Document 65yKn9errDg1RLvrZORG3XMj3
Attachment 2
* 77&
Analytical Report
Air Sampling Fluorochemical Report DuPont Washington Works - Air Sampling Program Round 9
Exygen Research Report No. L0001508
Testing Laboratory
Exygen Research 3058 Research Drive State College, PA 16801
Requester
Michael D Aucoin URS Corporation Barley Mill Plaza Building 27 Room 1260 Lancaster Pike and Rt 141 Wilmington, DE 19805
tm
CO JCt*
vp
oQ
- y kp )
=cy' Jf.O ' "j O j
ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
Page 1of 7
3058 Research Drive Staate College, PA 16801, USA
000387
T: 800.281.3219 F: 814.272.1019
exygen.com
Summary
jr
Seven solid media samples were received by Centre Analytical Laboratories, Inc. (dba Exygen Research) (Exygen) from DuPont Corporation. The media represent samples of air collected on OVS tubes. Please see Table 1 for a completed listing of samples received and field air volumes collected.
The samples were analyzed for Perfluorooctanoic Acid (C8 Acid) using liquid chromatography / mass spectrometry (LCMS).
The OVS tubes were separated into three fractions for specific fluorochemical analysis. Fraction A consisted of the filter, backing material and plastic ring. Fraction B contained the first bed of XAD resin and the PUF backing. Fraction C contained the second bed of XAD resin and PUF backing. Fractions A and B were extracted with 1 mL of methanol. Fraction C was not analyzed but saved for possible future analysis. Perfluorodecanoic Acid (CIO Acid) was added as a surrogate spike to each fraction prior to extraction.
Instrument operating conditions can be found at the beginning of each analytical run. Raw instrument data is given in Appendix A. Chain-of-custody information can be found in Appendix B.
ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
Page 2 of 7
000388
Results Summary
Request #
WWK-A-AMS 1-E9 A WWK-A-AMS1-E9 B WWK-A-AMS1-E9 C WWK-A-AMS 1-E9 (Total)
AirVolume Sampled(L)
1439 1439 1439
C8Acid (mg/m3) <0.00007 <0.00007
NA <0.00014
WWK-A-AMS2-E9 A WWK-A-AMS2-E9 B WWK-A-AMS2-E9 C WWK-A-AMS2-E9 (Total)
WWK-A-AMS3-E9 A WWK-A-AMS3-E9 B WWK-A-EMS3-E9 C WWK-A-EMS3-E9 (Total)
WWK-A-AMS4-E9 A WWK-A-AMS4-E9B WWK-A-AMS4-E9 C WWK-A-AMS4-E9 (Total)
1442 1442 1442 1392 1392 1392 1417 1417 1417
0.00011 <0.00007
NA 0.00011 0.00011 <0.00007
NA 0.00011 <0.00007 < 0.00007
NA <0.00014
WWK-A-AMS5-E9 A WWK-A-AMS5-E9 B WWK-A-AMS5-E9 C
WWK-A AMS5-E9 (Total)
1453 1453 1453
< 0.00007 < 0.00007
NA <0.00014
WWK-A-AMS6-E9 A WWK-A-AMS6-E9 B WWK-A-AMS6-E9 C
WWK-A AMS6-E9 (Total)
1429 1429 1429
< 0.00007
<
0.00007 NA
<0.00014
NA - Not Analyzed. B fraction was below the quantitation limit, therefore the backup fraction does not require analysis.
1. "<" is defined as not detected at or above the reported level.
2. Sample results have not been corrected for blank results or control spike recoveries.
3. Please note the following descriptions of the OVS sample tube fractions:
Fraction A B C
FractionDescription Frit Extract 1stsetbeadsextract 2ndsetbeadsextract (notanalyzed)
ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
Page 3 of 7
000389
QC Data
LCS Please note: One control sample was spiked with each perfluorooctanoic acid to give a final concentration of 500 ppb. Air was pulled through the tube at a rate of 1-liter per minute for one hour (60 liters of air). The fractions were separated and analyzed. The acceptable range for control recovery is 75-125%.
Request# Control 1
C8Acid
C8Acid
(amountspiked-ppb) (amountrecovered- ppb)
500 495
C8Acid (percentrecovery
99
Blanks Request#
WWK-A-AMSFBLK-E9A WWK-A-AMSFBLK-E9B
Voi. OfAir(L) 0 0
C8Acid (uq/fraction)
<0.10 <0.10
000390
ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH Page 4 of 7
Surrogates
A surrogate spike (CIO Acid) was added to all OVS tubes to give a final concentration of 500 ppb in the extract. Surrogate spike recoveries are given in the following table. There are no set criteria for surrogate spike recoveries. Advisory ranges are 75-125%.
Sample#
WWK-A-AMSFBLK-E9 A WWK-A-AMSFBLK-E9 B
WWK-A-AMS1-E9 A WWK-A-AMS1-E9 B WWK-A-AMS2-E9 A WWK-A-AMS2-E9 B WWK-A-AMS3-E9 A WWK-A-AMS3-E9 B WWK-A-AMS4-E9 A WWK-A-AMS4-E9 B WWK-A-AMS5-E9 A WWK-A-AMS5-E9 B WWK-A-AMS6-E9 A WWK-A-AMS6-E9 B
Control Spike A Control Spike B
AmountSpiked (PPb) 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500 500
AmountRecovered PercentRecovery (ppb) (%) 488 98 300 60* 504 101 362 72* 481 96 322 64* 512 102 332 66* 538 108 352 70* 500 100 335 67* 511 102 347 69* 490 98 297 59*
* Surrogate recovery outside of advisory range.
ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
Page 5 of 7
000391
Calculations
Request#
WWK-A-AMSFBLK-E9 A WWK-A-AMSFBLK-E9 B
WWK-A-AMS1-E9 A WWK-A-AMS1-E9 B WWK-A-AMS2-E9 A WWK-A-AMS2-E9 B WWK-A-AMS3-E9 A WWK-A-AMS3-E9 B WWK-A-AMS4-E9 A WWK-A-AMS4-E9 B WWK-A-AMS5-E9 A WWK-A-AMS5-E9 B WWK-A-AMS6-E9 A WWK-A-AMS6-E9 B
Control Spike A Control Spike B
Vol. OfAir (L) 0 0 1439 1439 1442 1442 1392 1392 1417 1417 1453 1453 1429 1429 0 0
C8Acid (raw-ppb)
<10 <10 <10 <10 158 <10 150 <10 <10 <10 69 <10 <10 <10 495 <10
C8Acid (ug/fraction)
<0.10 <0.10 <0.10 <0.10 0.16 <0.10 0.15 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 0.50 <0.10
C8Acid (mg/m3) <0.00007 <0.00007 0.00011 <0.00007 0.00011 <0.00007 <0.00007 <0.00007 <0.00007 <0.00007 <0.00007 <0.00007
COO 39
ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
ro Page 6 of 7
Example Calculation
For sample WWK-A-AMS2-E9 A C8 Acid.
= [158 ng/ml o f C8 Acid x (1 ml) x (1 u g / 1000 ng) x (1 m g / 1000 ug) ] / [(1442 L ) x (1 m3 /
1000 L )]
= 0.000Tlm g/m 3
-............ -
- - - ------ -
Signatures
V A . C _ lL
Paul Connolly, LCMS Tearn Leader
/
tvM.< Z / f b l- t c f
/(John Flaherty, Vice'fYesident
Other Lab Members Contributing to Data James Milier
Date
/sjoy
Date
ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
Page 7 of 7
000393
000394
OUt
Table 1. Login Information / Field Data
SampleID
Exygen LabID DateReceived Description
WWK-A-AMSFBLK-E9A WWK-A-AMSFBLK-E9B WWK-A-AMSFBLK-E9C
WWK-A-AMS1-E9A WWK-A-AMS1-E9B WWK-A-AMS1-E9C WWK-A-AMS2-E9A WWK-A-AMS2-E9B WWK-A-AMS2-E9C WWK-A-AMS3-E9A WWK-A-AMS3-E9B WWK-A-AMS3-E9C WWK-A-AMS4-E9A WWK-AAMS4-E9B WWK-A-AMS4-E9C WWK-A-AMS5-E9A WWK-A-AMS5-E9B WWK-AAMS5-E9C WWK-A-AMS6-E9A WWK-A-AMS6-E9B WWK-AAMS6-E9C
Control SpikeA Control SpikeB Control SpikeC
L0001508-1 L0001508-2 L0001508-3 L0001508-4 L0001508-5 L0001508-6 L0001508-7 L0001508-8 L0001508-9 L0001508-10 L0001508-11 L0001508-12 L0001508-13 L0001508-14 L0001508-15 L0001508-16 L0001508-17 L0001508-18 L0001508-19 L0001508-20 L0001508-21 L0001508-22 L0001508-23 L0001508-24
12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03
Fritextract 1stsetbeadsextract 2ndsetbeadsextract Fritextract 1stsetbeadsextract 2ndsetbeadsextract Fritextract 1stsetbeadsextract 2ndsetbeadsextract Fritextract 1stsetbeadsextract 2ndsetbeadsextract Fritextract 1stsetbeadsextract 2ndsetbeadsextract Fritextract 1stsetbeadsextract 2ndsetbeadsextract Fritextract 1stsetbeadsextract 2ndsetbeadsextract Fritextract 1stsetbeadsextract 2ndsetbeadsextract
AirVolume Sampled(L)
0 0 0 1439 I 1439 1439 ; 1442 1442 1442 1392 1392 1392 1417 1417 1417 1453 1453 1453 1429 1429 1429 0 0 0
C6CG00
Table 2. Chain of Custody
SampleID WWK-A-AMSFBLK-E9A WWK-A-AMSFBLK-E9B WWK-A-AMSFBLK-E9C
WWK-A-AMS1-E9A WWK-A-AMS1-E9B WWK-A-AMS1-E9C WWK-A-AMS2-E9A WWK-A-AMS2-E9B WWK-A-AMS2-E9C WWK-A-AMS3-E9A WWK-A-AMS3-E9B WWK-A-AMS3-E9C WWK-A-AMS4-E9A WWK-AAMS4-E9B WWK-A-AMS4-E9C WWK-A-AMS5-E9A WWK-A-AMS5-E9B WWK-AAMS5-E9C WWK-A-AMS6-E9A WWK-A-AMS6-E9B WWK-AAMS6-E9C
Control SpikeA Control SpikeB Control SpikeC
Date Collected 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03
NA NA NA
DateReceived atExygen 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03
DateExtracted byExygen 1/5/04 1/5/04 NA 1/5/04 1/5/04 NA 1/5/04 1/5/04 NA 1/5/04 1/5/04 NA 1/5/04 1/5/04 NA 1/5/04 1/5/04 NA 1/5/04 1/5/04 NA 1/5/04 1/5/04 NA
DateAnalyzed byExygen 1/5-1/6/04 1/5-1/6/04 NA 1/5-1/6/04 1/5-1/6/04 NA 1/5- 1/6/04 1/5-1/6/04 NA 1/5-1/6/04 1/5-1/6/04 NA 1/5- 1/6/04 1/5-1/6/04 NA 1/5- 1/6/04 1/5-1/6/04 NA 1/5- 1/6/04 1/5-1/6/04 NA 1/5-1/6/04 1/5-1/6/04 NA
ANALYTICAL DATA REVIEW SHEET
LC/MS
< J `vv'a eS "R-- /Miller"
Analyst
A?
