Document 4vvknQkEg9zw1ON21nggbNBqe

J. B. ALLOY COMPANY P.O. Box 230070 H uaton, TX 77223 , MATERIAL 8AFETY DATA SHEET Filler Metals and Welding Rods "ESSENTIALLY SIMILAR" to U.S. Department of Labor Form OSHA 20 (to comply with OSHA'e Hazard Communication Standard 20 CFR 1910.1200) 8ECTION I Nw; J.S. A--t Comply EmBTfwcr Phot*: 7T.Vq9fi-.79 77 Addr-- . 33#--3 66 th S t i Hooa ton .. TX 7701 1..................................................... ................... Tndt Ntmti J.B. AlloV____________________________________ ProeuctTypr Mild Steel ciMtmfOofK AWSER 70S-2.ER 70S-3IR 70S-6, .RG 45. t. flOSn? SECTION II HAZARDOUS INQREDIENLT8/Identlty Information *IMPORTANT: Thla Section covers materials from which this product Is manufactured._______ lngr*ewnM of Th4 Product CAS ` NO- OSHA PEL Mfl/M3 l ACQIH TLV MO/MS Iron 7A7q_flq_fi 10 (ssF^nOj) 1 l(hn SI ntwt wiim 7d7q_qfi_fi- 7S/in-71 -7 7A70_qp_fi % R IbsSIOjI 5 -iO-j 1 1 7 fHSt07l in ! C4ro*no0*ntetty NO NO NO NO f * 8ECTION III PHYSICAL DATA l NOT APPLICABLE SECTION IV FIRE AND EXPLOSION HAZARD DATA Welding arc and sparks can ignite combustibles and nammables. Refer to American National Standard Z49.1 for fire prevention during the use of welding and allied procedures. SECTION V HEALTH HAZARD DATA "Electric arc-welding may create one or more of the following health hazards: Fumes and oases can'be dangerous to your health. Arc Rays can Injure eyes and burn akin. Electric Shock can kill. EFFECT8 OF OVEREXPOSURE: "Short-term overexposure to welding fumes may result In discomfort such as: dizziness, nausea, or dryness or Irritation of nose, throat, of eyes, tightness In chest, fever and allergic reactions, (see Sections 4 and "Long-term (chronic) overexposure to welding fumes may lead to slderosls (Iron deposit Ift Hinge) and It believed by some investigators to affect pulmonary function. Chrtir1!?? in rsqulrid to N ?sn8W*fiil tF.RGSNCY & FIRST AID PROCEDURES: Remove to Irish sir, ttaln medical sttsrtftn. .frorftr-tf'!!# l*y *.!:? American Rad Cross. <*. *r.t t;* :c xu, fa **. *:,t,,l P,n ft COnfidenttal SECTION VI REACTIVITY DATA STABILITY: UNSTABLE:'NO' .; .im iCONDITlONS TO AVOID: NONE: UNLESS OTHERWISE SPECIFIED STABLE: YES CONDITIONS TO AVOID:<ONE: UNLESS OTHERWISE SPECIFIED ^COMPATIBILITY (MATERIALS TO AVOID): NONE.________________________ ' HAZARDOUS DECOMPOSITION PRODUCTS: The composition and quality ol welding fumes and gases are d**prndcn upon the metal being welded, the process, procedure, and electrodes used. Other conditions which also Influence r composition and quantity of the fumes and gases tb which workers may be exposed Include: coatings on tho metal be._. welded (such as paint, plating, or galvanizing), the nurrtbef ol welders and the volume of the work area, the quality pm amount of ventilation, the position of the welder's head with respect to the fume plume, as well as the presence o' contaminants in the atmosphere (such as chlorinated hydrocarbon vapors from cleaning and degreasing activities). When the electrdde'TS Consumed, the fume and gas decomposition products generated ere different In percent and forrr from the Ingredients listed In Section 2. Fume and gas decomposition productn, Wttfhdttheihgfedlerttslrt the electrode, ar* Important. The concentration of a given fume or gas component may decrenso or Increase by many times the origins concentration In the olectrodo. Also, new compounds not In the jeloctrode may form. Decomposition products of normal