Document 6w8XQZaKKm4L0VEVXvLDxav9E
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LA-MAR-KA MSDS for SODIUM HYDROXIDE, 0.01N TO 2.ON IN METHANOL
1 -PRODUCT IDENTIFICATION
PRODUCT NAME: COMMON SYNONYMS: CHEMICAL FAMILY:
FORMULA: FORMULA WT.:
CAS NO.: NIOSH/RTECS NO.: PRODUCT USE:
SODIUM HYDROXIDE, 0.01N TO 2N IN METHANOL N/A VOLUMETRIC SOLUTIONS AND CONCENTRATES
NAOH IN CH30H
40.09 1310-73-2 WB4905000
LABORATORY REAGENT
CHEMTREC # (800) 424-9300 LA-MAR-KA, INC.
10272 SOUTH PERDUE STREET BATON ROUGE, LA. 70814
EFFECTIVE: 05/01/89 REVISION #04
ISSUED: 04/14/90 REVIEWED 1-1-95
PRECAUTIONARY LABELING
LA-MAR-KA LABELING SYSTEM
HEALTH
3 SEVERE
FLAMMABILITY
3 SEVERE
(
REACTIVITY
1 SLIGHT
CONTACT
3 SEVERE
(POISON) (FLAMMABLE)
(CORROSIVE)
LABORATORY PROTECTIVE EQUIPMENT
GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES; CLASS B EXTINGUISHER
U.S. PRECAUTIONARY LABELING
POISON DANGER
FLAMMABLE. CAUSES BURNS. HARMFUL IF INHALED. MAY BE FATAL OR CAUSE BLINDNESS
IF SWALLOWED. KEEP AWAY FROM HEAT, SPARKS, FLAME. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. AVOID BREATHING VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. IN CASE OF FIRE, USE ALCOHOL FOAM, DRY CHEMICAL, CARBON DIOXIDE - WATER MAY BE INEFFECTIVE. IN CASE OF SPILL, SOAK UP WITH SAND OR EARTH. FLUSH SPILL AREA WITH WATER.
PRECAUTIONARY LABELING (CONTINUED)
INTERNATIONAL LABELING
AVOID CONTACT WITH EYES. AFTER CONTACT WITH SKIN, WASH IMMEDIATELY WITH PLENTY OF WATER. KEEP CONTAINER TIGHTLY CLOSED.
DO A 060625 CONFIDENTIAL
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LA-MAR-KA MSDS for SODIUM HYDROXIDE, 0.01N TO 2.ON IN METHANOL
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1 -PRODUCT IDENTIFICATION (continued)
LA-MAR-KA STORAGE COLOR CODE: RED (FLAMMABLE)
2 -COMPONENTS
COMPONENT SODIUM HYDROXIDE
METHANOL
CAS NO. 1310-73-2 67-56-1
WEIGHT <1-2 >99-98
OSHA/PEL ACGIH/TLV 2 MG/M3 2 MG/M3 200 PPM 200 PPM
3 -PHYSICAL DATA
BOILING POINT: 60 C (140 F) (AT 760 MM HG)
VAPOR PRESSURE (MMHG): 96 (20 C)
MELTING POINT: N/A
I SPECIFIC GRAVITY: 0.79-0.87 (H20=l)
VAPOR DENSITY (AIR=1): 1.11 EVAPORATION RATE: N/A
' { LUBILITY(H20): COMPLETE (100%)
% VOLATILES BY VOLUME: ~99 (21 C)
i PH: N/A
| ODOR THRESHOLD (P.P.M.): N/A
PHYSICAL STATE: LIQUID
COEFFICIENT WATER/OIL DISTRIBUTION: N/A
I APPEARANCE & ODOR: CLEAR, COLORLESS LIQUID. PUNGENT ODOR.
4 -FIRE AND EXPLOSION HAZARD DATA
FLASH POINT (CLOSED CUP): 12 C (54 F)
AUTOIGNITION TEMPERATURE: 463 C (867 F)
FLAMMABLE LIMITS: UPPER - 36.0 %
LOWER - 6.0 %
FIRE EXTINGUISHING MEDIA USE ALCOHOL FOAM, DRY CHEMICAL OR CARBON DIOXIDE. (WATER MAY BE INEFFECTIVE.)
