Document 6Ep1OrNOgNqgJymmaxqMYy44

PPG INDUSTRIES, Inc. STANDARD VCM SPEC1FICATION Appearance Color Acidity (as HC1) ppm, max. Iron (as Fe) ppm, max.. Nonvolatile ppm, max. Acetaldehyde ppm, max. Acetylene ppm, max. Water ppm, max. Peroxides (as Hfa) ppm, max. 1,3 Butadiene ppm, max. Ethyl Chloride ppm, max. VIny Acetylene ppm, max. Ethylene Bichloride ppm, max. Methyl Chloride ppm, max. Oxygen In Vapor Phase ppm, max. Clear Colorless 2 0.3* 50 0.4 2 100 0.06 lo 100 10 10 100 1000 * No standard Interplant Analytical Method available at this time. APPROVED October 23, 1975 SL 090427 PHYSICAL PROPERTIES AND CONSTANTS OF PURE VINYL CHLORIDE The following table contains the latest information available on the properties of vinyl chloride. Some of these properties were determined by Dow while others are calculations, estimations or determinations from the most reliable sources available. Property 1. Molecular Weight 2. Boiling Point at 760 mm 3. Melting Point 4. Odor, uninhibited inhibited 5. Color 6. Flash point 7. Autoignition Temperature 8. Flammable Limits, Vcl. % in air 9. Liquid Density, g/ml Ret.* (1) ffl (3) (4) (4) (4) (14) (5) (6) (3) Tamp. *C -13.80 -153.69 Gas at room temperature 472.22 (882'F) Room temperature 100 25 -20 -25 -30 62.501 Faint, sweet odor feifli . -- --a-- diuJA-iiiluhiiar - ---* .f Colorless Will form flammable mixtures at all normal ambient h nperatures 0.746 0.9013 0.9834 0.9918 0.9999 oV 6 I 7 4 References see page 19. SL 090428 Property 10. Density Change with Temperatjre g/mirc 11. Liguid Viscosity, cps 12. Vapor Viscosity, cps Ref.* Temp. *C (3) (between -30 & -20) (3) 100 25 -10 -20 --30 -40 (7) 100 25 Ivmn tHLWoe liquid viscosity! 0.00164 (approx! 0.100 0.185 0.248 0.274 c:D3 0.340 0.0138 0.0108 4? M 13. Surface Tension, dynes/em 14. Refractive Index, 0 line References see page 19. (3) 100 25 (8) 25 5.4 16.0 1.3642 * 5 SL 090429 * < ftipoty 15. Vapor Pressure, mm Hg Rif: Tamp. *c (2) 100 25 0 -25 --50 -75 -100 16. Change in Boiling Point with Pressure dt/dP *C/mm Hg (3) 25 -13.37 MMK MtSStME OF VWfl CMlOmDE MOMOME* 16.617 2.943 1,293 470 130 24.4 2.5 a01355 0.03423 17. Heat Capacity (liquid). Cp, cal./mole/deg. (3) 100 25 IS. Heat Capacity (Vapor), Cp, cal./mole/deg. (9) 19. Latent Heat of Vaporization A Hv, cal/mole (3) 100 25 100 25 -13.8 6 * References see page 19. 26.25 20.56 14.88 12.82 3.310 4.710 5,250 SL 090430 0 %\ X * -fr i? Pnperty 20 Latent Heat of Fusion, AHm, cal/mole 21. Heat of Formation A Hf, 298'K, Real/mole 22. Free Energy of Formation, Ff 298* K, Real/mole 23 Heat of Polymerization, A Hp, Real/mole 24. Critical Temperature, t,, *C Ref.* (3) Temp. *C (3) (10) (3) (3) (11) 25. Critical Pressure, P., atmospheres 26. Critical Volume, v,, cc/mole (11) (11) 27. Critical Compressibility (PV/RT), Z (11) 28 Volumetric Shrinkage upon Polymerization, approximate, % 29. Dielectric Constant at Frequency of 10s Hz (3) (3) 30. Dissipation Factor at Frequency of 10* Hz (3) 31. Solubility -- Soluble in CCI,, ether, ethanol and most organic solvents 32. Solubility of water in Vinyl Chloride, % 33. Solubility of 0, from air in Vinyl Chloride at 60 psig, ppm 34 Thermal Conductivity (Vapor), K, Cal /[secs. cm:(C/cm)i References tee page 19 (1) 112) (13) 112 -21 -21 112 25 23.8 (75*F) 0 10 20 30 1,172 8.480 12.386 --25.3 0.5 147 <------ 56 179 029 35 6.26 7.05 0.0011 4r & % 0.11 210 25 2.2 x 10-* 2.364 x 10-* 2.523 x 10-* 2.686x 10-* 4 7 SL 090431