Document 5bQEb9LBYqeQY5gaLkM1M4770
2277666..00000011
Exhibit 2766 33MmAAo022552277224433
EE Date
3/10/71
|
S5I./17./a74
16.0/1/08/855
||
Lo
AAttttaacchhmmeenntt 8 33MM CCoottttaaggee GGrroovvee PPFFCC AAiirr PPeerrmmititttinng HHiisttoory
-- -- Description
MPCA issues permit covering all air emission "exhaustive processes" at
a SE Se | Chcmolite. (Permit bears a notation added in 1976 indicating that this is
| heros tern conte ciet e the air permit tbr all of Chemolite.) The "Process Information" section of the permit refers to five "fluorination cells," which produce "organic fluorides." Six stacks were associated with this process, tt also notes that two cells were installed in
a remadn e a nts al 11995544,, ttwwooiinn 119957 and the fiifftthh in 1996622.. EExxhhaauusstt vvoolluummee ffrroomm tthhee cceellllss
is noted at 120 sclin, and a handwritten note indicates installation of a scrubber system adde.xt to two ceils in i974. Annual operating rate is listed as 6,000 hours.
MMPPCCAA iissssuueess PPeerrmmiitt ffoorr S3MM CCootttaagge GGrrove ppllaanntt.. TThhee ppeerrmmiitt ssttaatteess::
"Pemite's Prost Emenee ypc eso sols "Permittee's Production Equipment are three (3) process reaction vessels
uscd to fluorinate organic compounds. The process emissions are
mi ites pt pls hegre mise estimated to be 8 Ibs of acid vapors from each process vessel." ]'he o pa fomehr rs v" permit also describes the control equipments as follows: "The air
pollution abatement facility.., is a double scrubber system consisting of aa ccoouunntter ffllooww wwaatteerr spray ttoowweerr scrruubbbbeerr,, ffoolllloowweedd bbyy aa ccaauussttiicc//wwaatteerr connter flow spray tower, Teflon lined vent gases lines, and auxiliary,
LCotn MbRA Lenn veets nc ndly equipment." MPCA also notes that "[sJpccifications and calculations fe t ot pets ad os. submitted by Permittee indicate that all emissions from this facility will TE be in compliance with all Minnesota Pollution Control Agency
Regulations."
33MM ssuubbmmiittss aaiirr ppeerrmmiitt aapppplliicatiioonnffoorr aa ""nneewwfflluuoorroocchheemmiiccaalt ddiissttiillllaattiioonn
system to be instalIed at 3M's Chemolite plant."
The cover letter notes that emissions from this system arc fluorochemical
re be rm ena Buin vapors, ammonia and acetone." (Emphasis added.) Specifically, the
permit application notes estimated emissions of PFOA of 0,97 lbi]~r when
fo? operating. s | bom Tan te rc sme | MPCA later informed 3M that "[b]ecause the organic emissions from the mos spaem ses n i sore | [fluorochemicai disdllatien system] are below 25 tons pcr year...no n ems lon 3one vr no construction or operating permit will be required" for the new distillation
brent i | unit that would emit PFOA.
22776666..0000002
3MA02527244
[me TT agi Date | pilosa reactor systems ad wo ot ee chases ch |! || ocraoucsthiocmsicrcuablbecrl.l" prAopcpelsisca(tpieo.n5i)ncludes a diagorfathme 1/2/87
Description 3M submits an air emissions permit application for the pilot center
| ffaacciilliittyy 1to0bbeebbuuililtt aatt CCoottttaaggee GGrroovvee.. ""TThhiiss aapppplliiccaatiioonn covveerrss ffoouurr nneeww
pilot scale reactor systems and two pilot scale fluorochemicals cells with a caustic scrubber." Application includes a diagram of the fluorochemical ceil process (pg.
| hEe aplication includes ow grams showing the process equipment The application includes flow diagrams showing the process equipment. nis Tom he rch eos conto sco Emissions from the fluorochemical cells are controlled by a caustic | cernote,omiminons fh (he estore yon st and scrubber, and emissions from the reactors are reduced by vacuum jest and
a vent condenser.
The sample emissions calculation indicates that the emissions from the
cKoll bad ona wars cue" amison sensi ouigne s oy celI based on a "worst ease" emission scenario would be less than 3.29 ns eraof ns and recompense tous per year of inerts and "lluorocompounds in the form of CnFn+2, heen To where n ~ 1 to 4.
Diviion Bey a Cones Grove S8/T1A4/R8T7
| 33MM ssuubbmmiitss saiirr ecrmviissssiioonnss ppeerrmmiitt aapppplliiccaattiioonnffoorrtthhee. SSppeecciiaallttyy CChheemmiciaclasl.s
Division facility at Cottage Grove.
Included inthe "Descriptionof ity nd Principal Business Activity" Iilcluded in the "Description of Facility mad Principal Business Activity" Scion (3) is stent k(t pon po section (pg. 3) is a statement that "[t]he principal products produced are hci nd Rorochemenis adhesives and fluorochemicals."
Ae pia resto syst as chemicals chal nt the actor. fs "A typical reactor system has chemicals charged into the reactor. It is n tl nd pt andr vs, he vo pn then heated and put under vacuum. The vapors are separated using Vacuum ft ad onder a core vacuum jest and condenser and are collected in the decanter or receiver. Thaengeser acto blethne dsheid rnodg Tees The receivers are used for blending the finished product.... The reactors h o om 0 ainsi gahons- Tae scion ner range in size fi'om 70 gallons to 6,000 gallons." This section also notes a her as 19 troche ees ocd in B12 that "It]here are t 9 fluorochemical cells located in Building 15."
ef rt ne ttn re isi "Two water scrubbers have been included to reduce the acid emissions
a om he Morochernies cll. Ti ieof msi un psd from the fluorochemicat cells. This type ofinstallation is currently used mcthe Marochmca roductegdpmen. The seo oa on other fluoroehemical product equipment.. The scrubber is added as a Sy procurombecasy othe sche mcs wads safety precaution because of the acidic nature of HF and also used for enon edu acid emission reduction."
