Document 5kb2geaRYLbwVypB7ydEOk9xz
BIOACCUMULATION
TEST SUBSTANCE
Identity: NU-1E4t6h4y,ipEetrFfiOuSoAr,ooEcttPanOeSsAu,lfFo-n6a3m0i9d,e;ormaFXy-a1l2s.o b(1e- referred to as Octanesulfonamide, 1,1,2,2,3,3.4,4,5,5.6,6,7,7,8.8.8heptadecafluoro-N-ethyl-, CAS# 4151-502)
Remarks: Material is a white solid of uncharacterized purity.
METHOD
Methodiguideline followed: None Extraction and analysis procedures
wgievreen dfeovrissaemdplbiyn3goM.fthe
organisms.
Type: Environmental sampling of indigenous fish around a 3M
fluorochemical manufacturing facility.
GLP (YIN): No
Year: 1979
Remarks field: organisms from
tThheeTreeninsensoseinefoRrimvaetrinoneaorntsheammpalniunfgacptruorciendgurfaecsilotfy.the.
Four fish were caught and utiized as samples; Two channel catfish caught above Wheeler Dam, one white bass caught below and one white crappie caught above Wheeler Dam. Wheeler Dam is approximately 26 nautical mnoitlensodtoedwnisnttrheearmepforrotmhtohwe m3aMnyDemcialteusraPbloanvteeafnflduebnetldoiwscthhaerdgea.mItthweafsish were caught.
Adiltuetninpgp1mmlstoafnada1r0d0ofpFpMm-s3t4a2n2da(rNd-(EintFetOhSyEl aaclectoahotle)) wtoamsaprrkewpiatrhedetbhyyl acetate in a 10 mi volumetric flask.
Ootnheerwchhoalneneclhacnantefilshcawtfaisshdwisassechtoemdoagnednitzheedvatroicoruesaitnediovnieduaslamppalrets. wTehree homogenized to create individual samples.
lTahteerawlhiltineebbaeshsinhdadthae 6gi.l3l pclmatei.dm. adkiniknegr dupieac2o0r.e59s1amgpslaemtpalkeencojnusttaoifnfitnghe skin, filet, small part of the backbone, reproductive organs,partof the kidney, and rectum.
tTohcerwehaiteteacr1a6p.p6i8e4 hgardama sdianmkpelredcieonctoarienisnagmfpillete, tvaerkteenbrbaeeh,insdkitnheangidllbipllea.te
006086
All samples were homogenized in known volumes of DI water and divided into five aliquots each.
Samples were centrifuged, extracted with ethyl acetate, and analyzed by
GC for organic and inorganic fluoride.
RESULTS
EtFOSA Concentration
In Tennessee River Fish by GC
[ L cumpp e [ --S -- CLpmSm ) -- |
[WholeChannelTCatSfish [Whi Basscoresample
|--0.4-- 0 082]
[[WChhiatmeeCrlaCpaptifescohroelslasmple |14008 6 ]|
[[CChhaannneellCCaattifsshhPvaerrs 2 1. .3 15 7] ]
[C[hanCnelhCasahFMumasrcTMlee lCa1tNO3f.8s5h]
== CGoonnssiiastteeddooffmguasstcrloei,ntseksitni,nablordac,h,borneep;raondduCcaetisyasgteem, and fa.
Upon completion of GC analysis, there was concern that the values were
not definitive. Additional analysis was then done using Capillary Gas Chromatography with Electron Capture and a Microwave Sustained Helium Plasma Detector. Results from only the white bass core sample
and the catfish gill sample were described in this report.
Qualitative analysisofthe fish extracts using Capillary Gas
Chromatography with electron capture failed to quantitate EtFOSA.
However, the white bass core sample showed a peak with a retention time
similarto EtFOSA. This peak area was less than the EtFOSA standard,
but greater than
as a "very small
that seen
amount".
in the channel catfish gills, which was described
Analysis by a Microwave Sustained Helium
Plasma Detector found no fluorocarbon peaks. The results obtained by
the microwave plasma detector on spiked samples indicated that N-
EtFOSA, if present, could have been detected from its fluorine content at
0.1 ppm in the ethyl acetate extracts.
Remarks: The original report (5/22/79) referenced a sample for FM-3923. It was brought up after the report was generated that FM-3923 and FM3422 are both the same coumpound (N-EtFOSE alcohol). Analytical was conducted to verify its identity and it was found to be N-EtFOSA (F-6309).
