Document 6bdzEG86Bvyq9LEpgww65oMN6
FLEXON 766
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E^ON COMPANY. USA
A DIVISION OF EXXON CORPORATION
date ISSUED:
06/01/69
SUPERSEDES DATE: 05/19/B9
MATERIAL SAFETY DATA SHEET
EXXON COMPANY. U.S.A.
P.O. BOX 2180
HOUSTON, TX 77252-2180
A. IDENTIFICATION AND EMERGENCY INFORMATION
PRODUCT NAME FLEXON 766
CHEMICAL NAME Petroleum Process Oil
PRODUCT APPEARANCE AND ODOR Clear liquid, light yellow color Mild, bland petroleum odor
MEDICAL EMERGENCY TELEPHONE NUMBER (713) 656-3424
PRODUCT CODE 346046 - 03331
CAS NUMBER 64741-96-4
B. COMPONENTS AND HAZARD INFORMATION* 1
COMPONENTS
CAS NO. OF COMPONENTS
APPROXIMATE CONCENTRATION
Solvent refined heavy naphthenic distillate, petroleum
64741-96-4
100%
This product and all components are listed on the U.S. TSCA Inventory.
S e Section E for Health and Hazard Information.
See Section H for additional Environmental Information.
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (HMIS)
Health Flammability Reactivity
BASIS
1 1 0 Recommended by Exxon
EXPOSURE LIMIT FOR TOTAL PRODUCT 5 mg/m3 for oil mist in air
BASIS OSHA Regulation 29 CFR 1910.1000
5 mg/m3 for oil mist
Recommended by the American Conference of Governmental Industrial Hygienists (ACGIH)
5 mg/m3 for mist In air
Recommended by Exxon
C. PRIMARY ROUTES OF ENTRY AND EMERGENCY AND FIRST AID PROCEDURES
EYE CONTACT If splashed into the eyes, flush with clear water for 15 minutes or until Irritation subsides. If irritation persists, call a physician.
SKIN In ease of skin contact, remove any contaminated clothing and wash skin thoroughly with soap and water.
INHALATION Vapor pressure Is very low. Vapor inhalation under ambient conditions is normally not a problem. If overcome by vapor from hot product. Immediately remove from exposure and call a physician. If breathing is irregular or has stopped, start resuscitation; administer oxygen, if available. If overexposed to oil mist, remove from further exposure until excessive oil mist condition subsides.
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FLEXON 766
INGESTION If ingested, DO NOT inquce vomiting; call a physician immediately.
D. FIRE AND EXPLOSION HAZARD INFORMATION
FLASH POINT (MINIMUM) 220*C (428`F) ASTM D 92. Cleveland Open Cup
AUTOIGNITION TEMPERATURE Greater thai^ 260'C (500*F)
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) - HAZARD IDENTIFICATION
Health Flammabt1 tty Reactivity
BASIS
11
0 Recommended by Exxon
HANDLING PRECAUTIONS Use product with'cautlon around heat, sparks, pilot lights, static electricity, and open flame.
FLAMMABLE OR EXPLOSIVE LIMITS (APPROXIMATE PERCENT BY VOLUME IN AIR)
Estimated values: Lover Flammable Limit 0.9%
Upper Flammable Limit 7%
EXTINGUISHING MEDIA AND FIRE FIGHTING PROCEDURES Foam, water spray (fog), dry chemical, carbon dioxide and vaporizing liquid type extinguishing agents may all be suitable for extinguishing fires involving this type of product, depending on size or potential size of fire and circumstances related to the situation. Plan fire protection and response strategy through consultation with local fire protection authorities or appropriate specialIsts.
The following procedures for this type of product are based on the recommendations in the National Fire Protection Association's "Fire Protection Guide on Hazardous Materials", Eighth Edition (1984):
Use water spray, dry chemical, foam or carbon dioxide to extinguish the fire. Use water to keep fire-exposed containers cool. If a leak or spill htfs not ignited, use water spray to disperse the vapors and to provide protection for men attempting to stop a leak. Water spray may be used to flush spills away from exposures. Minimize breathing of gases, vapor, fumes or decomposition products. Use supplleo-alr breathing equipment for enclosed or confined spaces or as otherwise needed.
DECOMPOSITION PRODUCTS UNDER FIRE CONDITIONS Fumes, smoke, carbon monoxide, sulfur oxides, aldehydes and other decomposition products, in the case of incomplete combustion.
"EMPTY*1 CONTAINER WARNING
"Empty" containers retain residue (liquid and/or vapor) and can be dangerous. DO NOT
PRESSURIZE. CUT, WELD, BRAZE. SOLDER. DRILL. GRIND OR EXPOSE SUCH CONTAINERS TO HEAT.
