Document 6ReymJN0X15mXqgJ0BKYKEdZm
S. I. du Pont de Nemours & Co. Wilmington, Delaware
COPI
COPY TO:
DR.
YT --1
E.
EVANS, Hospital
DR. I. GU BEmAtuN
DR. H. . SLLEY
MR. J. SCHAEFER, Ethyl Gas.
.larch 13, 1935
Dr. Arnulf Esterer, Hswkesbury, Ontario, Canada..
Dear Dr. Esterer:
I am referring to our Medical Department a copy of your letter asking for information on the safe handling of tetra ethyl lead.
In the meantime, however, it should be .pointed out that rubber gloves in connection with tetra ethyl lead are extremely dangerous. They do not only prevent the absorption of tetra ethyl lead but present a hazard in themselves, as they are capable of absorbing appreciable quantities of tetra. ethyl lead without disclosing the fact by an obvious change in properties. They are, there fore, distinctly unsafe as they create an entirely false sense of security.
Tetra ethyl lead vapor is readily absorbed in any of the standard gas
masks. Absorbent charcoal, for instance, picks it up very readily. It is also
readily destroyed by strong acids or powerful oxidizing agents, but probably the
best gas mask used in conjunction with it is one of the standard masks equipt
with the so-called Universal eannister. On the other hand, our principle in
working tetra ethyl lead ourselves hs^s been that if there is' any tetra ethyl lead
vapor in the air there is something fundamentally wrong with the working conditions
and steps should immediately be taken to remedy these conditions. Laboratory
work, for instance, is done in specially constructed hoods which insure that no
lead ethyl vapor will come out into the room or reach the man who is doing the
work. Analytical methods can readily be devised for the determination of lead
ethyl vapor, but its odor gives a very delicate and very simple test. If suf
ficient lead ethyl is present in the atmosphere of the laboratory in which your
friend is working, so. that it can be readily sraeiled, -ne- would say that there is
entirely too much, and that the technique or method of operating should be
changed at once-.
'
Very truly yours,
SC:DSH
7. S. Cslcott
DIRECTOR.
HE 0000495