The attached report ("AR No. 7238 -- Determination of Fluorinated
006087
Alcohols in the sample
FliasbhelEexdtraasctFsM",-3190/2233/i7s9F)-6st3il0l9r.efeTrhsitso
FM-3923 when report also has
in
fact
icnocnotnesnitstaetn0c.i1esp.pTmhleevleals.t pHaorwaegvrearp,hainrdeivciaetweosftthheeabpirliotcyetdoudreeteucstedfluorine
indicates a detection limit of 0.5 ppm.
Tfihshe hfiorsmtorgeepnoratte(6b/y22g/a7s9)cdhersocmraitboegsraanpahlyys(iGsCo)fweitthhylealeccettraotneceaxpttraucrtes of
deexttercatcitosnt.haTthheavaenaGlyCsisrestehnotwiosntthiemepsreisdeenntciecaolftmoabtoetrhiaNls-MinefFisOhStEisasluceohol
aMnedFNO-SEEtFalOcSoEhoallcaonhdolNa-nEdtFtoOSNE-EatlFcoOhSoAl.stTahnedaGrdCs rweetreenttihone tsiammees o(fnoNt-
trheesoplrveeds)enbcyetohfefmleutorhoocdheumsiecdalisn itnhethfeirfsitsrhepeoxrttr.actTsh,ebufitrsetlreecptorrotnicnadpitcuartees
detection is not specific the first report were not
for fluorochemicals. Thus a specific identification of
the results reported fluorochemicals
in
d1e8tercotwa,bl0e.4b0ysGhCou.ld(Rbeepocrhtan1gaeldsotoha4.s13e,rraornsdiinnctohleu2mAn 4roowf,T0a.b0l0e4 1s.hIonultdhe
be changed to 0.06.)
TIthiencsleucdeosnda rdeepsocrrtip(t1i2o/n28o/f7G9)Csahnoawlsysaesmiosfinettheyrlpraecteattaiotne ienxttrhaectfisorsft rtewpoorto.f
the samples described in
described in report 1 samples report 2 used electron capture
1B and 3A. The work detection and references
a
trhepeofrltuoursiinnegamnidcrsuolwfaurvemosdues.taiInnefdluhoerliinuemmpoldaes,maMSdeHtPecDtimoent(hMoSdHiPsDs)peciinfic
for fluorine. The acetate extracts.
MSHPD results show no fiuorochemicals The results are interpreted as indicating
in the ethyl that F-63090
and N-EtFOSE atless than 0.1
aplpcmo.holIn(tFhMe-3fi4r2st2)reaporret,prNe-sEenttFOinStAhe(Fe-t6h3yl09a)ceatnadteN-extracts
tMoebFeOpSrEeseanlctorheoslp(ecFtMi-ve3l9y2a5t/)0.N8-2EatnFdOS3.E31alpcophmoli(n FsMa-m3p4l2e2)1Bhaadndapapte1a.r4e8d
and first
0.80 ppm in sample report appear not to
3A. Thus, have been
the GC-able compounds seen in the fluorochemicals and thus could not
have been N-MeFOSE alcohol, N-EtFOSE alcohol or N-EtFOSA.
Tinhoergfairnsitcrfelpuoorrtinsehionwtshethfeisphrteissesunec.e Tohfiusniwdaenstinfoitedreo-regvaanliucatfeludorininteheand of second report.
CONCLUSIONS
No reliable conclusions can be derived from this study.
Submitter: 3M Company, St. Paul, Minnesota, 55133
Environmental
Laboratory,
P.O.
Box
33331,
006088
DATA QUALITY
sRealmipalbiilnigtyd:esKiiginmiinscrhelraatinoknintgo 3t.heWoiuttfhaolultaannd usnadmeprlsitnagndpioinngtso,fvtehreifiable
data on the actual the manufacturing
fcaocniclietnytarnatdifornsoomfnfaltuuroarlocshoeumricceasl,sacintitvhiteiersivienr
from the
both
cmoannduiftaicotnusri(en.gg.farcaiilniteyvpernitosr)t,oasnadmpalicnlge,araunnydaeprpsltiacnadbilnegoenfvihroownmleonntgatlhe
Asdadmiptiloendallfiys,h twheeraenailnyttihceasladmaptlaicnognfalriecats,. thIterceains noltitlbeetodebfienictoinvecllyuded.
concluded which analytical data set is correct.
REFERENCES
F3iMshT."ecJhanmiceaslER.eGpaorgtno"nB,ioParcocjuemcutl7a8t-i2on74o0f,FDleucoartoucrh,emAilcaablasmian
Tenn. --
River
Tennessee River Fish, Report Number 001, May 22, 1979
3E.MGTaegcnhonni,caPlroRjeepcotr7t8"-F2l7u4o0r,ocDheecmaitcuarl,sAilnaTbeanmnaes--sTeeennRievsesreFeisRhi.v"eJraFmisehs, Report Number 100, December 28, 1978
3M requested Gillett, Comell
eUxnpievrertsoivtye,rvMiaerwc,h"B8i,o1a9cc9u3mulation
Studies",
Dr.
