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ooAR226-1381 CC prancing pa Cactii Ey ship tad fee RR RTI peg PROPOSAL } : g: Co uh ul ply 7 Dest hss Usd ful ot lr, pbb os sibsDp tokyoJ)Gb - toi HELE ~ Woith PE 1 Hg EID106191 Zp a0. Son pipe1d 2a "7 1. objectives : . The study's objectives are to determine whether ES a. Pregnancy'sutcone among female Washington Works employees is causally related to their occu- pational exposure to C-8. be Pregnancy outcome among wives of Washington Works employees is causally related to their husbands' H exposure to C-8. S II. Background and Rationale There have been five toxicologic experiments in which C-8 vas administered repeatedly to experimental animals and in which the male reproductive system was examined. In none of the studies were treatment-related testicular changes observed. Recently 3M conducted an oral rangefinder study of C-8. The purpose of this study was to determine the upper dose level f C-8 for a subsequent oral teratology study in rats. Suspensions f C-8 and corn oil were given by oral intubation to 5 groups of time-mated female rats (Charles River Sprague-Dawley derived). The doses received were 150, 100, 75, 50, or 25 mg/kg/day of C-8. These doses were given on days 6 through 150f gestation (i.e., the period of organogenesis). There was one control group that received only corn oil by intubation on these same days. Each dosed and control group consisted of 6 time-mated female rats. At day 20 of gestation the rats from the 3M study were sacrificed. Four fetuses were examined from each of four dams in the 150 and 25 mg/kg/day dose groups. All of the readable fetuses EID106192 000125 CT sectioned had eye lens abnormalities. The authors noted that . two previous teratology studies with chemically related compounds "I resulted in fetuses with sinilar abnormal changes in the lens - of the eye. - . At Washington Works significant occupational exposure to -8 is limited to the Teflon area. C-8 is a dispersing agent that is used in nearly all Teflon polymer and copolymer processes. The monomers do not contain C-8. Based on previous analyses of blood organic fluoride levels of workers, the greatest potential for C-8 exposure occurs in four jobs: TFE process operator, FEP proce + operator, TFE service operator, and FEP service operator. In the proposed study of pregnancy outcome, exposed female employees and wives of exposed male employees will be studied. Feffale workers are studied because they may have been exposed to -8 during or immediately prior to their pregnancies. Wives of male workers are studied because the husbands may somehow bring C-8 home with them and expose their wives at home. There is no evidence at present to suggest that C-8 exposure affects the husband's reproductive system. III. Specific Aims . Ristories of pregnancy outcome and of potential exposure 0 C-8 will be ascertained for g a. Washington Works active female employees, and = b. Wives of Washington Works active male employees. Potential exposure to C-8 will be determined from personal records, medical records, and employee interviews. Pregnancy outcome will be determined via self-adninistered questionnaires given to female employees and wives of male employees. : * EID106193 000126 oo .. "2 If an association is observed between pregnancy outcome end having had potential exposure to C-8, the association will be assessed as to whither it is causal or whether it is dne to other confounding factors. Iv. Methods A. study Groups 1. Workers with potential C-8 exposure a. Definition of exposure: Teflon area All Teflon area jobs will be defined as having potential exposure to C-8. These jobs will be further categorized as having either . high or low potential for exposure. ct Table I shows the exposure categorization scheme used in the previous liver function study of C-8 workers. Notice that several job titles appear in both the high and low exposure potential columns. This happens because exposure potentials for most Teflon area jobs depend on the particular time period and task considered. Within the high potential category, current TFE/FEP 5 service and process operators have the highest g potential for exposure based on blood organic s fluoride levels. Some mechanics, non-semiworks laboratorians, and chemists/engineers occasionally come in contact with C-8. However, thenaturesof their jobs and of the personnel record keeping system make it very difficult to determine these workers' exposure. to o EID106194 000127 te = C-8 or to other chemicals. For this reason, mechanics, non-semivorks laboratorians, and chenistsengineers will be defined as having unknown exposure potential. b. Selection of exposed workers All active male and female workers who have ever worked in a C-8 exposure job (as defined above) will be identified. Brief questionnaires will be given to these workers to determine who has ever been married. All ever married workers will be included and all never married will be excluded from the study. "2. Workers with no potential C-8 exposure a. Definition of non-exposure ALL non-Teflon area jobs, with the exception of the jobs with unknown exposure potential (e.g., mechanic), will be defined as having no potential for C-8 exposure. b. Selection of non-exposed workers (controls) 3 ALL of the plant's non-exposed active female workers will be selected as controls for the ex- posed female workers. For each C-8 exposed active male employee, one matched non-exposed male employee will be chosen 2s a control. Matching will be on payclass, birth date (+ 3 years), and adjusted service date (+ 3 years). The control for each exposed worker will . EIDI06195 000128 To : i . be the first eligible employee appearing in the yearly employee roster after the exposed worker's name. + Each male and female control will be given a questionnaire to determine whether he/she has ever been married. All never married con- trols will be dropped from the study. For the male subjects, new controls will be chosen to replace those controls who either were never married or who refused to participate in the study. B. Sources of Data _ il. Exposure histories Plant personnel will be responsible for: determining which active employees have ever had potential exposure to C-8. collecting detailed exposure histories on the study subjects. These histories will be assembled from personnel records, medical records, and employee interviews. The work histories should contain: name o color (white/non-white) birth date payclass 8 aate hired all jobs having C-8 exposure potential mCo-n8thjobasnd year the worker moved `in and out of EID106196 --_--_-------- 000329 ---- : :- each job's exposure potential (high or low) tbalkoeond organic fluoride level and date Exposure histories will be recorded on code sheets that will be designed and supplied by Medical Division. 2. Pregnancy outcome data All female study subjects will be asked to com- plete a self-administered questionnaire on pregnancy outcome. All male subjects will be given an initial questionnaire to determine whether they have ever been married and whether they are now living with their wives. Males ; who have been married but who no longer live with their "7 vives (e.g., because of divorce, separation, ordeath) will be asked to complete the pregnancy outcome questionnaire themselves. Males who are now living with their wives will be asked to give the questionnaire to their wives to complete. Never married workers will be dropped from the study. C. Major Response Variables The major measures of pregnancy outcome, which are to be ascertained via a self-administered questionnaire, include: 1. 4 Pregnancies 2. # Spontaneous abortions/miscarriages : 3. 4 Stillbirths 4. 1 Induced abortions (for medical or personal reasons) 5. # Live-born children 6. 4 Live-born children with birth defects or g other problems at birth EIDI06197 000130 7. Tsyeprevsedofatbbiritrhthdefects or problems ob- : . 8. Birth weights D. Potentially Confounding Variables Information on a number of potentially confounding factors will be ascertained via the pregnancy outcome questionnaire. These include: . "3% & 1. Maternal age 2. Paternal age 3. Infectious diseases (e.g., rubella) 4. Fsatmiilllybirhtihsstory of malformations/miscarriages/ 5. Medications/drugs 6. Ionizing radiation 7. smoking 8. oCthheemricaolccuepxaptoisounrse)s outside the plant (e.g., 9. Alcohol 10. Number of previous marriages 11. Birth control/desire for more children 12. pCeorlsoorn/neetlh)ni.city (to be determined by plant 3 E. Quality Control If the final product of this study is to fair well against peer review from outside of the Company, steps must be taken to assure, measure, and document the quality of the data collected. 1. Validation of pregnancy outcome supplied by female workers The responses on 1008 of the female workers' questionnaires should be validated. A worker's responses could be validated by checking existing Du Pont medical records and by contacting the worker's personal physician. This . EIDI06198 000131 : . last step would only be done after having obtained the worker's informed consent to do so. 2. validation of pregnancy outcome supplied by husbands The responses on 108 of the questionnaires given to workers' wives should also be compared with the responses given independently by their working husbands. This comparison will help document the quality of the responses given by husbands. 3. Validation of work histories supplied by the plant After work histories for exposed and nonexposed sub- . jects have been sent to Medical Division, data from a 7208 sample of these subjects will be auditted. For this audit the plant will be asked to supply the records from which these work histories have been assembled. F. Pilot Study : Prior to giving questionnaires to all study subjects, a pilot study should be done. This pilot study should include about 5 male and 5 female workers who have had nopotential -8 exposure. It will allow us to pre-test the pregnancy outcome questionnaire and other study procedures. z V. Sample Size A. Female Employees Currently there are 32 exempt, 130 non-exempt, and 159 wage roll females actively employed at the plant. Aas f April 1, about 50 of these women worked in theTeflon EID106199 000132 se CE - : - area. Only about one dozen of these women were in jobs. having