Document 5k1zY5gLky1Rd1eXNbvE9GLQ8
a H_ie
AR226-00333
May 18, 2000
MAIL
Dr. Charles Auer
Director Chemical Control Division
Office Of Pollution Prevention And Toxics United States Environmental Protection Agency
4R0o1omM 4S0tr3eeEta,sStoTuotwhewres(tMail Code 7405)
Washington, D. C. 20460
Re: Information On Perfluorooctane Sulfonates And Related Compounds
Dear Charlie:
Pursuant to our recent communications, 3M is enclosing additional
iinnffoorrmmaattiioonn osunpppelrefmleunotrosoicntfaonremsatuilofnonsautbemsiatnteddrteolaytoeud cproemvpioouunsdlys.undTehreceonvcelroosfedour
April 21,2000 and Voluntary basis as
May 4, partof
2000 letters. our continuing
Adgiasicnu,sswieonasrewiptrhovEiPdAingretghairsdiinnfgormation
on
a
fluorochemistry. Please note that someofthis information qualifies as confidential
business information (CBI); we also have enclosed a sanitized version of CBI
documents.
The enclosed information covers perfluorooctane sulfonates and certain related compounds listed in Table 1 of the document entitled: "Sulfonated Perfluorochemicals In The Environment: Sources, Dispersion, Fate And Effects", at 12 (March 1, 2000). Specifically, the information covers the following chemicals:
72-5 (lithium salt). =
Perfluorooctane sulfonates, including CAS numbers 1763-23-1 (acid); 29081-56-
9 (ammonium salt); 70225-14-8 (DEA salt); 2795-39-3 (potassium-salt); 29457-
= Perfluorooctanesulfonyl fluoride
005983
Charles Auer May 18, 2000 Page 2
= Perfluorooctanesulfonamide
= Perfluorooctane sulfonylamido (ethyl) acetate
= Perfluorodecanesuifonate
= Perfluorohexane sulfonate
= N-ethyl perfluorooctanesufonamide
= N-methylperfluorooctanesulfonamide
= N-ethylperfiuorooctanesulfonamidoethanol
= N-methylperfiuorooctane sulfonamidoethanol
= N-ethylperfluorooctanestifonamidaocerytlhaytle
= N-ethylperfluorooctanestifonamidaocerytlhaytle
= N-ethylperfiuorooctanesulfonammeithdaocerytlhaytel
= N-methyl perfluorooctanesulfonamidoethyl acrylate
previously
3M under
has provided you coverof our April
with information on perfluorooctane sulfonates 21, 2000 and May 4, 2000 letters. We are enclosing
some additional information on perflucrooctane sulfonates located as part of our
continuing file search. For each of information includes the following:
the
foregoing
related
compounds,
the
enclosed
= Copiesofpost-1976 studies and certain other information relating to the following eennvviirroonnmmeennttaall fsactieenacnedatrreaanss:por(ti); p(hiiy)siecnavliraonndmecnhteamlicmaolniptroorpienrgt;ieasn;d(i(i)iv) secuomtomxaicriyt"y.forFmoart.eac3hMsatlurdey,ad3yMhahsasprporveipdaerdeydoau swiutmhmaargyenienratlheexHePcVut"irvoebust `summary addressing each of these areas under coverofour May 4, 2000 letter.
= Cheoaplitehseofffepcotssta-r1e9as7:6 s(ti)udaiceustaentdoxciecirttyai(nii)otgheenortioxnifcoirtmya;tiioin)rreelpateiantgetdo-tdhoesefotlolxiocwiitnyg; (iv) pharmacokinetics; (v) teratology, and (vi) medical surveillance and epidemiology. 3M has included a detailed indexof this information subdivided by each compound.
005984
Charles Auer May 18, 2000 Page 3
= Listsofall studies in progress and planned studies, along with study protocols or study plans, where available.
= Abibliography of pre-1876 studies subdivided by each compound.
= Athbaitbwlieogarraepphryoovfidaicnugtceotpoixeisciotyf skteuydiaecsutseubsdtiuvdiideesd(wbiythearcefhecreonmcpeotuondth,eeHxPceVpt guidance).
= Abibliography of published studies in 3M's possession.
= APnleiansdeexnootfestthuadtitehsisini3nd'esx hpaosssbeesesniosnubbmeiltiteevdedatsoCbBeI.in3thMeaFlIrFeaRdAydhoacksetp.rovided
the the
Agency with a TSCA Section
lst of all fluorochemical-related 8(e) docket.
submissions
made
by
3M
to
information as3aMppirsocpornitaitneu.inAgsitysofuilererveiveiwewthainsdinwfilolrmsautpiopnl,emweentastkhetheantcyloousebdear several points in mind:
= The enclosed information spans several boxes. We have organized the
information in each To ensure that you
box and
with your
labeled file folders and indices to staff are able to access the most
aid EPA's pertinent
review.
information, we also other information.
are
attaching
to
this
letter
the
indices
covering
studies
and
= Manyof the studies refer to the test substance only by a 3M product identification bneuemnbeirncwliutdheda,"wT*h,erLe" aovrai"lFaCb"lep,reiftiixs.ofAtletnhonoutghpoasnsailbylseistoofdettheertmeistnesufbrsotmatnhcee has study report tself the identity of the test substance. Thus, we have used the index to provide this information based on 3M's historical records keyed to the p3rMovpirdoedducstpenciufmibceirnftoormdaettieornmoinnettheheicndoemxp,ossiutcihonaosfptehrecetnetstcosmupbosstiatnicoen,ansodlvheanvte rcoanntgexet,resfaelrtsftoorma alonwdeprupruirtiytgyrgardea.deoPfletahseecnoomtpeotuhnadt,thaentder"mnaornrotwherainngdee"xr"ewfiedres tfooramuhliagthieornspuhriatvyegreavdoel.vedFinoavlelry,tihtesyheoaurlsd,baendretchougs,niszoedmethoaft tphreodtuescttsubstances do not constitute current products.
