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ACUTE TOXICITY TO FISH ARDE-0195 Frees TEST SUBSTANCE Identity: Perfluorooctanesulfonate, Ammonium salt; may also be referred to as PFOS NH," salt or FC-93. (1-Octanesuffonic acid, 1,1,2,2,33,4,4,5,5,6,6,7,7,8,8,8-heptadecafluoro-, ammonium salt, CAS # 29081-56-9) Remarks: Test sample was taken from 3M production lot #1. The test sample is a mixture of the test substance in isopropanol and water (25% test substance, 20% isopropanol, 55% water). No calculations were made to adjust for the actual concentrationof the test substance in the test sample. METHOD Method: Not noted. Type: Static acute GLP: No Year completed: 1974 Species: Pimephales promelas Supplier: Not noted. Analytical monitoring: pH and DO content Exposure period: 96-hours Statistical methods: Plotted LCso. Test fish age: Not noted. Length and weight: Average length = 2 inches, Average weight = 1.5 g Loading: Not noted. Pretreatment: Not noted Test conditions: Dilution water: Carbon filtered city of St. Paul, MN water Dilution water chemistry: Not noted. Stock and test solution preparation: Not noted. Concentrations dosing rate: Once Stabilityof the test chemical solutions: Not noted. Exposure vessels: Not noted. Number of replicates: One. Number of concentrations: five plus a negative control Water chemistry during the study: Dissolved oxygen range (0 -- 96 hours): 4.5-5.7 mg/L (control exposure) 3.8-5.0 mg/L (125 mg/L exposure) 04610 RESULTS Not recorded at highest conc. (150 mg/L) due to 100% mortality. pH range (0 -- 96 hours) 77..00-77..00 ((c1o2n5trmogl/eLxpeoxspuorseu)re) Not recorded at 100% mortality. highest conc. (150 mg/L) due to Test te2m0p-er2a1tuCre(r6a9-n7g0eF()0 -- 96 hours) ENloemmiennatl vcaolnucee:nt9r6a-thioounrs:LCBks=co1nt0r0olm,g5/0L, (7C5.,.1n0o0t, d1e2t5e,rm1i5n0edm)g/L Mortality of controls: None ARdedmitairoknasl:ly, t9es5t%ingcownafsidceonncdeulcitmeitds ownertehenomtixctaulrceuolfattehdefotrestthissubmasttearniacle.in 20% isopropanol and 55% water. The value reported applies to that t`mhiextiumrpeaacntdofntothethperetsesetncsueobsfttahneceo.rgNanoicatstoelmvpetntwoarswmhaatdepotrotidoenteofrmtihnee toxicity can be contributed to the Perfluorooctanesulfonate, ammonium salt. CONCLUSIONS eTxhheibtietsetdsaam9p6l-ehocuorntLaCisnainfogr2f5at%hePaedrfmliunornooowctoafne1s0u0ifmogn/atLe, ammonium salt Submitter: 3M Company, St. Paul, Minnesota, 55133 Environmental Laboratory, P.O. Box 33331, DATA QUALITY Reliability: Kiimisch ranking 3. REFERENCES This study was conducted by the 3M Company, Environmental Laboratory, 10/15/74 to 10/19/74. OTHER Last changed: 5/3/00 04611 Te msm TTT ae tome A6\oul- static ). Test oxganten_Totlpd Kivi ow " Date Started \o-\% Ng z TingStarted | ET I i Tei ye : "Bitution sor x 00 pW honSkid i Material Tested FC As \ot Avg. Weight Msg sin 2Tuc Date Completed. A0-\O 1g er * . Plotted LC,0. 