,080 particles, ten microns or less, per cubic foot of air. All of these dust-particles are rounded or slightly angular, black opaque, amorphous, sooty or dark grey, in appearance under the Konimeter microsoope, and three microns or less in size. jJ - SLATE FLOURi Slate flour (300 mesh) gives rigidity to asphalt on "fast sur faces" such as steep roofs and pipe lines, and prevents its running off. It also produces desirable weathering properties. Mixtures as low as 10# slate flour and as high as 40# are used. An average of two tons of slate flour is used to each still which averages about 800 barrels of steam reduced asphalt. Since the slate flour is introduced by the use of closed pipe lines and centrifugal pumps, the only dust produced is that which results during the unloading of the sacks and dumping them into the hopper. The slate flour comes in 50-pound paper bags, 750 bags to a railroad box car. Four men with an average service of about a year, open the bags and dump the slate flour directly into a hopper from which it is siphoned by cac^ pressed air to a storage tank holding about 15 tons. About four carloads a month are received and an average of about 5-1/2 hours is required to unload each oar. About one and three-quarter million pounds were dumped during the last quarter period. The men wear MSA Camfo respirators. A screen analysis of this slate flour . showed that 99.7# passed through a 200 mesh soreen and 96.8# through a 325 mesh soreen. Due to the fineness of slate flour and its low bulk density (1.04) con siderable dust, an average of 12,007,680 particles, ten miorons or leas in size, per cubio foot of air, and counts as high as 16,538,880 partioles per cubio foot, are produced during dumping the sacks and filling the storage tank. About 98# of these dust particles are slightly angular, transparent, crystalline in appearaxxse under the Konimeter microscope, and five microns or less in sizej 2# are semi-opaque, slightly angular. There were a few plate like particles whieh appeared to contain small air bubbles, and a large nunber of small black particles. A petrographic examination made of a slate flour sample at the United States Bureau cf Mines Experiment Station in Pittsburgh, Pennsylvania showed that it con tained more than 1# Quartz (Si02) 30# Sericite (X2O-3AI2O3-6 S102-2H20), 40# opaque and 3C# five different unidentified constituents. A chemical analysis of slate granules and flour (Jour. Indust. Eyg.Vol.XV.,No. 2,Mar. 1933,p. 67) reports these constituents* Silicon. Dioxide . 5 9* 2 7% Titanium Dioxide. ..............0.99# Aluminum Oxide... Ferric Oxide..... ..............1.12# Ferrous Oxide ... Managanous Oxide. a 0. Calclua Oxide.... Barium Oxide..... Magnesium Oxide................2. 21# Potassium Oxide........ 3. 75# Sodium Oxide...................... 1.88# Water below 110C........... 0. 32# " above '* ........... 3.98# Phosphoric Oxide............. 0.11# Carbon Dioxide..................0.21# Ferric Sulphide................0.15# Specific Gravity - 2.795 "The silicon found, though expressed in the chemical analysis as silicon dioxide, is not differentiated chemically as to the forms present in the original minerals, whether free silica or silicate. " 396382 b u1 u z1 y y b I I t C I c I c t t c c c c c c c c c c E E -0 < STOOI 2987 Effect of Sl&te Flour on The Lungs - In his paper "Effects of Certain Silicate Dusts in the Lungs" read befijre the Industrial Hygiene Section of the American Publio' Health Association at Washington, D. C. on October 27, 1932, Dr. Waldesnar C. Dreeasen of the United States Public Health Service, reporting the results of his studies of workers exposed to Blate dust, vrrotet "Of the 48 cases of pneumoconiosis observed, all were in the first stage_except 5 cases. In general, the pneumoconiosis observed in the early or first stage cases resembled that induced by cement dust..-The bronchial striations, however, were somewhat more promi nent. There was always a moderate bilateral increase in the size and density of the hilar shadows with aecentuations of bronchial striations which extended well out into each lung field. The linear striations seemed "softer" in appearance and lacked same of the sharpness of detail which is usually observed in the X-rays of individuals who have inhaled silica dust. This diffuse, fine generalized fibrosis was chiefly confined to the lower two-thirds of the lung fields. "In the second stage an increased prominence of the above mentiozved characteristics was present with the appearance of flake like, dappled areas of increased density in both lung fields. In the third stage these dappled areas seemed to conglomerate, and in this manner gave way to massive, clouded areas of increased density." Dr. Dreessen found that although the silicate dusts of slate "induce a fine diffi&e, bilateral fibrosis of the lungs which is definitely demonstrable in the X-ray" workers exposed to slate dust do not begin to show definite first stage pneumooani^ sis until after more than ten years* exposure. He did not find any evidence that the resultant pneumoconiosis had led to disability. K - GRINDING PERRIS ROOTt Perris root is used in the manufacture of insecticides. It comes in 500-pound bales from the Dutch East Indies. In order to reduce dust, the bales are thoroughly wetted with white oil. The root is ground at the rate of 500 pounds an hour to pass through a 3/8"-screen. One man with three years* seryioe is exposed to an average dust concentration of 1,604,800 particles, ten microns or less, per cubic foot of air. About 80% of these dust particles are rather round, crystalline in appearance under the Konimeter microscope, and about five microns in size; 20% are sharply angular, five microns or less in size. The particles appear to be more inorganic than organic in character. Evidently the lighter root dust particles are either larger than 30 microns and were, therefore, filtered out by the Konimeter filter or were carried out by the exhaust ventilation, thus leaving the dirt or soil which had adhered to the roots. The grinder is located in a small room well ventilated by means of a 30-inch motor-driven fan. This explains the low dust concentration in the samples taken during the grinding operation. The operator wears rubber gloves, cover-alls, and is provided with a fresh air hose type of mask while grinding. To 'rhat Extent is Perris Toxic? According to recent studies by the United States Department of Agriculture (Indust. & Eng. Chem. Vol. 28, No.7, July 1936, pps. 815-821) Derris is a possible health hazard to those engaged in milling, grind ing, and diluting it (Perris) without the use of suitable protective measures. Pharmacological studies show that Perris and its water extracts affect the respira tory center which is initially stimulated and then, after fatal doses, completely depressed, with death resulting. Perris dust when applied to the armpits was also found to provoke a "mild evanescent irritation." L_ - :::g FrRirHRUK PLOV.TRS: Pyrethrum flowers are an important source of one 396383 -5&- R R 6 ? I fl H I Q 396384 n n n n n n r t n n n n n n i of the essential ingredients of insecticides. They come from Japan in mat covered bales weighing about 450 pounds. On an average, about ten bales are ground per shift. Opening the bales of compressed flowers is the dustiest part of the opera tion, producing or. an average 2,039,040 particles, ten microns or less, per cubio foot of air. About 85% of these particles are angular, crystalline in appearance under the Konimeter microscope, and three microns or less in size} about 15% are flat round particles and discs and shreds, ten microns or less. The crystalline -- appearing dust probably originates from the soil which has blown on the flowers or plants. One man. is exposed per shift for about four hours a day during a nine month, period. Ee wears a Willson dust respirator. The grinder is enclosed in a metal housing connected by a fourteen-inch duct to a sixteen-inch motor driven exhaust fan. Pyrethrum dust seems to irritate the skin of some individuals and not affect others in the least} as a matter of fact it causes an allergic type of reaetion in some individuals to such an extent that it is inadvisable for such persons to work in pyrethrum dust. M - MIXING AND PACKING "FLIT" POWDER; "Flit" powder is a mixture of pulverized derris root, pyrethrum flowers and other ingredients. It is mixed in a speoial room provided with exhaust ventilation by a man wearing a respirator. The dustiest part of this operation is sifting the pulverized derris and pyrethrum vdiieh produces an average of 8,722,560 particles, ten microns or less, per cubio foot of air. About 35% of these dust particles are angular, crystalline in appearance under the Konimeter microscope, and about three microns in aizej about 5% are less crystalline and more opaque, five microns or less in size. Filling Cans; Three-quarter and two and one-quarter ounce tin cans are fill ed by automatic machines, the filler ends of whioh are enclosed in a metal housing with a four-inch exhaust duct to a fourteen-inch motor-driven fan. That this ex haust arrangement is fairly effective is shown by an average dust concentration in samples taken at face level of the operator during the filling operation of 1,755,840 particles, ten microns or less, per cubic foot of air. The girl at the Sealer wears a bag-type dust respirator. VIII CLEANING TUBES AND DRUMS CONTENTS Cleaning tubes and drums of boilers and process equipment is a routine opera tion which produces considerable dust belonging more to the "nuisance" class than to the fibrosis causation group. Nevertheless, consideration should be given to keeping such dust down to a minimum of not more than 10,000,000 particles per cubic foot due to the number of men engaged in this work and their more or less continuous ex posure I 1 I I t I. - CRACKT'U COIL SOAKING DRUMS; Cracking coil soaking drums "coke-up" about once a month, so that in many cases they are almost completely filled with the ex ception of an opening down through the center no greater than twelve inches in diasw eter. At most plants, this coke is removed by a special machine} at -the others, men with an average service of ten years are regularly engaged in cleaning these drums by means of a concrete buster type of pneumatic chisel, starting at the top of the drum. One man works inside and two outside at the top manhole. The temperature inside the drum is about 90 degrees Fahrenheit. Each man works half an hour inside and is then relieved for about an hour. On an average, each man works about two and a half hours per shift, two shifts a week. A "boatswain" qhair is used to get in and out of the drum. They wear "hardboiled" hats and life-belts. Excellent ventilat:.on is provided by a 3-lean or an air syphon placed in the bottom manhole of the drum, as a result of which samples taken at face level of men during the operation of the pneumatic chisel had an average of only 311,520 dust particles, ten microns or less, per cubic foot of air. About 60>. of these particles were sharply angular, crystalline in appearance -59- S T 00I2989 under the Konimeter aicroscope, and about five microns or less in size) 35/C were round, semi-opaque, crystalline, about ten microns or over) and about 5% were smell black particles. There were 'also a few black scale-like particles over ten microns in size. The major portion of this dust is probably coke or carbon and the sealelike particles are. no doubt, metal from the sides of the drum or Aram the chisel. II. - CRACKING COIL TUBESt There