Reviewed by
dnature/Date
oi
/ /n / b Y
U g n a t u r e / Date
'/ * / * * {
0010 0 0 0 3 9 6
Sequence: C:\HPCHEM\1\SEQUENCE\010504.S
Sequence Table:
Method and Injection Info Part:
Line Location SampleName
Method
Inj SampleType InjVolume DataFile
1 Vial 1 2 Vial 1 3 Vial 2 4 Vial 3 5 Vial 4 6 Vial 5 7 Vial 6 3 - Vial 79 Vial 92 10 Vial 11 11 Vial 12 12 Vial 13 13 Vial 14 14 Vial 15 15 Vial 16 16 Vial 17 17 Vial 18 18 Vial 19 19 Vial 20 20 Vial 4 21 Vial 92 22 Vial 21 23 Vial 22 24 Vial 23 25 Vial 24 26 Vial 25 27 Vial 26 28 Vial 4 29 Vial 92 30 Vial 1 31 Vial 2 32 Vial 3 33 Vial 4 34 Vial 5 35 Vial 6 36 Vial 7
STD 50 ppb STD 50 ppb STD 100 ppb STD 250 ppb STD 500 ppb STD 750 ppb STD 1000 ppb STD 1500 ppb solvent blank L0001508-22 L0001508-23 L0001508-1 L0001508-2 L0001508-4 L0001508-5 L0001508-7 L0001508-8 L0001508-10 L0001508-11 STD 500 ppb solvent blank L0001508-13 L0001508-14 L0001508-16 L0001508-17 L0001508-19 L0001508-20 STD 500 ppb solvent blank STD 50 ppb STD 100 ppb STD 250 ppb STD 500 ppb STD 750 ppb STD 1000 ppb STD 1500 ppb
FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10
1 Sample 1 Calib 1 Calib 1 Calib 1 Calib 1 Calib 1 Calib 1 Calib 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Sample 1 Calib 1 Calib 1 Calib 1 Calib 1 Calib 1 Calib 1 Calib
Calibration Part: Line Location SampleName
Method CalLev Update RF Update RT Interval
2 Vial 1 3 Vial 2 4 Vial 3 5 Vial 4 6 Vial 5 7 Vial 6 8 Vial 7 30 Vial 1 31 Vial 2 32 Vial 3 33 Vial 4 34 Vial 5 35 Vial 6 36 Vial 7
STD 50 ppb STD 100 ppb STD 250 ppb STD 500 ppb STD 750 ppb STD 1000 ppb STD 1500 ppb STD 50 ppb STD 100 ppb STD 250 ppb STD 500 ppb STD 750 ppb STD 1000 ppb STD 1500 ppb
FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10 FC8-10
1 Replace Average 2 Replace Average 3 Replace Average 4 Replace Average 5 Replace Average 6 Replace Average 7 Replace Average 1 Average Average 2 Average Average 3 Average Average 4 Average Average 5 Average Average 6 Average Average 7 Average Average
-3 -3 -3 -3 -3 -3 -3 -3 -3 -3 -3 -3 -3 -3
1/5/04 5:11:04: PM jmiller j& jt * ' / r A i
i i n 11 1
0 0 0 3 9 7 P;age I of 2
Sequence: C:\HPCHEM\1\SEQUENCE\010504.S
,CMS5 1/5/04 5:11:04 PM jmiller
U01 2
Page 2 of 2 000398
LC/M S SYSTEM AND O PERATING CO ND ITIO NS
C lient: Dupont
EXYGEN STUDY: L0001508
Instrum ent:
H e w le tt-P a c k a rd 1100 LC/M SD (LC /M S 5) API-ES In te rfa c e - N e g a tiv e SIM m ode N itrogen: 10 L /m in a t 300C Fragm entor: Variable; Vcap: 3500V
Com puter:
H ew lett-P ackard Kayak w orkstation
Softw are:
M icrosoft W indows NT 4 .0 A g ile n t C hem S tation Version A .0 8 .0 3
HPLC Equipm ent:
HP G 1322A Solvent Degasser HP G1311A Q uaternary Pump HP G 1313A A utosam pler HP G 1316A Colum n T h e rm o s ta t HP G 1946A MSD
HPLC Colum n: Colum n T e m p .: M obile Phase (A): M obile Phase (B):
T h erm o H ypersil-K eystone Betasil C18, 30 x 2 .0 m m x 3pm 35 C 2m M A m m onium a c e ta te in O m niSolv W a te r HPLC grade M ethanol
Tim e
%A
0.0 70
6.0 10
1 0 .0
10
1 0 .0
STOP
Post T im e = 4 m in.
T o ta l run tim e = 14 m in.
Flow Rate: In je c te d Volum e:
0 .3 m L/m in 5 pL
%B
30 90 90 STOP
,,Page,1o,,f2
0013
000399
Ions m o n ito re d :
A n alyte C8 Acid (PFOA)
C10 Surrogate
Ion (m /z ) 369 469
Extraction D ate: January 5, 2004
A n a ly s t:
Jam es R. M ille r
Exygen Research '
3058 Research D rive, S tate C ollege, PA 16801 Phone: (814) 272-1039, FAX: (814) 231-1580
Page 2 of 2
0014
C00400
Instrument : LCMS5 Tue Dec 16 12:15:46 2003
m/z 112. 9$ gfO.Ol Ab 26297. Pw 0.62
G1946: API_ES Negative mode
Page 1 of 3 C:\HPCHEM\1\1946TUNE\ATUNES.TUN
m/z 602. DO gf0.02 Ab 36351 Pw 0.59
m/z 1034.05 max Ab 135231 Pw 0.66
ft |
J 110
L 115
m/z 163 4 05 max Ab 30783 ? Pw 0.64
____________________ 600
605
m/z 223'1.15 max Ab 346109 Pw 0.66
_______________________ 1 V .
1030
1035
1 | 1 1 J! I V | 1 1 1
1630
1635
1| l 111| 111
2230
2235
Scan: 50.00 - 3000.00 Samples: 8 Thresh: 0 Step: 0.10 29501 peaks Base: 2234.15 Abundance: 335232 F Raw,Gauss 0.3
100 n
80 -
60 -
40
20 _Ln
500
1000
1500
2000
2500
m/z gf 112.96 601.99 1034.05 1634.05 2234.15
Abund 243712
32600 147776 307520 335232
Rei Abund 100.00 13.38 60.64 126.18 137.55
Iso m/z 113.99 602.95
1035.05 1635.05 2235.15
Iso Abund Iso Ratio
4075
1.67
2771
8.50
32352
21.89
117312
38.15
156608
46.72
U01 5 G C 04 0 1
Instrument : LCMS5 Tue Dec 16 12:15:46 2003
Gl946: API_ES Negative mode
Page 2 of 3 C:\HPCHEM\1\1946TUNE\ATUNES.TUN
Mode: API--ES Polarity: NEG
Fragment Skim2 Lensl Lens2 Iris
Gain
VAR WidthGain 1031
6.0 WidthOffs VAR
-3.8 MassGain 93.65
14 MassOffs 0.516
-8
Energy
5.0
OpolPeak 300
OpolKnee 315
o
CM
QuadDC 0.00
EMV VCap
Status: CapCur ChamCur
1788 Samples
8
4000 Averages
1
StepSize 0.10
39 DryinqGas 7.0 0.51 Gas Temp 300
Quad Temp 99 Neb Pres 15
Instrument : LCMS5 Tue Dec 16 12:15:46 2003
G1946: API_ES Negative mode
Page 3 of 3 C:\HPCHEM\1\1946TUNE\ATUNES.TUN
Width Offset
0-
-20 -
Dynamic Parameter Ramp
-40 -
-60 -
-80 -
---- 100 -
-120 -
-140 -
-160 -----
500
Mass 112.99 1633.95
1000
T i | i . r- r-- ] i i i i ---- 1----1----1----'----1
1500
2000
2500
3000
Setting -159.00 -159.00
Mass 601.98 2233.91
Setting -159.00 -159.00
Mass 1033.99
Setting -159.00
Ljy
uO i 7
C0 0 4 0 3
i;Method C:\HPCHEM\1\METHODS\010504A.M Calibration Table
Calib. Data Modified
1/6/04 8:52:34 AM
Calculate Based on
External Standard Peak Area
Rel. Reference Window Abs. Reference Window Rel. Non-ref. Window Abs. Non-ref. Window Uncalibrated Peaks Partial Calibration Correct All Ret. Times
5.000 % 0.000 min 5.000 % 0.000 min not reported Yes, identified peaks are recalibrated No, only for identified peaks
Curve Type Origin Weight
Linear Ignored Equal
Recalibration Settings:
Average Response
:
Average Retention Time:
Average all calibrations Floating Average New 75%
Calibration Report Options : Printout of recalibrations within a sequence: Calibration Table after Recalibration Normal Report after Recalibration If the sequence is done with bracketing: Results of first cycle (ending previous bracket)
Signal 1: MSD1 369, EIC=368.7 :369.7 Signal 2: MSD1 469, EIC=468.7 :469.7
RetTime Lvl Amount
Area
Amt/Area Ref Grp Name
[min] Sig
[ppb]
!