[Sasf hippo sho fo dams pi |
Pages 6-7 of this application show a flow diagram of a typical
| fflluuoorroocchheemmiiccaall mmaannuuffaaccttuurriinngg pprroocceessss.. TThhee eemmiisssioonns ccaallccuullaattiioonn
| s wortcae coinsof 173 omen ash |
cceeeslltliissm._ aAtAesss
iiwnnoecraasrrtll-iiceearrsppceeerrmmmiitistsss,,iotthnheessosuufbbs1st7ta5anntccoeensss/ecymmeiaittriteeoddfoffrfrofomgmastthchees
from the
cceellllss aarree.
inns sd Thorocompounis be form of CoveS hee 4 "inerts and "fluorocompounds in the form of CnFn+2, where n = 1 to 4?'
| | Th application sso estimates the efcienyofthe scrbbers as 990%. | L The application also estimates the efficiency
--
of
the
scrubbers
as
99+%.
1]
2
22776666..0000003
swaazszrzss 3MA02527245
bse pe 1T00D//11a00t7/e8895 |MMPPCCAA aauutthhoorriizzcess tthhee iinnssttaallllaattiioDonnesaacnnr~dip0otppieo~rnraattiioonn oofafa cce~llll ooffff--ggaas sscermubbbbeerr
en condstng of wo suber) or Bldg 15.3 Spity | system (consisting of two scrubbers) for Building 15 at the Specialty
Chemicals Division a Cota Grove. Thi dua scribes sytem. !
|
replaced an arles scrubber Chemicals Division at Cottage
replaced an earlier scrubber.
Grove.
This dual scrubber system
| The Overien section under "Faily Description on pags 2) nes that The Overview section (under "Facility Description" on page 2) notes that
Specialty Chemicals producesa varity of roche, nd HF |
iS8spuuessceeidadltaayss. Ca hrraeawmwimmcaataletsreirpairalo.l.du"c'Thesheeaeevxxahhraaiueustsytt
of fluorochemicals, and that HF
ggaass aallssoo iinncclluuddeess uunnrreegguullaatteedd
Nuorocarbons ht sr by-products of the uorochamical procs fluorocarbons that are by-products of the fluorochemieal process,"
T2890 11/22/89 S070 03./07/90
pSrpTTrihuhioeeobrFF0etaao1crci9i1ll6wi9i8tti6yy,t8DDh, ecacesoosdcnncrtsrtiriripopoetltlniilloeoefdnndibabaclyiisyooeanipdpcdaaeyeccnnokktiefeifddei9esttsoo9w22w00e%errfSlccuuoooouurrnmooitccechhrrecemeuiurcirrcaeaelntntccwwellaislst,et, riinnssttaalllleedd scrubber with a dcsi~ efficiency" of 98.9%.
MosMfourPrPdCcdtCreeAAnasctrameuuleutehniaotsmorheoifzffeoehyosycfimtdhhhnroezofggritseeneonstnctsaahflllelluoamoltriiroiidcdnoeaeaaln(n(nHHadpFFrop)o)pceereexxsrhahsaataiauuiossunttoopoggfnmafasestwoeensstowinwtnahetatht0reerscersvoceunrSnutpbtbeoboecerfirrsaasly
Chemicals Divison sudden release from
Chemicals Division
st Cotage Grove fluorochcmical process
at Cottage Grove.
equipment
at
3M's
Specialty
lcaMMlttPPernrCCnnaAAatitiaavvmmeeneecppnnpooddellslsruithtaihieiooennoCCnccoootoatttnntaatthrggroeeealGGSysrpyroeostvcsveieemlpptl""ylapaon0nnCth'tteshhmaeepi~fucrlaaumlroiirotDocitcovhhieaesslomnilomowiwnceaos~oflppcceeelrlcalsstiiTo~n 3of7a3n Cheol" currently in operation at the Specialty Chemical Division of 3M
Chemolite."
TGThFhee)ppewerirmlmliitet nnioottness ttihnhaaottpaaernnateeixsoisns.itinnTgghsseccrrnuuebbwbbiiynngg sssyysstteiemsmmffeornrdhheyydddrrootoggeesnncofflvlueoorrriidHdei
(HF) wilt remain in operation. The new system is intended to recover HF
GGETOT 06,/27/91
ffoorr rreeuussee..
"nTTohhteespppeeerrcmmiifityt aalssmaasmmeefnnoddreeoddthseeetrtssuamorneuomcrheeriimcineemiasiseismoioinnvssiolliimmm.iitt oonn HHFF bbuutt ddoocess
not specify limits for other fluorochemical emissions,
| awaMPinnlPddClCoosApApeeerrrifeasaistttiuieoohesnnsroeoaififerxrteheiemmrseiteieissnssnmgiieoeohwnwnydpphhreyyeorddmgnrreooiFntgg#eefnn2Eo3ffAlruSoCoerr-ir9Addejea-7cI((iCtt00H-oI-FrF!))rseofscoecrraeruvN3bbe/ivbele;ssrssS.yi,ns"stwthaehllmlicsacat.hiooTnhe will serve three existing hydrogen fluoride reactor/receiver systems." The pfervmit lo ote hat the scrubbers ar being inlod vata by permit also notes that the "scrubbers are being installed voluntarily by 3M."
rSsCSeeeeaacrccctttoiiuoorornsnses.s.""11w.TT22.h1hI-eie-333nndeetiiedwwsdeinehssgctcnnirrftuyuebbfttbbhfeehierrcsseeimmeaanirricseesyssppii"oaao9cncnkk5uuee%nddniitttsootwawasseerr""ccfMolouuumoonrretoconcraecarurubbrmoroeennnntwwowworaratkkteeuurrpp
scrubbers with a design efficiency >95%.
3
22776666..00000044
amczszrass 3MA02527246
Date
|[ 70095 [NeoFeeCAnicsppnayrm rpieenv~Aennedmir es 3 ebper 07/00/93
TT -- Description
MPCA issues permit amendment. "'Amendment number 2 to this permit
|ofsome ofthe actrochemical els by increasitnhge amperage that cach allows the company to replace several tanks...and increase the capacity of some of the electrochemical cells by increasing the amperage that each
celt can handle."
|| THThFheewppielelrrmmiinitetraaelsassooe,nnootthteeessaltthlhaaottw.,awwbhlhieitleenitthsheesiaaocctntuusaallwisslhhloonrtotttteecrrhmamneegemm.iissssiioonn rraatce foorr |N0G4T-- /1779/955 --| SM3HaM-- IMt-'ewssruiuiablbllmmsi-- initDcssirevppaiaasrsreto-- ,77nt00heppeearrlmml-- oiiwtt apabppllpeil-- icecamattiiisoosnnio-- fonorsr wtIhiell-- CCnooortttaacggheea-- nGGgrreoo.vvee-- SSypeecciialltyy
Materials Division.
aFfFllroouuerroommrmroancGGouhLcIte-0hum01c1e,iu,cmraFFeilaadcccc.eceialllililltsslyiiIInnnnBBffoouurriimmlkadadtitniniooggnn,11,35iinniidndniiwwccaahhttieeiccsshhtthfhfalltutuoottrrhhiieennrraaeetteeasddrrehyssydttdriilorlloc11ca99arrbboonnss
are manuPactured.