1D000 PPU F2al[woee|JrolE sa] vr o J70]en|[eo |Jea0la[s]vo 70 [ofa Toad : " | oo Joo ee] [ozo]sol Jeafan] so so[nas]ao Jzolac]oy [zoel 20 sala Jada] ) im aol] 0[Elo TT old] GE = Ee pxwo - 2d: . : 100} FH TE fi fr Frey LG Goyg R mE eT e o ET h Lolly peli bain di EH SSHHEIL REECmmLeTeeb : PEalnyn ndig1 en fiaikie J 0 50 se WWW 0 wp "9% 100 Survival * }" 04612 Csiro (PRON So]faash] A 4.0.7" LAB REQUEST BOOK -- s25w BEST COPY AVAILABLE 5 4 Ae 2 WaterandWastewater SN - TO: REQUEST FOR LABORATORY WORK ENVIRONMENTAL ENGINEERING LABORATORY -- Lib Reauetho. 2 _ 454 BUILDING 53.6N ) Requestor Lab Personnel PDNrauomjoecttEoN0onQ.0TC0IONA_LsFCro qiNeuo.eeSmeT 10-- s -=11 ADneVsmeE,eRt JJ, HSoulmdpSleDuate:Fmor plDaeyuteExe.nTdiemed::+ Fim. +. HDiast.eSCpoemntp:ltad: 30-10 = : faa mgancacos Calcium Hardmng/lesssCasCO,a TTL TT TT TP Alkalinity,mi 0sCaCO "MT Alkalinity, mg/l as CaCO3 r rrr r r r r p emg Nitrate, rT mg/r l as NO3 rp 11 ---- 1 14 hors, mg 351 Silica, mg/l as 5107 r FT r T r T ori, molt a5 ) OIrtoho PhoPsopohhaiten,mmaa/alra5 7 rT r T r T r rr rr TTFoooxtu.allCCCyhrarnooimdmie,u,mm,gmtg/t5lasCasGNCrr Ferrocyaics,my 5 CN r r IEE r IE r I ECS T r S-- Tron, mg/tasFe rrr SurSfSactetannt,mmg/r lassLnAS : r 1 rp r 1 ------ e -- 1 -- T H +.TmBotOeaDln,SmugsD pendedSic, re] 1711 TTVooolrtabtiSilodelySi,udms,pgemndSeidtSeoslids,mg ~ r Hrrr y r s 1 TCTooottnaadllucBVtoialvacittityl,,e mSNooloisdTs,OmOg/Tl HTH r rer TT 1 Toul Golfo, No 1G mT Fecal Coliform, No./100 mi tr+ r " v FKFioecemadelirdSitareheNpittorcoogcecnus,m,gN/ol.s/s10N0 mo l H m r ] T TT TT H e es.t .77AC e 2-27r , AS H C I --0T RTT v1 eyo -- mm-- , - |) Somme, oO _-- -- -- re eee S PSY pmoo tk SHAY 7e 2-9z5e 2570m 046 nits Emiroomantel Engrs. Lab Canary--EnFicro-nmge2ntaa Engrs. ooo Lob ink--Eira Free 1 ote -- mof -- MDAATTAERISHAELETSAFETY am aM Center st. Paul, Minnesota 515-184040--1306040-3577 or (651) 737-6501 (24 hours) ACLoLpyrriigghhtt,s r1e9s99e,rveMdi.nnesCootpayinMginianngd/oarnddMoawnnluofaadcitnugrinogf Ctohmipsany. iisnfoarlmlaotwieodnpfroorvidtehde purpose that: of properly utilizing 3M products 1) pthreiorinafgorremeamteinotn iiss ocbotpaiiendedinffroumllaMw,ithandno changes unless 2) neither the distributed copy with nor the the original intention of eiasrnriensgolda oprrofoittherthweirseeon. DTIRVAIDSEIONNA:ME: 3M SPECIALTY MATERIALS IDFNCU-M9B3ERF/LUU.OPR.ACD.:Brand Etching Bath Additive IS9SU8E-D0:21D1e-c0e1m9b2e-r2 00-51135-09187-6 17, 1999 98-0211-0201-1 SUPERSEDES: September DOCUMENT: 10-3795-1 04, 1998 00-51135-09190-6 1. INGREDIENT C.A.S. NO. PERCENT WAAMTMEORN.IU.MooPuEvRuFiLtUiOeRsOeAsLeKeYLeeSeUeLsFeOeNeAsTsEi.u.u.s.s.s.s. 720708821--1586--59 19.0 - 5253..00 AIMSMOOPNRIOUPMYLPAELRCFOLHUOOLROA(LIKPYAL).S.U.L.F.O.N.A.T.E............... 66872-5603--007-4 0.1 - 22.00.0 AMMONIUM AMMONIUM PERFLUOROALKYL PERFLUOROALKYL SULFONATE....... SULFONATE....... 