= We have included some additional studies on perfluorooctane sulfonates located
aysoupawritthofinofuorrmcaotnitoinnuoinngmfiixleturreevsiecwo.ntAasinwineg
have discussed, perfluorooctane
we plan to sulfonates
provide in the
near with
future. studies
Please be advised, however, that and other information on aqueous
we already have provided you andor solvent solutions of
005985
Charles Auer May 18, 2000 Page 4
epenrcfllouscerdooicntfaonremastuilofnonlaitkeesw.iseAsintcolutdheesfsotruedgioeisnganredlcaetretdacinomoptoheurnddso,cutmheents on
cbootmhpotuhendcso.mpWoeunadrse ansotweplrlovaisdionng atoquyeoouutsodaanyd,/ohrowseovlevern,tisnoflourtmiaotnisoonfotnheosteh.er
types of mixtures containing information with you.
these
compounds
and
would
like
to
discuss
such
= Consistent with the information previously provided on perfiuorooctane
sulfonates, 3M has related compounds.
not provided Rather, we
you with all analytical chemistry have enclosed certain analytical
reports on chemistry
these.
reports which may understanding the
prove details
uosfefaunlaltyotiEcaPlAchinemiinstetrrpyremteitnhgocdesr;taoinr
studies; verifying
human
`and biomonitoring data.
= We provided previously under coverofour April 28, 2000 letter to Oscar Hernandez a "Use And Exposure Information Profile" or "UIP for perfluorooctane sulfonates. Our present intention is to provide you with cadodmiptlieontaeldtUimEeIPtofcolrarmisfyfoirndtuhstersiealrehlyagtieednceoamnpdouotnhdesr eraerlleyasneexitnfwoeremka.tio3nMtoneeds ensure that the data is accurate and placed in appropriate context.
= The information on perfiuorooctane sulfonates sent under cover of our May 4,
2K0e0n0WaeltlearcienocflutdheedUdnoivceurmseitnytsofrMeilantniensgottoa.ongPolienagsemencohtaentihsattitchirsesreeasrecahrcbhyaDlrs.o
eUnnicvoermspiatsysoefsRotchheessetreerlaMteeddiccoalmpCoeunntdesr.is Ipneradfdoirtmiionn,g cDro.mpMaarraitoinveAnmdeetrasbooflitshme
research there are
relating to perfluorooctane sulfonates and these related not documents yet available relating to this research.
chemicals;
005986
Charles Auer
May 18, 2000 Page 5
3M looks forward to discussing the enclosed information with you and other EPA staff. In the meantime, please do not hesitate to contact me withany
questions.
Very truly yours
Hillis QS fpr
William A. Weppner, Ph.D Director of Environmental, Health, And Regulatory Affairs Specialty Materials Markets 3M
Bldg 236-1B-10
3M Center
St. Paul, MN 55144
(651) 733-6374 (phone) (651) 733-1958 (fax)
E-mail: waweppner@mmm.com
Safety
Enclosures
005987
Perfluorooctane sulfonylamido(ethyl)acetate = PFOSAA
S12y9n,onEy2m1s1:3,FEC2-516069.,2,FCR-119000.4X, FC-128, FC-
PhysicallChemical Properties
Eintveironmental Fate and Transport [[TEencvhioRnempeornttaFa(stica)o(fWaFrubourrogmhreerspmiircoamsetnerFmethod for biodegradston of FC-128)
TabAoruatthoorry or|| Comaptleeted
Tyee
Tab`oAruantoorryor|| comDpalteeted Ew Lab| 1276 | Rebust sumrmeaproryt, Gehan
ee
____ _-------- ------|
[Fish
dota sheets wopon
data sheets
[ [Ready bodegradaboifiFyC-108X - BODICOD Labor1 aPtaocreies. --ROc-- oUmTpu-- tseurmmra-- ersyu,sc-- roopymof
Mimaspols, WN
arches
Siutmemary Reports
TabAourtahtoorry or "
Tyee
iEctoteoxiciy Elements
|Acute toxic of FC-128 to fathead minnow __| |Acute toxicty of FG-12 to fathead minnow |Acute toxicty of FG-128 to fathead minnow |A[TcouxitceittyooxficFC-o1f2F7C-to12a7citvoatfaetdhselauddmgeinnow | respiration
LabAourtahtoorry or| CompDlaetetion
aM Env. Lab| starz 6074 ansrr7
3M Env. Lab | 724781 MEnv. Lab| artast
Tipe Robust sduatmamasrhyee.tcsopes of Robust dsaulmamasrheye,tscopies of Robust sdautmamasrheye.tcsopies of Robust dsautmamasrheye.tcsomes of Robust dsautmamasrhyee,tscopies of
005988
S[RceraedeyniBnigodTeegsrta'dafboiritFyi:uor"aMdodFiCf-i1ed29OECD RSCwCit,zelrtiinagnedn,| 0/19/84
[[AMcitcirvoabtiecdsSMiiucdrogteoxReTsopxiicritaytioTneIsnthi-biFtCi-on10-9F-CX-100]| 3M Env. Lab| 10rtsie7