1 7.230 1 1 50.00000 1.65691e4 3.017 67e-3 1
C8 Acid
2 100.00000 3.17623e4 3.14839e-3
3 250.00000 8.32569e4 3.00275e-3
4 500.00000 1.6413 0e5 3.04636e-3
6 1000.00000 3.11575e5 3.20950e-3
7 1500.00000 4.52231e5 3.31689e-3
8.054 2 1 50.00000 2.02803e4 2.46545e-3 1 CIO Surrogate
2 100.00000 3.87371e4 2.58150e-3 -- 3 250.00000 1.02757e5 2.432 94e-3
4 500.00000 2.02772e5 2.46583e-3
6 1000.00000 3.83879e5 2.60499e-3
7 1500.00000 5.56723e5 2.69434e-3
More compound-specific settings:
Compound: C8 Acid Time Window
: From 7.057 min To 8.058 min
Compound: CIO Surrogate Time Window
: From 7.858 min To 8.663 min
Peak Sum Table
***No Entries in table***
! 'C00414 1/6/04 8:58:29 AM jmiller
`v
0018
C 0 0 4 0 4 Page 1 2
Method C :\HPCHEM\1\METHODS\010504A.M
I
Calibration Curves
C8 Acid at exp. RT: 7.230
MSD1 369, EIC=368.7:369.7
Correlation:
0.99950
Residual Std. Dev.: 6119.66339
Formula: y = mx + b
m: 301.15753
b: 5931.46096
x: Amount[ppb]
y : Area
CIO Surrogate at exp. RT: 8.054
MSD1 469, EIC=468.7 :469.7
Correlation:
0.99945
Residual Std. Dev.: 7922.05150
Formula: y = mx + b
m: 370.88490
b: 7356.34233
x: Amount[ppb]
y : Area
[ >C00414 1/6/04 8:58:29 AM jmiller
&
001 9
0 0 0 4 0 5 Page 2 of 2
Sample Name:STD 50 ppb Sample Info:Warm Up
Data file :C:\HPCHEM\l\DATA\Chemstor\11798592\A665984\FC000001.D
1
nS OO
o
"7:810
Acid Surrogat
33 58 .. 02 49
87 .. 02 88 66
21 70 43 65 41
MSD1 MSD1
43 66 99 ,,
EEIICC==346688.. 77 :: 34 66 99 .. 77
PC00414
*** End of Report ***
Tue, 6. Jan. 2004
09:19:04 am
0020
Page 1 of 1
C00406
Sample Name:STD 50 ppb Sample Info:
1
Data file :C:\HPCHEM\l\DATA\Chemstor\11798693\A668416\FC000002.D
Injection Date Acq Operator Instrument . Dilution
1/5/04 jmiller PC00414 1
5:28:22 PM
Seq Line Vial No. Inj . No. Inj . Voi.
: : : :
2 1 1 5 pi
Acq. Method Analysis Method Last Changed
FC8-10.M
C:\HPCHEM\1\METHODS\010504A.M
1/6/04
08:52:48 am
LC/MS analysis of perfluorooctanoic acid.
*MSD1 369, EIC=368.7:369.7 (CHEMSTORM1798693\A668416\FC000002.D) API-ES, Neg, SIM, Frag: Var
1800
7.235 - C8 Acid
1600H
1400
1200
1000H
800
600
400
200-4
*MSD1 469, EIC=468.7:469.7 (CHEMSTORM 1798693\A668416\FC000002.D) API-ES, Neg, SIM, Frag: Var 8.057- C10 Surrogate.
2000-
mm
1750-
1500-
1250 7
1000-
750-
500 d 250-
Compound Amount (ng/mL)
R.T.
78 Acid
34.60
.'10 Surrogat 35.54
7.235 8.057
Area
16351 20536
Signal
MSD1 369, EIC=3 68.7:369.7 MSD1 469, EIC=468.7:469.7
PC00414
*** End of Report ***
Tue, 6. Jan. 2004
09:19:42 am
Q02 i
Page 1 of 1
000407
Sample Name:STD 100 ppb Sample Info:
1
Data file :C:\HPCHEM\l\DATA\Chemstor\11798815\A670720\FC000003.D
Injection Date Acq Operator Instrument -- . Dilution
1/5/04 jmiller PC00414 1
5:43:23 PM
Seq Line Vial N o . Inj. No. Inj. Voi.
: : : :
3 2 1 5 pi
Acq. Method Analysis Method " Last Changed
FC8-10.M
C:\HPCHEM\1\METHODS\010504A.M
1/6/04
08:52:48 am
LC/MS analysis of perfluorooctanoic acid.
*MSD1 369, EIC=368.7:369.7 (CHEMSTORY11798815\A670720\FC000003.D) API-ES, Neg, SIM, Frag: Var 7.235- C8 Acic,
3000-
2500-
2000-
1500-
1000-
500-
MSD1 469, EIC=468.7:469.7 (CHEMSTOR\11798815\A670720\FC000003.D) API-ES, Neg, SIM, Frag: Var
4000
8.058- C10 Surrogate.
3500-
3000 -j
2500
2000
1500
1000-
500 -j
0-
Compound Amount (ng/mL)
R.T.
""08 Acid
84.67
H10 Surrogat 84.04
7.235 8.058
Area
31432 38526
Signal
MSD1 369, EIC=3 68.7 :369.7 MSD1 469, EIC=468.7:469.7
PC00414
*** End of Report ***
Tue, 6. Jan. 2004
09:20:20 am
0022
Page 1 of 1
COO408
Sample Name :STD 250 ppb Sample Info:
1
Data file :C:\HPCHEM\l\DATA\Chemstor\11798897\A672960\FC000004 .D
Injection Date Acq Operator Instrument Dilution
1/5/04 jmiller PC00414 1
5:58:25 PM
Seq Line Vial No. Inj. No. Inj. Voi.
: : : :
4 3 1 5 pi
Acq. Method Analysis Method Last Changed
FC8-10.M
C:\HPCHEM\1\METHODS\010504A.M
1/6/04
08:52:48 am
LC/MS analysis of perfluorooctanoic acid.
*MSD1 369, EIC=368.7:369.7 (CHEMSTORM 1798897\A672960\FC000004.D) API-ES, Neg, SIM, Frag: Var
8000-
7.240 - C8 Acid
7000-
6000-
5000-
4000-
3000 -d
2000-
1000-
0-A 1 1 1 i------- 1 ^ '
i------- 1------- 1------- 1------- 1------- 1-- --- ,------- ,------- -------,------- ,------- r------- r
2 4 6 8 min
*MSD1 469, EIC=468.7:469.7 (CHEMSTORM 1798897\A672960\FC000004.D) API-ES, Neg, SIM, Frag: Var
-
10000-
8.062 - C10 Surrogate
8000-
6000
4000 -
2000-
,,
i------- 1------- 1 i
JI
1------------------
i------- 1------- 1------- 1------- 1------- 1------- 1------- 1------- 1------- 1------- '------- 1------- 1------- r
Compound Amount (ng/mL)
R.T.
8 Acid
255.90
10 Surrogat 257.39
7.240 8.062
Area
82997 102820
Signal
MSD1 369, EIC=3 68.7:369.7 MSD1 469, EIC=468.7:469.7
PC00414
*** End of Report ***
Tue, 6. Jan. 2004
09:21:03 am
2 Page 1 of 1
000409
Sample Name :STD 500 ppb Sample Info :
1
Data file :C:\HPCHEM\l\DATA\Chemstor\11798978\A675328\FC000005 .D
Injection Date Acq Operator Instrument Dilution
1/5/04 jmi H e r PC00414 1
6:13:22 PM
Seq Line Vial No. Inj. No. Inj. Voi.
: : : :
5 4 1 5 ul
Acq. Method Analysis Method -. Last Changed
FC8-10.M
C:\HPCHEM\1\METHODS\010504A.M
1/6/04
08:52:48 am
LC/MS analysis of perfluorooctanoic acid.
*MSD1 369, EIC=368.7:369.7 (CHEMSTORM1798978\A675328\FC000005.D) API-ES, Neg, SIM, Frag: Var
16000
7.243 - C8 Acid
14000-
12000 ^
10000J
8000
6000
4000
2 0 0 0 -I
11111' 2
11' 4
11i 6
1 T r i- , 8
ir min
*MSD1 469, EIC=468.7:469.7 (CHEMSTORM 1798978\A675328\FC000005.D) API-ES, Neg, SIM, Frag: Var
j 8.069 - C10 Surrogate
12500-
7500j
2500__________J L ..........._
H------ ,------- (------- !------- 1------- ------- 1------- 1------- 1------- 1------- ------- ------- 1------- ------- 1------- 1------- 1------- 1------- 1------- 1------- r
Compound Amount (ng/mL)
R.T.
a8 Acid
517.39
10 Surrogat 517.99
7.243 8.069
Area
161749 199472
Signal
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
PC00414
*** End of Report ***
Tue, 6. Jan. 2004
09:21:32 am
024
Page 1 of 1
COO110
Sample Name:STD 750 ppb Sample Info:
1
Data file :C:\HPCHEM\l\DATA\Chemstor\11799076\A677568\FC000006 .D
Injection Date Acg Operator Instrument Dilution
1/5/04 jmiller PC00414 1
6:28:23 PM
Seq Line Vial No. Inj . No . Inj. Voi.
: : : :
6 5 1 5 pi
Acq. Method
FC8-10.M
Analysis Method C:\HPCHEM\1\METHODS\010504A.M
! Last Changed
1/6/04
08:52:48 am
i
' LC/MS analysis of perfluorooctanoic acid.
I" *M SD 1 369, EIC=368.7:369.7 (C H E M S T O R M 1799076\A677568\FC000006.D) A PI-ES, Neg, SIM , Frag: Var
f !