SPECIAL FIRE-FIGHTING PROCEDURES FIREFIGHTERS SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN POSITIVE PRESSURE
<
DO A 060626. CONFIDENTIAL
LA-MAR-KA MSDS for SODIUM HYDROXIDE,
Date Printed: 03-25-1996 0.01N TO 2.ON IN METHANOL
Page 3
4 -FIRE AND EXPLOSION HAZARD DATA (continued)
MODE. MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK. USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL.
UNUSUAL FIRE & EXPLOSION HAZARDS VAPORS MAY FLOW ALONG SURFACES TO DISTANT IGNITION SOURCES AND FLASH BACK. CLOSED CONTAINERS EXPOSED TO HEAT MAY EXPLODE. CONTACT WITH STRONG OXIDIZERS MAY CAUSE FIRE. BURNS WITH A CLEAR, ALMOST INVISIBLE FLAME. FLASH POINT GIVEN IS FOR SOLVENT.
TOXIC GASES PRODUCED CARBON MONOXIDE, CARBON DIOXIDE, FORMALDEHYDE
EXPLOSION DATA-SENSITIVITY TO MECHANICAL IMPACT NONE IDENTIFIED.
EXPLOSION DATA-SENSITIVITY TO STATIC DISCHARGE NONE IDENTIFIED.
5 -HEALTH HAZARD DATA
( IESHOLD LIMIT VALUE (TLV/TWA): 260 MG/M3
(200 PPM)
TLV (SKIN) IS FOR METHYL ALCOHOL.
SHORT-TERM EXPOSURE LIMIT (STEL): 310 MG/M3
(250 PPM)
STEL (SKIN) IS FOR METHYL ALCOHOL.
PERMISSIBLE EXPOSURE LIMIT (PEL): 260 MG/M3
(200 PPM)
PEL (SKIN) IS FOR METHYL ALCOHOL.
TOXICITY OF COMPONENTS
INTRAPERITONEAL RAT LD50 FOR SODIUM HYDROXIDE
INTRAPERITONEAL RAT LD50 FOR METHANOL
SUBCUTANEOUS MOUSE LD50 FOR METHANOL
SKIN RABBIT LD50 FOR METHANOL
CARCINOGENICITY: NTP: NO
IARC: NO
Z LIST:
NO
OSHA REG:
40 9540 9800 20
NO
MG/KG MG/KG MG/KG G/KG
CARCINOGENICITY NONE IDENTIFIED.
REPRODUCTIVE EFFECTS NONE IDENTIFIED.
OO A 060627 CONFIDENTIAL
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LA-MAR-KA MSDS for SODIUM HYDROXIDE, 0.0IN TO 2.ON IN METHANOL
5 -HEALTH HAZARD DATA (continued)
EFFECTS OF OVEREXPOSURE
INHALATION:
ULCERATION, AND BURNS TO MOUTH, THROAT, AND STOMACH, SEVERE IRRITATION OF RESPIRATORY SYSTEM
SKIN CONTACT:
SEVERE BURNS
EYE CONTACT:
SEVERE BURNS, PERMANENT EYE DAMAGE
SKIN ABSORPTION: NONE IDENTIFIED
INGESTION:
IS HARMFUL AND MAY BE FATAL, SEVERE BURNS TO MOUTH, THROAT, AND STOMACH
CHRONIC EFFECTS: NONE IDENTIFIED
TARGET ORGANS EYES, SKIN, CENTRAL NERVOUS SYSTEM, GI TRACT, RESPIRATORY SYSTEM, LUNGS,
LIVER, KIDNEYS
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE EYE DISORDERS, SKIN DISORDERS, LIVER OR KIDNEY DISORDERS
. ^IMARY ROUTES OF ENTRY INHALATION, INGESTION, ABSORPTION, SKIN CONTACT, EYE CONTACT
EMERGENCY AND FIRST AID PROCEDURES
INGESTION:
CALL A PHYSICIAN. IF SWALLOWED, IF CONSCIOUS, GIVE LARGE AMOUNTS OF WATER. INDUCE VOMITING.
