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Phone: (814)231-8032
Fax: (814)231o-r(8114)22315-15380
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Analytical Report
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Fluorochemical Characterization of Water and Sediment Samples
Port St. Lucie Resampling (E00-2003)
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Centre Analytical Laboratory Report No. 023-014P
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Testing Laboratory
Centre Analytical Laboratory, Inc.
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St3a0te48CoRlelsegeea,rcPhAD1r6i8ve01
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3M Environmental Laboratory Contact
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Kent R. Lindstrom
Bldg. 236-09
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+ St. PaPu.l0,.MBNox553133333-13331
Phone: (651) 778-5352
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Requester
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3M EnvironmentDaallTeeBcahcnoonlPohg.&Dy.Safety Services
Bldg. 2-3E-09
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St. PaPu.lO,.MBNox5353133331-3331
pacetoes
000992
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1 Introduction
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RCeenstrse aArnearyeipcoarlteLdafboorrathoreiaensa,lyInsci.s (oCfaensterr)iefsroofmwthaer3aMndEsnevrdoinmmeannttsaalmpLlaebsorreactoe.ivedTbhye
`sCeanmtprleesswtuedyrneucomlbleecrtaesdfsrigonmePdorotthSet.prLoujceiec,F5lo0r2i3d.a0a1n4darepartof 3MProject E00-2003. The'
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w(SeLprCeMcrSiIeMRSoc)cehafnaoirdmailvnocnalelccydhh.rroamcattoagzraapthoynwbayslrueqiuecsthedrofomr aaltsoamgprleas.pdehAmytmaslsofs4p6ciscamipnlteys.
`Thesampleswerepreparedandanalyzed by LC/MS/MSforthefollowinglistoffluorochemicals:
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+ Tetet Tootnas
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[ PertuorooctaneSufionvaride
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2 Sample Receipt
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Twihnederiseviadcmuoapllllseeacsimewpdelrebeceostnuwtbeameiinntee7rd/s1wi8en0ir0nadiarvenicddeuiav7le/pd1l.8a/Ss0ta0i.mcCpcholanetisanwi-neoefrrcesuasentcdoodwiyeveridenfnoonomta7tp2ir5oe0ns0er.ivsepTdr.heasFesonrattmyep-dflievnse
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AtachmentA.
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3 Holding Times
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`Theanalytical methodusedwasvalidatedagainst amaximumholding ime of 14days.Stabity
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afHtaevretshhiostwinmaecpoesrpiloadblhearsencoovtebreieesnavatltida1t0ed0,nhoLwefvoerpreirtisohdosuladnbgeenrottheandt1h4adtfaiye.ldfortfications
Pacez0rs
000993
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e ! _-- e -3 eo an =
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4 Met-Ahnalo yticdalasnd Preparatory
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4411.1 SLaCmIplMeSIPMrSepafroraLtGIiMSoIMnS Analysis
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LCTIheMScIarMtSidagnealwyassifsr,sTAfeoeryd-mwiiltiherpomrLtioofno4f0s%ammpeltheawnaosl tirnawnastfeerresdolfuotiaon.CsTShPoEeclauartteidwgaes.
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dimsectahradnoeld awnadstchoellSecPteEdcfoorluanmanlywsaisstbyheLnGeMlSutIeMdSw.ihTh1i0s 0t%reamtemtehntanroels.ultAedinmLa.npoeirgthtifoolnfd
concoftehesanmpltespraiorttoanoalysn's.
meLwxithtTiynprteo5a|wmaticeor.ftmTehteehadnidollu,tedTehxtereaxcttrsawctesrweetrheenfittreeartdeadnidtdhieseadmeto maafninnaervaosltuhmeewoaft4e0r
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samples,beginning withthesoldphaseextraction.
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412 SampleAnalbyyLOsMiSMsS
1 EeToles re,i So IcnolHuPmLn.C,Baansaeldioqunotthoefaexftrnacytoifinhjeecatneadlyatnedfopratsshedstatthiroonuagrhypahiausieipnthahseecoclhurmonmarteolgartiavpehitoc
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HtPheLlCiqsueidpmaorabtiiloenp,hEasSoI,MStphreoavnaildyetseairraeptiadainneddfaoccuarcahtaermacetaenrsifso:raanmaoluynztionfg amwei.deFroalnlgoewionfg
omrigdantiecmpceraoturems; mpiolnecochuilnuegsfaunroreocidohneirzsmeidc,a,lfsr.agEmentled, eandicsdegteentcetreadol.lyoIspoenrsapctehdarartarecaltateiryveiolsfy
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aAnHaelwylzeettth-ePacskaamrpdlHePex1t1r0a0ctHsP. LACnaslyysstiesmwacosuppelrefdotro maedMiucsriongmasseslUetcitmedarMeSaIctMiSownamosnuisteodintgo
(beStRwMe)e.nWa8t/e18r/s0a0mapnlde8s2we3r0e0.extSreadcitmeedbnetatnwdesniu8d/1g5e/s0a0mapnldes8w/1e7r/e00eaxtnrdaacntaeldyozned8/b1y8M0S0ManSd.