x
3MEnv. Lab| 103087
ABC
|Acute Toxicity of E2566-2 to Daphnia magna_| CLoalbuomrbaitao,ryM,O|_ 1/0/88
|Acute Toxicity of 2566-2 to Fathead Minnow
|
ABC Laboratory,
(Pimephales promelas
Columbia, MO| 1/12/88
Pace
Labornact.o,ries,
[s[uBbisodteagnrcaed)ation (methylene blue active
Minneapolis,
MN
215089
ASC
|Acute Toxicity of R104 to Daphnia magna CDourlpuotrha,tiMoN_n|, 617197
[Growth Inhibition of R1904 for Green Alga
ASCH Corporation,
Selenastrum capricomutum)
Duluth MN_| eraser
[Acute Toxicity of R1904 to Fathead Minnow
Asal | Corporation,
(Pimephales promelas
Duluth, MN_| _er27787
CorpoArSaCtHion,
|Microbics Microtox Toxicity Test - FC-120
Duluth MN_| 7/9167
Inhibition of R1904 for Activated Sludge
CorpoArSactlion,
Respiration
Duluth, MN_| 711017
ASCH
[R1904 BODRepoforr3tM Company
CoDruplourtaht,iMoNn_, | _yuro7
aRboobuutssttusduymrmealrabyi.ltmy,efminoal [Robust sumrmepaorryt. copies of Rabust sduamtamasrhye.stcsopies of
data sheets Robust summary, final
report Robust sruempomratry, final
[Robruespotrts,umcmoapireys, ocfodmaptuater] sheets
Robust sruepmomratry, final Robust summary, final
report Robust sruepmomratry, final Robust summary, copies off
data sheets Robust sruempomratry, inal Robust sruepmomratry, final
005989
N-MeFOSE Alcohol 7Sy9n0o(nMymesE: tFFMOS39E25m,ixL)45c2c87,96L--1403,09F,MPP3A9-7749,1c,c P7P9A6-3
Physical/Chemical Properties [Tech Rep-oSolrubitlty of FM 3925
oTrabAoruatthoorry||ComDpaltee.ted
Type
[Rleoxbcuersptt sfurmommaTreyc.h (reecphorrtep-ort.
3MEnv. | 1/879, Lab | 17179
|[ASnuaplpyotritc,al1M1e7t7ho0dology and
[TEintveironmental Fato and Transport
oTrabAoruatthoorry|| Compplaetteion,
Tye
Tech [Tech
RRepeortp-- CBohieodmreigctraaldaOtxiyogneSntuDdiees monaoFfnMFd3M92359,25|
3M
Env
Lab|
118179, 1/8/78
[Robust [reports
summary,2
technical
Tech Report- Distribution |Octanoiwater
coefficient
of
FM
3525
in
n-|
3M Env. tab | 11079
[Robust |report
summary,
technical
[Tech Repo-Adrsortption of FM-3925 on Soil
3MEnv. Lab
| |
3/22/79, 519/93
[R|oS bBuosytdsu(MmSmU)a.ryt,ecchrintiicqaulefrrepoomrt
[[TTeencnh. RReipvoerrtF-isBhi,oTaeccchu.muRlatieon-oFp flFuiouo roorcohcrehmeimct iaclaslsinin [Tennessee River Fish, Ar No. 7238 -Determination of|
3M Env. | 1520/22281/7799,, [R|Jo.bW.uGsitllseutmtm(aCroym,eyc)ri,ti3que from
[Fivorinated Alcohols in Fish Extracts
Lab | 1023779 [technical reports
`SummaryReports
Moe ----
oTrabAourtahtoorry|| Compplateetion
11]
[EFciotteoxicityElements [Tech Report- Aquatic Toxicity Studies: FM 3925
oTrabAourtahtoorry||Compplaetetion
Type
3M Env.
[[dRaopbhunsita,sucompmiaersioefsdfaotrafisshheeatnsd,
Lab 1879_ technical repo
005990
POSF Synonyms: Fx8
Physicachamica Properties Watersoubity estimate (screen)
TovAourthsotroroyr || comopwleetes sMEny tab | 517191834, |E[RoTbuucstkesruimmbawrayr.icsrhieqsutesby
Envicormental Fat and Transport
Taborstoroyr |Gampieton
[[RP EensvreoonrmseartlaolfAPsOpSeFctesnvO ionment Fare S | owieennevv..rLLaabb[T |rTmaDastoe || TTS eeechhmenacrtrrapeopnor----]
Summary Ropors
Taborbsetroroyr ComBaptrear
Toe
Wp ore ------ epe
Ecioteoxicty Elaments
Toborstoorry Campion
Tove
o6-nour Toy toFatheadMinow
ber Bate Mem tab | amma
[RsohboGotast suada
[rTe-stinute Exposure Actvaied Sludge ToxsTy Men Lab | sits _R[osnbeuestst samira Ga
005991
Methyl FOSEA
PhysicaitchamicalProperties
[S037 Sabi ofMeFOSEA Tn Aqueous Burs CabAourthaotroorr|y] comaptleeted
Tove
pUestiencgtiGonas Chromatography with Atomic Emission
6/14/69 [RToebcuhsnitcaSluRmempaorrty and
Environmenta Fate and Transport ([ODcettaenromiinWaattieorn)ooffhTe-5P96a9r.t4.on Cosfiaert(N-
Tabourtahtaorryof :
Lo
sm Env tab| 19994 [TReocbhunsitcaSluRmempaorrty ard
005992
Ethyl FOSEA
Simonyms: FX.13 81226, 0:1
Erythema rere
Teto| commres =
eosyetmryis ncrasricaitproopatonsat
|Cr pi2ny 0 van. dpen]
21450
| postsummary. eer
Envtonmentat reantTape Fem Sedo TPTEOE
Coavey|| Caoem LL
fi
easy Soseradainy Testor0-1
