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Attachment | Co Pagel AR226-1775 rath AIR DATA DUPONT WASHINGTON WORKS SITE "efTfhoirstss,ubbmoitthtaolfswuhmimcahriarzeesasasvoaciilaatbeldewiintfhorPmFatOiAonifnraoimr atthethfeoDlluoPwoinntg tWwaoshdiantgatcoonllWecotrikons site: 1. TSthuedfyi"rs(ttehfefoSrttudhya)s. beTehnedSetsucdryibiesdbteoinEgPcAonadsutchteed"Aiinr2Mpoadretsl.inTghVeerfiirfsitcpaatriton apenrdtaiisnpsarttooafirPmhoansietoIraictnigv/imtioedse.liTnhgeastetchoenfdenpcaertlipneerotfaitnhsetoWaasirhington Works site smuobnmiittotrailnpgr/omvoiddeelsinEgPiAn wthiethcodamtmaufnriotmytahnedPihsapsaertI owforPkh.asLeaIbfoarcattivoirtyiesd.ataThfirsom this work is included as Attachment 1. 2. TunhdeersteackoenndaesffaonrtiinstearnPaalrtDiuclPeoSnitzeprDoigstrraimbudteisoingAnneadlytsoisv.eriTfyh/irsefeifnfeoritnwpuatss to air deposition modeling. 2. The laboratory data for this effort is included as Attachment NthoitsejutnhcattutrheerAeiprreMsoednteloinnlgy VienrtiefrimceadtiiaotneSrtesuudlytsi.s nWoet caormepsluemtem;artihzerienfgorseocmoeommfetnhtes at otbhesePravrattiicloensSi0zeasDsiissttriibnuutnidoenrasntaalnydsiinsgoisfutnhdeerdartea.vieAw raenpdorwtildlocsuubmmeintttiendgtroeEsuPltAs pfroonm its completion Intermediate results from the Air Modeling Verification Study mAosnisttaotreeddaabmobvei,enDtuaPiornmteaissuinretmheenmtisdswtiotfhccoonndcuurcrteinntgaartdwios-ppehrasisoend msotuddeylitnogcoremspulatrs.e aAdmdbiitieonnt, ianiirtsiaalmmpoldeeslfirnogmrtuhnesfhiarsvtephbaeseenocfotnhdeucftieelddtporboeggrianmthheavperobceeesnsaonfaluynzdeedr.staInnding. hinotwermmoeddiealteedmaonnidtmoorniintgodraetda raensduldtsracfotmmpoadreel.inTgabrlunes1fiorncthliusdPehasasseumI macatrivyitoy.f `sThhoirwteyd-tthhraete aptainros otifmmeodineltehids/mpohansietoorfetdherepsurlotgsrwaemredigdetnheeramtoeddeilnuPnhdaesre-pIr.edRiecstultthse calolnccaesnetsratthieonmoodfePlFedOAvailnueaicr,itahsercoovmepra-rperedditoctqeudanotrifwiaasblienmaognrieteomreendtvwaliutehs.theRamtehaesru,riend vparleudei.ctiNoontreestuhlattsoivnera-cpornesdeircvtaitoinvies ecsotnismiadteeroefdaainraccocnecpetntarbalteiorness.ponTsheesfinocleloawninogverobservations can be made at this intermediate stage: 000004 z. Page 2 May 19,2004 + cMaosedse)l.edOnvaalvueersaogvee,r-tphreemdoicdtelmeoavseurr-perdedviacltueeds b3y3%aoppfrotxhiemtaitmeely(forti1m1eso,fwtiheth3a3 range `omfe1as2u1re0d7v3alufeo.r alTlhbiustloanrgeercaosvee.r-Ipnreodniectciaosne,isthaermesoudletolfcovhearn-pgriendgicwteidnd24cotnidmietsiotnhse that that occurred day. throughout the 24-hour period and are apparent from the wind rose for Moqduaentliefidabvlaelluiemsit.areFionr