James
OTHER
Last changed: 5/18/00
006089
3M REPORT: BIOACCUMULATION STUDIES
March 8, 1993
6. Re(1p2o(r28t(N7o5).*F0l0u1or(o5c1h2e2m1i7c9a)ls"inBTiennoesaseceRcivoeurfFmFilsuuhorlocahetmiicaolsinnTenn.RiverFish* andReportNo. 100 SYaemprlJiTonhfigscdpoeansitireognntfsp,ianparenerdlsattshieoqnudiitftofeioccuuotlnftfayuloslfinaagnc,dtluasarlagmedplelytiebnregmciapnuoaistneitoosn,fs,itnhceoWrrhreeescuntltstthaaeansddearaldrised,ecc1oonmfbuisendaiodeonntitay loafclkaboeflsclaenadr problem. These papers make a0 excelent example ofhow a litle knowledge can be.aduna.ng`uenrdoeursst.anding of the : 6 006090
Mm ons
~Te~chi3Mrac RpRlEPORT SUMMARY
J-- 4
EES-- 210
To TECHNICAL COMMMICATIONS CONTER -- 91300
(Importan
i"
t
=Ifreportis priv
Baviromme
anbehsidesofpape,
ntal Laboratory
neltw
(55
ocopies #0
& 50)
TCC.)
DEC 201978
r 0323 r
Decatur, Alabama - Temmesses miver rien
Torzio
Dioscoumulation of Fiuorochesicals 1s Tosa. River rish| aor
D. L. Bacon
snes 3. cagron
1353
Sees Loo peguese #71
pi
momh BOD Rees |HRS
Fx
= BEETFEET I
[STeDTeoeRcumaaate,uieruslep.lmiRa,-itsvq.eeunrasr,AsAMnebaaoaaltvapiedevieeapnundafenondrebaeassdsroUueisnantmWiiiicisaesriseItevlynee,hpdSeonmerteae13t,reraiItsnihare oT
he
( EEE EE eee AEEtnhlaya1rlbayecn)est"aSt(eReekxRcturnaEcNhtrsysoRefnso):Crhtanndanelschocafiaenri(bjieTteaTlurResEpEunctates). BEST-COPY A--V_A--ILABLE
ce: AKD.vmReiaicedkeedrr-236- .
--3Ru)
006091
oe
f---- BEST COPY AVAILABLE Tenn. River Fish/JEG
Ze
5/22/79
ToILorlimgugmacaenrniotcckhne(fom3lw)tu(co4art)lhi.sadtec"a3lWne'ivtsebhlistDo,ehccecas1ute0mu.urc9l,oamptbpAeialnaeb(id1an)m(aff2ia)spc.htloarnistnI,teahtfuhflselaubeanonelrtxwatotohrbasyesteenpheingvswhhiaoeswn Lhul P591.a800t%,ha1df dTeitsehctcaabulgehtlienveltsheofTenfnleusssreescheRmiivcearlsm.eas the Decavur RRESUELTSSAAnNUDDiDLissccuTussssiSon TTofahbilciehnthe1arevlseatttah(eFt3sh0ae5m,econrceetTneHtn-r3ta9it3o5in,ont,ainmdeinaTspHp-mt3,h4e3i2tn)hrfeieshfoifuocsoescpboeunnidossle SgatAaoraudemaapbltliyfeeaoartst.cs34ce,uoimftItesahttohcweasninraetlshtaeuhtoeltsgDteahsefstoerrfeolniutnohtetrehoascdtthiiesnmtshaiselccatmlersudascccbtlhi.eaencaerleaaelsgpeersrcoatdwtisefreissrsishv'f,etooussihaatseemr, results agreuelaWtieththeeartlhireere rfelpueorrcoeche(a3i)c(adl)s of interests Touice Stihhrneaoncnewhctobwoloimtcephearftifihisneshghstfwahlmoeuprolerteooscct,haaeulgmthihftcelauliolnracorotcgnhhetereemnicstachm,aaeln.n3eA.clr7oe4nstc'eapntrtfasirsv(eehT.iFeCc)s1oiayitfasoorir]aoectshh.emore $4Tf3xlodrupolcsrsioahocaachtneeienolinmcoarcflooasrtffwiatosthhuti.lysdmtbaPieywlauubeooerxopcrieuheceltspaairt.coeasdolnsitobiitonhsecicnhueiseahslaaprteaeerstiisvoinesaatticsLooeislnifiicciiecats cTh4a3s0n9ol