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DOW CORNING CORPORATION MATERIAL SAFETY DATA SHEET MATL NAME: DOW CORNING(R) 3-5000 SILICONE CONST. COAT.-GRAY rv EMERGENCY TELEPHONE NO.' (517) 496-5900 SECTION I - GENERAL INFORMATION MANUFACTURER'S NAME: DOW CORNING CORPORATION ADDRESS: SOUTH SAGINAW ROAD, MIDLAND MI 48686 PROPER SHIPPING NAME(49CFR 172.101): COMBUSTT^Li', I TO'JID NOS D.O.T. HAZARD NAME(49CFR 172.101): NAPHTHA D.O.T. ID NO(49CFR 172.101): NA 1993 D. O.T. HAZARD CLASS(49CFR 172.101): COMBUSTIBLE LIQUID (EXEMPT IN PACKAGES OF 110 GALLONS OR LESS). RCRA HAZARD CLASS(40CFR 261)(IF DISCARDED): IGNTTABLE (D001) E. P.A. PRIORITY POLLUTANTS(40CFR 122.53): NONE NFPA = NATIONAL FIRE PROTECTION ASSOCIATION - 704 HEALTH (NFPA): 2 FLAMMABILITY (NFPA): 2 REACTIVITY (NFPA): 0 CAS NO: MIXTURE DOW CORNING WARNING CODE: 20,70,75 GENERIC DESCRIPTION: SILICONE IN SOLVENT (FI,S6,17,02) SECTION II - HAZARDOUS INGREDIENTS AS DEFINED IN 29 CFR 1910.1200 (CARCINOGENS IDENTIFIED WITH AN ASTERISK *) DOW CORNING(R) 3-5000 SILICONE CONST. COAT.-GRAY CONTAINS: NAPHTHA (STODDARD SOLVENT) %: 100 %: X: %: 25 %i TLV (UNITS): TLV (UNITS): TLV (UNITS): TLV (UNITS): TLV (UNITS): 20 PPM 300 PPM; PEL 500 PPM COMMENT: DOW CORNING(R) 3-5000 TLV IS DOW CORNING IH GUIDE BASED ON METHYL ETHYL KETONE OXIME FORMED DURING CURING ON EXPOSURE TO WATER, MOISTURE, HUMID AIR. SECTION III - EFFECTS OF OVEREXPOSURE EYE: MAY CAUSE TEMPORARY DISCOMFORT. SKIN: SINGLE, PROLONGED EXPOSURE (HOURS) CAUSES NO KNOWN EFFECT. SEVERAL REPEATED, PROLONGED EXPOSURES MAY CAUSE SLIGHT IRRITATION. MAY CAUSE SENSITIZATION-SEE COMMENTS BELOW. INHALATION: PROLONGED OVEREXP. MAY CAUSE DROWSINESS, IRRITATE RESP. SYSTEM AND CAUSE SLIGHT CHANGES IN BLOOD CHEMISTRY THAT SHOULD RAPIDLY REVERT TO NORMAL WHEN OVEREXPOSURE ENDS. ORAL: AMOUNTS TRANSFERRED TO THE MOUTH DURING NORMAL OPERATIONS SHOULD NOT CAUSE INJURY. SWALLOWING SUBSTANTIAL AMOUNTS MAY CAUSE SOME INJURY. COMMENTS: TOXICOLOGY STUDIES WITH LABORATORY ANIMALS INDICATE THAT REPEATED PROLONGED OVEREXPOSURE TO METHYL ETHYL KETONE OXIME CAUSES ALLERGIC SKIN SENSITIZATION IN ANIMALS. 00 086330 CONFmPNTTAI DOW CORNING CORPORATION MATERIAL SAFETY DATA SHEET MATL NAME: DOW CORNING(R) 3-5000 SILICONE CONST. COAT.-GRAY SECTION IV - EMERGENCY AND FIRST AID PROCEDURES EYES: FLUSH WITH WATER. SKIN: WIPE OFF AND FLUSH WITH WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS. INHALATION: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION IF ILL EFFECTS PERSIST. ORAL: GET MEDICAL ATTENTION IF LARGE AMOUNTS SWALLOWED. DO NOT INDUCE VOMITING. COMMENTS: IF SPONTANEOUS VOMITING OCCURS, KEEP HEAD LOWER THAN HIPS TO PREVENT ASPIRATION OF LIQUID INTO LUNGS. SECTION V - FIRE AND EXPLOSION DATA FLASH POINT (METHOD USED): CLOSED CUP ABOVE 100F/38C AUTOIGNITION: NOT DETERMINED. FLAMMABILITY LIMITS IN AIR : LOWER:1.2% UPPER:6.0% EXTINGUISHING MEDIA: WATER WATER FOG X C02 X DRY CHEMICAL X FOAM X OTHER SPECIAL FIRE FIGHTING PROCEDURES: SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING SHOULD BE WORN IN FIGHTING FIRES INVOLVING CHEMICALS UNUSUAL FIRE AND EXPLOSION HAZARDS: VAPORS ARE HEAVIER THAN AIR AND CAN TRAVEL ALONG GROUND TO REMOTE IGNITION SOURCES. COMMENTS: FLAMMABILITY LIMITS ARE APPROXIMATE. SECTION VI - PHYSICAL DATA BOILING POINT(AT 760 MM HG): NOT APPLICABLE SPECIFIC GRAVITY (AT 77 DEG F/25 DEG C): 1.15 MELTING POINT: NOT APPLICABLE VAPOR PRESSURE (AT 77 DEG F/25 DEG C): 15 MM VAPOR DENSITY (AIR = 1 AT 77 DEG F/25 DEG C): 3.8 PERCENT VOLATILE BY WEIGHT (%): 25 EVAPORATION RATE (ETHER = 1): LESS THAN 1 SOLUBILITY IN WATER(%): LESS THAN 0.1% ODOR, APPEARANCE, COLOR: SOLVENT ODOR, LIQUID, GRAY. NOTE: THE ABOVE INFORMATION IS NOT INTENDED FOR USE IN PREPARING PRODUCT SPECIFICATIONS. CONTACT DOW CORNING BEFORE WRITING SPECIFICATIONS. 00 V&6331 con ftde-nttai. nOW CORNING CORPORATION MATERIAL SAFETY DATA SHEET MATL NAME: DOW CORNING(R) 3-5000 SILICONE CONST. COAT.