FFnFFiooootrrrrmmsmmaGGsTIsAIA0o--0c200i2U1atppllerridsosotvvsswiiiddfftleelhuussoolpprruiirrdoodoereccoeeeecsmmshsieisflsmslsoiiiwwcooannlddrriiapaaetrggeosrrsdaafumfmocosstr,,issoinppnnele.ccculiTiufdfhdiiicceinnseeggmmdfifoiossisrsiithoohaennessseeuummniiiiitssnt.ssdi.iioocnnastse b"batuhheenacaitccttlsootthhnna,ettslsooBBaollurucleileiiladldsddtleiibbndnoyyggswssel1ccri55rrtuhuabffbblfblbubleeuuoerroorrsrcsor.o.ooccchnhFFheteuuemmrrmirotihccliraecall,ral,.lccttpeehhlrleellodraraeenunaaddccctttriroooeerrnaasscc. ttiiToonnrhrBBesy~sysueastitldieedimimannsggsrcca77o0m0o,n,nsthttihnienieudneppiiictltlaoooottte FFFfaooocrrrimlmmityGGG,ILI-a-O00re?33 appllirrssoootsvvsiifcddlreeuussobrffibaadeccerii-lleciimttoyiynsaatsrinnooddlnlsevv.deen.ntt ddiiaaggrraammss..
Form GI-07 lists fluoride emissions.
TT795 06/I 7t96 | S3MMtnhnoetoCitofifitieetssagMMePGPCrCoAAvoeoffiniicttsineiennrtaettnotirioonnt0obburrn noomnbhaazzaarrtdoowuss fTlauaorrimnaatteedd g5a5s at the Cottage Grove incinerator.
OURS 01/24/97
| aai3nnnMcddimnnlleoiiorqqattuutifioiedirde.ssss(tMMhNroProPtouCiCufgAAi~hcoaottfthhfieeoianaadoqqdiuuinnteediaoioocuunlassatlebbsdduuetrmethnaeaeistrlrssssooopyyFmfsslttepeaelmoanmfnsaasttththtoeheTebbuCCuoronotitftcsalgugmoerearyiGGnebrraooetdevvdee ggppalaaasnnestst
|
nerandous duo othe presence ofacetone incinerator. Notification indicates that some
h~ardous due to the presence of acetone.
of
the
liquids
may
be
`
22776666..00000055
| maczsarzer
3MA02527247
[beDate
| 0077/2244/0977
|
|! |
299 6/22/t 999
pi re] MMPPCCAA
iissssuueess
aa
ccoommbbiinneedd
Description ppeerrmmiitt foorr tthhe CCoollltage
GGrrove
chemmiiccaallfafcaicliiltityy.,
PPaagge3e3oofftthhee ppeerrmmiitt ssttaatteess tthhaatt ""I(th]hiiss ppeermstit aauutthhoorriizzeess tthhee ooppeerraattiioonn ooff
apcpcaeemeelslrrelelmmnrfoiidifefttef:st-cedggoddaafMsusueannslsrddecccecerrrhtururbboPP7bb,ceeeehrrr1rmme9imssi9tyyti0ssc2Attaa3eCelnAmm-dcC.e9"Ji-lu69sTTl6-yhhe-2eLmbe1'0Oi,ccto-t-oi1vIn1r09eg9re3isesH.ddusyueaadeTccddrhttoiieOgOvvceniicttnteiteeoowsFsbbelpewwurreoeerrr1Ioie00id,,pep1r1rc(ee99Hvvo58iiF99noo)uus1asanso0lnldyylde|ad |
hose documents and increased he emissions int or SO amended March 7, 1990 and July21, 1993. The new permit
those documents and increased the emissions limit for SO2.
consolidated
|
cleTTllehhiismeemtinpptnseeoatrrctmmoohirricttneeaaxixddhchdadlaruruseecstsest)sls),ele,sssUUanSSnnittidtaatssccvkka11/r66VVi--eeo11nnu99:st
2c22a26co((ssrccrrsuuybbsbbteeerrmeesxxhchaoaunussstit))g,,i2n2g3344of((misistt (traenakcst)o.rasnydsteamnys ecmoinsssiisotinngonotf (rx
or
vTHTeeeixlEeessiscstttrttiiiirnennnocggggco))hwwveeawwamrssiiytihrrctseeaayaqqhlnsnuutciieIerrInmenell.dssdsiiggwwanniniititdffhhiicvcrraaaeennrggtitaaoMMrrudodsdottitdooafinifgliikccqusaaui)tt,iiiddoaonnnffedouueonadnddndmmeyearrateteMMmeririiininsaanslnl,i.oeeRRnxx.hh.uaa77unu00sist0t0ti7i(7nnn.gge1I2w3tt5o5oo00thr.hee
ttF recovery system.
| PS3PeyMeIrsrmtmssieuitmtib.NNmbooT.is.ths32eRR3ArAeCeeq-aCusq9-eo96snu6t-1-3teUIo/M0OsMM-Ps-1tC1ePA00eCkA--sOO11tpopeevrVVraoaaotdtniiiddootnnhAAeiooirfprfaeEaEnrnmimEsEiisliltseeisoccotnindrooePPccsheheeeremrrmiiiictc:a3all5CCetelhllel: scaaeSpssleyeesscsccoohtitccerfoimioicaacett.hdheecdedTommrwwihiicemictataarhhlneladttcchsaheeoetllnleccgsdel3hlhMlliaasnvvaaeseoreriebbeskesieetsplinnelltlroppmiienevinrrtossmmieedararnvvnteiihecnceneettpllffyeyoorrrssmhhotiuutththtiersddroodppwweunusn.rrc.pprooib1Tss"eheehdssee nnassosocctrrt"uutbbhbbeeerrss
specified or mandated in this permit."