operation include those originating from tho volatilization, reaction, or oxidation of the materials Shown In Section 2. plus those from the base metal and coating, etc., as noted above. . Reasonably expected fums constituents of then products tould Iflelutfs primarily oxltfot of Iron: secondarily eomplox oxides ol minginisi. silicon, nickel, chromium, molybdenum ind vansdlum. The present OSHA permissible exposure limits lor hexsvalenl chromium Is 0.05 mg/M snd for nickel I mg/M'. which will result In s slgnlllcint reduction (rent the 6 mg/M* general turns level. Gsseout reaction products may Include carbon monorlrin snd carbert dioxide. Ozone snd nitrogen oxides may be formed by the radiation from the arc. In stldlilon lo the shielding nssos like srgnn snd helium whenever they ere employed. Chromium compounds sre required to be considered carcinogenic by OSHA. Ono recommenclod woy to determine Iho composition and quantity of fumos and gases lo which worl.nrs ore exposed Is lo take an air sample from inside the weldor's holmot If worn or In thn worker's broathing zone. See AWS F1.1 and AWS FI. 2- 1985. available from Ihe American Welding Society. SEE AWS PUBLICATION: "FUMES AND GASES IN THE WELDING ENVIRONMENT" HAZARDOUS POLYMERIZATION: NOT APPLICABLE. SECTION VII SPILL OR LEAK PROCEDURES NOT APPLICABLE v WASTE DISPOSAL METHOD: Prevent waste from contaminating surrounding environment. Discard ony product resld". disposable container or liner In an environmentally acceptable manner. In full compliance with Federal. Slate end Local regulations. SECTION VIII SPECIAL PROTECTION INFORMATION (See Note) "Reod and understand the manufacturer's Instructions and the precautionary label on the product. Ventilation - Use- enough ventilation, local exhaust at the nrc, or both, to keep the fumes and gases from the worker's breathing zone and tb genorel area. Train the weldor to keep his head out of tho fumes. Respiratory Protection - Use respirable fume rcrpli ntor, or air supplied respirator when welding In a confined space or where local exhaust Of ventilation does not koep exposu e bolow the recommended exposure limit. Eye Protoctlon - Wear helmet or use face shield with filler lens. Provide protective screens end flesh goqples. II necessary, to shield others. As a rule ol thumb start with a shade that la too dark to see the weld zone. Then go the the next tighter shade which gives sufficient view ol lha weld zone. Proloctivo Clothing - Woar hand, head and body protectsn which help !o prevent ln|ury from radiation, sparks, and eler.trlcol shook. Sno ANSI Z*9.1. At r minimum this Inch, .js welder's gloves and a protective lace ehlold.'and may Include rum protectors, aprons, hnts. should*' protection, as well as dark substantial clolhlng. Train tho welder net to touch live electrical parts and )o Insulale hlmse'l Iron work and ground." ..sv,. . ' Section jx SPECIAL PRECAUTIONS (Sea Noie) * 3THER PRECAUTIONS: Use exhaust system to cl6t>l welding furrteS. Make sure that Inhaled air does no! ccnt^n *um lonstHuehls above permissible pxpoSure levels. NOTE: Other precautions for additional snlety Information on welding and culling. Sen American rtanriord Ztn Salety In Welding and Culling, nnd Ihn Wnldlng Hnndbcrlt, Vcl. 1, Chapter 9, Sfiln Prncllch* in We-'1"? and TuIh-mi bp-.: tjvnlUhlM'ffp'W VmpMa*p V,5?v'J,'/ l-.: :<?v ->e Road. p C. < . w/u. r.'ii,u,. i l ;*. DO A 061523 CONFIDENTIAL ALLOT ROOS CORPORATION MATERIAL SAFETY DATA SHEET (MS05) A