c1astfpirsehs,entsamatplohiSgAh,ertchucnaceontthreartisoanmspleinn. theSideiosessecttieeddcumin. tfoiron threatehsighhearvoconnotcenbtuornatdioontsermcainnobde foorffFe-r6e30d9.8 80oxplanat ions TrtgfhhiaegtofrtlowtuhuooesrlofyCcioshhrceeoaimscspaaiamlmprspleledes(swthowomhlwaieyhcohlGTeohitsahdfhiacvsvaohelrsueesaTsemtppBarlakeeyessnebnetfaTrthhoieimvgehsteehsrsesmmocanco.woilrsslcooiraamrtocstiu"iimb.ois SthiencerecsourltesWucmaspiibse wrairgooroLuuskloyn c[ormopaartehde. Aprosiasie sem iaersion, mTD[uh1ase4i.hlwTuhuFaittCsaeptloiefbnut0s2is4.,c4a0flhrapodvmpa.mb&pel`wlowhohnwoi,lleWohLtetfehiwlewoehurwlThdFiDatCmeb,eofcsdr0iaa.fmpf0ppi0lie4eeurs1fep8r,ae:mihoasda"gaoiyvaeewtmhmhaootnrlceltehor oCflftoailrelgMroeawrhipenoTgrsC:sifbllluueodreuoxecphleGmaailnycaatliLooncsotnhcefeonwrthritathteeioMbnia,tshsedroLwiFnvRaiCtnsgessoLsuelsftrhoonemrtthmheieoiivat.
006092
Tean. River Fish/JEG
--
.
722/79
i
TABLE 1
BEST COPY AVAILABLE hulle
'FLUOIRNOCTIEENMKIECSASLEECONRCIEVNETRRAPTSIHON (ppm)
sample
(1A - Whole rian
{18 - core (3 [3a - core (5)
6308
0.40
0.83 0.08
yrue-3a02s5 &(ny
0.713
3.3 M.D. (8)
T7otailn CFoimabnined Cope) (2)
1.13
0.40 (4) 0.004 (4)
(3a - Gills
1.48
34 - Liver
2.47
{ W-pare (1.3
3 - Muscle
wo.
0.80
0.38
0.3 wD.
2.74 (9 |
3A - Fat (8)
13.85
34 - Gall bladder 1.87
water blak
nD.
BuSbhyi)a acetate wo.
6.12
0.74
wp.
no. - '
.
Yootnotes to Table 1:
(1) uTsMe-d3;035thearnedfoTrUe-,342a2ccoamnbinaoetubevalrueesolivsedrewpiotrhtedG.C parameters
((23)) oSBruagvmaepndlse,onco`arFaerc,opzae3nr.t6sw1eiocfga,htki1d4onfecyoi,nnteariefcnitseuhds..skiasa,d bfaiclketb,ossr.eproductive
(4)
or
SFAmsesppurimeiesrsecnattrhaeat,tive3t.h8eo1fcoatahiecednrteesrtauttionofinastnhdeobttfaiiislnhe.ei,d
in the core are
vertcorao. ania.
(((678))) CNCooobmn.uttiu=atteNadodtooffdotmgouucsstctalrdeo.,istwkeisnt,ioabllootdr,ictb,oser,eprsoadduccatritvielasgyes.ies.
(9) pBTarrsooetgderni8nweitghhet,actaunadlwweeiigghhttpeorfcesnatmpolfe eusscedh, pa1r8i..8% less than
006093
mm)
BEST fs--
copy
AVAILABLE
Tenn. River Fioh/E
a.
sr22/19
33I.0. LDLioofnnfggeeerrrenrltoicvaestrpieocrnieevsirdeesnicdoencteimor,imeo.lder fish.
b2)) )
RDLCaioIrFnCgftAeearrientansfatldlu'aofrtreogonecdrbhiienoWngaeicicaegaaunldstup1iapiarefrtreeic:etsnitFtoyinlueoossfrooosortsgsiaiansisiooanltye
CTf1r2ihaueztophrieoletc.hccoearmneiRcoabssleassmcppalstoeosstfuoarlarartteaehsidrtseetprharareteesxstacfehthneaattsismvet)hemaesGo.fusteeFiwithbohoonelrreebrbifsiisssotmhsocvrcemoosonnictseenntsorrations,
TFalbuloerid3egi(7v8g)s tCoinecarnetsrualttisono,f tiahepeoerrganaicti(eRF)dens,adainoorgeanic
maoiz 3 (5) ORGTALONOIRCIL(ERF)CONACNEDNTIRNAOTRIGOANNSIC((p7a))
susple
=
1 a
0.7
us
.