are 183 tubes in a high pressure cracking coil unit. After running from twenty to twenty-five days, depending upon the char acter of the stock being run, the temperature and pressure, the petroleum coke whioh is deposited on'the tubes must be removed. Liberty air-driven tube cleauiers with cone and star cutters operated by men with an average service of six years are used for this purpose. The men work in gangs of six to eight and are exposed to dust about six hours every two shifts on an average. They wear neither goggles nor respi rators although a dust samole taken immediately after reversing the cleaning machine while in a tube contained as high as 9,062,400 particles, ten microns or less in size, per cubic foot. About 30% of these dust partioles are black, opaque in appearance under the Konimeter microscope, and two microns or less in size; 40% are angular, transparent, plate-like, ten microns or larger) and 30% are angular, transparent crystalline, five microns or less in size. Samples taken on the Cleaning Platform while cleaning Cracking Coil Furnace tubes at a Northern refinery had an average of 113,280 particles per cubio foot. Ninety-eight per cent, of these dust particles were rounded crystalline in appearance under the microscope and five microns or less in size. Samples taken in the passage way back of the furnace while tubes were being cleaned had as high as 1,076,160 particles, ten microns or less in size, per cubic foot of air. This indicates that the men in the passageway, back of the furnace are exposed to more dust thsui those on the cleaning platform. III. - WATER HEADERS AND BOILER TUBES> Tubes and headers are cleaned twioe a year by means of air-driven turbines. It has been found that cleaning can be done more effectively if done dry rather than wet because the dust can be blown out. If ~ water were used, the loosened material would soon form a paste which-would be smear ed back on the tubes by the action of the cleaning turbine. Regardless of the dust which is produced in concentrations as high as 30,359,040 particles, ten microns or less in size per cubic foot of air, workmen prefer working in dry drums rather than in wet ones. Eight men (two on each turbine) are engaged in this cleaning operation which requires about twelve days a year. Men with an average service of fifteen years are assigned to this job from the Labor Department. The temperature inside of the drums or headers is about 70 degrees Fahrenheit. In accordance with the usual prac tice, men operating the turbines, inside the drum or header, work about ten minutes end are relieved for ten minutes by their co-workers who assist in handling the air hose in and out of the drum manhole. Respirators have been provided in most oases but are not always worn. The average dust produced while cleaning water-headers and boiler tubes in samples taken fromt Lover Platform, Front Water Header................................... IB,306,048 part, per cu. ft. In #2 Drum While Cleaning '..'ater Wall and Tubes.... 5,664,000 n " " Inside Manhole Drum #3 While Being Cleaned.................28,320,000 " "" About 40% of the dust particles in the samples taken on the lower front water-header platform, while header was being cleaned, were rounded, dark red in appearanoe under the Konimeter microscope, and about two microns in size) 50% were opaque, more or less angular, and about five microns in size; 10% were crystalline, slightly angular,' and over ten microns in size. About 65% of tho particles in the sample taken inside .'-2 drum during cleaning were black, opaque, angular, less than two microns in size) and about 15% were round, more or less opaque, over ten microns. The concentration of dust INSIDE the dr*na during cleaning appears to decrease with the distance from 396385 -60- the manhole as is demonstrated by these oounts in samples from Drum 2 (Riley Boil er)** Location Particles per cu. ft. Inside Manhole. About 8 ft. Inside Drum. n 11 fl . it n ft 18 n " n n ! 24 n * ii n 19,257,600 4,078,080 2,265,600 1,585,920 1,132,800 The dust particles frcan inside the drum appear black, angular and were less than two microns in sice. The dust frcan these cleaning operations are supposed to be largely the results of metal corrosion and sediment (largely Calcium Carbonate and Calcium Phosphate) deposited by the treated Boiler Feed Water. A petrographic examination of a sample of dust from the Front Water Wall Header was made by the United States Bureau of Mines Experiment Station at Pittsburgh, Pennsylvania, who reported: Quartz (Si02).......................................................... Opaque or Coated with Opaque Material.. Unidentified Clay-like..................................... 1 per cent. 90 " n 9" n According to a chemical analysis of this same material made by a regular re finery chemist using the method of Adolph Knopf, U. S. Public Health Service, the dust oontained* Free Silica............................................................ 0,70 per cent. Combined Silica............................................. ...41.01 " " Although the analysis of the dust shows a low free silica content, the high dust concentrations found and the possibility that- at times such concentrations may be higher than those found, demonstrate the desirability of wearing respirators re gardless of the kind of dust encountered. IX - FOUNDRY OPERATIONS During recent years considerable attention has been focused upon the health of foundry workers by the operation of the so-callod "Silicosis Racket" which has ex tracted large sums of money from the Foundry Industry. It is difficult to isolate this type of work which gives rise to a very general exposure to dust which may iavolve all workers employed in the foundry. In many cases the worker is in such close contact with the duty atmosphere as to cause serious exposure. Much progress has been made in reducing the dustiness of our foundry operations and plans are now being considered which will further safeguard our foundry workers. The following is a brief outline of foundry dust producing operations* A. - POURING MOLTEN METAL INTO SAND MOULDS - About 19-1/2 tons of metal are poured per "heat". Thirty-five men with an average service of twelve years spend about one and a half hours pouring and six and a half hours moulding per day, five days a week. Goggles, asbestos leggings and congress-type shoes are worn by the men handling the molten metal. About 60% of the moulding sand, which is the principal source of dust, is free silica (Si02). During the pouring operation the foundry air appears to be full of dust and smoke, however, samples taken during this work aver aged only 396,480 particles ten microns or less in size per cubio foot of air. Praotdcally all of these dust particles appeared angular, crystalline under the Konimeter microscope and were about two microns or less in size. A sample of dust from the top of the crane rail over the moulding floor was 396386 S T 00I2990 1 I I L E E C C c c c c c c c E E E E C e: -61- given a petrographic examination by the U. S. Bureau of Mines Experiment Station in Pittsburgh, Pennsylvania who ^reported 50# quartz (SiOgb 155? Clay Mineral not com pletely identified. Kaolinite is AI2O3. 2 SiO 2. 2H2O* 5% Calcite (Ca CO3 ) and 30# Opaque. B. - "SEARING OUT" CASTINGS - After pouring, the castings are allowed to cool, then the moulds are liberally sprinkled with water from a hose. The bands or clamps are removed and the flask is thrown over and broken open. The rough eastings are pulled out,.piled up and trucked to the Cleaning Roam. "Shaking Out" is cox>sidered one of the serious occupational disease hazards encountered in industry the dustiest operation in founderies but due to the thorough wetting and careful handling by the men, samples taken during the operation had an average of only 858,230 dust particles ten microns or less per cubio foot of air. The impinger method would no doubt reveal much higher counts. About 98# of the dust partiolos were slightly angular crystalline in appearance under the Kaniaeter microscope and were one micron or less in size. "Shaking Out" is rather hot work, the men pez^ spire freely so that it would be difficult to enforce the wearing of goggles and res pirators. Twelve men with an average service of eig^it years work on this Job, eight hours per shift, five shifts per week. C/5 --I CD O PO CO VO After the castings have been removed the moulding sand is again wetted thoroughly worked over with a motor-driven sand cutter which is a series of revolv ing blades, similar to those on a lawn mower, operated by an electrio motor, mounted on a rubber-tired four-wheeled carriage which moves back and forth over the moulding floor. Moisture tests are made and viien these tests indicate 4.6 to 5.6 moisture the sand is considered ready for the moulders. During the operation of this sand cut ter, the operator is exposed to an average dust concentration of 1,529,280 partioles ten microns or less per cubic foot. These particles were less than twc microns *wd were slightly angular crystalline in appearance under the Konimeter microscope. C. - CLEANING CASTINGS - Various methods are used to clean castings depend ing on their size and shape. All of these methods produce more or less dust sane of which can be taken care of by exhaust ventilations, others cannot. The methods most commonly employed are? (a) Preliminary Cleaning - Castings are brought from the moulding floor during the night and deoosited in the Cleaning Room. The following morning the cores are knocked out, the sprues and gates are broken off and same scratch cleaning is done. This work produces considerable dust especially when the sand and old cores are shovelled through the ,-rating into the car or bucket below (3,455,040 particles ten microns or less per cubic foot of air). Under the Konimeter microscope about 10% of the dust particles appear angular, crystalline, three microns or less in sizej 20# were rounded crystalline, five microns in size and about 5# were scale-like sesni- opaque with a reddish-brown tinge and over ten microns in size. Pulmosan Respirators have been provided but are not always worn by men doing this work. NO attempt has been made to control dust from preliminary cleaning although same study has been given to the provision of a special air-tight roam with a grating flocr and a hopper underneath with a screw conveyer at the bottom to convey the debris to the disposal car or bucket and thus eliminate the dust-producing shovelling and handling. Under this plan exhaurt ducts with a series of outlets around the top of the hopper carry off the dust. Air is also introduced into the room about a man's breathing level the amount of air taken out is ,nreater them that introduced so that a negative pres- sure is maintained and a complete air change is made about every three minutes. to O) 00 (b) Tunblast - The Tunblast is a machine which combines tumbling with air bias4 inz. Prom 400 to 1500 pounds of castings are put into a drum which revolves about 10 They run from about 20 minutes to four hours, depending upon the type of castings and cleanliness required. While the castings are being tumbled they receive -62- \ a blast of #20 Steel shot through three 5/l6 inch nozzles under an air pressure of B5 pounds per square inch. Thie machine is operated by three men, with an average service of eight years, for a period of two and a half hours per per day, five days a week. Pulmosan Dust respirators are provided but are not always worn. A ten-inch exhaust pipe has been installed at the top of the machine