For Welding Consumables *nd Related Preducts CmcMoi with OSHA Hazsrd Cemuntcstlon Standard 29 C.F.R. 1910.1200 SECTION I - IDENTIFICATION Xgt ATOM ARC COVERED LOW HTDROOIH ElECTtOOIS wfarturor'O Naaei ALLOT RODS CORPORATION taeraency Telephene No. - 717/IS7-8911 (rossi P. 0. Ion I1T, Mil son Avenue, Nanever, PA 17IS1 Telephone No. far tnfemotion 717/917*4911 duet Trade Ntae(s)i TON ARC 7018, 7018*1, 7018LC, 701841, 7018 ALPHA ciemo, mi, nu-ci, mi-CM, i8-*2i, miN, maw, oil, macM, mu 0019M4, 1*018, T, mw, 9018-8JL 001 Ml, 12019442 1I0LN, 4190, 4140, 4940 Produet CUasiriut1an(a)i AM Al.l, I7018| K7018-1I 17019| 17019) E7018 AM Al.l, 17011-Alt mi*ai Kni*Cl| E801I-B2; H01M2L) V8018-C2) K8018484| 1901*4) 19018*89) 11001844 110018*02, 11201844, E1101944. EtOlt-W, E901I49L MIL*I*0022200/10A, MIL 1001840, MIL 12018441 NOT eiASSIPID (4190LH, 4190, 4140. 4940) SECTION U HAZARDOUS 1H8XC01IKTS WTAMTi THIS SECTION COVERS THE MATERIALS FROM WHICH THE RROOUCT IS MANUFACTURED. THE FUWS AMD OASES PROOUCEO OURINQ WELDlNO WITH NORMAL USE Of THIS PRODUCT ARC COYIRtO IN SECTION V. TERM HAZARDOUS* IN 'HAZARDOUS MATERIALS' SHOULD BE INTERPRETED AS A TERM REQUIRED ANO DEFINED IN OSKA ARD COMMUNICATION STAMOARD (29 C.F.R. 1910.1200) ANO IT DOES NOT NECESSARILY U9LY THE EXISTENCE OF --Hi tut IA) j*1um TCrT '"t Exposure (CAS No.1 Limit 1 (7439.84*8) j (7440*47*3) (7440*21.1) 1.0.9 io' Source (J) (2) A\) (11 (2) Ingredient Manoineto (9) Nickel fNII (C) Molybdenum (CAS Mo.l Exposure .Halt (7439.98-11 (7440-02*01 _ 1 (7439*88*7) 1 Source (1) (2) (1) (2) (1) (2) itr (7440.90.8) 1 (Dust) (1) (2) Pottstlum Sllleete (1312-78-1) (N/A) - (S) w sntcatp (8814.92.01 :1wa Cirtowtt _M117.8S*S) ( N/A > ID (3) Cslclum Fluoride (7784*78*5) 2.S at F (1) (2) (I) (2) Peteiilui Feldspar (88478.2S.S) (N/A) (3) nlum Dioxide (13483.47*71 _12________ _____ HL Zlreonlu* Sllceie (7440.67.2) 8 -iilUL Occupational Safety and Health Administration, 29 C.F.R. 1910.1000. P. .o..r.e.i.li.i.t.tl.o. Exposuref VL*i*m i*t ( rJ American Conference of Governmental Induitrlil Hygienists (AC01H) Threshold Halt Value (TivfR]). Not known: nulienee particulate concentration per OSHA 1910.1000. table 2*1, is I ag/M* respirable duit, and por AC01H la 10 ag/M*. In S01BCM. 9019CM, 12018. !*, 8018W, fOU-IIL. 8019-12L, 41J0LN. 1130, 4140. 4340. In JOlt *01C1. fel8N, fellm, 9018, 12018, *t*. 9019W,*10018, iO01*-Ml. 12619442, 41J0LN, 41S0, imOj ind 4140. ilSOlLnN. ^aijO01^ "h?.' *011, 901**' X20l8` 'T' WI-IIL, 8018-82L, 1001I*M, 12018-M2, In 8Q18W. Hot 1 n 7018 Alpha.__________________ nCTION III * PHYSICAL AND CHEMICAL DATA i products is shipped are nonhazirdoui, nonfiaseeibla, nonexplosive, and nonroaetlve. asoHamuii SECTION IV - FIRE AND EXPLOSION HAZARD DATA to-b'.Voiding or? and spirt; sen Ignlt* *>? .j . .*.s my...,. .. Dot* Reviled: J Ol'ns/en DO A 061524 CONFIDENTIAL I ttCTION V - REACTIVITY PATA WLftygglT19 Ml Wilding fuoos cannot ba classified Haply. Their w^oiltton and '"tjty ro faoandant upon tht total being welded, tha proean, procedures and alaetrodpsysed. Other condition* which alao Influence the tha fut and gaiai to which worker* tay ba oi^oiad inejudai coating* on tha ---------- *-------------- rwPar of walda and yolwwe of work arts, ,d with ratpact to tha twoe p1v*e, a* wan a* . lorinated hydrocarbon vapor* froa darning and Idlng futa* and gaata la by inhalation. Whan tha floctrada 1* contuwad, tha fwta and gat decoeposttlon product* arc different In percent and fort fro* the Ingredient* lilted