40000
7.244- C 8 Acid
I ., 35000 /
30000 t
RejectedC hram atogr^a
25000 20000 t 15000 ~ 10000t
A ction Take n
File N o .
H See
Initials/Date; / f a n
.... AAr
5000 Z
0t
`'
11
2
' 11' 4
1^
1 6
i
1
1
T
.
T
.
8
*M SD 1 469, EIC=468.7:469.7 (C H E M S T O R M 1799076\A677568\FC000006.D) A P I-ES, Neg, SIM , Frag: Var
] min
50000 -
8.068 - C 10 Surrogate
40000 -
30000-
20000 -
l 10000 -
i
0-
' T '1 2
I,!
4
Compound Amount (ng/mL)
R.T.
C8 Acid
1355.87
:10 Surrogat 1361.83
7.244 8.068
, 1-
Area 414262 512437
l
X
rr
1 ^'
i
6 8 min
Signal
MSDl 369, EIC=368.7:369.7 MSD1 469, EIC=4 68.7 :469.7
PC00414
*** End of Report ***
Tue, 6. Jan. 2004
09:22:12 am
025
Page 1 of 1
000411
Sample Name:STD 1000 ppb Sample Info:
1
Data file :C:\HPCHEM\l\DATA\Chemstor\11799177\A679744\FC000007.D
Injection Date Acq Operator Instrument Dilution
1/5/04 jmiller PC00414 1
6:43:23 PM
Seq Line Vial No. Inj. No. Inj. Voi.
: : : :
7 6 1 5 pi
Acq. Method Analysis Method Last Changed
FC8-10.M
C:\HPCHEM\1\METHODS\010504A.M
1/6/04
08:52:48 am
LC/MS analysis of perfluorooctanoic acid.
*MSD1 369, EIC=368.7:369.7 (CHEMSTORM1799177\A679744\FC000007.D) API-ES, Neg, SIM, Frag: Var
30000
7.251 - C8 Acid
-........ --
25000 ^
* 20000 15000-
10000^
5000 ^
o-
' 1 1 1 ' 1^ 2
11r 1 i 46
*MSD1 469, EIC=468.7:469.7 (CHEMSTORM 1799177\A679744\FC000007.D)
l
' T 8
API-ES, Neg, SIM, Frag: Var
T min
40000 -j
8.067 - C10 Surrogate
35000 -
30000 j
25000 j
20000 ^
15000 /
10000j
5000 / I
0
'''
I ' '* 2
Jl
'
I ' 'n i '^ '
T ! r
4 6 8 min
Compound Amount (ng/mL)
R.T.
Area
Signal
a8 Acid
1009.03
10 Surrogat 1016.30
7.251 8.067
309808 384288
MSD1 369, EIC=3 68.7 :369.7 MSD1 469, EIC=468.7:469.7
PC00414
*** End of Report ***
U26
Tue, 6. Jan. 2004
09:22:36 am
Page 1 of 1
000412
Ha-li.
Sample Name:STD 1500 ppb Sample Info :
1
Data file :C:\HPCHEM\l\DATA\Chemstor\11799214\A682176\FC000008.D
Injection Date Acq Operator Instrument Dilution
1/5/04 jmiller PC00414 1
6:58:21 PM
Seq Line Vial No. Inj.No. Inj. Voi.
: : : :
8 7 1 5 pi
Acq. Method Analysis Method -- Last Changed
FC8-10 .M
C :\HPCHEM\1\METH0DS\010504A.M
1/6/04
08:52:48 am
LC/MS analysis of perfluorooctanoic acid.
*MSD1 369, EIC=368.7:369.7 (CHEMSTORVI 1799214\A682176\FC000008.D) API-ES, Neg, SIM, Frag: Var
45000
7.242- C8 Add
40000 j
35000
30000 -
25000 /
20000 -j
15000
10000
5000-
_-------------------------------------------------------------------------------------------------------------U----- 1
--------- --------------
1 r . . -i
r
2 4 6 8 min
*MSD1 469, EIC=468.7:469.7 (CHEMSTORVI 1799214\A682176\FC000008.D) API-ES, Neg, SIM, Frag: Var
- 8.067 - C10 Surrogate
50000
40000 -
30000
20000
10000--
1l 'I-------1------- 1------- 1------- 1------- 1------- 1------- 1------- 1------- 1------- 1------- 1------- !------- 1------- 1------- 1------- 1------- 1------- 1------- 1-------
Compound Amount (ng/mL)
R.T.
Ac id
1474.85
10 Surrogat 1478.11
7.242 8.067
Area
450094 555566
Signal
MSDl 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
PC00414
*** End of Report ***
Tue, 6. Jan. 2004
09:23:36 am
0027
Page 1 of 1
COO4 1 3
Sample Namesolvent blank Sample Info:
Data file :C :\HPCHEM\1\DATA\Chemstor\11799290\A684416\FC000009.D
1
"'S8 Acid
0.00
:10 Surrogat 0.00
7.265 0.000
786 0
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
PC 00414
*** End of Report ***
Tue, 6. Jan. 2004
09:24:32 am
Q028
Page 1 of 1
C0 0 4 1 .4
Sample N a m e :L0001508-22 Sample Info:
1
Data file :C:\HPCHEM\l\DATA\Chemstor\11799347\A686784\FC000010.D
Injection Date Acq Operator Instrument Dilution
1/5/04 jmiller PC00414 1
7:28:22 PM
Seq Line Vial No. Inj. No. Inj. Vol.
: : : :
10 11
1 5 pi
Acq. Method Analysis Method Last Changed
FC8-10.M
C:\HPCHEM\1\METHODSV010504A.M
1/6/04
08:52:48 am
LC/MS analysis of perfluorooctanoic acid.
*MSD1 369, EIC=368.7:369.7 (CHEMSTORM1799347\A686784\FC000010.D) API-ES, Neg, SIM, Frag: Var 7.241 - C8 Acid
17500-
15000-
12500-
10000-
7500 d
5000-
2500-
0-
-i------ 1-
*MSD1 469, EIC=468.7:469.7 (CHEMSTORM 1799347\A686784\FC000010.D)
L
8 API-ES, Neg, SIM, Frag: Var
8.065- C10 Surrogate.
20000 -
15000-
10000-
5000-
2ompound
1 1 -- 1--- 1--- 1 24
Amount (ng/mL)
R.T.
Area
3 Acid
494.74
10 Surrogat 490.03
7.241 8.065
154927 189102
1 1 1 -1 ! 1 1 ' r
6 8 min
Signal
MSDl 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
i PC00414
*** End of Report ***
Tue, 6. Jan. 2004
08:56:39 am
029
Page 1 of 1
000415
Sample N a m e :L0001508-23 Sample Info:
Data file :C:\HPCHEM\l\DATA\Chemstor\11799425\A689024\FC000011.D
1
^8 Acid
0.35
10 Surrogat 297.04
i
7.243 8.060
6037 117524
MSD1 369, EIC=368.7:369.7 MSDl 469, EIC=468.7:469.7
PC00414
*** End of Report ***
Tue, 6. Jan. 2004
08:57:32 am
Q03
Page 1 of 1
c n 041_ 6_
Sample Name:L0001508-1 Sample Info:
Data file :C:\HPCHEM\l\DATA\Chemstor\11799484\A691584\FC000012.D
1
- '8 Acid
0.00
10 Surrogat 487.93
0.000 8.076
0 188321
MSDl 369, EIC=368.7:369.7 MSDl 469, EIC=468.7:469.7
PC00414
*** End of Report ***
u 3 1
Tue, 6. Jan. 2004
08:58:04 am
Page 1 of 1
00417
Sample Name :L0001508-2 Sample Info :
Data file :C:\HPCHEM\l\DATA\Chemstor\11799559\A693824\FC000013.D
1
> Compound Amount (ng/mL)
R.T.
-8 Acid
0.00
10 Surrogat 300.22
0.000 8.065
Area
0 118705
Signal
MSDl 369, EIC=368.7:369.7 MSDl 469, EIC=468.7:469.7
PC00414
*** End of Report ***
Tue, 6. Jan. 2004
08:58:34 am
0032
Page 1 of 1
COO418
Sample Name :L0001508-4 Sample Info:
Data file :C :\HPCHEM\l\DATA\Chemstor\11799617\A695936\FC000014.D
1
' Compound Amount (ng/mL)
R.T.
"8 Acid
0.00
:10 Surrogat 503.63
7.244 8.066
Area
2155 194146
Signal
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
I PC00414
*** End of Report ***
Tue, 6. Jan. 2004
09:00:01 am
u033
Page 1 of 1
00419
Sample Name :L0001508-5 Sample Info:
Data file :C:\HPCHEM\l\DATA\Chemstor\11799676\A698176\FC000015.D
1
`" ` 8 Acid
0.00
10 Surrogat 361.92
0.000 8.074
0 141586
MSD1 369, EIC=368.7 :369.7 MSD1 469, EIC=468.7:469.7
i PC00414
*** End of Report ***
Tue, 6. Jan. 2004
09:00:39 am
Q34
Page 1 of 1
COO4 2 0
Sample Name :L0001508-7 Sample Info:
1
Data file :C :\HPCHEM\l\DATA\Chemstor\11799748\A700352\FC000016.D
Injection Date Acq Operator Instrument Dilution
Acq. Method Analysis Method Last Changed
1/5/04 jmiller PC00414 1
8:58:42 PM
Seq Line Vial No. Inj. No. Inj. Voi.
: : : :
FC8-10.M
C :\HPCHEMX1\METH0DS\010504A.M
1/6/04
08:52:48 am
16 17
1 5 pi
LC/MS analysis of perfluorooctanoic acid.
*MSD1 369, EIC=368.7:369.7 (CHEMSTOR\11799748\A700352\FC000016.D) API-ES, Neg, SIM, Frag: Var
6000-
__________ ____
7.243 - C8 Acid,
5000
4000-
3000-
2000-
1000-
0-
*MSD1 469, EIC=468.7:469.7 (CH EMSTORV11799748\A700352\FC000016.D) API-ES, Neg, SIM, Frag: Var 8.071 - C10 Surrogate
min
20000 -
15000-
10000-
5000-
Compound Amount (ng/mL)
R.T.