mCpragay
csccumuaton suoSample 0-1 wit Cap| Ohant
Robust uSmoa, al Rous summary, tal
----
atrryor|| Com =
cue toy ofp13tonesmin | em tab | ari Roa baTsi
005993
Perfluorodecanesulfonate, Ammonium Salt (PFDS)
Synonyms: FC-120, FC-121, LR 42004
PhysicallChemical Properties [p NoneAvarabe e Tab`oAurtahtororoyr|] c] omBpalteeted Toe Environments Fate and Transport
TabAourthsotroorry|] ComBpalteeted
800/COD Testing Resuts Fe-120
[BODICOD Testing Resuts Fo-121:x Summary Reports (oneavaible ----
iPnaccoerporated,
Muinnneapois, sum r[eRpoobrutst summary, ab
LPaabcoreatories,
Miinnc,neapois,
[Robust summary, ab
wn
1187 report
Teb`oAurtshtoroorry|] comBpalteeted
Toe
Ecotosicity Elements [Foxy of FC-TtoW2ieTroXor [Fowety oT FC-1Tos2ca7reXd sud
[Acute ToxiofcEi25t66y-1to Dap magh na(n FC-i 121a -X)
lro[AmceileaTso)it of 26661 1 Fathead Minnow(imephales
aboaurtahtoor| orry] ComDpalteetion
Tove
Tn. Lab
Rosbutmmsaraymshae,et65
Ew. (3b| T0307 | Robussutmmsaurmymahroys.tiT
CLoalbuomrAbaBtioaCr,iMesO,)
Robust s"uompomratry, final
| LaborAaBtoCries, | Calambi, MO)
W588 | Roburstomsufimnmaarreyp.oretxo
mEnsviDriovsisyisotne,
[[SPtiamtiecpAhcaluetse
pTorxoimceiityaosf
FG-120
to
the
Fathead
Minnow,
[[ARneasloyusrtcseIc. Hampton, Ni
ware,
102
[Rroepbourstt summary, final
005994
[stDaatpihcnAiacmutaegTnoaricty of FC-120 to the Daphid [OECD Activated STudge Respiration Tan Test irobies Misrotox Test- F120
EmnsviDiovsiysisotne,
|Raensaoisutrsc,enc Hampton, Ni|_rev.
1952
Rreopbourstt summary, final
Robust summary, Gata
3 Env. Lab
sRhoebeutsst summary, da
005995
BiAbtltiaocghrmaepnhtysoftoPuLbetltiesrhetdo CLi.tAeuraetrurdeatiend3MM'asyP1o8s,se2s0s0i0on
1. POSF - Perfluorooctanesulfonyl fluoride
No literature located.
2. FOSA - Perfluorooctanesulfonamide
Aitmsemnadjaolre,meRtaFb,olJi.tTe.iSntreawtarbtl,ooRd. bMyancnoilndgo,n-acnodlBu.mnViitnajyeacvtiiroansucka.pilDleartyerGmCi-nEaCtiDo.n oJfoGurXn-a0l7o1fand Agricultural and Food Chemistry 37 (1989) 1130-1135. Certohsysl,peTr.fJl.u,oarnodocRt-anGe.sSuclhfnoenlalmmiadnen.(NMEePcFhOaSn)i,smaonfd ittosxmiceittayboofliateunpierqfuleupoersotoicctiadneeNs-ulfonamide (PFOS) to isolated rabbit renal cortical mitochondria (RCM). Toxicologist 9 (1989) 224. Gdirsotsrisbmuatino,n,M.eRli.minTaitsisoune,aannaldypsoitseontfaiafllfuoorribniaotaecdcusmuullfaotniaomnidienpoersatlilcyideex:pAosneedvraaltsu.atMioSn Tohfesis, UniversityofGeorgia, Athens, 1990. Lfloufogrroeanl,ipCh.aSt.i,c Ws.uAlf.onBeasntkos,thRe.Kr.edViamnpdoerrteMdeefirr,e aanntd, SDo.Fl.enWoiplsliisamisn.vicRreasi(dHuyamlentooxpitceirtay,of some Formicidac). Florida Entomologist 72 (1989) 140-146 MSualnfnliunrgam,iRd.,0a,,uJn.iVq.ueBrpuoclkynfeluro,rMin.aEt.edMiisnpseacgteilc,idea,ndinJ.tMh.e rBato.wDernu.gMMeettaabboolliissmmaanndddiDsipsopsoistiitoinonof 19.(1990) 205-211
Schnellmann, R.G., and R.O. Manning. uncoupler of oxidative phosphorylation.
Perfluorooctane sulfonamide: a Biochinica et Bicphysica Acta
structurally 1016 (1990)
novel 344-348
dVealnadyeerd-Maecetrio,nRi-nKs.e,ctCiSc.ideLsoffogrrecno,ntarnold oDf.S.olWeinlolpisaimss.inFiilcutoaro(aHlyimpehnaotpitcesrual:fonFeosr:miAcindaeew).clJaossuronfal
of Economic Entomology 78 (1985) 1190-1197.
Williams, D.F., invicta: control
C.S. with
Lofgren, and R-K. Vander luoroaliphatic sulfone bait
Meer. The toxicants.
red imported fire ant, Solenopsis Journalof Agricultural Entomology
4
(1987) 41-47.
3. PFOSAA - Perfluorooctane sulfonylamido (ethyl) acetate No literature located.
4. PFDS - Perfluorodecanesulfonate
No literature located.
5. PFHS - Perfluorohexanesulfonate
No literature located.
00599
BiAbtltiaocghrmaepnhtysoftoPuLbelttiesrhetdo LCi.tAeuraetrurdeatiend3MMa'yP1o8s,se2s0s0i0on
6. N-EFOSA -- N-cthyl perfluorooctanesulfonamide
aAgpapienls,t At.hGe,G,earnmdaSnFc.ocAkbrd-oEalcghha(fDaicrt.yoTpotxeircai:ty,Blsautbtleleltihdaale)e.ffJeotusr,naanldofpeErcfoonromamnicceoEnftSoumlofllougryam8i3d (1990) 1409-1414.
