Document 5Dw45Km3ZvwL4Z0916aJ8N650

AR226-2653 43 AR226-2653 ISC Modeling Methodology and Results Introduction This report summarizes dispersion modeling that was completed for the DuPont Washington Works facility to demonstrate that the emission limits included in Permit Application 1823C for the Thermal Converter complies with the C-8 assessment oftoxicity (CAT) recommended airborne screening level of 1.0 ug/m3 at the property line fence. In 2003, the fenceline along the Ohio River was modified for site security purposes. A Security Vulnerability Assessment was conducted for the Washington Works facility in 2002. The assessment concluded that the fenceline along the riverbank needed to be relocated as a countermeasure to any adversary gaming access to the site. The current modeling analysis includes this new fenceline. Emission Source Information Table 1 shows the stack parameters used in the model as well as the locations and emission rates for each emission point. Note that an emission point from previous modeling (C3HP) has been removed from the model and emission point T7IME has been added. Modeling Methodology Dispersion and deposition modeling was performed using EPA's Industrial Source Complex 3 Model (ISC3), version 02035. All modeling was done in accordance with the procedures in EPA's Guideline on Air Quality Models (40 CFR Part 51, Appendix W). The EPA regulatory default options and rural dispersion coefficients were selected in the model. The APFO emission sources were evaluated for downwash effects from surrounding buildings. EPA's Building Profile and Input Program (BPIP) was used to provide wind direction specific building parameters. All buildings on the site were evaluated to determine if they could potentially impact the stack by causing building downwash effects. Plot plans showing the location of buildings included in the model are shown in Figures 1 and 2. (The buildings included in the model are identical to the list submitted under Consent Order GWR-2001-019). A 100-meter grid extending out 4,000 meters from the source was used. In addition, discrete receptors with 100-meter spacing were placed on the plant property line. Terrain elevations were imported from electronic files obtained from the U.S. Geological Survey using the "highest" method to assign an elevation to each receptor. C:\c8\permits\2004 Thermal Converter Permit.doc One year ofon-site meteorological data (1996) was analyzed. Concurrent upper air data from Wilmington, OH was used to calculate twice-daily mixing depths. Missing data and measured wind speeds of less than 1 m/s were treated consistent with the recommendations made in EPA's On-site Meteorological Program Guidance for Regulatory Modeling. An anemometer height of 10 meters was used for the modeling. Modeling Results An averaging time of one year was used to determine the annual average ground level concentrations over the entire receptor grid. A contour plot of these concentrations is shown in Figure 3. The maximum annual average ground-level concentration predicted by the model was 0.299 |lg/m3. This concentration occurred at a receptor located on the plant fenceline north of the plant. Electronic Piles This report and the following electronic files were transmitted by email to Chris Arrington at WVDAQ on September XX, 2004: ISC Input file ISC Output file BPIP Input file BPIP Output file Meteorological Data file thermal_converter_2004.dat thermal_converter_2004.1st thermal_converter_2004.bpi thermal_converter_2004.bpo pkbiln96.asc C:\c8\permits\2004 Thermal Converter Pennit.doc 2 Permit Vent ID T61ZCE T61XE T61YE T5HGE T5HIE C2DTE C1FSE C1FKE T7IME R022EEF6 (Research) R022EEF86 (Research) R022EEF87 (Research) R022EEF89 (Research) Table 1 Stack Parameters Modeling Vent ID 699 697 694 658 652 231 274 268 662 Zone 17 UTM-E 442098 442128 442101 441928 441926 441941 441790 441774 442025 UTM-N 4346843 4346829 4346815 4346757 4346758 4346758 4346744 4346753 4346847 Stack Diameter ft 4 2.25 1.67 1.5 0.88 1.00 0.65 0.27 1.33 Stack Height ft 170 45 45 63 64 100 110 72.5 150 Stack Stack Stack Flow ACFM 12,000 2,000 344 6,478 4,031 1,200 667 100 1788 Velocity ft/sec 15.9 8.4 2.6 61.1 111.7 25.5 33.5 28.7 21.4 Temp F 124 176 112 142 139 53 min 41 min 110 86 Permit Annual C-8 Emissions Ib/yr 3,258 3 3 94 71 2,753 1,327 300 0.0010 EEF6 442086 4346624 2.5 EEF86 442069 4346627 2 EEF87 442058 4346634 2 EEF89 442063 4346635 2 47 8836 49 7540 49 1885 49 3770 80 12 80 0.3 80 3 80 0.6 C:\c8\pennils\2004 Thermal Converter Pen-nit.doc 4346900- 4346800-^ 4346700-H 4346600-4 4346500441600 441700 441800 441900 442000 Figure I - Building Plot Plan 442100 C:\c8\permits\2004 Thermal Converter Permit.doc 4346850 4346800---- 4346750 4346700 441850 441900 441950 442000 442050 C:\c8\permits\2004 Thermal Converter Pennit.doc Figure 2 Building 162/163 Detail C:\c8\permits\2004 Thermal Converter Pennit.doc Figure 3 Predicted Annual Average Concentrations ()lg/m3) /&,. ^jn^