| [port silty Io: 16300053 TO/71999 10/15/I999
|oPo33ufMfrttphshsoeeausbbPPeirmrmoooiifccttsesehssaasesppspDDpelelieitvccvreaaeteltliioeoooppnnsmmfcferoeonurnrbtttbthCCeherenssantdtdweirdldrlibttaeaititoonCCootoo0ftftrcacthgoearenestGeGorrclsoocvrvlreuea.ab.obbiTTedhrshseeeiTmppnoirrBiBismamuilaaiolrdrdnyyiisnnggof7700a
slpsppoioeiullmmsroopettteototsssiiiicmezmzheeeeoeddfimineentilhleNNceecolsotcevrvetoeterlhcmmhorbseebecemerhwr,seei,ccrmra1teiu99lc9bs9ce9ba9ue.le.lllblrsTmsyTyxhhisveettisleeelemmmbdi5eitstshhistsaoaniitstoocinwnwgossinniilltfflfroirobbrcleeaftggnhfitliheunnsmeoeooorpdpinpdeieeorefrwawiaetctmiiaootinnisosinosnisnoaf a
oioJelnerelrstetttrrceeeaetrrlgrlgottueooculdahlMMtveiioPomPolnCCainscnAAaarrrleedldqqcayauue.ttilie"elrrsddiinnwAAggpeprttrhriheielelsiiu11nnb99ss99mtta7a7.lli.ltlat"a"ettPPdiiloloeenanaasossofieefnntnshhiooegettsnseeeeiftthisshcccaaatrrtnuuttbbthebbemererreeorssd,aa,irfebbeiuucntnatootaaiorppeneesbrbsmeeitniiinnteasgg
installed voluntarily,'"
1T2/2I8/00S0| 203V5MTatsuu3bbMmiiCtostapappgpesliacGairtiooovnnefTCooerrnttthere.aaddTdhditeoiponrnioTmfaarmynepwurbgpaoghshceoofuheseisiBn bBiguhinloduignegg is |
25 at 3M Cottage Grove Center. The primary purpose of this bag,house is
tAtuutthohtonieetitcctao.isoicnn.nnhtsstettrTTraaodohhlllllleeiaastttthlhliMieoeetotniPntppoceaCaorrrfrftAnntiittoochchtPtuuiieselslssaarbbttmtteaeahihsgatmmthhtaoAoatttuhtuhmttseeeseeerrerre,en,((aabbdPPruruMeeMttnn)n)iiostsoeeAbbmmpppeeieeiiispsrrnnsimmggiiooitciitnnnssnasssottiffararnlrlorlrloeemeemFdggduueevovllxxaooaiitltnlssiuiutotonininnnMttnssagagCrrrePieeeylqmm.y.qui.0uisrs1isrsiiiinnooovggnner |
Attached is MPCA Permit Amendment Application Form - MCP-0I over
Page AQD Facility ID No.: 16300022
s
22776666..00000066
amaczsarzes
3MA02527248
DDataete
I 02003r3eMactsorusbyssteamstoaangiiniygn siezerfaronm p10e0smgialvlospton400.0 galolons,wand a]l | 6/6/2003
EE
DDeessccrriippttiioonn
=
dd3eMessccrsriuippbttmiiooiuntsssattaatttoeetssaltthhfaaattc""il[mimtayn]aounpfueafrcaatctiutnurgriinpngegroomppieetrrraaett-iiaoopnnpssliaactattthhioiissn.ssiittTeehcceoonnssiisstt ooff |
reactor systems ranging in size from 100 gallons tu 4000 gallons, and all
chemicals" associated equipment
chemicals,"
required
to
batch
synthesize
a
large
array
of
"T"TThhehiissPDffaaCcciiliisltyia aarllesssoocahhroocuuhssaeesnsdSSpMMilMMoDtD'pls'saPPnrrooopcceeerssasstiDDoenev,vecwl!iootpphmmbeaetnnctht CCreeenancttterorr((sP.PDDCC)). | crrTaaohnnmeggmiiPennDgrgcCiiennisssiiszazdeeroeffnsrreeooamsmrct55ah ggdaaaenlldllmooipnnnissliotm0toi.ps22l0a0ln00vteggoalalpllileoonrnnastts.hie.o.nP.,+.DwPCPirrthooddbuuacctttciihoonnreofaorcrtosarlsele innttoo
commerce is done at a de minimis level in the PDC.'"
[S005 8/19/2003
||
Ths eqest proposed hat 3 omit to ee Einar sore | Nap3airiMerodceusumiucsitbssimbsioioinotnnsimssnreviinnoneelvvwveeennatst!roobrerrayyeqt.q.cuuhTeTschhtheetG etoorrmueeiuqsqcsuuaseeelssattolptasee epprrpnpalaltiiticecoaanteiismooniniSsksssoetaiaotnrtneeeCassccattthlihecaoautnt,ln3$atMiVoa'nss foorr its
npccoooronndddeeuxenicnsstsatiaottfniiooorinnn,t,vhddoeeelscvcpaaeennsctitibifnnaiggctc,,bhddaiictsshcttiiehllmllcaahittcieioamonlni,,coaeipltec.r.raSetStaiocatatnnnisdodanlarikrpddereoremcemieasscissstsieioisoonnnh,afataccottocorcssuddooat
ptnhhroiiostsdeufixaciictsittlmitfa.yon.ruftIIhunnecsstttseeupaareddec,,difssiappcteecbchiiaifftisiccchaceicmihisietsmisyioiocunnaslafiracnectaagtoocrrtsssiooftantxeewparccroaaeclleccpusurslloeaagtsteertddahmaffotoerorneectaaccucehhrdat
ppcpEErhrrmToooeimccmdseeiusisscscsosiatoeenlmnssMMmauauassnsaniitusunntrffegga.arc.cttthhtueTTeurherhceidiiqassnutagppatirrtMtoioohoagnginrsxrssaaifmaaammnncuccdidlaamilmmltccyeAuuetulctlhhaashtiootineedcdssgvsszemarrbmieelssqqioessuuRsCiirirwoooeennnaddsrrsebboffyypiloorEEmoTmPPgcArAbhbaaanmiitconcnhlheaaonlllgtiytled
(MACT) chemical
(MACT)
standards promulgated ine 199% manufacturing Maximum Achievable
standards promulgated since 1998.
Control
Technology
fTtToohhiccissaallmrcceeuuqltluaahtetoeesdteepimmsrioisuspsssoiieoosdnnetsdso cfrtarhoolamctmu3lttMhahteeecoooeppnemetririasantstuiiioeoonnntssosaauftsr33eoMMmEmaCClloiostsstttioaaogguneerMGsGarrsooottevvrteehsiSSosMfMlwMMmDD,'e.
