Document 6Rpkmkz6eOnxbz2Ljdvqzyoad

AR 226. 677 FINAL MULTI-CITY STUDY FIELD REPORT FOR MOBILE ALABAMA AND PENSACOLA FLORIDA - BATTELLE DUXBURY ACTIVITIES . for . Project Number N100672-01" Submitted to September 29, 1999 Prepared by Christopher Gagnon Battelle 397 Washington Street Duxbury, MA 02332 (781) 934-0571 001001 | i TeCo t i fa 1 oe TABLE OF CONTENTS LL SUVEY SPECfc ADPIOVAL.c.ccvvonorosmoseoeooesese1 Ae RESUS cocoons 1 5: 352 IOBOSSHUEUMOBESNCAIVORNIIROENSSUo S occ .o ceo o Deviations and COIECVE BEONS...ccvmssses soreness 1110 13 1 LIST OF TABLES 1 oo mime mea LT 1 TTAABBLLEE21.. TABLE 3, CMUNHICRIPOALNITIOOESLFSEOAVMEGPNLTYESDOANNJDUANPEP2R3O,V1AL9SG9R9AN.TE.D.DURING CHROONFEVOENTLSOONJUGNEY24, 1999... SURVEY... | 1 TTTAAABBBLLLEE6SE4...CC CHHHRRROOOOOONNFFFEEN EVVOVOEEENNNOLTTTLSSSOOOLOONNNJJJOGUUUGNNNEEEYYG2295,,Y1199999.28,91.99...._.__.__LLLLc7 omm 3 33 TTAABBLLEES..CCOLLHECTREDOSAOMNFPELVEOESNFTLRSOOMONMJOUGBINLEY3E0, 1999A..L...........coosoroero ee || `TTTAAABBBLLLEEE 1L12L0... SSGAAPMMSPPPLLOIISNNIGGTISSOIINTTEEVPEPOROSISIFITITICIOOANNTSSIIOINNNPRMEEOSNBUSILALTCESOLcAreALe..r.FL..c...e..o.cocrvorors ee 13 12 1 | Final Field Rpt MobileALPensacola FL Y3TBPaetglTeeticehwyk ~01002 arfirs 1. INTRODUCTION `The objective of the sampling task in this study is to collect representative samples for trace- level analysis of FC residuals, to assess sources, dispersion in the environment, and human `exposure via the food chain. The cities selected for sample collection will be considered `study' or "control" cities. `Study' cities are considered those areas with FC production facilities or large . FC-consumers. `Control' cities do not contain FC productionorconsumption facilities and are `matchteod study cities based on general location, population size, and drinking water source. During the initial phase of the study phone calls were made to municipal agencies requesting. access to various matrices of interest. Based upon the level of cooperation received from the `municipal agencies, appropriate sampling strategies were developed. The Quality Assurance | Project Plan (QAPP) and the Survey Plan contain the appropriate information concerning the `matrices for collection and methods to be utilized for this process. | `The full project sampling scope is accomplished using two field teams: 1) Battelle's Duxbury Personnel collect drinking water, POTW, landfill and urban air samples, and 2) Battelle's Marine ' Sciences Laboratory (MSL) personnel collect surface water microlayer, bulk water and finfish i samples. This report summarizes the Duxbury team effort. A separate report summarizes the MSL activities. | 1.1 Survey Specific Approval | Organizations in Mobile Alabama responded favorably to sampling requests at the Publicly Owned Treatment Works (POTW), the municipal drinking water plant, and the Mobile Fire Department (for atmospheric sampling) and granted permission to sample at these sites. | Permission was not granted for sampling at the municipal landfill. Responsible parties in Pensacola Florida also responded favorably and granted permission for sampling at the POTW, the municipal drinking water plant, and the Pensacola Fire Department (for atmospheric ( sampling). Permission to sample was denied at the Pensacola municipal landfill. Table 1 highlights the cities visited during this survey and the