102
1.
;
1
10.3
0a
ater
wi.
0.01
spi"JtrnoooaneortvmgeiBasoernulaisictclhsh'yaleterflahwnupuiaoorlgriypninsrdteiesidun,ivonuagtlf.uoertshaalthivi4g1thho7eenirleyrheitsghethaxnpiriiesnqsotusreetgnsisttoaossirc,wFeflwsleavssvonreisieedoremlivoitanoelhuBAoalurlre to calculate low levoerlgsaniocf ofiruscartisdeflvoaslcuisteersouls eibetic S08ehlo0, s8BCtlha0oaiamtslcp"tylaeserru,iaiusrsmopVno`lacfoluwuoteTfesersxtuaphtmelehaasnoSarotgsfiaovorneniscEthheefseoalrsdoanrstohnliDoeserkgsarshnraieevcseer.bfvalJatuoteoitsrsiadoteyhecAScaoebaimnts'ersit`inMseih"'RcoOswTsare StghnocugennttratthieonssanpulpessnttersmeaaymRiRvfaervroemwabtteheeenrpmissihaostvi.eiddeAAlCLeEdSiato'Frigetsnihmiset,heFsiittioprTioedseuits,
006094
< feve Welsh
j
BEST COPY AVAILABLE
ibe
Tem. River Fien/aE
--
5/22/19
ao1clyawtoeiuelltiduzaalstleiyeomnbetoofleientshdeiecafltleuogtrhWoahcteheelmtiehecrelcDuomwn.hceenntTrhFaiotsiinogmnayoovfbere fctlahuueosreoddcahmcbm(yi1c)uls Settling of fluprochemicals before the dam: CS1oo8m.p5CaorrairseoinaTtoiorcfa".soirmgpa`lFaeoirc2ae:xfalmBuapodlr.ei,dtehethveajlouvhseissgthefsTrtFoCm,oTr6ag:ba0ln0ei4sc p1flpau,nodrif2doershtvoahwleue. orTlrtieorrongotntheinaeincaalTlyuesoerdaindafelosyrzepidrn:edsievniAtd'upaoilsnlsyiv.belr|ey shTixhgpehlisnpcaeoicniicoeensntwrihsaitcbihoantshadtwhhietcrhhee Tiiotrnoindsofcasonccernattrenatt,ioncsh:annel catfish, bad the lowest organic 2oTeihfateethai[cSliheisrmoeoitlftoecdthtuoeosanactimooapatslhtieesornpssost,ppuuedlciaiTesthdeiedod;nooal(ia3ytppdeifaesirsfhdiintfioofftiebcoiuncoieostnccsclptuueomscuiidioeeunssteeainsaidnaytohFnaietver Fon inder natural conditions. -- 1. Sample materiale
J 14 - Shmoavlel cWhhueaenleelr cDaatnfiisnhTe(nfnoetsasleuerusRivpeurn.otatus), caught 1B - WDhiiateinbaTseenne(sMsoeseousRivcehri:ysops), caught below W"heeler 34 = WDaeiatlescTreaapnpeises(ePsomoRsiiveer:annularis), caught sbove Wheolor 30 = fhaarvgeo Wchheaennleelr cbuatnFiinnhen(FsretsasteusrunRVpOuFn.etabun), CBight Standaras
6309, YM-UULS, und VM-3AZZ.
Tboynapfpimutisntgand1amrldsooff&4130009,ppm YuNt-a3n0d3a5r,d, an1d
FetHh-y3l433acwetoartoe,protpoamraerdk
leh ethyitscetate 1a separate 10 ml volumetris flasks.
3. Ansiysis Instrussnte/usterials
Blenger:
WVaarriinngg CPormomdeurcctisalDibvliseisodne,r, lMooudteel444.91-N3e6w3.Haratvfaoirlds,bleCTf0rRo0mB7.
006095
following:
BESTCOPY AVAILABL'E
:
Tenn. River Fish/JEG
--a=
5/22/79
Tiusventzer
5M9o9d0e3l, 4SCDaTc, tanvaatisl.abloen f4ro5m32T3ekmr Coapaay, P. O. Box
Disker pie;
531.5261SJaErcrnTylc1h`dGnuiAtoIhnSrtIi-eN0o2itnehbCioegonhktrca#alr5b1oR5ne0s8es3at5re:cehl cLuabtst,inGgosdcirsivmeadde
sizer:
|
"VToordtuesxtriGoesn.ie'ncMeo,delBoh#eKm-i5a5,0-GW,Y av1e17i1l6a.blo from Scientific
Contrtuge:
Dumca-15C lode #3204, available from Damon-IkC
BCootrtpioorna:tion, Needham Heights, MA.