FLAME, SPARKS. STATIC ELECTRICITY. OR OTHER SOURCES OF IGNITION; THEY MAY EXPLODE AND CAUSE
INJURY OR DEATH. Do not attempt to clean since residue is difficult to remove. "Empty* drums
should be completely drained, properly bunged and promptly returned to a drum reconditioner.
All other containers should be disposed of in an environmentally safe manner and in
accordance with governmental regulations. For work on tanks refer to Occupational
Safety and Health Administration regulations, ANSI Z49.1, and other governmental and
industrial references pertaining fo cleaning, repairing, wpldlng. or other contemplated
operations.
E HEALTH AND HAZARD INFORMATION
VARIABILITY AMONG INDIVIDUALS Health studies have shown that many petroleum hydrocarbons and synthetic lubricants pose potential human health risks which may vary from person to person. As a precaution, exposure to liquids, vapors, mists or fumes should be minimized.
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DATE ISSUED:
06/01/89
SUPERSEDES DATE: 05/19/89
FLEXON 766
EFFECTS OF OVEREXPOSURE (Signs and symptoms of exposure) Prolonged or repeated skin contact may cause skin irritation.
NATURE OF HAZARD AND TOXICITY INFORMATION In accordance with the current 05HA Hazard Communication Standard criteria, this product does not require a cancer hazard warning. This is because the product is formulated from base stocks which are severely hydrotreated, severely solvent extracted, and/or processed by mild hydrotreatment and extraction. Alternatively, it may consist of components not otherwise affected by IARC criteria, such as atmospheric distillates or synthetically derived materials, and as such is not characterized by current IARC classification criteria.
Prolonged or repeated skin contact with this product tends to remove skin oils, possibly leading to irritation and dermatitis; however, based on human experience and available toxicological data, this product Is Judged to be neither a "corrosive" nor an "Irritant" by OSHA criteria.
Product contacting the eyes may cause eye irritation.
Product has a low order of acute oral and dermal toxicity, but minute amounts aspirated into the lungs during ingestion or vomiting may cause mild to severe pulmonary injury and possibly death.
This product is Judged to have an acute oral LD50 (rat) greater than' 5 g/kg of body weight, and an acute dermal LD50 (rabbit) greater than 3.16 g/kg of body weight.
PRE-EXISTING MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY EXPOSURE None Recognized
F. PHYSICAL DATA
The following data are approximate or typical values and should not be used for precise design purposes.
BOILING RANGE IBP Approximately 329'C (625`F) by ASTM D 2887
VAPOR PRESSURE Less than 0.01 mm Hg a 20' C
SPECIFIC GRAVITY (IS.6 C/15.S C) 0.89
VAPOR DENSITY (AIR 1) Greater than 5
MOLECULAR WEIGHT Approximately 440
PERCENT VOLATILE BY VOLUME Negligible from open container in 4 hours e 38'C (100" F)
PH Essentially neutral
EVAPORATION RATE * 1 ATM. AND 28 C (77 F) (n-BUTYL ACETATE - 1)
Less than 0.01
POUR, CONGEALING OR MELTING POINT -9' C ( IS' F ) Pour Point by ASTM D 97
SOLUBILITY IN WATER 1 ATM. AND 25 C (77 F)
Negligible: less than o.1%
VISCOSITY 485 SSU P 100'F
G REACTIVITY
This product is stable and will not react violently with water. Hazardous polymerization will not occur. Avoid contact with strong oxidants such as liquid chlorine, concentrated oxygen, sodium hypochlorite or calcium hypochlorite.
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confidenttal
DATE ISSUED:
08/01/89
SUPERSEDES DATS 1 ^5/'9-89
FLEXON 766
H. ENVIRONMENTAL INFORMATION
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Recover free product. Add sand, earth, or other suitable absorbent to spill area. Minimize skin contact. Keep product out of sewers and watercourses by diking or Impounding. Advise authorities If product has entered or may enter sewers, watercourses, or extensive land areas. Assure conformity with applicable governmental regulations.
THE FOLLOWING INFORMATION MAY BE USEFUL IN COMPLYING WITH VARIOUS STATE AND FEDERAL LAWS AND REGULATIONS UNDER VARIOUS ENVIRONMENTAL STATUTES:
REPORTABLE QUANTITY (RQ), EPA REGULATION 40 CFR 302 (CERCLA Section 102) No RQ for product or any constituent greater than 1% or 0.1% (carcinogen).