and a six-inch exhaust pipe over the screen. The suction on these exhaust pipes is said to be about 2-l/2 inches water. Samples taken during the operation of this machine aver- aged 1,200,760 dust particles, ten microns or less in size, per cubic foot whioh ixk> dlcates that the dost control measures which have been provided sure getting results although there is still room for improvement. About 98# of the dust particles ap pear quartz-like under the Konimeter microscope) about 60# are five microns or less in size and are angular crystalline in appearance; 40# are ten microns or over in size, and rather rounded in appearance. There are also a large number of minute black metallic specks entirely too small and numerous to count accurately. ST00 I 2992 I I 1 (0) Sly Tumbling Kill - Cleans brass castings by a combination of tumbling und air-blasting with ,r3 Sand Blast Sand and 85 pounds per square inch air pressure. The Kill holds from 100 to 1500 pounds of castings and cleans five loads a day. Two men , with an average service of 15 years, operate this mill which runs about five hours a day. They wear Pulmosan Dust respirators and -oggles *dien opening the machine. This Kill is hooded with an 8-inch exhaust pipe having a 2-inch water suction, also a 10-inch exhaust pipe over the sand screen at the rear of the machine. Samples of dust taken during the operation of the Sly Tumbling Kill had as high as 2,492,160 particles ten microns or less in size per cubic foot of air and an average of 1,393,344 particles per cubic foot. About 90% of these dust particles were rounded' crystalline in appearance under the Konimeter microscope and two microns or less in size; 5% were black, opaque scale-like and 5% were rounded crystalline about five microns in size. (d) Tumbling Barrels - 36" x 42" Whiting Tumbling Barrels remove sand frcmcast ings. They hold from 1200 to 1500 pounds of castings per load nH revolve at 10 RPK. The castings are tumbled about two hours with about 700 pounds of one-inch unanneal ed cast malleable iron stars and jacks. An exhaust system with a 6-inch pipe through the trunnion having a suction of 1-1/4 inches water. This suction has been found inadequate to give the desired results consequently the suction is to be increased to 4-inches water. Samples taken during the operation of the Tumbling Barrels had an average of 1,348,032 dust particles ten microns or less in size per cubic foot of air. About 90# of these particles were angular crystalline in appearance under the Konimeter Microscope and three microns or less in size; about 10# were rounded sonicrystalline, ten microns in size. There were also a few triangular-shaped opaque metallic particles. Three men, with an average service of twelve years, operate these tumbling barrels eight hours a shift, five shifts a week. Pulmosan Dust Proof respirators and goggles have been provided but are not always worn. The type of Tumbling Barrels being vised has been condemned by a major campany because it is impossible to ventilate it properly. The holes in the end liners clog up when the barrel starts revolving, thus preventing circulation of air through the barrel. This condition has been remedied, in a new design now on the market, by the use of two shells - an inner perforated and an outer solid shell. Both trun nions are hollow and are connected with the air chamber between the two shells. Air under pressure is introduced through one trunnion and exhausted through the other. c c c c c c (e) Air-Blasting - Castings which cannot be tumbled due to their size and fragility are cleaned by air-blasting (85 pounds per jqvare inch) with mixture of approximately half and half sand and #40 Steel Grit. Syracuse Core sand is used when a special finish is desired. There are three men, with an average service of three years, on this job who v/ork 45 minutes of every hour, eight hours a shift, for one v/eek out of three weeks. This work is done in a special tight air conditioned room 00 1 ^` CO ^ c e G 662I001S .} while wearing a Sly Sand-blast Helmet supplied with outside fresh air provided by a special blower used for that .purpose only. Samples taken inside the room while a casting was being air-blasted had an average of 3,738,240 dust particles ten microns or less per cubic foot of air. About 80/5 of these dust particles were sharply angular crystalline in appearance under the Konimeter microscope and three microns or less in size; 20% were rounded quartz-like crystals about ten microns in size. There were also a few rust-like scales and a large number of black metallic particles too minute and too numerous to be counted accurately. The silicosis hazard of this opera tion could be greatly reduced by the use of steel abrasives exclusively. (f) Hough Snagging Wheels - These aachines are used for removing projections such as sprues, parts and gates from castings. There are two types of these wheelsi the DOUBLE END using either 19-1/2" x 3" Carborundum and Vitrified or 24" x 2-1/2-" Rednanol (Bakellte bound) Wheels; and the HORIZONTAL DISC Grinder having a 50" ' diameter vitrified wheel. These wheels are used by seven men having an average service of nine hours per shift, five shifts per week. Each wheel is hooded nrf has a four-inch suction pipe. There is an eight-inch suction pipe on the EorizontsLl Grinder. Goggles and respirators are provided but the latter are not always worn with the exception of the men on the Horizontal Grinders. Vitrified wheels are run at a slower speed (1800 RFK) than the Bakellte Bound Wheels which operate at 3400 RRL Samples taken during the operation of the Rough Shagging Wheels had the fol lowing dust concentrations. Double End Snagging Wheelsi Average Dust from Vitrified Wheels............ " " " Carborundum " ...... * n Bakellte Bound Wheels. 3,653,280 particles per cubic foot 3,322,820 * """ 2,662,080 " "n Horizontal Dlso Grindert Average Dust from 50" Vitrified Wheel............. 2,124,000 particles per cubic foot The average dust produced by all the Rough Snagging Wheels was 2,322,820 particles, ten microns or less in size, per cubic foot of air. About 80# of the dust particles from the vitrified wheels appeared black angi>lar opaque under the Konimeter microscope and two microns or less in size; 20# angular crystalline -about one micron or less. There were also a large number of black minute particles too small and numerous to count. The dust particles iVom the Hori zontal (Vitrified) wheel were approximately 90# angular, crystalline and 10# black opaque. All of these particles were about two microns or less in size. About 60# of the dust particles from the Bakellte bound wheel were black angular two microns or less in size;" 25# were angular crystalline, less than one micron in size and about 15# v/ere rounded crystalline about five microns in size. (g) Fine Snagging and Polishing Wheels - These wheels grind off small projec tions and remove rust from stock which has been in storage. There are three typesi DO'JELE 4" x 14" POLISHING EERY WHEELS - Wheels after being made up are dipped in glue and then rolled in Alundum Grinding Grain, sizes 60, 80 and 120 mesh. DOUBLE DISC GRINDERS - 36" discs covered with Cast Iren Grain or Silicon Carbide (an electric furnace product) and V.'IRE SCRATCH BRUSHES - made up with four 12" sections. Exhaust hoods with a suction of from three to five Indies water, have been installed on the Polishing Wheels and Disc Grinders. There is NO hood on the Wire Scratch Brushes. These wheels are used by four men with an average service of two years. They wear goggles and gloves but no respirators. Samples taken at face level during the operation of this equipment had the following average dust concentrations! 396389 .64- Dust Produced by 36" Disc Grinder.......................... 1,416,000 particles per cubic foot " " " 12" Wire Scratch Brush........... 736,320 " "" " " " 4" x 14" Polishing Wheels.. 481,440 " """ These comparatively low dust counts indicate that the dust control measures which have been provided are either effective or the dust particles produced are ever 30 microns in site and were thus filtered out by the Eonimeter filter# Under the microscope dust particles from the Polishing Wheels appeared all round crystalline and about one micron'in size. About 40# of the dust particles produced by the Double Disc Grinder were sharply angular, opaque about three microns or less in sizej 60# were less angular crystalline about one micron in size. The dust particles produced by the Wire Scratch Brush were all rounded, crystalline and about one micron in size# There were no metallic particles in any of the samples examined# Pew exhaust hoods have been installed on Wire Scratch Brushes because it has been generally assumed that these brushes did not produce any dust# This assumption, however, is untrue as one sample from a wire brush at a Southern Refinery had as high as 6,683,520 par ticles ten microns or less per cubic foot of air# (h) Cone Grinding Wheels - These wheels are operated with compressed air are used to do miscellaneous grinding on castings by four men, with an average sez>vice of twelve years, about two hours a day on an average. The cones are 5-l/4" x 3-1/4" vitrified and produce an average dust of 1,869,120 particles ten miorons or less per cubic foot of air. About 80# of these particles are sharp angular crystal line. In appearance under the Konimeter microscope they are five microns or less in sizej 20# are round opaque but non-metallic in appearance and five microns or over " in size, . There are no hoods over these wheels and the operators wear no respirators# Average Dustiness of Cleaning Room Air - A series of five samples were taken between 9:30 and 9:40 A. ID to determine the average amount of dust in the air of the cleaning room while the various cleaning operations were in full blast. Another series of five samples were taken about 3:30 P.M# in the afternoon after the room had been given its regular clean-up. There was quite a difference in the amount of dust in the air during the morning (2,166,480 particles ten microns or less per cubic foot of air) and during the afternoon toward the close of the shift (338,272 particles per cubic foot). About 95# of the dust particles in the evening samples were angular crystalline In appearance and about two microns in size. There were a few large semi-opaque or scale-like particles about 20 microns in size. About 98# of the dust particles in the morning samples were angular crystalline two microns or less in size and about 2# were round, crystalline over five microns in size. A sample of dust from top of one of the larger Exhaust Ducts in the center of the cleaning room was given a petrographic examination by the U.S. Bureau of Mines Experiment Station at Pittsburgh, Pennsylvania and found to contain 40# Quartz (Si.02), 20# Clay Mineral not completely identified; 40# opaque. D - CORE MAE IMG - A large number of cores are made by the Demmler Air Ope rated Core Machine which uses a mixture of two-thirds sea sand, one-third river sand and one gallon core oil per 60 gallons sand. There are three sources of dust in the operation of this machine: (1) Shovelling Sand to fill the Machine Hopper..1,019,520 particles per cubic foot (2) Blowing out Core-boxes................................................. 736,320 " ""n (3) Blowing sand into the Core-Moulds.................... .. 