TM8 Acid
157.75
10 Surrogat 480.82
7.243 8.071
I
Area
53440 185686
min
Signal
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
PC00414
*** End of Report ***
Tue, 6. Jan. 2004
09:01:23 am
035
Page 1 of 1
Sample Name :L0001508-8
Sample Info:
i
Data file :C:\HPCHEM\l\DATA\Chemstor\11799785\A702592\FC000017.D
i Injection Date ! Acq Operator
Instrument j*-' Dilution
i i Acq. Method
Analysis Method Last Changed
1/5/04 jmiller PC00414 1
9:13:45 PM
Seq Line Vial N o . Inj. No. Inj. Vol.
: : : :
FC8-10 .M
C :\HPCHEM\1\METHODS\010504A.M
1/6/04
08:52:48 am
LC/MS analysis of perfluorooctanoic acid.
1
17 18
1 5 pi
-*8 Acid
0.00
110 Surrogat 321.82
7.237 8.062
1154 126716
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7 :469.7
PC00414
*** End of Report ***
Tue, 6. Jan. 2004
09:01:51 am
u 0 36
Page 1 of 1
600422
Sample Name :L0001508-10 Sample Info:
1
Data file :C:\HPCHEM\l\DATA\Chemstor\11799822\A704768\FC000018.D
Injection Date Acq Operator Instrument .. Dilution
Acq. Method Analysis Method Last Changed
1/5/04 jmiller PC00414 1
9:28:46 PM
Seq Line Vial No. Inj.No. Inj. Voi.
: : : :
FC8-10.M
C:\HPCHEM\1\METHODS\010504A.M
1/6/04
08:52:48 am
18 19
1 5 pi
LC/MS analysis of perfluorooctanoic acid.
*MSD1 369, EIC=368.7:369.7 (CHEMSTORM 1799822\A704768\FC000018.D) API-ES, Neg, SIM, Frag: Var
_____
7.248- C8 Acid
5000
4000
3000
2000
1000
0-
*MSD1 469, EIC=468.7:469.7 (CHEMSTORM 1799822\A704768\FC000018.D) API-ES, Neg, SIM, Frag: Var
25000 -
8.071 - C10 Surrogati
20000 -
15000
10000-
5000-
0-
Compound Amount (ng/mL)
R.T.
~8 Acid
150.14
10 Surrogat 512.40
7.248 8.071
Area
51147 197399
LL
min
Signal
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
i1
j PC00414
*** End of Report ***
Tue, 6. Jan. 2004
09:02:46 am
> / Page 1 of 1
COO4 2 3
Sample Name :L0001508-11 Sample Info:
Data file :C:\HPCHEM\l\DATA\Chemstor\11799876\A706816\FC000019 .D
1
8 Acid
0.00
10 Surrogat 332.05
7.243 8.064
1032 130509
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
! ______________________________________________ *** End of Report ***
[ PC00414
Tue, 6. Jan. 2004
09:04:45 am
038
Page 1 of 1
COQ4 3 4
Sample Name:STD 500 ppb Sample Info:
1
Data file :C:\HPCHEM\l\DATA\Chemstor\11799913\A709056\FC000020.D
Injection Date i Acq Operator
Instrument Dilution
Acq. Method Analysis Method Last Changed
1/5/04 jmiller PC00414 1
9:58:46 PM
Seq Line Vial N o . Inj. No. Inj. Voi.
: : : :
FC8-10.M
C:\HPCHEM\1\METHODS\010504A.M
1/6/04
08:52:48 am
20 4 1
5 pi
LC/MS analysis of perfluorooctanoic acid.
*MSD1 369, EIC=368.7:369.7 (CHEMSTORM1799913\A709056\FC000020.D) API-ES, Neg, SIM, Frag: Var
20000
7.238 - C8 Acid
17500
15000
12500
10000-
7500 r 5000
2500-I
0
*MSD1 469, EIC=468.7:469.7 (CHEMSTORM 1799913\A709056\FC000020.D) API-ES, Neg, SIM, Frag: Var
25000 -I
8.062 - C10 Surrogate,
20000 15000-
10000-
5000-
Compound Amount (ng/mL)
R.T.
ia8 Acid
522.33
10 Surrogat 519.40
7.238 8.062
Area
163235 199995
Signal
MSD1 369, EIC=36 8 .7 :369.7 MSD1 469, EIC=468.7:469.7
t PC00414
*** End of Report ***
u039
Tue, 6. Jan. 2004
09:05:10 am
Page 1 of 1
000425
Sample Namesolvent blank Sample Info :
Data file :C:\HPCHEM\l\DATA\Chemstor\11799950\A711296\FC000021.D
Injection Date Acq Operator Instrument Dilution
1/5/04 jmi H e r PC00414 1
10:13:44 PM
Seq Line Vial N o . Inj. No. Inj. Vol.
: : : :
Acq. Method Analysis Method r~ Last Changed
FC8-10.M
C:\HPCHEM\1\METHODS\010504A.M
1/6/04
08:52:48 am
LC/MS analysis of perfluorooctanoic acid.
1
21 92
1 5 pi
''8 Acid
0.00
`10 Surrogat 0.00
0.000 0.000
0 0
MSD1 369, EIC=368.7 :369.7 MSD1 469, EIC=468.7:469.7
PC00414
*** End of Report ***
Tue, 6. Jan. 2004
u 0 40
09:05:38 am
Page 1 of 1
000426
Sample Name :L0001508-13 Sample Info:
Data file :C :\HPCHEM\l\DATA\Chemstor\11799985\A713536\FC000022.D
Injection Date Acq Operator Instrument Dilution
1/5/04 jmiller PC00414 1
10:28:46 PM
Seq Line Vial N o . Inj. No. Inj. Vol.
: : : :
Acq. Method Analysis Method Last Changed
FC8-10.M
C:\HPCHEM\1\METHODS\010504A.M
1/6/04
08:52:48 am
LC/MS analysis of perfluorooctanoic acid.
1
22 21
1 5 pi
--8 Acid
0.00
10 Surrogat 538.27
!
7.234 8.057
4731 206991
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
*** End of Report ***
PC00414
Tue, 6. Jan. 2004
09:08:34 am
0 0 41
Page 1 of 1
C0 0 4 2 7
Sample Name :L0001508-14 Sample Info:
Data file :C :\HPCHEM\l\DATA\Chemstor\11800039\A715840\FCOOO023.D
Injection Date Acq Operator Instrument M Dilution
Acq. Method Analysis Method Last Changed
1/5/04 jmiller PC00414 1
10:43:43 PM
Seq Line Vial No. Inj. No. Inj. Vol.
: : : :
FC8-10.M
C :\HPCHEMX1\METHODS\010504A.M
1/6/04
08:52:48 am
LC/MS analysis of perfluorooctanoic acid.
1
23 22
1 5 pi
--8 Acid
0.00
10 Surrogat 351.91
0.000 8.068
0 137876
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7 :469.7
!" PC00414
*** End of Report ***
U42
Tue, 6. Jan. 2004
09:08:58 am
Page 1 of 1
GOO4 2 8
Sample Name:L0001508-16
I Sample Info:
Data file :C :\HPCHEM\l\DATA\Chemstor\11800075\A718016\FC000024.D
1
Injection Date Acq Operator Instrument ^ Dilution
1/5/04 jmiller PC00414 1
10:58:44 PM
Seq Line Vial No. Inj. No. Inj. Voi.
: : : :
24 23
1 5 pi
Acq. Method Analysis Method Last Changed
FC8-10 .M
C:\HPCHEM\1\METHODS\010504A.M
1/6/04
08:52:48 am
LC/MS analysis of perfluorooctanoic acid.
*MSD1 369, EIC=368.7:369.7 (CHEMSTORM1800075\A718016\FC000024.D) API-ES, Neg, SIM, Frag: Var
3000
7.236- C8 Acid
2500-
2000
1500-
1000-
500-
8 *MSD1 469, EIC=468.7:469.7 (CHEMSTORM 1800075\A718016\FC000024.D) API-ES, Neg, SIM, Frag: Var
8.058- C10 Surrogate
min
20000
15000-
10000
5000
0-
Compound Amount (ng/mL)
R.T.
C8 Acid
68.95
10 Surrogat 499.80
7.236 8.058
Area
26697 192725
Signal
MSD1 369, EIC=3 68.7 :369.7 MSD1 469, EIC=468.7 :469.7
PC00414
*** End of Report ***
T u e , 6. J a n . 2004
09:10:24 am
0 0 43
Page 1 of 1
C004P9
Sample Kfame:L0001508-17 Sample Info:
Data file :C:\HPCHEM\l\DATA\Chemstor\11800112\A720256\FC000025.D
Infection Date Acq Operator Instrument Dilution
1/5/04 jmiller PC00414 1
11:13:44 PM
Seq Line Vial No. Inj. No. Inj. Voi.
1
25 24
1 5 pi
?8 Acid
0.00
:10 Surrogat 335.28
0.000 8.058
0 131706
MSD1 369, EIC=368.7 :369.7 MSD1 469, EIC=468.7 :469.7
PC00414
*** End of Report ***
0044
Tue, 6. Jan. 2004
09:10:53 am
Page 1 of 1
000430
Sample Name:L0001508-19 Sample Info:
Data file :C :\HPCHEM\l\DATA\Chemstor\11800165\A722432\FC000026.D
1
~f!8 Acid
0.00
:10 Surrogat 511.43
0.000 8.068
0 197040
MSD1 369, EIC=368.7 :369.7 MSDl 469, EIC=468.7:469.7
PC00414
*** End of Report ***
Tue, 6. Jan. 2004
09:11:41 am
U45
Page 1 of 1
000433.
Sample Name:L0001508-20 Sample Info:
Data file :C:\HPCHEM\l\DATA\Chemstor\11800201\A724736\FC000027.D
Injection Date Acq Operator Instrument Dilution
1/5/04 jmiller PC00414 1
11:43:44 PM
Seq Line Vial No. Inj. No. Inj. Vol.
: : : :
Acq. Method Analysis Method Last Changed
FC8-10.M
C:\HPCHEM\1\METHODS\010504A.M
1/6/04
08:52:48 am
LC/MS analysis of perfluorooctanoic acid.