R Fourn -ounceTowTidetmaodutMhieudntchluenarTogbilasisnebdottslnpee.sealed with
po1l3y5e-ean1tlcianpesa.r polyethylens (LPF) plastic bottle with .
;
Gas hromstograpn:
-
CThartoossartuocgerraphHPro-iwalotewetlrto.tbuPcakcairdardModNeodlolJOS7A13 iaaCt.ogrator-
B13o0t"hiogfotWhioa1aboHovsea.wvPaatlloablAcltof,romCA"Hew9l4e3t0t4-.Packard fo.
Column - SStx1-f1oo8t, cu1i/o8n"inoac"h60O/D8.0"stCahirnolmeasssornsteNeolA..packed
CfoaljuemcntorTem=peGraa-tsuorteumn- aItso3t0h0e0rmCa.l [0180 c.
Detector - Electron Capture at 300 C.
EFltohw) -pc~a4t0atcec;/minute of Argon:Methane (95/5).
|
"Li Carosolv! chromstograply sslvest availble roa
3
MNCo/rBooMda,nu"fGia"ctu45r4i1n8g, ChCe"mCihsitls,iog390v9eosHeiSgihelna:nd Aveaue,
00609
and fat.
Tenn. River Fish/JEG
"ie
5/22/79
:
Hratierr: e ae > Rete
BEST COPY AVAILABLE
TIT UL SILTS Santa ie SSaaagpeiisess 1244 s1h0rroyuaggnna404,s1a2d0.1108 weorree rerpmmoovevgedfrofmemshchee
2forneveeroy,
Hosen
A LIT
Bo,5premLe eenattesdivee estfin,S that. Cslielpee2d7Phacsaone,
ffilllplaete.dThye p1i83P04 crumsmampele'BcoucuE tond T This mFSBooim1optis1s,0mRee2my8maeerigstesd,SveAisrieassaAcsted,TtCoetrrne,IbEdlo"maigoRvvga8miri0ideo01ud)s CFpsahnatidtepievsRiesdeatulers. pigmuaenrzetees STiheitse Ssh atetnterholmen wsireotletenrvieaeid,12 1 MHinele LTagriecehrmomlteeiloutciaw:oTawtptirnreiset.u Spokvdtoyluienne,TL4Oe11E3Tt,heeerr,e
Spgfoarormppsmrlaeicsenrsat,noarcleryszsoridTingfotroAtF-h6e30f9,WotircFr-yi3n9g35,piosacnnaddRurePsN.n-t3S42A3e2 eweTrchiNe pAAozsPyifTeciuLmleYycdheSmeoirshAarizeeGsr, saiuAsmi1ne0,,00YsIoOLrToeHadS di5.e4at4.abceoeynLTTbaErReE Fr EI EnOC RT
The samples vere removed and centrifuged at 1500 rpm at
!
006097
Tosa. Biver Piah/JEG w- ,
saa
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5/22/79
ol
TABLE 4
FISH YEIGSTESDANFDOREETXUTYRLACATCIEOTNASTE VOLUMES
Sampo
WoRtogmhotkonofsteFish % W07ater EAFictsthnoinEce.s m
Description
(keine) Homogenste (ag). store
a- oul Bladder 1.20
ss usa 12
a - Liver
2.20
62.7 00.6 2.2
a - muscle
2.40
ss ames za
n= ra
2.40
es. sanz 2a
an - parts
2.00
#3 asso a0
a - ans
2.00
ws aeo 3.0
Vater Blank
2.40
wo
2.4
1A
2.40
57.8
1012.8
2.4
*
1B
2.40
32.7
1615.2
2.4
=
2.40
ws as00 2a
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TECHNICAL REPORT SUMMARY
701 TECHNICAL COMMNICATIONS CENTER -- 201%
= {im~p Ifro eporr tixt prina tedon nbt othsidesofpaper,sndtwocopiesto TCC.)
-- mafFm3yT
2/28/79
U0 . Environmental Laboratory (EE & PC)
Decatur, Alabama - Tennessee River Fish
Fluorochemicals in Tennessee River Fish
0222
78-2740
100
D. L. Bacon
i James .E..Gagnon...
51568
seconrd
g0L0abcoRemqiuenst o#G4io8i7e1usvorision)
BTorwmuonoied:en, CURRENT GRECTIVE
.
Progress Report.
| RECRcTaYl >
TT 213531 Syfri3eytes rd
EE & PC Decatur
. .