(ADpipcetly,opAteGr.a:LaBbloarttaetlolriydaacn)dcofniterlodl.perJfoourrnmaalncoefoEfccoonnosmuimceErnbtaoimtoplroogduyc8t3s (f1or99G0e)r1m5a3n-1c5o9c.kroach
iAtmsemnadjaolre,meRtaFb,olIitTe.iSntreawtarbtl,ooRd. bMyancnoilndgo,n-acnodlBu.mnViitnajyeacvtiiroanscuakp.ilDlaertyerGmCi-nEatCiDo.noJfoGurXn-a0l71ofand
Agricultural and Food Chemistry 37 (1989) 1130-1135.
eCrtohsysl,peTr.fJl.,uoarnodocRt-aGne. sSuclhfnoenlalmmiadnen.(NMEePcFhOaSn)i,smaonfd ittosxmiceittayboolfiateupneirqfuleupoersotoicctiadneeNs-ulfonamide
(PFOS) to isolated rabbit renal cortical mitochondria (RCM). Toxicologist 9 (1989) 224.
Forschler, Argentine
B.T., ants,
LainndepEivtahnesm,aGh.Mu.milPeer(iMmaeytre)r
(tHryemaetnmoepnttesrtar:ateFgoyrumsiicnigdaceo)nt(aaibnsterraiczte)d.
to J.
manage Entomol.
Sei. 29 (1994) 264-267.
Grossman, during and
M.R., Mispagel, MLE, after prolonged dietary
and Bowen, exposure to
aJ.hMi.ghDliystfrliubourtiinoanteadndsutlifsosuneameildimeipneasttiiocnidien.
rats
Journalof Agric. Food Chem. 40 (1992) 2505-2509.
dGirsotsrisbmuatnio,n,MeRl.iminTaitsisoune,aannaldypsoitseontafiafllfuoorrbiniaotaecdcusmuullfaotniaomnidienpoersatlicliydee:xpAosneedvraaltus.atMioSn Tohfesis,
University of Georgia, Athens, 1990.
fLloufogrroeanl,ipCh.aSt.i,cWs.uAl.fonBeasntkos,thReKr.edViamnpdoerrteMdeefirr,e aanntd, SDo.lFe.noWpislilsiaimnsv.icRreasi(dHuyamlentooxpitceirtay,of some
Formicidac). Florida Entomologist 72 (1989) 140-146.
SMualnfnliunrgam,iRd.,Oa,,unJ.iVq.ueBproulcykfnleuro,riMn.aEt.edMiinsspeacgteilci,dae,ndinJtMh.e rBato.wDernu.gMMeettaabboolliissmmaanndddiDsipsopsoistiitoinonof
19.(1990) 205-211
PNraobtbeienf.eldA, tDhJe.sisAnsubImnvietstteidgattoitohnoefGtrhaeduEaftfeecStcshoofoFlloufotrhoechUenmiivcearslistoyonfMLiivnenreFsaotttay,AcApirdi-lBi1n9d98i,ng
aRcetiido,nBi.Ln.s,ectGi.ciWd.e,Baegnanientstt, tahnedGSe.Jr.mBaanrccaoyc.krTooapcihca(lDiacntdyooprtaelrtao:xiBcliattytlolfidSaucl)f.luJroaumrinda,l aodfelayed-
Economic Entomolo8g3y (1990) 148-152.
(SDcihcatly,opCt.erSau:lfBlluatrtaemlildidraees)is(atbasntcreacatn).d vJ.apMoerdtiocxailciEtnytionmfoilelodg-yco2l9l(ec2t)e(d1G9e9r2)ma2n07c-o2c1k5r.oaches
uSncchonueplllemraonfn,oxRi.dGa.t,iavnedphRo.s0p.hoMraynlnaitniogn..PBeirofclhuiomriooccateatneBiscuplhfyosniacmaidAec:taa 1st0r1u6ct(u1ra9l9l0y)n3o4v4e-l348
eStchhynleplelrmfalnuno,roRo-ctGa.neThseulcfeolnlaumlairdee)ffoecntsraobbfaiturneinqalueprpeosxtiimcaildetuSbuullfelsu.rTamoixdic(oNl-ogy in Vitro 4 (1990)
71-74.
005997
BiAbtltiaocghrmaephnytsoftoPuLbetltiesrhetdo LCi.tAeruaetrurdeatiend3MM'asyP1o8s,se2s0s0i0on
cSmoictkhr,oaLchMe,s
(ADpipcetlyo,pAteGr.a:
TBloaxtitciidtayc,)r(eapbesltlreancct)e.,
aJ.ndEceoffne.ctEsnotfomsotla.rv8at9i(o2n)
compared among (1996) 402-410.
brown
SSutlufmupr,amDiGd;oNnePmreec-,anMdDP;osHtolnsatoanl,DIeF;vePlioccpamreinllto,, MVaJt;urMaatrieosn, aJTn.d FSetrutidlyiotyfitnhethEefRfaecbtbsitof
Toxicology (1997) 357.
FS1u7o,5r.mNo-sYa.n, aanndd cRaHs.teSmcshuebftfrearhrna.neLaanbtoerramtiotresy.eJvoaulrunatailoonfofEctownoosmliocw-Eancttoimnogltoogxyic8a4nt(s1a9g9a1i)ns1t70-
aSgua,iNn-st-Y(.w,oansudbtReHr.ranSechaenfftrearhmni.teTsopxeicciietsyIasnopdtelretahRalhitniomteeorfmiNt-icdtach.ylFpleorrfilduaorEonotcotmaonleosguilsftonTaLmide (1988) 73-78,
aSgua,iNns-tYs.u,blTeorktoarnoe,anM.t,eramnidteRs (HI.soSpctheerfafrRahhinn.otEesrtmiimtaitdiancg) o(rabasltrtaocxti)c.ityJo.fEscloonwo-maictciEnngttoomxoilcaongtys87
(1994) 398-401.