755,200 " "" " About 98# of the dust particles from blowing out the core boxes are dark, opaque in appearance and about one micron in size. The dust particles from blowing sand into the core moulds are angular crystalline less than one micron in size. 396390 I* U I UU I 1 t I I \ I t STOOI 2995 -65- Cores are ''smoothed up" after being baked in. the core oven by scratching off the rough edges with an. old hacksaw blade. This operation produces an average of 906,240 dust particles ten microns or less in sire per cubic foot of air. About 98# of these particles are angular, crystalline in appearance under the Konimeter mi croscope nd are less than one micron in sire. E, - SEPARATION OF BRASS FOUNDRY SKIMMINGS -- A Steinlein Separator, revolv ing about 25 RHL, separates brass from about 100 pounds of skimmings an hour. The separator has a 4-inch exhaust duct to a 12-inch fan which produces a suction of about four inches water. Samples taken during the operation of this machine had an average of 1,231,920 particles ten microns or less per cubic foot of air. About 96% of the dust particles in samples taken above the charging chute appeared opaque angular black in color under the Konimeter microscope and were less than one micron in site. About 80% of the dust particles in samples from the trunnion were more crystalline and rounded in appearance and less than one mioron in site. This wsls also true of the samples taken in front of the machine where the slag drops down into a bucket. The dust particles in samples from the metal being discharged from the machine were about 50# metallic in appearance about 50# angular crystalline. Both crystalline and opaque particles were about two microns or less in site. Six men, with an average service of seven years, take turns operating this machine which runs about two hours per day on an average. X - MASON'S OPERATIONS X. . TEARING OUT STILL FIRE BOXES - Two men with an average servioe of ten. years, spend two days a month on an average tearing out slag-covered bottoms of oraoking coil furnace fire boxes. Temperature inside fire box is about 85F. The bot toms which are composed of fire brick are broken up with "Bull Point" Pneumatio chisels. Samples taken inside the fire box while this work was in progress had dust concentrations as high as 1,019,520 particles ten microns or less per cubic foot of air. These particles were glassy sharply crystalline in appearance under the Koni-- meter microscope. About 90# were five microns or less in site and 10# were over ten microns. The larger particles were semi-opaque. There were also a large number of round black opaque particles about one micron or less in site. After the bottoms had been broken up ty the pneumatic chisels they are shovelled out through the fir^ box door and then reshovelled into trucks to be hauled away. This operation natural ly produces more dust than the breaking up inside the fire box. Although no wind was blowing samples taken at face level during the shovelling and loading had dust con centrations as high as 2,435,520 particles ten microns or less per cubic foot of air and an average of 1,345,200. Goggles but no respirators were worn by the workmen. II, -- CHIPPING OR CUTTING CONCRETE -- A large number of employees with an average service of three years, spend at least ten per cent, of their time dismant ling or cutting concrete structures with pneumatic chisels in the removal of old foundations, concrete supports and blocks and in cutting holes in walls and floors. Samples taken during the cutting or chipping of concrete had as high as 6,910,080 particles ten microns or less in size per cubic foot and a general average of 1,591,051 particles per cubic foot. All of these dust particles are slightly angular crystalline in appearance under the Konimeter microscope. About 85# of the dust par ticles -ere five microns or less in size; 10# between five and ten microns and about 5# over ten miorons in size. In many cases neither goggles or respirators were worn by the v/orlcnen. Regardless of the rather low dust counts found, men engaged in chip* ping or cutting concrete should wear concrete due to the high silica content, in the usual aggregatf> used in concrete. III. - CHIPPING MORTAR FROM BET-TEN BRICK - Chipping Mortar with pneumatic chisels from between bricks in walls of structures preparatory to weather-proofing is a particularly dusty operation. Samples taken during this work had dust 6rwm+---- 396391 -66- as hi;;h as 20,956,800 particles ten microns or less per cubic foot of air a general averace of 13,848,480 particles per cubic foot. All of these particles were angular crystalline in appearance under the Konimeter microscope and about six mi crons or less in sire. There were also a countless number of minute reddish-gray particles. This work was done by an outside contractor whose employees wore goggles but no dust respirators. IV. - CRUSHING FIRE BRICK - Fire bricks are crushed in a belt-driven Williams or a Motor-driven Sturtevant Brick Crusher so that 80# will pass through a 3/8" or a 150-mesh screen - ouch of it is powdered during the crushing. This material is then mixed with fire clay, crushed asbestos and cement to make "Canister" whioh is.used in tube sheet linings, packings or as mortar in building fire boxes of furnaces. Samples taken during the crushing of fire brick had dust concentrations as high as 11,554,560 particles ten microns or less in size per cubic foot and a general average of 2,562,960 particles per cubic foot. Crushing new fire briok produces about six times as many dust particles (4,375,733 per cubic foot) as is produced when crushing old. used fire brick (736,320 particles per cubic foot). ttader the konimeter mi croscope about 94# of the dust particles produced by crushing new fire brick appear angular crystalline, one micron or less in size} about 5# are opaque over ten mi crons and about 1# are dark opaque, scale-like about five microns in size. The dust particles from crushing old used fire brick are more rounded crystalline in appearance and are about five microns or less in size. An analysis of Alamo Fire-clay Brick, which is commonly used and was the new unused fire brick being crushed at the time our samples were taken, supplied by the manufacturers (Harbisan-Walker Refractories Company) reports* Silica...................................... Alumina and Titaniau .... Ferric Oxide..................... .. Lime............................................ Magnesia.................................. Alkalies................................... per oent. ti n it t it n it ft ti Fire brick is crushed by two men assigned from the Labor Departanent, the aver age service of these men is about 14 years. Two to three tons are crushed per day. The total length of exposure per month depends upon the demand for crushed fire brick and will vary from a general average of fifteen hours per man per month to as much as twelve hours a week. Goggles and M.S. A.Camfo dust respirators are worn. V. - SHARING FIRE BRICK ON EI1EHY WHEEL - Fire briok are ground to a specified shape and size on a 2" x 24" Carborundum (Grit 16, Grade 1, Bono 6C) Wheel which re volves 900 RPK, This wheel is almost completely enclosed by a hood which has a 4- inch duct to a 24-inch motor-driven fan operating at 1750 RRI. , but this exhaust is evidently inadequate as samples taken while rounding off the edges of a fire clay fur nace block had a dust concentration as high as 4,078,080 particles ten microns or less in size per cubic foot of air. The general average was 2,001,658 particles per cubic foot. All of these dust particles were slightly angular and slightly opaque in appearance under the microscope and five microns or less in size. One man wearing ro^gles and a K.S.A. Comfo respirator, with about 15 years service, spends an average of about tvio days a month shaprng fire brick and blocks on this rdieel. VI. - DISMANTLIN'; KASCHRY - Dismantling Masonry structures such as old boiler and still settings is a very dusty operation but was not included in this dust study as there v.as no work o.*' this type in progress at any of the plants at the time of our survey. S T 00I2996 I I t l c t t t t t c t c c c c c c c c c c c c 396392 e: S TO O I2997 -67- XI WOODWORKING OPERATIONS ** Woodworking operations, as performed in connection with the refining of pe troleum products and associated activities, are used in the production of patterns, box shooks, containers, and construction or maintenance work. These woodworking operations produce more or less dust which is largely organic and although it may have some spores and have an allergio effeot on some individuals, it is not consider ed harmful. Mr, D. Harrington of the U. S. Bureau of Mines advises that the U. S. De partment of Labpr in a recent bulletin indicate that workers breathing wood dust are far more definitely afflicted with tuberculosis than the general run of industrial workers. In large quantities, however, wood dust belongs in the "nuisance" class ona may also be an explosion hazard A. - BOX SHOOK MANUFACTURE - All pine lumber used in the manufacture of box shooks is "kiln-dried" and all gum lumber is "air-dried". Men work eight hours a shift, five shifts a week. (a) Resawing - Band saws, twenty-five feet four inches in circumference, re saw four-quarter and five-quarter lumber into 3/8-inch and l/2-ineh shooks respec tively. Samples taken during this resawing had an average dust concentration of 155,760 particles ten microns or less per cubic foot of air when sawing pine and 996,864 particles per cubic foot when sawing gum. These low oounts indicate that the exhaust and dust collecting system which has been provided is functioning. This exhaust system includes hoods over each saw with 8-inch ducts to a belt driven fan with five-foot blades revolving 3500 RR1. About 60# of the dust partioles in samples taken while resawing pine were crystalline, rather glass-like in appearanoe - prob ably resin - under the Konimeter microscope and over ten microns in size] 40# .were round with rough edges gray and opaque, five microns or less in size. About 80# of the dust particles from cutting gum lumber were round crystalline semi-opaque in ap pearance, five microns or less in size) 20# were aver five microns in size. Gum lum ber is resawed only about four days a month. (b) Ripsawing - Rip saws. 14 inohes in diameter cut ends ft*om four-quarter gum lumber. An exhaust system has been provided with a hood over each saw and four inch metal ducts to a belt-driven fan with six-foot blades revolving 3500 RIM. Samples taken during this operation had an average dust concentration of 169,920 particles ten microns or less per cubic foot of air. All of these particles were angular crys talline semi-opaque in appearance under the Konimeter microscope and about three tHcrons in size. (c) Cut-Off Sawing - Saw four-quarter lumber to make box ends. About 85# of the time gum lumber is sawed, and 15# pine lumber is sawed. Samples taken while saw ing gum lumber had an average dust concentration of 877,920 particles ten mierons or less per cubic foot of air. About 50# of these particles were round crystalline semi opaque, gray in color and from five to ten microns in size; 50# were slightly angiw lar crystalline in appearance under the Konimeter microsoope and three microns or less in size. There were also several very small black specks. The low dust count indi cates that either the particles were mostly over 30 microns in size and were thus filtered out by the porcelain filter or that the exhaust system was effective. (d) Planing - Planers or double surfacers resurface the four-quarter and five quarter lumber to give it the proper finish. There is an exhaust hood over each chine with an eight-inch metal duct to a