1
27 26
1 5 pi
,,Z8 Acid
0.00
L0 Surrogat 346.67
0.000 8.063
0 135931
MSD1 369, EIC=3 68.7:3 69.7 MSDl 469, EIC=468.7:469.7
PC00414
*** End of Report ***
Tue, 6. Jan. 2004
09:12:08 am
uU46
Page 1 of 1
000432
Sample Name:STD 500 ppb "* Sample Info :
1
Data file :C :\HPCHEM\l\DATA\Chemstor\11800237\A726848\FC000028.D
Injection Date Acq Operator Instrument ^ Dilution
1/5/04 jmiller PC00414 1
11:58:47 PM
Seq Line Vial No. Inj. No. Inj. Voi.
: : : :
28 4 1
5 pi
Acq. Method Analysis Method ... Last Changed
FC8-10.M
C:\HPCHEM\1\METHODS\010504A.M
1/6/04
08:52:48 am
LC/MS analysis of perfluorooctanoic acid.
MSD1 369, EIC=368.7:369.7 (CHEMSTORY11800237\A726848\FC000028.D) API-ES, Neg, SIM, Frag: Var
20000
7.230 - C8 Add
17500
15000
12500
10000
7500-|
5000
2500
0--
11 1 i 111i 1 11i 1 246
*MSD1 469, EIC=468.7:469.7 (CHEMSTORM1800237\A726848\FC000028.D)
i
1 1r ' 11
8 API-ES, Neg, SIM, Frag: Var
r min
25000 J
8.056- C10 Surrogate
20000 -
15000
10000-
5000
._
..
...
A .._____
J-----,----- 1------- 1------- ------- 1------- ------- >------- 1------- 1------- 1------- 1------- 1------- 1------- 1------- 1------- 1------- 1------- 1------- 1------- r
min
Compound Amount (ng/mL)
R.T.
Area
Signal
03 Acid
520.69
10 Surrogat 524.76
7.230 8.056
162742 201984
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
?C00414
*** End of Report ***
Tue, 6. Jan. 2004
09:12:37 am
U47
Page 1 of 1
000433
Sample Name :solvent blank Sample Info:
Data file :C:\HPCHEM\l\DATA\Chemstor\11800291\A729152\FC000029.D
1
~8 Acid
0.00
10 Surrogat 0.00
0.000 0.000
0 0
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
PC00414
*** End of Report ***
Tue, 6. Jan. 2004
09:14:05 am
U048
Page 1 of 1
C00434
Sample Name:STD 50 ppb -.V* Sample Info:
1
Data file :C :\HPCHEM\l\DATA\Chemstor\11800326\A731392\FC000030.D
Injection Date Acq Operator Instrument v . Dilution
1/6/04 jmiller PC00414 1
12:28:44 AM
Seq Line Vial No. Inj. No. Inj. Voi.
: : : :
30 1 1
5 pi
Acq. Method Analysis Method Last Changed
FC8-10.M
C:\HPCHEM\1\METHODS\010504A.M
1/6/04
08:52:48 am
LC/MS analysis of perfluorooctanoic acid.
*'MSD1 369, EIC=368.7:369.7 (CHEMSTOR\11800326\A731392\FC000030.D) API-ES, Neg, SIM, Frag: Var
1800
7.242- C8 Acid
W..1- 1600 -j
1400
1200
1000 /
800 /
600 /
400
200 - -
... **MSD1 469, EIC=468.7:469.7 (CHEMSTOR\11800326\A731392\FC000030.D) API-ES, Neg, SIM, Frag: Var
2250/
8.064- C10 Surrogata
2000 /
1750 /
1500 /
1250 /
1000/
750/
500/
250/ -
Compound Amount (ng/mL)
R.T.
C8 Acid
36.01
10 Surrogat 35.92
7.242 8.064
Area
16775 20680
Signal
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
-
*** End of Report ***
r PC00414
Tue, 6. Jan. 2004
08:55:19 am
0049
Page 1 of 1
G0Q435
Sample Name:STD 100 ppb Sample Info:
1
Data file :C:\HPCHEM\l\DATA\Chemstor\11800363\A733632\FC000031.D
Injection Date
Acq Operator
Instrument
Dilution r"
i
1 Acq. Method
Analysis Method Last Changed
1/6/04 jmiller PC00414 1
12:43:46 AM
Seq Line Vial No. Inj. No. Inj. Voi.
: : : :
FC8-10.M
C:\HPCHEM\1\METHODS\010504A.M
1/6/04
08:52:48 am
31 2 1
5 pi
LC/MS analysis of perfluorooctanoic acid.
r *MSD1 369, EIC=368.7:369.7 (CHEMSTORM1800363\A733632\FC000031 .D) API-ES, Neg, SIM, Frag: Var 1 7.234- C8 Acic
3000 ~
2500 ^
2000 -j
1500-
1000-
500-
-
'^ T T 11 ' 1 '5 1 1 1
246 *MSD1 469, EIC=468.7:469.7 (CHEMSTORM 1800363\A733632\FC000031.D)
J _____l_
-
1 iii| 8 min
API-ES, Neg, SIM, Frag: Var
4000 j
8.058- C10 Surrogate
3500 -j
3000 j
2500 j
2000 j
1500 -j
[ 1000^
-
500-
o-
J. l -,
1 r 1 '--- 1 r
8 min
I -CD -CM
Compound Amount (ng/mL)
R.T.
Area
Signal
,.08 Acid
86.92
10 Surrogat 85.74
7.234 8.058
32107 39157
MSDl 369, EIC= 368.7:369.7 MSDl 469 , E IC = 468.7:469.7
PC00414
*** End of Report ***
Tue, 6. Jan. 2004
09:14:30 am
0050
Page 1 of 1
COO4 3 6
Sample Name:STD 250 ppb Sample Info:
1
Data file :C:\HPCHEM\l\DATA\Chemstor\11800400\A735808\FC000032.D
Injection Date Acq Operator Instrument ... Dilution
1/6/04 jmiller PC00414 1
12:58:43 AM
Seq Line Vial No. Inj. No. Inj. Voi.
: : : :
32 3 1
5 pi
Acg. Method Analysis Method . Last Changed
FC8-10.M
C:\HPCHEM\1\METHODS\010504A.M
1/6/04
08:52:48 am
LC/MS analysis of perfluorooctanoic acid.
'MSD1 369, EIC=368.7:369.7 (CHEMSTORM1800400\A735808\FC000032.D) API-ES, Neg, SIM, Frag: Var
_________ __ 8000
_ __
7.227 - C8 Acid
7000
6000 -j
5000
4000
3000
2000
1000
0
*MSD1 469, EIC=468.7:469.7 (CHEMSTORM 1800400\A735808\FC000032.D) API-ES, Neg, SIM, Frag: Var
10000-
8.056- C10 Surrogate
8000-
6000-
4000-
2000-
Compound Amount (ng/mL)
R.T.
-78 Acid
257.77
:10 Surrogat 258.61
7.227 8.056
Area
83560 103270
Signal
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
i| PC00414
*** End of Report ***
U5 I
Tue, 6. Jan. 2004
09:15:07 am
Page 1 of 1
6 0 0 4 .3 7
Sample Name:STD 500 ppb Sample Info :
1
Data file :C:\HPCHEM\l\DATA\Chemstor\11800454\A737984\FC000033.D
Injection Date Acq Operator Instrument -- Dilution
1/6/04 jmiller PC00414 1
1:13:42 AM
Seq Line Vial No. Inj. No. Inj. Voi.
: : : :
33 4 1
5 p.1
Acq. Method Analysis Method Last Changed
FC8-10.M
C :\HPCHEM\1\METHODS\010504A.M
1/6/04
08:52:48 am
LC/MS analysis of perfluorooctanoic acid.
r ~ *MSD1 369, EIC=368.7:369.7 (CHEMSTORM1800454\A737984\FC000033.D) API-ES, Neg, SIM, Frag: Var
! 16000
1r. 1400012000 -j
----- - ___ _______
7.238 - C8 Acid -- ------ - ..................... - ------
10000-
8000 -
n 6000 -j
1 4000 -j
2000 ^
-CO - Tfr -CM
o*MSD1 469, EIC=468.7:469.7 (CHEMSTORM 1800454\A737984\FC000033.D)
l1
1r 1111 8 min
API-ES, Neg, SIM, Frag: Var
20000 /
j 17500 /
8.068- C10 Surrogate
15000 /
12500 -j
10000/
7500/
( 5000/
2500/
: 0
J\
' 11| I 1I | I I 1| I 11| ' 11I
2 4 6 8 min
Compound Amount (ng/mL)
R.T.
Area
Signal
'18 Acid
533.94
:10 Surrogat 536.36
7.238 8.068
166731 206284
MSD1 369 , EIC= 368.7:369.7 MSD1 469 , EIC= 468.7:469.7
PC00414
*** End of Report ***
u Ub 2
Tue, 6. Jan. 2004
09:15:27 am
Page 1 of 1
Sample Name:STD 750 ppb Sample Info:
1
Data file :C:\HPCHEM\l\DATA\Chemstor\11800491\A740288\FC000034.D
Injection Date Acq Operator Instrument Dilution
1/6/04 jmiller PC00414 1
1:28:42 AM
Seq Line Vial No. Inj. No. Inj. Vol.
: : : :
34 5 1
5 pi
Acq. Method Analysis Method Last Changed
FC8-10 .M
C :\HPCHEM\1\METHODS\010504A .M
1/6/04
08:52:48 am
LC/MS analysis of perfluorooctanoic acid.
*MSD1 369, EIC=368.7:369.7 (CHEMSTORM1800491 \A740288\FC000034.D) API-ES, Neg, SIM, Frag: Var
50000-
...... ..........
