Document 6RvJg7BN11rpZBJGrYo6qmEv6
U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration
MATERIAL SAFETY DATA SHEET
Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking 129 CFR 1915, 191G, 1917)
SECTION 1
MANUFACTURER'S NAME
EMERGENCY TELEPHONE NO.
Uniroyal Chemical - Division of Uniroyal, Inc.
203/723-3000
AOORESS f.Vumbc'. Street, City, State, end ZIP Code]
Elm St. - Naunatuck Connecticut 06770
CHEMICAL NAMf AND SYNONYMS
Polvvinvl Chloride. PVC
CHEMICAL. FAMILY
Polymerized chlorinated
1
hydrocarbon
TRADE NAME AND SYNONYMS
MARVINOL 22
formula
(_H2CCHC1)n
SECTION II - HAZARDOUS INGREDIENTS
PAINTS, PRESERVATIVES, & SOLVENTS PIGMENTS
% TLV
(Unit*'
ALLOYS AND METALLIC COATINGS
BASE METAL
CATALYST VEHICLE SOLVENTS AOOITIVES
ALLOYS
METALLIC COATINGS FILLER METAL PLUS COATING OR CORE FLUX OTHERS
OTHERS
HAZARDOUS MIXTURES OF OTHER LIQUIDS. SOLIDS. OR GASES
TLV X (Uniul
TLV X * (Units)
NOTE:
May contain trace amounts of vinyl chloride monomer. *0SHA Regulation #1910.93q sets lppm TLV limit.
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BOILING POINT (flF.J VAPOR PRESSURE (mm Hg.) VAPOR DENSITY /AIR-1) SOLUBILITY IN WATER APPEARANCE AND ODOR
SECTION 111 - PHYSICAL DATA
NA NA NA
SPECIFIC GRAVITY (H201)
PERCENT. VOLATILE BY VOLUME (M
EVAPORATION RATE
( ..
*1)
insolubl e
s White powder with no significant odor
1.4 NA NA
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
Flash point (Memoo u;<a) EXTINGUISHING MEDIA
NA
.. ,
Water spray
FLAMMABLE LIMITS
Lei
SPECIAL FIRE FIGHTING PROCEDURES R,, espira.tory pro,tec.ti.on may be needed due
Uel
to
release of corrosive gases under fire conditions.
UNUSUAL FIRE ANO EXPLOSION HAZARDS
Corcsive gases may be liberated under inten se heat conditio
PACE (1)
(Continued on reverse side)
Form CSMA-20 r<, r ji iz
SECTION V - HEALTH HAZARD DATA MARVINQL 22
THRESHOLD LIMIT VALUE
OSHA STD. (#1910.93g) sets 5 ppm ceiling and
EFFECTS OP OVEREXPOSURE
1 ppm TLV for vinyl chloride monomer.
No adverse effects
known associated with handling or use of Marvinol 22.
EMERGENCY ANO FIRST AID PROCEDURES
URL 07762
STABILITY
UNSTABLE
SECTION VI - REACTIVITY DATA
CONDITIONS TO AVOID
STABLE incompAT ability (Materials to avoid)
____ X____ 1
HAZARDOUS DECOMPOSITION PRODUCTS
HAZARDOUS POLYMERIZATION
MAY OCCUR WILL NOT OCCUR
CONDITIONS TO AVOlO
X
SECTION VII - SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASEO OR 5PILLEO
Sweep up powder and discard,
WASTE DISPOSAL METHOD
Sanitary land fill.
SECTION VIII - SPECIAL PROTECTION INFORMATION
respiratory PROTECTION (Specify type)
Dust mask advised.
ventilation
LOCAL. EXHAUST
mechanical (General)
Monitor workplace for VCM in air.
SPECIAL
OTHER
protective gloves other protective equipment
EYE PROTECTION
Refer to #1910.93q.
Goggles
SECTION IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO GE TAKEN IN HANDLING ANO STORING
__ ____ ___ ____ ______ _Store ..in...w e11 - vRnl-.i lat.pd Area.
Any intensive mixing operations should be equipped with efficient
" PTc h err r e CA u tTg n s
.... ..
exKav t ' ve n til at ib n.