-GRAY SECTION VII - REACTIVITY DATA STABILITY: STABLE INCOMPATABILITYCMATERIAL TO AVOID): OXIDIZING MATERIAL CAN CAUSE A REACTION. WATER, MOISTURE, HUMID AIR-CAUSE CURING. CONDITIONS TO AVOID: EXPOSURE TO WATER, MOISTURE, HUMID AIR UNTIL READY TO USE. HAZARDOUS DECOMPOSITION PRODUCTS: METAL OXIDES, SILICON DIOXIDE, CARBON DIOXIDE AND TRACES OF INCOMPLETELY BURNED CARBON PRODUCTS. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: NOT APPLICABLE COMMENTS: NONE. SECTION VIII - SPILL, LEAK, MAINTENANCE/REPAIR AND DISPOSAL PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: USE ABSORBENT MATERIAL TO COLLECT AND CONTAIN FOR SALVAGE OR DISPOSAL. REMOVE ALL SOURCES OF IGNITION AND WEAR PROPER PROTECTION EQUIPMENT. PROTECTIVE EQUIPMENT: EYES: USE PROPER PROTECTION -- SAFETY GLASSES, AS A MINIMUM. SKIN: AVOID CONTACT BY USING IMPERVIOUS PROTECTIVE CLOTHING, RUBBER OR PLASTIC GLOVES AS A MINIMUM, AND WASH IMMEDIATELY UPON ANY DETECTABLE CONTACT. INHALATION: USE RESPIRATORY PROTECTION UNLESS LOCAL EXHAUST VENTILATION IS ADEQUATE OR AIR SAMPLING DATA SHOW EXPOSURES ARE WITHIN TLV AND PEL GUIDELINES. WASTE DISPOSAL METHOD: DOW CORNING SUGGESTS THAT ALL LOCAL, STATE AND FEDERAL REGULATIONS CONCERNING HEALTH AND POLLUTION BE REVIEWED TO DETERMINE APPROVED DISPOSAL PROCEDURES. CONTACT DOW CORNING IF THERE ARE ANY DISPOSAL QUESTIONS. D.O.T. (49CFR 171.8)/E.P.A. (40CFR 117) SPILL REPORTING INFORMATION HAZARDOUS SUBSTANCE: NONE REPORTABLE QUANTITY: NOT APPLICABLE CONCENTRATION OF HAZARDOUS SUBSTANCE: NOT APPLICABLE REPORTABLE QUANTITY OF PRODUCT: NOT APPLICABLE COMMENTS; NONE DO DO/vp- r^T TAl DOW CORNING CORPORATION MATERIAL SAFETY DATA SHEET MATL NAME: DOW CORNING(R) 3-5000 SILICONE CONST. COAT.-GRAY SECTION IX - ROUTINE HANDLING PRECAUTIONS PROTECTIVE EQUIPMENT: EYES: USE PROPER PROTECTION -- SAFETY GLASSES, AS A MINIMUM. SKIN *: AVOID CONTACT BY USING IMPERVIOUS PROTECTIVE CLOTHING, RUBBER OR PLASTIC GLOVES AS A ilINTMUM, AND WASH IMMEDIATELY UPON ANY DETECTABLE CONTACT. INHALATION: USE RESPIRATORY PROTECTION UNLESS LOCAL EXHAUST VENTILATION IS ADEQUATE OR AIR SAMPLING DATA SHOW EXPOSURES ARE WITHIN TLV AND PEL GUIDELINES. VENTILATION: LOCAL EXHAUST: RECOMMENDED MECHANICAL (GENERAL): RECOMMENDED SUITABLE RESPIRATOR: ORGANIC VAPOR TYPE. THESE PRECAUTIONS ARE FOR ROOM TEMPERATURE HANDLING; USE AT ELEVATED TEMPERATURES, OR AEROSOL/SPRAY APPLICATIONS, MAY REQUIRE ADDED PRECAUTIONS. * GOOD PRACTICE REQUIRES THAT GROSS AMOUNT OF ANY CHEMICAL BE REMOVED FROM THE SKIN AS SOON AS PRACTICAL, ESPECIALLY BEFORE EATING OR SMOKING. COMMENTS: AVOID BREATHING VAPORS AND EYE AND SKIN CONTACT. USE ONLY WITH ADEQUATE VENTILATION. DO NOT TAKE INTERNALLY. SECTION X - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: KEEP CONTAINER CLOSED AND AWAY FROM HEAT, SPARKS, AND OPEN FLAME. OTHER PRECAUTIONS: THIS PRODUCT LIBERATES METHYL ETHYL KETOXIME (MEKO) WHEN EXPOSED TO WATER OR HUMID AIR. PROVIDE ADEQUATE VENTILATION DURING PROCESSING TO PREVENT MEKO VAPORS ABOVE 20 PPM (DOW CORNING EXPOSURE GUIDELINE) OR USE RESPIRATORY PROTECTION. COMMENTS: STATIC ELECTRICITY MAY ACCUMULATE AND CREATE A FIRE HAZARD. GROUND FIXED EQUIPMENT. BOND AND GROUND TRANSFER CONTAINERS AND EQUIPMENT. THESE DATA ARE OFFERED IN GOOD FAITH AS TYPICAL VALUES AND NOT AS A PRODUCT SPECIFICATION. NO WARRANTY, EITHER EXPRESSED OR IMPLIED, IS HEREBY MADE. THE RECOMMENDED INDUSTRIAL HYGIENE AND SAFE HANDLING PROCEDURES ARE BELIEVED TO BE GENERALLY APPLICABLE. HOWEVER, EACH USER SHOULD REVIEW THESE RECOMMENDATIONS IN THE SPECIFIC CONTEXT OF THE INTENDED USE AND DETERMINE WHETHER THEY ARE APPROPRIATE. PREPARED BY: JACK L. SHENEBERGER LAST REVISION DATE: DECEMBER 19, 1986 PREVIOUS REVISION DATE: OCTOBER 07, 1985 DATE: MARCH 17, 1988 (R) INDICATES REGISTERED OR TRADEMARK OF THE DOW CORNING CORPORATION. DO 086333 f OF.NTIAL C.ONF DOW CHEMICAL U.S.A. MR. KEITH STEVENS LOUISIANA HIGHWAY I PLAQUEMINE, LA 70765 MR. KEITH STEVENS DOW CORNING CORPORATION MATERIAL SAFETY DATA SHEET MATL NAME: DOW CORNING(R) 5700 ANTIMICROBIAL AGENT EMERGENCY TELEPHONE NO. (517) 496-5900 ...................................................... SECTION!"