a2g2reoefmtehnet3w3ictahsessa,mporli6n7g%roesfutlthsetthaitmem,etahseumroendibtoerleodw vtahleue was was below the quantifiable limit and the also below the detectable analytical model value. predicted a quantifiable number that Results from a Particle Size Distribution Analysis APFsOaAmplininagmbpireongtraaimrwatasthceoWnadsuhcitnegdttoonevWaolrukatsestithee. paLratbiocrleatsoirzey ddiasttarigbeunteiroant(ePdSdDu)rionfg dtheipsossiatmipolninmgodperloigngr.amDaerpeosiintciloundeodfiPn FAtOtAacihsmceonntsi2d.erPeSdDa miingfroartmiaotniopnaitshawnayinapnudt for air apdrdoivtiidoinngtoapnruopvdiaditnegd aPSmeDasisuroenoefatchceepPteSdD,watyhets0avmeprliifnygdepproosgirtaiomnaelsstoimwaatess.useIdn to calculate 72-hour average ambient air concentrations at 4 fence-line locations. Results from the sampling program are summarized below. + AatnfaovuerrfaegneceP-lSinDewlaocsatciaolncsu.laTtehdeuasvienrgadgaetaPScoDlliescstehdodwunriinngthae7f2o-lhloouwrinsgamtapbllei.ng event Particle Diameter, microns 40 Cumulative % Less Than Particle Size 0.056 [os os oom [man 7 0.072 65.1% Coa 7] 0.598 1 ThcoelsleectreedsualtttshceoWmapsahriengfatvoonraWbolrykwsitshitper(ecviircoaus19P9S5D),msehasouwreimnetnhtestafbolrePbFelOoAw. veCCos May 19P,a2g0e0s4 Particle Diameter, | `microns Mass Fraction | Cumulative % Less Than Particle Size Coo 1 s sem | [o C a o 02e 67| | ss ew | + The overall follows: mass concentrationof APFO/PFOA for the 3-day test period is as Station 1: Station 2: Station 3: Station 4: 0.0099 ug/m' 0.1099 ug/m' 0.1030 ug/m' 0.0034 ug/m' CVeornscaetnitlreatSiaomnpslicnogmp(aOrVeS)fatvuobreasb,lywhtoerperetvhiatoumsaj2o4r-ihtoyuorfsmaomnpiltionrgecdoldlaetcatewdasusbienlgoOwSaHA q3udainftfietratbiyonlelsismitthoafnap6p%r,osxhiomwaitneglyac0c.e1p4taubgl/em3p.recCios-iloonciantethdessaammpplleisnfgrmoemthSotadtoiloongsy2. and pAlrseov,iotuhse OcoVnScentturbaetsiaonmsplaibnogvwehaircehcosnhsoiswteSnttatwiiotnh4parsedtihcetepdremdoodmeilnarnestulutpswainnddwliotchation and Stations 2 and 3 as the predominant downwind location. 000006 May 19P,a2g0e0d4 Table 1. Summary of Phase 1 Intermediate Results for Modoling and Monitoring Eve1 nt 10Da5t0o3 25 9m003 7 8 12003 203 1s o12s10s3 RocopAtMoSr-Lo1cation Moudgeilme3d, 002030 102080 000000 000 Moniutgomr3ed, <0011s4 <003 <0wiz <ots Overpredictions 1 43 21 t10i8m3o AMS23 5 ues 3187a9 o0o9rs 300 or 2a39 43 78 11221010033 5 1zie0s o08t3 <003 28 0&7 on 60 1 oss 000 017 1 2 tosis nz Ams 001000 o<ot1s4 78 11221010033 9 11803 0 102 <1 os 73 017 os 2 1 ounsis 003 <oi4 21 m1meoss0s Ams:s 5 11903 001 021 <1 <014 000 <0is 5 7 8 200s 12103 000000 <<0014 15" o12s18s03 000583 <0013s 18 21 ntoszis Anse 5 112003 000020 <00114s 000 <0 s7 i1o20n03 1 oss 000100 <<0o1rs2 000 <0is 000007