approvals granted by municipal departments. | `Table 1. Municipalities Sampled and Approvals Granted During Survey | SChoundysotr|| Fi(rheiSDaemppalritnmgen)t WaDtreirnkPianngt|| iLumaenpaal (PenssconfL |Swdy|v |v7 | Nx | { N[AM=NoobAppirol valeReAreL| ved Swdy| Vv | v | 7 | NA | | Final Field Rpt Mobile AL Pensacola FL. ow BBatAlCeHllEewe 00100. tFuogdes 2. METHODS `PTrhoececodlulreecsti(oSnOPo'fse)n.viTrhoenmSeOntPa'lssuasmepdlienstwhaesMuclotnid-uCcitteydSatcucdoyrwdeirnge tworiStttaenndabrydBOapteterlalteiaonnd are ufiseelddt. oTthreasien pdeorcsuomneanltpsr,ioarlotnogfiweiltdhactthieviQtAiePsPa,ndsearlvseoassertvhee agsuairdeafnecreednocceudmoecnutmsfeonrtsthweh.ile in the collection of field samples. The methods used for collection are summarized below. TushiengcoallGeacrtimoinnof12poXsLitGioPnSdautnait(laactciotruddeinagndtolBoantgtietluldee)SOwaPs3c-o1m6p4-l0e1t.edIantsetarcuhmesnatmapclciunrgaclyocwataison voaflaiidrastaedmpblyescowmapsarcionmgplaenteacdquusiirnegd apoGseinteiornalveMrestuaslsapMoosidteilonPSo-f1knatomwonsplhoecratiicons.amTplheer.colTlheection aslalmopwlsintghewsaespacroantdeuccotleldecatciocnoorfdipnagrttiocBualtatteellaendSOvaPpoMr3-pMaCs-eF-c1o.m1p.ouTnhdesuusseinogfathgilsassyssftiebmer filter dforrinpkairntigcwulaatteermsautptpelrieasn,dPOaTpWol'ysu,reatnhdanleanfdofialmlsPweUrefocroltlheectveadpoarccpohradsien.g WtoatSeOrPsMa3m-pFl-e2s.0f.rom dSruirnfkaicnegwwaatteerr,sasmupplpelisewdebryetchoellmeucntiecdivpiaaldpilraenctt,swuebrmeercsoliloenctoefdtvhieasaamvapllveebsotytsltee.m.TaEpffwlauteenrt awnads BcaotltleelclteedSuOsPinMg3e-iFt-h7e.r0a.buScekdeitmoerntsmsaalmlpslaemspwleirnegcboelalkeecr.tedSuesdiinmgeantstsaainmlpelsessstweeerlespcoololnecitned using MMoobbiillee,wsacse Scoelclteicotned6ufsoirnagnaexvpallavneastyisotneomf,tihnePceonlslaecctoiloaniptrwoacsedcuorlleeicntePdenussaicnoglaa.stSailnuldegssesitneel | spoon supplied by the POTW. | 3. CHRONOLOGY Tables 2-7 highlight the events that occurred each day of the survey. Sample matrix collection | i tthiemeesvehnatvsetbhaetentrtarnasnpsicrreiddbeudrifnrgotmhtehesusravmepyl.e log; all other times All times have been have been recorded estimated in Easter based on Standard Time. `Table 2. Chronology of Events on June 23,1999 | [AmvemMobll. | 1 30-1500 |All material present andaccouned for. Department. Discuss location of Atmospheric sampler. we age on Saton LL. 1 Discover US Cost Guard Staton Mobile located slong river. Entered base and proceeded o- ( verify the GPS system. [Rewmiohowel. i Final Field Rpt Mobile AL Pensacola FL 01004 JBarelle opm i `Table 3. Chronologyof Events on June 24, 1999 | [1000 | Site2 tap watersamples collectedatStation LIfollowing the completion of si sampling. | [1030 |_ Amve_ atUS_ CGs_ wtio_ nand_ veri_ fyGP_ S. _________| | p am a eo s| | [TI15_ |Mr.Freeman collectedsludgeusingavalvesystemfromtheonsitetruckloading depot. _____| + [1260-1250 |Collectsurfacewater andsedimentsampleatSite3. _--_____________ | | [1300 | CollectQuietSurfacewatersampleatintersectionofTelegraph Rdand3MileCreck. | 1 Following abriefconversation we are allowed 0 intste sampling aEEE 1 [1830 CollectahemativeleachatesamplefromHallsMilCreek | 1 `Table 4. Chronologyof Events on June 25,1999 1 [TO45-TTIS |AniveatFederalExpressoffice,ship samplesandequipment, | [120 |DepanMobileforBoson. 