Document 6RQGMKpEnVrMjadvR4ony4Ndo

rn .' . r . t (*,41 . a ^ lOfil, I 7? R. C. Isham - bin/d!; ,M*1cr **rrr^itc : February 12 , 1979 ~-- ocP: STURGEON1, MO., DERAILMENT POSITION STATEMENT ro D. R. Bishop J. T. Nolan W. R. Corey P. S. Park J. R. Foehr -'.`R ..;.G. Pier r T. L. Gossage G.' Roush E. H. Harbison J. J. Spano ' J. S. Metcalf R. A. Stohr J. E. McKee G. Young J. C. McPhillips If you have any corrections or suggestions to this position statement, please phone extension 4-2G21. Also attached is the EPA news release of Sunday, Feb. 11. R C I :smt Att. i i I ! i-10 *irs.V.|k/77 I C004.7C lv- /2 1 2 / 7 9 f PCE ITI ON STATEMENT -- TRACE AMOUNTS QF TC DD IN CRUDE ORT1IOCHLORQPIIEMOL Q uestions & answers to be used only by hic pr in responding to direct MEDIA INQUIRIES At the request of the EPA we analyzed a reserve sample of the crude orthochloropheno 1 involved in the derailment at Sturgeon, Mo'. (Jan. 10, 1979) for tetrachloro dioxin. On Friday, Feb. 9, our analytical chemists reported finding this impurity at a .037 ppm average level in th reserve sample. We informed the EPA of this that evening and contacted the clean-up contractor the next morning. Since this is an extremely low level of tetrachloro dioxin contamina tion, just barely above what equipment can detect, we're sure there was no harm to the citizens of Sturgeon. We have notified the clean-up contractor so he can take the appro priate precautions with his people. The same protective clothing that protects clean-up workers from the crude orthochlorophenol would protect them from the miniscule amounts of tetrachloro dioxin. Q. Is this the same TCDD found at Seveso, Italy? A. Probably not. The 2,3,7^ isomer of tetrachlorodibenzo-para- dioxin released at Seveso can't be formed directly in our process. The impurity found in our sample is most probably a different isomer which is far less toxic. -more- Q. Why aid Monsanto wait so long to test its batch sample for TCDD? A . In the past we've analyzed crude orthochlorophenol for TCDD a number of times and never found TCDD. That was using the same analytical equipment which measures for tetrachloro dioxin down to .010 ppm. (three tests). We theorize the TCDD was an impurity in one of the components. Recently another chemical company reported that dioxins are ubiquitous and can be formed a number of ways, for example, by combustion. That is(everything from.-burning leaves to smoking a cigarette may form dioxins. We'll be working to find out how the small amounts of TCDD got in our product and eliminate the contamination. Q. Did Monsanto act quickly when it had this new knowledge on TCDD? A. Very quickly. We learned on the afternoon of Feb. 9 that there were trace amounts of TCDD in our chemical intermediate and informed the EPA that evening.. ^ Q. How can you say there was no harm to the citizens of Sturgeon when they were exposed to the vapor clouds for a long period of time? A. We monitored the air soon after the train derailment. The highest concentration of crude orthochlorophenol detected was .085 ppm. So if you percentage the -.'037 ppm TCDD contamination against the highest known crude orthochlorophenol concentration in the air of .085 p p m , you get a number so small it's meaningless to express. -more- Q. What would be the symptoms of TCDD poisoning? A. The first clinical sign would be chloracne. That's pus-like sacks formed on skin exposed to TCDD. Q. Is Monsanto doing any more testing of crude orthochlorophenol? A. Yes, we're continuing to analyze the product for other production impurities. The EPA had also been sent product from our reserve sample for their own analysis. Q. When will the cleanup be completed? A. It was reported on St. Louis radio on Feb. 9 that the cleanup is 95% complete. We understand the cleanup contractor is taking out all contaminated material down to a 200 ppm level. - - -oOo- EPA NEV.'S RELEASE OF 9 a.in. SUNDAY, FEB. 11 (P'noned from EPA Region VII Public Affairs Department to UPI, A P , Kansas City Star, Columbia Daily Tribune) . On Friday evening/ Feb- 9, the Monsanto Chemical Co. told EPA. Region VII officials that the shipment of chlorinated phenolic compounds v/hich was spilled in a rail car derailment in Sturgeon, Mo., on Jan. 10 contained trace quantities of a compound known as dioxin (TCDD).- Monsanto reported three samples measured, averaging 37 ppb (34, 36, 40 ppb). The company could not identify which particular- forms of TCDD were present. Acting on this information, Harry Gilmer, EPA Region VII on-scene coordinator, ordered the extraction of a sample of soil taken at the spill site sent to the University of 111. r Champaign. With the assistance of Region VII, Dr. Billie Fairless, Dr. R. D. Kleopfer, Dr. C. Cook of the University performed analyses which confirmed the presence of 2,3,7,8 TCDD at ..a levels less than 0.01 ppb. *- Gilmer's team had explored the possibility of dioxin contamination and had both performed some analyses and had contacted Monsanto on this point. According to medical scientists at EPA headquarters in Washington, DC, the new information is of concern but presents no cause for change in the cleanup procedures currently underway. Dr. J. Se'ister, senior medical advisor to the office of toxic substances, stated, "The presence of dioxin in the spill material changes the scope of our review but docs not present cause for *\ immediate alarm in the levels reported." t I -moreI Dr. Seister had led a team of medical and public health experts before a tov.n meeting in Sturgeon on Thursday night held at the request of Senator Tom Eagleton. Concern among residents is still strong as odors from the spill linger. Seister's group answered questions on the known and suspected effects of phenol and various chlorinated phenolic compounds as well as orthochlorophenol which were known at that time to be present in the spill material. They were preparing a report of recommendations for further studies in the area to be presented early this week. Additional samples of the spill material have been obtained from Monsanto by Region VII officials. These are being prepared for further analyses. Steve Jellineck, EP/i assistant administrator to toxic substances will be meeting with Seister1s group on Monday to coordinate further activities. "We intend to take all necessary steps to assure the continued identification and removal of these spill chemicals," declared Jellineck. "EPA headquarters will provide Region VII with any assistance needed to complete the job and protect the health of local residents." -0O0-