belt-driven fan with six-foot blades revolv- ing i500 RIM. Samples taken during t?ie operation of planers or double surfacers had & general average dust concentration of 509,760 particles ten microns or less per cubic foot of air when planing pine lumber and 415,360 particles per cubic foot when planing gum lumber. Particles of dust produced while planing pine lumber were crystalline rather round in appearance under the Konimeter microscope, about 75# were 396393 --68-- s 1u u i / y y y flTe microns or less in sizej 25# were larger than two microns rather opaque# Dust particles from planing gum lumber were round opaque in appearance and one cron or less in size* Dustiness of Shook Factory Air - A series of fire samples were taken at fire strategic points to determine the average dust concentration of the faetory air# These samples gave an average concentration of only 141,600 dust particles ten mi crons or less per" cubic foot of air which indicates that either the major portion of the dust is over SO miorons in size or that the ventilation system is proving effec tive. The latter is probably the more logical explanation although the excellent housekeeping is undoubtedly an important factor. About 98# of the dust partioles in the factory air samples were slightly angular crystalline in appearance under the Konimeter microscope and about five microns or less in sizej 2% were round, opaque dark gray in color and two microns or less in size. B. -- BELT SANDERS, SAND DISCS AND SPINDLES OR CYLINDERS -- This equipment is used for "squaring up" and smoothing surfaces of wooden patterns, cleaning finishing barrel-heading and staves and general mill work in the Carpenter Shops. Sanders are a notorious source of fine wood dusts. They are also contaminated with an appreciable amount of silica, if a sand-type of abrasive is used, consequently either hoods for the machines or respirators for the men engaged in operating these machines should be provided. We appreciate that it is rather difficult to properly hood a sander to prevent the fine dust being carried around by the abrasive member, particularly disc senders. Our attention has been called to a case where a e^. gaged in the use of senders suffered recurring respiratory illness and ultimately death from pneumonia. His 'attacks of illness seemed to correlate with extended use of the senders. (a) Belt Sanders - An 8" x 28-1/2 ft. Belt Sander (Lightning Adalox Cloth l^l/2 - 40 X Grit Norton Abrasives) runs on an average of two hours per day is used by eight different men with an average service of fifteen years. Samples taken while finishing #1 Pine lumber had a dust concentration as high as 15,519,360 par ticles ten microns or less per cubic foot of air and a general average of 3,443,712 particles per cubic foot. About 90# of these particles were angular crystalline in appearance under the Konimeter microscope and five microns or less in sizej 5% were over five microns in sizej 5% were opaque scale-like, ten microns or less in size. There was no hood over this sander and the dust produced was thrown into the shop air. A 6 in. x 18 ft. Belt Sanding machine (#3 Production Cloth Minnesota Mining Company) runs on average from four to six hours a week and is used by four different men, with an average service of four years. This work was formerly dene by hand on a lathe with sand paper. Samples taken while finishing the outside of a barrel had an average dust concentration of 481,440 particles ten microns or less per cubic foot. These particles were largely angular crystalline in appearance under the Kanimeter microscope. About 5C# were five microns or less, and 50# were over five mi crons in size. (b) Sand Discs or Wheels - These discs rim from 40# to 6C# of the time are usually used by everybody in the shop in which they are located. Samples taken during the operation of send discs or wheels had the following dust concentrations* 396394 I I I I I I C C c c c e  k 7 i n n qi No. Site (Dia. ) Abrasive Used Work Being Done I 7" #24 Sand Cleaning Paper Minn. heads Mining Co. Finished Barrels II 24" #i-l/2 Car- Squaring net Paper. Wood Minn. Min Pattern ing Co, III 30" IV 30" #40 Grit on Bristol Board. Gardner Ma chine Co. #2 Garnet Net Back. Gardner Machine Co. Smoothing off Pat tern Squaring Wood Pat tern Particles Per Cubic Foot 604,160 623,040 1,925,760 3,624,960 Characteristics of Dust Particles (Sizes and Per centages Estimated) 4 Angular crystalline about 50% five microns or less and 50% larger than five microns. About 55% angular crys talline two miorons or less) 5% quartz-like rounded about 10 mi crons in size. About 90% angular crys talline three microns or lessj 10% opaque angular one micron in size. About 98% semi-opaque, sand-like, one micron or less, 2% opaque 5 miorons or over in size. The sand disc in No, I was used in a well ventilated cabinet connected to a 48" motor driven fan by a 7-inch duot. The men wore goggles and "Camfo" respira tors. The sand wheels in No, II and Uc, III had hoods with about 3-1/2 inohes water suction connected to a 24" motor driven fan by 4-inch duots. The men wore neither goggles nor respirators. The wheel in No. 17 had an exhaust hood with a 6lnch duct connected to a 24-inch duct which in turn was connected with a 36-inch tor driven fan, (c) Sand Spindles ay Cylinders - Sand spindles or cylinders are used on an average of about two hours per man per day. No hood or suction exhaust has been pro vided for this equipment. Men using it do not wear goggles or respirators although the dust particles produced are more angular in appearance than those produced by sand discs or wheels. Samples-taken during the operation of Sand Spindles or Cylinders had the followin.- dust concentrations* Size (Dia. ) Abrasive Used Work Being Done Particles Per Cubic Foot 3" #3arnet Paper Cutting Inside 2,322,240 Gardner Machine Core Boxes Co. Characteristics of Dust Particles (Sizes and Percentage Estimated) About 60% quartz-like in appearance, ten mi crons or over in size) 40# semi-opaque five microns or less in size. 396395 -70- DUST PRODUCED BY SAND SPINDLES OR CYLINDERS (Concluded) Size (Dia. ) Abrasive Used 3-1/2" #l=l/2 Garnet Paper Minn. Mining Co. Work Being Done Putting Taper on Pattern. Particles Per Cubic Foot 877,920 Characteristics of Dust Particles (Sizes and Percentage Estimated) in About 90% angular crys talline two microns in size; 10% opaque five microns or less in size. injuuuoi C. - MAKING WOODEN CRATES - Two types of saws are used in preparing lumber for making crates for gasoline pumps and tankst (a) Band Saws - Samples taken during the operation of Band Saw had a dust concentration of 453,120 particles ten microns or less per cubic foot of air. All of these dust particles were round, opaque in appearance under the Konimeter mieroscope and three microns or less in size. (b) Railroad Saws - Samples taken during the operation of an 18" Railroad Saw had a dust concentration of 3,964,800 particles ten microns or less per cub^c foot of air. All of these particles were round, grayish opaque in appearance under the Konimeter microscope and about five microns or less in size. There were also nu merous minute gray specks too small to count accurately, XII ROCK EXCAVATION Rock excavation is usually a dust producing operation which is limited to con* struction activities in the petroleum industry. The hazardousness of rock excavation depends entirely upon the nature of the rock being excavated, the length of exposure and the methods being followed. The principal sources of dust are rock drilling, blasting, mucking and handling of the rock. Of these, drilling probably produces the greatest amount of dust. A. - DRILLING - The pneumatic rock drill operates essentially as a crushing device which shatters the rock to a powder at the point of impact. According to Theodore Hatch of the Harvard School of Public Health (N. Y. Ind. Bull. VoL. 15, No. 9 Sept. 1936) the particles of dust thus generated vary in size from one-quarter inoh or larger downto sub-microscopic diameters. The dust is removed from the drill hole by a stream of air or water or a combination of the two introduced through the hollow drill steel. In the case of jack-hammer drilling a considerable amount of rock dust ejected from the hole falls back to be crushed further before it is removed again. Quoting Mr. Hatch* "The amount of dust produced by a rock drill is surprisingly large - a jack-hammer, operating at the over-all rate of 100 feet of drilling per day, actually crushes more than 200 pounds of rock in eight hours. Cf this, at least five per cent, is in the form of particles smaller than ten microns; hence, more than fifty grans of dust small enough to be air floated is generated per foot drilled. In terms o' numbers of particles the figures are enormous - it has been found that a jack hammer produces as much es one billion particles of hygienic interest during one minute of operation". 396396 ST 00 I 3 0 0 I -71- B. - BLASTING - It is often said that blasting produces the greatest amount of dust in rock-excavation. This statement is contradicted by some authorities who refer to the fact that the blast dislodges a great deal of dust from the rook sur faces deposited there from earlier drilling operation in addition to that actually generated by it. Under this condition blasting is undoubtedly followed by a higher dust concentration than in the case when all the dust produced by drilling is oa^ tured and conveyed to a remote collector so that only that actually generated by the explosion escapes into the air. While it is undoubtedly true that if drilling is done dry, there will be de position of some of the dust on the surfaces of the excavation and later be raised by blasting, however, dust from this source is minimized if drilling is done wet, because the slushed out particles tend to form agglomerates, which are not so readi ly raised by the blasting operation. Also, when good practice is followed, the faoe and sides are wet down with water before blasting, and in mining work, there is a continuous water spray that is started onto the heading before the blast takes plaoe and continued for some time after to help allay the dust and to wet down the material, so that dust raised during mucking will be at a min imam. C. - MUCKING - The amount of dust pro due ed by mucking and other rook-handling operations varies greatly with the nature of the operation. On open excavation it is probably of li*ttle importance, bait in confined sources as in toxnnels and mines the dust concentration associated with rock handling may reach dangerooa levels. D. - DUST CONTROL - Methods for the control of doist in rock excavation as ` suggested by Mr. Hatch inoludet (a) - Wet Drilling and Wetting Down Rook WallB and Muck Piles - In general it may be said that water is less effective against qoiartz-bearlng rock than against silica-free material such as lime-stone. The oisefulness of water is limited when freezing temperatures are encountered and it prodoices objectionable working conditions especially for overhead drill operators and is certainly to be avoided if a pneojmonia hazard exists. A fundamental objection to the wet method is that the dust is not removed from the scene of operation bait simply suppressed near its source where it remains to be thrown into the air by a subsequent distoirbance such as blasting. (b) - General Ventilation - The purpose of general ventilation is to dilirte the dusty air with sufficient clean air to bring the concentration down to a satis factory level. Two precautions are required! 