In Section II. Decomposition product* Include thote originating froo th volitllfiction, reaction, or oxiditlon of the Mterlsli shown in Section II plus those froo bate betel, coating, ate. a* noted above. These coepenenta are virtually always present i* coaplex cwpoundi and not s petals (Characterization of Arc Welding Fueet American Maiding Society). faisonibly expected fume constituents froo these produett would Include fluorides end coeplox oxides of Iron, oanginese, silicon, and, when present, nlekel, chrooluo. polybdenuw, and copper. Oataous reaction products say Include carbon bonoxldo and carbon dioxide. Ozone and nitrogen axldes bay ba fervad by tha radiation froo the arc. Ona racowwended way to datorwlne the cooposltlon ond quantity of fuwos and oasai to which workers oro exposed is to take an air aawpla Inside the welders heloet, If worn, or In the worker's breathing zone, tee AM3I/Aws Fl.l, eve 11 able froo tha American Welding Society, P.O. box SHOCO, Mteal, FI lllle. StCTION VI - MALTM HAZARD bATA hreshold llolt Veluet 11 5 S%7HJ?*Tr>a Xctih o ACQIH recofwtended gonoral Holt for welding fuoe HOC (Mot Otherwise Cliulflec 104.19 preface statist #The TlV.TWA should Pe used at guides In tha control of neiijn neiiroi ano snouid not bo used at fine lines between safe and dangerous concentration*.* too faction V for tpoclflc fuoa constituent* which bay bodlfy thla tlv. can be dangarou* to your hoalth. Aggravation of preexisting nTIiyrjTTTTTTTme conditions oty oeeur In too* workers' SHORT-TERM (ACUTE) OVEREXPOSURE to wweelding e-y-es*. bVyOMreTsEuRlMt (jCnHRdOisMcIoCm) fOoVrEtREsXuPcOhSUcRsEi bdavizMzeinaedssto, ntleduirioeis, lsor (IdrroynnesdsepoorsiitrsritInattihoenToufngn) oaa.ten.n.d, t*>n>>rouaatt or It believed by*o* Invastlgator* to affect pulooniry function. SHOCK can kilt. See lection \ll. ARC RATS can Injure eyes and burn akin. ELECTRIC Coff8n\Iir3iild 6411 fer MdUtl t1d* *** first aid techniques reeaoeanded by tha gmnnuuunern wnen oreunt iNvIP.Tm I RHC NonooUbM7 r JtL StCTIOM VII - PRECAUTIONS FOR SAFI NANDI I MO AND USE/APPUCAIlt CONTROL KASURES J iMiwtlons and the precautionary label on irlcan National Standard 2-40.1, Safety In Melding and Cutting, published by the >. Sex 1*1040. Mlaol. FL 1)116 and OJHA PublUltlen M06 (296.F.R. 1910), 11. S. lea, Washington, D.C. 10402 for boro detail on oany of the following) tMa product. Sto Aaerlean Welding Society, Oovarfsaant Printing jpgHNi ii^am --.. .................. T\_u__n W.*l.o.o.4_o-lr.kWWt!eoe,arsrsthNaaet,Blotthh#eettt woMreldu!s"e,i--onffa,*ec.e* *!Ts.h.hh.a.1i.ne.#..l,.ddg..o.w"..t1iotthhthffeinltt-ne,errxt Ialin*gsh~. teArsthaadreulewhoicfhthgiuve*.* aautaffrltewlaintht va lothla^doaf to wold sene. Provide protectivei tcroent and flaah goggles, If naeassary, ta shield others. 5 otectlvo Clothing; . ... ___ protection which help to pravant Injury fro* radiation >irns ifti ei#*lrie*1 sShhoocckk.. SSaacc AANHS$I| 22*-4499..1);. 'AAti ice snlald and ojsyy Incluuddee ana eroteetors aprons aa oilnihloieuuo*, this hats, ihowldar includes welder's gloves and a orolectl protection, at well * dark aubitantia? va Ing `Train tha weldor not to touch live alacirlcal parti and to Insulate htasalf frtm w?rkVi JrJJ!. adurt for Qloinup.of Spill* or lee^n NOT APPLICAILS it 9 `jlspoc:' Method) Provont watte froo contaminating surroundln* jTouTTcp-iToTe fin*;->- "-- *- * .