-"gEnERAl'iNFORMATION............................................................ MANUFACTURER'iNAMEtDOWCORNINGCORPORATION.................................................................................. ADDRESS: SOUTH SAGINAW ROAD, MIDLAND MI 48686 PROPER SHIPPING NAME(49CFR 172.101): FLAMMABLE LIQUID NOS D.O.T. HAZARD NAME(49CFR 172.101): METHANOL D.O.T. ID N0(49CFR 172.101): UN 1993 D. O.T. HAZARD CLASS(49CFR 172.101); FLAMMABLE LIQUID RCRA HAZARD CLAS5(40CFR 261)I IF DISCARDED): 1GNITABLE (D001), F003 E. P.A. PRIORITY POLLUTANTS(40CFR 122.53): NONE NFPA = NATIONAL FIRE PROTECTION ASSOCIATION 704 HEALTH (NFPA): 1 FLAMMABILITY (NFPA): 3 REACTIVITY (NFPA): 0 CAS NO: MIXTURE DOW CORNING WARNING CODE: NOT USED GENERIC DESCRIPTION: ORGANOSILANE IN SOLVENT SECTION II - HAZARDOUS INGREDIENTS AS DEFINED IN 29 CFR 1910.1200 (CARCINOGENS IDENTIFIED WITH AN ASTERISK *) CAS NO. INGREDIENT 000067561 METHANOL (METHYL ALCOHOL) 002530872 (3-CHLOROPROPYLJTRIMETHOXYSILANE 027668526 3-(TRIMETH0XYSILYL}PROPYLDIMETHYLOCTADECYL AMMONIUM CHLORIDE WT.X 50 42 EXPOSURE LIMITS OSHA PEL: TWA 200 PPM ACGIH TLV-SKIN: TWA 200 PPM, STEL 250 PPM OBSERVE ABOVE LIMITS FOR METHANOL, FORMED ON EXPOSURE TO WATER OR HUMID AIR. OBSERVE ABOVE LIMITS FOR METHANOL, FORMED ON EXPOSURE TO WATER OR HUMID AIR. DO 006334 OONFTDFNTTAl DOW CORNING CORPORATION MATERIAL SAFETY DATA SHEET MATL NAME: DOW CORNING(R) 5700 ANTIMICROBIAL AGENT SECTION III - EFFECTS OF OVEREXPOSURE EYE: DIRECT CONTACT BURNS EYES WITH POSSIBLE PERMANENT INJURY, EVEN BLINDNESS. MIST MAY IRRITATE AND CAUSE PAIN AND WATERING. SKIN: A SINGLE RELATIVELY SHORT EXPOSURE (LESS THAN 24 HOURS) IRRITATES. REPEATED PROLONGED CONTACT (24 TO 48 HOURS) IRRITATES SERIOUSLY, MAY BURN MILDLY, INHALATION: MIST MAY IRRITATE NOSE AND THROAT. MAY CAUSE BLINDNESS, EVEN DEATH. ORAL: SWALLOWING SMALL AMOUNTS MAY CAUSE BLINDNESS, EVEN DEATH. COMMENTS: NO KNOWN ADVERSE CHRONIC HEALTH EFFECTS, BUT UNNECESSARY EXPOSURE TO ANY CHEMICAL SHOULD BE AVOIDED. THIS PRODUCT, AS WITH ANY CHEMICAL, MAY ENHANCE ALLERGIC CONDITIONS ON CERTAIN PEOPLE. WE DO NOT KNOW OF ANY MEDICAL CONDITIONS THAT MIGHT BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. SECTION IV - EMERGENCY AND FIRST AID PROCEDURES EYES: IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES. GET IMMEDIATE MEDICAL ATTENTION. SKIN: WIPE OFF AND FLUSH WITH WATER FOR 15 MINUTES. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS. INHALATION: REMOVE TO FRESH AIR. GET IMMEDIATE MEDICAL ATTENTION. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. GIVE OXYGEN IF BREATHING IS DIFFICULT. ORAL: GET IMMEDIATE MEDICAL ATTENTION. IF CONSCIOUS, INDUCE VOMITING. LIE DOWN, KEEP WARM, AND COVER EYES TO EXCLUDE LIGHT. COMMENT: TREAT SAME AS FOR METHANOL POISONING. SECTION V - FIRE AND EXPLOSION DATA FLASH POINT (METHOD USED): CLOSED CUP, 52F/11C AUTOIGNITION: ABOVE 800 F - BASED ON METHANOL. FLAMMABILITY LIMITS IN AIR : LOWER:6X UPPER: 36X EXTINGUISHING MEDIA: WATER WATER FOG X C02 X DRY CHEMICAL X FOAM X OTHER SPECIAL FIRE FIGHTING PROCEDURES: SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING SHOULD BE WORN IN FIGHTING FIRES INVOLVING CHEMICALS UNUSUAL FIRE AND EXPLOSION HAZARDS: VAPORS ARE HEAVIER THAN AIR AND CAN TRAVEL ALONG GROUND TO REMOTE IGNITION SOURCES. HAZARDOUS CHLORINE COMPOUNDS FORM. COMMENTS: FLAMMABILITY LIMITS ARE ESTIMATES BASED ON METHANOL. SECTION VI - PHYSICAL DATA BOILING POINT(i'760*MM HG):i47F/64C~(METHANOL).............................................................. SPECIFIC GRAVITY (AT 77 DEG F/25 DEG C): 0.88 MELTING POINT: NOT APPLICABLE VAPOR PRESSURE (AT 77 DEG F/25 DEG C): 100 MM VAPOR DENSITY (AIR = 1 AT 77 DEG F/25 DEG C): ABOVE ONE PERCENT VOLATILE BY WEIGHT (X): 58 EVAPORATION RATE (ETHER 1): LESS THAH ONE SOLUBILITY IN