SU.uSl.flEurPaAmidO.ffWiacseohfiPnegsttoinc,iDdeCs
and Toxic 1989.
Substances.
Pesticide
fact
sheet
number
205.
United States Air Facility. 5 pages.
Force,
Tyndal
AFB,
Florida.
Environmentally Acceptable
Live
Fire
Training
dVealnadyeedr-Maecetiro,nRf-lKu.o,riCn.aSt.edLotfoxgirceann,tsa.nPdeDstFi.cidWeilSlciiaemnsc.eC1o7nt(r1o9l8o6f)S4o4l9e-n4o5p5s.is invicta with
odVfealEnacdyoeernd-oMamecietcrio,EnRn-itKn.so,emctCoiScli.odeg7Ls8yoffog(rr1ec9no8,n5t)arno1ld19oD0f-FS1o.1l9eW7in.lolpisaimss.inFiilcutoaro(aHlyimpehnaotipctesrualf:onFeosr:miAcindeaew).clJaosusronfal
i`nWviilcltiaa:msc,onDt.rFo.l, wCi.tSh. fLloufogrroeanl,ipahnadtiRc-sKu.lfVoanendbeairtMteoexirc.anTthse. JroeudrinmaploorfteAdgrfiicruelatnutr,aSloElnentoopmsoilsogy 4
(1987) 41-47.
7. N-MeFOSA -- N-methyl perfluorooctanesulfonamide No literature located.
8. N-EtFOSE alcohol - N-ethyl perfluorooctane sulfonamidoethanol PNraobtbeeifne.ldA, tDhJe.sisAnsubImnvietstteidgattoitohneofGtrhaeduEaftfeecStcshoooflFloufotrhoechUenimviecraslistyonofLMiivnenreFsaotttay,AcApirdi-lBi1n9d9i8n.g 9. N-MeFOSE alcohol - N-methyl perfluorooctane sulfonamidocthanol No literature located.
005995
BiAbtltiaocghrmaephnytsoftoPuLbetltiesrhetdo LCi.tAeruaetrurdeatiend3MM'asyP1o8s,se2s0s0i0on
10. N-EtFOSEA ~ N-ethyl perfluorooctane sulfonamidoethyl acrylate No literature located.
11. N-EtFOSEMA ~ N-ethylperfluorooctane sulfonamidoethyl methacrylate No literature located.
12. N-McFOSEA ~ N-methylperfluorooctane sulfonamidoethyl acrylate
(Laabswtsroacnt,).R.JG. ,ChJeurms.,
P.C. Inf.
Cluster Comput.
Saenia.ly3si0so(f19a9c0r)yl1a3t7e-s14to4.guide
sampling
for
toxicity
testing
Lawson, RG, (erratum). J.
Jurs, Chem.
P.C. Inf.
Cluster Comput.
aScnia.ly3si1so(f19a9c1r)yl3a6t1e.s
to
guide
sampling
for
toxicity
testing
13. PFOS~ Additional references on Perfluorooctane sulfonate
PFOS
sStchhynleplelrmfalnunor,oRo-cGt.aneThseulcfeolnlaumlairdee)ffoecntsraobbfit 71-74,
urneinqalueprpoesxtiimcaildetuSbuullfesl.uraTmoixdic(oNl-ogy
in
Vitro
4
(1990)
PFOSH
alDcieviredbrseml(,iabcMsrt.ro,ascHot)om.seosBkbiaoywlavo,agriMic.oau,ls&SpaetProhfhal,ruTomr.aicnDeaiutftefidecrfaealtntcByeuaslcliiendtsit,nhem1e9it(na5db)uocl(ti1ic9oa9nl6ol)fyc7ia6nr5eb-rot76sd7ye.lreisvatteirvaesseofRLfAattiyn rat BPHieaorucfghliuhmoo.rmo,oBciBto.ap,nhoayisnc.dAAOcc.tiaSd.p(y1dP1eF2vO8o[Al1)d],.(P1Te9hr9ef2l)Muoe6r5co.ho7ac2nt.ainsemSUunldpehrolnyicinAgctihde (HPypFoOlSiAp)emaincd ECflfoefcitbroifc Acid. wHietnhwoliotdh,iuSm.pMe.r,flMucoKreoeo-cPteasneiks,ulPf.o,nCaotseteilnlroa,bbAi.tCs.(sObssitmraict)z., TT.eGr.atDoelovgeylo4p9m(e5)nt(a1l99t4ox)i3c9i5t.y study pCeorstfelluloor,ooAc.tCa.n,eHseunlfwoonoadte, i$n.rMa.b,biOtssim(iatbszt,raTc.tG).. DToexviecloolpogmiesntta1l4(t1o)xi(c1i9t9y4s)tu1d6y1 with lithium sHuartfoa,ctMa.n,tsanindwSahtienrod(aab,stKr.actS)o.luNbiilpiptoynanKdagcraiktiucaZlamsischeil9l1e(c1o)nc(e1n9t7r0a)ti2o7n-s3o1.f fluorinated ((Hp1ee9,r9fM0.l),u7ora3o9no-dc7tF4au2n,.eXs.ulfKoinniectiaccsida)ndcaltianleyazrefdreeesteenriefrigcyatrieolna(taibosntsrhaicpto).f sWuipierHacuiadxPueOSXiAebao 6(6) liHvoesromkiacwrao,sMo.m,esanbdyTp.eSraftlouho.riDniaftefderfeantcteysaciindst.heXeinndoubcitoiroincoafc2a3rb(o1x9y9l3e)s1t1e2r5a-s1e13i3s,ozymes in rat 4Ik5e0daa,ndT.p,eKr.oxFiuskoudmae,pr1o.lMifoerria,tiMo.n iEnnroa moltiove,rTb.yKpoemrafliu,orainndatTe.dSoucgtaa.neInsduulcpthioonniocfcacyitdo(cPhFrOSo)m,e P-