1 (180 [AmveinBoson | `Table 5. Chronology of Events on June 28,1999 || [0755 | DepanBostonforPensseont_______________________| 11 B ay E| 1 'A r patn e i _-- mpKaeegtesd 1 i i Table 6. Chronology of Events on June 29, 1999 1 07300800 | "usntRtoiipnpvge.daattPAafFtDeprSpaiadritsoocnu'sxsii0io7nc0mow0ilaftehottlooaniewroislfnamgtyphlaeernm.eeanrUbpoyonlndiugrthiytviiantlgweakstedhisScthoiavtoercneaduhsteheasttah(mehpeleselaremcwpaltsearlmocrircuit 1 [ topCo.mplete aif sample collector, cleanth ur and alec he Blank ard Blank Spike samples. | [0830 CollecSte ap watersamplefromPFDStation.____--~ Private cizens owned al propery surounding the act body. : 1 0915.0050 t"AhceacllomwearsopflaMciecdhitogaBnerAnvaernduDeahanldofMtohbeiElscHaimgbhiuaaCounty URlioes Aunty (ECURTS 1 4FFo0ol1lllWoow.wiinGgnogvabedriinscmceusntsotiuorStn.awditph VliaPiornerofwehweesrobnr'ousghotpoerhoen.WhSeLr7 Anvegry SwThpumapkinsg ssnidon ated water samples were collected, NFiiiiabidmaal ! "scTelhnueidrgeiefffuslgaueemdnptlsesisnagmwepelretesocwhoeleleeicncicaeindleluresacittonergbaysspuobomnerrgoimngththecobnvoeysernboelthheatfturaensrposrttrsehame. pTohte 1 [3 TColletStesmpvater, | i [[114181000 1530-7630 |CCDoiosllclloeevtteSSriPieetr32dssiuurdrfofaaLccaeenwwdaafttileelrr(anCnoddusnseetddyiiLmmeeannnttsdtirtohlmoecaetniedgdhoatftoHf1y3wd0a0ey9PoaBnruckhlReaohcaaRsddt.siBdoeocfaTesxa3roBwaynou | 1 linotceartseedcntionrgtthhneorrotahdw.esCtoolflPcentsaalctoelrana.tivFeollelsogwhaBtueelsaamhpRlde.spfartomlatnhdifsilclreacnk.d fTouhndstsemawllscorfefekthe 1 forth evening `Table 7. Chronology of Events on June 30, 1999 || OTT 1 equipment shipped to Batlle Duxbury Operations. i 4. RESULTS "This survey, as part of the Muli-City Study, resulted in the collectionofthe majority ofthe || samples samples described in Tables collected during the 3-5 of the QAPP. Tables 8 and 9 survey. As a result of the quality contain a description of all assurance audit conducted the during the initial survey several minor changes were required to the `QAPP. These amendments to the 1 document are ofthe sample located in collection Amendment 1 to Revision effort that occurred during 1. The following this survey. sections describe the results 1 FinalFieldRpt MobileALPensacola TT opmeeeo 0100 $Batell|e 1 _-- B=ee Senin | 1 `Table 8. Collected Samples from Mobile AL 1 `Volume Collected (L) Location Collected |DriWnatekrUniproncesg sed MCAT TunerGulla Pum See] ET -- RE 1------ cr | Ee LL Tir |PalmerGuillrdPumpingStation] 1 Pom Va Poel Pong ae Proceed R || hWeeaatmsb|| 1 i TitEwoemeaems e in | oWrPosed 1 [ming WeProesed Fos Wate P || Miecaine[ | 1 Ti k re we ee e rppon --| ed PomewarProceed [Ri Vat Poel | ease| |MealK | iit Meme 1k Me rreme pa --| { [ming MaerProesed Fos Wate Proceed | | eam Mean [ | TiTt ite Men mepa ER -- Fons We Pressed |L CanT a |--T -- ie11eterrT eeL 1 [Drinking WaterProcessed][ |MCCaaBn| Fors Wat reed TT THEEMMeeeyeyrsberFsir lFrbarate iioonna FFaacr ilcil]| [pate Pucesed | Meni |wea |The | Tit eenpee | ne rae] [Top Water Suet I 7 -- | Fyn Peymersietl esa meas Thee |e Frymaster Boymesien yeas Foster PSs Per EL-- (TopWeFeld eo veo [humane | upmen-------- com Tweom Tm Heme wMeeaan [ie fe ee a [ 1 h E-- e ---- n 7n -- a Final Fd Rpt bileAL PorsacoFLt. Ear eee wBBaattlieellilee 001007 1 i er`Table 8Continued oe [my] 1 E CRe I -- -- -- FaecdmeSienl e cTeiT o -- -- -- --[TeTT)eTT.eS------ wea T : { F PRee idese aenSehtenll [oemSesl wweedaik[ T Th e el o ee m pe e weak[1a | E PFfos -- tasce teeer--wMwaaaerr--ssie--w --ei [wim ece aoe ln|[----1--a ----Thioeenlie emt ea------------| [ FeverSsieemn wweedasrT T T e Taim cpa--------e --------|| E :} PRoaeeT chumenrsSieenn-- a[weds| [weanI ToToeinceha 1 ---- TT-- E E T E E ET -- -- -- 1I-- E--O --S --17 TT-- -- -- [FE aosoWaarFBeeldldbet-- [|vwecaaomopt|[ vE -- ioe epT p nT e--e -- ----e --| E Eer r r -- -- -- TTa-- EE ---- -- -- TTTYTT-- -- -- -- TT 1 E EFeor ta ellB-- al-- ---- [ofmenelibes TeTT [wcane | -- -- TTT T-- -- -- -- ---- hope-------- E [FportE oe FteeliiBtlook -- Frome [[|wwMeeeaaalk[ | Hec p re p 5----TT -- E HomvE imen -- EE -- [[wM7 eeawn|ES 5 EE 1--TTCcCeAv1Wiitmmwpin------ --1 HHEFoooovvreeennn -- w7 ceaakt|ET E -- Tcc 2c7 mc1m -- --] EE-- 7 camiTc -- lowTiamm-- ----| --| E r HFornT ovnemEslseenFedm bik e[|wa Meesaonn [ | oTc7 Ccm cCwWiamgmee-- e Mew ac wiec nr [En [ucus ET A -- Final Field Rpt MoAb LPei nsaclolaeFL Ba , 001008 = [=[elEem me [DoanAir (Paricalate) | MCB| 1Filer |MFDSwiionll ' [UrbanAir(Vapor) FieldSplke |MC448B| TPUF____[MFDSwionll [Urban Air(Particulate) Field Spike |MC4498 | IFiker |MPDSwionll [OrbanAir(Vapor) FieldBlank |MC450B| TPUF |MFDSwionll | [Urban Air (Pariculate) Field Blank |MC4SIB_| IFiker |MPDSwionll ! [Alternate LandfillLeachate |MC435B [1|HallsMilCreek [Alternate LandfillLeachate |MC35K [1THalsMilCreek [[AlterateLandil LeachateField Blank |MC436B | |HalsMillCresk [Altemate LandfillLeachate Field Blank |MC436K | | Halls MillCreck [AterateLandfillLeacheFieldBlank |MC436H | [HalsMillCresk [Quiet Surface Water mca | T [SMileCreek ! [Quiet Surface Water | MCABK| 1 [sMileCreek [QuietSurfaceWater MC4ssH| 1 [SMileCreek [Mobile TrpBlank "MCAS| 1 TBaelleDubuy | [MobileTripBlank | mC4seB| 1 [BaleDubay | 1] | | 1 . | | | | | | | | | BBaatteelllei.e. i F-- E Kets i po I Table 9. Collected Samples from Pensacola FL SameTD | Vatu Collected (4) Location Calcd [[DDrriinkkiinngg WWaatteerrUUnnpprroocceessseedd |MMCC331290B||1 1 |WWaannddAAvveerryySStt..PPuummppSSttaaiioonn || . i [DikingWaterUnprocesed |MC316K| 1 |WandAverySt.PumpStaion | [Drinking WierUnprocessed |MC315H|1 WandAvery.PumpStaion | 1 [DikingWie Unprocesed |MC318H|1 WandAvery.PumpStaion | [[DDrriinnkkiinngg VWiatteePUrnopcerscseesded |MMCC332201HB||1 1 WWaannddAvveerryyS.uPPuummppSStiasiioonn || [[DDrriinnkkiinnggWWoatte PPrroocceesssseedd |MMCCB|| 1 |WWaanndd vveerryyS..PPuummppSStuaaiioonn || 1 [[DDriinnikinnggWWaatteerPPrroocceesssseedd ||MMCC333245B8||1||WWaannddAAvveeryrSyt.PPuummppSStaaiioonn || [[DDriinnikinnggWWaattee PPrroocceessseedd ||MMCC33221KK|1 1 WWaannddAvveerryySt..PPuummppSStiaioonn || | [[DDriinnkiinnggWWatteePPrroocceesssseedd ||MMCC3S2B4KKT | 1T _[|WWaanndd vveeriy..PPuummppSSttaaiioonn || [IDrDiinkkiinnggVWoatteerPPrroocceessseedd ||MMCC3I3I5HK| |1 ||WWaannddAAvveerrySyt..PPuummppSStaoionn || 1 [[DDriinkkiinnggVWiattee PPrroocceessseedd |MMCCIW| | 1|WWaannddAvveeryySt..PPuummppSSuavtoonn __| [Drir nkingWar te Processe--d |M5 3250|E 1 WandY AverySt.