WATER(X): GREATER THAN 90 ODOR, APPEARANCE, COLOR: SOLVENT ODOR, LIQUID, VERY LITTLE COLOR. NOTE: THE ABOVE INFORMATION IS NOT INTENDED FOR USE IN PREPARING PRODUCT SPECIFICATIONS. CONTACT DOW CORNING BEFORE WRITING SPECIFICATIONS 00 086335 CONFIDENTIAL DOW CORNING CORPORATION MATERIAL SAFETY DATA SHEET MATL NAME: DOW CORNING(R) 5700 ANTIMICROBIAL AGENT STABILITY: STABLE SECTION VII - REACTIVITY DATA INCOMPATABlLITYfMATERIAL TO AVOID): OXIDIZING MATERIAL CAN CAUSE A REACTION. WATER OR HUMID AIR. CONDITIONS TO AVOID: EXPOSURE TO WATER OR AIR UNTIL READY TO USE. HAZARDOUS DECOMPOSITION PRODUCTS: NITROGEN OXIDES, CHLORINE COMPOUNDS. SILICON DIOXIDE. CARBON DIOXIDE, AND TRACES OF INCOMPLETELY BURNED CARBON PRODUCTS. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: NOT APPLICABLE COMMENTS: NONE SECTION VIII SPILL, LEAK, MAINTENANCE/REPAIR AND DISPOSAL PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: USE ABSORBENT MATERIAL TO COLLECT AND CONTAIN FOR SALVAGE OR DISPOSAL. REMOVE ALL SOURCES OF IGNITION AND WEAR PROPER PROTECTION EQUIPMENT. PROTECTIVE EQUIPMENT: EYES: USE CHEMICAL WORKER GOGGLES. SKIN: WASHING AT MEALTIME AND END OF SHIFT IS ADEQUATE. REMOVE CONTAMINATED CLOTHING AND SHOES AS SOON AS PRACTICAL AND CLEAN THOROUGHLY BEFORE REUSE. RUBBER OR PLASTIC GLOVES ARE RECOMMENDED. INHALATION: USE RESPIRATORY PROTECTION UNLESS LOCAL EXHAUST VENTILATION IS ADEQUATE OR AIR SAMPLING DATA SHOW EXPOSURES ARE WITHIN TLV AND PEL GUIDELINES. WASTE DISPOSAL METHOD: DOW CORNING SUGGESTS THAT ALL LOCAL, STATE AND FEDERAL REGULATIONS CONCERNING HEALTH AND POLLUTION BE REVIEWED TO DETERMINE APPROVED DISPOSAL PROCEDURES. CONTACT DOW CORNING IF THERE ARE ANY DISPOSAL QUESTIONS. D.O.T. (49CFR 171.8)/E.P.A. (40CFR 117) SPILL REPORTING INFORMATION HAZARDOUS SUBSTANCE: METHANOL REPORTABLE QUANTITY: 5,000 LBS. CONCENTRATION OF HAZARDOUS SUBSTANCE: 50X REPORTABLE QUANTITY OF PRODUCT: 10,000 LBS. COMMENTS: RELEASES OF REPORTABLE QUANTITIES OF THE ABOVE HAZARDOUS SUBSTANCES BEYOND FACILITY BOUNDARIES MAY BE REPORTABLE TO STATE OR LOCAL EMERGENCY RESPONSE AUTHORITIES UNDER TITLE III OF "SARA", THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986, SECTION 304. SEE 40CFR, PART 300, SUBPART I-EMERGENCY PLANNING AND COMMUNITY RIGHT TO KNOW. METHANOL, CAS NO. 67-56-1, IS A TOXIC CHEMICAL ALSO REPORTABLE UNDER SECTION 313 AND 40CFR PART 372. THIS PRODUCT IS TOXIC TO FISH. DO NOT DISCHARGE INTO LAKES, STREAMS, PONDS, OR PUBLIC WATERS UNLESS IN ACCORDANCE WITH NPDES PERMIT. CONTACT REGIONAL EPA OFFICE FOR GUIDANCE. oo 086336 CONFI^NT I Al. DOW CORNING CORPORATION MATERIAL SAFETY DATA SHEET HATL NAME: DOW CORNING(R) S700 ANTIMICROBIAL AGENT SECTION IX - ROUTINE HANDLING PRECAUTIONS PROTECTIVE EQUIPMENT: EYES: USE CHEMICAL WORKER GOGGLES. SKIN *: WASHING AT MEALTIME AND END OF SHIFT IS ADEQUATE. REMOVE CONTAMINATED CLOTHING AND SHOES AS SOON AS PRACTICAL AND CLEAN THOROUGHLY BEFORE REUSE. RUBBER OR PLASTIC GLOVES ARE RECOMMENDED. INHALATION: USE RESPIRATORY PROTECTION UNLESS LOCAL EXHAUST VENTILATION IS ADEQUATE OR AIR SAMPLING DATA SHOW EXPOSURES ARE WITHIN TLV AND PEL GUIDELINES. VENTILATION: LOCAL EXHAUST: RECOMMENDED MECHANICAL (GENERAL): RECOMMENDED SUITABLE RESPIRATOR: AIR-SUPPLIED OR SELF-CONTAINED. THESE PRECAUTIONS ARE FOR ROOM TEMPERATURE HANDLING. USE AT ELEVATED TEMFERATURES, OR AEROSOL/SPRAY APPLICATIONS. HAY REQUIRE ADDED PRECAUTIONS. * GOOD PRACTICE REQUIRES THAT GROSS AMOUNT OF ANY CHEMICAL BE REMOVED FROM THE SKIN AS SOON AS PRACTICAL, ESPECIALLY BEFORE EATING OR SMOKING. COMMENTS: DO NOT GET IN EYES, ON SKIN. OR ON CLOTHING. USE ONLY WITH ADEQUATE VENTILATION. DO NOT TAKE INTERNALLY. SECTION X - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: KEEP CONTAINER CLOSED AND AWAY FROM WATER, HEAT, SPARKS, AND OPEN FLAME. STORE BELOW 100F. OTHER PRECAUTIONS: STATIC ELECTRICITY MAY ACCUMULATE AND CREATE A FIRE HAZARD. GROUND FIXED EQUIPMENT. BOND AND GROUND TRANSFER CONTAINERS AND