INHALATION:
IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
SKIN CONTACT : IN CASE OF CONTACT, IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE RE-USE.
EYE CONTACT: IN CASE OF EYE CONTACT, IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
SARA/TITLE III HAZARD CATEGORIES AND LISTS
ACUTE: YES CHRONIC: YES FLAMMABILITY: YES PRESSURE: NO REACTIVITY: NO
EXTREMELY HAZARDOUS SUBSTANCE: NO
CERCLA HAZARDOUS SUBSTANCE:
YES CONTAINS POTASSIUM HYDROXIDE (RQ = 1000
LBS) AND METHANOL (RQ = 5000 LBS)
DO A 0606P8 CONFIDENTIAL
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LA-MAR-KA
MSDS for SODIUM HYDROXIDE, 0.01N TO 2.ON IN METHANOL
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5 -HEALTH HAZARD DATA (continued)
SARA 313 TOXIC CHEMICALS: GENERIC CLASS:
TSCA INVENTORY:
YES CONTAINS METHANOL CO5
YES
6 -REACTIVITY DATA
STABILITY: STABLE
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
CONDITIONS TO AVOID:
HEAT, FLAME, OTHER SOURCES OF IGNITION
INCOMPATIBLES:
STRONG OXIDIZING AGENTS, STRONG ACIDS, ZINC, ALUMINUM, MOST COMMON METALS, COMBUSTIBLE MATERIALS, ORGANIC
MATERIALS, MAGNESIUM, TIN
DECOMPOSITION PRODUCTS: CARBON MONOXIDE, CARBON DIOXIDE, FORMALDEHYDE
7 -SPILL & DISPOSAL PROCEDURES
( :ps to be taken in the event of a spill or discharge WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. SHUT OFF IGNITION SOURCES; NO FLARES, SMOKING OR FLAMES IN AREA. STOP LEAK IF
YOU CAN DO SO WITHOUT RISK. USE WATER SPRAY TO REDUCE VAPORS. TAKE UP WITH SAND OR OTHER NON-COMBUSTIBLE ABSORBENT MATERIAL AND PLACE INTO CONTAINER FOR LATER DISPOSAL. FLUSH AREA WITH WATER.
DISPOSAL PROCEDURE DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
ENVIRONMENTAL REGULATIONS.
EPA HAZARDOUS WASTE NUMBER:
U154 (TOXIC WASTE)
8 -INDUSTRIAL PROTECTIVE EQUIPMENT
EYE/SKIN PROTECTION:
THIS IS A LABORATORY-USE PRODUCT FOR WHICH NO INDUSTRIAL PROTECTIVE EQUIPMENT HAS BEEN DESIGNATED.
9 -STORAGE AND HANDLING PRECAUTIONS
LA-MAR-KA STORAGE COLOR CODE: RED (FLAMMABLE)
DO A 060629 CONFTDFNTIAL
LA-MAR-KA MSDS for SODIUM HYDROXIDE,
Date Printed: 03-25-1996 0.01N TO 2.ON IN METHANOL
Page 6
9 -STORAGE AND HANDLING PRECAUTIONS (continued)
STORAGE REQUIREMENTS KEEP CONTAINER TIGHTLY CLOSED. STORE IN A COOL, DRY, WELL-VENTILATED, FLAMMABLE LIQUID STORAGE AREA. ISOLATE FROM INCOMPATIBLE MATERIALS.
SPECIAL PRECAUTIONS BOND AND GROUND CONTAINERS WHEN TRANSFERRING LIQUID.
10 -TRANSPORTATION DATA AND ADDITIONAL INFORMATION
DOMESTIC (D.O.T.)
PROPER SHIPPING NAME: METHYL ALCOHOL,MIXTURE
HAZARD CLASS:
FLAMMABLE LIQUID
UN/NA: UN1230
REPORTABLE QUANTITY: 5000 LBS.