-- PumpSion | 1 ErrTry-- ---- --LEi ---- -- YYTT---- [TapWmerSrueyst ---- [ME eson| 1 [Y Remain -- | 1 [TeoWaerSi|em1------R--e[mMa en a] K t r rr r-- -- -- US TSE ---- T TY-- -- [T[ s apWTaeroSiept Vaere Sie[ |ss t-- 11 ----s [TRRaaMmmaaenn so sok|| E rT r-- -- -- 7TY-- -- 1 [TF s ap Watet rSie --------[ T T1 M -- e R2amaa dan -- 0H| 1 EErr -- -- TS EYYS---- EeEr -- -- E SEE---- 7 YT-- -- 1 [ETaroWaeFed-- o [Mess |----[Raman -- | C[lTaappWWaaterrFFeellddBBllaannkk | MMCo3sBhK| [R| am Rama andan|| 1 Final Field Rpt MoAbL PeinsalcolaeFL 3Baticle 00101 i _-- F[iges 1 `Table 9 Continued [DoW Fedak [Moms [ `"VSoelduimemeCnotllMeaca tsesd (L) m `Location Coll] ected. e [SE utar ceWaterStebl | MComp[ ET E 1 --T TToT Twb----ar] 1 [[SSutafaacseWWaeteerrSSheiilf [Sutfce Wier Stel || MMCC3a0omB|| |MCa0sm | 11 1 [TTeewwBrabyowr Terbaes 1 [[SSuurttaaceeeWWaatresrSitebfll [SaasWarSieFT || MMMCeOSsOOoIKK|[ [1 1 T [[|TTeTwBooaowrwbbaarr]] : E 7 r ---- CT -- ---- -- CTT T -- -- 1 Ee e e 1E T T P-- -- TTTT-- ---- -- I 1 EIET -- -- 5-- -- --rCTTT---- TT-- 1 [[SStuaccceWWaaterrSSiieeds [SutaceWaterSie5 | MMCeoOoGH|| |MCOTK| 1TI[TeTwBaoyowr bar] 1 [Teurbuor 1 E EE7 TT r T -- E -- ---- TTTT-- -- -- E ET e Ee -- 5I -- -- -- TE-- | 7TTTS---- TT -- [[SSeedliimmeenntSSuteebtt [Setimen Sir I| MMCeOaIsK|| ag000r TMcoup[mor Te|TwewwrbByayoosr [Tewbaor 1 E [[SST eedfiE immeenntSShteers _ I MMcCoOmUpK[|go20r0 T [|TTeewwrBBnayoorr -- 1 [[SSE eedfiimmeennttFFeellddBBaRnEk ||MMCCSOBBKB|-- | T |[TTeewwLrBTbuaoor-- r E i [BE OS TW fluen ---- | MecT|-- L -- T-- [EcUrATMusTYP----l] 1 [E RE OWE MCa@B|S T --1-- ECuAMTTaTYYnP ---- [[PPOOTTWWEEfMfwunen-- [FOTWEien ITMMMeeCsssomkK|[ | TT1||EBECCCUUAAUM MAanMPalanpPla----]] 1 [[PPOOTT EElifeuennFldBlak [POTWemem |MMMoCC3s36GKK||[T 1J||EBBCCCUUUAAAMMMuaaannPPlPalan] 1 [[[PB-- BOOOTTTWWEEeffmlluuuee-- ennn ---- [|MMeesiaov | |1 e 1|a |EEeCcCUuUAAAMMMme auanmP P PEnl ln a u] ] [[[BPO-- OOTTTWYSESihtdudeg-- gene -- Feli-- s-- -- M |MC[ 36H[||C " mo30r0M o + || BBEC CCCUUu UAAAMMMaa3 nnaPPnnmPp lnK ------] 1 [[FPOOTWWSSttuddggeeFietldBBllanakk ||MMeCs3a#s5sK|e| CUA| MsnBCPU MlanaPnl----o--]] 1 FinTal FiTeldTRpt MobEileeAL PeenseacoelarFL eese ----------001011 SBBaattteeltlel|e 1 1 "Table 9 Continued i [[iOtbawnmAAerPaprotincle) Pfeas en [Mca |"SediimepntoMas (g |eoswmm | |MC3e7B| Filer PDSuionsr | i [[UOrbbanAAiirrP(VaanpiocrlFiee)lFdieBlladnSkpike ||MMCC33540988|| IFPiUleRr ||PPreDDSSuuiioonnttrs || [[[[AAlllemrsmttecCLaannddiiLLeeaacchhwaee ||MMCC3I33%SBK|[11 ||NNoorhroofPPeetriidooLLaannadii || . 1 [[[AAllirtosec CCaannddiiLLeeaacchhaaeeFedBank ||MMCC3333s6H8|| 1 || NNoorrhhooffPPeertiooLLaanndaiil || 1 [[[AAllresvtecCCaannddiiLLeeaacchhaeFFiieellddBBlaannkk ||MMCC333366KH| | || NNoorrthhooffPPeerdtddooLLaanndatil || [QueSucewssTM |MCawsB| 1 |MichiganAve MobileHighway | 1 [[PQeuniseatcSoulrafaTcreiWpaBltaenrk" ||MMCC338easH|B|1 1 [|BMaimcehilglaneADvueb/uMyobilHighvay | | (Pe`nSsasmcpolleaTsoaprepannot part of this study| mash|1 |Batlle Dubay | 5.1 Sample Matrix Availability 1 Per client instructions no food items were collected during survey. Due to scheduling and permit 1 iatsscuietshenroMfoibnifilseh owrerPeencsoalcloecltadduureintgo thheiasltshurcvoenyc.erTnhs.e cBooltlhecPtiOonToWf PinOflTueWntisnftlrueeanmtsdaivdainloatbloeccfuorr sampling contained biological hazards. The staff at facilities in both cities indicated that the chlorination process occurs following secondary treatment. 1 `The collection of landfill leachate did not occur at either Mobile or Pensacola because permission was not granted in either city. In each city an altemative sample was taken from a 1 stream or creek located close to the landfill. Also collected, but not included in the QAPP, was a sample of quiet/undisturbed surface water. 