T ORTABSTRACT 00750 e adTo Seere ronrasGood TtComntonor
The microwave sustained helium plasma detector
system and capillary column with electron capture were utilized to examine fish extracts for fluorocarbon alcohol levels.
v
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c: D.Ricker-53-4 A.Welter A.Mendel
-
006101
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Introduction:
. ae
BESTCOPY Aya go:
Previous work!
the presence
indicated
a
need
for
more
definitive
answers
to
SnStatoemagnpyryltaqephu.hoiySdsatwbaihettecehltiosuefauvxnmreto,lrplaelacAacttlstisamrlbaoeaonmfd:aeftfclpeiaulcspoahttrnouotrtrc.aehke(emdMinSecHtaPfelDrcs)ot.nowretrhC(eeaCpGTCuieEslmCel)ndaorstyaconodgsaammsimscciihriiroccowyy,maav-e
A Kinnesota brows velisech sample, extracted as
a background check.
Previously
described
Was also analyzed
as
Results:
1. Capillary GasChromatography with ElectronCapture
{gemple 1M) having retention times SToEe To--bhe FTasiaben No compounds were detected in the Minnesota brown bullhe ad
chemical minutes,
standards (Table 1). Except for and solvent peaks, the chromat
a
peak
at
6.14
In comparison, samples 1B and 3A (bass oagndracmatwfaisshverfyromclean.
below 25 pe:
and iv
above Wheeler
respectively)
with retention time
showed
more than
detected
in
samples
1B
and
3A
(Table
s. milar 1).
to
F-6309 was
TABLE 1
QUALITATIVE ANALYSIS OF FISH
Sample
1B
aM 3A FM-3422 Std. F-6309 Std.
N.D. *
= =
= Notdetected = Very small amount == P1e0akppmArsetaanldeassrdthan
EXTRACTS FORFLUOROCHEMICALS
TReotcegnteioonntTiinmee(l(iMguitneus)tes
ad
N.D.
* N.D. "
N.D.
N.D.
N.D, hind N.D.
standard, but greater than * ;
2. Microwave Sustained Helium Plasma Detector: (MSHPD)
samples2. The
and
above samples were also sulfur detection modes.
analyzed by MSHPD The results
in
the
fluorine
amnidcroFw-a63v0e9,pliafsmparedseetnetc,torcouonldshpaivkeed sampleosbtsahionwedthbayt thFeM-3. 422
efxlturoarcitns,e coNnotenftluoartoctahrebo0n.1pepapkms' lweevrebeleeonibnsdeterhtveeecdtetehdiynlftrhaoemcetatachtteueiarl
.
5
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Discussion:
:
:
mTpherenesteianobtnoveedinirsneasmutplhlteesso.riingdiTihnceaatlelraretgpheoarttagmoouanvrteosldautoefiletoorgfatlnhueiocrporcfealsruebonorcniesneowfere nifoonnrtveorNltVaeFtrCir'liseng(ef.clgou.mo,proouFcnChd-es9m.5i)calwsas (hNiVFnCd.)e.redTbhyin-anlayoveerrscbhurnodmaantcoegroafphy
Integrity of the Standards:
TAFhfNet-e3r4c2o2mtphoeaurenidnbiotutisaheldthrfeeoprosroatum're, FcUoi-tm3pw8oa2us3ndsbrt(oaNun-gdehattrhydluphaFdOtShEagtivalFecnNo-ho3al9)d2d,i3f;faenrdent FreUt-e3n9t2i3on(atinmeew, sabmyplgea)s, cFhNro-m3a9t2o3gr(atphhey,oldtha"nstaFnMd-a3r4d2"3),, FSi-a3m4p3l3e,s oanfd hvFeaUrd-i3fb9ie2ce5antwieiormnep.rospeenItrtlywtaoslCaobdmeemlteeerdrcmibiaenlfeodrCehtehmbatieciantlghsesoeAnlntadlyFttKoi-c3usa9.l23LaIsbntarnfedoaralridty, CtghFey7sSaOm0p,lNeHELw)as F-63098 (N-ethylperfluorooctanesulfonamide:
pAsreopfa2r7atAuigoufnstst10a7n9d,ardtshe(niedwenFtUi-f3i0c2a3t,ionLotver5i18f,iedw?i)llabned uthseedolfdor FU-3923 has been properly labeled gs P-6309.
References:
#-
"
"oGfagnFolnu,oroJcahmeesmicEa.,ls3iMnTTeecnhnniecsasleeReRpiovretr FSuimsmha,r"y22"BMieoyacc19u7m9u.lation
..
HDaegteenr,minD.ati.o,n o3f 23 October 1979.
FTelcuhonriicnaaltedRepAolrctohoSlusmmairnyFi"sAhR B
EFox.tra7c2t3s8,"-
%
Spersonal Communication with A. Mendel.