1st. - the fresh air itself must be free from dust and 2nd. - it must be properly distributed through the work ings to insure maximum mixing with the doist laden air. (c) - Dust Exhaust Hoods on Erllls and Other Mucking Operations and Looal Sources of Dust - Effective doist control can be secured by means of a doist trap which surrounds the drill steel at the rock surface. The doist-laden air is captoired as it merges from the drill-hole by the inflow of clean air into the trap. To be effec tive, the inlet velocities must be great enough to prevent the oortward movenent of the dust and sufficient velocity moist be maintained at all points within the trap to present settling and clogging. The collected doist is conveyed by the air-stream through hose and piping to a suitable dust separator in which the air is freed from its dust load and thois is discharged from the apparatus as clean air. Traps of dif ferent designs are reqoiired with varioois drilling operations and special supporting devices are necessary to hold the trap in proper alignment with the several operat ing positions. (NOTEi The dust trap is satisfactory omder many conditions, but again under many other conditions has not proved satisfactory. RSB) 396397 -72- The dust dispersed during mucking, as well as that arising from rock drill ing, can be controlled by local exhaust ventilation and requires no elaborate apparatus. (d) - Personal Protection By Keans of Resplrators and Positive - Pressure Masks - An effective respirator or a positive-pressure mask supplied with an adequate quantity of dust-free air provides the wearer with protection when it fits the face properly and is worn continuously in dusty atmospheres. Respirators and masks have a legitimate place-ln the field of silicosis control, especially to provide pro tection against infrequent unexpected dust concentrations but cannot be recommended as a substitute for dust control in continuous operations. 1 ^ I I 1 ST UO I 3 U U Z 1 396398 t c c c c t c c c c c c c c c c c c E= -75- STO O I30U 3 PART III MEASURES FOR REDUCTION OF THE DUST HAZARD t** HOW CAN THE DUST KA7ARD BE REDUCED? - The quantity of dust inhaled may be minimized by the employment of these four methods outlined by Dr. M. Hummel in "Medioal Reoord"*- "1. Suppression of Dust Near It1 s Origin, by the use of exhaust draught, dust traps or water. The water has the advantage of a fly-paper effect on the silica particles, but the humidity created tends to favor infection by prolonging the life of pathogenic organisms outside the body and facilitat ing their entrance into the body. "2. Admixture of Adulterant Dust with the silica which may assist in the expulsion of silica from the lungs, retard the process of the disease or prevent the development of tuberculosis. However, the introduction of an additional foreign body into the lungs is of doubtful value fraught with potential danger and should be regarded very cautiously and con servatively. "3. Proper Ventilation, in connection with other methods, "4. Masks should be an ideal preventive measure but, unfortunately, most of the masks stopping the dust also stop the respiration, thus necessit&ting their frequent removal. They should be of an approved type, properly maintained, strictly supervised and their use rigidly enforced,n We do not believe that the use of water would have any outstanding effects on raising the humidity in most of the dust producing operations in the Petroleum T-n- . dustry, any more them, for example, sprinkling one's lawn would have. We believe it remains to be proved beyond doubt that the humidification of air actually favors bacteriological growth to the extent that the incidence of disease from pathogenic organisms is raised significantly. There has been much discussion on this subject, but little has been proven. Theoretically, it may be admitted that these organisms live longer in a moist atmosphere than in a dry atmosphere, but it is rather hazardous reasoning to conclude that for the reasons stated, the use of wet methods in dust control causes an Increase in disease. Tr. Kuanel's statement that most masks (we presume he means respirators) that stop dust also stop respirations, is a little strong. There are available today respirators that adequately remove dust without creating a resistance to breathing in excess of 15 to 30 millimeters of water column, and the tendency of progressive manufacturers of such devices is to further lower the resistance. Men during the war actually did fighting *hile wearing respiratory protective devices that had as much as 50 to 75 millimeters resistance. The resistance figures given for respira tors are measured at a rate of air flow of about three cubic feet a minute which is equivalent to the amount of air breathed by a person doing hard physical work, Pjst Respirators and Air Masks - Respirators and masks of various types have been used since the days of the alchemists and are mentioned by Agricola, Ramazzini and others. Control of the dust hazard by means of respiratory protective equipment is effective, provided: (1) the protective equipment is efficient, and (2) it is worn continuously. 396399 Efficient equipment is available, but for continuous use, day after day, this method -74- of control cannot bo depended upon to provide the first line of defensej in this re spect it nay be likened to the ;use of personal immunization as & primary safeguard against the spread of typhoid fever. Dust respirators and air masks do, however, have a definite place in the field of dust control, especially as an emergency measure, as a means of protection on infrequent dusty occupations as an adjunot to other more fundamental methods of prevention. Reports made to the National Silicosis Conference, called by the Secretary of Labor in February. (1937) to -study specific phases of the silicosis problem and pr^ sent suggestions for its solution, contained many recommendations by qualified au thorities on the subject which have been successfully employed under actual operating conditions. Briefly summarized measures for the control of dust and the prevention of pneumoooniosis includet A. -- DESIGN PLANT FOR DUST CONTRQ, - Much can be accomplished through design when new buildings are contemplated or when old buildings are to be remodeled. For instance, structural projections and ledges may be minimized to prevent the aocunnw lation of dust that might later be released into the atmosphere by air currents or by building vibration caused by travelling cranes, vibrating machinery, and equipment that have large reoiprocating parts. The Engineering Committee recognized the fact that our present day engineering and structural materials for factories do not per mit elimination of innumerable ledges and projections without prohibitive building and roofing coats. However, building interiors should be so contracted that they may be easily cleaned by washing, hosing, vacuum cleaning or brushing. In some eases operations may be located over gratings, beneath whioh equipment ia provided for re* moving the materials and dust that fall through. B. - PROVIDE BUILDING VENTILATION - Natural ventilation should usually be considered only an adjunct in removing or reducing dust in the air. Even though it is possible to have high roofs in one-story structures which will give the greatest benefit from natural ventilation, such methods cannot be relied upon to provide camplete protection in dusty operations. Where mechanical ventilating systems are pro vided, care should be taken to prevent strong drafts from open windows and doors de stroying the effectiveness of the system. Guards and shields should be placed in the vicinity of hooded and partially enclosed processes to prevent such a condition. C. - STORE DUSTY MATERIALS IN DUST-TIGHT BINS - Dusty materials should be stored in dust-tight bins, tanks, or enclosures, but each structure of this type should be provided vdth a breather or vent stack -- perhaps with an exhaust fan in the stack -- to permit the air displaced during loading to be carried outside the building. Basements may be used for storage purposes but should not be used for dusty manufacturing operations. D. - ENCLOSE MATERIAL HANDLING EQUIPMENT - Excessive dust created by mechan ized material - handling equipment can usually be controlled by provision of adequate housing and application of exhaust systems. Some materials can be kept in a moist condition while being handled, but when this is done, the material may dry out and be dispersed into the atmosphere as dust. E. - ISOLATE DUSTY PROCESSES - Where possible, several or all dusty processes may be isolated from the rest of the plant. This sometimes permits the installation of a more compact exhaust system resulting in more efficient operation and lower main tenance cost. F. - PROVIDE WET METHODS OF OPERATION - Water, oil, and other liquids may be used effectively: 396400 S T00I300U t C t t e t C tZ C c t= tz e e cz cz cz c cz S T 00I3005 -75- 1. To suppress dust at the point of origin in such operations as rock-drillings' handling, pulverising, and milling rock and crej grinding metal on grindstones; abrasive-wheel cutting of granite end sandstone. 2. To prevent the re-dispersion of dust that has settled on the floors, walls, and other surfaces such as in the granite indus try and in foundries. G. - DESIGN EQUIFKENT TO CONTROL DUST - When new machinery or other equipment is contemplated, the manufacturer can frequently be encouraged to include dust oomtrol features such as exhaust hoods as an Integral part of the design and construc tion. H. - PROVIDE EXHAUST SYSTEMS - In some operations, exhaust systems may be Installed to remove dust at its point of origin. In many cases several small systems are preferable to a larger system. Any mechanical ventilation system should be de signed to meet at least the minimum requirements of local State laws or industrial codes, or lacking such requirements, should be installed aooording to the best ao-- cepted practice. Dust Arresters - Provision of dust arresters will prevent hazardous dusts from being circulated into other parts of the plant or into the neighborhood. The location of dust arresters is very important, particularly if dry types of arresters are used. Provision should be made for removal of the eollected dust without its escape into the area where the arrester is located. I. - ESTABLISH MAINTENANCE AND GOOD HOUSEKEEPING PROCEDURE - Good housekeeping Is unquestionably the cheapest single method of controlling dust. Maintenance goes with it hand in hand. The best equipment in the world will not oontrol dust if su perintendents, foremen, and workers are careless and disorderly in their work. Eight suggestions are advanced by the Conference Committee! 1. If dust-tight equipment is installed it should be inspected at regular and frequent intervals and all defects should be cor rected as soon as they are deteeted. 2. Operations should be performed in a manner that will create the minimum amount of dust. 3. Use water under pressure where possible to clean building interiors. 4. If practicable, combine water with air for cleaning purposes. All cleaning should be done, if possible outside of working hours and men engaged in this operation should be provided with dust respirators. 5. Vaouum cleaning removes dust without dispersing it elsewhere. 6. Brushing is particularly adaptable for cleaning buildings of the older type of construction. 7. Low-pressure steam can sometimes be used to advantage. 