* - q % e___ ,AAK. -- --or..,, ,, ibtea *< \bn DO A 0615?5 CONFIDENTIAL allot boos corporation MATERIAL SAFETY DATA SHEET (MSDS) For Welding Consumables and Ralatad Products Cooplies with OSHA Hazard Communication Standard 29 C.F.R. 1910.1200 ' SECTION I - IDENTIFICATION Identity: REFRACTORY BACKING TAPE FOR WELDING Manufacturer's Naae: ALLOY ROOS CORPORATION Emergency Telephone No. - 717/637-8911 Address: P. 0. Bax 517, Wilson Avenue, Hanover, PA 17331 Telephone No. for Information - 717/637-8911 Product Trade Naae(s): REFRAC-T-8ACK Product Classlflcatlon(s): NOT CLASSIFIED SECTION II - HAZARDOUS INGREDIENTS IMPORTANT: THIS SECTION COVERS THE MATERIALS FROM WHICH THE PRODUCT IS MANUFACTURED. THE FIXES AND GASES ---------------- PRODUCED DURING WELDING WITH NORMAL USE OF THIS PRODUCT ARE COVERED IN SECTION V. THE TERM "HAZARDOUS" IN "HAZARDOUS MATERIALS" SHOULD BE INTERPRETED AS A TERM REQUIRED AKO DEFINED IN OSHA HAZARD COMMUNICATION STANDARD (29 C.F.R. 1910.1200) AND IT DOES NOT NECESSARILY IMPLY THE EXISTENCE OF ANY HAZARD. Ingredient ----------- Ceramic Tiles (CAS No.) (66402-68-4) Cordlerlte (fused Magnesium Aluminum Silicate) ' Ensure Limit 'eg/Wr (N/A) Source (3) Ingredient Aluminum Acrylic Adhesive (CAS No.) (7429-90-5) (9003-01-4) Exposure Limit 9/H3) 10 (N/A) Source (2) (3) - 1. Occupational Safety and Health Administration, 29 C.F.R. 1910.1000 Permissible Exposure Limit (PEL). 2. American Conference ,of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value (TLV[R]). 3. Not known; nuisance particulate concentration per OSHA 1910.1000, Table Z-3, Is 5 mg/M? respirable dust, and per ACGIH Is 10 mg/M*. SECTION III - PHYSICAL AND CHEMICAL DATA These products as shipped ara nonhazardous. nonflammable, nontxploslva, and nonraactlva. SECTION IV . FIRE AND EXPLOSION HAZARD DATA Nonflamable: Maiding arc and sparks can Ignite coebustlbles. Saa Z-49.1 referenced In Soetlon VII. SDS-21.1-.2 Data Revised: 02/15/88 DO 0 CONFIDENTIO' HAZARDOUS DECOMPOSITION PROOUCTS: Welding fumes cannot ba classified slaply. Their coeposltlon and quantity are dependent upon the Mtal being Melded, the process, procedures and electrodes used. Other conditions which also Influence the composition and quantity of the fumes and gases to Mhlch workers may be exposed Include: coatings on the metal being welded (suen as paint, plating, or galvanizing), nunfcar of welds and volume of work area, quality and amount of ventilation, position of welder's head with respect to the fume plume, as wall as the presence of contaminants In the atmosphere (such as chlorinated hydrocarbon vapors from cleaning and degreasing activities. The primary route of entry of welding fumes and gases Is by Inhalation. When the electrode Is consumed, the fume and gas decomposition products are different In percent and form from the Ingredients listed In Section 11. Decomposition products Include those originating from the volatilization, reaction, or oxidation of the materials shown In Section 11 plus those from base metal, coating, etc. as noted above. These components are virtually always present as complex compounds and not as metals (Characterization of Arc Welding Fume: American Welding Society). Reasonably expected fume constituents for Refrac-T-Back consist of vapors from the aeryllc adhesive. No decomposition of the cordlerlte tiles or aluminum tape will occur. The principal source of fumes will be the welding consumable employed. See the KSOS for the consumable which you are using for detailed Infornation concerning this fume. Gaseous reaction products may Include