7.234 - C8 Acid,
40000 30000 20000 -
10000-
Rejected Chromatogram
R o rm L]rw'\
K . f ni/<( /A
ActionTaken:
'
O Re-inject Re-extract
FSieleeCN3og.o,,.n..#..,~(,,,n r^
Initialsfngto*
8 *MSD1 469, EIC=468.7:469.7 (CHEMSTORM1800491\A740288\FC000034.D) API-ES, Neg, SIM, Frag: Var
60000 -
8.057 - C10 Surrogate
50000 r ,, 40000 -
30000 -
20000 -
10000-
0- ------- ,--------- 1~
24
Compound Amount (ng/mL)
R.T.
r C8 Acid
1385.81
110 Surrogat 1371.45
7 .234 8 .057
---- j------- ,--6
------ !------- ,------- 1------- '------- f 8 min
Area
Signal
423279 516007
MSDl 369, EIC=368.7: 369.7 MSDl 469, EIC=468.7:469.7
*.*
--
PC00414
* End of Report ***
U053
Tue, 6. Jan. 2004
09:16:08 am
Page 1 of 1
0 0 0 4 -9
Sample Name:STD 1000 ppb Sample Info :
t
Data file :C:\HPCHEM\l\DATA\Chemstor\11800528\A742528\FC000035.D
1
Injection Date Acq Operator Instrument Dilution
1/6/04 jmiller PC00414 1
1:43:44 AM
Seq Line Vial No. Inj. No. Inj. Voi.
: : : :
35 6 1
5 pi
Acq. Method Analysis Method ~~ Last Changed
FC8-10.M
C :\HPCHEMX1\METH0DS\010504A.M
1/6/04
08:52:48 am
LiC/MS analysis of perfluorooctanoic acid.
*MSD1 369, EIC=368.7:369.7 (CHEMSTORVI1800528\A742528\FC000035.D) API-ES, Neg, SIM, Frag: Var
30000
7.232- C8AciO
25000 -
20000
15000 -
10000 -
5000-
8 *MSD1 469, EIC=468.7:469.7 (CHEMSTOR',11800528\A742528\FC000035.D) API-ES, Neg, SIM, Frag: Var
8.057- C10 Surrogate
35000 -
min
30000 H
25000 -
20000 -
15000-
10000 -
5000-
0-
11
Compound Amount (ng/mL)
R.T.
-- 8 Acid
1021.81
10 Surrogai 1016.03
7.232 8.057
Area
313658 384185
Signal
MSD1 369, EIC=368.7 :369.7 MSD1 469, EIC=468.7:469.7
t
1
PC00414
*** End of Report ***
Tue, 6. Jan. 2004
US4
09:16:48 am
Page 1 of 1
000440
Sample Name:STD 1500 ppb Sample Info :
1
Data file :C:\HPCHEM\l\DATA\Chemstor\11800582\A744704\FC000036.D
Injection Date Acq Operator Instrument Dilution
Acq. Method Analysis Method Last Changed
1/6/04 jmiller PC00414 1
1:58:44 AM
Seq Line Vial No. Inj. No. Inj. Voi.
: : :
FC8-10.M
C :\HPCHEM\1\METHODS\010 504A .M
1/6/04
08:52:48 am
36 7 1
5 ul
LC/MS analysis of perfluorooctanoic acid.
*MSD1 369, EIC=368.7:369.7 (CHEMSTORM1800582\A744704\FC000036.D) API-ES, Neg, SIM, Frag: Var 7.229 - C8 Acid
50000 -
1 40000 -
30000 -
20000 -
10000-
1
.....
..
U A_ 1
' ' " 1` ' ' 1' ' ' 1' ' ' Ti i i 1
2 4 6 8 mi n
j """ *MSD1 469, EIC=468.7:469.7 (CHEMSTORM 1800582\A744704\FC000036.D) API-ES, Neg, SIM, Frag: Var
' 70000 ^
8.053 - C10 Surrogate
60000 -j f~ f
50000
40000 ^
30000^
20000 -j
100001
' 1' 1' 2
Compound Amount (ng/mL)
.78 Acid
1489.92
10 Surrogat 1485.15
111 4
R.T.
7.229 8.053
' 11
Area 454633 558177
. _L . 1 1 1 1r 1'
68
1r
min
Signal
MSD1 369, EIC=368.7:369.7 MSD1 469, EIC=468.7:469.7
f PC00414
*** End of Report ***
Tue, 6. Jan. 2004
09:17:08 am
u U55
Page 1 of 1
0004*1
3 0 5 8 R esearch Drive
S tate C ollege, PA 16801 RESEARCH
Phone: 814-272-1039 Fax: 814-231-1580
Login#. PPrroojjeecctt:Storage:
P10601080419
CompanyName: SubmittedBy:
DMuiPchoanetldDe.NAeumcooiunrs&Co, Inc.
LoginType: ImmediateReceiptofSamples
Started:
T
DateStart:------12/22/2003-------
DueDate: 01/05/2004
ReceivedDate: 12/20/2003
ReceivedBy: ROBB, SHAWN
SpreadSample:
Label:
ProjectTitle/Type: AnalysisofPFOAinOVSTubes/ ROUTINE
LEoxgyignenNoSteDs/:PI: MILLER, JAMES
ConformNotes:
ontorm ample: True
ConformCOC:
True
CCoonnffoorrmmSRaemqupeles:t: TTrruuee
Package PK0002109
Carton
Packages / Containers
Mail Date / Condition
Shipper / ID
12/20/2003 11:30:09AM Package & Contents Uncompromised
FEDEX 8363912984670200
Temp. Control/Temp. None
Direction / Handled By
RECEIVED ROBB, SHAWN
Container #
C0024018 C0024019 C0024020 C0024021 C0024022 C0024023 C0024024 C0024025 C0024026 C0024027 C0024028 C0024029 C0024030 C0024031 C0024032 C0024033 C0024034 C0024035 C0024036 C0024037 C0024038 C0024039 C0024040 C0024041
Gross Weight
2.0 g 2.0 g 2.0 g 2.0 g 2.0 g 2.0 g 2.0 g 2.0 g 2.0 g 2.0 g 2.0 g 2.0 g 2.0 g 2.0 g 2.0 g 2.0 g 2.0 g 2.0 g 2.0 g 2.0 g 2.0 g 2.0 g 2.0 g 2.0 g
pH
Container Type
Other Other Other Other Other Other Other Other Other Other Other Other Other Other Other Other Other Other Other Other Other Other Other Other
Miscellaneous Item Key
None
Description
Preservative NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE
ICOC
Mfg. Lot
Mfg. ID
1/6/2004 Login.rpt
Report Version: Dec 22 2003 10:44AM Page 1 of 4
Instance: n
R0078484
R0078484
Login
Sample ID L0001508-0001 L0001508-0002 L0001508-0003 L0001508-0004 L0001508-0005 L0001508-0006 L0001508-0007 L0001508-0008 L0001508-0009 L0001508-0010 L0001508-0011 unoCHSOi? orno
L0001508-0013 LOO01508-0014 LOO01508-0015 L0001508-0016 LOO01508-0017 LOO01508-0018 L0001508-0019 LOO01508-0020 L0001508-0021 L0001508-0022 L0001508-0023 L0001508-0024
Matrix GAS GAS GAS GAS GAS GAS GAS GAS GAS GAS GAS OA5r GAS GAS GAS GAS GAS GAS GAS GAS GAS GAS GAS GAS
Fraction OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes nWQ TnhoP
OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes OVS Tubes
Samples
Sample WWK-A-AMSFBLK-E9 A WWK-A-AMSFBLK-E9 B WWK-A-AMSFBLK-E9 C WWK-A-AMS1-E9 A WWK-A-AMS1-E9 B WWK-A-AMS 1-E9 C WWK-A-AMS2-E9 A WWK-A-AMS2-E9 B WWK-A-AMS2-E9 C WWK-A-AMS3-E9 A WWK-A-AMS3-E9 B \AAA/kr A.AMS9.PQ P
WWK-A-AMS4-E9 A WWK-A-AMS4-E9 B WWK-A-AMS4-E9 C WWK-A-AMS5-E9 A WWK-A-AMS5-E9 B WWK-A-AMS5-E9 C WWK-A-AMS6-E9 A WWK-A-AMS6-E9 B WWK-A-AMS6-E9 C CONTROL A CONTROL B CONTROL C
r
Date Sampled Date Received Date Due
12/19/2003 12/20/2003
01/05/2004
12/19/2003 12/20/2003
01/05/2004
12/19/2003 12/20/2003
01/05/2004
12/19/2003 12/20/2003
01/05/2004
12/19/2003 12/20/2003
01/05/2004
12/19/2003 12/20/2003
01/05/2004
12/19/2003 12/20/2003
01/05/2004
12/19/2003 12/20/2003
01/05/2004
12/19/2003 12/20/2003
01/05/2004
12/19/2003 12/20/2003
01/05/2004
12/19/2003 12/20/2003
01/05/2004
--12/20/2003 - Q1/05/2QQ4
12/19/2003 12/20/2003
01/05/2004
12/19/2003 12/20/2003
01/05/2004
12/19/2003 12/20/2003 01/05/2004
12/19/2003 12/20/2003 01/05/2004
12/19/2003 12/20/2003
01/05/2004
12/19/2003 12/20/2003
01/05/2004
12/19/2003 12/20/2003
01/05/2004
12/19/2003 12/20/2003
01/05/2004
12/19/2003 12/20/2003
01/05/2004
12/20/2003
01/05/2004
12/20/2003
01/05/2004
12/20/2003
01/05/2004
(-PIT
1/6/2004 Login.rpt
UQ57
Report Version: Dec 22 2003 10:44AM Page 2 of 4
Instance:
V( f j ,`J .'I.*U7
R0078484
R0078484
P L 0001508-0001
^ Container
C0024018/ Other /NONE
r
l L0001508-0002
f4,^ Container
C0024019/Other/NONE
L0001508-0003
Container
C0024020 / Other / NONE------------ - "' '
L0001508-0004
Container
C0024021 / Other/NONE
L0001508-0005
Container
r C0024022 / Other / NONE
_L0001508-0006
Container
C0024023/Other/NONE
L0001508-0007
Container
--> C0024024 / Other / NONE
L0001508-0008
Container
C0024025 / Other / NONE
-4.0001508-0009
Container
C0024026/Other/NONE
L0001508-0010
Container
C0024027/ Other /NONE
L0001508-0011
Container
C0024028 / Other / NONE
i.0 0 0 1508-0012
Container
C0024029 / Other / NONE
I ,, 1/6/2004 | Login.rpt
Bottles
Method
Method
Method
- --------------------------------------------------
Method
Method
Method
Method
Method
Method
Method
Method
Method
u U8
Report Version: Dec 22 2003 10:44AM Page 3 of 4
Instance:
R0078484
0 C O A 4 4 R0078484
i L0001508-0013
, Container
p C0024030 / Other / NONE
Method
L0001508-0014
Ii-- Container
1 C0024031 / Other / NONE
Method
L0001508-0015
Container
C0024032 / Other / NONE
Method
L0001508-0016--------------------------------------------------------
Container
C0024033 / Other / NONE
Method
L0001508-0017
Container
C0024034/Other/NONE
Method
^ ` L0001508-0018
Container
, ,, C0024035 / Other / NON E
Method
L0001508-0019
Container
C0024036/Other/NONE
Method
_L0001508-0020
Container
C0024037 / Other / NONE
Method
L0001508-0021
Container
-- C0024038 / Other / NONE
Method
L0001508-0022
Container
C0024039 / Other / NONE
Method
L0001508-0023
Container
C0024040/ Other /NONE
Method
L0001508-0024
Container
C0024041 / Other / NONE
Method
u0 b9
1/6/2004 Login.rpt
Report Version: Dec 22 2003 10:44AM Page 4 of 4
Instance:
R0078484
R0078484
F
0 1
C om p o site Num ber of C o n tain ers
000446
RESEARCH
PROJECT INFORMATION Client (name & address):
CHAIN OF CUSTODY/ANALYSIS REQUEST FORM
Exygen Research Sample Receiving * 3 1 1 7 Research Drive State College, PA 16801, USA T: 814.231.8032 F: 814.231.1580 exygenresearch.com
P a g e _____ o f ______
ANALYSES REQUESTED
rv ,
Project Manager (Name & E-mail Address): fA Au c iu a
Phone: ( 3 o5T )
iO - \ -3 K
Project Name: /V \C
p's vw^ k A ^ \ f o a
Sampler: ^ l r , X j 1^JfVt
Quotation # :
Please fill out this form com ple te ly to ensure correct analysis and proper handling of your samples.