68259-08-5 68250-08-6 00..11 -- 22..00 AMMONIUM PERFLUOROALKYL SULFONATE....... 68250-10-8 0.1 - 2.0 nTohteifciocmaptoinoenntsreoqfuitrheimsentpsrodoufctTSCaAr.e iAnLLcomapplpilainccaeblewicthhemtihcealchemical EixnigsrteidnigentCshemiincatlhisSubmsattaenrcieasl a(rEeINElCiSs)t,edoronatreheeExeumrpotpeapnolIymnevresntwohroyseof monomers are listed on EINECS. 2. PHYSICAL DATA BOILING POINT:........0uee..... VAPOR PRESSURE:................ VAPOR DENSITY:.....uveneeenssss SEOVLAUPBOIRLAITTIOYNIRNATWEA:T.E.R.:...................... PSPEERCCIEFNITCVOGLRAATVIILTEY::...................0..... PHicoeeis ieee, C8. 82 C C4(.Ini3t4iamlm)Hg C8C.alc1..0 @Ad2r0etC. <Ca1l.c0. BU@OA2C0=1C. moderate ccaa.. 716.1%Water=1 CAL T Abbreviations: N/D - Not Determined N/A - Not Applicable 04614 CA - Approximately DMSeDcSe:mbeFrC-9137, FL1U9O9R9AD Brand Etching Bath Additive PAGE 2 2. PHYSICAL DATA (continued) VISCOSITY:....viieueieneeeees NI(D0.1% Aqueous) MELTINGPOINT:..... 10010000 Nya APPLEiAqRuiAdN,CECAlNeDarODaOmRb:er solution, Ammonia, Isopropyl Alcohol odor. 3. FIRE AND EXPLOSION HAZARD DATA FFLLAAMSMHABPLOEINTL:I.M.I.T.S..=..L.E.L:....0.0.1.0..) N27/DC Sotaflash AFULTAOMIMGANBILTEIOLNIMTIETMSPE-RAUTEULR:E.:...........]. NN//DD EXWTaItNeGrU,ISCHaIrNbGonMEDdIiAo:xide, Dry chemical, Foam SPWEeCaIrALfuFlIlREpFrIoGtHecTtIiNvGePcRlOoCtEhDiUnRgE,S: including helmet, self-contained, aPnodsitpianvtes,prebsansdusreaorrounpdresarseusr,e wdaeimsatndanbdrealetghsi,ngfaapcpearmaatsku,s,anbdunker coat protective covering for exposed areas of the head. UNSUeSeUALHazFaIrREdouAsNDDeEcXoPmLpOoSsIiOtNioHnAZAsReDcSt:ion for products of combustion. 4. REACTIVITY DATA STABILITY: Stable INNCoOtMPaApTpIlBiIcLaIbTlYe.- MATERTALS/CONDITIONS TO AVOID: HAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur. HACZaArRbDoOnUSMoDnEoCxOiMdPeOSIanTdIONCarPbRoOnDUCDTiSo:xide, Oxides of Sulfur, Hydrogen Fluoride, Ammonia, Toxic Vapors, Gases or Particulates. 04615 Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately DMSeDcSe:mbeFrC-9137, F1L9U9O9RAD Brand Etching Bath Additive PAGE 3 5. ENVIRONMENTAL INFORMATION SPIRLefLerREStoPONoStEh:er sections of this MSDS for information regarding ppheyrssiocnaall panrdotehcetailvteh ehqauziaprdmse,nt.resVpeinrtatiolrayteparroetae.ctioEnx,tinvgenutiislhatailoln, and firgonmitihoanzarsdouracreesa.. CCoovnetarinWitshpilalb.sorbEevnatcuamtaeteruinaplr.oteCcotveedrpseprislolnnealrea AwiTtChfoLainghtusaWgaet,ercoBnrtaancdto3rMoFtihreer APTrCotefocatmi.on (SFyosrtefmusr.t)herCoilnlfeocrtmatuisoinngon anpopnr-osvpeadrkimnegtaltooclosn.tainCelre.an Suepalrestihdeuecownitatihnewra.ter. Place in an RECOMMENDED DISPOSAL: pIrnocdiuncetrsatewililn iancpleurdmeittHFe.d hazardous waste incinerator. Combustion ENCVoInRtOaNiMnEsNTAoLnlDyAT"Ae:xempt* solvents by `Rule 66 type regulations; COD=.41 . p0/r0o;melBaOsD)2=08=5.29mg/g1/.g; 96-Hr. LC50, Fathead Minnow(Pimephales REGULATORY Volatile OIrNgFaOnRiMcATICOoNm:pounds: 220 gas/Liter. VOC Less H20 & Exempt Solvents: N/A. bSeifnocreerdeigsuploastailo.ns vIanryt,heceovnseunlttofappanlicuanbcloentrroelglueldatiroenlseasoer oafuthtohrisities rmaetpeorritaalb,letqhueanutsietry.shoUu.lSd. dEePtAerHmainzeardiofusthWeasrteeleaNsuembeqrual=ifiDe0s01 as a (Ignitable) This product requirements is of TiSnCAc,ompElINiEaCnSc,e AwIiCtSh, tChDeSLc,heMmIiTcIalanrdegiKsorteraa.tion OTHTEhRisEpNrVoIdRuOcNtMEcNoTnAtLaiInNsFORoMnAeTIoOrN:more organic fluorochemicals that have the potential to resist degradation and persist in the environment. EPFCIRRAE HHAAZZAARRDD:CYLAeSsS: PRESSURE: No REACTIVITY: No ACUTE: Yes CHRONIC: Yes 6. SUGGESTED FIRST AID EYEImCmOeNdTiAaCtTe:ly flush eyes with large amounts of Water. Get immediate medical attention. 004616 Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately DMSeDcSe:mbeFrC-9137, FL1U9O9R9AD Brand Etching Bath Additive PAGE 4 6. SUGGESTED FIRST AID (continued) SKIFNlusCOhNTsAkCiTn: With large amounts of water. If irritation persists, get medical attention. INHIfALAsTiIgOnNs:/symptoms occur, remove person to fresh air. If signs/syaptons continue, call a physician. IF SHALLOWED: If swallowed, call the instruction of a a pphhyyssiicciiaann. iNmemveedriatgeilvye. aOnnyltyhinigndubcyemvooumtihtitnoganat unconscious person. 7. PRECAUTIONARY INFORMATION EYE PROTECTION: Avoid eye contact with vapor, spray, or mist. Hear vented goggles. SKIN PROTECTION: mAavtoeirdiaslk.in Aconptaaicrt.of gWelaorvesappmraodeprifartoem tghleovefsolWlhoewninghanmdaltienrgialt(hsi)s are recommended: butyl personal protection rubber. items as nUesceesosnaeryortomorperevofenttheskifnolcloonwtiancgt: mapardoen,ofcoevietrhaelrlso.f thPerotfeocltliovweinggarmamteenrtisal(so:ther than gloves) should be polyethylene/polyvinylidene chloride (Saranex). RECOMMENDED VENTILATION: pIrfoteexchtaiuosnt. venPtriolvaitdieonvenistilnaottioandeqaudaetqeu,ateuseto acpopnrtorporliatveaporrespiratory ocronmciesntt.rations below recommended exposure limits and/or control spray REASvPoIiRdATObRrYeatPhRiOnTgECToIfONa:irborne material. Select one of the following cNIoOnStHamianpapnrtosvedandreisnpiarcactoorrdsanbcaesewditohn OaiSrHbAorrengeulcaotnicoennst:ratiHoanlf-omfask organic vapor respirator with dust/mist prefilter. PREVENTION OF Do not eat, AdCrCiInkDENorTALsmoIkNeGEWSThIeOnN:using this product. Wash exposed areas thoroughly before eating. with soap and water. Hash hands after handling and RECOMMENDED STORAGE: oSrtorpeharamwaacyeuftriocmalasr.easSwthoerreeapwraoydufcrtommahyeatc.omeStionrteo ocuotntaocftdwiirtechtfood sunlight. Keep container closed when not in use. Keep container in 04617 Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MSDS: FC-93 FLUORAD December 17, 1999 Brand Etching Bath Additive PAGE 5 7. PRECAUTIONARY INFORMATION (continued) well-ventilated area. FIKREeepANDconEtXaPiLnOeSrIONtiAgVhOtIlDyANcClEo:sed. Flamsable 1iquid and vapor. Keep away from heat, sparks, open flame, and other sources of ignition. OTHNEoRsmPoRkEiCnAgU:TISOmNoAkRiYngINwFOhRiMlAeTIuOsNi:ng this product can result in ocfonttaheminhaatziaorndouosf dtheecomtpoobsaictcioonanpdr/oodrucstmsokemenatnidonleedadintothteheRefaocrtmiavtiitoyn Data section of this MSDS. HIS HAZARD RATINGS: HPEERASLONTAHL2:PROFTLEACMTMIAOBNI:LITXY:(Se3e pRrEeAcCaTuItViIoTnYs:, 0section 7.) EXPOSURE LIMITS INGREDIENT VALUE UNIT TYPE AUTH SKIN WAAMTMEORN.I.U.M.PuEvRvFuLiUOiRvOiAeLiKYnLniSnULiFiOeNiAeTEe.e.s... IISSOOPPRROOPPYYLL AALLCCOOHHOOLL ((IIPPAA))............................ IISSOOPPRROOPPYYLL AALLCCOOHHOOLL ((IIPPAA))............................ AAMMMMOONNIIUUMM PPEERRFFLLUUOORROOAALLKKYYLL SSUULLFFOONNAATTEE........ AMMONIUM AMMONIUM PERFLUOROALKYL PERFLUOROALKYL SSUULLFFOONNAATTEE........ N0.O1NE NMOGN/EM3 400 500 PPM PPM 540000 PPPPMM 0.1 0.1 Ma/M3 Ma/M3 0.1 0.1 MMGG//MM33 NTOANE aNMONE THA ACGIH TSTHEAL OAScHaAIH STEL OSHA THA aM THA aM Y Y TTHHAA aaMM YY t*heSKIpNoteNnOTtAiTaIlONc:ontrLiibsutteidonsubtsottahnecesoveirnadlilcateexdposwuirteh b'yY' thuendecrutSaKnIeoNusrerfoeurteto ibnyclduidriencgt mcuocnotuasctmewmibthranteheansdubseytea,ncee.ithVeerhibcyleasirbcaonrnealotre,r more skin particularly, absorption. S- OaUMR:CE OF3MEXRPeOcSoUmREmenLdIeMdITEDxApToAs:ure Guidelines - ACGIH: OSHA: American Conference Occupational Safety of Governmental Industrial and Health Administration Hygienists - NONE: None Established 8. HEALTH HAZARD DATA EVMEilCdONTEAyCeT:Irritation: signs/syaptoms can include redness, swelling, pain, and tearing. 04618 Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MDSeDcSe:mbeFrC-9137, F1L9U9O9RAD Brand Etching Bath Additive PAGE 6 8. HEALTH HAZARD DATA (continued) SKIN CONTACT: MsiilgdnsS/ksiynptIornrsitcaatnioninc(laufdteerrepdrnoelsosn,gedswoerllirnegp,eaatnedd contact): itching. Mtahyosebecaaubsseodrbebdy tihnrhoaulgahtiotnheasnkdi/noranidngepsrtoidounc.e effects similiar to INHsAiLnAgTlIeONo:verexposure, above recommended guidelines, may cause: Cheeandtarcahle,NerdviozuzsineSsyss,temdrDoewspirneessssi,on:incsoiogrndsi/nsaytmipotno,asslcoanwedincrleuadcetion `tine, slurred speech, giddiness and unconsciousness. sIorrreinteastsionof(tuhpepenrosreespaindrattohrryo)a:t, sicgonugsh/isnygaptaondmssnceaenziinngc.lude IF SHALLOWED: Ainnimtahlisstpurdoideusctcionnddiuccatteed