EQUIPMENT. COMMENTS: IRRITATING PROPERTIES OF METHANOL ARE INADEQUATE TO PREVENT OVER EXPOSURE. SECTION XI - COMMENTS REGULATORY COMPLIANCE: PRODUCT IS AN EPA REGISTERED PESTICIDE, AND ITS USE IS STRICTLY REGULATED BY THE FEDERAL INSECTICIDE, FUNGICIDE AND RODENTICIDE ACT, EPA REGULATIONS IN 40 CFR PARTS 150-180, AND LAWS AND REGULATIONS OF INDIVIDUAL STATES. YOU, THE USER, MUST BE CERTAIN THAT YOUR USE OF THIS PRODUCT IS IN FULL COMPLIANCE WITH THESE AND ANY OTHER APPROPRIATE GOVERNMENTAL REGULATIONS. THESE DATA ARE OFFERED IN GOOD FAITH AS TYPICAL VALUES AND NOT AS A PRODUCT SPECIFICATION. NO WARRANTY, EITHER EXPRESSED OR IMPLIED, IS HEREBY MADE. THE RECOMMENDED INDUSTRIAL HYGIENE AND SAFE HANDLING PROCEDURES ARE BELIEVED TO BE GENERALLY APPLICABLE. HOWEVER, EACH USER SHOULD REVIEW THESE RECOMMENDATIONS IN THE SPECIFIC CONTEXT OF THE INTENDED USE AND DETERMINE WHETHER THEY ARE APPROPRIATE. PREPARED BY: JACK L. SHENEBERGER LAST REVISION DATE: DECEMBFR 12, 19R8 PREVIOUS REVISION DATE: SEPTEMBER 25, 1985 DATE: DECEMBER 23, 1988 (R) INDICATES REGISTERED OR TRADEMARK OF THE DOW CORNING CORPORATION. DOW CHEMICAL CO, ATTN: VERN AMAR P.O. BOX 150 BLDG. 2307 PLAQUEMINE, LA 7076* DOW CORNING CORPORATION MATERIAL SAFETY DATA SHEET MATL NAME: DOW CORNINGCR) 36 EMULSION EMERGENCY TELEPHONE NO. (517) *96-5900 SECTION I - GENERAL INFORMATION MANUFACTURERS NAME: DOW CORNING CORPORATION ADDRESS: SOUTH 5AGINAW ROAD, MIDLAND MI *8686 PROPER SHIPPING NAMECA9CFR 172.101): NONE D.O.T. HAZARD NAMEC *9CFR 172.101): NONE D.O.T. ID NO(A9CFR 172.101): NONE D. O.T. HAZARD CLASSCA9CFR 172.101): NONE RCRA HAZARD CLASSCAOCFR 26DCIF DISCARDED): NONE E. P.A. PRIORITY POLLUTANTSCAOCFR 122.53): NONE NFPA = NATIONAL FIRE PROTECTION ASSOCIATION - 70* HEALTH (NFPA): 1 FLAMMABILITY (NFPA): 1 REACTIVITY (NFPA): o CAS NO: MIXTURE DOW CORNING WARNING CODE: 76 GENERIC DESCRIPTION: SILICONE EMULSION SECTION II - HAZARDOUS INGREDIENT NONE PRESENT % TLV (UNITS)* ONLY THOSE INGREDIENTS LISTED IN THIS SECTION HAVE BEEN DETERMINED TO BE HAZARDOUS AS DEFINED IN 29 CFR 1910.1200. AN INGREDIENT MARKED WITH AN ASTERISKS) IS ALSO LISTED IN 29 CFR 1910.1200(D) #* AS KNOWN OR SUSPECTED CARCINOGEN. COMMENT:NONE DO 08033 CONFIDENTIAL. DOW CORNING CORPORATION MATERIAL SAFETY DATA SHEET MATL NAME: DOM CORNINGCR) 36 EMULSION SECTION III - EFFECTS OF OVEREXPOSURE EYES: MAY CAUSE TEMPORARY DISCOMFORT. SKIN: SINGLE* PROLONGED EXPOSURE (HOURS) CAUSES NO KNOMN EFFECTS. SEVERAL REPEATED, PROLONGED EXPOSURES MAY CAUSE SLIGHT IRRITATION. INHALATION: NO IRRITATION TO NOSE OR THROAT EXPECTED. NO INJURY IS LIKELY FROM RELATIVELY SHORT EXPOSURES. ORAL: AMOUNTS TRANSFERRED TO THE MOUTH BY FINGERS, ETC., DURING NORMAL OPERATIONS SHOULD NOT CAUSE INJURY. COMMENT: NO KNOMN ADVERSE CHRONIC HEALTH EFFECTS, BUT UNNECESSARY EXPOSURE TO ANY CHEMICAL SHOULD BE AVOIDED. THIS PRODUCT, AS MITH ANY CHEMICAL, MAY ENHANCE ALLERGIC CONDITIONS ON CERTAIN PEOPLE. ME DO NOT KNOM OF ANY MEDICAL CONDITIONS THAT MIGHT BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. SECTION IV - EMERGENCY AND FIRST AID PROCEDURES EYES: FLUSH MITH MATER. SKIN: MIPE OFF AND FLUSH MITH MATER. INHALATION: NO PROBLEM. ORAL: NO PROBLEM. COMMENT: NONE. SECTION V - FIRE AND EXPLOSION DATA FLASH POINT (METHOD USED): OPEN CUP/CLOSED CUP - NONE AUTOIGNITION: NOT DETERMINED FLAMMABILITY LIMITS IN AIR : LOMER:N.D. UPPER: N.D. EXTINGUISHING MEDIA: MATER HATER FOG X C02 X DRY CHEMICAL X FOAM X OTHER SPECIAL FIRE FIGHTING PROCEDURES: SELF_CONTAINED BREATHING APPRARATUS AND PROTECTIVE CLOTHING SHOULD BE MORN IN FIGHTING FIRES INVOLVING CHEMICALS UNUSUAL FIRE AND EXPLOSION HAZARDS: NONE KNOMN TO DOM CORNING COMMENTS: n.D. - NOT DETERMINED. SECTION VI - PHYSICAL DATA BOILING POINTO 760 MM HG): 212F/100C SPECIFIC GRAVITY (AT 77 DEG F/25 DEG C): 1.0 MELTING POINT: NOT APPLICABLE VAPOR PRESSURE (AT 77 DEG F/25 DEG C): 30 MM VAPOR DENSITY (AIR = 1 AT 77 DEG F/25 DEG C): NOT APPLICABLE PERCENT VOLATILE BY VOLUME (X): ABOVE 40% EVAPORATION RATE (ETHER =1): LESS THAN 1 SOLUBILITY IN WATER(X): GREATER THAN 90X ODOR, APPEARANCE, COLOR: VERY LITTLE ODOR, LIQUID, HHITE COLOR NOTE: THE ABOVE INFORMATION IS NOT INTENDED FOR USE IN PREPARING PRODUCT SPECIFICATIONS. CONTACT DOM CORNING BEFORE HRITING SPECIFICATIONS DO 086339 CONFIDFNTTAl DOW CORNING CORPORATION MATERIAL SAFETY DATA SHEET MATL NAME: DOW CORNING(R) 36 EMULSION SECTION VII - REACTIVITY DATA STABILITY: STABLE INCOMPATABILITY(MATERIAL TO AVOID): OXIDIZING MATERIAL CAN CAUSE A REACTION. CONDITIONS TO AVOID: NOT APPLICABLE HAZARDOUS DECOMPOSITION PRODUCTS: SILICON DIOXIDE, CARBON DIOXIDE, AND TRACES OF INCOMPLETELY BURNED CARBON PRODUCTS. HAZARDOUS POLYMERIZATION: WILL NOT OCCUR CONDITIONS TO AVOID: NOT APPLICABLE COMMENTS: NONE SECTION VIII - SPILL, LEAK AND DISPOSAL PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: USE ABSORBENT MATERIAL TO COLLECT AND CONTAIN FOR SALVAGE OR DISPOSAL. PROTECTIVE EQUIPMENT: EYES: USE PROPER PROTECTION -- SAFETY GLASSES, AS A MINIMUM. SKIN: WASHING AT MEALTIME AND END OF SHIFT IS ADEQUATE. INHALATION: NO RESPIRATORY PROTECTION REQUIRED. WASTE DISPOSAL METHOD: DOW CORNING SUGGESTS THAT ALL LOCAL,STATE AND FEDERAL REGULATIONS CONCERNING HEALTH AND POLLUTION BE REVIEWED TO DETERMINE APPROVED DISPOSAL PROCEDURES. CONTACT DOW CORNING IF THERE ARE ANY DISPOSAL QUESTIONS. D.O.T. CA9CFR 171.8)/E.P.A. C40CFR 117) SPILL REPORTING INFORMATION HAZARDOUS SUBSTANCE: NONE REPORTABLE QUANTITY: NOT APPLICABLE CONCENTRATION OF HAZARDOUS SUBSTANCE: NOT APPLICABLE REPORTABLE QUANTITY OF PRODUCT: NOT APPLICABLE COMMENTS: NONE SECTION IX - ROUTINE HANDLING PRECAUTIONS PROTECTIVE EQUIPMENT: EYES: USE PROPER PROTECTECTION -- SAFETY GLASSES, AS A MINIMUM. SKIN *: WASHING AT MEALTIME AND END OF SHIFT IS ADEQUATE. INHALATION: NO RESPIRATORY PROTECTION REQUIRED. VENTILATION: LOCAL EXHAUST: NONE MECHANICAL (GENERAL): RECOMMENDED SUITABLE RESPIRATOR: NO RESPIRATORY PROTECTION REQUIRED. THESE PRECAUTIONS ARE FOR ROOM TEMPERATURE HANDLING, USE AT ELEVATED TEMPERATURE MAY REQUIRE ADDED PRECAUTIONS. x GOOD PRACTICE REQUIRES THAT GROSS AMOUNT OF ANY CHEMICAL BE REMOVED FROM THE SKIN AS SOON AS PRACTICAL, ESPECIALLY BEFORE EATING OR SMOKING. COMMENTS: NONE SECTION X - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: KEEP FROM FREEZING. USE REASONABLE CARE AND CAUTION. OTHER PRECAUTIONS: NONE KNOWN TO DOW CORNING. COMMENTS: NONE. DO 086340 CONFIDFNTTAL. DOW CORNING CORPORATION MATERIAL SAFETY DATA SHEET MATL NAME: DOW CORNINGCR) 36 EMULSION THESE DATA ARE OFFERED IN GOOD FAITH AS TYPICAL VALUES AND NOT AS A PRODUCT SPECIFICATION. NO WARRANTY, EITHER EXPRESSED OR IMPLIED, IS HEREBY MADE. THE RECOMMENDED INDUSTRIAL HYGIENE AND SAFE HANDLING PROCEDURES ARE BELIEVED TO BE GENERALLY APPLICABLE. HOWEVER, EACH USER SHOULD REVIEW THESE RECOMMENDATIONS IN THE SPECIFIC CONTEXT OF THE INTENDED USE AND DETERMINE WHETHER THEY ARE APPROPRIATE. PREPARED BY* JACK L. SHENEBERGER LAST REVISION DATE1 OCTOBER 01, 1985 PREVIOUS REVISION DATE: DECEMBER 02, 1980 DATE: JULY 31, 1987 (R) INDICATES REGISTERED OR TRADEMARK OF THE DOW CORNING CORPORATION. DO 086341 CONFIDENTIAL Material Safety Data Sheet Dow U.S.A The Dow Chemical Company Midland, Michigan 48674 Dow Chemical U.S.A.* Midland, MI 48674 Emergency Phone: 517-636-4400 Product code: 21100 Page: 1 Product Name: DIETHANOLAMINE - COMMERCIAL GRADE Effective Date: 12/20/90 Date Printed: 11/04/91 MSDS:000069 1. INGREDIENTS: (X w/w, unless otherwise noted) Diethanolamine CAS# 000111-42-2 99.0% This document is prepared pursuant to the OSHA Hazard Communication Standard (29 CFR 1910.1200). In addition, other substances not 'Hazardous' per this OSHA Standard may be listed. Where proprietary ingredient shows, the identity may be made available as provided in this standard. 