This method is used to caleulate emissions from all sources at this
osfsfaraeecicmmieiillniii--tttccyyeoo,,dnnwwtstiiiointtfnhhutuowottahuuhrseseeeoeosxxppycceeseertrpapettotmiiiono.onsnnsN,o,oofaafnnEEgddeCCnnnFFeoortootapplwweleereyrlalallattviissooauiniittsaeebddiinlneffBBoocurruiiimmllsododiiidnenoeggllnii77nn00tg.g.oiinTTnrhhaseebhseaeaxtichasxhrt.e-
ddaoffoeoberrtiroteeerttnrhrhamtemetessioidenenreesy3IdodMMefbbvtpw-eyyeslapccc,reiooecifmminsipfcypilclcsluceteoodtiimippnnneegg.grramNamotnainoaoatstlnregy.sires.ianialselEEormbbmafiaalislllfsayassnniTiaoccoveegnnassassislaaffaerrrbrsoooolumvueminnaeddEEmICCttRhihFFsaeesnpipppodrrrrnoooooccfrcceeaesescCssstseCoessssr,sraaaberiteeexfttihohseerte
movingoperations to Cotsge Grove. laboratory level, including analysis of
moving operations to Cottage Grove.
off-gases
via
IR
an.d/or
GC,
i before
o
6
22776666..00000077
maczsarzes
3MA02527249
CT e ai Date | || | Fnnsoaesce nmDwnoed T bPeCy noeeeroE smeenocostnenBe iot T ccoBaomi sioeitien-- | 6129/2004
Description This permit authorizes 3M to operate 3M's Specialty Materials
Manufacturing Operations located at 3M Cottage Grove Center, which manufactures a large variety of products and fine chemicals. Many of these are used by other 3M divisions as intermediates to produce adhesives and fluorochcmicals~ This facility is co-located with Chemical
Process Development Center (CPDC), which is a research and
development.
Tomoyo he iio it hefty aren on str The majority of thc emission uuits at the facility are reactors or reactor hae el a ly ports rc sys!en.ls. These emission units contribute p6marily VOC and HAP nnies: Som fo ely VOC wd AP emlssmns. Some of the other non-reactor emission units are: gnnders, ile: ga nn isin nl rgd, mixers, mills, holding tanks, electric ovens, vacuum ovens, mix tanka, Dse nik, lam co bo pm ve ak. process tanks, columns, centrifuges, boilers, and emergency generators. SOL y fo pons sp md emery ge This facility has pollution control equipment controlling PM, PM1 O, teVEmbna PND SO2, VOCs, and HAPs. 3M requested that one control device (CE 019 Eamon oed me Col ef (CE 01 gas scrubber) be included in the permit, and hence this permit contains e CE mt ndbrei requirements for CE 019, controlling Fluoride emissions.
;
22776666..00000088
swezsrzso 3MA02527250
2277666..00000099
3mMA0Az02s52277225511
AAttttaacchhmmeenntt 99
RelateBBdiibbtlloiioFoglgruraoaprphohcyyhooeffmiAAcrrattilicclAleetssmwwoisittphhhiiennri33cMMF''asstPPeoos&ssseeTssrssaiiononnsport'
Related
to
(as of November 13, 2007) Fluorochemical Atmospheric Fate (as of November 13, 2007)
&
Transport~
A oKKnaaliyiss)ee,rr,,unMMd,,atceettdla.I.,PPhhyyssiiccoocchheemmiiccaalt PPrrooppeerrttiieessooffFFlluuoorrootteelloommeerr AAllccoohhoollss,, ((AAbbssttiraacctt onIy), undated
B. aM MsaabPbuoutrreyyntSSi,,aclettSaaollu..,rAcdeutmomofossPppehhreefrrli~uccorDDienegagrtraeadddaaAtctiiioodnnsMMteoeccRhheaamnnoiitssemmRsseogofifoFFnlIsuu,oor(roAobttseetlloroammceetrrnAAlllycc)oo,hhoollss
undated as Potential
undated
Source
of Perfluorinated
Acids
to
Remote
Regions,
(Abstract
only),
C.Co MaMantadttthLhioieenssg,,-KKrOaO,n,gKKellTaarssamnmseepiieorerJtJr,,PaaonntddenW WtieaeglgmmfaoarnnPFFe,,rEEfvvlaaullouuaratitiinooann3too-effd2EEnnTvveiilrrooomnnemmreenBnttAaalllcEEoxh,capploo,ssuurree (a(AAnbdbsstLtrroaancctgt-oornnallnyy)g),e, uuTnnrddaaanttseepddort Potential_for PeuTuorinated 8-2 Telomer B Alcohol,
D. SSSummrifittahhcwwtiaicncktks,, iMMn.~Poeelttaaalrl.,,BGGeaeerooggLriravaperhpiahcnaidlcaaPannllddasTTmeeammpSpoaormrapalll eTTsrrfeennrddossmootffhPePeeNrroffrllutuhoorrAiinmnaaettreeiddcan and SEEuuurrrfooappceetaaannntAsArricncttiiPcc,o, l((aAArbbBssteteraaarcctLt ooivnnellyry))a,,nuudnndPdaaltateesddm. a Samples from the North American and
E.
PTTrrrooodmmupcp,t,
TTKK,, eettaal.l.,PPotoetnemtiiaall AAccccuummuullaattizoonn in Seasonal Wetlands, Nature 376.
ooffa@ CCFFCC-r-reeppllaacceemmeenntt DDeeggrraaddaattiioonn 327-330, July 27, 1095
Product in Seasonal Wetlands, Nature 376: 327-330, July 27, 1995
F. BaBonoudultEoocmnonnleeotgt,,iIJcCCa,l, Reetitsaakll.,AEEsnnsvevisirrsoomnnemmnetennt5ta(a1ll)RR:i5iss9kk-1AA2ss4sseeVsoslss.mmee1nn,tto1of9f9TT9rri(!fTluuoorrooaacceettiicc AAcciidd,, ITtuummaann and Ecological Risk Assessment 5(1):59-124 Vol. 1, 1999
Go SEElclliliiess,n, cDDeAA&,, eTettealac.lh.,ndAomlitmoogsoypsph7he(er1ri7ic)c:LL3ii8ffe1et6ti-imm3ee8o2of0f,FFl3tuu8oo1rr6oo-tt3ee8tlo2o0mm,eer2r0AA0ll3ccoohhoollss,, EEnnvviirroonnmmeennttaall Science & Technology 37( 17):3816-3820, 3816-3820, 2003
H. SAStmtooeccrkki,,cNNanLL,Teretotapla,ot.s,PpPohloeylryfeJl,TuuoEornrivininaratoteenddmeTTneetllaoolmmSeecrriAAelnlcccooehhoTolelsschaannnoddloSSguuyltjfb3on8na(a4mm)ii9dd9ee1ss-ii6nn,tthFheeeb.N.~obr1r5tt.hh
200 American
2004
Troposphere,
Environmental
Science
Technology 3~(4):991-6,
Feb.