.
"WNoi.nte1r4,998L,. D24.', AuCgoumsmterc1i97a9l. Chemicals Analytical Lab Request
6Sogun. "
A Han
006103
LL
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Tos Tecmicat
TECHNICAL
commer Gud 3%(3
REPORT
SUMMARY
(importan=t 8 apo isindon both sides ofpar, ndte copietso TCG.)
ecober 23, 1979
CENTRAL RESEARCH LABORATORIES, Analyetcal and Properties Research Labocatory] 0507
Eavixonmencal Engineering and Pollution Concrol
000007
AR No. 7238 - Determination of Fluorinated Alcohols in Fish Extraces
238
J. E. GAGNON = 209-15
DF. GEN = 201-15
042508
SECURITYD
EwerOmoNnoSs om
si
Caomin
Conienstl
Comment
d1onCslSousteorication)
owEeTvE
a ot
Requese No. A73LS4
3RECCHREMTIYCAL >
`NOevw eChimicafsRepBorNted
ACemnatlryaelicRaeseRaerpcorhe || RPEeOq3ueeCsEtorNo.- J5.150E.060G0agnon Chentcal Analysis
TOT ARESTRAACY. (R 50 150E m Tat errors ed We TR Coren CoS cTfhoieslhummeixcvtrirotawhcatvseelesfcuotrsrcoafntlnuecodarpotchuaerrlebioundmefapellccatoshimoaoln dveLeterevecetlsowreilsyrsetdem caondexacmaipniellary
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006104
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.
CENTRAL ANALYTICAL LABORATORY
Report No... J238._____....
Date.......0ctaker. 23,1979...
BEST COPY AVAI
Subject: Decerainacion of Fluorinaced Alcohols fn Fish Bxceacts
Requestor: . 4. 2 Guten. ___ Dept. Name ZEEE Proj. no, 21500600
Request No. ATUH________ Dated. Auer 8.2978
Report:
Introduccion
TThhei mSiacpcioiuiaavrey csoulsutmainnecdhchoemlaituonmcipsliaysawnitdheceeclteocrtro(nPDc-a8p5i0o)t-e<heevoenesttioogenapvhoicce esryisicieonsed
55 and Pesan to examine fish extract samples for the presence of fluorocarbon alcohols FM-3923,
Discussion and sessies
ToThheeecihhFetilocimaualscioypslsafasopernsiTcdleutppetocistnheoratayndiLeelsduesllfuotarecsosciofcroant.Liiontenhesfpooertcottrrnmae: dfeorcBeocecthiecaonne.leoemfheenrstcpsbeocrperieesseonnctiocmopfrnounds
GDLierenciaecSeeddsTtbhayecttCohlresu.ncsoacmapTralbeotnmhiasatleeicakoh.paetsSTsFf slDaamrepgelecetroipo-tshielTooteworevilensresaceseos.mecitaoiiconenienmgeisniptsoeesrksteoscesseoemeepnornees1se1n0t
tIchneeeyTrrnaewnitltqslueanroctvTeserreplecsoootavevdi.ecrytarhsec.Luebpsveled.alsamvSFTaahtieatslchyteiprvsFeealsptoemionrnrtagsoc.ceada.t1b("otbFniyripoeamaslesatoihneFmotolidsFeo.l"ouoisttetityoneecp.LtrFoecnvottemehn.eetotnicoonatrncFbghioeunpboaerbsiuseieelbodfaulp
RE ah entrants Te dove minenresarion agection
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CCTcooTouamtann.SSe0s0FgoeErntyatApi-Lrse6Cel,nast6n1o.fCHtHh-eeIlNic-uoTmvPeAcnororneife8ir0v/e1anc0t02mt3eoeschsimmiCiLhntrowntiocG.hthepHo.iEPpI.tD opTnorcokSghaesomWeAadLbTdOfR5e70on53008
TChoccrh"rioTeminaniteaoysgtroaTnpihneLain5ndcI as1680o0%sCe,isfot"rrTT ahnaFsiucfseao trvirinetedy, heotuodsekthsecueI MrmPpuDe-r8av5tou0nrnpl6a9iso5m6a.ne5tcaaavnidat5y362v00i30a.%3aKsnhdevaetscemhdeece1ps/iv1oa6nt"sy.
Ampconinaotneltyh0.s5usmle/smipnl.asmoaf Ssxeynmteeno.rLstobweerd: as. the scovenpor pes to preens Eachon
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eloccron boron
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006106
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October 23, 1979
aFST ROPY AVAILABLE
P32 species. These lace tuo samples do have a peak st the cecencion cine
Shes rm evel fn he eset seers encase trfunrine content at
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