396401 -76- 8. A responsible person should be assigned the task of supervis ing maintenance and housekeeping activities. Among other things he should make tests from time to time to make sure that the dust control program is achieving the desired re sults. J. - PROVIDE RESPIRATORS - The Conference Committee was of the unaminous opin ion that "dust elimination must be given primary consideration in solving the sili cosis problem". Nevertheless, when known methods of elimination are not applicable or are ineffective, respirators should be provided as "a last resort and for oc casional exposure only. Rotation of personnel under these conditions is advisable." The report definitely states that there will always be places where other methods will be inapplicable and ineffective, and respirators will be required for doing the work, also that there will be situations where respirators .will be the primary means of protecting the workmen. The scope of good use of respirators is consider ably beyond that of occasional exposure. The need of rotating personnel depends on the type of work done and the supervision given the workmen. In some operatina, respirators are as much a part of the workman* s equipment as his tools. Certainly, it cannot be expected that a person can wear a respirator for several hours con tinuously - but bow many jobs are there that would require a person to keep the res pirator on continuously for an extended period of time. The common practice in the majority of industrial occupations is that the person is intermittently exposed is afforded many opportunities for the periodic removal of the respiratory protec tive device. The two general types of respirators which the Committee considered suitable for protection against silica dust are* (a) Air-purifying respirators that filter out the duat particles. (b) Supplied-air respirators in which dust-free air breathed by the worker comes to him from an uncontaminated outside source. Host respirator manufacturers have submitted their devices for testing and approval by the U.S. Bureau of Hines, and only those which have been approved should be used. (a) Air-Purifying Types of Respirators - Of the air-purifying ela'ss, the type most commonly used is the mechanical filter respirator for mechanically-generated dust. These respirators give no protection from gases and vapors. They generally consist of half facepieces to which are attached an exhaust valve and a filtering medium that removes the dust from the inhaled air; seme are equipped with a filter medivm that removes paint mists and some fumes. They are light in weight pensive. Filter pads must be changed at certain intervals, depending on the conceit tration of dust. Some types restrict the field of vision. The general requirements of a safe and suitable Mechanical filter respirator are (1) adequate protection, (2) reasonable comfort and convenience, (3) an acceptable service life period of protec tion, (4) easy cleaning and sterilization, and (5) low cost of maintenance in good serviceable condition. Studies of mechanical filtration by fibrous materials made by such agencies as the United States Bureau of Mines (U.S.Bur. of Hines, Tech.Paper No. 394 (1926) and U. S. Pub. Health Bull.No. 177 (1928)) and the Harvard School of Public Health (Joura. Indust. Hyg. 9,26 (1927)) revealed that filtering efficiency varies with the particle size and the amount of solid particulate matter retained; also that the resistance to air flow varies with the amount of solid particulate matter retained and the rate of air flov. After all, the fundamental basis for judging the suitability of a respi rator is whether or not the amount of dust that is unretained or escapes through the filter under conditions of practical use is below the amount that would be harmful to breathe. This is not related to any percentage efficiency. In order to meet the Bureau of Hines requirements for approval, a respirator must satisfactorily remove GO O CD CJ O O cn C\J O co 00 dusts of the following size characteristicst 99 per cent smaller than 2.80 microns 95 TT Tl tt n .1. 80 n 90 tt n n ti 1. 40 ti 80 tt tt tt TT 1. 00 TT 70 n tt n 0. 85 It 60 n tt TT TT 0. 72 tt 50 ti n TT TT 0. 60 tt It will be noted that 80 per cent of the dust used in these approval tests is below one micron (l/2S,000th of an inch) and SO per cent is below 0.6 microns. Canisters will not remove dusts of these characteristics and should not be used as dust respi rators. STOOI 3007 In order to obtain the desired protection, it is essential that the faoepieces of the mechanical-filter respirators fit the face of the workman snugly but with a minimum of head-band tension. A simple practical test, suggested by Carlton E. Brown of the U. S. Bureau of Mines Experiment Station in Pittsburgh, Pennsylvania (Jour. Indust. Hyg. Feb. 1937 Vol. 19, No. 2, p.98), that anyone can rim to determine whether a respirator facepiece is making a tight seal, is to wear it in a high con centration of coal dust. The time of the test can be shortened by blowing a stream of air containing a high concentration of coal dust around the edges of the faopiece. The location and approximate magnitude of the leaks are shown by streaks of coal dust on the part of the face covered by the facepieoe. Another test, according to Mr. Brown, consists of plugging the intakes of the respirator and then attempting to inhale. This type of test could well be supplemented by the Coal dust test. (b) Supplied Air Respirators - Industrial processes such as pneumatic drilling,at>rasive blasting and spray coating have introduced atmospheric conditions for which the air-purifying type of respirators are not particularly suitable. Certain kinds of pneumatic drilling are responsible for dust concentrations so high that they would rapidly overload a dust respirator. The operator of an abrasive blasting outfit must be protected not only against the inhalation of air containing high concentra tions of dust, but also against impact and abrasion of the head and shoulder by the reboundin; abrasive and loosened abraded material. Spray coating is responsible fre quently for pollution of the surrounding atmosphere by a combination of particulate matter (mists that are liquid particles or a combination of solid and liquid par ticles) and harmful vapors resulting from the evaporation of the liquid vehicle of the coating used in the spray gun. Since these operations are carried out frequently in Isolated places at different locations at variouc times, they do not lend themselves always to general control measures. Therefore, supplied air respirators perform a definite service. The types in general use are those ^orsnonly known as hose masks, air-line respirators, and abrasive blasting respirators such p: sand blast masks, helmets, and hoods. Supplied-air respirators have the following advantages for routine non-emer gency use over those of the air-purifying respirators such as gas masks, mechanicalfilter respirators and the combination of gas mask with a mechanical filter* 1. NO resistance to inhalation. 2. Freedom from inward leakage of contaminated air. 3. Protection against all kinds of contaminants and even against at mospheres deficient in oxygen which will not poison or irritate the skin. 396403 Rnnf. i n n j s -78- 4. The Inflowing air reduces excessive perspiration and tends to cool the face, 5. V/hen a hand-operated blower is used a second person is always present, (With an approved mask, provided the facepiece is tight, the wearer can inhale enough air through the hose to es cape if the blower should stop). The Air-Line Respirator consists of a tight-fitting facepiece, a loosely fit ting facepiece or even a helmet or hood covering the head and extending down over the neck or shoulders. The air supplied to these respirators has been largely that ob tained from the compressed air source used in the performance of the work, as in sand blasting, pneumatic drilling and spray painting. This air is frequently con taminated with objectionable and, in some instances, harmful substances which, to some extent, can be removed by means of air-purifying appurtenances. In discussing "Res piratory Protective Devices" in the February (1937) issue of the Journal of Indus trial Hygiene and Toxicology, Mr. C. E. Brown of the United States Bureau of Mines wrotet "Using air from the ordinary compressed air system found in industry to supply respirators is not to be indiscriminately recanmended. These compressed air systems are usually of the high pressure, internally lu bricated, reciprocating-eompressor type. The air supplied by these systems is contaminated frequently with malodorous constituents such as vapors, mists and products of decomposition of the compressor lubrieant, slugs of water, and rust from the pipe line. All or most of these contaminants can be removed probably by some of the commercial air purifiers sold for this purpose. A pressure-reducing meohanlsm should be used also in the line to prevent any possibility of sudden accidental blasts of high-pressure air from Injuring the lungs of the wearer of the respirator. With a compressor of this type there is always the possibility, however rare it may be in well-kept systems, of the generation of carbon monoxide due to overheating of the compressor lu bricant (Jour. Indust.Eyg. 18,461 (1936)). This danger can be minimized or eliminated by the use of temperature controls or carbon monoxide alarms on the compressor which, of course, should be so maintained as to pre vent the generation of carbon monoxide. "The trend in supplied-air respirators is to use special low-pressure, externally lubricated, positive-pressure air-supply devices. Most of the objections to the high-pressure reciprocating-type compressor do not apply to an air-supply of this kind. Since these devices are not common in industry, however, it is usually necessary to purchase a special one for use with the respirator. Since air purifiers, pres sure-reducing mechanisms, and special compressor-oontrol or alarm me chanisms are not necessary, the price of this respirator complete with ai>-3upply device should not exceed that of the other type of respira tor without the air supvly system. "The use of a special air-conditioning unit to regulate the tempera ture and humidity of the air supplied to the respirator wearer is de sirable. " The minimum air supply for a respirator designed to use all the air for res piratory needs at a high degree of efficiency is generally agreed among Industrial Hygienists to be at least four to six times the air breathed per minute. As a general class, respirators with loose-fitting facepieces, hoods, or helmets require 396404 79- nere air than those with tigfrt fitting facepieces. e' * There is sane difference of opinion among users of respirators as to whether or not adjustments should be provided whereby the wearer can vary the flow of air to meet variations in his requirements. It was the opinion of the National Silioosis Conference Committee that definite recommendations for all situations cannot be made, but for many situations, and particularly where tight-fitting faoepieees are used, an adjustable flow is desirable and may even be necessary} also, most worloaen can learn to adjust the air properly. On the other hand fixed-flow procedures re quire a minimum amount of instruction and supervision and are the most conducive to safety under all conditions. While Eose Masks and Air-Line Respirators have many definite advantages the area of travel of the wearer is limited to the length of the hose, and movements are handicapped to some extent by the hose. Manifestly, the air for the hose the mask