1 ``TThhiesssaammpplliengislioncatteinodnesdifnorboutshe ciintiaeslownegr-etearlmtetrreadnfsproormt tshteudoyritghiantalissictuerrdeunetltyobaeilancgkcoofndaucccetsesd.. In Mobile the area surrounding the suggested inlet was industrialized with no pointsofaccess. A 1 bbaercgaeusceonosftoruucrtiinoanbicloitmyptaondyiswcalsosaeptphreonaacthuerde foofr opuerrmsiatmtpilnignga.cceIsnsPbeuntsatcheolmaapnraigveatredreensiieddenucs.es 1 surrounded the initial sampling location. 1 522 Onsite Observations Mthoebirilvee,r,AtLh:eyTdhiescPhaOrTgeW~i5s0l0o-c1a,t0e0d0afdejeatceonftfsthooraecoinatlodtehpeotchiannnaehligofhtlhyeinMdousbtirliealRiizveedra.reAatalong 1 spluarnftacseawmaptleerdswitaess tthweosamnadlltehrroefe,tsweoveprlaalnptesompalientwaeirneedfibsyhitnhgeacnidtyc.raDbubriinng.g pTehaek dprriondkuicntgiownater 1 both plants can produce approximately 50 MGD. The reservoir that is used as the drinking water 1 Final Field Rpt Mobile AL Pensacola FL PBrateeytoe rk0001101; {. p-agent I scoolulrecceteids aatsaprcirnegefkeld,ocmaatendmdaowdnesllaokpeecofnrsotmruScctheidllienngtehre R1d95.0l'asn.dfiAlllt.emAatsimvaelllebaacshsatweassitoebwsearsved 1 inthe creek when we arrived. 1 Pbeenisnagchoelaav,ilFyLc:onAtnamaritniactleedinwittheh lhoecaavlypampeetralosnftrhoemdtawyowiendaursrtirviaeld sdietsecsrainbdedhTieghxalrevBealsyoouf faescal ccoolnitfaomrimn.aAttedthweitdhrvionlkaitniglewoartgearnpicumcopmsptoautinodnsi.t wTahsosdeiswceolvlesreadrethfaittisedowmieothftchhaerccoiatly'fsilwteelrlsstoare . 1 remove the compounds. The well sampled was not filtered. The POTW sludge is incinerated onsite at the Goverment St. facility. t 53 Instrumentation Results 1 A`AicrcsoarmdpinlgestowSerOePcMol3l-eMcCte-dFdLu.rLi,ngthteheaisrusravmeypluesrincaglaibGreantieornalisMaectcaelpstaMboldeeilf iPtSis-1wiatihrisnam1p0l%ero.f 1 the expected results. Duxbury prior to the To deter initiation mine the of the st acce udy. ptable results a calibration was conducted The initial calibration curve resulted in a in R? value of 00..999978.reTshpeecctailvieblrya.tiTohnecuprevrecsengtendiefrfaetreedncine Minobrielceoradnedd vPaelnuseascoflraohmatdheR?inivtailaluecsaolifbr0a.t9i9o6n raanndged 1 from 0.0% to --5.6% for Mobile and ~3.9% 10 5.1% for Pensacola. 1 SaictceurloaccaytioofntsheinGMPoSbiulnei,tAwlaasbvaemraifwieedrepdertteoridmeipnoaerdtuirsnigngDuaxhbaunrdyheblydcGoamrpmairnin1g2aXbLeGnPcSh.maTrhkeon 1 Bbaetntcelhlmeaprrkopleorctatyivoenrasnusd tthhee lGoPcaStimoenadseutreermmeinntedwbays t3h0emientsetrrsu.meFnto.ll"oTwhiendgisffheirpemnecnetbteotwAeleanbathmea t2h3e%.inTsthreumreesnutltwsaosfrteihneitviearliifziecd.atiTonhsisfowraesacchonsdaumcptleidngatdtahye iCnoaMsotbiGluearardeSptraetsieonntMeodbiinlTeaobnleJu1n2e.: 1 "JTuhneer2es4ulbteotfwetehen vpeorsiiftiicoantsi.onTfhoer Minosbtirluemeinstawdaifsfelorsetncdeuroifn2g0shmieptemresntofnrJoumneMo2b3ilaendto0Pmeentsearcsoloan, Florida and was not used during the Pensacola survey. 