2. PHYSICAL DATA: BOILING POINT: 514F, 268C VAP PRESS: Low VAP DENSITY: Not determined. SOL. IN WATER: Completely miscible. SP. GRAVITY: 1.09 @ 30/4C FREEZING POINT: 82F, 28C. APPEARANCE: Colorless. ODOR: Slight ammoniacal odor. 3. FIRE AND EXPLOSION HAZARD DATA: FLASH POINT: 325F, 1&3C METHOD USED: Setaflash. FLAMMABLE LIMITS LFL: Not determined UFL: Not determined EXTINGUISHING MEDIA: Water fog, alcohol foam, C02, dry chemical. FIRE EXPLOSION HAZARDS: Not available. FIRE-FIGHTING EQUIPMENT: Wear self-contained, positive-pressure breathing apparatus, 4. REACTIVITY DATA: STABILITY: (CONDITIONS TO AVOID) Stable under normal storage conditions. (Continued on page 2 , over) (R) Indicates a Trademark of The Dow Chemical Company * An Operating Unit of The Dow Chemical Company r>Q 06634? conftoential Printed on Recycled and Recyclable Paper Dow Chemical U.S.A.* Midland, MI 48674 Emergency Phone: 517~636~4400 Product code: 21100 Page: 2 Product Name: DIETHANOLAMINE - COMMERCIAL GRADE Effective Date: 12/20/90 Date Printed: 11/0L/91 MSDS:000069 4. REACTIVITY DATA: (CONTINUED) INCOMPATIBILITY: (SPECIFIC MATERIALS TO AVOID) Strong oxidizers, strong acids. Product may potentially react with various halogenated organic solvents, resulting in temperature and/or pressure increases. HAZARDOUS DECOMPOSITION PRODUCTS: Possible nitrogen oxides. This product should not be heated above 60C in the presence of aluminum due to excessive corrosion and potential chemical reaction releasing flammable hydrogen gas. HAZARDOUS POLYMERIZATION: Will not occur. 5. ENVIRONMENTAL AND DISPOSAL INFORMATION: ACTION TO TAKE FOR SPILLS/LEAKS: Soak up with absorbent material or sand. Scoop into waste containers. DISPOSAL METHOD: Burn in approved incinerator. Follow all local, state, and federal requirements for disposal. 6. HEALTH HAZARD DATA: EYE: May cause severe irritation with corneal injury. SKIN CONTACT: Prolonged or repeated exposure may cause skin irritation, even a burn. DOT classification: non-corrosive. SKIN ABSORPTION: A single prolonged exposure is not likely to result in the material being absorbed through skin in harmful amounts. The LD50 for skin absorption in rabbits is approximately 12,000 mg/kg. INGESTION: Single dose oral toxicity is low. The oral LD50 for rats is between 710-1820 mg/kg. Small amounts swallowed incidental to normal handling operations are not likely to cause injury; swallowing amounts larger than that may cause i njury. INHALATION: At room temperature, exposures to vapors are unlikely due to physical properties; higher temperatures may generate vapor levels sufficient to cause irritation and other effects. Excessive exposure may cause liver and kidney injury. SYSTEMIC (OTHER TARGET ORGAN) EFFECTS: Results from repeated (Continued on page 3) (R) Indicates a Trademark of The Dow Chemical Company* * An Operating Unit of The Dow Chemical Company DO 086343 CONFTDFNTT Al. Dow Chemical U.S.A.* Midland, MI 48674 Emergency Phone: 517-636-4400 Product code: 21100 Page: 3 Product Name: DIETHANOLAMINE - COMMERCIAL GRADE Effective Date: 12/20/90 Date Printed: 11/0V91 M$D$:000069 6. HEALTH HAZARD DATA: (CONTINUED) exposure tests in laboratory animals include anemia (rats) and effects on kidney (rats and mice) and liver (mice). Heart and nervous system effects were also observed in these animals given exaggerated doses. Changes in other organs, causes of which are non-specific, were judged secondary to the poor health of the animals due to the extremely high doses given. MUTAGEN I CITY (EFFECTS ON GENETIC MATERIAL): Results of in vitro (test tube) mutagenicity tests have been negative. 7. FIRST AID: EYES: Irrigate with flowing water immediately and continuously for 15 minutes. Consult medical personnel, SKIN: Wash off in flowing water or shower. INGESTION: Induce vomiting if large amounts are ingested. Consult medical personnel. INHALATION: Remove to fresh air if effects occur. Consult medical personnel. NOTE TO PHYSICIAN: If burn is present, treat as any thermal burn, after decontamination. No specific antidote. Supportive care. Treatment based on judgment of the physician in response to reactions of the patient. Repeated excessive exposure may aggravate preexisting liver and kidney disease. 