a high potential for C-8 exposure. From 1965 though 1980 there were 103 leaves of absence. due to pregnancy (table IT). Thirteen of these leaves were among vage roll employees. B. Male Employees Over 300 men, or about ten percent of the plant's work- force currently work in the Teflon area. Within the Teflon area, 60 to 70 workers are in jobs that have high potential for C-8 exposure. Since each exposed male will be matched with one non-exposed male, the total number of males inluded in the study will be over 600. The number of active . fuorkers who no longer work in the Teflon area is unknown. The number of births to wives of male employees is also unknown. C. statistically Significant Excesss The national incidence rate for craniofacial malformations is about 2 per 1000 live births, and the rate for malformations of all types is about 20 per 1000. 2 Given these background rates, table III shows the minimum S nunber of births with malformations that must be observed in the study group to say that there is a statistically significant excess ( p<0.05). For instance, 2 malformations in 10 exposed live births is a significantly higher rate than a national rate of 2 per 1000. Two malformations per 10 exposed live births is also significantly higher than a - Plant rate of 0 per 50.nonexposed births. . EID106200 000133 VI. analyses . 1. Data on C-8 exposed female workers will be analyzed separately L- E from data on wives of exposed male workers. 2. C-8 exposed female workers and wives of exposed male workers will be compared with four control groups: + Female WW. vorkers never exposed to C-8 g Wives of male workers at W.W. never exposed to C-8 Non-W.W. female employees at another Du Pont plant Wives of non-W.W. employees at another Du Pont plant. 3. All of the measures of pregnancy outcome mentioned in the : earlier section on major response variables will be analyzed. 4% "he analyses will be adjusted for the effects of the potent- 1ally confounding variables mentioned earlier. Binary regression and Mantel-Haenszel methods will be used for these adjustments. 5. Analyses will take into account that only exposures occurring : immediately prior to conception or during the first tri- mester of the pregnancy are likely to produce malformations. 6. Hypothesis testing will be two-tailed, and significance will be judged at the 0.05 probability level. VII. Confidentiality and Informed Consent Any female employees, male employees, or wives of male employees who are asked to participate in this study will be EIDI06201 000134 Co asked to first read, understand, and then sign an informed con- . sent statement. This informed consent statement will clearly TI describe: = . The study's purpose and design. o dPeoctiednetiatlo prairstkisciapnadtebenineftihtes sttoudiyn.dividuals who How the data will be used. Tatheaniynditivmieduainl'stherigshttudytowirtehfouuste hin/her. ptroejpuadritcieciptaote tHoowtthheeisndtiuvdiyd'usalr.esults will be reported back All completed questionnaires, data forms, and raw data will be stored under lock and key or in limited-acess computer files. only the principal investigators will have unlimited acdess to these data. When the study is finished, the collected data will be stored in Du Pont's Hall of Records. All results will be published in aggregate or group forms only. Individual workers will not be identified. g EID106202 000135 TABLE I: SETXPUODSYUROEF CC-A8TEWGOORRKIEZRASTIAOTN WSACSHHEIMNEGTUOSNEDWOIRNKSLIVER FUNCTION : wo. EY 6-3: 4-5. 7 9 s-11 B13 15 S-17 : HIGHEXPOSUREPOTENTIAL - TPE Service Operator TFE Process Operator FEP Service Operator FEP Process Operator Semivorks Laboratorian Mechanic Midhanic (good possible) (possible) LZsnbgdirnaeetrorosranCh(eTneicshcAssistant) : No. 2. C64 Lo 46 Fes | 6-10 6-12 7-3 8-16 us-18" 6-20 vs-20 Lo EXPOSUREPOTENTIAL TFE Service Operator TFE Process Operator FEP Service Operator FEP Process Operator Semivorks Leboratorian TEFZEL-TELOMZR A MONOMER Operator . Operator Mechanic (unlikely) TPE Production Foresan Laboratorssn Chnist `or engineer 3 8 - EID106203 000136 = . i : : : a a of8 3 ov op g a a os "ov ofp : AE Eos fz =F z 505 eo fm iE Ss eo fz : is wa orf Is w aoe fda gf w oo oo PE fF Bs Ei se E "woul j Eos ou . EID106204 : 000137 3- : ' 2: 88gHH T3erg5e8 E4o5a4ng 2g .a FiseFgES:E voto gEgE: Ge5e as 35 [I EFEFM2SEL.9pE%8ESE A Lt.] EL%: ciIE Hdc8ozEHes.f SwaFFggE8Egh E3ni2xFc 55 oe oz o- pEge5gtEs 5 Eons "IFEEENE 8358a vee2g8e8 &ze23 ol Pog I: EPEER)E 3= ii1 225E3fi 8[mo =Z | !| F zjz e=EHlE gzz ii g 3 i1i |i sv EEE 3] |i| ]i -=3T o358% B3[EE5EFE ligd 383 i gg gs& c @ }i B5 i| ii| ~ oe [EFEg-REB%RgEi4EEfEE,2 |ji 3af2o4s & ':| iK E2En ieo]HB i ||| vo s[FSSeaEzR5sgiE5tcdy8i2 ii|||i ZE535I s,e88ct% y82 PE iii| ~~ [2Fe5Eo3TE0)5Ss2 i EEES }i i 5 gaLi8EEs5E s E5: EIDI06205 g8 2% La 000138 a Ce em STUDY OF PREGNANCY OUTCOME IN WIVES OF C-8 EXPOSED WORKERS "| preexcsocrndnser Medicoatlt reco) wIonrtkeerrvsiew x0 . |(odueemsotgiroanpnhaiifl)e Select sevaemrpleexpoofstd P.0. quest. to workez YES o oq > ves 2.0. quest] otfo wwoirfkeer | EIDI0S180 3 000139 eri on sass uncon 1 FR voRkER Exo 70 8 om Reaicar FgE n EN io Teles an 2 EID106215 000140