1 Afecect.orTdhiengstaompthleinQgAlPoPca,titohnesmfionriMombuimlediasrteanpcreebseenttweedeinnsTeadbilmeen1t0swaimtphltihnegfsoiltelsowpionsgitrieosnusltiss 500 1 cdailsctualnacteefdruosminSgitthee2GtaorSmitien3GiPsS3.69T.h6eandidstthaencedifsrtoanmcMeofbriolmeSSiittee1I1t0oSSiittee32isis11,,523617..22""., Tthhee 1 dcailsctualnacteiboneotfwaeenliSnietacr 2diasntadncSieteus3inigs ltehsesGtPhaSn rtehseulrtesquiinraeddis5t0a0ncfeeetofbulteswsiltlhabne5a0c0cefpeteetd.altThhoeugh imtisnhoiumludmbdeisntoatnecde.forThtheesraemcpolredsthwaetrtehecoalclteucatleddiosntabnoctehasliodnegsotfheashloocraeliwzaesd wpeelnlinbseuyloancdretahtiesd by 1 the bridge abutment. Table 11 provides the sampling locations for Pensacola FL. Although the GPS was lost an 1 astetdeimmpetntwacsolmleacdtieontosiptreosvaitdTeeaxnaracBcauryaotue wsterreeetlaodcdarteesdsaotralmoicantiiomnumforofea5c0h0-s1a,m0p0l0infegetsiatpe.artT.he ` FE 1 Final Field Rpt Mobile AL Pensacola FL , 1RBoattTeotbiieTo o|rk 001' 1. ertos 1 Table 10. Sampling Site Positions in Mobile AL TPaLlEmeMrieGyeurlslaWradtPeurmFplirnagtiSointiFoeinlty ||NN330063432103.3"0||" WW88881185'313499"" || 1n4d75ofHPurbiervtaPteRrec.eRA 1 MED Staion 11 NN 3O04S0E17.9TM 39113050664SSAo.lurtpBhorrBoealdBtlSuitn.de Highway ' Bridgeast side BridgeWes side 1 `Mobile River Site #3, west side [Fem `W8802'40.0" | BUnrdiedrgeAWfersitcastiodwen-Cochrane Gui Wer 3 Mile Geek NZIC [WHOTILT 1 [AltLeeachraten/HaallstMiill Cvreeek |N3037042|"8W813287|SchillengerR|d 1 Table 11. Sampling Site Positions in Pensacola FL 1 [[ARvaermyaSdi.aPunmpingSadon [PFD Smon# [|NNoottTTaakkeenn ||NNooitTTaakkeenn | NotTaken |NoiTsken |76C0o1SmcoefenAivcerHryighsunadyWSC | | 432.DavisHighvay | 1 BoatRampa Cervantes S 1 [Tota Bayon, Surface Weer 15 |TNotaken|NorTake[npPfidnataeirnsreccitiioonnid------] `erative LeachTTaetre Goch | Not Taken MQoebiWlaeeriMgh,ichie Ave and | NorTaken NotTaken NorTaien oBfucPlearhdiRddo.LBuaenladhFL. nor TAnvtee,recntdionVofiMoibcilheigaHignhway `Table 12. GPS Position Verification Results 1 Galbraton Loans R0MS 0ob5i"cWALBD 607233959 7 |NITHW0009S 1 N 303900.3" / W 88%03'35.3" N 3039'01.0"/ W 8803'35.2" a Final Field Rpt Mobile AL Pensacola FL. #Oe Batieltleseuk 0010: i. tn rnsage i 5. DEVIATIONS AND CORRECTIVE ACTIONS 1 The following QAPP deviations were noted/experienced during the collection of samples from Mobile AL andPensacolaFL: 1 The collectionofeffluent samples in Pensacola required the use ofa plastic jug that the POTW had on site. This jug was rinsed with the effluent prior to collection but no 1 verification ofits pre-coliection condition could be ascertained. To avoid the futureuseof local sampling equipment while collecting samples from the flumes of the POTW's a telescoping pole will be purchased that will allow for the direct placement of the sampling 1 containers into the sample stream. 1 DPuenesatcootlhae wleosrseocfotnhdeucctoeoldebrycodnitraecitnliynsgutbhmeesragmipnlgintghesuspapmlpilese,ctohnetacionlelrecitnitoon tohfe sseeddiimmeennttsainnd collecting the sample. "Cake" sludge was collected usinag stainless steel spoon provided by Escambia County Utilities Authority (ECUA) personnel. This spoon is what UCUA 1 p`meertshoannnoell pursieordutoriunsge.their regular sludge sample collection. The spoon was not cleaned with 1 TAlosoadvuoeidttohisthseitluoastsioonf tinhetsheamfpultuirnegtehqeuuinpimtewnitl,lnboe GcaPrSrierdeapdeirnsgosnawlelryebtyakaemneimnbPeernsoafcotlhae. 1 field team to the city being sampled. . Perclient instructions no food items were collected during survey. 