L SEElollluiisrs,,ceDDoaafvviiPdderAA.f,.l,ueeottraila,nl.a,DtDeegdergCaraadrdaboatxtiiyoolnnicoofAfcFt;ii'dtuuso.orroEotnteevllioormmoenermreAAnlltccoaohlhoolSslcs:i:eAAncLLeiik&keellTyyeAActhtmmnoooslspophgheyerriicc S3o8u1r2c5e3o3f1P6er-fl3u3o2r1i,na2t0e0d4Carboxytic Acids, Environmental Science & Technology
38(i2):3316 - 23~I, 2004
J.
HH(uCurFrll3eey(y,C, FM M2DD),3, CeeHtta2allC.,,HAA2tt0mmHoo)ss:pphhePerrrioiccduCCchhteesmmiaLsn~tdtrryMy
ooff4:24:2 echan
FFlluuoorrootteclloommeerr ism ofC1 tom
AAllccoohhooll Initiated
O
x
i
d
at
i
o
n,
1J(.CPPFhh3yy(ssC.. FCC2hh)ee3mmC..HAA2,,C1iH00288O::53H6633):55--P55r66o44d22u,,c22ts000a044n.d Mechanism q[ CI Atom Initiated Oxidation,
Ko PLLeaeir,it,iYYtiDDo,n, teCatolae,lf,i,DcDeiteeetnersrmsmifnionaratPtiiooolnnyofclfufoVVraaippnoaortrePPdrrSeeusslssfuuorrneeassm,,iOdOcect,taanSnouolll-f-AAoinirra,,maadnnoeddtWWhaaatnetoerlr-s-AA,iirarnd
Telomer Alcohols, J. Chem Eng, Data, 49:1013-1022, 2004 Partition Coefficientsfor Potyfluorinated Sutfonamide, Sulfonamidoethanots,
TelomerAlcohots, J. Chem Eng. Data, 49:1013-1022, 2004
and
H~ o33wMMerdd,oocetsshennooCtt nneeocceessmssaarripisllySyuaccboornnnaccutusirynwwgiit~thhtitshheefccoonnocclluusrsiioonnamss oopfrarhhtyyopptofottthhheieesseeassvoassleetinbofolcerthhsiiniaattt leeesastitnssfooomremeatooiffotnthheessee piblctions publication~.
However, the Company is subnfitting this inlbrnkation as part of the available scientific information
1
22776666..00001100
I3MMAAG022552277225522
L. oSStftooEccskkt.,mNaNtLLi,,oeenttsala.LMe, tVVhaaoppdoosrr,PPErrneevssissruuorrneemsseonoftfatthlheeSFFcliluueoonrcrieinn&aatteeTddecTTheenllooomlmoeegrryAA3llc5coo(h6ho)olls1s6---9- 3LLi1imm6i9itt9aattiioonnss of Estimations Me'thc~cts, Environmental Science & Technology 38(6): t 693-1699
M.
D (DeNeo-onMn,e,FIJBCCS,,Eee.vt aaCll.,4, 9AAmStmoOso2psNphCheHerr3iic)c
FFaattee ooffNN--MMeetthhsy!l (CHICII20H),
(PPAeebrrsfftllruuaoocrrtoobobnuuyttaa)nn,eePSSruuelslffeoonnrtaeamdmiiaddtoocetthhaannoolI
FLOUROS Conference, Aug. 2005 (N-MeFBSE. C4F9SO2N(CH3)(CH2CII20tI),
FLOUROS Conference, Aug. 2005
(Abstract
only),
Presented
at
No (EFAlllbliissst,,rDDacAAt,,oenetllyaa)l,t,, PTTrhheeeseDDnetegegrdraaadtdaaFttiiLooOnnUooRffFFOilSutooCrrooonttfeee[lrooemmneecrre,AAllAccuooghh.ooll2ss0ii0nn5tthhee TTrrooppoosspphheerree,, (Abstract only), Presented at FLOUROS Conference, Aug. 2005
. FGGolosussso.,rKKiUUn,aetetteaadll..,AiCcCoohoonlntstrariinbbduuttOiilnneggfi1tno0s,aa(BBAebetstttteecrracUUtnndodenerlryss)tt,aanPndrdieisnneggnotofeftdthhaeet PPFaaLrrOititUtiiRooOnnSBB.eehhaavviioorr ooff
Conference, Aug. 2005 Fluorinated Alcohols and
Conference, Aug. 2005
Otefins,
(Abstract
only),
Presented
at
FLOUROS
P. (KKAoobrsrzztecrnaniciootwwosnsklkiyi,),,SSHPH.r.e,esetetnatalel,.d, SSaotouuFrrLcceeOssoUofRfOPPeSerrffCllouunoofrreoorcceaanrrcbbeoo,xxyyAluIiigcc.AAc2ci0idd0ss5 iinn tthhee EEnnvviirroonnmmeenntt,, (Abstract only), Presented at FLOUROS Conference, Aug. 2005
Q.Qo /PMvaelrratfritlinun,o, rJJoW Wb,u,teeyttlalsa.ul.l,AfAiomtnmoamsoipsdpheheer(riCicc4FLLiIiJjS?eOrtiiNmmGeeHaa)nnCddHOOIxxCiidHdaSatt)iio,onn(PPArbrosotddruuaccctttssooonflfyNN)-,-EEtPthrhyeylslented at
FLOUROS Conference, Aug. 2005 Perfluorobutylsulfonamide (C4FgSO2N(It)CH2CH3),
FLOI_JROS Conference, Aug. 2005
(Abstract
only),
Presented
at
R. fMMoartattPthheirieefssl,,uoMMr,i, naacnntddedKKlTlaaesslmmoemeieieerrr,B, JJA,,lEEcvovahaloluulasat,tiio(oAnnbosoftfettahhceetEEonnnvlvyii)rr,oonnPmmreeesanettnaatlleFdFaoarttteeFaaLnnOddUEERxaOppSoo.ssuurree
Conference, Aug, 2005 ./'or Perfluorinated 7"elomer
Conference, Aug. 2005
B
Alcohols,
(Abstract
only),
Presented
at
FLOUROS
Svaovnnalny)RR,ooPoornne,,seAAn,,teamdn~ddatVVFoooLoggOtt,U, RPP,,OVVSaapCpooounufrrePPrrereensscsseuu,rreAesusogq.ffFF2ll0uu0oo5rrootteelloommeerr AAllccoohhoollss,, ((AAbbssttrraacctt only), Presented at FLOUROS Conference, Aug. 2005