should be fresh and pure, but unfortunately this is not always so. Abrasive Blasting Respirator - Abrasive blasting respirators consist essen tially of a hood, with windows, that fits loosely over the head and shoulders wTM* designed to withstand and protect the wearer's head, neck and shoulders from abra sion by the rebounding of particles of sand or gritj and a supply of fresh air, at least six cubic feet per minute, blown into the hood. Only equipment which las met the United States Bureau of Mines test requirements and vdiich is approved by the Medical and Safety Departments should be used. O C c o c <z (c) Acceptance and Use of Personal Respiratory Protection by Workman _ As stated in a paper by G. M. Kints and H. C. Fowler of the United States Bureau of Mines (I.C.6915 No.vl936) presented at the International Petroleum deposition and Congress, Tulsa, Oklahoma, May 21 1936, selecting respiratory protective equipment is simple compared with getting men to wear it after it is supplied. Generally worbnen will wear masks readily in places where they have seen others asphyxiated, or in some similar trouble, but they are likely to resist wearing protective equipment where the dust cannot be seen or where the fumes and mist have no objectionable odor. There are three main reasons for such resistance! First, inbred objection to any new idea} Seoond, the feeling that the individual, is a superman and can "take it" without protection} and. Third, the inconvenience of wearing the equipment. In a survey conducted among the employees of the Col gate-Palmolive-Peet Com- pany by Mr. F. E. Wallner of that Company's Insurance Department, it was found that the men didn't like the disfiguring appearance of a "musrle" over their faces. This survey also disclosed that some workers objected to the respirator beoause they thought it made breathing difficult when the real trouble was that they were not breathing correctly. Breathing through a respirator should be done deeply and slow ly and after the proper habit has been acquired much discomfort may be eliminated. Quoting Mr. Wallner* ^ o "Foremen should appreciate that the position of the straps that (q hold the respirator in place has much to do with confort. They should learn whether the straps shou..d be worn over the head or arouad the ^ neck. Same types have two straps, one to be worn around the neck, the other around the head." Probably the most effective plan in getting respirators worn is first to "sell" -80- ni nr. i nn i s the supervising personnel who in turn should "ell" the worker by education, possibly accompanied by strict and fair supervision and discipline. Employees exposed to dust hazards requiring the wearing of respirators should be convinced that it is essential to sacrifice some comfort and dignity to avoid serious cases of disability suffer ing, Every worker should have his own respirator. It requires time effort to adjust this protective device so it contacts the face snugly with a minimum of head- band tension. It. cannot be expected that the average workman will readjust a dif ferent respirator each day. Also, the psychological effect of using a respirator worn previously by another workman is not unimportant. Although he may not say any thing about it, it is naturally revolting to most men's principles of bodily sani tation to have to clamp over his face a device that has been soaked with sweat dirt of another man's face and into which one or more men have breathed day after dayl It is too much like using the other fellow's tooth brush. The best practioe is to mark every respirator so each workman can identify his own. (d) Use, Maintenance and Care of Respirators - Personal respiratory protective de vices must be maintained in a condition substantially the same as when reoelved from the manufacturer. Depending on the density of the dust replaceable filters should be changed frequently to prevent their becoming dogged and usually it is desirable to use a respirator without a facelet. However, if they are considered necessary, the facelets should be changed often to avoid skin irritation. A clean facelt gives the respirator a clean appearanoe and removes one objection to wearing it. The Colgate-Palmolive-Feet Company found that the habit of same workers of removing their respirators at intervals caused skin irritation. Everytime they did* this, dust settled on the surfaces that lay next to the worker's fboe and irritating partioles were transferred to the skin when the device was replaoed. It is, ther^ fore, best to have the employee wear his respirator constantly while under exposure. In same cases, ointments or petroleum jelly has helped to overcaae the irritating effeot of points that contact the skin. Where a considerable number of respirators are used, it is good practice to have a "Respirator Room" with an attendant who issues the respirators and cleans, sterilises and otherwise keeps them in good condition. Respirators may be cleansed by washing and brushing them with an antiseptic soap and warm water. They should be checked for damaged or improperly functioning parts suoh as rubber valve seats head-bands. If defective, these should be replaced by new parts. WHAT MEDICAL CONTROL SHOULD BE EXERCISED IN TIE SELECTION AND SUPERVISION Q MEN WORKING ON DUSTY JOBS7 - It is essential that adequate medical control be es^ ercised. Such control should include the examination, prior to initial working on dusty jobs of the. worker to insure that he is a suitable physical subject. This ex amination should preferably include X-ray examination of the lungs whioh permits closer control with subsequent X-ray tests as well as being a protection to the employer in the event of ary later legal action. A worker, to be classed as physically suitable, should be in addition, datermined to be a nosa-breather rather than a mouth-breather and the natural filters, ing capacity of the hose should be found to be satisfactory. G. Lehmann (J. Ind.5yg, 17,37 - 1935) indicates that the "Silicotic susceptibility of workers with poor na sal filtration is much greater than that of men with good nasal filters". He ad vises that Jobs with a silicosis hazard be held only by men with good nasal filters" and that mouth breathers are an especially bad risk. He suggests that the "dust re taining capacity of the nose be used as an index of the individual's qualification for working in a silicosis producing atmosphere". It is possible that Sternstein's technique for measuring nasal resistance ("Industrial Dusts - p.65) could be develop ed into a simple procedure for selecting men best adapted to dust exposure. ^ o> ^ According to Drinker and Hatch ("Industrial Dust" p.32) it is wise to select -81- STOO I 30 I I for dusty Jobs men who are pest the age of 40 and not young men Just taking up a trade. All workers engaged in harmful dusty operations should be periodically thor oughly re-examined, including X-ray tests. Particular emphasis should be planed on any indication of shortness of breath and chest pains Regulations should be enforced concerning the time limitation of work of any employees involved in a dust producing operation. Such Company regulations conoeraing sandblasting calling for a fixed six-month maximum period on such work, after whioh a minimum six-month period away from dust producing work should be followed more olosely. For protection from a legal angle, the worker should be given a final thojv ough examination including X-ray before being permanently transferred to same other type of work, laid off or discharged. CONCLUSION There is still a tremendous amount to be learned about pneumoconiosis dust-producing operations. One thing, however, is certain -there is a very definite tendency to require compensation for Industrial or occupational diseases. If these compensation costs are to be kept to a minimum and the health and safety of workman are to be promoted it will be necessary to make further studies and to promptly * adopt adequate precautionary measures. Many of these are now in effeot, the others should be put in force as soon as possible. After years of study and direct contact with the Dust Problem, Mr. Dan Harrington, Chief, Health and Safety Branch, United States Bureau of Hines, has came to this conclusion (Eng. St Min. Jour. March 1937 pps.119-21) with which we are heartily in accord "In the maze of uncertainties connected with almost all phases of the causation and diagnosis of dust disease, about the only really well-determined fact available is that breathing large quantities of dust (or possibly of certain dust) over extended periods is likely under some conditions to be harmful to health and that subsequent al leviation or cure is difficult or impossible. Therefore, it would seem to be logical to try to prevent dust formation thus preventing it from harming workers through respiration or otherwise. Here is a real Job for the engineer, and little or no help can be expected in these vital functions from any agency except the engineers and operat ing officials. "The most harmful of the ordinary dusts to breath is probably silica dust, but, on the other hand, not even free silica, supposed ly the most detrimental of the silica dusts, is harmful unless it is breathed, in considerable quantities and over extended periods. No human being ever lived any considerable time on this earth of ours without breathing silica dust (free silica dust), yet by no means all of the people of the world have or have had silicosis. In other words, the quantity of dust taken into the respiratory organs is a controll ing factor in dust respiratory harmfulness. "One common-sense answer is that any atmosphere in which dust is visible to the naked eye is certainly too dusty to be breathed with safety by human beings, and the wise, farsighted, human employer will imedlately start to decrease the dust content in any atmosphere where dust is visible. After he has eliminated visible dust, there may ^ ^ CO S T 0 0 I3 0 I2 -82- still remain enough very small invisible dust to cause ham to the health of those who breath it, but in any event if he has exerted suf ficient well-directed effort to remove the visible dust it is certain that much of the smaller invisible, and probably most harmful dust has also been removed. "Manifestly, if dust is kept out of the air breathed by workers, the latter cannot succumb to dust disease of a respiratory character." In closing, we acknowledge with gratitude the support and cooperation of Dr. W. J. Denno, General Medical Director, Standard Oil Company (New Jersey) whose vision and active interest in Medico-Safety problems made this Dust Study .possible. We also appreciate the advice and assistance rendered byr Mr. W. P. Yant, Director of Research k Development, Mine Safety Appliances Company, Pittsburgh, Pennsylvania. Dr. Leonard Greehburg, Executive Direotor, Division of Industrial Hygiene, Department of Labor, State of New York, New York, N.Y. Dr. R. R. Sayers, Senior Surgeon, U,S.Public Health Servioe Chief, Division of Industrial Hygiene, National Institute of Health, Washington, D.C. Mr. Daniel Harrington, Chief, Health and Safety Division United States Bureau of Mines, Washington, D.C. Dr. A. J. Lanza, Assistant Medical Director, Metropolitan Life Insurance Company, New York, N.Y. Mr. E. H. Barlow, Chief Engineer, Standard Oil Development Company, Elizabeth, New Jersey. Mr. H. N. Blakeslee, Department of Accident Prevention, American Petroleum Institute, New York, N.Y. New York. N.Y. July Fifteenth 19 3 7 R. S. Bonsib Chief Safety Inspector Standard Oil Co. (N. J. ) 396408