inwsetrreumaneanltypzaerdambeytMerSsMcaSnbonaf8o2u21n/d0i0n. ATthteacHhPmLenCtasnDdaMnSdIEM.S methods usedforanalysis and
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5 Analysis
1 CAIN +vs rs trevor rfom scsees 51 Calibration
fo5r00t,heacnodm1p0o0u0ndnsgolLfin(ptpetr)estf.orThLeCMCSalIbrMaStioannpaolyisnitss.wTehreepIrnesptarrumeednat 0re,sp2o5n,s5e0,ve1r0s0u,s25t0h,e
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y`intcerocepntacnwdeacosmnpelttoattierodnfcaooreeftfaiccihiepnooti(nn1t).anUscionegflfiinceiaerrnetogfredestseiromniwniatthi1o/nx(we)iwgehtriendge,ttehremsilnoepde.,
Acalbration curve is acceptablei'r >0.985 (2 0.970).
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Galbrationstandardsarepreparedusing thesame SPE procedureused forsamples.
Pacesces 000394
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`concentraarteiwiotnhisn +/-20%ofthe actualvalue.
Fortheresusreported here,calbationcreriaweremet
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52 BElaxnkts blrankaswcereipreoparnedandanawilthevyeryzexteractdion baoftsamcplehs. The
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Inlesvterlucmaelnbtrbaltaonnksst.iann.datrhdf, aondofarfcteemaknnomwn height esvoevlehnstawmepalrees.anlsAogaaonian,lyltzheedbalfatnrksevsehroyuhdgnho-t haveanytargetanalytespresent atorabove thelowrevelcalbration standard.For the
samplespresentedhere thainstrumentbanksarpcompliant.
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53 SSuumrograotgeastpieksesarenotacomponentofheLCIMSMSanalyticalmethods.
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5.4 MMaaitririsxpiSepsiwkeersepreparedforeveryfieldsamp usingal compoundsofinterest. Matrix
spike recoveriesare given inAtzchmenCt.
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QSWPalmCity-C-FMS-200ppt 8indicate a200pptspikingconcentration.
55 ADlufpilelidscaamtpelses wereanalyzedin duplicate. Resultsaregivenalongwihthesampleresults inAtachmentB.
1 DL erqiolasluwpapie in To 56 Laboratory Control Samples enaoclLhduLrCiSn.gReeascuhlesxartergaivceinsoealnl.onAglwirtehctohveerriaews dfoataailncoAtmipaocuhnmdenstwseDraebnedtEw.een70-130% 1
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Sample Thereare
nRo oetlhaetresdamCploemremteaendtcsommentsfor
this
dataset.
6 Data Summary
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inpartsper bio (pb) (194)on botahnas-receivedand cry-weight basis,
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Paceaces
000395
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7 Data/Sample Retention
Slaecrioinisc edaotGaiosasrchiovfecdoonrraottisevaahbiremreedipa randhsarddcopysreporrts mse psepcdAl
foldersmaintabyiCnenetder
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8 Attachments
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81 Atachment:ChantGusidy
ERT
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83
84
AAacthmeantcD:hMLatmGeSpMknefSRetocIoAvCenVri:aeSsn
Osta
(Sta
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85 AttachmenEt: LCIMSMSRaw AnalyticalData(Sediment andSiudgeSamples)
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9 Signatures
| v/o0 "JohnM. Flaherty,
Operations Manager
Date
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KevinJLioyd, Vice President
Date
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OferLabMembers ContrbuttoiDnega
Karon Smith
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Pacesars
000996
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HR
ANALYTICAL REPORT
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ANALYTICAL REPORT
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Centre Analytical
Laboratories, Inc.
3048 Research Drive Sats CollegePA T6001 10237-8032 Fa 7e2ai-izes
Anica Rast E00-2003 PortSt. Luci, FL Resampling (slid)
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