T. (YYAoobusuntngrga,,cCCtJJo,,nleeytta)al,,l.P,ArAwemtsmoensotpsephdheaertriicFcLFFlOluuUxxRooOffSPPeeCrrofflnluufooerrriiennnaactteee,ddAAAuccgii,ddss20iinn0tt5oo tthhee HHiigghh AArrcctriicc., (Abstract only), Presented at FLOUROS Conference, Aug. 2005
U. `BBaoonsdsssiOi,,thRReoorssssFaalnnuaao,,roeecttahalel.,m,iPPcrraeelllsiimmiiinnnFaairrsyyh,SSccBrrieereednnsiiAnnggnodoffMPPaeerrrifflnluueooMrraoooomccmitaaalnneesfSSurulotffmoonnGaartteeee((nPPlFaOOnSdS))and tathhneedFFOaartrhooeeerItFsslllauannoddrsos,,chEEnenvmviiirrcooannlsmmeiennntFtaa~llshPP.oolBllliuurttdiiosonnAn113d366M::33a22r33i-n-33e229M9,,a22m00m00a55i,~from Greenland and
V.go
BKKraaonnmnniananan,t, eKKdu.urruuannntldhhaaPccehhrafalllauamomr,,iSnSaeeteHHduuCnnoYnYutunan,m,iaannnaddn
TThhoommaassJJ.. ts in Liver
EEvvaannss,, CChhlloorriinnaatteedd,, sofPolar Bearsfro
m
Alaska,
Environmental Science & Technology 39(23), 2005 Brominaed, and Perfluorinated Contaminants in Livers
Environmental Science & Yeetmology 39(23), 2005
of Polar
Bears
from
Alaska,
W. PPPerrrecfvvlecuddoooruuorrcooassr,,boKKxooynlnsatstataennst,tiinnEoonssv,,ierettonaalml.,e,nSStooauulrrccSeecssi..eFFnicateteenaadnnddTeTTcrrhaannnsosplpooorgrttyoo(ffManuscript), 2005 Perfiuorocarbo.x3,'lates, Environmental Science and Technology (Manuscript), 2005
Xo REEemmlmamettietottn,,shEEiddpwwsaaBrreddtAAwe,.,eeenttaSla,el.r,CuoCmmomCmoumnncuientnittyyraEEtxxippooonsssuuarrneedttooExPPpeearrfsflluuurooerrooSooocucirtaacnenosoa,attOee::EM, Vol. 48,
No.8, Aug, 2006 Relationships Bet~,een
No. 8, Aug. 2006
Serum
Concentrations
and Exposure
Sources,
JOEM,
Vol.
48,
2277666..00001111
I3MMAAC022552277228533
Y. aMMnaadtritPinnr,o, dLJu.WWc.e.,S,teeuttdaialeI.,s, AAottfmmotohssepphOheeHrriiRccaCCdhihecemamilissatt~nry.d.o(of1fPPAeetrroffllmuuooIrnriootaaiitakktaaenndceOssxuutlldffoaotnniaaonmniodidefess::-KKEiiinnheetltiicc and Product Studies of the OH Radical cmd CI Atom .lnitic~ted Oxidation o)CN-Ethyl 2Po0r0f6luorobutanesifonamide, Environmental Science & Technology 40-86-4 72, Perfluorob~tanesulfonamide, Environmental Science & Technology 40:864- 872, 2006
2
PW Wearalflllliiunnoggrtoooncna,,rTbToJre.y,iteitcaaAll..c,
FFoorrmmaattiioonnooff ids during the
CC;zFF~sCCOOOOHH Aimospheric
((PPFFOOAA)) aanndd OOttheerr Oridation of5:2 Fhor
o
t
e
l
o
m
e
r
Alcohol, Environmental Sci&eTecnhncoloegy 40:924 - 930, Perfluorocarbo.\-vlic Acids during the A tmospheric Oxidation
.~lcoho!, Environmental Science & Technology 40:924 - 930,
2006 of 8:2
2006
Ftuoro~elomer
AAAA.. AYYtoomuuonnsggp,,heCCororiracal.FJo.,reemttaatalli.,o, nPP,eerErfnjllvuuioorrroiinnnmaaettneetddaAAlcciSiddcisseiinnncAeArr&ccttiiTcceSScnnhoonwwo:l:oNNgeyeww(EEE-vpviuiddbeleinnsccheecfjdoorr Avetrmsioosnp).heMraicr.Fo2r8m,2a0ti0o7n, Environmental Science & Tectmology (E-published
version). Mar. 28, 2007
BBBB.. BBPeuurttlt,,uCCorrraoaiaiggliMMy,l.,Pcerttoaadlli.,,ctRRiaaoppni,iddERRneevssipprooonnnsmseeenoqtf~a'lAArrScccttiiiccenRRciienngg&eeddTeSSceehaanll.osvlttooogCCyhha4a1nn(g1g)ee:ss 4iinn2 49,
2007 Perfluoroalk),t
2007
Production,
Enviro~wnental
Science
&
Technology
41
(I):
42
-
49,
3 22776666..00001122
I3MMAA0022552277225544
22776666..00001133
3mAo2527255
3MA02527255
Attachment 10
Attachment 10
CCoottttaaagIeenGdGurrsootsrveiealPPFFHCyCgM MieaannneuufSafaacmctptuulrriiinnnggg PPllaanntt Industrial Hvaiene Sampling
[oa DATE
MATERIAL SAMPLED
Coxcexirarion (si) CONCENTtL,~TION (MG/M3)
7/20i 1977 08/02/t977
1132//2222//11997777
0077.1/t22/,/11997788
02/09/1979
PFOA-based PFOA-based
PFOAbased [005-339 PFOA-based PFOAbused _[ND-10 PFOA-based Unspecified [021 1.57,93% Unspecified
PFOA-based
PFO~:based PFOA-b~sed
o.o3- 0.07 ..........
334,4
"
0.0~' '33.9 ........