PAGE (2)
Form OSHA-20
Rbv. May 72
LU.. r
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Trade Name : Uses: Chemical Name:
DATE:___February 23, 1972
UNIROYAL CHEMICAL
Division of UNIROYAL, Inc. Elm Street Naugatuck, Connecticut 06770
203-72S-5241
PRODUCT SAFETY DATA SHEET
- -MARVINOL50
Blending resin
Polyvinyl Chloride
URL 07763
Chemical and Physical Properties
Appearance;
White powder
Melting Point: Solubility:
Will soften when heated Insoluble in water
Specific Gravity
1.4
Corrosivity: Volatility;
Not corrosive Not volatile
Fire and Explosion Hazard
Flash Point:
NA
Autoignition Temperature: NA
Special Decomposition/Reactivity Precautions: None
Fire Fighting Media and Procedures: Water spray
NOTES:
Corrosive gases May be liberated under burning conditions.
PRODUCT SAFETY DATA SKSDT (Cont. )
Health Related Data Specific Hazard:
None
Handling Precautions:
None
MARVINOL^O
2.
First Aid Procedures:
None
Toxicology Background:
Synthetic polymer generally recognized as being physiologically inert.
URL 07764
Storage and Waste Djspos'al
Storage:
Store in cool, dry place
Cleanup:
May be swept up.
` Disposal:
r
Sanitary landfill.
Data Supplied Sy: R. J DCMLING
DATE:
November 17, 1972
UNIROYAL CHEMICAL
Division of UNIROYAL, Inc. Elm Street Naugatuck, Connecticut 06770
203-729-5241
PRODUCT SAFETY DATA SHEET
Trade Name:
MARVINOL 56
Uses:
' Blending resin
Chemical Name:
Polyvinyl Chloride - Polyvinyl Acetate Resin
URL 0776
Chemical and Physical Properties
Appearance:
White powder
Melting Point:
Will soften when heated
Solubility:
{
Insoluble in water
Specific Gravity
1.38
Corrosivity: Volatility:
Not corrosive Not volatile
Fire and Explosion Hazard
Flash Point:
NA
Autoigni1 ion Temperature:
NA
Special Decoraposition/Reactivity Precautions:
None
Fire Fighting Media and Procedures:
Water spray
NOTES:
Corrosive gases may be lit* conditions.
ted under burning
on
PRODUCT SAFETY DATA SHEET (Cont.)
Hea1+h Related Data
Specific Hazard:
None
Handling Precautions:
None
MARVINOL 56
2.
First Aid Procedures:
None
Toxicology Background:
Synthetic polymer generally recognized as being physiologically inert.
(
URL 07766
St or age and Waste Disposal
Storage:
Store in cool, dry place.
Cleanup:
May be swept up.
Disposal
Sanitary landfill.
Data Supplied By:
R. J. DOWLIN3
U.S. DEPARTMENT OF LABOR
Fm Appro.'3
" omb no. 41'Wns;
Occupationo! Safety and Health Administration
b'' MATERIAL SAFETY DATA SHEET
Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking (29 CFR 1915, 191G. 1917)
V
SECTION I
MANUFACTURER'S NAME
emergency telephone no.
Uniroyal Chemical - Division of Uniroyal, Inc.
203/723-3000
ADDRESS /.Vumicr. Street, City. State. end ZIP CodiJ
Elm St. - Naucatuck. Connecticut 06770
CHEMICAL WAWf ANQ SVNONYMS
1
Tradename and synonvm^
Polvvinvl Chloride. PVC
MARVINOL 5051
CHEMICAL, f AMILY
FORMULA
,
CCV1C 1 )
Polymerized chlorinated hydrocarbon 1* ii2tti-ici)n
SECTION II - HAZARDOUS INGREDIENTS
PAINTS, PRESERVATIVES. & SOLVENTS
TLV 1 % .. . .
(U"i t^l .
ALLOYS AND METALLIC COATINGS
PIGMENTS
BASE METAL
CAT ALVST
ALLOYS
VEHICLE SOLVENTS ADOITIVES
METALLIC COATINGS
FILLER METAL PLUS COATING OR CORE FLUX
OTHERS
OTHERS
HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS. OR GAScS
TLV X (Units!
. TLV
% (Units!