oenffeocrtgsaniicncflluudoinrgochleimviercadlisstwuhribcahncaerse,pwreeisgehntt laodsrse,nallosasndofheampapteotliotgei,c lefeftehcatrsg.y, Thaenrdenaeruerolnoogikcnaolw,n phuamnacnreahteiacl,th wehfefnectussefdroams iannttiecnidpeadteadndeixnpsotsruurcetetdo. these organic fluorochemicals Illness may result this material. from a single swallowing of a moderate quantity of pIarirni,tatviomointionfg,GasatbrdoomiinntaelstitneanlderTniessssu,es:naussiegan,s/sbylmopodtomisn vcaonmitiunsc,ludaend blood in feces. Cheeandtarcahle,NedrivzozuisneSsyss,temdrDowespirneessssi,on:mussciuglnasr/swyeaapktnoemsss,canincionocrlduidneation, sgliodwdeidnesrse,acttiroenmortsimea,ndfactoingvuuel,siobnlsu.rred vision, slurred speech, Ingestion may cause: dAsipfifriactuilotny bPrneeautnhoinnigt,is:Wheseizginnsg/,syacpotuogmhsingcaunpibnlcolouddeancdougphnienugm,onia, which can be fatal. OTAHERProHdEuAcLtTHTHoAxZiAciRtDyISNuFmOmRaMArTyIOSNh:eet is available. Tthheispportoedntuicatlctoontabiensabosnoerbeodr amnodreroermagiannicinftlhueorobocdhye.mifcoralslotnghatperhiaovdes of time, either accusulate with arseptehaetedpaerexnptosumroelse.cuTlheeroer aasrementoabkonloiwtnesh,umaannd hmeaaylth 04619 Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately MDSe0cSe:mbeFrC-9137, FL1U9O99RAD Brand Etching Bath Additive PAGE 7 8. HEALTH HAZARD DATA (continued) wehfefnectussedfroams anticipated exposure to these intended and instructed. organic fluorochemicals Tphoepulparteisoennceandofsoubrpgoapnuilcatfilounosr,ochseumcihcaalssWoirnketrhse, blhaosodbeofenthpeubgleisnheerdal wdoartkinegrsbaicnkdictaotetsheno197a0d'vse.rse3'esffeecptisd.emiological study of its own SECTION CHANGE DATES PRECAUTIONARY INFO. SECTION CHANGED SINCE September 04, 1998 ISSUE Abbreviations: N/D - Not Determined N/A - Not Applicable CA - Approximately TbheecoirnrfeocrtmataisonofinthethidsateMatiesrsiueadl.SafGMetyMAKDEaStaNSOhWeAeRtRA(NMTSIDESS), isEXbPeRlEiSeSvEeDdOtRo MIEMRPLCIHEADN,TABIINLCLIUTDYINOGR, FBIUTTNENSOSTFLORIMAITEPDARTTOI,CUALNAYR IPMUPRLPIOESDE WORARCROAUNRTSYEOFOF PwEhReFtOhReMrANtChEe O3RM pUrSoAdGuEctOFiTsRAfDiEt.forUsaerpairstirceuslpaornsipbulreposfeoranddetesrumiitnaibnlge for ucasner'asffmecetthotdheofuseuseandoraapppplliiccaattiioonn.of GaivGeMnptrohdeucvta,riestoymeofoffWahcitocrhsartehat uniquely the user ewivtahliunatethetheus3erM'sprokdnuocwtledtgoedeatndermcionnterowlh,ethietrisit eisssefnittialforthaat particular purpose and suitable for user's method of use or application. 3Dueptroovitdheesreimnoftoermaptoisosnibiilniteylectthratonieclecftorrmoniasc tarasnesrfveircemtaoy ihtasvecursetsoumletresd. rinepreerrsoernst,atioomnisssiaosnstooritsalctoemrpalteiotnesnesisn torhisacciunrfaocrym.atioInn,adSdMitmiaokne,s no iinnffoorrmmaattiioonn oinbtatihneedMSDfSromavaaidlaatbalbeadsieremcatylynotfrobme as current SH. as the 04620