ND"- 1.0
000...20016,6--!~.23.337,,,<9<o.02.d'08i.1...--.00.5.522............
00,00110- .0.0077
00..0044
......
04/11/1979 PFOA-b~ed
0.04
08101579 007-21 08/10./1979 PFOA-based
0,07- ~.1
100011979 | PFOA-based |0.04-095, 003-03 10/00/1~79 PF6k-based
o, o4 - 0:95, o.o~ : 0.3
[OU1|5Un/spe1cif9ied80 [0030.54 - 01/I 5/1980 Unspecified
0.03 - 0.54
05/01/1980 PFOA-based ""060.011--1122.'88....
05/05/1980 PFOA-based
00.0055-- 002.244
-
01,002 013, 0010.15 06~04/t 980 PFOA-based
o.i, 0.02, o,i.3, <o.oi- o.13
06/0'6/'1980 PFoA-based
00,111--001.122
06/30/1980 ~'Foa-based'
<<00.0011-- 00.0055
[00777//10~3//7119988100 |8UPUn7F,snOpsepA1ce-icbfi9faiiseeeddd5' 0
<<00.0011--00..1199 [0.1 - 1.0
0.1 - 1.0
TFOA-based | 007-015 08/11/1980 PFOA-based
o.of- 0.15 "
PFOAbased [003-017 12/19/1980
0033/22551/i9988"11'
05/15/1981 PFOA-based | 006-010 "'05/I 5/198i..
PFOA-based
0,03 - O. 17
[PPFFOOSShbaasseedd --TO0.O02
o.o6-o, i0
-- .......
51/1981 05/18/1981 05/19/1981 | PFOAbased [0.07-0.18 05/t9/1981
[ PPFFOOAAI-bb.aasseedd PFOA-based
0500525//12270I1!/1I999888111
PFOA-b~;ed PFOA2bas~d
10201981 |PFOS-hused [001-003 10/2'0/i981 .... PFOS-b~ed
.... 0.08 - 6,70
00.3077 - 0.!8
0601..300733- 223.28~.......
<o.oi- o.d~
..
0971371982 | Unspecified [0.003 - 0053 09/13/1982 . Unspeit{~d
0.003 - 0.053
0621/1984 | Unspecified [0.001 0033 06/21 / 1984 .....Unspecifi.ed
0066//1155//t1998844 |PPFFOOAA--bbaasseedd
0077//0033//I1998844_| PPFFOOAA-bbaassee~dt.
07/1~ii1984 , eF.Oa-based'"
10/03/1984 | PFOA-based | 002-036 10/03/1984 PFOA-based
0.00] - 0.033
.....
~<:o0loo.4-0-0o0.~0545
<~1.b.o0',330,i0<<20-0.000..024-0-3006..o6o2088
0,02 - 0,36
1120/1984 PFOA-based | <0.003- 008 11/20/1984 PF6A-based
<0.003 - 0.08
[PEBAbased |<002-702 PFBA-based
<0.02 - 70.2
1
-- |
22776666..00001144
ImA02s27256
3MA02527256
on | DATE
~'V[ATE RIAL
SAMPLED
CONCENTRATION
01012413/2/'7216591///191199988883554
||
PPPFFEOOCS'SH-~Sbbabassaees~del d PPFEOCS-HbSa-sbealsled
10[00.0,.2002206230L- 0.0o..,7~7033907
04/'26/'1983' PFOS-based
o.ooL 0.007 "
[000087572//220944171//111999985885555[PUFUUnnnOssspAppeeeccbciiifaffiiiseeededdd
1 000.,000322-0.15 0,002 0.003
08/29/1985 [04/2t/1986
PPPFFFOOOAAAb--abbaassseecddd
| 00o...0o0to12~2,--0o0..00o3303~3
.........
00540/2127/1!998866 | PPPFFFOOOAAA-bb-abaassseeeddd PFOA-base~I
|[000...000000858-0-0.0.1.1131I0, 6.0104 0.03
03o7s~00887)1~998866 PFOA-based 00..000054'-00..I1320,,0O2.O5-LO14.5-40.03
03/00/1990 PMSF-based
00..0055
PFOA-bas~d
00..0808001.I
04~'i 3/'1992 PFOA-based
<<00.,000022 -- 00.,0055 .....
0970'i/I993 PFOS-based
004-142
10/07/1993 PFOg'based
[080/158/197941|P5PFFOO7AA-1-bbaa9sseedd9"' 4|
00.4455 60,.000044-'00.1!55
[09T./06I/19795 11P5PPMMFSO7SFAt-~1b'b-baaas9sseeeddd95|[<<000..0.000070~72-2' 0006.,0050077.......
PFOA-based
<0'.002 - 0.65
(MG/M3)
-
05/12/1~)98 PMSF-b~sed
0.t3 - 0.34
000779/,//001666///111999999888 | PPPPERFMCOOHSSSSF--bb-baabas~s~eeseded_dd_| .... |<000<0....00000.006100209!189i.1-----00000..,.050.509009~1343535969,71,i66-4499447~
08/21/I 998 PPPRFEOOCSSH--hSba-absseaesdded | 000...000'00o0021181'0-.0'30i~.50534366363
"
02/'00/'1 }99 09/18/1999
~P'ReOOSSb-buasseedd PP~FOOAA-bba~sseedd
0.6)4 - 31~i <o.oba2 - <00047, <0.0042 - <0.o047 --
0077//0000/722000000 | PPPMMFSOSFSF-b-bubasasseeeddd
0.0056- 0.24
| <<000...0000000022 0-- .<000.0.o000090077
......
'
PFOS-based
<0.0002 - 0.0009
(TovoOa/0roi0oo/2u2s000o0o
|
PFOAbased PPFFOOAA--bbaasseedd
PFOA-based
| <0, <40, 0,032 07 <<00..00000022 -- 00..00003322 <0.4, <4.0, 0,032 - 0.1 i
....
(various
0dda1att0ee9ss7)) 2002
01/0 /2002
|
Unspecified
02002002 | UUnnssp,peceicfiifie~d
||<00..00000033 000.01025
02/00/200i Unspecified
2
22776666..00001155
2 S3MwaAo0z25s227r2z5s7
22776666..00001166
3mAo2s27258
3MA02527258
ode] jE
P : | SRol l::is|: (h5sH2T
(EE EE [1H
HSelEAEpl EEs) Her Ey
2 &
35
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= 3
1s8f gEllEEe|
% 33
din
3
i
-
g
1 [Hi
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|
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22776666..000017
3MA02527259
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