1 The collectionofPOTW influent did not occur a ther Mobileor Pensacola due to health concems. Both POTW influent streams available for sampling contained biological hazards. B+ Th collcuonofandl leachite did ot court ither Mobil or Pensacola because erision was not granted ineithercity. In each city an ltemative sample was taken froma stream or creek located 1 close tothe landfill `The QA Project Plan Section 7.3.5. states that "whole (bulk) water will be collected from three: sites within a surface water source of drinking water, and at the water treatment plant influent 1 and outflow... If the drinking water source is groundwater then the surface water samples will becollected from any selected lake, pond, or river..." In Mobile, erroneous information led the. field crew to collect from surface waters not used for drinking water. In Pensacola, drinking 1 `water is pumped from groundwater and so the surface water collected does not relate to drinking water supplies. Sampling specifics follow: 1 In Mobile surface water and sediments were collected from the Mobile River. When samples were collected at the drinking water treatment plant it was discovered that the source was not winerfaectnotthecoMlolbeictleedRfirvoemrtbhuetBriatghCerretheeksRpersienrgv-ofierd., mAasn-anmaadded,edBingotCer,etehke RMeosbeirlveoiRri.veSramples samples were later identified to be brackish (slightly saline) indicating that they were a Final FieldRptMobileALPensacolFLa Batiefle 00101 #Batelle | 1. coiatons coripcotiron] 1 scoalmlpelcitnedg itnasak rleegaidoenr of the river/estuary was notified of this system issue. that i tidally (seawater) influenced. The 1 + PPeennssaaccoollaa'ssudrefapceendweatnecre aonndgsreoduinmdenwtatsearmpfolresdrwienkriencgowlalteecrt,edthferoBmaytoheuTweaxsarchBoasyeonu.asDtuhee to 1 bsuyr/fmaicxeewdatweirthasnedawsaetdeirm)e.nt sampling site. This was also brackish water (influenced ! 1 `fWiehlidlecrneowtss'puecnidfeiresdtainndtihnegQtAhaPtPt,isqusiaetm/pulnediisstiunrtbeenddseudrffoarceuwsatienrawlaosnga:ltseorcmoltlreacntsepdo.rtIsttsudtyh.e "ITnhMeosbaimlpel,itnhgelaorceaatisounrsrionunbdoitnhgctihtieessuwgegreestaeldteirneldetfrwoams tihneduosrtirgiianlailzesditweidtuhentoopaoilnatcsk ooffaacccceessss.. 1 bAecbaaursgee ocofnosutrruicntaibiolnitcyotmopdainsyclwoasestahpepnraotaucrheeodffoourrpesarmmpiltitnign.g IacncePsesnsbaucotlhae,mparnivaagteerredseindieendceuss 1 surrounded the initial sampling location. 2 Final Feld Rpt MoAbLPeinsaclolaeFL ypatete001016 i Field Report Addendum - Mobile, Alabama and Pensacola, Florida Surveys 1 AtrmesopsepcthetorsiacmSpalmeprlpionsgitDieotnaiinlgs.. The followingdetailsareincludedheretocompletethefieldrecordwith 1 (Msotbaitlioen,#A1L1:) Tlohceataeird satam1p0l0e4r Sa.t BthriosasditeStw.as positioned approximately 30 feet from the 2-story fire station 1 Pesntsataicoonl(as,taFtLio:nT#h2e) laoicrastaemdpalte4ri43n2PeNn.saDcaovlias Hwiagshpwosaiyt.ionedapproximately4-5 feetfromthe 2-stfoirrey | rs `SurfaceWater Sampling. The following details are included here to complete thefieldrecord with respect MeMobilem , AL: The e surface wvaterr collleecctetdtaetnetachooff 3sseitersbleocnaetetdvwitehinsthoepMobtilee RivRerrinneveory case each case. 1 Peenascahccoalsae,wFiLt:hiTnh2emsuroffascheorweaitnecrcao.l0l.e5ctmdedepatteha.chRoef-tshuesp3esnidteesdbwoitthtionmtsheediTmeexnatrsBwaeyroeuwavaosicdoeldlienceteadcihn case. 1 Enon, Batelle Duxbury Operations LDatie se 001017