SAMPLE ANALYSIS
ExyLIMS# Client Sample Identification
Collection Collection
Date
T im e
Xf0I O
'w v o U .-ft-fV n s .f < m . &> i a \ i ) o 3 6 3 -1 5 * DkH) X 06H 4
W FT * ole5 1
ft-Am S t
>c __ 5 7 O ^ e o ><;
LAB USE ONLY __ ________________ !----- :---
CHAIN OF CUSTODY
Relinquished by ....... *
A
Date
Time 4 5 0
Specify M atrix Comments . fVsC
\ fk r
) \ frrr \ \ Iw
OTHER INFORMATION
Svitivi: 1
$O SO \O
o :z>
\Ju ~=F
PROJECT REQUIREMENTS Results Deadline: Laboratory Report Options:
I ISampleresultsonly EH Addcasenarrative EH Addqualitycontrolsummary EH Addcalibrationsummary I IAddrawdata EH Other
f! l.__
* .1
-V.3-0^
000447
Sampler(s): LK, REK
DuPont Washington Works Air Sampling Program
FedEx Airbill #:
Event Number
Event 5
Pump#
669842 669908 669901 669890 669796 669865 Hours
0 1 2 3 4
Station # AMS-1 AMS-2 AMS-3 AMS-4 AMS-5 AMS-6
Minutes 0 60 120 180 240
Exygen ID
Calibration (pre) Date Start Time Date Stop Time Calibration (post) Total Minutes Total Volume
WWK-A-AMS1-E9 1004 18-Dec 0619 19-Dec 0641
0.9642
1460
WWK-A-AMS2-E9 1.008 18-Dec 0624 19-Dec 0644
0.9671
1460
WWK-A-AMS3-E9 1.005 18-Dec 0625 19-Dec 0644
0.9030
1459
WWK-A-AMS4-E9 1.005 18-Dec 0632 19-Dec 0651
0.9377
1458
WWK-A-AMS5-E9 1.006 18-Dec 0608 19-Dec 0629
0.9837
1461
WWK-A-AMS6-E9 1.007 18-Dec 0648 19-Dec 0700
0.9618
1451
Hours
Minutes Hours Minutes Hours Minutes Hours
Minutes
5
300 10 600 15 900
20
1200
6
360 11 660 16 960
21
1260
7
420 12 720 17 1020
22
1320
8
480 13 780 18 1080
23
1380
9
540 14 840 19 1140
24
1440
C
SAFER operational:
yes yesorno
Comments: Total minutescolumnisthereadingfromthemonitorcounter.
12/19/2003
Page 1 of 2
airdataevent9
Sample "Condition Upon Receipt" Form
PrQCCCOl rr
_______
Exvsen Studv =
^
Date & Time Received
Condition of Samles
Temoorary Storage Location
Initials (SOate
Wavbill#
/fy A V t//* Sc~i
t L/C / / ///,,
PC**. 2 Jt. ]
(2 / 4 F? //7 o
1
-
Comments:
-A /C r vFi'v
a.Jz^_
0 062
Joe
.COO*'"3
Express USAMrMU 3 3 f c 3 H 2 W t ?
LuO^rvtrv V W k t - l i ____rwSt V
Company - f ^ v W 0A6
A d d re ss 'S-V ^ 4 .
SpytXl
l \ ttCht t
. Dept/RoofSue/Roofn
City Q . V v K t v V '" V < A __________ - ^ t t e V v `V Z IE .- M m l ;
2 YourInternalBillingReference \ 3 To
S W n WRNeacmipeient's
^ '' i :? '~~V~ )0 Q D 3> ?
SRI-ftSQ
, u.' ''
Company
^ Af, o \ _ q ,
A ddress
-*
A
To "HOLD" at FedEx location, prim FedExaddress.
?it<^>rcU
" :f s
if'CC
We cannot deliverto PO. boxes or Pi. ZIP codes.
A ddress
OeptyFloofiuite/Ftoom
City VS~V .Q&.V { P ,^
asta
State \
fi4L
zip Hf'KO )
L
6 iv'i ' O o 0
Recipient's Copy
4 a Express Package Service
Packagesupto 150lbs.
FedEx Priority Overnight
I
i
FedEx
Standard
O
v
e
r
n
i
g
h
t r i F e d EDelivery commitment
rosy
x fi
be
rs
later in
t Ove
some areas.
rnight
Next businessmorning
1-- 1 Nextbustness afternoon
Earliestnextbusiness morning delivery to select locations
\ I FedEx2Day
j | FedEx Express Saver
Second business day
Third business day
I---------- FedEx Envelope rate not available. Minimum charge: One-pound rata ---------------
4b Express Freight Service
[ l FedExtOay Freight*
1-- ' Next busmess oay
5 \ FedEx2Qay Freight
*-- I Second business day
Packagesover 150lbs.
Delivery commitment may be later in some areas.
\ \ FedEx 3Day Freight
'-- I Third business oay
* Call for Confirmation;
5 Packaging
n FedEx Envelope*
.' ,
i~lFedE xPak*
Includes FedEx Small Pak. FedEx Large Pak, and FedEx Sturdy Pak
y *Dec^edvalueless
O ther
:ial Handling
lYDdnoy
R in clu d e FedEx address in S ection 3.
rI_--_ ji Ha tOFLeDd EWxeLeokcdaatiyo n
(I--__ iJ Ha tOFLeDd ESxatLuordc aatyio n
Not availableTex
Available onlyfor
FedEx First Overnight
FedEx PriontyOvernight
and FedEx2Day to
D oes th is sh ip m e n t c o n ta in da ng ero us goods?
select locations
One box m ustbe checked. ----------------
Yess per attached
QYes I Shipper's Declaration
Slipper's Declaration
not required
Dangerous Goods (including Dry Ice) cannot be shipped in FedEx packaging.
( l Dry Ice
I-- ! DryIfce, 9, UN 1845-
I I C argo A ircraft Only
7 Payment Biiito:
P I ObtainRecip.
`der _ Q Recipient jThird Party 1~1 CreditCard\ \ jC a s h / C h e c kI-------------------- EnterFedExA cct No. or C reditCard No. b e lo w .---------------- -- Acct No.
Total Packages
^Qur lability is limited lo i l fB unless ynii d o le re T g fie r v-iiue See back for lieta ils.
8 Releas
tatara Sign to authori devA
'FAQA\dl
Byiyhing yfiu authorize us to deliver this shipmentw ithout obtaining a signature ra g re e to indemnify and hold us harmless from any resuming claims.
Q uestions? V isit our Web site at fedex.com
oBr8cv.aDlal t1e.1800/00.1G*oPa.Frte#d1E57x6*18200.1496943-.3Z030319F.edExPfllNTED!NU.S.A. WCSI02 *
NI VO
o o
II
WNoasChhinagrgtoenSWhipoprkesr
W M IIIlliW
Ship To:
Exygen Research 3058 Research Drive State College, PA 16801 Attn: Shawn Robb or John Flaherty 814-272-1039
Date: 10/27/2003 NCS #: 38-200304715
Routing: FED EX ( SEE ABOVE ACCT) FH :. B.: c o l l e c t Date Shipped: B / L:
Phone Number:
Quantity
1
Product Code / Description
Box containing glass sample tubes for analysis
Weight
10
Units
lbs.
Freight Class: TUBES, GLASS, NOI. Originator: Crane, Alison A Cost Code: 7035-507483-862200 Purchase Order #: Value for Customs:
Dimensions: Ship From: Stores
Status:
Phone:4448
Hazardous Shipment? No O Yes
MSDS Sheets Required? No O Yes
Material Class: Corrosive Flammable
Shipping #:
Toxic
Other
64
Special Instructions: This N-C-S will cover 6 shipments beginning 10/30/03.
> > > Will deliver package to Stores with completed FEDEX Bill. CRG Account Number 2230-5551-6. Weekend samples will be delivered directly to FEDEX. < < < <
Comments:
u65
