Document 6p414ywwEqdEGLR0XbzgKGR3

MONSANTO TERPHENYLS - M onsanto T e c h n ic a l B u l l e t i n No. P-106 November 6, 1950 5 7> 'x te Us 3 US/5, MONSANTO TERPHENYLS Monsanto Technical Bulletin No. P-106 November 6, 1950 >/,s/v?. Monsanto Chemical Company Phosphate Division St. Louis, Missouri INTRODUCTION RECEIVED APR 13 r-.' k'w...SANTO COMPANY INFORMATION CENTER ST. LOUIS The Monsanto TERPHENYLS are a series of hydro carbon solids ranging in melting point from a little above room temperature to as high as 210C. (4l0p.). Monsanto TERPHENYLS have found use as plasticizers, softening agents, wax additives and extenders, and in paper coatings. Various properties of the TER PHENYLS are presented in this bulletin to facilitate the selection of the proper one for specific appli cations . The Information contained In thia bulletin i, to our beat knowledge, true end accurate, but alI recommenJetlona or auggeatlone are made without guarantee, eince the conditione of uae are beyond our control. The Moneento C hemic al Company dlacleima any liability incurred In connection with the uae of theee data or auggeetione. Kurthermore, nothing contained herein ahall be conatrue.l aa a recommendation to uae any product in conflict with eaiatlng patema covering any malarial or ita uae. 061S122 TOWOLDMONOQ39194 Formula: PHYSICAL PROPERTIES Ortho Meta Para Color - NPA: <1-5 Density - g./cc.: 1.14 Melting Point: Completely liquid 55C. (131F.) <3-5 1.164 90C. (194F.) Solidification Temp First crystals . -- <90C. (<194F.) Hold point , 53-55g. (127-131 F.) Distillation Range: 330-350C. D-20 corrected (626-662F.) Flash Point: 171C. (340F.) Flame Point: 193C. (390F.) 83-8C. (I8l-185F.) 368-378C. (694-712F.) 207C. (405f.) 229C. (445f.) Viscosity S.tJ.S. -----------------aFTT0F.: 40.6 1[See Graph No. I) 39-3 Solubility: See Graphs Nos. II, III and IV <2.0 1.236 213C. (4l5F.) 209-213c. (408-4l5F.) -- 38l-388c. (7l8-730F.) 207C. (405F.) 238C. (460f.) 28.8 (at 22 0635133 TOWOLDMONOQ39195 Vapor Pressure (mm. of Mercury): TC. 90 100 110 120 130 l4o 150 160 170 180 190 200 210 220 230 240 250 260 270 280 290 300 310 320 330 340 350 360 370 380 Ortho 0.17 0.3 0.5 0.9 1-5 2.4 3-7 5-7 8.2 12.0 18.0 25-0 35.O 46.0 62.0 82.0 110.0 140.0 180.0 230.0 290.0 360.0 450.0 550.0 670.0 810.0 990.0 1160.0 1390.0 1600.0 Meta - 0.15 0.3 0.5 0.8 1.3 2.0 3. 4.6 6.8 9.8 14.0 19.0 26.0 36.0 48.0 63.0 83.0 110.0 140.0 180.0 220.0 270.0 340.0 410.0 500.0 610.0 730.0 870.0 Para - - - - 0.15 0-3 0.6 1.0 1.9 3-2 5-5 9.1 14.0 19.0 26.0 35.0 46.0 61.0 80.0 101.0 130.0 165.0 210.0 260.0 320.0 390.0 470.0 570.0 680.0 Solid Terphenyl Ortho Meta Para ELECTRICAL PROPERTIES Dielectric Constant 2.54 2.62 . ' Resistivity - ohm-cm. 16<5UC. _ 82TOTTT09 250UC. - 2600 X 109 "Q 30 X 10* STABILITY No detectible effect on boiling Terphenyls In 10$ Sulfuric Acid or Caustic Soda. 001512*1 TOWOLDMONOQ39196 COMPATIBILITY Ortho Terphenyl Other Component % Ortho Terphenyl In Mixture TT------n--sr--------75------- "90 Paraffin (120/125F-) Barnsdall (l60/l65P.) Beeswax Opal Wax Stearic Acid "N" Wood Rosin CCc CCc CcC i C Ii Ii I i ccIi Meta Terphenyl Other Component % Meta Terphenyl in Mixture lb 2 50 5 go Paraffin (120/125F.) .Incompatible with 2% or more Meta Terphenyl Barnsdall Wax (160/165UP.) CBi i Ceresin IIi Carnauba Wax C Cci Candelllla Wax CCI i Montan Wax IIi Beeswax IIi Japan Wax cII Opal Wax ccI i I. G. Wax 0 IIi Stroba Wax IIi Acra Wax ccB Stearic Acid III Shellac c II Manila Resin (Loba B) c I I Ester Gum c I I. "N" Wood Rosin (Hercules) ccI I Piccolite Resin (85) c I I Staybelllte Resin BII Para Terphenyl Other Component Paraffin (120/l25P.) Paradene No. 1 Paradene No. 2 "N" Wood Rosin % Para Terphenyl in Mixture 1-2 1 5 10-75 i cI CI I Note: C m Compatible I Incompatible B a Almost Compatible -3- TOWOLDMONOQ39197 COMPARATIVE HARDNESS (Smaller values denote greater hardness) Average Penetration in cm. x 10'2 In 60 seconds at 25C. under load Indicated (ASTM D-5-25) Material 50 Grams 150 Grams 250 Grams Meta Terphenyl Para Terphenyl Carnauba Wax 0 0 2-3 0 0 3-3 0 2-3 4.7 Candelllla Wax 0 3-3 4.7 Ortho Terphenyl 1.3 4.0 10.7 50# Paraffin & 50# Meta Terphenyl 3-7 12.3 18.0 75# Paraffin & 25# Meta Terphenyl 7.3 18.0 25-3 Ceresln Wax 9-3 15-7 26.0 95# Paraffin & 5# Meta Terphenyl 10.7 21.0 29-7 98# Paraffin & 2# Meta Terphenyl 11.7 26.0 32-7 Paraffin Wax 14.3 23-3 31-3 Montan Wax 15-0 28.7 37-3 Mixed Isomeric Terphenyl No aging Aged 24 hours 60.0 28.7 " AVAILABILITY The Terphenyls are available In limited quantities. sc:wa-m-1150 rev. -im 0bl512b printed In U.S.A. TOWOLDMONOQ39198 TEMPERATURE. DEGREES FAHRENHEIT VISCOSITY. SAYBOLT UNIVERSAL SECONDS VISCOSITY. SAYBOLT UNIVERSAL SECONDS TEMPERATURE. DEGREES FAHRENHEIT 06151^7 ! TOWOLDMONOQ39199 T em p.C . Graph II - SOLUBILITY OF ORTHO TfcKFtlfcHiL. TOWOLDMON0039200 Graph III SOLUBILITY OP META TERPHENYL Temp C .. TOWOLDMONOQ39201 Temp Graph IV - SOLUBILITY OP PARA TER PHENYL TOWOLDMON0039202 / Monsanto Chemicals-Plastics _______ u For further Information about Monsanto TERPHENYLS contact the nearest Monsanto office. MONSANTO CHEMICAL COMPANY St. Louis Birmingham Boston Charlotte Chicago Cincinnati Cleveland Detroit Los Angeles New York Philadelphia Portland (Ore.) San Francisco Seattle Monsanto (Canada) Ltd. Montreal Toronto Representatives in the Principal Cities of the World 0615131 TOWOLDMONOQ39203