NOTE:
May contain trace amounts of vinyl chloride monomer. '
URL 07767
BOILING POINT (F.) VAPOR PPFSSUP.E (mm Mg.] VAPCR DENSITY (013 = 1} SOLUBILITY IN WATER APPEARANCE AND ODOR
SECTION 111 - PHYSICALDATA
NA NA NA
SPECIFIC GRAVITY (H2OM)
PERCENT. VOLATILE
BY VOLUME (t/>)
EVAPORATION RATE U ------------------------- -t)
insolubl e
, White Dcwder with no significant odor
r --4
NA NA
SECTION IV - FIRE AND EXPLOSION'HAZARD DATA
FLASH POINT (.Me'.noa u'i"d)
NA
j F LAMM ABLE LIMITS
Lei
EXTINGUISHING MEDIA
Water spray
SPECIAL FIRE FIGHTING PROCEDURES Respiratory protection may be needed due
Uel
to
release of corrosive gases under fire conditions.
UNUSUAL r-IHL and EXPLOSION HAZARDS
Corrosive g ases may be liberated unc3er intense heat conditic
?AC 2 'I'
(Contnr:*?d on reverse side)
Form OSIIA-20
r, * y i:
SECTION V - HEALTH HAZARD DATA MARVINOL 5051
THRESHOLO limit VALUE
OSHA Emergency Temporary Std. (#1910.93q) set 50 ppm
'FFECTS C1P OVEREXPOSURE '
ceiling for vinyl chloride monomer.
No adverse effects known
associated with handling or use of Marvinol 22.
EMERGENCY ANO FJR5T AID PROCEDURES
SECTION Vi! - SPILL OR LEAK PROCEDURES
steps t~5~8 takFn in "case" NUvTeR 1 ALlfRELE ASE O OR SPILLED
33
---------------------------------------------------------------------------------------------------------------------------------- CO
Sweep up powder and discard^__________________________________-j co
WASTE OlSPOSAL. METHOD
Sanitary land fill.
SECTION VIII - SPECIAL PROTECTION INFORMATION
respiratory prote . !ON [Specify !}pe)
Dust mask advised
VENTILATION
LOCAL EXHAUST
X
SPECIAL
MECHANICAL (Gi'-.erai)
OTHER
PROTECTIVE GL.QV ES
eve puoiection
Goggles
OTHER PROTECTIVE EQUIPMENT
SECTION IX - SPECIAL PRECAUTIONS
PRECAUTIONS TO 8E TAKEN IN H A N O LING ANO STORING
_ . ,,
., ,
Store irr well-ventilated area.
Any intensive mixing operations should be equipped with efficient
otmTTTii'ec'autToVjs
"
''
exhaus t--VeTTti'XaTio nT "
PAGE (2)
CFO 9 \J 5*0
'
Form OCHA-2Q
R*'.Wjy U
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l"'TvOVALI
[=31
Trade .Name: Uses: Chemical Name:
BATE: February 23, 1972
UNIRCYAL CHEMICAL
Division of UNIROYAL, Inc.
E!m Street
Naugatuck, Connecticut CG770
203.72S-52X
PRODUCT SAFETY DATA SHEET.
MARVINOL^SQOO
Blending resin
Polyvinyl Chloride
URL 07769
Chemical and Physical Procerries
Appearance:
White powder
Melting.Point: Solubility:
Will soften when heated Insoluble in water
i
Specific Gravity:
1.4
Corrosivity: Volatility:
Not corrosive Not volatile
"
Fire and Explosion Hazard
Flash Point:
NA
Autoignition 'Temperature: IA
Special Deccmpositicn/'Reactivity Precautions: None
Fire Fighting Media and Procedures: Water spray
NOTES
Corrosive gases may be liberated under burning conditions. Product is self-extinguishing.
L
PRODUCT S.M'KTY DATA ['-~T f Cont
i
' Health Relared Oats .
r: pecific Hazard
None
MA.RVINOL.58QC>
Handling Precautions:
None
First Aid Procedures:
None
Toxicology Background
Synthetic polyner generally recognized as being physiologically inert.
W L 07770
Storaae and Waste Disrcsal
Storage:
Store in cool, dry place
Cleanup:
. May be swept up,
Disposal; ..
Sanitary landfill
Data Supplied Cy:
R. J DCWLING