LABELS: FLAMMABLE LIQUID
REGULATORY REFERENCES: 49CFR 172.101; 173.119
INTERNATIONAL (I.M.O.)
( OPER SHIPPING NAME: METHANOL
'i-.-i.ZARD CLASS:
3.2
UN: UN1230
MARINE POLLUTANTS: NO
LABELS: FLAMMABLE LIQUID, POISON
REGULATORY REFERENCES: 49CFR 172.102; PART 176;
I.M.O. PAGE: 3 087 PACKAGING GROUP: II
IMO
AIR (I.C.A.O.)
PROPER SHIPPING NAME: METHANOL
HAZARD CLASS:
3.2
UN: UN1230
LABELS: FLAMMABLE LIQUID, POISON
REGULATORY REFERENCES: 49CFR 172.101;
173.6;
PACKAGING GROUP: PART 175; ICAO/IATA
II
U.S. CUSTOMS HARMONIZATION NUMBER: 28152000007
N/A = NOT APPLICABLE OR NOT AVAILABLE N/E = NOT ESTABLISHED
THE INFORMATION IN THIS MATERIAL SAFETY DATA SHEET MEETS THE REQUIREMENTS OF
THE UNITED STATES OCCUPATIONAL SAFETY AND HEALTH ACT AND REGULATIONS
PROMULGATED THEREUNDER (29 CFR 1910.1200 ET. SEQ.) AND THE CANADIAN WORKPLACE
HAZARDOUS MATERIALS INFORMATION SYSTEM.
THIS DOCUMENT IS INTENDED ONLY AS A
GUIDE TO THE APPROPRIATE PRECAUTIONARY HANDLING OF THE MATERIAL BY A PERSON
TRAINED IN, OR SUPERVISED BY A PERSON TRAINED IN, CHEMICAL HANDLING. THE USER
IS RESPONSIBLE FOR DETERMINING THE PRECAUTIONS AND DANGERS OF THIS CHEMICAL
060^30 DO
LA-MAR-KA MSDS for SODIUM HYDROXIDE,
Date Printed: 03-25-1996 0.01N TO 2.ON IN METHANOL
Page 7
10 -TRANSPORTATION DATA AND ADDITIONAL INFORMATION (continued)
FOR HIS OR HER PARTICULAR APPLICATION. DEPENDING ON USAGE, PROTECTIVE CLOTHING INCLUDING EYE AND FACE GUARDS AND RESPIRATORS MUST BE USED TO AVOID CONTACT
WITH MATERIAL OR BREATHING CHEMICAL VAPORS/FUMES.
EXPOSURE TO THIS PRODUCT MAY HAVE SERIOUS ADVERSE HEALTH EFFECTS. THIS
CHEMICAL MAY INTERACT WITH OTHER SUBSTANCES. SINCE THE POTENTIAL USES ARE SO
VARIED, LA-MAR-KA CANNOT WARN OF ALL OF THE POTENTIAL DANGERS OF
USE OR INTERACTION WITH OTHER CHEMICALS OR MATERIALS.
LA-MAR-KA
WARRANTS THAT THE CHEMICAL MEETS THE SPECIFICATIONS SET FORTH ON THE LABEL.
LA-MAR-KA DISCLAIMS ANY OTHER WARRANTIES, EXPRESSED OR IMPLIED, WITH REGARD TO THE PRODUCT SUPPLIED HEREUNDER, ITS MERCHANTABILITY OR ITS FITNESS FOR A PARTICULAR PURPOSE.
THE USER SHOULD RECOGNIZE THAT THIS PRODUCT CAN CAUSE SEVERE INJURY AND EVEN
DEATH, ESPECIALLY IF IMPROPERLY HANDLED OR THE KNOWN DANGERS OF USE ARE NOT
HEEDED.
READ ALL PRECAUTIONARY INFORMATION.
AS NEW DOCUMENTED GENERAL
SAFETY INFORMATION BECOMES AVAILABLE, LA-MAR-KA WILL PERIODICALLY REVISE
THIS MATERIAL SAFETY DATA SHEET.
( APPROVED BY LA-MAR-KA, INC.
DO Co NF
J 06063! Ir>NTtAL