THRESHOLD PLANNING QUANTITY (TPQ), EPA REGULATION 40 CFR 3SS (SARA Sections 301-304) No TPQ for product or any constituent greater than IX or 0.1% (carcinogen).
TOXIC CHEMICAL RELEASE REPORTING, EPA REGULATION 40 CFR 372 (SARA Section 313) No toxic chemical is present greater than 1% or 0.1% (carcinogen).
HAZARDOUS CHEMICAL REPORTING, EPA REGULATION 40 CFR 370 (SARA Sections 311-312)
Acute Chronic Fire
Pressure Reactive
EPA HAZARD CLASSIFICATION CODE: Hazard Hazard
Hazard Hazard
Hazard
Not Applicable XXX
I. PROTECTION AND PRECAUTIONS
VENTILATION Use local exhaust to capture vapor, mists or fumes, if necessary. Provide ventilation sufficient to prevent exceeding recommended exposure limit or buildup of explosive concentrations of vapor in air. No smoking, flame or other Ignition sources.
RESPIRATORY PROTECTION Use supplied-air respiratory protection in confined or enclosed spaces, if needed.
PROTECTIVE GLOVES Use chemical-resistant gloves, if needed, to avoid prolonged or repeated skin contact.
EYE PROTECTION Use splash goggles or face shield when eye contact may occur.
OTHER PROTECTIVE EQUIPMENT Use chemical-resistant apron or other impervious clothing, if needed, to avoid contaminating regular clothing, which could result in prolonged or repeated skin contact.
WORK PRACTICES / ENGINEERING CONTROLS Keep containers closed when not in use. oxidants.
Do not store near heat, sparks, flame or strong
In order to prevent fire or explosion hazards, use appropriate equipment.
Information on electrical equipment appropriate for use with this product may be found in the latest edition of the National Electrical Code (NFPA-70). This document Is available from the National Fire Protection Association, Batterymarch Park, Quincy, Massachusetts 02269.
PERSONAL HYGIENE
Minimize breathing vapor, mist or fumes. Avoid prolonged or repeated contact with skin. Remove contaminated clothing; launder or dry-clean before re-use. Remove contaminated shoes and thoroughly clean before re-use; discard if oil-soaked. Cleanse skin thoroughly after contact, before breaks and meals, and at end of work period. Product is readily removed from skin by waterless hand cleaners followed by washing thoroughly with soap and water.
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CONFIDENTIAL
DATE ISSUED:
06/01/89
SUPERSEDES DATE: 05/19/89
FLEXON 766
J. TRANSPORTATION AND OSHA RELATED LABEL INFORMATION
TRANSPORTATION INCIDENT INFORMATION For further information relative to spills resulting from tr 'sportatlon Incidents, refer to latest Department of Transportation Emergency Response Gu jebook for Hazardous Materials Incidents. DOT P 5800.3.
DOT IDENTIFICATION NUMBER Not appllcaole
OSHA REQUIRED LABEL INFORMATION In compliance with hazard and rIght-to-know requirements, the following OSHA Hazard Warnings should be found on a label, bill of lading or invoice accompanying this shipment.
(OSHA Hazard Warnings not applicable for this product; therefore, no OSHA warnings would appear on the label.)
Note: Product label will contain additional non-OSHA related Information.
The Information and recommendations contained herein are, to the best of Exxon's knowledge and belief, accurate and reliable as of the date Issued. Exxon does not warrant or guarantee their accuracy or reliability, and Exxon shall not be liable for any loss or damage arising out f the use thereof.
The information and recommendations are offered for the user's consideration and examination, and It Is the user's responsibl1Ity to satisfy Itself that they are suitable and complete f r Its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is Included on the container.
The Environmental Information included under Section H hereof as well as the Hazardous Materials Identification System (HMIS) and National Fire Protection Association (NFPA) ratings have been included by Exxon Company, U.S.A. In order to provide additional health and hazard classification Information. The ratings recomnended are based upon the criteria supplied by the developers of these rating systems, together with Exxon's interpretation of the available data.
FOR ADDITIONAL INFORMATION ON HEALTH EFFECTS CONTACT:
DIRECTOR OF INDUSTRIAL HYGIENE EXXON COMPANY, U.S.A. P. 0. BOX 2180 ROOM 3157 HOUSTON, TX 77252-2180 (713) 656-2443
FOR OTHER PRODUCT INFORMATION CONTACT;
MANAGER. MARKETING TECHNICAL SERVICES EXXON COMPANY, U.S.A. P. 0. BOX 2180 ROOM 2355 HOUSTON, TX 77252-2180 (713) 656-5949
945-C277IMW-0C2;
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DATE ISSUED:
06/01/89
SUPERSEDES DATE- 05/19/89