005999
BiAbtltiaocghrmaepnhtysoftoPuLbetltiesrhetdo LCi.tAeuraetrurdeatiend3MM'asyP1o8s,se2s0s0i0on
P1e9r8a7,xi3s0o4m-e3s08i.n Biology and Medicine. H.D. Fahimi and H. Sies, Eds., Berlin: Springer-Verlag, soKtforpzueucrtkouaxr,eisHa.onmdaYilanmdfaautdctiayn,agcJ,iacdtHoioxvriiitdeya,t(iaSob.ns,-tWrraeaclttaa)t.neadBbeieon,czhTy.em,me.SsuPgihana,rraTm.a,lciIovklee.rdab4,y1T(d.4r)uCg(hsa1r9ra9ec1lt)aetr6ii1os7nt.si6hc2iso3pfs,ibnedtuwceteinon fLoyrocnh,arPa.cA.t,erTiozimnegr,flKuo.rBo.a,lGkranoesssu,lfMo.nLa.tesF.astAnaatlo.mCbhoemmb.aSr7d(m1e4n)t(1a9n8d5)ta2n9d8e4m-2m9a8s9.s spectrometry aRneamedreob,iAc.c,oanndditDieonbsus(,absR.tracBti)o.deCgrhaedmaobsilpihteyroef3f2l(u8o)ri(n1a9t9ed6)su1r5f6a3ct-a1n5t7s4.under acrobic and 1sS0uolhbfleoennaiifcufsea-cc,tiedAd.ibKs.ya,ppAeotrMeo.nxtiEsirnoidmkuescspeorrnoo,lfipCfe.errHaotoxogirssstoirnmoamml,oufMsa.tetKyliiavmcelri.adnPBdh-,oaxJrimWda.actoiDleopnoigeayrnrdae.notdPheeTrrofralicuctoiorvliootogicyets7akn2enown (1993) 90.
PFOS.K salt
BPurbolwinc,HeR.aBl.thTEhnegiTnreeeraitnmge,ntUnainvderDsiistpyoosaflNoefwAqSuouetohusWaFlielsm,FAousrtmrianliga,Fo1a98m6., Masters Thesis in
tCraevaaltlmie,ntL.p,laAn.t.GeEllnevriar,oannmdenAt.alLaTnodxoinceo.logLyasanrdemCohveamlisatnrdyb1i2od(e1g9r9a3d)at1i7o7n7-i1n7a8w8,astewater
fCihraenf,igDhtBi.ng faonadm.ESEKn.virCohnimaen.ntaElcoPrnoogmriecsssofmNeo.mb2r, aMnaeyt1r9e8a6t,me1n0t4o-f10w9a.stewaters containing
3Ch4a7n8,-0D6B,.CivDiilspEonsgailneoefrwiansgtLeawbaotreartocroyn,taNianvianlg Calif. 93043, April 1978, 19 pes.
aqueous film Construction
BfaotrtmailnigonfCoeanmte(rA,FPFoFr)t.
TM No. Hueneme,
M-
BcCahhteatmnai.lciaDolnB.pCreonDctieessrps,oessPa.olrotTfHMwuaeNsnot.eemwMea-,t5e4Cra-l7ci9fo-.n1t9a93i,0n4Ci3in,vgiaSleqEpunte.goiu1ns9e7ef9ri,iln2mg1fLopgarsbm.oirnagtofroya,mN(aAvaFlFFC)on-sibryupchtyisoinco-
N(CohA.aFnFM,F:)-D5.-4B-A.80Ts-ouxm1i0mc,aCsriuyvboisltfaEpnnrcgoeig:nreeDesirssiptnoogsadLalatboeofrwoanatsodtreeyvw,ealNtoaepvrmaelcnoCtnotonasfitnarilulncgAtaiFqonuFeBoatutrsteaafltiimloemnntfCoepnrrtmoeciren,sgsPefosor,atmTM
Hueneme, Calif. 93043, August, 1980,6 pgs.
UfChSoia:amnN,(aABvF.ySF.FCKi).v,iwlTasEPtn.egsiWnfueore,rriaenncgdovLRearWbyoo.rfatRiootrswyla,acnPtiodvr.et iHMnuegermenbdeiremanetn,se.CtArGeea9ot3rm0ge4in3ato,IfOnascttqi.utue1to9eo8u0fs,fT1ie0lcmphgnfsoo.rlmoignygfor
E1Dn9av9r5iw,rion6n,7m-Re7.n3t.L:.,AR.DeE.licOatttemaBna,laEn.ceC.. NNaotrimoannal,FJi. rEe.PGroottte,catniodnCA.sPs.ocHianaatuisoknaJ.ouFrnoaalm, aMnady!thJeune
PDliaMnta.io1,0pLe.raRt.i,oannsdPRr.ogFr.eLsasn3ge(.19E8f4f)ec4t2o-f46W.ater Quality on Fire Fighting Foams.