8. HANDLING PRECAUTIONS: EXPOSURE GUIDELINE (S) : 0SHA PEL and ACGIH TLV are 3 ppm. VENTILATION: Provide general and/or local exhaust ventilation to control airborne levels below the exposure guidelines. RESPIRATORY PROTECTION: Atmospheric levels should be maintained below the exposure guideline. When respiratory protection is required for certain operations, use an approved air-purifying respirator. SKIN PROTECTION: Use protective clothing impervious to this material. Selection of specific items such as gloves, boots, apron, or full-body suit will depend on operation. (Continued on page k , over) (R) Indicates a Trademark of The Dow Chemical Company < An Operating Unit of The Dow Chemical Company DO 086344 CONFIDFNTTAL Dow Chemical U.S.A.* Midland, MI 48674 Emergency Phone: 517-636-4400 Product code: 21100 Page: A Product Name: DIETHANOLAMINE - COMMERCIAL GRADE Effective Date: 12/20/90 Date Printed: 11/0A/91 MSDS:000069 8. HANDLING PRECAUTIONS: (CONTINUED) EYE PROTECTION: Use chemical goggles. 9. ADDITIONAL INFORMATION: SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Prevent eye contact. Avoid skin contact. Avoid breathing vapors if generated. Do not use sodium nitrite or other nitrosating agents in formulations containing this product. Suspected cancer-causing nitrosamines could be formed. MSDS STATUS: Revised sections 6, 8, 9 and Regulatory Information section. For information regarding state/provincial and federal regulations see The Regulatory Information Section. (R) Indicates a trademark of The Dow Chemical Company* * An Operating Unit of The Dow Chemical Company OO 086345 CONFTDFNTTAI. Dow Chemical U.S.A.* Midland, MI 48674 Emergency Phone: 517-636-4400 Product code: 21100 Page: R-l Product Name: DIETHANOLAMINE - COMMERCIAL GRADE Effective Date: 12/20/90 Date Printed: 11/04/91 MSDS:000069 REGULATORY INFORMATION: (Not meant to be all-inclusive--selected regulations represented.) NOTICE: The information herein is presented in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ from one location to another; it is the buyer's responsibility to ensure that its activities comply with federal, state or provincial, and local laws. The following specific information is made for the purpose of complying with numerous federal, state or provincial, and local laws and regulations. See MSD Sheet for health and safety information. U.S. REGULATIONS SARA 30 INFORMATION: This product contains the following substances subject to the reporting requirements of Section 30 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: CHEMICAL NAME CAS NUMBER CONCENTRATION DIETHANOLAMINE 000111-42-2 99 % SARA HAZARD CATEGORY: This product has been reviewed according to the EPA "Hazard Categories" promulgated under Sections 311 and 312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: An immediate health hazard A delayed health hazard CANADIAN REGULATIONS The Workplace Hazardous Materials Information System (W.H.M.I.S.) Classification for this product is: D2B The Transportation of Dangerous Goods Act (T.D.G.A.) classification for this product is: (Continued on page R-2 , over) (R) Indicates a Trademark of The Dow Chemical Company ft An Operating Unit of The Dow Chemical Company DO 086346 CONFTDFNTTAl Dow Chemical U.S.A.* Midland, MI 48674 Emergency Phone: 517-636-4400 Product code: 21100 Page: R-2 Product Name: DIETHANOLAMINE - COMMERCIAL GRADE Effective Date: 12/20/90 Date Printed: 11/0L/91 MSDS:000069 REGULATORY INFORMATION (CONTINUED) Not regulated. * (R) Indicates a Trademark of The Dow Chemical Company The Information Herein Is Given In Good Faith, But No Warranty, Express Or Implied, is Made. Consult The Dow Chemical Company For Further Information. * An Operating Unit of The Dow Chemical Company DO 086347 CONFTDFNT TA1.