carbon monoxide and carbon dioxide. Ozone and nitrogen oxides may be formed by the radiation from the arc. One recoanended way to determine the composition and quantity of fumes and gases to which workers are exposed Is to take an air sample Inside the welders helmet, if worn, or In the worker's breathing zone. See ANS1/AWS Fl.l, available from the American Welding Society, P.0. Box 351040, Miami, FI 3313S. SECTION VI - IEAL1H HAZARD DATA Threshold Limit Value: The ACQIH recoanended general limit for welding fume NOC (Not Otherwise Classified) --Is 5 mg/fij" The-'ACUIH 1984-85 preface states: 'The TLV-TWA should be used as guides In the control of health hazards and should not be used as firm lines between safe and dangerous concentrations.* See Section V for specific fume constituents which may modify this TLV. Effects of Overexposure: FUMES AND GASES can be dangerous to your health. Aggravation of preexisting respiratory or allergic conditions may occur In some workers. SHORT-TERM (ACUTE) OVEREXPOSURE to welding fumes nay result In discomfort such as: dizziness, nausea, or dryness or Irritation of nose, throat, or eyes. LONG TERM (CHRONIC) OVEREXPOSURE nay lead to slderosls (Iron deposits In the lung) and Is believed by some Investigators to affect pulmonary function. ARC RAYS can Injure eyes and bum skin. ELECTRIC SHOCK can kill. See Section VII. Emergency t First Aid Procedures; Call for medical aid. Evloy first aid techniques recowended by the American ked Cross"-------------------- "'CAffCIHOGEMCllY H1P7 i akC Monographs? usha Kequiateg? SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE/APPLICABLE CONTROL MEASURES Read and understand the manufacturer's Instructions and the precautionary label on this product. See American National Standard Z-49.1, Safety In Welding and Cutting, published by the American Welding Society, P.0. Box 352040, Miami, FL 33135 and OSHA Publication 2206 (29 C.F.R. 1910), U. S. Govarnment Printing Offlca, Washington, D.C. 20402 for more detail on many of tha following: Vantllatlon: Usa mnough vantllatlon, local axhaust at tha arc, or both, to keep tha fumes and gasas below the TLVVIn tha workar's braathing zona and tha ganaral araa. Train tha waldar to kaap his haad out of tha fumes. Respiratory Protection: Use respirable fume respirator or air supplied respirator when welding In confined space or where local exhaust or ventilation does not kaap exposure below TLV. Eve Protection: Wear helmet or usa face shield with filter Ians. As a rule of thunb, start with a shade which Is too 'dark to sat tha weld zona. Than go to tha next lighter shade which glvas sufficient view of tha weld zona. Provide protective screens and flash goggles. If necessary, to shield others. Protective Clothing: Wear haad. hand and body protection which help to prevent Injury from radiation, sparks and'electrical shock. See ANSI Z-49.1. At a minimum, this Includes welders gloves and a protective face shield and may Include arm protectors, aprons, hats, shoulder protection, as well as dark substantial clothing. Train the welder not to touch live electrical parts and to Insulate himself from work and ground. Procedure for Cleanup of Spills or Leaks: NOT APPLICABLE Waste Disposal Method: Prevent waste from contaminating surrounding envlrererert. Discard try product, `residue, cliposaole container, or liner In an envIrotvnerUlly acceptable mtnrtr. In fell sev 't-ce uuh Frir.l; Stt- lir*l KSOS-21.3-.4 DO A 061527 CONFIDENTIAL