006009
Attachments to Letter to C. Auer dated May 18, 2000 Bibliography of Published Literature in 3M'sPossession
RpHriyoldjtgeocent.,NaPTt.riDeo.pn,aarlaenLddafbJoo.rrF.atthWoearlUyk,SerAA.uigrE.nFvo1ir9r8co9en,um5ne5dnetpraglsI.nstteudriaegsenicnysAupgproeretmoeftntheDOliEve 1fi4r8e9t-r1a4i8ni9n-gAlfacbiyliOtiaeks
Johnson, J.D, S.J. Gibson, and R.E. Ober. Cholestyramine-enhanced fecal Carbon-14 in rats after administration of ammonium perfluorooctanoate or
elimination potassium
of
perfluorooctanesulfonate. Fundamental and Applied Toxicology 4 (1984) 972-976.
Kroop, RH. and
Technical Report
J.E.
No.
Martin. Treatabilityofaqueous film-forming foams
AFWL-TR-73-279, Air Force Weapons Labor
used
for
firefighting.
New Mexico, 87117, Feb.
1974, 94 pgs.
atory (DEE), KirtlandAFB, Available from NTIS, order no. AD-755 336,
fLoarntdroena-tmAemnotlodf,waS.s,taenwdatDe.rB.coCnhtaani.niAnpgpalifciarteifoignohtfirnogtaagteinntg (bAiFoFloFg)i,caulndcaontteadcrteopro(rtR,B/C7p)gpsr.ocess
Landon-Arnold, S.E. Microbial treatabilityof aqueous film forming foam (AFFF) with a
chemostat and a rotating biological contactor. Ph.D. Dissertation, University of Oklahoma,
4N8o1r0m6a,n8,0O0k-l5a2.1-908620.0,(UOnridveerrsNiot.y83M0i2cr4o5f2i)l.ms International, 300 N. Zeeb Road, Ann Arbor, Mich.
McKay, J.C., August 1988,
and B. 457-8.
Mason.
Improved
fire
training
facility
plan.
The Military Engineer $23
Mueller,
fighting
J.A.,
foam
E.-W.
waste.
Poth, and
Regional
W.W. Melvin. REHL(K)
Environmental Health La
b6o7r-a1t4orBiyo(lAogFiLcCa)l,trUeSaAtmFe,ntKoeflfliyrAeFB,
TX, 78241, Sept. 1967, 38 pgs.
O'Brien, A. F. Treatmentof Aqueous Film Forming Foam (AFFF) Wastewater at Andrews Air
Force Base, Maryland. December 1, 1994.
Masters `Thesis, University of Maryland, College Park, Maryland,
Saam, R-D., P.A. Rakowski, and GM. Aydlett. Treatabilityoffirefighting school wastewaters:
U.S. Navy Compliance with POTW pretreatment Purdue Industrial Waste Conference, undated, 40
requirements. pgs.
Presented
at
the
34th
Annual
Salazar, Review
S. M. Toxicity ofAqueous and Biological Assessment.
Film Forming Foams to Marine Organisms: Literature Naval Ocean Systems Center, San Diego,California,
`Technical Document 825, July 1985.
aShnidnloidqau,idK.m,ixatnurdesT.. NBoamsuircas,tuMdiisecsoifbioliiltyroefpfelluleonrtoacanrdbfoinreaenxdti`nhgyudirsohcianrgboangesnutrsf.Jacotuarntnsalinomficelles
Physical Chemistry 84 (1980) 365-369. S1Vce9an8tl6uel-MlNio,ocrvRoe.cmoMbs.emsrB.i3o0Dd,eegp1ra9a8rd7t,amte3in4otpnoaogffeBsAi.qouleogoyu,sUFniilvmerFsoitrymoifngDaFyotaomn,CDoamyptoonn,enOtH.in NLoavboermabteorr3y0,
PFOS.Lisalt
Costello, Henwood, and Osimitz, Sulfonate in Rabbits" (abstract)
"Developmental
Toxicity
Study
with
Lithium
Perfluorooctane
006001
BiAbtltiaocghrmaepnhtyosfPtoubLeltitsehretdo CLi.tAeruaetrurdeatiend3MMasyP1o8s,se2s0s0i0on
EPA, "New Pesiicide Fact Sheet; Lithium Perfluorooctane Sulfonate (LPOS)" (abstract)
SHuelnfwoonaotde,iCnoRsattesl"lo(aabnsdtrOascit)mitz, "Developmental Toxicity Study with Lithium Perfluorooctane
JMloiautshrinuuadml,otefHtC.r,oadlNel.coyikldesdaunsld,fIantMte.earAnfrdaatlcoietnShoic,uiSme.npcKeearnf1le5us4ohri(on1oa9c,9t2aa)nned45sK4u.l-f4Mo6on0a,ttoemirnat.heSatdusdoyrobnedtfhielmmimsycicbcillliety of
eeSnnhttihinaoaldlpaym,iacKn.e,dllMee.nctoKrnoocbpeyaonytfarsashtoiil,ountaionofdnlNoi.ftphYaiaruammfapfgeiurncfchlhuiao.ironEofccfoteacmntpeoosufuln"fdioscn:eabtTeerh.geJ"oefufofrrencmatalotfiOoftnoePmhfpyweartaetruroenonthet.he
Chemist9ry1 (1987) 5292-5294.
sical
pbTeeahrmafovrliiuo,orrKao.no,d-cKdt.yannKaeimshiaucrlafp,oronHp.aetrSetai/neddsai,ientKm.hiaExnseoudlmhsiey,psKtt.eamdMseeocgfauafrnloiu,oonCri.ocT-ah2nu-dnuincgad,teiacoannamdincmoHosl.umnHreioftafcftmaanntns.ltPhhiausnes
S{cDieEnFceU2M7A0Q(1a9n9d2)li8t8h3i-um89d3o.decy sulfate DEFUMAC aqueous mixtures. CoulhamynlcdhPlooorliiydmeder
006002